WO2022045367A1 - Fresh cheese, manufacturing method therefor, and method for improving aftertaste - Google Patents

Fresh cheese, manufacturing method therefor, and method for improving aftertaste Download PDF

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Publication number
WO2022045367A1
WO2022045367A1 PCT/JP2021/031976 JP2021031976W WO2022045367A1 WO 2022045367 A1 WO2022045367 A1 WO 2022045367A1 JP 2021031976 W JP2021031976 W JP 2021031976W WO 2022045367 A1 WO2022045367 A1 WO 2022045367A1
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ppb
hardness
fresh cheese
content
cheese
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PCT/JP2021/031976
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French (fr)
Japanese (ja)
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沙良 中川
未央 山田
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株式会社明治
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Priority to JP2022545768A priority Critical patent/JPWO2022045367A1/ja
Priority to CN202180053483.XA priority patent/CN115996641A/en
Publication of WO2022045367A1 publication Critical patent/WO2022045367A1/en

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    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23CDAIRY PRODUCTS, e.g. MILK, BUTTER OR CHEESE; MILK OR CHEESE SUBSTITUTES; MAKING THEREOF
    • A23C19/00Cheese; Cheese preparations; Making thereof
    • A23C19/06Treating cheese curd after whey separation; Products obtained thereby
    • A23C19/068Particular types of cheese
    • A23C19/076Soft unripened cheese, e.g. cottage or cream cheese

Definitions

  • the present invention relates to fresh cheese, a method for producing the same, and a method for improving the aftertaste.
  • fresh cheese which is a non-aged cheese, has a relatively high water content as compared with aged cheese, and is characterized by having a fresh milk aroma and a refreshing acidity.
  • Some fresh cheeses have a soft and smooth texture, such as cream cheese, and some have an elastic texture, such as pasta filata cheese.
  • fresh cheese is produced by heat-sterilizing raw milk or concentrated milk, and then adding organic acids such as lactic acid and citric acid, lactic acid bacteria, and milk-clotting enzyme to generate curd.
  • fresh cheese is eaten as it is by applying it to bread and crackers, and it is also widely used in secondary processing as a raw material for confectionery / bakery, processed foods, and processed cheese.
  • Typical examples of fresh cheese include cream cheese, mascarpone, fromage blanc, cottage cheese, quark, pasta filata (mozzarella cheese, bullata, cachocabaro cheese, skamorza cheese, provalone cheese, string cheese, etc.).
  • Patent Document 1 It has been reported to provide fresh cheese having an appropriate hardness and a smooth texture by setting the hardness and the surface roughness of the cut surface within a specific range (Patent Document 1).
  • Non-Patent Document 1 the relationship between various aroma components of cheese and the degree of preference of cheese has been considered.
  • the present invention has been made in view of the above-mentioned problems of the prior art, and one object of the present invention is to provide fresh cheese having an excellent aftertaste.
  • the present inventors have found that in fresh cheese, the ratio of the content and hardness of a specific aroma component (content / hardness of a specific aroma component) and the aftertaste of aftertaste. They have been correlated and have been found to be able to impart an excellent aftertaste to fresh cheese by adjusting the ratio of content and hardness of specific aroma components.
  • the present invention is based on such findings.
  • [1] It contains at least one aroma component selected from ⁇ -dodecalactone and z-daily lactone, and the ratio of the content of the aroma component to the hardness of fresh cheese (content / hardness of the aroma component) is as follows.
  • the content (ppb) / hardness (gf) of ⁇ -dodecalactone is 0.80 ppb / gf or more.
  • the content (ppb) / hardness (gf) of z-daily lactone is 0.26 ppb / gf or more.
  • the total amount (ppb) / hardness (gf) of 2-heptanone and ⁇ -dodecalactone is 0.86 ppb / gf or more.
  • the total amount (ppb) / hardness (gf) of 2-heptanone and z-daily lactone is 0.33 ppb / gf or more.
  • the total amount (ppb) / hardness (gf) of ⁇ -dodecalactone and z-daily lactone is 1.06 ppb / gf or more.
  • the ratio of the content of the aroma component containing at least one selected from ⁇ -dodecalactone and z-daily lactone to the hardness of the fresh cheese refers to the aftertaste.
  • a method for producing fresh cheese which comprises a step of adjusting so as to be equal to or higher than a set threshold.
  • [12] It comprises (1) a step of preparing a card containing the aroma component, and (2) a step of adjusting the ratio of the content of the aroma component to the hardness to obtain fresh cheese from the card [11]. ]
  • the method described in. [13] The ratio of the content of the aroma component containing at least one selected from ⁇ -dodecalactone and z-daily lactone to the hardness of the pasta filler (content of aroma component / hardness) is set with reference to the aftertaste.
  • a method for producing pasta filata which comprises a step of adjusting the pasta filata so as to be equal to or higher than the threshold value.
  • a method for producing pasta filata wherein the aroma component is added in any one or more of a step of preparing the curd, a step of kneading the curd, and a step of immersing the kneaded fresh cheese in brine.
  • the ratio of the content of the aroma component containing at least one selected from ⁇ -dodecalactone and z-daily lactone to the hardness of the fresh cheese refers to the aftertaste.
  • a method for improving the aftertaste of fresh cheese which comprises a step of adjusting so as to be equal to or higher than the set threshold value.
  • fresh cheese means, for example, natural cheese that is barely or completely aged, such as pasta filata (mozzarella cheese, bullata, string cheese, etc.), cream cheese, quark, fromage blanc, cottage cheese, etc. Mascarpone Harumi cheese, Feta, etc. can be mentioned.
  • the pasta filata cheese is a cheese that requires a pasta filata process during its production, and the pasta filata process is a large cheese curd while heating the cheese curd at an appropriate pH. Knead until there are no lumps, and knead or spread until the physical properties become smooth.
  • the content and hardness of the aroma component comprising at least one selected from ⁇ -dodecalactone and cis-6-Dodecen-4-lide (denoted as z-daily lactone).
  • a fresh cheese is provided in which the ratio (content / hardness of aroma component) is adjusted to be equal to or higher than a threshold set with reference to the aftertaste of the aftertaste.
  • the fresh cheese satisfies at least one of the following (i) to (vi).
  • the content (ppb) / hardness (gf) of ⁇ -dodecalactone is 0.80 ppb / gf or more.
  • the content (ppb) / hardness (gf) of z-daily lactone is 0.26 ppb / gf or more.
  • the total amount (ppb) / hardness (gf) of 2-heptanone and ⁇ -dodecalactone is 0.86 ppb / gf or more.
  • the total amount (ppb) / hardness (gf) of 2-heptanone and z-daily lactone is 0.33 ppb / gf or more.
  • the total amount (ppb) / hardness (gf) of ⁇ -dodecalactone and z-daily lactone is 1.06 ppb / gf or more.
  • the total amount (ppb) / hardness (gf) of 2-heptanone, ⁇ -dodecalactone and z-daily lactone is 1.13 ppb / gf or more.
  • the fresh cheese satisfies (vi).
  • the threshold of ⁇ -dodecalactone content (ppb) / hardness (gf) is usually 0.80 ppb / gf or 0.85 ppb / gf, preferably 1.17 ppb /. It is gf or 1.21 ppb / gf, more preferably 1.54 ppb / gf or 1.57 ppb / gf.
  • the upper limit of the ratio of the content (ppb) of ⁇ -dodecalactone to the hardness (gf) is not particularly limited, but is, for example, 6.4 ppb / gf.
  • the z-daily lactone content (ppb) / hardness (gf) threshold is usually 0.26 ppb / gf or 0.30 ppb / gf, preferably 0.42 ppb /. It is gf or 0.44 ppb / gf, more preferably 0.57 ppb / gf or 0.58 ppb / gf.
  • the upper limit of the ratio of the content (ppb) of the z-daily lactone to the hardness (gf) is not particularly limited, but is, for example, 2.4 ppb / gf.
  • the threshold (lower limit) of the ratio of 2-heptanone content (ppb) to hardness (gf) is usually 0.053 (ppb / gf) or 0.055 (ppb / gf). It is preferably 0.063 (ppb / gf) or 0.073 (ppb / gf), and more preferably 0.077 ppb / gf or 0.093 (ppb / gf).
  • the upper limit of the ratio of the 2-heptanone content (ppb) to the hardness (gf) is not particularly limited, but is, for example, 0.31 ppb / gf.
  • the threshold for the total amount (ppb) / hardness (gf) of 2-heptanone and ⁇ -dodecalactone is usually 0.85 ppb / gf or 0.93 ppb / gf, preferably 0.93 ppb / gf. It is 1.22 ppb / gf or 1.23 ppb / gf, more preferably 1.50 ppb / gf or 1.61 ppb / gf.
  • the upper limit of the total amount (ppb) / hardness (gf) of 2-heptanone and ⁇ -dodecalactone is not particularly limited, but is, for example, 6.0 ppb / gf.
  • the threshold of total amount (ppb) / hardness (gf) of 2-heptanone and z-daily lactone is usually 0.33 ppb / gf or 0.35 ppb / gf, preferably 0.35 ppb / gf. It is 0.48 ppb / gf or 0.50 ppb / gf, more preferably 0.63 ppb / gf or 0.64 ppb / gf.
  • the upper limit of the total amount (ppb) / hardness (gf) of 2-heptanone and z-daily lactone is not particularly limited, but is, for example, 2.0 ppb / gf.
  • the threshold of total amount (ppb) / hardness (gf) of ⁇ -dodecalactone and z-daily lactone is usually 1.06 ppb / gf or 1.15 ppb / gf, which is preferable. Is 1.59 ppb / gf or 1.65 ppb / gf, more preferably 2.16 ppb / gf.
  • the upper limit of the total amount (ppb) / hardness (gf) of 2-heptanone and z-daily lactone is not particularly limited, but is, for example, 8.7 ppb / gf.
  • the above threshold of total amount (ppb) / hardness (gf) of 2-heptanone, ⁇ -dodecalactone and z-daily lactone is usually 1.13 ppb / gf or 1.21 ppb /. It is gf, preferably 1.65 ppb / gf or 1.71 ppb / gf, and more preferably 2.18 ppb / gf or 2.22 ppb / gf.
  • the upper limit of the total amount (ppb) / hardness (gf) of 2-heptanone, ⁇ -dodecalactone and z-daily lactone is not particularly limited, but is, for example, 8.8 ppb / gf.
  • the content of each aroma component in fresh cheese can be measured using GS-MS analysis.
  • the details of the measurement conditions can be carried out according to Test Example 2 described later.
  • a sample fresh cheese
  • DHS dynamic headspace gas chromatograph
  • the content of 2-heptanone is usually 5 to 260 ppb, preferably 10 to 250 ppb, and more preferably 15 to 200 ppb.
  • the content of ⁇ -dodecalactone is usually 150 to 2600 ppb, preferably 200 to 2500 ppb, and more preferably 220 to 2000 ppb.
  • the content of z-daily lactone is usually 50 to 2600 ppb, preferably 60 to 2500 ppb, and more preferably 70 to 2000 ppb.
  • the total amount of 2-heptanone, ⁇ -dodecalactone and z-daily lactone is usually 205-5460 ppb, preferably 270-5250 ppb, more preferably 305-4600 ppb.
  • the hardness of the fresh cheese is not particularly limited, but is usually 50 to 3000 gf, preferably 65 to 2800 gf, and more preferably 80 to 2500 gf.
  • water content, the fat content, and the fat content (FDM) in the solid content of the fresh cheese are not particularly limited and can be appropriately set according to the type and properties of the desired fresh cheese.
  • the water content of fresh cheese is usually 30 to 82% by mass, preferably 35 to 80% by mass, and more preferably 40 to 70% by mass.
  • the water content is preferably 40 to 60% by mass, more preferably 42 to 55% by mass.
  • the water content of fresh cheese, which is a pasta filler is within the above range, the quality is good from the viewpoint of microbiological viewpoint and maintenance of fibrousness. If the other components are the same and the production method and fermentation period are the same, the hardness tends to decrease as the water content increases.
  • the fat content of fresh cheese is usually 0 to 45% by mass, preferably 3 to 40% by mass, and more preferably 15 to 35% by mass.
  • the FDM content of fresh cheese is usually 0 to 85% by mass, preferably 18 to 80% by mass, and more preferably 20 to 75% by mass. If the method of producing fresh cheese and the fermentation period are the same, the hardness tends to decrease as the FDM increases.
  • fresh cheese is obtained by adjusting the ratio of aroma component and hardness to a desired range to give a lingering aftertaste.
  • the aftertaste of fresh cheese can be determined according to the sensory evaluation of Test Example 3 described later.
  • the aftertaste of fresh cheese is not only the enhancement of milk flavor derived from milk and the thickness of milk flavor, but also the cream-flavored aftertaste that remains in the nasal cavity after ingesting and chewing fresh cheese. It is said that.
  • fresh cheese can be in the form of packaging or containerization. Therefore, according to one aspect of the present invention, according to one aspect of the present invention, a packaged food or a packaged food containing the fresh cheese is provided. Further, from the viewpoint of suppressing volatilization and decomposition of aroma components, the packaging and the container used for the fresh cheese are preferably those in which all (the entire surface) or a part of the fresh cheese is shielded from light. In the case of partial shading, it is more preferable that one side of the fresh cheese is shaded. Packaging and containers are not restricted in shape. Examples of packaging and containers include plastic containers, soft bags, standing type soft bags, cans, bottles and the like.
  • the material of the packaging and the container is preferably partially or wholly light-shielding, and for example, a material such as aluminum foil, an aluminum vapor-deposited film, a film laminated with paper, a can, a brown bottle, or UV-cut plastic is used.
  • a material such as aluminum foil, an aluminum vapor-deposited film, a film laminated with paper, a can, a brown bottle, or UV-cut plastic is used.
  • fresh cheese is manufactured by a person skilled in the art by appropriately adjusting the conditions of each manufacturing process so that the ratio of the aroma component and the hardness becomes equal to or higher than the preset threshold value. can do. Therefore, according to a preferred embodiment of the present invention, the ratio of the content of the aroma component containing at least one selected from ⁇ -dodecalactone and z-daily lactone to the hardness of the fresh cheese (content of aroma component / hardness). )
  • a method for producing fresh cheese which comprises a step of adjusting the aftertaste so as to be equal to or higher than a set threshold value with reference to the aftertaste.
  • the fresh cheese satisfies at least one of the above (i) to (vi).
  • the method for producing fresh cheese is: It includes (1) a step of preparing a card containing the above-mentioned aroma component, and (2) a step of adjusting the ratio of the content of the above-mentioned aroma component to the hardness to obtain the above-mentioned fresh cheese from the above-mentioned card.
  • the step (1) is described in the above step. It includes a step of adding a fragrance containing the above-mentioned aroma component.
  • the step (2) is described in the above step.
  • Under environmental control where volatilization or decomposition of the above aroma components is suppressed It comprises the steps of softening the cheese and / or fermenting the fresh cheese.
  • the step (2) above is In order to adjust the hardness, it comprises a step of adjusting the fat content, FDM and final water content of fresh cheese.
  • the content of an aroma component containing at least one selected from ⁇ -dodecalactone and z-daily lactone by appropriately combining each of the production conditions described below, the content of an aroma component containing at least one selected from ⁇ -dodecalactone and z-daily lactone, and the content of the aroma component of fresh cheese.
  • the hardness ratio (content of aroma component / hardness) can be adjusted to a desired range.
  • the freezing method for freezing the card is the same as the general freezing method for the card, but the quick freezing method is particularly preferable.
  • the storage temperature of the frozen card is ⁇ 20 ° C. or lower, more preferably ⁇ 50 ° C. or lower, and preferably ⁇ 80 ° C. or lower when stored for a longer period of time.
  • a commercially available frozen card may be thawed and a part or all thereof may be used.
  • the lactic acid bacterium starter used in the production of fresh cheese may be any lactic acid bacterium that can be used in fresh cheese, and its genus and species are arbitrary, and for example, Lactobacillus, Cremoris, Bulgaria, Thermophilus, etc. Known lactic acid bacteria can be mentioned.
  • the lactic acid bacterium starter is preferably Lactobacillus, Bulgaria, or Thermophilus.
  • known acids used in foods and / or food additives are directly added to raw milk, including organic acids such as lactic acid, acetic acid and citric acid, and inorganic acids such as phosphoric acid. You can also do it.
  • the pasta filata heats the produced curd and / or thawed curd, stretches it, stretches it appropriately, forms it, and cools it to obtain fresh cheese.
  • the fresh cheese may be allowed to stand and aged (fermented).
  • fresh cheese may be packaged or contained in a container, if desired, before or after standing.
  • the aroma component and hardness of the fresh cheese can be variously adjusted by adjusting the components of the raw milk.
  • Raw milk refers to unsterilized raw milk, and raw milk such as milk, sheep milk, and goat milk can be used, but milk is preferable.
  • the raw material milk it is preferable to use the raw material milk containing a high volume of aroma components such as ⁇ -dodecalactone, z-daily lactone and 2-heptanone.
  • raw milk having a fat content, FDM and its ratio suitable for the hardness examples of suitable raw milk include raw milk produced in Hokkaido, and more preferably Tokachi, Hokkaido. For example, it is preferable to use 60% or more of raw milk from Hokkaido and Tokachi, Hokkaido.
  • the aroma component of the fresh cheese is adjusted by adding a commercially available flavor containing ⁇ -dodecalactone, z-daily lactone, 2-heptanone and the like. You can also do it.
  • the timing of adding the flavor is not limited, but it is preferable to carry out in one or more steps of adding to the raw milk, preparing the curd, kneading the curd and immersing in fresh cheese brine. Considering the loss of fragrance, it is preferably in the process of preparing a card that has reached room temperature and the kneading process.
  • the lactones and the like in the curd and fresh cheese may be adjusted to increase, or the lactones and the like may be added to the curd and fresh cheese.
  • the composition can be adjusted according to the final aroma component content, hardness, type and properties of various fresh cheeses. For example, after separating skim milk or cream from unsterilized raw milk using a cream separator or the like, these skim milk and cream are prepared in a predetermined mixing ratio and blended into the milk to adjust the milk fat content. Can be done.
  • full fat milk, partially skim milk, skim milk, milk powder, and cream can also be used as raw materials, and further, by heat concentration, centrifugal concentration, filter membrane concentration, vacuum concentration, freeze concentration, etc. Concentrated milk can also be used.
  • heating conditions may be set according to the final aroma component content, hardness, type, and properties of various fresh cheeses.
  • the heating conditions may be, for example, heat sterilization (HTST sterilization) at about 60 ° C. for 30 minutes, or after reaching a temperature of about 72 to 75 ° C. for 15 seconds.
  • HTST sterilization heat sterilization
  • the heat sterilization step for example, it may be quickly cooled to about 40 ° C. with a plate heat exchanger or the like.
  • the pH of standardized milk and the rate of change in pH can be set in consideration of the final hardness of various fresh cheeses.
  • the pH of the standardized milk may be, for example, about 5 to 6.5.
  • the amount of rennet used to prepare the curd can be set in consideration of the final hardness of various fresh cheeses.
  • the amount of rennet added is the amount required for curdling in about 20 to 40 minutes.
  • the amount of rennet may be, for example, 10 to 300 ppm or 10 to 100 ppm with respect to the standardized milk.
  • the cutting size of the coagulated product during card making can be selected in consideration of the hardness of the final fresh cheese.
  • the heating method of the curd can be appropriately selected according to the final aroma component content, hardness, type, and properties of various fresh cheeses.
  • the method for heating the curd include a method of immersing the cheese curd in hot water at 70 to 80 ° C., a method of using steam, a method of heating by Joule heating or microwave. From the viewpoint of suppressing the decrease of aroma components and milk components, the method using steam, Joule heating or microwave is preferable as the heating method. Further, the above heating method can be particularly preferably used when the fresh cheese is pasta filata.
  • a stabilizer and / or a cream may be added to the acidified and curd curd or the like.
  • the addition step may be performed before or after the stirring and mixing step or the fat globules dispersion treatment step.
  • the stabilizer may be added to the cream and then added to the curd. In this case, the stabilizer is well dispersed by homogenizing the cream to which the stabilizer is added.
  • the stabilizer added in the addition step thickening polysaccharides such as carboxymethyl cellulose, alginate, locust bean gum, tara gum, guar gum, xanthan gum, gellan gum, and pectin, and gelatin can be used, and cellulose, It is also possible to use dietary fiber such as indigestible dextrin, or to use both in combination.
  • the content of the stabilizer in the card is preferably 5% by mass or less.
  • the curd obtained by the above method contains a high amount of aroma component containing at least one of z-daily lactone and ⁇ -dodecalactone from the viewpoint of producing the final desired fresh cheese. Is preferable. Also, the card preferably further comprises 2-heptanone.
  • the content of ⁇ -dodecalactone is usually 150 to 15000 ppb, preferably 200 to 10000 ppb, and more preferably 220 to 8000 ppb.
  • the content of z-daily lactone is usually 50 to 7000 ppb, preferably 60 to 6000 ppb, and more preferably 80 to 5000 ppb.
  • the content of 2-heptanone is usually 5 to 500 ppb, preferably 10 to 400 ppb, and more preferably 5 to 300 ppb.
  • the total amount of 2-heptanone, ⁇ -dodecalactone and z-daily lactone is usually 205 to 22,500 ppb, preferably 270 to 16400 ppb, more preferably 305 to 8800 ppb.
  • the card containing the above components may be prepared from raw milk, or may be used by thawing a pre-manufactured frozen card, and a card prepared from raw milk and a card obtained by thawing a frozen card may be appropriately mixed. May be used. It is preferable to prepare the curd after confirming that the content of the aroma component (2-heptanone content, ⁇ -dodecalactone content, z-daily lactone content, etc.) is within a desired range.
  • the aroma component (2-heptanone content, ⁇ -dodecalactone content, z-daily lactone content, etc.
  • an emulsifying machine for emulsification and kneading in the production of fresh cheese, an emulsifying machine, a kneading machine, or the like may be used. ..
  • the kneader for example, by using a twin-screw extruder, the above heating and stretching can be performed at the same time.
  • the method for forming fresh cheese can be appropriately selected according to the type of various cheeses and the desired hardness.
  • Burrata in the step of stretching and then molding, it is preferable to add cream to form the burrata so as not to leak, and then cool and fill the container.
  • string cheese it is preferable that after undergoing a stretching step of pasta filata, it is stretched and molded, cut and cooled, immersed in brine, and then filled in a container.
  • the hardness of cheese prepared from curd can also be adjusted by kneading.
  • fresh cheese may be allowed to stand as appropriate after production.
  • the standing of fresh cheese is preferable from the viewpoint of increasing the aroma component by fermentation.
  • the standing temperature is not particularly limited, but is, for example, ⁇ 80 to 10 ° C., preferably ⁇ 50 to 8 ° C., and more preferably ⁇ 40 to 6 ° C.
  • Mozzarella is preferably 1-10 ° C, most preferably 2-6 ° C.
  • the standing period is, for example, 7 to 120 days, 10 to 90 days, preferably 15 to 60 days.
  • the conditions for filling the container with fresh cheese can be set in a desired range according to the type and properties of the fresh cheese.
  • the curd is molded and manufactured after stretching (kneading), but it may be cooled after molding and filled with fresh cheese in a container containing a preservative solution, or sterilized water or sterilized water in the container. It may be filled in a preservation solution.
  • a preservation solution 0.1 to 2.0% by weight of sodium chloride may be contained.
  • calcium chloride is added to the preservation solution, it is preferable to add 0.05 to 0.25% by mass of calcium chloride in terms of dihydrate.
  • the preservative solution may contain a preservative such as nisin or sodium acetate.
  • the pH of the storage solution is arbitrarily determined, but can be, for example, pH 4 to 7.
  • the pH of the storage solution is preferably pH 5 to 7 when eating directly. 0.5-2% by weight whey may be added to the preservative to give a milky feel.
  • the pH of fresh cheese is usually 4 to 7, but the pH can be appropriately set according to the desired properties of cheese.
  • the pH is preferably 5.0 to 6.3 from the viewpoint of maintaining fibrousness, preservability, and good flavor at the time of direct eating.
  • the higher the pH the lower the hardness tends to be.
  • an aroma component selected from 2-heptanone, ⁇ -dodecalactone and z-daily lactone may be appropriately added during the above production process, and the present invention also includes such an embodiment.
  • the ratio of the content and hardness of the aroma component containing at least one selected from ⁇ -dodecalactone and z-daily lactone (content of aroma component / hardness).
  • a method for improving the aftertaste of fresh cheese which comprises a step of adjusting the aftertaste to be equal to or higher than a set threshold value with reference to the aftertaste.
  • the method for producing fresh cheese satisfies at least one of the above (i) to (vi).
  • the method for improving the aftertaste of fresh cheese can be carried out according to the above-mentioned fresh cheese and the method for producing the same.
  • Aspect 1 It contains at least one aroma component selected from ⁇ -dodecalactone and z-daily lactone, and the ratio of the content of the aroma component to the hardness of fresh mozzarella cheese (content of aroma component / hardness) is as follows (i). )-(Vi), fresh mozzarella cheese: (I) The content (ppb) / hardness (gf) of ⁇ -dodecalactone is 0.80 ppb / gf or more, preferably 1.17 ppb / gf or more, more preferably 1.54 ppb / gf or more, for example 1.54 ppb /.
  • the content (ppb) / hardness (gf) of z-daily lactone is 0.26 ppb / gf or more, preferably 0.42 ppb / gf or more, more preferably 0.57 ppb / gf or more, for example 0.57 ppb /.
  • the total amount (ppb) / hardness (gf) of 2-heptanone and ⁇ -dodecalactone is 0.86 ppb / gf or more, preferably 1.23 ppb / gf or more, more preferably 1.61 ppb / gf or more, for example.
  • the total amount (ppb) / hardness (gf) of 2-heptanone and z-daily lactone is 0.33 ppb / gf or more, preferably 0.48 ppb / gf or more, more preferably 0.63 ppb / gf or more, for example.
  • the total amount (ppb) / hardness (gf) of ⁇ -dodecalactone and z-daily lactone is 1.06 ppb / gf or more, preferably 1.58 ppb / gf or more, more preferably 2.16 ppb / gf or more.
  • 2.16 ppb / gf or more and 3.40 ppb / gf or less is 1.06 ppb / gf or more.
  • the total amount (ppb) / hardness (gf) of 2-heptanone, ⁇ -dodecalactone and z-daily lactone is 1.13 ppb / gf or more, preferably 1.65 ppb / gf or more, more preferably 2.18 ppb. It is / gf or more, for example, 2.18 ppb / gf or more and 3.50 ppb / gf or less.
  • Aspect 2. A packaged food or a packaged food containing the fresh mozzarella cheese according to the first aspect.
  • Aspect 3. The packaged food or packaged food according to aspect 2, wherein all or part of the fresh mozzarella cheese is shielded from light.
  • the ratio of the content of the aroma component containing at least one selected from ⁇ -dodecalactone and z-daily lactone to the hardness of the fresh mozzarella cheese is set with reference to the aftertaste.
  • a method for producing fresh mozzarella cheese which comprises a step of adjusting so as to be equal to or higher than the specified threshold.
  • An embodiment comprising (1) a step of preparing a card containing the aroma component, and (2) a step of adjusting the ratio of the content of the aroma component to the hardness to obtain fresh mozzarella cheese from the card. The method according to 4.
  • the ratio of the content of the aroma component containing at least one selected from ⁇ -dodecalactone and z-daily lactone to the hardness of the fresh mozzarella cheese is set with reference to the aftertaste.
  • a method for producing fresh mozzarella cheese which comprises a step of adjusting so as to be equal to or higher than the specified threshold.
  • the ratio of the content of the aroma component containing at least one selected from ⁇ -dodecalactone and z-daily lactone to the hardness of the fresh mozzarella cheese is set with reference to the aftertaste.
  • a method for improving the aftertaste of fresh mozzarella cheese which comprises a step of adjusting the amount to be equal to or higher than the specified threshold.
  • Test Example 1 Production of fresh cheese [Test group 1] Standardized milk is obtained using raw milk derived from cows (produced in Tochigi), skim milk, and cream, sterilized (heated to 75 ° C), cooled to 36 ° C, and 10% lactic acid is added dropwise to the prepared milk.
  • a predetermined amount of a frozen lactic acid bacterium starter (Christian Hansen) was added and mixed, and the mixture was stirred in an incubator for 20 minutes. Further, 50 ppm of rennet (Christian Hansen) was added to the obtained mixture, and the mixture was held and solidified, cut into 1 cm squares, and gently stirred. After stirring for 30 minutes at 36 ° C., the curd and whey were separated. Then, it was maturated in a constant temperature room at 40 ° C. and compressed with a pump to remove whey, and a cheese curd having FDM 52% and pH 5.2 was obtained.
  • the curd was heated to 75 ° C. with hot water, stretched, and then cooled to form a spherical shape.
  • the obtained fresh cheese was allowed to stand in a constant temperature room at 4 ° C. for 27 days.
  • the water content was 62%
  • the fat content was 20.5%
  • the FDM was 54%.
  • Test Zone 2 The same operation as in Test Group 1 was carried out, and the cheese curd was heated to 75 ° C. with hot water, stretched, and then cooled to form a spherical shape to obtain fresh cheese.
  • the obtained fresh cheese was allowed to stand in a constant temperature room at 4 ° C. for 36 days.
  • the water content was 60%
  • the fat content was 21.6%
  • the FDM was 54%.
  • a hardness measuring jig (resin columnar plunger ( ⁇ 10 ⁇ H50)) is attached to the Ez test, and the strain rate is 75% of the sample thickness at a sample temperature of 10 ° C. , The measurement speed was set to 1.0 mm / sec, and the maximum test force (hardness) was measured.
  • the Full Evaporation DHS method was carried out using the autosampler MPS2 (GRESTEL). Specifically, nitrogen purging was performed at 40 ° C. at a flow rate of 100 ml / min for 5 minutes and at 80 ° C. at a flow rate of 100 ml / min for 20 minutes, and the sample aroma component in the vial was adsorbed on the collector TenaxTA. TDU was used for thermal desorption of TenaxTA.
  • Test Example 3 Sensory evaluation With respect to the fresh cheese obtained in Test Example 1, the "aftertaste" was evaluated on a five-point scale using a trained panel of 10 people based on the following scores, and an average score was calculated. Each of the 10 panels has specialized knowledge about cheese and conducts sensory evaluation of cheese at least twice a month. Of the 10 panels, 8 had more than 10 years of sensory evaluation experience, 1 had 7 years of sensory evaluation experience, and 1 had 4 years of sensory evaluation experience.
  • Test Example 4 Correlation analysis To calculate the correlation coefficient between the ratio of the amount of aroma component to the hardness of Test Example 1 (amount of aroma component / hardness: ppb / gf) and the sensory evaluation result of Test Example 3. Correlation analysis was performed by.
  • the correlation coefficient between the ratio of the content of z-daily lactone and the hardness and the sensory evaluation result of Test Example 3 was as shown in FIG. It was confirmed that there is a correlation between the content (ppb) / hardness (gf) of z-daily lactone and the aftertaste.
  • ppb content
  • gf hardness
  • the correlation coefficient between the ratio of the total amount of 2-heptanone and ⁇ -dodecalactone to the hardness (amount of aroma component / hardness: ppb / gf) and the sensory evaluation result of Test Example 3 is shown in FIG. It was a street. It was confirmed that there was a correlation between the total amount (ppb) / hardness (gf) of 2-heptanone and ⁇ -dodecalactone and the aftertaste.
  • the correlation coefficient between the total amount of 2-heptanone and z-daily lactone and the hardness ratio and the sensory evaluation result of Test Example 3 was as shown in FIG. It was confirmed that there was a correlation between the total amount (ppb) / hardness (gf) of 2-heptanone and z-daily lactone and the aftertaste.
  • ppb total amount
  • gf hardness
  • the correlation coefficient between the ratio of the total amount of ⁇ -dodecalactone and z-daily lactone to the hardness and the sensory evaluation result of Test Example 3 was as shown in FIG. It was confirmed that there is a correlation between the total amount (ppb) / hardness (gf) of ⁇ -dodecalactone and z-daily lactone and the aftertaste.
  • ppb total amount
  • gf hardness
  • the correlation coefficient between the total amount of the three aroma components and the hardness ratio and the sensory evaluation result of Test Example 3 was as shown in FIG. It was confirmed that there is a correlation between the total amount (ppb) / hardness (gf) of the three aroma components and the aftertaste.
  • ppb total amount
  • gf hardness

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Abstract

The objective of the present invention is to provide a fresh cheese with an excellent aftertaste. The fresh cheese is such that the content-to-hardness ratio (flavor component content/hardness) of a flavor component, formed by including at least one component selected from γ-dodecalactone and z-dairy lactone, is adjusted to be greater than or equal to a threshold value that is set with reference to the aftertastes.

Description

フレッシュチーズ、その製造方法および後味の余韻の向上方法Fresh cheese, how to make it and how to improve the aftertaste
 本発明は、フレッシュチーズ、その製造方法および後味の余韻の向上方法に関する。 The present invention relates to fresh cheese, a method for producing the same, and a method for improving the aftertaste.
 日本におけるナチュラルチーズの消費は拡大傾向にある。ナチュラルチーズは2000種類以上存在し、固形分中の脂肪含有量や水分含有量、熟成の有無、カビの添加の有無などで分類される。中でも、非熟成チーズであるフレッシュチーズは、熟成チーズに比べて比較的水分値が高く新鮮なミルクの香りや爽やかな酸味があるのが特徴である。フレッシュチーズには、クリームチーズのように軟らかく滑らかな食感を持つものや、パスタフィラータチーズのように弾力性のある食感を目指したものもある。一般的にフレッシュチーズは、原料乳または濃縮乳を加熱殺菌した後、乳酸やクエン酸などの有機酸や乳酸菌、凝乳酵素を添加してカードを生成させることによって製造される。 The consumption of natural cheese in Japan is on the rise. There are more than 2000 types of natural cheese, which are classified according to the fat content and water content in the solid content, the presence or absence of aging, and the presence or absence of the addition of mold. Among them, fresh cheese, which is a non-aged cheese, has a relatively high water content as compared with aged cheese, and is characterized by having a fresh milk aroma and a refreshing acidity. Some fresh cheeses have a soft and smooth texture, such as cream cheese, and some have an elastic texture, such as pasta filata cheese. Generally, fresh cheese is produced by heat-sterilizing raw milk or concentrated milk, and then adding organic acids such as lactic acid and citric acid, lactic acid bacteria, and milk-clotting enzyme to generate curd.
 フレッシュチーズは軟らかな特徴を利用して、パンやクラッカーにぬってそのまま食されるほか、製菓・製パン原料、加工食品原料、プロセスチーズ原料として、二次加工にも多く利用されている。フレッシュチーズの代表的なものには、クリームチーズ、マスカルポーネ、フロマージュブラン、カッテージチーズ、クワルク、パスタフィラータ(モッツァレラチーズ、ブッラータ、カチョカバロチーズ、スカモルツァチーズ、プロバローネチーズ、ストリングチーズ等)等がある。 Utilizing its soft characteristics, fresh cheese is eaten as it is by applying it to bread and crackers, and it is also widely used in secondary processing as a raw material for confectionery / bakery, processed foods, and processed cheese. Typical examples of fresh cheese include cream cheese, mascarpone, fromage blanc, cottage cheese, quark, pasta filata (mozzarella cheese, bullata, cachocabaro cheese, skamorza cheese, provalone cheese, string cheese, etc.).
 近年、フレッシュチーズの食感を改善する観点から、種々の検討が行われている。例えば、硬度と切断面の表面粗さを特定の範囲に設定することにより、適度な硬度と滑らかな食感を有するフレッシュチーズを提供することが報告されている(特許文献1)。 In recent years, various studies have been conducted from the viewpoint of improving the texture of fresh cheese. For example, it has been reported to provide fresh cheese having an appropriate hardness and a smooth texture by setting the hardness and the surface roughness of the cut surface within a specific range (Patent Document 1).
 一方で、フレッシュチーズをはじめとするチーズにおいて、消費者の需要をさらに喚起する観点からは、消費者の嗜好に合わせてフレーバーを改善することも重要な課題である。例えば、制御された量で乳性ミネラルをチーズ作製プロセスに加えると、新鮮な乳製品に特徴的な乳フレーバーノートを有する乳製品が得られることが報告されている(特許文献2)。また、チェダーチーズに含まれる香気成分の同定とその官能性評価を実施することにより、チーズの各種香気成分とチーズの嗜好度との関係についての考察がなされている(非特許文献1)。 On the other hand, in cheese such as fresh cheese, it is also an important issue to improve the flavor according to the taste of consumers from the viewpoint of further stimulating the demand of consumers. For example, it has been reported that adding a controlled amount of milky minerals to the cheese making process yields dairy products with milk flavor notes characteristic of fresh dairy products (Patent Document 2). Further, by identifying the aroma components contained in cheddar cheese and evaluating their sensuality, the relationship between various aroma components of cheese and the degree of preference of cheese has been considered (Non-Patent Document 1).
 一方で、フレッシュチーズにおいて、後味の余韻を向上させる技術的手段は何ら報告されていない。 On the other hand, no technical means for improving the aftertaste of fresh cheese has been reported.
特開2002-253116号公報Japanese Patent Application Laid-Open No. 2002-253116 特開2018-117568号公報Japanese Unexamined Patent Publication No. 2018-117568
 本発明は、上記従来技術の課題点に鑑みてなされたものであり、後味の余韻に優れたフレッシュチーズを提供することを一つの目的とする。 The present invention has been made in view of the above-mentioned problems of the prior art, and one object of the present invention is to provide fresh cheese having an excellent aftertaste.
 本発明者らは、上記課題に鑑み、鋭意研究を重ねた結果、フレッシュチーズにおいて、特定の香気成分の含有量および硬度の比(特定の香気成分の含有量/硬度)と後味の余韻とが相関しており、特定の香気成分の含有量および硬度の比を調整することにより、フレッシュチーズに優れた後味の余韻を付与しうることを見出した。本発明は、かかる知見に基づくものである。 As a result of diligent research in view of the above problems, the present inventors have found that in fresh cheese, the ratio of the content and hardness of a specific aroma component (content / hardness of a specific aroma component) and the aftertaste of aftertaste. They have been correlated and have been found to be able to impart an excellent aftertaste to fresh cheese by adjusting the ratio of content and hardness of specific aroma components. The present invention is based on such findings.
 本発明の一実施態様によれば、以下の[1]~[16]が提供される。
[1]γ-ドデカラクトンおよびz-デイリーラクトンから選択される少なくとも一つの香気成分を含み、該香気成分の含有量と、フレッシュチーズの硬度の比(香気成分の含有量/硬度)が、以下の(i)~(vi)のうち少なくとも一つを満たす、フレッシュチーズ:
 (i)γ-ドデカラクトンの含有量(ppb)/硬度(gf)が0.80ppb/gf以上である、
 (ii)z-デイリーラクトンの含有量(ppb)/硬度(gf)が0.26ppb/gf以上である、
 (iii)2-ヘプタノンおよびγ-ドデカラクトンの合計量(ppb)/硬度(gf)が0.86ppb/gf以上である、
 (iv)2-ヘプタノンおよびz-デイリーラクトンの合計量(ppb)/硬度(gf)が0.33ppb/gf以上である、
 (v)γ-ドデカラクトンおよびz-デイリーラクトンの合計量(ppb)/硬度(gf)が1.06ppb/gf以上である、
 (vi)2-ヘプタノン、γ-ドデカラクトンおよびz-デイリーラクトンの合計量(ppb)/硬度(gf)が1.13ppb/gf以上である。
[2](i)γ-ドデカラクトンの含有量(ppb)/硬度(gf)が1.17ppb/gf以上である、[1]に記載のフレッシュチーズ。
[3](ii)z-デイリーラクトンの含有量(ppb)/硬度(gf)が0.42ppb/gf以上である、[1]または[2]に記載のフレッシュチーズ。
[4](iii)2-ヘプタノンおよびγ-ドデカラクトンの合計量(ppb)/硬度(gf)が1.23ppb/gf以上である、[1]~[3]のいずれかに記載のフレッシュチーズ。
[5](iv)2-ヘプタノンおよびz-デイリーラクトンの合計量(ppb)/硬度(gf)が0.48ppb/gf以上である、[1]~[4]のいずれかに記載のフレッシュチーズ。
[6](v)γ-ドデカラクトンおよびz-デイリーラクトンの合計量(ppb)/硬度(gf)が1.59ppb/gf以上である、請求項1~5のいずれか一項に記載のフレッシュチーズ。
[7](vi)2-ヘプタノン、γ-ドデカラクトンおよびz-デイリーラクトンの合計量(ppb)/硬度(gf)が1.65ppb/gf以上である、[1]~[6]のいずれかに記載のフレッシュチーズ。
[8]上記フレッシュチーズが、パスタフィラータである、[1]~[7]のいずれかに記載のフレッシュチーズ。
[9][1]~[8]のいずれかに記載のフレッシュチーズを含んでなる、包装食品または容器詰食品。
[10]フレッシュチーズの全部または一部が遮光されてなる、[9]に記載の包装食品または容器詰食品。
[11]γ-ドデカラクトンおよびz-デイリーラクトンから選択される少なくとも一つを含む香気成分の含有量とフレッシュチーズの硬度の比(香気成分の含有量/硬度)が、後味の余韻を参照して設定された閾値以上になるように調整する工程を含んでなる、フレッシュチーズの製造方法。
[12]
 (1)上記香気成分を含んでなるカードを準備する工程、および
 (2)上記香気成分の含有量と硬度の比を調整して、前記カードからフレッシュチーズを得る工程
を含んでなる、[11]に記載の方法。
[13]
 γ-ドデカラクトンおよびz-デイリーラクトンから選択される少なくとも一つを含む香気成分の含有量とパスタフィラーの硬度の比(香気成分の含有量/硬度)が、後味の余韻を参照して設定された閾値以上になるように調整する工程を含んでなる、パスタフィラータの製造方法であって、
 カードを準備する工程、カードを混錬する工程および混錬したフレッシュチーズをブラインに浸漬する工程のいずれか1以上の工程で前記香気成分を添加する、パスタフィラータの製造方法。
[14]フレッシュチーズが、[1]~[8]のいずれかに記載されたフレッシュチーズである、[11]~[13]のいずれかに記載の方法。
[15]γ-ドデカラクトンおよびz-デイリーラクトンから選択される少なくとも一つを含む香気成分の含有量とフレッシュチーズの硬度の比(香気成分の含有量/硬度)が、後味の余韻を参照して設定された閾値以上になるように調整する工程を含んでなる、フレッシュチーズにおける後味の余韻の向上方法。
[16]フレッシュチーズが、[1]~[8]のいずれかに記載されたフレッシュチーズである、[15]に記載の方法。
According to one embodiment of the present invention, the following [1] to [16] are provided.
[1] It contains at least one aroma component selected from γ-dodecalactone and z-daily lactone, and the ratio of the content of the aroma component to the hardness of fresh cheese (content / hardness of the aroma component) is as follows. Fresh cheese that satisfies at least one of (i) to (vi):
(I) The content (ppb) / hardness (gf) of γ-dodecalactone is 0.80 ppb / gf or more.
(Ii) The content (ppb) / hardness (gf) of z-daily lactone is 0.26 ppb / gf or more.
(Iii) The total amount (ppb) / hardness (gf) of 2-heptanone and γ-dodecalactone is 0.86 ppb / gf or more.
(Iv) The total amount (ppb) / hardness (gf) of 2-heptanone and z-daily lactone is 0.33 ppb / gf or more.
(V) The total amount (ppb) / hardness (gf) of γ-dodecalactone and z-daily lactone is 1.06 ppb / gf or more.
(Vi) The total amount (ppb) / hardness (gf) of 2-heptanone, γ-dodecalactone and z-daily lactone is 1.13 ppb / gf or more.
[2] (i) The fresh cheese according to [1], wherein the content (ppb) / hardness (gf) of γ-dodecalactone is 1.17 ppb / gf or more.
[3] The fresh cheese according to [1] or [2], wherein the content (ppb) / hardness (gf) of (ii) z-daily lactone is 0.42 ppb / gf or more.
[4] The fresh cheese according to any one of [1] to [3], wherein the total amount (ppb) / hardness (gf) of (iii) 2-heptanone and γ-dodecalactone is 1.23 ppb / gf or more. ..
[5] The fresh cheese according to any one of [1] to [4], wherein the total amount (ppb) / hardness (gf) of (iv) 2-heptanone and z-daily lactone is 0.48 ppb / gf or more. ..
[6] The fresh according to any one of claims 1 to 5, wherein the total amount (ppb) / hardness (gf) of (v) γ-dodecalactone and z-daily lactone is 1.59 ppb / gf or more. cheese.
[7] Any of [1] to [6], wherein the total amount (ppb) / hardness (gf) of (vi) 2-heptanone, γ-dodecalactone and z-daily lactone is 1.65 ppb / gf or more. Fresh cheese listed in.
[8] The fresh cheese according to any one of [1] to [7], wherein the fresh cheese is pasta filata.
[9] A packaged food or a packaged food containing the fresh cheese according to any one of [1] to [8].
[10] The packaged food or the packaged food according to [9], wherein all or part of the fresh cheese is shielded from light.
[11] The ratio of the content of the aroma component containing at least one selected from γ-dodecalactone and z-daily lactone to the hardness of the fresh cheese (content of the aroma component / hardness) refers to the aftertaste. A method for producing fresh cheese, which comprises a step of adjusting so as to be equal to or higher than a set threshold.
[12]
It comprises (1) a step of preparing a card containing the aroma component, and (2) a step of adjusting the ratio of the content of the aroma component to the hardness to obtain fresh cheese from the card [11]. ] The method described in.
[13]
The ratio of the content of the aroma component containing at least one selected from γ-dodecalactone and z-daily lactone to the hardness of the pasta filler (content of aroma component / hardness) is set with reference to the aftertaste. A method for producing pasta filata, which comprises a step of adjusting the pasta filata so as to be equal to or higher than the threshold value.
A method for producing pasta filata, wherein the aroma component is added in any one or more of a step of preparing the curd, a step of kneading the curd, and a step of immersing the kneaded fresh cheese in brine.
[14] The method according to any one of [11] to [13], wherein the fresh cheese is the fresh cheese according to any one of [1] to [8].
[15] The ratio of the content of the aroma component containing at least one selected from γ-dodecalactone and z-daily lactone to the hardness of the fresh cheese (content of the aroma component / hardness) refers to the aftertaste. A method for improving the aftertaste of fresh cheese, which comprises a step of adjusting so as to be equal to or higher than the set threshold value.
[16] The method according to [15], wherein the fresh cheese is the fresh cheese according to any one of [1] to [8].
 本発明によれば、フレッシュチーズに優れた後味の余韻を付与することができる。 According to the present invention, it is possible to give fresh cheese an excellent aftertaste.
γ-ドデカラクトンの含有量と硬度の比(γ-ドデカラクトンの含有量/硬度)と、後味の余韻に関する官能評価結果との相関関係を示すグラフである。It is a graph which shows the correlation between the ratio of the content and hardness of γ-dodecalactone (content / hardness of γ-dodecalactone), and the sensory evaluation result regarding the aftertaste of the aftertaste. z-デイリーラクトンの含有量と硬度の比(z-デイリーラクトンの含有量/硬度)と、後味の余韻に関する官能評価結果との相関関係を示すグラフである。It is a graph which shows the correlation between the ratio of the content and hardness of z-daily lactone (content / hardness of z-daily lactone), and the sensory evaluation result about the aftertaste of the aftertaste. 2-ヘプタノンおよびγ-ドデカラクトンの合計量と硬度の比((2-ヘプタノン+γ-ドデカラクトン)/硬度)と、後味の余韻に関する官能評価結果との相関関係を示すグラフである。It is a graph which shows the correlation between the ratio ((2-heptanone + γ-dodecalactone) / hardness) of the total amount of 2-heptanone and γ-dodecalactone, and the sensory evaluation result about the aftertaste. 2-ヘプタノンおよびz-デイリーラクトンの合計量と硬度の比((2-ヘプタノン+z-デイリーラクトン)/硬度)と、後味の余韻に関する官能評価結果との相関関係を示すグラフである。It is a graph which shows the correlation between the ratio ((2-heptanone + z-daily lactone) / hardness) of the total amount of 2-heptanone and z-daily lactone, and the sensory evaluation result about the aftertaste of the aftertaste. γ-ドデカラクトンおよびz-デイリーラクトンの合計量の合計量と硬度の比((γ-ドデカラクトン+z-デイリーラクトン)/硬度)と、後味の余韻に関する官能評価結果との相関関係を示すグラフである。A graph showing the correlation between the total amount of γ-dodecalactone and z-daily lactone and the ratio of hardness ((γ-dodecalactone + z-daily lactone) / hardness) to the sensory evaluation result regarding the aftertaste. be. 3種の香気成分(2-ヘプタノン、γ-ドデカラクトンおよびz-デイリーラクトン)の合計量と硬度の比(3種の香気成分の合計量/硬度)と、後味の余韻に関する官能評価結果との相関関係を示すグラフである。The ratio of the total amount of the three aroma components (2-heptanone, γ-dodecalactone and z-daily lactone) to the hardness (total amount / hardness of the three aroma components) and the sensory evaluation result regarding the aftertaste. It is a graph which shows the correlation.
発明の具体的説明Specific description of the invention
 本明細書において「フレッシュチーズ」とは例えば、殆ど熟成しないか全く熟成しないナチュラルチーズを意味し、パスタフィラータ(モッツァレラチーズ、ブッラータ、ストリングチーズなど)、クリームチーズ、クワルク、フロマージュブラン、カッテージチーズ、マスカルポーネハルミチーズ、フェタ等が挙げられる。なお、パスタフィラータチーズとは、その製造中において、パスタフィラータ(pasta filata)プロセスを必要とするチーズであり、パスタフィラータプロセスとは、適切なpHで、チーズカードを加熱しながら、大きな塊がなくなるまで捏ね上げて、物性が滑らかになるまで混練や展延することである。 As used herein, the term "fresh cheese" means, for example, natural cheese that is barely or completely aged, such as pasta filata (mozzarella cheese, bullata, string cheese, etc.), cream cheese, quark, fromage blanc, cottage cheese, etc. Mascarpone Harumi cheese, Feta, etc. can be mentioned. The pasta filata cheese is a cheese that requires a pasta filata process during its production, and the pasta filata process is a large cheese curd while heating the cheese curd at an appropriate pH. Knead until there are no lumps, and knead or spread until the physical properties become smooth.
 本発明の一実施態様によれば、γ-ドデカラクトンおよびcis-6-Dodecen-4-olide(z-デイリーラクトンと記載する)から選択される少なくとも一つを含む香気成分の含有量と硬度の比(香気成分の含有量/硬度)が、後味の余韻を参照して設定された閾値以上になるように調整されてなるフレッシュチーズが提供される。 According to one embodiment of the invention, the content and hardness of the aroma component comprising at least one selected from γ-dodecalactone and cis-6-Dodecen-4-lide (denoted as z-daily lactone). A fresh cheese is provided in which the ratio (content / hardness of aroma component) is adjusted to be equal to or higher than a threshold set with reference to the aftertaste of the aftertaste.
 本発明の好ましい実施態様によれば、フレッシュチーズは、以下の(i)~(vi)のうち少なくとも一つを満たすものである。
 (i)γ-ドデカラクトンの含有量(ppb)/硬度(gf)が0.80ppb/gf以上である、
 (ii)z-デイリーラクトンの含有量(ppb)/硬度(gf)でが0.26ppb/gf以上である、
 (iii)2-ヘプタノンおよびγ-ドデカラクトンの合計量(ppb)/硬度(gf)でが0.86ppb/gf以上である、
 (iv)2-ヘプタノンおよびz-デイリーラクトンの合計量(ppb)/硬度(gf)が0.33ppb/gf以上である、
 (v)γ-ドデカラクトンおよびz-デイリーラクトンの合計量(ppb)/硬度(gf)が1.06ppb/gf以上である、
 (vi)2-ヘプタノン、γ-ドデカラクトンおよびz-デイリーラクトンの合計量(ppb)/硬度(gf)が1.13ppb/gf以上である。
 本発明は、如何なる理論にも拘束されるものではないが、上記の(i)~(vi)のうち少なくとも一つを満たすフレッシュチーズが優れた後味の余韻を付与される理由は、フレッシュチーズの硬度が低いほど、フレッシュチーズを食した際に香気成分を感じやすくなるためである、と推察される。このため、例えば、香気成分の含有量が一定である場合、硬度が低いほど優れた後味の余韻を感じやすくなると推察される。
According to a preferred embodiment of the present invention, the fresh cheese satisfies at least one of the following (i) to (vi).
(I) The content (ppb) / hardness (gf) of γ-dodecalactone is 0.80 ppb / gf or more.
(Ii) The content (ppb) / hardness (gf) of z-daily lactone is 0.26 ppb / gf or more.
(Iii) The total amount (ppb) / hardness (gf) of 2-heptanone and γ-dodecalactone is 0.86 ppb / gf or more.
(Iv) The total amount (ppb) / hardness (gf) of 2-heptanone and z-daily lactone is 0.33 ppb / gf or more.
(V) The total amount (ppb) / hardness (gf) of γ-dodecalactone and z-daily lactone is 1.06 ppb / gf or more.
(Vi) The total amount (ppb) / hardness (gf) of 2-heptanone, γ-dodecalactone and z-daily lactone is 1.13 ppb / gf or more.
Although the present invention is not bound by any theory, the reason why fresh cheese satisfying at least one of (i) to (vi) above is given an excellent aftertaste is that of fresh cheese. It is presumed that the lower the hardness, the easier it is to feel the aroma component when eating fresh cheese. Therefore, for example, when the content of the aroma component is constant, it is presumed that the lower the hardness, the easier it is to feel the aftertaste of an excellent aftertaste.
 本発明の好ましい態様によれば、フレッシュチーズは、(vi)を満たしていることが好ましい。 According to the preferred embodiment of the present invention, it is preferable that the fresh cheese satisfies (vi).
 本発明の一実施態様によれば、γ-ドデカラクトンの含有量(ppb)/硬度(gf)の閾値は、通常0.80ppb/gfまたは0.85ppb/gfであり、好ましくは1.17ppb/gfまたは1.21ppb/gfであり、より好ましくは1.54ppb/gfまたは1.57ppb/gfである。また、γ-ドデカラクトンの含有量(ppb)と硬度(gf)の比の上限は、特に限定されないが、例えば、6.4ppb/gfである。 According to one embodiment of the invention, the threshold of γ-dodecalactone content (ppb) / hardness (gf) is usually 0.80 ppb / gf or 0.85 ppb / gf, preferably 1.17 ppb /. It is gf or 1.21 ppb / gf, more preferably 1.54 ppb / gf or 1.57 ppb / gf. The upper limit of the ratio of the content (ppb) of γ-dodecalactone to the hardness (gf) is not particularly limited, but is, for example, 6.4 ppb / gf.
 本発明の一実施態様によれば、z-デイリーラクトンの含有量(ppb)/硬度(gf)の閾値は、通常0.26ppb/gfまたは0.30ppb/gfであり、好ましくは0.42ppb/gfまたは0.44ppb/gfであり、より好ましくは0.57ppb/gfまたは0.58ppb/gfである。また、z-デイリーラクトンの含有量(ppb)と硬度(gf)の比の上限は、特に限定されないが、例えば、2.4ppb/gfである。 According to one embodiment of the invention, the z-daily lactone content (ppb) / hardness (gf) threshold is usually 0.26 ppb / gf or 0.30 ppb / gf, preferably 0.42 ppb /. It is gf or 0.44 ppb / gf, more preferably 0.57 ppb / gf or 0.58 ppb / gf. The upper limit of the ratio of the content (ppb) of the z-daily lactone to the hardness (gf) is not particularly limited, but is, for example, 2.4 ppb / gf.
 本発明の一実施態様によれば、2-ヘプタノンの含有量(ppb)と硬度(gf)の比の閾値(下限)は通常0.053(ppb/gf)または0.055(ppb/gf)であり、好ましくは0.063(ppb/gf)または0.073(ppb/gf)であり、より好ましくは0.077ppb/gfまたは0.093(ppb/gf)である。また、2-ヘプタノンの含有量(ppb)と硬度(gf)の比の上限は、特に限定されないが、例えば、0.31ppb/gfである。 According to one embodiment of the invention, the threshold (lower limit) of the ratio of 2-heptanone content (ppb) to hardness (gf) is usually 0.053 (ppb / gf) or 0.055 (ppb / gf). It is preferably 0.063 (ppb / gf) or 0.073 (ppb / gf), and more preferably 0.077 ppb / gf or 0.093 (ppb / gf). The upper limit of the ratio of the 2-heptanone content (ppb) to the hardness (gf) is not particularly limited, but is, for example, 0.31 ppb / gf.
 本発明の一実施態様によれば、2-ヘプタノンおよびγ-ドデカラクトンの合計量(ppb)/硬度(gf)の閾値は、通常0.85ppb/gfまたは0.93ppb/gfであり、好ましくは1.22ppb/gfまたは1.23ppb/gfであり、より好ましくは1.50ppb/gfまたは1.61ppb/gfである。また、2-ヘプタノンおよびγ-ドデカラクトンの合計量(ppb)/硬度(gf)の上限は、特に限定されないが、例えば、6.0ppb/gfである。 According to one embodiment of the invention, the threshold for the total amount (ppb) / hardness (gf) of 2-heptanone and γ-dodecalactone is usually 0.85 ppb / gf or 0.93 ppb / gf, preferably 0.93 ppb / gf. It is 1.22 ppb / gf or 1.23 ppb / gf, more preferably 1.50 ppb / gf or 1.61 ppb / gf. The upper limit of the total amount (ppb) / hardness (gf) of 2-heptanone and γ-dodecalactone is not particularly limited, but is, for example, 6.0 ppb / gf.
 本発明の一実施態様によれば、2-ヘプタノンおよびz-デイリーラクトンの合計量(ppb)/硬度(gf)の閾値は、通常0.33ppb/gfまたは0.35ppb/gfであり、好ましくは0.48ppb/gfまたは0.50ppb/gfであり、より好ましくは0.63ppb/gfまたは0.64ppb/gfである。また、2-ヘプタノンおよびz-デイリーラクトンの合計量(ppb)/硬度(gf)の上限は、特に限定されないが、例えば、2.0ppb/gfである。 According to one embodiment of the invention, the threshold of total amount (ppb) / hardness (gf) of 2-heptanone and z-daily lactone is usually 0.33 ppb / gf or 0.35 ppb / gf, preferably 0.35 ppb / gf. It is 0.48 ppb / gf or 0.50 ppb / gf, more preferably 0.63 ppb / gf or 0.64 ppb / gf. The upper limit of the total amount (ppb) / hardness (gf) of 2-heptanone and z-daily lactone is not particularly limited, but is, for example, 2.0 ppb / gf.
 本発明の一実施態様によれば、γ-ドデカラクトンおよびz-デイリーラクトンの合計量(ppb)/硬度(gf)の閾値は、通常1.06ppb/gfまたは1.15ppb/gfであり、好ましくは1.59ppb/gfまたは1.65ppb/gfであり、より好ましくは2.16ppb/gfである。また、2-ヘプタノンおよびz-デイリーラクトンの合計量(ppb)/硬度(gf)の上限は、特に限定されないが、例えば、8.7ppb/gfである。 According to one embodiment of the present invention, the threshold of total amount (ppb) / hardness (gf) of γ-dodecalactone and z-daily lactone is usually 1.06 ppb / gf or 1.15 ppb / gf, which is preferable. Is 1.59 ppb / gf or 1.65 ppb / gf, more preferably 2.16 ppb / gf. The upper limit of the total amount (ppb) / hardness (gf) of 2-heptanone and z-daily lactone is not particularly limited, but is, for example, 8.7 ppb / gf.
 本発明の一実施態様によれば、2-ヘプタノン、γ-ドデカラクトンおよびz-デイリーラクトンの合計量(ppb)/硬度(gf)の上記閾値は、通常1.13ppb/gfまたは1.21ppb/gfであり、好ましくは1.65ppb/gfまたは1.71ppb/gfであり、より好ましくは2.18ppb/gfまたは2.22ppb/gfである。また、2-ヘプタノン、γ-ドデカラクトンおよびz-デイリーラクトンの合計量(ppb)/硬度(gf)の上限は、特に限定されないが、例えば、8.8ppb/gfである。 According to one embodiment of the invention, the above threshold of total amount (ppb) / hardness (gf) of 2-heptanone, γ-dodecalactone and z-daily lactone is usually 1.13 ppb / gf or 1.21 ppb /. It is gf, preferably 1.65 ppb / gf or 1.71 ppb / gf, and more preferably 2.18 ppb / gf or 2.22 ppb / gf. The upper limit of the total amount (ppb) / hardness (gf) of 2-heptanone, γ-dodecalactone and z-daily lactone is not particularly limited, but is, for example, 8.8 ppb / gf.
 フレッシュチーズにおける各香気成分の含有量は、GS-MS分析を用いて測定することができる。測定条件の詳細は、後述する試験例2に準じて実施することができる。具体的には、鼻腔に残る後味の余韻を評価するため、香気成分の測定方法として、好ましくは、試料(フレッシュチーズ)をアセトンで抽出してからダイナミックヘッドスペースガスクロマトグラフ(DHS)法で分析することが好ましい。 The content of each aroma component in fresh cheese can be measured using GS-MS analysis. The details of the measurement conditions can be carried out according to Test Example 2 described later. Specifically, in order to evaluate the aftertaste remaining in the nasal cavity, as a method for measuring the aroma component, preferably, a sample (fresh cheese) is extracted with acetone and then analyzed by a dynamic headspace gas chromatograph (DHS) method. Is preferable.
 フレッシュチーズにおいて、2-ヘプタノンの含有量は、通常5~260ppbであり、好ましくは10~250ppbであり、より好ましくは15~200ppbである。 In fresh cheese, the content of 2-heptanone is usually 5 to 260 ppb, preferably 10 to 250 ppb, and more preferably 15 to 200 ppb.
 フレッシュチーズにおいて、γ-ドデカラクトンの含有量は、通常150~2600ppbであり、好ましくは200~2500ppbであり、より好ましくは220~2000ppbである。 In fresh cheese, the content of γ-dodecalactone is usually 150 to 2600 ppb, preferably 200 to 2500 ppb, and more preferably 220 to 2000 ppb.
 フレッシュチーズにおいて、z-デイリーラクトンの含有量は、通常50~2600ppbであり、好ましくは60~2500ppbであり、より好ましくは70~2000ppbである。 In fresh cheese, the content of z-daily lactone is usually 50 to 2600 ppb, preferably 60 to 2500 ppb, and more preferably 70 to 2000 ppb.
 フレッシュチーズにおいて、2-ヘプタノン、γ-ドデカラクトンおよびz-デイリーラクトンの合計量は、通常205~5460ppbであり、好ましくは270~5250ppbであり、より好ましくは305~4600ppbである。 In fresh cheese, the total amount of 2-heptanone, γ-dodecalactone and z-daily lactone is usually 205-5460 ppb, preferably 270-5250 ppb, more preferably 305-4600 ppb.
 また、フレッシュチーズの硬度は、1辺2cmの立方体に切り出したフレッシュチーズを表面が乾燥しないようにラップで包み、10℃にて2時間静置して調温した後、円柱型プランジャー(φ10×H50)を用いて1.0mm/secにてサンプル厚さに対して75%圧縮したときの最大試験力として測定することができる。測定条件のさらなる詳細は、後述する試験例2に準じて実施することができる。 For the hardness of fresh cheese, wrap the fresh cheese in a cube with a side of 2 cm in a wrap so that the surface does not dry, leave it at 10 ° C for 2 hours to adjust the temperature, and then adjust the temperature, and then use a cylindrical plunger (φ10). It can be measured as the maximum test force when compressed by 75% with respect to the sample thickness at 1.0 mm / sec using × H50). Further details of the measurement conditions can be carried out according to Test Example 2 described later.
 フレッシュチーズの硬度は、特に限定されないが、通常50~3000gfであり、好ましくは65~2800gfであり、より好ましくは80~2500gfである。 The hardness of the fresh cheese is not particularly limited, but is usually 50 to 3000 gf, preferably 65 to 2800 gf, and more preferably 80 to 2500 gf.
 また、フレッシュチーズの水分含有量、脂肪含有量、および固形分中の脂肪含有量(FDM)は、特に限定されず、所望のフレッシュチーズの種類および性質に応じて適宜設定することができる。 Further, the water content, the fat content, and the fat content (FDM) in the solid content of the fresh cheese are not particularly limited and can be appropriately set according to the type and properties of the desired fresh cheese.
 フレッシュチーズの水分含有量は、通常30~82質量%であり、好ましくは35~80質量%であり、より好ましくは40~70質量%である。
 なお、フレッシュチーズがパスタフィラータの場合、水分含有量は、好ましくは40~60質量%であり、より好ましくは42~55質量%である。パスタフィラーであるフレッシュチーズの水分含有量が上記の範囲内であることにより、微生物学的観点や繊維性の維持の観点から品質が良好なものとなる。なお、他の成分が同一で製法、発酵期間が同一であれば、水分含有量が高まるほど硬度が低下する傾向にある。
The water content of fresh cheese is usually 30 to 82% by mass, preferably 35 to 80% by mass, and more preferably 40 to 70% by mass.
When the fresh cheese is pasta filata, the water content is preferably 40 to 60% by mass, more preferably 42 to 55% by mass. When the water content of fresh cheese, which is a pasta filler, is within the above range, the quality is good from the viewpoint of microbiological viewpoint and maintenance of fibrousness. If the other components are the same and the production method and fermentation period are the same, the hardness tends to decrease as the water content increases.
 フレッシュチーズの脂肪含有量は、通常0~45質量%であり、好ましくは3~40質量%であり、より好ましくは15~35質量%である。 The fat content of fresh cheese is usually 0 to 45% by mass, preferably 3 to 40% by mass, and more preferably 15 to 35% by mass.
 フレッシュチーズのFDM含有量は、通常0~85質量%であり、好ましくは18~80質量%であり、より好ましくは20~75質量%である。フレッシュチーズの製法、発酵期間が同一であれば、FDMが高まるほど硬度が低下する傾向にある。 The FDM content of fresh cheese is usually 0 to 85% by mass, preferably 18 to 80% by mass, and more preferably 20 to 75% by mass. If the method of producing fresh cheese and the fermentation period are the same, the hardness tends to decrease as the FDM increases.
 本発明の一つの実施態様によれば、フレッシュチーズは、香気成分と硬度との比を所望の範囲に調整して、後味の余韻が付与されたものである。フレッシュチーズの後味の余韻は、後述する試験例3の官能評価に準じて判定することができる。好ましい態様によれば、フレッシュチーズの後味の余韻は、乳由来する単なるミルク風味の増強やミルク風味の厚みだけでなく、フレッシュチーズを摂取して咀嚼してから感じる、鼻腔に残るクリーム風味の余韻とされる。 According to one embodiment of the present invention, fresh cheese is obtained by adjusting the ratio of aroma component and hardness to a desired range to give a lingering aftertaste. The aftertaste of fresh cheese can be determined according to the sensory evaluation of Test Example 3 described later. According to a preferred embodiment, the aftertaste of fresh cheese is not only the enhancement of milk flavor derived from milk and the thickness of milk flavor, but also the cream-flavored aftertaste that remains in the nasal cavity after ingesting and chewing fresh cheese. It is said that.
 また、フレッシュチーズは包装形態または容器詰めの形態にすることができる。したがって、本発明の一つの態様によれば、本発明の一つの態様によれば、上記フレッシュチーズを含んでなる、包装食品または容器詰食品が提供される。また、フレッシュチーズに用いられる包装および容器はそれぞれ、香気成分の揮発や分解を抑制する観点からは、フレッシュチーズの全部(全表面)または一部が遮光されるものであることが好ましい。一部遮光の場合、フレッシュチーズの半面が遮光されていることがより好ましい。包装および容器は、形状に制限がない。包装および容器としては、例えば、プラスチック容器、ソフトバック、スタンディングタイプのソフトバック、缶、ビン等が挙げられる。包装および容器の材質は、一部または全部に遮光性があることが好ましく、例えば、アルミ箔、アルミ蒸着フィルム、紙等を積層したフィルム、缶、褐色瓶やUVカットのプラスチック等の材質を用いることにより、チーズや保存液の光劣化や酸化を抑制し、チーズの後味の余韻をより顕著に発揮させることができる。 Also, fresh cheese can be in the form of packaging or containerization. Therefore, according to one aspect of the present invention, according to one aspect of the present invention, a packaged food or a packaged food containing the fresh cheese is provided. Further, from the viewpoint of suppressing volatilization and decomposition of aroma components, the packaging and the container used for the fresh cheese are preferably those in which all (the entire surface) or a part of the fresh cheese is shielded from light. In the case of partial shading, it is more preferable that one side of the fresh cheese is shaded. Packaging and containers are not restricted in shape. Examples of packaging and containers include plastic containers, soft bags, standing type soft bags, cans, bottles and the like. The material of the packaging and the container is preferably partially or wholly light-shielding, and for example, a material such as aluminum foil, an aluminum vapor-deposited film, a film laminated with paper, a can, a brown bottle, or UV-cut plastic is used. As a result, it is possible to suppress photodeterioration and oxidation of the cheese and the preservative solution, and to make the aftertaste of the cheese more remarkable.
 本発明の一つの実施態様によれば、フレッシュチーズは、上記香気成分と硬度の比を指標として予め設定した上記閾値以上となるように、各製造工程の条件を当業者が適宜調整して製造することができる。したがって、本発明の好ましい態様によれば、γ-ドデカラクトンおよびz-デイリーラクトンから選択される少なくとも一つを含む香気成分の含有量と、フレッシュチーズの硬度の比(香気成分の含有量/硬度)が、後味の余韻を参照して設定された閾値以上になるように調整する工程を含んでなる、フレッシュチーズの製造方法が提供される。より好ましい態様によれば、上記フレッシュチーズは、上記(i)~(vi)のうち少なくとも一つを満たすものとされる。 According to one embodiment of the present invention, fresh cheese is manufactured by a person skilled in the art by appropriately adjusting the conditions of each manufacturing process so that the ratio of the aroma component and the hardness becomes equal to or higher than the preset threshold value. can do. Therefore, according to a preferred embodiment of the present invention, the ratio of the content of the aroma component containing at least one selected from γ-dodecalactone and z-daily lactone to the hardness of the fresh cheese (content of aroma component / hardness). ) Provided is a method for producing fresh cheese, which comprises a step of adjusting the aftertaste so as to be equal to or higher than a set threshold value with reference to the aftertaste. According to a more preferred embodiment, the fresh cheese satisfies at least one of the above (i) to (vi).
 また、本発明のより具体的な態様によれば、上記フレッシュチーズの製造方法は、
 (1)上記香気成分を含んでなるカードを準備する工程、および
 (2)上記香気成分の含有量と硬度の比を調整して、上記カードから上記フレッシュチーズを得る工程を含んでなる。
Further, according to a more specific aspect of the present invention, the method for producing fresh cheese is:
It includes (1) a step of preparing a card containing the above-mentioned aroma component, and (2) a step of adjusting the ratio of the content of the above-mentioned aroma component to the hardness to obtain the above-mentioned fresh cheese from the above-mentioned card.
 なお、好ましい態様によれば、上記(1)の工程は、
 上記香気成分を含む香料を添加する工程
を含んでなる。
According to the preferred embodiment, the step (1) is described in the above step.
It includes a step of adding a fragrance containing the above-mentioned aroma component.
 また、好ましい態様によれば、上記(2)の工程は、
 上記香気成分の揮発または分解の抑制される環境管理下において、
 チーズを軟化させ、かつ/または
 フレッシュチーズを発酵させる工程
を含んでなる。
Further, according to a preferred embodiment, the step (2) is described in the above step.
Under environmental control where volatilization or decomposition of the above aroma components is suppressed
It comprises the steps of softening the cheese and / or fermenting the fresh cheese.
 好ましい態様によれば、上記(2)の工程は、
 硬度を調整するために、フレッシュチーズの脂肪含有量、FDM、最終水分含有量を調整する工程を含んでなる。
According to a preferred embodiment, the step (2) above is
In order to adjust the hardness, it comprises a step of adjusting the fat content, FDM and final water content of fresh cheese.
 以下、上記フレッシュチーズの製造方法の具体的一例を説明する。本発明の実施態様によれば、以下に記載の各製造条件を適宜組み合わせることにより、γ-ドデカラクトンおよびz-デイリーラクトンから選択される少なくとも一つを含む香気成分の含有量と、フレッシュチーズの硬度の比(香気成分の含有量/硬度)を所望の範囲に調整することができる。 Hereinafter, a specific example of the above-mentioned method for producing fresh cheese will be described. According to an embodiment of the present invention, by appropriately combining each of the production conditions described below, the content of an aroma component containing at least one selected from γ-dodecalactone and z-daily lactone, and the content of the aroma component of fresh cheese. The hardness ratio (content of aroma component / hardness) can be adjusted to a desired range.
 上記フレッシュチーズの製造においては、まず、生乳、部分脱脂乳、濃縮乳、クリーム等を用いて標準化を行い、標準化乳を殺菌し、冷却して得られる仕込み乳に有機酸および乳酸菌スターターを添加し、混合しながら攪拌する。次に、得られた混合物にレンネットを添加し、保持し、凝固させる。次に、凝固物をカッティングして攪拌しながらホエイを排出し、さらに調温攪拌する。次に、カードとホエイを分離し、圧縮してホエイを除き至適pHになったことを確認してカードを得た。なお、カードは凍結してもよい。 In the production of the above fresh cheese, first, standardization is performed using raw milk, partially defatted milk, concentrated milk, cream, etc., the standardized milk is sterilized, and an organic acid and a lactic acid bacterium starter are added to the prepared milk obtained by cooling. , Stir while mixing. Rennet is then added to the resulting mixture, retained and coagulated. Next, the coagulated product is cut and the whey is discharged while stirring, and the temperature is further controlled and stirred. Next, the card and whey were separated and compressed to remove the whey, and the pH was confirmed to be the optimum pH, and the card was obtained. The card may be frozen.
 カードの凍結のための冷凍方法は、一般的なカードの冷凍方法に準じるものの、その中でも特に急速冷凍方法が好ましい。凍結したカードの保管温度は-20℃以下であり、より好ましくは-50℃以下、より長期間保存する場合は好ましくは-80℃以下である。本発明では、市販の凍結カードを解凍して、その一部または全部を用いてもよい。 The freezing method for freezing the card is the same as the general freezing method for the card, but the quick freezing method is particularly preferable. The storage temperature of the frozen card is −20 ° C. or lower, more preferably −50 ° C. or lower, and preferably −80 ° C. or lower when stored for a longer period of time. In the present invention, a commercially available frozen card may be thawed and a part or all thereof may be used.
 フレッシュチーズの製造において用いられる上記乳酸菌スターターは、フレッシュチーズで使用することができる乳酸菌であればよく、その属および種は任意であり、例えば、ラクチス菌、クレモリス菌、ブルガリア菌、サーモフィラス菌などの公知の乳酸菌を挙げることができる。上記乳酸菌スターターは、好ましくは、ラクチス菌、ブルガリア菌、サーモフィラス菌である。上記有機酸による添加の場合、乳酸、酢酸、クエン酸などの有機酸、リン酸などの無機酸をはじめとして、食品および/または食品添加物において使用されている公知の酸を原料乳に直接添加することもできる。 The lactic acid bacterium starter used in the production of fresh cheese may be any lactic acid bacterium that can be used in fresh cheese, and its genus and species are arbitrary, and for example, Lactobacillus, Cremoris, Bulgaria, Thermophilus, etc. Known lactic acid bacteria can be mentioned. The lactic acid bacterium starter is preferably Lactobacillus, Bulgaria, or Thermophilus. In the case of addition with the above organic acid, known acids used in foods and / or food additives are directly added to raw milk, including organic acids such as lactic acid, acetic acid and citric acid, and inorganic acids such as phosphoric acid. You can also do it.
 次に、パスタフィラータは、生成したカードおよび/または解凍したカードを加熱し、ストレッチング、適宜延伸して成形を行い、冷却してフレッシュチーズを得る。冷却後にフレッシュチーズは、静置し、熟成(発酵)させてもよい。また、フレッシュチーズは、静置前または後において、所望により包装しまたは容器に収容してもよい。 Next, the pasta filata heats the produced curd and / or thawed curd, stretches it, stretches it appropriately, forms it, and cools it to obtain fresh cheese. After cooling, the fresh cheese may be allowed to stand and aged (fermented). In addition, fresh cheese may be packaged or contained in a container, if desired, before or after standing.
 上記フレッシュチーズの製造において、フレッシュチーズの香気成分や硬度は、原料乳の成分を調整することによって多様に調整することができる。原料乳とは、未殺菌の生乳のことをいい、牛乳、羊乳、山羊乳などの生乳を使用可能であるが、好ましくは牛乳である。また、原料乳は、γ-ドデカラクトンおよびz-デイリーラクトンや、2-ヘプタノン等の香気成分を高容量で含有する原料乳を使用することが好ましい。また、最終的な所望のフレッシュチーズの硬度を勘案して、それに適した、脂肪含有量、FDMやその割合を有する原料乳を使用することが好ましい。好適な原料乳としては、例えば、北海道産の原料乳、より好ましくは北海道十勝産等が挙げられる。例えば、北海道産の原料乳、北海道十勝産を60%以上使用することなどが好ましい。 In the production of the above fresh cheese, the aroma component and hardness of the fresh cheese can be variously adjusted by adjusting the components of the raw milk. Raw milk refers to unsterilized raw milk, and raw milk such as milk, sheep milk, and goat milk can be used, but milk is preferable. Further, as the raw material milk, it is preferable to use the raw material milk containing a high volume of aroma components such as γ-dodecalactone, z-daily lactone and 2-heptanone. Further, in consideration of the hardness of the final desired fresh cheese, it is preferable to use raw milk having a fat content, FDM and its ratio suitable for the hardness. Examples of suitable raw milk include raw milk produced in Hokkaido, and more preferably Tokachi, Hokkaido. For example, it is preferable to use 60% or more of raw milk from Hokkaido and Tokachi, Hokkaido.
 なお、上記フレッシュチーズ(例えば、パスタフィラータ)の製造において、γ-ドデカラクトンおよびz-デイリーラクトンや、2-ヘプタノン等が含まれる市販香料を添加することで、フレッシュチーズの香気成分を調整することもできる。香料を添加するタイミングは問わないが、原料乳に添加する工程、カードを準備する工程、カードを混錬する工程およびフレッシュチーズブラインに浸漬する工程の1つ以上の工程で実施することが好ましく、香料の損失を考慮すると好ましくは常温になったカードを準備する工程、混錬工程中である。 In the production of the above fresh cheese (for example, pasta filata), the aroma component of the fresh cheese is adjusted by adding a commercially available flavor containing γ-dodecalactone, z-daily lactone, 2-heptanone and the like. You can also do it. The timing of adding the flavor is not limited, but it is preferable to carry out in one or more steps of adding to the raw milk, preparing the curd, kneading the curd and immersing in fresh cheese brine. Considering the loss of fragrance, it is preferably in the process of preparing a card that has reached room temperature and the kneading process.
 さらに、フレッシュチーズにミルク感を増すために、カードやフレッシュチーズ中のラクトン類などが増加するように調整してもよいし、カードやフレッシュチーズにラクトン類などを添加してもよい。 Further, in order to increase the milky feeling of the fresh cheese, the lactones and the like in the curd and fresh cheese may be adjusted to increase, or the lactones and the like may be added to the curd and fresh cheese.
 また、仕込み乳の製造においては、各種フレッシュチーズの最終的な香気成分含有量、硬度、種類、性質に応じて、その組成を調整することができる。例えば、クリームセパレーターなどを用いて、未殺菌の生乳から脱脂乳やクリームを分離した後、これら脱脂乳およびクリームを所定の混合比率で仕込み乳中に配合して乳脂肪の含有量を調整することができる。また、仕込み乳の製造においては、全脂乳、部分脱脂乳、脱脂乳、粉乳、クリームも原料として使用可能であり、さらに、加熱濃縮、遠心濃縮、ろ過膜濃縮、真空濃縮、凍結濃縮等によって濃縮した濃縮乳も使用可能である。 Further, in the production of prepared milk, the composition can be adjusted according to the final aroma component content, hardness, type and properties of various fresh cheeses. For example, after separating skim milk or cream from unsterilized raw milk using a cream separator or the like, these skim milk and cream are prepared in a predetermined mixing ratio and blended into the milk to adjust the milk fat content. Can be done. In addition, in the production of prepared milk, full fat milk, partially skim milk, skim milk, milk powder, and cream can also be used as raw materials, and further, by heat concentration, centrifugal concentration, filter membrane concentration, vacuum concentration, freeze concentration, etc. Concentrated milk can also be used.
 また、各種フレッシュチーズの最終的な香気成分含有量、硬度、種類、性質に応じて、仕込み乳の標準化を実施して標準化乳を得ることが好ましい。 In addition, it is preferable to standardize the prepared milk according to the final aroma component content, hardness, type, and properties of various fresh cheeses to obtain standardized milk.
 標準化乳の殺菌工程においては、各種フレッシュチーズの最終的な香気成分含有量、硬度、種類、性質に応じて加熱条件を設定してもよい。加熱条件は、例えば、約60℃で30分間、または約72~75℃で達温した後15秒間加熱殺菌(HTST殺菌)してもよい。 In the sterilization process of standardized milk, heating conditions may be set according to the final aroma component content, hardness, type, and properties of various fresh cheeses. The heating conditions may be, for example, heat sterilization (HTST sterilization) at about 60 ° C. for 30 minutes, or after reaching a temperature of about 72 to 75 ° C. for 15 seconds.
 加熱殺菌工程後は、例えば、プレート式熱交換器等で速やかに約40℃まで冷却してもよい。 After the heat sterilization step, for example, it may be quickly cooled to about 40 ° C. with a plate heat exchanger or the like.
 また、標準化乳のpHおよびpH変化速度は、各種フレッシュチーズの最終的な硬度を勘案して、設定することができる。標準化乳のpHは、例えば、5~6.5程度としてもよい。 In addition, the pH of standardized milk and the rate of change in pH can be set in consideration of the final hardness of various fresh cheeses. The pH of the standardized milk may be, for example, about 5 to 6.5.
 また、カードの調製に使用されるレンネットの量は、各種フレッシュチーズの最終的な硬度を勘案して、設定することができる。また、レンネットの添加量は20~40分程度で凝乳させるのに必要な量とする。レンネットの量は、標準化乳に対して、例えば、10~300ppmであってもよいし、10~100ppmであってもよい。 Also, the amount of rennet used to prepare the curd can be set in consideration of the final hardness of various fresh cheeses. The amount of rennet added is the amount required for curdling in about 20 to 40 minutes. The amount of rennet may be, for example, 10 to 300 ppm or 10 to 100 ppm with respect to the standardized milk.
 レンネットを添加した後、凝固物のカードメイキング時のカッティングサイズは、最終的なフレッシュチーズの硬度を勘案して選択することができる。 After adding rennet, the cutting size of the coagulated product during card making can be selected in consideration of the hardness of the final fresh cheese.
 また、カードの加熱方法は、各種フレッシュチーズの最終的な香気成分含有量、硬度、種類、性質に応じて適宜選択することができる。カードの加熱方法としては、例えば、チーズカードを70~80℃の熱水につける方法、水蒸気を使用する方法、ジュール加熱やマイクロウェーブにより加熱する方法等が挙げられる。香気成分や乳成分の減少を抑制する観点からは、加熱方法としては、水蒸気を使用する方法、ジュール加熱やマイクロウェーブが好ましい。また、上記加熱方法は、フレッシュチーズがパスタフィラータの場合に特に好適に使用することができる。 In addition, the heating method of the curd can be appropriately selected according to the final aroma component content, hardness, type, and properties of various fresh cheeses. Examples of the method for heating the curd include a method of immersing the cheese curd in hot water at 70 to 80 ° C., a method of using steam, a method of heating by Joule heating or microwave. From the viewpoint of suppressing the decrease of aroma components and milk components, the method using steam, Joule heating or microwave is preferable as the heating method. Further, the above heating method can be particularly preferably used when the fresh cheese is pasta filata.
 また、酸性化して凝乳したカード等に対し、安定剤および/またはクリームを添加してもよい。添加工程は、攪拌混合、脂肪球分散処理工程の前後どちらで行ってもよい。また、安定剤とクリームを両方添加する場合は、安定剤をクリームに添加してからカードに添加してもよい。この場合、安定剤を添加したクリームを均質処理することによって、安定剤がよく分散されることになる。添加工程で添加する安定剤としては、カルボキシメチルセルロース、アルギン酸塩、ローカストビーンガム、タラガム、グアーガム、キサンタンガム、ジェランガム、ペクチン等の増粘多糖類やゼラチンを使用することが可能であり、また、セルロース、難消化性デキストリン等の食物繊維を使用すること、また両者を併せて使用することも可能である。カード中の上記安定剤の含有量は、好ましくは5質量%以下である。 Further, a stabilizer and / or a cream may be added to the acidified and curd curd or the like. The addition step may be performed before or after the stirring and mixing step or the fat globules dispersion treatment step. When both the stabilizer and the cream are added, the stabilizer may be added to the cream and then added to the curd. In this case, the stabilizer is well dispersed by homogenizing the cream to which the stabilizer is added. As the stabilizer added in the addition step, thickening polysaccharides such as carboxymethyl cellulose, alginate, locust bean gum, tara gum, guar gum, xanthan gum, gellan gum, and pectin, and gelatin can be used, and cellulose, It is also possible to use dietary fiber such as indigestible dextrin, or to use both in combination. The content of the stabilizer in the card is preferably 5% by mass or less.
 上記方法により得られるカードは、最終的な所望のフレッシュチーズを製造する観点から、z-デイリーラクトン、γ-ドデカラクトンのうち少なくとも一つを含んでなる香気成分を高容量で含有していることが好ましい。また、カードは2-ヘプタノンをさらに含んでなることが好ましい。 The curd obtained by the above method contains a high amount of aroma component containing at least one of z-daily lactone and γ-dodecalactone from the viewpoint of producing the final desired fresh cheese. Is preferable. Also, the card preferably further comprises 2-heptanone.
 カードにおいて、γ-ドデカラクトンの含有量は、通常150~15000ppbであり、好ましくは200~10000ppbであり、より好ましくは220~8000ppbである。 In the card, the content of γ-dodecalactone is usually 150 to 15000 ppb, preferably 200 to 10000 ppb, and more preferably 220 to 8000 ppb.
 カードにおいて、z-デイリーラクトンの含有量は、通常50~7000ppbであり、好ましくは60~6000ppbであり、より好ましくは80~5000ppbである。 In the card, the content of z-daily lactone is usually 50 to 7000 ppb, preferably 60 to 6000 ppb, and more preferably 80 to 5000 ppb.
 カードにおいて、2-ヘプタノンの含有量は、通常5~500ppbであり、好ましくは10~400ppbであり、より好ましくは5~300ppbである。 In the card, the content of 2-heptanone is usually 5 to 500 ppb, preferably 10 to 400 ppb, and more preferably 5 to 300 ppb.
 カードにおいて、2-ヘプタノン、γ-ドデカラクトンおよびz-デイリーラクトンの合計量は、通常205~22500ppbであり、好ましくは270~16400ppbであり、より好ましくは305~8800ppbである。 In the card, the total amount of 2-heptanone, γ-dodecalactone and z-daily lactone is usually 205 to 22,500 ppb, preferably 270 to 16400 ppb, more preferably 305 to 8800 ppb.
 上記構成成分を含有するカードは、生乳から調製してもよいが、予め製造された凍結カードを解凍して使用してもよく、生乳から調製したカードと凍結カードを解凍したカードを適宜混合して使用してもよい。カードの調製は、香気成分の含有量(2-ヘプタノン含有量、γ-ドデカラクトン含有量、z-デイリーラクトン含有量等)が所望の範囲になるように確認して実施することが好ましい。 The card containing the above components may be prepared from raw milk, or may be used by thawing a pre-manufactured frozen card, and a card prepared from raw milk and a card obtained by thawing a frozen card may be appropriately mixed. May be used. It is preferable to prepare the curd after confirming that the content of the aroma component (2-heptanone content, γ-dodecalactone content, z-daily lactone content, etc.) is within a desired range.
 フレッシュチーズの製造における乳化や混錬は、乳化機、混錬機などを用いればよく、乳化機では、例えば、ケトル型、2軸スクリューをもつクッカー型、サーモシリンダー型等の乳化機を使用できる。混錬機では、例えば、2軸エクストルーダーを用いると、上記の加熱とストレッチングを同時に行うことができる。 For emulsification and kneading in the production of fresh cheese, an emulsifying machine, a kneading machine, or the like may be used. .. In the kneader, for example, by using a twin-screw extruder, the above heating and stretching can be performed at the same time.
 フレッシュチーズの成形方法は、各種チーズの種類、所望の硬度に応じて適宜選択することができる。例えば、ブッラータでは、ストレッチングしてから成形する工程において、クリームを加えて漏れないように成形した後、冷却して容器に充填することが好ましい。また、ストリングチーズでは、パスタフィラータのストレッチング工程を経た後、延伸して成形したのち、切断・冷却して、ブラインに浸漬し、その後容器に充填することが好ましい。特に、パスタフィラータの場合、カードから調製されるチーズの硬度は混練することによっても調整することができる。 The method for forming fresh cheese can be appropriately selected according to the type of various cheeses and the desired hardness. For example, in Burrata, in the step of stretching and then molding, it is preferable to add cream to form the burrata so as not to leak, and then cool and fill the container. Further, for string cheese, it is preferable that after undergoing a stretching step of pasta filata, it is stretched and molded, cut and cooled, immersed in brine, and then filled in a container. In particular, in the case of pasta filata, the hardness of cheese prepared from curd can also be adjusted by kneading.
 また、フレッシュチーズは、製造後、適宜静置してもよい。フレッシュチーズの静置は、発酵により香気成分を増加させる観点から好ましい。静置温度としては、特に限定されないが、例えば、-80~10℃、好ましくは、-50~8℃、より好ましくは-40~6℃である。モッツァレラは好ましくは1~10℃、最も好ましくは2~6℃である。また、静置期間としては、例えば、7~120日間、10~90日間、好ましくは15~60日間である。 In addition, fresh cheese may be allowed to stand as appropriate after production. The standing of fresh cheese is preferable from the viewpoint of increasing the aroma component by fermentation. The standing temperature is not particularly limited, but is, for example, −80 to 10 ° C., preferably −50 to 8 ° C., and more preferably −40 to 6 ° C. Mozzarella is preferably 1-10 ° C, most preferably 2-6 ° C. The standing period is, for example, 7 to 120 days, 10 to 90 days, preferably 15 to 60 days.
 また、フレッシュチーズを容器に充填する際の条件は、フレッシュチーズの種類および性質に応じて、所望の範囲に設定することができる。例えば、モッツァレラでは、カードがストレッチング(混練)後に成形されて製造されるが、成形後に冷却して、保存液の入った容器にフレッシュチーズを充填してもよいし、容器中に殺菌水または保存液に充填してもよい。このとき、フレッシュチーズ表面のぬめりを抑制する観点から、0.1~2.0重量%の塩化ナトリウムを含有してもよい。保存液に塩化カルシウムを添加する場合には、2水和物換算で0.05~0.25質量%の塩化カルシウムも添加することが好ましい。さらに、微生物汚染を防ぐ観点から保存液にナイシンや酢酸ナトリウム等の保存料を含有してもよい。保存液のpHは任意に定められるが、例えばpH4~7と定めることができる。保存液のpHは、直食する場合にはpH5~7が好ましい。ミルク感を付与するために保存液に0.5~2質量%ホエイを添加してもよい。 Further, the conditions for filling the container with fresh cheese can be set in a desired range according to the type and properties of the fresh cheese. For example, in mozzarella, the curd is molded and manufactured after stretching (kneading), but it may be cooled after molding and filled with fresh cheese in a container containing a preservative solution, or sterilized water or sterilized water in the container. It may be filled in a preservation solution. At this time, from the viewpoint of suppressing the sliminess of the surface of fresh cheese, 0.1 to 2.0% by weight of sodium chloride may be contained. When calcium chloride is added to the preservation solution, it is preferable to add 0.05 to 0.25% by mass of calcium chloride in terms of dihydrate. Further, from the viewpoint of preventing microbial contamination, the preservative solution may contain a preservative such as nisin or sodium acetate. The pH of the storage solution is arbitrarily determined, but can be, for example, pH 4 to 7. The pH of the storage solution is preferably pH 5 to 7 when eating directly. 0.5-2% by weight whey may be added to the preservative to give a milky feel.
 フレッシュチーズのpHは通常、4~7であるが、所望とするチーズの性質に応じて適宜pHを設定することもできる。モッツァレラなどパスタフィラータでは、繊維性の維持、保存性、直食時の風味の良好さからpH5.0~6.3とすることが好ましい。同じ製法や組成の場合、pHが高いほど硬度が低い傾向にある、 The pH of fresh cheese is usually 4 to 7, but the pH can be appropriately set according to the desired properties of cheese. For pasta filata such as mozzarella, the pH is preferably 5.0 to 6.3 from the viewpoint of maintaining fibrousness, preservability, and good flavor at the time of direct eating. In the case of the same manufacturing method and composition, the higher the pH, the lower the hardness tends to be.
 なお、上記製造工程中に、2-ヘプタノン、γ-ドデカラクトンおよびz-デイリーラクトンから選択される香気成分を適宜添加してもよく、本発明にはかかる態様も包含される。 It should be noted that an aroma component selected from 2-heptanone, γ-dodecalactone and z-daily lactone may be appropriately added during the above production process, and the present invention also includes such an embodiment.
 また、本発明の別の態様によれば、γ-ドデカラクトンおよびz-デイリーラクトンから選択される少なくとも一つを含んでなる香気成分の含有量と硬度の比(香気成分の含有量/硬度)が、後味の余韻を参照して設定された閾値以上になるように調整する工程を含んでなる、フレッシュチーズにおける後味の余韻の向上方法が提供される。好ましい態様によれば、フレッシュチーズの製造方法は、上記(i)~(vi)のうち少なくとも一つを満たすものとされる。
 フレッシュチーズにおける後味の余韻の向上方法は、上記フレッシュチーズおよびその製造方法に準じて実施することができる。
Further, according to another aspect of the present invention, the ratio of the content and hardness of the aroma component containing at least one selected from γ-dodecalactone and z-daily lactone (content of aroma component / hardness). However, there is provided a method for improving the aftertaste of fresh cheese, which comprises a step of adjusting the aftertaste to be equal to or higher than a set threshold value with reference to the aftertaste. According to a preferred embodiment, the method for producing fresh cheese satisfies at least one of the above (i) to (vi).
The method for improving the aftertaste of fresh cheese can be carried out according to the above-mentioned fresh cheese and the method for producing the same.
 以下に本発明の好ましい態様を記載する。
 態様1.γ-ドデカラクトンおよびz-デイリーラクトンから選択される少なくとも一つの香気成分を含み、該香気成分の含有量とフレッシュモッツァレラチーズの硬度の比(香気成分の含有量/硬度)が、以下の(i)~(vi)のうち少なくとも一つを満たす、フレッシュモッツァレラチーズ:
 (i)γ-ドデカラクトンの含有量(ppb)/硬度(gf)が0.80ppb/gf以上、好ましくは1.17ppb/gf以上、より好ましくは1.54ppb/gf以上、例えば1.54ppb/gf以上2.50ppb/gf以下である、
 (ii)z-デイリーラクトンの含有量(ppb)/硬度(gf)が0.26ppb/gf以上、好ましくは0.42ppb/gf以上、より好ましくは0.57ppb/gf以上、例えば0.57ppb/gf以上0.95ppb/gf以下である、
 (iii)2-ヘプタノンおよびγ-ドデカラクトンの合計量(ppb)/硬度(gf)が0.86ppb/gf以上、好ましくは1.23ppb/gf以上、より好ましくは1.61ppb/gf以上、例えば1.61ppb/gf以上2.55ppb/gf以下である、
 (iv)2-ヘプタノンおよびz-デイリーラクトンの合計量(ppb)/硬度(gf)が0.33ppb/gf以上、好ましくは0.48ppb/gf以上、より好ましくは0.63ppb/gf以上、例えば0.63ppb/gf以上1.01ppb/gf以下である、
 (v)γ-ドデカラクトンおよびz-デイリーラクトンの合計量(ppb)/硬度(gf)が1.06ppb/gf以上、好ましくは1.58ppb/gf以上、より好ましくは2.16ppb/gf以上、例えば2.16ppb/gf以上3.40ppb/gf以下である、
 (vi)2-ヘプタノン、γ-ドデカラクトンおよびz-デイリーラクトンの合計量(ppb)/硬度(gf)が1.13ppb/gf以上、好ましくは1.65ppb/gf以上、より好ましくは2.18ppb/gf以上、例えば2.18ppb/gf以上3.50ppb/gf以下である。
 態様2.態様1に記載のフレッシュモッツァレラチーズを含んでなる、包装食品または容器詰食品。
 態様3.フレッシュモッツァレラチーズの全部または一部が遮光されてなる、態様2に記載の包装食品または容器詰食品。
 態様4.γ-ドデカラクトンおよびz-デイリーラクトンから選択される少なくとも一つを含む香気成分の含有量とフレッシュモッツァレラチーズの硬度の比(香気成分の含有量/硬度)が、後味の余韻を参照して設定された閾値以上になるように調整する工程を含んでなる、フレッシュモッツァレラチーズの製造方法。
 態様5.(1)前記香気成分を含んでなるカードを準備する工程、および
 (2)前記香気成分の含有量と硬度の比を調整して、前記カードからフレッシュモッツァレラチーズを得る工程
を含んでなる、態様4に記載の方法。
 態様6.γ-ドデカラクトンおよびz-デイリーラクトンから選択される少なくとも一つを含む香気成分の含有量とフレッシュモッツァレラチーズの硬度の比(香気成分の含有量/硬度)が、後味の余韻を参照して設定された閾値以上になるように調整する工程を含んでなる、フレッシュモッツァレラチーズの製造方法であって、
 カードを準備する工程、カードを混錬する工程および混錬したフレッシュモッツァレラチーズをブラインに浸漬する工程のいずれか1以上の工程で前記香気成分を添加する、フレッシュモッツァレラチーズの製造方法。
 態様7.γ-ドデカラクトンおよびz-デイリーラクトンから選択される少なくとも一つを含む香気成分の含有量とフレッシュモッツァレラチーズの硬度の比(香気成分の含有量/硬度)が、後味の余韻を参照して設定された閾値以上になるように調整する工程を含んでなる、フレッシュモッツァレラチーズにおける後味の余韻の向上方法。
Hereinafter, preferred embodiments of the present invention will be described.
Aspect 1. It contains at least one aroma component selected from γ-dodecalactone and z-daily lactone, and the ratio of the content of the aroma component to the hardness of fresh mozzarella cheese (content of aroma component / hardness) is as follows (i). )-(Vi), fresh mozzarella cheese:
(I) The content (ppb) / hardness (gf) of γ-dodecalactone is 0.80 ppb / gf or more, preferably 1.17 ppb / gf or more, more preferably 1.54 ppb / gf or more, for example 1.54 ppb /. Gf or more and 2.50 ppb / gf or less,
(Ii) The content (ppb) / hardness (gf) of z-daily lactone is 0.26 ppb / gf or more, preferably 0.42 ppb / gf or more, more preferably 0.57 ppb / gf or more, for example 0.57 ppb /. Gf or more and 0.95 ppb / gf or less,
(Iii) The total amount (ppb) / hardness (gf) of 2-heptanone and γ-dodecalactone is 0.86 ppb / gf or more, preferably 1.23 ppb / gf or more, more preferably 1.61 ppb / gf or more, for example. 1.61 ppb / gf or more and 2.55 ppb / gf or less,
(Iv) The total amount (ppb) / hardness (gf) of 2-heptanone and z-daily lactone is 0.33 ppb / gf or more, preferably 0.48 ppb / gf or more, more preferably 0.63 ppb / gf or more, for example. 0.63 ppb / gf or more and 1.01 ppb / gf or less,
(V) The total amount (ppb) / hardness (gf) of γ-dodecalactone and z-daily lactone is 1.06 ppb / gf or more, preferably 1.58 ppb / gf or more, more preferably 2.16 ppb / gf or more. For example, 2.16 ppb / gf or more and 3.40 ppb / gf or less.
(Vi) The total amount (ppb) / hardness (gf) of 2-heptanone, γ-dodecalactone and z-daily lactone is 1.13 ppb / gf or more, preferably 1.65 ppb / gf or more, more preferably 2.18 ppb. It is / gf or more, for example, 2.18 ppb / gf or more and 3.50 ppb / gf or less.
Aspect 2. A packaged food or a packaged food containing the fresh mozzarella cheese according to the first aspect.
Aspect 3. The packaged food or packaged food according to aspect 2, wherein all or part of the fresh mozzarella cheese is shielded from light.
Aspect 4. The ratio of the content of the aroma component containing at least one selected from γ-dodecalactone and z-daily lactone to the hardness of the fresh mozzarella cheese (content of aroma component / hardness) is set with reference to the aftertaste. A method for producing fresh mozzarella cheese, which comprises a step of adjusting so as to be equal to or higher than the specified threshold.
Aspect 5. An embodiment comprising (1) a step of preparing a card containing the aroma component, and (2) a step of adjusting the ratio of the content of the aroma component to the hardness to obtain fresh mozzarella cheese from the card. The method according to 4.
Aspect 6. The ratio of the content of the aroma component containing at least one selected from γ-dodecalactone and z-daily lactone to the hardness of the fresh mozzarella cheese (content of aroma component / hardness) is set with reference to the aftertaste. A method for producing fresh mozzarella cheese, which comprises a step of adjusting so as to be equal to or higher than the specified threshold.
A method for producing fresh mozzarella cheese, wherein the aroma component is added in any one or more steps of preparing a card, kneading the card, and immersing the kneaded fresh mozzarella cheese in brine.
Aspect 7. The ratio of the content of the aroma component containing at least one selected from γ-dodecalactone and z-daily lactone to the hardness of the fresh mozzarella cheese (content of aroma component / hardness) is set with reference to the aftertaste. A method for improving the aftertaste of fresh mozzarella cheese, which comprises a step of adjusting the amount to be equal to or higher than the specified threshold.
 以下、本発明に関して実施例を挙げて説明するが、本発明は、これにより限定されるものではない。なお、特段の記載のない限り、本明細書に記載の測定方法および単位は日本工業規格(JIS)の規定に従う。また、特段の記載のない限り、「%」は「質量%」を意味する。 Hereinafter, the present invention will be described with reference to examples, but the present invention is not limited thereto. Unless otherwise specified, the measurement methods and units described in this specification are in accordance with the provisions of the Japanese Industrial Standards (JIS). Unless otherwise specified, "%" means "mass%".
試験例1:フレッシュチーズの製造
[試験区1]
 牛由来の生乳(栃木産)、脱脂乳、クリームを用いて標準化乳を得て、殺菌(75℃達温)して36℃に冷却して得られた仕込み乳に10%乳酸を滴下しpHを6.2にした。pHが6.2になった時点で、凍結乳酸菌スターター(クリスチャンハンセン社)を所定量添加して混合しながら、インキュベーター内で20分間攪拌した。さらに、得られた混合物にレンネット(クリスチャンハンセン社)を50ppm添加し、保持して凝固させ、1cm角にカッティングして緩やかに攪拌した。36℃にしながら30分間攪拌した後カードとホエイを分離した。その後、40℃恒温室でマチュレーションしポンプで圧縮してホエイを除きFDM52%、pH5.2のチーズカードを得た。
Test Example 1: Production of fresh cheese [Test group 1]
Standardized milk is obtained using raw milk derived from cows (produced in Tochigi), skim milk, and cream, sterilized (heated to 75 ° C), cooled to 36 ° C, and 10% lactic acid is added dropwise to the prepared milk. Was set to 6.2. When the pH reached 6.2, a predetermined amount of a frozen lactic acid bacterium starter (Christian Hansen) was added and mixed, and the mixture was stirred in an incubator for 20 minutes. Further, 50 ppm of rennet (Christian Hansen) was added to the obtained mixture, and the mixture was held and solidified, cut into 1 cm squares, and gently stirred. After stirring for 30 minutes at 36 ° C., the curd and whey were separated. Then, it was maturated in a constant temperature room at 40 ° C. and compressed with a pump to remove whey, and a cheese curd having FDM 52% and pH 5.2 was obtained.
 次に、カードを熱水で、75℃に加熱しストレッチングを行った後冷却しながら球状に成形した。
 得られたフレッシュチーズを4℃恒温室に27日間静置した。得られたフレッシュチーズにおいて、水分含有量62%、脂肪含有量20.5%、FDM54%であった。
Next, the curd was heated to 75 ° C. with hot water, stretched, and then cooled to form a spherical shape.
The obtained fresh cheese was allowed to stand in a constant temperature room at 4 ° C. for 27 days. In the obtained fresh cheese, the water content was 62%, the fat content was 20.5%, and the FDM was 54%.
[試験区2]
 試験区1と同様に操作し、チーズカードを熱水で、75℃に加熱しストレッチングを行った後冷却しながら球状にしてフレッシュチーズを得た。
 得られたフレッシュチーズを4℃恒温室に36日間静置した。
 得られたフレッシュチーズにおいて、水分含有量60%、脂肪含有量21.6%、FDM54%であった。
[Test Zone 2]
The same operation as in Test Group 1 was carried out, and the cheese curd was heated to 75 ° C. with hot water, stretched, and then cooled to form a spherical shape to obtain fresh cheese.
The obtained fresh cheese was allowed to stand in a constant temperature room at 4 ° C. for 36 days.
In the obtained fresh cheese, the water content was 60%, the fat content was 21.6%, and the FDM was 54%.
[試験区3]
 牛由来の生乳(北海道十勝産)、脱脂乳、クリームを用いて標準化乳からカードを得て蒸気でストレッチングした以外は試験区1と同様の操作により得られるフレッシュチーズを取得し、製造後36日静置した。
 得られたフレッシュチーズにおいて、水分含有量60%、脂肪含有量21.6%、FDM54%であった。
[試験区4]
 牛由来の生乳(北海道十勝産)脱脂乳、クリームを用いて標準化乳からカードを得て蒸気でストレッチングした以外は試験区1と同様の操作により得られるフレッシュチーズを取得し、製造後9日静置した。
 得られたフレッシュチーズにおいて、水分含有量60%、脂肪含有量18.4%、FDM46%であった。
[試験区5]
 牛由来の生乳(栃木県産)、脱脂乳、クリームを用いて標準化乳からカードを得て、2-ヘプタノン(東京化成工業株式会社製)、γ-ドデカラクトン(長谷香川香料株式会社製)、z-デイリーラクトン(長谷香川香料株式会社製)をそれぞれ4ppm、200ppm、50ppmとなるように添加し、チーズカードを熱水でストレッチングした以外は試験区1と同様の操作により得られるフレッシュチーズを取得し、製造後9日静置した。
 得られたフレッシュチーズにおいて、水分含有量67%、脂肪含有量13.9%、FDM42%であった。
[Test Zone 3]
Fresh cheese obtained by the same operation as in Test Group 1 was obtained except that raw milk derived from cows (produced in Tokachi, Hokkaido), skim milk, and cream were used to obtain curd from standardized milk and stretched with steam. I left it for a day.
In the obtained fresh cheese, the water content was 60%, the fat content was 21.6%, and the FDM was 54%.
[Test Zone 4]
Raw milk derived from cows (produced in Tokachi, Hokkaido) Fresh cheese obtained by the same operation as in Test Group 1 except that the curd was obtained from standardized milk using skim milk and cream and stretched with steam, and 9 days after production. It was left still.
In the obtained fresh cheese, the water content was 60%, the fat content was 18.4%, and the FDM was 46%.
[Test Zone 5]
Obtain a card from standardized milk using raw milk derived from cows (produced in Tochigi prefecture), skim milk, and cream, 2-heptanone (manufactured by Tokyo Kasei Kogyo Co., Ltd.), γ-dodecalactone (manufactured by Hase Kagawa Fragrance Co., Ltd.), Fresh cheese obtained by the same operation as in Test Group 1 except that z-daily lactone (manufactured by Hase Kagawa Fragrance Co., Ltd.) was added to 4 ppm, 200 ppm, and 50 ppm, respectively, and the cheese curd was stretched with hot water. It was obtained and allowed to stand for 9 days after production.
In the obtained fresh cheese, the water content was 67%, the fat content was 13.9%, and the FDM was 42%.
試験例2:フレッシュチーズの分析
 以下の条件に従い、試験例1で得られたフレッシュチーズの硬度測定および香気分析を行った。
 硬度測定
 硬度は以下の通り測定した。測定は4回行い、その平均値を求めた。
(1)1辺2cmの立方体に切り出したフレッシュチーズを表面が乾燥しないようにラップで包み、10℃2時間静置して調温して測定サンプルを得た。
(2)Ez Test(島津製作所)を用い、下記の条件でサンプルの硬度を測定した(N=4)。具体的には、Ez testに硬さ測定用治具(樹脂製円柱型プランジャー(φ10×H50))をサンプルに取り付け、サンプル温度10℃にて、歪率をサンプル厚さに対して75%、測定速度を1.0mm/secに設定し最大試験力(硬度)を測定した。
Test Example 2: Analysis of fresh cheese According to the following conditions, the hardness of the fresh cheese obtained in Test Example 1 was measured and the aroma was analyzed.
Hardness measurement The hardness was measured as follows. The measurement was performed four times, and the average value was calculated.
(1) Fresh cheese cut into a cube having a side of 2 cm was wrapped in a wrap so that the surface did not dry, and allowed to stand at 10 ° C. for 2 hours to adjust the temperature to obtain a measurement sample.
(2) Using Ez Test (Shimadzu Corporation), the hardness of the sample was measured under the following conditions (N = 4). Specifically, a hardness measuring jig (resin columnar plunger (φ10 × H50)) is attached to the Ez test, and the strain rate is 75% of the sample thickness at a sample temperature of 10 ° C. , The measurement speed was set to 1.0 mm / sec, and the maximum test force (hardness) was measured.
 香気分析
 50ml遠沈管に密閉した容器内で均質化フレッシュチーズ2gを採取し、アセトン8mlとIS(cyclooctanol 10ppm100μL)を添加し、振とう機(株式会社スギヤマゲン)にて50rpm15分間攪拌した。4℃で2,000rpm 10分間遠心分離した後、約7mlを2gの無水硫酸ナトリウムで脱水し、200μlを10mlバイアル瓶に採集した。
Aroma analysis 2 g of homogenized fresh cheese was collected in a container sealed with a 50 ml centrifuge tube, 8 ml of acetone and IS (cyclooctanol 10 ppm 100 μL) were added, and the mixture was stirred with a shaker (Sugiamagen Co., Ltd.) for 15 minutes at 50 rpm. After centrifugation at 2,000 rpm for 10 minutes at 4 ° C., about 7 ml was dehydrated with 2 g of anhydrous sodium sulfate, and 200 μl was collected in a 10 ml vial.
 次に、香気成分捕集は、オートサンプラMPS2(GERSTEL社)を使用し、Full Evaporation DHS法を実施した。具体的には、40℃にて流量100ml/分で5分、80℃にて流量100ml/分で20分窒素パージを行い、バイアル瓶中の試料香気成分を捕集剤TenaxTAに吸着させた。TenaxTAの加熱脱着はTDUを使用した。 Next, for the collection of aroma components, the Full Evaporation DHS method was carried out using the autosampler MPS2 (GRESTEL). Specifically, nitrogen purging was performed at 40 ° C. at a flow rate of 100 ml / min for 5 minutes and at 80 ° C. at a flow rate of 100 ml / min for 20 minutes, and the sample aroma component in the vial was adsorbed on the collector TenaxTA. TDU was used for thermal desorption of TenaxTA.
 GS-MS分析はAgilent GC7890A、MS5975C(アジレント・テクノロジー社)を使用し、カラムはDB-WAXUI(0.25mm×0.25μm×30M)(アジレント・テクノロジー社)を用いた。GC-MSの分析条件としては、40℃で2.5分間保持した後、毎分15℃ずつ150℃まで昇温、さらに毎分5℃ずつ240℃まで昇温させ、10分間保持した。この条件下で、2-ヘプタノン、γ-ドデカラクトン、z-デイリーラクトンの含有量を測定した。 Agilent GC789A and MS5975C (Agilent Technologies) were used for GS-MS analysis, and DB-WAXUI (0.25 mm × 0.25 μm × 30M) (Agilent Technologies) was used as the column. As the analysis conditions for GC-MS, after holding at 40 ° C. for 2.5 minutes, the temperature was raised to 150 ° C. at 15 ° C. per minute, further raised to 240 ° C. at 5 ° C. per minute, and held for 10 minutes. Under these conditions, the contents of 2-heptanone, γ-dodecalactone, and z-daily lactone were measured.
 結果は、表1に示される通りであった。
Figure JPOXMLDOC01-appb-T000001
The results were as shown in Table 1.
Figure JPOXMLDOC01-appb-T000001
試験例3:官能評価
 試験例1で得られたフレッシュチーズについて、10名の訓練されたパネルにより、以下のスコアを基準として、「後味の余韻」を5段階で評価し平均点を算出した。
 なお、10名のパネルのそれぞれは、チーズについての専門知識を有し、1か月に2回以上、チーズの官能評価を実施しているパネルである。10名のパネルのうち、8名は10年以上の官能評価の経験を有し、1名は7年の官能評価の経験、1名は4年の官能評価の経験を有していた。
Test Example 3: Sensory evaluation With respect to the fresh cheese obtained in Test Example 1, the "aftertaste" was evaluated on a five-point scale using a trained panel of 10 people based on the following scores, and an average score was calculated.
Each of the 10 panels has specialized knowledge about cheese and conducts sensory evaluation of cheese at least twice a month. Of the 10 panels, 8 had more than 10 years of sensory evaluation experience, 1 had 7 years of sensory evaluation experience, and 1 had 4 years of sensory evaluation experience.
スコア
 1点:非常に短い
 2点:短い
 3点:やや長い
 4点:長い
 5点:非常に長い
Score 1 point: Very short 2 points: Short 3 points: Slightly long 4 points: Long 5 points: Very long
Figure JPOXMLDOC01-appb-T000002
Figure JPOXMLDOC01-appb-T000002
試験例4:相関分析
 試験例1の香気成分の量と硬度の比(香気成分の量/硬度:ppb/gf)と、試験例3の官能評価結果との間の相関係数を計算することによる相関分析を実施した。
Test Example 4: Correlation analysis To calculate the correlation coefficient between the ratio of the amount of aroma component to the hardness of Test Example 1 (amount of aroma component / hardness: ppb / gf) and the sensory evaluation result of Test Example 3. Correlation analysis was performed by.
 結果は、以下の表3~8に示される通りであった。 The results are as shown in Tables 3-8 below.
1種の香気成分についてγ-ドデカラクトン
 γ-ドデカラクトンの含有量と硬度の比(ppb/gf)と、試験例4の官能評価結果との関係は、表3に示される通りであった。
Figure JPOXMLDOC01-appb-T000003
The relationship between the ratio of the content of γ -dodecalactone γ-dodecalactone to the hardness (ppb / gf) and the sensory evaluation result of Test Example 4 for one aroma component was as shown in Table 3.
Figure JPOXMLDOC01-appb-T000003
 また、γ-ドデカラクトンの含有量と硬度の比と、試験例3の官能評価結果との相関関係は、図1に示される通りであった。
 γ-ドデカラクトンの含有量(ppb)/硬度(gf)と、後味の余韻には相関があることが確認された。特に、0.80ppb/gf以上のとき、例えば0.85ppb/gf以上のとき、鼻腔にクリーム風味の余韻が残るフレッシュチーズとなり、1.17ppb/gf以上のとき、例えば1.21ppb/gf以上のとき、より長く鼻腔にクリーム風味の余韻が残るフレッシュチーズ(スコア3.5)となり、1.54ppb/gf以上のとき、例えば1.57ppb/gf以上のとき、より一層長く鼻腔にクリーム風味の余韻が残るフレッシュチーズ(スコア4以上)となることが確認された。
The correlation between the ratio of the content of γ-dodecalactone and the hardness and the sensory evaluation result of Test Example 3 was as shown in FIG.
It was confirmed that there is a correlation between the content (ppb) / hardness (gf) of γ-dodecalactone and the aftertaste. In particular, when it is 0.80 ppb / gf or more, for example, when it is 0.85 ppb / gf or more, it becomes a fresh cheese with a creamy aftertaste in the nasal cavity, and when it is 1.17 ppb / gf or more, for example, 1.21 ppb / gf or more. When it becomes fresh cheese (score 3.5) with a cream-flavored finish remaining in the nasal cavity for a longer period of time, when it is 1.54 ppb / gf or higher, for example, 1.57 ppb / gf or higher, the cream-flavored finish is longer in the nasal cavity. It was confirmed that the remaining fresh cheese (score 4 or higher).
z-デイリーラクトン
 z-デイリーラクトンの含有量と硬度の比(ppb/gf)と、試験例4の官能評価結果との関係は、表4に示される通りであった。
Figure JPOXMLDOC01-appb-T000004
z-Daily Lactone The relationship between the content of z-daily lactone and the hardness ratio (ppb / gf) and the sensory evaluation result of Test Example 4 is as shown in Table 4.
Figure JPOXMLDOC01-appb-T000004
 また、z-デイリーラクトンの含有量と硬度の比と、試験例3の官能評価結果との相関係数は、図2に示される通りであった。
 z-デイリーラクトンの含有量(ppb)/硬度(gf)と、後味の余韻には相関があることが確認された。特に、0.26ppb/gf以上のとき、例えば0.30ppb/gf以上のとき、鼻腔にクリーム風味の余韻が残るフレッシュチーズとなり、0.42ppb/gf以上のとき、例えば0.44ppb/gf以上のとき、より長く鼻腔にクリーム風味の余韻が残るフレッシュチーズ(スコア3.5)となり、0.57ppb/gf以上のとき、例えば0.58ppb/gf以上のとき、より一層長く鼻腔にクリーム風味の余韻が残るフレッシュチーズ(スコア4以上)となることが確認された。
The correlation coefficient between the ratio of the content of z-daily lactone and the hardness and the sensory evaluation result of Test Example 3 was as shown in FIG.
It was confirmed that there is a correlation between the content (ppb) / hardness (gf) of z-daily lactone and the aftertaste. In particular, when it is 0.26 ppb / gf or more, for example, when it is 0.30 ppb / gf or more, it becomes a fresh cheese with a creamy aftertaste in the nasal cavity, and when it is 0.42 ppb / gf or more, for example, 0.44 ppb / gf or more. When it becomes fresh cheese (score 3.5) with a cream-flavored finish remaining in the nasal cavity for a longer period of time, when it is 0.57 ppb / gf or higher, for example, 0.58 ppb / gf or higher, the cream-flavored finish is longer in the nasal cavity. It was confirmed that the remaining fresh cheese (score 4 or higher).
2種の香気成分の組み合わせについて
2-ヘプタノンおよびγ-ドデカラクトン
 2-ヘプタノンおよびγ-ドデカラクトンの合計量(2-ヘプタノン+γ-ドデカラクトン)と硬度の比(ppb/gf)と、試験例4の官能評価結果との関係は、表5に示される通りであった。
About the combination of two kinds of aroma components
2-Heptanone and γ-dodecalactone What is the relationship between the total amount of 2-heptanone and γ-dodecalactone (2-heptanone + γ-dodecalactone) and the hardness ratio (ppb / gf) and the sensory evaluation result of Test Example 4? , As shown in Table 5.
Figure JPOXMLDOC01-appb-T000005
Figure JPOXMLDOC01-appb-T000005
 また、2-ヘプタノンおよびγ-ドデカラクトンの合計量と硬度の比(香気成分の量/硬度:ppb/gf)と、試験例3の官能評価結果との相関係数は、図3に示される通りであった。
 2-ヘプタノンおよびγ-ドデカラクトンの合計量(ppb)/硬度(gf)と、後味の余韻には相関があることが確認された。特に、0.85ppb/gf以上のとき、例えば0.93ppb/gf以上のとき、鼻腔にクリーム風味の余韻が残るフレッシュチーズとなり、1.22ppb/gf以上のとき、例えば1.23ppb/gf以上のとき、より長く鼻腔にクリーム風味の余韻が残るフレッシュチーズ(スコア3.5)となり、1.50ppb/gf以上のとき、例えば1.61ppb/gf以上のとき、より一層長く鼻腔にクリーム風味の余韻が残るフレッシュチーズ(スコア4以上)となることが確認された。
Further, the correlation coefficient between the ratio of the total amount of 2-heptanone and γ-dodecalactone to the hardness (amount of aroma component / hardness: ppb / gf) and the sensory evaluation result of Test Example 3 is shown in FIG. It was a street.
It was confirmed that there was a correlation between the total amount (ppb) / hardness (gf) of 2-heptanone and γ-dodecalactone and the aftertaste. In particular, when it is 0.85 ppb / gf or more, for example, when it is 0.93 ppb / gf or more, it becomes a fresh cheese with a creamy aftertaste in the nasal cavity, and when it is 1.22 ppb / gf or more, for example, 1.23 ppb / gf or more. When it becomes fresh cheese (score 3.5) with a cream-flavored finish remaining in the nasal cavity for a longer period of time, when it is 1.50 ppb / gf or higher, for example, 1.61 ppb / gf or higher, the cream-flavored finish is longer in the nasal cavity. It was confirmed that the remaining fresh cheese (score 4 or higher).
2-ヘプタノンおよびz-デイリーラクトン
 2-ヘプタノンおよびz-デイリーラクトンの合計量(2-ヘプタノン+z-デイリーラクトン)と硬度の比(ppb/gf)と、試験例4の官能評価結果との関係は、表6に示される通りであった。
2-Heptanone and z-Daily Lactone What is the relationship between the total amount of 2-heptanone and z-daily lactone (2-heptanone + z-daily lactone) and the hardness ratio (ppb / gf) and the sensory evaluation result of Test Example 4? , As shown in Table 6.
Figure JPOXMLDOC01-appb-T000006
Figure JPOXMLDOC01-appb-T000006
 また、2-ヘプタノンおよびz-デイリーラクトンの合計量と硬度の比と、試験例3の官能評価結果との相関係数は、図4に示される通りであった。
 2-ヘプタノンおよびz-デイリーラクトンの合計量(ppb)/硬度(gf)と、後味の余韻には相関があることが確認された。特に、0.33ppb/gf以上のとき、例えば0.35ppb/gf以上のとき、鼻腔にクリーム風味の余韻が残るフレッシュチーズとなり、0.48ppb/gf以上のとき、例えば0.50ppb/gf以上のとき、より長く鼻腔にクリーム風味の余韻が残るフレッシュチーズとなり、0.63ppb/gf以上のとき、例えば0.64ppb/gf以上のとき、より一層長く鼻腔にクリーム風味の余韻が残るフレッシュチーズとなることが確認された。
The correlation coefficient between the total amount of 2-heptanone and z-daily lactone and the hardness ratio and the sensory evaluation result of Test Example 3 was as shown in FIG.
It was confirmed that there was a correlation between the total amount (ppb) / hardness (gf) of 2-heptanone and z-daily lactone and the aftertaste. In particular, when it is 0.33 ppb / gf or more, for example, when it is 0.35 ppb / gf or more, it becomes a fresh cheese with a creamy aftertaste in the nasal cavity, and when it is 0.48 ppb / gf or more, for example, 0.50 ppb / gf or more. When it becomes a fresh cheese with a cream-flavored finish remaining in the nasal cavity for a longer time, when it is 0.63 ppb / gf or more, for example, when it is 0.64 ppb / gf or more, it becomes a fresh cheese with a cream-flavored finish remaining in the nasal cavity for a longer time. It was confirmed that.
γ-ドデカラクトンおよびz-デイリーラクトン
 γ-ドデカラクトンおよびz-デイリーラクトンの合計量(γ-ドデカラクトン+z-デイリーラクトン)と硬度の比(ppb/gf)と、試験例4の官能評価結果との関係は、表7に示される通りであった。
Figure JPOXMLDOC01-appb-T000007
Gamma-dodecalactone and z -daily lactone The ratio of the total amount of γ-dodecalactone and z-daily lactone (γ-dodecalactone + z-daily lactone) to hardness (ppb / gf), and the sensory evaluation results of Test Example 4 The relationship was as shown in Table 7.
Figure JPOXMLDOC01-appb-T000007
 また、γ-ドデカラクトンおよびz-デイリーラクトンの合計量と硬度の比と、試験例3の官能評価結果との相関係数は、図5に示される通りであった。
 γ-ドデカラクトンおよびz-デイリーラクトンの合計量(ppb)/硬度(gf)と、後味の余韻には相関があることが確認された。特に、1.06ppb/gf以上のとき、例えば1.15ppb/gf以上のとき、鼻腔にクリーム風味の余韻が残るフレッシュチーズとなり、1.59ppb/gf以上のとき、例えば1.65ppb/gf以上のとき、より長く鼻腔にクリーム風味の余韻が残るフレッシュチーズ(スコア3.5)となり、2.16ppb/gf以上のとき、より一層長く鼻腔にクリーム風味の余韻が残るフレッシュチーズ(スコア4以上)となることが確認された。
The correlation coefficient between the ratio of the total amount of γ-dodecalactone and z-daily lactone to the hardness and the sensory evaluation result of Test Example 3 was as shown in FIG.
It was confirmed that there is a correlation between the total amount (ppb) / hardness (gf) of γ-dodecalactone and z-daily lactone and the aftertaste. In particular, when it is 1.06 ppb / gf or more, for example, when it is 1.15 ppb / gf or more, it becomes a fresh cheese with a creamy aftertaste in the nasal cavity, and when it is 1.59 ppb / gf or more, for example, 1.65 ppb / gf or more. When the cheese has a creamy finish in the nasal cavity for a longer time (score 3.5), and when it is 2.16 ppb / gf or higher, the fresh cheese has a creamy finish in the nasal cavity for a longer time (score 4 or higher). It was confirmed that it would be.
3種の香気成分の組み合わせについて
 3種の香気成分(2-ヘプタノン、γ-ドデカラクトンおよびz-デイリーラクトン)の合計量と硬度の比(ppb/gf)と、試験例4の官能評価結果との関係は、表8に示される通りであった。
Figure JPOXMLDOC01-appb-T000008
About the combination of 3 kinds of aroma components The ratio (ppb / gf) of the total amount of 3 kinds of aroma components (2-heptanone, γ-dodecalactone and z-daily lactone) to the hardness, and the sensory evaluation result of Test Example 4 The relationship was as shown in Table 8.
Figure JPOXMLDOC01-appb-T000008
 また、3種の香気成分の合計量と硬度の比と、試験例3の官能評価結果との相関係数は、図6に示される通りであった。
 3種の香気成分の合計量(ppb)/硬度(gf)と、後味の余韻には相関があることが確認された。特に、1.13ppb/gf以上のとき、例えば1.21ppb/gf以上のとき、鼻腔にクリーム風味の余韻が残るフレッシュチーズとなり、1.65ppb/gf以上のとき、例えば1.71ppb/gf以上のとき、より長く鼻腔にクリーム風味の余韻が残るフレッシュチーズ(スコア3.5)となり、2.18ppb/gf以上のとき、例えば2.22ppb/gf以上のとき、より一層長く鼻腔にクリーム風味の余韻が残るフレッシュチーズ(スコア4以上)となることが確認された。
The correlation coefficient between the total amount of the three aroma components and the hardness ratio and the sensory evaluation result of Test Example 3 was as shown in FIG.
It was confirmed that there is a correlation between the total amount (ppb) / hardness (gf) of the three aroma components and the aftertaste. In particular, when it is 1.13 ppb / gf or more, for example, when it is 1.21 ppb / gf or more, it becomes a fresh cheese with a creamy aftertaste in the nasal cavity, and when it is 1.65 ppb / gf or more, for example, 1.71 ppb / gf or more. When it becomes fresh cheese (score 3.5) with a cream-flavored finish remaining in the nasal cavity for a longer period of time, when it is 2.18 ppb / gf or higher, for example, 2.22 ppb / gf or higher, the cream-flavored finish is longer in the nasal cavity. It was confirmed that the remaining fresh cheese (score 4 or higher).

Claims (16)

  1.  γ-ドデカラクトンおよびz-デイリーラクトンから選択される少なくとも一つの香気成分を含み、該香気成分の含有量とフレッシュチーズの硬度の比(香気成分の含有量/硬度)が、以下の(i)~(vi)のうち少なくとも一つを満たす、フレッシュチーズ:
     (i)γ-ドデカラクトンの含有量(ppb)/硬度(gf)が0.80ppb/gf以上である、
     (ii)z-デイリーラクトンの含有量(ppb)/硬度(gf)が0.26ppb/gf以上である、
     (iii)2-ヘプタノンおよびγ-ドデカラクトンの合計量(ppb)/硬度(gf)が0.86ppb/gf以上である、
     (iv)2-ヘプタノンおよびz-デイリーラクトンの合計量(ppb)/硬度(gf)が0.33ppb/gf以上である、
     (v)γ-ドデカラクトンおよびz-デイリーラクトンの合計量(ppb)/硬度(gf)が1.06ppb/gf以上である、
     (vi)2-ヘプタノン、γ-ドデカラクトンおよびz-デイリーラクトンの合計量(ppb)/硬度(gf)が1.13ppb/gf以上である。
    It contains at least one aroma component selected from γ-dodecalactone and z-daily lactone, and the ratio of the content of the aroma component to the hardness of fresh cheese (content / hardness of the aroma component) is as follows (i). Fresh cheese that meets at least one of (vi):
    (I) The content (ppb) / hardness (gf) of γ-dodecalactone is 0.80 ppb / gf or more.
    (Ii) The content (ppb) / hardness (gf) of z-daily lactone is 0.26 ppb / gf or more.
    (Iii) The total amount (ppb) / hardness (gf) of 2-heptanone and γ-dodecalactone is 0.86 ppb / gf or more.
    (Iv) The total amount (ppb) / hardness (gf) of 2-heptanone and z-daily lactone is 0.33 ppb / gf or more.
    (V) The total amount (ppb) / hardness (gf) of γ-dodecalactone and z-daily lactone is 1.06 ppb / gf or more.
    (Vi) The total amount (ppb) / hardness (gf) of 2-heptanone, γ-dodecalactone and z-daily lactone is 1.13 ppb / gf or more.
  2.  (i)γ-ドデカラクトンの含有量(ppb)/硬度(gf)が1.17ppb/gf以上である、請求項1に記載のフレッシュチーズ。 (I) The fresh cheese according to claim 1, wherein the content (ppb) / hardness (gf) of γ-dodecalactone is 1.17 ppb / gf or more.
  3.  (ii)z-デイリーラクトンの含有量(ppb)/硬度(gf)が0.42ppb/gf以上である、請求項1または2に記載のフレッシュチーズ。 (Ii) The fresh cheese according to claim 1 or 2, wherein the content (ppb) / hardness (gf) of z-daily lactone is 0.42 ppb / gf or more.
  4.  (iii)2-ヘプタノンおよびγ-ドデカラクトンの合計量(ppb)/硬度(gf)が1.23ppb/gf以上である、請求項1~3のいずれか一項に記載のフレッシュチーズ。 (Iii) The fresh cheese according to any one of claims 1 to 3, wherein the total amount (ppb) / hardness (gf) of 2-heptanone and γ-dodecalactone is 1.23 ppb / gf or more.
  5.  (iv)2-ヘプタノンおよびz-デイリーラクトンの合計量(ppb)/硬度(gf)が0.48ppb/gf以上である、請求項1~4のいずれか一項に記載のフレッシュチーズ。 (Iv) The fresh cheese according to any one of claims 1 to 4, wherein the total amount (ppb) / hardness (gf) of 2-heptanone and z-daily lactone is 0.48 ppb / gf or more.
  6.  (v)γ-ドデカラクトンおよびz-デイリーラクトンの合計量(ppb)/硬度(gf)が1.58ppb/gf以上である、請求項1~5のいずれか一項に記載のフレッシュチーズ。 (V) The fresh cheese according to any one of claims 1 to 5, wherein the total amount (ppb) / hardness (gf) of γ-dodecalactone and z-daily lactone is 1.58 ppb / gf or more.
  7.  (vi)2-ヘプタノン、γ-ドデカラクトンおよびz-デイリーラクトンの合計量(ppb)/硬度(gf)が1.65ppb/gf以上である、請求項1~6のいずれか一項に記載のフレッシュチーズ。 (Vi) The invention according to any one of claims 1 to 6, wherein the total amount (ppb) / hardness (gf) of 2-heptanone, γ-dodecalactone and z-daily lactone is 1.65 ppb / gf or more. Fresh cheese.
  8.  前記フレッシュチーズが、パスタフィラータである、請求項1~7のいずれか一項に記載のフレッシュチーズ。 The fresh cheese according to any one of claims 1 to 7, wherein the fresh cheese is pasta filata.
  9.  請求項1~8のいずれか一項に記載のフレッシュチーズを含んでなる、包装食品または容器詰食品。 A packaged food or a packaged food containing the fresh cheese according to any one of claims 1 to 8.
  10.  フレッシュチーズの全部または一部が遮光されてなる、請求項9に記載の包装食品または容器詰食品。 The packaged food or packaged food according to claim 9, wherein all or part of the fresh cheese is shielded from light.
  11.  γ-ドデカラクトンおよびz-デイリーラクトンから選択される少なくとも一つを含む香気成分の含有量とフレッシュチーズの硬度の比(香気成分の含有量/硬度)が、後味の余韻を参照して設定された閾値以上になるように調整する工程を含んでなる、フレッシュチーズの製造方法。 The ratio of the content of the aroma component containing at least one selected from γ-dodecalactone and z-daily lactone to the hardness of the fresh cheese (aroma component content / hardness) is set with reference to the aftertaste. A method for producing fresh cheese, which comprises a step of adjusting the cheese so that it exceeds the threshold value.
  12.  (1)前記香気成分を含んでなるカードを準備する工程、および
     (2)前記香気成分の含有量と硬度の比を調整して、前記カードからフレッシュチーズを得る工程
    を含んでなる、請求項11に記載の方法。
    The claim comprises the steps of (1) preparing a card containing the aroma component, and (2) adjusting the ratio of the content of the aroma component to the hardness to obtain fresh cheese from the card. 11. The method according to 11.
  13.  γ-ドデカラクトンおよびz-デイリーラクトンから選択される少なくとも一つを含む香気成分の含有量とパスタフィラーの硬度の比(香気成分の含有量/硬度)が、後味の余韻を参照して設定された閾値以上になるように調整する工程を含んでなる、パスタフィラータの製造方法であって、
     カードを準備する工程、カードを混錬する工程および混錬したフレッシュチーズをブラインに浸漬する工程のいずれか1以上の工程で前記香気成分を添加する、パスタフィラータの製造方法。
    The ratio of the content of the aroma component containing at least one selected from γ-dodecalactone and z-daily lactone to the hardness of the pasta filler (content of aroma component / hardness) is set with reference to the aftertaste. A method for producing pasta filata, which comprises a step of adjusting the pasta filata so as to be equal to or higher than the threshold value.
    A method for producing pasta filata, wherein the aroma component is added in any one or more of a step of preparing the curd, a step of kneading the curd, and a step of immersing the kneaded fresh cheese in brine.
  14.  フレッシュチーズが、請求項1~8のいずれか一項に記載されたフレッシュチーズである、請求項11から13のいずれかに記載の方法。 The method according to any one of claims 11 to 13, wherein the fresh cheese is the fresh cheese according to any one of claims 1 to 8.
  15.  γ-ドデカラクトンおよびz-デイリーラクトンから選択される少なくとも一つを含む香気成分の含有量とフレッシュチーズの硬度の比(香気成分の含有量/硬度)が、後味の余韻を参照して設定された閾値以上になるように調整する工程を含んでなる、フレッシュチーズにおける後味の余韻の向上方法。 The ratio of the content of the aroma component containing at least one selected from γ-dodecalactone and z-daily lactone to the hardness of the fresh cheese (aroma component content / hardness) is set with reference to the aftertaste. A method for improving the aftertaste of fresh cheese, which comprises a step of adjusting the cheese so that it exceeds the threshold value.
  16.  フレッシュチーズが、請求項1~8のいずれか一項に記載されたフレッシュチーズである、請求項15に記載の方法。 The method according to claim 15, wherein the fresh cheese is the fresh cheese according to any one of claims 1 to 8.
PCT/JP2021/031976 2020-08-31 2021-08-31 Fresh cheese, manufacturing method therefor, and method for improving aftertaste WO2022045367A1 (en)

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6440481B1 (en) * 2000-03-06 2002-08-27 Bongards' Creameries, Inc. Method of making pasta filata cheese
JP2005261434A (en) * 2004-03-17 2005-09-29 Kraft Foods Research & Development Inc Mozzarella type string cheese product
JP2010075133A (en) * 2008-09-29 2010-04-08 Meiji Milk Prod Co Ltd Method for producing natural cheese

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6440481B1 (en) * 2000-03-06 2002-08-27 Bongards' Creameries, Inc. Method of making pasta filata cheese
JP2005261434A (en) * 2004-03-17 2005-09-29 Kraft Foods Research & Development Inc Mozzarella type string cheese product
JP2010075133A (en) * 2008-09-29 2010-04-08 Meiji Milk Prod Co Ltd Method for producing natural cheese

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