WO2022105375A1 - 一种多c形高中空度亮光纤维及其制备方法 - Google Patents

一种多c形高中空度亮光纤维及其制备方法 Download PDF

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Publication number
WO2022105375A1
WO2022105375A1 PCT/CN2021/117086 CN2021117086W WO2022105375A1 WO 2022105375 A1 WO2022105375 A1 WO 2022105375A1 CN 2021117086 W CN2021117086 W CN 2021117086W WO 2022105375 A1 WO2022105375 A1 WO 2022105375A1
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Prior art keywords
fiber
cavity
shaped high
bright
shaped
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PCT/CN2021/117086
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English (en)
French (fr)
Inventor
张守运婷
李圣军
孙燕琳
刘艳丽
杨卫星
钱婷婷
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浙江桐昆新材料研究院有限公司
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Publication of WO2022105375A1 publication Critical patent/WO2022105375A1/zh

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    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00Formation of filaments, threads, or the like
    • D01D5/24Formation of filaments, threads, or the like with a hollow structure; Spinnerette packs therefor
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00Formation of filaments, threads, or the like
    • D01D5/253Formation of filaments, threads, or the like with a non-circular cross section; Spinnerette packs therefor
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/58Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products
    • D01F6/60Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from polyamides
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/58Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products
    • D01F6/62Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from polyesters

Definitions

  • the invention relates to the field of fibers, in particular to a multi-C-shaped high-cavity bright fiber and a preparation method thereof.
  • Polyester and nylon are the most widely used raw materials for clothing fabrics. Their fabrics have good wrinkle resistance and shape retention, but their fabrics are heavy, have poor moisture absorption and air permeability, and are prone to static electricity due to friction, making them stuffy.
  • the amount of consumption has increased rapidly. China has become the country with the largest production and demand of polyester chemical fiber.
  • the development of production and demand is related to people's pursuit of wearing comfort, light weight and aesthetics. The pursuit of asymmetry restricts its further development to a large extent.
  • the present invention proposes a multi-C-shaped high hollowness bright fiber and a preparation method thereof, which can effectively solve the above problems.
  • the purpose of the present invention is to provide a kind of multi-C-shaped high hollow density bright fiber and its preparation method.
  • the multi-C-shaped high-cavity bright fiber and its spinneret of the present invention have simple structure and convenient use.
  • the multi-C-shaped melt extrusion slits are used to pass through the fiber filaments, and are distributed in an equal diameter ring around the center of the fiber.
  • the unique multi-cavity profiled cross-sectional structure, the hollowness can be as high as 40-50%, the fabric has a good lightening effect, the hollow contour of the fiber and the gap between the fibers formed by the irregular contour of the surrounding, further improve
  • the fiber is lightweight, and the moisture absorption, air permeability and antistatic properties of the fiber fabric are improved, and the outline of the fiber has a good optical effect, plus the light transmittance caused by the cavity, the fiber and fabric have a good optical effect.
  • the reflective light-transmitting effect has a bright luster.
  • a multi-C-shaped high-cavity bright fiber the fiber comprises a plurality of fiber filaments distributed around the center of the fiber in an equal diameter ring, every two of the fiber filaments are mutually joined, and both of the fiber filaments are A first cavity is provided; the center of the fiber is also provided with a second cavity formed by a plurality of the fiber filaments distributed in a circular shape with an equal diameter; the cross-section of the fiber filament is C-shaped; The outer contour is surrounded by a plurality of arcs connected end to end.
  • the invention adopts multi-C-shaped melt extrusion slits through fiber filaments, and is distributed in an equal diameter ring around the center of the fiber, forming a unique multi-cavity shaped special-shaped cross-sectional structure, and the hollowness can be as high as 40-50%.
  • the fabric has a better lightening effect, and the hollow contour of the fiber plus the gaps between the fibers formed by the irregular contour of the periphery further improves the lightness of the fiber and improves the fiber fabric.
  • Moisture absorption, air permeability and anti-static performance, and the outline of the fiber has good optical effect, plus the light transmittance caused by more cavities, the fiber and fabric have a good light-reflecting and light-transmitting effect and have a bright luster.
  • the fiber Through the first cavity and the second cavity, the fiber has a high degree of hollowness and light weight, and the multi-cavity improves the light transmission and reflection effect of the fiber.
  • the fiber is formed by arcs connected end to end.
  • the optical effect of the contour, its fibers and fabrics have good moisture absorption, breathability, heat preservation and anti-static properties, as well as high light weight effect and super glossy brightness, and the wearing comfort and appearance are good.
  • the present invention also provides a method for preparing the multi-C-shaped high-cavity bright fiber
  • the preparation method of the described multi-C-shaped high-cavity bright light fiber is as follows:
  • polyester or nylon is used as the raw material, and the spinneret of multi-C-shaped high and high hollowness bright fibers is used for melt spinning;
  • the controlled cooling and blowing temperature is 14-16°C lower, compared with the production conditions of the corresponding specifications, the spinning speed is reduced by 3-5%, the stretching ratio is reduced by 0.5-1.0%, and the temperature of a hot roll is reduced by 3-5%. Lower the temperature by 5 ⁇ 10°C, the temperature of the second hot box is 3 ⁇ 10°C higher, and the component pressure is 140 ⁇ 150kgf/cm 2 .
  • the present invention also provides a spinneret for preparing multi-C-shaped high-cavity bright fibers.
  • the extrusion seam is C-shaped.
  • the fiber filaments constituting the fibers prepared by the spinneret are C-shaped, and can form the first cavity and the third cavity.
  • the number of the extrusion slits on the spinneret is 8-20.
  • the number of the extrusion slits is between 8 and 20, the structural strength of the prepared fiber is better, the lightening effect is also better, and the optical effect is better; When the number is less than 8, the strength of the prepared fiber structure is poor, and the hollowness is not high; and when the number of the extrusion slits is greater than 20, since each extrusion slit must ensure a certain slit width, so The more the number of extrusion slits, the more difficult it is to manufacture the spinneret, and the more the number of extrusion slits, the smaller the width of each extrusion slit, which also leads to preparation The fiber structure strength is not high.
  • the distance between the inner end points of each two of the extrusion slits is 0.5-1.0 mm.
  • the minimum distance between every two extrusion slits is 0.08-0.15 mm.
  • the width of each of the extrusion slits is 0.05-0.08 mm.
  • the present invention has the following advantages and beneficial effects:
  • the multi-C-shaped high-cavity bright fiber and its spinneret of the present invention have simple structure and convenient use.
  • the multi-C-shaped melt extrusion slits are used to pass through the fiber filaments, and are distributed in an equal diameter ring around the center of the fiber.
  • the unique multi-cavity profiled cross-sectional structure, the hollowness can be as high as 40-50%, the fabric has a good lightening effect, the hollow contour of the fiber and the gap between the fibers formed by the irregular contour of the surrounding, further improve
  • the fiber is lightweight, and the moisture absorption, air permeability and antistatic properties of the fiber fabric are improved, and the outline of the fiber has a good optical effect, plus the light transmittance caused by the cavity, the fiber and fabric have a good optical effect.
  • the reflective light-transmitting effect has a bright luster.
  • Example 1 is a schematic structural diagram of the spinneret in Example 2 of the present invention.
  • Figure 2 is a schematic structural diagram of the fiber prepared by Example 2 of the present invention.
  • Embodiment 3 is a schematic structural diagram of the spinneret in Embodiment 3 of the present invention.
  • Example 4 is a schematic structural diagram of the fiber prepared by Example 3 of the present invention.
  • FIG. 5 is a schematic structural diagram of the spinneret in Embodiment 4 of the present invention.
  • Example 6 is a schematic diagram of the structure of the fiber prepared by Example 4 of the present invention.
  • the fiber includes a plurality of fiber filaments 11 distributed around the center of the fiber with equal diameters, each two of the fiber filaments 11 are joined to each other, and two of the fiber filaments 11 are provided with a first cavity 12; the center of the fiber 1 is also provided with a plurality of the fiber filaments 11.
  • the cross section of the fiber filament 11 is C-shaped; the outer contour of the fiber is formed by a plurality of arcs connected end to end.
  • the present invention adopts multi-C-shaped melt extrusion slits through the fiber filaments 11, and is distributed in an equal diameter ring around the center of the fiber to form a unique multi-cavity shaped cross-sectional structure, and the hollowness can be as high as 40-50% , the fabric has a better lightening effect, the hollow contour of the fiber plus the gap between the fibers formed by the irregular contour of the periphery further improves the lightweight of the fiber and improves the fiber fabric High moisture absorption, air permeability and anti-static performance, and the outline of the fiber has a good optical effect, plus the light transmittance caused by the cavity, the fiber and fabric have a good light reflection and light transmission effect and have a bright luster.
  • the moisture regain and moisture absorption rate of the fibers are measured.
  • the fibers and fabrics of the present invention have 20-30% increase.
  • the wicking height of the fabric is tested.
  • the fiber of the present invention has a The wicking height of the fibers and fabrics of the invention is increased by 20-30%.
  • the drip diffusion area and drip diffusion time of the fabric are tested.
  • the fiber of the present invention is similar to the conventional fiber of the same specification. Compared with the fiber and fabric of the present invention, the drip diffusion area of the fabric is increased by 20-30%, and the drip diffusion time is shortened by 15-20%.
  • the moisture permeability of the fabric is tested. Compared with the conventional fibers of the same specification, the fibers of the present invention are And the moisture permeability of the fabric is increased by 25-30%.
  • the air permeability of the fabric is tested. Compared with the conventional fibers of the same specification, the air permeability of the fibers and fabrics of the present invention is increased by 25%. -30%.
  • the surface resistance, charge surface density and charge half-life of fabrics are tested.
  • the fibers of the present invention and The conductivity indicators of the fabric such as specific resistance, charge surface density and charge half-life are 30-40% lower.
  • a multi-C-shaped high-cavity bright fiber the fiber includes a plurality of fiber filaments distributed around the center of the fiber with an equal diameter and an annular shape, each two of the fiber filaments are joined to each other, and two Each of the fiber filaments is provided with a first cavity; the center of the fiber is also provided with a second cavity formed by a plurality of the fiber filaments distributed in a circular shape with equal diameters; the cross-section of the fiber filaments is C-shaped
  • the outer contour of the fiber is formed by a plurality of arcs connected end to end.
  • the present invention also provides a method for preparing the multi-C-shaped high-cavity bright fiber
  • the preparation method of the described multi-C-shaped high-cavity bright light fiber is as follows:
  • polyester is used as the raw material, and the spinneret of multi-C-shaped high and high hollowness bright fibers is used for melt spinning;
  • the controlled cooling and blowing temperature is 14-16°C lower, compared with the production conditions of the corresponding specifications, the spinning speed is reduced by 3-5%, the stretching ratio is reduced by 0.5-1.0%, and the temperature of a hot roll is reduced by 3-5%. Lower the temperature by 5 ⁇ 10°C, the temperature of the second hot box is 3 ⁇ 10°C higher, and the component pressure is 140 ⁇ 150kgf/cm2.
  • the present invention also provides a spinneret for preparing multi-C-shaped high-cavity bright fibers.
  • the spinneret is provided with a plurality of extrusion slits 21 that are annularly distributed around the center of the spinneret with equal diameters.
  • Each of the extrusion slits 21 is C-shaped.
  • the number of the extrusion slits 21 on the spinneret is eight.
  • the distance between the inner end points of each two of the extrusion slits 21 is 1.0 mm.
  • the minimum distance between every two extrusion slits 21 is 0. 15mm.
  • the width of each of the extrusion slits 21 is 0.08 mm.
  • the cooling blowing temperature is 14°C
  • the spinning speed is 3900m/min
  • the stretching ratio is 2.3
  • the temperature of the first hot roller is 80°C
  • the temperature of the second hot box is 162°C
  • the component pressure is 140 kgf/cm2.
  • the spinning speed is reduced by 5%
  • the draw ratio is reduced by 1.0%
  • the temperature of the first heating roller is reduced by 5 °C
  • the second heating box The temperature decreased by 3°C.
  • the multi-C-shaped high-hollowness bright fiber prepared by the spinneret of this embodiment has a fiber moisture regain of 0.49%, a saturated moisture absorption rate of 37%, a wicking height of 97cm, a drip diffusion time of 10.61, and a diffusion area of 771 mm2/30s (, the moisture permeability of the fabric is 7000 g/(m2.d), the surface resistance of the fabric is 1.15 ⁇ 1010 ⁇ .m, the surface charge density is 81uc/m2, the charge half-life is 133 S, and the plane contrast gloss is 1.77.
  • the multi-C-shaped high-cavity bright fiber prepared by the spinneret of this embodiment Compared with the existing conventional fibers of the same specification, the multi-C-shaped high-cavity bright fiber prepared by the spinneret of this embodiment: the fiber moisture regain is increased by 22%, the saturated moisture absorption rate is increased by 23%, and the wicking height is increased 21%, the drip diffusion time is shortened by 15%, the diffusion area is increased by 16%, the moisture permeability of the fabric is increased by 22%, the surface resistance of the fabric is reduced by 27%, the surface charge density is reduced by 30%, the charge half-life is shortened by 25%, and the plane contrast gloss is improved. 61%.
  • a multi-C-shaped high-cavity bright fiber the fiber includes a plurality of filaments distributed around the center of the fiber with an equal diameter and an annular shape, and every two filaments are joined to each other, and the two filaments are connected to each other.
  • Each of the fiber filaments is provided with a first cavity; the center of the fiber is also provided with a second cavity formed by a plurality of the fiber filaments distributed in a circular shape with equal diameters; the cross-section of the fiber filaments is C-shaped
  • the outer contour of the fiber is formed by a plurality of arcs connected end to end.
  • the present invention also provides a method for preparing the multi-C-shaped high-cavity bright fiber
  • the preparation method of the described multi-C-shaped high-cavity bright light fiber is as follows:
  • polyester is used as the raw material, and the spinneret of multi-C-shaped high and high hollowness bright fibers is used for melt spinning;
  • the controlled cooling and blowing temperature is 14-16°C lower, compared with the production conditions of the corresponding specifications, the spinning speed is reduced by 3-5%, the stretching ratio is reduced by 0.5-1.0%, and the temperature of a hot roll is reduced by 3-5%. Lower the temperature by 5 ⁇ 10°C, the temperature of the second hot box is 3 ⁇ 10°C higher, and the component pressure is 140 ⁇ 150kgf/cm2.
  • the present invention also provides a spinneret for preparing multi-C-shaped high-cavity bright fibers.
  • the spinneret is provided with a plurality of extrusion slits 21 that are annularly distributed around the center of the spinneret with equal diameters.
  • Each of the extrusion slits 21 is C-shaped.
  • the number of the extrusion slits 21 on the spinneret is 20.
  • the distance between the inner end points of each two of the extrusion slits 21 is 0.5 mm.
  • the minimum distance between every two extrusion slits 21 is 0.08 mm.
  • the width of each of the extrusion slits 21 is 0.05 mm.
  • the cooling blowing temperature is 16°C
  • the spinning speed is 3780m/min
  • the stretching ratio is 2.0
  • the temperature of the first hot roller is 75°C
  • the temperature of the second hot box is 155°C.
  • the component pressure is 150 kgf/cm2.
  • the spinning speed is reduced by 10%
  • the draw ratio is reduced by 1.0%
  • the temperature of the first heating roller is reduced by 10 °C
  • the second heating box The temperature is reduced by 10°C.
  • the multi-C-shaped high-cavity bright fiber prepared by the spinneret of this embodiment has a fiber moisture regain of 0.55%, a saturated moisture absorption rate of 39%, a wicking height of 104cm, a drip diffusion time of 8.41S, and a diffusion area of 872 mm2/ 30s, the moisture permeability of the fabric is 6300 g/(m2.d), the surface resistance of the fabric is 9.3 ⁇ 109 ⁇ .m, the surface charge density is 54 uc/m2, the charge half-life is 114 S, and the plane contrast gloss is 1.89.
  • the multi-C-shaped high-cavity bright fiber prepared by the spinneret of this embodiment the fiber moisture regain is increased by 31%, the saturated moisture absorption rate is increased by 30%, and the wicking height is increased 30%, the drip diffusion time is shortened by 30%, the diffusion area is increased by 30%, the moisture permeability of the fabric is increased by 30%, the surface resistance of the fabric is reduced by 40%, the surface charge density is reduced by 40%, the charge half-life is shortened by 40%, and the plane contrast gloss is improved. 80%.
  • a multi-C-shaped high-cavity bright fiber the fiber includes a plurality of filaments distributed around the center of the fiber with an equal diameter and an annular shape, and every two filaments are joined to each other, and the two filaments are Each of the fiber filaments is provided with a first cavity; the center of the fiber is also provided with a second cavity formed by a plurality of the fiber filaments distributed in a circular shape with equal diameters; the cross-section of the fiber filaments is C-shaped
  • the outer contour of the fiber is formed by a plurality of arcs connected end to end.
  • the present invention also provides a method for preparing the multi-C-shaped high-cavity bright fiber
  • the preparation method of the described multi-C-shaped high-cavity bright light fiber is as follows:
  • nylon 6 nylon 6
  • a spinneret with multiple C-shaped high and high hollowness bright fibers is used for melt spinning
  • the controlled cooling and blowing temperature is 14-16°C lower, compared with the production conditions of the corresponding specifications, the spinning speed is reduced by 3-5%, the stretching ratio is reduced by 0.5-1.0%, and the temperature of a hot roll is reduced by 3-5%. Lower the temperature by 5 ⁇ 10°C, the temperature of the second hot box is 3 ⁇ 10°C higher, and the component pressure is 140 ⁇ 150kgf/cm2.
  • the present invention also provides a spinneret for preparing multi-C-shaped high-cavity bright fibers.
  • the spinneret is provided with a plurality of extrusion slits 21 that are annularly distributed around the center of the spinneret with equal diameters.
  • Each of the extrusion slits 21 is C-shaped.
  • the number of the extrusion slits 21 on the spinneret is 12.
  • the distance between the inner end points of each two of the extrusion slits 21 is 0.65 mm.
  • the minimum distance between every two extrusion slits 21 is 0.10 mm.
  • the width of each of the extrusion slits 21 is 0.07 mm.
  • the cooling blowing temperature is 15°C
  • the spinning speed is 3900m/min
  • the stretching ratio is 2.38
  • the temperature of the first hot roller is 77°C
  • the temperature of the second hot box is 158°C.
  • the component pressure is 146 kgf/cm2.
  • the spinning speed is reduced by 7%
  • the draw ratio is reduced by 0.8%
  • the temperature of the first heating roller is reduced by 8 °C
  • the second heating box The temperature decreased by 7°C.
  • the multi-C-shaped high-cavity bright fiber prepared by the spinneret of this embodiment has a fiber moisture regain of 0.50%, a saturated moisture absorption rate of 38%, a wicking height of 114cm, a drip diffusion time of 9.0S, and a diffusion area of 840 mm2/ 30s, the moisture permeability of the fabric is 6750 g/(m2.d), the surface resistance of the fabric is 1.01 ⁇ 1010 ⁇ .m, the surface charge density is 58 uc/m2, the charge half-life is 124 S, and the plane contrast gloss is 1.89.
  • the multi-C-shaped high-cavity bright fiber prepared by the spinneret of this embodiment the fiber moisture regain is increased by 25%, the saturated moisture absorption rate is increased by 25%, and the wicking height is increased 26%, the drip diffusion time is shortened by 24%, the diffusion area is increased by 25%, the moisture permeability of the fabric is increased by 25%, the surface resistance of the fabric is reduced by 35%, the surface charge density is reduced by 36%, the charge half-life is shortened by 34%, and the plane contrast gloss is improved. 80%.
  • the terms “arranged”, “connected” and “connected” should be understood in a broad sense, for example, it may be a fixed connection, a detachable connection, or an integral connection ; It can be directly connected, or indirectly connected through an intermediate medium, and it can be the internal connection of two components.
  • the specific meanings of the above terms in the present invention can be understood in specific situations.

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Spinning Methods And Devices For Manufacturing Artificial Fibers (AREA)
  • Artificial Filaments (AREA)

Abstract

一种多C形高中空度亮光纤维,纤维包括多个围绕纤维的中心等径环状分布的纤维丝(11),每两个纤维丝(11)相互接合,且两个纤维丝(11)均设有第一空腔(12),纤维的中心还设有由多个纤维丝(11)等径环状分布所构成的第二空腔(13),纤维丝(11)的截面呈C字型,纤维的外轮廓由多个弧线首尾相接环绕而成。

Description

一种多C形高中空度亮光纤维及其制备方法 技术领域
本发明涉及纤维领域,具体涉及一种多C形高中空度亮光纤维及其制备方法。
背景技术
涤纶和锦纶是使用量最大的服装面料原料,其织物具有很好的抗皱性和保形性,但其织物沉重、吸湿透气性差,并容易因摩擦产生静电,穿着闷热。近年来,随着生产技术和人们对穿着需求的发展,用量迅速增长,中国已经成为涤纶化纤最大的生产和需求国家,生产和需求的发展与人们追求穿着舒适性、轻质化以及美观度的追求不相对称,这在很大程度上制约着其进一步发展。
基于上述情况,本发明提出了一种多C形高中空度亮光纤维及其制备方法,可有效解决以上问题。
技术解决方案
本发明的目的在于提供一种多C形高中空度亮光纤维及其制备方法。本发明的多C形高中空度亮光纤维及其喷丝板,结构简单,使用方便,通过纤维丝,采用多C形熔体挤出缝,并围绕纤维的中心等径环状分布,组成具有独特的多空腔形异形截面结构,中空度可高达40~50%,织物具有较好的轻质化效应,纤维的中空轮廓再加周边不规格轮廓造形成的纤维之间的空隙,进一步提高了纤维的轻质化,并改善了纤维织物的吸湿透气性以及防静电性能,且纤维的轮廓,具有较好的光学效应,再加多空腔造成的透光性,纤维及织物具有很好的反光透光效应 具有明亮的光泽。
本发明通过下述技术方案实现:
一种多C形高中空度亮光纤维,所述纤维包括多个围绕所述纤维的中心等径环状分布的纤维丝,每两个所述纤维丝相互接合,且两个所述纤维丝均设有第一空腔;所述纤维的中心还设有由多个所述纤维丝等径环状分布所构成的第二空腔;所述纤维丝的截面呈C字型;所述纤维的外轮廓由多个弧线首尾相接环绕而成。
本发明通过纤维丝,采用多C形熔体挤出缝,并围绕所述纤维的中心等径环状分布,组成具有独特的多空腔形异形截面结构,中空度可高达40~50%,织物具有较好的轻质化效应,所述纤维的中空轮廓再加周边不规格轮廓造形成的所述纤维之间的空隙,进一步提高了所述纤维的轻质化,并改善了纤维织物的吸湿透气性以及防静电性能,且所述纤维的轮廓,具有较好的光学效应,再加多空腔造成的透光性,纤维及织物具有很好的反光透光效应 具有明亮的光泽。
通过所述第一空腔和第二空腔,所述纤维的中空度及轻质化程度高,多空腔提高了纤维透光反光效果,再加所述纤维由弧线首尾相接环绕构成轮廓的光学效应,其纤维及织物具有较好的吸湿透气、保暖及防静电性能以及较高的轻质效应和超有光的光泽亮度,穿着舒适性和外观美观度好。
本发明还提供了一种所述的多C形高中空度亮光纤维的制备方法,
所述的多C形高中空度亮光纤维的制备方法如下:
在现有FDY纺丝机上,以涤纶或锦纶为原料,采用多C形高中空度亮光纤维的喷丝板,进行熔融纺丝;
所述熔融纺丝过程中,控制冷却吹风温度低14~16℃,与相应规格产品的生产条件相比,纺丝速度降低3~5%,拉伸倍数降低0.5~1.0%,一热辊温度降低5~10℃,二热箱温度高3~10℃,组件压力140~150kgf/cm 2
本发明还提供了一种制备多C形高中空度亮光纤维的喷丝板,所述喷丝板上设有多个围绕所述喷丝板中心等径环状分布的挤出缝,每个所述挤出缝呈C字型。
通过C字型的所述挤出缝,确保所述喷丝板制得的构成所述纤维的所述纤维丝呈C字型,且能形成所述第一空腔和第三空腔。
优选的,所述喷丝板上的所述挤出缝的数量为8~20个。
当所述挤出缝的数量为8~20个之间时,所制备的纤维的结构强度较好,轻质化效应也较好,还有较好的光学效应;当所述挤出缝的数量少于8时,制备的纤维结构强度较差,且中空度也不高;而所述挤出缝的数量大于20时,由于每个所述挤出缝必须要保证一定的缝宽,所述挤出缝的个数越多,所述喷丝板的制造难度越大,而且所述挤出缝的个数越多,每个所述挤出缝的宽度就越小,这也导致制备的纤维结构强度不高。
优选的,每两个所述挤出缝内端点之间的距离为0.5~1.0mm。
保持较近的距离,确保制备的纤维有足够的结构强度。
优选的,每两个所述挤出缝之间的最小距离为0.08~0.15mm。
确保每个所述挤出缝所喷出的纤维丝能和其他纤维丝相接合。
优选的,每个所述挤出缝的宽度均为0.05~0.08mm。
保证制备的纤维足够的结构强度,以及纤维有足够的中空度。
有益效果
本发明与现有技术相比,具有以下优点及有益效果:
本发明的多C形高中空度亮光纤维及其喷丝板,结构简单,使用方便,通过纤维丝,采用多C形熔体挤出缝,并围绕纤维的中心等径环状分布,组成具有独特的多空腔形异形截面结构,中空度可高达40~50%,织物具有较好的轻质化效应,纤维的中空轮廓再加周边不规格轮廓造形成的纤维之间的空隙,进一步提高了纤维的轻质化,并改善了纤维织物的吸湿透气性以及防静电性能,且纤维的轮廓,具有较好的光学效应,再加多空腔造成的透光性,纤维及织物具有很好的反光透光效应 具有明亮的光泽。
附图说明
图1为本发明实施例2中的所述喷丝板的结构示意图;
图2为本发明通过实施例2制备的所述纤维的结构示意图;
图3为本发明实施例3中的所述喷丝板的结构示意图;
图4为本发明通过实施例3制备的所述纤维的结构示意图;
图5为本发明实施例4中的所述喷丝板的结构示意图;
图6为本发明通过实施例4制备的所述纤维的结构示意图。
本发明的最佳实施方式
为了使本领域的技术人员更好地理解本发明的技术方案,下面结合具体实施例对本发明的优选实施方案进行描述,但是应当理解,附图仅用于示例性说明,不能理解为对本专利的限制;为了更好说明本实施例,附图某些部件会有省略、放大或缩小,并不代表实际产品的尺寸;对于本领域技术人员来说,附图中某些公知结构及其说明可能省略是可以理解的。附图中描述位置关系仅用于示例性说明,不能理解为对本专利的限制。
实施例 1
如图2、4和6所示,一种多C形高中空度亮光纤维,所述纤维包括多个围绕所述纤维的中心等径环状分布的纤维丝11,每两个所述纤维丝11相互接合,且两个所述纤维丝11均设有第一空腔12;所述纤维1的中心还设有由多个所述纤维丝11等径环状分布所构成的第二空腔13;所述纤维丝11的截面呈C字型;所述纤维的外轮廓由多个弧线首尾相接环绕而成。
本发明通过纤维丝11,采用多C形熔体挤出缝,并围绕所述纤维的中心等径环状分布,组成具有独特的多空腔形异形截面结构,中空度可高达40~50%,织物具有较好的轻质化效应,所述纤维的中空轮廓再加周边不规格轮廓造形成的所述纤维之间的空隙,进一步提高了所述纤维的轻质化,并改善了纤维织物的吸湿透气性以及防静电性能,且所述纤维的轮廓,具有较好的光学效应,再加多空腔造成的透光性,纤维及织物具有很好的反光透光效应 具有明亮的光泽。
按照国标GB/T 6503-2008(《化学纤维回潮率试验方法》)测定纤维的回潮率和吸湿率,本发明的所述纤维与相同规格常规纤维相比,其纤维及织物吸湿率、回潮率提高20-30%。
按照国标GB/T 21665.1-2008(《纺织品吸湿速干性的评定 第1部分:单项组合试验法》),测试织物的芯吸高度,本发明的所述纤维与相同规格常规纤维相比,本发明的所述纤维及织物的芯吸高度提高20-30%。
按照国标GB/T 21655.2-2009(《纺织品吸湿速干性的评定第2部分:动态水分传递法》),测试织物滴水扩散面积、滴水扩散时间,本发明的所述纤维与相同规格常规纤维相比,本发明的所述纤维及织物的织物滴水扩散面积提高20-30%,滴水扩散时间缩短15-20%。
按照国标GB/T 12704-1991(《织物透湿量测定方法 透湿杯法》),测试织物的透湿量,本发明的所述纤维与相同规格常规纤维相比,本发明的所述纤维及织物的透湿量提高25-30%。
按照国标GB/T 5453-1997(《纺织品织物透气性的测定》)测试织物透气量,本发明的所述纤维与相同规格常规纤维相比,本发明的所述纤维及织物的透气量提高25-30%。
按照国标GB/T 12703-91(《纺织品静电测试方法》)测试织物表比电阻、电荷面密度以及电荷半衰期,本发明的所述纤维与相同规格常规纤维相比,本发明的所述纤维及织物的比电阻、电荷面密度以及电荷半衰期等导电性指标低30-40%。
按照GB/T 8686-1988(《织物光泽测试方法》)测试纤维织物的光泽亮度,在入射角45°,观察角45°,入射光照度E在390lx条件下测试本发明的所述纤维与相同规格常规纤维的平面对比光泽度,本发明的所述纤维与比常规有光纤维及织物高出60-80%。
实施例 2
如图1所示,一种多C形高中空度亮光纤维,所述纤维包括多个围绕所述纤维的中心等径环状分布的纤维丝,每两个所述纤维丝相互接合,且两个所述纤维丝均设有第一空腔;所述纤维的中心还设有由多个所述纤维丝等径环状分布所构成的第二空腔;所述纤维丝的截面呈C字型;所述纤维的外轮廓由多个弧线首尾相接环绕而成。
本发明还提供了一种所述的多C形高中空度亮光纤维的制备方法,
所述的多C形高中空度亮光纤维的制备方法如下:
在现有FDY纺丝机上,以涤纶为原料,采用多C形高中空度亮光纤维的喷丝板,进行熔融纺丝;
所述熔融纺丝过程中,控制冷却吹风温度低14~16℃,与相应规格产品的生产条件相比,纺丝速度降低3~5%,拉伸倍数降低0.5~1.0%,一热辊温度降低5~10℃,二热箱温度高3~10℃,组件压力140~150kgf/cm2。
本发明还提供了一种制备多C形高中空度亮光纤维的喷丝板,所述喷丝板上设有多个围绕所述喷丝板中心等径环状分布的挤出缝21,每个所述挤出缝21呈C字型。
进一步地,在本实施例中,所述喷丝板上的所述挤出缝21的数量为8个。
进一步地,在本实施例中,每两个所述挤出缝21内端点之间的距离为1.0mm。
进一步地,在本实施例中,每两个所述挤出缝21之间的最小距离为0. 15mm。
进一步地,在本实施例中,每个所述挤出缝21的宽度均为0.08mm。
且在使用本实施例参数的所述喷丝板时的其他参数要求,冷却吹风温度14℃,纺丝速度3900m/min,拉伸倍数2.3,一热辊温度80℃,二热箱温度162℃,组件压力140 kgf/cm2。
使用本实施例参数的所述喷丝板时的其他参数要求与现有喷丝板相比:纺丝速度降低5%,拉伸倍数降低1.0%,一热辊温度降低5℃,二热箱温度降低3℃。
通过本实施例的所述喷丝板制得的多C形高中空度亮光纤维,纤维回潮率0.49%,饱和吸湿率37%,芯吸高度97cm、滴水扩散时间10.61,扩散面积771 mm2/30s(,织物透湿量7000 g/(m2.d) 织物表比电阻1.15×1010Ω.m,电荷面密度81uc/m2以及电荷半衰期133 S,平面对比光泽度1.77。
通过本实施例的所述喷丝板制得的多C形高中空度亮光纤维与现有的相同规格常规纤维相比:纤维回潮率提高22%,饱和吸湿率提高23%,芯吸高度提高21%、滴水扩散时间缩短15%,扩散面积提高16%,织物透湿量提高22%,织物表比电阻降低27%,电荷面密度降低30%以及电荷半衰期缩短25%,平面对比光泽度提高61%。
实施例 3
如图3所示,一种多C形高中空度亮光纤维,所述纤维包括多个围绕所述纤维的中心等径环状分布的纤维丝,每两个所述纤维丝相互接合,且两个所述纤维丝均设有第一空腔;所述纤维的中心还设有由多个所述纤维丝等径环状分布所构成的第二空腔;所述纤维丝的截面呈C字型;所述纤维的外轮廓由多个弧线首尾相接环绕而成。
本发明还提供了一种所述的多C形高中空度亮光纤维的制备方法,
所述的多C形高中空度亮光纤维的制备方法如下:
在现有FDY纺丝机上,以涤纶为原料,采用多C形高中空度亮光纤维的喷丝板,进行熔融纺丝;
所述熔融纺丝过程中,控制冷却吹风温度低14~16℃,与相应规格产品的生产条件相比,纺丝速度降低3~5%,拉伸倍数降低0.5~1.0%,一热辊温度降低5~10℃,二热箱温度高3~10℃,组件压力140~150kgf/cm2。
本发明还提供了一种制备多C形高中空度亮光纤维的喷丝板,所述喷丝板上设有多个围绕所述喷丝板中心等径环状分布的挤出缝21,每个所述挤出缝21呈C字型。
进一步地,在本实施例中,所述喷丝板上的所述挤出缝21的数量为20个。
进一步地,在本实施例中,每两个所述挤出缝21内端点之间的距离为0.5mm。
进一步地,在本实施例中,每两个所述挤出缝21之间的最小距离为0.08mm。
进一步地,在本实施例中,每个所述挤出缝21的宽度均为0.05mm。
且在使用本实施例参数的所述喷丝板时的其他参数要求,冷却吹风温度16℃,纺丝速度3780m/min,拉伸倍数2.0,一热辊温度75℃,二热箱温度155℃,组件压力150 kgf/cm2。
使用本实施例参数的所述喷丝板时的其他参数要求与现有喷丝板相比:纺丝速度降低10%,拉伸倍数降低1.0%,一热辊温度降低10℃,二热箱温度降低10 ℃。
通过本实施例的所述喷丝板制得的多C形高中空度亮光纤维,纤维回潮率0.55%,饱和吸湿率39%,芯吸高度104cm、滴水扩散时间8.41S,扩散面积872 mm2/30s,织物透湿量6300 g/(m2.d) ,织物表比电阻9.3×109Ω.m,电荷面密度54 uc/m2以及电荷半衰期114 S,平面对比光泽度1.89。
通过本实施例的所述喷丝板制得的多C形高中空度亮光纤维与现有的相同规格常规纤维相比:纤维回潮率提高31%,饱和吸湿率提高30%,芯吸高度提高30%、滴水扩散时间缩短30%,扩散面积提高30%,织物透湿量提高30%,织物表比电阻降低40%,电荷面密度降低40%以及电荷半衰期缩短40%,平面对比光泽度提高80%。
实施例 4
如图5所示,一种多C形高中空度亮光纤维,所述纤维包括多个围绕所述纤维的中心等径环状分布的纤维丝,每两个所述纤维丝相互接合,且两个所述纤维丝均设有第一空腔;所述纤维的中心还设有由多个所述纤维丝等径环状分布所构成的第二空腔;所述纤维丝的截面呈C字型;所述纤维的外轮廓由多个弧线首尾相接环绕而成。
本发明还提供了一种所述的多C形高中空度亮光纤维的制备方法,
所述的多C形高中空度亮光纤维的制备方法如下:
在现有FDY纺丝机上,以锦纶6(尼龙6)为原料,采用多C形高中空度亮光纤维的喷丝板,进行熔融纺丝;
所述熔融纺丝过程中,控制冷却吹风温度低14~16℃,与相应规格产品的生产条件相比,纺丝速度降低3~5%,拉伸倍数降低0.5~1.0%,一热辊温度降低5~10℃,二热箱温度高3~10℃,组件压力140~150kgf/cm2。
本发明还提供了一种制备多C形高中空度亮光纤维的喷丝板,所述喷丝板上设有多个围绕所述喷丝板中心等径环状分布的挤出缝21,每个所述挤出缝21呈C字型。
进一步地,在本实施例中,所述喷丝板上的所述挤出缝21的数量为12个。
进一步地,在本实施例中,每两个所述挤出缝21内端点之间的距离为0.65mm。
进一步地,在本实施例中,每两个所述挤出缝21之间的最小距离为0.10mm。
进一步地,在本实施例中,每个所述挤出缝21的宽度均为0.07mm。
且在使用本实施例参数的所述喷丝板时的其他参数要求,冷却吹风温度15℃,纺丝速度3900m/min,拉伸倍数2.38,一热辊温度77℃,二热箱温度158℃,组件压力146 kgf/cm2。
使用本实施例参数的所述喷丝板时的其他参数要求与现有喷丝板相比:纺丝速度降低7%,拉伸倍数降低0.8%,一热辊温度降低8℃,二热箱温度降低7 ℃。
通过本实施例的所述喷丝板制得的多C形高中空度亮光纤维,纤维回潮率0.50%,饱和吸湿率38%,芯吸高度114cm、滴水扩散时间9.0S,扩散面积840 mm2/30s,织物透湿量6750 g/(m2.d),织物表比电阻1.01×1010Ω.m,电荷面密度58 uc/m2以及电荷半衰期124 S,平面对比光泽度1.89。
通过本实施例的所述喷丝板制得的多C形高中空度亮光纤维与现有的相同规格常规纤维相比:纤维回潮率提高25%,饱和吸湿率提高25%,芯吸高度提高26%、滴水扩散时间缩短24%,扩散面积提高25%,织物透湿量提高25%,织物表比电阻降低35%,电荷面密度降低36%以及电荷半衰期缩短34%,平面对比光泽度提高80%。
依据本发明的描述及附图,本领域技术人员很容易制造或使用本发明的多C形高中空度亮光纤维及其喷丝板,并且能够产生本发明所记载的积极效果。
如无特殊说明,本发明中,若有术语“长度”、“宽度”、“上”、“下”、“前”、“后”、“左”、“右”、“竖直”、“水平”、“顶”、“底”“内”、“外”、“顺时针”、“逆时针”、“轴向”、“径向”、“周向”等指示的方位或位置关系是基于附图所示的方位或位置关系,仅是为了便于描述本发明和简化描述,而不是指示或暗示所指的装置或元件必须具有特定的方位、以特定的方位构造和操作,因此本发明中描述方位或位置关系的用语仅用于示例性说明,不能理解为对本专利的限制,对于本领域的普通技术人员而言,可以结合附图,并根据具体情况理解上述术语的具体含义。
除非另有明确的规定和限定,本发明中,若有术语“设置”、“相连”及“连接”应做广义理解,例如,可以是固定连接,也可以是可拆卸连接,或一体地连接;可以是直接相连,也可以通过中间媒介间接相连,可以是两个元件内部的连通。对于本领域的普通技术人员而言,可以具体情况理解上述术语在本发明中的具体含义。
以上所述,仅是本发明的较佳实施例,并非对本发明做任何形式上的限制,凡是依据本发明的技术实质对以上实施例所作的任何简单修改、等同变化,均落入本发明的保护范围之内。

Claims (7)

  1. 一种多C形高中空度亮光纤维,其特征在于:所述纤维包括多个围绕所述纤维的中心等径环状分布的纤维丝(11),每两个所述纤维丝(11)相互接合,且两个所述纤维丝(11)均设有第一空腔(12);所述纤维(1)的中心还设有由多个所述纤维丝(11)等径环状分布所构成的第二空腔(13);所述纤维丝(11)的截面呈C字型;所述纤维的外轮廓由多个弧线首尾相接环绕而成。
  2. 一种如权利要求1所述的多C形高中空度亮光纤维的制备方法,其特征在于:
    所述的多C形高中空度亮光纤维的制备方法如下:
    在现有FDY纺丝机上,以涤纶或锦纶为原料,采用多C形高中空度亮光纤维的喷丝板,进行熔融纺丝;
    所述熔融纺丝过程中,控制冷却吹风温度低14~16℃,与相应规格产品的生产条件相比,纺丝速度降低3~5%,拉伸倍数降低0.5~1.0%,一热辊温度降低5~10℃,二热箱温度高3~10℃,组件压力140~150kgf/cm 2
  3. 根据权利要求2所述的多C形高中空度亮光纤维的制备方法,其特征在于:所述喷丝板上设有多个围绕所述喷丝板中心等径环状分布的挤出缝(21),每个所述挤出缝(21)呈C字型。
  4. 根据权利要求3所述的多C形高中空度亮光纤维的制备方法,其特征在于:所述喷丝板上的所述挤出缝(21)的数量为8~20个。
  5. 根据权利要求3所述的多C形高中空度亮光纤维的制备方法,其特征在于:每两个所述挤出缝(21)内端点之间的距离为0.5~1.0mm。
  6. 根据权利要求3所述的多C形高中空度亮光纤维的制备方法,其特征在于:每两个所述挤出缝(21)之间的最小距离为0.08~0.15mm。
  7. 根据权利要求3所述的多C形高中空度亮光纤维的制备方法,其特征在于:每个所述挤出缝(21)的宽度均为0.05~0.08mm。
PCT/CN2021/117086 2020-11-23 2021-09-08 一种多c形高中空度亮光纤维及其制备方法 WO2022105375A1 (zh)

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