WO2022110054A1 - Photodetector, manufacturing method therefor, chip, and optical device - Google Patents

Photodetector, manufacturing method therefor, chip, and optical device Download PDF

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Publication number
WO2022110054A1
WO2022110054A1 PCT/CN2020/132411 CN2020132411W WO2022110054A1 WO 2022110054 A1 WO2022110054 A1 WO 2022110054A1 CN 2020132411 W CN2020132411 W CN 2020132411W WO 2022110054 A1 WO2022110054 A1 WO 2022110054A1
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WO
WIPO (PCT)
Prior art keywords
layer
electrode
electrode contact
contact layer
photodetector
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PCT/CN2020/132411
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French (fr)
Chinese (zh)
Inventor
曹均凯
曹高奇
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华为技术有限公司
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Priority to PCT/CN2020/132411 priority Critical patent/WO2022110054A1/en
Priority to CN202080102963.6A priority patent/CN115943335A/en
Publication of WO2022110054A1 publication Critical patent/WO2022110054A1/en

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    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B6/00Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
    • G02B6/24Coupling light guides
    • G02B6/42Coupling light guides with opto-electronic elements
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/08Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof in which radiation controls flow of current through the device, e.g. photoresistors
    • H01L31/10Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof in which radiation controls flow of current through the device, e.g. photoresistors characterised by at least one potential-jump barrier or surface barrier, e.g. phototransistors
    • H01L31/101Devices sensitive to infrared, visible or ultraviolet radiation
    • H01L31/102Devices sensitive to infrared, visible or ultraviolet radiation characterised by only one potential barrier or surface barrier
    • H01L31/109Devices sensitive to infrared, visible or ultraviolet radiation characterised by only one potential barrier or surface barrier the potential barrier being of the PN heterojunction type

Definitions

  • the present application relates to the technical field of optical communication, and in particular, to a photodetector, a preparation method thereof, a chip and an optical device.
  • the working mechanism of the wavelength-selective switches (WSS) structure is that the colored light beams are incident on the free space in the WSS structure from the input fiber, and then the colored light beams are regularly transmitted through the action of various optical elements set in the free space. Dispersed into monochromatic beams of different wavelengths, and then through the action of geometric optics, the monochromatic beams of different wavelengths enter different output fibers. Therefore, the WSS structure can select different output wavelengths according to actual application needs, and can adjust the output optical power independently.
  • the light beam is transmitted in free space in the WSS structure, only the entrance and exit are provided with optical fibers.
  • a fiber tap detection device on the input or output fiber of the WSS structure.
  • the detection of the optical signal transmitted in the optical fiber 1 can be realized without destroying the optical path of the original optical fiber 1 .
  • the input fiber and output fiber of the WSS structure are usually fiber arrays (Fiber Array), it is necessary to install a large number of fiber tap detection devices 2 to meet the requirements of real-time detection.
  • using a large number of optical fiber tap detection devices 2 requires a large installation space, which will lead to increased volume, complex structure, and increased cost of the optical fiber communication system.
  • the present application provides a photodetector, a preparation method thereof, a chip and an optical device, which are used to provide a new type of photodetector.
  • a photodetector provided by the present application includes: a substrate, a first electrode contact layer, a photosensitive layer, a second electrode contact layer, and a passivation layer that are sequentially stacked on the substrate;
  • the first electrode and the second electrode on the chemical layer; the first electrode contact layer and the second electrode contact layer are doped semiconductor layers with opposite polarities, for example, the first electrode contact layer is a P-type doped semiconductor layer, and the second electrode contact layer is a P-type doped semiconductor layer.
  • the contact layer is an N-type doped semiconductor layer, or the first electrode contact layer is an N-type doped semiconductor layer, and the second electrode contact layer is a P-type doped semiconductor layer.
  • the photodetector also includes a through hole penetrating at least the photosensitive layer and the second electrode contact layer; the orthographic projections of the first electrode and the second electrode on the substrate are respectively located outside the orthographic projection of the through hole on the substrate, and the first electrode and the second electrode are insulated from each other, the first electrode is electrically connected to the first electrode contact layer through a first groove penetrating the film layer between the first electrode and the first electrode contact layer, and the second electrode is electrically connected to the first electrode contact layer through the passivation layer.
  • the second groove is electrically connected to the second electrode contact layer.
  • the first electrode contact layer and the second electrode contact layer form a PN junction.
  • the photosensitive layer captures the light passing through the via hole V0
  • the PN junction can convert the optical signal into an electrical signal, thereby realizing Detection of optical signals.
  • the photodetector is not limited in structure to a photodiode (Photodiode, PD), an avalanche photodiode (Avalanche Photodiode, APD) or a heterojunction phototransistor (Hetero junction Photodiode, HPT) and the like.
  • the orthographic projections of the first electrode and the second electrode on the substrate are respectively located outside the orthographic projection of the through hole on the substrate, so that the orthographic projection of the first electrode on the substrate and the first Neither of the orthographic projections of the two electrodes on the substrate can cover the through hole, thus preventing the first electrode and the second electrode from blocking light passing through the through hole.
  • the photodetector of the present application can be applied to various structures based on the transmission of light in free space.
  • the photodetector can be arranged on the transmission path of monochromatic light in free space, and the monochromaticity and direction of the transmission of these light beams can be used. Due to the characteristics of the Gaussian distribution of light intensity and light intensity, when the monochromatic beam passes through the photodetector, a small number of photons at the edge of the beam will enter the photodetector, so that the light signal can be detected in real time without interfering with the light transmission.
  • the photodetector is arranged on the transmission path of the monochromatic light in the free space of the WSS structure.
  • the photodetector can directly obtain photons from the transmission path of monochromatic light without the help of other devices, it can be fixed on the transmission path of monochromatic light without complex mechanical fixing parts, which is different from using existing devices. Compared with the optical fiber tap detection device, the overall structure complexity and cost can be reduced.
  • the electrical contact performance between the P-type doped semiconductor layer and the metal electrode is generally not as good as the electrical contact performance between the N-type doped semiconductor layer and the metal electrode. Therefore, for the P-type doped semiconductor layer, a metal contact electrode can be formed first between the P-type doped semiconductor layer and the metal electrode. Therefore, in the present application, if the first electrode contact layer is a P-type doped semiconductor layer, a metal contact electrode may be provided between the first electrode contact layer and the first electrode. If the second electrode contact layer is a P-type doped semiconductor layer, a metal contact electrode may be provided between the second electrode contact layer and the second electrode. It is not limited here.
  • the second electrode contact layer is generally set as a P-type doped semiconductor layer. Therefore, in this application, the second electrode contact layer is a P-type doped semiconductor layer, and the photodetector further includes a layer located on the second electrode. The metal contacts the electrode with the second electrode contact layer to improve the electrical contact performance between the second electrode and the second electrode contact layer.
  • the present application does not limit the shapes of the first electrode and the second electrode.
  • the second electrode has a closed annular structure surrounding the through hole;
  • the first electrode has an annular structure arranged around the second electrode and having an opening.
  • the opening of the first electrode is to avoid a short circuit between the first electrode and the second electrode, and the first electrode and the second electrode are drawn out from two sides of the through hole respectively.
  • the shape of the groove can be set to be similar to the shape of the electrode.
  • the shape of the second groove is a closed ring surrounding the through hole;
  • the shape of a groove is an annular shape with an opening arranged around the second groove.
  • the through hole in order to avoid the photodetector from affecting the light passing through the area where the through hole is located, the through hole can penetrate all the film layers along the thickness direction of the substrate, that is, the through hole penetrates through the passivation layer, the second electrode contact layer, A photosensitive layer, a first electrode contact layer and a substrate.
  • the through hole may only penetrate the second electrode contact layer, the photosensitive layer and the first electrode contact layer.
  • the through hole can only penetrate the second electrode contact layer and the photosensitive layer.
  • the shape of the through hole is not limited in the present application, and it may be any shape, such as polymorphic shape, circular shape, oval shape, and the like.
  • shape of the through hole is circular, it can be ensured that the distance from the center of the through hole to the boundary of the through hole is the same. Moreover, the circular via is easier to realize in the process.
  • the photodetector when the second electrode contact layer is formed, a capping layer can be formed first, and then the capping layer can be doped. If the doping area covers the area where the via hole is located, the via hole will penetrate the remaining doping area after the doping area. It is the second electrode contact layer. If the doped region does not cover the region where the through hole is located, the doped region is the second electrode contact layer. Therefore, in the present application, the photodetector further includes a cover layer provided in the same layer as the second electrode contact layer, the shape of the second electrode contact layer is annular, and the cover layer is arranged around the second electrode contact layer; The intrinsic material of the second electrode contact layer and the cover layer is the same, but the doping concentration is different.
  • the cover layer is generally lightly doped, and the second electrode contact layer is generally heavily doped.
  • the intrinsic material of the second electrode contact layer and the cover layer are the same, and the electrical doping types of the two are different, for example, the cover layer is N-type doped, the second electrode contact layer is P-type doping, or the cover layer is P-type doping type doping, and the second electrode contact layer is N-type doped.
  • a chip provided by the present application includes a drive circuit, and at least one photodetector of any of the above-mentioned embodiments of the present application connected to the drive circuit.
  • the photoelectric energy detector can convert the captured optical signal into an electrical signal
  • the driving circuit can amplify the electrical signal and output it to realize the detection of the optical signal.
  • the present application provides an optical device comprising a wavelength selective switch structure and at least one photodetector, wherein the photodetector is arranged on a transmission path of monochromatic light in the free space of the wavelength selective switch structure.
  • the photodetector can directly obtain photons from the transmission path of monochromatic light without the help of other devices, it can be fixed on the transmission path of monochromatic light without complex mechanical fixing parts, which is different from using existing devices.
  • the optical fiber tap detection device the overall cost and overall structural complexity can be reduced.
  • the present application provides a method for preparing a photodetector, comprising: firstly forming a first electrode contact layer, a photosensitive layer and a second electrode contact layer on a substrate in sequence, and forming at least a through photosensitive layer and a through hole of the second electrode contact layer; then a first passivation layer is formed on the second electrode contact layer, and a first groove and a through passivation penetrating the first passivation layer and deep to the surface of the first electrode contact layer are formed The second groove of the passivation layer; finally, the first electrode and the second electrode are formed on the first passivation layer; wherein, the orthographic projections of the first electrode and the second electrode on the substrate are respectively located on the positive side of the through hole on the substrate.
  • the first electrode contact layer and the second electrode contact layer are doped semiconductor layers with opposite polarities, for example, the first electrode contact layer is a P-type doped semiconductor layer, and the second electrode contact layer is an N-type doped semiconductor layer, Alternatively, the first electrode contact layer is an N-type doped semiconductor layer, and the second electrode contact layer is a P-type doped semiconductor layer.
  • the first electrode contact layer and the second electrode contact layer form a PN junction.
  • the PN junction can convert the optical signal Converted into electrical signals, so as to realize the detection of optical signals.
  • the photodetector is not limited in structure to a photodiode (Photodiode, PD), an avalanche photodiode (Avalanche Photodiode, APD) or a heterojunction phototransistor (Hetero junction Photodiode, HPT) and the like.
  • the first electrode contact layer, the photosensitive layer and the second electrode contact layer are sequentially formed on the substrate, and through holes at least penetrating through the photosensitive layer and the second electrode contact layer are formed, which may include : First, the first electrode contact layer, the photosensitive layer and the cover layer are formed on the substrate in sequence; then the second passivation layer is formed on the cover layer, and the via hole passing through the second passivation layer is formed, so that the exposed cover The layer is annular or circular; then the exposed cover layer is doped to form a second electrode contact layer; and then a through hole penetrating at least the photosensitive layer and the second electrode contact layer is formed.
  • the first electrode contact layer, the photosensitive layer, and the second electrode contact layer are sequentially formed on the substrate, and a through hole penetrating at least the photosensitive layer and the second electrode contact layer is formed , which may include: firstly forming a first electrode contact layer, a photosensitive layer and a cover layer on the area of the substrate except the central area; then forming a second passivation layer on the cover layer, and forming a second passivation layer through The via hole of the chemical layer is formed, so that the exposed cover layer is annular; and then the exposed cover layer is doped to form a second electrode contact layer.
  • the method further includes: removing the central region of the substrate, so that in the formed photodetector, there is no film in the region where the through hole is located Floor.
  • a first passivation layer is formed on the second electrode contact layer, and a first groove that penetrates the first passivation layer and is deep to the surface of the first electrode contact layer and penetrates the passivation layer is formed
  • the second groove may include: first forming a third groove penetrating the second passivation layer, the cover layer and the photosensitive layer; then forming the first passivation layer on the second electrode contact layer, so that the first passivation layer can be formed.
  • the passivation layer covers the sidewall of the third groove to protect the sidewall of the third groove; then a second groove is formed through the first passivation layer, and a second groove through the third groove is formed in the area where the third groove is located.
  • the depth of the third groove is relatively deep, and the first electrode needs to climb over the sidewall of the third groove and the first electrode.
  • the contact layer is electrically connected. If the depth of the sidewall is deep, the first electrode is likely to be disconnected at the sidewall. Therefore, optionally, in this application, the first electrode contact layer, the photosensitive layer and the second electrode are sequentially formed on the substrate.
  • the method may further include: removing the second passivation layer, the cover layer and the photosensitive layer in the preset area, so that the remaining cover layer and the photosensitive layer are removed.
  • the sensitive layer has a ring structure. Therefore, the subsequently formed first electrode only needs to penetrate the first groove of the first passivation layer to be electrically connected to the first electrode contact layer.
  • one electrode contact layer is a P-type doped semiconductor layer
  • the other electrode contact layer is an N-type doped semiconductor layer.
  • the electrical contact performance between the P-type doped semiconductor layer and the metal electrode is not as good as the electrical contact performance between the N-type doped semiconductor layer and the metal electrode. Therefore, for the P-type doped semiconductor layer, a metal contact electrode can be formed first between the P-type doped semiconductor layer and the metal electrode. Therefore, in the present application, if the first electrode contact layer is a P-type doped semiconductor layer, a metal contact electrode may be provided between the first electrode contact layer and the first electrode. If the second electrode contact layer is a P-type doped semiconductor layer, a metal contact electrode may be provided between the second electrode contact layer and the second electrode. It is not limited here.
  • the second electrode contact layer is generally set as a P-type doped semiconductor layer. Therefore, in this application, after the first electrode contact layer, the photosensitive layer and the second electrode contact layer are sequentially formed on the substrate , before forming the first passivation layer on the second electrode contact layer, may further include: forming a ring-shaped metal contact electrode on the second electrode contact layer, and annealing the metal contact electrode, so that the second electrode to be formed The second electrode contact layer is electrically connected through the metal contact electrode.
  • FIG. 1 is a schematic diagram of the detection performed by an optical fiber tap detection device in the related art
  • Fig. 2 is the structural representation that the optical fiber tap detection device is applied in the WSS structure in the related art
  • FIG. 3a is a schematic top-view structural diagram of a photodetector in an embodiment of the present application.
  • Fig. 3b is a schematic cross-sectional structure diagram of the photodetector shown in Fig. 3a along the AA' direction;
  • Fig. 3c is a schematic cross-sectional structure diagram of the photodetector shown in Fig. 3a along the BB' direction;
  • FIG. 4 is a schematic flowchart of a method for preparing a photodetector according to an embodiment of the present application
  • FIG. 5 is a schematic flowchart of a method for preparing a photodetector provided by another embodiment of the present application.
  • 6a is a top view of a structure formed after performing the steps of the preparation method in the present application.
  • Figure 6b is a schematic cross-sectional structure diagram of the structure shown in Figure 6a along the AA' direction;
  • 7a is a top view of a structure formed after performing the steps of the preparation method in the present application.
  • Fig. 7b is a schematic cross-sectional structure diagram of the structure shown in Fig. 7a along the AA' direction;
  • FIG. 8a is a top view of a structure formed after performing the steps of the preparation method in the present application.
  • Fig. 8b is a schematic cross-sectional structure diagram of the structure shown in Fig. 8a along the AA' direction;
  • 9a is a top view of a structure formed after performing the steps of the preparation method in the present application.
  • Figure 9b is a schematic cross-sectional structure diagram of the structure shown in Figure 9a along the AA' direction;
  • 10a is a top view of a structure formed after performing the steps of the preparation method in the present application.
  • Fig. 10b is a schematic cross-sectional structure diagram of the structure shown in Fig. 10a along the AA' direction;
  • 11a is a top view of the structure formed after performing the steps of the preparation method in the present application.
  • Figure 11b is a schematic cross-sectional structure diagram of the structure shown in Figure 11a along the AA' direction;
  • Fig. 11c is a schematic cross-sectional structure diagram of the structure shown in Fig. 11a along the BB' direction;
  • Figure 12a is a top view of the structure formed after performing the steps of the preparation method in the present application.
  • Figure 12b is a schematic cross-sectional structure diagram of the structure shown in Figure 12a along the AA' direction;
  • Figure 12c is a schematic cross-sectional structure diagram of the structure shown in Figure 12a along the BB' direction;
  • Figure 13a is a top view of the structure formed after performing the steps of the preparation method in the present application.
  • Figure 13b is a schematic cross-sectional structure diagram of the structure shown in Figure 13a along the AA' direction;
  • Figure 13c is a schematic cross-sectional structure diagram of the structure shown in Figure 13a along the BB' direction;
  • FIG. 14a is a schematic top-view structural diagram of a photodetector in yet another embodiment of the present application.
  • Fig. 14b is a schematic cross-sectional structure diagram of the photodetector shown in Fig. 14a along the AA' direction;
  • Fig. 14c is a schematic cross-sectional structure diagram of the photodetector shown in Fig. 14a along the BB' direction;
  • FIG. 15a is a schematic top-view structural diagram of a photodetector in yet another embodiment of the present application.
  • Fig. 15b is a schematic cross-sectional structure diagram of the photodetector shown in Fig. 15a along the AA' direction;
  • Fig. 15c is a schematic cross-sectional structure diagram of the photodetector shown in Fig. 15a along the BB' direction;
  • 16 is a schematic flowchart of a method for fabricating a photodetector provided by another embodiment of the present application.
  • Figure 17a is a top view of the structure formed after performing the steps of the preparation method of the present application.
  • Fig. 17b is a schematic cross-sectional structure diagram of the structure shown in Fig. 17a along the AA' direction;
  • Fig. 18a is another schematic cross-sectional structure diagram of the photodetector shown in Fig. 14a along the AA' direction;
  • Fig. 18b is another schematic cross-sectional structure diagram of the photodetector shown in Fig. 14a along the BB' direction;
  • Fig. 19a is another schematic cross-sectional structure diagram of the photodetector shown in Fig. 15a along the AA' direction;
  • Fig. 19b is another schematic cross-sectional structure diagram of the photodetector shown in Fig. 15a along the BB' direction;
  • FIG. 20 is a schematic flowchart of a method for fabricating a photodetector provided by another embodiment of the present application.
  • Figure 21a is a top view of the structure formed after performing the steps of the preparation method in the present application.
  • Figure 21b is a schematic cross-sectional structure diagram of the structure shown in Figure 21a along the AA' direction;
  • Fig. 22a is another schematic cross-sectional structure diagram of the photodetector shown in Fig. 15a along the AA' direction;
  • Fig. 22b is another schematic cross-sectional structure diagram of the photodetector shown in Fig. 15a along the BB' direction;
  • FIG. 23 is a schematic flowchart of a method for fabricating a photodetector provided by another embodiment of the present application.
  • Fig. 24a is another schematic cross-sectional structure diagram of the photodetector shown in Fig. 15a along the AA' direction;
  • Figure 24b is another schematic cross-sectional structure diagram of the photodetector shown in Figure 15a along the BB' direction;
  • FIG. 25 is a schematic structural diagram of a chip provided by an embodiment of the application.
  • 26 is a schematic diagram of an arrangement of a plurality of photodetectors in a chip provided by an embodiment of the application;
  • FIG. 27 is a schematic diagram of an arrangement of a plurality of photodetectors in a chip according to another embodiment of the present application.
  • the photodetectors provided in the embodiments of the present application can be widely used in various structures based on free space transmission of light.
  • the photodetector when applied to the WSS structure, the photodetector is arranged on the transmission path of monochromatic light in the free space of the WSS structure.
  • the monochromatic beam passes through the photodetector, a small number of photons at the edge of the beam will enter the photodetector, thereby Capable of real-time tap detection of optical signals without interfering with optical transmission.
  • the photodetector can also be applied in the aerospace field.
  • the communication between some satellite devices will use free space optical communication technology, and the photodetector can perform real-time detection on these optical communications.
  • Fig. 3a exemplarily shows a schematic top view structure of a photodetector in an embodiment of the present application
  • Fig. 3b is a schematic cross-sectional structure diagram of the photodetector shown in Fig. 3a along the AA' direction
  • Fig. 3c is a photodetector shown in Fig. 3a Schematic diagram of the cross-sectional structure of the device along the BB' direction.
  • the photodetector 10 provided by the present application includes: a substrate 11, a first electrode contact layer 12, a photosensitive layer 13, a second electrode contact layer 14 and The passivation layer 15, and the first electrode 161 and the second electrode 162 located on the passivation layer 15; wherein, the first electrode contact layer 12 and the second electrode contact layer 14 are doped semiconductor layers with opposite polarities, such as the first electrode contact layer 12 and the second electrode contact layer 14.
  • An electrode contact layer 12 is a P-type doped semiconductor layer
  • the second electrode contact layer 14 is an N-type doped semiconductor layer
  • the first electrode contact layer 12 is an N-type doped semiconductor layer
  • the second electrode contact layer 14 is P-type doped semiconductor layer.
  • the photodetector 10 further includes a through hole V0 penetrating at least the photosensitive layer 13 and the second electrode contact layer 14;
  • the outer side of the orthographic projection of 11; the first electrode 161 and the second electrode 162 are insulated from each other, and the first electrode 161 passes through the first groove V1 and the first electrode 161 through the film layer between the first electrode 161 and the first electrode contact layer 12.
  • An electrode contact layer 12 is electrically connected, and the second electrode 162 is electrically connected to the second electrode contact layer 14 through the second groove V2 penetrating the passivation layer 15 .
  • the first electrode contact layer 12 and the second electrode contact layer 14 form a PN junction, which can convert the optical signal into an electrical signal when the photosensitive layer 13 captures the light passing through the via V0 , so as to realize the detection of the optical signal, and ensure that the light passing through the through hole V0 is not disturbed.
  • the photodetector is not limited in structure to a photodiode (Photodiode, PD), an avalanche photodiode (Avalanche Photodiode, APD) or a heterojunction phototransistor (Hetero junction Photodiode, HPT) and the like.
  • the photodetector of the present application can be applied to various structures based on the transmission of light in free space.
  • the photodetector can be arranged on the transmission path of monochromatic light in free space, and the monochromaticity and direction of the transmission of these light beams can be used. After the monochromatic beam passes through the through-hole area of the photodetector, a small number of photons at the edge of the beam will enter the photodetector, so that the optical signal can be detected in real time without interfering with the optical transmission.
  • the photodetector when applied to the WSS structure, the photodetector is arranged on the transmission path of the monochromatic light in the free space of the WSS structure.
  • the photodetector can directly obtain photons from the transmission path of monochromatic light without the help of other devices, it can be fixed on the transmission path of monochromatic light without complex mechanical fixing parts, which is different from using existing devices. Compared with the optical fiber tap detection device, the overall structure complexity and cost can be reduced.
  • FIG. 4 exemplarily shows a schematic flowchart of a method for fabricating a photodetector provided by an embodiment of the present application. As shown in Figure 4, the method mainly includes the following steps:
  • the contact layer is a doped semiconductor layer of opposite polarity.
  • step S401 sequentially forms the first electrode contact layer, the photosensitive layer and the second electrode contact layer on the substrate, and forms at least through holes penetrating the photosensitive layer and the second electrode contact layer, It may include: firstly forming a first electrode contact layer, a photosensitive layer and a cover layer on the substrate in sequence; then forming a second passivation layer on the cover layer, and forming a via hole penetrating the second passivation layer, so as to expose the The cover layer is annular or circular; then the exposed cover layer is doped to form a second electrode contact layer; and then a through hole penetrating at least the photosensitive layer and the second electrode contact layer is formed.
  • step S401 sequentially forms a first electrode contact layer, a photosensitive layer and a second electrode contact layer on the substrate, and forms at least through holes penetrating the photosensitive layer and the second electrode contact layer , may include: firstly forming the first electrode contact layer, the photosensitive layer and the cover layer on the substrate except the central area, so that while the first electrode contact layer, the light sensitive layer and the cover layer are formed, A through hole is formed in the central area through the first electrode contact layer, the photosensitive layer and the cover layer; then a second passivation layer is formed on the cover layer, and a via hole through the second passivation layer is formed, so that the exposed cover The layer is annular; the exposed cap layer is then doped to form a second electrode contact layer.
  • the central area is the area where the through hole is located, which may be a circular area. Further, after doping the exposed capping layer to form the second electrode contact layer, the method further includes: removing the central region of the substrate, so that the through hole still penetrates the substrate.
  • step S402 forms a first passivation layer on the second electrode contact layer, and forms a first groove and a through passivation penetrating the first passivation layer and deep to the surface of the first electrode contact layer
  • the second groove of the passivation layer may include: firstly forming a third groove penetrating the second passivation layer, the cover layer and the photosensitive layer; then forming the first passivation layer on the second electrode contact layer, so that the first passivation layer can be formed.
  • a passivation layer covers the sidewall of the third groove to protect the sidewall of the third groove; then a second groove is formed through the first passivation layer, and is formed in the area where the third groove is located The first groove penetrates through the first passivation layer, so that the first groove penetrates through the first passivation layer and is deep to the surface of the first electrode contact layer.
  • the depth of the third groove is relatively deep, and the first electrode needs to climb over the sidewall of the third groove and the first electrode.
  • the contact layer is electrically connected. If the depth of the sidewall is deep, the first electrode is likely to be disconnected at the sidewall. Therefore, optionally, in this application, the first electrode contact layer, the photosensitive layer and the second electrode are sequentially formed on the substrate.
  • the method may further include: removing the second passivation layer, the cover layer and the photosensitive layer in the preset area, so that the remaining cover layer and the photosensitive layer are removed.
  • the sensitive layer has a ring structure. Therefore, the subsequently formed first electrode only needs to penetrate the first groove of the first passivation layer to be electrically connected to the first electrode contact layer.
  • one electrode contact layer is a P-type doped semiconductor layer
  • the other electrode contact layer is an N-type doped semiconductor layer.
  • the electrical contact performance between the P-type doped semiconductor layer and the metal electrode is not as good as the electrical contact performance between the N-type doped semiconductor layer and the metal electrode. Therefore, for the P-type doped semiconductor layer, a metal contact electrode can be formed first between the P-type doped semiconductor layer and the metal electrode. Therefore, in the present application, if the first electrode contact layer is a P-type doped semiconductor layer, a metal contact electrode may be provided between the first electrode contact layer and the first electrode. If the second electrode contact layer is a P-type doped semiconductor layer, a metal contact electrode may be provided between the second electrode contact layer and the second electrode. It is not limited here.
  • the second electrode contact layer is generally set as a P-type doped semiconductor layer. Therefore, in this application, the second electrode contact layer is a P-type doped semiconductor layer, and the first electrodes are sequentially formed on the substrate.
  • the method may further include: forming a ring-shaped metal contact electrode on the second electrode contact layer, and contacting the metal The contact electrode is annealed so that the second electrode to be formed is electrically connected to the second electrode contact layer through the metal contact electrode.
  • the first electrode contact layer as an N-type doped semiconductor layer
  • the second electrode contact layer as a P-type doped semiconductor layer
  • a metal contact electrode disposed between the second electrode contact layer and the second electrode as an example
  • FIG. 5 exemplarily shows a schematic flowchart of a method for fabricating a photodetector provided by another embodiment of the present application. As shown in Figure 5, the method mainly includes the following steps:
  • FIG. 6a is a top view of the structure formed after performing the steps of the preparation method in the present application
  • FIG. 6b is a schematic cross-sectional structure diagram of the structure shown in FIG. 6a along the AA' direction.
  • the first electrode contact layer 12 may be epitaxially grown on the substrate 11
  • the photosensitive layer 13 may be epitaxially grown on the first electrode contact layer 12
  • the cover layer 17 may be epitaxially grown on the photosensitive layer 13 .
  • the materials of the first electrode contact layer 12 , the photosensitive layer 13 and the capping layer 17 may be InP/InGaAs, Ge/Si, GaN, GaAs and other material systems, but are not limited thereto.
  • FIG. 7a is a top view of the structure formed after performing the steps of the preparation method in the present application
  • FIG. 7b is a schematic cross-sectional structure diagram of the structure shown in FIG. 7a along the AA' direction.
  • a second passivation layer 152 may be formed on the capping layer 17 first, and the second passivation layer 152 may be patterned to form via holes penetrating the second passivation layer 152 , so that the exposed cover layer 17 is annular or circular or regular polygon as shown in FIG. 7 a , which is not limited herein.
  • Figure 8a is a top view of a structure formed after performing the steps of the preparation method in the present application
  • Figure 8b is a schematic cross-sectional structure diagram of the structure shown in Figure 8a along the AA' direction.
  • the second electrode contact layer 14 may be formed by doping the exposed capping layer 17 through a diffusion or ion implantation process. That is, the epitaxial materials of the second electrode contact layer 14 and the cover layer 17 are the same, the intrinsic materials of the two are the same, but the doping concentration is different, the cover layer 17 is generally lightly doped, and the second electrode contact layer 14 is generally heavily doped .
  • the intrinsic material of the second electrode contact layer 14 and the cover layer 17 are the same, and the electrical doping types of the two are different, for example, the cover layer 17 is N-type doped, and the second electrode contact layer 14 is P-type doped, or, The capping layer 17 is P-type doped, and the second electrode contact layer 14 is N-type doped.
  • the boundary shape of the second electrode contact layer and the shape of the subsequently formed through hole can be designed to be the same, and the center of the second electrode contact layer and the center of the subsequently formed through hole can be designed to overlap, so as to ensure photoelectric detection.
  • the performance of the device in the same plane perpendicular to the light passing direction is as centrosymmetric as possible.
  • Figure 9a is a top view of a structure formed after performing the steps of the preparation method in the present application
  • Figure 9b is a schematic cross-sectional structure diagram of the structure shown in Figure 9a along the AA' direction.
  • a ring-shaped metal contact electrode 18 is formed on the second electrode contact layer 14, and the metal contact electrode 18 is annealed. The center of the metal contact electrode 18 may coincide with the center of the through hole to be formed.
  • FIG. 10a is a top view of a structure formed after performing the steps of the preparation method in the present application
  • FIG. 10b is a schematic cross-sectional structure diagram of the structure shown in FIG. 10a along the AA' direction.
  • the through hole V0 may penetrate through the second electrode contact layer 14 , the photosensitive layer 13 , the first electrode contact layer 12 and the substrate 11 .
  • the through hole V0 may only penetrate the second electrode contact layer 14 , the photosensitive layer 13 and the first electrode contact layer 12 .
  • the through hole V0 may only penetrate the second electrode contact layer 14 and the photosensitive layer 13 .
  • the shape of the through hole is not limited in the present application, and it may be any shape, such as polymorphic shape, circular shape, oval shape, and the like.
  • shape of the through hole V0 is a circle, it can be ensured that the distance from the center of the through hole V0 to the boundary of the through hole V0 is the same.
  • the circular via is easier to realize in the process.
  • the cover layer 17 is arranged around the second electrode contact layer 14, and the through hole V0 penetrates through the second electrode contact layer 14 to ensure that the functional area of the photodetector (ie the first electrode contacts Layer 12 , photosensitive layer 13 and second electrode contact layer 14 are facing the edge of the via hole V0 ), so that the photons passing through the via hole V0 are easily captured, thereby improving the sensitivity.
  • FIG. 11a is a top view of a structure formed after performing the steps of the preparation method in the present application
  • FIG. 11b is a schematic cross-sectional structure diagram of the structure shown in FIG. 11a along the AA' direction
  • FIG. 11c is the structure shown in FIG. 11a.
  • a third groove V3 is formed through the second passivation layer 152 , the photosensitive layer 13 and the capping layer 17 .
  • FIG. 12a is a top view of a structure formed after performing the steps of the preparation method in the present application
  • FIG. 12b is a schematic cross-sectional structure diagram of the structure shown in FIG. 12a along the direction AA'
  • FIG. 12c is the structure shown in FIG. 12a Schematic diagram of the cross-sectional structure along the BB' direction.
  • the first passivation layer 151 formed on the metal contact electrode 18 may cover the sidewalls of the via hole V0 and the sidewalls of the third groove V3, so as to protect the epitaxial material at the via hole V0 and the third groove V3 to protection.
  • FIG. 13a is a top view of a structure formed after performing the steps of the preparation method in the present application
  • FIG. 13b is a schematic cross-sectional structure diagram of the structure shown in FIG. 13a along the AA' direction
  • FIG. 13c is the structure shown in FIG. 13a. Schematic diagram of the cross-sectional structure along the BB' direction.
  • a photolithography process can be used to form the second groove V2 penetrating the first passivation layer 151, and a photolithography process can be used to form the first groove V1 penetrating the first passivation layer 151 in the region where the third groove V3 is located, so as to The first groove V1 penetrates through the first passivation layer 151 and is deep to the surface of the first electrode contact layer 12 .
  • the second groove V2 and the first groove V1 penetrating through the first passivation layer 151 may be formed simultaneously by one photolithography process.
  • FIG. 14a is a top view of a structure formed after performing the steps of the preparation method in the present application
  • FIG. 14b is a schematic cross-sectional structure diagram of the structure shown in FIG. 14a along the direction AA'
  • FIG. 14c is the structure shown in FIG. 14a Schematic diagram of the cross-sectional structure along the BB' direction.
  • the orthographic projection of the first electrode 161 and the second electrode 162 located on the first passivation layer 151 on the substrate 11 is located outside the orthographic projection of the through hole V0 on the substrate 11, and the first electrode 161 and the second electrode 162 are mutually Insulation, the first electrode 161 is electrically connected to the first electrode contact layer 12 through the first groove V1, and the second electrode 162 is electrically connected to the metal contact electrode 18 through the second groove V2.
  • the shapes of the first electrode and the second electrode are not limited.
  • the second electrode 162 has a closed annular structure surrounding the through hole V0;
  • the first electrode 161 has an annular structure arranged around the second electrode 162 and having an opening, The opening of the first electrode 161 is to prevent the first electrode 161 and the second electrode 162 from being short-circuited, and the first electrode 161 and the second electrode 162 are drawn out from two sides of the through hole, respectively.
  • the shape of the groove can be set to be similar to the shape of the electrode.
  • the shape of the second groove V2 is a closed ring surrounding the through hole V0; the first groove
  • the shape of V1 is an annular shape provided around the second groove V2 and having an opening.
  • the photodetector in the present application is formed.
  • the passivation layer is formed by two passivation layers, a first passivation layer and a second passivation layer.
  • Figures 14a to 14c can be seen for the case where the through hole V0 penetrates all the film layers.
  • the through hole V0 does not penetrate all the film layers, please refer to FIG. 15a to FIG. 15c.
  • FIG. 16 exemplarily shows a schematic flowchart of a method for fabricating a photodetector provided by another embodiment of the present application. As shown in Figure 16, the method mainly includes the following steps:
  • FIG. 17a is a top view of the structure formed after performing the steps of the preparation method in the present application
  • FIG. 17b is a schematic cross-sectional structure diagram of the structure shown in FIG. 17a along the AA' direction.
  • the second passivation layer 152 , the cover layer 17 and the photosensitive layer 13 in the preset area S1 are removed, so that the remaining cover layer 17 and the photosensitive layer 13 have a ring structure.
  • step S1506 is different from step S506 in the first example, and other steps can be referred to in the first embodiment, which will not be repeated here.
  • the photodetector in the present application is formed.
  • the passivation layer is formed by two passivation layers, a first passivation layer and a second passivation layer. 14a and 18a and 18b.
  • FIG. 18a is a schematic cross-sectional structure diagram of the structure shown in FIG. 14a along the AA' direction
  • FIG. 18b is the structure shown in FIG. 14a along the BB' direction.
  • FIG. 19a is a schematic cross-sectional structure diagram of the structure shown in FIG. 15a along the direction AA'
  • FIG. 19b is the structure shown in FIG. 15a along BB Schematic diagram of the cross-sectional structure in the 'direction'.
  • FIG. 20 exemplarily shows a schematic flowchart of a method for fabricating a photodetector provided by another embodiment of the present application. As shown in Figure 20, the method mainly includes the following steps:
  • FIG. 21a is a top view of the structure formed after performing the steps of the preparation method in the present application
  • FIG. 21b is a schematic cross-sectional structure diagram of the structure shown in FIG. 21a along the AA' direction.
  • a first electrode contact layer 12 , a photosensitive layer 13 and a capping layer 17 are epitaxially grown on the substrate 11 on regions other than the central region in sequence.
  • a through hole V0 penetrating the first electrode contact layer 12 , the photosensitive layer 13 and the capping layer 17 is formed in the central region.
  • the central area is the area where the through hole is located, which may be a circular area.
  • this example is only different from step S2001 and step S501 in the first embodiment.
  • this example has been formed in step S2001, and the through hole only penetrates the first electrode contact layer 12, the photosensitive layer 13 and the The second electrode contacts 17. Therefore, compared with Example 1, step S505 is omitted, and other steps can be referred to in Example 1, which will not be repeated here.
  • FIGS. 15a, 22a and 22b are schematic cross-sectional structure diagram of the structure shown in FIG. 15a along the direction AA', and FIG. 22b is the structure shown in FIG. 15a along BB Schematic diagram of the cross-sectional structure in the 'direction'.
  • step 2004, before step S2005 it may further include removing the central region of the substrate. Therefore, in the photodetector finally formed, the through hole penetrates through all the film layers, as shown in FIG. 14a to FIG. 14c for details.
  • FIG. 23 exemplarily shows a schematic flowchart of a method for fabricating a photodetector provided by another embodiment of the present application. As shown in Figure 23, the method mainly includes the following steps:
  • step S2305 is different from the step S2005 in the third example.
  • step S2005 refers to the third embodiment, which will not be repeated here.
  • FIG. 24a is a schematic cross-sectional structure diagram of the structure shown in FIG. 15a along the direction AA'
  • FIG. 24b is the structure shown in FIG. 15a along BB Schematic diagram of the cross-sectional structure in the 'direction'.
  • step S2304 before step S2005, it may further include removing the central region of the substrate. Therefore, in the photodetector finally formed, the through holes penetrate through all the film layers, as shown in FIG. 14a to FIG. 14c for details.
  • the first electrode contact layer, the photosensitive layer and the second electrode contact layer are stacked and arranged around the through hole, and when the photosensitive layer captures the light passing through the through hole, it can The optical signal is converted into an electrical signal, thereby realizing the detection of the optical signal.
  • the present application also provides a chip 100 , the chip 100 includes a driving circuit 101 and at least one photodetector 10 provided in any of the above-mentioned embodiments connected to the driving circuit 101 (in FIG. 25 , a photoelectric detector 10
  • the detector 10 is shown as an example).
  • the photoelectric energy detector 10 can convert the captured optical signal into an electrical signal, and the driving circuit 101 can amplify the electrical signal and output it to realize the detection of the optical signal.
  • the number and arrangement of the photodetectors 10 can be designed according to the actual application, which is not limited herein.
  • a plurality of the photodetectors 10 are arranged along the first direction.
  • a plurality of the photodetectors 10 are arranged along the first direction. arranged in a matrix.
  • the present application also provides an optical device, comprising a wavelength selective switch structure and at least one photodetector, wherein the photodetector is arranged on a transmission path of monochromatic light in the free space of the wavelength selective switch structure.
  • the monochromatic optical signal be guaranteed not to be disturbed, but also the volume of the WSS structure can be guaranteed not to increase.
  • the photodetector can directly obtain photons from the transmission path of monochromatic light without the help of other devices, it can be fixed on the transmission path of monochromatic light without complex mechanical fixing parts, which is different from using existing devices. Compared with the optical fiber tap detection device, the overall cost and overall structural complexity can be reduced.

Abstract

A photodetector (10), a manufacturing method therefor, a chip (100), and an optical device. The photodetector (10) comprises: a substrate (11); a first electrode contact layer (12), a photosensitive layer (13), a second electrode contact layer (14), and a passivation layer (15) which are sequentially stacked on the substrate (11); and a first electrode (161) and a second electrode (162). The photodetector (10) further comprises a through hole (V0) at least penetrating through the photosensitive layer (13) and the second electrode contact layer (14); the first electrode contact layer (12) and the second electrode contact layer (14) are doped semiconductor layers having opposite polarities; the first electrode (161) and the second electrode (162) are insulated from each other; the first electrode (161) is electrically connected to the first electrode contact layer (12) by means of a first recess (V1); the second electrode (162) is electrically connected to the second electrode contact layer (14) by means of a second recess (V2). In the photodetector (10), when light to be detected passes through the through hole (V0), the photosensitive layer (13) may capture some of photons passing through the through hole (V0) to convert an optical signal into an electric signal, thereby achieving the detection of the light to be detected, and ensuring that the light to be detected is not disturbed.

Description

光电探测器、其制备方法、芯片及光学装置Photodetector, its preparation method, chip and optical device 技术领域technical field
本申请涉及光通信技术领域,尤指一种光电探测器、其制备方法、芯片及光学装置。The present application relates to the technical field of optical communication, and in particular, to a photodetector, a preparation method thereof, a chip and an optical device.
背景技术Background technique
波长选择开关(Wavelength-selective switches,WSS)结构的工作机理是彩色光束由输入光纤入射到WSS结构内的自由空间,然后通过自由空间内设置的各种光学元件的作用,将彩色光束规律性地分散成不同波长的单色光束,再通过几何光学的作用,不同波长的单色光束进入不同的输出光纤内。因此WSS结构能够根据实际的应用需要选择不同的输出波长,并可以单独调整输出光功率等。The working mechanism of the wavelength-selective switches (WSS) structure is that the colored light beams are incident on the free space in the WSS structure from the input fiber, and then the colored light beams are regularly transmitted through the action of various optical elements set in the free space. Dispersed into monochromatic beams of different wavelengths, and then through the action of geometric optics, the monochromatic beams of different wavelengths enter different output fibers. Therefore, the WSS structure can select different output wavelengths according to actual application needs, and can adjust the output optical power independently.
由于光束在WSS结构中是在自由空间传输的,只有在入口和出口设置有光纤,为了实现对光信号的检测,需要在WSS结构的输入或输出光纤上安装光纤抽头检测装置。参见图1,当光纤1内的光束传输至光纤连接处时,会有少量的光束从光纤断面射出,通过机械固定件3安装在光纤1连接处的光纤抽头检测装置2俘获从光纤1断面射出的光,从而既能实现对光纤1内传输的光信号进行检测,又不会破坏原光纤1的光路。参见图2,由于WSS结构的输入光纤和输出光纤通常是光纤阵列(Fiber Array),因此需要安装大量的光纤抽头检测装置2才能够满足实时检测的要求。但是大量的使用光纤抽头检测装置2需要较大的安装空间,从而会导致光纤通信系统的体积增大、结构复杂、成本增加等。Since the light beam is transmitted in free space in the WSS structure, only the entrance and exit are provided with optical fibers. In order to realize the detection of the optical signal, it is necessary to install a fiber tap detection device on the input or output fiber of the WSS structure. Referring to Figure 1, when the light beam in the fiber 1 is transmitted to the fiber optic connection, a small amount of light beam will be emitted from the fiber optic section. Therefore, the detection of the optical signal transmitted in the optical fiber 1 can be realized without destroying the optical path of the original optical fiber 1 . Referring to FIG. 2, since the input fiber and output fiber of the WSS structure are usually fiber arrays (Fiber Array), it is necessary to install a large number of fiber tap detection devices 2 to meet the requirements of real-time detection. However, using a large number of optical fiber tap detection devices 2 requires a large installation space, which will lead to increased volume, complex structure, and increased cost of the optical fiber communication system.
发明内容SUMMARY OF THE INVENTION
本申请的提供一种光电探测器、其制备方法、芯片及光学装置,用于提供一种新型的光电探测器。The present application provides a photodetector, a preparation method thereof, a chip and an optical device, which are used to provide a new type of photodetector.
第一方面,本申请提供的一种光电探测器,包括:衬底、依次层叠设置于衬底上的第一电极接触层、光敏感层、第二电极接触层和钝化层,以及位于钝化层上的第一电极和第二电极;第一电极接触层和第二电极接触层为极性相反的掺杂半导体层,例如第一电极接触层为P型掺杂半导体层,第二电极接触层为N型掺杂半导体层,或者,第一电极接触层为N型掺杂半导体层,第二电极接触层为P型掺杂半导体层。光电探测器还包括至少贯穿光敏感层和第二电极接触层的通孔;第一电极和第二电极在衬底上的正投影分别位于通孔在衬底的正投影的外侧,第一电极和第二电极相互绝缘,第一电极通过贯穿位于第一电极与第一电极接触层之间的膜层的第一凹槽与第一电极接触层电连接,第二电极通过贯穿钝化层的第二凹槽与第二电极接触层电连接。In a first aspect, a photodetector provided by the present application includes: a substrate, a first electrode contact layer, a photosensitive layer, a second electrode contact layer, and a passivation layer that are sequentially stacked on the substrate; The first electrode and the second electrode on the chemical layer; the first electrode contact layer and the second electrode contact layer are doped semiconductor layers with opposite polarities, for example, the first electrode contact layer is a P-type doped semiconductor layer, and the second electrode contact layer is a P-type doped semiconductor layer. The contact layer is an N-type doped semiconductor layer, or the first electrode contact layer is an N-type doped semiconductor layer, and the second electrode contact layer is a P-type doped semiconductor layer. The photodetector also includes a through hole penetrating at least the photosensitive layer and the second electrode contact layer; the orthographic projections of the first electrode and the second electrode on the substrate are respectively located outside the orthographic projection of the through hole on the substrate, and the first electrode and the second electrode are insulated from each other, the first electrode is electrically connected to the first electrode contact layer through a first groove penetrating the film layer between the first electrode and the first electrode contact layer, and the second electrode is electrically connected to the first electrode contact layer through the passivation layer. The second groove is electrically connected to the second electrode contact layer.
在该光电探测器中,第一电极接触层和第二电极接触层形成PN结,当光敏感层俘获穿过通孔V0的光时,该PN结可以将光信号转换为电信号,从而实现对光信号的检测。需要指出的是,该光电探测器在结构上不限于光电二极管(Photodiode,PD)、雪崩光电二极管(Avalanche Photodiode,APD)或异质结光电晶体管(Hetero junction Photodiode,HPT)等。In this photodetector, the first electrode contact layer and the second electrode contact layer form a PN junction. When the photosensitive layer captures the light passing through the via hole V0, the PN junction can convert the optical signal into an electrical signal, thereby realizing Detection of optical signals. It should be pointed out that the photodetector is not limited in structure to a photodiode (Photodiode, PD), an avalanche photodiode (Avalanche Photodiode, APD) or a heterojunction phototransistor (Hetero junction Photodiode, HPT) and the like.
需要说明的是,本申请中,第一电极和第二电极在衬底上的正投影分别位于通孔在衬底的正投影的外侧是为了使第一电极在衬底上的正投影和第二电极在衬底上的正投影均 不能覆盖通孔,这样避免第一电极和第二电极阻挡穿过通孔的光。It should be noted that, in this application, the orthographic projections of the first electrode and the second electrode on the substrate are respectively located outside the orthographic projection of the through hole on the substrate, so that the orthographic projection of the first electrode on the substrate and the first Neither of the orthographic projections of the two electrodes on the substrate can cover the through hole, thus preventing the first electrode and the second electrode from blocking light passing through the through hole.
本申请的光电探测器可以应用于各种基于自由空间传输光的结构中,具体可以将该光电探测器设置于自由空间中单色光的传输路径上,利用这些光束传输的单色性、方向性以及光强的高斯分布特点,当单色光束穿过该光电探测器后,光束边缘少部分光子会进入光电探测器,从而能够实时抽头检测光信号,而不会干扰光传输。例如,当应用于WSS结构中时,将该光电探测器设置于WSS结构的自由空间中单色光的传输路径上,因此,不仅可以保证单色光信号不受干扰,而且可以保证WSS结构的体积不会增加。并且,由于该光电探测器不需要借助其他器件就可以直接从单色光的传输路径上获取光子,因此不需要复杂的机械固定件就可以固定在单色光的传输路径上,与采用现有的光纤抽头检测装置相比,可以降低整体结构复杂性和成本。The photodetector of the present application can be applied to various structures based on the transmission of light in free space. Specifically, the photodetector can be arranged on the transmission path of monochromatic light in free space, and the monochromaticity and direction of the transmission of these light beams can be used. Due to the characteristics of the Gaussian distribution of light intensity and light intensity, when the monochromatic beam passes through the photodetector, a small number of photons at the edge of the beam will enter the photodetector, so that the light signal can be detected in real time without interfering with the light transmission. For example, when applied to the WSS structure, the photodetector is arranged on the transmission path of the monochromatic light in the free space of the WSS structure. Therefore, not only the monochromatic light signal can be guaranteed not to be disturbed, but also the stability of the WSS structure can be guaranteed. Volume does not increase. In addition, since the photodetector can directly obtain photons from the transmission path of monochromatic light without the help of other devices, it can be fixed on the transmission path of monochromatic light without complex mechanical fixing parts, which is different from using existing devices. Compared with the optical fiber tap detection device, the overall structure complexity and cost can be reduced.
在实际应用中,一般P型掺杂半导体层与金属电极的电性接触性能没有N型掺杂半导体层与金属电极的电性接触性能好。因此,对于P型掺杂半导体层,可以在P型掺杂半导体层与金属电极之间先形成金属接触电极。因此,在本申请中,如果第一电极接触层为P型掺杂半导体层,可以在第一电极接触层和第一电极之间设置金属接触电极。如果第二电极接触层为P型掺杂半导体层,可以在第二电极接触层和第二电极之间设置金属接触电极。在此不作限定。In practical applications, the electrical contact performance between the P-type doped semiconductor layer and the metal electrode is generally not as good as the electrical contact performance between the N-type doped semiconductor layer and the metal electrode. Therefore, for the P-type doped semiconductor layer, a metal contact electrode can be formed first between the P-type doped semiconductor layer and the metal electrode. Therefore, in the present application, if the first electrode contact layer is a P-type doped semiconductor layer, a metal contact electrode may be provided between the first electrode contact layer and the first electrode. If the second electrode contact layer is a P-type doped semiconductor layer, a metal contact electrode may be provided between the second electrode contact layer and the second electrode. It is not limited here.
在具体实施时,一般将第二电极接触层设置为P型掺杂半导体层,因此,在本申请中,第二电极接触层为P型掺杂半导体层,光电探测器还包括位于第二电极与第二电极接触层之间的金属接触电极,以提高第二电极与第二电极接触层的电性接触性能。In specific implementation, the second electrode contact layer is generally set as a P-type doped semiconductor layer. Therefore, in this application, the second electrode contact layer is a P-type doped semiconductor layer, and the photodetector further includes a layer located on the second electrode. The metal contacts the electrode with the second electrode contact layer to improve the electrical contact performance between the second electrode and the second electrode contact layer.
本申请对第一电极和第二电极的形状不作限定。但是考虑到光电探测器的性能的对称性,第二电极呈包围通孔的闭合环形结构;第一电极呈围绕第二电极设置且具有开口的环形结构。第一电极的开口的是为了避免第一电极与第二电极发生短路,第一电极和第二电极分别从通孔的两侧引出。The present application does not limit the shapes of the first electrode and the second electrode. However, considering the symmetry of the performance of the photodetector, the second electrode has a closed annular structure surrounding the through hole; the first electrode has an annular structure arranged around the second electrode and having an opening. The opening of the first electrode is to avoid a short circuit between the first electrode and the second electrode, and the first electrode and the second electrode are drawn out from two sides of the through hole respectively.
进一步地,为了增加电极与电极接触层的接触面积,凹槽的形状可以设置为与电极形状相似,示例性的,在本申请中,第二凹槽的形状呈包围通孔的闭合环形;第一凹槽的形状呈围绕第二凹槽设置且具有开口的环形。Further, in order to increase the contact area between the electrode and the electrode contact layer, the shape of the groove can be set to be similar to the shape of the electrode. Exemplarily, in this application, the shape of the second groove is a closed ring surrounding the through hole; The shape of a groove is an annular shape with an opening arranged around the second groove.
在具体实施时,为了避免光电探测器对穿过通孔所在区域的光带来影响,通过可以贯穿沿衬底厚度方向的所有膜层,即通孔贯穿钝化层、第二电极接触层、光敏感层、第一电极接触层以及衬底。当衬底的吸收光谱与待检测光的波长不交叠时,通孔可以仅贯穿第二电极接触层、光敏感层和第一电极接触层。进一步,当衬底的吸收光谱与待检测光的波长不交叠,且第一电极接触层和衬底的外延材质相同时,通孔可以仅贯穿第二电极接触层和光敏感层。In the specific implementation, in order to avoid the photodetector from affecting the light passing through the area where the through hole is located, the through hole can penetrate all the film layers along the thickness direction of the substrate, that is, the through hole penetrates through the passivation layer, the second electrode contact layer, A photosensitive layer, a first electrode contact layer and a substrate. When the absorption spectrum of the substrate does not overlap the wavelength of the light to be detected, the through hole may only penetrate the second electrode contact layer, the photosensitive layer and the first electrode contact layer. Further, when the absorption spectrum of the substrate does not overlap the wavelength of the light to be detected, and the epitaxial material of the first electrode contact layer and the substrate is the same, the through hole can only penetrate the second electrode contact layer and the photosensitive layer.
本申请对通孔的形状不作限定,可以是任何形状,例如正多变形、圆形、椭圆形等。当通孔形状为圆形时,可以保证通孔的中心至通孔边界各处的距离相同。并且,工艺上圆形通孔更容易实现。The shape of the through hole is not limited in the present application, and it may be any shape, such as polymorphic shape, circular shape, oval shape, and the like. When the shape of the through hole is circular, it can be ensured that the distance from the center of the through hole to the boundary of the through hole is the same. Moreover, the circular via is easier to realize in the process.
在本申请中,第二电极接触层在形成时可以先形成覆盖层,然后对覆盖层进行掺杂,如果掺杂区覆盖通孔所在区域,那么通孔贯穿掺杂区后剩余的掺杂区就是第二电极接触层。如果掺杂区不覆盖通孔所在的区域,那么掺杂区即为第二电极接触层。因此,在本申请中,光电探测器中还包括与第二电极接触层同层设置的覆盖层,第二电极接触层的形状呈环形,所述覆盖层围绕所述第二电极接触层设置;第二电极接触层与覆盖层的本征材质相同,但 是掺杂浓度不同,覆盖层一般为轻掺杂,第二电极接触层一般为重掺杂。或者,第二电极接触层与覆盖层的本征材质相同,二者电学掺杂类型不同,例如覆盖层为N型掺杂,第二电极接触层为P型掺杂,或者,覆盖层为P型掺杂,第二电极接触层为N型掺杂。In the present application, when the second electrode contact layer is formed, a capping layer can be formed first, and then the capping layer can be doped. If the doping area covers the area where the via hole is located, the via hole will penetrate the remaining doping area after the doping area. It is the second electrode contact layer. If the doped region does not cover the region where the through hole is located, the doped region is the second electrode contact layer. Therefore, in the present application, the photodetector further includes a cover layer provided in the same layer as the second electrode contact layer, the shape of the second electrode contact layer is annular, and the cover layer is arranged around the second electrode contact layer; The intrinsic material of the second electrode contact layer and the cover layer is the same, but the doping concentration is different. The cover layer is generally lightly doped, and the second electrode contact layer is generally heavily doped. Alternatively, the intrinsic material of the second electrode contact layer and the cover layer are the same, and the electrical doping types of the two are different, for example, the cover layer is N-type doped, the second electrode contact layer is P-type doping, or the cover layer is P-type doping type doping, and the second electrode contact layer is N-type doped.
第二方面,本申请提供的一种芯片,包括驱动电路,以及与所述驱动电路连接的至少一个本申请上述实施例提供的任一种光电探测器。其中,光电能探测器可以将俘获的光信号转换为电信号,而驱动电路可以将该电信号放大后输出,实现对光信号的检测。In a second aspect, a chip provided by the present application includes a drive circuit, and at least one photodetector of any of the above-mentioned embodiments of the present application connected to the drive circuit. Among them, the photoelectric energy detector can convert the captured optical signal into an electrical signal, and the driving circuit can amplify the electrical signal and output it to realize the detection of the optical signal.
第三方面,本申请提供的一种光学装置,包括波长选择开关结构和至少一个光电探测器,所述光电探测器设置在所述波长选择开关结构的自由空间中单色光的传输路径上。不仅可以保证单色光信号不受干扰,而且可以保证WSS结构的体积不会增加。并且,由于该光电探测器不需要借助其他器件就可以直接从单色光的传输路径上获取光子,因此不需要复杂的机械固定件就可以固定在单色光的传输路径上,与采用现有的光纤抽头检测装置相比,可以整体降低成本和整体结构复杂性。In a third aspect, the present application provides an optical device comprising a wavelength selective switch structure and at least one photodetector, wherein the photodetector is arranged on a transmission path of monochromatic light in the free space of the wavelength selective switch structure. Not only can the monochromatic optical signal be guaranteed not to be disturbed, but also the volume of the WSS structure can be guaranteed not to increase. In addition, since the photodetector can directly obtain photons from the transmission path of monochromatic light without the help of other devices, it can be fixed on the transmission path of monochromatic light without complex mechanical fixing parts, which is different from using existing devices. Compared with the optical fiber tap detection device, the overall cost and overall structural complexity can be reduced.
第四方面,本申请提供的一种光电探测器的制备方法,包括:首先在在衬底上依次形成第一电极接触层、光敏感层和第二电极接触层,并形成至少贯穿光敏感层和第二电极接触层的通孔;接着在第二电极接触层上形成第一钝化层,并形成贯穿第一钝化层且深至第一电极接触层表面的第一凹槽和贯穿钝化层的第二凹槽;最后在第一钝化层上形成第一电极和第二电极;其中,第一电极和第二电极在衬底上的正投影分别位于通孔在衬底的正投影的外侧;第一电极和第二电极相互绝缘,第一电极通过第一凹槽与第一电极接触层电连接,第二电极通过第二凹槽与第二电极接触层电连接。其中,第一电极接触层和第二电极接触层为极性相反的掺杂半导体层,例如第一电极接触层为P型掺杂半导体层,第二电极接触层为N型掺杂半导体层,或者,第一电极接触层为N型掺杂半导体层,第二电极接触层为P型掺杂半导体层。In a fourth aspect, the present application provides a method for preparing a photodetector, comprising: firstly forming a first electrode contact layer, a photosensitive layer and a second electrode contact layer on a substrate in sequence, and forming at least a through photosensitive layer and a through hole of the second electrode contact layer; then a first passivation layer is formed on the second electrode contact layer, and a first groove and a through passivation penetrating the first passivation layer and deep to the surface of the first electrode contact layer are formed The second groove of the passivation layer; finally, the first electrode and the second electrode are formed on the first passivation layer; wherein, the orthographic projections of the first electrode and the second electrode on the substrate are respectively located on the positive side of the through hole on the substrate. The outside of the projection; the first electrode and the second electrode are insulated from each other, the first electrode is electrically connected to the first electrode contact layer through the first groove, and the second electrode is electrically connected to the second electrode contact layer through the second groove. Wherein, the first electrode contact layer and the second electrode contact layer are doped semiconductor layers with opposite polarities, for example, the first electrode contact layer is a P-type doped semiconductor layer, and the second electrode contact layer is an N-type doped semiconductor layer, Alternatively, the first electrode contact layer is an N-type doped semiconductor layer, and the second electrode contact layer is a P-type doped semiconductor layer.
采用本申请提供的上述制备方法形成的光电探测器,第一电极接触层和第二电极接触层形成PN结,当光敏感层俘获穿过通孔V0的光时,该PN结可以将光信号转换为电信号,从而实现对光信号的检测。需要指出的是,该光电探测器在结构上不限于光电二极管(Photodiode,PD)、雪崩光电二极管(Avalanche Photodiode,APD)或异质结光电晶体管(Hetero junction Photodiode,HPT)等。In the photodetector formed by the above-mentioned preparation method provided in this application, the first electrode contact layer and the second electrode contact layer form a PN junction. When the photosensitive layer captures the light passing through the through hole V0, the PN junction can convert the optical signal Converted into electrical signals, so as to realize the detection of optical signals. It should be pointed out that the photodetector is not limited in structure to a photodiode (Photodiode, PD), an avalanche photodiode (Avalanche Photodiode, APD) or a heterojunction phototransistor (Hetero junction Photodiode, HPT) and the like.
在一种可能的实现方式中,在衬底上依次形成第一电极接触层、光敏感层和第二电极接触层,并形成至少贯穿光敏感层和第二电极接触层的通孔,可以包括:先在衬底上依次形成第一电极接触层、光敏感层和覆盖层;然后在覆盖层上形成第二钝化层,并形成贯穿第二钝化层的过孔,以使露出的覆盖层呈环形或圆形;接着对露出的覆盖层进行掺杂形成第二电极接触层;之后形成至少贯穿光敏感层和第二电极接触层的通孔。In a possible implementation manner, the first electrode contact layer, the photosensitive layer and the second electrode contact layer are sequentially formed on the substrate, and through holes at least penetrating through the photosensitive layer and the second electrode contact layer are formed, which may include : First, the first electrode contact layer, the photosensitive layer and the cover layer are formed on the substrate in sequence; then the second passivation layer is formed on the cover layer, and the via hole passing through the second passivation layer is formed, so that the exposed cover The layer is annular or circular; then the exposed cover layer is doped to form a second electrode contact layer; and then a through hole penetrating at least the photosensitive layer and the second electrode contact layer is formed.
或者,在另一种可能的实现方式中,在衬底上依次形成第一电极接触层、光敏感层和第二电极接触层,并形成至少贯穿光敏感层和第二电极接触层的通孔,可以包括:先在衬底上除了中心区域之外的区域上依次形成第一电极接触层、光敏感层和覆盖层;接着在覆盖层上形成第二钝化层,并形成贯穿第二钝化层的过孔,以使露出的覆盖层呈环形;之后对露出的覆盖层进行掺杂形成第二电极接触层。Or, in another possible implementation manner, the first electrode contact layer, the photosensitive layer, and the second electrode contact layer are sequentially formed on the substrate, and a through hole penetrating at least the photosensitive layer and the second electrode contact layer is formed , which may include: firstly forming a first electrode contact layer, a photosensitive layer and a cover layer on the area of the substrate except the central area; then forming a second passivation layer on the cover layer, and forming a second passivation layer through The via hole of the chemical layer is formed, so that the exposed cover layer is annular; and then the exposed cover layer is doped to form a second electrode contact layer.
在本申请中,在对露出的覆盖层进行掺杂形成第二电极接触层之后,还包括:去除衬底的中心区域,以使形成的光电探测器中,通孔所在的区域不存在任何膜层。In the present application, after doping the exposed cover layer to form the second electrode contact layer, the method further includes: removing the central region of the substrate, so that in the formed photodetector, there is no film in the region where the through hole is located Floor.
在一种可能的实现方式中,在第二电极接触层上形成第一钝化层,并形成贯穿第一钝 化层且深至第一电极接触层表面的第一凹槽和贯穿钝化层的第二凹槽,可以包括:先形成贯穿第二钝化层、覆盖层和光敏感层的第三凹槽;接着在第二电极接触层上形成第一钝化层,从而可以使第一钝化层包覆第三凹槽的侧壁,以对第三凹槽的侧壁进行保护;然后形成贯穿第一钝化层的第二凹槽,并在第三凹槽所在的区域形成贯穿第一钝化层的第一凹槽,以使第一凹槽贯穿第一钝化层且深至第一电极接触层表面。In a possible implementation manner, a first passivation layer is formed on the second electrode contact layer, and a first groove that penetrates the first passivation layer and is deep to the surface of the first electrode contact layer and penetrates the passivation layer is formed The second groove may include: first forming a third groove penetrating the second passivation layer, the cover layer and the photosensitive layer; then forming the first passivation layer on the second electrode contact layer, so that the first passivation layer can be formed. The passivation layer covers the sidewall of the third groove to protect the sidewall of the third groove; then a second groove is formed through the first passivation layer, and a second groove through the third groove is formed in the area where the third groove is located. A first groove of the passivation layer, so that the first groove penetrates the first passivation layer and is deep to the surface of the first electrode contact layer.
可以理解的是,由于第一电极与第一电极接触层之间具有多层膜层,因此第三凹槽的深度较深,第一电极需要爬过第三凹槽的侧壁与第一电极接触层电连接,如果侧壁深度深第一电极容易在侧壁时发生断路,因此,可选的,在本申请中,在衬底上依次形成第一电极接触层、光敏感层和第二电极接触层之后,在第二电极接触层上形成第一钝化层之前,还可以包括:去除预设区域内的第二钝化层、覆盖层和光敏感层,以使剩下的覆盖层和光敏感层呈环形结构。从而后续形成的第一电极仅需要贯穿第一钝化层的第一凹槽就可以与第一电极接触层电连接。It can be understood that since there are multiple layers between the first electrode and the contact layer of the first electrode, the depth of the third groove is relatively deep, and the first electrode needs to climb over the sidewall of the third groove and the first electrode. The contact layer is electrically connected. If the depth of the sidewall is deep, the first electrode is likely to be disconnected at the sidewall. Therefore, optionally, in this application, the first electrode contact layer, the photosensitive layer and the second electrode are sequentially formed on the substrate. After the electrode contact layer, and before forming the first passivation layer on the second electrode contact layer, the method may further include: removing the second passivation layer, the cover layer and the photosensitive layer in the preset area, so that the remaining cover layer and the photosensitive layer are removed. The sensitive layer has a ring structure. Therefore, the subsequently formed first electrode only needs to penetrate the first groove of the first passivation layer to be electrically connected to the first electrode contact layer.
如前所述,在本申请中,第一电极接触层和第二电极接触层中,一个电极接触层为P型掺杂半导体层,另一个电极接触层为N型掺杂半导体层。一般P型掺杂半导体层与金属电极的电性接触性能没有N型掺杂半导体层与金属电极的电性接触性能好。因此,对于P型掺杂半导体层,可以在P型掺杂半导体层与金属电极之间先形成金属接触电极。因此,在本申请中,如果第一电极接触层为P型掺杂半导体层,可以在第一电极接触层和第一电极之间设置金属接触电极。如果第二电极接触层为P型掺杂半导体层,可以在第二电极接触层和第二电极之间设置金属接触电极。在此不作限定。As mentioned above, in the present application, among the first electrode contact layer and the second electrode contact layer, one electrode contact layer is a P-type doped semiconductor layer, and the other electrode contact layer is an N-type doped semiconductor layer. Generally, the electrical contact performance between the P-type doped semiconductor layer and the metal electrode is not as good as the electrical contact performance between the N-type doped semiconductor layer and the metal electrode. Therefore, for the P-type doped semiconductor layer, a metal contact electrode can be formed first between the P-type doped semiconductor layer and the metal electrode. Therefore, in the present application, if the first electrode contact layer is a P-type doped semiconductor layer, a metal contact electrode may be provided between the first electrode contact layer and the first electrode. If the second electrode contact layer is a P-type doped semiconductor layer, a metal contact electrode may be provided between the second electrode contact layer and the second electrode. It is not limited here.
在具体实施时,一般将第二电极接触层设置为P型掺杂半导体层,因此,在本申请中,在衬底上依次形成第一电极接触层、光敏感层和第二电极接触层之后,在第二电极接触层上形成第一钝化层之前,还可以包括:在第二电极接触层上形成环形的金属接触电极,并对金属接触电极进行退火,以使将要形成的第二电极通过金属接触电极与第二电极接触层电连接。In specific implementation, the second electrode contact layer is generally set as a P-type doped semiconductor layer. Therefore, in this application, after the first electrode contact layer, the photosensitive layer and the second electrode contact layer are sequentially formed on the substrate , before forming the first passivation layer on the second electrode contact layer, may further include: forming a ring-shaped metal contact electrode on the second electrode contact layer, and annealing the metal contact electrode, so that the second electrode to be formed The second electrode contact layer is electrically connected through the metal contact electrode.
附图说明Description of drawings
图1为相关技术中光纤抽头检测装置进行检测的示意图;FIG. 1 is a schematic diagram of the detection performed by an optical fiber tap detection device in the related art;
图2为相关技术中光纤抽头检测装置应用于WSS结构中的结构示意图;Fig. 2 is the structural representation that the optical fiber tap detection device is applied in the WSS structure in the related art;
图3a为本申请一种实施例中光电探测器的俯视结构示意图;FIG. 3a is a schematic top-view structural diagram of a photodetector in an embodiment of the present application;
图3b为图3a所示光电探测器沿AA’方向的剖面结构示意图;Fig. 3b is a schematic cross-sectional structure diagram of the photodetector shown in Fig. 3a along the AA' direction;
图3c为图3a所示光电探测器沿BB’方向的剖面结构示意图;Fig. 3c is a schematic cross-sectional structure diagram of the photodetector shown in Fig. 3a along the BB' direction;
图4为本申请一种实施例所提供的光电探测器的制备方法的流程示意图;4 is a schematic flowchart of a method for preparing a photodetector according to an embodiment of the present application;
图5为本申请又一实施例所提供的光电探测器的制备方法的流程示意图;5 is a schematic flowchart of a method for preparing a photodetector provided by another embodiment of the present application;
图6a为执行本申请中制备方法的步骤后形成的结构的俯视图;6a is a top view of a structure formed after performing the steps of the preparation method in the present application;
图6b为图6a所示结构沿AA’方向的剖面结构示意图;Figure 6b is a schematic cross-sectional structure diagram of the structure shown in Figure 6a along the AA' direction;
图7a为执行本申请中制备方法的步骤后形成的结构的俯视图;7a is a top view of a structure formed after performing the steps of the preparation method in the present application;
图7b为图7a所示结构沿AA’方向的剖面结构示意图;Fig. 7b is a schematic cross-sectional structure diagram of the structure shown in Fig. 7a along the AA' direction;
图8a为执行本申请中制备方法的步骤后形成的结构的俯视图;8a is a top view of a structure formed after performing the steps of the preparation method in the present application;
图8b为图8a所示结构沿AA’方向的剖面结构示意图;Fig. 8b is a schematic cross-sectional structure diagram of the structure shown in Fig. 8a along the AA' direction;
图9a为执行本申请中制备方法的步骤后形成的结构的俯视图;9a is a top view of a structure formed after performing the steps of the preparation method in the present application;
图9b为图9a所示结构沿AA’方向的剖面结构示意图;Figure 9b is a schematic cross-sectional structure diagram of the structure shown in Figure 9a along the AA' direction;
图10a为执行本申请中制备方法的步骤后形成的结构的俯视图;10a is a top view of a structure formed after performing the steps of the preparation method in the present application;
图10b为图10a所示结构沿AA’方向的剖面结构示意图;Fig. 10b is a schematic cross-sectional structure diagram of the structure shown in Fig. 10a along the AA' direction;
图11a为执行本申请中制备方法的步骤后形成的结构的俯视图;11a is a top view of the structure formed after performing the steps of the preparation method in the present application;
图11b为图11a所示结构沿AA’方向的剖面结构示意图;Figure 11b is a schematic cross-sectional structure diagram of the structure shown in Figure 11a along the AA' direction;
图11c为图11a所示结构沿BB’方向的剖面结构示意图;Fig. 11c is a schematic cross-sectional structure diagram of the structure shown in Fig. 11a along the BB' direction;
图12a为执行本申请中制备方法的步骤后形成的结构的俯视图;Figure 12a is a top view of the structure formed after performing the steps of the preparation method in the present application;
图12b为图12a所示结构沿AA’方向的剖面结构示意图;Figure 12b is a schematic cross-sectional structure diagram of the structure shown in Figure 12a along the AA' direction;
图12c为图12a所示结构沿BB’方向的剖面结构示意图;Figure 12c is a schematic cross-sectional structure diagram of the structure shown in Figure 12a along the BB' direction;
图13a为执行本申请中制备方法的步骤后形成的结构的俯视图;Figure 13a is a top view of the structure formed after performing the steps of the preparation method in the present application;
图13b为图13a所示结构沿AA’方向的剖面结构示意图;Figure 13b is a schematic cross-sectional structure diagram of the structure shown in Figure 13a along the AA' direction;
图13c为图13a所示结构沿BB’方向的剖面结构示意图;Figure 13c is a schematic cross-sectional structure diagram of the structure shown in Figure 13a along the BB' direction;
图14a为本申请又一种实施例中光电探测器的俯视结构示意图;FIG. 14a is a schematic top-view structural diagram of a photodetector in yet another embodiment of the present application;
图14b为图14a所示光电探测器沿AA’方向的剖面结构示意图;Fig. 14b is a schematic cross-sectional structure diagram of the photodetector shown in Fig. 14a along the AA' direction;
图14c为图14a所示光电探测器沿BB’方向的剖面结构示意图;Fig. 14c is a schematic cross-sectional structure diagram of the photodetector shown in Fig. 14a along the BB' direction;
图15a为本申请又一种实施例中光电探测器的俯视结构示意图;FIG. 15a is a schematic top-view structural diagram of a photodetector in yet another embodiment of the present application;
图15b为图15a所示光电探测器沿AA’方向的剖面结构示意图;Fig. 15b is a schematic cross-sectional structure diagram of the photodetector shown in Fig. 15a along the AA' direction;
图15c为图15a所示光电探测器沿BB’方向的剖面结构示意图;Fig. 15c is a schematic cross-sectional structure diagram of the photodetector shown in Fig. 15a along the BB' direction;
图16为本申请又一实施例所提供的光电探测器的制备方法的流程示意图;16 is a schematic flowchart of a method for fabricating a photodetector provided by another embodiment of the present application;
图17a为执行本申请中制备方法的步骤后形成的结构的俯视图;Figure 17a is a top view of the structure formed after performing the steps of the preparation method of the present application;
图17b为图17a所示结构沿AA’方向的剖面结构示意图;Fig. 17b is a schematic cross-sectional structure diagram of the structure shown in Fig. 17a along the AA' direction;
图18a为图14a所示光电探测器沿AA’方向的又一种剖面结构示意图;Fig. 18a is another schematic cross-sectional structure diagram of the photodetector shown in Fig. 14a along the AA' direction;
图18b为图14a所示光电探测器沿BB’方向的又一种剖面结构示意图;Fig. 18b is another schematic cross-sectional structure diagram of the photodetector shown in Fig. 14a along the BB' direction;
图19a为图15a所示光电探测器沿AA’方向的又一种剖面结构示意图;Fig. 19a is another schematic cross-sectional structure diagram of the photodetector shown in Fig. 15a along the AA' direction;
图19b为图15a所示光电探测器沿BB’方向的又一种剖面结构示意图;Fig. 19b is another schematic cross-sectional structure diagram of the photodetector shown in Fig. 15a along the BB' direction;
图20为本申请又一实施例所提供的光电探测器的制备方法的流程示意图;20 is a schematic flowchart of a method for fabricating a photodetector provided by another embodiment of the present application;
图21a为执行本申请中制备方法的步骤后形成的结构的俯视图;Figure 21a is a top view of the structure formed after performing the steps of the preparation method in the present application;
图21b为图21a所示结构沿AA’方向的剖面结构示意图;Figure 21b is a schematic cross-sectional structure diagram of the structure shown in Figure 21a along the AA' direction;
图22a为图15a所示光电探测器沿AA’方向的又一种剖面结构示意图;Fig. 22a is another schematic cross-sectional structure diagram of the photodetector shown in Fig. 15a along the AA' direction;
图22b为图15a所示光电探测器沿BB’方向的又一种剖面结构示意图;Fig. 22b is another schematic cross-sectional structure diagram of the photodetector shown in Fig. 15a along the BB' direction;
图23为本申请又一实施例所提供的光电探测器的制备方法的流程示意图;23 is a schematic flowchart of a method for fabricating a photodetector provided by another embodiment of the present application;
图24a为图15a所示光电探测器沿AA’方向的又一种剖面结构示意图;Fig. 24a is another schematic cross-sectional structure diagram of the photodetector shown in Fig. 15a along the AA' direction;
图24b为图15a所示光电探测器沿BB’方向的又一种剖面结构示意图;Figure 24b is another schematic cross-sectional structure diagram of the photodetector shown in Figure 15a along the BB' direction;
图25为本申请一种实施例提供的芯片的结构示意图;FIG. 25 is a schematic structural diagram of a chip provided by an embodiment of the application;
图26为本申请一种实施例提供的芯片中多个光电探测器的排列方式示意图;26 is a schematic diagram of an arrangement of a plurality of photodetectors in a chip provided by an embodiment of the application;
图27为本申请又一种实施例提供的芯片中多个光电探测器的排列方式示意图。FIG. 27 is a schematic diagram of an arrangement of a plurality of photodetectors in a chip according to another embodiment of the present application.
具体实施方式Detailed ways
为了使本申请的目的、技术方案和优点更加清楚,下面将结合附图对本申请作进一步地详细描述。然而,示例实施方式能够以多种形式实施,且不应被理解为限于在此阐述的 实施方式;相反,提供这些实施方式使得本申请更全面和完整,并将示例实施方式的构思全面地传达给本领域的技术人员。在图中相同的附图标记表示相同或类似的结构,因而将省略对它们的重复描述。本申请中所描述的表达位置与方向的词,均是以附图为例进行的说明,但根据需要也可以做出改变,所做改变均包含在本申请保护范围内。本申请的附图仅用于示意相对位置关系不代表真实比例。In order to make the objectives, technical solutions and advantages of the present application clearer, the present application will be further described in detail below with reference to the accompanying drawings. Example embodiments, however, can be embodied in various forms and should not be construed as limited to the embodiments set forth herein; rather, these embodiments are provided so that this application will be thorough and complete, and will fully convey the concept of example embodiments to those skilled in the art. The same reference numerals in the drawings denote the same or similar structures, and thus their repeated descriptions will be omitted. The words expressing position and direction described in this application are all described by taking the accompanying drawings as an example, but changes can also be made according to needs, and the changes are all included in the protection scope of this application. The drawings in the present application are only used to illustrate the relative positional relationship and do not represent the actual scale.
需要说明的是,在以下描述中阐述了具体细节以便于充分理解本申请。但是本申请能够以多种不同于在此描述的其它方式来实施,本领域技术人员可以在不违背本申请内涵的情况下做类似推广。因此本申请不受下面公开的具体实施方式的限制。说明书后续描述为实施本申请的较佳实施方式,然所述描述乃以说明本申请的一般原则为目的,并非用以限定本申请的范围。本申请的保护范围当视所附权利要求所界定者为准。It should be noted that specific details are set forth in the following description in order to facilitate a full understanding of the present application. However, the present application can be implemented in many other ways different from those described herein, and those skilled in the art can make similar promotions without departing from the connotation of the present application. Accordingly, the present application is not limited by the specific embodiments disclosed below. Subsequent descriptions in the specification are preferred embodiments for implementing the present application. However, the descriptions are for the purpose of illustrating the general principles of the present application and are not intended to limit the scope of the present application. The scope of protection of this application should be determined by the appended claims.
为了方便理解本申请实施例提供的光电探测器,下面首先说明一下其具体应用场景。本申请实施例提供的光电探测器可以广泛应用在各种基于自由空间传输光的结构。比如应用到WSS结构中,将光电探测器设置在WSS结构的自由空间中单色光的传输路径上,当单色光束穿过光电探测器后,光束边缘少部分光子会进入光电探测器,从而能够实时抽头检测光信号,而不会干扰光传输。In order to facilitate the understanding of the photodetector provided by the embodiment of the present application, the specific application scenario of the photodetector is first described below. The photodetectors provided in the embodiments of the present application can be widely used in various structures based on free space transmission of light. For example, when applied to the WSS structure, the photodetector is arranged on the transmission path of monochromatic light in the free space of the WSS structure. When the monochromatic beam passes through the photodetector, a small number of photons at the edge of the beam will enter the photodetector, thereby Capable of real-time tap detection of optical signals without interfering with optical transmission.
在具体实施时,该光电探测器还可以应用在航天领域,例如一些卫星设备之间的通信会采用自由空间的光通信技术,而该光电探测器可以对这些光通信进行实时检测。During specific implementation, the photodetector can also be applied in the aerospace field. For example, the communication between some satellite devices will use free space optical communication technology, and the photodetector can perform real-time detection on these optical communications.
为了便于理解本申请实施例提供的光电探测器,下面将结合具体实施例和附图对本申请提供的光电探测器、其制备方法、芯片及光学装置进行具体说明。In order to facilitate the understanding of the photodetector provided by the embodiments of the present application, the photodetector, its preparation method, chip and optical device provided by the present application will be described in detail below with reference to specific embodiments and accompanying drawings.
图3a示例性示出了本申请一种实施例中光电探测器的俯视结构示意图,图3b为图3a所示光电探测器沿AA’方向的剖面结构示意图,图3c为图3a所示光电探测器沿BB’方向的剖面结构示意图。Fig. 3a exemplarily shows a schematic top view structure of a photodetector in an embodiment of the present application, Fig. 3b is a schematic cross-sectional structure diagram of the photodetector shown in Fig. 3a along the AA' direction, and Fig. 3c is a photodetector shown in Fig. 3a Schematic diagram of the cross-sectional structure of the device along the BB' direction.
参见图3a至图3c,本申请提供的光电探测器10,包括:衬底11、依次层叠设置于衬底11上的第一电极接触层12、光敏感层13、第二电极接触层14和钝化层15,以及位于钝化层15上的第一电极161和第二电极162;其中,第一电极接触层12和第二电极接触层14为极性相反的掺杂半导体层,例如第一电极接触层12为P型掺杂半导体层,第二电极接触层14为N型掺杂半导体层,或者,第一电极接触层12为N型掺杂半导体层,第二电极接触层14为P型掺杂半导体层。该光电探测器10还包括至少贯穿光敏感层13和第二电极接触层14的通孔V0;第一电极161和第二电极162在衬底11上的正投影分别位于通孔V0在衬底11的正投影的外侧;第一电极161和第二电极162相互绝缘,第一电极161通过贯穿位于第一电极161与第一电极接触层12之间的膜层的第一凹槽V1与第一电极接触层12电连接,第二电极162通过贯穿钝化层15的第二凹槽V2与第二电极接触层14电连接。3a to 3c, the photodetector 10 provided by the present application includes: a substrate 11, a first electrode contact layer 12, a photosensitive layer 13, a second electrode contact layer 14 and The passivation layer 15, and the first electrode 161 and the second electrode 162 located on the passivation layer 15; wherein, the first electrode contact layer 12 and the second electrode contact layer 14 are doped semiconductor layers with opposite polarities, such as the first electrode contact layer 12 and the second electrode contact layer 14. An electrode contact layer 12 is a P-type doped semiconductor layer, the second electrode contact layer 14 is an N-type doped semiconductor layer, or, the first electrode contact layer 12 is an N-type doped semiconductor layer, and the second electrode contact layer 14 is P-type doped semiconductor layer. The photodetector 10 further includes a through hole V0 penetrating at least the photosensitive layer 13 and the second electrode contact layer 14; The outer side of the orthographic projection of 11; the first electrode 161 and the second electrode 162 are insulated from each other, and the first electrode 161 passes through the first groove V1 and the first electrode 161 through the film layer between the first electrode 161 and the first electrode contact layer 12. An electrode contact layer 12 is electrically connected, and the second electrode 162 is electrically connected to the second electrode contact layer 14 through the second groove V2 penetrating the passivation layer 15 .
在该光电探测器中,第一电极接触层12和第二电极接触层14形成PN结,当光敏感层13俘获穿过通孔V0的光时,该PN结可以将光信号转换为电信号,从而实现对光信号的检测,并且保证穿过通孔V0的光不受干扰。需要指出的是,该光电探测器在结构上不限于光电二极管(Photodiode,PD)、雪崩光电二极管(Avalanche Photodiode,APD)或异质结光电晶体管(Hetero junction Photodiode,HPT)等。In this photodetector, the first electrode contact layer 12 and the second electrode contact layer 14 form a PN junction, which can convert the optical signal into an electrical signal when the photosensitive layer 13 captures the light passing through the via V0 , so as to realize the detection of the optical signal, and ensure that the light passing through the through hole V0 is not disturbed. It should be pointed out that the photodetector is not limited in structure to a photodiode (Photodiode, PD), an avalanche photodiode (Avalanche Photodiode, APD) or a heterojunction phototransistor (Hetero junction Photodiode, HPT) and the like.
本申请的光电探测器可以应用于各种基于自由空间传输光的结构中,具体可以将该光电探测器设置于自由空间中单色光的传输路径上,利用这些光束传输的单色性、方向性以 及光强的高斯分布特点,当单色光束穿过该光电探测器的通孔区域后,光束边缘少部分光子会进入光电探测器,从而能够实时抽头检测光信号,而不会干扰光传输。例如,当应用于WSS结构中时,将该光电探测器设置于WSS结构的自由空间中单色光的传输路径上,因此,不仅可以保证单色光信号不受干扰,而且可以保证WSS结构的体积不会增加。并且,由于该光电探测器不需要借助其他器件就可以直接从单色光的传输路径上获取光子,因此不需要复杂的机械固定件就可以固定在单色光的传输路径上,与采用现有的光纤抽头检测装置相比,可以降低整体结构复杂性和成本。The photodetector of the present application can be applied to various structures based on the transmission of light in free space. Specifically, the photodetector can be arranged on the transmission path of monochromatic light in free space, and the monochromaticity and direction of the transmission of these light beams can be used. After the monochromatic beam passes through the through-hole area of the photodetector, a small number of photons at the edge of the beam will enter the photodetector, so that the optical signal can be detected in real time without interfering with the optical transmission. . For example, when applied to the WSS structure, the photodetector is arranged on the transmission path of the monochromatic light in the free space of the WSS structure. Therefore, not only the monochromatic light signal can be guaranteed not to be disturbed, but also the stability of the WSS structure can be guaranteed. Volume does not increase. In addition, since the photodetector can directly obtain photons from the transmission path of monochromatic light without the help of other devices, it can be fixed on the transmission path of monochromatic light without complex mechanical fixing parts, which is different from using existing devices. Compared with the optical fiber tap detection device, the overall structure complexity and cost can be reduced.
图4示例性示出了本申请一种实施例所提供的光电探测器的制备方法的流程示意图。如图4所示,该方法主要包括以下步骤:FIG. 4 exemplarily shows a schematic flowchart of a method for fabricating a photodetector provided by an embodiment of the present application. As shown in Figure 4, the method mainly includes the following steps:
S401、在衬底上依次形成第一电极接触层、光敏感层和第二电极接触层,并形成至少贯穿光敏感层和第二电极接触层的通孔;第一电极接触层和第二电极接触层为极性相反的掺杂半导体层。S401, forming a first electrode contact layer, a photosensitive layer and a second electrode contact layer on the substrate in sequence, and forming through holes at least penetrating the photosensitive layer and the second electrode contact layer; the first electrode contact layer and the second electrode contact layer The contact layer is a doped semiconductor layer of opposite polarity.
S402、在第二电极接触层上形成第一钝化层,并形成贯穿第一钝化层且深至第一电极接触层表面的第一凹槽和贯穿钝化层的第二凹槽。S402 , forming a first passivation layer on the second electrode contact layer, and forming a first groove penetrating the first passivation layer and deep to the surface of the first electrode contact layer and a second groove penetrating the passivation layer.
S403、在第一钝化层上形成第一电极和第二电极;其中,第一电极和第二电极在衬底上的正投影分别位于通孔在衬底的正投影的外侧;第一电极和第二电极相互绝缘,第一电极通过第一凹槽与第一电极接触层电连接,第二电极通过第二凹槽与第二电极接触层电连接。S403, forming a first electrode and a second electrode on the first passivation layer; wherein the orthographic projections of the first electrode and the second electrode on the substrate are respectively located outside the orthographic projection of the through hole on the substrate; the first electrode The second electrode is insulated from each other, the first electrode is electrically connected to the first electrode contact layer through the first groove, and the second electrode is electrically connected to the second electrode contact layer through the second groove.
在一种可能的实现方式中,步骤S401在衬底上依次形成第一电极接触层、光敏感层和第二电极接触层,并形成至少贯穿光敏感层和第二电极接触层的通孔,可以包括:先在衬底上依次形成第一电极接触层、光敏感层和覆盖层;接着在覆盖层上形成第二钝化层,并形成贯穿第二钝化层的过孔,以使露出的覆盖层呈环形或圆形;然后对露出的覆盖层进行掺杂形成第二电极接触层;之后形成至少贯穿光敏感层和第二电极接触层的通孔。In a possible implementation manner, step S401 sequentially forms the first electrode contact layer, the photosensitive layer and the second electrode contact layer on the substrate, and forms at least through holes penetrating the photosensitive layer and the second electrode contact layer, It may include: firstly forming a first electrode contact layer, a photosensitive layer and a cover layer on the substrate in sequence; then forming a second passivation layer on the cover layer, and forming a via hole penetrating the second passivation layer, so as to expose the The cover layer is annular or circular; then the exposed cover layer is doped to form a second electrode contact layer; and then a through hole penetrating at least the photosensitive layer and the second electrode contact layer is formed.
在又一种可能的实现方式中,步骤S401在衬底上依次形成第一电极接触层、光敏感层和第二电极接触层,并形成至少贯穿光敏感层和第二电极接触层的通孔,可以包括:先在衬底上除了中心区域之外的区域上依次形成第一电极接触层、光敏感层和覆盖层,从而在形成第一电极接触层、光敏感层和覆盖层的同时,在中心区域形成贯穿第一电极接触层、光敏感层和覆盖层的通孔;接着在覆盖层上形成第二钝化层,并形成贯穿第二钝化层的过孔,以使露出的覆盖层呈环形;然后对露出的覆盖层进行掺杂形成第二电极接触层。其中,中心区域为通孔所在的区域,可以为圆形区域。进一步地,对露出的覆盖层进行掺杂形成第二电极接触层之后,还包括:去除衬底的中心区域,从而使通孔还贯穿衬底。In yet another possible implementation manner, step S401 sequentially forms a first electrode contact layer, a photosensitive layer and a second electrode contact layer on the substrate, and forms at least through holes penetrating the photosensitive layer and the second electrode contact layer , may include: firstly forming the first electrode contact layer, the photosensitive layer and the cover layer on the substrate except the central area, so that while the first electrode contact layer, the light sensitive layer and the cover layer are formed, A through hole is formed in the central area through the first electrode contact layer, the photosensitive layer and the cover layer; then a second passivation layer is formed on the cover layer, and a via hole through the second passivation layer is formed, so that the exposed cover The layer is annular; the exposed cap layer is then doped to form a second electrode contact layer. The central area is the area where the through hole is located, which may be a circular area. Further, after doping the exposed capping layer to form the second electrode contact layer, the method further includes: removing the central region of the substrate, so that the through hole still penetrates the substrate.
在一种可能的实现方式中,步骤S402在第二电极接触层上形成第一钝化层,并形成贯穿第一钝化层且深至第一电极接触层表面的第一凹槽和贯穿钝化层的第二凹槽,可以包括:先形成贯穿第二钝化层、覆盖层和光敏感层的第三凹槽;接着在第二电极接触层上形成第一钝化层,从而可以使第一钝化层包覆第三凹槽的侧壁,以对第三凹槽的侧壁进行保护;然后形成贯穿第一钝化层的第二凹槽,并在第三凹槽所在的区域形成贯穿第一钝化层的第一凹槽,以使第一凹槽贯穿第一钝化层且深至第一电极接触层表面。In a possible implementation manner, step S402 forms a first passivation layer on the second electrode contact layer, and forms a first groove and a through passivation penetrating the first passivation layer and deep to the surface of the first electrode contact layer The second groove of the passivation layer may include: firstly forming a third groove penetrating the second passivation layer, the cover layer and the photosensitive layer; then forming the first passivation layer on the second electrode contact layer, so that the first passivation layer can be formed. A passivation layer covers the sidewall of the third groove to protect the sidewall of the third groove; then a second groove is formed through the first passivation layer, and is formed in the area where the third groove is located The first groove penetrates through the first passivation layer, so that the first groove penetrates through the first passivation layer and is deep to the surface of the first electrode contact layer.
可以理解的是,由于第一电极与第一电极接触层之间具有多层膜层,因此第三凹槽的深度较深,第一电极需要爬过第三凹槽的侧壁与第一电极接触层电连接,如果侧壁深度深第一电极容易在侧壁时发生断路,因此,可选的,在本申请中,在衬底上依次形成第一电 极接触层、光敏感层和第二电极接触层之后,在第二电极接触层上形成第一钝化层之前,还可以包括:去除预设区域内的第二钝化层、覆盖层和光敏感层,以使剩下的覆盖层和光敏感层呈环形结构。从而后续形成的第一电极仅需要贯穿第一钝化层的第一凹槽就可以与第一电极接触层电连接。It can be understood that since there are multiple layers between the first electrode and the contact layer of the first electrode, the depth of the third groove is relatively deep, and the first electrode needs to climb over the sidewall of the third groove and the first electrode. The contact layer is electrically connected. If the depth of the sidewall is deep, the first electrode is likely to be disconnected at the sidewall. Therefore, optionally, in this application, the first electrode contact layer, the photosensitive layer and the second electrode are sequentially formed on the substrate. After the electrode contact layer, and before forming the first passivation layer on the second electrode contact layer, the method may further include: removing the second passivation layer, the cover layer and the photosensitive layer in the preset area, so that the remaining cover layer and the photosensitive layer are removed. The sensitive layer has a ring structure. Therefore, the subsequently formed first electrode only needs to penetrate the first groove of the first passivation layer to be electrically connected to the first electrode contact layer.
如前所述,在本申请中,第一电极接触层和第二电极接触层中,一个电极接触层为P型掺杂半导体层,另一个电极接触层为N型掺杂半导体层。一般P型掺杂半导体层与金属电极的电性接触性能没有N型掺杂半导体层与金属电极的电性接触性能好。因此,对于P型掺杂半导体层,可以在P型掺杂半导体层与金属电极之间先形成金属接触电极。因此,在本申请中,如果第一电极接触层为P型掺杂半导体层,可以在第一电极接触层和第一电极之间设置金属接触电极。如果第二电极接触层为P型掺杂半导体层,可以在第二电极接触层和第二电极之间设置金属接触电极。在此不作限定。As mentioned above, in the present application, among the first electrode contact layer and the second electrode contact layer, one electrode contact layer is a P-type doped semiconductor layer, and the other electrode contact layer is an N-type doped semiconductor layer. Generally, the electrical contact performance between the P-type doped semiconductor layer and the metal electrode is not as good as the electrical contact performance between the N-type doped semiconductor layer and the metal electrode. Therefore, for the P-type doped semiconductor layer, a metal contact electrode can be formed first between the P-type doped semiconductor layer and the metal electrode. Therefore, in the present application, if the first electrode contact layer is a P-type doped semiconductor layer, a metal contact electrode may be provided between the first electrode contact layer and the first electrode. If the second electrode contact layer is a P-type doped semiconductor layer, a metal contact electrode may be provided between the second electrode contact layer and the second electrode. It is not limited here.
在具体实施时,一般将第二电极接触层设置为P型掺杂半导体层,因此,在本申请中,第二电极接触层为P型掺杂半导体层,在衬底上依次形成第一电极接触层、光敏感层和第二电极接触层之后,在第二电极接触层上形成第一钝化层之前,还可以包括:在第二电极接触层上形成环形的金属接触电极,并对金属接触电极进行退火,以使将要形成的第二电极通过金属接触电极与第二电极接触层电连接。In the specific implementation, the second electrode contact layer is generally set as a P-type doped semiconductor layer. Therefore, in this application, the second electrode contact layer is a P-type doped semiconductor layer, and the first electrodes are sequentially formed on the substrate. After the contact layer, the photosensitive layer and the second electrode contact layer, and before the first passivation layer is formed on the second electrode contact layer, the method may further include: forming a ring-shaped metal contact electrode on the second electrode contact layer, and contacting the metal The contact electrode is annealed so that the second electrode to be formed is electrically connected to the second electrode contact layer through the metal contact electrode.
下面以第一电极接触层为N型掺杂半导体层,第二电极接触层为P型掺杂半导体层,且在第二电极接触层和第二电极之间设置有金属接触电极为例,结合具体实施例对本申请进行详细说明。需要说明的是,本实施例是为了更好的解释本发明,但不限制本申请。In the following, taking the first electrode contact layer as an N-type doped semiconductor layer, the second electrode contact layer as a P-type doped semiconductor layer, and a metal contact electrode disposed between the second electrode contact layer and the second electrode as an example, the combination The specific embodiments describe the present application in detail. It should be noted that this embodiment is for better explanation of the present invention, but does not limit the present application.
实施例一、 Embodiment 1.
图5示例性示出了本申请又一实施例所提供的光电探测器的制备方法的流程示意图。如图5所示,该方法主要包括以下步骤:FIG. 5 exemplarily shows a schematic flowchart of a method for fabricating a photodetector provided by another embodiment of the present application. As shown in Figure 5, the method mainly includes the following steps:
S501、在衬底上依次形成第一电极接触层、光敏感层和覆盖层。S501 , forming a first electrode contact layer, a photosensitive layer and a cover layer on the substrate in sequence.
参见图6a和图6b,图6a为执行本申请中制备方法的步骤后形成的结构的俯视图,图6b为图6a所示结构沿AA’方向的剖面结构示意图。可以先在衬底11上外延生长第一电极接触层12,接着在第一电极接触层12上外延生长光敏感层13,之后再在光敏感层13上外延生长覆盖层17。在具体实施时,第一电极接触层12、光敏感层13以及覆盖层17的材料可以是InP/InGaAs、Ge/Si、GaN、GaAs等材料体系,但不限于此。6a and 6b, FIG. 6a is a top view of the structure formed after performing the steps of the preparation method in the present application, and FIG. 6b is a schematic cross-sectional structure diagram of the structure shown in FIG. 6a along the AA' direction. First, the first electrode contact layer 12 may be epitaxially grown on the substrate 11 , then the photosensitive layer 13 may be epitaxially grown on the first electrode contact layer 12 , and then the cover layer 17 may be epitaxially grown on the photosensitive layer 13 . In specific implementation, the materials of the first electrode contact layer 12 , the photosensitive layer 13 and the capping layer 17 may be InP/InGaAs, Ge/Si, GaN, GaAs and other material systems, but are not limited thereto.
S502、在覆盖层上形成第二钝化层,并形成贯穿第二钝化层的过孔,以使露出的覆盖层呈环形或圆形。S502 , forming a second passivation layer on the cover layer, and forming a via hole penetrating the second passivation layer, so that the exposed cover layer is annular or circular.
参见图7a和图7b,图7a为执行本申请中制备方法的步骤后形成的结构的俯视图,图7b为图7a所示结构沿AA’方向的剖面结构示意图。为了便于后续实现对覆盖层17的进行掺杂,可以先在覆盖层17上形成第二钝化层152,并对第二钝化层152进行构图,形成贯穿第二钝化层152的过孔,以使露出的覆盖层17呈环形或如图7a所示的圆形或者正多边形等,在此不作限定。7a and 7b, FIG. 7a is a top view of the structure formed after performing the steps of the preparation method in the present application, and FIG. 7b is a schematic cross-sectional structure diagram of the structure shown in FIG. 7a along the AA' direction. In order to facilitate the subsequent doping of the capping layer 17 , a second passivation layer 152 may be formed on the capping layer 17 first, and the second passivation layer 152 may be patterned to form via holes penetrating the second passivation layer 152 , so that the exposed cover layer 17 is annular or circular or regular polygon as shown in FIG. 7 a , which is not limited herein.
S503、对露出的覆盖层进行掺杂形成第二电极接触层。S503 , doping the exposed cover layer to form a second electrode contact layer.
参见图8a和图8b,图8a为执行本申请中制备方法的步骤后形成的结构的俯视图,图8b为图8a所示结构沿AA’方向的剖面结构示意图。可以通过扩散或者离子注入工艺对露出的覆盖层17进行掺杂形成第二电极接触层14。即第二电极接触层14与覆盖层17的外延材料是相同,二者本征材质相同,但是掺杂浓度不同,覆盖层17一般为轻掺杂,第 二电极接触层14一般为重掺杂。或者,第二电极接触层14与覆盖层17的本征材质相同,二者电学掺杂类型不同,例如覆盖层17为N型掺杂,第二电极接触层14为P型掺杂,或者,覆盖层17为P型掺杂,第二电极接触层14为N型掺杂。Referring to Figures 8a and 8b, Figure 8a is a top view of a structure formed after performing the steps of the preparation method in the present application, and Figure 8b is a schematic cross-sectional structure diagram of the structure shown in Figure 8a along the AA' direction. The second electrode contact layer 14 may be formed by doping the exposed capping layer 17 through a diffusion or ion implantation process. That is, the epitaxial materials of the second electrode contact layer 14 and the cover layer 17 are the same, the intrinsic materials of the two are the same, but the doping concentration is different, the cover layer 17 is generally lightly doped, and the second electrode contact layer 14 is generally heavily doped . Alternatively, the intrinsic material of the second electrode contact layer 14 and the cover layer 17 are the same, and the electrical doping types of the two are different, for example, the cover layer 17 is N-type doped, and the second electrode contact layer 14 is P-type doped, or, The capping layer 17 is P-type doped, and the second electrode contact layer 14 is N-type doped.
本申请中,可以将第二电极接触层的边界形状和后续形成的通孔的形状设计为相同,且将第二电极接触层的中心与后续形成的通孔的中心设计为重合,保证光电探测器在垂直于光通过方向的同一平面的性能尽可能中心对称。In this application, the boundary shape of the second electrode contact layer and the shape of the subsequently formed through hole can be designed to be the same, and the center of the second electrode contact layer and the center of the subsequently formed through hole can be designed to overlap, so as to ensure photoelectric detection. The performance of the device in the same plane perpendicular to the light passing direction is as centrosymmetric as possible.
S504、在第二电极接触层上形成环形的金属接触电极,并对金属接触电极进行退火,以使将要形成的第二电极通过金属接触电极与第二电极接触层电连接。S504 , forming an annular metal contact electrode on the second electrode contact layer, and annealing the metal contact electrode, so that the second electrode to be formed is electrically connected to the second electrode contact layer through the metal contact electrode.
参见图9a和图9b,图9a为执行本申请中制备方法的步骤后形成的结构的俯视图,图9b为图9a所示结构沿AA’方向的剖面结构示意图。在第二电极接触层14上形成环形的金属接触电极18,并对金属接触电极18进行退火处理,金属接触电极18的中心可以与将要形成的通孔的中心重合。Referring to Figures 9a and 9b, Figure 9a is a top view of a structure formed after performing the steps of the preparation method in the present application, and Figure 9b is a schematic cross-sectional structure diagram of the structure shown in Figure 9a along the AA' direction. A ring-shaped metal contact electrode 18 is formed on the second electrode contact layer 14, and the metal contact electrode 18 is annealed. The center of the metal contact electrode 18 may coincide with the center of the through hole to be formed.
S505、形成至少贯穿光敏感层和第二电极接触层的通孔。S505 , forming a through hole penetrating at least the photosensitive layer and the second electrode contact layer.
在具体实施时,参见图10a和图10b,图10a为执行本申请中制备方法的步骤后形成的结构的俯视图,图10b为图10a所示结构沿AA’方向的剖面结构示意图。通孔V0可以贯穿第二电极接触层14、光敏感层13、第一电极接触层12以及衬底11。当衬底的吸收光谱与待检测光的波长不交叠时,通孔V0可以仅贯穿第二电极接触层14、光敏感层13和第一电极接触层12。进一步,当衬底的吸收光谱与待检测光的波长不交叠,且第一电极接触层和衬底的外延材质相同时,通孔V0可以仅贯穿第二电极接触层14和光敏感层13。10a and 10b, FIG. 10a is a top view of a structure formed after performing the steps of the preparation method in the present application, and FIG. 10b is a schematic cross-sectional structure diagram of the structure shown in FIG. 10a along the AA' direction. The through hole V0 may penetrate through the second electrode contact layer 14 , the photosensitive layer 13 , the first electrode contact layer 12 and the substrate 11 . When the absorption spectrum of the substrate does not overlap with the wavelength of the light to be detected, the through hole V0 may only penetrate the second electrode contact layer 14 , the photosensitive layer 13 and the first electrode contact layer 12 . Further, when the absorption spectrum of the substrate does not overlap with the wavelength of the light to be detected, and the epitaxial material of the first electrode contact layer and the substrate is the same, the through hole V0 may only penetrate the second electrode contact layer 14 and the photosensitive layer 13 .
本申请对通孔的形状不作限定,可以是任何形状,例如正多变形、圆形、椭圆形等。当通孔V0形状为圆形时,可以保证通孔V0的中心至通孔V0边界各处的距离相同。并且,工艺上圆形通孔更容易实现。The shape of the through hole is not limited in the present application, and it may be any shape, such as polymorphic shape, circular shape, oval shape, and the like. When the shape of the through hole V0 is a circle, it can be ensured that the distance from the center of the through hole V0 to the boundary of the through hole V0 is the same. Moreover, the circular via is easier to realize in the process.
继续参见图10a和图10b,形成通孔V0后,覆盖层17围绕第二电极接触层14设置,通孔V0贯穿第二电极接触层14,保证光电探测器的功能区域(即第一电极接触层12、光敏感层13以及第二电极接触层14三者的正对区域)紧邻通孔V0边缘,这样穿过通孔V0的光子容易被俘获,从而提高灵敏度。10a and 10b, after forming the through hole V0, the cover layer 17 is arranged around the second electrode contact layer 14, and the through hole V0 penetrates through the second electrode contact layer 14 to ensure that the functional area of the photodetector (ie the first electrode contacts Layer 12 , photosensitive layer 13 and second electrode contact layer 14 are facing the edge of the via hole V0 ), so that the photons passing through the via hole V0 are easily captured, thereby improving the sensitivity.
S506、形成贯穿第二钝化层、光敏感层和覆盖层的第三凹槽。S506 , forming a third groove penetrating the second passivation layer, the photosensitive layer and the capping layer.
参见图11a至图11c,图11a为执行本申请中制备方法的步骤后形成的结构的俯视图,图11b为图11a所示结构沿AA’方向的剖面结构示意图,图11c为图11a所示结构沿BB’方向的剖面结构示意图。形成贯穿第二钝化层152、光敏感层13和覆盖层17的第三凹槽V3。11a to 11c, FIG. 11a is a top view of a structure formed after performing the steps of the preparation method in the present application, FIG. 11b is a schematic cross-sectional structure diagram of the structure shown in FIG. 11a along the AA' direction, and FIG. 11c is the structure shown in FIG. 11a. Schematic diagram of the cross-sectional structure along the BB' direction. A third groove V3 is formed through the second passivation layer 152 , the photosensitive layer 13 and the capping layer 17 .
S507、在金属接触电极上形成第一钝化层。S507, forming a first passivation layer on the metal contact electrode.
参见图12a至图12c,图12a为执行本申请中制备方法的步骤后形成的结构的俯视图,图12b为图12a所示结构沿AA’方向的剖面结构示意图,图12c为图12a所示结构沿BB’方向的剖面结构示意图。在金属接触电极18上形成的第一钝化层151可以包覆通孔V0的侧壁和第三凹槽V3的侧壁,从而对通孔V0处和第三凹槽V3处的外延材料起到保护作用。12a to 12c, FIG. 12a is a top view of a structure formed after performing the steps of the preparation method in the present application, FIG. 12b is a schematic cross-sectional structure diagram of the structure shown in FIG. 12a along the direction AA', and FIG. 12c is the structure shown in FIG. 12a Schematic diagram of the cross-sectional structure along the BB' direction. The first passivation layer 151 formed on the metal contact electrode 18 may cover the sidewalls of the via hole V0 and the sidewalls of the third groove V3, so as to protect the epitaxial material at the via hole V0 and the third groove V3 to protection.
S508、形成贯穿第一钝化层的第二凹槽,并在第三凹槽所在的区域形成贯穿第一钝化层的第一凹槽,以使第一凹槽贯穿第一钝化层且深至第一电极接触层表面。S508 , forming a second groove penetrating the first passivation layer, and forming a first groove penetrating the first passivation layer in the region where the third groove is located, so that the first groove penetrates the first passivation layer and deep to the surface of the first electrode contact layer.
参见图13a至图13c,图13a为执行本申请中制备方法的步骤后形成的结构的俯视图,图13b为图13a所示结构沿AA’方向的剖面结构示意图,图13c为图13a所示结构沿BB’ 方向的剖面结构示意图。可以采用光刻工艺形成贯穿第一钝化层151的第二凹槽V2,并在第三凹槽V3所在的区域采用光刻工艺形成贯穿第一钝化层151的第一凹槽V1,以使第一凹槽V1贯穿第一钝化层151且深至第一电极接触层12表面。13a to 13c, FIG. 13a is a top view of a structure formed after performing the steps of the preparation method in the present application, FIG. 13b is a schematic cross-sectional structure diagram of the structure shown in FIG. 13a along the AA' direction, and FIG. 13c is the structure shown in FIG. 13a. Schematic diagram of the cross-sectional structure along the BB' direction. A photolithography process can be used to form the second groove V2 penetrating the first passivation layer 151, and a photolithography process can be used to form the first groove V1 penetrating the first passivation layer 151 in the region where the third groove V3 is located, so as to The first groove V1 penetrates through the first passivation layer 151 and is deep to the surface of the first electrode contact layer 12 .
在具体实施时,可以采用一次光刻工艺同时形成贯穿第一钝化层151的第二凹槽V2和第一凹槽V1。In a specific implementation, the second groove V2 and the first groove V1 penetrating through the first passivation layer 151 may be formed simultaneously by one photolithography process.
S509、在第一钝化层上形成第一电极和第二电极。S509 , forming a first electrode and a second electrode on the first passivation layer.
参见图14a至图14c,图14a为执行本申请中制备方法的步骤后形成的结构的俯视图,图14b为图14a所示结构沿AA’方向的剖面结构示意图,图14c为图14a所示结构沿BB’方向的剖面结构示意图。位于第一钝化层151上的第一电极161和第二电极162在衬底11上的正投影位于通孔V0在衬底11的正投影的外侧,第一电极161和第二电极162相互绝缘,第一电极161通过第一凹槽V1与第一电极接触层12电连接,第二电极162通过第二凹槽V2与金属接触电极18电连接。14a to 14c, FIG. 14a is a top view of a structure formed after performing the steps of the preparation method in the present application, FIG. 14b is a schematic cross-sectional structure diagram of the structure shown in FIG. 14a along the direction AA', and FIG. 14c is the structure shown in FIG. 14a Schematic diagram of the cross-sectional structure along the BB' direction. The orthographic projection of the first electrode 161 and the second electrode 162 located on the first passivation layer 151 on the substrate 11 is located outside the orthographic projection of the through hole V0 on the substrate 11, and the first electrode 161 and the second electrode 162 are mutually Insulation, the first electrode 161 is electrically connected to the first electrode contact layer 12 through the first groove V1, and the second electrode 162 is electrically connected to the metal contact electrode 18 through the second groove V2.
在具体实施时,对第一电极和第二电极的形状不作限定。但是考虑到光电探测器的性能的对称性,如图14a所示,第二电极162呈包围通孔V0的闭合环形结构;第一电极161呈围绕第二电极162设置且具有开口的环形结构,第一电极161的开口的是为了避免第一电极161与第二电极162发生短路,第一电极161和第二电极162分别从通孔的两侧引出。During specific implementation, the shapes of the first electrode and the second electrode are not limited. However, considering the symmetry of the performance of the photodetector, as shown in FIG. 14a, the second electrode 162 has a closed annular structure surrounding the through hole V0; the first electrode 161 has an annular structure arranged around the second electrode 162 and having an opening, The opening of the first electrode 161 is to prevent the first electrode 161 and the second electrode 162 from being short-circuited, and the first electrode 161 and the second electrode 162 are drawn out from two sides of the through hole, respectively.
进一步地,为了增加电极与电极接触层的接触面积,凹槽的形状可以设置为与电极形状相似,参见图13a,第二凹槽V2的形状呈包围通孔V0的闭合环形;第一凹槽V1的形状呈围绕第二凹槽V2设置且具有开口的环形。Further, in order to increase the contact area between the electrode and the electrode contact layer, the shape of the groove can be set to be similar to the shape of the electrode. Referring to FIG. 13a, the shape of the second groove V2 is a closed ring surrounding the through hole V0; the first groove The shape of V1 is an annular shape provided around the second groove V2 and having an opening.
经过上述步骤S501至S509,形成本申请中的光电探测器,在该光电探测器中,钝化层由第一顿化层和第二钝化层两层钝化层形成。对于通孔V0贯穿所有膜层的情况可以参见图14a至图14c。对于,通孔V0并没有贯穿所有膜层的情况可以参见图15a至图15c。After the above steps S501 to S509, the photodetector in the present application is formed. In the photodetector, the passivation layer is formed by two passivation layers, a first passivation layer and a second passivation layer. Figures 14a to 14c can be seen for the case where the through hole V0 penetrates all the film layers. For the case where the through hole V0 does not penetrate all the film layers, please refer to FIG. 15a to FIG. 15c.
实施例二、Embodiment two,
图16示例性示出了本申请又一实施例所提供的光电探测器的制备方法的流程示意图。如图16所示,该方法主要包括以下步骤:FIG. 16 exemplarily shows a schematic flowchart of a method for fabricating a photodetector provided by another embodiment of the present application. As shown in Figure 16, the method mainly includes the following steps:
S1601、在衬底上依次形成第一电极接触层、光敏感层和覆盖层。S1601 , forming a first electrode contact layer, a photosensitive layer and a cover layer on the substrate in sequence.
S1602、在覆盖层上形成第二钝化层,并形成贯穿第二钝化层的过孔,以使露出的覆盖层呈环形或圆形。S1602 , forming a second passivation layer on the capping layer, and forming a via hole penetrating the second passivation layer, so that the exposed capping layer is annular or circular.
S1603、对露出的覆盖层进行掺杂形成第二电极接触层。S1603 , doping the exposed cover layer to form a second electrode contact layer.
S1604、在第二电极接触层上形成环形的金属接触电极,并对金属接触电极进行退火,以使将要形成的第二电极通过金属接触电极与第二电极接触层电连接。S1604 , forming a ring-shaped metal contact electrode on the second electrode contact layer, and annealing the metal contact electrode, so that the second electrode to be formed is electrically connected to the second electrode contact layer through the metal contact electrode.
S1605、形成至少贯穿光敏感层和第二电极接触层的通孔。S1605 , forming a through hole penetrating at least the photosensitive layer and the second electrode contact layer.
S1606、去除预设区域内的第二钝化层、覆盖层和光敏感层,以使剩下的覆盖层和光敏感层呈环形结构。S1606 , removing the second passivation layer, the cover layer and the photosensitive layer in the preset area, so that the remaining cover layer and the photosensitive layer have a ring structure.
在具体实施时,参见图17a和图17b,图17a为执行本申请中制备方法的步骤后形成的结构的俯视图,图17b为图17a所示结构沿AA’方向的剖面结构示意图。去除预设区域S1内的第二钝化层152、覆盖层17和光敏感层13,以使剩下的覆盖层17和光敏感层13呈环形结构。17a and 17b, FIG. 17a is a top view of the structure formed after performing the steps of the preparation method in the present application, and FIG. 17b is a schematic cross-sectional structure diagram of the structure shown in FIG. 17a along the AA' direction. The second passivation layer 152 , the cover layer 17 and the photosensitive layer 13 in the preset area S1 are removed, so that the remaining cover layer 17 and the photosensitive layer 13 have a ring structure.
S1607、在金属接触电极上形成第一钝化层。S1607, forming a first passivation layer on the metal contact electrode.
S1608、形成贯穿第一钝化层的第二凹槽,并在第三凹槽所在的区域形成贯穿第一钝化层的第一凹槽,以使第一凹槽贯穿第一钝化层且深至第一电极接触层表面。S1608 , forming a second groove penetrating the first passivation layer, and forming a first groove penetrating the first passivation layer in the region where the third groove is located, so that the first groove penetrates the first passivation layer and deep to the surface of the first electrode contact layer.
S1609、在第一钝化层上形成第一电极和第二电极。S1609, forming a first electrode and a second electrode on the first passivation layer.
该实例与实例一相比,仅是步骤S1506与实例一中的步骤S506不同,其它步骤可以参见实施例一,在此不再赘述。Compared with the first example, only step S1506 is different from step S506 in the first example, and other steps can be referred to in the first embodiment, which will not be repeated here.
经过上述步骤S1601至S1609,形成本申请中的光电探测器,在该光电探测器中,钝化层由第一顿化层和第二钝化层两层钝化层形成。对于通孔V0贯穿所有膜层的情况可以参见图14a以及图18a和图18b,图18a为图14a所示结构沿AA’方向的剖面结构示意图,图18b为图14a所示结构沿BB’方向的剖面结构示意图。对于通孔V0并没有贯穿所有膜层的情况可以参见图15a以及图19a和图19b,图19a为图15a所示结构沿AA’方向的剖面结构示意图,图19b为图15a所示结构沿BB’方向的剖面结构示意图。After the above steps S1601 to S1609, the photodetector in the present application is formed. In the photodetector, the passivation layer is formed by two passivation layers, a first passivation layer and a second passivation layer. 14a and 18a and 18b. FIG. 18a is a schematic cross-sectional structure diagram of the structure shown in FIG. 14a along the AA' direction, and FIG. 18b is the structure shown in FIG. 14a along the BB' direction. Schematic diagram of the cross-sectional structure. 15a and 19a and 19b, FIG. 19a is a schematic cross-sectional structure diagram of the structure shown in FIG. 15a along the direction AA', and FIG. 19b is the structure shown in FIG. 15a along BB Schematic diagram of the cross-sectional structure in the 'direction'.
实例三、Example three,
图20示例性示出了本申请又一实施例所提供的光电探测器的制备方法的流程示意图。如图20所示,该方法主要包括以下步骤:FIG. 20 exemplarily shows a schematic flowchart of a method for fabricating a photodetector provided by another embodiment of the present application. As shown in Figure 20, the method mainly includes the following steps:
S2001、在衬底上除了中心区域之外的区域上依次形成第一电极接触层、光敏感层和覆盖层。S2001 , forming a first electrode contact layer, a photosensitive layer and a cover layer in sequence on the regions except the central region on the substrate.
参见图21a和图21b,图21a为执行本申请中制备方法的步骤后形成的结构的俯视图,图21b为图21a所示结构沿AA’方向的剖面结构示意图。在衬底11上除了中心区域之外的区域上依次外延生长第一电极接触层12、光敏感层13和覆盖层17。从而在形成第一电极接触层12、光敏感层13和覆盖层17的同时,在中心区域形成贯穿第一电极接触层12、光敏感层13和覆盖层17的通孔V0。其中,中心区域为通孔所在的区域,可以为圆形区域。21a and 21b, FIG. 21a is a top view of the structure formed after performing the steps of the preparation method in the present application, and FIG. 21b is a schematic cross-sectional structure diagram of the structure shown in FIG. 21a along the AA' direction. A first electrode contact layer 12 , a photosensitive layer 13 and a capping layer 17 are epitaxially grown on the substrate 11 on regions other than the central region in sequence. Thus, while forming the first electrode contact layer 12 , the photosensitive layer 13 and the capping layer 17 , a through hole V0 penetrating the first electrode contact layer 12 , the photosensitive layer 13 and the capping layer 17 is formed in the central region. The central area is the area where the through hole is located, which may be a circular area.
S2002、在覆盖层上形成第二钝化层,并形成贯穿第二钝化层的过孔,以使露出的覆盖层呈环形。S2002 , forming a second passivation layer on the cover layer, and forming a via hole penetrating the second passivation layer, so that the exposed cover layer is annular.
S2003、对露出的覆盖层进行掺杂形成第二电极接触层。S2003 , doping the exposed cover layer to form a second electrode contact layer.
S2004、在第二电极接触层上形成环形的金属接触电极,并对金属接触电极进行退火,以使将要形成的第二电极通过金属接触电极与第二电极接触层电连接。S2004 , forming an annular metal contact electrode on the second electrode contact layer, and annealing the metal contact electrode, so that the second electrode to be formed is electrically connected to the second electrode contact layer through the metal contact electrode.
S2005、形成贯穿第二钝化层、光敏感层和覆盖层的第三凹槽。S2005 , forming a third groove penetrating the second passivation layer, the photosensitive layer and the cover layer.
S2006、在金属接触电极上形成第一钝化层。S2006, forming a first passivation layer on the metal contact electrode.
S2007、形成贯穿第一钝化层的第二凹槽,并在第三凹槽所在的区域形成贯穿第一钝化层的第一凹槽,以使第一凹槽贯穿第一钝化层且深至第一电极接触层表面。S2007, forming a second groove penetrating the first passivation layer, and forming a first groove penetrating the first passivation layer in the region where the third groove is located, so that the first groove penetrates the first passivation layer and deep to the surface of the first electrode contact layer.
S2008、在第一钝化层上形成第一电极和第二电极。S2008, forming a first electrode and a second electrode on the first passivation layer.
该实例与实施例一相比,仅是步骤S2001与实施例一中的步骤S501不同,另外,该实例在步骤S2001中已经形成,通孔仅贯穿第一电极接触层12、光敏感层13和第二电极接触17,因此与实例一相比,省去了步骤S505,其它步骤可以参见实施例一,在此不再赘述。Compared with the first embodiment, this example is only different from step S2001 and step S501 in the first embodiment. In addition, this example has been formed in step S2001, and the through hole only penetrates the first electrode contact layer 12, the photosensitive layer 13 and the The second electrode contacts 17. Therefore, compared with Example 1, step S505 is omitted, and other steps can be referred to in Example 1, which will not be repeated here.
经过上述步骤S2001至S2008,形成的光电探测器可以参见图15a、图22a和图22b,图22a为图15a所示结构沿AA’方向的剖面结构示意图,图22b为图15a所示结构沿BB’方向的剖面结构示意图。After the above steps S2001 to S2008, the formed photodetector can be seen in FIGS. 15a, 22a and 22b. FIG. 22a is a schematic cross-sectional structure diagram of the structure shown in FIG. 15a along the direction AA', and FIG. 22b is the structure shown in FIG. 15a along BB Schematic diagram of the cross-sectional structure in the 'direction'.
进一步地,在该实例中,在步骤2004之后,在步骤S2005之前还可以包括去除衬底的中心区域。从而使最终形成的光电探测器中,通孔贯穿所有膜层,具体可以参见图14a 至图14c。Further, in this example, after step 2004, before step S2005, it may further include removing the central region of the substrate. Therefore, in the photodetector finally formed, the through hole penetrates through all the film layers, as shown in FIG. 14a to FIG. 14c for details.
实例四、Example 4.
图23示例性示出了本申请又一实施例所提供的光电探测器的制备方法的流程示意图。如图23所示,该方法主要包括以下步骤:FIG. 23 exemplarily shows a schematic flowchart of a method for fabricating a photodetector provided by another embodiment of the present application. As shown in Figure 23, the method mainly includes the following steps:
S2301、在衬底上除了中心区域之外的区域上依次形成第一电极接触层、光敏感层和覆盖层。S2301 , forming a first electrode contact layer, a photosensitive layer and a cover layer in sequence on the regions except the central region on the substrate.
S2302、在覆盖层上形成第二钝化层,并形成贯穿第二钝化层的过孔,以使露出的覆盖层呈环形。S2302 , forming a second passivation layer on the cover layer, and forming a via hole penetrating the second passivation layer, so that the exposed cover layer is in a ring shape.
S2303、对露出的覆盖层进行掺杂形成第二电极接触层。S2303 , doping the exposed cover layer to form a second electrode contact layer.
S2304、在第二电极接触层上形成环形的金属接触电极,并对金属接触电极进行退火,以使将要形成的第二电极通过金属接触电极与第二电极接触层电连接。S2304 , forming an annular metal contact electrode on the second electrode contact layer, and annealing the metal contact electrode, so that the second electrode to be formed is electrically connected to the second electrode contact layer through the metal contact electrode.
S2305、去除预设区域内的第二钝化层、覆盖层和光敏感层,以使剩下的覆盖层和光敏感层呈环形结构。S2305 , removing the second passivation layer, the cover layer and the photosensitive layer in the preset area, so that the remaining cover layer and the photosensitive layer have a ring structure.
S2306、在金属接触电极上形成第一钝化层。S2306, forming a first passivation layer on the metal contact electrode.
S2307、形成贯穿第一钝化层的第二凹槽,并在第三凹槽所在的区域形成贯穿第一钝化层的第一凹槽,以使第一凹槽贯穿第一钝化层且深至第一电极接触层表面。S2307 , forming a second groove penetrating the first passivation layer, and forming a first groove penetrating the first passivation layer in the region where the third groove is located, so that the first groove penetrates the first passivation layer and deep to the surface of the first electrode contact layer.
S2308、在第一钝化层上形成第一电极和第二电极。S2308, forming a first electrode and a second electrode on the first passivation layer.
该实例与实例三相比,仅是步骤S2305与实例三中的步骤S2005不同,其它步骤可以参见实施例三,在此不再赘述。Compared with the third example, only step S2305 is different from the step S2005 in the third example. For other steps, refer to the third embodiment, which will not be repeated here.
经过上述步骤S2301至S2308,形成的光电探测器可以参见图15a、图24a和图24b,图24a为图15a所示结构沿AA’方向的剖面结构示意图,图24b为图15a所示结构沿BB’方向的剖面结构示意图。After the above steps S2301 to S2308, the photodetector formed can be seen in FIGS. 15a, 24a and 24b. FIG. 24a is a schematic cross-sectional structure diagram of the structure shown in FIG. 15a along the direction AA', and FIG. 24b is the structure shown in FIG. 15a along BB Schematic diagram of the cross-sectional structure in the 'direction'.
进一步地,在该实例中,在步骤S2304之后,在步骤S2005之前还可以包括去除衬底的中心区域。从而使最终形成的光电探测器中,通孔贯穿所有膜层,具体可以参见图14a至图14c。Further, in this example, after step S2304, before step S2005, it may further include removing the central region of the substrate. Therefore, in the photodetector finally formed, the through holes penetrate through all the film layers, as shown in FIG. 14a to FIG. 14c for details.
本申请提供的光电探测器,在通孔的周围设置有层叠设置的第一电极接触层、光敏感层以及第二电极接触层,且在当光敏感层俘获穿过通孔的光时,可以将光信号转换为电信号,从而实现对光信号的检测。In the photodetector provided by the present application, the first electrode contact layer, the photosensitive layer and the second electrode contact layer are stacked and arranged around the through hole, and when the photosensitive layer captures the light passing through the through hole, it can The optical signal is converted into an electrical signal, thereby realizing the detection of the optical signal.
参照图25,本申请还提供了一种芯片100,该芯片100包括驱动电路101以及与所述驱动电路101连接的至少一个上述任一实施例提供的光电探测器10(图25中以一个光电探测器10为例进行示意)。其中,该光电能探测器10可以将俘获的光信号转换为电信号,而驱动电路101可以将该电信号放大后输出,实现对光信号的检测。Referring to FIG. 25 , the present application also provides a chip 100 , the chip 100 includes a driving circuit 101 and at least one photodetector 10 provided in any of the above-mentioned embodiments connected to the driving circuit 101 (in FIG. 25 , a photoelectric detector 10 The detector 10 is shown as an example). The photoelectric energy detector 10 can convert the captured optical signal into an electrical signal, and the driving circuit 101 can amplify the electrical signal and output it to realize the detection of the optical signal.
在具体实施时,光电探测器10的数量和排列方式可以根据实际应用场合进行设计,在此不作限定。例如在一种实施例中,如图26所示,多个所述光电探测器10沿第一方向排列,在另一种实施例中,如图27所示,多个所述光电探测器10呈矩阵排列。During specific implementation, the number and arrangement of the photodetectors 10 can be designed according to the actual application, which is not limited herein. For example, in one embodiment, as shown in FIG. 26 , a plurality of the photodetectors 10 are arranged along the first direction. In another embodiment, as shown in FIG. 27 , a plurality of the photodetectors 10 are arranged along the first direction. arranged in a matrix.
本申请还提供了一种光学装置,包括波长选择开关结构和至少一个光电探测器,所述光电探测器设置在所述波长选择开关结构的自由空间中单色光的传输路径上。不仅可以保证单色光信号不受干扰,而且可以保证WSS结构的体积不会增加。并且,由于该光电探测器不需要借助其他器件就可以直接从单色光的传输路径上获取光子,因此不需要复杂的 机械固定件就可以固定在单色光的传输路径上,与采用现有的光纤抽头检测装置相比,可以整体降低成本和整体结构复杂性。The present application also provides an optical device, comprising a wavelength selective switch structure and at least one photodetector, wherein the photodetector is arranged on a transmission path of monochromatic light in the free space of the wavelength selective switch structure. Not only can the monochromatic optical signal be guaranteed not to be disturbed, but also the volume of the WSS structure can be guaranteed not to increase. In addition, since the photodetector can directly obtain photons from the transmission path of monochromatic light without the help of other devices, it can be fixed on the transmission path of monochromatic light without complex mechanical fixing parts, which is different from using existing devices. Compared with the optical fiber tap detection device, the overall cost and overall structural complexity can be reduced.
显然,本领域的技术人员可以对本申请进行各种改动和变型而不脱离本申请的保护范围。这样,倘若本申请的这些修改和变型属于本申请权利要求及其等同技术的范围之内,则本申请也意图包含这些改动和变型在内。Obviously, those skilled in the art can make various changes and modifications to the present application without departing from the protection scope of the present application. Thus, if these modifications and variations of the present application fall within the scope of the claims of the present application and their equivalents, the present application is also intended to include these modifications and variations.

Claims (17)

  1. 一种光电探测器,其特征在于,包括:衬底、依次层叠设置于所述衬底上的第一电极接触层、光敏感层、第二电极接触层、钝化层以及第一电极和第二电极;A photodetector is characterized by comprising: a substrate, a first electrode contact layer, a photosensitive layer, a second electrode contact layer, a passivation layer, a first electrode and a first electrode contact layer, a photosensitive layer, a second electrode contact layer, a passivation layer, and a first electrode and a two electrodes;
    所述光电探测器还包括至少贯穿所述光敏感层和所述第二电极接触层的通孔;The photodetector further includes a through hole penetrating at least the photosensitive layer and the second electrode contact layer;
    所述第一电极接触层和所述第二电极接触层为极性相反的掺杂半导体层;The first electrode contact layer and the second electrode contact layer are doped semiconductor layers with opposite polarities;
    所述第一电极和所述第二电极在所述衬底上的正投影分别位于所述通孔在所述衬底的正投影的外侧;Orthographic projections of the first electrode and the second electrode on the substrate are respectively located outside the orthographic projection of the through hole on the substrate;
    所述第一电极和所述第二电极相互绝缘,所述第一电极通过贯穿位于所述第一电极与所述第一电极接触层之间的膜层的第一凹槽与所述第一电极接触层电连接,所述第二电极通过贯穿所述钝化层的第二凹槽与所述第二电极接触层电连接。The first electrode and the second electrode are insulated from each other, and the first electrode is connected to the first electrode through a first groove penetrating the film layer between the first electrode and the first electrode contact layer. The electrode contact layer is electrically connected, and the second electrode is electrically connected to the second electrode contact layer through a second groove penetrating the passivation layer.
  2. 根据权利要求1所述的光电探测器,其特征在于,所述第二电极呈包围所述通孔的闭合环形结构;The photodetector according to claim 1, wherein the second electrode is in a closed annular structure surrounding the through hole;
    所述第一电极呈围绕所述第二电极设置且具有开口的环形结构。The first electrode has an annular structure arranged around the second electrode and having an opening.
  3. 根据权利要求2所述的光电探测器,其特征在于,所述第二凹槽的形状呈包围所述通孔的闭合环形;The photodetector according to claim 2, wherein the shape of the second groove is a closed ring surrounding the through hole;
    所述第一凹槽的形状呈围绕所述第二凹槽设置且具有开口的环形。The shape of the first groove is an annular shape arranged around the second groove and having an opening.
  4. 根据权利要求1至3任一项所述的光电探测器,其特征在于,所述通孔还贯穿所述第一电极接触层。The photodetector according to any one of claims 1 to 3, wherein the through hole further penetrates the first electrode contact layer.
  5. 根据权利要求4所述的光电探测器,其特征在于,所述通孔还贯穿所述衬底和所述钝化层。The photodetector according to claim 4, wherein the through hole further penetrates through the substrate and the passivation layer.
  6. 根据权利要求1至3任一项所述的光电探测器,其特征在于,所述通孔的形状为圆形。The photodetector according to any one of claims 1 to 3, wherein the shape of the through hole is a circle.
  7. 根据权利要求1至3任一项所述的光电探测器,其特征在于,第二电极接触层的形状呈环形;The photodetector according to any one of claims 1 to 3, wherein the shape of the second electrode contact layer is annular;
    所述光电探测器还包括与所述第二电极接触层同层设置的覆盖层,且所述覆盖层围绕所述第二电极接触层设置;The photodetector further includes a cover layer arranged in the same layer as the second electrode contact layer, and the cover layer is arranged around the second electrode contact layer;
    所述第二电极接触层与所述覆盖层的本征材质相同,掺杂浓度不同或电学掺杂类型不同。The second electrode contact layer and the cover layer have the same intrinsic material, different doping concentrations or different electrical doping types.
  8. 根据权利要求1至3任一项所述的光电探测器,其特征在于,所述第一电极接触层为N型掺杂半导体层,所述第二电极接触层为P型掺杂半导体层;所述光电探测器还包括位于所述第二电极与所述第二电极接触层之间的金属接触电极。The photodetector according to any one of claims 1 to 3, wherein the first electrode contact layer is an N-type doped semiconductor layer, and the second electrode contact layer is a P-type doped semiconductor layer; The photodetector also includes a metal contact electrode between the second electrode and the second electrode contact layer.
  9. 一种芯片,其特征在于,包括驱动电路,以及与所述驱动电路连接的至少一个如权利要求1至8任一项所述的光电探测器。A chip, characterized by comprising a driving circuit, and at least one photodetector according to any one of claims 1 to 8 connected to the driving circuit.
  10. 一种光学装置,其特征在于,包括波长选择开关结构和至少一个如权利要求1至8任一项所述的光电探测器;An optical device, characterized by comprising a wavelength selective switch structure and at least one photodetector according to any one of claims 1 to 8;
    所述光电探测器设置在所述波长选择开关结构的自由空间中单色光的传输路径上。The photodetector is arranged on the transmission path of monochromatic light in the free space of the wavelength selective switch structure.
  11. 一种光电探测器的制备方法,其特征在于,包括:A method for preparing a photodetector, comprising:
    在衬底上依次形成第一电极接触层、光敏感层和第二电极接触层,并形成至少贯穿所述光敏感层和所述第二电极接触层的通孔;其中,所述第一电极接触层和所述第二电极接触层为极性相反的掺杂半导体层;A first electrode contact layer, a photosensitive layer and a second electrode contact layer are sequentially formed on the substrate, and a through hole is formed at least through the photosensitive layer and the second electrode contact layer; wherein, the first electrode The contact layer and the second electrode contact layer are doped semiconductor layers with opposite polarities;
    在所述第二电极接触层上形成第一钝化层,并形成贯穿所述第一钝化层且深至所述第一电极接触层表面的第一凹槽和贯穿所述钝化层的第二凹槽;A first passivation layer is formed on the second electrode contact layer, and a first groove penetrating the first passivation layer and deep to the surface of the first electrode contact layer and a groove penetrating the passivation layer are formed the second groove;
    在所述第一钝化层上形成第一电极和第二电极;其中,所述第一电极和所述第二电极在所述衬底上的正投影分别位于所述通孔在所述衬底的正投影的外侧;所述第一电极和所述第二电极相互绝缘,所述第一电极通过所述第一凹槽与所述第一电极接触层电连接,所述第二电极通过所述第二凹槽与所述第二电极接触层电连接。A first electrode and a second electrode are formed on the first passivation layer; wherein, the orthographic projections of the first electrode and the second electrode on the substrate are respectively located on the substrate of the through hole. The outer side of the orthographic projection of the bottom; the first electrode and the second electrode are insulated from each other, the first electrode is electrically connected to the first electrode contact layer through the first groove, and the second electrode is The second groove is electrically connected to the second electrode contact layer.
  12. 根据权利要求11所述的制备方法,其特征在于,在衬底上依次形成第一电极接触层、光敏感层和第二电极接触层,并形成至少贯穿所述光敏感层和所述第二电极接触层的通孔,包括:The preparation method according to claim 11, wherein a first electrode contact layer, a photosensitive layer and a second electrode contact layer are sequentially formed on the substrate, and at least through the photosensitive layer and the second electrode contact layer are formed. Through holes for electrode contact layers, including:
    在所述衬底上依次形成第一电极接触层、光敏感层和覆盖层;forming a first electrode contact layer, a photosensitive layer and a cover layer in sequence on the substrate;
    在所述覆盖层上形成第二钝化层,并形成贯穿所述第二钝化层的过孔,以使露出的所述覆盖层呈环形或圆形;forming a second passivation layer on the cover layer, and forming a via hole passing through the second passivation layer, so that the exposed cover layer is annular or circular;
    对露出的所述覆盖层进行掺杂形成第二电极接触层;Doping the exposed cover layer to form a second electrode contact layer;
    形成至少贯穿所述光敏感层和所述第二电极接触层的通孔。A through hole is formed through at least the photosensitive layer and the second electrode contact layer.
  13. 根据权利要求11所述的制备方法,其特征在于,在衬底上依次形成第一电极接触层、光敏感层和第二电极接触层,并形成至少贯穿所述光敏感层和所述第二电极接触层的通孔,包括:The preparation method according to claim 11, wherein a first electrode contact layer, a photosensitive layer and a second electrode contact layer are sequentially formed on the substrate, and at least through the photosensitive layer and the second electrode contact layer are formed. Through holes for electrode contact layers, including:
    在所述衬底上除了中心区域之外的区域上依次形成第一电极接触层、光敏感层和覆盖层;forming a first electrode contact layer, a photosensitive layer and a cover layer in sequence on the region except the central region on the substrate;
    在所述覆盖层上形成第二钝化层,并形成贯穿所述第二钝化层的过孔,以使露出的所述覆盖层呈环形;forming a second passivation layer on the cover layer, and forming a via hole passing through the second passivation layer, so that the exposed cover layer is annular;
    对露出的所述覆盖层进行掺杂形成第二电极接触层。Doping the exposed capping layer to form a second electrode contact layer.
  14. 根据权利要求13所述的制备方法,其特征在于,在对露出的所述覆盖层进行掺杂形成第二电极接触层之后,还包括:The preparation method according to claim 13, wherein after doping the exposed cover layer to form the second electrode contact layer, further comprising:
    去除所述衬底的所述中心区域。The central region of the substrate is removed.
  15. 根据权利要求12至14任一项所述的制备方法,其特征在于,在所述第二电极接触层上形成第一钝化层,并形成贯穿所述第一钝化层且深至所述第一电极接触层表面的第一凹槽和贯穿所述钝化层的第二凹槽,包括:The preparation method according to any one of claims 12 to 14, wherein a first passivation layer is formed on the second electrode contact layer, and is formed through the first passivation layer and deep to the The first groove on the surface of the first electrode contact layer and the second groove through the passivation layer, including:
    形成贯穿所述第二钝化层、所述覆盖层和所述光敏感层的第三凹槽;forming a third groove through the second passivation layer, the capping layer and the photosensitive layer;
    在所述第二电极接触层上形成第一钝化层;forming a first passivation layer on the second electrode contact layer;
    形成贯穿所述第一钝化层的第二凹槽,并在所述第三凹槽所在的区域形成贯穿所述第一钝化层的第一凹槽,以使所述第一凹槽贯穿所述第一钝化层且深至所述第一电极接触层表面。forming a second groove penetrating the first passivation layer, and forming a first groove penetrating the first passivation layer in the region where the third groove is located, so that the first groove penetrates The first passivation layer is deep to the surface of the first electrode contact layer.
  16. 根据权利要求12至14任一项所述的制备方法,其特征在于,在衬底上依次形成第一电极接触层、光敏感层和第二电极接触层之后,在所述第二电极接触层上形成第一钝化层之前,还包括:The preparation method according to any one of claims 12 to 14, wherein after the first electrode contact layer, the photosensitive layer and the second electrode contact layer are sequentially formed on the substrate, the second electrode contact layer is formed on the substrate. Before forming the first passivation layer thereon, it also includes:
    去除预设区域内的所述第二钝化层、所述覆盖层和所述光敏感层,以使剩下的所述覆盖层和所述光敏感层呈环形结构。The second passivation layer, the cover layer and the photosensitive layer in the preset area are removed, so that the remaining cover layer and the photosensitive layer have a ring structure.
  17. 根据权利要求12至14任一项所述的制备方法,其特征在于,所述第一电极接触层为N型掺杂半导体层,所述第二电极接触层为P型掺杂半导体层;在衬底上依次形成第一电极接触层、光敏感层和第二电极接触层之后,在所述第二电极接触层上形成第一钝化层之前,还包括:The preparation method according to any one of claims 12 to 14, wherein the first electrode contact layer is an N-type doped semiconductor layer, and the second electrode contact layer is a P-type doped semiconductor layer; After the first electrode contact layer, the photosensitive layer and the second electrode contact layer are sequentially formed on the substrate, and before the first passivation layer is formed on the second electrode contact layer, the method further includes:
    所述第二电极接触层上形成环形的金属接触电极,并对所述金属接触电极进行退火,以使将要形成的第二电极通过所述金属接触电极与所述第二电极接触层电连接。An annular metal contact electrode is formed on the second electrode contact layer, and the metal contact electrode is annealed, so that the second electrode to be formed is electrically connected to the second electrode contact layer through the metal contact electrode.
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