WO2022024785A1 - Cell constituent element, storage cell, assembled cell, and electric vehicle - Google Patents

Cell constituent element, storage cell, assembled cell, and electric vehicle Download PDF

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Publication number
WO2022024785A1
WO2022024785A1 PCT/JP2021/026644 JP2021026644W WO2022024785A1 WO 2022024785 A1 WO2022024785 A1 WO 2022024785A1 JP 2021026644 W JP2021026644 W JP 2021026644W WO 2022024785 A1 WO2022024785 A1 WO 2022024785A1
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WO
WIPO (PCT)
Prior art keywords
separator
negative electrode
foot
battery
electrode plate
Prior art date
Application number
PCT/JP2021/026644
Other languages
French (fr)
Japanese (ja)
Inventor
智紀 武部
Original Assignee
昭和電工マテリアルズ株式会社
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Publication of WO2022024785A1 publication Critical patent/WO2022024785A1/en

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/06Lead-acid accumulators
    • H01M10/12Construction or manufacture
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/10Primary casings, jackets or wrappings of a single cell or a single battery
    • H01M50/102Primary casings, jackets or wrappings of a single cell or a single battery characterised by their shape or physical structure
    • H01M50/112Monobloc comprising multiple compartments
    • H01M50/114Monobloc comprising multiple compartments specially adapted for lead-acid cells
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/40Separators; Membranes; Diaphragms; Spacing elements inside cells
    • H01M50/46Separators, membranes or diaphragms characterised by their combination with electrodes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/40Separators; Membranes; Diaphragms; Spacing elements inside cells
    • H01M50/463Separators, membranes or diaphragms characterised by their shape
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/40Separators; Membranes; Diaphragms; Spacing elements inside cells
    • H01M50/463Separators, membranes or diaphragms characterised by their shape
    • H01M50/466U-shaped, bag-shaped or folded
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

Definitions

  • This disclosure relates to battery components, storage batteries, assembled batteries and electric vehicles.
  • Patent Document 1 discloses a method for manufacturing an electrode plate containing a bag separator.
  • the electrode plate is sandwiched by bending the separator.
  • a bag-shaped separator is provided by forming a plurality of welded portions on the separator.
  • An object of one aspect of the present disclosure is to provide battery components, storage batteries, assembled batteries and electric vehicles capable of satisfactorily preventing damage to the separator.
  • the battery components according to one aspect of the present disclosure include a first electrode plate and a separator that overlap each other in the first direction, and the first electrode plate is along a second direction orthogonal to the first direction with the main body portion. It has a foot portion that protrudes from the main body and is covered with a separator, and the separator has a base portion having a first thickness and a thick portion having a second thickness thicker than the first thickness and abutting on the foot portion. And prepare.
  • the foot of the first electrode plate is covered with a separator. Therefore, for example, when the first electrode plate is housed in the battery case, the load tends to be concentrated on the portion of the separator that comes into contact with the foot portion.
  • the thick portion of the separator abuts on the foot portion. As a result, the load-bearing performance of the portion of the separator that comes into contact with the foot portion is satisfactorily improved. Therefore, according to the above aspect, damage to the separator can be satisfactorily prevented.
  • the separator further comprises a first main surface facing the first electrode plate, the thick portion has a first rib projecting from the first main surface toward the first electrode plate, and the first rib is a foot. It may come into contact with the portion. In this case, it becomes difficult for the base of the separator to come into contact with the foot.
  • the thick portion may have a plurality of first ribs, and the foot portion may abut on two or more first ribs. In this case, the base of the separator is less likely to come into contact with the foot.
  • the separator may further include a second main surface located on the opposite side of the first main surface, and the thick portion may have a second rib protruding from the second main surface to the opposite side of the first rib.
  • the first part and the second part of the separator are joined to each other, and each of the first part and the second part may face the foot part in the second direction. In this case, the foot is less likely to be exposed from the separator.
  • the first part and the second part may be welded to each other.
  • the first portion and the second portion can be firmly joined.
  • the dimensions of the first portion and the second portion in the third direction orthogonal to the first direction and the second direction may be equal to or larger than the dimensions of the foot portion in the third direction. In this case, the foot portion is less likely to be exposed except at the portion where the first portion and the second portion are joined in the separator.
  • the separator may be folded back on the foot side of the first electrode plate in the second direction.
  • the foot can be well covered by the folded portion of the separator.
  • the separator may have an opening located on the foot side of the first electrode plate in the second direction. For example, when the battery component and the electrolytic solution are housed in the battery case, the electrolytic solution tends to flow in the battery component.
  • the corners of the foot may be chamfered. In this case, it is possible to suppress the load concentration from the foot portion to a specific portion of the thick portion, as compared with the embodiment in which the foot portion is provided with an unchamfered angle, for example.
  • the thickness of the foot in the first direction is smaller than the thickness of the maximum thickness of the first electrode in the first direction, and the foot is located between one end and the other end of the first electrode in the first direction. You may. For example, when the battery component is laid down and the battery component is transported by using a transport device such as a belt conveyor, the foot portion is separated from the transport device. Therefore, it becomes difficult for the separator to be sandwiched between the foot and the transport device. Therefore, it is possible to suppress damage to the separator caused by the foot during transportation of the battery component.
  • the storage battery includes the battery component and an electric tank in which the battery component is housed, and the battery component is laminated on the first electrode plate via a separator in the first direction.
  • the second electrode plate is further provided, and the thick portion is sandwiched between the foot portion and the bottom portion of the battery case.
  • This storage battery includes battery components that can satisfactorily prevent breakage of the separator.
  • the separator is less likely to be damaged when the battery components are housed in the battery case. Therefore, it is possible to satisfactorily suppress a short circuit between the first electrode plate and the second electrode plate that are laminated with each other via the separator.
  • the battery case has a clasp that is provided on the bottom and protrudes along the second direction, and the thick portion may be sandwiched between the foot and the clasp. In this case, damage to the separator is suppressed by sandwiching the thick portion between the foot portion and the bracket.
  • the size of the foot in the first direction and the third direction orthogonal to the second direction may be larger than the size of the clasp in the third direction.
  • the load is less likely to be concentrated from the foot portion to the specific portion of the bracket, so that the thick portion is less likely to be damaged satisfactorily.
  • the size of the foot in the first direction and the third direction orthogonal to the second direction may be less than or equal to the size of the clasp in the third direction. In this case, even if the position of the battery component in the battery case is displaced, the thick portion is likely to be sandwiched between the foot portion and the bracket.
  • the above storage battery may be a lead storage battery.
  • the assembled battery according to one aspect of the present disclosure includes the above-mentioned storage battery.
  • the assembled battery comprises a storage battery that includes battery components that can satisfactorily prevent breakage of the separator. Therefore, in the storage battery, it is possible to satisfactorily suppress a short circuit between the first electrode plate and the second electrode plate laminated with each other via the separator.
  • the electric vehicle according to one aspect of the present disclosure is equipped with the above-mentioned assembled battery.
  • This electric vehicle comprises a storage battery that includes a battery component that can satisfactorily prevent breakage of the separator. Therefore, in the storage battery, it is possible to satisfactorily suppress a short circuit between the first electrode plate and the second electrode plate laminated with each other via the separator.
  • a battery component a storage battery, an assembled battery and an electric vehicle capable of satisfactorily preventing damage to the separator.
  • FIG. 1 is a perspective view showing a part of the storage battery according to the embodiment broken.
  • FIG. 2 is a plan view showing a negative electrode according to an embodiment.
  • FIG. 3 is a cross-sectional view taken along the line III-III of FIG.
  • FIG. 4A is a plan view showing a separator sheet
  • FIG. 4B is a schematic cross-sectional view taken along the line IVb-IVb of FIG. 4A.
  • 5A is a plan view showing the bottom of the main body
  • FIG. 5B is a schematic cross-sectional view taken along the line Vb-Vb of FIG. 5A
  • FIG. c) is a schematic cross-sectional view taken along the line Vc-Vc of FIG. 5 (a).
  • FIG. 5A is a plan view showing the bottom of the main body
  • FIG. 5B is a schematic cross-sectional view taken along the line Vb-Vb of FIG. 5A
  • FIG. c) is a schematic cross-sectional view taken along
  • FIG. 6 is a plan view showing a negative electrode wrapped in a separator.
  • FIG. 7A is an enlarged view of the region surrounded by the alternate long and short dash line shown in FIG. 6, and FIG. 7B is a cross-sectional view taken along the line VIIb-VIIb of FIG. 7A.
  • Is. 8 (a) is a cross-sectional view taken along the line VIIIa-VIIIa of FIG. 7 (a)
  • FIG. 8 (b) is a cross-sectional view taken along the line VIIIb-VIIIb of FIG. 7 (a). It is a figure.
  • FIG. 9 is an enlarged cross-sectional view of a main part of the storage battery.
  • FIG. 9 is an enlarged cross-sectional view of a main part of the storage battery.
  • FIG. 10A is an enlarged cross-sectional view of a main part of the separator and the negative electrode according to the first modification
  • FIG. 10B is an enlarged cross-sectional view of the main part of the separator and the negative electrode according to the second modification.
  • FIG. 11 is a plan view showing a negative electrode wrapped in the separator according to the third modification.
  • FIG. 1 is a perspective view showing a part of the storage battery according to the present embodiment broken.
  • the storage battery 1 is, for example, a control valve type lead storage battery.
  • the storage battery 1 is used, for example, as a battery of an automobile, a backup power source used in the event of a power failure, and a main power source of an electric vehicle (or an electric vehicle) such as an electric forklift.
  • an assembled battery composed of a plurality of storage batteries 1 may be used.
  • the electric vehicle may have an assembled battery including a plurality of storage batteries 1.
  • the storage battery 1 is, for example, a clad-type lead-acid battery provided with a clad-type electrode.
  • the storage battery 1 includes an electrode group 3, a positive electrode terminal 5A, a negative electrode terminal 5B, a water tap 6, and a case 7.
  • the electrode group 3 has a plurality of positive electrodes 10, a plurality of negative electrodes 12, and a plurality of separators 13.
  • the positive electrode 10 and the negative electrode 12 are arranged alternately.
  • a separator 13 is interposed between the adjacent positive electrode 10 and the negative electrode 12. Therefore, the positive electrode 10 is laminated on the negative electrode 12 via the separator 13.
  • the negative electrode 12 is arranged at the end of the positive electrode 10, the negative electrode 12, and the separator 13 in the arrangement direction (hereinafter, may be simply referred to as “arrangement direction” or “stacking direction”).
  • arrangement direction hereinafter, may be simply referred to as “arrangement direction” or “stacking direction”.
  • each of the positive electrode 10, the negative electrode 12, and the separator 13 is also referred to as a battery component.
  • the direction (stacking direction) in which the plurality of positive electrodes 10, the plurality of negative electrodes 12, and the plurality of separators 13 overlap each other is referred to as the first direction X.
  • the direction orthogonal to the first direction X is referred to as the second direction Y
  • the direction orthogonal to the first direction X and the second direction Y is referred to as the third direction Z.
  • the second direction Y corresponds to the direction in which the electrode group 3 is housed in the case 7.
  • the second direction Y and the third direction Z are orthogonal to each other, but the present invention is not limited to this.
  • the second direction Y and the third direction Z may intersect with each other.
  • the positive electrode 10 (second electrode plate) is, for example, a clad type positive electrode plate.
  • the positive electrode 10 has a tubular electrode group 14.
  • the tubular electrode group 14 has a plurality of tubular electrodes 15.
  • the plurality of tubular electrodes 15 are arranged in a row.
  • Each of the plurality of tubular electrodes 15 has, for example, a clad tube, a core metal inserted in the clad tube, and a positive electrode material filled between the clad tube and the core metal.
  • the clad tube is a tubular porous tube also called a gauntlet, and is formed of, for example, glass, resin, or the like.
  • the positive electrode material may contain a positive electrode active material and an additive.
  • the positive electrode active material is, for example, lead powder, lead tan, or the like. Examples of the additive include carbon materials, reinforcing short fibers and the like.
  • the positive electrode active material after chemical conversion is, for example, lead dioxide or the like.
  • FIG. 2 is a plan view showing a negative electrode according to an embodiment.
  • the negative electrode 12 (first electrode plate) is a negative electrode plate having a negative electrode lattice body 12a and a selvage portion 12b.
  • the negative electrode grid body 12a is the main body portion of the negative electrode 12, and holds the negative electrode material 12c.
  • the thickness of the portion of the negative electrode 12 where the negative electrode material 12c is held is larger than the thickness of the negative electrode grid 12a, but is not limited to this.
  • the negative electrode material 12c may contain a negative electrode active material and an additive.
  • the negative electrode active material is, for example, spongy lead or the like.
  • Examples of the additive include barium sulfate, a carbon material, and reinforcing short fibers.
  • the selvage portion 12b is a terminal portion protruding from the negative electrode grid body 12a along the second direction Y.
  • the selvage portion 12b and the negative electrode grid body 12a do not overlap each other in the arrangement direction.
  • the negative electrode grid 12a is covered with the separator 13.
  • the negative electrode lattice body 12a is provided with convex portions 12d and 12e.
  • the convex portions 12d and 12e are foot portions that are arranged at predetermined intervals and project outward from the negative electrode grid body 12a.
  • the convex portions 12d and 12e project along the direction opposite to the projecting direction of the selvage portion 12b.
  • the protruding direction of the selvage portion 12b and the protruding direction of the convex portions 12d and 12e are orthogonal to the arrangement direction, respectively. Further, the selvage portion 12b and the negative electrode lattice body 12a do not overlap each other in the arrangement direction.
  • FIG. 3 is a cross-sectional view taken along the line III-III of FIG.
  • the convex portion 12d is located between one end A1 and the other end A2 of the negative electrode lattice body 12a in the first direction X.
  • the convex portion 12d has a tip surface 12f, a first side surface 12g, a second side surface 12h, a first angle 12i, and a second angle 12j.
  • the first side surface 12g is located on one end A1 side of the negative electrode lattice body 12a in the first direction X. In other words, the first side surface 12g is closer to one end A1 than the other end A2 in the first direction X.
  • the second side surface 12h is located on the other end A2 side of the negative electrode grid body 12a in the first direction X. In other words, the second side surface 12h is closer to the other end A2 than the other end A1 in the first direction X.
  • the first angle 12i is formed by the tip surface 12f and the first side surface 12g
  • the second angle 12j is formed by the tip surface 12f and the second side surface 12h.
  • each of the first corner 12i and the second corner 12j is chamfered.
  • each of the chamfered first corner 12i and second corner 12j has a round surface, but the present invention is not limited to this.
  • first angle 12i and the second angle 12j are chamfered after, for example, forming the convex portion 12d, but the present invention is not limited to this.
  • the chamfered first angle 12i and the second angle 12j may be formed.
  • the first corner 12i and the second corner 12j may have a shape such as a round surface without chamfering.
  • the thickness T1 of the convex portion 12d is smaller than the thickness T2 of the negative electrode lattice body 12a.
  • the maximum thickness T3 in the region of the negative electrode 12 where the negative electrode material 12c is provided is larger than the thickness T2 of the negative electrode lattice body 12a. Therefore, in the present embodiment, the maximum thickness of the negative electrode 12 corresponds to the maximum thickness T3 in the above region.
  • the thickness of the negative electrode grid 12a may be greater than or equal to the maximum thickness in the region of the negative electrode 12 where the negative electrode material 12c is provided. In this case, the maximum thickness of the negative electrode 12 corresponds to the thickness of the negative electrode lattice body 12a.
  • the convex portion 12e is located between one end A1 and the other end A2 of the negative electrode lattice body 12a in the first direction X, similarly to the convex portion 12d. Further, from the viewpoint of preventing damage to the separator 13 due to the convex portion 12e, each corner of the convex portion 12e is chamfered in the same manner as the convex portion 12d. The thickness of the convex portion 12e is smaller than the maximum thickness of the negative electrode 12.
  • each positive electrode 10 is electrically connected to the positive electrode terminal 5A.
  • Each positive electrode 10 and the positive electrode terminal 5A are electrically connected by a positive electrode strap 17.
  • the positive electrode strap 17 is connected to the selvage portion 10a of the positive electrode 10.
  • Each negative electrode 12 is electrically connected to the negative electrode terminal 5B.
  • Each negative electrode 12 and the negative electrode terminal 5B are electrically connected by a negative electrode strap 18.
  • the negative electrode strap 18 is connected to the selvage portion 12b of the negative electrode 12.
  • the separator 13 is a battery member (battery separator) for preventing a short circuit between the positive electrode 10 and the negative electrode 12.
  • the separator 13 is provided as long as it electronically insulates between the positive electrode 10 and the negative electrode 12 while allowing ions to permeate, and has resistance to oxidizing property on the positive electrode 10 side and reducing property on the negative electrode 12 side.
  • Examples of the material (material) of such a separator 13 include glass fiber, resin, and an inorganic substance.
  • the separator 13 covers the negative electrode lattice body 12a and the convex portions 12d and 12e of the negative electrode 12, and the selvage portion 12b of the negative electrode 12 is exposed from the separator 13.
  • FIG. 4A is a plan view showing a separator sheet
  • FIG. 4B is a schematic cross-sectional view taken along the line IVb-IVb of FIG. 4A.
  • the separator sheet 30 has a base 31, a pair of edges 32 and 33, and a plurality of ribs 34.
  • the base portion 31 is a sheet-like portion that is the main portion of the separator sheet 30 and exhibits flexibility.
  • the base 31 has a first main surface 31a and a second main surface 31b.
  • the second main surface 31b is located on the opposite side of the first main surface 31a in the first direction X.
  • the first main surface 31a and the second main surface 31b have a rectangular shape when viewed from the first direction X, but the present invention is not limited to this.
  • the pair of edge portions 32, 33 are portions provided at both ends of the separator sheet 30 in the third direction Z.
  • Each of the edges 32 and 33 extends from one end to the other end of the separator sheet 30 in the second direction Y.
  • One end of the separator sheet 30 in the second direction Y corresponds to, for example, the upper end of the paper surface in FIG. 4A.
  • the other end of the separator sheet 30 in the second direction Y corresponds to, for example, the lower end of the paper surface in FIG. 4A.
  • Each of the edges 32 and 33 may extend continuously or intermittently.
  • the edge portion 32 is provided at one end of the separator sheet 30 in the third direction Z
  • the edge portion 33 is provided at the other end of the separator sheet 30 in the third direction Z.
  • One end of the third direction Z corresponds to, for example, the left end of the paper surface in FIG. 4A.
  • the other end of the third direction Z corresponds to, for example, the right end of the paper surface in FIG. 4A.
  • the pair of edge portions 32, 33 are provided with ribs different from the ribs 34.
  • each of the pair of edge portions 32 and 33 may be provided with one or a plurality of ribs extending from one end to the other end of the separator sheet 30 in the second direction Y.
  • the plurality of ribs 34 are provided, for example, in order to improve the durability of the separator sheet 30, improve the fluidity of the electrolytic solution in the case 7, and the like.
  • the plurality of ribs 34 project from the base 31 along the first direction X and are separated from each other.
  • Each of the plurality of ribs 34 has a rectangular shape when viewed from the first direction X.
  • Each of the plurality of ribs 34 extends from one end to the other end of the separator sheet 30 in the second direction Y, and extends in parallel with each other.
  • the cross section of the rib 34 orthogonal to the extending direction of the rib 34 has a rectangular shape, but is not limited to this.
  • the cross section may be, for example, trapezoidal or inverted trapezoidal.
  • the dimension (width) of the rib 34 along the third direction Z is, for example, 0.30% or more and 2.5% or less of the dimension of the separator sheet 30 along the third direction Z.
  • the dimension (height) of the rib 34 along the first direction X is, for example, greater than 100% (thickness) of the dimension (thickness) of the base 31 along the first direction X and 1000% or less.
  • the rib 34 has a plurality of first ribs 34a provided on the first main surface 31a and a plurality of second ribs 34b provided on the second main surface 31b.
  • the first rib 34a projects from the first main surface 31a along the first direction X.
  • the second rib 34b protrudes from the second main surface 31b on the side opposite to the first rib 34a.
  • the first rib 34a and the second rib 34b have the same shape and completely overlap each other.
  • the portion of the separator sheet 30 where the rib 34 is provided is also referred to as the thick portion TP1 of the separator sheet 30 (and the separator 13).
  • the portion where the base portion 31 and the rib 34 overlap each other is also referred to as a thick portion TP1. Therefore, the thick portion TP1 has a rib 34.
  • the thickness of the thick portion TP1 in the present embodiment is the thickness of the base 31 and the height of the first rib 34a. It corresponds to the sum of the height and the height of the second rib 34b.
  • the second thickness T5 is, for example, 2000, which is larger than 100% of the first thickness T4. % Or less.
  • the case 7 has a main body 20 and a lid 22.
  • the main body 20 is a box-shaped electric tank.
  • the main body 20 is made of a material such as polypropylene.
  • the main body 20 houses the electrode group 3 and the electrolytic solution.
  • the main body 20 is composed of four side surface portions and a bottom portion 24.
  • the lid 22 covers the opening of the main body 20.
  • the lid 22 is provided with a positive electrode terminal 5A, a negative electrode terminal 5B, and a water tap 6.
  • a refilling tap 6 is provided between the positive electrode terminal 5A and the negative electrode terminal 5B.
  • FIG. 5A is a plan view showing the bottom of the main body 20
  • FIG. 5B is a schematic cross-sectional view taken along the line Vb-Vb of FIG. 5A
  • FIG. 5B is a schematic cross-sectional view.
  • (C) is a schematic cross-sectional view taken along the line Vc-Vc of FIG. 5 (a).
  • the main body 20 has a clasp 25 provided on the bottom 24 and projecting along the second direction Y.
  • the bracket 25 is a member for separating the positive electrode 10 and the negative electrode 12 from the bottom portion 24.
  • the clutter 25 may be detachably provided with respect to the main body 20 or may be integrated with the main body 20. In the former case, the Kura 25 is a separate part from the case 7.
  • the clasp 25 and the main body 20 may be integrally molded.
  • the class 25 has a substantially lattice shape when viewed from the second direction Y.
  • the clasp 25 has a plurality of first bone portions 26 extending along the first direction X and a second bone portion 27 extending along the third direction Z.
  • the plurality of first bone portions 26 are arranged apart from each other in, for example, the third direction Z, and extend from one side surface of the main body 20 in the first direction X to the other side surface. In the second direction Y, one end 26a of the first bone portion 26 is in contact with the bottom portion 24.
  • the other end 26b of the first bone portion 26 is located closer to the lid 22 than the second bone portion 27.
  • the other end 26b of the first bone portion 26 is closer to the lid 22 than the second bone portion 27.
  • the dimension S3 of the first bone portion 26 in the third direction Z is equal to or less than the dimension S1 of the convex portion 12d and the dimension S2 of the convex portion 12e along the third direction Z (see FIG. 2). From the viewpoint of suppressing the deposition of the active material on the Kura 25, the dimension S3 is, for example, 100% or less of the dimension S1 or the dimension S2, but is not limited thereto.
  • the plurality of second bone portions 27 are arranged apart from each other in, for example, the first direction X, and extend from one side surface to the other side surface of the main body 20 in the third direction Z.
  • the first bone portion and the second bone portion 27 are orthogonal to each other when viewed from the second direction Y.
  • FIG. 6 is a plan view showing a negative electrode wrapped in a separator.
  • the separator 13 corresponds to the bag-shaped work piece of the separator sheet 30 and encloses the negative electrode 12.
  • the selvage portion 12b of the negative electrode 12 is exposed from the separator 13, and the convex portions 12d and 12e of the negative electrode 12 are covered with the separator 13.
  • the separator 13 is formed, for example, by folding one separator sheet 30 in half along the second direction Y and then sealing a desired portion.
  • the separator sheet 30 is folded back on the convex portions 12d and 12e sides of the negative electrode 12 in the second direction Y so that the negative electrode 12 is sandwiched between the separator sheets 30.
  • the separator sheet 30 in the second direction Y, the separator sheet 30 is folded back outside the convex portions 12d and 12e of the negative electrode 12.
  • the folded portion of the separator sheet 30 faces the convex portions 12d and 12e in the second direction Y.
  • At least a part of each of the edges 32 and 33 is located outside the negative electrode 12 in the third direction Z.
  • the separator sheet 30 may be folded in half as the negative electrode 12 moves.
  • the separator 13 has a main portion 41, a pair of sealing portions 42, 43, a bent portion 44, and a joint portion 45.
  • the main portion 41 is a portion that accommodates the negative electrode lattice body 12a of the negative electrode 12.
  • the main portion 41 is composed of a base portion 31 and edge portions 32, 33 (see (a) of FIG. 4) of the separator sheet 30. Therefore, the main portion 41 has a first main surface 31a provided with the first rib 34a and a second main surface 31b provided with the second rib 34b (see (b) in FIG. 4).
  • the first main surface 31a faces the negative electrode 12, and the second main surface 31b is an exposed surface. Therefore, the positive electrode 10 (see FIG. 1) in the electrode group 3 faces the second main surface 31b of the separator sheet 30.
  • the pair of sealing portions 42, 43 is a portion for maintaining a state in which the separator sheet 30 is folded in half.
  • the seal portion 42 is formed on the edge portion 32 (see (a) in FIG. 4), and the seal portion 43 is formed on the edge portion 33 (see (a) in FIG. 4).
  • Each of the sealing portions 42 and 43 is located outside the negative electrode 12 in the third direction Z.
  • Each of the seal portions 42 and 43 extends in the second direction Y. As a result, the movement of the negative electrode 12 along the third direction Z can be suppressed by the sealing portions 42 and 43.
  • the sealing portions 42 and 43 do not have to be completely sealed.
  • a region through which the electrolytic solution can pass may be provided on at least one of the sealing portions 42 and 43.
  • the seal portions 42 and 43 are, for example, an ultrasonic welding portion, a heat seal portion, a cold seal portion, a gear seal portion, and the like.
  • the gear seal portion is a portion that is mechanically bonded by pressurization using a gear.
  • each of the seal portions 42 and 43 is a gear seal portion extending from one end to the other end of the separator 13 in the second direction Y.
  • the bent portion 44 is a portion to be folded back in the separator sheet 30. At least a part of the bent portion 44 may come into contact with the negative electrode lattice body 12a.
  • An opening 44a is provided in a part of the bent portion 44.
  • the opening 44a is, for example, a portion provided to improve the fluidity of the electrolytic solution in the separator 13.
  • the opening 44a is provided at a position that does not overlap with any of the convex portions 12d and 12e in the second direction Y.
  • the opening 44a is provided, for example, in the central portion of the separator 13 in the third direction Z, but is not limited thereto.
  • the opening 44a is formed by cutting a part of the bent portion 44.
  • the joint portion 45 is a portion for maintaining the state of the separator sheet 30 folded in half, like the seal portions 42 and 43.
  • the joint portion 45 is a portion for joining a part of the first main surface 31a of the separator sheet 30 and another part.
  • the part and the other part are portions that do not overlap the negative electrode 12 in the first direction X, and are located on the opposite side of the bent portion 44 in the second direction Y. Therefore, the joint portion 45 is located on one end side of the separator 13 in the second direction Y and outside the negative electrode 12 when viewed from the first direction X. Therefore, the joint portion 45 in the case 7 is located on the opposite side of the bottom portion 24 (see (a) of FIG. 5) of the main body 20 (electric tank) via the negative electrode 12.
  • the joint portion 45 faces the negative electrode lattice body 12a of the negative electrode 12 in the second direction Y and faces the selvage portion 12b in the third direction Z.
  • the joint 45 extends along the third direction Z. Specifically, the joint portion 45 extends from one end to the other end of the separator 13 in the third direction Z, and is provided on the main portion 41 and the seal portion 42. That is, a part of the joint portion 45 overlaps with the seal portion 42.
  • the joint portion 45 is, for example, a portion where the separator sheet 30 itself is welded. In this case, in the joint portion 45, a part of the first main surface 31a and another part are welded. From the viewpoint of preventing poor welding, the joint portion 45 may be formed by ultrasonic welding or the like.
  • the joint portion 45 may be provided after the formation of the seal portions 42, 43, or may be provided before the formation of the seal portions 42, 43.
  • FIG. 7A is an enlarged view of the region surrounded by the alternate long and short dash line shown in FIG. 6, and FIG. 7B is a cross-sectional view taken along the line VIIb-VIIb of FIG. 7A. Is.
  • the first rib 34a included in the thick portion TP1 overlaps the convex portion 12d in the second direction Y.
  • at least two first ribs 34a overlap the convex portion 12d in the second direction Y. Therefore, even when the positions of the negative electrode 12 and the separator 13 are displaced, the state in which at least one first rib 34a overlaps the convex portion 12d in the second direction Y can be satisfactorily maintained.
  • the convex portion 12e also overlaps with at least one first rib 34a in the second direction Y.
  • the convex portion 12e may overlap with two or more first ribs 34a.
  • FIG. 8 (a) is a cross-sectional view taken along the line VIIIa-VIIIa of FIG. 7 (a), and FIG. 8 (b) is a cross-sectional view taken along the line VIIIb-VIIIb of FIG. 7 (a). It is a figure.
  • the bent portion 44 of the separator 13 is in contact with the convex portion 12d.
  • the tip surface 12f, the first angle 12i, and the second angle 12j are separated from the base 31, but they are separated from each other. Not limited to.
  • a part of the base portion 31 may abut on at least one of the tip surface 12f, the first corner 12i and the second corner 12j.
  • the convex portion 12e is also in contact with the thick portion TP1.
  • FIG. 9 is an enlarged cross-sectional view of a main part of the storage battery.
  • the electrolytic solution and the positive electrode are omitted.
  • the convex portions 12d and 12e of the negative electrode 12 are the bottom portion of the main body 20. Facing 24.
  • the convex portion 12d faces the bracket 25 on the bottom portion 24 in the second direction Y, and the separator 13 is located between the convex portion 12d and the bracket 25. Therefore, the separator 13 is sandwiched between the convex portion 12d and the bracket 25 in the second direction Y.
  • the thick portion TP1 of the separator 13 is sandwiched between the convex portion 12d and the first bone portion 26 of the bracket 25 in the second direction Y.
  • the first rib 34a comes into contact with the convex portion 12d
  • the second rib 34b comes into contact with the clasp 25.
  • the base 31 of the separator 13 may be in contact with at least one of the convex portion 12d and the clasp 25, or may be separated from both the convex portion 12d and the clasp 25.
  • the convex portion 12e faces the bracket 25 in the second direction Y like the convex portion 12d, and the thick portion TP1 is separated from the convex portion 12e and the bracket 25 in the second direction Y. It is sandwiched by the first bone portion 26 of the above.
  • the base 31 of the separator 13 may be in contact with at least one of the convex portion 12e and the clasp 25, or may be separated from both the convex portion 12e and the clasp 25.
  • the separator sheet 30 and the negative electrode 12 are prepared.
  • the first main surface 31a of the separator sheet 30 and the negative electrode 12 are opposed to each other.
  • the separator sheet 30 is folded in half to form the bent portion 44, and the negative electrode 12 is sandwiched by the separator sheet 30.
  • the negative electrode lattice body 12a of the negative electrode 12 is completely covered with the separator sheet 30, and a part of the selvage portion 12b of the negative electrode 12 is exposed from the separator sheet 30.
  • the seal portions 42, 43 and the joint portion 45 are formed on the separator sheet 30.
  • the seal portions 42 and 43 are formed by, for example, a gear seal or the like.
  • the joint portion 45 is formed by, for example, ultrasonic welding using an ultrasonic welding device including a horn.
  • the separator sheet 30 is attracted to the joint portion 45 at least in the second direction Y. Since the bent portion 44 is formed on the separator sheet 30, tension is generated in the separator sheet 30 at least in the second direction Y. As a result, a part of the separator sheet 30 is pressed against the convex portions 12d and 12e of the negative electrode 12. Subsequently, by forming the opening 44a in the bent portion 44, the separator 13 that encloses the negative electrode 12 is formed.
  • the negative electrode 12 wrapped in the separator 13 is conveyed by a conveyor such as a belt conveyor. At this time, the negative electrode 12 wrapped in the separator 13 is laid down on the transfer device. In other words, the negative electrode 12 wrapped in the separator 13 is arranged on the transport device so that the protruding directions of the convex portions 12d and 12e of the negative electrode 12 are orthogonal to the height direction. As described above, since each of the convex portions 12d and 12e is located between one end A1 and the other end A2 of the negative electrode lattice body 12a, the convex portions 12d and 12e can be separated from the above-mentioned transport device.
  • the positive electrode 10 and the negative electrode 12 are alternately laminated.
  • the selvage portions 10a of the positive electrode 10 are electrically connected to each other via the positive electrode strap 17, and the selvage portions 12b of the negative electrode 12 are electrically connected to each other via the negative electrode strap 18.
  • the electrode group 3 including the plurality of positive electrodes 10, the plurality of negative electrodes 12, and the plurality of separators 13 is formed.
  • the electrode group 3 is housed in the main body 20.
  • each of the convex portions 12d and 12e of the negative electrode 12 is arranged on the bracket 25 on the bottom portion 24. Subsequently, the main body 20 is sealed with the lid 22. At this time, each positive electrode 10 is electrically connected to the positive electrode terminal 5A, and each negative electrode 12 is electrically connected to the negative electrode terminal 5B. Subsequently, the electrolytic solution is supplied into the case 7 via the refill plug 6. As a result, the storage battery 1 is manufactured.
  • each of the convex portions 12d and 12e of the negative electrode 12 is covered with the separator 13.
  • the convex portions 12d and 12e of the negative electrode 12 abut on the bottom 24 of the main body 20. Therefore, the load tends to be concentrated on the portions of the separator 13 that come into contact with the convex portions 12d and 12e.
  • the thick portion TP1 of the separator 13 comes into contact with the convex portions 12d and 12e.
  • the load-bearing performance of the portions of the separator 13 that come into contact with the convex portions 12d and 12e is satisfactorily improved. Therefore, according to the present embodiment, damage to the separator 13 can be satisfactorily prevented.
  • the thick portion TP1 abuts on the convex portions 12d and 12e of the negative electrode 12.
  • the portion of the base portion 31 of the separator 13 where the first rib 34a is not provided is less likely to come into contact with the convex portions 12d and 12e. Therefore, it is difficult for the load from the convex portions 12d and 12e to be applied to the portion of the separator 13 having a relatively low load-bearing performance (that is, the portion of the separator 13 where the rib 34 is not provided). Therefore, in the present embodiment, as described above, damage to the separator 13 can be satisfactorily prevented.
  • the separator 13 includes a first main surface 31a facing the negative electrode 12, and the thick portion TP1 has a first rib 34a protruding from the first main surface 31a toward the negative electrode 12.
  • the 1 rib 34a abuts on the convex portion 12d.
  • the base portion 31 of the separator 13 is less likely to come into contact with the convex portion 12d.
  • the convex portion 12d is in contact with two or more first ribs 34a. In this case, the base portion 31 of the separator 13 is less likely to come into contact with the convex portion 12d.
  • the separator 13 includes a second main surface 31b located on the opposite side of the first main surface 31a, and the thick portion TP1 projects from the second main surface 31b on the opposite side to the first rib 34a. It has a second rib 34b.
  • the separator 13 when the battery component is housed in the main body 20 of the case 7, it is possible to satisfactorily prevent damage to the portion of the separator 13 sandwiched between the convex portion 12d and the bottom portion 24 of the main body 20. In addition, in the present embodiment, it is possible to satisfactorily prevent damage to the portion of the separator 13 sandwiched between the convex portion 12e and the bottom portion 24.
  • the separator 13 is folded back at the convex portions 12d and 12r of the negative electrode 12 in the second direction Y. Therefore, the convex portions 12d and 12e can be well covered by the bent portion 44 of the separator 13 and its surroundings.
  • the separator 13 has an opening 44a located on the convex portions 12d and 12e side of the negative electrode 12 in the second direction Y.
  • the electrolytic solution easily flows in the electrode group 3.
  • the first corner 12i and the second corner 12j of the convex portion 12d are chamfered.
  • the load concentration from the convex portion 12d to the specific portion of the thick portion TP1 can be suppressed as compared with the embodiment in which the convex portion 12d is provided with an unchamfered angle, for example.
  • the corners of the convex portion 12e can also be chamfered. Therefore, it is possible to suppress the load concentration from the convex portion 12e to the specific portion of the thick portion TP1.
  • the thickness T1 of the convex portion 12d in the first direction X is smaller than the maximum thickness T3 of the negative electrode 12 in the first direction X
  • the convex portion 12d is the negative electrode lattice of the negative electrode 12 in the first direction X. It is located between one end A1 and the other end A2 of the body 12a.
  • the separator 13 is less likely to be sandwiched between the convex portion 12d and the transport device.
  • the case 7 has a clasp 25 provided on the bottom portion 24 and projecting along the second direction Y, and the thick portion TP1 is sandwiched between the convex portions 12d and the clasp 25. Therefore, the thick portion TP1 is sandwiched between the convex portion 12d and the bracket 25, so that the separator 13 is prevented from being damaged.
  • the dimension S1 of the convex portion 12d in the third direction Z is equal to or less than the dimension S3 of the bracket 25 in the third direction Z. Therefore, when the negative electrode 12 wrapped in the separator 13 is housed in the case 7, the load is less likely to be concentrated from the convex portion 12d to the specific portion of the bracket 25. Therefore, the thick portion TP1 is satisfactorily less likely to be damaged.
  • FIG. 10A is an enlarged cross-sectional view of a main part of the separator and the negative electrode according to the first modification.
  • the first rib 34a and the second rib 34b provided on the separator 13A do not overlap each other in the thickness direction of the base 31.
  • the second rib 34b is located between two adjacent first ribs 34a in the third direction Z.
  • the separator 13A has a thick portion TP2 including the first rib 34a and a thick portion TP3 including the second rib 34b.
  • the thickness of the thick portion TP2 corresponds to the sum of the thickness of the base 31 and the height of the first rib 34a.
  • the thickness of the thick portion TP3 corresponds to the sum of the thickness of the base 31 and the height of the second rib 34b.
  • the thick portion TP2 abuts on the negative electrode 12 (more specifically, the convex portions 12d and 12e), and the thick portion TP3 It abuts on the bottom 24 (more specifically, the class 25) of the main body 20. Even in such a first modification, the same action and effect as those of the above embodiment can be achieved.
  • FIG. 10B is an enlarged cross-sectional view of a main part of the separator and the negative electrode according to the second modification.
  • the dimension S4 along the third direction Z of the first bone portion 26A included in the bracket 25A is larger than the dimension S1 of the convex portion 12d.
  • the dimension S1 of the convex portion 12d in the third direction Z is smaller than the dimension S4 of the bracket 25A in the third direction Z.
  • the dimension S4 is larger than the dimension S2 (see FIG. 2) of the convex portion 12e. Also in such a second modification, the same action and effect as those of the above embodiment are exhibited.
  • the thick portion TP1 is likely to be sandwiched between the convex portion 12d and the bracket 25A.
  • the dimension S2 of the convex portion 12e in the third direction Z is smaller than the dimension S4 of the Kura 25A in the third direction Z, the thick portion TP1 is likely to be sandwiched between the convex portion 12e and the Kura 25A.
  • FIG. 11 is a plan view showing a negative electrode wrapped in the separator according to the third modification.
  • the separator 13B does not have a bent portion facing the convex portions 12d and 12e of the negative electrode 12 in the second direction Y. Therefore, in the third modification, the separator 13B is composed of two separator sheets 30.
  • a separator sheet 30 located on one end side of the negative electrode 12 in the first direction X (hereinafter, may be referred to as a “first separator sheet”) and a separator located on the other end side of the negative electrode 12 in the first direction X.
  • the separator 13B is formed by joining the sheet 30 (hereinafter, may be referred to as a "second separator sheet") to each other at the sealing portions 42, 43 and the like.
  • the first separator sheet is arranged at a position where it can come into contact with one end of the negative electrode 12 in the first direction X.
  • the second separator sheet is arranged at a position where it can come into contact with the other end of the negative electrode 12 in the first direction X.
  • the separator 13B has joints 51 and 52 facing the negative electrode 12 in the second direction Y in addition to the joint 45 instead of the bent portion.
  • Each of the joint portions 51 and 52 is a portion where a part (first part) of the separator 13B and another part (second part) are joined to each other.
  • a part of the separator 13B is included in the first separator sheet, and the other part of the separator 13B is included in the second separator sheet.
  • the joint portion 51 faces the convex portion 12d in the second direction Y
  • the joint portion 52 faces the convex portion 12e in the second direction Y.
  • the dimension S5 of the joint portion 51 in the third direction Z is equal to or larger than the dimension S1 of the convex portion 12d.
  • the dimensions of the first portion and the second portion corresponding to the joint portion 51 along the third direction Z are equal to or larger than the dimension S1 of the convex portion 12d.
  • the dimension S6 of the joint portion 52 in the third direction Z is equal to or larger than the dimension S2 of the convex portion 12e.
  • the dimension of the first portion and the second portion corresponding to the joint portion 52 along the third direction Z is equal to or larger than the dimension S2 of the convex portion 12e.
  • Each of the joint portions 51 and 52 extends along the third direction Z.
  • the joint portion 51 extends from one end to the other end of the separator 13B in the third direction Z, and is provided on the main portion 41 and the seal portion 42.
  • the joint portion 52 extends from the other end of the third direction Z toward one end, and is provided on the main portion 41 and the seal portion 42.
  • the joint portions 51 and 52 are aligned in the third direction Z and are separated from each other.
  • An opening 53 is provided between the joints 51 and 52 in the third direction Z.
  • the opening 53 is a portion of the separator 13B where the first separator sheet and the second separator sheet are not joined to each other.
  • the opening 53 is located on the convex portions 12d and 12e side in the second direction Y. In other words, the opening 53 is closer to the convex portions 12d and 12e than the selvage portion 12b in the second direction Y.
  • the opening 53 does not overlap the convex portions 12d and 12e in the second direction Y
  • each of the joining portions 51 and 52 is, for example, a portion where the first separator sheet and the second separator sheet are welded to each other. From the viewpoint of preventing poor welding, each of the joint portions 51 and 52 may be formed by ultrasonic welding or the like. Each of the joint portions 51 and 52 may be provided after the formation of the seal portions 42 and 43, or may be provided before the formation of the seal portions 42 and 43.
  • the separator 13B is composed of two separator sheets 30, but the separator 13B is not limited to this.
  • a separator sheet folded in half along the third direction Z may be used. That is, the separator according to the third modification may be formed from one separator sheet.
  • the battery component according to one aspect of the present disclosure is not limited to the above embodiment and the above modification.
  • the above-described embodiment and the above-mentioned modification may be combined as appropriate.
  • the first modification and the second modification may be combined.
  • the ribs seen from the first direction extend linearly, but the ribs are not limited to this.
  • the ribs when viewed from the first direction, may extend in a wavy pattern or may extend in a zigzag pattern.
  • the rib may have a point shape (dot shape), a circular shape, an elliptical shape, or a polygonal shape when viewed from the first direction.
  • the rib may have a polygonal pyramid shape, a polygonal pyramid shape, a conical shape, or a truncated cone shape.
  • the cross section of the rib may be a semicircular shape or a polygonal shape.
  • the ribs may extend along the second direction or may extend along the third direction. Seen from the first direction, the fishbone structure may be formed by a plurality of ribs.
  • the thick portion includes ribs, but the thickness is not limited to this.
  • the thick portion may be a portion thicker than the thinnest portion of the separator, and may not include ribs.
  • the separator may have both a thick portion with ribs and a thick portion without ribs.
  • the separator sheet is folded in half along the second direction, but the present invention is not limited to this.
  • the separator sheet may be folded in half along the third direction. In this case, the bent portion of the separator may not be provided with an opening.
  • the separator is formed from one separator sheet, but is not limited thereto.
  • the separator may be formed from a plurality of separator sheets.
  • seal portions may be formed on both ends of the separator in the third direction, or seal portions may be formed on only one side in the third direction.
  • joint portions are formed on both sides of the separator in the second direction. A joint may be formed on only one side in the second direction. Therefore, when the separator is formed from a plurality of separator sheets, the separator may be a bag-shaped processed product, a tubular processed product, or a processed product different from the bag-shaped processed product and the tubular processed product. good.
  • Electrode group 5A ... Positive electrode terminal, 5B ... Negative electrode terminal, 7 ... Case, 10 ... Positive electrode (second electrode plate), 10a ... Ear, 12 ... Negative electrode (first electrode plate), 12a ... Negative electrode lattice, 12b ... Ear, 12c ... Negative electrode material, 12d, 12e ... Convex, 12i ... First corner (corner), 12j ... Second corner (corner), 13, 13A, 13B ... Separator, 20 ... Main body , 22 ... lid, 24 ... bottom, 25, 25A ... class, 30 ... separator sheet, 31 ... base, 31a ... first main surface, 31b ... second main surface, 32, 33 ...

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Cell Separators (AREA)
  • Secondary Cells (AREA)

Abstract

This cell constituent element comprises a first electrode plate and a separator that overlap each other in a first direction. The first electrode plate has a body part and foot part that projects from the body part along a second direction orthogonal to the first direction and that is covered by the separator. The separator is provided with a base having a first thickness, and a thick part that has a second thickness greater than the first thickness and that abuts the foot part.

Description

電池構成要素、蓄電池、組電池及び電動車Battery components, storage batteries, assembled batteries and electric vehicles
 本開示は、電池構成要素、蓄電池、組電池及び電動車に関する。 This disclosure relates to battery components, storage batteries, assembled batteries and electric vehicles.
 電池には、正極と負極との短絡を防止するためのセパレータが用いられる。例えば、下記特許文献1には、袋セパレータ入り電極板の製造方法が開示される。下記特許文献1においては、セパレータを折り曲げることによって、電極板が挟み込まれる。加えて、複数箇所の溶着部分がセパレータに形成されることによって、袋状のセパレータが設けられる。 A separator is used for the battery to prevent a short circuit between the positive electrode and the negative electrode. For example, Patent Document 1 below discloses a method for manufacturing an electrode plate containing a bag separator. In Patent Document 1 below, the electrode plate is sandwiched by bending the separator. In addition, a bag-shaped separator is provided by forming a plurality of welded portions on the separator.
特許第4661423号公報Japanese Patent No. 4661423
 電池に収容されるセパレータが破損することによって当該セパレータに開口が形成されると、当該開口を介して正極と負極とが短絡しやすくなる。このため、セパレータの破損を防止可能な態様が望まれている。 If an opening is formed in the separator due to damage to the separator housed in the battery, the positive electrode and the negative electrode are likely to be short-circuited through the opening. Therefore, a mode capable of preventing damage to the separator is desired.
 本開示の一側面の目的は、セパレータの破損を良好に防止可能な電池構成要素、蓄電池、組電池及び電動車の提供である。 An object of one aspect of the present disclosure is to provide battery components, storage batteries, assembled batteries and electric vehicles capable of satisfactorily preventing damage to the separator.
 本開示の一側面に係る電池構成要素は、第1方向にて互いに重なる第1極板及びセパレータを備え、第1極板は、本体部と、第1方向に直交する第2方向に沿って本体部から突出すると共にセパレータに覆われる足部とを有し、セパレータは、第1厚さを有する基部と、第1厚さよりも厚い第2厚さを有すると共に足部に当接する肉厚部とを備える。 The battery components according to one aspect of the present disclosure include a first electrode plate and a separator that overlap each other in the first direction, and the first electrode plate is along a second direction orthogonal to the first direction with the main body portion. It has a foot portion that protrudes from the main body and is covered with a separator, and the separator has a base portion having a first thickness and a thick portion having a second thickness thicker than the first thickness and abutting on the foot portion. And prepare.
 この電池構成要素では、第1極板の足部はセパレータに覆われる。このため、例えば第1極板を電池の電槽に収容する場合等にて、セパレータのうち足部と当接する部分に荷重が集中する傾向がある。ここで上記電池構成要素では、セパレータの肉厚部が足部に当接する。これにより、セパレータのうち足部と当接する部分の耐荷重性能が良好に向上する。したがって上記一側面によれば、セパレータの破損を良好に防止可能である。 In this battery component, the foot of the first electrode plate is covered with a separator. Therefore, for example, when the first electrode plate is housed in the battery case, the load tends to be concentrated on the portion of the separator that comes into contact with the foot portion. Here, in the battery component, the thick portion of the separator abuts on the foot portion. As a result, the load-bearing performance of the portion of the separator that comes into contact with the foot portion is satisfactorily improved. Therefore, according to the above aspect, damage to the separator can be satisfactorily prevented.
 セパレータは、第1極板に対向する第1主面をさらに備え、肉厚部は、第1主面から第1極板に向かって突出する第1リブを有し、第1リブは、足部に当接してもよい。この場合、セパレータの基部が足部に当接しにくくなる。 The separator further comprises a first main surface facing the first electrode plate, the thick portion has a first rib projecting from the first main surface toward the first electrode plate, and the first rib is a foot. It may come into contact with the portion. In this case, it becomes difficult for the base of the separator to come into contact with the foot.
 肉厚部は、第1リブを複数有し、足部は、2つ以上の第1リブに当接してもよい。この場合、セパレータの基部が足部により当接しにくくなる。 The thick portion may have a plurality of first ribs, and the foot portion may abut on two or more first ribs. In this case, the base of the separator is less likely to come into contact with the foot.
 セパレータは、第1主面の反対側に位置する第2主面をさらに備え、肉厚部は、第2主面から第1リブと反対側に突出する第2リブを有してもよい。例えば、電池構成要素が電槽に収容される場合等にて、セパレータにおいて足部と電槽とに挟まれる部分の破損を良好に防止可能である。 The separator may further include a second main surface located on the opposite side of the first main surface, and the thick portion may have a second rib protruding from the second main surface to the opposite side of the first rib. For example, when the battery component is housed in the battery case, it is possible to satisfactorily prevent damage to the portion of the separator sandwiched between the foot and the battery case.
 セパレータの第1部分と第2部分とが互いに接合されており、第1部分と第2部分とのそれぞれは、第2方向において足部に対向してもよい。この場合、足部がセパレータから露出しにくくなる。 The first part and the second part of the separator are joined to each other, and each of the first part and the second part may face the foot part in the second direction. In this case, the foot is less likely to be exposed from the separator.
 第1部分と第2部分とは、互いに溶着されてもよい。この場合、第1部分と第2部分とを強固に接合できる。 The first part and the second part may be welded to each other. In this case, the first portion and the second portion can be firmly joined.
 第1方向及び第2方向に直交する第3方向における第1部分及び第2部分の寸法は、第3方向における足部の寸法以上でもよい。この場合、セパレータにおいて第1部分と第2部分とが接合している箇所以外にて、足部がより露出しにくくなる。 The dimensions of the first portion and the second portion in the third direction orthogonal to the first direction and the second direction may be equal to or larger than the dimensions of the foot portion in the third direction. In this case, the foot portion is less likely to be exposed except at the portion where the first portion and the second portion are joined in the separator.
 セパレータは、第2方向における第1極板の足部側にて折り返されてもよい。この場合、セパレータの折り返された部分によって足部が良好に覆われ得る。 The separator may be folded back on the foot side of the first electrode plate in the second direction. In this case, the foot can be well covered by the folded portion of the separator.
 セパレータは、第2方向における第1極板の足部側に位置する開口部を有してもよい。例えば、電池構成要素及び電解液が電槽に収容される場合、当該電解液が電池構成要素内を流動しやすくなる。 The separator may have an opening located on the foot side of the first electrode plate in the second direction. For example, when the battery component and the electrolytic solution are housed in the battery case, the electrolytic solution tends to flow in the battery component.
 足部の角は、面取りされてもよい。この場合、例えば足部に面取りされていない角が設けられる態様と比較して、肉厚部の特定箇所に対する足部からの荷重集中を抑制できる。 The corners of the foot may be chamfered. In this case, it is possible to suppress the load concentration from the foot portion to a specific portion of the thick portion, as compared with the embodiment in which the foot portion is provided with an unchamfered angle, for example.
 第1方向における足部の厚さは、第1方向における第1極板の最大厚みの厚さよりも小さく、足部は、第1方向における第1極板の一端と他端との間に位置してもよい。例えば、電池構成要素を寝かせ、当該電池構成要素をベルトコンベア等の搬送装置を用いて搬送する場合、足部が搬送装置から離間する。このため、セパレータが足部と搬送装置に挟まれにくくなる。よって、電池構成要素の搬送時における足部に起因したセパレータの破損を抑制できる。 The thickness of the foot in the first direction is smaller than the thickness of the maximum thickness of the first electrode in the first direction, and the foot is located between one end and the other end of the first electrode in the first direction. You may. For example, when the battery component is laid down and the battery component is transported by using a transport device such as a belt conveyor, the foot portion is separated from the transport device. Therefore, it becomes difficult for the separator to be sandwiched between the foot and the transport device. Therefore, it is possible to suppress damage to the separator caused by the foot during transportation of the battery component.
 本開示の一側面に係る蓄電池は、上記電池構成要素と、電池構成要素が収容される電槽と、を備え、電池構成要素は、第1方向においてセパレータを介して第1極板に積層される第2極板をさらに有し、肉厚部は、足部と電槽の底部とに挟まれる。この蓄電池は、セパレータの破損を良好に防止可能な電池構成要素を含む。加えて、肉厚部が足部と電槽の底部とに挟まれるので、電池構成要素を電槽に収容するときにセパレータが破損しにくくなる。このため、セパレータを介して互いに積層される第1極板と第2極板との短絡を良好に抑制可能である。 The storage battery according to one aspect of the present disclosure includes the battery component and an electric tank in which the battery component is housed, and the battery component is laminated on the first electrode plate via a separator in the first direction. The second electrode plate is further provided, and the thick portion is sandwiched between the foot portion and the bottom portion of the battery case. This storage battery includes battery components that can satisfactorily prevent breakage of the separator. In addition, since the thick portion is sandwiched between the foot and the bottom of the battery case, the separator is less likely to be damaged when the battery components are housed in the battery case. Therefore, it is possible to satisfactorily suppress a short circuit between the first electrode plate and the second electrode plate that are laminated with each other via the separator.
 電槽は、底部上に設けられると共に第2方向に沿って突出するクラを有し、肉厚部は、足部とクラとによって挟まれてもよい。この場合、足部とクラとの間に肉厚部が挟まれることによって、セパレータの破損が抑制される。 The battery case has a clasp that is provided on the bottom and protrudes along the second direction, and the thick portion may be sandwiched between the foot and the clasp. In this case, damage to the separator is suppressed by sandwiching the thick portion between the foot portion and the bracket.
 第1方向及び第2方向に直交する第3方向における足部の寸法は、第3方向におけるクラの寸法よりも大きくてもよい。この場合、電池構成要素を電槽に収容するときに足部からクラの特定箇所に荷重が集中しにくくなるので、肉厚部が良好に破損しにくくなる。 The size of the foot in the first direction and the third direction orthogonal to the second direction may be larger than the size of the clasp in the third direction. In this case, when the battery component is housed in the battery case, the load is less likely to be concentrated from the foot portion to the specific portion of the bracket, so that the thick portion is less likely to be damaged satisfactorily.
 第1方向及び第2方向に直交する第3方向における足部の寸法は、第3方向におけるクラの寸法以下でもよい。この場合、電槽における電池構成要素の位置がずれた場合であっても、肉厚部が足部とクラとの間に挟まれやすくなる。 The size of the foot in the first direction and the third direction orthogonal to the second direction may be less than or equal to the size of the clasp in the third direction. In this case, even if the position of the battery component in the battery case is displaced, the thick portion is likely to be sandwiched between the foot portion and the bracket.
 上記蓄電池は、鉛蓄電池でもよい。 The above storage battery may be a lead storage battery.
 本開示の一側面に係る組電池は、上記蓄電池を備える。この組電池は、セパレータの破損を良好に防止可能な電池構成要素を含む蓄電池を備える。このため、当該蓄電池において、セパレータを介して互いに積層される第1極板と第2極板との短絡を良好に抑制可能である。 The assembled battery according to one aspect of the present disclosure includes the above-mentioned storage battery. The assembled battery comprises a storage battery that includes battery components that can satisfactorily prevent breakage of the separator. Therefore, in the storage battery, it is possible to satisfactorily suppress a short circuit between the first electrode plate and the second electrode plate laminated with each other via the separator.
 本開示の一側面に係る電動車は、上記組電池を備える。この電動車は、セパレータの破損を良好に防止可能な電池構成要素を含む蓄電池を備える。このため、当該蓄電池において、セパレータを介して互いに積層される第1極板と第2極板との短絡を良好に抑制可能である。 The electric vehicle according to one aspect of the present disclosure is equipped with the above-mentioned assembled battery. This electric vehicle comprises a storage battery that includes a battery component that can satisfactorily prevent breakage of the separator. Therefore, in the storage battery, it is possible to satisfactorily suppress a short circuit between the first electrode plate and the second electrode plate laminated with each other via the separator.
 本開示の一側面によれば、セパレータの破損を良好に防止可能な電池構成要素、蓄電池、組電池及び電動車を提供できる。 According to one aspect of the present disclosure, it is possible to provide a battery component, a storage battery, an assembled battery and an electric vehicle capable of satisfactorily preventing damage to the separator.
図1は、実施形態に係る蓄電池の一部を破断して示す斜視図である。FIG. 1 is a perspective view showing a part of the storage battery according to the embodiment broken. 図2は、実施形態に係る負極を示す平面図である。FIG. 2 is a plan view showing a negative electrode according to an embodiment. 図3は、図2のIII-III線に沿った断面図である。FIG. 3 is a cross-sectional view taken along the line III-III of FIG. 図4の(a)は、セパレータシートを示す平面図であり、図4の(b)は、図4の(a)のIVb-IVb線に沿った概略断面図である。FIG. 4A is a plan view showing a separator sheet, and FIG. 4B is a schematic cross-sectional view taken along the line IVb-IVb of FIG. 4A. 図5の(a)は、本体の底部を示す平面図であり、図5の(b)は、図5の(a)のVb-Vb線に沿った概略断面図であり、図5の(c)は、図5の(a)のVc-Vc線に沿った概略断面図である。5A is a plan view showing the bottom of the main body, FIG. 5B is a schematic cross-sectional view taken along the line Vb-Vb of FIG. 5A, and FIG. c) is a schematic cross-sectional view taken along the line Vc-Vc of FIG. 5 (a). 図6は、セパレータに包まれる負極を示す平面図である。FIG. 6 is a plan view showing a negative electrode wrapped in a separator. 図7の(a)は、図6に示される一点鎖線にて囲んだ領域の拡大図であり、図7の(b)は、図7の(a)のVIIb-VIIb線に沿った断面図である。FIG. 7A is an enlarged view of the region surrounded by the alternate long and short dash line shown in FIG. 6, and FIG. 7B is a cross-sectional view taken along the line VIIb-VIIb of FIG. 7A. Is. 図8の(a)は、図7の(a)のVIIIa-VIIIa線に沿った断面図であり、図8の(b)は、図7の(a)のVIIIb-VIIIb線に沿った断面図である。8 (a) is a cross-sectional view taken along the line VIIIa-VIIIa of FIG. 7 (a), and FIG. 8 (b) is a cross-sectional view taken along the line VIIIb-VIIIb of FIG. 7 (a). It is a figure. 図9は、蓄電池の要部拡大断面図である。FIG. 9 is an enlarged cross-sectional view of a main part of the storage battery. 図10の(a)は、第1変形例に係るセパレータ及び負極の要部拡大断面図であり、図10の(b)は、第2変形例に係るセパレータ及び負極の要部拡大断面図である。FIG. 10A is an enlarged cross-sectional view of a main part of the separator and the negative electrode according to the first modification, and FIG. 10B is an enlarged cross-sectional view of the main part of the separator and the negative electrode according to the second modification. be. 図11は、第3変形例に係るセパレータに包まれる負極を示す平面図である。FIG. 11 is a plan view showing a negative electrode wrapped in the separator according to the third modification.
 以下、添付図面を参照して、本開示の一側面の好適な実施形態について詳細に説明する。なお、以下の説明において、同一要素又は同一機能を有する要素には、同一符号を用いることとし、重複する説明は省略する。 Hereinafter, preferred embodiments of one aspect of the present disclosure will be described in detail with reference to the accompanying drawings. In the following description, the same reference numerals will be used for the same elements or elements having the same function, and duplicate description will be omitted.
 図1は、本実施形態に係る蓄電池の一部を破断して示す斜視図である。図1に示されるように、蓄電池1は、例えば、制御弁式の鉛蓄電池である。蓄電池1は、例えば自動車のバッテリー、停電時等に利用されるバックアップ用電源、及び、電動フォークリフト等の電動車(もしくは電気車)の主電源に用いられる。これらの場合、複数の蓄電池1によって構成される組電池が用いられることがある。例えば、上記電動車は、複数の蓄電池1を含む組電池を有することがある。本実施形態では、蓄電池1は、例えば、クラッド式電極を備えるクラッド式鉛蓄電池である。蓄電池1は、電極群3と、正極端子5Aと、負極端子5Bと、補水栓6と、ケース7とを備える。 FIG. 1 is a perspective view showing a part of the storage battery according to the present embodiment broken. As shown in FIG. 1, the storage battery 1 is, for example, a control valve type lead storage battery. The storage battery 1 is used, for example, as a battery of an automobile, a backup power source used in the event of a power failure, and a main power source of an electric vehicle (or an electric vehicle) such as an electric forklift. In these cases, an assembled battery composed of a plurality of storage batteries 1 may be used. For example, the electric vehicle may have an assembled battery including a plurality of storage batteries 1. In the present embodiment, the storage battery 1 is, for example, a clad-type lead-acid battery provided with a clad-type electrode. The storage battery 1 includes an electrode group 3, a positive electrode terminal 5A, a negative electrode terminal 5B, a water tap 6, and a case 7.
 電極群3は、複数の正極10と、複数の負極12と、複数のセパレータ13とを有する。電極群3では、正極10と負極12とが交互に配置されている。隣り合う正極10と負極12との間には、セパレータ13が介在している。このため、正極10は、セパレータ13を介して負極12に積層される。本実施形態では、電極群3において、正極10、負極12及びセパレータ13の配列方向(以下、単に「配列方向」もしくは「積層方向」と称することもある)の端部には、負極12が配置されている。加えて、正極10と、負極12と、セパレータ13とのそれぞれは、電池構成要素とも呼称される。以下では、複数の正極10と、複数の負極12と、複数のセパレータ13とが互いに重なる方向(積層方向)を第1方向Xとする。また、第1方向Xに直交する方向を第2方向Yとし、第1方向X及び第2方向Yに直交する方向を第3方向Zとする。本実施形態では、第2方向Yは電極群3がケース7に収容される方向に相当する。第2方向Yと第3方向Zとは互いに直交しているが、これに限られない。第2方向Yと第3方向Zとは、互いに交差していればよい。 The electrode group 3 has a plurality of positive electrodes 10, a plurality of negative electrodes 12, and a plurality of separators 13. In the electrode group 3, the positive electrode 10 and the negative electrode 12 are arranged alternately. A separator 13 is interposed between the adjacent positive electrode 10 and the negative electrode 12. Therefore, the positive electrode 10 is laminated on the negative electrode 12 via the separator 13. In the present embodiment, in the electrode group 3, the negative electrode 12 is arranged at the end of the positive electrode 10, the negative electrode 12, and the separator 13 in the arrangement direction (hereinafter, may be simply referred to as “arrangement direction” or “stacking direction”). Has been done. In addition, each of the positive electrode 10, the negative electrode 12, and the separator 13 is also referred to as a battery component. In the following, the direction (stacking direction) in which the plurality of positive electrodes 10, the plurality of negative electrodes 12, and the plurality of separators 13 overlap each other is referred to as the first direction X. Further, the direction orthogonal to the first direction X is referred to as the second direction Y, and the direction orthogonal to the first direction X and the second direction Y is referred to as the third direction Z. In the present embodiment, the second direction Y corresponds to the direction in which the electrode group 3 is housed in the case 7. The second direction Y and the third direction Z are orthogonal to each other, but the present invention is not limited to this. The second direction Y and the third direction Z may intersect with each other.
 正極10(第2極板)は、例えば、クラッド式正極板である。正極10は、管状電極群14を有している。管状電極群14は、複数の管状電極15を有する。複数の管状電極15は、一列に配列されている。複数の管状電極15のそれぞれは、例えば、クラッドチューブ、当該クラッドチューブ内に挿入された芯金、及び、クラッドチューブと芯金との間に充填された正極材を有する。クラッドチューブは、ガントレットとも呼称される筒状の多孔体チューブであり、例えば、ガラス、樹脂等によって形成される。正極材は、正極活物質と、添加剤とを含み得る。正極活物質は、例えば、鉛粉、鉛丹等である。添加剤としては、炭素材料、又は、補強用短繊維等が挙げられる。化成後の正極活物質は、例えば二酸化鉛等である。 The positive electrode 10 (second electrode plate) is, for example, a clad type positive electrode plate. The positive electrode 10 has a tubular electrode group 14. The tubular electrode group 14 has a plurality of tubular electrodes 15. The plurality of tubular electrodes 15 are arranged in a row. Each of the plurality of tubular electrodes 15 has, for example, a clad tube, a core metal inserted in the clad tube, and a positive electrode material filled between the clad tube and the core metal. The clad tube is a tubular porous tube also called a gauntlet, and is formed of, for example, glass, resin, or the like. The positive electrode material may contain a positive electrode active material and an additive. The positive electrode active material is, for example, lead powder, lead tan, or the like. Examples of the additive include carbon materials, reinforcing short fibers and the like. The positive electrode active material after chemical conversion is, for example, lead dioxide or the like.
 図2は、実施形態に係る負極を示す平面図である。負極12(第1極板)は、負極格子体12aと、耳部12bとを有する負極板である。負極格子体12aは、負極12における本体部であり、負極材12cを保持する。本実施形態では、負極12において負極材12cが保持される部分の厚さは、負極格子体12aの厚さよりも大きいが、これに限られない。負極材12cは、負極活物質と、添加剤とを含み得る。負極活物質は、例えば、海綿状鉛等である。添加剤としては、硫酸バリウム、炭素材料、又は、補強用短繊維等が挙げられる。耳部12bは、第2方向Yに沿って負極格子体12aから突出する端子部である。耳部12bと負極格子体12aとは、配列方向において互いに重なっていない。本実施形態では、負極格子体12aは、セパレータ13によって覆われている。負極格子体12aには、凸部12d,12eが設けられている。凸部12d,12eは、所定の間隔をあけて配置されており、負極格子体12aから外側に向かって突出している足部である。凸部12d,12eは、耳部12bの突出方向と反対側の方向に沿って突出している。本実施形態では、耳部12bの突出方向と、凸部12d,12eの突出方向とのそれぞれは、配列方向に対して直交している。また、耳部12bと負極格子体12aとは、配列方向において互いに重なっていない。 FIG. 2 is a plan view showing a negative electrode according to an embodiment. The negative electrode 12 (first electrode plate) is a negative electrode plate having a negative electrode lattice body 12a and a selvage portion 12b. The negative electrode grid body 12a is the main body portion of the negative electrode 12, and holds the negative electrode material 12c. In the present embodiment, the thickness of the portion of the negative electrode 12 where the negative electrode material 12c is held is larger than the thickness of the negative electrode grid 12a, but is not limited to this. The negative electrode material 12c may contain a negative electrode active material and an additive. The negative electrode active material is, for example, spongy lead or the like. Examples of the additive include barium sulfate, a carbon material, and reinforcing short fibers. The selvage portion 12b is a terminal portion protruding from the negative electrode grid body 12a along the second direction Y. The selvage portion 12b and the negative electrode grid body 12a do not overlap each other in the arrangement direction. In the present embodiment, the negative electrode grid 12a is covered with the separator 13. The negative electrode lattice body 12a is provided with convex portions 12d and 12e. The convex portions 12d and 12e are foot portions that are arranged at predetermined intervals and project outward from the negative electrode grid body 12a. The convex portions 12d and 12e project along the direction opposite to the projecting direction of the selvage portion 12b. In the present embodiment, the protruding direction of the selvage portion 12b and the protruding direction of the convex portions 12d and 12e are orthogonal to the arrangement direction, respectively. Further, the selvage portion 12b and the negative electrode lattice body 12a do not overlap each other in the arrangement direction.
 図3は、図2のIII-III線に沿った断面図である。図3に示されるように、凸部12dは、第1方向Xにおける負極格子体12aの一端A1と他端A2との間に位置する。凸部12dは、先端面12fと、第1側面12gと、第2側面12hと、第1角12iと、第2角12jとを有する。第1側面12gは、第1方向Xにおける負極格子体12aの一端A1側に位置する。換言すると、第1側面12gは、第1方向Xにおいて、他端A2よりも一端A1に近い。第2側面12hは、第1方向Xにおける負極格子体12aの他端A2側に位置する。換言すると、第2側面12hは、第1方向Xにおいて、一端A1よりも他端A2に近い。第1角12iは先端面12fと第1側面12gとによってなされており、第2角12jは、先端面12fと第2側面12hとによってなされる。凸部12dに起因するセパレータ13の破損防止の観点から、第1角12iと第2角12jとのそれぞれは、面取りされている。本実施形態では、面取りされた第1角12iと第2角12jとのそれぞれは、丸面になっているが、これに限られない。第1角12iと第2角12jとのそれぞれは、例えば、凸部12dの形成後に面取りされるが、これに限られない。凸部12dの形成完了時に、面取りされた第1角12iと第2角12jとが形成されてもよい。換言すると、第1角12iと第2角12jとは、面取り工程をしなくとも丸面等の形状を有し得る。 FIG. 3 is a cross-sectional view taken along the line III-III of FIG. As shown in FIG. 3, the convex portion 12d is located between one end A1 and the other end A2 of the negative electrode lattice body 12a in the first direction X. The convex portion 12d has a tip surface 12f, a first side surface 12g, a second side surface 12h, a first angle 12i, and a second angle 12j. The first side surface 12g is located on one end A1 side of the negative electrode lattice body 12a in the first direction X. In other words, the first side surface 12g is closer to one end A1 than the other end A2 in the first direction X. The second side surface 12h is located on the other end A2 side of the negative electrode grid body 12a in the first direction X. In other words, the second side surface 12h is closer to the other end A2 than the other end A1 in the first direction X. The first angle 12i is formed by the tip surface 12f and the first side surface 12g, and the second angle 12j is formed by the tip surface 12f and the second side surface 12h. From the viewpoint of preventing damage to the separator 13 due to the convex portion 12d, each of the first corner 12i and the second corner 12j is chamfered. In the present embodiment, each of the chamfered first corner 12i and second corner 12j has a round surface, but the present invention is not limited to this. Each of the first angle 12i and the second angle 12j is chamfered after, for example, forming the convex portion 12d, but the present invention is not limited to this. When the formation of the convex portion 12d is completed, the chamfered first angle 12i and the second angle 12j may be formed. In other words, the first corner 12i and the second corner 12j may have a shape such as a round surface without chamfering.
 凸部12dの厚さT1は、負極格子体12aの厚さT2よりも小さい。第1方向Xにおいて、負極12のうち負極材12cが設けられる領域における最大厚さT3は、負極格子体12aの厚さT2よりも大きい。このため本実施形態では、負極12の最大厚みは、上記領域における最大厚さT3に相当する。なお、負極格子体12aの厚さは、負極12のうち負極材12cが設けられる領域における最大厚さ以上でもよい。この場合、負極12の最大厚みは、負極格子体12aの厚さに相当する。 The thickness T1 of the convex portion 12d is smaller than the thickness T2 of the negative electrode lattice body 12a. In the first direction X, the maximum thickness T3 in the region of the negative electrode 12 where the negative electrode material 12c is provided is larger than the thickness T2 of the negative electrode lattice body 12a. Therefore, in the present embodiment, the maximum thickness of the negative electrode 12 corresponds to the maximum thickness T3 in the above region. The thickness of the negative electrode grid 12a may be greater than or equal to the maximum thickness in the region of the negative electrode 12 where the negative electrode material 12c is provided. In this case, the maximum thickness of the negative electrode 12 corresponds to the thickness of the negative electrode lattice body 12a.
 図示しないが、凸部12eは、凸部12dと同様に、第1方向Xにおいて負極格子体12aの一端A1と他端A2との間に位置する。また、凸部12eに起因するセパレータ13の破損防止の観点から、凸部12eにおける各角は、凸部12dと同様に面取りされている。凸部12eの厚さは、負極12の最大厚みよりも小さい。 Although not shown, the convex portion 12e is located between one end A1 and the other end A2 of the negative electrode lattice body 12a in the first direction X, similarly to the convex portion 12d. Further, from the viewpoint of preventing damage to the separator 13 due to the convex portion 12e, each corner of the convex portion 12e is chamfered in the same manner as the convex portion 12d. The thickness of the convex portion 12e is smaller than the maximum thickness of the negative electrode 12.
 図1に戻って、各正極10は、正極端子5Aと電気的に接続されている。各正極10と正極端子5Aとは、正極ストラップ17によって電気的に接続されている。正極ストラップ17は、正極10の耳部10aに接続されている。各負極12は、負極端子5Bと電気的に接続されている。各負極12と負極端子5Bとは、負極ストラップ18によって電気的に接続されている。負極ストラップ18は、負極12の耳部12bに接続されている。 Returning to FIG. 1, each positive electrode 10 is electrically connected to the positive electrode terminal 5A. Each positive electrode 10 and the positive electrode terminal 5A are electrically connected by a positive electrode strap 17. The positive electrode strap 17 is connected to the selvage portion 10a of the positive electrode 10. Each negative electrode 12 is electrically connected to the negative electrode terminal 5B. Each negative electrode 12 and the negative electrode terminal 5B are electrically connected by a negative electrode strap 18. The negative electrode strap 18 is connected to the selvage portion 12b of the negative electrode 12.
 セパレータ13は、正極10と負極12との短絡を防止するための電池用部材(電池用セパレータ)である。セパレータ13は、正極10と負極12との間を電子的には絶縁する一方でイオンを透過させ、且つ、正極10側における酸化性及び負極12側における還元性に対する耐性を備えるものであれば、特に制限されない。このようなセパレータ13の材料(材質)としては、ガラス繊維、樹脂、無機物等が挙げられる。本実施形態では、セパレータ13は負極12の負極格子体12a及び凸部12d,12eを覆っており、且つ、負極12の耳部12bはセパレータ13から露出している。 The separator 13 is a battery member (battery separator) for preventing a short circuit between the positive electrode 10 and the negative electrode 12. The separator 13 is provided as long as it electronically insulates between the positive electrode 10 and the negative electrode 12 while allowing ions to permeate, and has resistance to oxidizing property on the positive electrode 10 side and reducing property on the negative electrode 12 side. There are no particular restrictions. Examples of the material (material) of such a separator 13 include glass fiber, resin, and an inorganic substance. In the present embodiment, the separator 13 covers the negative electrode lattice body 12a and the convex portions 12d and 12e of the negative electrode 12, and the selvage portion 12b of the negative electrode 12 is exposed from the separator 13.
 ここで図4の(a),(b)を参照しながら、セパレータ13の加工前製品であるセパレータシートの構造について説明する。図4の(a)は、セパレータシートを示す平面図であり、図4の(b)は、図4の(a)のIVb-IVb線に沿った概略断面図である。図4の(a),(b)に示されるように、セパレータシート30は、基部31と、一対の縁部32,33と、複数のリブ34とを有する。 Here, the structure of the separator sheet, which is the unprocessed product of the separator 13, will be described with reference to FIGS. 4 (a) and 4 (b). FIG. 4A is a plan view showing a separator sheet, and FIG. 4B is a schematic cross-sectional view taken along the line IVb-IVb of FIG. 4A. As shown in FIGS. 4A and 4B, the separator sheet 30 has a base 31, a pair of edges 32 and 33, and a plurality of ribs 34.
 基部31は、セパレータシート30の主要部となるシート状部分であり、可撓性を示す。基部31は、第1主面31aと、第2主面31bとを有する。セパレータシート30内にて、第2主面31bは、第1方向Xにおいて第1主面31aの反対側に位置する。本実施形態では、第1主面31a及び第2主面31bは、第1方向Xから見て矩形状を呈するが、これに限られない。 The base portion 31 is a sheet-like portion that is the main portion of the separator sheet 30 and exhibits flexibility. The base 31 has a first main surface 31a and a second main surface 31b. In the separator sheet 30, the second main surface 31b is located on the opposite side of the first main surface 31a in the first direction X. In the present embodiment, the first main surface 31a and the second main surface 31b have a rectangular shape when viewed from the first direction X, but the present invention is not limited to this.
 一対の縁部32,33は、第3方向Zにおけるセパレータシート30の両端に設けられる部分である。縁部32,33のそれぞれは、第2方向Yにおけるセパレータシート30の一端から他端まで延在する。第2方向Yにおけるセパレータシート30の一端は、例えば、図4の(a)における紙面上端に相当する。第2方向Yにおけるセパレータシート30の他端は、例えば、図4の(a)における紙面下端に相当する。縁部32,33のそれぞれは、連続的に延在してもよいし、間欠的に延在してもよい。縁部32は第3方向Zにおけるセパレータシート30の一端に設けられ、縁部33は第3方向Zにおけるセパレータシート30の他端に設けられる。第3方向Zの一端は、例えば、図4の(a)における紙面左端に相当する。第3方向Zの他端は、例えば、図4の(a)における紙面右端に相当する。本実施形態では、一対の縁部32,33には、リブ34とは異なるリブが設けられる。例えば、一対の縁部32,33のそれぞれには、第2方向Yにおけるセパレータシート30の一端から他端まで延在するリブ等が一又は複数設けられてもよい。 The pair of edge portions 32, 33 are portions provided at both ends of the separator sheet 30 in the third direction Z. Each of the edges 32 and 33 extends from one end to the other end of the separator sheet 30 in the second direction Y. One end of the separator sheet 30 in the second direction Y corresponds to, for example, the upper end of the paper surface in FIG. 4A. The other end of the separator sheet 30 in the second direction Y corresponds to, for example, the lower end of the paper surface in FIG. 4A. Each of the edges 32 and 33 may extend continuously or intermittently. The edge portion 32 is provided at one end of the separator sheet 30 in the third direction Z, and the edge portion 33 is provided at the other end of the separator sheet 30 in the third direction Z. One end of the third direction Z corresponds to, for example, the left end of the paper surface in FIG. 4A. The other end of the third direction Z corresponds to, for example, the right end of the paper surface in FIG. 4A. In the present embodiment, the pair of edge portions 32, 33 are provided with ribs different from the ribs 34. For example, each of the pair of edge portions 32 and 33 may be provided with one or a plurality of ribs extending from one end to the other end of the separator sheet 30 in the second direction Y.
 複数のリブ34は、例えば、セパレータシート30の耐久性向上、ケース7内における電解液の流動性向上等を図るために設けられる。複数のリブ34は、第1方向Xに沿って基部31から突出しており、互いに離間している。複数のリブ34のそれぞれは、第1方向Xから見て矩形状を呈する。複数のリブ34のそれぞれは、第2方向Yにおけるセパレータシート30の一端から他端まで延在しており、且つ、互いに平行に延在している。リブ34の延在方向に対して直交するリブ34の断面は、矩形状を呈するが、これに限られない。当該断面は、例えば、台形状でもよいし、逆台形状でもよい。第3方向Zに沿ったリブ34の寸法(幅)は、例えば、第3方向Zに沿ったセパレータシート30の寸法の0.30%以上2.5%以下である。第1方向Xに沿ったリブ34の寸法(高さ)は、例えば、第1方向Xに沿った基部31の寸法(厚さ)の100%より大きく1000%以下である。図4の(b)に示されるように、リブ34は、第1主面31aに設けられる複数の第1リブ34aと、第2主面31bに設けられる複数の第2リブ34bとを有する。第1リブ34aは、第1方向Xに沿って第1主面31aから突出する。第2リブ34bは、第2主面31bから第1リブ34aと反対側に突出する。本実施形態では、第1リブ34aと第2リブ34bとは、互いに同一形状を有し、且つ、互いに完全に重なっている。 The plurality of ribs 34 are provided, for example, in order to improve the durability of the separator sheet 30, improve the fluidity of the electrolytic solution in the case 7, and the like. The plurality of ribs 34 project from the base 31 along the first direction X and are separated from each other. Each of the plurality of ribs 34 has a rectangular shape when viewed from the first direction X. Each of the plurality of ribs 34 extends from one end to the other end of the separator sheet 30 in the second direction Y, and extends in parallel with each other. The cross section of the rib 34 orthogonal to the extending direction of the rib 34 has a rectangular shape, but is not limited to this. The cross section may be, for example, trapezoidal or inverted trapezoidal. The dimension (width) of the rib 34 along the third direction Z is, for example, 0.30% or more and 2.5% or less of the dimension of the separator sheet 30 along the third direction Z. The dimension (height) of the rib 34 along the first direction X is, for example, greater than 100% (thickness) of the dimension (thickness) of the base 31 along the first direction X and 1000% or less. As shown in FIG. 4B, the rib 34 has a plurality of first ribs 34a provided on the first main surface 31a and a plurality of second ribs 34b provided on the second main surface 31b. The first rib 34a projects from the first main surface 31a along the first direction X. The second rib 34b protrudes from the second main surface 31b on the side opposite to the first rib 34a. In the present embodiment, the first rib 34a and the second rib 34b have the same shape and completely overlap each other.
 以下では、セパレータシート30においてリブ34が設けられる部分は、セパレータシート30(及びセパレータ13)における肉厚部TP1とも呼称される。換言すると、セパレータシート30(及びセパレータ13)において、基部31とリブ34とが互いに重なる部分は、肉厚部TP1とも呼称される。このため、肉厚部TP1は、リブ34を有する。上述したように、第1リブ34aと第2リブ34bとは互いに完全に重なっていることから、本実施形態における肉厚部TP1の厚さは、基部31の厚さと、第1リブ34aの高さと、第2リブ34bの高さとの合計に相当する。基部31の厚さを第1厚さT4とし、肉厚部TP1の厚さを第2厚さT5としたとき、第2厚さT5は、例えば、第1厚さT4の100%より大きく2000%以下である。 In the following, the portion of the separator sheet 30 where the rib 34 is provided is also referred to as the thick portion TP1 of the separator sheet 30 (and the separator 13). In other words, in the separator sheet 30 (and the separator 13), the portion where the base portion 31 and the rib 34 overlap each other is also referred to as a thick portion TP1. Therefore, the thick portion TP1 has a rib 34. As described above, since the first rib 34a and the second rib 34b completely overlap each other, the thickness of the thick portion TP1 in the present embodiment is the thickness of the base 31 and the height of the first rib 34a. It corresponds to the sum of the height and the height of the second rib 34b. When the thickness of the base portion 31 is the first thickness T4 and the thickness of the thick portion TP1 is the second thickness T5, the second thickness T5 is, for example, 2000, which is larger than 100% of the first thickness T4. % Or less.
 図1に戻って、ケース7は、本体20と、蓋22とを有する。本体20は、箱状を呈している電槽である。本体20は、例えばポリプロピレン等の材料で形成されている。本体20は、電極群3及び電解液を収容する。本体20は、4つの側面部と、底部24とにより構成されている。蓋22は、本体20の開口部を覆う。蓋22には、正極端子5Aと、負極端子5Bと、補水栓6とが設けられる。正極端子5Aと負極端子5Bとの間には、補水栓6が設けられる。 Returning to FIG. 1, the case 7 has a main body 20 and a lid 22. The main body 20 is a box-shaped electric tank. The main body 20 is made of a material such as polypropylene. The main body 20 houses the electrode group 3 and the electrolytic solution. The main body 20 is composed of four side surface portions and a bottom portion 24. The lid 22 covers the opening of the main body 20. The lid 22 is provided with a positive electrode terminal 5A, a negative electrode terminal 5B, and a water tap 6. A refilling tap 6 is provided between the positive electrode terminal 5A and the negative electrode terminal 5B.
 図5の(a)は、本体20の底部を示す平面図であり、図5の(b)は、図5の(a)のVb-Vb線に沿った概略断面図であり、図5の(c)は、図5の(a)のVc-Vc線に沿った概略断面図である。図5の(a)~(c)に示されるように、本体20は、底部24上に設けられると共に第2方向Yに沿って突出するクラ25を有する。クラ25は、正極10及び負極12と、底部24とを離間させるための部材である。クラ25は、本体20に対して着脱可能に設けられてもよいし、本体20に一体化されてもよい。前者の場合、クラ25は、ケース7とは別部品となる。後者の場合、クラ25と本体20とは一体成型されてもよい。クラ25が設けられることによって、正極10及び/又は負極12から脱落した活物質の堆積物に起因した短絡を抑制できる。クラ25は、第2方向Yから見て略格子形状を有する。クラ25は、第1方向Xに沿って延在する複数の第1骨部26と、第3方向Zに沿って延在する第2骨部27とを有する。複数の第1骨部26は、例えば第3方向Zにおいて互いに離間して配置されており、第1方向Xにおける本体20の一側面から他側面まで延在する。第2方向Yにおいて、第1骨部26の一端26aは底部24に接する。第2方向Yにおいて、第1骨部26の他端26bは、第2骨部27よりも蓋22側に位置する。換言すると、第2方向Yにおいて、第1骨部26の他端26bは、第2骨部27よりも蓋22に近い。第3方向Zにおける第1骨部26の寸法S3は、第3方向Zに沿った凸部12dの寸法S1及び凸部12eの寸法S2(図2を参照)以下である。クラ25上における活物質の堆積を抑制する観点から、寸法S3は、例えば、寸法S1もしくは寸法S2の100%以下であるが、これに限られない。複数の第2骨部27は、例えば第1方向Xにおいて互いに離間して配置されており、第3方向Zにおける本体20の一側面から他側面まで延在する。第1骨部と第2骨部27とは、第2方向Yから見て互いに直交している。 5A is a plan view showing the bottom of the main body 20, FIG. 5B is a schematic cross-sectional view taken along the line Vb-Vb of FIG. 5A, and FIG. 5B is a schematic cross-sectional view. (C) is a schematic cross-sectional view taken along the line Vc-Vc of FIG. 5 (a). As shown in FIGS. 5A to 5C, the main body 20 has a clasp 25 provided on the bottom 24 and projecting along the second direction Y. The bracket 25 is a member for separating the positive electrode 10 and the negative electrode 12 from the bottom portion 24. The clutter 25 may be detachably provided with respect to the main body 20 or may be integrated with the main body 20. In the former case, the Kura 25 is a separate part from the case 7. In the latter case, the clasp 25 and the main body 20 may be integrally molded. By providing the class 25, it is possible to suppress a short circuit caused by a deposit of active material that has fallen off from the positive electrode 10 and / or the negative electrode 12. The class 25 has a substantially lattice shape when viewed from the second direction Y. The clasp 25 has a plurality of first bone portions 26 extending along the first direction X and a second bone portion 27 extending along the third direction Z. The plurality of first bone portions 26 are arranged apart from each other in, for example, the third direction Z, and extend from one side surface of the main body 20 in the first direction X to the other side surface. In the second direction Y, one end 26a of the first bone portion 26 is in contact with the bottom portion 24. In the second direction Y, the other end 26b of the first bone portion 26 is located closer to the lid 22 than the second bone portion 27. In other words, in the second direction Y, the other end 26b of the first bone portion 26 is closer to the lid 22 than the second bone portion 27. The dimension S3 of the first bone portion 26 in the third direction Z is equal to or less than the dimension S1 of the convex portion 12d and the dimension S2 of the convex portion 12e along the third direction Z (see FIG. 2). From the viewpoint of suppressing the deposition of the active material on the Kura 25, the dimension S3 is, for example, 100% or less of the dimension S1 or the dimension S2, but is not limited thereto. The plurality of second bone portions 27 are arranged apart from each other in, for example, the first direction X, and extend from one side surface to the other side surface of the main body 20 in the third direction Z. The first bone portion and the second bone portion 27 are orthogonal to each other when viewed from the second direction Y.
 次に、図6を参照しながら、電池構成要素に含まれる、負極とセパレータとを組み合わせた構造について詳細に説明する。図6は、セパレータに包まれる負極を示す平面図である。図6に示されるように、セパレータ13は、セパレータシート30の袋状加工物に相当し、負極12を包んでいる。上述したように、負極12の耳部12bは、セパレータ13から露出しており、負極12の凸部12d,12eは、セパレータ13に覆われる。セパレータ13は、例えば、1枚のセパレータシート30を第2方向Yに沿って二つ折りした後、所望の箇所が封止されることによって形成される。このとき、負極12がセパレータシート30にて挟まれるように、第2方向Yにおける負極12の凸部12d,12e側にてセパレータシート30が折り返される。換言すると、第2方向Yにおいて、負極12の凸部12d,12eよりも外側にてセパレータシート30が折り返される。これにより、セパレータシート30において折り返される部分は、第2方向Yにおいて、凸部12d,12eに対向する。縁部32,33のそれぞれにおける少なくとも一部は、第3方向Zにおいて負極12の外側に位置する。作業性向上の観点から、負極12の移動に伴ってセパレータシート30が二つ折りされてもよい。セパレータ13は、主部41と、一対のシール部42,43と、屈曲部44と、接合部45とを有する。 Next, with reference to FIG. 6, the structure in which the negative electrode and the separator included in the battery component are combined will be described in detail. FIG. 6 is a plan view showing a negative electrode wrapped in a separator. As shown in FIG. 6, the separator 13 corresponds to the bag-shaped work piece of the separator sheet 30 and encloses the negative electrode 12. As described above, the selvage portion 12b of the negative electrode 12 is exposed from the separator 13, and the convex portions 12d and 12e of the negative electrode 12 are covered with the separator 13. The separator 13 is formed, for example, by folding one separator sheet 30 in half along the second direction Y and then sealing a desired portion. At this time, the separator sheet 30 is folded back on the convex portions 12d and 12e sides of the negative electrode 12 in the second direction Y so that the negative electrode 12 is sandwiched between the separator sheets 30. In other words, in the second direction Y, the separator sheet 30 is folded back outside the convex portions 12d and 12e of the negative electrode 12. As a result, the folded portion of the separator sheet 30 faces the convex portions 12d and 12e in the second direction Y. At least a part of each of the edges 32 and 33 is located outside the negative electrode 12 in the third direction Z. From the viewpoint of improving workability, the separator sheet 30 may be folded in half as the negative electrode 12 moves. The separator 13 has a main portion 41, a pair of sealing portions 42, 43, a bent portion 44, and a joint portion 45.
 主部41は、負極12の負極格子体12aを収容する部分である。主部41は、セパレータシート30の基部31及び縁部32,33(図4の(a)を参照)から構成される。このため、主部41は、第1リブ34aが設けられる第1主面31aと、第2リブ34bが設けられる第2主面31bとを有する(図4の(b)を参照)。本実施形態では、第1主面31aが負極12に対向しており、第2主面31bが露出面となっている。このため、電極群3における正極10(図1を参照)は、セパレータシート30の第2主面31bに対向する。 The main portion 41 is a portion that accommodates the negative electrode lattice body 12a of the negative electrode 12. The main portion 41 is composed of a base portion 31 and edge portions 32, 33 (see (a) of FIG. 4) of the separator sheet 30. Therefore, the main portion 41 has a first main surface 31a provided with the first rib 34a and a second main surface 31b provided with the second rib 34b (see (b) in FIG. 4). In the present embodiment, the first main surface 31a faces the negative electrode 12, and the second main surface 31b is an exposed surface. Therefore, the positive electrode 10 (see FIG. 1) in the electrode group 3 faces the second main surface 31b of the separator sheet 30.
 一対のシール部42,43は、セパレータシート30が二つ折りされる状態を維持するための部分である。シール部42は縁部32(図4の(a)を参照)に形成され、シール部43は縁部33(図4の(a)を参照)に形成される。シール部42,43のそれぞれは、第3方向Zにおいて負極12の外側に位置する。シール部42,43のそれぞれは、第2方向Yに延在している。これにより、第3方向Zに沿った負極12の移動が、シール部42,43によって抑制できる。シール部42,43では、完全に密封されなくてもよい。セパレータ13内における電解液の流動性の観点から、シール部42,43の少なくとも一方では、電解液が通過可能な領域が設けられてもよい。シール部42,43は、例えば、超音波溶着部、ヒートシール部、コールドシール部、ギアシール部等である。ギアシール部は、ギアを用いた加圧によって機械的に貼り合わされる部分である。本実施形態では、シール部42,43のそれぞれは、第2方向Yにおけるセパレータ13の一端から他端まで延在するギアシール部である。 The pair of sealing portions 42, 43 is a portion for maintaining a state in which the separator sheet 30 is folded in half. The seal portion 42 is formed on the edge portion 32 (see (a) in FIG. 4), and the seal portion 43 is formed on the edge portion 33 (see (a) in FIG. 4). Each of the sealing portions 42 and 43 is located outside the negative electrode 12 in the third direction Z. Each of the seal portions 42 and 43 extends in the second direction Y. As a result, the movement of the negative electrode 12 along the third direction Z can be suppressed by the sealing portions 42 and 43. The sealing portions 42 and 43 do not have to be completely sealed. From the viewpoint of the fluidity of the electrolytic solution in the separator 13, a region through which the electrolytic solution can pass may be provided on at least one of the sealing portions 42 and 43. The seal portions 42 and 43 are, for example, an ultrasonic welding portion, a heat seal portion, a cold seal portion, a gear seal portion, and the like. The gear seal portion is a portion that is mechanically bonded by pressurization using a gear. In the present embodiment, each of the seal portions 42 and 43 is a gear seal portion extending from one end to the other end of the separator 13 in the second direction Y.
 屈曲部44は、セパレータシート30において折り返される部分である。屈曲部44の少なくとも一部は、負極格子体12aに当接し得る。屈曲部44の一部には、開口部44aが設けられる。開口部44aは、例えば、セパレータ13内における電解液の流動性を向上するために設けられる部分である。開口部44aは、第2方向Yにおいて凸部12d,12eのいずれにも重ならない位置に設けられる。開口部44aは、例えば第3方向Zにおけるセパレータ13の中央部に設けられるが、これに限られない。例えば、屈曲部44の一部が切断されることによって、開口部44aが形成される。 The bent portion 44 is a portion to be folded back in the separator sheet 30. At least a part of the bent portion 44 may come into contact with the negative electrode lattice body 12a. An opening 44a is provided in a part of the bent portion 44. The opening 44a is, for example, a portion provided to improve the fluidity of the electrolytic solution in the separator 13. The opening 44a is provided at a position that does not overlap with any of the convex portions 12d and 12e in the second direction Y. The opening 44a is provided, for example, in the central portion of the separator 13 in the third direction Z, but is not limited thereto. For example, the opening 44a is formed by cutting a part of the bent portion 44.
 接合部45は、シール部42,43と同様に、二つ折りされたセパレータシート30の状態を維持するための部分である。接合部45は、セパレータシート30の第1主面31aの一部と別の一部とを接合する部分である。当該一部と当該別の一部とは、第1方向Xにおいて負極12に重ならない部分であり、第2方向Yにおいて屈曲部44の反対側に位置する。このため、接合部45は、第2方向Yにおけるセパレータ13の一端側であって、第1方向Xから見て負極12の外側に位置する。よって、ケース7内における接合部45は、負極12を介して本体20(電槽)の底部24(図5の(a)を参照)の反対側に位置する。また、接合部45は、第2方向Yにて負極12の負極格子体12aに対向し、且つ、第3方向Zにおいて耳部12bに対向する。接合部45は、第3方向Zに沿って延在している。具体的には、接合部45は、第3方向Zにおけるセパレータ13の一端から他端に向かって延在しており、主部41及びシール部42に設けられる。すなわち、接合部45の一部は、シール部42に重なる。接合部45は、例えば、セパレータシート30自体が溶着された部分である。この場合、接合部45においては、第1主面31aの一部と別の一部とが溶着されている。溶着不良の防止の観点から、接合部45は、超音波溶着等によって形成されてもよい。接合部45は、シール部42,43の形成後に設けられてもよいし、シール部42,43の形成前に設けられてもよい。 The joint portion 45 is a portion for maintaining the state of the separator sheet 30 folded in half, like the seal portions 42 and 43. The joint portion 45 is a portion for joining a part of the first main surface 31a of the separator sheet 30 and another part. The part and the other part are portions that do not overlap the negative electrode 12 in the first direction X, and are located on the opposite side of the bent portion 44 in the second direction Y. Therefore, the joint portion 45 is located on one end side of the separator 13 in the second direction Y and outside the negative electrode 12 when viewed from the first direction X. Therefore, the joint portion 45 in the case 7 is located on the opposite side of the bottom portion 24 (see (a) of FIG. 5) of the main body 20 (electric tank) via the negative electrode 12. Further, the joint portion 45 faces the negative electrode lattice body 12a of the negative electrode 12 in the second direction Y and faces the selvage portion 12b in the third direction Z. The joint 45 extends along the third direction Z. Specifically, the joint portion 45 extends from one end to the other end of the separator 13 in the third direction Z, and is provided on the main portion 41 and the seal portion 42. That is, a part of the joint portion 45 overlaps with the seal portion 42. The joint portion 45 is, for example, a portion where the separator sheet 30 itself is welded. In this case, in the joint portion 45, a part of the first main surface 31a and another part are welded. From the viewpoint of preventing poor welding, the joint portion 45 may be formed by ultrasonic welding or the like. The joint portion 45 may be provided after the formation of the seal portions 42, 43, or may be provided before the formation of the seal portions 42, 43.
 図7の(a)は、図6に示される一点鎖線にて囲んだ領域の拡大図であり、図7の(b)は、図7の(a)のVIIb-VIIb線に沿った断面図である。図7の(a),(b)に示されるように、肉厚部TP1に含まれる第1リブ34aは、第2方向Yにおいて凸部12dに重なっている。本実施形態では、少なくとも2つの第1リブ34aが、第2方向Yにおいて凸部12dに重なっている。このため、負極12とセパレータ13との位置がずれた場合であっても、少なくとも1つの第1リブ34aが、第2方向Yにおいて凸部12dに重なる状体を良好に維持できる。図示しないが、凸部12eもまた、第2方向Yにおいて少なくとも1つの第1リブ34aに重なっている。凸部12eは、2つ以上の第1リブ34aに重なってもよい。 FIG. 7A is an enlarged view of the region surrounded by the alternate long and short dash line shown in FIG. 6, and FIG. 7B is a cross-sectional view taken along the line VIIb-VIIb of FIG. 7A. Is. As shown in FIGS. 7A and 7B, the first rib 34a included in the thick portion TP1 overlaps the convex portion 12d in the second direction Y. In this embodiment, at least two first ribs 34a overlap the convex portion 12d in the second direction Y. Therefore, even when the positions of the negative electrode 12 and the separator 13 are displaced, the state in which at least one first rib 34a overlaps the convex portion 12d in the second direction Y can be satisfactorily maintained. Although not shown, the convex portion 12e also overlaps with at least one first rib 34a in the second direction Y. The convex portion 12e may overlap with two or more first ribs 34a.
 図8の(a)は、図7の(a)のVIIIa-VIIIa線に沿った断面図であり、図8の(b)は、図7の(a)のVIIIb-VIIIb線に沿った断面図である。図7の(a)及び図8の(a)に示されるように、セパレータ13の屈曲部44が、凸部12dに当接している。本実施形態では図7の(b)及び図8の(b)に示されるように、先端面12f、第1角12i及び第2角12jは、基部31に対して離間しているが、これに限られない。基部31の一部が先端面12f、第1角12i及び第2角12jの少なくとも一つに当接してもよい。図示しないが、凸部12eもまた、肉厚部TP1に当接している。 8 (a) is a cross-sectional view taken along the line VIIIa-VIIIa of FIG. 7 (a), and FIG. 8 (b) is a cross-sectional view taken along the line VIIIb-VIIIb of FIG. 7 (a). It is a figure. As shown in (a) of FIG. 7 and (a) of FIG. 8, the bent portion 44 of the separator 13 is in contact with the convex portion 12d. In the present embodiment, as shown in (b) of FIG. 7 and (b) of FIG. 8, the tip surface 12f, the first angle 12i, and the second angle 12j are separated from the base 31, but they are separated from each other. Not limited to. A part of the base portion 31 may abut on at least one of the tip surface 12f, the first corner 12i and the second corner 12j. Although not shown, the convex portion 12e is also in contact with the thick portion TP1.
 図9は、蓄電池の要部拡大断面図である。図9においては、電解液及び正極は省略されている。図9に示されるように、電池構成要素に含まれ、且つ、セパレータ13に包まれる負極12が、ケース7の本体20に収容されるとき、負極12の凸部12d,12eが本体20の底部24に対向する。本実施形態では、凸部12dは、第2方向Yにおいて底部24上のクラ25に対向し、且つ、凸部12dとクラ25との間にはセパレータ13が位置する。よって、セパレータ13は、第2方向Yにおいて凸部12dとクラ25とによって挟まれる。本実施形態では、セパレータ13の肉厚部TP1が、第2方向Yにおいて凸部12dとクラ25の第1骨部26とによって挟まれる。このとき、凸部12dには第1リブ34aが接触し、クラ25には第2リブ34bが接触する。セパレータ13の基部31は、凸部12dとクラ25との少なくとも一方に接してもよいし、凸部12dとクラ25との両方に対して離間してもよい。なお図示しないが、凸部12eは、凸部12dと同様に、第2方向Yにおいてクラ25に対向しており、且つ、肉厚部TP1が第2方向Yにおいて凸部12eとクラ25の別の第1骨部26とによって挟まれる。セパレータ13の基部31は、凸部12eとクラ25との少なくとも一方に接してもよいし、凸部12eとクラ25との両方に対して離間してもよい。 FIG. 9 is an enlarged cross-sectional view of a main part of the storage battery. In FIG. 9, the electrolytic solution and the positive electrode are omitted. As shown in FIG. 9, when the negative electrode 12 included in the battery component and wrapped in the separator 13 is housed in the main body 20 of the case 7, the convex portions 12d and 12e of the negative electrode 12 are the bottom portion of the main body 20. Facing 24. In the present embodiment, the convex portion 12d faces the bracket 25 on the bottom portion 24 in the second direction Y, and the separator 13 is located between the convex portion 12d and the bracket 25. Therefore, the separator 13 is sandwiched between the convex portion 12d and the bracket 25 in the second direction Y. In the present embodiment, the thick portion TP1 of the separator 13 is sandwiched between the convex portion 12d and the first bone portion 26 of the bracket 25 in the second direction Y. At this time, the first rib 34a comes into contact with the convex portion 12d, and the second rib 34b comes into contact with the clasp 25. The base 31 of the separator 13 may be in contact with at least one of the convex portion 12d and the clasp 25, or may be separated from both the convex portion 12d and the clasp 25. Although not shown, the convex portion 12e faces the bracket 25 in the second direction Y like the convex portion 12d, and the thick portion TP1 is separated from the convex portion 12e and the bracket 25 in the second direction Y. It is sandwiched by the first bone portion 26 of the above. The base 31 of the separator 13 may be in contact with at least one of the convex portion 12e and the clasp 25, or may be separated from both the convex portion 12e and the clasp 25.
 続いて、本実施形態における蓄電池1の製造方法の一例を簡潔に説明する。まず、セパレータシート30及び負極12を準備する。このとき、セパレータシート30の第1主面31aと負極12とを対向させる。続いて、セパレータシート30を二つ折りすることによって、屈曲部44を形成すると共にセパレータシート30によって負極12を挟み込む。このとき、負極12の負極格子体12aがセパレータシート30にて完全に覆われると共に、負極12の耳部12bの一部がセパレータシート30から露出する。続いて、セパレータシート30にシール部42,43及び接合部45を形成する。シール部42,43は、例えば、ギアシール等によって形成される。接合部45は、例えば、ホーンを含む超音波溶着装置を用いた超音波溶着等によって形成される。接合部45の形成時、少なくとも第2方向Yにてセパレータシート30が接合部45に引き寄せられる。セパレータシート30に屈曲部44が形成されていることから、セパレータシート30には少なくとも第2方向Yにおける張力が生じる。これにより、セパレータシート30の一部が負極12の凸部12d,12eに押し当てられる。続いて、屈曲部44に開口部44aを形成することによって、負極12を包むセパレータ13が形成される。セパレータ13に包まれる負極12は、例えば、ベルトコンベア等の搬送装置によって搬送される。このとき、セパレータ13に包まれる負極12は、当該搬送装置上にて寝かされる。換言すると、負極12の凸部12d,12eの突出方向が高さ方向に直交するように、セパレータ13に包まれる負極12は、上記搬送装置上に配置される。上述したように、凸部12d,12eのそれぞれは、負極格子体12aの一端A1と他端A2との間に位置することから、凸部12d,12eは、上記搬送装置から離間し得る。 Subsequently, an example of the manufacturing method of the storage battery 1 in the present embodiment will be briefly described. First, the separator sheet 30 and the negative electrode 12 are prepared. At this time, the first main surface 31a of the separator sheet 30 and the negative electrode 12 are opposed to each other. Subsequently, the separator sheet 30 is folded in half to form the bent portion 44, and the negative electrode 12 is sandwiched by the separator sheet 30. At this time, the negative electrode lattice body 12a of the negative electrode 12 is completely covered with the separator sheet 30, and a part of the selvage portion 12b of the negative electrode 12 is exposed from the separator sheet 30. Subsequently, the seal portions 42, 43 and the joint portion 45 are formed on the separator sheet 30. The seal portions 42 and 43 are formed by, for example, a gear seal or the like. The joint portion 45 is formed by, for example, ultrasonic welding using an ultrasonic welding device including a horn. At the time of forming the joint portion 45, the separator sheet 30 is attracted to the joint portion 45 at least in the second direction Y. Since the bent portion 44 is formed on the separator sheet 30, tension is generated in the separator sheet 30 at least in the second direction Y. As a result, a part of the separator sheet 30 is pressed against the convex portions 12d and 12e of the negative electrode 12. Subsequently, by forming the opening 44a in the bent portion 44, the separator 13 that encloses the negative electrode 12 is formed. The negative electrode 12 wrapped in the separator 13 is conveyed by a conveyor such as a belt conveyor. At this time, the negative electrode 12 wrapped in the separator 13 is laid down on the transfer device. In other words, the negative electrode 12 wrapped in the separator 13 is arranged on the transport device so that the protruding directions of the convex portions 12d and 12e of the negative electrode 12 are orthogonal to the height direction. As described above, since each of the convex portions 12d and 12e is located between one end A1 and the other end A2 of the negative electrode lattice body 12a, the convex portions 12d and 12e can be separated from the above-mentioned transport device.
 次に、正極10と、セパレータ13に包まれる負極12とのそれぞれを複数準備する。続いて、正極10と当該負極12とを交互に積層する。続いて、正極ストラップ17を介して正極10の耳部10a同士を電気的に接続させると共に、負極ストラップ18を介して負極12の耳部12b同士を電気的に接続させる。これにより、複数の正極10と、複数の負極12と、複数のセパレータ13が含まれる電極群3を形成する。続いて、電極群3を本体20に収容する。このとき、負極12の凸部12d,12eのそれぞれは、底部24上のクラ25上に配置される。続いて、本体20を蓋22によって封止する。このとき、各正極10を正極端子5Aと電気的に接続させると共に、各負極12を負極端子5Bと電気的に接続させる。続いて、補水栓6を介して電解液をケース7内に供給する。これにより、蓄電池1が製造される。 Next, prepare a plurality of each of the positive electrode 10 and the negative electrode 12 wrapped in the separator 13. Subsequently, the positive electrode 10 and the negative electrode 12 are alternately laminated. Subsequently, the selvage portions 10a of the positive electrode 10 are electrically connected to each other via the positive electrode strap 17, and the selvage portions 12b of the negative electrode 12 are electrically connected to each other via the negative electrode strap 18. As a result, the electrode group 3 including the plurality of positive electrodes 10, the plurality of negative electrodes 12, and the plurality of separators 13 is formed. Subsequently, the electrode group 3 is housed in the main body 20. At this time, each of the convex portions 12d and 12e of the negative electrode 12 is arranged on the bracket 25 on the bottom portion 24. Subsequently, the main body 20 is sealed with the lid 22. At this time, each positive electrode 10 is electrically connected to the positive electrode terminal 5A, and each negative electrode 12 is electrically connected to the negative electrode terminal 5B. Subsequently, the electrolytic solution is supplied into the case 7 via the refill plug 6. As a result, the storage battery 1 is manufactured.
 以上に説明した本実施形態に係る蓄電池1に含まれる電池構成要素では、負極12の凸部12d,12eのそれぞれはセパレータ13に覆われる。蓄電池1を製造するために、当該電池構成要素をケース7の本体20に収容する場合等にて、本体20の底部24には負極12の凸部12d,12eが当接する。このため、セパレータ13のうち凸部12d,12eに当接する部分に荷重が集中する傾向がある。ここで本実施形態では、セパレータ13の肉厚部TP1が凸部12d,12eに当接する。これにより、セパレータ13のうち凸部12d,12eに当接する部分の耐荷重性能が良好に向上する。したがって本実施形態によれば、セパレータ13の破損を良好に防止可能である。 In the battery component included in the storage battery 1 according to the present embodiment described above, each of the convex portions 12d and 12e of the negative electrode 12 is covered with the separator 13. When the battery component is housed in the main body 20 of the case 7 in order to manufacture the storage battery 1, the convex portions 12d and 12e of the negative electrode 12 abut on the bottom 24 of the main body 20. Therefore, the load tends to be concentrated on the portions of the separator 13 that come into contact with the convex portions 12d and 12e. Here, in the present embodiment, the thick portion TP1 of the separator 13 comes into contact with the convex portions 12d and 12e. As a result, the load-bearing performance of the portions of the separator 13 that come into contact with the convex portions 12d and 12e is satisfactorily improved. Therefore, according to the present embodiment, damage to the separator 13 can be satisfactorily prevented.
 加えて、本実施形態では、肉厚部TP1が負極12の凸部12d,12eに当接する。これによって、セパレータ13の基部31にて第1リブ34aが設けられない部分は、凸部12d,12eに当接しにくくなる。このため、セパレータ13のうち耐荷重性能が比較的低い部分(すなわち、セパレータ13のうちリブ34が設けられない部分)には、凸部12d,12eからの荷重が加わりにくい。したがって本実施形態では、上述した通り、セパレータ13の破損を良好に防止可能である。 In addition, in the present embodiment, the thick portion TP1 abuts on the convex portions 12d and 12e of the negative electrode 12. As a result, the portion of the base portion 31 of the separator 13 where the first rib 34a is not provided is less likely to come into contact with the convex portions 12d and 12e. Therefore, it is difficult for the load from the convex portions 12d and 12e to be applied to the portion of the separator 13 having a relatively low load-bearing performance (that is, the portion of the separator 13 where the rib 34 is not provided). Therefore, in the present embodiment, as described above, damage to the separator 13 can be satisfactorily prevented.
 本実施形態では、セパレータ13は、負極12に対向する第1主面31aを備え、肉厚部TP1は、第1主面31aから負極12に向かって突出する第1リブ34aを有し、第1リブ34aは、凸部12dに当接する。この場合、セパレータ13の基部31が凸部12dに当接しにくくなる。加えて、凸部12dは、2つ以上の第1リブ34aに当接している。この場合、セパレータ13の基部31が凸部12dにより当接しにくくなる。 In the present embodiment, the separator 13 includes a first main surface 31a facing the negative electrode 12, and the thick portion TP1 has a first rib 34a protruding from the first main surface 31a toward the negative electrode 12. The 1 rib 34a abuts on the convex portion 12d. In this case, the base portion 31 of the separator 13 is less likely to come into contact with the convex portion 12d. In addition, the convex portion 12d is in contact with two or more first ribs 34a. In this case, the base portion 31 of the separator 13 is less likely to come into contact with the convex portion 12d.
 本実施形態では、セパレータ13は、第1主面31aの反対側に位置する第2主面31bを備え、肉厚部TP1は、第2主面31bから第1リブ34aと反対側に突出する第2リブ34bを有する。例えば、電池構成要素がケース7の本体20に収容される場合等にて、セパレータ13において凸部12dと本体20の底部24とに挟まれる部分の破損を良好に防止可能である。加えて本実施形態では、セパレータ13において凸部12eと底部24とに挟まれる部分の破損も良好に防止可能である。 In the present embodiment, the separator 13 includes a second main surface 31b located on the opposite side of the first main surface 31a, and the thick portion TP1 projects from the second main surface 31b on the opposite side to the first rib 34a. It has a second rib 34b. For example, when the battery component is housed in the main body 20 of the case 7, it is possible to satisfactorily prevent damage to the portion of the separator 13 sandwiched between the convex portion 12d and the bottom portion 24 of the main body 20. In addition, in the present embodiment, it is possible to satisfactorily prevent damage to the portion of the separator 13 sandwiched between the convex portion 12e and the bottom portion 24.
 本実施形態では、セパレータ13は、第2方向Yにおける負極12の凸部12d,12r側にて折り返される。このため、セパレータ13の屈曲部44及びその周囲によって凸部12d,12eが良好に覆われ得る。 In the present embodiment, the separator 13 is folded back at the convex portions 12d and 12r of the negative electrode 12 in the second direction Y. Therefore, the convex portions 12d and 12e can be well covered by the bent portion 44 of the separator 13 and its surroundings.
 本実施形態では、セパレータ13は、第2方向Yにおける負極12の凸部12d,12e側に位置する開口部44aを有する。例えば、電池構成要素を含む電極群3及び電解液がケース7に収容される場合、当該電解液が電極群3内を流動しやすくなる。 In the present embodiment, the separator 13 has an opening 44a located on the convex portions 12d and 12e side of the negative electrode 12 in the second direction Y. For example, when the electrode group 3 including the battery component and the electrolytic solution are housed in the case 7, the electrolytic solution easily flows in the electrode group 3.
 本実施形態では、凸部12dの第1角12i及び第2角12jは、面取りされている。この場合、例えば凸部12dに面取りされていない角が設けられる態様と比較して、肉厚部TP1の特定箇所に対する凸部12dからの荷重集中を抑制できる。図示しないが、本実施形態では、凸部12eの角もまた面取りされ得る。このため、肉厚部TP1の特定箇所に対する凸部12eからの荷重集中も抑制できる。 In the present embodiment, the first corner 12i and the second corner 12j of the convex portion 12d are chamfered. In this case, the load concentration from the convex portion 12d to the specific portion of the thick portion TP1 can be suppressed as compared with the embodiment in which the convex portion 12d is provided with an unchamfered angle, for example. Although not shown, in the present embodiment, the corners of the convex portion 12e can also be chamfered. Therefore, it is possible to suppress the load concentration from the convex portion 12e to the specific portion of the thick portion TP1.
 本実施形態では、第1方向Xにおける凸部12dの厚さT1は、第1方向Xにおける負極12の最大厚さT3よりも小さく、凸部12dは、第1方向Xにおける負極12の負極格子体12aの一端A1と他端A2との間に位置する。例えば、セパレータ13に包まれる負極12を寝かせ、当該負極12をベルトコンベア等の搬送装置を用いて搬送する場合、凸部12dが搬送装置から離間する。このため、セパレータ13が凸部12dと搬送装置に挟まれにくくなる。よって、セパレータ13に包まれる負極12の搬送時における凸部12dに起因したセパレータ13の破損を抑制できる。加えて本実施形態では、上記搬送時における凸部12eに起因したセパレータ13の破損も抑制できる。 In the present embodiment, the thickness T1 of the convex portion 12d in the first direction X is smaller than the maximum thickness T3 of the negative electrode 12 in the first direction X, and the convex portion 12d is the negative electrode lattice of the negative electrode 12 in the first direction X. It is located between one end A1 and the other end A2 of the body 12a. For example, when the negative electrode 12 wrapped in the separator 13 is laid down and the negative electrode 12 is conveyed by using a conveying device such as a belt conveyor, the convex portion 12d is separated from the conveying device. Therefore, the separator 13 is less likely to be sandwiched between the convex portion 12d and the transport device. Therefore, it is possible to suppress damage to the separator 13 due to the convex portion 12d during transportation of the negative electrode 12 wrapped in the separator 13. In addition, in the present embodiment, damage to the separator 13 due to the convex portion 12e during the transportation can be suppressed.
 本実施形態に係る正極10、負極12及びセパレータ13を含む電池構成要素が利用される蓄電池1を用いることによって、セパレータ13の破損を良好に防止可能である。このため、セパレータ13を介して互いに積層される正極10と負極12との短絡を良好に抑制可能である。加えて本実施形態では、ケース7は、底部24上に設けられると共に第2方向Yに沿って突出するクラ25を有し、肉厚部TP1は、凸部12dとクラ25とによって挟まれる。このため、凸部12dとクラ25との間に肉厚部TP1が挟まれることによって、セパレータ13の破損が抑制される。さらには本実施形態では、第3方向Zにおける凸部12dの寸法S1は、第3方向Zにおけるクラ25の寸法S3以下である。このため、セパレータ13に包まれる負極12をケース7に収容するときに凸部12dからクラ25の特定箇所に荷重が集中しにくくなる。このため、肉厚部TP1が良好に破損しにくくなる。 By using the storage battery 1 in which the battery components including the positive electrode 10, the negative electrode 12, and the separator 13 according to the present embodiment are used, damage to the separator 13 can be satisfactorily prevented. Therefore, it is possible to satisfactorily suppress a short circuit between the positive electrode 10 and the negative electrode 12 that are laminated to each other via the separator 13. In addition, in the present embodiment, the case 7 has a clasp 25 provided on the bottom portion 24 and projecting along the second direction Y, and the thick portion TP1 is sandwiched between the convex portions 12d and the clasp 25. Therefore, the thick portion TP1 is sandwiched between the convex portion 12d and the bracket 25, so that the separator 13 is prevented from being damaged. Further, in the present embodiment, the dimension S1 of the convex portion 12d in the third direction Z is equal to or less than the dimension S3 of the bracket 25 in the third direction Z. Therefore, when the negative electrode 12 wrapped in the separator 13 is housed in the case 7, the load is less likely to be concentrated from the convex portion 12d to the specific portion of the bracket 25. Therefore, the thick portion TP1 is satisfactorily less likely to be damaged.
 以下では、図10及び図11を参照しながら、上記実施形態の変形例について説明する。以下の変形例において、上記実施形態と重複する箇所の説明は省略する。したがって以下では、上記実施形態と異なる箇所を主に説明する。 Hereinafter, a modified example of the above embodiment will be described with reference to FIGS. 10 and 11. In the following modification, the description of the part overlapping with the above embodiment will be omitted. Therefore, in the following, the parts different from the above-described embodiment will be mainly described.
 図10の(a)は、第1変形例に係るセパレータ及び負極の要部拡大断面図である。図10の(a)に示されるように、セパレータ13Aに設けられる第1リブ34aと第2リブ34bとは、基部31の厚さ方向において互いに重なっていない。第1変形例では、第2リブ34bは、第3方向Zにおいて隣り合う2つの第1リブ34aの間に位置する。セパレータ13Aは、第1リブ34aを含む肉厚部TP2と、第2リブ34bを含む肉厚部TP3とを有する。肉厚部TP2の厚さは、基部31の厚さと第1リブ34aの高さとの合計に相当する。肉厚部TP3の厚さは、基部31の厚さと第2リブ34bの高さとの合計に相当する。第1変形例では、電極群3がケース7の本体20に収容されるとき、肉厚部TP2は負極12(より具体的には、凸部12d,12e)に当接し、肉厚部TP3は本体20の底部24(より具体的には、クラ25)に当接する。このような第1変形例においても、上記実施形態と同様の作用効果が奏され得る。 FIG. 10A is an enlarged cross-sectional view of a main part of the separator and the negative electrode according to the first modification. As shown in FIG. 10A, the first rib 34a and the second rib 34b provided on the separator 13A do not overlap each other in the thickness direction of the base 31. In the first modification, the second rib 34b is located between two adjacent first ribs 34a in the third direction Z. The separator 13A has a thick portion TP2 including the first rib 34a and a thick portion TP3 including the second rib 34b. The thickness of the thick portion TP2 corresponds to the sum of the thickness of the base 31 and the height of the first rib 34a. The thickness of the thick portion TP3 corresponds to the sum of the thickness of the base 31 and the height of the second rib 34b. In the first modification, when the electrode group 3 is housed in the main body 20 of the case 7, the thick portion TP2 abuts on the negative electrode 12 (more specifically, the convex portions 12d and 12e), and the thick portion TP3 It abuts on the bottom 24 (more specifically, the class 25) of the main body 20. Even in such a first modification, the same action and effect as those of the above embodiment can be achieved.
 図10の(b)は、第2変形例に係るセパレータ及び負極の要部拡大断面図である。図10の(b)に示されるように、クラ25Aに含まれる第1骨部26Aの第3方向Zに沿った寸法S4は、凸部12dの寸法S1よりも大きい。換言すると、第3方向Zにおける凸部12dの寸法S1は、第3方向Zにおけるクラ25Aの寸法S4よりも小さい。また図示しないが、寸法S4は、凸部12eの寸法S2(図2を参照)よりも大きい。このような第2変形例においても、上記実施形態と同様の作用効果が奏される。加えて、ケース7における負極12の位置がずれた場合であっても、肉厚部TP1が凸部12dとクラ25Aとの間に挟まれやすい。同様に、第3方向Zにおける凸部12eの寸法S2は、第3方向Zにおけるクラ25Aの寸法S4よりも小さいので、肉厚部TP1が凸部12eとクラ25Aとの間に挟まれやすい。 FIG. 10B is an enlarged cross-sectional view of a main part of the separator and the negative electrode according to the second modification. As shown in FIG. 10B, the dimension S4 along the third direction Z of the first bone portion 26A included in the bracket 25A is larger than the dimension S1 of the convex portion 12d. In other words, the dimension S1 of the convex portion 12d in the third direction Z is smaller than the dimension S4 of the bracket 25A in the third direction Z. Although not shown, the dimension S4 is larger than the dimension S2 (see FIG. 2) of the convex portion 12e. Also in such a second modification, the same action and effect as those of the above embodiment are exhibited. In addition, even when the position of the negative electrode 12 in the case 7 is displaced, the thick portion TP1 is likely to be sandwiched between the convex portion 12d and the bracket 25A. Similarly, since the dimension S2 of the convex portion 12e in the third direction Z is smaller than the dimension S4 of the Kura 25A in the third direction Z, the thick portion TP1 is likely to be sandwiched between the convex portion 12e and the Kura 25A.
 図11は、第3変形例に係るセパレータに包まれる負極を示す平面図である。図11に示されるように、セパレータ13Bは、上記実施形態及び上記変形例と異なり、第2方向Yにおいて負極12の凸部12d,12eに対向する屈曲部を有さない。このため第3変形例では、セパレータ13Bは、2枚のセパレータシート30から構成される。例えば、第1方向Xにおいて負極12の一端側に位置するセパレータシート30(以下では「第1セパレータシート」と称することがある)と、第1方向Xにおいて負極12の他端側に位置するセパレータシート30(以下では「第2セパレータシート」と称することがある)とが、シール部42,43等にて互いに接合されることによって、セパレータ13Bが形成される。第1セパレータシートは、第1方向Xにおける負極12の一端に接し得る位置に配置される。第2セパレータシートは、第1方向Xにおける負極12の他端に接し得る位置に配置される。 FIG. 11 is a plan view showing a negative electrode wrapped in the separator according to the third modification. As shown in FIG. 11, unlike the above-described embodiment and the above-mentioned modification, the separator 13B does not have a bent portion facing the convex portions 12d and 12e of the negative electrode 12 in the second direction Y. Therefore, in the third modification, the separator 13B is composed of two separator sheets 30. For example, a separator sheet 30 located on one end side of the negative electrode 12 in the first direction X (hereinafter, may be referred to as a “first separator sheet”) and a separator located on the other end side of the negative electrode 12 in the first direction X. The separator 13B is formed by joining the sheet 30 (hereinafter, may be referred to as a "second separator sheet") to each other at the sealing portions 42, 43 and the like. The first separator sheet is arranged at a position where it can come into contact with one end of the negative electrode 12 in the first direction X. The second separator sheet is arranged at a position where it can come into contact with the other end of the negative electrode 12 in the first direction X.
 セパレータ13Bは、上記屈曲部の代わりに、接合部45に加えて、第2方向Yにおいて負極12に対向する接合部51,52を有する。接合部51,52のそれぞれは、セパレータ13Bの一部(第1部分)と他の一部(第2部分)とが互いに接合する部分である。セパレータ13Bの一部は第1セパレータシートに含まれ、セパレータ13Bの他の一部は第2セパレータシートに含まれる。接合部51は第2方向Yにおいて凸部12dに対向し、接合部52は第2方向Yにおいて凸部12eに対向する。凸部12dの露出を防止する観点から、第3方向Zにおける接合部51の寸法S5は、凸部12dの寸法S1以上である。換言すると、接合部51に相当する上記第1部分ならびに上記第2部分の第3方向Zに沿った寸法は、凸部12dの寸法S1以上である。凸部12eの露出を防止する観点から、第3方向Zにおける接合部52の寸法S6は、凸部12eの寸法S2以上である。換言すると、換言すると、接合部52に相当する上記第1部分ならびに上記第2部分の第3方向Zに沿った寸法は、凸部12eの寸法S2以上である。 The separator 13B has joints 51 and 52 facing the negative electrode 12 in the second direction Y in addition to the joint 45 instead of the bent portion. Each of the joint portions 51 and 52 is a portion where a part (first part) of the separator 13B and another part (second part) are joined to each other. A part of the separator 13B is included in the first separator sheet, and the other part of the separator 13B is included in the second separator sheet. The joint portion 51 faces the convex portion 12d in the second direction Y, and the joint portion 52 faces the convex portion 12e in the second direction Y. From the viewpoint of preventing the convex portion 12d from being exposed, the dimension S5 of the joint portion 51 in the third direction Z is equal to or larger than the dimension S1 of the convex portion 12d. In other words, the dimensions of the first portion and the second portion corresponding to the joint portion 51 along the third direction Z are equal to or larger than the dimension S1 of the convex portion 12d. From the viewpoint of preventing the convex portion 12e from being exposed, the dimension S6 of the joint portion 52 in the third direction Z is equal to or larger than the dimension S2 of the convex portion 12e. In other words, the dimension of the first portion and the second portion corresponding to the joint portion 52 along the third direction Z is equal to or larger than the dimension S2 of the convex portion 12e.
 接合部51,52のそれぞれは、第3方向Zに沿って延在している。接合部51は、接合部45と同様に、第3方向Zにおけるセパレータ13Bの一端から他端に向かって延在しており、主部41及びシール部42に設けられる。接合部52は、第3方向Zの他端から一端に向かって延在しており、主部41及びシール部42に設けられる。接合部51,52は、第3方向Zにおいて並んでおり、且つ、互いに離間している。第3方向Zにおける接合部51,52の間には、開口部53が設けられる。開口部53は、セパレータ13Bのうち第1セパレータシートと第2セパレータシートとが互いに接合していない部分である。開口部53は、第2方向Yにおいて凸部12d,12e側に位置する。換言すると、開口部53は、第2方向Yにおいて、耳部12bよりも凸部12d,12eに近い。開口部53は、第2方向Yにおいて凸部12d,12eに重なっていない。 Each of the joint portions 51 and 52 extends along the third direction Z. Like the joint portion 45, the joint portion 51 extends from one end to the other end of the separator 13B in the third direction Z, and is provided on the main portion 41 and the seal portion 42. The joint portion 52 extends from the other end of the third direction Z toward one end, and is provided on the main portion 41 and the seal portion 42. The joint portions 51 and 52 are aligned in the third direction Z and are separated from each other. An opening 53 is provided between the joints 51 and 52 in the third direction Z. The opening 53 is a portion of the separator 13B where the first separator sheet and the second separator sheet are not joined to each other. The opening 53 is located on the convex portions 12d and 12e side in the second direction Y. In other words, the opening 53 is closer to the convex portions 12d and 12e than the selvage portion 12b in the second direction Y. The opening 53 does not overlap the convex portions 12d and 12e in the second direction Y.
 接合部51,52によるセパレータシート同士の接合を強固にする観点から、接合部51,52のそれぞれは、例えば、第1セパレータシートと第2セパレータシートとが互いに溶着された部分である。溶着不良の防止の観点から、接合部51,52のそれぞれは、超音波溶着等によって形成されてもよい。接合部51,52のそれぞれは、シール部42,43の形成後に設けられてもよいし、シール部42,43の形成前に設けられてもよい。 From the viewpoint of strengthening the bonding between the separator sheets by the joining portions 51 and 52, each of the joining portions 51 and 52 is, for example, a portion where the first separator sheet and the second separator sheet are welded to each other. From the viewpoint of preventing poor welding, each of the joint portions 51 and 52 may be formed by ultrasonic welding or the like. Each of the joint portions 51 and 52 may be provided after the formation of the seal portions 42 and 43, or may be provided before the formation of the seal portions 42 and 43.
 以上に説明した第3変形例においても、上記実施形態と同様の作用効果が奏され得る。なお第3変形例では、セパレータ13Bは2枚のセパレータシート30から構成されるが、これに限られない。例えば、第3方向Zに沿って二つ折りにされたセパレータシートが用いられてもよい。すなわち、1枚のセパレータシートから第3変形例に係るセパレータが形成されてもよい。 Even in the third modification described above, the same action and effect as those of the above embodiment can be achieved. In the third modification, the separator 13B is composed of two separator sheets 30, but the separator 13B is not limited to this. For example, a separator sheet folded in half along the third direction Z may be used. That is, the separator according to the third modification may be formed from one separator sheet.
 本開示の一側面に係る電池構成要素は、上記実施形態及び上記変形例に限られない。上記実施形態及び上記変形例は、適宜組み合わされてもよい。例えば、第1変形例と第2変形例とが組み合わされてもよい。 The battery component according to one aspect of the present disclosure is not limited to the above embodiment and the above modification. The above-described embodiment and the above-mentioned modification may be combined as appropriate. For example, the first modification and the second modification may be combined.
 上記実施形態及び上記変形例では、第1方向から見たリブは直線状に延在しているが、これに限られない。例えば、第1方向から見て、リブは波線状に延在してもよいし、ジグザグ状に延在してもよい。また、リブは、第1方向から見て、点形状(ドット形状)でもよいし、円形状でもよいし、楕円形状でもよいし、多角形状でもよい。もしくは、リブは、多角錐形状でもよいし、多角錐台形状でもよいし、円錐形状でもよいし、円錐台形状でもよい。リブの断面は、半円形状でもよいし、多角形状でもよい。リブは、第2方向に沿って延在してもよいし、第3方向に沿って延在してもよい。第1方向から見て、複数のリブによってフィッシュボーン構造が形成されてもよい。 In the above embodiment and the above modification, the ribs seen from the first direction extend linearly, but the ribs are not limited to this. For example, when viewed from the first direction, the ribs may extend in a wavy pattern or may extend in a zigzag pattern. Further, the rib may have a point shape (dot shape), a circular shape, an elliptical shape, or a polygonal shape when viewed from the first direction. Alternatively, the rib may have a polygonal pyramid shape, a polygonal pyramid shape, a conical shape, or a truncated cone shape. The cross section of the rib may be a semicircular shape or a polygonal shape. The ribs may extend along the second direction or may extend along the third direction. Seen from the first direction, the fishbone structure may be formed by a plurality of ribs.
 上記実施形態及び上記変形例では、肉厚部はリブを含んでいるが、これに限られない。例えば、肉厚部は、セパレータのうち最も薄い部分よりも厚い部分であればよく、リブを含まなくてもよい。セパレータは、リブを有する肉厚部と、リブを有さない肉厚部との両方を有してもよい。 In the above embodiment and the above modification, the thick portion includes ribs, but the thickness is not limited to this. For example, the thick portion may be a portion thicker than the thinnest portion of the separator, and may not include ribs. The separator may have both a thick portion with ribs and a thick portion without ribs.
 上記実施形態、上記第1変形例及び上記第2変形例では、第2方向に沿ってセパレータシートが二つ折りされているが、これに限られない。例えば、電極群の寸法等によっては、第3方向に沿ってセパレータシートが二つ折りされてもよい。この場合、セパレータの屈曲部に開口部が設けられなくてもよい。 In the above-described embodiment, the above-mentioned first modification, and the above-mentioned second modification, the separator sheet is folded in half along the second direction, but the present invention is not limited to this. For example, depending on the dimensions of the electrode group and the like, the separator sheet may be folded in half along the third direction. In this case, the bent portion of the separator may not be provided with an opening.
 上記実施形態、上記第1変形例及び上記第2変形例では、セパレータは1枚のセパレータシートから形成されるが、これに限られない。例えば、セパレータは、複数枚のセパレータシートから形成されてもよい。この場合、第3方向におけるセパレータの両端側にシール部が形成されてもよいし、第3方向における一方側のみにシール部が形成されてもよい。また、第2方向におけるセパレータの両側に接合部が形成されることが好ましいが、これに限られない。第2方向における一方側のみに接合部が形成されてもよい。よって、セパレータが複数枚のセパレータシートから形成される場合、当該セパレータは、袋状加工物でもよいし、筒状加工物でもよいし、袋状加工物及び筒状加工物とは異なる加工物でもよい。 In the above-described embodiment, the above-mentioned first modification, and the above-mentioned second modification, the separator is formed from one separator sheet, but is not limited thereto. For example, the separator may be formed from a plurality of separator sheets. In this case, seal portions may be formed on both ends of the separator in the third direction, or seal portions may be formed on only one side in the third direction. Further, it is preferable, but not limited to, joint portions are formed on both sides of the separator in the second direction. A joint may be formed on only one side in the second direction. Therefore, when the separator is formed from a plurality of separator sheets, the separator may be a bag-shaped processed product, a tubular processed product, or a processed product different from the bag-shaped processed product and the tubular processed product. good.
 1…蓄電池、3…電極群、5A…正極端子、5B…負極端子、7…ケース、10…正極(第2極板)、10a…耳部、12…負極(第1極板)、12a…負極格子体、12b…耳部、12c…負極材、12d,12e…凸部、12i…第1角(角)、12j…第2角(角)、13,13A,13B…セパレータ、20…本体、22…蓋、24…底部、25,25A…クラ、30…セパレータシート、31…基部、31a…第1主面、31b…第2主面、32,33…縁部、34…リブ、34a…第1リブ、34b…第2リブ、41…主部、42,43…シール部、44…屈曲部、44a…開口部、45,51,52…接合部、S1~S6…寸法、TP1,TP2,TP3…肉厚部。 1 ... Storage battery, 3 ... Electrode group, 5A ... Positive electrode terminal, 5B ... Negative electrode terminal, 7 ... Case, 10 ... Positive electrode (second electrode plate), 10a ... Ear, 12 ... Negative electrode (first electrode plate), 12a ... Negative electrode lattice, 12b ... Ear, 12c ... Negative electrode material, 12d, 12e ... Convex, 12i ... First corner (corner), 12j ... Second corner (corner), 13, 13A, 13B ... Separator, 20 ... Main body , 22 ... lid, 24 ... bottom, 25, 25A ... class, 30 ... separator sheet, 31 ... base, 31a ... first main surface, 31b ... second main surface, 32, 33 ... edge, 34 ... rib, 34a ... 1st rib, 34b ... 2nd rib, 41 ... Main part, 42, 43 ... Seal part, 44 ... Bending part, 44a ... Opening, 45, 51, 52 ... Joint part, S1 to S6 ... Dimensions, TP1, TP2, TP3 ... Thick part.

Claims (18)

  1.  第1方向にて互いに重なる第1極板及びセパレータを備え、
     前記第1極板は、本体部と、前記第1方向に直交する第2方向に沿って前記本体部から突出すると共に前記セパレータに覆われる足部とを有し、
     前記セパレータは、第1厚さを有する基部と、前記第1厚さよりも厚い第2厚さを有すると共に前記足部に当接する肉厚部とを備える、
    電池構成要素。
    It is provided with a first electrode plate and a separator that overlap each other in the first direction.
    The first electrode plate has a main body portion and a foot portion that protrudes from the main body portion and is covered with the separator along a second direction orthogonal to the first direction.
    The separator comprises a base having a first thickness and a thick portion having a second thickness thicker than the first thickness and abutting on the foot.
    Battery component.
  2.  前記セパレータは、前記第1極板に対向する第1主面をさらに備え、
     前記肉厚部は、前記第1主面から前記第1極板に向かって突出する第1リブを有し、
     前記第1リブは、前記足部に当接する、請求項1に記載の電池構成要素。
    The separator further comprises a first main surface facing the first electrode plate.
    The thick portion has a first rib protruding from the first main surface toward the first electrode plate.
    The battery component according to claim 1, wherein the first rib abuts on the foot portion.
  3.  前記肉厚部は、前記第1リブを複数有し、
     前記足部は、2つ以上の前記第1リブに当接する、請求項2に記載の電池構成要素。
    The thick portion has a plurality of the first ribs, and the thick portion has a plurality of the first ribs.
    The battery component according to claim 2, wherein the foot portion abuts on two or more of the first ribs.
  4.  前記セパレータは、前記第1主面の反対側に位置する第2主面をさらに備え、
     前記肉厚部は、前記第2主面から前記第1リブと反対側に突出する第2リブを有する、請求項2または3に記載の電池構成要素。
    The separator further comprises a second main surface located on the opposite side of the first main surface.
    The battery component according to claim 2 or 3, wherein the thick portion has a second rib protruding from the second main surface to the opposite side of the first rib.
  5.  前記セパレータの第1部分と第2部分とが互いに接合されており、
     前記第1部分と前記第2部分とのそれぞれは、前記第2方向において前記足部に対向している、請求項1~4のいずれか一項に記載の電池構成要素。
    The first part and the second part of the separator are joined to each other.
    The battery component according to any one of claims 1 to 4, wherein each of the first portion and the second portion faces the foot portion in the second direction.
  6.  前記第1部分と前記第2部分とは、互いに溶着されている、請求項5に記載の電池構成要素。 The battery component according to claim 5, wherein the first portion and the second portion are welded to each other.
  7.  前記第1方向及び前記第2方向に直交する第3方向における前記第1部分及び前記第2部分の寸法は、前記第3方向における前記足部の寸法以上である、請求項5又は6に記載の電池構成要素。 5. The aspect of claim 5 or 6, wherein the dimensions of the first portion and the second portion in the first direction and the third direction orthogonal to the second direction are equal to or larger than the dimensions of the foot portion in the third direction. Battery components.
  8.  前記セパレータは、前記第2方向における前記第1極板の前記足部側にて折り返されている、請求項1~4のいずれか一項に記載の電池構成要素。 The battery component according to any one of claims 1 to 4, wherein the separator is folded back on the foot side of the first electrode plate in the second direction.
  9.  前記セパレータは、前記第2方向における前記第1極板の前記足部側に位置する開口部を有する、請求項5~8のいずれか一項に記載の電池構成要素。 The battery component according to any one of claims 5 to 8, wherein the separator has an opening located on the foot side of the first electrode plate in the second direction.
  10.  前記足部の角は、面取りされている、請求項1~9のいずれか一項に記載の電池構成要素。 The battery component according to any one of claims 1 to 9, wherein the corner of the foot is chamfered.
  11.  前記第1方向における前記足部の厚さは、前記第1方向における前記第1極板の最大厚みの厚さよりも小さく、
     前記足部は、前記第1方向における前記第1極板の一端と他端との間に位置する、請求項1~10のいずれか一項に記載の電池構成要素。
    The thickness of the foot in the first direction is smaller than the thickness of the maximum thickness of the first electrode in the first direction.
    The battery component according to any one of claims 1 to 10, wherein the foot portion is located between one end and the other end of the first electrode plate in the first direction.
  12.  請求項1~11のいずれか一項に記載の電池構成要素と、
     前記電池構成要素が収容される電槽と、
    を備え、
     前記電池構成要素は、前記第1方向において前記セパレータを介して前記第1極板に積層される第2極板をさらに有し、
     前記肉厚部は、前記足部と前記電槽の底部とに挟まれる、
    蓄電池。
    The battery component according to any one of claims 1 to 11.
    An electric tank in which the battery components are housed, and
    Equipped with
    The battery component further comprises a second electrode plate laminated on the first electrode plate via the separator in the first direction.
    The thick portion is sandwiched between the foot portion and the bottom portion of the electric tank.
    Storage battery.
  13.  前記電槽は、前記底部上に設けられると共に前記第2方向に沿って突出するクラを有し、
     前記肉厚部は、前記足部と前記クラとによって挟まれる、請求項12に記載の蓄電池。
    The battery case has a bracket provided on the bottom and protruding along the second direction.
    The storage battery according to claim 12, wherein the thick portion is sandwiched between the foot portion and the clasp.
  14.  前記第1方向及び前記第2方向に直交する第3方向における前記足部の寸法は、前記第3方向における前記クラの寸法よりも大きい、請求項13に記載の蓄電池。 The storage battery according to claim 13, wherein the dimension of the foot portion in the first direction and the third direction orthogonal to the second direction is larger than the dimension of the clasp in the third direction.
  15.  前記第1方向及び前記第2方向に直交する第3方向における前記足部の寸法は、前記第3方向における前記クラの寸法以下である、請求項13に記載の蓄電池。 The storage battery according to claim 13, wherein the dimension of the foot portion in the first direction and the third direction orthogonal to the second direction is equal to or less than the dimension of the clasp in the third direction.
  16.  鉛蓄電池である、請求項12~15のいずれか一項に記載の蓄電池。 The storage battery according to any one of claims 12 to 15, which is a lead storage battery.
  17.  請求項12~16のいずれか一項に記載の蓄電池を備える組電池。 An assembled battery including the storage battery according to any one of claims 12 to 16.
  18.  請求項17に記載の組電池を備える電動車。 An electric vehicle equipped with the assembled battery according to claim 17.
PCT/JP2021/026644 2020-07-28 2021-07-15 Cell constituent element, storage cell, assembled cell, and electric vehicle WO2022024785A1 (en)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003346767A (en) * 2002-05-30 2003-12-05 Matsushita Electric Ind Co Ltd Separator for storage battery and lead acid storage battery using the same
JP2004127800A (en) * 2002-10-04 2004-04-22 Matsushita Electric Ind Co Ltd Lead-acid battery
JP2010140772A (en) * 2008-12-12 2010-06-24 Panasonic Corp Lead storage battery
JP2017069023A (en) * 2015-09-30 2017-04-06 株式会社Gsユアサ Lead storage battery

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003346767A (en) * 2002-05-30 2003-12-05 Matsushita Electric Ind Co Ltd Separator for storage battery and lead acid storage battery using the same
JP2004127800A (en) * 2002-10-04 2004-04-22 Matsushita Electric Ind Co Ltd Lead-acid battery
JP2010140772A (en) * 2008-12-12 2010-06-24 Panasonic Corp Lead storage battery
JP2017069023A (en) * 2015-09-30 2017-04-06 株式会社Gsユアサ Lead storage battery

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