WO2022095816A1 - Composition herbicide ternaire comprenant un composé oxyiminoaryle substitué par un dérivé acide carboxylique et son utilisation - Google Patents

Composition herbicide ternaire comprenant un composé oxyiminoaryle substitué par un dérivé acide carboxylique et son utilisation Download PDF

Info

Publication number
WO2022095816A1
WO2022095816A1 PCT/CN2021/127863 CN2021127863W WO2022095816A1 WO 2022095816 A1 WO2022095816 A1 WO 2022095816A1 CN 2021127863 W CN2021127863 W CN 2021127863W WO 2022095816 A1 WO2022095816 A1 WO 2022095816A1
Authority
WO
WIPO (PCT)
Prior art keywords
herbicidal composition
methyl
active ingredient
ternary
inhibitors
Prior art date
Application number
PCT/CN2021/127863
Other languages
English (en)
Chinese (zh)
Inventor
李平生
彭学岗
赵德
张景远
金涛
Original Assignee
青岛清原化合物有限公司
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 青岛清原化合物有限公司 filed Critical 青岛清原化合物有限公司
Publication of WO2022095816A1 publication Critical patent/WO2022095816A1/fr

Links

Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
    • A01N33/16—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds containing nitrogen-to-oxygen bonds
    • A01N33/18—Nitro compounds
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N35/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having two bonds to hetero atoms with at the most one bond to halogen, e.g. aldehyde radical
    • A01N35/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having two bonds to hetero atoms with at the most one bond to halogen, e.g. aldehyde radical at least one of the bonds to hetero atoms is to nitrogen
    • A01N35/10—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having two bonds to hetero atoms with at the most one bond to halogen, e.g. aldehyde radical at least one of the bonds to hetero atoms is to nitrogen containing a carbon-to-nitrogen double bond
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
    • A01N37/22—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof the nitrogen atom being directly attached to an aromatic ring system, e.g. anilides
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
    • A01N37/26—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof containing the group; Thio analogues thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
    • A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
    • A01N43/06—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings
    • A01N43/10—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings with sulfur as the ring hetero atom
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/50—1,3-Diazoles; Hydrogenated 1,3-diazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/60—1,4-Diazines; Hydrogenated 1,4-diazines
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/647—Triazoles; Hydrogenated triazoles
    • A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/66—1,3,5-Triazines, not hydrogenated and not substituted at the ring nitrogen atoms
    • A01N43/68—1,3,5-Triazines, not hydrogenated and not substituted at the ring nitrogen atoms with two or three nitrogen atoms directly attached to ring carbon atoms
    • A01N43/70—Diamino—1,3,5—triazines with only one oxygen, sulfur or halogen atom or only one cyano, thiocyano (—SCN), cyanato (—OCN) or azido (—N3) group directly attached to a ring carbon atom
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/707—1,2,3- or 1,2,4-triazines; Hydrogenated 1,2,3- or 1,2,4-triazines
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/74—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
    • A01N43/78—1,3-Thiazoles; Hydrogenated 1,3-thiazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/82—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with three ring hetero atoms
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • A01N47/30—Derivatives containing the group >N—CO—N aryl or >N—CS—N—aryl
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • A01N47/36—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< directly attached to at least one heterocyclic ring; Thio analogues thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • A01N47/38—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< where at least one nitrogen atom is part of a heterocyclic ring; Thio analogues thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
    • A01N57/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds
    • A01N57/20—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds containing acyclic or cycloaliphatic radicals
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01P—BIOCIDAL, PEST REPELLANT, PEST ATTRACTANT OR PLANT GROWTH REGULATORY ACTIVITY OF CHEMICAL COMPOUNDS OR PREPARATIONS
    • A01P13/00—Herbicides; Algicides
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01P—BIOCIDAL, PEST REPELLANT, PEST ATTRACTANT OR PLANT GROWTH REGULATORY ACTIVITY OF CHEMICAL COMPOUNDS OR PREPARATIONS
    • A01P13/00—Herbicides; Algicides
    • A01P13/02—Herbicides; Algicides selective

Definitions

  • the invention belongs to the field of pesticides, and in particular relates to a ternary herbicidal composition comprising a carboxylic acid derivative-substituted oxyimino aryl compound and its application.
  • Chemical weeding is the most economical and effective method for weed control in farmland.
  • the long-term continuous and high-dose use of chemical herbicides of a single species or single mode of action is likely to cause problems such as weed resistance and resistance evolution.
  • the rational compounding or compounding of herbicide compounds has the advantages of expanding the weed spectrum, improving the control effect, delaying the occurrence and development of drug resistance and drug resistance of weeds, etc., and is one of the most effective methods to solve the above problems. Therefore, there is an urgent need to develop herbicidal compositions with high safety, broad herbicidal spectrum, synergistic effects and solving the problem of resistant weeds.
  • the present invention provides a ternary herbicidal composition
  • a ternary herbicidal composition comprising an oxyimino aryl compound substituted with a carboxylic acid derivative and an application thereof.
  • Leaf and other weed problems have the characteristics of expanding the herbicidal spectrum, reducing the application amount, producing synergistic effects and solving resistant weeds.
  • a ternary herbicidal composition comprising a carboxylic acid derivative-substituted oxyimino aryl compound, characterized in that it comprises herbicidal effective amounts of active ingredient A, active ingredient B and active ingredient C, wherein,
  • Active ingredient A is N-(2-aminoethyl)-2-aminoethyl-N-(2-aminoethyl)-2-aminoethyl-N-(2-aminoethyl)-2-aminoethyl-N-(2-aminoethyl)-2-aminoethyl-N-(2-aminoethyl)-2-aminoethyl
  • the active ingredients B and C are respectively selected from any one of the following types of compounds and another compound of different types:
  • VLCFA inhibitors Acetochlor (CAS No.: 34256-82-1), Metolachlorsperm (CAS No.: 87392-12-9), Meafenpyr (CAS No.: 447399-55- 5), metolachlor (CAS number: 86763-47-5), fenfenacil (CAS number: 73250-68-7), dimethachlor (CAS number: 87674-68-8), Butachlor (CAS No.: 23184-66-9), Pretochlor (CAS No.: 51218-49-6);
  • Microtubule assembly inhibitor pendimethalin (CAS No.: 40487-42-1), Zhongdingling (CAS No.: 33629-47-9);
  • EPSPS inhibitor glyphosate (CAS number: 1071-83-6);
  • GS inhibitor glufosinate-ammonium (CAS number: 77182-82-2);
  • PSII inhibitors atrazine (CAS number: 1912-24-9), terbutin (CAS number: 5915-41-3), mezotrione (CAS number: 21087-64-9), isocyanurate (CAS number: 21087-64-9) Proprion (CAS No.: 34123-59-6), Chlormelon (CAS No.: 15545-48-9), Azafenazone (CAS No.: 129909-90-6), Diuron (CAS No.: 330) -54-1), barnyardgrass (CAS number: 709-98-8);
  • HPPD inhibitor isoxaflutole (CAS number: 141112-29-0), mesotrione (CAS number: 104206-82-8);
  • DOXP inhibitor clomazone (CAS number: 81777-89-1), bixlozone (CAS number: 81777-95-9);
  • PDS inhibitor diflufenac (CAS number: 83164-33-4);
  • PPO inhibitor sulfentrazone (CAS number: 122836-35-5), oxadiazon (CAS number: 19666-30-9);
  • ALS inhibitors penoxsulam (CAS number: 219714-96-2), thiazosulfuron (CAS number: 317815-83-1), imazamox (CAS number: 114311-32) -9), nicosulfuron (CAS number: 111991-09-4), rimsulfuron (CAS number: 122931-48-0), chlorpyrisulfuron (CAS number: 100784-20-1), Sulfentrazone (CAS No.: 98967-40-9), Sulfentrazone (CAS No.: 147150-35-4), Imazamil (CAS No.: 104098-48-8), Thifensulfuron-methyl (CAS number: 79277-27-3), flufenoxsulam (CAS number: 874195-61-6), bensulfuron-methyl (CAS number: 83055-99-6), pyrazosulfuron (CAS number: 83055-99-6) 93697-74-6);
  • ACCase inhibitors quizalofop-p-ethyl (CAS number: 100646-51-3), clethodim (CAS number: 99129-21-2);
  • the weight ratio of A, B and C is 1 ⁇ 200:1 ⁇ 1000:0.1 ⁇ 5000, 5 ⁇ 150:5 ⁇ 600:1 ⁇ 3000, 8 ⁇ 120:10 ⁇ 500:5 ⁇ 1000, 10 ⁇ 100 : 20 ⁇ 400:10 ⁇ 800, 20 ⁇ 90:30 ⁇ 300:30 ⁇ 600, 25 ⁇ 80:80 ⁇ 200:50 ⁇ 300 or 30 ⁇ 60:100 ⁇ 150:100 ⁇ 200.
  • the mass percentage content of A, B and C in the herbicidal composition accounts for 1-95% of the total, preferably 10-80%.
  • the herbicidal composition also includes conventional adjuvants including carriers and/or surfactants.
  • carrier means an organic or inorganic, natural or synthetic substance. They facilitate application of the active ingredient, the carrier being generally inert and must be agriculturally acceptable, especially by the plants being treated.
  • the carrier can be solid, such as clay, natural or synthetic silicates, silica, resins, waxes, solid fertilizers, etc.; or liquid, such as water, alcohols, ketones, petroleum fractions, aromatic or waxy hydrocarbons, chlorine Substitute hydrocarbons, liquefied gas, etc.
  • Surfactants may include emulsifying agents, dispersing agents or wetting agents, which may be ionic or non-ionic. Examples which may be mentioned are the salts of polyacrylic acid, lignosulfonate, phenolsulfonic acid or naphthalenesulfonic acid, ethylene oxide with aliphatic alcohols or with aliphatic acids or with aliphatic amines with substituted phenols (particularly polymers of alkylphenols or arylphenols), sulfosuccinates, taurine derivatives (especially taurine alkyl esters) and phosphate esters of alcohols or polyhydroxyethylated phenols, Alkyl sulfonates, alkylaryl sulfonates, alkyl sulfates, lauryl ether sulfates, fatty alcohol sulfates, and sulfated hexadec-, heptadeca-, and octadecanol and
  • compositions may also contain various other components such as protective colloids, binders, thickeners, thixotropic agents, penetrants, stabilizers, chelating agents, dyes, colorants and polymers.
  • composition of the present invention can be mixed with the following active substances, such as known substances in "World Encyclopedia of Pesticide New Variety Technology", China Agricultural Science and Technology Press, 2010.9 and the documents cited herein.
  • active substances such as known substances in "World Encyclopedia of Pesticide New Variety Technology", China Agricultural Science and Technology Press, 2010.9 and the documents cited herein.
  • the herbicidal active substances mentioned below (Note: the name of the compound, or the common name according to the International Organization for Standardization (ISO), or the chemical name, with a code name when appropriate): Acetochlor, Butachlor, Alachlor, Metolachlor, Metolachlor, Spermatachlor, Pretolachlor, Toxachlor, Clochlor, Naprochlor, R-Levonachlor, Propionil , fenflufen, fenflufen, difenafen, dichlorfen, fenbutafen, brombutafen, dimethafen, high-efficiency dimethafen, ethoxy
  • the herbicidal composition further comprises at least one safener selected from:
  • Dichlorophenylpyrazole carboxylic acid derivatives preferred compounds are, for example, ethyl 1-(2,4-dichlorophenyl)-5-methylpyrazole-3-carboxylate (S1-2), 1-(2,4-Dichlorophenyl)-5-isopropylpyrazole-3-carboxylic acid ethyl ester (S1-3), 1-(2,4-dichlorophenyl)-5-(1 ,1-Dimethyl-ethyl)pyrazole-3-carboxylic acid ethyl ester (S1-4), 1-(2,4-dichlorophenyl)-5-phenylpyrazole-3-carboxylic acid ethyl ester Esters (S1-5), and related compounds described in EP-A-333131 and EP-A-269806.
  • Triazole carboxylic acid (S1) compounds the preferred compound is for example fenchlorazole, namely 1-(2,4-dichlorophenyl)-5-trichloromethyl-(1H)-1 , 2,4-triazole-3-carboxylic acid ethyl ester (S1-6) and related compounds (see EP-A-174562 and EP-A-346620).
  • S2 8-quinolineoxyacetic acid (S2) compounds, preferably 1-methylhex-1-yl (5-chloro-8-quinolineoxy) acetate (S2-1, cloquintocet- mexyl), such as PM (pp. 195-196), (1,3-dimethylbutan-1-yl)(5-chloro-8-quinolinyloxy)acetate (S2-2), 4- Allyloxybutyl (5-chloro-8-quinolinyloxy) acetate (S2-3), 1-allyloxyprop-2-yl (5-chloro-8-quinolinyloxy) yl) acetate (S2-4), (5-chloro-8-quinolinyloxy) ethyl acetate (S2-5), (5-chloro-8-quinolinyloxy) methyl acetate (S2- 6), (5-chloro-8-quinolineoxy) allyl acetate (S2-7), 2-(2-propyleneiminooxy)-1-ethy
  • 5-chloro-8-quinolinyloxy)malonic acid compounds preferred compounds are for example (5-chloro-8-quinolinyloxy)diethyl malonate, (5-chloro-8 -quinolinyloxy)diallyl malonate, (5-chloro-8-quinolinyloxy)-malonate methylethyl ester and related compounds described in EP-A-0582198.
  • phenoxyacetic acid phenoxypropionic acid or aromatic carboxylic acid type active compounds such as 2,4-dichlorophenoxyacetic acid (and ester) (2,4-D), 4-chloro-2- Methylphenoxypropionate (2-methyl-4-chloropropionic acid (mecoprop)), MCPA or 3,6-dichloro-2-methoxybenzoic acid (and ester) (dicamba) .
  • aromatic carboxylic acid type active compounds such as 2,4-dichlorophenoxyacetic acid (and ester) (2,4-D), 4-chloro-2- Methylphenoxypropionate (2-methyl-4-chloropropionic acid (mecoprop)), MCPA or 3,6-dichloro-2-methoxybenzoic acid (and ester) (dicamba) .
  • the safeners are preferably bisfenoxazole acid (CAS: 163520-33-0), cyprosulfamide (CAS: 221667-31-8), pyraclostrobin (CAS: 135590-91-9), quinoquine (CAS: 135590-91-9) : 99607-70-2), one or more of gibberellic acid (CAS: 7-06-5), furilazole (CAS: 121776-33-8), metcamifen (CAS: 129531-12-0).
  • the abbreviated form of the generic name of the active compound includes in each case all customary derivatives, such as esters and salts, as well as isomers, in particular optical isomers, in particular one or more commercially available forms.
  • the common name denotes esters or salts, it also includes in each case all other customary derivatives, such as other esters and salts, free acids and neutral compounds, as well as isomers, especially optical isomers, especially in one or more commercially available forms.
  • the chemical names of compounds given represent at least one compound covered by the generic name, usually the preferred compound.
  • salts also include salts formed by the exchange of cations with hydrogen atoms in the sulfonamide group.
  • 2 methyl 4 chloride derivatives include but are not limited to: 2 methyl 4 chloride sodium salt, potassium salt, dimethylammonium salt, isopropylamine salt, etc., and 2 methyl 4 chloro methyl ester, ethyl ester, isooctyl ester, ethyl sulfide Esters, etc.
  • 2,4-D derivatives include, but are not limited to: 2,4-D salts such as sodium, potassium, dimethylammonium, triethanolammonium, isopropylamine, choline, etc., and 2,4 -D esters such as methyl ester, ethyl ester, butyl ester, isooctyl ester, etc.
  • the salts of the compounds are preferably in the form of the respective alkali metal, alkaline earth metal or ammonium salts, preferably the respective alkali metal salts, more preferably the respective sodium or potassium salts, Most preferably in the form of the respective sodium salts.
  • compositions of the present invention may be diluted or used directly by the user prior to use. Its preparation can be prepared by the usual processing method, that is, after mixing the active substance with a liquid solvent or a solid carrier, and then adding one or more of surfactants such as dispersing agent, stabilizer, wetting agent, adhesive, defoaming agent, etc. kind.
  • surfactants such as dispersing agent, stabilizer, wetting agent, adhesive, defoaming agent, etc. kind.
  • the specific formulations of the herbicidal composition are dispersible oil suspensions, water suspensions, suspoemulsions, wettable powders, emulsifiable concentrates, water dispersible granules (dry suspensions), water emulsions, and microemulsions.
  • compositions of the present invention can be mixed with solid and liquid additives conventionally used in prior art formulations.
  • the amount of active ingredient used varies with external conditions, such as temperature, humidity, properties of herbicides used, and the like. It can vary widely, eg between 0.001 and 1.0 kg/ha, or more active substance, but is preferably between 0.005 and 750 g/ha, especially between 0.005 and 500 g/ha.
  • compositions of the present invention can be applied by spraying to the foliage of the plants to be treated, ie to weeds, especially to surfaces that are infested or susceptible to infestation.
  • the present invention also provides an application of the herbicidal composition in controlling weeds; and a method for controlling unwanted plant growth, comprising applying the herbicidal composition to plants, plant parts, plants The area where seeds or plants grow.
  • the herbicidal composition is used to selectively control weeds in useful crops, more preferably, the useful crops are transgenic crops or crops treated with genome editing technology.
  • the compounds of the present invention can be used to treat all plants and plant parts.
  • Plant varieties and cultivars can be obtained by conventional propagation and breeding methods or by genetic engineering methods.
  • Genetically modified plants are those in which a heterologous gene (transgene) has been stably integrated into the genome of the plant.
  • a transgene defined by its specific location in the plant genome is called a transformation event or transgenic event.
  • Genetically modified plant cultivars that can be treated according to the invention include those resistant to one or more biotic stresses (pests, such as nematodes, insects, mites, fungi, etc.) or abiotic stresses (drought, low temperature, soil salinization etc.), or it contains other desirable features. Plants can be genetically modified to exhibit traits such as herbicide tolerance, insect tolerance, modified oil characteristics, or drought tolerance. Information on available genetically modified plants comprising single gene transformation events or combinations of transformation events can be obtained, for example, from publicly available databases maintained by the United States Department of Agriculture.
  • composition of the present invention is environmentally friendly and is easily degraded in the environment.
  • the herbicidal composition of the present invention has low cost and convenient use, and its popularization and application have huge economic and social benefits.
  • the test soil was quantitatively filled to 3/4 of the pot, and then watered from the bottom of the pot to make the soil completely wet to saturation.
  • the pretreated weed seeds (Amaranthus thorn, Amaranthus amaranthus) were evenly and quantitatively sown on the surface, covered with soil 0.5-2cm according to the size of the seeds, and used 24 hours after sowing.
  • the desired active ingredient A comes from patent CN202010281666.4, and its preparation example is as follows:
  • the desired Active Ingredient B and Active Ingredient C are purchased from the reagent company.
  • the original medicines were all made of acetone as solvent, diluted with 0.1% emulsifier Tween-80 aqueous solution, and diluted with current use.
  • Each treatment was repeated 3 times, with 5 pots per treatment, and 30 weed seeds were sown in each pot.
  • the whole seedlings of surviving weeds were cut off along the soil surface with a blade, and the fresh weight of the weeds was weighed with an analytical balance. For dead weeds, the fresh weight is zero.
  • the investigation was conducted 15 days after treatment, and a total of 1 investigation was conducted.
  • Colby's test was used to evaluate the types of combined effects of any two or three combinations on weeds.
  • E (%) (fresh weight of weeds in the treatment area/fresh weight of weeds in the control area) ⁇ 100
  • X represents the weed survival rate of A when the dosage is P
  • Y represents the weed survival rate of B when the dosage is Q
  • E0 represents the theoretical weed survival rate of A+B when the dosage is (P+Q)
  • E represents Actual weed survival for each treatment.
  • X, Y, Z, and N respectively represent the actual survival rate of n single agents, and n is the number of compound herbicide varieties.
  • E0-E>10% it shows synergistic effect; when E0-E ⁇ -10%, it shows antagonism; when E0-E is between ⁇ 10%, it shows that there is additive effect.
  • the weeds were cultivated in pots, using a 180 ⁇ 140mm plastic nutrient bowl, placed in an enamel plate, and containing the surface soil (4/5 places) collected from the farmland that had been air-dried and sieved, and the soil humidity was initially controlled at 20%, select weed seeds with full and uniform grains, soak them in warm water at 25°C for 6 hours, and germinate them in a biochemical incubator (dark) at 28°C. Place the just white weed seeds evenly on the soil surface, according to the size of the seeds. Size and then cover with soil 0.5-1cm.
  • the original medicines were all made of acetone as solvent, diluted with 0.1% emulsifier Tween-80 aqueous solution, and diluted with current use.
  • Each treatment was repeated 3 times, with 5 pots per treatment, and 30 weed seeds were sown in each pot, for a total of 150 seeds per treatment.
  • test shared medicine once. After the 3 leaves of Papia chinensis, thinned the seedlings, kept 20 weeds in each pot, and kept 100 weeds in each treatment, and then continued to cultivate until 4-5 leaves were evenly sprayed on stems and leaves.
  • the cultured test materials were evenly placed on a platform with an area of 0.5m 2 , and the stems and leaves of the 3WP-2000 walking spray tower were sprayed with a spray volume of 450 kg/ha.
  • the spray pressure is 0.3MPa. After all the liquid medicine is sprayed, close the air valve, open the spray tower door after 30 seconds, and take out the nutrition bowl. Then open the air valve, spray 50ml of water, and clean the spray pipe.
  • the present invention unexpectedly finds that the composition is used for controlling broad-leaved weeds such as Amaranthus thorn and Amaranthus amaranthus, as well as grass weeds such as Pseudomonas auratus, etc.
  • broad-leaved weeds such as Amaranthus thorn and Amaranthus amaranthus
  • grass weeds such as Pseudomonas auratus, etc.
  • this synergistic effect is more significant at low doses, which can reduce the dosage of the drug, reduce the pollution to the environment, and reduce the cost of agricultural use by rational compounding. It is efficient and has good application prospects.

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Zoology (AREA)
  • Wood Science & Technology (AREA)
  • Plant Pathology (AREA)
  • Environmental Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Agronomy & Crop Science (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

La présente invention appartient au domaine des pesticides, et concerne en particulier une composition herbicide ternaire comprenant un composé oxyiminoaryle substitué par un dérivé acide carboxylique et son utilisation. La composition herbicide ternaire comprend une quantité herbicide efficace d'un ingrédient actif A, d'un ingrédient actif B, et d'un ingrédient actif C, l'ingrédient actif A étant, et les ingrédients actifs B et C étant respectivement n'importe quel composé et un autre composé différent sélectionné parmi les types suivants : les inhibiteurs de VLCFA, les inhibiteurs d'assemblage des microtubules, les inhibiteurs EPSPS, etc. La composition peut efficacement réguler divers problèmes liés à des mauvaises herbes telles que de la famille des poacées ou des mauvaises herbes à larges feuilles, et présente les caractéristiques d'élargir le spectre herbicide, réduisant la quantité d'application, produisant des effets de synergie et résolvant les questions des mauvaises herbes résistantes, etc.
PCT/CN2021/127863 2020-11-06 2021-11-01 Composition herbicide ternaire comprenant un composé oxyiminoaryle substitué par un dérivé acide carboxylique et son utilisation WO2022095816A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN202011226390.6 2020-11-06
CN202011226390.6A CN114431236B (zh) 2020-11-06 2020-11-06 包含羧酸衍生物取代的氧基亚氨基芳基化合物的三元除草组合物及其应用

Publications (1)

Publication Number Publication Date
WO2022095816A1 true WO2022095816A1 (fr) 2022-05-12

Family

ID=81360880

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/CN2021/127863 WO2022095816A1 (fr) 2020-11-06 2021-11-01 Composition herbicide ternaire comprenant un composé oxyiminoaryle substitué par un dérivé acide carboxylique et son utilisation

Country Status (2)

Country Link
CN (1) CN114431236B (fr)
WO (1) WO2022095816A1 (fr)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2024013015A1 (fr) 2022-07-11 2024-01-18 Bayer Aktiengesellschaft Compositions herbicides
EP4353082A1 (fr) * 2022-10-14 2024-04-17 Bayer Aktiengesellschaft Compositions herbicides

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2023222831A1 (fr) 2022-05-20 2023-11-23 Syngenta Crop Protection Ag Compositions herbicides
WO2023222836A1 (fr) 2022-05-20 2023-11-23 Syngenta Crop Protection Ag Compositions herbicides
WO2023222834A1 (fr) 2022-05-20 2023-11-23 Syngenta Crop Protection Ag Compositions herbicides

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1408227A (zh) * 2001-09-28 2003-04-09 广西金燕子农药有限公司 异丙草胺、嗪草酮复合除草剂
CN102771475A (zh) * 2012-07-23 2012-11-14 河南金田地农化有限责任公司 一种含仲丁灵的微囊悬浮剂
CN102907424A (zh) * 2012-07-19 2013-02-06 河南金田地农化有限责任公司 一种含二甲戊灵的微囊悬浮剂
CN103125488A (zh) * 2013-03-28 2013-06-05 海利尔药业集团股份有限公司 一种含有精二甲吩草胺与二甲戊乐灵的除草组合物
CN103271028A (zh) * 2013-06-19 2013-09-04 北京燕化永乐农药有限公司 一种复配除草剂
CN104585213A (zh) * 2015-01-09 2015-05-06 浙江新农化工股份有限公司 一种含二甲戊灵、苯噻酰草胺以及吡嘧磺隆或氯吡嘧磺隆的除草组合物及其制剂和应用
CN108293988A (zh) * 2018-02-23 2018-07-20 南京高正农用化工有限公司 一种包含砜吡草唑的除草组合物及其用途
CN109221173A (zh) * 2018-09-20 2019-01-18 山东滨农科技有限公司 一种含仲丁灵的除草剂组合物
CN110250176A (zh) * 2019-06-17 2019-09-20 上海明德立达生物科技有限公司 一种特丁津和精异丙甲草胺的微囊悬浮-悬浮剂及其制备方法和应用

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4329537A1 (de) * 1993-09-02 1995-03-09 Basf Ag Substituierte 1-Amino-3-phenyluracile
US5486521A (en) * 1994-03-21 1996-01-23 Uniroyal Chemical Company, Inc. Pyrimidinyl aryl ketone oximes

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1408227A (zh) * 2001-09-28 2003-04-09 广西金燕子农药有限公司 异丙草胺、嗪草酮复合除草剂
CN102907424A (zh) * 2012-07-19 2013-02-06 河南金田地农化有限责任公司 一种含二甲戊灵的微囊悬浮剂
CN102771475A (zh) * 2012-07-23 2012-11-14 河南金田地农化有限责任公司 一种含仲丁灵的微囊悬浮剂
CN103125488A (zh) * 2013-03-28 2013-06-05 海利尔药业集团股份有限公司 一种含有精二甲吩草胺与二甲戊乐灵的除草组合物
CN103271028A (zh) * 2013-06-19 2013-09-04 北京燕化永乐农药有限公司 一种复配除草剂
CN104585213A (zh) * 2015-01-09 2015-05-06 浙江新农化工股份有限公司 一种含二甲戊灵、苯噻酰草胺以及吡嘧磺隆或氯吡嘧磺隆的除草组合物及其制剂和应用
CN108293988A (zh) * 2018-02-23 2018-07-20 南京高正农用化工有限公司 一种包含砜吡草唑的除草组合物及其用途
CN109221173A (zh) * 2018-09-20 2019-01-18 山东滨农科技有限公司 一种含仲丁灵的除草剂组合物
CN110250176A (zh) * 2019-06-17 2019-09-20 上海明德立达生物科技有限公司 一种特丁津和精异丙甲草胺的微囊悬浮-悬浮剂及其制备方法和应用

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2024013015A1 (fr) 2022-07-11 2024-01-18 Bayer Aktiengesellschaft Compositions herbicides
EP4353082A1 (fr) * 2022-10-14 2024-04-17 Bayer Aktiengesellschaft Compositions herbicides

Also Published As

Publication number Publication date
CN114431236B (zh) 2024-02-02
CN114431236A (zh) 2022-05-06

Similar Documents

Publication Publication Date Title
CN114431244B (zh) 包含hppd抑制剂类除草剂的三元除草组合物及其应用
WO2022095816A1 (fr) Composition herbicide ternaire comprenant un composé oxyiminoaryle substitué par un dérivé acide carboxylique et son utilisation
CN109526973B (zh) 包含砜吡草唑的三元除草组合物及其应用
CN114304165B (zh) 一种二元除草组合物及其应用
CN109497075B (zh) 包含trifludimoxazin的三元除草组合物及其应用
CN110946144B (zh) 包含二氯异噁草松的除草组合物及其应用
WO2020010690A1 (fr) Composition herbicide ternaire contenant de la cypyrafluone et application associée
CN112741097B (zh) 包含n-(1,3,4-噁二唑-2-基)芳基甲酰胺类化合物的除草组合物及其应用
WO2020215604A1 (fr) Composition herbicide comprenant un composé de trifluorométhylpyridazine et son application
WO2020124531A1 (fr) Composition herbicide ternaire contenant du cyclopyrimorate et application associée
CN109418274B (zh) 一种三元除草组合物及其应用
WO2020015105A1 (fr) Composition herbicide binaire contenant un herbicide inhibiteur de hppd et son utilisation
WO2020047890A1 (fr) Composition herbicide comprenant un composé d&#39;amide hétérocyclique et son utilisation
RU2807159C9 (ru) Гербицидная композиция, содержащая r-пиридилоксикарбоновую кислоту и производное, и ее применение
RU2807159C2 (ru) Гербицидная композиция, содержащая r-пиридилоксикарбоновую кислоту и производное, и ее применение
WO2023202364A1 (fr) Composition herbicide contenant un dérivé d&#39;oxime formyle pyrimidine et son utilisation
WO2023197899A1 (fr) Composition herbicide contenant un composé aromatique substitué par un cycle condensé et son utilisation
WO2021036251A1 (fr) Composition herbicide contenant des dérivés d&#39;acide pyridyloxycarboxylique de type r et son application
WO2021017502A1 (fr) Composition herbicide contenant un dérivé d&#39;acide pyridyloxy carboxylique de type r et son utilisation
WO2021017817A1 (fr) Composition herbicide contenant un dérivé d&#39;acide pyridyloxycarboxylique de type r et son utilisation
CN117941690A (zh) 包含四氟络草胺的除草组合物及其应用
CN117658998A (zh) 包含r型吡啶氧基羧酸衍生物的除草组合物及其应用
CN117652508A (zh) 包含羧酸衍生物取代的氧基亚氨基芳基化合物的除草组合物及其应用
CN117941694A (zh) 包含取代的嘧啶甲酰基肟类化合物的除草组合物及其应用
CN117941696A (zh) 包含稠环取代的芳香类化合物的除草组合物及其应用

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 21888513

Country of ref document: EP

Kind code of ref document: A1

NENP Non-entry into the national phase

Ref country code: DE

122 Ep: pct application non-entry in european phase

Ref document number: 21888513

Country of ref document: EP

Kind code of ref document: A1