WO2022132749A1 - A process for producing alpha-olefins - Google Patents

A process for producing alpha-olefins Download PDF

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Publication number
WO2022132749A1
WO2022132749A1 PCT/US2021/063283 US2021063283W WO2022132749A1 WO 2022132749 A1 WO2022132749 A1 WO 2022132749A1 US 2021063283 W US2021063283 W US 2021063283W WO 2022132749 A1 WO2022132749 A1 WO 2022132749A1
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catalyst
stream
concentration
ligand
aluminum
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PCT/US2021/063283
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French (fr)
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Brent Carl NORRIS
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Shell Oil Company
Shell Internationale Research Maatschappij Bv
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Publication of WO2022132749A1 publication Critical patent/WO2022132749A1/en

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/26—Catalytic processes with hydrides or organic compounds
    • C07C2/32—Catalytic processes with hydrides or organic compounds as complexes, e.g. acetyl-acetonates
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/26—Catalytic processes with hydrides or organic compounds
    • C07C2/32—Catalytic processes with hydrides or organic compounds as complexes, e.g. acetyl-acetonates
    • C07C2/34—Metal-hydrocarbon complexes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C07C2531/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • C07C2531/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/22—Organic complexes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

Definitions

  • the invention relates to a process for producing alpha-olefins wherein the concentration of co-catalyst is controlled.
  • Linear alpha olefins are a valuable comonomer for linear low-density polyethylene and high-density polyethylene.
  • Such olefins are also valuable as a chemical intermediate in the production of plasticizer alcohols, fatty acids, detergent alcohols, polyalphaolefins, oil field drilling fluids, lubricant oil additives, linear alkylbenzenes, alkenylsuccinic anhydrides, alkyldimethylamines, dialkylmethylamines, alpha-olefin sulfonates, internal olefin sulfonates, chlorinated olefins, linear mercaptans, aluminum alkyls, alkyldiphenylether disulfonates, and other chemicals.
  • US 6,683,187 describes a bis(arylimino)pyridine ligand, catalyst precursors and catalyst systems derived from this ligand for ethylene oligomerization to form linear alpha olefins.
  • the patent teaches the production of linear alpha olefins with a Schulz-Flory oligomerization product distribution. In such a process, a wide range of oligomers are produced, and the fraction of each olefin can be determined by calculation on the basis of the K-factor.
  • the K-factor is the molar ratio of (C n +2)/C n , where n is the number of carbons in the linear alpha olefin product.
  • the invention provides a process for producing alpha-olefins comprising contacting an ethylene feed with an oligomerization catalyst system in an oligomerization reaction zone under oligomerization reaction conditions to produce a product stream comprising alpha-olefins wherein the catalyst system comprises an iron-ligand complex and a modified methyl aluminoxane (MMAO) co-catalyst wherein the co-catalyst feed stream to the reaction zone is diluted in a solvent to a concentration of less than 1 wt% aluminum in the co-catalyst feed stream.
  • MMAO modified methyl aluminoxane
  • the invention further provides a process for producing alpha-olefins comprising: a) preparing a co-catalyst stream by diluting, in a first dilution step, a modified methyl aluminoxane (MMAO) stream having a concentration of greater than 4 wt% aluminum in a first solvent to form a co-catalyst stream having a concentration of less than 1.5 wt% aluminum; and b) contacting an ethylene feed with an oligomerization catalyst system in an oligomerization reaction zone under oligomerization reaction conditions to produce a product stream comprising alpha-olefins wherein the catalyst system comprises an iron-ligand complex and the co-catalyst stream.
  • MMAO modified methyl aluminoxane
  • the process comprises converting an olefin feed into a higher oligomer product stream by contacting the feed with an oligomerization catalyst system and a co-catalyst in an oligomerization reaction zone under oligomerization conditions.
  • an ethylene feed may be contacted with an iron-ligand complex and modified methyl aluminoxane under oligomerization conditions to produce a product slate of alpha olefins having a specific k-factor.
  • the olefin feed to the process comprises ethylene.
  • the feed may also comprise olefins having from 3 to 8 carbon atoms.
  • the ethylene may be pretreated to remove impurities, especially impurities that impact the reaction, product quality or damage the catalyst.
  • the ethylene may be dried to remove water.
  • the ethylene may be treated to reduce the oxygen content of the ethylene. Any pretreatment method known to one of ordinary skill in the art can be used to pretreat the feed.
  • the oligomerization catalyst system may comprise one or more oligomerization catalysts as described further herein.
  • the oligomerization catalyst is a metal-ligand complex that is effective for catalyzing an oligomerization process.
  • the ligand may comprise a bis(arylimino)pyridine compound, a bis(alkylimino)pyridine compound or a mixed aryl-alkyl iminopyridine compound.
  • the ligand comprises a pyridine bis(imine) group.
  • the ligand may be a bis(arylimino)pyridine compound having the structure of Formula I.
  • Ri, R2 and R3 are each independently hydrogen, optionally substituted hydrocarbyl, hydroxo, cyano or an inert functional group.
  • R4 and R5 are each independently hydrogen, optionally substituted hydrocarbyl, hydroxo, cyano or an inert functional group.
  • R6 and R7 are each independently an aryl group as shown in Formula II. The two aryl groups (R6 and R7) on one ligand may be the same or different.
  • R9, R10, R11, R12 are each independently hydrogen, optionally substituted hydrocarbyl, hydroxo, cyano, an inert functional group, fluorine, or chlorine. Any two of R1-R3, and R9-R11 vicinal to one another taken together may form a ring.
  • R12 may be taken together with R11, R4 or R5 to form a ring.
  • R 2 and R4 or R 3 and R5 may be taken together to form a ring.
  • a hydrocarbyl group is a group containing only carbon and hydrogen. The number of carbon atoms in this group is preferably in the range of from 1 to 30.
  • An optionally substituted hydrocarbyl is a hydrocarbyl group that optionally contains one or more “inert” heteroatom-containing functional groups.
  • Inert means that the functional groups do not interfere to any substantial degree with the oligomerization process. Examples of these inert groups include fluoride, chloride, iodide, stannanes, ethers, hydroxides, alkoxides and amines with adequate steric shielding.
  • the optionally substituted hydrocarbyl group may include primary, secondary and tertiary carbon atoms groups.
  • Primary carbon atom groups are a -CH2-R group wherein R may be hydrogen, an optionally substituted hydrocarbyl or an inert functional group.
  • Examples of primary carbon atom groups include -CH3, -C2H5, -CH2CI, -CH2OCH3, -CIHLN ⁇ Hs ⁇ , and -CH2Ph.
  • Secondary carbon atom groups are a -CH-R2 or -CH (R)(R') group wherein R and R' may be optionally substituted hydrocarbyl or an inert functional group.
  • Tertiary carbon atom groups are a -C-(R)(R')(R") group wherein R, R', and R" may be optionally substituted hydrocarbyl or an inert functional group.
  • Examples of tertiary carbon atom groups include -C(CH 3 ) 3 , -CCI3, - C ⁇ CPh, 1-Adamantyl, and -C(CH 3 )2(OCH 3 )
  • An inert functional group is a group other than optionally substituted hydrocarbyl that is inert under the oligomerization conditions. Inert has the same meaning as provided above. Examples of inert functional groups include halide, ethers, and amines, in particular tertiary amines.
  • R1-R5, R8-R12 and R13-R17 may be selected to enhance other properties of the ligand, for example, solubility in non-polar solvents.
  • R1-R5, R8-R12 and R13-R17 may be selected to enhance other properties of the ligand, for example, solubility in non-polar solvents.
  • oligomerization catalysts are further described below having the structure shown in Formula 3.
  • a ligand of Formula III wherein R1-R5, R9-R11 and R14-R16, are hydrogen; and R8, R12, R13 and R17 are fluorine.
  • a ligand of Formula III wherein R1-R5, Rs, Rio, R12, R14 and R16 are hydrogen; R13, R15 and R17 are methyl and R9 and R11 are tert-butyl.
  • a ligand of Formula III wherein R1-R5, Rs, R12, R14 and R16 are hydrogen; R13, R15 and R17 are methyl; R9 and R11 are phenyl and R10 is an alkoxy.
  • a ligand of Formula III wherein R1-R5, R8, R10, R11 and R14- R16 are hydrogen; R 9 and R12 are methyl; and R13 and R17 are fluorine.
  • a ligand of Formula III wherein R1-R3, R9-R11 and R14-R16, are hydrogen; R 4 and R5 are phenyl and Rs, R12, RB and R17 are fluorine.
  • a ligand of Formula III wherein R1-R5, Rs-Rg, R11-R12, R13- R14 and R16-R17 are hydrogen; and R10 and RB are fluorine.
  • a ligand of Formula III wherein R1-R5, R8, R10, R12, R13, R15 and R17 are hydrogen; and R9, R11, R14 and RB are fluorine.
  • a ligand of Formula III wherein R1-R5, R9, R11-R12, R14 and R16-R17 are hydrogen; and Rs, R10, R13 and RB are fluorine.
  • a ligand of Formula III wherein R1-R5, Rs-Rg, R11-R12, R14 and R16 are hydrogen; R10 is tert-butyl; and R13, R15 and R17 are methyl.
  • a ligand of Formula III is provided wherein R1-R5, R9-R12, R14 and R16, are hydrogen; R 8 is fluorine; and R13, R15 and R17 are methyl.
  • a ligand of Formula III wherein R1-R5, R9-R12, R13, Ris and R17 are hydrogen; R8 is tert-butyl; and R14 and R17, are methyl.
  • a ligand of Formula III wherein R1-R5, R9-R12, R13-R14 and R16-R17 are hydrogen; and Rs and R15 are tert-butyl.
  • a ligand of Formula III wherein R1-R5, R8-R10, R13-R14 and R16-R17 are hydrogen; R15 is tert-butyl; and R11 and R12 are taken together to form an aryl group.
  • a ligand of Formula III wherein R1-R5, R9-R12, R14-R17 are hydrogen; and R 8 and R13 are methyl.
  • a ligand of Formula III wherein R1-R5, R8-R9.R11-R12, R14 and Ri6 are hydrogen; R10 is fluorine; and R13, R15 and R17 are methyl.
  • a ligand of Formula III wherein R1-R5, R8, R10, R12, R14 and R16 are hydrogen; R9 and R11 are fluorine; and R13, R15 and R17 are methyl.
  • a ligand of Formula III wherein R1-R5, R8-R9,R11-R12, R14 and R16 ARe hydrogen; R10 is an alkoxy; and R13, R15 and R17 are methyl.
  • a ligand of Formula III wherein R1-R5, R8-R9.R11-R12, R14 and R16 are hydrogen; R10 is a silyl ether; and R13, R15 and R17 are methyl.
  • a ligand of Formula III wherein R1-R5, Rs, R10, R12, Ru-R16 are hydrogen; R9 and R11 are methyl; and R13 and R17 are ethyl.
  • a ligand of Formula III wherein R1-R5, R9-R12, and R14-R17 are hydrogen; and R 8 and R13 are ethyl.
  • a ligand of Formula III wherein R1-R5, R9-R11 and R14-R16 are hydrogen; and R 8 , R12, R13 and R17 are chlorine.
  • a ligand of Formula III wherein R1-R5, R9, R11, R14 and R16 are hydrogen; and R 8 , R10, R12, R13, R15 and R17 are methyl.
  • a ligand of Formula III wherein R1-R5, R9-R10, R12, R14-R15 and R17 are hydrogen; and R 8 , R11, R13 and Rie are methyl.
  • a ligand of Formula III is provided wherein R1-R17 are hydrogen.
  • a ligand of Formula III wherein R1-R5, Rs, R10, R12, R13, R15 and R17 are hydrogen; and R9, R11, R14 and R16 are tert-butyl. In one embodiment, a ligand of Formula III is provided wherein R1-R5, R8-R12, R14 and R16, are hydrogen; and R13, R15 and R17 are methyl.
  • a ligand of Formula III wherein R1-R5, R9, R11-R12, R14 and R16 are hydrogen; R8 and R10 are fluorine; and RB, RI, and R17 are methyl.
  • a ligand of Formula III wherein R1-R5, R9, R11-R12, R14 and R16-R17 are hydrogen; and Rs, R10, R13 and R15 are methyl.
  • a ligand of Formula III wherein R1-R5, R9-R11 and R14-RB are hydrogen; R 8 and R12 are chlorine; and R13 and R17 are fluorine.
  • a ligand of Formula III wherein R1-R5, R8, R10, R12, R14 and RB are hydrogen; and R9, R11, R13, R15 and R17 are methyl.
  • a ligand of Formula III wherein R1-R5, R9-R11 and R13-R14 and R16-R17 are hydrogen; R8 and R12 are chlorine; and R15 is tert-butyl.
  • a ligand of Formula III wherein R1-R5, R9-R11 and R13-R17 are hydrogen; and Rs and R12 are chlorine.
  • a ligand of Formula III wherein R1-R5, R9-R12, and R14-R17 are hydrogen; and R 8 and R13 are chlorine.
  • a ligand of Formula III wherein R1-R5, R9, R11-R12, R14 and R16-R17 are hydrogen; and R 8 , R10, R13 and RB are chlorine.
  • a ligand of Formula III wherein R1-R5, R9, R11-R12, and R14, and R16-Ri7 are hydrogen; R10 and R15 are methyl; and R 8 and R13 are chlorine.
  • a ligand of Formula III wherein R1-R5, R9-R11 and R13-R14 and R16-Ri7 are hydrogen; R15 is fluorine; and R 8 and R12 are chlorine.
  • a ligand of Formula III wherein R1-R5, R8-R9, R11-R12, R14- R15 and R17 are hydrogen; R10 is tert-butyl; and R13 and R16 are methyl.
  • a ligand of Formula III wherein R1-R5, R9-R11, R14 and RB are hydrogen; R 8 and R12 are fluorine; and R13, R15 and R17 are methyl.
  • a ligand of Formula III wherein R1-R5, R9-R10, R12, R14-R15 and R17 are hydrogen; R 8 and R13 are methyl; and R11 and R16 are isopropyl.
  • a ligand of Formula III wherein R1-R5, R9-R12 and R14-R16 are hydrogen; R 8 is ethyl; and R13 and R17 are fluorine.
  • a ligand of Formula III wherein R2-R5, R9-R10, R12, R14-R15 and R17 are hydrogen; R1 is methoxy; and R 8 , R11, R13 and RB are methyl.
  • a ligand of Formula III is provided wherein R2-R5, R8-R12, R14 and R16, are hydrogen; Ri is methoxy; and R13, R15 and R17 are methyl.
  • a ligand of Formula III wherein R2-R5, R9-R12, and R14-R17 are hydrogen; Ri is methoxy; and R8 and R13 are ethyl.
  • a ligand of Formula III wherein R2-R5, R9, R11-R12, R14 and R16-R17 are hydrogen; Ri is tert-butyl; and Rs, R10, R13 and Ris are methyl.
  • a ligand of Formula III wherein R2-R5, R8-R12, R14 and R16 are hydrogen; Ri is tert-butyl; and R13, R15 and R17 are methyl.
  • a ligand of Formula III wherein R2-R5, R9, R11, R14 and R16, are hydrogen; Ri is methoxy; and Rs, R10, R12, R13, Ris and R17 are methyl.
  • a ligand of Formula III wherein R2-R5, R9, R11, R14 and RR, are hydrogen; Ri is alkoxy; and Rs, R10, R12, R13, R15 and R17 are methyl.
  • a ligand of Formula III wherein R2-R5, R9, R11, R14 and Rie are hydrogen; Ri is tert-butyl; and Rs, R10, R12, R13, R15 and R17 are methyl.
  • the ligand may be a compound having the structure of Formula I, wherein one of R6 and R7 is aryl as shown in Formula II and one of Re and R7 is pyridyl as shown in Formula IV.
  • Re and R7 may be pyrrolyl.
  • R1, R2 and R3 are each independently hydrogen, optionally substituted hydrocarbyl, hydroxo, cyano or an inert functional group.
  • R4 and R5 are each independendy hydrogen, optionally substituted hydrocarbyl, hydroxo, cyano or an inert functional group.
  • Rs-Ri2 and R18-R21 are each independendy hydrogen, optionally substituted hydrocarbyl, hydroxo, cyano, an inert functional group, fluorine, or chlorine. Any two of R1-R3, and R9-R11 vicinal to one another taken together may form a ring.
  • R 12 may be taken together with R11, R4 or R5 to form a ring.
  • R 2 and R4 or R 3 and R5 may be taken together to form a ring.
  • a ligand of Formula V wherein R1-R5, R9, R11 and R18-R21 are hydrogen; and R8, R10, and R12 are methyl.
  • a ligand of Formula V wherein R1-R5, R9-R11 and R18-R21 are hydrogen; and R8 and R12 are ethyl.
  • the ligand may be a compound having the structure of Formula I, wherein one of R6 and R7 is aryl as shown in Formula II and one of Re and R7 is cyclohexyl as shown in Formula VI.
  • Re and R7 may be cyclohexyl.
  • Ri, R2 and R3 are each independently hydrogen, optionally substituted hydrocarbyl, hydroxo, cyano or an inert functional group.
  • R4 and R5 are each independently hydrogen, optionally substituted hydrocarbyl, hydroxo, cyano or an inert functional group.
  • Rs-Ri2 and R22-R26 are each independently hydrogen, optionally substituted hydrocarbyl, hydroxo, cyano, an inert functional group, fluorine, or chlorine. Any two of R1-R3, and R9-R11 vicinal to one another taken together may form a ring.
  • R 12 may be taken together with R11, R4 or R5 to form a ring.
  • R 2 and R4 or R 3 and R5 may be taken together to form a ring.
  • a ligand of Formula VII is provided wherein R1-R5, R 9 , R11 and R22-R26 are hydrogen; and R8, R10, and R12 are methyl.
  • R6 and R7 may be adamantyl or another cycloalkane.
  • the ligand may be a compound having the structure of Formula I, wherein one of R6 and R7 is aryl as shown in Formula II and one of Re and R7 is ferrocenyl as shown in Formula VIII.
  • Re and R7 may be ferrocenyl.
  • Ri, R2 and R3 are each independently hydrogen, optionally substituted hydrocarbyl, hydroxo, cyano or an inert functional group.
  • R4 and R5 are each independently hydrogen, optionally substituted hydrocarbyl, hydroxo, cyano or an inert functional group.
  • R8-Ri2 and R27 -R35 are each independently hydrogen, optionally substituted hydrocarbyl, hydroxo, cyano, an inert functional group, fluorine, or chlorine. Any two of R1-R3, and R9-R11 vicinal to one another taken together may form a ring.
  • R12 may be taken together with R11, R4 or R5 to form a ring.
  • R2 and R4 or R3 and Rs may be taken together to form a ring.
  • a ligand of Formula IX is provided wherein R1-R5, R9, R11 and R27 -R35 are hydrogen; and R8, R10, and R12 are methyl.
  • a ligand of Formula IX is provided wherein R1-R5, R9-R11, and R27 -R35 are hydrogen; and Rs and R12 are ethyl.
  • the ligand may be a bis(alkylamino)pyridine.
  • the alkyl group may have from 1 to 50 carbon atoms.
  • the alkyl group may be a primary, secondary, or tertiary alkyl group.
  • the alkyl group may be selected from the group consisting of methyl, ethyl, propyl, isopropyl, butyl, sec-butyl, isobutyl, and tert-butyl.
  • the alkyl group may be selected from any n-alkyl or structural isomer of an n-alkyl having 5 or more carbon atoms, e.g., n-pentyl; 2-methyl-butyl; and 2,2-dimethylpropyl.
  • the ligand may be an alkyl-alkyl iminopyridine, where the two alkyl groups are different. Any of the alkyl groups described above as being suitable for a bis (alkylamino) pyridine are also suitable for this alkyl-alkyl iminopyridine.
  • the ligand may be an aryl alkyl iminopyridine.
  • the aryl group may be of a similar nature to any of the aryl groups described with respect to the bis(arylimino)pyridine compound and the alkyl group may be of a similar nature to any of the alkyl groups described with respect to the bis(alkylamino)pyridine compound.
  • any structure that combines features of any two or more of these ligands can be a suitable ligand for this process.
  • the oligomerization catalyst system may comprise a combination of one or more of any of the described oligomerizations catalysts.
  • the ligand feedstock may contain between 0 and 10 wt.% bisimine pyridine impurity, preferably 0-1 wt.% bisimine pyridine impurity, most preferably 0-0.1 wt.% bisimine pyridine impurity. This impurity is believed to cause the formation of polymers in the reactor, so it is preferable to limit the amount of this impurity that is present in the catalyst system.
  • the bisimine pyridine impurity is a ligand of Formula II in which three of R8, R12, R13, and R17 are each independently optionally substituted hydrocarbyl.
  • the bisimine pyridine impurity is a ligand of Formula II in which all four of R8, R12, R13, and R17 are each independently optionally substituted hydrocarbyl.
  • the metal may be a transition metal, and the metal is preferably present as a compound having the formula MX transit, where M is the metal, X is a monoanion and n represents the number of monoanions (and the oxidation state of the metal).
  • the metal can comprise any Group 4-10 transition metal.
  • the metal can be selected from the group consisting of titanium, zirconium, hafnium, vanadium, niobium, tantalum, chromium, molybdenum, tungsten, manganese, iron, cobalt, nickel, palladium, platinum, ruthenium and rhodium.
  • the metal is cobalt or iron.
  • the metal is iron.
  • the metal of the metal compound can have any positive formal oxidation state of from 2 to 6 and is preferably 2 or 3.
  • the monoanion may comprise a halide, a carboxylate, a [3-diketonate, a hydrocarboxide, an optionally substituted hydrocarbyl, an amide or a hydride.
  • the hydrocarboxide may be an alkoxide, an aryloxide or an aralkoxide.
  • the halide may be fluorine, chlorine, bromine or iodine.
  • the carboxylate may be any Ci to C20 carboxylate.
  • the carboxylate may be acetate, a propionate, a butyrate, a pentanoate, a hexanoate, a heptanoate, an octanoate, a nonanoate, a decanoate, an undecanoate, or a dodecanoate.
  • the carboxylate may be 2-ethylhexanoate or trifluoroacetate.
  • the ⁇ -diketonate may be any C1 to C20 ⁇ -diketonate.
  • the ⁇ -diketonate may be acetylacetonate, hexafluoroacetylacetonate, or benzoylacetonate.
  • the hydrocarboxide may be any C1 to C20 hydtocarboxide.
  • the hydtocatboxide may be a Ci to C20 alkoxide, or a C6 to C20 aryloxide.
  • the alkoxide may be methoxide, ethoxide, a propoxide (e.g., iso-propoxide) or a butoxide (e.g., tert-butoxide).
  • the aryloxide may be phenoxide
  • the number of monoanions equals the formal oxidation state of the metal atom.
  • metal compounds include iron acetylacetonate, iron chloride, and iron bis(2-ethylhexanoate).
  • a co-catalyst is used in the oligomerization reaction.
  • the co-catalyst may be a compound that is capable of transferring an optionally substituted hydrocarbyl or hydride group to the metal atom of the catalyst and is also capable of abstracting an X" group from the metal atom M.
  • the co-catalyst may also be capable of serving as an electron transfer reagent or providing sterically hindered counterions for an active catalyst.
  • the co-catalyst may comprise two compounds, for example one compound that is capable of transferring an optionally substituted hydrocarbyl or hydride group to metal atom M and another compound that is capable of abstracting an X group from metal atom M.
  • Suitable compounds for transferring an optionally substituted hydrocarbyl or hydride group to metal atom M include organoaluminum compounds, alkyl lithium compounds, Grignards, alkyl tin and alkyl zinc compounds.
  • Suitable compounds for abstracting an X group from metal atom M include strong neutral Lewis acids such as SbF5, BF3 and Ar 3 B wherein Ar is a strong electron- withdrawing aryl group such as C6F5 or 3,5-(CF 3 ) 2 C6H3.
  • a neutral Lewis acid donor molecule is a compound which may suitably act as a Lewis base, such as ethers, amines, sulfides and organic nitrites.
  • the co-catalyst is preferably an organoaluminum compound which may comprise an alkylaluminum compound, an aluminoxane or a combination thereof.
  • the alkylaluminum compound may be trialkylaluminum, an alkylaluminum halide, an alkylaluminum alkoxide or a combination thereof.
  • the alkyl group of the alkylaluminum compound may be any Ci to C20 alkyl group.
  • the alkyl group may be methyl, ethyl, propyl, butyl, pentyl, hexyl, heptyl or octyl.
  • the alkyl group may be an iso-alkyl group.
  • the trialkylaluminum compound may comprise trimethylaluminum (TMA), triethylaluminum (TEA), tripropylaluminum, tributylaluminum, tripentylaluminum, trihexylaluminum, triheptylaluminum, trioctylaluminum or mixtures thereof.
  • the trialkylaluminum compound may comprise tri-n-propylaluminum (TNPA), tri-n-butylaluminum (TNBA), tri-iso- butylaluminum (TIB A), tri-n-hexylaluminum, tri-n-octylaluminum (TNOA).
  • the halide group of the alkylaluminum halide may be chloride, bromide or iodide.
  • the alkylaluminum halide may be diethylaluminum chloride, diethylaluminum bromide, ethylaluminum dichloride, ethylaluminum sesquichloride or mixtures thereof.
  • the alkoxide group of the alkylaluminum alkoxide may be any Ci to C20 alkoxy group.
  • the alkoxy group may be methoxy, ethoxy, propoxy, butoxy, pentoxy, hexoxy, heptoxy or octoxy.
  • the alkylaluminum alkoxide may be diethylaluminum ethoxide.
  • the aluminoxane compound may be methylaluminoxane (MAO), ethylaluminoxane, modified methylaluminoxane (MMAO), n-propylaluminoxane, iso-propyl-aluminoxane, n- butylaluminoxane, sec-butylaluminoxane, iso-butylaluminoxane, t-butylaluminoxane, 1-pentyl- aluminoxane, 2-pentyl-aluminoxane, 3-pentyl-aluminoxane, iso-pentyl-aluminoxane, neopentylaluminoxane, or mixtures thereof.
  • MAO methylaluminoxane
  • MMAO modified methylaluminoxane
  • n-propylaluminoxane iso-propyl-aluminoxane
  • the preferred co-catalyst is modified methylaluminoxane.
  • the synthesis of modified methylaluminoxane may be carried out in the presence of other trialkylaluminum compounds in addition to trimethylaluminum.
  • the products incorporate both methyl and alkyl groups from the added trialkylaluminum and are referred to as modified methyl aluminoxanes, MMAO.
  • the MMAO may be more soluble in nonpolar reaction media, more stable to storage, have enhanced performance as a cocatalyst, or any combination of these.
  • the performance of the resulting MMAO may be superior to either of the trialkylaluminum starting materials or to simple mixtures of the two starting materials.
  • the added trialkylaluminum may be triethylaluminum, triisobutylaluminum or triisooctylaluminum.
  • the co-catalyst is MMAO, wherein preferably about 25% of the methyl groups are replaced with iso-butyl groups.
  • the co-catalyst may be formed in situ in the reactor by providing the appropriate precursors into the reactor.
  • One or more solvents may be used in the reaction.
  • the solvents may be used to dissolve or suspend the catalyst or the co-catalyst and/ or keep the ethylene dissolved.
  • the solvent may be any solvent that can modify the solubility of any of these components or of reaction products. Suitable solvents include hydrocarbons, for example, alkanes, alkenes, cycloalkanes, and aromatics. Different solvents may be used in the process, for example, one solvent can be used for the catalyst and another for the co-catalyst. It is preferred for the solvent to have a boiling point that is not substantially similar to the boiling point of any of the alpha olefin products as this will make the product separation step more difficult. Aromatics
  • Aromatic solvents can be any solvent that contains an aromatic hydrocarbon, preferably having a carbon number of 6 to 20. These solvents may include pure aromatics, or mixtures of pure aromatics, isomers as well as heavier solvents, for example C9 and C10 solvents. Suitable aromatic solvents include benzene, toluene, xylene (including ortho-xylene, meta-xylene, para-xylene and mixtures thereof) and ethylbenzene.
  • Alkane solvents may be any solvent that contains an alkyl hydrocarbon. These solvents may include straight chain alkanes and branched or iso-alkanes having from 3 to 20 carbon atoms and mixtures of these alkanes. The alkanes may be cycloalkanes.
  • Suitable solvents include propane, isobutane, n-butane, butane (n-butane or a mixture of linear and branched C4 acyclic alkanes), pentane (n-pentane or a mixture of linear and branched acyclic alkanes), hexane (n-hexane or a mixture of linear and branched C6 acyclic alkanes), heptane (n-heptane or a mixture of linear and branched C7 acyclic alkanes), octane (n-octane or a mixture of linear and branched C8 acyclic alkanes) and isooctane.
  • Suitable solvents also include cyclohexane and methylcyclohexane.
  • the solvent comprises C6, C7 and C8 alkanes, that may include linear, branched and iso-alkanes.
  • the catalyst system may be formed by mixing together the ligand, the metal, the co-catalyst and optional additional compounds in a solvent.
  • the feed may be present in this step.
  • the catalyst system may be prepared by contacting the metal or metal compound with the ligand to form a catalyst precursor mixture and then contacting the catalyst precursor mixture with the co-catalyst in the reactor to form the catalyst system.
  • the catalyst system may be prepared outside of the reactor vessel and fed into the reactor vessel. In other embodiments, the catalyst system may be formed in the reactor vessel by passing each of the components of the catalyst system separately into the reactor. In other embodiments, one or more catalyst precursors may be formed by combining at least two components outside of the reactor and then passing the one or more catalyst precursors into the reactor to form the catalyst system.
  • the co-catalyst is preferably fed into the reactor in a solvent, and the co-catalyst may be diluted to reduce the concentration of aluminum in the co-catalyst feed stream.
  • One co-catalyst, MMAO is typically available in 7 wt% aluminum solutions. This MMAO stream is preferably diluted before it is fed to the reaction zone. In one embodiment, the MMAO is diluted with additional solvent before it is loaded into the pump that will inject it into the reaction zone. In another embodiment, the MMAO is diluted with additional solvent and stored at that aluminum concentration for a period of time. The MMAO may then be further diluted before it is fed into the reaction zone.
  • the MMAO is diluted to a concentration of less than 2.5 wt% aluminum, preferably less than 1 wt% aluminum.
  • the MMAO may be further diluted to a concentration of less than 0.5 wt% aluminum, less than 0.25 wt% aluminum or less than 0.1 wt% aluminum.
  • the co-catalyst (MMAO) stream fed to the reaction zone may have an aluminum concentration of from 0.01 to 2 wt%, preferably of from 0.01 to 1 wt% aluminum, more preferably of from 0.01 to 0.5 wt% aluminum.
  • the co-catalyst stream may be even further diluted before it is fed to the reaction zone.
  • the co-catalyst (MMAO) stream fed to the reaction zone may have an aluminum concentration of from 200 ppmw to 20,000 ppmw, preferably of from 300 ppmw to 10,000 ppmw, more preferably of from 500 ppmw to 7,000 ppmw.
  • the solvent used for the dilution of the co-catalyst feed stream may be any of the solvents described above that are useful in this invention.
  • the solvent comprises xylene.
  • the oligomerization reaction is a reaction that converts the olefin feed in the presence of an oligomerization catalyst and a co-catalyst into a higher oligomer product stream.
  • the oligomerization reaction may be conducted over a range of temperatures of from -100 °C to 300 °C, preferably in the range of from 0 °C to 200 °C, and more preferably in the range of from 50 °C to 150 °C.
  • the oligomerization reaction may be conducted at a pressure of from 0.01 to 15 MPa and more preferably from 1 to 10 MPa.
  • the optimum conditions of temperature and pressure used for a specific catalyst system, to maximize the yield of oligomer, and to minimize the impact of competing reactions, for example dimerization and polymerization can be determined by one of ordinary skill in the art.
  • the temperature and pressure are selected to yield a product slate with a K-factor in the range of from 0.40 to 0.90, preferably in the range of from 0.45 to 0.80, more preferably in the range of from 0.5 to 0.7.
  • Residence times in the reactor of from 3 to 60 min have been found to be suitable, depending on the activity of the catalyst.
  • the reaction is carried out in the absence of air and moisture.
  • the oligomerization reaction can be carried out in the liquid phase or mixed gas-liquid phase, depending on the volatility of the feed and product olefins at the reaction conditions.
  • the oligomerization reaction may be carried out in a conventional fashion. It may be carried out in a stirred tank reactor, wherein solvent, olefin and catalyst or catalyst precursors are added continuously to a stirred tank and solvent, product, catalyst, and unused reactant are removed from the stirred tank with the product separated and the unused reactant recycled back to the stirred tank.
  • the oligomerization reaction may be carried out in a batch reactor, wherein the catalyst precursors and reactant olefin are charged to an autoclave or other vessel and after being reacted for an appropriate time, product is separated from the reaction mixture by conventional means, for example, distillation.
  • the oligomerization reaction may be carried out in a gas lift reactor.
  • This type of reactor has two vertical sections (a riser section and a downcomer section) and a gas separator at the top.
  • the gas feed ethylene
  • the gas feed is injected at the bottom of the riser section to drive circulation around the loop (up the riser section and down the downcomer section).
  • the oligomerization reaction may be carried out in a pump loop reactor.
  • This type of reactor has two vertical sections, and it uses a pump to drive circulation around the loop.
  • a pump loop reactor can be operated at a higher circulation rate than a gas lift reactor.
  • the oligomerization reaction may be carried out in a once-through reactor.
  • This type of reactor feeds the catalyst, co-catalyst, solvent and ethylene to the inlet of the reactor and/ or along the reactor length and the product is collected at the reactor outlet.
  • This type of reactor is a plug flow reactor.
  • the higher oligomers produced in the oligomerization reaction contains catalyst from the reaction step. To stop further reactions that can produce byproducts and other undesired components, it is important to deactivate the catalyst downstream from the reactor.
  • the catalyst is deactivated by addition of an acidic species having a pKA(aq) of less than 25.
  • the deactivated catalyst can then be removed by water washing in a liquid/liquid extractor.
  • the resulting alpha-olefins have a chain length of from 4 to 100 carbon atoms, preferably 4 to 30 carbon atoms and most preferably 4 to 20 carbon atoms.
  • the alpha-olefins are even- numbered alpha-olefins.
  • the product olefins can be recovered by distillation or other separation techniques depending on the intended use of the products.
  • the solvents) used in the reaction preferably have a boiling point that is different from the boiling point of any of the alpha-olefin products to make the separation easier.
  • the distillation steps comprise columns for separating ethylene and the main linear alpha olefin products, for example, butene, hexene, and octene.
  • the products produced by the process may be used in a number of applications.
  • the olefins produced by this process may have improved qualities as compared to olefins produced by other processes.
  • the butene, hexene and/ or octene produced may be used as a comonomer in making polyethylene.
  • the octene produced may be used to produce plasticizer alcohols.
  • the decene produced may be used to produce polyalphaolefins.
  • the dodecene and/ or tetradecene produced may be used to produce alkylbenzene and/ or detergent alcohols.
  • the hexadecene and/ or octadecene produced may be used to produce alkenyl succinates and/ or oilfield chemicals.
  • the C20+ products may be used to produce lubricant additives and/ or waxes.
  • a portion of any unreacted ethylene that is removed from the reactor with the products may be recycled to the reactor.
  • This ethylene may be recovered in the distillation steps used to separate the products.
  • the ethylene may be combined with the fresh ethylene feed ot it may be fed separately to the reactor.
  • a portion of any solvent used in the reaction may be recycled to the reactor.
  • the solvent may be recovered in the distillation steps used to separate the products. Examples
  • This example was conducted in a 600 mL stirred Parr reactor.
  • the reactor was fed ethylene, solvent, iron-ligand complex catalyst and MMAO co-catalyst continuously throughout the examples.
  • the runs were conducted at 65.6 °C.
  • the MMAO concentration shown in the Figure is the concentration after a first dilution step when the MMAO was loaded into the syringe pump. That MMAO stream was further diluted by a factor of 10 before it was injected into the reactor.
  • the amount of polymer was calculated by collecting a mass of polymer and normalizing it to the amount of ethylene consumed during the run. The numbers are reported as ppmw (mass of polymer/mass of ethylene consumed x (1x10 6 ).
  • the meltout polymer shown in the Figure for the different MMAO concentration runs is the polymer collected from the reactor after the run. This polymer was collected by passing xylene through the reaction zone and associated equipment, first at reaction temperature to remove residual AO’s and then twice at elevated temperatures to recover the polymer.

Abstract

A process for producing alpha-olefins comprising contacting an ethylene feed with an oligomerization catalyst system in an oligomerization reaction zone under oligomerization reaction conditions to produce a product stream comprising alpha-olefins wherein the catalyst system comprises an iron-ligand complex and a modified methyl aluminoxane (MMAO) co-catalyst wherein the co-catalyst feed stream to the reaction zone is diluted in a solvent to a concentration of less than 1 wt% aluminum in the co-catalyst feed stream.

Description

A PROCESS FOR PRODUCING ALPHA-OLEFINS
Field of the Invention
The invention relates to a process for producing alpha-olefins wherein the concentration of co-catalyst is controlled.
Background
The oligomerization of olefins, such as ethylene, produces butene, hexene, octene, and other valuable linear alpha olefins. Linear alpha olefins are a valuable comonomer for linear low-density polyethylene and high-density polyethylene. Such olefins are also valuable as a chemical intermediate in the production of plasticizer alcohols, fatty acids, detergent alcohols, polyalphaolefins, oil field drilling fluids, lubricant oil additives, linear alkylbenzenes, alkenylsuccinic anhydrides, alkyldimethylamines, dialkylmethylamines, alpha-olefin sulfonates, internal olefin sulfonates, chlorinated olefins, linear mercaptans, aluminum alkyls, alkyldiphenylether disulfonates, and other chemicals.
US 6,683,187 describes a bis(arylimino)pyridine ligand, catalyst precursors and catalyst systems derived from this ligand for ethylene oligomerization to form linear alpha olefins. The patent teaches the production of linear alpha olefins with a Schulz-Flory oligomerization product distribution. In such a process, a wide range of oligomers are produced, and the fraction of each olefin can be determined by calculation on the basis of the K-factor. The K-factor is the molar ratio of (Cn+2)/Cn, where n is the number of carbons in the linear alpha olefin product.
It would be advantageous to develop an improved process that would provide an oligomerization product distribution having a desired K-factor and product quality while limiting the polymer fouling in the reaction zone and associated equipment.
Summary of the Invention
The invention provides a process for producing alpha-olefins comprising contacting an ethylene feed with an oligomerization catalyst system in an oligomerization reaction zone under oligomerization reaction conditions to produce a product stream comprising alpha-olefins wherein the catalyst system comprises an iron-ligand complex and a modified methyl aluminoxane (MMAO) co-catalyst wherein the co-catalyst feed stream to the reaction zone is diluted in a solvent to a concentration of less than 1 wt% aluminum in the co-catalyst feed stream. The invention further provides a process for producing alpha-olefins comprising: a) preparing a co-catalyst stream by diluting, in a first dilution step, a modified methyl aluminoxane (MMAO) stream having a concentration of greater than 4 wt% aluminum in a first solvent to form a co-catalyst stream having a concentration of less than 1.5 wt% aluminum; and b) contacting an ethylene feed with an oligomerization catalyst system in an oligomerization reaction zone under oligomerization reaction conditions to produce a product stream comprising alpha-olefins wherein the catalyst system comprises an iron-ligand complex and the co-catalyst stream. he Drawings icts the results of Example 1
Figure imgf000004_0001
The process comprises converting an olefin feed into a higher oligomer product stream by contacting the feed with an oligomerization catalyst system and a co-catalyst in an oligomerization reaction zone under oligomerization conditions. In one embodiment, an ethylene feed may be contacted with an iron-ligand complex and modified methyl aluminoxane under oligomerization conditions to produce a product slate of alpha olefins having a specific k-factor.
Olefin Feed
The olefin feed to the process comprises ethylene. The feed may also comprise olefins having from 3 to 8 carbon atoms. The ethylene may be pretreated to remove impurities, especially impurities that impact the reaction, product quality or damage the catalyst. In one embodiment, the ethylene may be dried to remove water. In another embodiment, the ethylene may be treated to reduce the oxygen content of the ethylene. Any pretreatment method known to one of ordinary skill in the art can be used to pretreat the feed.
Oligomerization Catalyst
The oligomerization catalyst system may comprise one or more oligomerization catalysts as described further herein. The oligomerization catalyst is a metal-ligand complex that is effective for catalyzing an oligomerization process. The ligand may comprise a bis(arylimino)pyridine compound, a bis(alkylimino)pyridine compound or a mixed aryl-alkyl iminopyridine compound. In one embodiment, the ligand comprises a pyridine bis(imine) group. The ligand may be a bis(arylimino)pyridine compound having the structure of Formula I.
Figure imgf000005_0001
Ri, R2 and R3 are each independently hydrogen, optionally substituted hydrocarbyl, hydroxo, cyano or an inert functional group. R4 and R5 are each independently hydrogen, optionally substituted hydrocarbyl, hydroxo, cyano or an inert functional group. R6 and R7 are each independently an aryl group as shown in Formula II. The two aryl groups (R6 and R7) on one ligand may be the same or different.
Figure imgf000005_0002
Rs, R9, R10, R11, R12 are each independently hydrogen, optionally substituted hydrocarbyl, hydroxo, cyano, an inert functional group, fluorine, or chlorine. Any two of R1-R3, and R9-R11 vicinal to one another taken together may form a ring. R12 may be taken together with R11, R4 or R5 to form a ring. R2 and R4 or R3 and R5 may be taken together to form a ring. A hydrocarbyl group is a group containing only carbon and hydrogen. The number of carbon atoms in this group is preferably in the range of from 1 to 30.
An optionally substituted hydrocarbyl is a hydrocarbyl group that optionally contains one or more “inert” heteroatom-containing functional groups. Inert means that the functional groups do not interfere to any substantial degree with the oligomerization process. Examples of these inert groups include fluoride, chloride, iodide, stannanes, ethers, hydroxides, alkoxides and amines with adequate steric shielding. The optionally substituted hydrocarbyl group may include primary, secondary and tertiary carbon atoms groups.
Primary carbon atom groups are a -CH2-R group wherein R may be hydrogen, an optionally substituted hydrocarbyl or an inert functional group. Examples of primary carbon atom groups include -CH3, -C2H5, -CH2CI, -CH2OCH3, -CIHLN^Hs^, and -CH2Ph. Secondary carbon atom groups are a -CH-R2 or -CH (R)(R') group wherein R and R' may be optionally substituted hydrocarbyl or an inert functional group. Examples of secondary carbon atom groups include - CH(CH3)2, -CHCI2, -CHPI12, -CH(CH3)(OCH3), -CH=CH2, and cyclohexyl. Tertiary carbon atom groups are a -C-(R)(R')(R") group wherein R, R', and R" may be optionally substituted hydrocarbyl or an inert functional group. Examples of tertiary carbon atom groups include -C(CH3)3, -CCI3, - CΞCPh, 1-Adamantyl, and -C(CH3)2(OCH3)
An inert functional group is a group other than optionally substituted hydrocarbyl that is inert under the oligomerization conditions. Inert has the same meaning as provided above. Examples of inert functional groups include halide, ethers, and amines, in particular tertiary amines.
Substituent variations of R1-R5, R8-R12 and R13-R17 may be selected to enhance other properties of the ligand, for example, solubility in non-polar solvents. Several embodiments of possible oligomerization catalysts are further described below having the structure shown in Formula 3.
Figure imgf000007_0001
In one embodiment, a ligand of Formula III is provided wherein R1-R5, R9-R11 and R14-R16, are hydrogen; and R8, R12, R13 and R17 are fluorine.
In one embodiment, a ligand of Formula III is provided wherein R1-R5, Rs, Rio, R12, R14 and R16 are hydrogen; R13, R15 and R17 are methyl and R9 and R11 are tert-butyl.
In one embodiment, a ligand of Formula III is provided wherein R1-R5, Rs, R12, R14 and R16 are hydrogen; R13, R15 and R17 are methyl; R9 and R11 are phenyl and R10 is an alkoxy.
In one embodiment, a ligand of Formula III is provided wherein R1-R5, R8, R10, R11 and R14- R16 are hydrogen; R9 and R12 are methyl; and R13 and R17 are fluorine.
In one embodiment, a ligand of Formula III is provided wherein R1-R3, R9-R11 and R14-R16, are hydrogen; R4 and R5 are phenyl and Rs, R12, RB and R17 are fluorine.
In one embodiment, a ligand of Formula III is provided wherein R1-R5, Rs-Rg, R11-R12, R13- R14 and R16-R17 are hydrogen; and R10 and RB are fluorine.
In one embodiment, a ligand of Formula III is provided wherein R1-R5, R8, R10, R12, R13, R15 and R17 are hydrogen; and R9, R11, R14 and RB are fluorine.
In one embodiment, a ligand of Formula III is provided wherein R1-R5, R9, R11-R12, R14 and R16-R17 are hydrogen; and Rs, R10, R13 and RB are fluorine.
In one embodiment, a ligand of Formula III is provided wherein R1-R5, Rs-Rg, R11-R12, R14 and R16 are hydrogen; R10 is tert-butyl; and R13, R15 and R17 are methyl. In one embodiment, a ligand of Formula III is provided wherein R1-R5, R9-R12, R14 and R16, are hydrogen; R8 is fluorine; and R13, R15 and R17 are methyl.
In one embodiment, a ligand of Formula III is provided wherein R1-R5, R9-R12, R13, Ris and R17 are hydrogen; R8 is tert-butyl; and R14 and R17, are methyl.
In one embodiment, a ligand of Formula III is provided wherein R1-R5, R9-R12, R13-R14 and R16-R17 are hydrogen; and Rs and R15 are tert-butyl.
In one embodiment, a ligand of Formula III is provided wherein R1-R5, R8-R10, R13-R14 and R16-R17 are hydrogen; R15 is tert-butyl; and R11 and R12 are taken together to form an aryl group.
In one embodiment, a ligand of Formula III is provided wherein R1-R5, R9-R12, R14-R17 are hydrogen; and R8 and R13 are methyl.
In one embodiment, a ligand of Formula III is provided wherein R1-R5, R8-R9.R11-R12, R14 and Ri6 are hydrogen; R10 is fluorine; and R13, R15 and R17 are methyl.
In one embodiment, a ligand of Formula III is provided wherein R1-R5, R8, R10, R12, R14 and R16 are hydrogen; R9 and R11 are fluorine; and R13, R15 and R17 are methyl.
In one embodiment, a ligand of Formula III is provided wherein R1-R5, R8-R9,R11-R12, R14 and R16 ARe hydrogen; R10 is an alkoxy; and R13, R15 and R17 are methyl.
In one embodiment, a ligand of Formula III is provided wherein R1-R5, R8-R9.R11-R12, R14 and R16 are hydrogen; R10 is a silyl ether; and R13, R15 and R17 are methyl.
In one embodiment, a ligand of Formula III is provided wherein R1-R5, Rs, R10, R12, Ru-R16 are hydrogen; R9 and R11 are methyl; and R13 and R17 are ethyl.
In one embodiment, a ligand of Formula III is provided wherein R1-R5, R9-R12, and R14-R17 are hydrogen; and R8 and R13 are ethyl.
In one embodiment, a ligand of Formula III is provided wherein R1-R5, R9-R11 and R14-R16 are hydrogen; and R8, R12, R13 and R17 are chlorine.
In one embodiment, a ligand of Formula III is provided wherein R1-R5, R9, R11, R14 and R16 are hydrogen; and R8, R10, R12, R13, R15 and R17 are methyl.
In one embodiment, a ligand of Formula III is provided wherein R1-R5, R9-R10, R12, R14-R15 and R17 are hydrogen; and R8, R11, R13 and Rie are methyl.
In one embodiment, a ligand of Formula III is provided wherein R1-R17 are hydrogen.
In one embodiment, a ligand of Formula III is provided wherein R1-R5, Rs, R10, R12, R13, R15 and R17 are hydrogen; and R9, R11, R14 and R16 are tert-butyl. In one embodiment, a ligand of Formula III is provided wherein R1-R5, R8-R12, R14 and R16, are hydrogen; and R13, R15 and R17 are methyl.
In one embodiment, a ligand of Formula III is provided wherein R1-R5, R9, R11-R12, R14 and R16 are hydrogen; R8 and R10 are fluorine; and RB, RI, and R17 are methyl.
In one embodiment, a ligand of Formula III is provided wherein R1-R5, R9, R11-R12, R14 and R16-R17 are hydrogen; and Rs, R10, R13 and R15 are methyl.
In one embodiment, a ligand of Formula III is provided wherein R1-R5, R9-R11 and R14-RB are hydrogen; R8 and R12 are chlorine; and R13 and R17 are fluorine.
In one embodiment, a ligand of Formula III is provided wherein R1-R5, R8, R10, R12, R14 and RB are hydrogen; and R9, R11, R13, R15 and R17 are methyl.
In one embodiment, a ligand of Formula III is provided wherein R1-R5, R9-R11 and R13-R14 and R16-R17 are hydrogen; R8 and R12 are chlorine; and R15 is tert-butyl.
In one embodiment, a ligand of Formula III is provided wherein R1-R5, R9-R11 and R13-R17 are hydrogen; and Rs and R12 are chlorine.
In one embodiment, a ligand of Formula III is provided wherein R1-R5, R9-R12, and R14-R17 are hydrogen; and R8 and R13 are chlorine.
In one embodiment, a ligand of Formula III is provided wherein R1-R5, R9, R11-R12, R14 and R16-R17 are hydrogen; and R8, R10, R13 and RB are chlorine.
In one embodiment, a ligand of Formula III is provided wherein R1-R5, R9, R11-R12, and R14, and R16-Ri7 are hydrogen; R10 and R15 are methyl; and R8 and R13 are chlorine.
In one embodiment, a ligand of Formula III is provided wherein R1-R5, R9-R11 and R13-R14 and R16-Ri7 are hydrogen; R15 is fluorine; and R8 and R12 are chlorine.
In one embodiment, a ligand of Formula III is provided wherein R1-R5, R8-R9, R11-R12, R14- R15 and R17 are hydrogen; R10 is tert-butyl; and R13 and R16 are methyl.
In one embodiment, a ligand of Formula III is provided wherein R1-R5, R9-R11, R14 and RB are hydrogen; R8 and R12 are fluorine; and R13, R15 and R17 are methyl.
In one embodiment, a ligand of Formula III is provided wherein R1-R5, R9-R10, R12, R14-R15 and R17 are hydrogen; R8 and R13 are methyl; and R11 and R16 are isopropyl.
In one embodiment, a ligand of Formula III is provided wherein R1-R5, R9-R12 and R14-R16 are hydrogen; R8 is ethyl; and R13 and R17 are fluorine.
In one embodiment, a ligand of Formula III is provided wherein R2-R5, R9-R10, R12, R14-R15 and R17 are hydrogen; R1 is methoxy; and R8, R11, R13 and RB are methyl. In one embodiment, a ligand of Formula III is provided wherein R2-R5, R8-R12, R14 and R16, are hydrogen; Ri is methoxy; and R13, R15 and R17 are methyl.
In one embodiment, a ligand of Formula III is provided wherein R2-R5, R9-R12, and R14-R17 are hydrogen; Ri is methoxy; and R8 and R13 are ethyl.
In one embodiment, a ligand of Formula III is provided wherein R2-R5, R9, R11-R12, R14 and R16-R17 are hydrogen; Ri is tert-butyl; and Rs, R10, R13 and Ris are methyl.
In one embodiment, a ligand of Formula III is provided wherein R2-R5, R8-R12, R14 and R16 are hydrogen; Ri is tert-butyl; and R13, R15 and R17 are methyl.
In one embodiment, a ligand of Formula III is provided wherein R2-R5, R9, R11, R14 and R16, are hydrogen; Ri is methoxy; and Rs, R10, R12, R13, Ris and R17 are methyl.
In one embodiment, a ligand of Formula III is provided wherein R2-R5, R9, R11, R14 and RR, are hydrogen; Ri is alkoxy; and Rs, R10, R12, R13, R15 and R17 are methyl.
In one embodiment, a ligand of Formula III is provided wherein R2-R5, R9, R11, R14 and Rie are hydrogen; Ri is tert-butyl; and Rs, R10, R12, R13, R15 and R17 are methyl.
In another embodiment, the ligand may be a compound having the structure of Formula I, wherein one of R6 and R7 is aryl as shown in Formula II and one of Re and R7 is pyridyl as shown in Formula IV. In another embodiment, Re and R7 may be pyrrolyl.
Figure imgf000010_0001
R1, R2 and R3 are each independently hydrogen, optionally substituted hydrocarbyl, hydroxo, cyano or an inert functional group. R4 and R5 are each independendy hydrogen, optionally substituted hydrocarbyl, hydroxo, cyano or an inert functional group. Rs-Ri2 and R18-R21 are each independendy hydrogen, optionally substituted hydrocarbyl, hydroxo, cyano, an inert functional group, fluorine, or chlorine. Any two of R1-R3, and R9-R11 vicinal to one another taken together may form a ring. R12 may be taken together with R11, R4 or R5 to form a ring. R2 and R4 or R3 and R5 may be taken together to form a ring.
Figure imgf000011_0001
In one embodiment, a ligand of Formula V is provided wherein R1-R5, R9, R11 and R18-R21 are hydrogen; and R8, R10, and R12 are methyl.
In one embodiment, a ligand of Formula V is provided wherein R1-R5, R9-R11 and R18-R21 are hydrogen; and R8 and R12 are ethyl.
In another embodiment, the ligand may be a compound having the structure of Formula I, wherein one of R6 and R7 is aryl as shown in Formula II and one of Re and R7 is cyclohexyl as shown in Formula VI. In another embodiment, Re and R7 may be cyclohexyl.
Figure imgf000012_0002
Ri, R2 and R3 are each independently hydrogen, optionally substituted hydrocarbyl, hydroxo, cyano or an inert functional group. R4 and R5 are each independently hydrogen, optionally substituted hydrocarbyl, hydroxo, cyano or an inert functional group. Rs-Ri2 and R22-R26 are each independently hydrogen, optionally substituted hydrocarbyl, hydroxo, cyano, an inert functional group, fluorine, or chlorine. Any two of R1-R3, and R9-R11 vicinal to one another taken together may form a ring. R12 may be taken together with R11, R4 or R5 to form a ring. R2 and R4 or R3 and R5 may be taken together to form a ring.
Figure imgf000012_0001
In one embodiment, a ligand of Formula VII is provided wherein R1-R5, R9, R11 and R22-R26 are hydrogen; and R8, R10, and R12 are methyl. In another embodiment, R6 and R7 may be adamantyl or another cycloalkane.
In another embodiment, the ligand may be a compound having the structure of Formula I, wherein one of R6 and R7 is aryl as shown in Formula II and one of Re and R7 is ferrocenyl as shown in Formula VIII. In another embodiment, Re and R7 may be ferrocenyl.
(VIII)
Figure imgf000013_0001
Ri, R2 and R3 are each independently hydrogen, optionally substituted hydrocarbyl, hydroxo, cyano or an inert functional group. R4 and R5 are each independently hydrogen, optionally substituted hydrocarbyl, hydroxo, cyano or an inert functional group. R8-Ri2 and R27 -R35 are each independently hydrogen, optionally substituted hydrocarbyl, hydroxo, cyano, an inert functional group, fluorine, or chlorine. Any two of R1-R3, and R9-R11 vicinal to one another taken together may form a ring. R12 may be taken together with R11, R4 or R5 to form a ring. R2 and R4 or R3 and Rs may be taken together to form a ring.
Figure imgf000014_0001
embodiment, a ligand of Formula IX is provided wherein R1-R5, R9, R11 and R27 -R35 are hydrogen; and R8, R10, and R12 are methyl.
In one embodiment, a ligand of Formula IX is provided wherein R1-R5, R9-R11, and R27 -R35 are hydrogen; and Rs and R12 are ethyl.
In another embodiment, the ligand may be a bis(alkylamino)pyridine. The alkyl group may have from 1 to 50 carbon atoms. The alkyl group may be a primary, secondary, or tertiary alkyl group. The alkyl group may be selected from the group consisting of methyl, ethyl, propyl, isopropyl, butyl, sec-butyl, isobutyl, and tert-butyl. The alkyl group may be selected from any n-alkyl or structural isomer of an n-alkyl having 5 or more carbon atoms, e.g., n-pentyl; 2-methyl-butyl; and 2,2-dimethylpropyl.
In another embodiment, the ligand may be an alkyl-alkyl iminopyridine, where the two alkyl groups are different. Any of the alkyl groups described above as being suitable for a bis (alkylamino) pyridine are also suitable for this alkyl-alkyl iminopyridine.
In another embodiment, the ligand may be an aryl alkyl iminopyridine. The aryl group may be of a similar nature to any of the aryl groups described with respect to the bis(arylimino)pyridine compound and the alkyl group may be of a similar nature to any of the alkyl groups described with respect to the bis(alkylamino)pyridine compound. In addition to the ligand structures described hereinabove, any structure that combines features of any two or more of these ligands can be a suitable ligand for this process. Further, the oligomerization catalyst system may comprise a combination of one or more of any of the described oligomerizations catalysts.
The ligand feedstock may contain between 0 and 10 wt.% bisimine pyridine impurity, preferably 0-1 wt.% bisimine pyridine impurity, most preferably 0-0.1 wt.% bisimine pyridine impurity. This impurity is believed to cause the formation of polymers in the reactor, so it is preferable to limit the amount of this impurity that is present in the catalyst system.
In one embodiment, the bisimine pyridine impurity is a ligand of Formula II in which three of R8, R12, R13, and R17 are each independently optionally substituted hydrocarbyl.
In one embodiment, the bisimine pyridine impurity is a ligand of Formula II in which all four of R8, R12, R13, and R17 are each independently optionally substituted hydrocarbyl.
Metal
The metal may be a transition metal, and the metal is preferably present as a compound having the formula MX„, where M is the metal, X is a monoanion and n represents the number of monoanions (and the oxidation state of the metal).
The metal can comprise any Group 4-10 transition metal. The metal can be selected from the group consisting of titanium, zirconium, hafnium, vanadium, niobium, tantalum, chromium, molybdenum, tungsten, manganese, iron, cobalt, nickel, palladium, platinum, ruthenium and rhodium. In one embodiment, the metal is cobalt or iron. In a preferred embodiment, the metal is iron. The metal of the metal compound can have any positive formal oxidation state of from 2 to 6 and is preferably 2 or 3.
The monoanion may comprise a halide, a carboxylate, a [3-diketonate, a hydrocarboxide, an optionally substituted hydrocarbyl, an amide or a hydride. The hydrocarboxide may be an alkoxide, an aryloxide or an aralkoxide. The halide may be fluorine, chlorine, bromine or iodine.
The carboxylate may be any Ci to C20 carboxylate. The carboxylate may be acetate, a propionate, a butyrate, a pentanoate, a hexanoate, a heptanoate, an octanoate, a nonanoate, a decanoate, an undecanoate, or a dodecanoate. In addition, the carboxylate may be 2-ethylhexanoate or trifluoroacetate.
The β -diketonate may be any C1 to C20 β -diketonate. The β -diketonate may be acetylacetonate, hexafluoroacetylacetonate, or benzoylacetonate. The hydrocarboxide may be any C1 to C20 hydtocarboxide. The hydtocatboxide may be a Ci to C20 alkoxide, or a C6 to C20 aryloxide. The alkoxide may be methoxide, ethoxide, a propoxide (e.g., iso-propoxide) or a butoxide (e.g., tert-butoxide). The aryloxide may be phenoxide
Generally, the number of monoanions equals the formal oxidation state of the metal atom.
Preferred embodiments of metal compounds include iron acetylacetonate, iron chloride, and iron bis(2-ethylhexanoate). In addition to the oligomerization catalyst, a co-catalyst is used in the oligomerization reaction.
Co-catalyst
The co-catalyst may be a compound that is capable of transferring an optionally substituted hydrocarbyl or hydride group to the metal atom of the catalyst and is also capable of abstracting an X" group from the metal atom M. The co-catalyst may also be capable of serving as an electron transfer reagent or providing sterically hindered counterions for an active catalyst.
The co-catalyst may comprise two compounds, for example one compound that is capable of transferring an optionally substituted hydrocarbyl or hydride group to metal atom M and another compound that is capable of abstracting an X group from metal atom M. Suitable compounds for transferring an optionally substituted hydrocarbyl or hydride group to metal atom M include organoaluminum compounds, alkyl lithium compounds, Grignards, alkyl tin and alkyl zinc compounds. Suitable compounds for abstracting an X group from metal atom M include strong neutral Lewis acids such as SbF5, BF3 and Ar3B wherein Ar is a strong electron- withdrawing aryl group such as C6F5 or 3,5-(CF3)2C6H3. A neutral Lewis acid donor molecule is a compound which may suitably act as a Lewis base, such as ethers, amines, sulfides and organic nitrites.
The co-catalyst is preferably an organoaluminum compound which may comprise an alkylaluminum compound, an aluminoxane or a combination thereof.
The alkylaluminum compound may be trialkylaluminum, an alkylaluminum halide, an alkylaluminum alkoxide or a combination thereof. The alkyl group of the alkylaluminum compound may be any Ci to C20 alkyl group. The alkyl group may be methyl, ethyl, propyl, butyl, pentyl, hexyl, heptyl or octyl. The alkyl group may be an iso-alkyl group.
The trialkylaluminum compound may comprise trimethylaluminum (TMA), triethylaluminum (TEA), tripropylaluminum, tributylaluminum, tripentylaluminum, trihexylaluminum, triheptylaluminum, trioctylaluminum or mixtures thereof. The trialkylaluminum compound may comprise tri-n-propylaluminum (TNPA), tri-n-butylaluminum (TNBA), tri-iso- butylaluminum (TIB A), tri-n-hexylaluminum, tri-n-octylaluminum (TNOA). The halide group of the alkylaluminum halide may be chloride, bromide or iodide. The alkylaluminum halide may be diethylaluminum chloride, diethylaluminum bromide, ethylaluminum dichloride, ethylaluminum sesquichloride or mixtures thereof.
The alkoxide group of the alkylaluminum alkoxide may be any Ci to C20 alkoxy group. The alkoxy group may be methoxy, ethoxy, propoxy, butoxy, pentoxy, hexoxy, heptoxy or octoxy. The alkylaluminum alkoxide may be diethylaluminum ethoxide.
The aluminoxane compound may be methylaluminoxane (MAO), ethylaluminoxane, modified methylaluminoxane (MMAO), n-propylaluminoxane, iso-propyl-aluminoxane, n- butylaluminoxane, sec-butylaluminoxane, iso-butylaluminoxane, t-butylaluminoxane, 1-pentyl- aluminoxane, 2-pentyl-aluminoxane, 3-pentyl-aluminoxane, iso-pentyl-aluminoxane, neopentylaluminoxane, or mixtures thereof.
The preferred co-catalyst is modified methylaluminoxane. The synthesis of modified methylaluminoxane may be carried out in the presence of other trialkylaluminum compounds in addition to trimethylaluminum. The products incorporate both methyl and alkyl groups from the added trialkylaluminum and are referred to as modified methyl aluminoxanes, MMAO. The MMAO may be more soluble in nonpolar reaction media, more stable to storage, have enhanced performance as a cocatalyst, or any combination of these. The performance of the resulting MMAO may be superior to either of the trialkylaluminum starting materials or to simple mixtures of the two starting materials. The added trialkylaluminum may be triethylaluminum, triisobutylaluminum or triisooctylaluminum. In one embodiment, the co-catalyst is MMAO, wherein preferably about 25% of the methyl groups are replaced with iso-butyl groups.
In one embodiment, the co-catalyst may be formed in situ in the reactor by providing the appropriate precursors into the reactor.
Solvent
One or more solvents may be used in the reaction. The solvents) may be used to dissolve or suspend the catalyst or the co-catalyst and/ or keep the ethylene dissolved. The solvent may be any solvent that can modify the solubility of any of these components or of reaction products. Suitable solvents include hydrocarbons, for example, alkanes, alkenes, cycloalkanes, and aromatics. Different solvents may be used in the process, for example, one solvent can be used for the catalyst and another for the co-catalyst. It is preferred for the solvent to have a boiling point that is not substantially similar to the boiling point of any of the alpha olefin products as this will make the product separation step more difficult. Aromatics
Aromatic solvents can be any solvent that contains an aromatic hydrocarbon, preferably having a carbon number of 6 to 20. These solvents may include pure aromatics, or mixtures of pure aromatics, isomers as well as heavier solvents, for example C9 and C10 solvents. Suitable aromatic solvents include benzene, toluene, xylene (including ortho-xylene, meta-xylene, para-xylene and mixtures thereof) and ethylbenzene.
Alkanes
Alkane solvents may be any solvent that contains an alkyl hydrocarbon. These solvents may include straight chain alkanes and branched or iso-alkanes having from 3 to 20 carbon atoms and mixtures of these alkanes. The alkanes may be cycloalkanes. Suitable solvents include propane, isobutane, n-butane, butane (n-butane or a mixture of linear and branched C4 acyclic alkanes), pentane (n-pentane or a mixture of linear and branched acyclic alkanes), hexane (n-hexane or a mixture of linear and branched C6 acyclic alkanes), heptane (n-heptane or a mixture of linear and branched C7 acyclic alkanes), octane (n-octane or a mixture of linear and branched C8 acyclic alkanes) and isooctane. Suitable solvents also include cyclohexane and methylcyclohexane. In one embodiment, the solvent comprises C6, C7 and C8 alkanes, that may include linear, branched and iso-alkanes.
Catalyst System
The catalyst system may be formed by mixing together the ligand, the metal, the co-catalyst and optional additional compounds in a solvent. The feed may be present in this step.
In one embodiment, the catalyst system may be prepared by contacting the metal or metal compound with the ligand to form a catalyst precursor mixture and then contacting the catalyst precursor mixture with the co-catalyst in the reactor to form the catalyst system.
In some embodiments, the catalyst system may be prepared outside of the reactor vessel and fed into the reactor vessel. In other embodiments, the catalyst system may be formed in the reactor vessel by passing each of the components of the catalyst system separately into the reactor. In other embodiments, one or more catalyst precursors may be formed by combining at least two components outside of the reactor and then passing the one or more catalyst precursors into the reactor to form the catalyst system.
The co-catalyst is preferably fed into the reactor in a solvent, and the co-catalyst may be diluted to reduce the concentration of aluminum in the co-catalyst feed stream. One co-catalyst, MMAO, is typically available in 7 wt% aluminum solutions. This MMAO stream is preferably diluted before it is fed to the reaction zone. In one embodiment, the MMAO is diluted with additional solvent before it is loaded into the pump that will inject it into the reaction zone. In another embodiment, the MMAO is diluted with additional solvent and stored at that aluminum concentration for a period of time. The MMAO may then be further diluted before it is fed into the reaction zone.
In one embodiment, the MMAO is diluted to a concentration of less than 2.5 wt% aluminum, preferably less than 1 wt% aluminum. The MMAO may be further diluted to a concentration of less than 0.5 wt% aluminum, less than 0.25 wt% aluminum or less than 0.1 wt% aluminum. The co-catalyst (MMAO) stream fed to the reaction zone may have an aluminum concentration of from 0.01 to 2 wt%, preferably of from 0.01 to 1 wt% aluminum, more preferably of from 0.01 to 0.5 wt% aluminum.
The co-catalyst stream may be even further diluted before it is fed to the reaction zone. The co-catalyst (MMAO) stream fed to the reaction zone may have an aluminum concentration of from 200 ppmw to 20,000 ppmw, preferably of from 300 ppmw to 10,000 ppmw, more preferably of from 500 ppmw to 7,000 ppmw.
The solvent used for the dilution of the co-catalyst feed stream may be any of the solvents described above that are useful in this invention. In one embodiment, the solvent comprises xylene. Reaction Conditions
The oligomerization reaction is a reaction that converts the olefin feed in the presence of an oligomerization catalyst and a co-catalyst into a higher oligomer product stream.
Temperature
The oligomerization reaction may be conducted over a range of temperatures of from -100 °C to 300 °C, preferably in the range of from 0 °C to 200 °C, and more preferably in the range of from 50 °C to 150 °C.
Pressure
The oligomerization reaction may be conducted at a pressure of from 0.01 to 15 MPa and more preferably from 1 to 10 MPa.
The optimum conditions of temperature and pressure used for a specific catalyst system, to maximize the yield of oligomer, and to minimize the impact of competing reactions, for example dimerization and polymerization can be determined by one of ordinary skill in the art. The temperature and pressure are selected to yield a product slate with a K-factor in the range of from 0.40 to 0.90, preferably in the range of from 0.45 to 0.80, more preferably in the range of from 0.5 to 0.7. Residence Time
Residence times in the reactor of from 3 to 60 min have been found to be suitable, depending on the activity of the catalyst. In one embodiment, the reaction is carried out in the absence of air and moisture.
Gas Phase, Uquid Phase or Mixed Gas-Liquid Phase
The oligomerization reaction can be carried out in the liquid phase or mixed gas-liquid phase, depending on the volatility of the feed and product olefins at the reaction conditions.
Reactor type
The oligomerization reaction may be carried out in a conventional fashion. It may be carried out in a stirred tank reactor, wherein solvent, olefin and catalyst or catalyst precursors are added continuously to a stirred tank and solvent, product, catalyst, and unused reactant are removed from the stirred tank with the product separated and the unused reactant recycled back to the stirred tank.
In another embodiment, the oligomerization reaction may be carried out in a batch reactor, wherein the catalyst precursors and reactant olefin are charged to an autoclave or other vessel and after being reacted for an appropriate time, product is separated from the reaction mixture by conventional means, for example, distillation.
In another embodiment, the oligomerization reaction may be carried out in a gas lift reactor. This type of reactor has two vertical sections (a riser section and a downcomer section) and a gas separator at the top. The gas feed (ethylene) is injected at the bottom of the riser section to drive circulation around the loop (up the riser section and down the downcomer section).
In another embodiment, the oligomerization reaction may be carried out in a pump loop reactor. This type of reactor has two vertical sections, and it uses a pump to drive circulation around the loop. A pump loop reactor can be operated at a higher circulation rate than a gas lift reactor.
In another embodiment, the oligomerization reaction may be carried out in a once-through reactor. This type of reactor feeds the catalyst, co-catalyst, solvent and ethylene to the inlet of the reactor and/ or along the reactor length and the product is collected at the reactor outlet. One example of this type of reactor is a plug flow reactor. Catalyst Deactivation
The higher oligomers produced in the oligomerization reaction contains catalyst from the reaction step. To stop further reactions that can produce byproducts and other undesired components, it is important to deactivate the catalyst downstream from the reactor.
In one embodiment, the catalyst is deactivated by addition of an acidic species having a pKA(aq) of less than 25. The deactivated catalyst can then be removed by water washing in a liquid/liquid extractor.
Product Separation
The resulting alpha-olefins have a chain length of from 4 to 100 carbon atoms, preferably 4 to 30 carbon atoms and most preferably 4 to 20 carbon atoms. The alpha-olefins are even- numbered alpha-olefins.
The product olefins can be recovered by distillation or other separation techniques depending on the intended use of the products. The solvents) used in the reaction preferably have a boiling point that is different from the boiling point of any of the alpha-olefin products to make the separation easier.
In one embodiment, the distillation steps comprise columns for separating ethylene and the main linear alpha olefin products, for example, butene, hexene, and octene.
Product qualities and characteristics
The products produced by the process may be used in a number of applications. The olefins produced by this process may have improved qualities as compared to olefins produced by other processes. In one embodiment, the butene, hexene and/ or octene produced may be used as a comonomer in making polyethylene. In one embodiment, the octene produced may be used to produce plasticizer alcohols. In one embodiment, the decene produced may be used to produce polyalphaolefins. In one embodiment, the dodecene and/ or tetradecene produced may be used to produce alkylbenzene and/ or detergent alcohols. In one embodiment, the hexadecene and/ or octadecene produced may be used to produce alkenyl succinates and/ or oilfield chemicals. In one embodiment, the C20+ products may be used to produce lubricant additives and/ or waxes.
Recycle
A portion of any unreacted ethylene that is removed from the reactor with the products may be recycled to the reactor. This ethylene may be recovered in the distillation steps used to separate the products. The ethylene may be combined with the fresh ethylene feed ot it may be fed separately to the reactor.
A portion of any solvent used in the reaction may be recycled to the reactor. The solvent may be recovered in the distillation steps used to separate the products. Examples
Example 1
This example was conducted in a 600 mL stirred Parr reactor. The reactor was fed ethylene, solvent, iron-ligand complex catalyst and MMAO co-catalyst continuously throughout the examples. The runs were conducted at 65.6 °C. The MMAO concentration shown in the Figure is the concentration after a first dilution step when the MMAO was loaded into the syringe pump. That MMAO stream was further diluted by a factor of 10 before it was injected into the reactor.
The amount of polymer was calculated by collecting a mass of polymer and normalizing it to the amount of ethylene consumed during the run. The numbers are reported as ppmw (mass of polymer/mass of ethylene consumed x (1x106). The meltout polymer shown in the Figure for the different MMAO concentration runs is the polymer collected from the reactor after the run. This polymer was collected by passing xylene through the reaction zone and associated equipment, first at reaction temperature to remove residual AO’s and then twice at elevated temperatures to recover the polymer.

Claims

1. A process for producing alpha-olefins comprising contacting an ethylene feed with an oligomerization catalyst system in an oligomerization reaction zone under oligomerization reaction conditions to produce a product stream comprising alpha-olefins wherein the catalyst system comprises an iron-ligand complex and a modified methyl aluminoxane (MMAO) co-catalyst wherein the co-catalyst feed stream to the reaction zone is diluted in a solvent to a concentration of less than 1 wt% aluminum in the co-catalyst feed stream.
2. The process of claim 1 wherein the concentration of MMAO is less than 0.5 wt% aluminum in the co-catalyst feed stream.
3. The process of any of claims 1-2 wherein the concentration of MMAO is less than 0.25 wt% aluminum in the co-catalyst feed stream.
4. The process of any of claims 1-3 wherein the concentration of MMAO is less than 0.1 wt% aluminum in the co-catalyst feed stream.
5. The process of any of claims 1-4 wherein the solvent comprises one or more alkanes and/ or aromatics.
6. The process of any of claims 1-5 wherein the solvent comprises xylene.
7. A process for producing alpha-olefins comprising: a. preparing a co-catalyst stream by diluting, in a first dilution step, a modified methyl aluminoxane (MMAO) stream having a concentration of greater than 4 wt% aluminum in a first solvent to form a co-catalyst stream having a concentration of less than 1.5 wt% aluminum; and b. contacting an ethylene feed with an oligomerization catalyst system in an oligomerization reaction zone under oligomerization reaction conditions to produce a product stream comprising alpha-olefins wherein the catalyst system comprises an iron-ligand complex and the co-catalyst stream.
8. The process of claim 7 wherein the co-catalyst stream is further diluted, in a second dilution step, in a second solvent to a concentration of less than 0.5 wt% aluminum before step b).
9. The process of claim 7 wherein the co-catalyst stream is further diluted, in a second dilution step, in a second solvent to a concentration of less than 0.1 wt% aluminum before step b).
10. The process of claim 7 wherein the co-catalyst stream is further diluted, in a second dilution step, in a second solvent to a concentration of less than 0.05 wt% aluminum before step b).
11. The process of claim 7 wherein the co-catalyst stream is further diluted, in a second dilution step, in a second solvent to a concentration of less than 0.03 wt% aluminum before step b).
12. The process of claim 8 wherein the first dilution step comprises diluting the MMAO stream to form a co-catalyst stream having a concentration of less than 0.5 wt% aluminum and the second dilution step comprises further diluting the co-catalyst stream to a concentration of less than 0.05 wt% aluminum before step b).
13. The process of any of claims 8-12 wherein the first and second solvents are the same.
14. The process of any of claims 8-13 wherein the first and second solvent each comprise one or more alkanes and/ or aromatics.
15. The process of claim 14 wherein the first and second solvents comprise xylene.
16. The process of any of claims 8-15 wherein the co-catalyst stream is stored at that concentration for a period of time before being further diluted in the second dilution step.
17. The process of claim 16 wherein the period of time is at least 30 minutes.
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