WO2022170537A1 - Electronic device having through hole with high aspect ratio and forming method therefor, and electronic device - Google Patents

Electronic device having through hole with high aspect ratio and forming method therefor, and electronic device Download PDF

Info

Publication number
WO2022170537A1
WO2022170537A1 PCT/CN2021/076402 CN2021076402W WO2022170537A1 WO 2022170537 A1 WO2022170537 A1 WO 2022170537A1 CN 2021076402 W CN2021076402 W CN 2021076402W WO 2022170537 A1 WO2022170537 A1 WO 2022170537A1
Authority
WO
WIPO (PCT)
Prior art keywords
hole
holes
dielectric layer
section
layer
Prior art date
Application number
PCT/CN2021/076402
Other languages
French (fr)
Chinese (zh)
Inventor
范鲁明
焦慧芳
李檀
应成伟
王敬元璋
Original Assignee
华为技术有限公司
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 华为技术有限公司 filed Critical 华为技术有限公司
Priority to PCT/CN2021/076402 priority Critical patent/WO2022170537A1/en
Priority to CN202180086462.8A priority patent/CN116711474A/en
Publication of WO2022170537A1 publication Critical patent/WO2022170537A1/en

Links

Images

Classifications

    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10BELECTRONIC MEMORY DEVICES
    • H10B12/00Dynamic random access memory [DRAM] devices

Definitions

  • the present application relates to the field of storage technologies, and in particular, to an electronic device with a high aspect ratio through hole, a method for forming the same, and an electronic device.
  • DRAM dynamic random access memory
  • CPU central processing unit
  • hard disks external memory
  • the DRAM may include multiple word lines (WL) and multiple bit lines (bit lines, BL).
  • a memory cell is provided at the intersection of a WL and a BL, as shown in Figure 1.
  • a structure diagram of a memory cell is shown, the memory cell includes a transistor (transistor) and a capacitor (capacitor) electrically connected to the transistor, the transistor (transistor) is electrically connected to BL3 and WL4, wherein the transistor is used to control the relationship between BL3 and the capacitor. On or off between, capacitors are used to store charge.
  • transistors 12 are first prepared in the logic area and the storage area of the substrate 11, wherein the logic area is responsible for functions such as logic control and signal processing, and the storage area is responsible for data storage. Then, a wiring layer 14 is formed on the logic region, and the transistors 12 of the logic region and the wiring layer 14 of the logic region are connected to form a circuit structure. However, only the dielectric layer 13 is formed in the memory region. As shown in FIG. 2b, after the wiring layer 14 of the logic region is completed, the through hole 8 is formed in the dielectric layer 13 of the storage region. In conjunction with FIG. 2 c , the capacitor 2 is formed in the through hole 8 .
  • capacitors are connected to transistors located in this area to form 1T (transistor) 1C (capacitor) memory cells, and further, an embedded DRAM compatible with existing logic processes can be formed.
  • the storage capacity per unit area of the storage area increases, that is, the integration density of transistors and through holes in the storage area is increasing. Therefore, it is necessary to choose to reduce the opening size of the capacitor through hole and increase the hole depth.
  • the aspect ratio of the above-mentioned through hole (the ratio of h to d in Fig. 2b) needs to be made larger and larger, for example, d is several tens of nanometers, and h is about 1 micrometer.
  • d is several tens of nanometers
  • h is about 1 micrometer.
  • Embodiments of the present application provide an electronic device with a high aspect ratio through hole, a method for forming the same, and an electronic device, and the main purpose is to provide a method for opening a through hole with a high aspect ratio.
  • the present application provides a method for forming an electronic device, the method for forming an electronic device comprising: a first transistor on a substrate, where the first transistors may be multiple, and the first transistors may be fin transistors ; stacking a first dielectric layer on the substrate with the first transistor, the first dielectric layer may be one layer, or multiple layers stacked in sequence; opening through the first dielectric layer to the first transistor The first section of the through hole; filling material at least at a position close to the orifice of the first section of the through hole in the first section of the through hole, so that the filled material forms a temporary block for the orifice of the first section of the through hole Filling layer; stacking a second dielectric layer on the first dielectric layer, the second dielectric layer can be of the same material as the first dielectric layer; opening in the second dielectric layer to communicate with the first section of through holes remove the temporary filling layer, for example, by an etching process; and form a capacitor electrically connected to the first transistor in the connected first
  • a first section of through hole is first opened in the first dielectric layer, and then the first section of through hole is at least close to the first section of through hole in the first section of through hole.
  • a temporary filling layer is filled at the position of the hole, that is, the hole of the first section of the through hole is blocked, and then a second dielectric layer is formed on the first dielectric layer, and then the second dielectric layer is opened and The second section of through holes communicated with the first section of through holes.
  • each opening here can use a low aspect ratio opening technology, for example,
  • the opening process will not pose a great challenge.
  • opening a first segment of through hole in the first dielectric layer that penetrates to the first transistor includes: using dry etching from a surface of the first dielectric layer away from the substrate toward The first transistor opens a hole to form a first section of through hole with a conical structure, and the aperture size of the first section of through hole gradually decreases along the direction close to the substrate; a second section of through hole is opened in the second dielectric layer and communicated with the first section of through hole.
  • the second section of through holes includes: using dry etching to open holes from the surface of the second dielectric layer away from the first dielectric layer toward the first section of through holes to form a second section of through holes with a conical structure, the second section of through holes having a conical structure.
  • the aperture size of the segment through holes gradually decreases along the direction close to the substrate; wherein, the aperture diameter of one end of the second segment through hole close to the first segment through hole is smaller than the aperture diameter of the first segment through hole close to the second segment through hole. , so as to form a step at the junction of the through hole of the first section and the through hole of the second section.
  • the obvious difference is the difference between the first-stage through-holes and the second-stage through-holes. Steps are formed at the junction.
  • the thickness of the first dielectric layer is equal to the thickness of the second dielectric layer.
  • the process parameters for opening the first stage of through holes and the process parameters for opening the second stage of through holes can be substantially the same, so that the entire opening process can be simplified.
  • the substrate is provided with a storage area
  • the process includes: forming the first transistor on the storage area; the substrate is further provided with a logic area, the storage area and the logic area are separated by isolation trenches; the forming method further includes: forming a second transistor on the logic region to obtain a memory, wherein the process of forming the second transistor is the same as the process of forming the first transistor.
  • the forming method further includes:
  • a first wiring layer is stacked on the logic region, the first wiring layer includes a third dielectric layer, and multiple metal layers formed in the third dielectric layer until the first metal layer is formed; forming on the first metal layer A first cover layer; wherein, the distance from the surface of the first cover layer away from the substrate to the surface of the second transistor away from the substrate is a first preset distance, and the first preset distance is equal to the first segment to be formed The depth of the via.
  • the first wiring layer on the logic region and the first dielectric layer on the storage region can be formed at the same time or not at the same time.
  • the first cover layer is formed on the first metal layer. , the first cover layer can avoid contamination or damage to the first metal layer when the first section of through holes are formed.
  • the material of the first cover layer and the material of the third dielectric layer are the same.
  • Directly using the first capping layer of the same material as the third dielectric layer can simplify the manufacturing process.
  • the thickness of the first cover layer is smaller than the thickness of the third dielectric layer.
  • the forming method before opening the second via hole in the second dielectric layer, the forming method further includes: stacking a second wiring layer on the first cover layer, and the second wiring layer includes a fourth dielectric layer. an electrical layer, and a multi-layer metal layer formed in the fourth dielectric layer until a second metal layer is formed; a second capping layer is formed on the second metal layer; wherein, the surface of the second capping layer away from the substrate reaches The distance between the surfaces of the first cover layer away from the substrate is a second preset distance, and the second preset distance is equal to the depth of the second through hole to be formed.
  • the second covering layer formed here can also have the effect of protecting the second metal layer.
  • the forming method further includes: in the second section of through holes at least close to the orifices of the second section of through holes Filling material at the position, so that the filled material forms a temporary filling layer that blocks the opening of the second section of through holes; stacking a fifth dielectric layer on the second dielectric layer; opening and closing in the fifth dielectric layer The third section of through holes communicated with the second section of through holes.
  • the through hole for accommodating the capacitor can also be formed through the three-time opening process.
  • the material of the temporary filling layer is polysilicon, carbon or metal.
  • removing the temporary filling layer includes: using an etching process to remove the temporary filling layer.
  • an etching process For example, when polysilicon is used as the material for the temporary filling layer, the material can be removed by wet etching; when carbon is used as the material for the temporary filling layer, the material can be removed by dry etching; when metal is used as the material
  • the material of the layer is temporarily filled, the material may be removed by a wet etching process.
  • the capacitor when the capacitor is formed in the connected first section of through holes, the second section of through holes and the third section of through holes, it includes: A first electrode layer is formed on the side of the second-stage through hole and the side of the third-stage through hole, respectively, a capacitor dielectric layer is formed on the first electrode layer, a second electrode layer is formed on the capacitor dielectric layer, and the first electrode layer is formed. is electrically connected to the first transistor.
  • the aspect ratio of the first via hole formed in the first dielectric layer is less than or equal to 5:1; and/or, the second via hole formed in the second dielectric layer has an aspect ratio of less than or equal to 5:1; The aspect ratio of the segment vias is less than or equal to 5:1.
  • the first stage of through holes and the second stage of through holes may be formed using a low aspect ratio process.
  • the present application provides an electronic device, the electronic device includes a substrate, a first transistor, a first dielectric layer, a second dielectric layer and a capacitor; wherein, the first transistor is disposed on the substrate, and the first transistor is disposed on the substrate.
  • a dielectric layer is stacked on the substrate with the first transistor, the first dielectric layer has a first segment of vias penetrating through the first transistor, the second dielectric layer is stacked on the first dielectric layer, the second The dielectric layer has a second section of through holes that communicate with the first section of through holes, and has a step at the junction of the first section of through holes and the second section of through holes, and the capacitor is formed in the first section of through holes that are connected. the hole and the second through hole, and the capacitor is electrically connected with the first transistor.
  • the through hole includes a first section of through hole and a second section of through hole that communicate with each other, and there is a step at the junction of the first section of through hole and the second section of through hole. That is to say, the through-holes in the electronic device are not obtained by one-time opening, but are obtained by at least two opening-hole processes. , first through the first opening technology to obtain the first section of through holes, and then through another opening technology to form the second through holes.
  • a low aspect ratio opening technique can be used for the primary opening, and in turn, a high aspect ratio through hole for accommodating the capacitor can be formed.
  • the first-stage through-holes and the second-stage through-holes are both conical structures whose aperture sizes gradually decrease in the direction close to the substrate, and the second-stage through-holes close to the first-stage through-holes are conical structures.
  • the diameter of one end of the hole is smaller than the diameter of one end of the through hole of the first section close to the through hole of the second section, so as to form a step at the junction of the through hole of the first section and the through hole of the second section.
  • the depth of the through holes in the first section is equal to the depth of the through holes in the second section.
  • the depth of the through holes in the first section may not be equal to the depth of the through holes in the second section.
  • the depth of the through holes in the first section or the depth of the through holes in the second section is equal to half the depth of the through holes.
  • the capacitor includes a first electrode layer, a capacitor dielectric layer and a second electrode layer, the first electrode layer is formed on the side and bottom surfaces of the first section of the through hole, and is formed on the second section of the through hole On the side of the hole, a capacitor dielectric layer is formed on the first electrode layer, a second electrode layer is formed on the capacitor dielectric layer, and the first electrode layer is electrically connected to the first transistor.
  • the material of the capacitor dielectric layer may be made of a material with a high dielectric constant, so as to prolong the retention time of the stored data.
  • the electronic device further includes a third dielectric layer, the third dielectric layer is stacked on the second dielectric layer, and the third dielectric layer has holes in the third dielectric layer that communicate with the second section of through holes
  • the third section of the through hole has a step at the junction of the second section of the through hole and the third section of the through hole; the capacitor is also formed in the third section of the through hole, and a first electrode layer is formed on the side of the third section of through hole, A capacitor dielectric layer is formed on the first electrode layer in the third through hole, a second electrode layer is formed on the capacitor dielectric layer in the third through hole, and the first electrode layer and the capacitor in the third through hole are formed on the first electrode layer.
  • the dielectric layer and the second electrode layer are respectively connected with the corresponding first electrode layer, the capacitor dielectric layer and the second electrode layer in the second through hole. That is, the through holes may be formed by connecting the first section of through holes, the second section of through holes and the third section of through holes.
  • the electronic device is a memory
  • the substrate is provided with a storage area
  • the first transistor is provided in the storage area.
  • the substrate is further provided with a logic region, and the storage region and the logic region are separated by an isolation trench;
  • the electronic device further includes: a plurality of second transistors and wiring layers, a plurality of second transistors The transistors are arranged in the logic region; the wiring layer is stacked on the logic region having the second transistor.
  • the second transistor in the logic region and the first transistor in the storage region can be formed simultaneously, or can be produced by the same process.
  • the function of the circuit structure formed by the plurality of second transistors and the wiring layer here can be to control the storage function of the storage area, such as read and write address decoding, read and write action execution, data cache, etc., and can also include data calculation, graphics data processing and other functions.
  • the wiring layer includes stacked metal layers, and a dielectric layer for isolating two adjacent metal layers, and the interface between the first section of through holes and the second section of through holes is located in the same phase between two adjacent metal layers.
  • the first transistor and the second transistor are fabricated using the same process.
  • the formation method for forming the electronic device can be simplified.
  • the electronic device further includes: a word line and a bit line formed on the storage region, the word line and the bit line are respectively connected to the first transistor, the word line, the bit line, the first dielectric layer
  • a word line and a bit line formed on the storage region, the word line and the bit line are respectively connected to the first transistor, the word line, the bit line, the first dielectric layer
  • the preparation process can be simplified.
  • the through holes of the first section and the through holes of the second section are connected to form a through hole for accommodating the capacitor; or, the through holes of the first section and the through holes of the second section that are communicated are formed.
  • the hole forms part of a through hole for accommodating the capacitor, wherein the aspect ratio of the through hole for accommodating the capacitor is greater than or equal to 10:1.
  • the vias used to accommodate the capacitors may be referred to as high aspect ratio vias.
  • the present application also provides an electronic device, comprising a printed circuit board and an electronic device made in any implementation manner of the above-mentioned first aspect or an electronic device of any implementation manner of the above-mentioned second aspect, the printed circuit The board is electrically connected to the electronic device.
  • the electronic device provided by the embodiment of the present application includes the electronic device of the first aspect embodiment or the second aspect embodiment. Therefore, the electronic device provided by the embodiment of the present application and the electronic device of the above technical solution can solve the same technical problems and achieve the same expected effect.
  • the electronic device further includes a logic processing circuit, and the logic processing circuit and the electronic device are integrated in the same chip. Thereby, the electronic device forms an embedded electronic device.
  • the electronic device further includes a logic processing circuit, the logic processing circuit is integrated in the first chip, the electronic device is integrated in the second chip, the first chip and the second chip are stacked and electrically connected, The stacked first chip and the second chip are arranged on the printed circuit board. so that the electronic device forms a self-contained electronic device.
  • the electronic device further includes a logic processing circuit, the logic processing circuit is integrated in the first chip, the electronic device is integrated in the second chip, and the first chip and the second chip are respectively arranged on the printed circuit board. on the circuit board and are electrically connected through the printed circuit board. so that the electronic device forms a self-contained electronic device.
  • Fig. 1 is the structural representation of a memory cell in DRAM
  • Figure 2a, Figure 2b and Figure 2c are schematic structural diagrams corresponding to the completion of each step in the method for forming a memory in the prior art
  • FIG. 3 is a partial structural schematic diagram of an electronic device according to an embodiment of the application.
  • FIG. 4 is a schematic partial structure diagram of another electronic device according to an embodiment of the application.
  • FIG. 5 is a schematic partial structure diagram of another electronic device according to an embodiment of the present application.
  • FIG. 6 is a schematic diagram of a partial structure of a memory according to an embodiment of the present application.
  • FIG. 7 is a process flow diagram of a method for forming an electronic device according to an embodiment of the present application.
  • FIG. 8 is a cross-sectional view after each step of the process flow of FIG. 7 is completed;
  • 9a, 9b, 9c, 9d, 9e, 9f, 9g, 9h, 9i, 9j, 9k, and 9l are the steps in the method for forming a memory according to the embodiment of the present application after completion of each step
  • FIG. 10 is a schematic structural diagram of a first section of through holes, a second section of through holes and a third section of through holes formed in an embodiment of the application;
  • FIG. 11 is a schematic diagram of a partial structure of a memory according to an embodiment of the present application.
  • 01-PCB 02-chip; 021-first chip; 022-second chip;
  • Embodiments of the present application provide an electronic device.
  • the electronic device may include a mobile phone (mobile phone), a tablet computer (pad), a smart wearable product (eg, a smart watch, a smart bracelet), a virtual reality (VR) device, an augmented reality (AR), It can also be home appliances, automobiles, artificial intelligence and other equipment, and can also be servers, data centers, and so on.
  • the embodiments of the present application do not specifically limit the specific form of the above electronic device.
  • a memory a central processing unit (central processing unit, CPU), or an image graphics processing unit (graphic processing unit, GPU), etc. may be included.
  • the memory is used to store the operation data of the CPU or the GPU.
  • DRAM has a simpler structure than other memories, for example, compared with Static Random-Access Memory (SRAM), one memory cell in SRAM has six transistors, while one memory cell in DRAM has six transistors. Has only one transistor. In this case, DRAM has very high density, high capacity per unit volume, and low cost. Furthermore, DRAM is widely used in electronic equipment.
  • SRAM Static Random-Access Memory
  • Fig. 3 shows a partial structure diagram of an electronic device
  • the electronic device may include a printed circuit board (PCB) 01 and a chip package structure integrated on the PCB 01, and the chip package structure can pass through a ball array ( ball grid array, BGA) is connected to PCB01.
  • PCB printed circuit board
  • BGA ball grid array
  • the chip package structure includes a stacked first chip 021 and a second chip 022, one of the first chip 021 and the second chip 022 is a logic chip, such as a CPU or GPU, and the other chip is a DRAM,
  • the first chip 021 and the second chip 022 can be connected through a through silicon via (TSV) and a redistribution layer (RDL).
  • TSV through silicon via
  • RDL redistribution layer
  • FIG. 4 shows a partial structure diagram of another electronic device.
  • the electronic device also includes a PCB01 and a first chip 021 and a second chip 022 respectively integrated on the PCB01.
  • the first chip 021 and the second chip 022 can be respectively Connect with PCB01 through BGA.
  • one of the first chip 021 and the second chip 022 is a logic chip
  • the other chip is a DRAM
  • the logic chip and the DRAM can be electrically connected through metal wires arranged on the PCB01.
  • the logic chip and the DRAM are two independent chips, the DRAM can be called a standalone DRAM.
  • FIG. 5 is a partial structure diagram of another electronic device, which also includes a PCB01 and a chip 02 including a system on a chip (SOC) integrated on the PCB01.
  • the chip 02 integrates the DRAM and the logic processing circuit into the same chip, so the DRAM can be called an embedded DRAM.
  • Figure 6 shows a partial structure diagram of the DRAM.
  • the multiple WLs are arranged in parallel along the first direction (X direction in Figure 6), and the multiple BLs are arranged along the first The two directions (the Y direction in FIG. 6 ) are arranged in parallel.
  • the X direction and the Y direction here may be perpendicular, and may also have included angles in other ranges.
  • a memory cell At a position where a line of WL and a line of BL intersect, a memory cell is provided. Since there are a plurality of WLs and a plurality of BLs, thus, a plurality of memory cells arranged in an array are formed, and two adjacent memory cells are separated by a partition wall (not shown in the figure).
  • a memory cell includes a transistor and a capacitor, and the transistor may be a fin transistor (FinFET), such as a tri-gate transistor (TG).
  • the transistor has a gate 1-2, a source 1-3 and a drain 1-1.
  • a gate (gate) 1-2 is connected to WL
  • a drain (drain) 1-1 is connected to BL
  • a source (source) 1-3 is connected to the capacitor 2.
  • the drain (drain) 1-1 may be connected to the capacitor 2
  • the source (source) 1-3 may be connected to BL.
  • the voltage signal on the WL controls the on or off of the transistor, and then reads the data information stored in the capacitor through the BL, or writes the data signal into the capacitor for storage through the BL, so as to realize the read and write operation.
  • the width of the capacitor For example, if the capacitor is cylindrical, it is necessary to reduce the radial size of the capacitor, and in order not to reduce the capacity of the capacitor, ensure For data storage time, it is necessary to lengthen the depth dimension of the capacitor. In this case, a capacitor with a high aspect ratio will be formed.
  • the radial dimension of the capacitor has now been developed to several tens of nanometers, and the depth dimension has reached 1 micron. .
  • a through hole can be opened in the dielectric layer, a first electrode layer can be formed on the wall surface of the through hole, a capacitor dielectric layer can be formed on the first electrode layer, and a second electrode layer can be formed on the capacitor dielectric layer.
  • the electrode layer is formed, thereby forming a capacitor arranged in the through hole.
  • the top shape of the through hole is formed first, and when the bottom shape is etched continuously, the diameter of the top through hole will be enlarged.
  • methods of etching, redepositing, and re-etching are required.
  • the realization method is to use etching gas with more carbon content in dry etching, such as octafluorocyclobutane (C4F8), and the resulting polymer (Polymer) will be deposited on the sidewall of the through hole to protect the etched gas.
  • the diameter of the via hole is not enlarged, and the excess polymer needs to be drained out of the via hole to avoid affecting the subsequent etching process.
  • the polymer In the etching process of low aspect ratio (for example, the aspect ratio is within 7:1 to 10:1), the polymer is easier to discharge, but as the aspect ratio increases (for example, the aspect ratio is greater than 10:1), the polymer It is easy to deposit a large amount at the bottom of the through hole, which blocks the subsequent etching process, resulting in the phenomenon that the through hole is not etched to the bottom.
  • the capacitive etching process of DRAM has the characteristics of high aspect ratio and small via size at the same time, so it is a great challenge to the etching process.
  • the present application proposes a method for forming an electronic device, wherein a through hole in the electronic device has a high aspect ratio, and the forming method includes using a low aspect ratio opening process to form a through hole with a high depth ratio, which is combined below
  • the accompanying drawings illustrate the formation method of the electronic device in detail.
  • FIG. 7 is a process flow diagram of the method for forming the electronic device
  • FIG. 8 is a cross-sectional view of each step of the process flow diagram of FIG. 7 after completion.
  • FIG. 8( a ) is the structure diagram after step S1 is completed.
  • Step S1 includes: forming the first transistor 121 on the substrate 1 .
  • the first transistor 121 in (a) of FIG. 8 is an exemplary structure, and in some alternative embodiments, the first transistor 121 may be formed by a gate electrode, a source electrode and a drain electrode provided on the substrate 1 .
  • the substrate here may be a semiconductor material, for example, a single crystal silicon substrate, a single crystal germanium substrate, or a silicon-on-insulator (SOI) substrate.
  • SOI silicon-on-insulator
  • the first transistor here may be a low-voltage metal-oxide-semiconductor field-effect transistor (MOSFET), such as a tri-gate transistor (TG).
  • MOSFET metal-oxide-semiconductor field-effect transistor
  • TG tri-gate transistor
  • step S2 includes: stacking on the substrate having the first transistor 121 The first dielectric layer 71 . It can also be understood that the first dielectric layer 71 covers the substrate having the plurality of first transistors 121 .
  • the first dielectric layer can be a multi-layer stack structure or a single-layer structure as shown in (b) in FIG. 8 , and the dielectric material of the first dielectric layer can be silicon oxide, silicon nitride, silicon oxynitride, One or a combination of at least two of fluorine-doped silica, boron-doped silica, phosphorus-doped silica, or boron-phosphorus-doped silica.
  • step S3 is the structure diagram after step S3 is completed, and step S3 includes: opening through to the first dielectric layer 71 The first segment of the through hole 81 of the first transistor 121 .
  • a first transistor 121 corresponds to a first segment through hole 81 .
  • FIG. 8 exemplarily depicts a first transistor 121 and a first segment corresponding to the first transistor 121 Through hole 81 .
  • the first section of through holes may be formed by a dry etching process capable of forming low aspect ratio (eg, aspect ratio less than or equal to 5:1) through holes.
  • the opening process steps may be as follows: first, the top shape of the first section of through holes is formed on the part of the first dielectric layer away from the substrate, and the top section of the first section of through holes is formed by using Etching gas with high carbon content, such as octafluorocyclobutane (C 4 F 8 ), the polymer (Polymer) generated in this way will be deposited on the sidewall of the through hole to protect the diameter of the etched through hole from being enlarged , and discharge the excess polymer out of the through hole, continue to etch the bottom topography, and finally form the first section of through hole.
  • Etching gas with high carbon content such as octafluorocyclobutane (C 4 F 8 )
  • step S4 in the first section of the through hole 81 at least close to the first Materials are filled at the positions of the openings of the through holes 81 of the first section, so that the filled materials form a temporary filling layer 9 that blocks the openings of the through holes of the first section.
  • the temporary filling layer here may be as shown in (d) of FIG. 8 , only filling the positions of the first-stage through holes away from the orifice of the substrate, or filling the entire first-stage through-holes.
  • the material of the temporary filling layer 9 may have various choices, for example, polysilicon, carbon, or metal (eg, copper, iron, tungsten), etc. may be used.
  • step S5 includes: stacking a second dielectric layer on the first dielectric layer 71 Dielectric layer 72 .
  • the second dielectric layer can also be a multi-layer stack structure or a single-layer structure as shown in (e) in FIG. 8 , and the dielectric material of the second dielectric layer can also be silicon oxide, silicon nitride, silicon oxynitride , one of fluorine-doped silica, boron-doped silica, phosphorus-doped silica, or boron-phosphorus-doped silica, or a combination of at least two of them.
  • step S6 includes: opening and first in the second dielectric layer 72 A second section of through holes 82 communicated with one section of through holes 81 .
  • a dry etching process may also be used to open the second through hole 82 in the second dielectric layer 72 , and the specific process steps are the same as the above-mentioned process of opening the first through hole 81 .
  • the purpose of forming the temporary filling layer 9 in the first through hole 81 in step S4 is to prevent the dielectric material from being filled in the first dielectric layer 71 when the second dielectric layer 72 is formed on the first dielectric layer 71.
  • the through hole 81 of the first section that is, the position of the through hole 81 of the first section is occupied first by the temporary filling layer 9, so at least the position of the hole of the through hole of the first section can be filled.
  • step S7 includes: removing the temporary filling layer 9 .
  • the process for removing the temporary filling layer may be different depending on the filling material. For example, if polysilicon is used as the filling material, wet etching may be used to remove the polysilicon. If metal is used as the filling material, the metal can also be removed by wet etching. If carbon is used as the filling material, the carbon can be removed by dry etching. Of course, other removal processes may also be employed.
  • step S8 includes: connecting the first section of through holes 81 and The capacitor 2 electrically connected to the first transistor 121 is formed in the second through hole 82 .
  • the forming method further includes the following steps: filling a material at least at a position close to an opening of the second-stage through-hole in the second-stage through-hole to form a temporary filling layer; stacking a third dielectric layer on the second dielectric layer layer; a third section of through hole is opened in the third dielectric layer and communicated with the second section of through hole. Then, the temporary filling layer is removed.
  • the removal of the temporary filling layer here not only needs to remove the temporary filling layer in the first section of through holes, but also needs to remove the temporary filling layer in the second section of through holes.
  • the method can be performed according to the above-mentioned method for forming the third stage of through holes, which will not be repeated here.
  • each opening process can use a low aspect ratio opening process, That is to say, compared with the one-time opening of the prior art, the present application utilizes at least two low-aspect-ratio opening techniques to realize through-holes with high aspect ratios.
  • the aspect ratio continues to increase, and it will not increase the difficulty of the opening process.
  • the aspect ratio is greater than or equal to 10:1
  • the hole depth in the aspect ratio of the through hole here can be 300 nanometers (nm) to 1.
  • the pore size in the aspect ratio of the via may be between 30 nanometers (nm) and 40 nanometers (nm).
  • further reduced through holes can also be formed using the methods shown in FIG. 7 and FIG. 8 .
  • the above-mentioned electronic device is a DRAM, it can also be formed by the method shown in the above-mentioned FIGS. 7 and 8 .
  • other electronic devices that have capacitors and need to open through holes for accommodating capacitors can also be formed by the methods shown in FIGS. 7 and 8 . method is formed.
  • the DRAM may be a stand-alone DRAM or an embedded DRAM.
  • FIG. 9a is a cross-section of a memory after the first step in the formation process.
  • the first transistor 121 is formed in the storage area
  • the second transistor 122 is formed in the logic area.
  • FIG. 9a only an example is shown.
  • a first transistor 121 and a second transistor 122 are provided.
  • FIGS. 9a to 9k of the present application only a method for forming one memory cell (including a first transistor and a capacitor connected to it) is illustrated in FIGS. 9a to 9k of the present application, and the rest of the memory cells are the same as those described in FIGS. 9a to 9k .
  • the memory cells are formed in the same way.
  • the function of the storage area here is an area for storing data.
  • the substrate 1 can be designed to have a memory area for storing data, or a logic area to have a data processing function.
  • the substrate 1 may also be divided into a plurality of regions, including memory regions and logic regions.
  • the above-mentioned logic area may also have other functions, such as generating control signals. These control signals may be read and write control signals for controlling read and write operations of data in the storage area.
  • the first transistor 121 includes a drain electrode 1-1, a gate electrode 1-2 and a source electrode 1-3 all formed on the substrate 1, and between the drain electrode 1-1 and the source electrode 1-3 can be communicated through the substrate 1 .
  • the second transistor 122 may also include a drain electrode 1-1, a gate electrode 1-2 and a source electrode 1-3, which are all formed on the substrate 1, and the space between the drain electrode 1-1 and the source electrode 1-3 may be communicated through the substrate 1 .
  • a planar gate logic process technology can be used to manufacture the first transistor and the second transistor. , it can also be fabricated by high K dielectric metal gate (HKMG) logic process technology, or it can be fabricated by Fin field-efffect transistor (FinFET) logic process technology.
  • HKMG high K dielectric metal gate
  • FinFET Fin field-efffect transistor
  • the first transistor of the storage area and the second transistor of the logic area can be formed by using compatible logic process means, and further, the fabrication process of the entire storage area can be simplified.
  • FIG. 9b is a cross-sectional view of the structure shown in FIG. 9a after completing the second step.
  • the bit line 3 and the word line 4 are formed in the storage area, and the bit line 3 is connected to the drain 1-1.
  • the word line 4 is connected to the gate electrode 1-2, and the bit line 3 may also be connected to the source electrode 1-3.
  • FIG. 9b only one bit line 3 and one word line 4 are shown, in practice, a plurality of parallel bit lines 3 and a plurality of parallel word lines 4 are formed.
  • FIG. 9c is a cross-sectional view of the structure shown in FIG. 9b after completing the third step.
  • the first wiring layer 141 is stacked on the logic region with the second transistor 122, and the first wiring layer 141 is stacked on the logic region with the first transistor, the word A first dielectric layer 71 is stacked on the memory regions of the lines and bit lines.
  • the above-mentioned first dielectric layer 71 on the storage region and the first wiring layer 141 on the logic region can be formed simultaneously.
  • the first dielectric layer 71 may be formed first, and then the first wiring layer 141 may be formed.
  • the first wiring layer 141 may be formed first, and then the first dielectric layer 71 may be formed.
  • the optional forming process includes: forming a dielectric layer on both the logic area and the storage area at the same time; and then only forming a dielectric layer on the logic area forming a metal layer; and simultaneously forming a dielectric layer on both the dielectric layer in the storage area and the dielectric layer with the metal layer in the logic area. That is, a dielectric layer is formed on the logic region and the memory region at the same time.
  • a first dielectric layer 71 formed by stacking multiple layers of dielectric layers can be fabricated in the storage area, and a third layer formed by stacking multiple layers of dielectric layers in the logic area.
  • the dielectric layer 73 has multiple metal layers in the third dielectric layer 73 .
  • the material of the first dielectric layer 71 and the material of the third dielectric layer 73 may be the same, or of course, may be different.
  • the conductive channel can be a through hole filled with conductive material, a metal column, or other conductive structures.
  • the first capping layer 111 is formed on the first metal layer 61, and when the first metal layer 61 is formed on the first metal layer 61 After the first capping layer 111 is formed on the storage region 61, the formation of the first dielectric layer 71 on the storage region is stopped.
  • the distance H1 from the surface of the first cover layer 111 away from the substrate 1 to the surface of the second transistor 122 away from the substrate 1 is a first preset distance, and the first preset distance here can be is the depth of the first through hole to be formed.
  • the above-mentioned material of the first capping layer 111 may be the same as that of the third dielectric layer 73 , for example, both may be silicon oxide or both may be silicon nitride. Of course, the material of the first cover layer 111 may also be different from the material of the third dielectric layer 73 .
  • the circuit structure formed by the first wiring layer 141 and the plurality of second transistors 122 is only a part of the circuit structure of the logic region, and the remaining circuit structures are formed later.
  • FIG. 9d is a cross-sectional view of the structure shown in FIG. 9c after the fourth step is completed.
  • a first through hole 81 penetrating to the first transistor is formed in the first dielectric layer 71 .
  • the through hole 81 of the first segment penetrates to the drain electrode 1-1
  • the drain electrode 1-1 is connected to the BL
  • the through hole 81 of the first segment penetrates to the source electrode 1-3.
  • a dry etching process with a low aspect ratio can be used. As shown in FIG. 9d , along the direction close to the substrate 1 (the direction P1 in FIG. 9d ), the radial dimension of the through holes 81 of the first section gradually decreases.
  • the depth h1 of the first through hole 81 formed is equal to the first preset height H1.
  • the first cover layer 111 on the first metal layer 61 can protect the first metal layer 61 and prevent the first metal layer 61 Contaminated with other impurities, or prevent the first metal layer 61 from being damaged.
  • the thickness of the first cover layer 61 may be smaller than the thickness of the third dielectric layer 73 between two adjacent metal layers, or may be the same as the thickness of the third dielectric layer 73 between two adjacent metal layers. The thicknesses of the dielectric layers 73 are equal.
  • FIG. 9e is a cross-sectional view after the fifth step is completed on the basis of the structure shown in FIG. 9d.
  • a material is filled in the first-stage through-hole 81 at least at a position close to the orifice of the first-stage through-hole , so that the filled material forms a temporary filling layer 9 that blocks the openings of the through holes of the first section.
  • the orifice of the through hole of the first section here refers to the orifice of the through hole of the first section that is far away from the substrate 1 .
  • the temporary filling layer 9 is only formed at the opening of the first section of through holes 81, and the entire first section of through holes 81 is not filled.
  • PVD Physical Vapor Deposition
  • CVD chemical vapor deposition
  • FIG. 9f is a cross-sectional view after the sixth step is completed on the basis of the structure shown in FIG. 9e.
  • the temporary filling layer on the surface of the storage area away from the substrate 1 and the surface of the logic area away from the substrate 1 are removed. Temporary filling layer on the surface.
  • an etching or chemical mechanical polishing process can be used to remove it.
  • 9g is a cross-sectional view of the structure shown in FIG. 9f after the seventh step is completed.
  • the second dielectric layer 72 is stacked on the first dielectric layer 71 and the first cover layer 111 is stacked The second wiring layer 142 .
  • the above-mentioned stacking of the second wiring layer 142 directly on the first capping layer 111 refers to the case where the material of the first capping layer 111 and the material of the third dielectric layer 73 are the same. If the material of the first capping layer 111 and the material of the third dielectric layer 73 are different, the first capping layer 111 needs to be removed before stacking the second wiring layer 142 .
  • the above-mentioned second dielectric layer 72 on the storage region and the second wiring layer 142 on the logic region can be formed simultaneously.
  • the second dielectric layer 72 may be formed first, and then the second wiring layer 142 may be formed.
  • the second wiring layer 142 may be formed first, and then the second dielectric layer 72 may be formed.
  • the second wiring layer 142 here includes the fourth dielectric layer 74 , and a multi-layer metal layer formed in the fourth dielectric layer 74 .
  • the process of forming the second dielectric layer 72 and the second wiring layer 142 at the same time may be the same as the process of forming the first dielectric layer 71 and the first wiring layer 141 at the same time, and the specific process steps of the simultaneous formation will not be repeated here. Repeat.
  • the formation process of the bit line 3 and the word line 4, the first dielectric layer 71, the second dielectric layer 72, the first wiring layer 141 and the second wiring layer 142 can be the same, which can simplify the manufacturing process of the entire electronic device .
  • the material of the fourth dielectric layer 74 in the second wiring layer 142 may be the same as or different from the material of the second dielectric layer 72 , the material of the first dielectric layer 71 and the material of the third dielectric layer 73 .
  • the second capping layer 112 is formed on the second metal layer 62. After the second capping layer 112 is formed on the layer 62, the formation of the second dielectric layer 72 in the storage region may be stopped.
  • the distance H2 from the surface of the second cover layer 112 away from the substrate 1 to the surface of the first cover layer 111 away from the substrate 1 is a second preset distance, and the second preset distance here may be The depth of the second through hole to be formed.
  • FIG. 9h is a cross-sectional view after the eighth step is completed on the basis of the structure shown in FIG. 9g.
  • a second section of through holes connected to the first section of through holes 81 are formed in the second dielectric layer 72 82.
  • a dry etching process with a low aspect ratio can be used to form, and in some optional embodiments, the second-stage through-holes 82
  • the topography is also a conical structure, that is, as shown in FIG. 9h , along the direction close to the substrate 1 (the P1 direction shown in FIG. 9h ), the radial dimension of the second through hole 82 gradually decreases.
  • the depth h2 of the second via hole 82 is equal to the second predetermined height H2 .
  • the depth of the second-stage through-holes 82 may be equal to the depth of the first-stage through-holes 81, for example, equal to one-half or one-third of the final through-holes.
  • the same process conditions can be used when etching the first-stage through holes 81 and the second-stage through holes 82 , for example, the flow rate, temperature, pressure in the etching chamber, bias power, etc. of the etching gas are the same. Further, the entire opening process is simplified.
  • the step shown in FIG. 9i can be continued.
  • the first-stage through-holes are removed.
  • FIG. 9j is a cross-sectional view after the tenth step is completed on the basis of the structure shown in FIG. 9i.
  • the first electrode layer 101 is formed in the first section of through holes 81 and the second section of through holes 82 that communicate with each other.
  • the capacitor dielectric layer 102 and the second electrode layer 103 are formed in the first section of through holes 81 and the second section of through holes 82 that communicate with each other.
  • the first electrode layer 101 is respectively formed on the side surface and the bottom surface of the through hole 81 of the first stage, and the first electrode layer 101 is formed on the side surface of the through hole 82 of the second stage;
  • a capacitor dielectric layer 102 is formed on an electrode layer 101, on the first electrode layer 101 on the side of the through hole 81 of the first section, and on the first electrode layer 101 on the side of the through hole 82 in the second section;
  • a second electrode layer 103 is formed on the capacitive dielectric layer 102 on the bottom surface of the through hole 81 , on the capacitive dielectric layer 102 on the side surface of the first through hole 81 , and on the capacitive dielectric layer 102 on the side surface of the second through hole 82 .
  • the through hole filled with the first electrode layer 101 , the capacitor dielectric layer 102 and the second electrode layer 103 forms a capacitor, and the first electrode layer on the bottom surface of the first segment of through hole 81 is electrically connected to the first transistor.
  • forming the capacitor dielectric layer 102 on the first electrode layer 101 on the side surface of the through hole 81 of the first section means that the capacitor dielectric layer is along the radial direction of the through hole 81 of the first section (as shown in the Q direction of FIG. 9j ). ) is formed on the first electrode layer.
  • Forming the second electrode layer 103 on the capacitor dielectric layer 102 on the side surface of the through hole 81 of the first stage means that the second electrode layer is formed on the capacitor along the radial direction of the through hole 81 of the first stage (the Q direction in FIG. 9j ). on the dielectric layer.
  • Forming the capacitor dielectric layer 102 on the first electrode layer 101 on the side surface of the second through hole 82 means that the capacitor dielectric layer is formed on the first electrode layer 101 along the radial direction of the second through hole 82 (the Q direction in FIG. 9j ). on the electrode layer.
  • Forming the second electrode layer 103 on the capacitor dielectric layer 102 on the side of the second through hole 82 means that the second electrode layer is formed on the capacitor along the radial direction of the second through hole 82 (the Q direction in FIG. 9j ). on the dielectric layer.
  • the first electrode layer 101 and the second electrode layer 103 are both metal layers, and the capacitor dielectric layer 102 can be made of high dielectric constant K (HK) material to prolong the retention time of stored data.
  • HK high dielectric constant K
  • the capacitor dielectric layer 102 and the second electrode layer 103 When forming the first electrode layer 101 , the capacitor dielectric layer 102 and the second electrode layer 103 , PVD or CVD deposition can be used, and after the first electrode layer 101 is formed, the second dielectric layer 72 can be separated from the lining. After the surface of the bottom 1 and the first electrode layer 101 on the surface of the second cover layer 112 away from the substrate 1 are removed, the capacitor dielectric layer 102 and the second electrode layer 103 are formed in sequence. Therefore, as shown in FIG. 9j, A capacitor dielectric layer 102 and a second electrode layer 103 are deposited on the surfaces of the logic region and the storage region away from the substrate.
  • FIG. 9k is a cross-sectional view of the structure shown in FIG. 9j after completing the eleventh step.
  • the capacitor dielectric layer 102 and the second electrode layer 103 on the surface of the logic region away from the substrate are removed.
  • the twelfth step is a cross-sectional view after the twelfth step is completed on the basis of the structure shown in FIG. 9k.
  • the second electrode layer 103 of the storage area and the second cover layer 112 of the logic area are formed Three wiring layers 143, in this case, the second electrode layer 103 serving as the capacitor can be electrically connected to the logic region through the third wiring layer, and the second electrode layer 103 can be powered by a power supply located in the logic region.
  • the method for forming the memory also includes: after completing FIG. 9h , filling material at least at a position close to the orifice of the second-stage through-hole 82 in the second-stage through-hole 82, so that the filled material forms a temporary filling layer 9 that blocks the orifice of the first-stage through-hole 82,
  • the fifth dielectric layer 75 is further formed on the second dielectric layer 72 in the storage area, and the fourth dielectric layer 75 is formed on the second capping layer 112 (the material of the second capping layer 112 here is the same as that of the fourth dielectric layer)
  • the wiring layer 144 is formed until the third metal layer 63 is formed, and then the third cover layer 113 is formed on the third metal layer.
  • the distance between the surfaces is a third preset distance H3, and the third preset distance H3 is equal to the depth of the third
  • a third through hole 83 is formed in the third dielectric layer 73 , and the third through hole 83 is communicated with the second through hole 82 .
  • the depth h3 of the formed third-stage through holes 83 is equal to the third preset distance H3.
  • the temporary filling layer in the first through hole 81 and the second through hole 82 is removed, and then the first through hole, the second through hole and the second through hole in the connected first through hole, the second through hole and the second through hole are removed.
  • a capacitor is formed in the three-segment through hole.
  • a step 15 is also formed at the interface between the second through hole 82 and the third through hole 83 .
  • the structure shown in FIG. 91 is a memory including a first stage of through hole and a second stage of through hole, and the memory is compared with the existing one-time opening.
  • the memory of the holes the obvious difference is that there is a step at the interface of the first section of through holes 81 and the second section of through holes 82 .
  • N is a positive integer greater than or equal to 2
  • the depth of the through holes 81 of the first stage or the depth of the through holes 82 of the second stage is equal to one-half the depth of the through holes.
  • the first through hole is opened, so the interface between the first through hole and the second through hole is located between two adjacent metal layers.
  • the area of the cross-section of the first-stage through-holes 81 away from the opening of the substrate 1 may be It is equal to the area of the cross section of the opening of the second section of through holes 82 away from the substrate, and may also be close to the area of the cross section of the opening of the second section of through holes 82 away from the substrate.
  • FIG. 11 is a structural diagram of a memory, which shows a plurality of capacitors 2 .
  • a plurality of through holes can be formed at the same time, and when the first electrode layer, the capacitor dielectric layer and the second electrode layer are respectively formed in the formed plurality of through holes, the first electrode layer can also be formed at the same time , forming a capacitor dielectric layer and a second electrode layer at the same time, and then, as shown in FIG. 11 , the second electrode layers 103 of a plurality of through holes can be connected together as a common second electrode layer, in this case, the power supply through the common The second electrode layer supplies power to the plurality of capacitors.
  • the first electrode layer 101 when PVD or CVD deposition method is used to form a plurality of capacitors 2, as shown in FIG.
  • the first electrode layer 101 deposited on the surface of the second dielectric layer 72 away from the substrate 1 needs to be removed to prevent the formation of multiple capacitors 2 connected in series.
  • capacitor dielectric layer 102 and the second electrode layer 103 are formed by PVD or CVD deposition, it is not necessary to remove the capacitor dielectric layer 102 and the second electrode layer 103 formed on the second dielectric layer 72.
  • a structure in which a capacitor dielectric layer 102 and a second electrode layer 103 are formed on the second dielectric layer 71 as shown in FIG. 11 will be formed, and the second electrode layer 103 is shared by a plurality of capacitors here.

Abstract

Embodiments of the present application provide an electronic device having a through hole with a high aspect ratio and a forming method therefor, and an electronic device, relate to the technical field of electronic devices, and are used for providing a method for forming a through hole with a high aspect ratio. The method of forming the electronic device comprises: stacking a first dielectric layer on a substrate having a first transistor; forming a first section through hole penetrating through the first transistor in the first dielectric layer; filling a material at a location within the first section through hole at least close to an aperture of the first section through hole, such that the filled material forms a temporary fill layer blocking the aperture of the first section through hole; stacking a second dielectric layer on the first dielectric layer, the second dielectric layer being the same as the material of the first dielectric layer; and forming in the second dielectric layer a second section through hole communicated with the first section through hole, the first section through hole and the second section through hole that are communicated with each other being through holes for accommodating a capacitor. Moreover, a hole opening process with a low aspect ratio can be adopted for opening each time.

Description

具有高深宽比的通孔的电子器件及其形成方法、电子设备Electronic device with high aspect ratio through hole, method for forming the same, and electronic device 技术领域technical field
本申请涉及存储技术领域,尤其涉及一种具有高深宽比的通孔的电子器件及其形成方法、电子设备。The present application relates to the field of storage technologies, and in particular, to an electronic device with a high aspect ratio through hole, a method for forming the same, and an electronic device.
背景技术Background technique
在计算系统中,动态随机存取存储器(dynamic random access memory,DRAM)作为一种内存结构,可以用于暂存中央处理器(central processing unit,CPU)的运算数据,以及与硬盘等外部存储器交换数据,是计算系统中非常重要的组成部分。In a computing system, dynamic random access memory (DRAM), as a memory structure, can be used to temporarily store the operation data of the central processing unit (CPU) and exchange it with external memory such as hard disks. Data is a very important part of a computing system.
为了增加DRAM的存储容量,该DRAM可以包括多条字线(word line,WL)和多条位线(bit line,BL),一条WL和一条BL交叉位置处设置有一个存储单元,图1示出了一个存储单元的结构图,该存储单元包括晶体管(transistor)和与该晶体管电连接的电容器(capacitor),晶体管(transistor)与BL3和WL4电连接,其中,晶体管用于控制BL3和电容器之间的导通或断开,电容器用于存储电荷。In order to increase the storage capacity of the DRAM, the DRAM may include multiple word lines (WL) and multiple bit lines (bit lines, BL). A memory cell is provided at the intersection of a WL and a BL, as shown in Figure 1. A structure diagram of a memory cell is shown, the memory cell includes a transistor (transistor) and a capacitor (capacitor) electrically connected to the transistor, the transistor (transistor) is electrically connected to BL3 and WL4, wherein the transistor is used to control the relationship between BL3 and the capacitor. On or off between, capacitors are used to store charge.
上述DRAM在制备时,如图2a所示,先在衬底11的逻辑区和存储区分别制备晶体管12,其中,逻辑区负责逻辑控制和信号处理等功能,存储区负责数据存储。然后在逻辑区上形成布线层14,逻辑区的晶体管12和该逻辑区的布线层14相连接构成电路结构。但是,在存储区仅形成介电层13。如图2b所示,当完成逻辑区的布线层14后,再在存储区的介电层13内形成通孔8。结合图2c,在通孔8内形成电容器2。During the preparation of the above DRAM, as shown in FIG. 2a, transistors 12 are first prepared in the logic area and the storage area of the substrate 11, wherein the logic area is responsible for functions such as logic control and signal processing, and the storage area is responsible for data storage. Then, a wiring layer 14 is formed on the logic region, and the transistors 12 of the logic region and the wiring layer 14 of the logic region are connected to form a circuit structure. However, only the dielectric layer 13 is formed in the memory region. As shown in FIG. 2b, after the wiring layer 14 of the logic region is completed, the through hole 8 is formed in the dielectric layer 13 of the storage region. In conjunction with FIG. 2 c , the capacitor 2 is formed in the through hole 8 .
这样的话,在存储区,电容器连接位于该区的晶体管,构成1T(transistor)1C(capacitor)的存储单元,进而,可以形成和现有逻辑(logic)工艺相兼容的嵌入式DRAM。In this way, in the storage area, capacitors are connected to transistors located in this area to form 1T (transistor) 1C (capacitor) memory cells, and further, an embedded DRAM compatible with existing logic processes can be formed.
随着工艺节点的不断微缩,在存储区单位面积的存储容量增加,即存储区的晶体管和通孔的集成密度越来越大,从而,因此,需要选择减少电容通孔开口尺寸而增加孔深的方案,即上述通孔的深宽比(如图2b的h与d的比值)需要做的越来越大,比如,d为几十纳米,h达到1微米左右。而图2a至图2c的现有工艺很难做到这种深宽比的通孔,并且工艺继续微缩的难度也会越来越大。With the continuous shrinking of process nodes, the storage capacity per unit area of the storage area increases, that is, the integration density of transistors and through holes in the storage area is increasing. Therefore, it is necessary to choose to reduce the opening size of the capacitor through hole and increase the hole depth. , that is, the aspect ratio of the above-mentioned through hole (the ratio of h to d in Fig. 2b) needs to be made larger and larger, for example, d is several tens of nanometers, and h is about 1 micrometer. However, it is difficult for the existing processes of FIGS. 2a to 2c to achieve through holes with such an aspect ratio, and it will become more and more difficult to continue to shrink the process.
发明内容SUMMARY OF THE INVENTION
本申请的实施例提供一种具有高深宽比的通孔的电子器件及其形成方法、电子设备,主要目的是提供一种开设具有高深宽比的通孔的方法。Embodiments of the present application provide an electronic device with a high aspect ratio through hole, a method for forming the same, and an electronic device, and the main purpose is to provide a method for opening a through hole with a high aspect ratio.
为达到上述目的,本申请的实施例采用如下技术方案:To achieve the above object, the embodiments of the present application adopt the following technical solutions:
第一方面,本申请提供了一种电子器件的形成方法,该电子器件的形成方法包括:在衬底上第一晶体管,这里的第一晶体管可以是多个,第一晶体管可以是鳍式晶体管;在具有第一晶体管的衬底上堆叠第一介电层,该第一介电层可以是一层,也可以是依次堆叠的多层;在第一介电层内开设贯通至第一晶体管的第一段通孔;在第一段通孔内的至少靠近第一段通孔的孔口的位置处填充材料,以使填充的材料形成将第一段通孔的孔口堵住的临时填充层;在第一介电层上堆叠第二介电层,该第二介电层可以与 第一介电层的材料相同;在第二介电层内开设与第一段通孔相连通的第二段通孔;去除临时填充层,比如通过刻蚀工艺去除;在相连通的第一段通孔和第二段通孔内形成和第一晶体管电连接的电容器。In a first aspect, the present application provides a method for forming an electronic device, the method for forming an electronic device comprising: a first transistor on a substrate, where the first transistors may be multiple, and the first transistors may be fin transistors ; stacking a first dielectric layer on the substrate with the first transistor, the first dielectric layer may be one layer, or multiple layers stacked in sequence; opening through the first dielectric layer to the first transistor The first section of the through hole; filling material at least at a position close to the orifice of the first section of the through hole in the first section of the through hole, so that the filled material forms a temporary block for the orifice of the first section of the through hole Filling layer; stacking a second dielectric layer on the first dielectric layer, the second dielectric layer can be of the same material as the first dielectric layer; opening in the second dielectric layer to communicate with the first section of through holes remove the temporary filling layer, for example, by an etching process; and form a capacitor electrically connected to the first transistor in the connected first through hole and the second through hole.
本申请实施例提供的电子器件的形成方法中,在形成通孔时,先在第一介电层内开设第一段通孔,然后在第一段通孔内的至少靠近第一段通孔的孔口的位置处填充临时填充层,也就是将第一段通孔的孔口封堵,再在第一介电层上形成第二介电层,然后在第二介电层内开设与第一段通孔相连通的第二段通孔。In the method for forming an electronic device provided by the embodiment of the present application, when forming the through hole, a first section of through hole is first opened in the first dielectric layer, and then the first section of through hole is at least close to the first section of through hole in the first section of through hole. A temporary filling layer is filled at the position of the hole, that is, the hole of the first section of the through hole is blocked, and then a second dielectric layer is formed on the first dielectric layer, and then the second dielectric layer is opened and The second section of through holes communicated with the first section of through holes.
基于上述描述,本申请至少包含两次开孔工艺,这样的话,当最终形成的通孔为高深宽比的通孔时,这里的每一次开孔可以采用低深宽比开孔技术,比如,在开设第一段通孔时,可以先从第一介电层的表面进行刻蚀,形成第一段通孔的顶部形貌,在刻蚀时可以采用含碳量较多的刻蚀气体,以使刻蚀气体生成的聚合物沉积在通孔的侧壁上,这样在继续朝衬底方向刻蚀时,沉积在通孔的侧壁上的聚合物可以保护已经刻蚀的通孔的直径不会被扩大,且在刻蚀的过程中可以将多余的聚合物及时排出,保障底部形貌形成,进而,最终形成低深宽比的第一段通孔。Based on the above description, the present application includes at least two opening processes. In this case, when the finally formed through hole is a high aspect ratio through hole, each opening here can use a low aspect ratio opening technology, for example, When opening the first section of through holes, you can first etch from the surface of the first dielectric layer to form the top shape of the first section of through holes, and you can use etching gas with more carbon content during etching, So that the polymer generated by the etching gas is deposited on the sidewall of the through hole, so that when continuing to etch towards the substrate, the polymer deposited on the sidewall of the through hole can protect the diameter of the etched through hole It will not be enlarged, and the excess polymer can be discharged in time during the etching process to ensure the formation of the bottom topography, and finally, the first section of through holes with low aspect ratio are formed.
所以,利用本申请的多次开孔技术形成通孔时,即使随着通孔深宽比的进一步提高,也不会对开孔工艺造成较大的挑战。Therefore, when the through hole is formed by the multiple opening technology of the present application, even with the further improvement of the aspect ratio of the through hole, the opening process will not pose a great challenge.
在第一方面可能的实现方式中,在第一介电层内开设贯通至第一晶体管的第一段通孔,包括:采用干法刻蚀由第一介电层的远离衬底的表面朝第一晶体管开孔,形成圆锥形结构的第一段通孔,第一段通孔沿靠近衬底方向孔径尺寸逐渐减小;在第二介电层内开设与第一段通孔相连通的第二段通孔,包括:采用干法刻蚀由第二介电层的远离第一介电层的表面朝第一段通孔开孔,形成圆锥形结构的第二段通孔,第二段通孔沿靠近衬底方向孔径尺寸逐渐减小;其中,第二段通孔的靠近第一段通孔的一端的孔径,小于第一段通孔的靠近第二段通孔的一端的孔径,以在第一段通孔与第二段通孔的交界处形成台阶。In a possible implementation manner of the first aspect, opening a first segment of through hole in the first dielectric layer that penetrates to the first transistor includes: using dry etching from a surface of the first dielectric layer away from the substrate toward The first transistor opens a hole to form a first section of through hole with a conical structure, and the aperture size of the first section of through hole gradually decreases along the direction close to the substrate; a second section of through hole is opened in the second dielectric layer and communicated with the first section of through hole. The second section of through holes includes: using dry etching to open holes from the surface of the second dielectric layer away from the first dielectric layer toward the first section of through holes to form a second section of through holes with a conical structure, the second section of through holes having a conical structure. The aperture size of the segment through holes gradually decreases along the direction close to the substrate; wherein, the aperture diameter of one end of the second segment through hole close to the first segment through hole is smaller than the aperture diameter of the first segment through hole close to the second segment through hole. , so as to form a step at the junction of the through hole of the first section and the through hole of the second section.
也就是,在采用干法刻蚀第一段通孔和第二段通孔时,相比现有的一次开孔工艺,很明显的区别是在第一段通孔与第二段通孔的交界处形成有台阶。That is, when dry etching the first-stage through-holes and the second-stage through-holes, compared with the existing one-time opening process, the obvious difference is the difference between the first-stage through-holes and the second-stage through-holes. Steps are formed at the junction.
在第一方面可能的实现方式中,第一介电层的厚度等于第二介电层的厚度。In a possible implementation manner of the first aspect, the thickness of the first dielectric layer is equal to the thickness of the second dielectric layer.
这样的话,在开设第一段通孔时的工艺参数,和开设第二段通孔时的工艺参数可以是基本相同的,从而,可以简化整个开孔工艺。In this way, the process parameters for opening the first stage of through holes and the process parameters for opening the second stage of through holes can be substantially the same, so that the entire opening process can be simplified.
在第一方面可能的实现方式中,衬底设置有存储区,在形成第一晶体管时,包括:在所述存储区上形成第一晶体管;衬底还设置有逻辑区,存储区和逻辑区之间被隔离沟槽隔开;形成方法还包括:在逻辑区上形成第二晶体管,以制得存储器,其中,形成第二晶体管的工艺与形成第一晶体管的工艺相同。In a possible implementation manner of the first aspect, the substrate is provided with a storage area, and when the first transistor is formed, the process includes: forming the first transistor on the storage area; the substrate is further provided with a logic area, the storage area and the logic area are separated by isolation trenches; the forming method further includes: forming a second transistor on the logic region to obtain a memory, wherein the process of forming the second transistor is the same as the process of forming the first transistor.
这样的话,采用相兼容的逻辑工艺制备存储区的第一晶体管和逻辑区的第二晶体管,也会简化工艺。In this case, using compatible logic processes to fabricate the first transistor in the memory region and the second transistor in the logic region will also simplify the process.
在第一方面可能的实现方式中,在逻辑区上形成第二晶体管之后,在第一介电层内开设第一段通孔之前,形成方法还包括:In a possible implementation manner of the first aspect, after forming the second transistor on the logic region and before opening the first segment of through holes in the first dielectric layer, the forming method further includes:
在逻辑区上堆叠第一布线层,第一布线层包括第三介电层,以及形成在第三介电层内的多层金属层,直至形成第一金属层;在第一金属层上形成第一覆盖层;其中, 第一覆盖层的远离衬底的表面至第二晶体管的远离衬底的表面之间的距离为第一预设距离,第一预设距离等于所要形成的第一段通孔的深度。A first wiring layer is stacked on the logic region, the first wiring layer includes a third dielectric layer, and multiple metal layers formed in the third dielectric layer until the first metal layer is formed; forming on the first metal layer A first cover layer; wherein, the distance from the surface of the first cover layer away from the substrate to the surface of the second transistor away from the substrate is a first preset distance, and the first preset distance is equal to the first segment to be formed The depth of the via.
这里的逻辑区上的第一布线层和存储区上的第一介电层可以同时形成,也可以不同时形成,当形成第一金属层后,再在第一金属层上形成第一覆盖层,该第一覆盖层可以避免在形成第一段通孔时,对第一金属层造成污染或者损坏。Here, the first wiring layer on the logic region and the first dielectric layer on the storage region can be formed at the same time or not at the same time. After the first metal layer is formed, the first cover layer is formed on the first metal layer. , the first cover layer can avoid contamination or damage to the first metal layer when the first section of through holes are formed.
在第一方面可能的实现方式中,第一覆盖层的材料和第三介电层的材料相同。In a possible implementation manner of the first aspect, the material of the first cover layer and the material of the third dielectric layer are the same.
直接采用与第三介电层的材料相同的第一覆盖层可以简化制造工艺。Directly using the first capping layer of the same material as the third dielectric layer can simplify the manufacturing process.
在第一方面可能的实现方式中,第一覆盖层的厚度小于第三介电层的厚度。In a possible implementation manner of the first aspect, the thickness of the first cover layer is smaller than the thickness of the third dielectric layer.
在第一方面可能的实现方式中,在第二介电层内开设第二段通孔之前,形成方法还包括:在第一覆盖层上堆叠第二布线层,第二布线层包括第四介电层,以及形成在第四介电层内的多层金属层,直至形成第二金属层;在第二金属层上形成第二覆盖层;其中,第二覆盖层的远离衬底的表面至第一覆盖层的远离衬底的表面之间的距离为第二预设距离,第二预设距离等于所要形成的第二段通孔的深度。In a possible implementation manner of the first aspect, before opening the second via hole in the second dielectric layer, the forming method further includes: stacking a second wiring layer on the first cover layer, and the second wiring layer includes a fourth dielectric layer. an electrical layer, and a multi-layer metal layer formed in the fourth dielectric layer until a second metal layer is formed; a second capping layer is formed on the second metal layer; wherein, the surface of the second capping layer away from the substrate reaches The distance between the surfaces of the first cover layer away from the substrate is a second preset distance, and the second preset distance is equal to the depth of the second through hole to be formed.
同上述的形成第一覆盖层的目的一样,这里形成的第二覆盖层也是能够起到保护第二金属层的效果。The same as the purpose of forming the first covering layer described above, the second covering layer formed here can also have the effect of protecting the second metal layer.
在第一方面可能的实现方式中,在开设第二段通孔之后,在去除临时填充层之前,形成方法还包括:在第二段通孔内的至少靠近第二段通孔的孔口的位置处填充材料,以使填充的材料形成将第二段通孔的孔口堵住的临时填充层;在第二介电层上堆叠第五介电层;在第五介电层内开设与第二段通孔相连通的第三段通孔。In a possible implementation manner of the first aspect, after the opening of the second section of through holes and before removing the temporary filling layer, the forming method further includes: in the second section of through holes at least close to the orifices of the second section of through holes Filling material at the position, so that the filled material forms a temporary filling layer that blocks the opening of the second section of through holes; stacking a fifth dielectric layer on the second dielectric layer; opening and closing in the fifth dielectric layer The third section of through holes communicated with the second section of through holes.
也就是说,也可以通过三次开孔工艺形成容纳电容器的通孔。That is to say, the through hole for accommodating the capacitor can also be formed through the three-time opening process.
在第一方面可能的实现方式中,临时填充层的材料为多晶硅、碳或者金属。In a possible implementation manner of the first aspect, the material of the temporary filling layer is polysilicon, carbon or metal.
在第一方面可能的实现方式中,去除所述临时填充层,包括:采用刻蚀工艺去除临时填充层。比如,当采用多晶硅作为临时填充层的材料时,可以利用湿法刻蚀工艺去除该材料,当采用碳作为临时填充层的材料时,可以利用干法刻蚀工艺去除该材料,当采用金属作为临时填充层的材料时,可以利用湿法刻蚀工艺去除该材料。In a possible implementation manner of the first aspect, removing the temporary filling layer includes: using an etching process to remove the temporary filling layer. For example, when polysilicon is used as the material for the temporary filling layer, the material can be removed by wet etching; when carbon is used as the material for the temporary filling layer, the material can be removed by dry etching; when metal is used as the material When the material of the layer is temporarily filled, the material may be removed by a wet etching process.
在第一方面可能的实现方式中,在相连通的第一段通孔、第二段通孔和第三段通孔内形成电容器时,包括:在第一段通孔的侧面和底面、第二段通孔的侧面,以及第三段通孔的侧面分别形成第一电极层,在第一电极层上形成电容介质层,在电容介质层上形成第二电极层,并使第一电极层与第一晶体管电连接。In a possible implementation manner of the first aspect, when the capacitor is formed in the connected first section of through holes, the second section of through holes and the third section of through holes, it includes: A first electrode layer is formed on the side of the second-stage through hole and the side of the third-stage through hole, respectively, a capacitor dielectric layer is formed on the first electrode layer, a second electrode layer is formed on the capacitor dielectric layer, and the first electrode layer is formed. is electrically connected to the first transistor.
在第一方面可能的实现方式中,在第一介电层内形成的第一段通孔的深宽比小于或等于5∶1;和/或,在第二介电层内形成的第二段通孔的深宽比小于或等于5∶1。In a possible implementation manner of the first aspect, the aspect ratio of the first via hole formed in the first dielectric layer is less than or equal to 5:1; and/or, the second via hole formed in the second dielectric layer has an aspect ratio of less than or equal to 5:1; The aspect ratio of the segment vias is less than or equal to 5:1.
从而,可以利用低深宽比工艺形成第一段通孔和第二段通孔。Thus, the first stage of through holes and the second stage of through holes may be formed using a low aspect ratio process.
第二方面,本申请提供了一种电子器件,该电子器件包括衬底、第一晶体管、第一介电层、第二介电层和电容器;其中,第一晶体管设置在衬底上,第一介电层堆叠在具有第一晶体管的衬底上,第一介电层内具有贯通至第一晶体管的第一段通孔,第二介电层堆叠在第一介电层上,第二介电层内具有与第一段通孔相连通的第二段通孔,且在第一段通孔与第二段通孔的交界处具有台阶,电容器,形成在相连通的第一段通孔和第二段通孔内,且电容器与第一晶体管电连接。In a second aspect, the present application provides an electronic device, the electronic device includes a substrate, a first transistor, a first dielectric layer, a second dielectric layer and a capacitor; wherein, the first transistor is disposed on the substrate, and the first transistor is disposed on the substrate. A dielectric layer is stacked on the substrate with the first transistor, the first dielectric layer has a first segment of vias penetrating through the first transistor, the second dielectric layer is stacked on the first dielectric layer, the second The dielectric layer has a second section of through holes that communicate with the first section of through holes, and has a step at the junction of the first section of through holes and the second section of through holes, and the capacitor is formed in the first section of through holes that are connected. the hole and the second through hole, and the capacitor is electrically connected with the first transistor.
本申请实施例提供的电子器件中,由于通孔包括相连通的第一段通孔和第二段通 孔,且在第一段通孔与第二段通孔的交界处具有台阶。也就是说,该电子器件中的通孔不是一次开孔得到,而是至少采用两次开孔工艺,比如,可以采用上述第一方面任一实施方式的电子器件的形成方法制得,也就是,先通过第一次开孔技术得到第一段通孔,再通过另一次开孔技术形成第二段通孔,和现有技术的仅有一次开孔工艺相比,本申请实施例的每一次开孔可以采用低深宽比的开孔技术,进而,可以形成具有高深宽比的用于容纳电容器的通孔。In the electronic device provided by the embodiment of the present application, the through hole includes a first section of through hole and a second section of through hole that communicate with each other, and there is a step at the junction of the first section of through hole and the second section of through hole. That is to say, the through-holes in the electronic device are not obtained by one-time opening, but are obtained by at least two opening-hole processes. , first through the first opening technology to obtain the first section of through holes, and then through another opening technology to form the second through holes. A low aspect ratio opening technique can be used for the primary opening, and in turn, a high aspect ratio through hole for accommodating the capacitor can be formed.
在第二方面可能的实现方式中,第一段通孔和第二段通孔均为沿靠近衬底方向孔径尺寸逐渐减小的圆锥形结构,且第二段通孔的靠近第一段通孔的一端的孔径,小于第一段通孔的靠近第二段通孔的一端的孔径,以在第一段通孔与第二段通孔的交界处形成台阶。In a possible implementation manner of the second aspect, the first-stage through-holes and the second-stage through-holes are both conical structures whose aperture sizes gradually decrease in the direction close to the substrate, and the second-stage through-holes close to the first-stage through-holes are conical structures. The diameter of one end of the hole is smaller than the diameter of one end of the through hole of the first section close to the through hole of the second section, so as to form a step at the junction of the through hole of the first section and the through hole of the second section.
在第二方面可能的实现方式中,沿堆叠方向,第一段通孔的深度等于第二段通孔的深度。当然,第一段通孔的深度也可以不等于第二段通孔的深度。In a possible implementation manner of the second aspect, along the stacking direction, the depth of the through holes in the first section is equal to the depth of the through holes in the second section. Of course, the depth of the through holes in the first section may not be equal to the depth of the through holes in the second section.
在第二方面可能的实现方式中,沿堆叠方向,第一段通孔的深度或者第二段通孔的深度等于通孔的深度的二分之一。In a possible implementation manner of the second aspect, along the stacking direction, the depth of the through holes in the first section or the depth of the through holes in the second section is equal to half the depth of the through holes.
在第二方面可能的实现方式中,电容器包括第一电极层、电容介质层和第二电极层,第一电极层形成在第一段通孔的侧面和底面上,以及形成在第二段通孔的侧面上,电容介质层形成在第一电极层上,第二电极层形成在电容介质层上,且第一电极层与第一晶体管电连接。In a possible implementation manner of the second aspect, the capacitor includes a first electrode layer, a capacitor dielectric layer and a second electrode layer, the first electrode layer is formed on the side and bottom surfaces of the first section of the through hole, and is formed on the second section of the through hole On the side of the hole, a capacitor dielectric layer is formed on the first electrode layer, a second electrode layer is formed on the capacitor dielectric layer, and the first electrode layer is electrically connected to the first transistor.
在第二方面可能的实现方式中,电容介质层的材料可以采用高介电常数材料制得,以延长存储数据保持时间。In a possible implementation manner of the second aspect, the material of the capacitor dielectric layer may be made of a material with a high dielectric constant, so as to prolong the retention time of the stored data.
在第二方面可能的实现方式中,电子器件还包括第三介电层,第三介电层堆叠在第二介电层上,且第三介电层内具有与第二段通孔相连通的第三段通孔,在第二段通孔与第三段通孔的交界处具有台阶;电容器还形成在第三段通孔内,第三段通孔的侧面形成有第一电极层,第三段通孔内的第一电极层上形成有电容介质层,第三段通孔内的电容介质层上形成有第二电极层,且第三段通孔内的第一电极层、电容介质层和第二电极层分别与第二段通孔内的相对应的第一电极层、电容介质层和第二电极层相连接。也就是说,通孔可以由相连通的第一段通孔、第二段通孔和第三段通孔形成。In a possible implementation manner of the second aspect, the electronic device further includes a third dielectric layer, the third dielectric layer is stacked on the second dielectric layer, and the third dielectric layer has holes in the third dielectric layer that communicate with the second section of through holes The third section of the through hole has a step at the junction of the second section of the through hole and the third section of the through hole; the capacitor is also formed in the third section of the through hole, and a first electrode layer is formed on the side of the third section of through hole, A capacitor dielectric layer is formed on the first electrode layer in the third through hole, a second electrode layer is formed on the capacitor dielectric layer in the third through hole, and the first electrode layer and the capacitor in the third through hole are formed on the first electrode layer. The dielectric layer and the second electrode layer are respectively connected with the corresponding first electrode layer, the capacitor dielectric layer and the second electrode layer in the second through hole. That is, the through holes may be formed by connecting the first section of through holes, the second section of through holes and the third section of through holes.
在第二方面可能的实现方式中,电子器件为存储器,衬底设置有存储区,第一晶体管设置在存储区。In a possible implementation manner of the second aspect, the electronic device is a memory, the substrate is provided with a storage area, and the first transistor is provided in the storage area.
在第二方面可能的实现方式中,衬底还设置有逻辑区,存储区和逻辑区之间被隔离沟槽隔开;电子器件还包括:多个第二晶体管和布线层,多个第二晶体管设置在逻辑区;布线层堆叠在具有第二晶体管的逻辑区上。In a possible implementation manner of the second aspect, the substrate is further provided with a logic region, and the storage region and the logic region are separated by an isolation trench; the electronic device further includes: a plurality of second transistors and wiring layers, a plurality of second transistors The transistors are arranged in the logic region; the wiring layer is stacked on the logic region having the second transistor.
在具体实施时,逻辑区的第二晶体管和存储区的第一晶体管可以同时形成,也可以采用相同的工艺制得。During specific implementation, the second transistor in the logic region and the first transistor in the storage region can be formed simultaneously, or can be produced by the same process.
这里的多个第二晶体管和布线层形成的电路结构的功能可以是控制存储区的存储功能,如读写地址译码,读写动作执行,数据缓存等,也可以包含数据计算,图形数据处理等功能。The function of the circuit structure formed by the plurality of second transistors and the wiring layer here can be to control the storage function of the storage area, such as read and write address decoding, read and write action execution, data cache, etc., and can also include data calculation, graphics data processing and other functions.
在第二方面可能的实现方式中,布线层包括相堆叠的金属层,以及用于隔离相邻两层金属层的介电层,第一段通孔和第二段通孔的交界面位于相邻两层金属层之间。In a possible implementation manner of the second aspect, the wiring layer includes stacked metal layers, and a dielectric layer for isolating two adjacent metal layers, and the interface between the first section of through holes and the second section of through holes is located in the same phase between two adjacent metal layers.
在第二方面可能的实现方式中,第一晶体管和第二晶体管采用相同的工艺制得。这样的话,可以简化形成该电子器件的形成方法。In a possible implementation manner of the second aspect, the first transistor and the second transistor are fabricated using the same process. In this case, the formation method for forming the electronic device can be simplified.
在第二方面可能的实现方式中,电子器件还包括:形成在存储区上的字线和位线,字线和位线分别与第一晶体管连接,字线、位线、第一介电层和第二介电层,以及布线层采用相同的工艺制得。同样的,可以简化制备工艺。In a possible implementation manner of the second aspect, the electronic device further includes: a word line and a bit line formed on the storage region, the word line and the bit line are respectively connected to the first transistor, the word line, the bit line, the first dielectric layer The same process as the second dielectric layer and the wiring layer is used. Likewise, the preparation process can be simplified.
在第二方面可能的实现方式中,相连通的第一段通孔和第二段通孔形成用于容纳所述电容器的通孔;或者,相连通的第一段通孔和第二段通孔形成用于容纳电容器的通孔的部分,其中,用于容纳电容器的通孔的深宽比大于或者等于10∶1。这样的话,可以把用于容纳该电容器的通孔称为高深宽比通孔。In a possible implementation manner of the second aspect, the through holes of the first section and the through holes of the second section are connected to form a through hole for accommodating the capacitor; or, the through holes of the first section and the through holes of the second section that are communicated are formed. The hole forms part of a through hole for accommodating the capacitor, wherein the aspect ratio of the through hole for accommodating the capacitor is greater than or equal to 10:1. As such, the vias used to accommodate the capacitors may be referred to as high aspect ratio vias.
第三方面,本申请还提供了一种电子设备,包括印制电路板和上述第一方面任一实现方式中制得的电子器件或者上述第二方面任一实现方式的电子器件,印制电路板与电子器件电连接。In a third aspect, the present application also provides an electronic device, comprising a printed circuit board and an electronic device made in any implementation manner of the above-mentioned first aspect or an electronic device of any implementation manner of the above-mentioned second aspect, the printed circuit The board is electrically connected to the electronic device.
本申请实施例提供的电子设备包括第一方面实施例或者第二方面实施例的电子器件,因此本申请实施例提供的电子设备与上述技术方案的电子器件能够解决相同的技术问题,并达到相同的预期效果。The electronic device provided by the embodiment of the present application includes the electronic device of the first aspect embodiment or the second aspect embodiment. Therefore, the electronic device provided by the embodiment of the present application and the electronic device of the above technical solution can solve the same technical problems and achieve the same expected effect.
在第三方面可能的实现方式中,电子设备还包括逻辑处理电路,逻辑处理电路和电子器件集成在同一芯片中。从而使该电子器件形成嵌入式电子器件。In a possible implementation manner of the third aspect, the electronic device further includes a logic processing circuit, and the logic processing circuit and the electronic device are integrated in the same chip. Thereby, the electronic device forms an embedded electronic device.
在第三方面可能的实现方式中,电子设备还包括逻辑处理电路,该逻辑处理电路集成在第一芯片中,电子器件集成在第二芯片中,第一芯片和第二芯片堆叠并电连接,相堆叠的第一芯片和第二芯片设置在印制电路板上。以使该电子器件形成独立式电子器件。In a possible implementation manner of the third aspect, the electronic device further includes a logic processing circuit, the logic processing circuit is integrated in the first chip, the electronic device is integrated in the second chip, the first chip and the second chip are stacked and electrically connected, The stacked first chip and the second chip are arranged on the printed circuit board. so that the electronic device forms a self-contained electronic device.
在第三方面可能的实现方式中,电子设备还包括逻辑处理电路,该逻辑处理电路集成在第一芯片中,电子器件集成在第二芯片中,第一芯片和第二芯片分别设置在印制电路板上,并通过印制电路板电连接。以使该电子器件形成独立式电子器件。In a possible implementation manner of the third aspect, the electronic device further includes a logic processing circuit, the logic processing circuit is integrated in the first chip, the electronic device is integrated in the second chip, and the first chip and the second chip are respectively arranged on the printed circuit board. on the circuit board and are electrically connected through the printed circuit board. so that the electronic device forms a self-contained electronic device.
附图说明Description of drawings
图1为DRAM中的一个存储单元的结构示意图;Fig. 1 is the structural representation of a memory cell in DRAM;
图2a、图2b和图2c为现有技术中形成存储器的方法中各步骤完成后相对应的结构示意图;Figure 2a, Figure 2b and Figure 2c are schematic structural diagrams corresponding to the completion of each step in the method for forming a memory in the prior art;
图3为本申请实施例的一种电子设备的部分结构示意图;FIG. 3 is a partial structural schematic diagram of an electronic device according to an embodiment of the application;
图4为本申请实施例的另一种电子设备的部分结构示意图;4 is a schematic partial structure diagram of another electronic device according to an embodiment of the application;
图5为本申请实施例的另一种电子设备的部分结构示意图;5 is a schematic partial structure diagram of another electronic device according to an embodiment of the present application;
图6为本申请实施例的存储器的部分结构示意图;6 is a schematic diagram of a partial structure of a memory according to an embodiment of the present application;
图7为本申请实施例的电子器件的形成方法的工艺流程图;7 is a process flow diagram of a method for forming an electronic device according to an embodiment of the present application;
图8为图7工艺流程的每一步骤完成后的剖面图;FIG. 8 is a cross-sectional view after each step of the process flow of FIG. 7 is completed;
图9a、图9b、图9c、图9d、图9e、图9f、图9g、图9h、图9i、图9j、图9k、图9l为本申请实施例中形成存储器的方法中各步骤完成后相对应的结构示意图;9a, 9b, 9c, 9d, 9e, 9f, 9g, 9h, 9i, 9j, 9k, and 9l are the steps in the method for forming a memory according to the embodiment of the present application after completion of each step The corresponding structure diagram;
图10为本申请实施例中形成有第一段通孔、第二段通孔和第三段通孔的结构示意图;10 is a schematic structural diagram of a first section of through holes, a second section of through holes and a third section of through holes formed in an embodiment of the application;
图11为本申请实施例的存储器的部分结构示意图。FIG. 11 is a schematic diagram of a partial structure of a memory according to an embodiment of the present application.
附图标记:Reference number:
01-PCB;02-芯片;021-第一芯片;022-第二芯片;01-PCB; 02-chip; 021-first chip; 022-second chip;
11-衬底;12-晶体管;121-第一晶体管;1-1-漏极;1-2-栅极;1-3-源极;122-第二晶体管;13-介电层;14-布线层;141-第一布线层;142-第二布线层;143-第三布线层;15-台阶;2-电容器;3-位线;4-字线;5-隔离沟槽;6-金属层;61-第一金属层;62-第二金属层;63-第三金属层;71-第一介电层;72-第二介电层;73-第三介电层;74-第四介电层;75-第五介电层;8-通孔;81-第一段通孔;82-第二段通孔;83-第三段通孔;9-临时填充层;101-第一电极层;102-电容介质层;103-第二电极层;111-第一覆盖层;112-第二覆盖层;113-第三覆盖层。11-substrate; 12-transistor; 121-first transistor; 1-1-drain; 1-2-gate; 1-3-source; 122-second transistor; 13-dielectric layer; 14- wiring layer; 141-first wiring layer; 142-second wiring layer; 143-third wiring layer; 15-step; 2-capacitor; 3-bit line; 4-word line; 5-isolation trench; 6- metal layer; 61-first metal layer; 62-second metal layer; 63-third metal layer; 71-first dielectric layer; 72-second dielectric layer; 73-third dielectric layer; 74- Fourth dielectric layer; 75 - fifth dielectric layer; 8 - through hole; 81 - first through hole; 82 - second through hole; 83 - third through hole; 9 - temporary filling layer; 101 - first electrode layer; 102 - capacitive dielectric layer; 103 - second electrode layer; 111 - first cover layer; 112 - second cover layer; 113 - third cover layer.
具体实施方式Detailed ways
本申请实施例提供一种电子设备。该电子设备可以包括手机(mobile phone)、平板电脑(pad)、智能穿戴产品(例如,智能手表、智能手环)、虚拟现实(virtual reality,VR)设备、增强现实(augmented reality,AR),还可以是家用电器,还可以是汽车、人工智能等设备,还可以是服务器(server)、数据中心(data center)等。本申请实施例对上述电子设备的具体形式不做特殊限制。Embodiments of the present application provide an electronic device. The electronic device may include a mobile phone (mobile phone), a tablet computer (pad), a smart wearable product (eg, a smart watch, a smart bracelet), a virtual reality (VR) device, an augmented reality (AR), It can also be home appliances, automobiles, artificial intelligence and other equipment, and can also be servers, data centers, and so on. The embodiments of the present application do not specifically limit the specific form of the above electronic device.
在上述所述的电子设备中,可以包括存储器,以及中央处理单元(central processing unit,CPU),或者,图像图形处理单元(graphic processing unit,GPU)等。其中,存储器用于存储CPU或者GPU的运算数据。In the above-mentioned electronic device, a memory, a central processing unit (central processing unit, CPU), or an image graphics processing unit (graphic processing unit, GPU), etc. may be included. Among them, the memory is used to store the operation data of the CPU or the GPU.
在存储器中,由于DRAM相比其他存储器结构简单,比如与静态随机存取存储器(Static Random-Access Memory,SRAM)相比,SRAM中的一个存储单元具有六个晶体管,而DRAM中的一个存储单元仅具有一个晶体管。这样的话,DRAM拥有非常高的密度,单位体积的容量较高,成本也较低,进而,DRAM在电子设备中被广泛的应用。In memory, because DRAM has a simpler structure than other memories, for example, compared with Static Random-Access Memory (SRAM), one memory cell in SRAM has six transistors, while one memory cell in DRAM has six transistors. Has only one transistor. In this case, DRAM has very high density, high capacity per unit volume, and low cost. Furthermore, DRAM is widely used in electronic equipment.
图3所示的为一种电子设备的部分结构图,该电子设备可以包括印制电路板(printed circuit board,PCB)01和集成在PCB01上的芯片封装结构,芯片封装结构可以通过球阵列(ball grid array,BGA)与PCB01连接。Fig. 3 shows a partial structure diagram of an electronic device, the electronic device may include a printed circuit board (PCB) 01 and a chip package structure integrated on the PCB 01, and the chip package structure can pass through a ball array ( ball grid array, BGA) is connected to PCB01.
在图3中,芯片封装结构包括堆叠的第一芯片021和第二芯片022,第一芯片021和第二芯片022中的一个芯片为逻辑芯片,比如为CPU或者GPU,另一个芯片为DRAM,并且第一芯片021和第二芯片022之间可以通过硅通孔(through silicon via,TSV)和重布线层(redistribution layer,RDL)相导通。在图3中,由于逻辑芯片和DRAM为两个相独立的芯片,因此该DRAM可以被称为独立式DRAM。In FIG. 3, the chip package structure includes a stacked first chip 021 and a second chip 022, one of the first chip 021 and the second chip 022 is a logic chip, such as a CPU or GPU, and the other chip is a DRAM, In addition, the first chip 021 and the second chip 022 can be connected through a through silicon via (TSV) and a redistribution layer (RDL). In FIG. 3 , since the logic chip and the DRAM are two independent chips, the DRAM can be called a stand-alone DRAM.
图4所示的为另一种电子设备的部分结构图,该电子设备也包括PCB01和分别集成在PCB01上的第一芯片021和第二芯片022,第一芯片021和第二芯片022可以分别通过BGA与PCB01连接。其中,第一芯片021和第二芯片022的一个芯片为逻辑芯片,另一个芯片为DRAM,逻辑芯片和DRAM可以通过布设在PCB01上金属走线实现电导通。和图3相同,由于逻辑芯片和DRAM为两个相独立的芯片,因此该DRAM可以被称为独立式DRAM。FIG. 4 shows a partial structure diagram of another electronic device. The electronic device also includes a PCB01 and a first chip 021 and a second chip 022 respectively integrated on the PCB01. The first chip 021 and the second chip 022 can be respectively Connect with PCB01 through BGA. Wherein, one of the first chip 021 and the second chip 022 is a logic chip, and the other chip is a DRAM, and the logic chip and the DRAM can be electrically connected through metal wires arranged on the PCB01. Like FIG. 3 , since the logic chip and the DRAM are two independent chips, the DRAM can be called a standalone DRAM.
图5所示的为另一种电子设备的部分结构图,该电子设备也包括PCB01和集成在PCB01上的包含芯片上系统(system on a chip,SOC)的芯片02。芯片02将DRAM 和逻辑处理电路集成到同一芯片中,因此,该DRAM可以被称为嵌入式DRAM。FIG. 5 is a partial structure diagram of another electronic device, which also includes a PCB01 and a chip 02 including a system on a chip (SOC) integrated on the PCB01. The chip 02 integrates the DRAM and the logic processing circuit into the same chip, so the DRAM can be called an embedded DRAM.
图6所示的是DRAM的部分结构图,在DRAM中,包含有多条WL和多条BL,多条WL沿第一方向(如图6中的X方向)平行布设,多条BL沿第二方向(如图6中的Y方向)平行布设。这里的X方向与Y方向可以相垂直,也可以具有其他范围的夹角。Figure 6 shows a partial structure diagram of the DRAM. In the DRAM, there are multiple WLs and multiple BLs. The multiple WLs are arranged in parallel along the first direction (X direction in Figure 6), and the multiple BLs are arranged along the first The two directions (the Y direction in FIG. 6 ) are arranged in parallel. The X direction and the Y direction here may be perpendicular, and may also have included angles in other ranges.
在一条WL和一条BL相交叉的位置处,设置有一个存储单元。由于具有多条WL和多条BL,这样一来,就形成了呈阵列布设的多个存储单元,且相邻两个存储单元之间被隔离墙(图中未示出)隔开。At a position where a line of WL and a line of BL intersect, a memory cell is provided. Since there are a plurality of WLs and a plurality of BLs, thus, a plurality of memory cells arranged in an array are formed, and two adjacent memory cells are separated by a partition wall (not shown in the figure).
继续结合图6,一个存储单元包括一个晶体管和一个电容器,该晶体管可以是鳍式晶体管(FinFET),例如三栅极晶体管(tri-gate transistor,TG)。晶体管具有栅极(gate)1-2、源极(source)1-3和漏极(drain)1-1。栅极(gate)1-2与WL连接,漏极(drain)1-1与BL连接,源极(source)1-3与电容器2连接。也可以是,漏极(drain)1-1与电容器2连接,源极(source)1-3与BL连接。Continuing with reference to FIG. 6 , a memory cell includes a transistor and a capacitor, and the transistor may be a fin transistor (FinFET), such as a tri-gate transistor (TG). The transistor has a gate 1-2, a source 1-3 and a drain 1-1. A gate (gate) 1-2 is connected to WL, a drain (drain) 1-1 is connected to BL, and a source (source) 1-3 is connected to the capacitor 2. The drain (drain) 1-1 may be connected to the capacitor 2, and the source (source) 1-3 may be connected to BL.
具体工作时,WL上的电压信号控制晶体管的导通或者断开,进而通过BL读取存储在电容器中的数据信息,或者通过BL将数据信号写入电容器中进行存储,以实现读写操作。During specific operation, the voltage signal on the WL controls the on or off of the transistor, and then reads the data information stored in the capacitor through the BL, or writes the data signal into the capacitor for storage through the BL, so as to realize the read and write operation.
随着半导体技术的发展,为了提升单位面积集成度,需要缩小电容器的宽度尺寸,比如,电容器为圆筒状(Cylinder),就是需要缩小电容器的径向尺寸,又为了不减少电容器的容量,保障数据存储时间,需要加长电容器的深度尺寸,这样的话,就会形成具有高深宽比(aspect ratio)的电容器,例如,现在已经发展至电容器的径向尺寸为几十纳米,深度尺寸达到了1微米。With the development of semiconductor technology, in order to improve the integration per unit area, it is necessary to reduce the width of the capacitor. For example, if the capacitor is cylindrical, it is necessary to reduce the radial size of the capacitor, and in order not to reduce the capacity of the capacitor, ensure For data storage time, it is necessary to lengthen the depth dimension of the capacitor. In this case, a capacitor with a high aspect ratio will be formed. For example, the radial dimension of the capacitor has now been developed to several tens of nanometers, and the depth dimension has reached 1 micron. .
在形成电容器时,可以先在介电层内开设通孔,再在通孔的壁面上形成第一电极层,再在第一电极层上形成电容介质层,然后在电容介质层上形成第二电极层,进而形成设置在通孔内的电容器。When forming a capacitor, a through hole can be opened in the dielectric layer, a first electrode layer can be formed on the wall surface of the through hole, a capacitor dielectric layer can be formed on the first electrode layer, and a second electrode layer can be formed on the capacitor dielectric layer. The electrode layer is formed, thereby forming a capacitor arranged in the through hole.
利用干法刻蚀工艺在介电层内刻蚀通孔时,通孔的顶部形貌先形成,在继续刻蚀底部形貌时,这样会扩大顶部的通孔直径。为了尽量保证通孔的顶部直径和底部直径相同,需要采用刻蚀、再沉积、再刻蚀的方式。实现方法是在干法刻蚀中,采用含碳量较多的刻蚀气体,如八氟环丁烷(C4F8),生成的聚合物(Polymer)会沉积在通孔侧壁,保护已经刻蚀出的通孔直径不被扩大,而多余Polymer需要排出通孔,以避免影响后续的刻蚀过程。When the through hole is etched in the dielectric layer by the dry etching process, the top shape of the through hole is formed first, and when the bottom shape is etched continuously, the diameter of the top through hole will be enlarged. In order to ensure that the top and bottom diameters of the via holes are the same as possible, methods of etching, redepositing, and re-etching are required. The realization method is to use etching gas with more carbon content in dry etching, such as octafluorocyclobutane (C4F8), and the resulting polymer (Polymer) will be deposited on the sidewall of the through hole to protect the etched gas. The diameter of the via hole is not enlarged, and the excess polymer needs to be drained out of the via hole to avoid affecting the subsequent etching process.
在低深宽比的刻蚀工艺(如深宽比在7:1~10:1内),Polymer较容易排出,但随着深宽比增大(如深宽比大于10:1),Polymer容易大量沉积在通孔底部,阻挡后续的刻蚀过程,造成通孔没有刻蚀到底部的现象。DRAM的电容刻蚀工艺,同时具有高深宽比和小通孔尺寸的特点,因此对刻蚀工艺的挑战很大。In the etching process of low aspect ratio (for example, the aspect ratio is within 7:1 to 10:1), the polymer is easier to discharge, but as the aspect ratio increases (for example, the aspect ratio is greater than 10:1), the polymer It is easy to deposit a large amount at the bottom of the through hole, which blocks the subsequent etching process, resulting in the phenomenon that the through hole is not etched to the bottom. The capacitive etching process of DRAM has the characteristics of high aspect ratio and small via size at the same time, so it is a great challenge to the etching process.
本申请提出了一种电子器件的形成方法,该电子器件中的通孔具有高深宽比,且该形成方法包括了利用低深宽比的开孔工艺形成具有高深度比的通孔,下面结合附图对该电子器件的形成方法详细说明。The present application proposes a method for forming an electronic device, wherein a through hole in the electronic device has a high aspect ratio, and the forming method includes using a low aspect ratio opening process to form a through hole with a high depth ratio, which is combined below The accompanying drawings illustrate the formation method of the electronic device in detail.
结合图7和图8,对该电子器件的形成方法详细介绍。图7为该电子器件的形成方法的工艺流程图,图8为该图7工艺流程的每一步骤完成后的剖面图。With reference to FIG. 7 and FIG. 8 , the method for forming the electronic device is described in detail. FIG. 7 is a process flow diagram of the method for forming the electronic device, and FIG. 8 is a cross-sectional view of each step of the process flow diagram of FIG. 7 after completion.
参照图7的步骤S1和图8中的(a)的结构图,图8中的(a)为完成步骤S1后的结构图,步骤S1包括:在衬底1上形成第一晶体管121。图8中的(a)的第一晶体管121为示例性的结构,在一些可选择的实施方式中,第一晶体管121可以由设置在衬底1上的栅极、源极和漏极形成。Referring to the structure diagram of step S1 in FIG. 7 and FIG. 8( a ), FIG. 8( a ) is the structure diagram after step S1 is completed. Step S1 includes: forming the first transistor 121 on the substrate 1 . The first transistor 121 in (a) of FIG. 8 is an exemplary structure, and in some alternative embodiments, the first transistor 121 may be formed by a gate electrode, a source electrode and a drain electrode provided on the substrate 1 .
这里的衬底可以为半导体材料,例如为单晶硅衬底、单晶锗衬底或绝缘体上硅(silicon-on-insulator,SOI)衬底等。本领域技术人员可以根据实际需求选择合适的材料作为衬底,本申请在此不作限定。The substrate here may be a semiconductor material, for example, a single crystal silicon substrate, a single crystal germanium substrate, or a silicon-on-insulator (SOI) substrate. Those skilled in the art can select a suitable material as the substrate according to actual needs, which is not limited in this application.
另外,这里的第一晶体管可以为低电压的金氧半场效晶体管(metal-oxide-semiconductor field-effect transistor,MOSFET),比如,三栅极晶体管(tri-gate transistor,TG)。还有,在衬底上形成第一晶体管时,可以是形成如图6所示的呈阵列排布的多个第一晶体管。In addition, the first transistor here may be a low-voltage metal-oxide-semiconductor field-effect transistor (MOSFET), such as a tri-gate transistor (TG). Also, when the first transistors are formed on the substrate, a plurality of first transistors arranged in an array as shown in FIG. 6 may be formed.
继续参照图7的步骤S2和图8中的(b)的结构图,图8中的(b)为完成步骤S2后的结构图,步骤S2包括:在具有第一晶体管121的衬底上堆叠第一介电层71。也可以这样理解,第一介电层71覆盖在具有多个第一晶体管121的衬底上。Continue to refer to the structural diagram of step S2 in FIG. 7 and (b) in FIG. 8 , (b) in FIG. 8 is the structural diagram after completing step S2, and step S2 includes: stacking on the substrate having the first transistor 121 The first dielectric layer 71 . It can also be understood that the first dielectric layer 71 covers the substrate having the plurality of first transistors 121 .
该第一介电层可以为多层堆叠结构或如图8中的(b)所示的单层结构,第一介电层的介电材料可以是氧化硅、氮化硅、氮氧化硅、掺氟的二氧化硅、掺硼的二氧化硅、掺磷的二氧化硅或掺硼磷的二氧化硅中的一种或者至少两种的组合。The first dielectric layer can be a multi-layer stack structure or a single-layer structure as shown in (b) in FIG. 8 , and the dielectric material of the first dielectric layer can be silicon oxide, silicon nitride, silicon oxynitride, One or a combination of at least two of fluorine-doped silica, boron-doped silica, phosphorus-doped silica, or boron-phosphorus-doped silica.
继续参照图7的步骤S3和图8中的(c)的结构图,图8中的(c)为完成步骤S3后的结构图,步骤S3包括:在第一介电层71内开设贯通至第一晶体管121的第一段通孔81。Continue to refer to the structure diagram of step S3 in FIG. 7 and (c) in FIG. 8 , (c) in FIG. 8 is the structure diagram after step S3 is completed, and step S3 includes: opening through to the first dielectric layer 71 The first segment of the through hole 81 of the first transistor 121 .
需要说明的是,当第一晶体管121为多个时,第一段通孔81也为多个,且多个第一段通孔81与多个第一晶体管121是一对一设置的,即一个第一晶体管121,对应开设一个第一段通孔81,图8中的(c)示例性的画出了一个第一晶体管121,以及与该一个第一晶体管121相对应的一个第一段通孔81。It should be noted that when there are multiple first transistors 121 , there are also multiple first-segment through holes 81 , and the multiple first-segment through-holes 81 and the multiple first transistors 121 are arranged one-to-one, that is, A first transistor 121 corresponds to a first segment through hole 81 . (c) in FIG. 8 exemplarily depicts a first transistor 121 and a first segment corresponding to the first transistor 121 Through hole 81 .
该第一段通孔可以采用能够形成低深宽比(例如,深宽比小于或等于5∶1)通孔的干法刻蚀工艺制得。当采用干法刻蚀工艺开设第一段通孔时,开孔工艺步骤可以为:先在第一介电层的远离衬底的部分将第一段通孔的顶部形貌形成,并采用含碳量较多的刻蚀气体,如八氟环丁烷(C 4F 8),这样生成的聚合物(Polymer)会沉积在通孔侧壁,保护已经刻蚀出的通孔直径不被扩大,并且将多余Polymer排出通孔,继续刻蚀底部形貌,最终形成第一段通孔。 The first section of through holes may be formed by a dry etching process capable of forming low aspect ratio (eg, aspect ratio less than or equal to 5:1) through holes. When a dry etching process is used to open the first section of through holes, the opening process steps may be as follows: first, the top shape of the first section of through holes is formed on the part of the first dielectric layer away from the substrate, and the top section of the first section of through holes is formed by using Etching gas with high carbon content, such as octafluorocyclobutane (C 4 F 8 ), the polymer (Polymer) generated in this way will be deposited on the sidewall of the through hole to protect the diameter of the etched through hole from being enlarged , and discharge the excess polymer out of the through hole, continue to etch the bottom topography, and finally form the first section of through hole.
继续参照图7的步骤S4和图8中的(d)的结构图,图8中的(d)为完成步骤S4后的结构图,步骤S4:在第一段通孔81内的至少靠近第一段通孔81的孔口的位置处填充材料,以使填充的材料形成将第一段通孔的孔口堵住的临时填充层9。Continue to refer to the structure diagram of step S4 in FIG. 7 and (d) in FIG. 8 , (d) in FIG. 8 is the structure diagram after completing step S4, step S4: in the first section of the through hole 81 at least close to the first Materials are filled at the positions of the openings of the through holes 81 of the first section, so that the filled materials form a temporary filling layer 9 that blocks the openings of the through holes of the first section.
这里的临时填充层可以如图8中的(d)所示,仅将第一段通孔的远离衬底的孔口的位置填满,也可以将整个第一段通孔填满。The temporary filling layer here may be as shown in (d) of FIG. 8 , only filling the positions of the first-stage through holes away from the orifice of the substrate, or filling the entire first-stage through-holes.
临时填充层9的材料可以具有多种选择,比如,可以采用多晶硅、碳或者金属(例如,铜、铁、钨)等。The material of the temporary filling layer 9 may have various choices, for example, polysilicon, carbon, or metal (eg, copper, iron, tungsten), etc. may be used.
继续参照图7的步骤S5和图8中的(e)的结构图,图8中的(e)为完成步骤S5后的结构图,步骤S5包括:在第一介电层71上堆叠第二介电层72。Continue to refer to the structural diagram of step S5 in FIG. 7 and (e) in FIG. 8 , (e) in FIG. 8 is the structural diagram after step S5 is completed, and step S5 includes: stacking a second dielectric layer on the first dielectric layer 71 Dielectric layer 72 .
该第二介电层也可以为多层堆叠结构或图8中的(e)所示的单层结构,第二介电层的介电材料也可以是氧化硅、氮化硅、氮氧化硅、掺氟的二氧化硅、掺硼的二氧化硅、掺磷的二氧化硅或掺硼磷的二氧化硅中的一种或者至少两种的组合。The second dielectric layer can also be a multi-layer stack structure or a single-layer structure as shown in (e) in FIG. 8 , and the dielectric material of the second dielectric layer can also be silicon oxide, silicon nitride, silicon oxynitride , one of fluorine-doped silica, boron-doped silica, phosphorus-doped silica, or boron-phosphorus-doped silica, or a combination of at least two of them.
继续参照图7的步骤S6和图8中的(f)的结构图,图8中的(f)为完成步骤S6后的结构图,步骤S6包括:在第二介电层72内开设与第一段通孔81相连通的第二段通孔82。Continue to refer to the structure diagram of step S6 in FIG. 7 and (f) in FIG. 8 , (f) in FIG. 8 is the structure diagram after step S6 is completed, and step S6 includes: opening and first in the second dielectric layer 72 A second section of through holes 82 communicated with one section of through holes 81 .
在第二介电层72内开设第二段通孔82也可以采用干法刻蚀工艺,具体工艺步骤如上述的开设第一段通孔81的工艺。A dry etching process may also be used to open the second through hole 82 in the second dielectric layer 72 , and the specific process steps are the same as the above-mentioned process of opening the first through hole 81 .
基于上述可知,在步骤S4中的第一段通孔81内形成临时填充层9的目的是:防止在第一介电层71上形成第二介电层72时,介电材料又填充在第一段通孔81内,也就是通过临时填充层9将第一段通孔81的位置先占据,所以,至少将第一段通孔的孔口的位置填充满即可。Based on the above, the purpose of forming the temporary filling layer 9 in the first through hole 81 in step S4 is to prevent the dielectric material from being filled in the first dielectric layer 71 when the second dielectric layer 72 is formed on the first dielectric layer 71. In the through hole 81 of the first section, that is, the position of the through hole 81 of the first section is occupied first by the temporary filling layer 9, so at least the position of the hole of the through hole of the first section can be filled.
继续参照图7的步骤S7和图8中的(g)的结构图,图8中的(g)为完成步骤S7后的结构图,步骤S7包括:去除临时填充层9。Continue to refer to the structure diagram of step S7 in FIG. 7 and (g) in FIG. 8 , (g) in FIG. 8 is the structure diagram after step S7 is completed, and step S7 includes: removing the temporary filling layer 9 .
去除临时填充层的工艺可以根据填充材料的不同选择不同的去除工艺,比如,若采用多晶硅作为填充材料时,可以采用湿法刻蚀去除多晶硅。若采用金属作为填充材料时,也可以采用湿法刻蚀去除金属。若采用碳作为填充材料时,可以采用干法刻蚀去除碳。当然,也可以采用其他去除工艺。The process for removing the temporary filling layer may be different depending on the filling material. For example, if polysilicon is used as the filling material, wet etching may be used to remove the polysilicon. If metal is used as the filling material, the metal can also be removed by wet etching. If carbon is used as the filling material, the carbon can be removed by dry etching. Of course, other removal processes may also be employed.
继续参照图7的步骤S8和图8中的(h)的结构图,图8中的(h)为完成步骤S8后的结构图,步骤S8包括:在相连通的第一段通孔81和第二段通孔82内形成和第一晶体管121电连接的电容器2。Continue to refer to the structural diagram of step S8 in FIG. 7 and (h) in FIG. 8 , (h) in FIG. 8 is the structural diagram after completing step S8, and step S8 includes: connecting the first section of through holes 81 and The capacitor 2 electrically connected to the first transistor 121 is formed in the second through hole 82 .
上述步骤S1至步骤S8中,仅示出了包含两段通孔,若还包含第三段通孔时,在去除临时填充层之前,在第二介电层内开设第二段通孔之后,该形成方法还包括以下步骤:在第二段通孔内的至少靠近第二段通孔的孔口的位置处填充材料,以形成临时填充层;在第二介电层上堆叠第三介电层;在第三介电层内开设与第二段通孔相连通第三段通孔。然后再去除临时填充层,这里的去除临时填充层就不仅需要去除第一段通孔内的临时填充层,还需要去除第二段通孔内的临时填充层。In the above steps S1 to S8, only two sections of through holes are shown. If a third section of through holes is also included, before the temporary filling layer is removed, after the second section of through holes is opened in the second dielectric layer, The forming method further includes the following steps: filling a material at least at a position close to an opening of the second-stage through-hole in the second-stage through-hole to form a temporary filling layer; stacking a third dielectric layer on the second dielectric layer layer; a third section of through hole is opened in the third dielectric layer and communicated with the second section of through hole. Then, the temporary filling layer is removed. The removal of the temporary filling layer here not only needs to remove the temporary filling layer in the first section of through holes, but also needs to remove the temporary filling layer in the second section of through holes.
若还包括第四段通孔时,可以依照上述的形成第三段通孔的方法执行,在此不再赘述。If the fourth stage of through holes is also included, the method can be performed according to the above-mentioned method for forming the third stage of through holes, which will not be repeated here.
结合上述步骤S1至步骤S8,可以看出,在形成贯通在介电层内的通孔时,至少要包括两次开孔工艺,且每一次开孔工艺可以采用低深宽比开孔工艺,也就是说,相比现有技术的一次开孔,本申请利用至少两次低深宽比开孔技术,就可以实现具有高深宽比的通孔,这样的话,即使通孔不断微缩,通孔的深宽比不断增大,也不会提高开孔工艺难度。示例性的,当深宽比大于或者等于10∶1时,就可以采用图7和图8所示方法形成,这里的通孔的深宽比中的孔深可以在300纳米(nm)至1微米(μm)之间,通孔的深宽比中的孔径可以在30纳米(nm)至40纳米(nm)之间。当然,进一步微缩的通孔也可以采用图7和图8所示方法形成。Combining the above steps S1 to S8, it can be seen that when forming a through hole through the dielectric layer, at least two opening processes are required, and each opening process can use a low aspect ratio opening process, That is to say, compared with the one-time opening of the prior art, the present application utilizes at least two low-aspect-ratio opening techniques to realize through-holes with high aspect ratios. The aspect ratio continues to increase, and it will not increase the difficulty of the opening process. Exemplarily, when the aspect ratio is greater than or equal to 10:1, it can be formed by the method shown in FIG. 7 and FIG. 8 , and the hole depth in the aspect ratio of the through hole here can be 300 nanometers (nm) to 1. The pore size in the aspect ratio of the via may be between 30 nanometers (nm) and 40 nanometers (nm). Of course, further reduced through holes can also be formed using the methods shown in FIG. 7 and FIG. 8 .
当上述电子器件为DRAM时,也可以采用上述图7和图8所示方法形成,当然,具有电容器的,且需要开设容纳电容器的通孔的其他电子器件也可以采用图7和图8 所示方法形成。When the above-mentioned electronic device is a DRAM, it can also be formed by the method shown in the above-mentioned FIGS. 7 and 8 . Of course, other electronic devices that have capacitors and need to open through holes for accommodating capacitors can also be formed by the methods shown in FIGS. 7 and 8 . method is formed.
下面结合附图对本申请提供的一种DRAM的具体实施方式进行详细描述,该DRAM可以是独立式DRAM,也可以是嵌入式DRAM。A specific implementation manner of a DRAM provided by the present application will be described in detail below with reference to the accompanying drawings. The DRAM may be a stand-alone DRAM or an embedded DRAM.
如图9a所示,衬底1设置有存储区和逻辑区,且存储区和逻辑区之间被隔离沟槽5隔开,图9a为一种存储器在形成过程中完成第一步骤后的剖面图,在该第一步骤中,在存储区形成第一晶体管121,在逻辑区形成第二晶体管122,这里的第一晶体管121和第二晶体管122分别为多个,在图9a中,仅示例了一个第一晶体管121和一个第二晶体管122。As shown in FIG. 9a, the substrate 1 is provided with a storage area and a logic area, and the storage area and the logic area are separated by an isolation trench 5. FIG. 9a is a cross-section of a memory after the first step in the formation process. In the first step, the first transistor 121 is formed in the storage area, and the second transistor 122 is formed in the logic area. Here, there are multiple first transistors 121 and second transistors 122 respectively. In FIG. 9a, only an example is shown. A first transistor 121 and a second transistor 122 are provided.
需要说明的是,本申请的图9a至图9k中仅示例一个存储单元(包括一个第一晶体管和与其相连接的一个电容器)的形成方法,其余的存储单元和图9a至图9k所述的存储单元的形成方法相同。It should be noted that, only a method for forming one memory cell (including a first transistor and a capacitor connected to it) is illustrated in FIGS. 9a to 9k of the present application, and the rest of the memory cells are the same as those described in FIGS. 9a to 9k . The memory cells are formed in the same way.
这里的存储区的功能为用于存储数据的区域。在芯片设计时,衬底1可以被设计成具有存储数据的存储区,或者是被设计成具有数据处理功能的逻辑区。在一种实施方式中,衬底1还可以被划分多个区域,其中包括存储区和逻辑区。上述逻辑区还可以具有其他功能,例如产生控制信号。这些控制信号可以是读写控制信号,用于控制存储区中数据的读写操作。The function of the storage area here is an area for storing data. During chip design, the substrate 1 can be designed to have a memory area for storing data, or a logic area to have a data processing function. In one embodiment, the substrate 1 may also be divided into a plurality of regions, including memory regions and logic regions. The above-mentioned logic area may also have other functions, such as generating control signals. These control signals may be read and write control signals for controlling read and write operations of data in the storage area.
继续结合图9a,第一晶体管121包括均形成在衬底1上的漏极1-1、栅极1-2和源极1-3,漏极1-1和源极1-3之间可以通过衬底1相连通。同样的,第二晶体管122也可以包括均形成在衬底1上的漏极1-1、栅极1-2和源极1-3,漏极1-1和源极1-3之间可以通过衬底1相连通。Continuing with reference to FIG. 9a , the first transistor 121 includes a drain electrode 1-1, a gate electrode 1-2 and a source electrode 1-3 all formed on the substrate 1, and between the drain electrode 1-1 and the source electrode 1-3 can be communicated through the substrate 1 . Similarly, the second transistor 122 may also include a drain electrode 1-1, a gate electrode 1-2 and a source electrode 1-3, which are all formed on the substrate 1, and the space between the drain electrode 1-1 and the source electrode 1-3 may be communicated through the substrate 1 .
在形成第一晶体管121和第二晶体管122时,可以采用相同的逻辑工艺制得,以图9a为例,可以采用平面型栅极结构(planar gate)逻辑工艺技术制作第一晶体管和第二晶体管,也可以采用高介电常数介质层金属栅极(high K dielectric metal gate,HKMG)逻辑工艺技术制作,也可以采用鳍式场效应晶体管(Fin field-efffect transistor,FinFET)逻辑工艺技术制作。When forming the first transistor 121 and the second transistor 122, the same logic process can be used to manufacture the first transistor and the second transistor. Taking FIG. 9a as an example, a planar gate logic process technology can be used to manufacture the first transistor and the second transistor. , it can also be fabricated by high K dielectric metal gate (HKMG) logic process technology, or it can be fabricated by Fin field-efffect transistor (FinFET) logic process technology.
这样的话,可以采用相兼容的逻辑(logic)工艺手段形成存储区的第一晶体管和逻辑区的第二晶体管,进而,可以简化整个存储区的制备工艺。In this way, the first transistor of the storage area and the second transistor of the logic area can be formed by using compatible logic process means, and further, the fabrication process of the entire storage area can be simplified.
图9b为图9a所示结构基础上完成第二步骤后的剖面图,在该第二步骤中,在存储区形成位线3和字线4,且使得位线3与漏极1-1连接,字线4与栅极1-2连接,也可以是位线3与源极1-3连接。FIG. 9b is a cross-sectional view of the structure shown in FIG. 9a after completing the second step. In the second step, the bit line 3 and the word line 4 are formed in the storage area, and the bit line 3 is connected to the drain 1-1. , the word line 4 is connected to the gate electrode 1-2, and the bit line 3 may also be connected to the source electrode 1-3.
同样的,在图9b中,仅示出了一条位线3和一条字线4,实际中,会形成相平行的多条位线3和多条相平行的字线4。Similarly, in FIG. 9b, only one bit line 3 and one word line 4 are shown, in practice, a plurality of parallel bit lines 3 and a plurality of parallel word lines 4 are formed.
图9c为图9b所示结构基础上完成第三步骤后的剖面图,在该第三步骤中,在具有第二晶体管122的逻辑区上堆叠第一布线层141,在具有第一晶体管、字线和位线的存储区上堆叠第一介电层71。9c is a cross-sectional view of the structure shown in FIG. 9b after completing the third step. In the third step, the first wiring layer 141 is stacked on the logic region with the second transistor 122, and the first wiring layer 141 is stacked on the logic region with the first transistor, the word A first dielectric layer 71 is stacked on the memory regions of the lines and bit lines.
上述的存储区上的第一介电层71,和逻辑区上的第一布线层141可以同时形成。也可以是先形成第一介电层71,再形成第一布线层141。也可以是先形成第一布线层141,再形成第一介电层71。The above-mentioned first dielectric layer 71 on the storage region and the first wiring layer 141 on the logic region can be formed simultaneously. Alternatively, the first dielectric layer 71 may be formed first, and then the first wiring layer 141 may be formed. Alternatively, the first wiring layer 141 may be formed first, and then the first dielectric layer 71 may be formed.
若第一介电层71和第一布线层141同时形成时,可选择的形成过程包括:同时在 逻辑区和存储区上均形成一层介电层;然后仅在逻辑区的介电层上形成金属层;再同时在存储区的介电层上和逻辑区的具有金属层的介电层上均形成一层介电层。也就是说,同时在逻辑区和存储区形成介电层。If the first dielectric layer 71 and the first wiring layer 141 are formed at the same time, the optional forming process includes: forming a dielectric layer on both the logic area and the storage area at the same time; and then only forming a dielectric layer on the logic area forming a metal layer; and simultaneously forming a dielectric layer on both the dielectric layer in the storage area and the dielectric layer with the metal layer in the logic area. That is, a dielectric layer is formed on the logic region and the memory region at the same time.
重复上述的步骤,结合图9c,可以在存储区制得由多层介电层相堆叠形成的第一介电层71,以及在逻辑区制得由多层介电层相堆叠形成的第三介电层73,且第三介电层73内具有多层金属层。这里的第一介电层71的材料和第三介电层73的材料可以相同,当然,也可以不同。Repeating the above steps, with reference to FIG. 9c, a first dielectric layer 71 formed by stacking multiple layers of dielectric layers can be fabricated in the storage area, and a third layer formed by stacking multiple layers of dielectric layers in the logic area. The dielectric layer 73 has multiple metal layers in the third dielectric layer 73 . Here, the material of the first dielectric layer 71 and the material of the third dielectric layer 73 may be the same, or of course, may be different.
需要说明的是:在形成上述的多层金属层时,不仅包括与衬底相平行布设的金属层,也包括用于连接相平行的不同金属层的导电通道。该导电通道可以是填充有导电材料的通孔,也可以是金属柱,也可以是其他导电结构。It should be noted that when the above-mentioned multi-layer metal layers are formed, not only the metal layers arranged in parallel with the substrate, but also the conductive paths for connecting different parallel metal layers are included. The conductive channel can be a through hole filled with conductive material, a metal column, or other conductive structures.
按照上述的形成第一布线层的方法执行时,直至形成至如图9c所示的第一金属层61时,再在第一金属层61上形成第一覆盖层111,当在第一金属层61上形成第一覆盖层111后,停止在存储区上形成第一介电层71。When the above-mentioned method for forming the first wiring layer is performed, until the first metal layer 61 as shown in FIG. 9c is formed, the first capping layer 111 is formed on the first metal layer 61, and when the first metal layer 61 is formed on the first metal layer 61 After the first capping layer 111 is formed on the storage region 61, the formation of the first dielectric layer 71 on the storage region is stopped.
如图9c所示,第一覆盖层111的远离衬底1的表面至第二晶体管122的远离衬底1的表面之间的距离H1为第一预设距离,这里的第一预设距离可以是所要形成的第一段通孔的深度。As shown in FIG. 9c , the distance H1 from the surface of the first cover layer 111 away from the substrate 1 to the surface of the second transistor 122 away from the substrate 1 is a first preset distance, and the first preset distance here can be is the depth of the first through hole to be formed.
上述的第一覆盖层111的材料可以与第三介电层73的材料相同,比如,都可以是氧化硅或者都可以是氮化硅。当然,第一覆盖层111的材料也可以和第三介电层73的材料不同。The above-mentioned material of the first capping layer 111 may be the same as that of the third dielectric layer 73 , for example, both may be silicon oxide or both may be silicon nitride. Of course, the material of the first cover layer 111 may also be different from the material of the third dielectric layer 73 .
继续结合图9c,第一布线层141和多个第二晶体管122构成的电路结构仅是逻辑区的电路结构的一部分,后续再形成其余的电路结构。Continuing with reference to FIG. 9c, the circuit structure formed by the first wiring layer 141 and the plurality of second transistors 122 is only a part of the circuit structure of the logic region, and the remaining circuit structures are formed later.
图9d为图9c所示结构基础上完成第四步骤后的剖面图,在该第四步骤中,在第一介电层71内形成贯通至第一晶体管的第一段通孔81。具体的是,当源极1-3与BL连接时,第一段通孔81贯通至漏极1-1,当漏极1-1与BL连接时,第一段通孔81贯通至源极1-3。FIG. 9d is a cross-sectional view of the structure shown in FIG. 9c after the fourth step is completed. In the fourth step, a first through hole 81 penetrating to the first transistor is formed in the first dielectric layer 71 . Specifically, when the source electrode 1-3 is connected to the BL, the through hole 81 of the first segment penetrates to the drain electrode 1-1, and when the drain electrode 1-1 is connected to the BL, the through hole 81 of the first segment penetrates to the source electrode 1-3.
在形成第一段通孔81时,可以采用低深宽比的干法刻蚀工艺形成,且在一些可选择的实施方式中,第一段通孔81的形貌为圆锥形结构,也就是如图9d所示,沿靠近衬底1的方向(如图9d的P1方向),第一段通孔81的径向尺寸逐渐减小。When forming the through holes 81 in the first section, a dry etching process with a low aspect ratio can be used. As shown in FIG. 9d , along the direction close to the substrate 1 (the direction P1 in FIG. 9d ), the radial dimension of the through holes 81 of the first section gradually decreases.
因为在形成第一覆盖层111后,就停止第一介电层的堆叠,这样的话,结合图9c,形成的第一段通孔81的深度h1等于第一预设高度H1。Because the stacking of the first dielectric layer is stopped after the first capping layer 111 is formed, in this case, referring to FIG. 9c , the depth h1 of the first through hole 81 formed is equal to the first preset height H1.
另外,在第一介电层71内刻蚀第一段通孔81时,第一金属层61上的第一覆盖层111可以对第一金属层61起到保护作用,防止第一金属层61被其他杂质污染,或者防止第一金属层61被损坏。In addition, when the first through hole 81 is etched in the first dielectric layer 71 , the first cover layer 111 on the first metal layer 61 can protect the first metal layer 61 and prevent the first metal layer 61 Contaminated with other impurities, or prevent the first metal layer 61 from being damaged.
在一些可选择的实施方式中,第一覆盖层61的厚度可以小于相邻两层金属层之间的第三介电层73的厚度,也可以与相邻两层金属层之间的第三介电层73的厚度相等。In some optional embodiments, the thickness of the first cover layer 61 may be smaller than the thickness of the third dielectric layer 73 between two adjacent metal layers, or may be the same as the thickness of the third dielectric layer 73 between two adjacent metal layers. The thicknesses of the dielectric layers 73 are equal.
图9e为图9d所示结构基础上完成第五步骤后的剖面图,在该第五步骤中,在第一段通孔81内的至少靠近第一段通孔的孔口的位置处填充材料,以使填充的材料形成将第一段通孔的孔口堵住的临时填充层9。这里的第一段通孔的孔口指的是第一段通孔的远离衬底1的孔口。图9e示例性的仅在第一段通孔81的孔口处形成临时填充层 9,并未将整个第一段通孔81填满。FIG. 9e is a cross-sectional view after the fifth step is completed on the basis of the structure shown in FIG. 9d. In the fifth step, a material is filled in the first-stage through-hole 81 at least at a position close to the orifice of the first-stage through-hole , so that the filled material forms a temporary filling layer 9 that blocks the openings of the through holes of the first section. The orifice of the through hole of the first section here refers to the orifice of the through hole of the first section that is far away from the substrate 1 . In Fig. 9e, the temporary filling layer 9 is only formed at the opening of the first section of through holes 81, and the entire first section of through holes 81 is not filled.
在一些可选择的实施方式中,可以采用物理气相沉积法(Physical Vapor Deposition,PVD),或者化学气相沉积法(Chemical Vapor Deposition,CVD)形成临时填充层9,这样的话,也会在逻辑区的远离衬底1的表面,以及存储区的远离衬底1的表面上均形成临时填充层9。In some alternative embodiments, physical vapor deposition (Physical Vapor Deposition, PVD) or chemical vapor deposition (Chemical Vapor Deposition, CVD) can be used to form the temporary filling layer 9, in this case, it will also be in the logic area. A temporary filling layer 9 is formed on the surface away from the substrate 1 and the surface of the storage region away from the substrate 1 .
图9f为图9e所示结构基础上完成第六步骤后的剖面图,在该第六步骤中,去除存储区的远离衬底1的表面上的临时填充层和逻辑区的远离衬底1的表面上的临时填充层。9f is a cross-sectional view after the sixth step is completed on the basis of the structure shown in FIG. 9e. In the sixth step, the temporary filling layer on the surface of the storage area away from the substrate 1 and the surface of the logic area away from the substrate 1 are removed. Temporary filling layer on the surface.
在去除上述的临时填充层时,可以采用刻蚀或者化学机械研磨工艺去除。When removing the above-mentioned temporary filling layer, an etching or chemical mechanical polishing process can be used to remove it.
图9g为图9f所示结构基础上完成第七步骤后的剖面图,在该第七步骤中,在第一介电层71上堆叠第二介电层72,在第一覆盖层111上堆叠第二布线层142。9g is a cross-sectional view of the structure shown in FIG. 9f after the seventh step is completed. In the seventh step, the second dielectric layer 72 is stacked on the first dielectric layer 71 and the first cover layer 111 is stacked The second wiring layer 142 .
上述的直接在第一覆盖层111上堆叠第二布线层142指的是第一覆盖层111的材料和第三介电层73的材料相同的情况下。若第一覆盖层111的材料和第三介电层73的材料不相同,则在堆叠第二布线层142之前,需要将第一覆盖层111去除。The above-mentioned stacking of the second wiring layer 142 directly on the first capping layer 111 refers to the case where the material of the first capping layer 111 and the material of the third dielectric layer 73 are the same. If the material of the first capping layer 111 and the material of the third dielectric layer 73 are different, the first capping layer 111 needs to be removed before stacking the second wiring layer 142 .
上述的存储区上的第二介电层72,和逻辑区上的第二布线层142可以同时形成。也可以是先形成第二介电层72,再形成第二布线层142。也可以是先形成第二布线层142,再形成第二介电层72。The above-mentioned second dielectric layer 72 on the storage region and the second wiring layer 142 on the logic region can be formed simultaneously. Alternatively, the second dielectric layer 72 may be formed first, and then the second wiring layer 142 may be formed. Alternatively, the second wiring layer 142 may be formed first, and then the second dielectric layer 72 may be formed.
这里的第二布线层142包括第四介电层74,以及形成在第四介电层74内的多层金属层。The second wiring layer 142 here includes the fourth dielectric layer 74 , and a multi-layer metal layer formed in the fourth dielectric layer 74 .
第二介电层72和第二布线层142同时形成的工艺,和上述的第一介电层71和第一布线层141同时形成的工艺可以相同,具体的同时形成的工艺步骤在此不再赘述。The process of forming the second dielectric layer 72 and the second wiring layer 142 at the same time may be the same as the process of forming the first dielectric layer 71 and the first wiring layer 141 at the same time, and the specific process steps of the simultaneous formation will not be repeated here. Repeat.
另外,位线3和字线4、第一介电层71、第二介电层72、第一布线层141和第二布线层142的形成工艺可以相同,这样可以简化整个电子器件的制造工艺。In addition, the formation process of the bit line 3 and the word line 4, the first dielectric layer 71, the second dielectric layer 72, the first wiring layer 141 and the second wiring layer 142 can be the same, which can simplify the manufacturing process of the entire electronic device .
第二布线层142中的第四介电层74的材料可以和第二介电层72的材料、第一介电层71的材料和第三介电层73的材料相同,也可以不相同。The material of the fourth dielectric layer 74 in the second wiring layer 142 may be the same as or different from the material of the second dielectric layer 72 , the material of the first dielectric layer 71 and the material of the third dielectric layer 73 .
继续结合图9g,在形成第二布线层142时,直至形成至如图9g所示的第二金属层62时,再在第二金属层62上形成第二覆盖层112,当在第二金属层62上形成第二覆盖层112后,可以停止在存储区形成第二介电层72。Continuing with reference to FIG. 9g, when the second wiring layer 142 is formed, until the second metal layer 62 as shown in FIG. 9g is formed, the second capping layer 112 is formed on the second metal layer 62. After the second capping layer 112 is formed on the layer 62, the formation of the second dielectric layer 72 in the storage region may be stopped.
如图9c,第二覆盖层112的远离衬底1的表面至第一覆盖层111的远离衬底1的表面之间的距离H2为第二预设距离,这里的第二预设距离可以是所要形成的第二段通孔的深度。As shown in FIG. 9c , the distance H2 from the surface of the second cover layer 112 away from the substrate 1 to the surface of the first cover layer 111 away from the substrate 1 is a second preset distance, and the second preset distance here may be The depth of the second through hole to be formed.
图9h为图9g所示结构基础上完成第八步骤后的剖面图,在该第八步骤中,在第二介电层72内形成与第一段通孔81相连通的第二段通孔82。在形成第二段通孔82时,可以和第一段通孔81一样,采用低深宽比的干法刻蚀工艺形成,且在一些可选择的实施方式中,第二段通孔82的形貌也为圆锥形结构,也就是如图9h所示,沿靠近衬底1的方向(图9h所示的P1方向),第二段通孔82的径向尺寸逐渐减小。9h is a cross-sectional view after the eighth step is completed on the basis of the structure shown in FIG. 9g. In the eighth step, a second section of through holes connected to the first section of through holes 81 are formed in the second dielectric layer 72 82. When forming the second-stage through holes 82, the same as the first-stage through-holes 81, a dry etching process with a low aspect ratio can be used to form, and in some optional embodiments, the second-stage through-holes 82 The topography is also a conical structure, that is, as shown in FIG. 9h , along the direction close to the substrate 1 (the P1 direction shown in FIG. 9h ), the radial dimension of the second through hole 82 gradually decreases.
因为在形成第二覆盖层112后,就停止第二介电层的堆叠,这样的话,结合图9h,形成的第二段通孔82的深度h2等于第二预设高度H2。Because the stacking of the second dielectric layer is stopped after the second capping layer 112 is formed, in this case, referring to FIG. 9h , the depth h2 of the second via hole 82 is equal to the second predetermined height H2 .
基于上述的两次开孔工艺,相比现有的一次开孔工艺,如图9h所示,在第一段通 孔81与第二段通孔82的交界处形成台阶15。Based on the above-mentioned two-stage opening process, compared with the existing one-stage opening process, as shown in FIG.
在形成第二段通孔82时,第二段通孔82的深度可以和第一段通孔81的深度相等,比如,均等于最终的通孔的二分之一或者三分之一。这样的话,在刻蚀第一段通孔81和第二段通孔82时,可以采用相同的工艺条件,比如,刻蚀气体的流量、温度、刻蚀腔体内压力、偏置功率等相同。进而,会简化整个开孔工艺。When forming the second-stage through holes 82, the depth of the second-stage through-holes 82 may be equal to the depth of the first-stage through-holes 81, for example, equal to one-half or one-third of the final through-holes. In this way, the same process conditions can be used when etching the first-stage through holes 81 and the second-stage through holes 82 , for example, the flow rate, temperature, pressure in the etching chamber, bias power, etc. of the etching gas are the same. Further, the entire opening process is simplified.
若上述的第一段通孔81和第二段通孔82形成了最终的通孔,就可以继续执行图9i所示步骤,在图9i所示的第九步骤中,去除第一段通孔81内的临时填充层。If the above-mentioned first-stage through holes 81 and second-stage through-holes 82 form the final through-holes, the step shown in FIG. 9i can be continued. In the ninth step shown in FIG. 9i, the first-stage through-holes are removed. Temporary fill layer within 81.
图9j为图9i所示结构基础上完成第十步骤后的剖面图,在该第十步骤中,在相贯通的第一段通孔81和第二段通孔82内形成第一电极层101、电容介质层102和第二电极层103。9j is a cross-sectional view after the tenth step is completed on the basis of the structure shown in FIG. 9i. In the tenth step, the first electrode layer 101 is formed in the first section of through holes 81 and the second section of through holes 82 that communicate with each other. , the capacitor dielectric layer 102 and the second electrode layer 103 .
比如,在第一段通孔81的侧面和底面分别形成第一电极层101、以及在第二段通孔82的侧面形成第一电极层101;再在第一段通孔81的底面的第一电极层101上、第一段通孔81的侧面的第一电极层101上,以及第二段通孔82的侧面的第一电极层101上均形成电容介质层102;再在第一段通孔81的底面的电容介质层102上、第一段通孔81的侧面的电容介质层102上,以及第二段通孔82的侧面的电容介质层102上均形成第二电极层103。这样一来,填充有第一电极层101、电容介质层102和第二电极层103的通孔形成了电容器,第一段通孔81底面的第一电极层与第一晶体管电连接。For example, the first electrode layer 101 is respectively formed on the side surface and the bottom surface of the through hole 81 of the first stage, and the first electrode layer 101 is formed on the side surface of the through hole 82 of the second stage; A capacitor dielectric layer 102 is formed on an electrode layer 101, on the first electrode layer 101 on the side of the through hole 81 of the first section, and on the first electrode layer 101 on the side of the through hole 82 in the second section; A second electrode layer 103 is formed on the capacitive dielectric layer 102 on the bottom surface of the through hole 81 , on the capacitive dielectric layer 102 on the side surface of the first through hole 81 , and on the capacitive dielectric layer 102 on the side surface of the second through hole 82 . In this way, the through hole filled with the first electrode layer 101 , the capacitor dielectric layer 102 and the second electrode layer 103 forms a capacitor, and the first electrode layer on the bottom surface of the first segment of through hole 81 is electrically connected to the first transistor.
需要说明的是:在第一段通孔81的侧面的第一电极层101上形成电容介质层102指的是:电容介质层沿第一段通孔81的径向(如图9j的Q方向)形成在第一电极层上。It should be noted that: forming the capacitor dielectric layer 102 on the first electrode layer 101 on the side surface of the through hole 81 of the first section means that the capacitor dielectric layer is along the radial direction of the through hole 81 of the first section (as shown in the Q direction of FIG. 9j ). ) is formed on the first electrode layer.
在第一段通孔81的侧面的电容介质层102上形成第二电极层103指的是:第二电极层沿第一段通孔81的径向(如图9j的Q方向)形成在电容介质层上。Forming the second electrode layer 103 on the capacitor dielectric layer 102 on the side surface of the through hole 81 of the first stage means that the second electrode layer is formed on the capacitor along the radial direction of the through hole 81 of the first stage (the Q direction in FIG. 9j ). on the dielectric layer.
在第二段通孔82的侧面的第一电极层101上形成电容介质层102指的是:电容介质层沿第二段通孔82的径向(如图9j的Q方向)形成在第一电极层上。Forming the capacitor dielectric layer 102 on the first electrode layer 101 on the side surface of the second through hole 82 means that the capacitor dielectric layer is formed on the first electrode layer 101 along the radial direction of the second through hole 82 (the Q direction in FIG. 9j ). on the electrode layer.
在第二段通孔82的侧面的电容介质层102上形成第二电极层103指的是:第二电极层沿第二段通孔82的径向(如图9j的Q方向)形成在电容介质层上。Forming the second electrode layer 103 on the capacitor dielectric layer 102 on the side of the second through hole 82 means that the second electrode layer is formed on the capacitor along the radial direction of the second through hole 82 (the Q direction in FIG. 9j ). on the dielectric layer.
这里的第一电极层101和第二电极层103均为金属层,电容介质层102可以采用高介电常数(high dielectric constant K,HK)材料制得,以延长存储数据保持时间。Here, the first electrode layer 101 and the second electrode layer 103 are both metal layers, and the capacitor dielectric layer 102 can be made of high dielectric constant K (HK) material to prolong the retention time of stored data.
在形成第一电极层101、电容介质层102和第二电极层103时,可以采用PVD或者CVD沉积形成,并且,在形成第一电极层101后,可以将第二介电层72的远离衬底1的表面,以及第二覆盖层112的远离衬底1的表面上的第一电极层101去除后,再依次形成电容介质层102和第二电极层103,所以,如图9j所示,在逻辑区和存储区的远离衬底的表面均沉积有电容介质层102和第二电极层103。When forming the first electrode layer 101 , the capacitor dielectric layer 102 and the second electrode layer 103 , PVD or CVD deposition can be used, and after the first electrode layer 101 is formed, the second dielectric layer 72 can be separated from the lining. After the surface of the bottom 1 and the first electrode layer 101 on the surface of the second cover layer 112 away from the substrate 1 are removed, the capacitor dielectric layer 102 and the second electrode layer 103 are formed in sequence. Therefore, as shown in FIG. 9j, A capacitor dielectric layer 102 and a second electrode layer 103 are deposited on the surfaces of the logic region and the storage region away from the substrate.
图9k为图9j所示结构基础上完成第十一步骤后的剖面图,在该第十一步骤中,去除逻辑区的远离衬底的表面的电容介质层102和第二电极层103。9k is a cross-sectional view of the structure shown in FIG. 9j after completing the eleventh step. In the eleventh step, the capacitor dielectric layer 102 and the second electrode layer 103 on the surface of the logic region away from the substrate are removed.
图9l为图9k所示结构基础上完成第十二步骤后的剖面图,在该第十二步骤中,在存储区的第二电极层103上和逻辑区的第二覆盖层112上形成第三布线层143,这样的话,作为该电容器的第二电极层103可以通过第三布线层与逻辑区电连接,通过 位于逻辑区的电源给第二电极层103供电。91 is a cross-sectional view after the twelfth step is completed on the basis of the structure shown in FIG. 9k. In the twelfth step, the second electrode layer 103 of the storage area and the second cover layer 112 of the logic area are formed Three wiring layers 143, in this case, the second electrode layer 103 serving as the capacitor can be electrically connected to the logic region through the third wiring layer, and the second electrode layer 103 can be powered by a power supply located in the logic region.
图10给出的是当通孔除包括第一段通孔81和第二段通孔81之外,还包括第三段通孔83时,该存储器的形成方法还包括:在完成图9h之后,在第二段通孔82内的至少靠近第二段通孔的孔口的位置处填充材料,以使填充的材料形成将第一段通孔82的孔口堵住的临时填充层9,再在存储区的第二介电层72上继续形成第五介电层75,以及在第二覆盖层112(这里的第二覆盖层112与第四介电层的材料相同)上形成第四布线层144,直至形成第三金属层63,再在第三金属层上形成第三覆盖层113,第三覆盖层113的远离衬底1的表面至第二覆盖层112的远离衬底1的表面之间的距离为第三预设距离H3,第三预设距离H3等于所要形成的第三段通孔的深度。What is shown in FIG. 10 is that when the through holes include a third section of through holes 83 in addition to the first section of through holes 81 and the second section of through holes 81 , the method for forming the memory also includes: after completing FIG. 9h , filling material at least at a position close to the orifice of the second-stage through-hole 82 in the second-stage through-hole 82, so that the filled material forms a temporary filling layer 9 that blocks the orifice of the first-stage through-hole 82, The fifth dielectric layer 75 is further formed on the second dielectric layer 72 in the storage area, and the fourth dielectric layer 75 is formed on the second capping layer 112 (the material of the second capping layer 112 here is the same as that of the fourth dielectric layer) The wiring layer 144 is formed until the third metal layer 63 is formed, and then the third cover layer 113 is formed on the third metal layer. The distance between the surfaces is a third preset distance H3, and the third preset distance H3 is equal to the depth of the third section of through holes to be formed.
继续结合图10,再在第三介电层73内形成第三段通孔83,并使第三段通孔83与第二段通孔82相连通。这样的话,形成的第三段通孔83的深度h3等于第三预设距离H3。Continuing with reference to FIG. 10 , a third through hole 83 is formed in the third dielectric layer 73 , and the third through hole 83 is communicated with the second through hole 82 . In this case, the depth h3 of the formed third-stage through holes 83 is equal to the third preset distance H3.
若不在继续形成第四段通孔,就将第一段通孔81、第二段通孔82内的临时填充层去除,再在相连通的第一段通孔、第二段通孔和第三段通孔内形成电容器。If the fourth through hole is not to be formed, the temporary filling layer in the first through hole 81 and the second through hole 82 is removed, and then the first through hole, the second through hole and the second through hole in the connected first through hole, the second through hole and the second through hole are removed. A capacitor is formed in the three-segment through hole.
继续结合图10,在第二段通孔82和第三段通孔83的交界面处也形成有台阶15。Continuing with reference to FIG. 10 , a step 15 is also formed at the interface between the second through hole 82 and the third through hole 83 .
当通过两次开孔工艺形成具有高深宽比的通孔时,图9l所示的结构为包括第一段通孔和第二段通孔的一种存储器,该存储器相比现有的一次开孔的存储器,明显的区别是在第一段通孔81和第二段通孔82的交界面处具有台阶。When a via hole with a high aspect ratio is formed by a double opening process, the structure shown in FIG. 91 is a memory including a first stage of through hole and a second stage of through hole, and the memory is compared with the existing one-time opening. The memory of the holes, the obvious difference is that there is a step at the interface of the first section of through holes 81 and the second section of through holes 82 .
若采用上述存储器的形成方法制得具有N(N为大于或等于2的正整数)段的通孔时,每相邻两段通孔的交界面处均具有台阶。If a through hole having N (N is a positive integer greater than or equal to 2) segments is obtained by using the method for forming a memory, there are steps at the interface between every two adjacent segments of through holes.
还有,如图9l所示,沿堆叠方向,第一段通孔81的深度或者第二段通孔82的深度等于通孔的深度的二分之一。Also, as shown in FIG. 91 , along the stacking direction, the depth of the through holes 81 of the first stage or the depth of the through holes 82 of the second stage is equal to one-half the depth of the through holes.
继续如图9l所示,由于在形成至第一金属层后,开设第一段通孔,所以,第一段通孔和第二段通孔的交界面位于相邻两层金属层之间。Continuing as shown in FIG. 91 , after the first metal layer is formed, the first through hole is opened, so the interface between the first through hole and the second through hole is located between two adjacent metal layers.
在一些可选择的实施方式中,当刻蚀第一段通孔81和第二段通孔82的工艺条件相同时,第一段通孔81的远离衬底1的开口的横断面的面积可以等于第二段通孔82的远离衬底的开口的横断面的面积,也可以接近第二段通孔82的远离衬底的开口的横断面的面积。In some alternative embodiments, when the process conditions for etching the first-stage through-holes 81 and the second-stage through-holes 82 are the same, the area of the cross-section of the first-stage through-holes 81 away from the opening of the substrate 1 may be It is equal to the area of the cross section of the opening of the second section of through holes 82 away from the substrate, and may also be close to the area of the cross section of the opening of the second section of through holes 82 away from the substrate.
图11所示的是一种存储器的结构图,该图中示出了多个电容器2。在形成该结构的存储器时,多个通孔可以同时形成,在形成的多个通孔内分别形成第一电极层、电容介质层和第二电极层时,也可以是同时形成第一电极层,同时形成电容介质层和同时形成第二电极层,进而,如图11所示,多个通孔的第二电极层103可以连接在一起,作为公共第二电极层,这样的话,电源通过公共第二电极层向多个电容器供电。FIG. 11 is a structural diagram of a memory, which shows a plurality of capacitors 2 . When forming the memory of this structure, a plurality of through holes can be formed at the same time, and when the first electrode layer, the capacitor dielectric layer and the second electrode layer are respectively formed in the formed plurality of through holes, the first electrode layer can also be formed at the same time , forming a capacitor dielectric layer and a second electrode layer at the same time, and then, as shown in FIG. 11 , the second electrode layers 103 of a plurality of through holes can be connected together as a common second electrode layer, in this case, the power supply through the common The second electrode layer supplies power to the plurality of capacitors.
在一些可选择的实施方式中,当采用PVD或者CVD沉积方式形成多个电容器2时,如图11所示,在多个相连通的第一段通孔81和第二段通孔82内同时形成第一电极层101之后,在形成电容介质层102之前,需要对第二介电层72的远离衬底1的表面上沉积的第一电极层101去除掉,以防止形成的多个电容器2相串联。In some optional embodiments, when PVD or CVD deposition method is used to form a plurality of capacitors 2, as shown in FIG. After the first electrode layer 101 is formed, before the capacitor dielectric layer 102 is formed, the first electrode layer 101 deposited on the surface of the second dielectric layer 72 away from the substrate 1 needs to be removed to prevent the formation of multiple capacitors 2 connected in series.
但是,在PVD或者CVD沉积方式形成电容介质层102和第二电极层103后,不需要将形成在第二介电层72上的电容介质层102和第二电极层103去除,这样的话, 就会形成如图11所示的在第二介电层71上形成有电容介质层102和第二电极层103的结构,这里的多个电容器共用第二电极层103。However, after the capacitor dielectric layer 102 and the second electrode layer 103 are formed by PVD or CVD deposition, it is not necessary to remove the capacitor dielectric layer 102 and the second electrode layer 103 formed on the second dielectric layer 72. A structure in which a capacitor dielectric layer 102 and a second electrode layer 103 are formed on the second dielectric layer 71 as shown in FIG. 11 will be formed, and the second electrode layer 103 is shared by a plurality of capacitors here.
需要说明的是:本申请涉及的“等于”或者“相等”之类的描述,比如,第一段通孔的深度等于第二段通孔的深度,再比如,第一介电层的厚度等于第二介电层的厚度等,这里的“等于”可以是完全等于,也可以是接近等于,“相等”可以是完全相等,也可以是接近相等。It should be noted that: in the description of “equal” or “equal” involved in this application, for example, the depth of the through hole in the first section is equal to the depth of the through hole in the second section, and for example, the thickness of the first dielectric layer is equal to The thickness of the second dielectric layer, etc., "equal" here can be completely equal or nearly equal, and "equal" can be completely equal or nearly equal.
在本说明书的描述中,具体特征、结构、材料或者特点可以在任何的一个或多个实施例或示例中以合适的方式结合。In the description of this specification, the particular features, structures, materials or characteristics may be combined in any suitable manner in any one or more embodiments or examples.
以上所述,仅为本申请的具体实施方式,但本申请的保护范围并不局限于此,任何熟悉本技术领域的技术人员在本申请揭露的技术范围内,可轻易想到变化或替换,都应涵盖在本申请的保护范围之内。因此,本申请的保护范围应以所述权利要求的保护范围为准。The above are only specific embodiments of the present application, but the protection scope of the present application is not limited to this. should be covered within the scope of protection of this application. Therefore, the protection scope of the present application should be subject to the protection scope of the claims.

Claims (25)

  1. 一种电子器件,其特征在于,包括:An electronic device, characterized in that, comprising:
    衬底;substrate;
    第一晶体管,设置在所述衬底上;a first transistor, disposed on the substrate;
    第一介电层,堆叠在具有所述第一晶体管的所述衬底上,所述第一介电层内具有贯通至所述第一晶体管的第一段通孔;a first dielectric layer, stacked on the substrate with the first transistor, the first dielectric layer having a first segment of through hole penetrating through the first transistor;
    第二介电层,堆叠在所述第一介电层上,所述第二介电层内具有与所述第一段通孔相连通的第二段通孔,且在所述第一段通孔与所述第二段通孔的交界处具有台阶;a second dielectric layer stacked on the first dielectric layer, the second dielectric layer has a second segment of through holes connected to the first segment of through holes, and the first segment There is a step at the junction of the through hole and the second section of through hole;
    电容器,形成在相连通的所述第一段通孔和所述第二段通孔内,且所述电容器与所述第一晶体管电连接。A capacitor is formed in the connected first through hole and the second through hole, and the capacitor is electrically connected with the first transistor.
  2. 根据权利要求1所述的电子器件,其特征在于,所述第一段通孔和所述第二段通孔均为沿靠近所述衬底方向孔径尺寸逐渐减小的圆锥形结构,且所述第二段通孔的靠近所述第一段通孔的一端的孔径,小于所述第一段通孔的靠近所述第二段通孔的一端的孔径,以在所述第一段通孔与所述第二段通孔的交界处形成所述台阶。The electronic device according to claim 1, wherein the first section of through holes and the second section of through holes are both conical structures with a gradually decreasing aperture size along a direction close to the substrate, and the The hole diameter of the end of the second section of through holes close to the first section of through holes is smaller than the hole diameter of the first section of through holes close to the second section of through holes, so as to pass through the first section of through holes. The step is formed at the junction of the hole and the through hole of the second section.
  3. 根据权利要求1或2所述的电子器件,其特征在于,沿堆叠方向,所述第一段通孔的深度等于所述第二段通孔的深度。The electronic device according to claim 1 or 2, wherein, along the stacking direction, the depth of the through holes of the first section is equal to the depth of the through holes of the second section.
  4. 根据权利要求1~3中任一项所述的电子器件,其特征在于,所述电容器包括第一电极层、电容介质层和第二电极层,所述第一电极层形成在所述第一段通孔的侧面和底面上,以及形成在所述第二段通孔的侧面上,所述电容介质层形成在所述第一电极层上,所述第二电极层形成在所述电容介质层上,且所述第一电极层与所述第一晶体管电连接。The electronic device according to any one of claims 1 to 3, wherein the capacitor comprises a first electrode layer, a capacitor dielectric layer and a second electrode layer, and the first electrode layer is formed on the first electrode layer. The side and bottom surfaces of the segment via holes, and the side surfaces of the second segment via holes, the capacitive dielectric layer is formed on the first electrode layer, and the second electrode layer is formed on the capacitive dielectric layer, and the first electrode layer is electrically connected to the first transistor.
  5. 根据权利要求4所述的电子器件,其特征在于,所述电子器件还包括:The electronic device according to claim 4, wherein the electronic device further comprises:
    第三介电层,堆叠在所述第二介电层上,且所述第三介电层内具有与所述第二段通孔相连通的第三段通孔,在所述第二段通孔与所述第三段通孔的交界处具有台阶;A third dielectric layer is stacked on the second dielectric layer, and the third dielectric layer has a third section of through holes in communication with the second section of through holes. There is a step at the junction of the through hole and the third section of through hole;
    所述电容器还形成在所述第三段通孔内;the capacitor is also formed in the third segment of the through hole;
    所述第三段通孔的侧面形成有所述第一电极层,所述第三段通孔内的所述第一电极层上形成有所述电容介质层,所述第三段通孔内的所述电容介质层上形成有所述第二电极层,且所述第三段通孔内的所述第一电极层、所述电容介质层和所述第二电极层分别与所述第二段通孔内的相对应的所述第一电极层、所述电容介质层和所述第二电极层相连接。The first electrode layer is formed on the side surface of the through hole of the third section, and the capacitor dielectric layer is formed on the first electrode layer in the through hole of the third section. The second electrode layer is formed on the capacitor dielectric layer, and the first electrode layer, the capacitor dielectric layer and the second electrode layer in the third through hole are respectively connected with the first electrode layer. The corresponding first electrode layer, the capacitor dielectric layer and the second electrode layer in the two-stage through hole are connected.
  6. 根据权利要求1~5中任一项所述的电子器件,其特征在于,所述电子器件为存储器,所述衬底设置有存储区,所述第一晶体管设置在所述存储区。The electronic device according to any one of claims 1 to 5, wherein the electronic device is a memory, the substrate is provided with a storage area, and the first transistor is provided in the storage area.
  7. 根据权利要求6所述的电子器件,其特征在于,所述衬底还设置有逻辑区,所述存储区和所述逻辑区之间被隔离沟槽隔开;The electronic device according to claim 6, wherein the substrate is further provided with a logic area, and the storage area and the logic area are separated by an isolation trench;
    所述电子器件还包括:The electronic device also includes:
    多个第二晶体管,设置在所述逻辑区;a plurality of second transistors, arranged in the logic region;
    布线层,堆叠在具有所述多个第二晶体管的所述逻辑区上。a wiring layer stacked on the logic region having the plurality of second transistors.
  8. 根据权利要求7所述的电子器件,其特征在于,所述布线层包括相堆叠的金属层,以及用于隔离相邻两层所述金属层的介电层,所述第一段通孔和所述第二段通孔 的交界面位于相邻两层所述金属层之间。8. The electronic device according to claim 7, wherein the wiring layer comprises stacked metal layers, and a dielectric layer for isolating two adjacent metal layers, the first through-hole and The interface of the second through hole is located between two adjacent metal layers.
  9. 根据权利要求7或8所述的电子器件,其特征在于,所述第一晶体管和所述第二晶体管采用相同的工艺制得。The electronic device according to claim 7 or 8, wherein the first transistor and the second transistor are manufactured by the same process.
  10. 根据权利要求7~9中任一项所述的电子器件,其特征在于,所述电子器件还包括:形成在所述存储区上的字线和位线,所述字线和所述位线分别与所述第一晶体管连接,所述字线、所述位线、所述第一介电层和所述第二介电层,以及所述布线层采用相同的工艺制得。The electronic device according to any one of claims 7 to 9, wherein the electronic device further comprises: word lines and bit lines formed on the storage region, the word lines and the bit lines Connected to the first transistor respectively, the word line, the bit line, the first dielectric layer, the second dielectric layer, and the wiring layer are fabricated by the same process.
  11. 根据权利要求1~10中任一项所述的电子器件,其特征在于,相连通的所述第一段通孔和所述第二段通孔形成用于容纳所述电容器的通孔;或者,相连通的所述第一段通孔和所述第二段通孔形成用于容纳所述电容器的通孔的部分,其中,用于容纳所述电容器的所述通孔的深宽比大于或者等于10∶1。The electronic device according to any one of claims 1 to 10, wherein the first through-holes and the second through-holes are connected to form through-holes for accommodating the capacitors; or , the connected first section of through holes and the second section of through holes form a part of a through hole for accommodating the capacitor, wherein the aspect ratio of the through hole for accommodating the capacitor is greater than Or equal to 10:1.
  12. 一种电子器件的形成方法,其特征在于,包括:A method for forming an electronic device, comprising:
    在衬底上形成第一晶体管;forming a first transistor on the substrate;
    在具有所述第一晶体管的所述衬底上堆叠第一介电层;stacking a first dielectric layer on the substrate with the first transistor;
    在所述第一介电层内开设贯通至所述第一晶体管的第一段通孔;opening a first segment of through hole through the first transistor in the first dielectric layer;
    在所述第一段通孔内的至少靠近所述第一段通孔的孔口的位置处填充材料,以使填充的所述材料形成将所述第一段通孔的孔口堵住的临时填充层;A material is filled at a position in the first section of through holes at least close to the orifice of the first section of through hole, so that the filled material forms a hole that blocks the orifice of the first section of through hole. Temporary filling layer;
    在所述第一介电层上堆叠第二介电层;stacking a second dielectric layer on the first dielectric layer;
    在所述第二介电层内开设与所述第一段通孔相连通的第二段通孔;opening a second section of through holes connected to the first section of through holes in the second dielectric layer;
    去除所述临时填充层;removing the temporary filling layer;
    在相连通的所述第一段通孔和所述第二段通孔内形成和所述第一晶体管电连接的电容器。A capacitor electrically connected to the first transistor is formed in the first through hole and the second through hole that are connected to each other.
  13. 根据权利要求12所述的电子器件的形成方法,其特征在于,在所述第一介电层内开设贯通至所述第一晶体管的所述第一段通孔,包括:The method for forming an electronic device according to claim 12, wherein the opening of the first segment of through holes in the first dielectric layer that penetrates to the first transistor comprises:
    采用干法刻蚀由所述第一介电层的远离所述衬底的表面朝所述第一晶体管开孔,形成圆锥形结构的所述第一段通孔,所述第一段通孔沿靠近所述衬底方向孔径尺寸逐渐减小;Dry etching is used to open holes from the surface of the first dielectric layer away from the substrate toward the first transistor to form the first section of through holes in the conical structure, and the first section of through holes The aperture size gradually decreases along the direction close to the substrate;
    在所述第二介电层内开设与所述第一段通孔相连通的所述第二段通孔,包括:Opening the second section of through holes in the second dielectric layer and communicating with the first section of through holes includes:
    采用干法刻蚀由所述第二介电层的远离所述第一介电层的表面朝所述第一段通孔开孔,形成圆锥形结构的所述第二段通孔,所述第二段通孔沿靠近所述衬底方向孔径尺寸逐渐减小;Dry etching is used to open holes from the surface of the second dielectric layer away from the first dielectric layer toward the first section of through holes to form the second section of through holes in a conical structure. The aperture size of the second section of through holes gradually decreases along the direction close to the substrate;
    其中,所述第二段通孔的靠近所述第一段通孔的一端的孔径,小于所述第一段通孔的靠近所述第二段通孔的一端的孔径,以在所述第一段通孔与所述第二段通孔的交界处形成台阶。Wherein, the hole diameter of the end of the second section of through holes close to the first section of through holes is smaller than the hole diameter of the first section of through holes close to the second section of through holes, so that in the first section of through holes A step is formed at the junction of one section of through holes and the second section of through holes.
  14. 根据权利要求12或13所述的电子器件的形成方法,其特征在于,所述第一介电层的厚度等于所述第二介电层的厚度。The method for forming an electronic device according to claim 12 or 13, wherein the thickness of the first dielectric layer is equal to the thickness of the second dielectric layer.
  15. 根据权利要求12-14中任一项所述的电子器件的形成方法,其特征在于,所述衬底设置有存储区,在形成所述第一晶体管时,包括:在所述存储区上形成所述第一晶体管;The method for forming an electronic device according to any one of claims 12-14, wherein the substrate is provided with a storage area, and when the first transistor is formed, the method includes: forming on the storage area the first transistor;
    所述衬底还设置有逻辑区,所述存储区和所述逻辑区之间被隔离沟槽隔开;The substrate is further provided with a logic area, and the storage area and the logic area are separated by isolation trenches;
    所述形成方法还包括:The forming method also includes:
    在所述逻辑区上形成第二晶体管,以制得存储器,其中,形成所述第二晶体管的工艺与形成所述第一晶体管的工艺相同。A second transistor is formed on the logic region to produce a memory, wherein the process of forming the second transistor is the same as the process of forming the first transistor.
  16. 根据权利要求15所述的电子器件的形成方法,其特征在于,在所述逻辑区上形成所述第二晶体管之后,在所述第一介电层内开设所述第一段通孔之前,所述形成方法还包括:The method for forming an electronic device according to claim 15, wherein after forming the second transistor on the logic region and before opening the first through hole in the first dielectric layer, The forming method also includes:
    在所述逻辑区上堆叠第一布线层,所述第一布线层包括第三介电层,以及形成在所述第三介电层内的多层金属层,直至形成第一金属层;stacking a first wiring layer on the logic region, the first wiring layer including a third dielectric layer, and multiple metal layers formed within the third dielectric layer until the first metal layer is formed;
    在所述第一金属层上形成第一覆盖层;其中,所述第一覆盖层的远离所述衬底的表面至所述第二晶体管的远离所述衬底的表面之间的距离为第一预设距离,所述第一预设距离等于所要形成的所述第一段通孔的深度。A first capping layer is formed on the first metal layer; wherein, the distance from the surface of the first capping layer away from the substrate to the surface of the second transistor away from the substrate is the first A preset distance, the first preset distance is equal to the depth of the through hole of the first segment to be formed.
  17. 根据权利要求16所述的电子器件的形成方法,其特征在于,所述第一覆盖层的材料和所述第三介电层的材料相同。The method for forming an electronic device according to claim 16, wherein the material of the first cover layer and the material of the third dielectric layer are the same.
  18. 根据权利要求17所述的电子器件的形成方法,其特征在于,在所述第二介电层内开设所述第二段通孔之前,所述形成方法还包括:The method for forming an electronic device according to claim 17, wherein before opening the second through hole in the second dielectric layer, the forming method further comprises:
    在所述第一覆盖层上堆叠第二布线层,所述第二布线层包括第四介电层,以及形成在所述第四介电层内的多层金属层,直至形成第二金属层;A second wiring layer is stacked on the first capping layer, the second wiring layer includes a fourth dielectric layer, and multiple metal layers formed within the fourth dielectric layer until the second metal layer is formed ;
    在所述第二金属层上形成第二覆盖层;其中,所述第二覆盖层的远离所述衬底的表面至所述第一覆盖层的远离所述衬底的表面之间的距离为第二预设距离,所述第二预设距离等于所要形成的所述第二段通孔的深度。A second capping layer is formed on the second metal layer; wherein, the distance from the surface of the second capping layer far away from the substrate to the surface of the first capping layer far away from the substrate is The second preset distance is equal to the depth of the through hole of the second segment to be formed.
  19. 根据权利要求12-18中任一项所述的电子器件的形成方法,其特征在于,在开设所述第二段通孔之后,在去除所述临时填充层之前,所述形成方法还包括:The method for forming an electronic device according to any one of claims 12-18, characterized in that, after opening the second section of through holes, before removing the temporary filling layer, the forming method further comprises:
    在所述第二段通孔内的至少靠近所述第二段通孔的孔口的位置处填充材料,以使填充的所述材料形成将所述第二段通孔的孔口堵住的临时填充层;A material is filled at a position in the second-stage through-hole at least close to the opening of the second-stage through-hole, so that the filled material forms a material that blocks the opening of the second-stage through-hole Temporary filling layer;
    在所述第二介电层上堆叠第五介电层;stacking a fifth dielectric layer on the second dielectric layer;
    在所述第五介电层内开设与所述第二段通孔相连通的第三段通孔。A third section of through holes communicated with the second section of through holes is opened in the fifth dielectric layer.
  20. 根据权利要求12-19中任一项所述的电子器件的形成方法,其特征在于,所述临时填充层的材料为多晶硅、碳或者金属。The method for forming an electronic device according to any one of claims 12 to 19, wherein the material of the temporary filling layer is polysilicon, carbon or metal.
  21. 根据权利要求19所述的电子器件的形成方法,其特征在于,在相连通的所述第一段通孔、所述第二段通孔和所述第三段通孔内形成所述电容器时,包括:The method for forming an electronic device according to claim 19, wherein the capacitor is formed in the connected through holes of the first section, the through holes of the second section and the through holes of the third section. ,include:
    在所述第一段通孔的侧面和底面、所述第二段通孔的侧面,以及所述第三段通孔的侧面分别形成第一电极层,在所述第一电极层上形成电容介质层,在所述电容介质层上形成第二电极层,并使所述第一电极层与所述第一晶体管电连接。A first electrode layer is formed on the side surface and bottom surface of the first through hole, the side surface of the second through hole, and the side surface of the third through hole, and a capacitor is formed on the first electrode layer. A dielectric layer, a second electrode layer is formed on the capacitor dielectric layer, and the first electrode layer is electrically connected to the first transistor.
  22. 根据权利要求12-21中任一项所述的电子器件的形成方法,其特征在于,去除所述临时填充层,包括:The method for forming an electronic device according to any one of claims 12-21, wherein removing the temporary filling layer comprises:
    采用刻蚀工艺去除所述临时填充层。The temporary filling layer is removed by an etching process.
  23. 根据权利要求12-22中任一项所述的电子器件的形成方法,在所述第一介电层内形成的所述第一段通孔的深宽比小于或等于5∶1;和/或,The method for forming an electronic device according to any one of claims 12 to 22, wherein the aspect ratio of the first segment of through holes formed in the first dielectric layer is less than or equal to 5:1; and/ or,
    在所述第二介电层内形成的所述第二段通孔的深宽比小于或等于5∶1。The aspect ratio of the second via hole formed in the second dielectric layer is less than or equal to 5:1.
  24. 一种电子设备,其特征在于,包括:An electronic device, comprising:
    印制电路板;printed circuit boards;
    如权利要求1~11中任一项所述的电子器件,或者如权利要求12~23中任一项所述的电子器件的形成方法制得的电子器件;The electronic device according to any one of claims 1 to 11, or the electronic device obtained by the method for forming an electronic device according to any one of claims 12 to 23;
    所述印制电路板与所述电子器件电连接。The printed circuit board is electrically connected to the electronic device.
  25. 根据权利要求24所述的电子设备,其特征在于,所述电子设备还包括:The electronic device according to claim 24, wherein the electronic device further comprises:
    逻辑处理电路,所述逻辑处理电路和所述电子器件集成在同一芯片中。A logic processing circuit, the logic processing circuit and the electronic device are integrated in the same chip.
PCT/CN2021/076402 2021-02-09 2021-02-09 Electronic device having through hole with high aspect ratio and forming method therefor, and electronic device WO2022170537A1 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
PCT/CN2021/076402 WO2022170537A1 (en) 2021-02-09 2021-02-09 Electronic device having through hole with high aspect ratio and forming method therefor, and electronic device
CN202180086462.8A CN116711474A (en) 2021-02-09 2021-02-09 Electronic device with through hole with high depth-to-width ratio, forming method of electronic device and electronic equipment

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/CN2021/076402 WO2022170537A1 (en) 2021-02-09 2021-02-09 Electronic device having through hole with high aspect ratio and forming method therefor, and electronic device

Publications (1)

Publication Number Publication Date
WO2022170537A1 true WO2022170537A1 (en) 2022-08-18

Family

ID=82837372

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/CN2021/076402 WO2022170537A1 (en) 2021-02-09 2021-02-09 Electronic device having through hole with high aspect ratio and forming method therefor, and electronic device

Country Status (2)

Country Link
CN (1) CN116711474A (en)
WO (1) WO2022170537A1 (en)

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20070120230A1 (en) * 2005-11-30 2007-05-31 Samsung Electronics Co. Ltd. Layer structure, method of forming the layer structure, method of manufacturing a capacitor using the same and method of manufacturing a semiconductor device using the same
CN103489831A (en) * 2012-06-11 2014-01-01 爱思开海力士有限公司 Semiconductor device with multi-layered storage node and method for fabricating the same
US20160064386A1 (en) * 2014-08-27 2016-03-03 Young-Geun Park Semiconductor devices and methods of fabricating the same
CN111106095A (en) * 2018-10-29 2020-05-05 长鑫存储技术有限公司 Groove and forming method thereof, preparation method of capacitor and capacitor

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20070120230A1 (en) * 2005-11-30 2007-05-31 Samsung Electronics Co. Ltd. Layer structure, method of forming the layer structure, method of manufacturing a capacitor using the same and method of manufacturing a semiconductor device using the same
CN103489831A (en) * 2012-06-11 2014-01-01 爱思开海力士有限公司 Semiconductor device with multi-layered storage node and method for fabricating the same
US20160064386A1 (en) * 2014-08-27 2016-03-03 Young-Geun Park Semiconductor devices and methods of fabricating the same
CN111106095A (en) * 2018-10-29 2020-05-05 长鑫存储技术有限公司 Groove and forming method thereof, preparation method of capacitor and capacitor

Also Published As

Publication number Publication date
CN116711474A (en) 2023-09-05

Similar Documents

Publication Publication Date Title
US11690210B2 (en) Three-dimensional dynamic random-access memory array
TWI784180B (en) Three dimensional memory device having embedded dynamic random access memory units
US7241655B2 (en) Method of fabricating a vertical wrap-around-gate field-effect-transistor for high density, low voltage logic and memory array
TWI471981B (en) Method for fabricating memory device with buried digit lines and buried word lines
US7919803B2 (en) Semiconductor memory device having a capacitor structure with a desired capacitance and manufacturing method therefor
KR101892709B1 (en) Vertical gate device with reduced word line resistivity
US6599799B2 (en) Double sided container capacitor for DRAM cell array and method of forming same
WO2023097909A1 (en) Semiconductor structure and preparation method therefor
JP2000164822A (en) Semiconductor storage device and its manufacture
TWI814065B (en) Memory device
TW202245069A (en) Semiconductor device
WO2022170537A1 (en) Electronic device having through hole with high aspect ratio and forming method therefor, and electronic device
US6413832B1 (en) Method for forming inner-cylindrical capacitor without top electrode mask
WO2023272880A1 (en) Transistor array and manufacturing method therefor, and semiconductor device and manufacturing method therefor
WO2023272881A1 (en) Transistor array and method for manufacturing same, and semiconductor device and method for manufacturing same
TWI786722B (en) Semiconductor device structure with conductive plugs of different aspect ratios and manganese-containing linling layer and method for preparing the same
CN113540026B (en) Bit line structure, manufacturing method thereof, semiconductor memory and electronic equipment
US7056790B2 (en) DRAM cell having MOS capacitor and method for manufacturing the same
JP2004031886A (en) Manufacturing method of contact
WO2023097907A1 (en) Semiconductor structure and method for preparing same
TWI793835B (en) Memory device with vertical field effect transistor and method for preparing the same
CN113540027B (en) Bit line structure, manufacturing method thereof, semiconductor memory and electronic equipment
TWI826301B (en) Semiconductor structure and method for manufacturing the same
JPH11214645A (en) Semiconductor memory and manufacture thereof
TWI473211B (en) Random access memory and manufacturing method for node thereof

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 21925202

Country of ref document: EP

Kind code of ref document: A1

WWE Wipo information: entry into national phase

Ref document number: 202180086462.8

Country of ref document: CN

NENP Non-entry into the national phase

Ref country code: DE

122 Ep: pct application non-entry in european phase

Ref document number: 21925202

Country of ref document: EP

Kind code of ref document: A1