WO2022036888A1 - B1-level 35kv looped network cable for urban rail transit traction power supply system - Google Patents

B1-level 35kv looped network cable for urban rail transit traction power supply system Download PDF

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Publication number
WO2022036888A1
WO2022036888A1 PCT/CN2020/128229 CN2020128229W WO2022036888A1 WO 2022036888 A1 WO2022036888 A1 WO 2022036888A1 CN 2020128229 W CN2020128229 W CN 2020128229W WO 2022036888 A1 WO2022036888 A1 WO 2022036888A1
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layer
parts
power supply
supply system
rail transit
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PCT/CN2020/128229
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French (fr)
Chinese (zh)
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郑建平
张中云
刘亚欣
卢金贺
杨斌
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江苏亨通电力电缆有限公司
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Publication of WO2022036888A1 publication Critical patent/WO2022036888A1/en

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B7/00Insulated conductors or cables characterised by their form
    • H01B7/17Protection against damage caused by external factors, e.g. sheaths or armouring
    • H01B7/29Protection against damage caused by extremes of temperature or by flame
    • H01B7/295Protection against damage caused by extremes of temperature or by flame using material resistant to flame
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B7/00Insulated conductors or cables characterised by their form
    • H01B7/17Protection against damage caused by external factors, e.g. sheaths or armouring
    • H01B7/18Protection against damage caused by wear, mechanical force or pressure; Sheaths; Armouring
    • H01B7/20Metal tubes, e.g. lead sheaths
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B9/00Power cables
    • H01B9/02Power cables with screens or conductive layers, e.g. for avoiding large potential gradients

Definitions

  • the invention relates to the field of power supply cables, in particular to a B 1 -level 35kV ring network cable for traction power supply systems of urban rail transit.
  • the ring network cable used in the traction power supply system of rail transit mainly includes the outgoing cable from the main substation to the traction substation and the connecting cable between the traction substations.
  • the ring network cable has the characteristics of flame retardant, when the cable burns under fire conditions, it will still cause heat release hazards to the outside world, and the anti-rat bite performance of the cable is limited.
  • the purpose of the present invention is to provide a B 1 -level 35kV ring network cable for urban rail transit traction power supply system, which can improve the heat release problem when the ring network cable is burned, and can improve the ability to prevent rodent bites.
  • an embodiment of the present invention provides a B 1 -level 35kV ring network cable for an urban rail transit traction power supply system, including a cable core assembly, a high flame-retardant fireproof layer and a copper-zinc alloy layer coated on the outside of the cable core assembly.
  • a high flame retardant fireproof layer is sandwiched between the cable core assembly and the copper-zinc alloy layer.
  • the high flame retardant fire protection layer is made of a ceramified polyolefin material.
  • the class B 1 35kV ring network cable for the urban rail transit traction power supply system further includes a polymer protective layer, and the polymer protective layer is the highest level of the B 1 class 35kV ring network cable for the urban rail transit traction power supply system. outer layer.
  • the cable core assembly includes a conductor and a set of protective layers overlying the conductor.
  • the protective layer group includes a conductor shielding layer, a cross-linked polyethylene insulating layer, and an insulating shielding layer that are sequentially coated on the outside of the conductor, and the high flame retardant fireproof layer and the copper-zinc alloy layer are distributed on the insulating shielding layer. outside.
  • the protective layer group further includes a semiconducting resistive water tape covered by the insulating shielding layer, and both the high flame retardant fireproof layer and the copper-zinc alloy layer are distributed on the outer side of the semiconducting resistive water tape.
  • the protective layer group further includes a copper wire shielding layer covered with a semiconducting resistance water tape, and both the high flame retardant fireproof layer and the copper-zinc alloy layer are distributed on the outer side of the copper wire shielding layer.
  • the protective layer group further includes a flame-retardant wrapping tape layer covered by the copper wire shielding layer, and the high flame-retardant fire-retardant layer and the copper-zinc alloy layer are both distributed on the outer side of the flame-retardant wrapping tape layer.
  • the protective layer group further includes a waterproof layer covered by a flame retardant wrapping tape layer, and both the high flame retardant fireproof layer and the copper-zinc alloy layer are distributed on the outer side of the waterproof layer.
  • the raw materials for preparing the polymer protective layer include: 30-50 parts of ethylene-vinyl acetate copolymer resin, 40-70 parts of polyolefin elastomer, 5-15 parts of compatibilizer , 10-30 parts of composite reinforcing agent, 1-5 parts of composite lubricant, 10-20 parts of ceramic zinc borate, 40-80 parts of ultra-fine composite flame retardant, 1-5 parts of antioxidant, 1-3 parts of Dicumyl peroxide, 1-3 parts of triallyl isocyanurate, 0.5-2 parts of ultraviolet absorber, 1-5 parts of environmental protection termite agent, 1-5 parts of environmental protection rodent agent.
  • the ultra-fine composite flame retardant includes magnesium hydroxide and aluminum hydroxide.
  • the beneficial effects of the B1 - level 35kV ring network cable for the urban rail transit traction power supply system in the embodiment of the present invention include: the B1 - level 35kV ring network cable for the urban rail transit traction power supply system provided by the embodiment of the present invention includes a cable core assembly and a package
  • the copper-zinc alloy layer can help the high flame-retardant fire-retardant layer to play a role of flame retardant and fire prevention, thereby reducing the heat-releasing hazard, and can also use the smooth and hard nature of the copper-zinc alloy layer to prevent rat bite hazards.
  • FIG. 1 is a schematic cross-sectional structure diagram of a B 1 -level 35kV ring network cable used in an urban rail transit traction power supply system in an embodiment of the present invention
  • FIG. 2 is a flow chart of the preparation process of the B 1 -level 35kV ring network cable for the traction power supply system of the urban rail transit in the embodiment of the present invention.
  • Icon 010-B1 class 35kV ring network cable for urban rail transit traction power supply system; 100-Cable core assembly; 210-High flame retardant fireproof layer; 220-Copper-zinc alloy layer; 230-Polymer protective layer; 110-Conductor; 120-protective layer group; 121-conductor shielding layer; 122-cross-linked polyethylene insulating layer; 123-insulating shielding layer; 124-semiconductor resistance water tape; 125-copper wire shielding layer; ; 127 - Waterproof layer.
  • orientation or positional relationship indicated by the terms “inside”, “outside”, etc. is based on the orientation or positional relationship shown in the accompanying drawings, or is usually placed when the product of the invention is used.
  • the orientation or positional relationship is only for the convenience of describing the present invention and simplifying the description, rather than indicating or implying that the referred device or element must have a specific orientation, be constructed and operated in a specific orientation, and therefore should not be construed as a limitation of the present invention.
  • connection should be understood in a broad sense, for example, it may be a fixed connection or a detachable connection, or It can be connected in one piece; it can be a mechanical connection or an electrical connection; it can be directly connected or indirectly connected through an intermediate medium, and it can be internal communication between two components.
  • this embodiment provides a B 1 -level 35kV ring network cable 010 for an urban rail transit traction power supply system, which can be used indoors, outdoors, underground, tunnels, cable trays or cable trenches that are often soaked in water, Substation cable interlayer and other places, especially for rail transit traction power supply system, such as: the outgoing cable from the main substation to the traction substation and the connection cable between the traction substations, etc.
  • the grade B 35kV ring network cable 010 for urban rail transit traction power supply system includes a cable core assembly 100; further, the cable core assembly 100 includes a conductor 110 and a protective layer group 120 wrapped around the conductor 110, wherein the conductor 110 is used for Conductive, the protective layer group 120 has the functions of shielding and waterproofing.
  • the above-mentioned conductor 110 can be selected according to needs, for example, it can be a copper conductor; further, the second type of twisted and compressed copper conductor specified in the GB/T3956-2008 standard can be used, and the conductor 110 has a smooth surface and no damage to insulation. burrs, sharp edges, and raised or broken single lines are not specifically limited here.
  • the protective layer group 120 includes a conductor shielding layer 121 , a cross-linked polyethylene insulating layer 122 (XLPE insulating layer) and an insulating shielding layer 123 which are sequentially wrapped around the conductor 110 .
  • XLPE insulating layer cross-linked polyethylene insulating layer 122
  • the conductor shielding layer 121 can use a 35kV inner shielding material, and the performance should meet the requirements of the GB/T12706.3-2008 standard.
  • the cross-linked polyethylene insulating layer 122 (XLPE insulating layer) can be made of 35kV chemically cross-linked insulating material, and the performance should meet the requirements of the GB/T12706.3-2008 standard.
  • the insulating shielding layer 123 can use a 35kV non-peelable semi-conductive outer shielding material, and the performance should meet the requirements of the GB/T12706.3-2008 standard.
  • the protective layer group 120 further includes a semiconducting resistive water tape 124 covered by the insulating shielding layer 123 , and a copper wire shielding layer 125 covered by the semiconducting resistive water tape 124 .
  • the semiconducting resistance water tape 124 can be wrapped around the insulating shielding layer 123 as a buffer layer for copper wire shielding. It should be further noted that the semiconducting resistance water tape 124 wrapped around the insulating shielding layer 123 may be one layer, two layers, three layers, etc., which is not specifically limited here; that is, the insulating shielding layer 123 may be a single layer The wrapping semiconducting resistive water tape 124 may also be a multilayer wrapping semiconducting resistive water tape 124 .
  • the copper wire shielding layer 125 may adopt a copper wire sparsely wound structure. It should be noted that the size of the copper wire shielding cross-sectional area can be determined according to the system fault short-circuit current.
  • the protective layer group 120 further includes a flame retardant wrapping tape layer 126 covered by the copper wire shielding layer 125 ; wrapping the flame retardant wrapping tape around the copper wire shielding layer 125 can protect the inner layer from being burned by flames.
  • the number of layers of flame retardant wrapping tapes wrapped around the copper wire shielding layer 125 may be one layer, two layers, three layers, etc., which is not specifically limited here; It can be a single-layer wrapping flame-retardant wrapping tape, or a multi-layer wrapping flame-retardant wrapping tape.
  • the protective layer group 120 further includes a waterproof layer 127 covered by the flame-retardant wrapping tape layer 126 .
  • the waterproof layer 127 may be an aluminum-plastic waterproof layer 127 .
  • the aluminum-plastic waterproof layer 127 may adopt a longitudinally-wrapped aluminum-plastic composite tape structure.
  • the B1 level 35kV ring network cable 010 for the urban rail transit traction power supply system in this embodiment further includes a high flame-retardant fireproof layer 210 and a copper-zinc alloy layer 220 that are coated on the outside of the cable core assembly 100 .
  • the high flame-retardant fireproof layer 210 can absorb a large amount of heat when it encounters flame burning, so as to avoid the danger of heat release to the outside world caused by the burning of the B 1 class 35kV ring network cable 010 for the traction power supply system of urban rail transit in the event of fire.
  • the copper-zinc alloy layer 220 can assist the highly flame-retardant and fire-resistant layer 210 to play a flame-retardant and fire-resistant role, thereby reducing heat release hazards, and can also use the smooth and hard properties of the copper-zinc alloy layer 220 to prevent rat bite hazards.
  • the high flame retardant fireproof layer 210 is sandwiched between the cable core assembly 100 and the copper-zinc alloy layer 220, so that the copper-zinc alloy layer 220 located outside the high flame-retardant fireproof layer 210 can be used to prevent the high flame-retardant fireproof layer 220.
  • the layer 210 is directly burned by the flame, so as to ensure that the high flame-retardant fire - proof layer 210 can fully exert its ability to absorb a large amount of fire in the event of an open flame such as a fire.
  • the effect of heat can effectively improve the harm of heat release to the outside world when the B 1 -level 35kV ring network cable 010 is burned for the traction power supply system of urban rail transit.
  • the high flame retardant fireproof layer 210 is sandwiched between the cable core assembly 100 and the copper-zinc alloy layer 220, and the high flame retardant fireproof layer 210 can also be located outside the aluminum-plastic waterproof layer 127, and the aluminum-plastic composite layer is longitudinally wrapped.
  • the aluminum-plastic waterproof layer 127 with structure can be combined with the extruded high flame-retardant fireproof layer 210 to form the aluminum-plastic comprehensive waterproof layer 127 to realize the radial waterproof feature, so as to further ensure the B 1 class 35kV ring network for the traction power supply system of urban rail transit. Water resistance of cable 010.
  • the high flame retardant fireproof layer 210 can be made of ceramicized polyolefin (high thermal insulation ceramicized polyolefin) material, a large amount of ceramic powder is added to the material, the combustion calorific value is low, and the flame at about 550 ° C is made.
  • the closed porous ceramic structure generated by porcelainization under ablation can have a good thermal insulation effect.
  • the low-temperature porcelain reaction process absorbs a large amount of heat, which effectively reduces the temperature of the insulating materials such as the insulating shielding layer 123 of the cable core assembly 100, and effectively reduces the B 1 class 35kV ring network cable 010 used in the urban rail transit traction power supply system. Heat release rate and total heat release.
  • using the ceramicized polyolefin material can prevent the flame from burning through the high flame-retardant fireproof layer 210 on the one hand, and protect the cable core assembly 100;
  • the leakage channel of the decomposed gas prevents the leakage of the internal gas from damaging the integrity of the outer sheath; when the outer sheath is burned by the flame, the propagation distance of the flame and the heat release of the outer sheath are controlled.
  • the copper-zinc alloy layer 220 can be wrapped around the outside of the high flame-retardant fireproof layer 210 by using a copper-zinc alloy strip with a higher hardness.
  • the hard alloy material prevents rats from chewing on the cable core.
  • the number of layers of the copper-zinc alloy layer 220 wrapped around the high flame retardant fireproof layer 210 may be one, two or three layers, etc., which is not specifically limited here; that is, the high flame retardant fireproof layer
  • a single-layer copper-zinc alloy layer 220 can be wrapped outside the 210, or at least two copper-zinc alloy layers 220 can be overlapped and wrapped.
  • the B1 - level 35kV ring network cable 010 for the urban rail transit traction power supply system in this embodiment further includes a polymer protective layer 230, and the polymer protection layer 230 is the most important part of the B1 - level 35kV ring network cable 010 for the urban rail transit traction power supply system.
  • This setting makes the B 1 -level 35kV ring network cable 010 for urban rail transit traction power supply system simultaneously waterproof, fireproof, rodent-proof, termite-proof and UV-proof to meet more diverse needs.
  • the polymer protective layer 230 may be a low calorific value, halogen-free, low-smoke flame retardant polyolefin sheath material, and an efficient and environmentally friendly anti-mouse and termite agent is added to the polymer.
  • the raw materials for preparing the polymer protective layer 230 include:
  • the content of vinyl acetate (VA) in ethylene-vinyl acetate copolymer resin (EVA) is roughly 35-45%;
  • EVA-g-MA is maleic anhydride modified EVA, and the purpose is to promote coupling agent and dispersion agent, so that the ultra-fine composite flame retardant is dispersed more uniformly in the resin.
  • the above-mentioned ultra-fine composite flame retardants are ultra-fine magnesium hydroxide and aluminum hydroxide, and the use of ultra-fine composite flame retardants can make the dispersion in the resin better and more uniform.
  • the weight ratio of magnesium hydroxide to aluminum hydroxide may be 1:1-1.5.
  • ceramized zinc borate generates zinc oxide during the combustion process to promote the formation of char-forming agent, and in the flame retardant system of magnesium hydroxide and aluminum hydroxide, it can promote char-forming and form ceramization, that is, it can be dehydrated and carbonized to form a certain The thickness and strength of the carbon layer block combustion, effectively play the role of smoke suppression, flame retardant, and anti dripping.
  • the ceramicized zinc borate/aluminum hydroxide/magnesium hydroxide has a synergistic effect and has excellent flame retardant performance, so as to further improve the flame retardant performance of B 1 class 35kV ring network cable 010 for urban rail transit traction power supply system.
  • the above-mentioned composite reinforcing agent includes at least one of carbon black, white carbon black, acetylene carbon black and diatomaceous earth, and further, the composite reinforcing agent includes carbon black, white carbon black, acetylene carbon black and diatomaceous earth. any two.
  • the above-mentioned composite lubricant can be selected from at least one of zinc stearate and hydroxy silicone oil; further, the composite lubricant can be selected from zinc stearate and hydroxy silicone oil, and the weight ratio of the two can be 1:0.5-1.5.
  • antioxidants generally select hindered phenolic antioxidants, which can be any at least one such as antioxidant 1076, antioxidant 264 and antioxidant 1010, which are not specifically limited here;
  • Stabilizer can be any at least one such as 2-hydroxy-4-methoxy benzophenone and 2-hydroxy-4-n-octyloxy benzophenone, which is not specifically limited here;
  • the environmental protection termite agent generally selects any at least one such as chlorpyrifos and carbamate, which is not specifically limited here.
  • the preparation method of the polymer protective layer 230 includes: weighing and mixing each raw material, transferring it to a twin-screw extruder for extrusion, the temperature is 120-180° C., the screw speed is 60-600 rpm, and then Pelletize at 120-140°C.
  • the preparation method of the polymer protective layer 230 is as follows: 30 parts of ethylene-vinyl acetate copolymer resin, 40 parts of polyolefin elastomer, 5 parts of compatibilizer, 10 parts of composite reinforcing agent, 1 part of composite lubricant 10 parts of ceramic zinc borate, 40 parts of ultra-fine composite flame retardant, 1 part of antioxidant, 1 part of dicumyl peroxide, 1 part of triallyl isocyanurate, 0.5 part of ultraviolet absorber 1 part of environmental protection termite agent, 1 part of environmental protection rodent agent are mixed, transferred to a twin-screw extruder for extrusion, the temperature is 120 ° C, the screw speed is 60 rpm, and then pelletized at 120 ° C.
  • the preparation process of the B 1 -level 35kV ring network cable 010 for the urban rail transit traction power supply system of the present embodiment includes: using a three-layer co-extrusion process to sequentially coat the conductor shielding layer 121 on the outside of the conductor 110, cross-linking The polyethylene insulating layer 122 and the insulating shielding layer 123; then the semiconducting resistance water tape 124 covered by the insulating shielding layer 123; then the copper wire shielding layer 125 covered by the semiconducting resistance water tape 124; then the copper wire
  • the flame retardant wrapping tape layer 126 covered by the shielding layer 125; then the waterproof layer 127 and the high flame retardant fireproof layer 210 are sequentially wrapped outside the flame retardant wrapping tape layer 126;
  • the copper-zinc alloy layer 220 is clad; finally, the copper-zinc alloy layer 220 is covered with a polymer protective layer 230; after that, the finished product inspection is performed.
  • test results of the B 1 -level 35kV ring network cable 010 used in the urban rail transit traction power supply system of this embodiment are as follows:
  • B 1 grade 35kV ring network cable 010 for urban rail transit traction power supply system measured according to the test method specified in GB 31247-2014, and the measured results meet the B 1 grade classification criterion; burning dripping objects / The particle level meets d 0 level, that is, there is no burning droplets/particles within 1200s; the flue gas toxicity level meets t 0 level, that is, ZA level 2 ; the corrosiveness level meets a 1 level, that is, the electrical conductivity ⁇ 2.5 ⁇ s/mm , PH ⁇ 4.3.
  • Anti-ultraviolet performance of class B 1 35kV ring network cable 010 for urban rail transit traction power supply system perform artificial weather resistance aging test (xenon lamp method) in accordance with the provisions of GB/T 12527-2008, after 42 days of aging, protect the The rate of change in tensile strength and the rate of change in elongation at break conform to the standard.
  • Example 2 is similar to Example 1, the difference lies in the specific preparation method of the polymer protective layer, the preparation method of the polymer protective layer 230 in Example 2 is: 50 parts of ethylene-vinyl acetate copolymer resin, 70 parts of poly Olefin elastomer, 15 parts of compatibilizer, 30 parts of composite reinforcing agent, 5 parts of composite lubricant, 20 parts of ceramic zinc borate, 80 parts of ultrafine composite flame retardant, 5 parts of antioxidant, 3 parts of peroxide Dicumylbenzene, 3 parts of triallyl isocyanurate, 2 parts of ultraviolet absorber, 5 parts of environmental protection termite repellant, 5 parts of environmental protection rodent repellant were mixed, transferred to a twin-screw extruder for extrusion, The temperature is 180°C, the screw speed is 600 rpm, and the pellets are formed at 140°C.
  • the ethylene-vinyl acetate copolymer resin contains 40% VA;
  • the ultra-fine composite flame retardant includes aluminum hydroxide and magnesium hydroxide in a weight ratio of 1:1;
  • the composite reinforcing agent includes a weight ratio of 1:1.5 carbon black and white carbon black;
  • composite lubricants include zinc stearate, hydroxy silicone oil in a weight ratio of 1:1.5;
  • antioxidants include antioxidant 1076;
  • UV absorbers include 2-hydroxy-4-methoxydiol Benzophenone; environmentally friendly rodent repellents include capsaicin; environmentally friendly termite control agents include chlorpyrifos.
  • Example 3 is similar to Example 1, the difference lies in the specific preparation method of the polymer protective layer.
  • the preparation method of the polymer protective layer 230 in Example 3 is: 40 parts of ethylene-vinyl acetate copolymer resin, 50 parts of poly Olefin elastomer, 10 parts of compatibilizer, 20 parts of composite reinforcing agent, 3 parts of composite lubricant, 15 parts of ceramic zinc borate, 70 parts of ultrafine composite flame retardant, 3 parts of antioxidant, 2 parts of peroxide Dicumylbenzene, 2 parts of triallyl isocyanurate, 1 part of ultraviolet absorber, 3 parts of environmentally friendly termite repellant, and 3 parts of environmentally friendly rodent repellant were mixed and transferred to a twin-screw extruder for extrusion.
  • the temperature is 150°C
  • the screw speed is 200 rpm
  • the pellets are formed at 130°C.
  • the ethylene-vinyl acetate copolymer resin contains 35% VA;
  • the ultrafine composite flame retardant includes aluminum hydroxide and magnesium hydroxide in a weight ratio of 1:1.5;
  • the composite reinforcing agent includes a weight ratio of 1:1 acetylene carbon black or diatomaceous earth;
  • the composite lubricant includes zinc stearate and hydroxy silicone oil in a weight ratio of 1:0.5;
  • the antioxidant includes antioxidant 264;
  • the ultraviolet absorber includes 2-hydroxy-4-n-octyloxy benzophenone;
  • environmentally friendly rodent repellants include capsaicin and trans-capsaicin; environmentally friendly termite inhibitors include carbamates.
  • Example 4 is similar to Example 1, the difference lies in the specific preparation method of the polymer protective layer.
  • the preparation method of the polymer protective layer 230 in Example 4 is: 40 parts of ethylene-vinyl acetate copolymer resin, 50 parts of poly Olefin elastomer, 12 parts of compatibilizer, 16 parts of composite reinforcing agent, 4 parts of composite lubricant, 12 parts of ceramic zinc borate, 56 parts of ultrafine composite flame retardant, 2 parts of antioxidant, 3 parts of peroxide Dicumyl benzene, 1 part of triallyl isocyanurate, 0.8 part of ultraviolet absorber, 4 parts of environmental protection termite agent, and 3 parts of environmental protection rodent repellant were mixed and transferred to a twin-screw extruder for extrusion.
  • the temperature is 170°C
  • the screw speed is 400 rpm
  • the pellets are formed at 125°C.
  • the ethylene-vinyl acetate copolymer resin contains 45% VA;
  • the ultra-fine composite flame retardant includes aluminum hydroxide and magnesium hydroxide in a weight ratio of 1:1.2;
  • the composite reinforcing agent includes a weight ratio of 1:1.5 of carbon black and diatomaceous earth;
  • the composite lubricant includes zinc stearate and hydroxy silicone oil in a weight ratio of 1:0.8;
  • the antioxidant includes antioxidant 1010;
  • the ultraviolet absorber includes 2-hydroxy-4-methoxydiol Benzophenone and 2-hydroxy-4-n-octyloxybenzophenone;
  • environmental rodent repellents include trans-capsaicin;
  • environmental termite repellents include chlorpyrifos and carbamates.
  • Example 5 is similar to Example 1, the difference lies in the specific preparation method of the polymer protective layer, the preparation method of the polymer protective layer 230 in Example 5 is: 35 parts of ethylene-vinyl acetate copolymer resin, 55 parts of poly Olefin elastomer, 8 parts of compatibilizer, 22 parts of composite reinforcing agent, 3 parts of composite lubricant, 16 parts of ceramic zinc borate, 65 parts of ultrafine composite flame retardant, 2 parts of antioxidant, 1 part of peroxide Dicumylbenzene, 3 parts of triallyl isocyanurate, 1 part of ultraviolet absorber, 2 parts of environmental protection termite repellant, 5 parts of environmental protection rodent repellant were mixed, transferred to a twin-screw extruder for extrusion, The temperature is 140°C, the screw speed is 100 rpm, and then the pellets are formed at 135°C.
  • the ethylene-vinyl acetate copolymer resin contains 41% VA;
  • the ultra-fine composite flame retardant includes aluminum hydroxide and magnesium hydroxide in a weight ratio of 1:1.1;
  • the composite reinforcing agent includes a weight ratio of 1:1 : 1:1 carbon black, white carbon black, acetylene carbon black and diatomaceous earth;
  • composite lubricants include hydroxy silicone oil; antioxidants include antioxidant 1076, antioxidant 264 and antioxidant 1010;
  • UV absorbers include 2-Hydroxy-4-methoxybenzophenone;
  • environment-friendly rodent repellents include capsaicin; environment-friendly termite repellents include chlorpyrifos.
  • the class B 1 35kV ring network cable 010 for the urban rail transit traction power supply system can utilize the high flame retardant fireproof layer 210 to absorb a large amount of heat when encountering flame burning, so as to avoid urban rail transit traction power supply.
  • the system uses B 1 class 35kV ring network cable 010 to burn in the event of fire, which will cause heat release to the outside world.
  • the copper-zinc alloy layer 220 can assist the high flame-retardant fire-retardant layer 210 to play the role of flame-retardant and fire-proof, thereby reducing the risk of fire.
  • the heat release hazard can also be prevented by the smooth and hard nature of the copper-zinc alloy layer 220 to prevent rat bite hazard.

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Abstract

A B1-level 35kV looped network cable for an urban rail transit traction power supply system, relating to the field of power supply circuits. The B1-level 35kV looped network cable for the urban rail transit traction power supply system comprises a cable core assembly (100), and a high-flame-retardant fireproof layer (210) and a copper-zinc alloy layer (220) that cover the cable core assembly (100). According to the B1-level 35kV looped network cable for the urban rail transit traction power supply system can solve the problem of heat release during cable combustion and improve the rat bite prevention capacity.

Description

一种城市轨道交通牵引供电系统用B 1级35kV环网电缆 A kind of urban rail transit traction power supply system B Class 1 35kV ring network cable
本申请要求2020年8月18日向中国国家知识产权局的申请号为202010834277.X的专利申请的优先权。This application claims the priority of the patent application with the application number 202010834277.X filed with the State Intellectual Property Office of China on August 18, 2020.
技术领域technical field
本发明涉及供电电缆领域,具体而言,涉及一种城市轨道交通牵引供电系统用B 1级35kV环网电缆。 The invention relates to the field of power supply cables, in particular to a B 1 -level 35kV ring network cable for traction power supply systems of urban rail transit.
背景技术Background technique
轨道交通牵引供电系统用环网电缆主要包括主变电站到牵引变电站的出线电缆以及各牵引变电站之间的联络电缆。The ring network cable used in the traction power supply system of rail transit mainly includes the outgoing cable from the main substation to the traction substation and the connecting cable between the traction substations.
相关技术中,环网电缆虽然具有阻燃的特性,但是电缆在火灾条件下燃烧时仍然会对外界产生热释放的危害,且电缆的防鼠咬性能有限。In the related art, although the ring network cable has the characteristics of flame retardant, when the cable burns under fire conditions, it will still cause heat release hazards to the outside world, and the anti-rat bite performance of the cable is limited.
发明内容SUMMARY OF THE INVENTION
本发明的目的在于提供一种城市轨道交通牵引供电系统用B 1级35kV环网电缆,其能够改善环网电缆燃烧时的热释放问题,且能够改善防鼠咬的能力。 The purpose of the present invention is to provide a B 1 -level 35kV ring network cable for urban rail transit traction power supply system, which can improve the heat release problem when the ring network cable is burned, and can improve the ability to prevent rodent bites.
本发明的实施例是这样实现的:Embodiments of the present invention are implemented as follows:
第一方面,本发明实施例提供一种城市轨道交通牵引供电系统用B 1级35kV环网电缆,包括缆芯组件和包覆于缆芯组件外部的高阻燃防火层和铜锌合金层。 In a first aspect, an embodiment of the present invention provides a B 1 -level 35kV ring network cable for an urban rail transit traction power supply system, including a cable core assembly, a high flame-retardant fireproof layer and a copper-zinc alloy layer coated on the outside of the cable core assembly.
在可选的实施方式中,高阻燃防火层夹设于缆芯组件和铜锌合金层之间。In an optional embodiment, a high flame retardant fireproof layer is sandwiched between the cable core assembly and the copper-zinc alloy layer.
在可选的实施方式中,高阻燃防火层由陶瓷化聚烯烃材料制成。In an alternative embodiment, the high flame retardant fire protection layer is made of a ceramified polyolefin material.
在可选的实施方式中,城市轨道交通牵引供电系统用B 1级35kV环网 电缆还包括聚合物保护层,聚合物保护层为城市轨道交通牵引供电系统用B 1级35kV环网电缆的最外层。 In an optional embodiment, the class B 1 35kV ring network cable for the urban rail transit traction power supply system further includes a polymer protective layer, and the polymer protective layer is the highest level of the B 1 class 35kV ring network cable for the urban rail transit traction power supply system. outer layer.
在可选的实施方式中,缆芯组件包括导体和包覆于导体外的保护层组。In an alternative embodiment, the cable core assembly includes a conductor and a set of protective layers overlying the conductor.
在可选的实施方式中,保护层组包括导体外依次包覆的导体屏蔽层、交联聚乙烯绝缘层和绝缘屏蔽层,且高阻燃防火层和铜锌合金层均分布于绝缘屏蔽层的外侧。In an optional embodiment, the protective layer group includes a conductor shielding layer, a cross-linked polyethylene insulating layer, and an insulating shielding layer that are sequentially coated on the outside of the conductor, and the high flame retardant fireproof layer and the copper-zinc alloy layer are distributed on the insulating shielding layer. outside.
在可选的实施方式中,保护层组还包括绝缘屏蔽层外包覆的半导电阻水带,且高阻燃防火层和铜锌合金层均分布于半导电阻水带的外侧。In an optional embodiment, the protective layer group further includes a semiconducting resistive water tape covered by the insulating shielding layer, and both the high flame retardant fireproof layer and the copper-zinc alloy layer are distributed on the outer side of the semiconducting resistive water tape.
在可选的实施方式中,保护层组还包括半导电阻水带外包覆的铜丝屏蔽层,且高阻燃防火层和铜锌合金层均分布于铜丝屏蔽层的外侧。In an optional embodiment, the protective layer group further includes a copper wire shielding layer covered with a semiconducting resistance water tape, and both the high flame retardant fireproof layer and the copper-zinc alloy layer are distributed on the outer side of the copper wire shielding layer.
在可选的实施方式中,保护层组还包括铜丝屏蔽层外包覆的阻燃绕包带层,且高阻燃防火层和铜锌合金层均分布于阻燃绕包带层的外侧。In an optional embodiment, the protective layer group further includes a flame-retardant wrapping tape layer covered by the copper wire shielding layer, and the high flame-retardant fire-retardant layer and the copper-zinc alloy layer are both distributed on the outer side of the flame-retardant wrapping tape layer. .
在可选的实施方式中,保护层组还包括阻燃绕包带层外包覆的防水层,且高阻燃防火层和铜锌合金层均分布于防水层的外侧。In an optional embodiment, the protective layer group further includes a waterproof layer covered by a flame retardant wrapping tape layer, and both the high flame retardant fireproof layer and the copper-zinc alloy layer are distributed on the outer side of the waterproof layer.
在可选的实施方式中,按照重量份计,聚合物保护层的制备原料包括:30-50份乙烯-醋酸乙烯共聚物树脂、40-70份聚烯烃弹性体、5-15份相容剂、10-30份复合补强剂、1-5份复合润滑剂、10-20份陶瓷化硼酸锌、40-80份超细化复合阻燃剂、1-5份抗氧剂、1-3份过氧化二异丙苯、1-3份三烯丙基异氰脲酸酯、0.5-2份紫外线吸收剂、1-5份环保防白蚁剂、1-5份环保防鼠剂。In an optional embodiment, in parts by weight, the raw materials for preparing the polymer protective layer include: 30-50 parts of ethylene-vinyl acetate copolymer resin, 40-70 parts of polyolefin elastomer, 5-15 parts of compatibilizer , 10-30 parts of composite reinforcing agent, 1-5 parts of composite lubricant, 10-20 parts of ceramic zinc borate, 40-80 parts of ultra-fine composite flame retardant, 1-5 parts of antioxidant, 1-3 parts of Dicumyl peroxide, 1-3 parts of triallyl isocyanurate, 0.5-2 parts of ultraviolet absorber, 1-5 parts of environmental protection termite agent, 1-5 parts of environmental protection rodent agent.
在可选的实施方式中,超细化复合阻燃剂包括氢氧化镁和氢氧化铝。In an optional embodiment, the ultra-fine composite flame retardant includes magnesium hydroxide and aluminum hydroxide.
本发明实施例的城市轨道交通牵引供电系统用B 1级35kV环网电缆的有益效果包括:本发明实施例提供的城市轨道交通牵引供电系统用B 1级35kV环网电缆包括缆芯组件和包覆于缆芯组件外部的高阻燃防火层和铜锌合金层;其中,高阻燃防火层能够在遇到火焰灼烧时吸收大量的热量,避免环网电缆在火灾情况下燃烧对外界产生热释放的危害,而铜锌合金层一方面可以协助高阻燃防火层起到阻燃、防火的作用,进而减少热释放危害, 还可以利用铜锌合金层光滑坚硬的性质防止鼠咬危害。 The beneficial effects of the B1 - level 35kV ring network cable for the urban rail transit traction power supply system in the embodiment of the present invention include: the B1 - level 35kV ring network cable for the urban rail transit traction power supply system provided by the embodiment of the present invention includes a cable core assembly and a package The high flame retardant fireproof layer and the copper-zinc alloy layer covering the outside of the cable core assembly; among them, the high flame retardant fireproof layer can absorb a lot of heat when it encounters flame burning, so as to avoid the burning of the ring network cable in the event of fire to the outside world. On the one hand, the copper-zinc alloy layer can help the high flame-retardant fire-retardant layer to play a role of flame retardant and fire prevention, thereby reducing the heat-releasing hazard, and can also use the smooth and hard nature of the copper-zinc alloy layer to prevent rat bite hazards.
附图说明Description of drawings
为了更清楚地说明本发明实施例的技术方案,下面将对实施例中所需要使用的附图作简单地介绍,应当理解,以下附图仅示出了本发明的某些实施例,因此不应被看作是对范围的限定,对于本领域普通技术人员来讲,在不付出创造性劳动的前提下,还可以根据这些附图获得其他相关的附图。In order to illustrate the technical solutions of the embodiments of the present invention more clearly, the following briefly introduces the accompanying drawings used in the embodiments. It should be understood that the following drawings only show some embodiments of the present invention, and therefore do not It should be regarded as a limitation of the scope, and for those of ordinary skill in the art, other related drawings can also be obtained according to these drawings without any creative effort.
图1为本发明实施例中城市轨道交通牵引供电系统用B 1级35kV环网电缆的剖面结构示意图; 1 is a schematic cross-sectional structure diagram of a B 1 -level 35kV ring network cable used in an urban rail transit traction power supply system in an embodiment of the present invention;
图2为本发明实施例中城市轨道交通牵引供电系统用B 1级35kV环网电缆的制备工艺流程图。 FIG. 2 is a flow chart of the preparation process of the B 1 -level 35kV ring network cable for the traction power supply system of the urban rail transit in the embodiment of the present invention.
图标:010-城市轨道交通牵引供电系统用B1级35kV环网电缆;100-缆芯组件;210-高阻燃防火层;220-铜锌合金层;230-聚合物保护层;110-导体;120-保护层组;121-导体屏蔽层;122-交联聚乙烯绝缘层;123-绝缘屏蔽层;124-半导电阻水带;125-铜丝屏蔽层;126-阻燃绕包带层;127-防水层。Icon: 010-B1 class 35kV ring network cable for urban rail transit traction power supply system; 100-Cable core assembly; 210-High flame retardant fireproof layer; 220-Copper-zinc alloy layer; 230-Polymer protective layer; 110-Conductor; 120-protective layer group; 121-conductor shielding layer; 122-cross-linked polyethylene insulating layer; 123-insulating shielding layer; 124-semiconductor resistance water tape; 125-copper wire shielding layer; ; 127 - Waterproof layer.
具体实施方式detailed description
为使本发明实施例的目的、技术方案和优点更加清楚,下面将结合本发明实施例中的附图,对本发明实施例中的技术方案进行清楚、完整地描述,显然,所描述的实施例是本发明一部分实施例,而不是全部的实施例。通常在此处附图中描述和示出的本发明实施例的组件可以以各种不同的配置来布置和设计。In order to make the purposes, technical solutions and advantages of the embodiments of the present invention clearer, the technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the accompanying drawings in the embodiments of the present invention. Obviously, the described embodiments These are some embodiments of the present invention, but not all embodiments. The components of the embodiments of the invention generally described and illustrated in the drawings herein may be arranged and designed in a variety of different configurations.
因此,以下对在附图中提供的本发明的实施例的详细描述并非旨在限制要求保护的本发明的范围,而是仅仅表示本发明的选定实施例。基于本发明中的实施例,本领域普通技术人员在没有作出创造性劳动前提下所获得的所有其他实施例,都属于本发明保护的范围。Thus, the following detailed description of the embodiments of the invention provided in the accompanying drawings is not intended to limit the scope of the invention as claimed, but is merely representative of selected embodiments of the invention. Based on the embodiments of the present invention, all other embodiments obtained by those of ordinary skill in the art without creative efforts shall fall within the protection scope of the present invention.
在本发明的描述中,需要说明的是,术语“内”、“外”等指示的方位或位置关系为基于附图所示的方位或位置关系,或者是该发明产品使用时惯常 摆放的方位或位置关系,仅是为了便于描述本发明和简化描述,而不是指示或暗示所指的装置或元件必须具有特定的方位、以特定的方位构造和操作,因此不能理解为对本发明的限制。In the description of the present invention, it should be noted that the orientation or positional relationship indicated by the terms "inside", "outside", etc. is based on the orientation or positional relationship shown in the accompanying drawings, or is usually placed when the product of the invention is used. The orientation or positional relationship is only for the convenience of describing the present invention and simplifying the description, rather than indicating or implying that the referred device or element must have a specific orientation, be constructed and operated in a specific orientation, and therefore should not be construed as a limitation of the present invention.
在本发明的描述中,还需要说明的是,除非另有明确的规定和限定,术语“设置”、“连接”应做广义理解,例如,可以是固定连接,也可以是可拆卸连接,或一体地连接;可以是机械连接,也可以是电连接;可以是直接相连,也可以通过中间媒介间接相连,可以是两个元件内部的连通。对于本领域的普通技术人员而言,可以具体情况理解上述术语在本发明中的具体含义。In the description of the present invention, it should also be noted that, unless otherwise expressly specified and limited, the terms "arrangement" and "connection" should be understood in a broad sense, for example, it may be a fixed connection or a detachable connection, or It can be connected in one piece; it can be a mechanical connection or an electrical connection; it can be directly connected or indirectly connected through an intermediate medium, and it can be internal communication between two components. For those of ordinary skill in the art, the specific meanings of the above terms in the present invention can be understood in specific situations.
实施例1Example 1
请参照图1,本实施例提供一种城市轨道交通牵引供电系统用B 1级35kV环网电缆010,其能够用于室内、室外、地下、隧道、电缆桥架或经常被水浸泡的电缆沟、变电所电缆夹层等场所等,特别是用于轨道交通牵引供电系统,例如:主变电站到牵引变电站的出线电缆以及各牵引变电站之间的联络电缆等。 Please refer to FIG. 1 , this embodiment provides a B 1 -level 35kV ring network cable 010 for an urban rail transit traction power supply system, which can be used indoors, outdoors, underground, tunnels, cable trays or cable trenches that are often soaked in water, Substation cable interlayer and other places, especially for rail transit traction power supply system, such as: the outgoing cable from the main substation to the traction substation and the connection cable between the traction substations, etc.
城市轨道交通牵引供电系统用B 1级35kV环网电缆010包括缆芯组件100;进一步地,缆芯组件100包括导体110和包覆于导体110外的保护层组120,其中,导体110用于导电,保护层组120具有屏蔽、防水等作用。 The grade B 35kV ring network cable 010 for urban rail transit traction power supply system includes a cable core assembly 100; further, the cable core assembly 100 includes a conductor 110 and a protective layer group 120 wrapped around the conductor 110, wherein the conductor 110 is used for Conductive, the protective layer group 120 has the functions of shielding and waterproofing.
需要说明的是,上述导体110可以根据需要选择,例如可以是铜导体;进一步地,可以采用GB/T3956-2008标准规定的第2种绞合紧压铜导体,导体110表面光洁、无损伤绝缘的毛刺、锐边以及凸起或断裂的单线,在此不作具体限定。It should be noted that the above-mentioned conductor 110 can be selected according to needs, for example, it can be a copper conductor; further, the second type of twisted and compressed copper conductor specified in the GB/T3956-2008 standard can be used, and the conductor 110 has a smooth surface and no damage to insulation. burrs, sharp edges, and raised or broken single lines are not specifically limited here.
保护层组120包括导体110外依次包覆的导体屏蔽层121、交联聚乙烯绝缘层122(XLPE绝缘层)和绝缘屏蔽层123。The protective layer group 120 includes a conductor shielding layer 121 , a cross-linked polyethylene insulating layer 122 (XLPE insulating layer) and an insulating shielding layer 123 which are sequentially wrapped around the conductor 110 .
可选地,导体屏蔽层121可以采用35kV内屏料,性能应当符合GB/T12706.3-2008标准的规定。Optionally, the conductor shielding layer 121 can use a 35kV inner shielding material, and the performance should meet the requirements of the GB/T12706.3-2008 standard.
可选地,交联聚乙烯绝缘层122(XLPE绝缘层)可以采用35kV化学 交联绝缘料,性能应当符合GB/T12706.3-2008标准的规定。Optionally, the cross-linked polyethylene insulating layer 122 (XLPE insulating layer) can be made of 35kV chemically cross-linked insulating material, and the performance should meet the requirements of the GB/T12706.3-2008 standard.
可选地,绝缘屏蔽层123可以采用35kV不可剥离半导电外屏料,性能应当符合GB/T12706.3-2008标准的规定。Optionally, the insulating shielding layer 123 can use a 35kV non-peelable semi-conductive outer shielding material, and the performance should meet the requirements of the GB/T12706.3-2008 standard.
保护层组120还包括绝缘屏蔽层123外包覆的半导电阻水带124、以及半导电阻水带124外包覆的铜丝屏蔽层125。The protective layer group 120 further includes a semiconducting resistive water tape 124 covered by the insulating shielding layer 123 , and a copper wire shielding layer 125 covered by the semiconducting resistive water tape 124 .
需要说明的是,半导电阻水带124可以绕包在绝缘屏蔽层123外作为铜丝屏蔽的缓冲层。需要进一步说明的是,绝缘屏蔽层123外绕包的半导电阻水带124可以是一层、两层、三层等,在此不作具体限定;也就是说,绝缘屏蔽层123外可以单层绕包半导电阻水带124,也可以是多层绕包半导电阻水带124。It should be noted that the semiconducting resistance water tape 124 can be wrapped around the insulating shielding layer 123 as a buffer layer for copper wire shielding. It should be further noted that the semiconducting resistance water tape 124 wrapped around the insulating shielding layer 123 may be one layer, two layers, three layers, etc., which is not specifically limited here; that is, the insulating shielding layer 123 may be a single layer The wrapping semiconducting resistive water tape 124 may also be a multilayer wrapping semiconducting resistive water tape 124 .
可选地,铜丝屏蔽层125可以采用铜丝疏绕结构。需要说明的是,铜丝屏蔽截面积大小可以根据系统故障短路电流确定。Optionally, the copper wire shielding layer 125 may adopt a copper wire sparsely wound structure. It should be noted that the size of the copper wire shielding cross-sectional area can be determined according to the system fault short-circuit current.
保护层组120还包括铜丝屏蔽层125外包覆的阻燃绕包带层126;在铜丝屏蔽层125外绕包阻燃绕包带可以保护内层不受火焰灼烧。The protective layer group 120 further includes a flame retardant wrapping tape layer 126 covered by the copper wire shielding layer 125 ; wrapping the flame retardant wrapping tape around the copper wire shielding layer 125 can protect the inner layer from being burned by flames.
需要说明的是,铜丝屏蔽层125外绕包的阻燃绕包带的层数可以是一层、两层、三层等,在此不作具体限定;也就是说,铜丝屏蔽层125外可以单层绕包阻燃绕包带,也可以是多层绕包阻燃绕包带。It should be noted that the number of layers of flame retardant wrapping tapes wrapped around the copper wire shielding layer 125 may be one layer, two layers, three layers, etc., which is not specifically limited here; It can be a single-layer wrapping flame-retardant wrapping tape, or a multi-layer wrapping flame-retardant wrapping tape.
保护层组120还包括阻燃绕包带层126外包覆的防水层127,具体地,防水层127可以是铝塑防水层127。The protective layer group 120 further includes a waterproof layer 127 covered by the flame-retardant wrapping tape layer 126 . Specifically, the waterproof layer 127 may be an aluminum-plastic waterproof layer 127 .
可选地,铝塑防水层127可以采用纵包铝塑复合带结构。Optionally, the aluminum-plastic waterproof layer 127 may adopt a longitudinally-wrapped aluminum-plastic composite tape structure.
本实施例的城市轨道交通牵引供电系统用B 1级35kV环网电缆010还包括包覆于缆芯组件100外部的高阻燃防火层210和铜锌合金层220。其中,高阻燃防火层210能够在遇到火焰灼烧时吸收大量的热量,避免城市轨道交通牵引供电系统用B 1级35kV环网电缆010在火灾情况下燃烧对外界产生热释放的危害,而铜锌合金层220一方面可以协助高阻燃防火层210起到阻燃、防火的作用,进而减少热释放危害,还可以利用铜锌合金层220光滑坚硬的性质防止鼠咬危害。 The B1 level 35kV ring network cable 010 for the urban rail transit traction power supply system in this embodiment further includes a high flame-retardant fireproof layer 210 and a copper-zinc alloy layer 220 that are coated on the outside of the cable core assembly 100 . Among them, the high flame-retardant fireproof layer 210 can absorb a large amount of heat when it encounters flame burning, so as to avoid the danger of heat release to the outside world caused by the burning of the B 1 class 35kV ring network cable 010 for the traction power supply system of urban rail transit in the event of fire. On the one hand, the copper-zinc alloy layer 220 can assist the highly flame-retardant and fire-resistant layer 210 to play a flame-retardant and fire-resistant role, thereby reducing heat release hazards, and can also use the smooth and hard properties of the copper-zinc alloy layer 220 to prevent rat bite hazards.
进一步地,高阻燃防火层210夹设于缆芯组件100和铜锌合金层220之间,这样一来,可以利用位于高阻燃防火层210外部的铜锌合金层220防止高阻燃防火层210直接受到火焰的灼烧,进而确保在火灾等出现明火灼烧城市轨道交通牵引供电系统用B 1级35kV环网电缆010的情况下确保高阻燃防火层210能够充分的发挥其吸收大量热量的作用,以有效改善城市轨道交通牵引供电系统用B 1级35kV环网电缆010燃烧时对外界产生热释放的危害。 Further, the high flame retardant fireproof layer 210 is sandwiched between the cable core assembly 100 and the copper-zinc alloy layer 220, so that the copper-zinc alloy layer 220 located outside the high flame-retardant fireproof layer 210 can be used to prevent the high flame-retardant fireproof layer 220. The layer 210 is directly burned by the flame, so as to ensure that the high flame-retardant fire - proof layer 210 can fully exert its ability to absorb a large amount of fire in the event of an open flame such as a fire. The effect of heat can effectively improve the harm of heat release to the outside world when the B 1 -level 35kV ring network cable 010 is burned for the traction power supply system of urban rail transit.
需要说明的是,高阻燃防火层210夹设于缆芯组件100和铜锌合金层220之间,还可以使高阻燃防火层210位于铝塑防水层127的外部,纵包铝塑复合带结构的铝塑防水层127可以与挤包高阻燃防火层210共同组成铝塑综合防水层127,实现径向防水的特性,以进一步确保城市轨道交通牵引供电系统用B 1级35kV环网电缆010的防水性。 It should be noted that the high flame retardant fireproof layer 210 is sandwiched between the cable core assembly 100 and the copper-zinc alloy layer 220, and the high flame retardant fireproof layer 210 can also be located outside the aluminum-plastic waterproof layer 127, and the aluminum-plastic composite layer is longitudinally wrapped. The aluminum-plastic waterproof layer 127 with structure can be combined with the extruded high flame-retardant fireproof layer 210 to form the aluminum-plastic comprehensive waterproof layer 127 to realize the radial waterproof feature, so as to further ensure the B 1 class 35kV ring network for the traction power supply system of urban rail transit. Water resistance of cable 010.
可选地,高阻燃防火层210可以采用陶瓷化聚烯烃(高隔热陶瓷化聚烯烃)材料制成,该材料中添加了大量的陶瓷粉,燃烧热值低,在550℃左右的火焰烧蚀下瓷化生成的密闭多孔隙陶瓷结构,可以起到良好的隔热效果。同时,低温瓷化反应过程吸收了大量的热量,有效降低了缆芯组件100的绝缘屏蔽层123等绝缘材料的温度,有效降低了城市轨道交通牵引供电系统用B 1级35kV环网电缆010的热释放率和热释放总量。也就是说,采用陶瓷化聚烯烃材料一方面能够防止火焰烧穿高阻燃防火层210,对缆芯组件100起到保护作用;另一方面用于阻断绝缘屏蔽层123、XLPE绝缘层受热分解气体的外泄通道,防止内部气体外泄破坏外护层的完整性;外护层在经受火焰灼烧时,控制火焰的传播距离和外护层的热释放量。 Optionally, the high flame retardant fireproof layer 210 can be made of ceramicized polyolefin (high thermal insulation ceramicized polyolefin) material, a large amount of ceramic powder is added to the material, the combustion calorific value is low, and the flame at about 550 ° C is made. The closed porous ceramic structure generated by porcelainization under ablation can have a good thermal insulation effect. At the same time, the low-temperature porcelain reaction process absorbs a large amount of heat, which effectively reduces the temperature of the insulating materials such as the insulating shielding layer 123 of the cable core assembly 100, and effectively reduces the B 1 class 35kV ring network cable 010 used in the urban rail transit traction power supply system. Heat release rate and total heat release. That is to say, using the ceramicized polyolefin material can prevent the flame from burning through the high flame-retardant fireproof layer 210 on the one hand, and protect the cable core assembly 100; The leakage channel of the decomposed gas prevents the leakage of the internal gas from damaging the integrity of the outer sheath; when the outer sheath is burned by the flame, the propagation distance of the flame and the heat release of the outer sheath are controlled.
可选地,铜锌合金层220可以采用硬度较大的铜锌合金带材绕包于高阻燃防火层210的外部,一方面可以协助高阻燃防火层210完成其使命,另一方面光滑坚硬的合金材料可以防止大鼠啃咬缆芯。Optionally, the copper-zinc alloy layer 220 can be wrapped around the outside of the high flame-retardant fireproof layer 210 by using a copper-zinc alloy strip with a higher hardness. The hard alloy material prevents rats from chewing on the cable core.
需要说明的是,高阻燃防火层210外绕包的铜锌合金层220的层数可以是一层、两层或三层等,在此不作具体限定;也就是说,高阻燃防火层210外可以绕包单层的铜锌合金层220,也可以重叠绕包至少两层铜锌合金层220。It should be noted that the number of layers of the copper-zinc alloy layer 220 wrapped around the high flame retardant fireproof layer 210 may be one, two or three layers, etc., which is not specifically limited here; that is, the high flame retardant fireproof layer A single-layer copper-zinc alloy layer 220 can be wrapped outside the 210, or at least two copper-zinc alloy layers 220 can be overlapped and wrapped.
本实施例的城市轨道交通牵引供电系统用B 1级35kV环网电缆010还包括聚合物保护层230,聚合物保护层230为城市轨道交通牵引供电系统用B 1级35kV环网电缆010的最外层;进一步地,聚合物保护层230包覆在铜锌合金层220的外部,其具有防鼠防蚁防紫外线的作用。如此设置,使得城市轨道交通牵引供电系统用B 1级35kV环网电缆010同时具有防水、防火、防鼠、防白蚁和防紫外线的性能,以满足更多元的需求。 The B1 - level 35kV ring network cable 010 for the urban rail transit traction power supply system in this embodiment further includes a polymer protective layer 230, and the polymer protection layer 230 is the most important part of the B1 - level 35kV ring network cable 010 for the urban rail transit traction power supply system. Outer layer; further, the polymer protective layer 230 is coated on the outside of the copper-zinc alloy layer 220, which has the functions of anti-rat, anti-term and anti-ultraviolet. This setting makes the B 1 -level 35kV ring network cable 010 for urban rail transit traction power supply system simultaneously waterproof, fireproof, rodent-proof, termite-proof and UV-proof to meet more diverse needs.
可选地,聚合物保护层230可以采用低热值无卤低烟阻燃聚烯烃护套料,其该聚合物内添加了高效环保型防鼠蚁剂。Optionally, the polymer protective layer 230 may be a low calorific value, halogen-free, low-smoke flame retardant polyolefin sheath material, and an efficient and environmentally friendly anti-mouse and termite agent is added to the polymer.
进一步地,按照重量份计,聚合物保护层230的制备原料包括:Further, in parts by weight, the raw materials for preparing the polymer protective layer 230 include:
Figure PCTCN2020128229-appb-000001
Figure PCTCN2020128229-appb-000001
其中,乙烯-醋酸乙烯共聚物树脂(EVA)中醋酸乙烯酯(VA)的含量大致为35-45%;EVA-g-MA为马来酸酐改性EVA,目的起到偶联剂和分散促进剂,使超细化复合阻燃剂在树脂中分散更加均匀。Among them, the content of vinyl acetate (VA) in ethylene-vinyl acetate copolymer resin (EVA) is roughly 35-45%; EVA-g-MA is maleic anhydride modified EVA, and the purpose is to promote coupling agent and dispersion agent, so that the ultra-fine composite flame retardant is dispersed more uniformly in the resin.
上述超细化复合阻燃剂为超细化的氢氧化镁和氢氧化铝,采用超细化复合阻燃剂能够使其在树脂中分散性更好、更加均匀。氢氧化镁和氢氧化铝的重量比可以是1:1-1.5。The above-mentioned ultra-fine composite flame retardants are ultra-fine magnesium hydroxide and aluminum hydroxide, and the use of ultra-fine composite flame retardants can make the dispersion in the resin better and more uniform. The weight ratio of magnesium hydroxide to aluminum hydroxide may be 1:1-1.5.
需要说明的是,陶瓷化硼酸锌在燃烧过程中生成氧化锌促进成炭剂的形成,在氢氧化镁和氢氧化铝阻燃体系中能促进成炭并形成陶瓷化,即能够脱水碳化形成一定厚度和强度的碳层,阻断燃烧,有效起到抑烟、阻燃、抗滴落的作用。并且陶瓷化硼酸锌/氢氧化铝/氢氧化镁具有协同效应,具有优异的阻燃性能,以进一步提升城市轨道交通牵引供电系统用B 1级35kV环网电缆010的阻燃性能。 It should be noted that ceramized zinc borate generates zinc oxide during the combustion process to promote the formation of char-forming agent, and in the flame retardant system of magnesium hydroxide and aluminum hydroxide, it can promote char-forming and form ceramization, that is, it can be dehydrated and carbonized to form a certain The thickness and strength of the carbon layer block combustion, effectively play the role of smoke suppression, flame retardant, and anti dripping. And the ceramicized zinc borate/aluminum hydroxide/magnesium hydroxide has a synergistic effect and has excellent flame retardant performance, so as to further improve the flame retardant performance of B 1 class 35kV ring network cable 010 for urban rail transit traction power supply system.
上述复合补强剂包括炭黑、白炭黑、乙炔炭黑和硅藻土中的至少一种,进一步地,复合补强剂包括炭黑、白炭黑、乙炔炭黑和硅藻土中的任意两种。The above-mentioned composite reinforcing agent includes at least one of carbon black, white carbon black, acetylene carbon black and diatomaceous earth, and further, the composite reinforcing agent includes carbon black, white carbon black, acetylene carbon black and diatomaceous earth. any two.
上述复合润滑剂可以选用硬脂酸锌和羟基硅油中的至少一种;进一步地,复合润滑剂可以选用硬脂酸锌和羟基硅油,两者重量比可以是1:0.5-1.5。The above-mentioned composite lubricant can be selected from at least one of zinc stearate and hydroxy silicone oil; further, the composite lubricant can be selected from zinc stearate and hydroxy silicone oil, and the weight ratio of the two can be 1:0.5-1.5.
上述抗氧剂一般选用受阻酚类抗氧剂,可以是抗氧剂1076、抗氧剂264和抗氧剂1010等任意至少一种,在此不作具体限定;紫外线吸收剂一般选用苯酮类光稳定剂,可以是2-羟基-4-甲氧基二苯甲酮和2-羟基-4-正辛氧基二苯甲酮等任意至少一种,在此不作具体限定;环保防鼠剂一般选用辣椒素、辣椒碱和反式辣椒素等任意至少一种,在此不作具体限定;环保防白蚁剂一般选用氯吡硫磷和氨基甲酸酯等任意至少一种,在此不作具体限定。The above-mentioned antioxidants generally select hindered phenolic antioxidants, which can be any at least one such as antioxidant 1076, antioxidant 264 and antioxidant 1010, which are not specifically limited here; Stabilizer, can be any at least one such as 2-hydroxy-4-methoxy benzophenone and 2-hydroxy-4-n-octyloxy benzophenone, which is not specifically limited here; Select any at least one of capsaicin, capsaicin and trans-capsaicin, etc., which is not specifically limited here; the environmental protection termite agent generally selects any at least one such as chlorpyrifos and carbamate, which is not specifically limited here.
可选地,聚合物保护层230的制备方法包括:将各原料称量混合,转入双螺旋挤出机中进行挤出,温度为120~180℃,螺杆转速60~600转/分,再在120~140℃下造粒成型。Optionally, the preparation method of the polymer protective layer 230 includes: weighing and mixing each raw material, transferring it to a twin-screw extruder for extrusion, the temperature is 120-180° C., the screw speed is 60-600 rpm, and then Pelletize at 120-140°C.
本实施例中,聚合物保护层230的制备方法为:将30份乙烯-醋酸乙烯共聚物树脂、40份聚烯烃弹性体、5份相容剂、10份复合补强剂、1份复合润滑剂、10份陶瓷化硼酸锌、40份超细化复合阻燃剂、1份抗氧剂、1份过氧化二异丙苯、1份三烯丙基异氰脲酸酯、0.5份紫外线吸收剂、1份环保防白蚁剂、1份环保防鼠剂混合,转入双螺旋挤出机中进行挤出,温度 为120℃,螺杆转速60转/分,再在120℃下造粒成型。In this embodiment, the preparation method of the polymer protective layer 230 is as follows: 30 parts of ethylene-vinyl acetate copolymer resin, 40 parts of polyolefin elastomer, 5 parts of compatibilizer, 10 parts of composite reinforcing agent, 1 part of composite lubricant 10 parts of ceramic zinc borate, 40 parts of ultra-fine composite flame retardant, 1 part of antioxidant, 1 part of dicumyl peroxide, 1 part of triallyl isocyanurate, 0.5 part of ultraviolet absorber 1 part of environmental protection termite agent, 1 part of environmental protection rodent agent are mixed, transferred to a twin-screw extruder for extrusion, the temperature is 120 ° C, the screw speed is 60 rpm, and then pelletized at 120 ° C.
请参照图2,本实施例的城市轨道交通牵引供电系统用B 1级35kV环网电缆010制备工艺流程包括:利用三层共挤工艺在导体110的外部依次包覆导体屏蔽层121、交联聚乙烯绝缘层122和绝缘屏蔽层123;然后在绝缘屏蔽层123外包覆的半导电阻水带124;然后在半导电阻水带124外包覆的铜丝屏蔽层125;然后在铜丝屏蔽层125外包覆的阻燃绕包带层126;然后在阻燃绕包带层126外依次包覆的防水层127和高阻燃防火层210;然后在高阻燃防火层210外部包覆铜锌合金层220;最后在铜锌合金层220包覆聚合物保护层230;之后再进行成品检测。 Referring to FIG. 2 , the preparation process of the B 1 -level 35kV ring network cable 010 for the urban rail transit traction power supply system of the present embodiment includes: using a three-layer co-extrusion process to sequentially coat the conductor shielding layer 121 on the outside of the conductor 110, cross-linking The polyethylene insulating layer 122 and the insulating shielding layer 123; then the semiconducting resistance water tape 124 covered by the insulating shielding layer 123; then the copper wire shielding layer 125 covered by the semiconducting resistance water tape 124; then the copper wire The flame retardant wrapping tape layer 126 covered by the shielding layer 125; then the waterproof layer 127 and the high flame retardant fireproof layer 210 are sequentially wrapped outside the flame retardant wrapping tape layer 126; The copper-zinc alloy layer 220 is clad; finally, the copper-zinc alloy layer 220 is covered with a polymer protective layer 230; after that, the finished product inspection is performed.
本实施例的城市轨道交通牵引供电系统用B 1级35kV环网电缆010检测结果如下: The test results of the B 1 -level 35kV ring network cable 010 used in the urban rail transit traction power supply system of this embodiment are as follows:
1、20℃时城市轨道交通牵引供电系统用B 1级35kV环网电缆010的导体110直流电阻符合GB/T 3956-2008的规定。 1. The DC resistance of conductor 110 of B 1 35kV ring network cable 010 for urban rail transit traction power supply system at 20°C meets the requirements of GB/T 3956-2008.
2、城市轨道交通牵引供电系统用B 1级35kV环网电缆010的阻燃性能:按照GB 31247-2014规定的试验方法进行测定,测得结果满足B 1级的分级判据;燃烧滴落物/微粒等级满足d 0级,即1200s内无燃烧滴落物/微粒;烟气毒性等级满足t 0级,即达到ZA 2级;腐蚀性等级满足a 1级,即电导率≤2.5μs/mm,PH≥4.3。 2. Flame retardant performance of B 1 grade 35kV ring network cable 010 for urban rail transit traction power supply system: measured according to the test method specified in GB 31247-2014, and the measured results meet the B 1 grade classification criterion; burning dripping objects / The particle level meets d 0 level, that is, there is no burning droplets/particles within 1200s; the flue gas toxicity level meets t 0 level, that is, ZA level 2 ; the corrosiveness level meets a 1 level, that is, the electrical conductivity ≤ 2.5μs/mm , PH≥4.3.
3、城市轨道交通牵引供电系统用B 1级35kV环网电缆010的径向阻水性能:城市轨道交通牵引供电系统用B 1级35kV环网电缆010样品在水中浸泡72小时后,去除绝缘层外面的复合层后,用肉眼观察,绝缘层外表面是干燥的。 3. Radial water blocking performance of B 1 class 35kV ring network cable 010 for urban rail transit traction power supply system: After soaking the B 1 class 35kV ring network cable 010 sample in water for 72 hours, the insulation layer was removed After the outer composite layer, visually observe that the outer surface of the insulating layer is dry.
4、城市轨道交通牵引供电系统用B 1级35kV环网电缆010的防鼠性能:按照JB/T 10696.10-2011的规定进行大鼠啃咬试验,防护等级达到“显著”,即防护率≥0.9,无齿痕或轻齿痕。 4. The anti-rat performance of B 1 class 35kV ring network cable 010 for urban rail transit traction power supply system: according to the regulations of JB/T 10696.10-2011, the rat gnawing test is carried out, and the protection level reaches "significant", that is, the protection rate is ≥ 0.9 , no dents or light dents.
5、城市轨道交通牵引供电系统用B 1级35kV环网电缆010的防白蚁性能:按照JB/T 10696.9-2011的规定“实验群体法”进行白蚁试验,蛀蚀等级达到1级,即无齿痕。 5. Anti-termite performance of class B 1 35kV ring network cable 010 for urban rail transit traction power supply system: Termite test was conducted in accordance with the provisions of JB/T 10696.9-2011 "Experimental Colony Method", and the decay level reached level 1, that is, no tooth marks. .
6、城市轨道交通牵引供电系统用B 1级35kV环网电缆010的防紫外线性能:按照GB/T 12527-2008的规定进行人工耐气候老化试验(氙灯法),经过42天的老化后,护套抗张强度变化率和断裂伸长率变化率符合标准的规定。 6. Anti-ultraviolet performance of class B 1 35kV ring network cable 010 for urban rail transit traction power supply system: perform artificial weather resistance aging test (xenon lamp method) in accordance with the provisions of GB/T 12527-2008, after 42 days of aging, protect the The rate of change in tensile strength and the rate of change in elongation at break conform to the standard.
实施例2Example 2
实施例2与实施例1类似,不同之处在于聚合物防护层的具体制备方法,实施例2中聚合物保护层230的制备方法为:将50份乙烯-醋酸乙烯共聚物树脂、70份聚烯烃弹性体、15份相容剂、30份复合补强剂、5份复合润滑剂、20份陶瓷化硼酸锌、80份超细化复合阻燃剂、5份抗氧剂、3份过氧化二异丙苯、3份三烯丙基异氰脲酸酯、2份紫外线吸收剂、5份环保防白蚁剂、5份环保防鼠剂混合,转入双螺旋挤出机中进行挤出,温度为180℃,螺杆转速600转/分,再在140℃下造粒成型。Example 2 is similar to Example 1, the difference lies in the specific preparation method of the polymer protective layer, the preparation method of the polymer protective layer 230 in Example 2 is: 50 parts of ethylene-vinyl acetate copolymer resin, 70 parts of poly Olefin elastomer, 15 parts of compatibilizer, 30 parts of composite reinforcing agent, 5 parts of composite lubricant, 20 parts of ceramic zinc borate, 80 parts of ultrafine composite flame retardant, 5 parts of antioxidant, 3 parts of peroxide Dicumylbenzene, 3 parts of triallyl isocyanurate, 2 parts of ultraviolet absorber, 5 parts of environmental protection termite repellant, 5 parts of environmental protection rodent repellant were mixed, transferred to a twin-screw extruder for extrusion, The temperature is 180°C, the screw speed is 600 rpm, and the pellets are formed at 140°C.
其中,乙烯-醋酸乙烯共聚物树脂中含有40%的VA;超细化复合阻燃剂包括重量比为1:1的氢氧化铝和氢氧化镁;复合补强剂包括重量比为1:1.5的炭黑和白炭黑;复合润滑剂包括重量比为1:1.5的硬脂酸锌、羟基硅油;抗氧剂包括抗氧剂1076;紫外线吸收剂包括2-羟基-4-甲氧基二苯甲酮;环保防鼠剂包括辣椒素;环保防白蚁剂包括氯吡硫磷。Among them, the ethylene-vinyl acetate copolymer resin contains 40% VA; the ultra-fine composite flame retardant includes aluminum hydroxide and magnesium hydroxide in a weight ratio of 1:1; the composite reinforcing agent includes a weight ratio of 1:1.5 carbon black and white carbon black; composite lubricants include zinc stearate, hydroxy silicone oil in a weight ratio of 1:1.5; antioxidants include antioxidant 1076; UV absorbers include 2-hydroxy-4-methoxydiol Benzophenone; environmentally friendly rodent repellents include capsaicin; environmentally friendly termite control agents include chlorpyrifos.
实施例3Example 3
实施例3与实施例1类似,不同之处在于聚合物防护层的具体制备方法,实施例3中聚合物保护层230的制备方法为:将40份乙烯-醋酸乙烯共聚物树脂、50份聚烯烃弹性体、10份相容剂、20份复合补强剂、3份复合润滑剂、15份陶瓷化硼酸锌、70份超细化复合阻燃剂、3份抗氧剂、2份过氧化二异丙苯、2份三烯丙基异氰脲酸酯、1份紫外线吸收剂、3份环保防白蚁剂、3份环保防鼠剂混合,转入双螺旋挤出机中进行挤出,温度为150℃,螺杆转速200转/分,再在130℃下造粒成型。Example 3 is similar to Example 1, the difference lies in the specific preparation method of the polymer protective layer. The preparation method of the polymer protective layer 230 in Example 3 is: 40 parts of ethylene-vinyl acetate copolymer resin, 50 parts of poly Olefin elastomer, 10 parts of compatibilizer, 20 parts of composite reinforcing agent, 3 parts of composite lubricant, 15 parts of ceramic zinc borate, 70 parts of ultrafine composite flame retardant, 3 parts of antioxidant, 2 parts of peroxide Dicumylbenzene, 2 parts of triallyl isocyanurate, 1 part of ultraviolet absorber, 3 parts of environmentally friendly termite repellant, and 3 parts of environmentally friendly rodent repellant were mixed and transferred to a twin-screw extruder for extrusion. The temperature is 150°C, the screw speed is 200 rpm, and the pellets are formed at 130°C.
其中,乙烯-醋酸乙烯共聚物树脂中含有35%的VA;超细化复合阻燃剂包括重量比为1:1.5的氢氧化铝和氢氧化镁;复合补强剂包括重量比为1:1的乙炔炭黑或硅藻土;复合润滑剂包括重量比为1:0.5的硬脂酸锌、羟基硅 油;抗氧剂包括抗氧剂264;紫外线吸收剂包括2-羟基-4-正辛氧基二苯甲酮;环保防鼠剂包括辣椒碱和反式辣椒素;环保防白蚁剂包括氨基甲酸酯。Among them, the ethylene-vinyl acetate copolymer resin contains 35% VA; the ultrafine composite flame retardant includes aluminum hydroxide and magnesium hydroxide in a weight ratio of 1:1.5; the composite reinforcing agent includes a weight ratio of 1:1 acetylene carbon black or diatomaceous earth; the composite lubricant includes zinc stearate and hydroxy silicone oil in a weight ratio of 1:0.5; the antioxidant includes antioxidant 264; the ultraviolet absorber includes 2-hydroxy-4-n-octyloxy benzophenone; environmentally friendly rodent repellants include capsaicin and trans-capsaicin; environmentally friendly termite inhibitors include carbamates.
实施例4Example 4
实施例4与实施例1类似,不同之处在于聚合物防护层的具体制备方法,实施例4中聚合物保护层230的制备方法为:将40份乙烯-醋酸乙烯共聚物树脂、50份聚烯烃弹性体、12份相容剂、16份复合补强剂、4份复合润滑剂、12份陶瓷化硼酸锌、56份超细化复合阻燃剂、2份抗氧剂、3份过氧化二异丙苯、1份三烯丙基异氰脲酸酯、0.8份紫外线吸收剂、4份环保防白蚁剂、3份环保防鼠剂混合,转入双螺旋挤出机中进行挤出,温度为170℃,螺杆转速400转/分,再在125℃下造粒成型。Example 4 is similar to Example 1, the difference lies in the specific preparation method of the polymer protective layer. The preparation method of the polymer protective layer 230 in Example 4 is: 40 parts of ethylene-vinyl acetate copolymer resin, 50 parts of poly Olefin elastomer, 12 parts of compatibilizer, 16 parts of composite reinforcing agent, 4 parts of composite lubricant, 12 parts of ceramic zinc borate, 56 parts of ultrafine composite flame retardant, 2 parts of antioxidant, 3 parts of peroxide Dicumyl benzene, 1 part of triallyl isocyanurate, 0.8 part of ultraviolet absorber, 4 parts of environmental protection termite agent, and 3 parts of environmental protection rodent repellant were mixed and transferred to a twin-screw extruder for extrusion. The temperature is 170°C, the screw speed is 400 rpm, and the pellets are formed at 125°C.
其中,乙烯-醋酸乙烯共聚物树脂中含有45%的VA;超细化复合阻燃剂包括重量比为1:1.2的氢氧化铝和氢氧化镁;复合补强剂包括重量比为1:1.5的炭黑和硅藻土;复合润滑剂包括重量比为1:0.8的硬脂酸锌、羟基硅油;抗氧剂包括抗氧剂1010;紫外线吸收剂包括2-羟基-4-甲氧基二苯甲酮和2-羟基-4-正辛氧基二苯甲酮;环保防鼠剂包括反式辣椒素;环保防白蚁剂包括氯吡硫磷和氨基甲酸酯。Among them, the ethylene-vinyl acetate copolymer resin contains 45% VA; the ultra-fine composite flame retardant includes aluminum hydroxide and magnesium hydroxide in a weight ratio of 1:1.2; the composite reinforcing agent includes a weight ratio of 1:1.5 of carbon black and diatomaceous earth; the composite lubricant includes zinc stearate and hydroxy silicone oil in a weight ratio of 1:0.8; the antioxidant includes antioxidant 1010; the ultraviolet absorber includes 2-hydroxy-4-methoxydiol Benzophenone and 2-hydroxy-4-n-octyloxybenzophenone; environmental rodent repellents include trans-capsaicin; environmental termite repellents include chlorpyrifos and carbamates.
实施例5Example 5
实施例5与实施例1类似,不同之处在于聚合物防护层的具体制备方法,实施例5中聚合物保护层230的制备方法为:将35份乙烯-醋酸乙烯共聚物树脂、55份聚烯烃弹性体、8份相容剂、22份复合补强剂、3份复合润滑剂、16份陶瓷化硼酸锌、65份超细化复合阻燃剂、2份抗氧剂、1份过氧化二异丙苯、3份三烯丙基异氰脲酸酯、1份紫外线吸收剂、2份环保防白蚁剂、5份环保防鼠剂混合,转入双螺旋挤出机中进行挤出,温度为140℃,螺杆转速100转/分,再在135℃下造粒成型。Example 5 is similar to Example 1, the difference lies in the specific preparation method of the polymer protective layer, the preparation method of the polymer protective layer 230 in Example 5 is: 35 parts of ethylene-vinyl acetate copolymer resin, 55 parts of poly Olefin elastomer, 8 parts of compatibilizer, 22 parts of composite reinforcing agent, 3 parts of composite lubricant, 16 parts of ceramic zinc borate, 65 parts of ultrafine composite flame retardant, 2 parts of antioxidant, 1 part of peroxide Dicumylbenzene, 3 parts of triallyl isocyanurate, 1 part of ultraviolet absorber, 2 parts of environmental protection termite repellant, 5 parts of environmental protection rodent repellant were mixed, transferred to a twin-screw extruder for extrusion, The temperature is 140°C, the screw speed is 100 rpm, and then the pellets are formed at 135°C.
其中,乙烯-醋酸乙烯共聚物树脂中含有41%的VA;超细化复合阻燃剂包括重量比为1:1.1的氢氧化铝和氢氧化镁;复合补强剂包括重量比为1:1:1:1的炭黑、白炭黑、乙炔炭黑和硅藻土;复合润滑剂包括羟基硅油;抗氧剂包括抗氧剂1076、抗氧剂264和抗氧剂1010;紫外线吸收剂包括2- 羟基-4-甲氧基二苯甲酮;环保防鼠剂包括辣椒素;环保防白蚁剂包括氯吡硫磷。Among them, the ethylene-vinyl acetate copolymer resin contains 41% VA; the ultra-fine composite flame retardant includes aluminum hydroxide and magnesium hydroxide in a weight ratio of 1:1.1; the composite reinforcing agent includes a weight ratio of 1:1 : 1:1 carbon black, white carbon black, acetylene carbon black and diatomaceous earth; composite lubricants include hydroxy silicone oil; antioxidants include antioxidant 1076, antioxidant 264 and antioxidant 1010; UV absorbers include 2-Hydroxy-4-methoxybenzophenone; environment-friendly rodent repellents include capsaicin; environment-friendly termite repellents include chlorpyrifos.
综上所述,本发明提供的城市轨道交通牵引供电系统用B 1级35kV环网电缆010能够利用高阻燃防火层210在遇到火焰灼烧时吸收大量的热量,避免城市轨道交通牵引供电系统用B 1级35kV环网电缆010在火灾情况下燃烧对外界产生热释放的危害,而铜锌合金层220一方面可以协助高阻燃防火层210起到阻燃、防火的作用,进而减少热释放危害,还可以利用铜锌合金层220光滑坚硬的性质防止鼠咬危害。 To sum up, the class B 1 35kV ring network cable 010 for the urban rail transit traction power supply system provided by the present invention can utilize the high flame retardant fireproof layer 210 to absorb a large amount of heat when encountering flame burning, so as to avoid urban rail transit traction power supply. The system uses B 1 class 35kV ring network cable 010 to burn in the event of fire, which will cause heat release to the outside world. On the one hand, the copper-zinc alloy layer 220 can assist the high flame-retardant fire-retardant layer 210 to play the role of flame-retardant and fire-proof, thereby reducing the risk of fire. The heat release hazard can also be prevented by the smooth and hard nature of the copper-zinc alloy layer 220 to prevent rat bite hazard.
以上仅为本发明的优选实施例而已,并不用于限制本发明,对于本领域的技术人员来说,本发明可以有各种更改和变化。凡在本发明的精神和原则之内,所作的任何修改、等同替换、改进等,均应包含在本发明的保护范围之内。The above are only preferred embodiments of the present invention, and are not intended to limit the present invention. For those skilled in the art, the present invention may have various modifications and changes. Any modification, equivalent replacement, improvement, etc. made within the spirit and principle of the present invention shall be included within the protection scope of the present invention.

Claims (10)

  1. 一种城市轨道交通牵引供电系统用B 1级35kV环网电缆,其特征在于,包括缆芯组件和包覆于所述缆芯组件外部的高阻燃防火层和铜锌合金层。 A class B 1 35kV ring network cable for urban rail transit traction power supply system is characterized in that it includes a cable core assembly, a high flame retardant fireproof layer and a copper-zinc alloy layer coated on the outside of the cable core assembly.
  2. 根据权利要求1所述的城市轨道交通牵引供电系统用B 1级35kV环网电缆,其特征在于,所述高阻燃防火层夹设于所述缆芯组件和所述铜锌合金层之间。 The class B 1 35kV ring network cable for urban rail transit traction power supply system according to claim 1, wherein the high flame retardant fireproof layer is sandwiched between the cable core assembly and the copper-zinc alloy layer .
  3. 根据权利要求1所述的城市轨道交通牵引供电系统用B 1级35kV环网电缆,其特征在于,所述高阻燃防火层由陶瓷化聚烯烃材料制成。 The B 1 grade 35kV ring network cable for urban rail transit traction power supply system according to claim 1, characterized in that, the high flame retardant fireproof layer is made of ceramicized polyolefin material.
  4. 根据权利要求1所述的城市轨道交通牵引供电系统用B 1级35kV环网电缆,其特征在于,所述城市轨道交通牵引供电系统用B 1级35kV环网电缆还包括聚合物保护层,所述聚合物保护层为所述城市轨道交通牵引供电系统用B 1级35kV环网电缆的最外层。 The B1-level 35kV ring network cable for urban rail transit traction power supply system according to claim 1 , characterized in that, the B1 - level 35kV ring network cable for urban rail transit traction power supply system further comprises a polymer protective layer, so the The polymer protective layer is the outermost layer of the B 1 -level 35kV ring network cable used in the urban rail transit traction power supply system.
  5. 根据权利要求4所述的城市轨道交通牵引供电系统用B 1级35kV环网电缆,其特征在于,按照重量份计,所述聚合物保护层的制备原料包括:30-50份乙烯-醋酸乙烯共聚物树脂、40-70份聚烯烃弹性体、5-15份相容剂、10-30份复合补强剂、1-5份复合润滑剂、10-20份陶瓷化硼酸锌、40-80份超细化复合阻燃剂、1-5份抗氧剂、1-3份过氧化二异丙苯、1-3份三烯丙基异氰脲酸酯、0.5-2份紫外线吸收剂、1-5份环保防白蚁剂、1-5份环保防鼠剂。 The B 1 grade 35kV ring network cable for urban rail transit traction power supply system according to claim 4, characterized in that, in parts by weight, the preparation raw materials of the polymer protective layer include: 30-50 parts of ethylene-vinyl acetate Copolymer resin, 40-70 parts of polyolefin elastomer, 5-15 parts of compatibilizer, 10-30 parts of composite reinforcing agent, 1-5 parts of composite lubricant, 10-20 parts of ceramic zinc borate, 40-80 parts parts of ultra-fine composite flame retardant, 1-5 parts of antioxidant, 1-3 parts of dicumyl peroxide, 1-3 parts of triallyl isocyanurate, 0.5-2 parts of ultraviolet absorber, 1-5 parts of environmental protection termite agent, 1-5 parts of environmental protection rodent agent.
  6. 根据权利要求5所述的城市轨道交通牵引供电系统用B 1级35kV环网电缆,其特征在于,所述超细化复合阻燃剂包括氢氧化镁和氢氧化铝。 The B 1 -level 35kV ring network cable for urban rail transit traction power supply system according to claim 5, wherein the ultra-fine composite flame retardant comprises magnesium hydroxide and aluminum hydroxide.
  7. 根据权利要求1所述的城市轨道交通牵引供电系统用B 1级35kV环网电缆,其特征在于,所述缆芯组件包括导体和包覆于所述导体外的保护层组。 The B 1 -level 35kV ring network cable for urban rail transit traction power supply system according to claim 1, characterized in that, the cable core assembly includes a conductor and a protective layer group wrapped around the conductor.
  8. 根据权利要求7所述的城市轨道交通牵引供电系统用B 1级35kV环网电缆,其特征在于,所述保护层组包括所述导体外依次包覆的导体屏蔽层、交联聚乙烯绝缘层和绝缘屏蔽层,且所述高阻燃防火层和所述铜锌合金层均分布于所述绝缘屏蔽层的外侧。 The B1 - level 35kV ring network cable for urban rail transit traction power supply system according to claim 7, wherein the protective layer group comprises a conductor shielding layer and a cross-linked polyethylene insulating layer that are sequentially wrapped outside the conductor. and an insulating shielding layer, and both the high flame retardant fireproof layer and the copper-zinc alloy layer are distributed on the outer side of the insulating shielding layer.
  9. 根据权利要求8所述的城市轨道交通牵引供电系统用B 1级35kV环网电缆,其特征在于,所述保护层组还包括所述绝缘屏蔽层外依次包覆的半导电阻水带和铜丝屏蔽层,且所述高阻燃防火层和所述铜锌合金层均分布于所述铜丝屏蔽层的外侧。 The B 1 -level 35kV ring network cable for urban rail transit traction power supply system according to claim 8, characterized in that, the protective layer group further comprises semiconducting resistance water tape and copper wire which are sequentially wrapped outside the insulating shielding layer. A wire shielding layer, and the high flame retardant fireproof layer and the copper-zinc alloy layer are both distributed on the outer side of the copper wire shielding layer.
  10. 根据权利要求9所述的城市轨道交通牵引供电系统用B 1级35kV环网电缆,其特征在于,所述保护层组还包括所述铜丝屏蔽层外依次包覆的阻燃绕包带层和防水层,且所述高阻燃防火层和所述铜锌合金层均分布于所述防水层的外侧。 The B 1 -level 35kV ring network cable for the traction power supply system of urban rail transit according to claim 9, wherein the protective layer group further comprises a flame retardant wrapping tape layer sequentially wrapped outside the copper wire shielding layer and a waterproof layer, and both the high flame retardant fireproof layer and the copper-zinc alloy layer are distributed on the outer side of the waterproof layer.
PCT/CN2020/128229 2020-08-18 2020-11-12 B1-level 35kv looped network cable for urban rail transit traction power supply system WO2022036888A1 (en)

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CN111834041A (en) * 2020-08-18 2020-10-27 江苏亨通电力电缆有限公司 Urban rail transit pulls B for power supply system135 kV-level ring network cable
CN112435787A (en) * 2020-11-05 2021-03-02 江苏亨通电力电缆有限公司 Torsion-resistant cable for 66kV fan power transmission and preparation method and application thereof
CN112876758A (en) * 2021-01-13 2021-06-01 江苏亨通电力电缆有限公司 B1-level control cable for power equipment and manufacturing process

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