WO2022068165A1 - Efficient vpsa oxygen production process and system thereof - Google Patents

Efficient vpsa oxygen production process and system thereof Download PDF

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Publication number
WO2022068165A1
WO2022068165A1 PCT/CN2021/085289 CN2021085289W WO2022068165A1 WO 2022068165 A1 WO2022068165 A1 WO 2022068165A1 CN 2021085289 W CN2021085289 W CN 2021085289W WO 2022068165 A1 WO2022068165 A1 WO 2022068165A1
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adsorption
pressure
tower
tank
oxygen production
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PCT/CN2021/085289
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French (fr)
Chinese (zh)
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李祎
杨波
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成都华西堂投资有限公司
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • B01D53/047Pressure swing adsorption
    • B01D53/0476Vacuum pressure swing adsorption
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • B01D53/047Pressure swing adsorption
    • B01D53/053Pressure swing adsorption with storage or buffer vessel
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B13/00Oxygen; Ozone; Oxides or hydroxides in general
    • C01B13/02Preparation of oxygen
    • C01B13/0229Purification or separation processes
    • C01B13/0248Physical processing only
    • C01B13/0259Physical processing only by adsorption on solids
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2210/00Purification or separation of specific gases
    • C01B2210/0028Separation of the specific gas from gas mixtures containing a minor amount of this specific gas
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2210/00Purification or separation of specific gases
    • C01B2210/0043Impurity removed
    • C01B2210/0046Nitrogen

Definitions

  • the invention relates to the technical field of industrial oxygen production, in particular to an efficient VPSA oxygen production process.
  • PSA oxygen enrichment has the advantages of low investment, low energy consumption, simple equipment and flexible operation, especially in the small and medium-scale oxygen production process, which greatly reduces the production energy consumption, and is widely used in chemical industry, medicine and environmental protection (waste incineration). , industrial oxygen-enriched combustion and wastewater treatment, etc.).
  • the vacuum pressure swing adsorption process uses the vacuum method to regenerate the adsorbent, and the regeneration effect is good, and at the same time, the amount of flushing gas is effectively reduced, and the energy consumption is reduced.
  • the VPSA process uses air as the raw material.
  • the moisture, carbon dioxide and nitrogen components in the air are adsorbed by the molecular sieve in the lower part, and the unadsorbed oxygen is enriched at the top of the adsorption tower as the product gas output.
  • the pressure equalization operation of the existing adsorption tower is carried out through the pressure equalization valve at the top of the tower. During this period, the adsorption tower cannot produce oxygen and the utilization rate is low. Therefore, two adsorption towers are usually set up. When the oxygen is released, the other adsorption tower is in the state of vacuum regeneration. The two adsorption towers alternately repeat oxygen production and regeneration to achieve continuous oxygen extraction.
  • the work efficiency is often not high, and the utilization rate of the adsorbent is only 40%.
  • Invention patent CN106698357A discloses a three-tower low-pressure adsorption vacuum desorption method for preparing oxygen.
  • the device includes a blower, a vacuum pump, a first adsorption tower, a second adsorption tower, a third adsorption tower, a first pressure equalizing tank, and a second equalizing tank. and oxygen buffer tank.
  • the utilization rate of oxygen is improved by adding a first pressure equalizing tank and a second pressure equalizing tank to collect oxygen-depleted gas, but at the same time only one tower is adsorbing, one tower is pressure equalizing, and one tower is evacuating, that is, one adsorption cycle Only 1/3 of the time is adsorbed, and the adsorption efficiency is low.
  • the present invention provides an efficient VPSA oxygen production process. This process increases the proportion of the adsorption time, makes the adsorbent fully utilized, and significantly improves the work efficiency and the utilization rate of the adsorbent.
  • An efficient VPSA oxygen production process including pressure equalizing tank, blower, vacuum pump, oxygen enrichment tank and at least 3 adsorption towers; the oxygen production cycle of a single adsorption tower includes:
  • Adsorption The air blower sends the air into the adsorption tower to produce oxygen and sends it to the oxygen-enriched tank;
  • Vacuum analysis use a vacuum pump to vacuum the adsorption tower to regenerate the adsorbent
  • Equalizing and boosting use the gas in the equalizing tank to inflate the adsorption tower and equalize the pressure, so that the air pressure in the tower and the equalizing tank are balanced;
  • the adsorption time in the oxygen production cycle is longer than the vacuum desorption time
  • the adsorption time in the oxygen production cycle is longer than the vacuum desorption time
  • all the adsorption towers are connected to the pressure equalizing tank in sequence, and the pressure is equalized or communicated with each other.
  • the pressure is equalized and boosted to realize the conversion of the adsorption tower from adsorption to desorption and the conversion of the adsorption tower from desorption to adsorption.
  • the VPSA oxygen production process of the present invention has no less than two adsorption towers in the adsorption state at the same time.
  • adsorption towers Preferably, if there are 3 adsorption towers, two towers are adsorbed and one tower is regenerated at the same time; if there are 4 adsorption towers, three adsorption towers are regenerated at the same time, and one tower is regenerated; if there are 5 adsorption towers, three adsorption towers are regenerated at the same time. ; If there are 6 adsorption towers, at the same time four adsorption towers and two towers are regenerated.
  • the number of adsorption towers in the present invention is n, and the steps of the oxygen production cycle are sequentially divided into 2n stages at the same time: D+A, (A) 2x , A+B, (C) 2y ;
  • D+A means D step plus A step, which is the first stage;
  • A+B means A step plus B step, which is the 2x+2 stage.
  • All adsorption towers are divided and rolled according to this stage to carry out the oxygen production cycle, and in the same time period, the pressure equalization tank only operates to equalize the pressure of one adsorption tower, and performs pressure equalization and pressure equalization for each tower in sequence. .
  • the volume of the pressure equalizing tank in the present invention is not less than the volume of the adsorption tower, so that the pressure of the pressure equalizing tank after the pressure equalization is close to the atmospheric pressure, forming a necessary pressure difference with the adsorption tower in the pressure equalizing and boosting operation, so as to increase the pressure in the pressure equalizing operation.
  • the pressure equalization and pressure increase operation of the adsorption tower is quickly completed. Recover the oxygen in the dead space of the adsorption tower after the adsorption is completed, and improve the oxygen yield of the device.
  • the time for equalizing the pressure and increasing the pressure each time is 1-5s. Shorten the time of pressure equalization, increase the proportion of adsorption time, and easily adjust the proportion of adsorption and vacuum time, and realize alternate adsorption and regeneration of multiple towers.
  • the air pressure of the pressure equalizing tank is maintained between -5kPa ⁇ +5kPa.
  • the air pressure of the conventional adsorption tower after adsorption is about 50kPa, and the air pressure after vacuuming is about -50kPa. It can form an ideal pressure difference with the adsorption tower and quickly equalize the pressure.
  • the present invention also provides a system for the high-efficiency VPSA oxygen production process, including a blower, a vacuum pump, an oxygen-enriched tank, a pressure equalizing tank, and an adsorption tower group formed by paralleling at least three adsorption towers.
  • the blower, the oxygen-enriched tank and the vacuum pump Each adsorption tower is respectively connected, the pressure equalizing tank and each adsorption tower form a passage that can be switched on and off, and a program-controlled valve is arranged on the connecting pipeline between each equipment.
  • the blower is provided with an air buffer tank on the connecting pipeline with the adsorption tower group
  • the vacuum pump is provided with a vacuum buffer tank on the connecting pipeline with the adsorption tower group.
  • the air pressure of the vacuum buffer tank is the same as that of the adsorption tower.
  • the air pressure of the adsorption tower reaches the analytical negative pressure of about -50kPa, it switches to the next adsorption tower for vacuuming.
  • the adsorption tower is under pressure equalization.
  • the vacuum valve of the adsorption tower has not been opened during this process, and the vacuum pump will vacuum the vacuum buffer tank, which not only saves the energy consumed by the vacuum pump but also reduces the pressure fluctuation of the vacuum pump, which provides better protection. equipment.
  • the air pressure of the air buffer tank is the same as that of the adsorption tower.
  • the air pressure of the adsorption tower reaches about 50kPa, it switches to the next adsorption tower.
  • the adsorption tower is in the process of equalizing and boosting for 1 to 5 seconds.
  • the intake valve of the adsorption tower has not been opened, and the air from the blower is poured into the buffer tank, which not only avoids the blockage of the blower, but also reserves the blower. consumption and energy.
  • the air inlet of the blower is provided with a filter
  • the air outlet of the blower is provided with a heat exchanger.
  • the air entering the adsorption tower is first filtered, and the clean air is used as the raw material to enter the blower.
  • the air is cooled by the heat exchanger, so that the temperature is lowered to the optimum adsorption performance temperature of the molecular sieve, and then enters the adsorption that has been regenerated and is in a working state. tower.
  • the air inlet of the vacuum pump is provided with a filter to filter out part of the adsorbent dust carried by the air after entering the adsorption tower, and discharge clean nitrogen into the atmosphere.
  • the present invention adopts the pressure equalizing tank to complete the smooth release and pressure equalizing and pressure increasing operation of the adsorption tower, so that the pressure in the tower after the equalization is balanced with the pressure equalizing tank, and the pressure of the adsorption tower of about plus or minus 50kpa can be adjusted within a few seconds.
  • the internal pressure is quickly equalized to close to the atmospheric pressure of the air, the rapid pressure equalization is performed before adsorption, and the rapid punching is performed after the adsorption to improve the pressure equalization and punching efficiency of the device.
  • the pressure equalization time in the oxygen production cycle is saved. , increasing the proportion of adsorption time, so that the adsorbent is fully utilized, and the oxygen in the dead space of the adsorption tower is effectively recovered.
  • the present invention divides the steps of the oxygen production cycle into 2n stages of the same time in sequence. Since the pressure equalization time is only a few seconds, the pressure equalization and the adsorption operation are classified into the same stage, and the adsorption tower is divided and rolled according to this stage. Oxygen cycle is cycled, and the pressure equalizing tank alternately discharges and equalizes pressure and equalizes pressure for each tower. After the distribution according to this method, the oxygen production system can always be in multiple towers for simultaneous adsorption, and the towers in the adsorption state are more than the towers that are evacuated and the program waits, which effectively improves the utilization efficiency of molecular sieves. For example, the three-tower process has always had two Each tower is evacuated in one tower, and the adsorption time of each adsorption tower is longer than the time of vacuuming, and the utilization rate of molecular sieve is as high as 66%.
  • the pressure is further equalized by the air buffer tank or the vacuum buffer tank, which further accelerates the pressure equalization time, and avoids the direct pressure equalization with the air buffer tank or the vacuum buffer tank.
  • the pressure fluctuations of other adsorption towers can be reduced, so that the pressure fluctuations of the operating system are smaller and the stability is higher.
  • Fig. 1 is the 3 tower structure schematic diagram of the VPSA oxygen production system of the present invention.
  • Figure 2 is a schematic diagram of the 4-column structure of the VPSA oxygen production system of the present invention.
  • Figure 3 is a schematic diagram of the 5-column structure of the VPSA oxygen production system of the present invention.
  • Figure 4 is a schematic diagram of the structure of the 6 towers of the VPSA oxygen production system of the present invention.
  • An efficient VPSA oxygen production process including pressure equalization tank, blower, vacuum pump, oxygen enrichment tank and at least 3 adsorption towers; the oxygen production cycle of a single adsorption tower includes:
  • Adsorption The air blower sends the air into the adsorption tower to produce oxygen and sends it to the oxygen-enriched tank;
  • Vacuum analysis use a vacuum pump to vacuum the adsorption tower to regenerate the adsorbent
  • Equalizing and boosting use the gas in the equalizing tank to inflate the adsorption tower and equalize the pressure, so that the air pressure in the tower and the equalizing tank are balanced;
  • the adsorption time in the oxygen production cycle is longer than the vacuum desorption time, and all the adsorption towers are connected with the pressure equalizing tank in order to release the pressure or to increase the pressure to realize the conversion from adsorption to desorption of adsorption towers.
  • Embodiment 1 This embodiment is on the basis of Embodiment 1:
  • the volume of the pressure equalizing tank is not less than the volume of the adsorption tower, so that the pressure of the pressure equalizing tank after pressure equalization is close to atmospheric pressure, and a large pressure difference is formed with the adsorption tower in the next pressure equalizing operation, so that the adsorption can be quickly absorbed within 1-5s.
  • the tower completes the pressure equalization operation.
  • the first cycle the pressure of the adsorption tower 50kPa and the pressure equalization tank 0kPa after the pressure equalization is +17kPa, the pressure after the adsorption tower -50kPa and the pressure equalization tank +17kPa equalization and boosting is -22kPa;
  • the second cycle the pressure of the adsorption tower 50kPa and the pressure equalization tank -22kPa after the pressure equalization is +2kPa, the pressure after the adsorption tower -50kPa and the pressure equalization tank +2kPa equalization and boosting is -17kPa;
  • the third cycle the pressure of the adsorption tower 50kPa and the pressure equalization tank -17kPa after the pressure equalization is +5kPa, and the pressure after the adsorption tower -50kPa and the pressure equalization tank +5kPa equalization and boosting is -13kPa;
  • the 4th cycle the pressure after adsorption tower 50kPa and pressure equalizing tank-13kPa equalizing pressure is +8kPa, and the pressure after adsorption tower-50kPa and pressure equalizing tank+8kPa equalizing pressure boosting is-11kPa;
  • the pressure of the pressure equalizing tank is gradually stabilized in a certain positive and negative range with the continuous repetition of the oxygen production cycle, and is close to the atmospheric pressure. .
  • Embodiment 1 This embodiment is on the basis of Embodiment 1:
  • the volume of the pressure equalizing tank is equal to the volume of the adsorption tower, and the time for each time of pressure equalization and pressure equalization is 5s.
  • Embodiment 1 This embodiment is on the basis of Embodiment 1:
  • the air pressure of the pressure equalizing tank is maintained between -15kPa ⁇ +15kPa.
  • the air pressure of the conventional adsorption tower after adsorption is about 50kPa, and the air pressure after vacuuming is about -50kPa. It can form an ideal pressure difference with the adsorption tower and quickly equalize the pressure.
  • Embodiment 1 This embodiment is on the basis of Embodiment 1:
  • the volume of the pressure equalizing tank is 3 times the volume of the adsorption tower, and the time for each time of pressure equalization and pressure equalization and pressure increase is 1s.
  • Embodiment 1 This embodiment is on the basis of Embodiment 1:
  • the number of the adsorption towers is n, and the steps of the oxygen production cycle are sequentially divided into 2n stages at the same time: D+A, (A) 2x , A+B, (C) 2y ;
  • All adsorption towers are divided and rolled according to this stage to carry out the oxygen production cycle, and in the same time period, the pressure equalizing tank only operates to equalize the pressure of one adsorption tower, and alternately performs equalization and pressure equalization for each tower.
  • D+A refers to the pressure equalization and then the adsorption
  • A+B refers to the first adsorption and then the pressure equalization; since the pressure equalization time is only a few seconds, the pressure equalization and the adsorption operation are classified into the same stage, and the adsorption time can be timely according to the oxygen purity requirements. adjust.
  • the oxygen production cycle is divided into isochronous stages, and then the flow of each adsorption tower is sorted according to the pressure equalization requirements, and an efficient oxygen production process can be realized.
  • D+A means D steps plus A steps, which is the first stage;
  • A+B means A steps plus B steps, which is the 2x+2 stage.
  • the equipment is composed of blower (C), vacuum pump (P), adsorption tower (T1-T3), air buffer tank (V1), vacuum buffer tank (V2), pressure equalizing tank (V3), rich Oxygen tank (V4), filter U1, filter U2, heat exchanger (E), program-controlled valve group (A1 ⁇ A5).
  • Equalizing and boosting open the program-controlled valve A4, close A1, A2, A3, and A5, and put the pressure of the equalizing tank into the adsorption tower to increase the pressure of the adsorption tower.
  • Adsorption Open the program-controlled valves A1, A2, close A3, A4, and A5, and cool the air to about 40 degrees through the heat exchanger and send it to the adsorption tower for adsorption and separation to produce oxygen, and the enriched oxygen enters the oxygen storage tank from the top of the tower ( V4), adjust the oxygen pressure by adjusting the outlet of the oxygen storage tank (V4) and send the enriched oxygen to the oxygen-consuming section.
  • the equipment is composed of blower (C), vacuum pump (P), adsorption tower (T1-T4), air buffer tank (V1), vacuum buffer tank (V2), pressure equalizing tank (V3), rich Oxygen tank (V4), filter U1, filter U2, heat exchanger (E), program-controlled valve group (A1 ⁇ A5).
  • the equipment is composed of blower (C), vacuum pump (P), adsorption tower (T1-T5), air buffer tank (V1), vacuum buffer tank (V2), pressure equalizing tank (V3), rich Oxygen tank (V4), filter U1, filter U2, heat exchanger (E), program-controlled valve group (A1 ⁇ A5).
  • the flow control in Table 3 is realized.
  • three adsorption towers are adsorbing at the same time in each time period, and two adsorption towers are vacuuming; the pressure equalizing tank alternately boosts and discharges pressure for each adsorption tower one by one during the whole process. .
  • the sorbent utilization rate is as high as 60%.
  • the device is composed of: blower (C), vacuum pump (P), adsorption tower (T1-T6), air buffer tank (V1), vacuum buffer tank (V2), pressure equalizing tank (V3), rich Oxygen tank (V4), filter U1, filter U2, heat exchanger (E), program-controlled valve group (A1 ⁇ A5).
  • the oxygen production system based on the high-efficiency VPSA oxygen production process includes a blower, a vacuum pump, an oxygen-enriched tank, a pressure equalizing tank and an adsorption tower group formed by at least three adsorption towers in parallel.
  • oxygen enrichment tank and vacuum pump are respectively connected to each adsorption tower, the pressure equalization tank and each adsorption tower form a circulation passage, and the connection pipes between each equipment are provided with program-controlled valves.
  • Embodiment 11 This embodiment is based on Embodiment 11:
  • the blower is provided with an air buffer tank on the connection pipeline with the adsorption tower group
  • the vacuum pump is provided with a vacuum buffer tank on the connection pipeline with the adsorption tower group.
  • the air pressure of the air buffer tank during adsorption is equivalent to the pressure value of the blower, and the air pressure of the vacuum buffer tank during vacuuming is equivalent to the pressure value of the vacuum pump.
  • the air pressure of the vacuum buffer tank is the same as that of the adsorption tower.
  • the air pressure of the adsorption tower reaches about -50kPa, it switches to the next adsorption tower to start vacuuming.
  • the adsorption tower is equalized with the pressure equalizing tank.
  • the initial pressure of the vacuum pump is the pressure after the pressure equalization, instead of starting from the atmospheric pressure, so that the pressure of the adsorption tower reaches the negative pressure in a very short time, which reduces the pressure at the inlet of the vacuum pump. Fluctuations, better protection of the equipment.
  • Embodiment 11 This embodiment is based on Embodiment 11:
  • the air inlet of the blower is provided with a filter, and the air outlet of the blower is provided with a heat exchanger.
  • the air entering the adsorption tower is first filtered, and the clean air is used as the raw material to enter the blower. After the pressure is increased, it is cooled by the heat exchanger, so that the temperature is lowered to the optimum adsorption performance temperature of the molecular sieve, and then enters the adsorption that has been regenerated and is in a working state. tower.
  • the air inlet of the vacuum pump is provided with a filter.
  • two or more vacuum pumps can be set up to ensure the independent operation of each vacuuming tower without interfering with each other.
  • the blower adopted by the utility model can be a Roots blower, a centrifugal blower or a water ring blower; the heat exchanger is a water-cooled air cooler, the filter is a self-cleaning air filter, and the program-controlled valve model is a pneumatic/hydraulic butterfly valve.
  • the specific specifications and models are selected by the size of the device and user needs.

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Abstract

Provided is an efficient VPSA oxygen production process, comprising a pressure equalizing tank (V3), a blower (C), a vacuum pump (P), an oxygen enrichment tank (V4) and at least three adsorption towers (T1, T2, T3); the oxygen production cycle of a single adsorption tower comprises: adsorption, release and pressure equalization, vacuum desorption, and pressure equalization and pressure boosting; and the adsorption time in the oxygen production cycle is longer than the vacuumization desorption time, all of the adsorption towers communicate in order with the pressure equalizing tank for release and pressure equalization or pressure equalization and pressure boosting, and the conversion of the adsorption towers from adsorption to desorption and the conversion of the adsorption towers from desorption to adsorption are achieved. The process increases the proportion of adsorption time, enables an adsorbent to be fully utilized, and thus significantly improves work efficiency and the utilization rate of the adsorbent.

Description

一种高效的VPSA制氧工艺及其系统An efficient VPSA oxygen production process and its system 技术领域technical field
本发明涉及工业制氧技术领域,具体涉及一种高效的VPSA制氧工艺。The invention relates to the technical field of industrial oxygen production, in particular to an efficient VPSA oxygen production process.
背景技术Background technique
变压吸附法富氧具有投资少、能耗低、设备简单、操作灵活等优点,特别是在中小规模制氧工艺上,大大降低了生产能耗,广泛应用于化工、医药和环保(垃圾焚烧、工业富氧燃烧和废水处理等)领域。其中真空变压吸附工艺(VPSA)运用抽真空方式对吸附剂进行再生,再生效果较好,同时有效减少了冲洗气量,降低了能耗。PSA oxygen enrichment has the advantages of low investment, low energy consumption, simple equipment and flexible operation, especially in the small and medium-scale oxygen production process, which greatly reduces the production energy consumption, and is widely used in chemical industry, medicine and environmental protection (waste incineration). , industrial oxygen-enriched combustion and wastewater treatment, etc.). Among them, the vacuum pressure swing adsorption process (VPSA) uses the vacuum method to regenerate the adsorbent, and the regeneration effect is good, and at the same time, the amount of flushing gas is effectively reduced, and the energy consumption is reduced.
VPSA工艺是以空气为原料,在吸附器内,空气中的水分、二氧化碳和氮气等组分经过下部的分子筛吸附,未被吸附的氧气在吸附塔顶部富积作为产品气输出。现有的吸附塔均压操作是通过塔顶的均压阀门进行的,在这段时间内,吸附塔不能产氧,利用率低,因此,通常设置两个吸附塔,当一只吸附塔产出氧气时,另一只吸附塔处于抽真空再生状态,两只吸附塔交替重复产氧和再生,实现连续抽取氧气,往往工作效率还是不高,吸附剂利用率只有40%。The VPSA process uses air as the raw material. In the adsorber, the moisture, carbon dioxide and nitrogen components in the air are adsorbed by the molecular sieve in the lower part, and the unadsorbed oxygen is enriched at the top of the adsorption tower as the product gas output. The pressure equalization operation of the existing adsorption tower is carried out through the pressure equalization valve at the top of the tower. During this period, the adsorption tower cannot produce oxygen and the utilization rate is low. Therefore, two adsorption towers are usually set up. When the oxygen is released, the other adsorption tower is in the state of vacuum regeneration. The two adsorption towers alternately repeat oxygen production and regeneration to achieve continuous oxygen extraction. The work efficiency is often not high, and the utilization rate of the adsorbent is only 40%.
发明专利CN106698357A公开了一种三塔低压吸附真空解吸制备氧气的方法,装置包括鼓风机、真空泵、第一吸附塔、第二吸附塔、第三吸附塔、第一均压罐、第二均压罐和氧气缓冲罐。该方法通过增设第一均压罐和第二均压罐收集贫氧气体来提高氧气的利用率,但同一时间只有一个塔在吸附,一个塔在均压,一个塔抽真空,即一个吸附周期内,只有1/3时间在吸附,吸附效率低。Invention patent CN106698357A discloses a three-tower low-pressure adsorption vacuum desorption method for preparing oxygen. The device includes a blower, a vacuum pump, a first adsorption tower, a second adsorption tower, a third adsorption tower, a first pressure equalizing tank, and a second equalizing tank. and oxygen buffer tank. In this method, the utilization rate of oxygen is improved by adding a first pressure equalizing tank and a second pressure equalizing tank to collect oxygen-depleted gas, but at the same time only one tower is adsorbing, one tower is pressure equalizing, and one tower is evacuating, that is, one adsorption cycle Only 1/3 of the time is adsorbed, and the adsorption efficiency is low.
发明内容SUMMARY OF THE INVENTION
针对上述技术问题,本发明提供了一种高效的VPSA制氧工艺。该工艺加大了吸附时间的占比,使吸附剂被充分利用,显著提高了工作效率和吸附剂的 利用率。In view of the above technical problems, the present invention provides an efficient VPSA oxygen production process. This process increases the proportion of the adsorption time, makes the adsorbent fully utilized, and significantly improves the work efficiency and the utilization rate of the adsorbent.
为了实现发明目的,本发明采用的技术方案是:In order to realize the purpose of the invention, the technical scheme adopted in the present invention is:
一种高效的VPSA制氧工艺,包括均压罐、鼓风机、真空泵、富氧罐和至少3台吸附塔;单个吸附塔的制氧周期包括:An efficient VPSA oxygen production process, including pressure equalizing tank, blower, vacuum pump, oxygen enrichment tank and at least 3 adsorption towers; the oxygen production cycle of a single adsorption tower includes:
A、吸附:鼓风机将空气送入吸附塔制取氧气并送入富氧罐;A. Adsorption: The air blower sends the air into the adsorption tower to produce oxygen and sends it to the oxygen-enriched tank;
B、顺放均压:吸附塔完成吸附后,关断进出口阀停止送氧,而将塔内气体放入均压罐,使塔内气压与均压罐平衡;B. Smooth release and pressure equalization: After the adsorption tower completes the adsorption, the inlet and outlet valves are closed to stop supplying oxygen, and the gas in the tower is put into the pressure equalizing tank to balance the air pressure in the tower and the pressure equalizing tank;
C、真空解析:利用真空泵对吸附塔抽真空,使吸附剂再生;C. Vacuum analysis: use a vacuum pump to vacuum the adsorption tower to regenerate the adsorbent;
D、均压升压:利用均压罐内的气体对吸附塔充气均压,使塔内气压与均压罐平衡;D. Equalizing and boosting: use the gas in the equalizing tank to inflate the adsorption tower and equalize the pressure, so that the air pressure in the tower and the equalizing tank are balanced;
所述制氧周期中吸附的时间长于真空解析的时间,所述制氧周期中的吸附时间长于抽真空解吸的时间,所有吸附塔按顺序依次与所述均压罐连通顺放均压或连通均压升压,实现吸附塔从吸附到解吸的转换和吸附塔从解吸到吸附的转换。The adsorption time in the oxygen production cycle is longer than the vacuum desorption time, the adsorption time in the oxygen production cycle is longer than the vacuum desorption time, and all the adsorption towers are connected to the pressure equalizing tank in sequence, and the pressure is equalized or communicated with each other. The pressure is equalized and boosted to realize the conversion of the adsorption tower from adsorption to desorption and the conversion of the adsorption tower from desorption to adsorption.
本发明的VPSA制氧工艺同时间处于吸附状态的吸附塔不少于两台。The VPSA oxygen production process of the present invention has no less than two adsorption towers in the adsorption state at the same time.
优选地,若吸附塔为3台,同时间两塔吸附一塔再生;若吸附塔为4台,同时间三塔吸附一塔再生;若吸附塔为5台,同时间三塔吸附两塔再生;若吸附塔为6台,同时间四塔吸附两塔再生。Preferably, if there are 3 adsorption towers, two towers are adsorbed and one tower is regenerated at the same time; if there are 4 adsorption towers, three adsorption towers are regenerated at the same time, and one tower is regenerated; if there are 5 adsorption towers, three adsorption towers are regenerated at the same time. ; If there are 6 adsorption towers, at the same time four adsorption towers and two towers are regenerated.
本发明所述吸附塔的个数为n,将所述制氧周期的步骤依序划分为相同时间的2n个阶段:D+A、(A) 2x、A+B、(C) 2yThe number of adsorption towers in the present invention is n, and the steps of the oxygen production cycle are sequentially divided into 2n stages at the same time: D+A, (A) 2x , A+B, (C) 2y ;
其中,(A) 2x指2x个阶段,每个阶段均为A步骤;(C) 2y指2y个阶段,每个阶段均为C步骤,且x+y=n-1,x≠0,y≠0,x≥y; Among them, (A) 2x refers to 2x stages, each stage is A step; (C) 2y refers to 2y stages, each stage is C step, and x+y=n-1, x≠0, y ≠0,x≥y;
D+A表示D步骤加A步骤,为第一个阶段;A+B表示A步骤加B步骤, 为第2x+2个阶段。D+A means D step plus A step, which is the first stage; A+B means A step plus B step, which is the 2x+2 stage.
所有吸附塔按该阶段划分滚动进行制氧周期循环,且在同个时间段,均压罐只对一个吸附塔均压操作,并分别按顺序对各塔进行顺放均压和均压升压。All adsorption towers are divided and rolled according to this stage to carry out the oxygen production cycle, and in the same time period, the pressure equalization tank only operates to equalize the pressure of one adsorption tower, and performs pressure equalization and pressure equalization for each tower in sequence. .
本发明所述均压罐的体积不小于吸附塔的体积,使顺放均压后的均压罐气压接近大气压,形成均压升压操作中与吸附塔必须的压差,从而在均压升压过程中迅速对吸附塔完成均压升压操作。达到回收吸附塔完成吸附后其死空间的氧气而提高装置的氧气收率。The volume of the pressure equalizing tank in the present invention is not less than the volume of the adsorption tower, so that the pressure of the pressure equalizing tank after the pressure equalization is close to the atmospheric pressure, forming a necessary pressure difference with the adsorption tower in the pressure equalizing and boosting operation, so as to increase the pressure in the pressure equalizing operation. During the pressure process, the pressure equalization and pressure increase operation of the adsorption tower is quickly completed. Recover the oxygen in the dead space of the adsorption tower after the adsorption is completed, and improve the oxygen yield of the device.
优选地,每次顺放均压和均压升压的时间为1~5s。缩短均压的时间,增加吸附时间占比,方便调节吸附和抽真空时间的比例,实现多塔交替吸附和再生。Preferably, the time for equalizing the pressure and increasing the pressure each time is 1-5s. Shorten the time of pressure equalization, increase the proportion of adsorption time, and easily adjust the proportion of adsorption and vacuum time, and realize alternate adsorption and regeneration of multiple towers.
进一步优选地,所述均压罐的气压保持在-5kPa~+5kPa之间。常规的吸附塔在吸附后的气压在50kPa左右,抽真空后的气压在-50kPa左右,均压罐在交替的顺放均压和均压升压操作中气压维持在-5kPa~+5kPa间,能与吸附塔形成理想的压力差,迅速均压。Further preferably, the air pressure of the pressure equalizing tank is maintained between -5kPa~+5kPa. The air pressure of the conventional adsorption tower after adsorption is about 50kPa, and the air pressure after vacuuming is about -50kPa. It can form an ideal pressure difference with the adsorption tower and quickly equalize the pressure.
本发明还提供了该高效的VPSA制氧工艺的系统,包括鼓风机、真空泵、富氧罐、均压罐和至少3台吸附塔并联而成的吸附塔组,所述鼓风机、富氧罐和真空泵分别连接各个吸附塔,所述均压罐与各个吸附塔均形成可以开关控制的通路,各设备间的连接管道上均设置有程控阀。The present invention also provides a system for the high-efficiency VPSA oxygen production process, including a blower, a vacuum pump, an oxygen-enriched tank, a pressure equalizing tank, and an adsorption tower group formed by paralleling at least three adsorption towers. The blower, the oxygen-enriched tank and the vacuum pump Each adsorption tower is respectively connected, the pressure equalizing tank and each adsorption tower form a passage that can be switched on and off, and a program-controlled valve is arranged on the connecting pipeline between each equipment.
优选地,所述鼓风机在与所述吸附塔组的连接管道上设置有空气缓冲罐,所述真空泵在与所述吸附塔组的连接管道上设置有真空缓冲罐。Preferably, the blower is provided with an air buffer tank on the connecting pipeline with the adsorption tower group, and the vacuum pump is provided with a vacuum buffer tank on the connecting pipeline with the adsorption tower group.
在吸附塔抽真空过程中,真空缓冲罐的气压与吸附塔相同,当吸附塔的气压到达-50kPa左右的解析负压,切换到下一个吸附塔抽真空,而此时吸附塔正处于均压升压1~5s的过程中,这个过程中吸附塔的抽真空阀还未打开,真空泵对真空缓冲罐抽真空,既储蓄了真空泵消耗的能量又降低了真空泵的压力波动, 更好的保护了设备。During the vacuuming process of the adsorption tower, the air pressure of the vacuum buffer tank is the same as that of the adsorption tower. When the air pressure of the adsorption tower reaches the analytical negative pressure of about -50kPa, it switches to the next adsorption tower for vacuuming. At this time, the adsorption tower is under pressure equalization. In the process of boosting pressure for 1 to 5s, the vacuum valve of the adsorption tower has not been opened during this process, and the vacuum pump will vacuum the vacuum buffer tank, which not only saves the energy consumed by the vacuum pump but also reduces the pressure fluctuation of the vacuum pump, which provides better protection. equipment.
将鼓风机出口来气放入空气缓冲罐进行储能,在鼓风机送风的吸附过程中,空气缓冲罐的气压与吸附塔相同,当吸附塔的气压到达50kPa左右时,切换到下一个吸附塔开始送风,而此时吸附塔正处在1~5s的均压升压过程,吸附塔的进气阀还未打开,鼓风机出来的空气灌入缓冲罐,既避免了鼓风机阻塞,又储备了风机的消耗跟能量。Put the air from the blower outlet into the air buffer tank for energy storage. During the adsorption process of the blower, the air pressure of the air buffer tank is the same as that of the adsorption tower. When the air pressure of the adsorption tower reaches about 50kPa, it switches to the next adsorption tower. At this time, the adsorption tower is in the process of equalizing and boosting for 1 to 5 seconds. The intake valve of the adsorption tower has not been opened, and the air from the blower is poured into the buffer tank, which not only avoids the blockage of the blower, but also reserves the blower. consumption and energy.
优选地,所述鼓风机的进风口设置有过滤器,鼓风机的出风口设置有换热器。进入吸附塔的空气,先经过滤,以洁净空气为原料,进入鼓风机,升压后经换热器降温,使温度降到分子筛最佳吸附性能温度状态,再进入已经再生完毕处于工作状态的吸附塔。Preferably, the air inlet of the blower is provided with a filter, and the air outlet of the blower is provided with a heat exchanger. The air entering the adsorption tower is first filtered, and the clean air is used as the raw material to enter the blower. After boosting, the air is cooled by the heat exchanger, so that the temperature is lowered to the optimum adsorption performance temperature of the molecular sieve, and then enters the adsorption that has been regenerated and is in a working state. tower.
优选地,所述真空泵的进风口设置有过滤器,过滤掉空气进入吸附塔后携带的部分吸附剂粉尘,排出清洁的氮气到大气中。Preferably, the air inlet of the vacuum pump is provided with a filter to filter out part of the adsorbent dust carried by the air after entering the adsorption tower, and discharge clean nitrogen into the atmosphere.
本发明的有益效果在于:The beneficial effects of the present invention are:
1、本发明采用均压罐来完成吸附塔的顺放均压和均压升压操作,使均压后的塔内气压与均压罐平衡,可将正负50kpa左右的吸附塔气压在数秒内快速均压至接近空气大气压,在吸附前进行快速均压,在吸附后进行快速冲压,达到提高装置均压和冲压效率,较传统的均压方法,节省了制氧周期内的均压时间,加大了吸附时间的占比,使吸附剂被充分利用,又有效的回收了吸附塔死空间的氧气。1. The present invention adopts the pressure equalizing tank to complete the smooth release and pressure equalizing and pressure increasing operation of the adsorption tower, so that the pressure in the tower after the equalization is balanced with the pressure equalizing tank, and the pressure of the adsorption tower of about plus or minus 50kpa can be adjusted within a few seconds. The internal pressure is quickly equalized to close to the atmospheric pressure of the air, the rapid pressure equalization is performed before adsorption, and the rapid punching is performed after the adsorption to improve the pressure equalization and punching efficiency of the device. Compared with the traditional pressure equalization method, the pressure equalization time in the oxygen production cycle is saved. , increasing the proportion of adsorption time, so that the adsorbent is fully utilized, and the oxygen in the dead space of the adsorption tower is effectively recovered.
2、本发明将制氧周期的步骤依序划分为相同时间的2n个阶段,由于均压时间仅为数秒,将均压与吸附操作归在同一阶段中,吸附塔按该阶段划分滚动进行制氧周期循环,均压罐对各塔交替进行顺放均压和均压升压。按该方法分配后,制氧系统可一直处于多塔同时吸附,且处 于吸附状态的塔多于抽真空的和程序等待的塔,有效地提高了分子筛利用效率,如三塔工艺就一直有两个塔在吸附一个塔抽真空,而且每个吸附塔的吸附时间都长于抽真空的时间,分子筛的利用率高达66%。2. The present invention divides the steps of the oxygen production cycle into 2n stages of the same time in sequence. Since the pressure equalization time is only a few seconds, the pressure equalization and the adsorption operation are classified into the same stage, and the adsorption tower is divided and rolled according to this stage. Oxygen cycle is cycled, and the pressure equalizing tank alternately discharges and equalizes pressure and equalizes pressure for each tower. After the distribution according to this method, the oxygen production system can always be in multiple towers for simultaneous adsorption, and the towers in the adsorption state are more than the towers that are evacuated and the program waits, which effectively improves the utilization efficiency of molecular sieves. For example, the three-tower process has always had two Each tower is evacuated in one tower, and the adsorption time of each adsorption tower is longer than the time of vacuuming, and the utilization rate of molecular sieve is as high as 66%.
3、增加空气缓冲罐和真空缓冲罐,在吸附塔抽真空时,先与真空缓冲罐均压,使真空泵抽真空的起始压力为均压后的压力,而不是从大气压力开始,让吸附塔压力在极短时间内到达负压,降低了真空泵入口的压力波动,更好的保护了设备。3. Increase the air buffer tank and the vacuum buffer tank. When the adsorption tower is evacuated, first equalize the pressure with the vacuum buffer tank, so that the initial pressure of the vacuum pump is the pressure after the pressure equalization, instead of starting from the atmospheric pressure, let the adsorption The tower pressure reaches the negative pressure in a very short time, which reduces the pressure fluctuation at the inlet of the vacuum pump and better protects the equipment.
4、吸附塔与均压罐初步均压后,再经空气缓冲罐或者真空缓冲罐进一步均压,进一步的加速了均压的时间,并且避免了直接与空气缓冲罐或者真空缓冲罐均压导致的其它吸附塔的压力波动,这样操作的系统压力波动更小,稳定性更高。4. After the initial pressure equalization of the adsorption tower and the pressure equalizing tank, the pressure is further equalized by the air buffer tank or the vacuum buffer tank, which further accelerates the pressure equalization time, and avoids the direct pressure equalization with the air buffer tank or the vacuum buffer tank. The pressure fluctuations of other adsorption towers can be reduced, so that the pressure fluctuations of the operating system are smaller and the stability is higher.
附图说明Description of drawings
图1为本发明VPSA制氧系统的3塔结构示意图。Fig. 1 is the 3 tower structure schematic diagram of the VPSA oxygen production system of the present invention.
图2为本发明VPSA制氧系统的4塔结构示意图。Figure 2 is a schematic diagram of the 4-column structure of the VPSA oxygen production system of the present invention.
图3为本发明VPSA制氧系统的5塔结构示意图。Figure 3 is a schematic diagram of the 5-column structure of the VPSA oxygen production system of the present invention.
图4为本发明VPSA制氧系统的6塔结构示意图。Figure 4 is a schematic diagram of the structure of the 6 towers of the VPSA oxygen production system of the present invention.
具体实施方式Detailed ways
为了更加清楚、详细地说明本实用新型的目的技术方案,下面通过相关实施例对本实用新型进行进一步描述。以下实施例仅为具体说明本实用新型的实施方法,并不限定本实用新型的保护范围。In order to illustrate the technical solutions of the present invention more clearly and in detail, the present invention will be further described below through relevant embodiments. The following examples are only to specifically illustrate the implementation method of the present invention, and do not limit the protection scope of the present invention.
实施例1Example 1
一种高效的VPSA制氧工艺,包括均压罐、鼓风机、真空泵、富氧罐和至 少3台吸附塔;单个吸附塔的制氧周期包括:An efficient VPSA oxygen production process, including pressure equalization tank, blower, vacuum pump, oxygen enrichment tank and at least 3 adsorption towers; the oxygen production cycle of a single adsorption tower includes:
A、吸附:鼓风机将空气送入吸附塔制取氧气并送入富氧罐;A. Adsorption: The air blower sends the air into the adsorption tower to produce oxygen and sends it to the oxygen-enriched tank;
B、顺放均压:吸附塔完成吸附后,停止送氧,将塔内剩余气体放入均压罐,使塔内气压与均压罐平衡;B. Smooth release and pressure equalization: after the adsorption tower completes adsorption, stop sending oxygen, and put the remaining gas in the tower into the pressure equalizing tank to balance the pressure in the tower and the pressure equalizing tank;
C、真空解析:利用真空泵对吸附塔抽真空,使吸附剂再生;C. Vacuum analysis: use a vacuum pump to vacuum the adsorption tower to regenerate the adsorbent;
D、均压升压:利用均压罐内的气体对吸附塔充气均压,使塔内气压与均压罐平衡;D. Equalizing and boosting: use the gas in the equalizing tank to inflate the adsorption tower and equalize the pressure, so that the air pressure in the tower and the equalizing tank are balanced;
所述制氧周期中的吸附时间长于抽真空解吸的时间,所有吸附塔按顺序依次与所述均压罐连通顺放均压或连通均压升压,实现吸附塔从吸附到解吸的转换和吸附塔从解吸到吸附的转换。The adsorption time in the oxygen production cycle is longer than the vacuum desorption time, and all the adsorption towers are connected with the pressure equalizing tank in order to release the pressure or to increase the pressure to realize the conversion from adsorption to desorption of adsorption towers. The conversion of the adsorption column from desorption to adsorption.
实施例2Example 2
本实施例在实施例1的基础上:This embodiment is on the basis of Embodiment 1:
所述均压罐的体积不小于吸附塔的体积,使均压后的均压罐气压接近大气压,在下一次均压操作中与吸附塔形成大的压力差,从而在1-5s内迅速对吸附塔完成均压操作。The volume of the pressure equalizing tank is not less than the volume of the adsorption tower, so that the pressure of the pressure equalizing tank after pressure equalization is close to atmospheric pressure, and a large pressure difference is formed with the adsorption tower in the next pressure equalizing operation, so that the adsorption can be quickly absorbed within 1-5s. The tower completes the pressure equalization operation.
按均压罐体积为吸附塔2倍计算(可根据项目需要增加均压罐的体积):Calculated according to the volume of the pressure equalizing tank is twice the adsorption tower (the volume of the pressure equalizing tank can be increased according to the needs of the project):
第一周期:吸附塔50kPa与均压罐0kPa顺放均压后的压力为+17kPa,吸附塔-50kPa与均压罐+17kPa均压升压后的压力为-22kPa;The first cycle: the pressure of the adsorption tower 50kPa and the pressure equalization tank 0kPa after the pressure equalization is +17kPa, the pressure after the adsorption tower -50kPa and the pressure equalization tank +17kPa equalization and boosting is -22kPa;
第二周期:吸附塔50kPa与均压罐-22kPa顺放均压后的压力为+2kPa,吸附塔-50kPa与均压罐+2kPa均压升压后的压力为-17kPa;The second cycle: the pressure of the adsorption tower 50kPa and the pressure equalization tank -22kPa after the pressure equalization is +2kPa, the pressure after the adsorption tower -50kPa and the pressure equalization tank +2kPa equalization and boosting is -17kPa;
第三周期:吸附塔50kPa与均压罐-17kPa顺放均压后的压力为+5kPa,吸附塔-50kPa与均压罐+5kPa均压升压后的压力为-13kPa;The third cycle: the pressure of the adsorption tower 50kPa and the pressure equalization tank -17kPa after the pressure equalization is +5kPa, and the pressure after the adsorption tower -50kPa and the pressure equalization tank +5kPa equalization and boosting is -13kPa;
第四周期:吸附塔50kPa与均压罐-13kPa顺放均压后的压力为+8kPa,吸附 塔-50kPa与均压罐+8kPa均压升压后的压力为-11kPa;The 4th cycle: the pressure after adsorption tower 50kPa and pressure equalizing tank-13kPa equalizing pressure is +8kPa, and the pressure after adsorption tower-50kPa and pressure equalizing tank+8kPa equalizing pressure boosting is-11kPa;
均压罐的压力随着制氧周期不断重复逐步稳定在一定正负范围,并接近大气压,每次顺放均压和均压升压的时间为2-3s。。The pressure of the pressure equalizing tank is gradually stabilized in a certain positive and negative range with the continuous repetition of the oxygen production cycle, and is close to the atmospheric pressure. .
实施例3Example 3
本实施例在实施例1的基础上:This embodiment is on the basis of Embodiment 1:
所述均压罐的体积等于吸附塔的体积,每次顺放均压和均压升压的时间为5s。The volume of the pressure equalizing tank is equal to the volume of the adsorption tower, and the time for each time of pressure equalization and pressure equalization is 5s.
实施例4Example 4
本实施例在实施例1的基础上:This embodiment is on the basis of Embodiment 1:
所述均压罐的气压保持在-15kPa~+15kPa之间。常规的吸附塔在吸附后的气压在50kPa左右,抽真空后的气压在-50kPa左右,均压罐在交替的顺放均压和均压升压操作中气压维持在-15kPa~+15kPa间,能与吸附塔形成理想的压力差,迅速均压。The air pressure of the pressure equalizing tank is maintained between -15kPa~+15kPa. The air pressure of the conventional adsorption tower after adsorption is about 50kPa, and the air pressure after vacuuming is about -50kPa. It can form an ideal pressure difference with the adsorption tower and quickly equalize the pressure.
实施例5Example 5
本实施例在实施例1的基础上:This embodiment is on the basis of Embodiment 1:
所述均压罐的体积是吸附塔体积的3倍,每次顺放均压和均压升压的时间为1s。The volume of the pressure equalizing tank is 3 times the volume of the adsorption tower, and the time for each time of pressure equalization and pressure equalization and pressure increase is 1s.
实施例6Example 6
本实施例在实施例1的基础上:This embodiment is on the basis of Embodiment 1:
所述吸附塔的个数为n,将所述制氧周期的步骤依序划分为相同时间的2n个阶段:D+A、(A) 2x、A+B、(C) 2yThe number of the adsorption towers is n, and the steps of the oxygen production cycle are sequentially divided into 2n stages at the same time: D+A, (A) 2x , A+B, (C) 2y ;
其中,(A) 2x指2x个阶段,每个阶段均为A步骤;(C) 2y指2y个阶段,每个阶段均为C步骤,且x+y=n-1,x≠0,y≠0,x≥y; Among them, (A) 2x refers to 2x stages, each stage is A step; (C) 2y refers to 2y stages, each stage is C step, and x+y=n-1, x≠0, y ≠0, x≥y;
所有吸附塔按该阶段划分滚动进行制氧周期循环,且在同个时间段,均压罐只对一个吸附塔均压操作,并对各塔交替进行顺放均压和均压升压。All adsorption towers are divided and rolled according to this stage to carry out the oxygen production cycle, and in the same time period, the pressure equalizing tank only operates to equalize the pressure of one adsorption tower, and alternately performs equalization and pressure equalization for each tower.
D+A指先均压升压后吸附,A+B指先吸附后顺放均压;由于均压时间仅为数秒,将均压与吸附操作归在同一阶段中,吸附时间可根据氧气纯度要求适时调节。D+A refers to the pressure equalization and then the adsorption, A+B refers to the first adsorption and then the pressure equalization; since the pressure equalization time is only a few seconds, the pressure equalization and the adsorption operation are classified into the same stage, and the adsorption time can be timely according to the oxygen purity requirements. adjust.
根据该公式将制氧周期划分为等时的各个阶段,再根据均压要求对各吸附塔的流程滚动排序,即可实现高效的制氧工艺。According to this formula, the oxygen production cycle is divided into isochronous stages, and then the flow of each adsorption tower is sorted according to the pressure equalization requirements, and an efficient oxygen production process can be realized.
D+A表示D步骤加A步骤,为第一个阶段;A+B表示A步骤加B步骤,为第2x+2个阶段。D+A means D steps plus A steps, which is the first stage; A+B means A steps plus B steps, which is the 2x+2 stage.
实施例7Example 7
三塔流程系统Three-tower process system
如图1所示,装置设备构成:鼓风机(C)、真空泵(P)、吸附塔(T1~T3)、空气缓冲罐(V1)、真空缓冲罐(V2)、均压罐(V3)、富氧罐(V4)、过滤器U1、过滤器U2、换热器(E)、程控阀组(A1~A5)。As shown in Figure 1, the equipment is composed of blower (C), vacuum pump (P), adsorption tower (T1-T3), air buffer tank (V1), vacuum buffer tank (V2), pressure equalizing tank (V3), rich Oxygen tank (V4), filter U1, filter U2, heat exchanger (E), program-controlled valve group (A1~A5).
单个吸附塔的周期操作流程:The cycle operation process of a single adsorption tower:
(1)吸附制氧(1) Oxygen production by adsorption
a、均压升压:压开启程控阀A4,关闭A1、A2、A3、A5,将均压罐压力放入吸附塔,使吸附塔升压。a. Equalizing and boosting: open the program-controlled valve A4, close A1, A2, A3, and A5, and put the pressure of the equalizing tank into the adsorption tower to increase the pressure of the adsorption tower.
b、吸附:开启程控阀A1、A2,关闭A3、A4、A5,将空气经换热器冷却至40度左右送入吸附塔进行吸附分离制取氧气,富氧气从塔顶进入氧气储罐(V4),通过氧气储罐(V4)出口调节对氧气压力进行调节并将富氧送至用氧工段。b. Adsorption: Open the program-controlled valves A1, A2, close A3, A4, and A5, and cool the air to about 40 degrees through the heat exchanger and send it to the adsorption tower for adsorption and separation to produce oxygen, and the enriched oxygen enters the oxygen storage tank from the top of the tower ( V4), adjust the oxygen pressure by adjusting the outlet of the oxygen storage tank (V4) and send the enriched oxygen to the oxygen-consuming section.
c、顺放均压:开启程控阀A3,关闭A1、A2、A4、A5,将吸附塔压力放入均压罐(V3),对吸附塔降压(时间根据实际降压情况可设)。c. Smooth discharge and pressure equalization: Open the program-controlled valve A3, close A1, A2, A4, and A5, put the pressure of the adsorption tower into the pressure equalization tank (V3), and depressurize the adsorption tower (the time can be set according to the actual depressurization).
(2)吸附剂再生(2) Regeneration of adsorbent
关闭A1、A2、A3、A4,打开A5开始抽真空,将吸附剂所吸附的氮气排放至大气中,使吸附剂再生。Close A1, A2, A3, A4, open A5 to start vacuuming, and discharge the nitrogen adsorbed by the adsorbent to the atmosphere to regenerate the adsorbent.
三个吸附塔的制氧流程控制:Oxygen production process control of three adsorption towers:
表1三塔程控时间分配表Table 1 Three-tower program-controlled time allocation table
Figure PCTCN2021085289-appb-000001
Figure PCTCN2021085289-appb-000001
通过对各个程控阀的开启与关闭,实现表1的流程控制。三塔系统的制氧工艺,每个时间段都有两个吸附塔同时在吸附,一个吸附塔在抽真空;均压罐在整个过程对每个吸附塔逐个轮流交替升压和顺放均压操作。吸附剂利用率高达66%。By opening and closing each program-controlled valve, the process control in Table 1 is realized. In the oxygen production process of the three-tower system, two adsorption towers are adsorbing at the same time in each time period, and one adsorption tower is vacuuming; the pressure equalizing tank alternately boosts and discharges the pressure for each adsorption tower one by one during the whole process. . The adsorbent utilization rate is as high as 66%.
实施例8Example 8
四塔流程系统Four-tower process system
如图2所示,装置设备构成:鼓风机(C)、真空泵(P)、吸附塔(T1~T4)、空气缓冲罐(V1)、真空缓冲罐(V2)、均压罐(V3)、富氧罐(V4)、过滤器U1、过滤器U2、换热器(E)、程控阀组(A1~A5)。As shown in Figure 2, the equipment is composed of blower (C), vacuum pump (P), adsorption tower (T1-T4), air buffer tank (V1), vacuum buffer tank (V2), pressure equalizing tank (V3), rich Oxygen tank (V4), filter U1, filter U2, heat exchanger (E), program-controlled valve group (A1~A5).
四个吸附塔的制氧流程控制:Oxygen production process control of four adsorption towers:
表2四塔程控时间分配表Table 2 Four-tower program-controlled time allocation table
Figure PCTCN2021085289-appb-000002
Figure PCTCN2021085289-appb-000002
Figure PCTCN2021085289-appb-000003
Figure PCTCN2021085289-appb-000003
通过对各个程控阀的开启与关闭,实现表2的流程控制。四塔系统的制氧工艺,每个时间段都有三个吸附塔同时在吸附,一个吸附塔在抽真空;均压罐在整个过程对每个吸附塔逐个轮流交替升压和顺放均压操作。吸附剂利用率高达75%。By opening and closing each program-controlled valve, the process control in Table 2 is realized. In the oxygen production process of the four-column system, three adsorption towers are simultaneously adsorbing in each time period, and one adsorption tower is vacuuming; the pressure equalizing tank alternately boosts and equalizes pressure for each adsorption tower one by one during the whole process. The adsorbent utilization rate is as high as 75%.
实施例9Example 9
五塔流程系统Five-tower process system
如图3所示,装置设备构成:鼓风机(C)、真空泵(P)、吸附塔(T1~T5)、空气缓冲罐(V1)、真空缓冲罐(V2)、均压罐(V3)、富氧罐(V4)、过滤器U1、过滤器U2、换热器(E)、程控阀组(A1~A5)。As shown in Figure 3, the equipment is composed of blower (C), vacuum pump (P), adsorption tower (T1-T5), air buffer tank (V1), vacuum buffer tank (V2), pressure equalizing tank (V3), rich Oxygen tank (V4), filter U1, filter U2, heat exchanger (E), program-controlled valve group (A1~A5).
五个吸附塔的制氧流程控制:Oxygen production process control of five adsorption towers:
表3五塔程控时间分配表Table 3 Five-tower program-controlled time allocation table
Figure PCTCN2021085289-appb-000004
Figure PCTCN2021085289-appb-000004
通过对各个程控阀的开启与关闭,实现表3的流程控制。五塔系统的制氧工艺,每个时间段都有三个吸附塔同时在吸附,两个吸附塔在抽真空;均压罐在整个过程对每个吸附塔逐个轮流交替升压和顺放均压操作。吸附剂利用率高 达60%。By opening and closing each program-controlled valve, the flow control in Table 3 is realized. In the oxygen production process of the five-column system, three adsorption towers are adsorbing at the same time in each time period, and two adsorption towers are vacuuming; the pressure equalizing tank alternately boosts and discharges pressure for each adsorption tower one by one during the whole process. . The sorbent utilization rate is as high as 60%.
实施例10Example 10
六塔流程系统Six tower process system
如图4所示,装置设备构成:鼓风机(C)、真空泵(P)、吸附塔(T1~T6)、空气缓冲罐(V1)、真空缓冲罐(V2)、均压罐(V3)、富氧罐(V4)、过滤器U1、过滤器U2、换热器(E)、程控阀组(A1~A5)。As shown in Figure 4, the device is composed of: blower (C), vacuum pump (P), adsorption tower (T1-T6), air buffer tank (V1), vacuum buffer tank (V2), pressure equalizing tank (V3), rich Oxygen tank (V4), filter U1, filter U2, heat exchanger (E), program-controlled valve group (A1~A5).
六个吸附塔的制氧流程控制:Oxygen production process control of six adsorption towers:
表4六塔程控时间分配表Table 4 Program-controlled time allocation table for six towers
Figure PCTCN2021085289-appb-000005
Figure PCTCN2021085289-appb-000005
通过对各个程控阀的开启与关闭,实现表4的流程控制。六塔系统的制氧工艺,每个时间段都有四个吸附塔同时在吸附,两个吸附塔在抽真空;均压罐在整个过程对每个吸附塔逐个轮流交替升压和顺放均压操作。吸附剂利用率高达66%。By opening and closing each program-controlled valve, the process control in Table 4 is realized. In the oxygen production process of the six-column system, four adsorption towers are adsorbing at the same time in each time period, and two adsorption towers are vacuuming; the pressure equalizing tank alternately boosts and equalizes pressure for each adsorption tower one by one during the whole process. operate. The adsorbent utilization rate is as high as 66%.
实施例11Example 11
如图1-4所示,基于该高效的VPSA制氧工艺的制氧系统,包括鼓风机、真空泵、富氧罐、均压罐和至少3台吸附塔并联而成的吸附塔组,所述鼓风机、富氧罐和真空泵分别连接各个吸附塔,所述均压罐与各个吸附塔均形成循环通路,各设备间的连接管道上均设置有程控阀。As shown in Figure 1-4, the oxygen production system based on the high-efficiency VPSA oxygen production process includes a blower, a vacuum pump, an oxygen-enriched tank, a pressure equalizing tank and an adsorption tower group formed by at least three adsorption towers in parallel. , oxygen enrichment tank and vacuum pump are respectively connected to each adsorption tower, the pressure equalization tank and each adsorption tower form a circulation passage, and the connection pipes between each equipment are provided with program-controlled valves.
实施例12Example 12
本实施例在实施例11的基础上:This embodiment is based on Embodiment 11:
所述鼓风机在与所述吸附塔组的连接管道上设置有空气缓冲罐,所述真空泵在与所述吸附塔组的连接管道上设置有真空缓冲罐。The blower is provided with an air buffer tank on the connection pipeline with the adsorption tower group, and the vacuum pump is provided with a vacuum buffer tank on the connection pipeline with the adsorption tower group.
空气缓冲罐在吸附时的气压等同于鼓风机的压力值,真空缓冲罐在抽真空时的气压等同于真空泵的压力值。The air pressure of the air buffer tank during adsorption is equivalent to the pressure value of the blower, and the air pressure of the vacuum buffer tank during vacuuming is equivalent to the pressure value of the vacuum pump.
在吸附塔抽真空过程中,真空缓冲罐的气压与吸附塔相同,当吸附塔的气压到达-50kPa左右时,切换到下一个吸附塔开始抽真空,吸附塔在与均压罐顺放均压后与真空缓冲罐进一步均压,使真空泵抽真空的起始压力为均压后的压力,而不是从大气压力开始,让吸附塔压力在极短时间内到达负压,降低了真空泵入口的压力波动,更好的保护了设备。During the vacuuming process of the adsorption tower, the air pressure of the vacuum buffer tank is the same as that of the adsorption tower. When the air pressure of the adsorption tower reaches about -50kPa, it switches to the next adsorption tower to start vacuuming. The adsorption tower is equalized with the pressure equalizing tank. Then, it is further equalized with the vacuum buffer tank, so that the initial pressure of the vacuum pump is the pressure after the pressure equalization, instead of starting from the atmospheric pressure, so that the pressure of the adsorption tower reaches the negative pressure in a very short time, which reduces the pressure at the inlet of the vacuum pump. Fluctuations, better protection of the equipment.
实施例13Example 13
本实施例在实施例11的基础上:This embodiment is based on Embodiment 11:
所述鼓风机的进风口设置有过滤器,鼓风机的出风口设置有换热器。进入吸附塔的空气,先经过滤,以洁净空气为原料,进入鼓风机,升压后经换热器降温,使温度降到分子筛最佳吸附性能温度状态,再进入已经再生完毕处于工作状态的吸附塔。The air inlet of the blower is provided with a filter, and the air outlet of the blower is provided with a heat exchanger. The air entering the adsorption tower is first filtered, and the clean air is used as the raw material to enter the blower. After the pressure is increased, it is cooled by the heat exchanger, so that the temperature is lowered to the optimum adsorption performance temperature of the molecular sieve, and then enters the adsorption that has been regenerated and is in a working state. tower.
所述真空泵的进风口设置有过滤器。The air inlet of the vacuum pump is provided with a filter.
本系统在有2塔或者多塔同时抽真空时,可通过设置2台或多台真空泵,保障抽真空的各塔独立运行,互不干扰。When the system has two or more towers for vacuuming at the same time, two or more vacuum pumps can be set up to ensure the independent operation of each vacuuming tower without interfering with each other.
本实用新型采用的鼓风机可为罗茨鼓风机、离心鼓风机或者水环鼓风机;换热器为水冷式空气冷却器,过滤器为自洁式空气过滤器,程控阀型号为气动/液动蝶阀。具体规格型号由装置规模和用户需求选定。The blower adopted by the utility model can be a Roots blower, a centrifugal blower or a water ring blower; the heat exchanger is a water-cooled air cooler, the filter is a self-cleaning air filter, and the program-controlled valve model is a pneumatic/hydraulic butterfly valve. The specific specifications and models are selected by the size of the device and user needs.
以上所述实施例仅表达了本发明的具体实施方式,其描述较为具体和详细,但并不能因此而理解为对本发明专利范围的限制。应当指出的是,对于本领域的普通技术人员来说,在不脱离本发明构思的前提下,还可以做出若干变形和改进,这些都属于本发明的保护范围。The above-mentioned embodiments only represent specific embodiments of the present invention, and the descriptions thereof are specific and detailed, but should not be construed as limiting the patent scope of the present invention. It should be pointed out that for those of ordinary skill in the art, without departing from the concept of the present invention, several modifications and improvements can also be made, which all belong to the protection scope of the present invention.

Claims (10)

  1. 一种高效的VPSA制氧工艺,其特征在于,包括均压罐、鼓风机、真空泵、富氧罐和至少3台吸附塔;单个吸附塔的制氧周期包括:An efficient VPSA oxygen production process is characterized in that, comprising a pressure equalizing tank, a blower, a vacuum pump, an oxygen enrichment tank and at least 3 adsorption towers; the oxygen production cycle of a single adsorption tower includes:
    A、吸附:鼓风机将空气送入吸附塔制取氧气并送入富氧罐;A. Adsorption: The air blower sends the air into the adsorption tower to produce oxygen and sends it to the oxygen-enriched tank;
    B、顺放均压:吸附塔完成吸附后,停止送氧,将塔内剩余气体放入均压罐,使塔内气压与均压罐压力平衡;B. Smooth release and pressure equalization: After the adsorption tower completes the adsorption, stop sending oxygen, and put the remaining gas in the tower into the pressure equalizing tank to balance the pressure in the tower and the pressure equalizing tank;
    C、真空解析:利用真空泵对吸附塔抽真空,使吸附剂再生;C. Vacuum analysis: use a vacuum pump to vacuum the adsorption tower to regenerate the adsorbent;
    D、均压升压:利用均压罐内的气体对吸附塔充压,使塔内气压与均压罐压力平衡;D. Equalizing and boosting: using the gas in the equalizing tank to pressurize the adsorption tower, so that the air pressure in the tower and the pressure in the equalizing tank are balanced;
    所述制氧周期中的吸附时间长于抽真空解吸的时间,所有吸附塔按顺序依次与所述均压罐连通顺放均压或连通均压升压,实现吸附塔从吸附到解吸的转换和吸附塔从解吸到吸附的转换。The adsorption time in the oxygen production cycle is longer than the vacuum desorption time, and all the adsorption towers are connected with the pressure equalizing tank in order to release the pressure or to increase the pressure to realize the conversion from adsorption to desorption of adsorption towers. The conversion of the adsorption column from desorption to adsorption.
  2. 根据权利要求1所述高效的VPSA制氧工艺,其特征在于,同时间处于吸附状态的吸附塔不少于两台。The high-efficiency VPSA oxygen production process according to claim 1 is characterized in that there are no less than two adsorption towers in an adsorption state at the same time.
  3. 根据权利要求2所述高效的VPSA制氧工艺,其特征在于,若吸附塔为3台,同时间两塔吸附一塔再生;若吸附塔为4台,同时间三塔吸附一塔再生;若吸附塔为5台,同时间三塔吸附两塔再生;若吸附塔为6台,同时间四塔吸附两塔再生。The high-efficiency VPSA oxygen production process according to claim 2 is characterized in that, if the number of adsorption towers is 3, two towers are adsorbed and one tower is regenerated at the same time; if there are 4 adsorption towers, three towers are adsorbed and one tower is regenerated at the same time; If the number of adsorption towers is 5, the three adsorption towers will be regenerated at the same time; if the number of adsorption towers is 6, the four adsorption towers will be regenerated at the same time.
  4. 根据权利要求1所述高效的VPSA制氧工艺,其特征在于,吸附塔的个数为n,将所述制氧周期的步骤依序划分为相同时间的2n个阶段:D+A、(A) 2x、A+B、(C) 2yThe efficient VPSA oxygen production process according to claim 1, wherein the number of adsorption towers is n, and the steps of the oxygen production cycle are sequentially divided into 2n stages at the same time: D+A, (A) ) 2x , A+B, (C) 2y ;
    其中,(A) 2x指2x个阶段,每个阶段均为A步骤;(C) 2y指2y个阶段,每个阶段均为C步骤,且x+y=n-1,x≠0,y≠0,x≥y; Among them, (A) 2x refers to 2x stages, each stage is A step; (C) 2y refers to 2y stages, each stage is C step, and x+y=n-1, x≠0, y ≠0,x≥y;
    所有吸附塔按该阶段划分滚动进行制氧周期循环,且在同个时间段,均压 罐只对一个吸附塔均压操作,并对各塔交替进行顺放均压和均压升压。All adsorption towers are divided and rolled according to this stage to carry out the oxygen production cycle, and in the same time period, the pressure equalizing tank only performs pressure equalization operation on one adsorption tower, and alternately performs pressure equalization and pressure equalization for each tower.
  5. 根据权利要求1所述高效的VPSA制氧工艺,其特征在于,所述均压罐的体积不小于吸附塔的体积。The efficient VPSA oxygen production process according to claim 1, wherein the volume of the pressure equalizing tank is not less than the volume of the adsorption tower.
  6. 根据权利要求5所述高效的VPSA制氧工艺,其特征在于,每次顺放均压和均压升压的时间为1~5s。The high-efficiency VPSA oxygen production process according to claim 5, characterized in that, the time for equalizing the pressure and increasing the pressure each time is 1-5s.
  7. 根据权利要求1所述高效的VPSA制氧工艺的系统,其特征在于,包括鼓风机、真空泵、富氧罐、均压罐和至少3台吸附塔并联而成的吸附塔组,所述鼓风机、富氧罐和真空泵分别连接各个吸附塔,所述均压罐与各个吸附塔均形成循环通路,各设备间的连接管道上均设置有程控阀。The system of efficient VPSA oxygen production process according to claim 1, is characterized in that, comprises the adsorption tower group formed by blower, vacuum pump, oxygen-enriched tank, pressure equalizing tank and at least 3 adsorption towers in parallel, The oxygen tank and the vacuum pump are respectively connected to each adsorption tower, the pressure equalization tank and each adsorption tower form a circulation passage, and a program-controlled valve is arranged on the connecting pipeline between each equipment.
  8. 根据权利要求7所述高效的VPSA制氧工艺的系统,其特征在于,所述鼓风机在与所述吸附塔组的连接管道上设置有空气缓冲罐,所述真空泵在与所述吸附塔组的连接管道上设置有真空缓冲罐。The high-efficiency VPSA oxygen production process system according to claim 7, characterized in that, an air buffer tank is provided on the connecting pipeline of the blower with the adsorption tower group, and the vacuum pump is connected with the adsorption tower group. A vacuum buffer tank is arranged on the connecting pipeline.
  9. 根据权利要求7所述高效的VPSA制氧工艺的系统,其特征在于,所述鼓风机的进风口设置有过滤器,鼓风机的出风口设置有换热器。The high-efficiency VPSA oxygen production process system according to claim 7, wherein the air inlet of the blower is provided with a filter, and the air outlet of the blower is provided with a heat exchanger.
  10. 根据权利要求7所述高效的VPSA制氧工艺的系统,其特征在于,所述真空泵的进风口设置有过滤器。The high-efficiency VPSA oxygen production process system according to claim 7, wherein a filter is provided at the air inlet of the vacuum pump.
PCT/CN2021/085289 2020-09-29 2021-04-02 Efficient vpsa oxygen production process and system thereof WO2022068165A1 (en)

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