WO2022139736A1 - Additive manufacturing method for metal or ceramic added 3d printing using photopolymers and 3d printer using this method - Google Patents

Additive manufacturing method for metal or ceramic added 3d printing using photopolymers and 3d printer using this method Download PDF

Info

Publication number
WO2022139736A1
WO2022139736A1 PCT/TR2021/051220 TR2021051220W WO2022139736A1 WO 2022139736 A1 WO2022139736 A1 WO 2022139736A1 TR 2021051220 W TR2021051220 W TR 2021051220W WO 2022139736 A1 WO2022139736 A1 WO 2022139736A1
Authority
WO
WIPO (PCT)
Prior art keywords
printer head
printer
composite mixture
extruder
paste
Prior art date
Application number
PCT/TR2021/051220
Other languages
French (fr)
Inventor
Bilal DEMİREL
Mohamed SHEHADA
Original Assignee
T.C. Erciyes Universitesi
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by T.C. Erciyes Universitesi filed Critical T.C. Erciyes Universitesi
Publication of WO2022139736A1 publication Critical patent/WO2022139736A1/en

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C64/00Additive manufacturing, i.e. manufacturing of three-dimensional [3D] objects by additive deposition, additive agglomeration or additive layering, e.g. by 3D printing, stereolithography or selective laser sintering
    • B29C64/10Processes of additive manufacturing
    • B29C64/106Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F10/00Additive manufacturing of workpieces or articles from metallic powder
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F12/00Apparatus or devices specially adapted for additive manufacturing; Auxiliary means for additive manufacturing; Combinations of additive manufacturing apparatus or devices with other processing apparatus or devices
    • B22F12/40Radiation means
    • B22F12/41Radiation means characterised by the type, e.g. laser or electron beam
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F12/00Apparatus or devices specially adapted for additive manufacturing; Auxiliary means for additive manufacturing; Combinations of additive manufacturing apparatus or devices with other processing apparatus or devices
    • B22F12/50Means for feeding of material, e.g. heads
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C64/00Additive manufacturing, i.e. manufacturing of three-dimensional [3D] objects by additive deposition, additive agglomeration or additive layering, e.g. by 3D printing, stereolithography or selective laser sintering
    • B29C64/20Apparatus for additive manufacturing; Details thereof or accessories therefor
    • B29C64/205Means for applying layers
    • B29C64/209Heads; Nozzles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C64/00Additive manufacturing, i.e. manufacturing of three-dimensional [3D] objects by additive deposition, additive agglomeration or additive layering, e.g. by 3D printing, stereolithography or selective laser sintering
    • B29C64/30Auxiliary operations or equipment
    • B29C64/307Handling of material to be used in additive manufacturing
    • B29C64/314Preparation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C64/00Additive manufacturing, i.e. manufacturing of three-dimensional [3D] objects by additive deposition, additive agglomeration or additive layering, e.g. by 3D printing, stereolithography or selective laser sintering
    • B29C64/30Auxiliary operations or equipment
    • B29C64/307Handling of material to be used in additive manufacturing
    • B29C64/321Feeding
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B33ADDITIVE MANUFACTURING TECHNOLOGY
    • B33YADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
    • B33Y10/00Processes of additive manufacturing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B33ADDITIVE MANUFACTURING TECHNOLOGY
    • B33YADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
    • B33Y30/00Apparatus for additive manufacturing; Details thereof or accessories therefor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B33ADDITIVE MANUFACTURING TECHNOLOGY
    • B33YADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
    • B33Y40/00Auxiliary operations or equipment, e.g. for material handling
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B33ADDITIVE MANUFACTURING TECHNOLOGY
    • B33YADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
    • B33Y70/00Materials specially adapted for additive manufacturing
    • B33Y70/10Composites of different types of material, e.g. mixtures of ceramics and polymers or mixtures of metals and biomaterials
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C32/00Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ
    • C22C32/0094Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ with organic materials as the main non-metallic constituent, e.g. resin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F10/00Additive manufacturing of workpieces or articles from metallic powder
    • B22F10/10Formation of a green body
    • B22F10/18Formation of a green body by mixing binder with metal in filament form, e.g. fused filament fabrication [FFF]
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F2999/00Aspects linked to processes or compositions used in powder metallurgy
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B28WORKING CEMENT, CLAY, OR STONE
    • B28BSHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B1/00Producing shaped prefabricated articles from the material
    • B28B1/001Rapid manufacturing of 3D objects by additive depositing, agglomerating or laminating of material

Definitions

  • AM additive Manufacturing
  • SLS Selective Laser Sintering
  • FDM Fusion Deposition Modeling
  • FFF Fusion Filament production
  • SLA Stereolithography
  • EBM Electron Beam Melting
  • DLP Digital Light Polymerization
  • Thermal gradients under rapid laser heating and cooling rates within ceramic parts keeps to be an important factor inducing defects such as cracks and distortions. Although preheating the powder beds can help moderating this phenomenon, the high melting points of ceramics place more strain on the manufacturing process. The rough surface quality of ceramic parts after processing, undesirable porosity and large shrinkage also limit their application areas.
  • Figure 1 Perspective view of the three dimensional printer.
  • Figure 2 Side view of the three dimensional printer.
  • a photosensitive resin (Photopolymer resin) is mixed with ceramic powder or metal powder.
  • the ceramic or metal powder ratio can be increased to 80-90%, unlike other methods.
  • the mixture which is made to the consistency of paste, can be pressed on a flat surface with the help of a spiral using a transmission organ like a hose.
  • the infrastructure of the FDM (Fusion deposition modelling) 3D printer can be used.
  • the paste-like mixture is connected to the printer head with a feeding hose (10) such as a plastic hose. Normally the FDM 3D printer has a heater.
  • the heater used in FDM is deactivated and instead a single screw, push extruder is used.
  • a powerful UV source is placed just under the extruder. The extruder spiral presses the mixed paste into the hose, and the paste that comes out of the extruder nozzle hardens as soon as it is exposed to UV light.
  • the printer consists of the motors (1) moving on the X, Y and Z axes, the paste mixing unit (2), the spiral spring (5) to press the raw material to the printer head, the printer head (3), the UV source (6) under the printer head screw (4) and the control screen (7).
  • the three dimensional printer using Fusion Deposition Modelling has the following in its most basic form
  • Printer head (3) which is the nozzle part of the extruder and where the composite mixture is transferred to the printing plate
  • Feeding motor (8) that enables the composite mixture to be transmitted to the feeding hose (10),
  • UV source (6) which enables the resin (composite mixture) used for the product to harden and is located under the screw of the printer head
  • Control screen (7) where all functions of the 3D printing device are controlled.
  • the related composite mixture can also be prepared in another device and transferred to the printer head (3) with the help of an extruder.
  • the UV source (6) comprises UV lamps radiating in the entire visible region, and the control screen (7) means the computer hardware and screen on which all functions of the 3D printing device are controlled.

Abstract

There are several different types of Additive Manufacturing (AM) depending on the type of material to be produced. The common point of all of these methods is that the object to be produced is drawn in any CAD program and divided into layers to be printed on a 3D printer. The AM method includes various technologies such as Selective Laser Sintering (SLS), Fusion Deposition Modeling (FDM), Fusion Filament production (FFF), Stereolithography (SLA), Electron Beam Melting (EBM) and Digital Light Polymerization (DLP) for the production of complex, high-volume net-shape components.

Description

ADDITIVE MANUFACTURING METHOD FOR METAE OR CERAMIC ADDED 3D PRINTING USING PHOTOPOEYMERS AND 3D PRINTER USING THIS METHOD
Field of Invention
There are several different types of Additive Manufacturing (AM) depending on the type of material to be produced. The common point of all of these methods is that the object to be produced is drawn in any CAD program and divided into layers to be printed on a 3D printer. The AM method includes various technologies such as Selective Laser Sintering (SLS), Fusion Deposition Modeling (FDM), Fusion Filament production (FFF), Stereolithography (SLA), Electron Beam Melting (EBM) and Digital Light Polymerization (DLP) for the production of complex, high- volume net- shape components.
State of the Art of the Invention (Prior Art)
Although there are many technologies in 3D printing of ceramics, the proportion of ceramic powder does not exceed 60% by volume, except for bulk solid-based technologies such as SLS and SLM, which use laser beams that causes residual stresses.
Thermal gradients under rapid laser heating and cooling rates within ceramic parts keeps to be an important factor inducing defects such as cracks and distortions. Although preheating the powder beds can help moderating this phenomenon, the high melting points of ceramics place more strain on the manufacturing process. The rough surface quality of ceramic parts after processing, undesirable porosity and large shrinkage also limit their application areas.
In addition, one of the biggest limitations of SLS today is the lack of materials that can be produced in powder form needed for this printing method, which affects the low variety of materials available.
Brief Description and Aims of the Invention Although there are many technologies in 3D printing of ceramics, the proportion of ceramic powder does not exceed 60% by volume, except for bulk solid-based technologies such as Selective Laser Sintering (SLS) and Selective Laser Melting (SLM), which use laser beams that causes residual stresses. Thermal gradients under rapid laser heating and cooling rates within ceramic parts keeps to be an important factor inducing defects such as cracks and distortions. Although preheating the powder beds can help moderating this phenomenon, the high melting points of ceramics place more strain on the manufacturing process. The rough surface quality of ceramic parts after processing, undesirable porosity and large shrinkage also limit their application areas. In addition, one of the biggest limitations of SLS today is the lack of materials that can be produced in powder form needed for this printing method, which affects the low variety of materials available.
Both the FDM and SLA techniques are limited to polymeric materials only, whereas the subject matter of the present invention is both a new technique in this field and offers reliable use for metal and ceramic materials. On the other hand, this method is both inexpensive and easy to use.
Definitions of Drawings Explaining the Invention
The figures prepared to better explain the three dimensional printer developed with this invention are explained below.
Figure 1 - Perspective view of the three dimensional printer.
Figure 2 - Side view of the three dimensional printer.
Figure 3 - Side view of the feeding unit
Definition of Elements/Pieces/Parts Composing the Invention
To better explain the three dimensional printer developed with this invention, the parts/pieces/elements in the figures prepared are numbered separately and the explanation of each number is given below.
1. Motor 2. Paste mixing unit
3. Printer head
4. Transmission organ (Extruder screw)
5. Spiral spring
6. UV source
7. Control screen
8. Feeding Motor
9. Feeding System
10. Feeding Hose
Detailed Description of the Invention
This study is briefly a new technique for new 3D additive manufacturing methods for ceramic, metal and composite materials. According to this technique, in the first stage, a photosensitive resin (Photopolymer resin) is mixed with ceramic powder or metal powder. In this method, the ceramic or metal powder ratio can be increased to 80-90%, unlike other methods. The mixture, which is made to the consistency of paste, can be pressed on a flat surface with the help of a spiral using a transmission organ like a hose. In this method, the infrastructure of the FDM (Fusion deposition modelling) 3D printer can be used. At this point, the paste-like mixture is connected to the printer head with a feeding hose (10) such as a plastic hose. Normally the FDM 3D printer has a heater. In this method, the heater used in FDM is deactivated and instead a single screw, push extruder is used. On the other hand, a powerful UV source is placed just under the extruder. The extruder spiral presses the mixed paste into the hose, and the paste that comes out of the extruder nozzle hardens as soon as it is exposed to UV light.
In this study, part of the FDM technique for printing ceramic and metal composites, mixing ceramic or metal powder and photosensitive resin in paste consistency and using UV light is essential and this is a different point from other methods.
This invention covers the design and production of 3D printers for ceramic or metal composite production. The printer consists of the motors (1) moving on the X, Y and Z axes, the paste mixing unit (2), the spiral spring (5) to press the raw material to the printer head, the printer head (3), the UV source (6) under the printer head screw (4) and the control screen (7).
The three dimensional printer using Fusion Deposition Modelling has the following in its most basic form;
• Motors (1) that move the plate on which the part to be 3D printed along the X, Y, Z axes is placed,
• The paste mixing unit (2), where the composite mixture is prepared,
• Printer head (3), which is the nozzle part of the extruder and where the composite mixture is transferred to the printing plate,
• Feeding hose (10) that transmits the composite mixture taken from the paste mixing unit to the printer head,
• Feeding motor (8) that enables the composite mixture to be transmitted to the feeding hose (10),
• Transmission organ (extruder screw) (4) that provides the transfer of the pastelike mixture to the printer head,
• Spiral spring (5), which ensures that the extruder nozzle (printer head) is pressed onto the product printing platform,
• UV source (6), which enables the resin (composite mixture) used for the product to harden and is located under the screw of the printer head,
• Control screen (7) where all functions of the 3D printing device are controlled.
The related composite mixture can also be prepared in another device and transferred to the printer head (3) with the help of an extruder. The UV source (6) comprises UV lamps radiating in the entire visible region, and the control screen (7) means the computer hardware and screen on which all functions of the 3D printing device are controlled.

Claims

CLAIMS A three dimensional printer using Fusion Deposition Modelling and comprising:
• Motors (1) that move the plate on which the part to be 3D printed along the X, Y, Z axes is placed,
• The paste mixing unit
(2), where the composite mixture is prepared,
• Printer head (3), which is the nozzle part of the extruder and where the composite mixture is transferred to the printing plate,
• Feeding hose (10) that transmits the composite mixture taken from the paste mixing unit to the printer head,
• Control screen (7) where all functions of the 3D printing device are controlled, characterized in that; it further comprises:
• Feeding motor (8) that enables the composite mixture to be transmitted to the feeding hose (10),
• Transmission organ (extruder screw) (4) that provides the transfer of the pastelike composite mixture to the printer head,
• Spiral spring (5), which ensures that the extruder nozzle (printer head) is pressed onto the product printing platform,
• UV source (6), which enables the composite mixture used for the product to harden and is located under the screw of the Printer head. A method of operation of a three dimensional printer according to claim 1, characterized in that it comprises the steps of:
• Mixing the photosensitive photopolymer resin with ceramic powder or metal powder in the paste mixing unit,
• Pressing the mixture, which has been brought to paste consistency in the paste mixing unit, to a flat surface with the help of a spiral spring using the transmission organ,
• Hardening of the paste coming out of the nozzle of the printer head (extruder) by exposing to UV light.
5
3. A three dimensional printer according to claim 1, characterized in that the feeding hose (10) is a plastic hose.
6
PCT/TR2021/051220 2020-12-22 2021-11-16 Additive manufacturing method for metal or ceramic added 3d printing using photopolymers and 3d printer using this method WO2022139736A1 (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
TR202021198 2020-12-22
TR2020/21198 2020-12-22
TR202104413 2021-03-08
TR2021/004413 2021-03-08

Publications (1)

Publication Number Publication Date
WO2022139736A1 true WO2022139736A1 (en) 2022-06-30

Family

ID=82160011

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/TR2021/051220 WO2022139736A1 (en) 2020-12-22 2021-11-16 Additive manufacturing method for metal or ceramic added 3d printing using photopolymers and 3d printer using this method

Country Status (1)

Country Link
WO (1) WO2022139736A1 (en)

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20140265034A1 (en) * 2013-03-12 2014-09-18 Orange Maker LLC 3d printing using spiral buildup
CN105618756A (en) * 2015-08-25 2016-06-01 国家电网公司 Device for realizing 3D metal printing by virtue of supporting structure
KR20180099285A (en) * 2017-02-28 2018-09-05 주식회사 그립플레이 A 3d-printer with improved precision of driving
CN211071828U (en) * 2019-11-06 2020-07-24 北京科技大学 3D printing device for laser selective solidified metal

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20140265034A1 (en) * 2013-03-12 2014-09-18 Orange Maker LLC 3d printing using spiral buildup
CN105618756A (en) * 2015-08-25 2016-06-01 国家电网公司 Device for realizing 3D metal printing by virtue of supporting structure
KR20180099285A (en) * 2017-02-28 2018-09-05 주식회사 그립플레이 A 3d-printer with improved precision of driving
CN211071828U (en) * 2019-11-06 2020-07-24 北京科技大学 3D printing device for laser selective solidified metal

Similar Documents

Publication Publication Date Title
CN105415687B (en) A kind of Alternative 3D printing method
CN105764674B (en) 3D printing method using slip
US7158849B2 (en) Method for rapid prototyping by using linear light as sources
US20190329501A1 (en) Systems and methods for calibration feedback for additive manufacturing
CN106007723B (en) A kind of manufacturing method of SiC ceramic biscuit
DE60115009T2 (en) METHOD FOR PRODUCING A PATTERNED GRINDING TOOL, USING A RAPID PROTOTYPE TECHNOLOGY FOR THE REFERENCE MOLDING PIECE
Chua et al. A study of the state-of-the-art rapid prototyping technologies
US6238614B1 (en) Selective infiltration manufacturing method and apparatus to fabricate prototypes and moulds by infiltrating molten droplets selectively into layers of powder
CN110002883B (en) Photocuring 3D printed polysilazane ceramic product and preparation method thereof
US11420384B2 (en) Selective curing additive manufacturing method
CN100391721C (en) Quick forming method by adoption of projection technique
CN106182772B (en) Multiple material rapid prototyping molding machine and method
CN109414862A (en) By the extruder of the equipment of extrusion-compound extrusion moulding (CEM) increasing material manufacturing metal parts
CN106188932B (en) A kind of powder for molding and powder face molding machine based on DLP technologies
JP3454636B2 (en) 3D shape creation method by powder lamination method
CN109676747A (en) A kind of more material ceramics photocuring print system mechanisms and crude green body preparation method
Godec et al. Introduction to additive manufacturing
US7079915B2 (en) Method for rapid prototyping by using plane light as sources
JPH08156106A (en) Manufacture of three dimensional object
WO2022139736A1 (en) Additive manufacturing method for metal or ceramic added 3d printing using photopolymers and 3d printer using this method
Nee et al. On the improvement of the stereolithography (SL) process
US11458687B2 (en) Additive manufacturing system
TR2021004413A1 (en) ADDITIVE MANUFACTURING METHOD FOR 3D PRINTING WITH METAL OR CERAMIC ADDITIVES USING PHOTOPOLYMER AND 3D PRINTER USING THIS METHOD
US11911848B2 (en) Systems and methods for additive manufacturing
CN113400437A (en) Method for preparing ceramic material through ultraviolet beam synchronous curing assisted direct-writing 3D printing

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 21911716

Country of ref document: EP

Kind code of ref document: A1

NENP Non-entry into the national phase

Ref country code: DE

122 Ep: pct application non-entry in european phase

Ref document number: 21911716

Country of ref document: EP

Kind code of ref document: A1