WO2022021344A1 - Magnetic random access memory and device, and read-write control method - Google Patents

Magnetic random access memory and device, and read-write control method Download PDF

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Publication number
WO2022021344A1
WO2022021344A1 PCT/CN2020/106252 CN2020106252W WO2022021344A1 WO 2022021344 A1 WO2022021344 A1 WO 2022021344A1 CN 2020106252 W CN2020106252 W CN 2020106252W WO 2022021344 A1 WO2022021344 A1 WO 2022021344A1
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layer
random access
access memory
magnetic
tunnel junction
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PCT/CN2020/106252
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French (fr)
Chinese (zh)
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赵巍胜
李智
曹凯华
张昆
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北京航空航天大学
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    • GPHYSICS
    • G11INFORMATION STORAGE
    • G11CSTATIC STORES
    • G11C11/00Digital stores characterised by the use of particular electric or magnetic storage elements; Storage elements therefor
    • G11C11/02Digital stores characterised by the use of particular electric or magnetic storage elements; Storage elements therefor using magnetic elements
    • G11C11/16Digital stores characterised by the use of particular electric or magnetic storage elements; Storage elements therefor using magnetic elements using elements in which the storage effect is based on magnetic spin effect
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10BELECTRONIC MEMORY DEVICES
    • H10B61/00Magnetic memory devices, e.g. magnetoresistive RAM [MRAM] devices
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10NELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10N50/00Galvanomagnetic devices
    • H10N50/10Magnetoresistive devices
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10NELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10N59/00Integrated devices, or assemblies of multiple devices, comprising at least one galvanomagnetic or Hall-effect element covered by groups H10N50/00 - H10N52/00

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  • the present invention relates to the technical field of magnetic memory, and in particular, to a magnetic random access memory, a device and a read-write control method.
  • Magnetic random access memory has the advantages of unlimited erasing and rewriting times, non-volatility, fast read and write speed, and radiation resistance. Ideal for memory and in-memory computing.
  • Electric field (voltage) regulated magnetic anisotropy (VCMA) is a hot field in spintronics and has great potential in magnetic random access memory.
  • MRAM based on VCMA effect can significantly reduce the current density required for magnetization inversion by adjusting the structure of the magnetic memory device and applying a bias voltage during the inversion process in the process of magnetization inversion of the free layer induced by the usual current. The size can be further reduced, while the write power consumption is greatly reduced. However, as the size of magnetic random access memory is reduced, the VCMA effect coefficient cannot meet the requirements of MRAM.
  • One object of the present invention is to provide a magnetic random access memory, which can significantly improve the interface effect between the dielectric layer and the magnetic tunnel junction, thereby greatly improving the VCMA effect provided for the magnetic tunnel junction, thereby optimizing the power consumption, writing, and power consumption of the magnetic random access memory. performance such as entry speed and thermal stability.
  • Another object of the present invention is to provide a magnetic random access memory device.
  • Another object of the present invention is to provide a control method of a magnetic random access memory.
  • a magnetic random access memory comprising:
  • a magnetic tunnel junction is at least partially disposed on the dielectric layer.
  • the magnetic tunnel junction includes a free ferromagnetic layer, a tunneling layer provided on the free ferromagnetic layer, and a reference ferromagnetic layer provided on the tunneling layer, the free ferromagnetic layer at least partially on the dielectric layer; or,
  • the magnetic tunnel junction includes a free ferromagnetic layer disposed between the ferroelectric layer and the dielectric layer, and a reference ferromagnetic layer disposed at least partially on the dielectric layer.
  • it further comprises a first electrode electrically connected to the reference ferromagnetic layer and a second electrode electrically connected to the free ferromagnetic layer.
  • it further includes a bottom electrode electrically connected to the ferroelectric layer.
  • the bottom electrode includes a bottom electrode layer and a third electrode electrically connected to the bottom electrode layer, and the ferroelectric layer is disposed on the bottom electrode layer.
  • it further includes a metal layer disposed between the ferroelectric layer and the dielectric layer.
  • the bottom area of the tunneling layer is smaller than the top area of the free ferromagnetic layer, and the second electrode is disposed on the free ferromagnetic layer.
  • the bottom area of the ferroelectric layer is smaller than the top area of the bottom electrode layer, and the third electrode is disposed on the bottom electrode layer.
  • the present invention also discloses a magnetic random access memory device, comprising the above magnetic random access memory and a control circuit electrically connected with the magnetic random access memory;
  • the control circuit is used for applying a read voltage or a write current on the magnetic tunnel junction, and applying a forward bias voltage or a negative bias voltage on the negative capacitance structure formed by the ferroelectric layer and the dielectric layer To reduce or improve the magnetic anisotropy of the magnetic tunnel junction.
  • the invention also discloses a read-write control method of the magnetic random storage device, comprising:
  • a forward bias voltage is applied to both ends of the negative capacitance structure formed by the ferroelectric layer and the dielectric layer through a control circuit to reduce the magnetic anisotropy of the magnetic tunnel junction;
  • Data writing is completed by applying a writing current corresponding to the data to be written at both ends of the magnetic tunnel junction by the control circuit;
  • a read voltage is applied across the magnetic tunnel junction by a control circuit, and data stored in the magnetic tunnel junction is determined according to the change of the read voltage.
  • it further includes:
  • a forward bias is applied to both ends of the negative capacitance structure formed by the ferroelectric layer and the dielectric layer while the write current corresponding to the data to be written is applied to both ends of the magnetic tunnel junction through the control circuit Voltage;
  • a negative bias voltage is applied to both ends of the negative capacitance structure formed by the ferroelectric layer and the dielectric layer while the read voltage is applied across the magnetic tunnel junction through the control circuit.
  • a negative capacitance structure is formed by arranging a dielectric layer and a ferroelectric layer, so that the dielectric layer can obtain a voltage gain effect.
  • the interface effect of the junction is greatly improved, thereby greatly improving the VCMA effect provided for the magnetic tunnel junction, thereby optimizing the power consumption, writing speed and thermal stability of the magnetic random access memory.
  • FIG. 1 shows a structural diagram of a magnetic random access memory according to an embodiment of the present invention
  • Fig. 2 shows the structure diagram of the connection between the magnetic random access memory and the external control circuit in the first embodiment of the present invention
  • Fig. 3 shows the voltage timing diagram of the first electrode and the second electrode in the first embodiment of the present invention
  • FIG. 4 shows a flowchart of a method for controlling a magnetic random access memory according to an embodiment of the present invention
  • FIG. 5 is a schematic structural diagram of a computer device applying a magnetic random access memory according to an embodiment of the present invention.
  • FIG. 6 shows a structural diagram of a magnetic random access memory according to Embodiment 2 of the present invention.
  • FIG. 7 shows a structural diagram of a magnetic random access memory according to Embodiment 3 of the present invention.
  • first part over or on the second part may include embodiments in which the first part and the second part are formed in direct contact, and may also include additionally forming between the first part and the second part. parts so that the first part and the second part may not be in direct contact.
  • present invention may repeat reference numerals and/or characters in various embodiments. This repetition is for the purpose of simplicity and clarity, and does not in itself indicate a relationship between the various embodiments and/or configurations discussed.
  • spatially relative terms such as “below”, “below”, “lower”, “above”, “upper” and the like may be used herein to describe the The relationship of one element or part to another (or other) elements or parts.
  • spatially relative terms are intended to encompass different orientations of the device in use or operation.
  • the device may be otherwise oriented (rotated 90 degrees or at other orientations) and the spatially relative descriptors used herein interpreted accordingly.
  • An existing Magnetic Tunnel Junction (MTJ)-based Magnetic Random Access Memory (MRAM) includes a spin-orbit moment layer and at least one magnetic tunnel junction disposed on the spin-orbit moment layer.
  • the magnetic tunnel junction includes a reference (ferromagnetic) layer 133, a potential barrier layer (tunneling layer 132) and a free (ferromagnetic) layer 131 arranged from top to bottom, the bottom surface of the free layer and the upper surface of the spin-orbit moment layer Surface contact fixation.
  • the resistance value of the magnetic tunnel junction depends on the magnetization directions of the free layer and the reference layer. If the magnetization directions of the free layer and the reference layer are consistent, the resistance value of the magnetic tunnel junction is small and the magnetic tunnel junction is in a low resistance state. On the contrary, if the magnetization directions of the free layer and the reference layer are opposite, the resistance value of the magnetic tunnel junction is larger, and the magnetic tunnel junction is in a high resistance state.
  • the magnetization direction of the reference layer is preset as a fixed and constant magnetization direction. For example, a synthetic antiferromagnetic layer can be used to make the magnetization direction of the reference layer fixed, and the magnetization direction of the free layer can be changed by writing operations. In the later data reading, the data stored in the memory can be determined by determining the resistance state of the magnetic tunnel junction through the reading circuit.
  • VCMA Voltage Control Magnetic Anisotropy
  • STT-MRAM based on VCMA effect is a new type of non-volatile magnetic random access memory that realizes information writing through spin current.
  • spin current When current flows through the magnetic layer, the current will be polarized, forming a spin-polarized current.
  • Spin electrons transfer spin momentum to the magnetic moment of the free layer, so that the magnetic moment of the spin magnetic layer changes direction after gaining spin momentum. This process is called spin transfer torque.
  • VCMA technology can significantly reduce the current density required for magnetization inversion by adjusting the structure of the magnetic memory device and applying a bias voltage during the inversion process in the usual current-induced magnetization inversion of the free layer, enabling the device size to be further improved. reduction, while substantially reducing write power consumption.
  • the VCMA effect coefficient cannot meet the requirements of MRAM.
  • the advantages brought by VCMA technology to MRAM are directly related to the VCMA effect coefficient (that is, the magnetic anisotropy change brought by unit electric field, unit fJ/Vm, the typical value is 100fJ/Vm).
  • the bias voltage Under the bias voltage, a stronger magnetic anisotropy modulation effect can be produced, thereby optimizing the write power consumption, write speed, write error rate and thermal stability of the MRAM (these indicators are in a trade-off relationship with each other).
  • the current VCMA effect coefficient cannot meet the requirements of MRAM.
  • a negative capacitance structure is formed by arranging a ferroelectric layer and a dielectric layer, so as to increase the amount of charge accumulation at the interface of the ferroelectric layer and the dielectric layer, thereby increasing the strength of the VCMA effect. Therefore, when the same VCMA effect strength as the existing STT-MRAM is formed, the writing current density required by the present invention is lower, the device size can be reduced, and the demand for the continuous miniaturization of the magnetic random access memory is satisfied.
  • a first electrode electrically connected to the reference ferromagnetic layer, a second electrode electrically connected to the free ferromagnetic layer, and a bottom electrode electrically connected to the ferroelectric layer are arranged in the magnetic random access memory, forming a structure with three external Magnetic random access memory for electrodes.
  • the negative capacitance structure is pressurized through the second electrode and the bottom electrode, and data writing and reading are performed through the first electrode and the second electrode.
  • the data writing and reading currents do not pass through the ferroelectric layer, which avoids the influence of the dielectric ferroelectric layer on the data reading and writing process, further reduces the requirements for the writing current density, and is conducive to further shrinking the size of the device.
  • the present embodiment discloses a magnetic random access memory.
  • the magnetic random access memory includes a ferroelectric layer 110 , a dielectric layer 120 disposed on the ferroelectric layer 110 , and a magnetic layer at least partially disposed on the dielectric layer 120 . tunnel junction.
  • the dielectric layer 120 can obtain a voltage gain effect, and the magnetic tunnel junction is arranged on the dielectric layer 120 and the ferroelectric layer 110, which can significantly improve the dielectric
  • the interface effect between the electrical layer 120 and the magnetic tunnel junction can greatly improve the VCMA effect provided for the magnetic tunnel junction, thereby optimizing the power consumption, writing speed and thermal stability of the magnetic random access memory.
  • Q is the charge accumulation
  • V is the applied voltage
  • ferroelectric materials as ordinary capacitors has:
  • the ferroelectric layer 110 and the dielectric layer 120 are disposed up and down and are in electrical contact, which is equivalent to connecting the ferroelectric layer 110 and the dielectric layer 120 in series to form a negative capacitance structure, which can improve the equivalent capacitance.
  • the amount of charge accumulation at the interface between the ferroelectric layer 110 and the dielectric layer 120 is increased, thereby increasing the strength of the VCMA effect.
  • the magnetic tunnel junction includes a free ferromagnetic layer 131 , a tunneling layer 132 disposed on the free ferromagnetic layer 131 and a reference ferromagnetic layer disposed on the tunneling layer 132 133 , the free ferromagnetic layer 131 is at least partially disposed on the dielectric layer 120 .
  • the free ferromagnetic layer 131 of the magnetic tunnel junction is disposed on the dielectric layer 120, and under the action of the negative capacitance structure of the ferroelectric layer 110 and the dielectric layer 120, a stronger VCMA is generated under the condition of an applied voltage effect, increase or decrease the magnetic anisotropy of the magnetic tunnel junction, and facilitate the writing of data.
  • the free ferromagnetic layer 131 may include two ferromagnetic layers and a metal coupling layer between the two ferromagnetic layers.
  • the two ferromagnetic layers and the metal coupling layer between the two ferromagnetic layers form a synthetic free ferromagnetic layer 131, which can improve the thermal stability of the memory and reduce the difficulty of processing the memory.
  • the structure composed of the tunnel layer and the free ferromagnetic layer 131 may be provided in multiple numbers, that is, the magnetic tunnel junction includes multiple combined layer structures and reference ferromagnetic structures formed on the multiple combined layer structures layer 133 , wherein each combined layer structure includes a free ferromagnetic layer 131 and a tunneling layer 132 provided on the free ferromagnetic layer 131 .
  • the magnetic random access memory further includes a first electrode 150 electrically connected to the reference ferromagnetic layer 133 and a second electrode 160 electrically connected to the free ferromagnetic layer 131 . It can be understood that, by connecting the first electrode 150 and the second electrode 160 to an external control circuit, as shown in FIG. 2 .
  • the external control circuit can input the write current and the read voltage into the magnetic random access memory through the first electrode 150 and the second electrode 160 to realize the writing and reading of data.
  • the magnetic random access memory further includes a bottom electrode electrically connected to the ferroelectric layer 110 .
  • the second electrode 160 is electrically connected to the free ferromagnetic layer 131.
  • the bottom area of the tunneling layer 132 can be made smaller than the top area of the free ferromagnetic layer 131, and the second electrode 160 is disposed on the free ferromagnetic layer 131, thereby reducing the magnetic random access memory (RAM) capacity. size, easy to process molding.
  • RAM magnetic random access memory
  • the bottom electrode may include a bottom electrode layer 171 and a third electrode 172 electrically connected to the bottom electrode layer 171 , and the ferroelectric layer 110 is disposed on the bottom electrode layer 171 .
  • the ferroelectric layer 110 and its upper structure can be supported, and the bottom electrode layer 171 and the ferroelectric layer 110 can be in surface contact , and the third electrode 172 can be electrically connected with the external control circuit, and the connection method is simple.
  • the bottom area of the ferroelectric layer 110 can be made smaller than the top area of the bottom electrode layer 171, and the third electrode 172 is disposed on the bottom electrode layer 171, thereby further reducing the size of the magnetic random access memory. , which is convenient for process forming.
  • the ferroelectric layer 110 since the ferroelectric material of the ferroelectric layer 110 has dielectric properties, the ferroelectric layer 110 will affect the writing current of data.
  • a bottom electrode electrically connected to the ferroelectric layer 110 and a second electrode 160 electrically connected to the free ferromagnetic layer 131 are provided.
  • a forward bias voltage can be applied between the second electrode 160 and the third electrode 172 to reduce the magnetic anisotropy of the free ferromagnetic layer 131 , thereby reducing the writing current and magnetic field.
  • the thermal stability of the random access memory makes it possible to complete the data writing operation in the magnetic tunnel junction by inputting a small writing current between the first electrode 150 and the second electrode 160 .
  • the VCMA effect of the ferroelectric layer 110 still partially exists after the end of the applied voltage, that is, the VCMA effect is non-volatile.
  • an external voltage can be applied during data writing to reduce the perpendicular magnetic anisotropy of the free ferromagnetic layer 131
  • a negative bias voltage can be applied after data writing is completed to improve the free ferromagnetic layer 131 .
  • Various anisotropy of perpendicular magnetism that is, improving the thermal stability of the magnetic tunnel junction and preventing the magnetic tunnel junction from being affected by the environment.
  • the magnetic random access memory further includes a metal layer 140 disposed between the ferroelectric layer 110 and the dielectric layer 120 .
  • a metal layer 140 disposed between the ferroelectric layer 110 and the dielectric layer 120 .
  • the metal layer 140 may be provided as a seed layer with a specific lattice structure to improve its film formation quality.
  • first electrode 150 , the second electrode 160 and the third electrode 172 in this embodiment is only an example. In other embodiments, the first electrode 150 , the second electrode 160 and the third electrode 172 Other setting methods can also be used, which can be directly or indirectly electrically connected to the reference ferromagnetic layer 133, the free ferromagnetic layer 131 and the bottom electrode layer 171 without short-circuiting other layer structures.
  • the shape, size and arrangement of the third electrode 160 and the third electrode 172 are not limited.
  • the material of the free ferromagnetic layer 131 and the reference ferromagnetic layer 133 may be ferromagnetic metal, and the material of the tunneling layer 132 may be oxide.
  • the ferromagnetic metal may be a single or mixed metal material formed of at least one of cobalt iron CoFe, cobalt iron boron CoFeB or nickel iron NiFe, wherein the ratio of the mixed metal materials may be the same or different.
  • the oxide may be one of oxides such as magnesium oxide MgO or aluminum oxide Al 2 O 3 , which is used to generate the tunneling magnetoresistance effect. In practical applications, ferromagnetic metals and oxides can also adopt other feasible materials, which are not limited in the present invention.
  • the material of the ferroelectric layer 110 may include hafnium oxide and doped one or more elements selected from elements such as silicon, zirconium, aluminum, lanthanum, yttrium, gadolinium, magnesium, and strontium.
  • the material of the ferroelectric layer 110 may include zirconia and doped one or more elements, the one or more elements are selected from elements such as silicon, hafnium, aluminum, lanthanum, yttrium, gadolinium, magnesium and strontium, iron
  • the material of the electrical layer 110 may include strontium titanate and doped one or more elements selected from elements such as silicon, zirconium, aluminum, lanthanum, yttrium, gadolinium, magnesium, and hafnium.
  • the ferroelectric layer 110 may also be selected from other materials available in the art, which are not limited in the present invention.
  • the material of the dielectric layer 120 may include hafnium oxide, zirconium oxide, magnesium oxide, aluminum oxide, strontium titanate and other metal oxides.
  • the dielectric layer 120 may also be selected from other feasible materials in the art. material, which is not limited in the present invention.
  • the layers of the magnetic random access memory can be arranged from bottom to top by conventional chemical vapor deposition, physical vapor deposition (including sputtering), ion beam epitaxy, atomic layer deposition or magnetron sputtering. are sequentially formed on the bottom electrode layer 171, and then the final magnetic random access memory is prepared by traditional nano-device processing techniques such as photolithography and etching.
  • this embodiment also discloses a magnetic random access memory device.
  • the magnetic random access memory device includes the magnetic random access memory described in this embodiment and a control circuit electrically connected to the magnetic random access memory.
  • control circuit is used to apply a read voltage or a write current on the magnetic tunnel junction, and a forward bias voltage or negative capacitance is applied to the negative capacitance structure formed by the ferroelectric layer 110 and the dielectric layer 120 bias voltage to reduce or increase the magnetic anisotropy of the magnetic tunnel junction.
  • the implementation of the device can refer to the implementation of the memory, and details are not repeated here.
  • this embodiment also discloses a read-write control method for a magnetic random access memory device.
  • the method includes:
  • a forward bias voltage is applied to both ends of the negative capacitance structure formed by the ferroelectric layer 110 and the dielectric layer 120 through a control circuit to reduce the magnetic anisotropy of the magnetic tunnel junction.
  • S200 Complete data writing by applying a writing current corresponding to the data to be written at both ends of the magnetic tunnel junction through a control circuit.
  • S300 Apply a read voltage to both ends of the magnetic tunnel junction through a control circuit, and determine the data stored in the magnetic tunnel junction according to the change of the read voltage.
  • the method further comprises:
  • the method further comprises:
  • the magnetic anisotropy of the magnetic tunnel junction can be improved, thereby reducing the probability of false inversion during data reading.
  • the implementation of the method can refer to the implementation of the memory and the device, and details are not repeated here.
  • the magnetic random access memory in this embodiment can be used to form equipment such as computer chips.
  • the computer device may be, for example, a personal computer, a laptop computer, a cellular phone, a camera phone, a smart phone, a personal digital assistant, a media player, a navigation device, an email device, a game console, a tablet computer, a wearable device Or a combination of any of these devices.
  • the computer device specifically includes a memory, a processor, and a computer program stored in the memory and executable on the processor, and the memory can use the magnetic random access memory described in this embodiment.
  • FIG. 5 shows a schematic structural diagram of a computer device 600 suitable for implementing the embodiments of the present application.
  • a computer device 600 includes a central processing unit (CPU) 601 that can be loaded into a random access memory (RAM) 603 according to a program stored in a read only memory (ROM) 602 or from a storage section 608 program to perform various appropriate tasks and processes.
  • RAM random access memory
  • ROM read only memory
  • various programs and data necessary for the operation of the system 600 are also stored.
  • the CPU 601 , the ROM 602 , and the RAM 603 are connected to each other through a bus 604 .
  • An input/output (I/O) interface 605 is also connected to bus 604 .
  • the following components are connected to the I/O interface 605: an input section 606 including a keyboard, a mouse, etc.; an output section 607 including a cathode ray tube (CRT), a liquid crystal feedback device (LCD), etc., and a speaker, etc.; a storage section including a hard disk, etc. 608; and a communication section 609 including network interface cards such as LAN cards, modems, and the like.
  • the communication section 609 performs communication processing via a network such as the Internet.
  • a drive 610 is also connected to the I/O interface 605 as needed.
  • a removable medium 611 such as a magnetic disk, an optical disk, a magneto-optical disk, a semiconductor memory, etc., is mounted on the drive 610 as needed so that a computer program read therefrom is installed as the storage section 608 as needed.
  • each layer of the magnetic random access memory is only to illustrate the relative positional relationship of each layer. According to the device application and preparation process of the magnetic random access memory, each layer can be from top to bottom in actual space.
  • the bottom-up sequence setting that is, the top-bottom sequence of each layer of the magnetic random access memory can be reversed, so as to optimize the film quality or device performance. Therefore, different from the first embodiment, in this embodiment, the upper and lower positions of each layer of the magnetic random access memory are opposite to those of the first embodiment. As shown in FIG.
  • the magnetic random access memory consists of bottom electrode 270 , ferroelectric layer 210 , metal layer 240 , dielectric layer 220 , free ferromagnetic layer 231 , tunneling layer 232 , reference The ferromagnetic layer 233 and the first electrode.
  • the magnetic random access memory also includes a second electrode 260 in electrical contact with the free ferromagnetic layer 231 . Since the first electrode is located at the bottom layer of the magnetic random access memory in this embodiment, the first electrode may include a first electrode layer 251 and a first external electrode 252 located on the first electrode layer 251 .
  • the other technical features of this embodiment are similar to those in the first embodiment, and are not repeated here.
  • the dielectric layer can be replaced by the tunneling layer, that is, at this time, the magnetic tunnel junction includes a set of A free ferromagnetic layer between the ferroelectric layer and the dielectric layer and a reference ferromagnetic layer disposed at least partially on the dielectric layer.
  • a part of the magnetic tunnel junction is between the ferroelectric layer and the dielectric layer, and the other part of the magnetic tunnel junction is arranged on the dielectric layer to realize non-volatile storage of data. For example, as shown in FIG.
  • the magnetic random access memory includes a first electrode 350 , a reference ferromagnetic layer 333 , a dielectric layer 320 , a free ferromagnetic layer 331 , a ferroelectric layer 310 and a bottom electrode layer 371 in order from top to bottom.
  • the magnetic random access memory further includes a third electrode 372 in electrical contact with the bottom electrode layer 371 and a second electrode 360 in electrical contact with the free ferromagnetic layer 331 .
  • a forward bias voltage needs to be applied between the first electrode and the third electrode to reduce the free ferromagnetic layer Therefore, the write current and the thermal stability of the magnetic random access memory are reduced, so that the data write operation in the magnetic tunnel junction can be completed by inputting a small write current between the first electrode and the second electrode.
  • Other technical features of this embodiment are similar to those in the first embodiment, and are not repeated here.

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Abstract

A magnetic random access memory and device, and a read-write control method. The magnetic random access memory comprises: a ferroelectric layer (110); a dielectric layer (120) provided above the ferroelectric layer (110); and a magnetic tunnel junction, wherein at least one part of the magnetic tunnel junction is provided on the dielectric layer (120). The present invention can significantly improve the interface effect of the dielectric layer (120) and the magnetic tunnel junction, thereby greatly improving a VCMA effect provided for the magnetic tunnel junction, and further optimizing the performance of the magnetic random access memory, such as power consumption, a writing speed, and thermal stability.

Description

磁性随机存储器、装置及读写控制方法Magnetic random access memory, device and read/write control method 技术领域technical field
本发明涉及磁性存储器技术领域,尤其涉及一种磁性随机存储器、装置及读写控制方法。The present invention relates to the technical field of magnetic memory, and in particular, to a magnetic random access memory, a device and a read-write control method.
背景技术Background technique
随着半导体工艺尺寸的不断缩小,摩尔定律放缓,漏电流的增加和互联延迟成为传统CMOS存储器的瓶颈。寻找新一代存储技术的解决方案成为集成电路研究的重点,其中磁性随机存储单元器受到广泛关注。相对比传统器件,磁性随机存储器(Magnetic random access memory,MRAM)具有无限擦写次数、非易失性、读写速度快和抗辐照等优点,有望成为通用存储器,是构建下一代非易失存储器以及存内计算的理想器件。As the size of the semiconductor process continues to shrink, Moore's Law slows down, the increase in leakage current and the interconnection delay become the bottleneck of traditional CMOS memory. Finding solutions for next-generation memory technology has become the focus of integrated circuit research, among which magnetic random access memory cells have received extensive attention. Compared with traditional devices, Magnetic random access memory (MRAM) has the advantages of unlimited erasing and rewriting times, non-volatility, fast read and write speed, and radiation resistance. Ideal for memory and in-memory computing.
电场(电压)调控磁各向异性(VCMA)是自旋电子学当前的一个热门领域,在磁性随机存储器方面有巨大的应用潜力。基于VCMA效应的MRAM在通常的电流引发自由层磁化翻转的过程中,通过对磁存储器件进行结构调整,并在翻转过程中施加偏置电压,可以显著降低磁化翻转所需的电流密度,使器件尺寸得以进一步降低,同时大幅降低写入功耗。但是,随着对磁性随机存储器尺寸的降低,VCMA效应系数不能满足MRAM的需求。Electric field (voltage) regulated magnetic anisotropy (VCMA) is a hot field in spintronics and has great potential in magnetic random access memory. MRAM based on VCMA effect can significantly reduce the current density required for magnetization inversion by adjusting the structure of the magnetic memory device and applying a bias voltage during the inversion process in the process of magnetization inversion of the free layer induced by the usual current. The size can be further reduced, while the write power consumption is greatly reduced. However, as the size of magnetic random access memory is reduced, the VCMA effect coefficient cannot meet the requirements of MRAM.
发明内容SUMMARY OF THE INVENTION
本发明的一个目的在于提供一种磁性随机存储器,可显著提高介电层和磁隧道结的界面效应,从而大幅度提高为磁隧道结提供的VCMA效应,进而优化磁性随机存储器的功耗、写入速度和热稳定性等性能。本发明的另一个目的在于提供一种磁性随机存储装置。本发明的还一个目的在于提供一种磁性随机存储器的控制方法。One object of the present invention is to provide a magnetic random access memory, which can significantly improve the interface effect between the dielectric layer and the magnetic tunnel junction, thereby greatly improving the VCMA effect provided for the magnetic tunnel junction, thereby optimizing the power consumption, writing, and power consumption of the magnetic random access memory. performance such as entry speed and thermal stability. Another object of the present invention is to provide a magnetic random access memory device. Another object of the present invention is to provide a control method of a magnetic random access memory.
为了达到以上目的,本发明一方面公开了一种磁性随机存储器,包括:In order to achieve the above purpose, one aspect of the present invention discloses a magnetic random access memory, comprising:
铁电层;ferroelectric layer;
介电层,设于所述铁电层上;以及a dielectric layer disposed on the ferroelectric layer; and
磁隧道结,至少部分设于所述介电层上。A magnetic tunnel junction is at least partially disposed on the dielectric layer.
优选的,所述磁隧道结包括自由铁磁层、设于所述自由铁磁层上的隧穿层以及设于所述隧穿层上的参考铁磁层,所述自由铁磁层至少部分设于所述介电层上;或者,Preferably, the magnetic tunnel junction includes a free ferromagnetic layer, a tunneling layer provided on the free ferromagnetic layer, and a reference ferromagnetic layer provided on the tunneling layer, the free ferromagnetic layer at least partially on the dielectric layer; or,
所述磁隧道结包括设于所述铁电层和所述介电层间的自由铁磁层以及至少部分设于所述介电层上的参考铁磁层。The magnetic tunnel junction includes a free ferromagnetic layer disposed between the ferroelectric layer and the dielectric layer, and a reference ferromagnetic layer disposed at least partially on the dielectric layer.
优选的,进一步包括与所述参考铁磁层电连接的第一电极和与所述自由铁磁层电连接的第二电极。Preferably, it further comprises a first electrode electrically connected to the reference ferromagnetic layer and a second electrode electrically connected to the free ferromagnetic layer.
优选的,进一步包括与所述铁电层电连接的底电极。Preferably, it further includes a bottom electrode electrically connected to the ferroelectric layer.
优选的,所述底电极包括底电极层和所述底电极层电连接的第三电极,所述铁电层设于所述底电极层上。Preferably, the bottom electrode includes a bottom electrode layer and a third electrode electrically connected to the bottom electrode layer, and the ferroelectric layer is disposed on the bottom electrode layer.
优选的,进一步包括设于所述铁电层和所述介电层间的金属层。Preferably, it further includes a metal layer disposed between the ferroelectric layer and the dielectric layer.
优选的,所述隧穿层的底面积小于所述自由铁磁层的顶面积,所述第二电极设于所述自由铁磁层上。Preferably, the bottom area of the tunneling layer is smaller than the top area of the free ferromagnetic layer, and the second electrode is disposed on the free ferromagnetic layer.
优选的,所述铁电层的底面积小于所述底电极层的顶面积,所述第三电极设于所述底电极层上。Preferably, the bottom area of the ferroelectric layer is smaller than the top area of the bottom electrode layer, and the third electrode is disposed on the bottom electrode layer.
本发明还公开了一种磁性随机存储装置,包括如上所述的磁性随机存储器以及与所述磁性随机存储器电连接的控制电路;The present invention also discloses a magnetic random access memory device, comprising the above magnetic random access memory and a control circuit electrically connected with the magnetic random access memory;
所述控制电路用于在所述磁隧道结上施加读取电压或写入电流,在所述铁电层和介电层形成的负电容结构上施加正向偏置电压或负向偏置电压以降低或提高磁隧道结的磁各向异性。The control circuit is used for applying a read voltage or a write current on the magnetic tunnel junction, and applying a forward bias voltage or a negative bias voltage on the negative capacitance structure formed by the ferroelectric layer and the dielectric layer To reduce or improve the magnetic anisotropy of the magnetic tunnel junction.
本发明还公开了一种磁性随机存储装置的读写控制方法,包括:The invention also discloses a read-write control method of the magnetic random storage device, comprising:
在写入阶段:During the write phase:
通过控制电路向铁电层和介电层形成的负电容结构的两端上施加正向偏置电压以降低磁隧道结的磁各向异性;A forward bias voltage is applied to both ends of the negative capacitance structure formed by the ferroelectric layer and the dielectric layer through a control circuit to reduce the magnetic anisotropy of the magnetic tunnel junction;
通过控制电路在所述磁隧道结的两端施加与待写入的数据对应的写入电流完成数据写入;Data writing is completed by applying a writing current corresponding to the data to be written at both ends of the magnetic tunnel junction by the control circuit;
在读取阶段:During the read phase:
通过控制电路在所述磁隧道结的两端施加读取电压,根据所述读取电压的变化确定磁隧道结存储的数据。A read voltage is applied across the magnetic tunnel junction by a control circuit, and data stored in the magnetic tunnel junction is determined according to the change of the read voltage.
优选的,进一步包括:Preferably, it further includes:
在写入阶段:During the write phase:
在通过控制电路在所述磁隧道结的两端施加与待写入的数据对应的写入电流的同时,向铁电层和介电层形成的负电容结构的两端上施加正向偏置电压;A forward bias is applied to both ends of the negative capacitance structure formed by the ferroelectric layer and the dielectric layer while the write current corresponding to the data to be written is applied to both ends of the magnetic tunnel junction through the control circuit Voltage;
在读取阶段:During the read phase:
在通过控制电路在所述磁隧道结的两端施加读取电压的同时,向铁电层和介电层形成的负电容结构的两端上施加负向偏置电压。A negative bias voltage is applied to both ends of the negative capacitance structure formed by the ferroelectric layer and the dielectric layer while the read voltage is applied across the magnetic tunnel junction through the control circuit.
本发明通过设置介电层和铁电层形成负电容结构,可使介电层得到电压增益效应,将磁隧道结设置在介电层和铁电层上,可显著提高介电层和磁隧道结的界面效应,从而大幅度提高为磁隧道结提供的VCMA效应,进而优化磁性随机存储器的功耗、写入速度和热稳定性等性能。In the present invention, a negative capacitance structure is formed by arranging a dielectric layer and a ferroelectric layer, so that the dielectric layer can obtain a voltage gain effect. The interface effect of the junction is greatly improved, thereby greatly improving the VCMA effect provided for the magnetic tunnel junction, thereby optimizing the power consumption, writing speed and thermal stability of the magnetic random access memory.
附图说明Description of drawings
为了更清楚地说明本发明实施例或现有技术中的技术方案,下面将对实施例或现有技术描述中所需要使用的附图作简单地介绍,显而易见地,下面描述中的附图仅仅是本发明的一些实施例,对于本领域普通技术人员来讲,在不付出创造性劳动的前提下,还可以根据这些附图获得其他的附图。In order to explain the embodiments of the present invention or the technical solutions in the prior art more clearly, the following briefly introduces the accompanying drawings that need to be used in the description of the embodiments or the prior art. Obviously, the accompanying drawings in the following description are only These are some embodiments of the present invention. For those of ordinary skill in the art, other drawings can also be obtained according to these drawings without creative efforts.
图1示出本发明实施例一磁性随机存储器的结构图;FIG. 1 shows a structural diagram of a magnetic random access memory according to an embodiment of the present invention;
图2示出本发明实施例一中磁性随机存储器与外部控制电路连接的结构图;Fig. 2 shows the structure diagram of the connection between the magnetic random access memory and the external control circuit in the first embodiment of the present invention;
图3示出本发明实施例一中第一电极和第二电极的电压时序图;Fig. 3 shows the voltage timing diagram of the first electrode and the second electrode in the first embodiment of the present invention;
图4示出本发明实施例一磁性随机存储器的控制方法的流程图;4 shows a flowchart of a method for controlling a magnetic random access memory according to an embodiment of the present invention;
图5示出应用本发明实施例一磁性随机存储器的计算机设备的结构示意图。FIG. 5 is a schematic structural diagram of a computer device applying a magnetic random access memory according to an embodiment of the present invention.
图6示出本发明实施例二磁性随机存储器的结构图;FIG. 6 shows a structural diagram of a magnetic random access memory according to Embodiment 2 of the present invention;
图7示出本发明实施例三磁性随机存储器的结构图。FIG. 7 shows a structural diagram of a magnetic random access memory according to Embodiment 3 of the present invention.
具体实施方式detailed description
下面将结合本发明实施方式中的附图,对本发明实施方式中的技术方案进行清楚、完整地描述,显然,所描述的实施方式仅仅是本发明一部分实施方式,而不是全部的实施方式。基于本发明中的实施方式,本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施方式,都属于本发明保护的范围。The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the accompanying drawings in the embodiments of the present invention. Obviously, the described embodiments are only a part of the embodiments of the present invention, but not all of the embodiments. Based on the embodiments of the present invention, all other embodiments obtained by persons of ordinary skill in the art without creative efforts shall fall within the protection scope of the present invention.
以下公开内容提供了许多用于实现本发明的不同特征的不同实施例或实例。下面描述了组件和布置的具体实例以简化本发明。当然,这些仅仅是实例,而不旨在限制本发明。例如,以下描述中,在第二部件上方或者上形成第一部件可以包括第一部件和第二部件直接接触形成的实施例,并且也可以包括在第一部件和第二部件之间可以形成额外 的部件,从而使得第一部件和第二部件可以不直接接触的实施例。此外,本发明可在各个实施例中重复参考标号和/或字符。该重复是为了简单和清楚的目的,并且其本身不指示所讨论的各个实施例和/或配置之间的关系。The following disclosure provides many different embodiments or examples for implementing different features of the invention. Specific examples of components and arrangements are described below to simplify the present disclosure. Of course, these are only examples and are not intended to limit the invention. For example, in the following description, forming the first part over or on the second part may include embodiments in which the first part and the second part are formed in direct contact, and may also include additionally forming between the first part and the second part. parts so that the first part and the second part may not be in direct contact. Furthermore, the present invention may repeat reference numerals and/or characters in various embodiments. This repetition is for the purpose of simplicity and clarity, and does not in itself indicate a relationship between the various embodiments and/or configurations discussed.
而且,为便于描述,在此可以使用诸如“在…之下”、“在…下方”、“下部”、“在…之上”、“上部”等空间相对术语,以描述如图所示的一个元件或部件与另一个(或另一些)原件或部件的关系。除了图中所示的方位外,空间相对术语旨在包括器件在使用或操作中的不同方位。装置可以以其它方式定向(旋转90度或在其它方位上),而本文使用的空间相对描述符可以同样地做出相应的解释。Also, for ease of description, spatially relative terms such as "below", "below", "lower", "above", "upper" and the like may be used herein to describe the The relationship of one element or part to another (or other) elements or parts. In addition to the orientation shown in the figures, spatially relative terms are intended to encompass different orientations of the device in use or operation. The device may be otherwise oriented (rotated 90 degrees or at other orientations) and the spatially relative descriptors used herein interpreted accordingly.
现有基于磁隧道结(Magnetic Tunnel Junction,MTJ)的磁性随机访问存储器(Magnetic Random Access Memory,MRAM)包括自旋轨道矩层以及设于所述自旋轨道矩层上的至少一个磁隧道结。其中,磁隧道结包括自上向下设置的参考(铁磁)层133、势垒层(隧穿层132)和自由(铁磁)层131,自由层的底面与自旋轨道矩层的上表面接触固定。An existing Magnetic Tunnel Junction (MTJ)-based Magnetic Random Access Memory (MRAM) includes a spin-orbit moment layer and at least one magnetic tunnel junction disposed on the spin-orbit moment layer. The magnetic tunnel junction includes a reference (ferromagnetic) layer 133, a potential barrier layer (tunneling layer 132) and a free (ferromagnetic) layer 131 arranged from top to bottom, the bottom surface of the free layer and the upper surface of the spin-orbit moment layer Surface contact fixation.
磁隧道结的电阻值取决于自由层和参考层的磁化方向,如果自由层与参考层的磁化方向一致,则磁隧道结的电阻值较小,磁隧道结处于低阻态。反之,如果自由层与参考层的磁化方向相反,则磁隧道结的电阻值较大,磁隧道结处于高阻态。其中,参考层的磁化方向预先设置为固定不变的磁化方向,例如可采用合成反铁磁层使参考层的磁化方向固定不变,自由层的磁化方向可通过写入操作而被改变。在后期数据读取时,通过读取电路确定磁隧道结的阻态即可确定存储器中存储的数据。The resistance value of the magnetic tunnel junction depends on the magnetization directions of the free layer and the reference layer. If the magnetization directions of the free layer and the reference layer are consistent, the resistance value of the magnetic tunnel junction is small and the magnetic tunnel junction is in a low resistance state. On the contrary, if the magnetization directions of the free layer and the reference layer are opposite, the resistance value of the magnetic tunnel junction is larger, and the magnetic tunnel junction is in a high resistance state. The magnetization direction of the reference layer is preset as a fixed and constant magnetization direction. For example, a synthetic antiferromagnetic layer can be used to make the magnetization direction of the reference layer fixed, and the magnetization direction of the free layer can be changed by writing operations. In the later data reading, the data stored in the memory can be determined by determining the resistance state of the magnetic tunnel junction through the reading circuit.
电压调控磁各向异性(Voltage Control Magnetic Anisotropy,VCMA)的作用机理为在MTJ两端施加的电场导致电子电荷的累积,引起界面原子轨道和态密度的变化,从而导致界面磁各向异性的变化。基于VCMA效应的STT-MRAM是通过自旋电流实现信息写入的一种新型非易失性磁随机存储器。电流流过磁性层时,电流将被极化,形成自旋极化电流。自旋电子将自旋动量传递给自由层的磁矩,使自旋磁性层的磁矩获得自旋动量后改变方向,这个过程称为自旋传输矩。通过向自由层输入电流使自由层的磁矩发生翻转,从而改变磁隧道结的阻态,实现数据的写入。VCMA技术在通常的电流引发自由层磁化翻转的过程中,通过对磁存储器件进行结构调整,并在翻转过程中施加偏置电压,可以显著降低磁化翻转所需的电流密度,使器件尺寸得以进一步降低,同时大幅降低写入功耗。The mechanism of Voltage Control Magnetic Anisotropy (VCMA) is that the electric field applied at both ends of the MTJ leads to the accumulation of electron charges, which causes the change of the interface atomic orbital and density of states, which leads to the change of the interface magnetic anisotropy. . STT-MRAM based on VCMA effect is a new type of non-volatile magnetic random access memory that realizes information writing through spin current. When current flows through the magnetic layer, the current will be polarized, forming a spin-polarized current. Spin electrons transfer spin momentum to the magnetic moment of the free layer, so that the magnetic moment of the spin magnetic layer changes direction after gaining spin momentum. This process is called spin transfer torque. By inputting a current into the free layer, the magnetic moment of the free layer is reversed, thereby changing the resistance state of the magnetic tunnel junction and realizing data writing. VCMA technology can significantly reduce the current density required for magnetization inversion by adjusting the structure of the magnetic memory device and applying a bias voltage during the inversion process in the usual current-induced magnetization inversion of the free layer, enabling the device size to be further improved. reduction, while substantially reducing write power consumption.
但是,随着对磁性随机存储器尺寸的降低,VCMA效应系数不能满足MRAM的需求。VCMA技术给MRAM带来的优势与VCMA效应系数(即单位电场带来的磁各向异 性变化,单位fJ/V-m,典型值为100fJ/V-m)直接相关,较高的VCMA效应系数可在同样的偏置电压下,可产生更强的磁各向异性调制效应,从而优化MRAM的写入功耗、写入速度、写入错误率和热稳定性(这几个指标互为权衡关系)。但是,在器件尺寸降低的趋势下,目前的VCMA效应系数不能满足MRAM的需求。以STT-MRAM为例,其写入电流密度通常为10 6~10 8A/cm 2,这导致其在器件尺寸小于40nm时写入电流急剧上升,进一步缩小器件尺寸极为困难。因此,本发明通过设置铁电层和介电层形成负电容结构,提高铁电层和介电层的界面电荷积累量,进而提高VCMA效应强度。从而,当形成与现有的STT-MRAM相同的VCMA效应强度时,本发明所需的写入电流密度更低,器件尺寸可以减小,满足了磁性随机存储器不断小型化的需求。进一步,优选的,在磁性随机存储器中设置与参考铁磁层电连接的第一电极、与自由铁磁层电连接的第二电极以及与铁电层电连接的底电极,形成具有三个外接电极的磁性随机存储器。通过第二电极和底电极对负电容结构加压,通过第一电极和第二电极进行数据写入和读取。数据写入和读取电流不经过铁电层,避免了具有介电性的铁电层对数据读写过程的影响,进一步降低写入电流密度的要求,利于器件尺寸的进一步缩小。 However, as the size of magnetic random access memory is reduced, the VCMA effect coefficient cannot meet the requirements of MRAM. The advantages brought by VCMA technology to MRAM are directly related to the VCMA effect coefficient (that is, the magnetic anisotropy change brought by unit electric field, unit fJ/Vm, the typical value is 100fJ/Vm). Under the bias voltage, a stronger magnetic anisotropy modulation effect can be produced, thereby optimizing the write power consumption, write speed, write error rate and thermal stability of the MRAM (these indicators are in a trade-off relationship with each other). However, under the trend of decreasing device size, the current VCMA effect coefficient cannot meet the requirements of MRAM. Taking STT-MRAM as an example, its write current density is usually 10 6 -10 8 A/cm 2 , which leads to a sharp increase in the write current when the device size is smaller than 40 nm, and it is extremely difficult to further reduce the device size. Therefore, in the present invention, a negative capacitance structure is formed by arranging a ferroelectric layer and a dielectric layer, so as to increase the amount of charge accumulation at the interface of the ferroelectric layer and the dielectric layer, thereby increasing the strength of the VCMA effect. Therefore, when the same VCMA effect strength as the existing STT-MRAM is formed, the writing current density required by the present invention is lower, the device size can be reduced, and the demand for the continuous miniaturization of the magnetic random access memory is satisfied. Further, preferably, a first electrode electrically connected to the reference ferromagnetic layer, a second electrode electrically connected to the free ferromagnetic layer, and a bottom electrode electrically connected to the ferroelectric layer are arranged in the magnetic random access memory, forming a structure with three external Magnetic random access memory for electrodes. The negative capacitance structure is pressurized through the second electrode and the bottom electrode, and data writing and reading are performed through the first electrode and the second electrode. The data writing and reading currents do not pass through the ferroelectric layer, which avoids the influence of the dielectric ferroelectric layer on the data reading and writing process, further reduces the requirements for the writing current density, and is conducive to further shrinking the size of the device.
实施例一Example 1
根据本发明的一个方面,本实施例公开了一种磁性随机存储器。如图1所示,本实施例中,所述磁性随机存储器包括铁电层110、设于所述铁电层110上的介电层120以及至少部分设于所述介电层120上的磁隧道结。According to an aspect of the present invention, the present embodiment discloses a magnetic random access memory. As shown in FIG. 1 , in this embodiment, the magnetic random access memory includes a ferroelectric layer 110 , a dielectric layer 120 disposed on the ferroelectric layer 110 , and a magnetic layer at least partially disposed on the dielectric layer 120 . tunnel junction.
本发明通过设置介电层120和铁电层110形成负电容结构,可使介电层120得到电压增益效应,将磁隧道结设置在介电层120和铁电层110上,可显著提高介电层120和磁隧道结的界面效应,从而大幅度提高为磁隧道结提供的VCMA效应,进而优化磁性随机存储器的功耗、写入速度和热稳定性等性能。In the present invention, by setting the dielectric layer 120 and the ferroelectric layer 110 to form a negative capacitance structure, the dielectric layer 120 can obtain a voltage gain effect, and the magnetic tunnel junction is arranged on the dielectric layer 120 and the ferroelectric layer 110, which can significantly improve the dielectric The interface effect between the electrical layer 120 and the magnetic tunnel junction can greatly improve the VCMA effect provided for the magnetic tunnel junction, thereby optimizing the power consumption, writing speed and thermal stability of the magnetic random access memory.
具体的,对于形成铁电层110的铁电材料来说,其存在通常情况下不能稳定的负电容区域。根据本领域公知的正反馈模型:Specifically, for the ferroelectric material forming the ferroelectric layer 110 , there is a negative capacitance region that cannot be stabilized under normal circumstances. According to the positive feedback model known in the art:
Q=C 0(V+a fQ) Q=C 0 (V+a f Q)
其中,Q为电荷积累,V为外加电压。Among them, Q is the charge accumulation, and V is the applied voltage.
将铁电材料作为通常电容则有:Using ferroelectric materials as ordinary capacitors has:
Q=C feV=C 0(V+a fQ) Q=C fe V=C 0 (V+a f Q)
则有:Then there are:
Figure PCTCN2020106252-appb-000001
Figure PCTCN2020106252-appb-000001
可见,当C fe<0时,由于正反馈模型无法稳定,铁电材料将持续充电直到被正反馈模型中被忽略的非线性项所限制。但是如果在铁电材料上串联一个普通电容,使得两者的总电容为正,则整个体系得以稳定,同时铁电材料和串联的普通电容的总电容值大于两者各自的电容,即: It can be seen that when C fe < 0, since the positive feedback model cannot be stabilized, the ferroelectric material will continue to charge until it is limited by the neglected nonlinear term in the positive feedback model. However, if an ordinary capacitor is connected in series with the ferroelectric material, so that the total capacitance of the two is positive, the whole system can be stabilized, and the total capacitance value of the ferroelectric material and the ordinary capacitor connected in series is greater than their respective capacitances, namely:
C tot -1=C fe -1+C cap -1 C tot -1 =C fe -1 +C cap -1
由此,铁电层110和介电层120上下设置并电接触,等同于将铁电层110与介电层120串联形成负电容结构,可实现提高等效电容的作用。同时提高铁电层110和介电层120的界面电荷积累量,进而提高VCMA效应强度。Therefore, the ferroelectric layer 110 and the dielectric layer 120 are disposed up and down and are in electrical contact, which is equivalent to connecting the ferroelectric layer 110 and the dielectric layer 120 in series to form a negative capacitance structure, which can improve the equivalent capacitance. At the same time, the amount of charge accumulation at the interface between the ferroelectric layer 110 and the dielectric layer 120 is increased, thereby increasing the strength of the VCMA effect.
在可选的实施方式中,所述磁隧道结包括自由铁磁层131、设于所述自由铁磁层131上的隧穿层132以及设于所述隧穿层132上的参考铁磁层133,所述自由铁磁层131至少部分设于所述介电层120上。可以理解的是,磁隧道结的自由铁磁层131设置在介电层120上,在铁电层110和介电层120的负电容结构的作用下,在外加电压情况下产生更强的VCMA效应,提高或降低磁隧道结的磁各向异性,便于数据的写入。优选的,自由铁磁层131可包括两个铁磁层及两个铁磁层间的金属耦合层。两个铁磁层及两个铁磁层间的金属耦合层形成合成的自由铁磁层131,可提高存储器的热稳定性,降低存储器加工难度。In an optional embodiment, the magnetic tunnel junction includes a free ferromagnetic layer 131 , a tunneling layer 132 disposed on the free ferromagnetic layer 131 and a reference ferromagnetic layer disposed on the tunneling layer 132 133 , the free ferromagnetic layer 131 is at least partially disposed on the dielectric layer 120 . It can be understood that the free ferromagnetic layer 131 of the magnetic tunnel junction is disposed on the dielectric layer 120, and under the action of the negative capacitance structure of the ferroelectric layer 110 and the dielectric layer 120, a stronger VCMA is generated under the condition of an applied voltage effect, increase or decrease the magnetic anisotropy of the magnetic tunnel junction, and facilitate the writing of data. Preferably, the free ferromagnetic layer 131 may include two ferromagnetic layers and a metal coupling layer between the two ferromagnetic layers. The two ferromagnetic layers and the metal coupling layer between the two ferromagnetic layers form a synthetic free ferromagnetic layer 131, which can improve the thermal stability of the memory and reduce the difficulty of processing the memory.
在其他可选的实施方式中,隧道层和自由铁磁层131组成的结构可设置多个,即磁隧道结包括多个组合的层结构和形成在多个组合的层结构上的参考铁磁层133,其中每个组合的层结构包括自由铁磁层131和设于所述自由铁磁层131上的隧穿层132。In other optional embodiments, the structure composed of the tunnel layer and the free ferromagnetic layer 131 may be provided in multiple numbers, that is, the magnetic tunnel junction includes multiple combined layer structures and reference ferromagnetic structures formed on the multiple combined layer structures layer 133 , wherein each combined layer structure includes a free ferromagnetic layer 131 and a tunneling layer 132 provided on the free ferromagnetic layer 131 .
在优选的实施方式中,磁性随机存储器进一步包括与所述参考铁磁层133电连接的第一电极150和与所述自由铁磁层131电连接的第二电极160。可以理解的是,通过将第一电极150和第二电极160接入外部的控制电路中,如图2所示。外部的控制电路可通过第一电极150和第二电极160向磁性随机存储器中输入写入电流和读取电压,实现数据的写入和读取。In a preferred embodiment, the magnetic random access memory further includes a first electrode 150 electrically connected to the reference ferromagnetic layer 133 and a second electrode 160 electrically connected to the free ferromagnetic layer 131 . It can be understood that, by connecting the first electrode 150 and the second electrode 160 to an external control circuit, as shown in FIG. 2 . The external control circuit can input the write current and the read voltage into the magnetic random access memory through the first electrode 150 and the second electrode 160 to realize the writing and reading of data.
在优选的实施方式中,磁性随机存储器进一步包括与所述铁电层110电连接的底电极。可以理解的是,第二电极160与自由铁磁层131电连接,通过将底电极和第二电极160接入外部的控制电路中,通过外部的控制电路向底电极和第二电极160通过不同方向的电压,从而使铁电层110和介电层120形成的负电容结构提高或降低磁隧道结的磁 各向异性,实现数据的写入。优选的,可使所述隧穿层132的底面积小于所述自由铁磁层131的顶面积,将所述第二电极160设于所述自由铁磁层131上,从而降低磁性随机存储器的尺寸,便于工艺成型。In a preferred embodiment, the magnetic random access memory further includes a bottom electrode electrically connected to the ferroelectric layer 110 . It can be understood that the second electrode 160 is electrically connected to the free ferromagnetic layer 131. By connecting the bottom electrode and the second electrode 160 to an external control circuit, the bottom electrode and the second electrode 160 pass through different paths through the external control circuit. Therefore, the negative capacitance structure formed by the ferroelectric layer 110 and the dielectric layer 120 increases or decreases the magnetic anisotropy of the magnetic tunnel junction, thereby realizing data writing. Preferably, the bottom area of the tunneling layer 132 can be made smaller than the top area of the free ferromagnetic layer 131, and the second electrode 160 is disposed on the free ferromagnetic layer 131, thereby reducing the magnetic random access memory (RAM) capacity. size, easy to process molding.
更优选的,所述底电极可包括底电极层171和所述底电极层171电连接的第三电极172,所述铁电层110设于所述底电极层171上。可以理解的是,通过将底电极设置为底电极层171和第三电极172的形式,可对铁电层110及其上层结构形成支撑,并且使底电极层171与铁电层110形成面接触,而第三电极172可与外部控制电路电连接,连接方式简单。优选的,可使所述铁电层110的底面积小于所述底电极层171的顶面积,将所述第三电极172设于所述底电极层171上,从而进一步降低磁性随机存储器的尺寸,便于工艺成型。More preferably, the bottom electrode may include a bottom electrode layer 171 and a third electrode 172 electrically connected to the bottom electrode layer 171 , and the ferroelectric layer 110 is disposed on the bottom electrode layer 171 . It can be understood that, by providing the bottom electrode in the form of the bottom electrode layer 171 and the third electrode 172, the ferroelectric layer 110 and its upper structure can be supported, and the bottom electrode layer 171 and the ferroelectric layer 110 can be in surface contact , and the third electrode 172 can be electrically connected with the external control circuit, and the connection method is simple. Preferably, the bottom area of the ferroelectric layer 110 can be made smaller than the top area of the bottom electrode layer 171, and the third electrode 172 is disposed on the bottom electrode layer 171, thereby further reducing the size of the magnetic random access memory. , which is convenient for process forming.
在该优选的实施方式中,由于铁电层110的铁电材料具有介电性,铁电层110会对数据的写入电流产生影响。为了避免磁隧道结的磁各向异性的改变与数据的读写存在冲突,设置与铁电层110电连接的底电极以及与自由铁磁层131电连接的第二电极160。在实际使用时,如图3所示,可通过在第二电极160和第三电极172间施加正向偏置电压,降低自由铁磁层131的磁各向异性,从而降低写入电流及磁随机存储器的热稳定性,使在第一电极150和第二电极160间输入很小的写入电流即可完成磁隧道结中的数据写入操作。In this preferred embodiment, since the ferroelectric material of the ferroelectric layer 110 has dielectric properties, the ferroelectric layer 110 will affect the writing current of data. In order to avoid conflict between the change of magnetic anisotropy of the magnetic tunnel junction and the reading and writing of data, a bottom electrode electrically connected to the ferroelectric layer 110 and a second electrode 160 electrically connected to the free ferromagnetic layer 131 are provided. In actual use, as shown in FIG. 3 , a forward bias voltage can be applied between the second electrode 160 and the third electrode 172 to reduce the magnetic anisotropy of the free ferromagnetic layer 131 , thereby reducing the writing current and magnetic field. The thermal stability of the random access memory makes it possible to complete the data writing operation in the magnetic tunnel junction by inputting a small writing current between the first electrode 150 and the second electrode 160 .
在数据写入完成后,由于铁电层110剩余极化的存在,其VCMA效应在外加电压结束后依然部分存在,即VCMA效应存在非易失性。在STT-MRAM中,可在写入数据时施加外加电压以降低自由铁磁层131的垂直磁各向异性,在数据写入完成后可施加负向偏置电压,提高自由铁磁层131的垂直磁各种异性,即提高磁隧道结的热稳定性,防止磁隧道结受到环境影响。After the data writing is completed, due to the existence of the remanent polarization of the ferroelectric layer 110, the VCMA effect of the ferroelectric layer 110 still partially exists after the end of the applied voltage, that is, the VCMA effect is non-volatile. In STT-MRAM, an external voltage can be applied during data writing to reduce the perpendicular magnetic anisotropy of the free ferromagnetic layer 131 , and a negative bias voltage can be applied after data writing is completed to improve the free ferromagnetic layer 131 . Various anisotropy of perpendicular magnetism, that is, improving the thermal stability of the magnetic tunnel junction and preventing the magnetic tunnel junction from being affected by the environment.
在优选的实施方式中,磁性随机存储器进一步包括设于所述铁电层110和所述介电层120间的金属层140。可以理解的是,对部分铁电材料(如氧铪锆)而言,优选的可在其与介电层120之间设置阻隔层,并且对部分介电层120或铁电层110而言,可设置金属层140作为具有特定晶格结构的种子层以提高其成膜质量。In a preferred embodiment, the magnetic random access memory further includes a metal layer 140 disposed between the ferroelectric layer 110 and the dielectric layer 120 . It can be understood that, for some ferroelectric materials (such as hafnium zirconium oxide), it is preferable to set a barrier layer between the dielectric layer 120 and the dielectric layer 120 , and for some of the dielectric layers 120 or the ferroelectric layer 110 , The metal layer 140 may be provided as a seed layer with a specific lattice structure to improve its film formation quality.
需要说明的是,磁隧道结可选用圆柱、立方体或圆台等常见形状,以降低成本并有利于尺寸持续小型化,同时适用于双界面结构和多界面结构等多种存储器结构。在其他实施方式中,也可选用其他形状,本发明对此并不作限定。It should be noted that common shapes such as cylinder, cube or truncated cone can be used for the magnetic tunnel junction to reduce cost and facilitate the continuous miniaturization of size. In other embodiments, other shapes may also be selected, which are not limited in the present invention.
需要说明的是,本实施例的第一电极150、第二电极160和第三电极172的设置方式仅为示例,在其他实施方式中,第一电极150、第二电极160和第三电极172也可以采用其他设置方式,可直接或间接与参考铁磁层133、自由铁磁层131和底电极层171电连接且不短路其他层结构即可,本发明对第一电极150、第二电极160和第三电极172的形状、大小和设置方式均不作限定。It should be noted that the arrangement of the first electrode 150 , the second electrode 160 and the third electrode 172 in this embodiment is only an example. In other embodiments, the first electrode 150 , the second electrode 160 and the third electrode 172 Other setting methods can also be used, which can be directly or indirectly electrically connected to the reference ferromagnetic layer 133, the free ferromagnetic layer 131 and the bottom electrode layer 171 without short-circuiting other layer structures. The shape, size and arrangement of the third electrode 160 and the third electrode 172 are not limited.
优选的,所述自由铁磁层131和参考铁磁层133的材料可为铁磁金属,所述隧穿层132的材料可为氧化物。其中,铁磁金属可为钴铁CoFe、钴铁硼CoFeB或镍铁NiFe等材料中的至少一种形成的单一或混合金属材料,其中混合的金属材料的比例可以相同也可以不同。所述氧化物可为氧化镁MgO或氧化铝Al 2O 3等氧化物中的一种,用于产生隧穿磁阻效应。在实际应用中,铁磁金属和氧化物还可以采用其他可行的材料,本发明对此并不作限定。 Preferably, the material of the free ferromagnetic layer 131 and the reference ferromagnetic layer 133 may be ferromagnetic metal, and the material of the tunneling layer 132 may be oxide. The ferromagnetic metal may be a single or mixed metal material formed of at least one of cobalt iron CoFe, cobalt iron boron CoFeB or nickel iron NiFe, wherein the ratio of the mixed metal materials may be the same or different. The oxide may be one of oxides such as magnesium oxide MgO or aluminum oxide Al 2 O 3 , which is used to generate the tunneling magnetoresistance effect. In practical applications, ferromagnetic metals and oxides can also adopt other feasible materials, which are not limited in the present invention.
优选的,铁电层110的材料可包括氧化铪及掺杂的一种或多种元素,该一种或多种元素选自硅、锆、铝、镧、钇、钆、镁与锶等元素,铁电层110的材料可包括氧化锆及掺杂的一种或多种元素,该一种或多种元素选自硅、铪、铝、镧、钇、钆、镁与锶等元素,铁电层110的材料可包括钛酸锶及掺杂的一种或多种元素,该一种或多种元素选自硅、锆、铝、镧、钇、钆、镁与铪等元素。在其他实施方式中,铁电层110还可以选用本领域其他可行的材料,本发明对此并不作限定。Preferably, the material of the ferroelectric layer 110 may include hafnium oxide and doped one or more elements selected from elements such as silicon, zirconium, aluminum, lanthanum, yttrium, gadolinium, magnesium, and strontium. , the material of the ferroelectric layer 110 may include zirconia and doped one or more elements, the one or more elements are selected from elements such as silicon, hafnium, aluminum, lanthanum, yttrium, gadolinium, magnesium and strontium, iron The material of the electrical layer 110 may include strontium titanate and doped one or more elements selected from elements such as silicon, zirconium, aluminum, lanthanum, yttrium, gadolinium, magnesium, and hafnium. In other embodiments, the ferroelectric layer 110 may also be selected from other materials available in the art, which are not limited in the present invention.
优选的,介电层120的材料可包括氧化铪、氧化锆、氧化镁、氧化铝、钛酸锶和其他金属氧化物,在其他实施方式中,介电层120还可以选用本领域其他可行的材料,本发明对此并不作限定。Preferably, the material of the dielectric layer 120 may include hafnium oxide, zirconium oxide, magnesium oxide, aluminum oxide, strontium titanate and other metal oxides. In other embodiments, the dielectric layer 120 may also be selected from other feasible materials in the art. material, which is not limited in the present invention.
在优选的实施方式中,可通过传统的化学气相沉积、物理气相沉积(包含溅镀)、离子束外延、原子层沉积或磁控溅射等方法将磁性随机存储器的各层按照从下到上的顺序依次形成在底电极层171上,然后通过光刻、刻蚀等传统纳米器件加工工艺来制备形成最终的磁性随机存储器。In a preferred embodiment, the layers of the magnetic random access memory can be arranged from bottom to top by conventional chemical vapor deposition, physical vapor deposition (including sputtering), ion beam epitaxy, atomic layer deposition or magnetron sputtering. are sequentially formed on the bottom electrode layer 171, and then the final magnetic random access memory is prepared by traditional nano-device processing techniques such as photolithography and etching.
基于相同原理,本实施例还公开了一种磁性随机存储装置。磁性随机存储装置包括如本实施例所述的磁性随机存储器以及与所述磁性随机存储器电连接的控制电路。Based on the same principle, this embodiment also discloses a magnetic random access memory device. The magnetic random access memory device includes the magnetic random access memory described in this embodiment and a control circuit electrically connected to the magnetic random access memory.
其中,所述控制电路用于在所述磁隧道结上施加读取电压或写入电流,在所述铁电层110和介电层120形成的负电容结构上施加正向偏置电压或负向偏置电压以降低或提高磁隧道结的磁各向异性。Wherein, the control circuit is used to apply a read voltage or a write current on the magnetic tunnel junction, and a forward bias voltage or negative capacitance is applied to the negative capacitance structure formed by the ferroelectric layer 110 and the dielectric layer 120 bias voltage to reduce or increase the magnetic anisotropy of the magnetic tunnel junction.
由于该装置解决问题的原理与以上存储器类似,因此本装置的实施可以参见存储器的实施,在此不再赘述。Since the principle of the device for solving the problem is similar to the above memory, the implementation of the device can refer to the implementation of the memory, and details are not repeated here.
基于相同原理,本实施例还公开了一种磁性随机存储装置的读写控制方法。本实施例中,如图4所示,所述方法包括:Based on the same principle, this embodiment also discloses a read-write control method for a magnetic random access memory device. In this embodiment, as shown in FIG. 4 , the method includes:
在写入阶段:During the write phase:
S100:通过控制电路向铁电层110和介电层120形成的负电容结构的两端上施加正向偏置电压以降低磁隧道结的磁各向异性。S100: A forward bias voltage is applied to both ends of the negative capacitance structure formed by the ferroelectric layer 110 and the dielectric layer 120 through a control circuit to reduce the magnetic anisotropy of the magnetic tunnel junction.
S200:通过控制电路在所述磁隧道结的两端施加与待写入的数据对应的写入电流完成数据写入。S200: Complete data writing by applying a writing current corresponding to the data to be written at both ends of the magnetic tunnel junction through a control circuit.
在读取阶段:During the read phase:
S300:通过控制电路在所述磁隧道结的两端施加读取电压,根据所述读取电压的变化确定磁隧道结存储的数据。S300: Apply a read voltage to both ends of the magnetic tunnel junction through a control circuit, and determine the data stored in the magnetic tunnel junction according to the change of the read voltage.
在优选的实施方式中,所述方法进一步包括:In a preferred embodiment, the method further comprises:
在写入阶段:During the write phase:
S400:在通过控制电路在所述磁隧道结的两端施加与待写入的数据对应的写入电流的同时,向铁电层110和介电层120形成的负电容结构的两端上施加正向偏置电压。可以理解的是,通过第二电极160和第三电极172施加正向偏置电压,可以降低磁隧道结的磁各向异性,从而降低写入阶段时写入电流的电流密度。S400 : while applying a writing current corresponding to the data to be written at both ends of the magnetic tunnel junction through a control circuit, apply a writing current to both ends of the negative capacitance structure formed by the ferroelectric layer 110 and the dielectric layer 120 Forward Bias Voltage. It can be understood that by applying a forward bias voltage to the second electrode 160 and the third electrode 172, the magnetic anisotropy of the magnetic tunnel junction can be reduced, thereby reducing the current density of the writing current in the writing stage.
在优选的实施方式中,所述方法进一步包括:In a preferred embodiment, the method further comprises:
在读取阶段:During the read phase:
S500:在通过控制电路在所述磁隧道结的两端施加读取电压的同时,向铁电层110和介电层120形成的负电容结构的两端上施加负向偏置电压。S500 : applying a negative bias voltage to both ends of the negative capacitance structure formed by the ferroelectric layer 110 and the dielectric layer 120 while applying the read voltage to both ends of the magnetic tunnel junction through the control circuit.
可以理解的是,通过第二电极160和第三电极172施加负向偏置电压,可以提高磁隧道结的磁各向异性,从而降低数据读取时的误翻转概率。It can be understood that by applying a negative bias voltage to the second electrode 160 and the third electrode 172, the magnetic anisotropy of the magnetic tunnel junction can be improved, thereby reducing the probability of false inversion during data reading.
由于该方法解决问题的原理与以上存储器和装置类似,因此本方法的实施可以参见存储器和装置的实施,在此不再赘述。Since the principle of the method for solving the problem is similar to the above memory and device, the implementation of the method can refer to the implementation of the memory and the device, and details are not repeated here.
本实施例中的磁性随机存储器可用于形成计算机芯片等设备。具体的,计算机设备例如可以为个人计算机、膝上型计算机、蜂窝电话、相机电话、智能电话、个人数字助理、媒体播放器、导航设备、电子邮件设备、游戏控制台、平板计算机、可穿戴设备或者这些设备中的任何设备的组合。在一个典型的实例中计算机设备具体包括存储器、处 理器以及存储在存储器上并可在处理器上运行的计算机程序,所述存储器可采用本实施例所述的磁性随机存储器。The magnetic random access memory in this embodiment can be used to form equipment such as computer chips. Specifically, the computer device may be, for example, a personal computer, a laptop computer, a cellular phone, a camera phone, a smart phone, a personal digital assistant, a media player, a navigation device, an email device, a game console, a tablet computer, a wearable device Or a combination of any of these devices. In a typical example, the computer device specifically includes a memory, a processor, and a computer program stored in the memory and executable on the processor, and the memory can use the magnetic random access memory described in this embodiment.
下面参考图5,其示出了适于用来实现本申请实施例的计算机设备600的结构示意图。Referring next to FIG. 5 , it shows a schematic structural diagram of a computer device 600 suitable for implementing the embodiments of the present application.
如图5所示,计算机设备600包括中央处理单元(CPU)601,其可以根据存储在只读存储器(ROM)602中的程序或者从存储部分608加载到随机访问存储器(RAM))603中的程序而执行各种适当的工作和处理。在RAM603中,还存储有系统600操作所需的各种程序和数据。CPU601、ROM602、以及RAM603通过总线604彼此相连。输入/输出(I/O)接口605也连接至总线604。As shown in FIG. 5, a computer device 600 includes a central processing unit (CPU) 601 that can be loaded into a random access memory (RAM) 603 according to a program stored in a read only memory (ROM) 602 or from a storage section 608 program to perform various appropriate tasks and processes. In the RAM 603, various programs and data necessary for the operation of the system 600 are also stored. The CPU 601 , the ROM 602 , and the RAM 603 are connected to each other through a bus 604 . An input/output (I/O) interface 605 is also connected to bus 604 .
以下部件连接至I/O接口605:包括键盘、鼠标等的输入部分606;包括诸如阴极射线管(CRT)、液晶反馈器(LCD)等以及扬声器等的输出部分607;包括硬盘等的存储部分608;以及包括诸如LAN卡,调制解调器等的网络接口卡的通信部分609。通信部分609经由诸如因特网的网络执行通信处理。驱动器610也根据需要连接至I/O接口605。可拆卸介质611,诸如磁盘、光盘、磁光盘、半导体存储器等等,根据需要安装在驱动器610上,以便于从其上读出的计算机程序根据需要被安装如存储部分608。The following components are connected to the I/O interface 605: an input section 606 including a keyboard, a mouse, etc.; an output section 607 including a cathode ray tube (CRT), a liquid crystal feedback device (LCD), etc., and a speaker, etc.; a storage section including a hard disk, etc. 608; and a communication section 609 including network interface cards such as LAN cards, modems, and the like. The communication section 609 performs communication processing via a network such as the Internet. A drive 610 is also connected to the I/O interface 605 as needed. A removable medium 611, such as a magnetic disk, an optical disk, a magneto-optical disk, a semiconductor memory, etc., is mounted on the drive 610 as needed so that a computer program read therefrom is installed as the storage section 608 as needed.
实施例二Embodiment 2
磁性随机存储器各膜层的上、下顺序仅为了说明各层的相对位置关系,根据磁性随机存储器的器件应用和制备工艺的不同,各层在实际空间中可以是自上向下也可以是自下而上的顺序设置,即磁性随机存储器各层的上下顺序可以反转,以利于优化薄膜质量或器件性能。因此,与实施例一不同的是,本实施例中,磁性随机存储器各层的上下位置与实施例一相反。如图6所示,本实施例中,磁性随机存储器自上而下依次为底电极270、铁电层210、金属层240、介电层220、自由铁磁层231、隧穿层232、参考铁磁层233和第一电极。磁性随机存储器还包括与自由铁磁层231电接触的第二电极260。由于本实施例中第一电极位于磁性随机存储器的底层,因此,第一电极可包括第一电极层251和位于所述第一电极层251上的第一外接电极252。本实施例的其他技术特征与实施例一中类似,在此不再赘述。The upper and lower order of each film layer of the magnetic random access memory is only to illustrate the relative positional relationship of each layer. According to the device application and preparation process of the magnetic random access memory, each layer can be from top to bottom in actual space. The bottom-up sequence setting, that is, the top-bottom sequence of each layer of the magnetic random access memory can be reversed, so as to optimize the film quality or device performance. Therefore, different from the first embodiment, in this embodiment, the upper and lower positions of each layer of the magnetic random access memory are opposite to those of the first embodiment. As shown in FIG. 6 , in this embodiment, the magnetic random access memory consists of bottom electrode 270 , ferroelectric layer 210 , metal layer 240 , dielectric layer 220 , free ferromagnetic layer 231 , tunneling layer 232 , reference The ferromagnetic layer 233 and the first electrode. The magnetic random access memory also includes a second electrode 260 in electrical contact with the free ferromagnetic layer 231 . Since the first electrode is located at the bottom layer of the magnetic random access memory in this embodiment, the first electrode may include a first electrode layer 251 and a first external electrode 252 located on the first electrode layer 251 . The other technical features of this embodiment are similar to those in the first embodiment, and are not repeated here.
实施例三Embodiment 3
与实施例一和实施例二不同的是,本实施例中,通过设置隧穿层与铁电层的材料和厚度,则介电层可由隧穿层代替,即此时,磁隧道结包括设于所述铁电层和所述介电层间的自由铁磁层以及至少部分设于所述介电层上的参考铁磁层。磁隧道结的一部分在铁 电层和介电层之间,磁隧道结的另一部分设于介电层之上,实现数据的非易失性存储。例如,如图7所示,磁性随机存储器自上而下依次为第一电极350、参考铁磁层333、介电层320、自由铁磁层331、铁电层310和底电极层371。磁性随机存储器进一步包括与所述底电极层371电接触的第三电极372和与所述自由铁磁层331电接触的第二电极360。Different from Embodiment 1 and Embodiment 2, in this embodiment, by setting the material and thickness of the tunneling layer and the ferroelectric layer, the dielectric layer can be replaced by the tunneling layer, that is, at this time, the magnetic tunnel junction includes a set of A free ferromagnetic layer between the ferroelectric layer and the dielectric layer and a reference ferromagnetic layer disposed at least partially on the dielectric layer. A part of the magnetic tunnel junction is between the ferroelectric layer and the dielectric layer, and the other part of the magnetic tunnel junction is arranged on the dielectric layer to realize non-volatile storage of data. For example, as shown in FIG. 7 , the magnetic random access memory includes a first electrode 350 , a reference ferromagnetic layer 333 , a dielectric layer 320 , a free ferromagnetic layer 331 , a ferroelectric layer 310 and a bottom electrode layer 371 in order from top to bottom. The magnetic random access memory further includes a third electrode 372 in electrical contact with the bottom electrode layer 371 and a second electrode 360 in electrical contact with the free ferromagnetic layer 331 .
在实际应用中,与实施例一中的磁性随机存储器的数据读写控制方法不同,本实施例中,需通过在第一电极和第三电极间施加正向偏置电压,降低自由铁磁层的磁各向异性,从而降低写入电流及磁随机存储器的热稳定性,使在第一电极和第二电极间输入很小的写入电流即可完成磁隧道结中的数据写入操作。本实施例的其他技术特征与实施例一中类似,在此不再赘述。In practical applications, different from the data read/write control method of the magnetic random access memory in the first embodiment, in this embodiment, a forward bias voltage needs to be applied between the first electrode and the third electrode to reduce the free ferromagnetic layer Therefore, the write current and the thermal stability of the magnetic random access memory are reduced, so that the data write operation in the magnetic tunnel junction can be completed by inputting a small write current between the first electrode and the second electrode. Other technical features of this embodiment are similar to those in the first embodiment, and are not repeated here.
还需要说明的是,术语“包括”、“包含”或者其任何其他变体意在涵盖非排他性的包含,从而使得包括一系列要素的过程、方法、商品或者设备不仅包括那些要素,而且还包括没有明确列出的其他要素,或者是还包括为这种过程、方法、商品或者设备所固有的要素。在没有更多限制的情况下,由语句“包括一个……”限定的要素,并不排除在包括所述要素的过程、方法、商品或者设备中还存在另外的相同要素。It should also be noted that the terms "comprising", "comprising" or any other variation thereof are intended to encompass a non-exclusive inclusion such that a process, method, article or device comprising a series of elements includes not only those elements, but also Other elements not expressly listed, or which are inherent to such a process, method, article of manufacture, or apparatus are also included. Without further limitation, an element qualified by the phrase "comprising a..." does not preclude the presence of additional identical elements in the process, method, article of manufacture or device that includes the element.
本说明书中的各个实施例均采用递进的方式描述,各个实施例之间相同相似的部分互相参见即可,每个实施例重点说明的都是与其他实施例的不同之处。尤其,对于系统实施例而言,由于其基本相似于方法实施例,所以描述的比较简单,相关之处参见方法实施例的部分说明即可。Each embodiment in this specification is described in a progressive manner, and the same and similar parts between the various embodiments may be referred to each other, and each embodiment focuses on the differences from other embodiments. In particular, as for the system embodiments, since they are basically similar to the method embodiments, the description is relatively simple, and for related parts, please refer to the partial descriptions of the method embodiments.
以上所述仅为本申请的实施例而已,并不用于限制本申请。对于本领域技术人员来说,本申请可以有各种更改和变化。凡在本申请的精神和原理之内所作的任何修改、等同替换、改进等,均应包含在本申请的权利要求范围之内。The above descriptions are merely examples of the present application, and are not intended to limit the present application. Various modifications and variations of this application are possible for those skilled in the art. Any modification, equivalent replacement, improvement, etc. made within the spirit and principle of this application shall be included within the scope of the claims of this application.

Claims (11)

  1. 一种磁性随机存储器,其特征在于,包括:A magnetic random access memory, comprising:
    铁电层;ferroelectric layer;
    介电层,设于所述铁电层上;以及a dielectric layer disposed on the ferroelectric layer; and
    磁隧道结,至少部分设于所述介电层上。A magnetic tunnel junction is at least partially disposed on the dielectric layer.
  2. 根据权利要求1所述的磁性随机存储器,其特征在于,所述磁隧道结包括自由铁磁层、设于所述自由铁磁层上的隧穿层以及设于所述隧穿层上的参考铁磁层,所述自由铁磁层至少部分设于所述介电层上;或者,The magnetic random access memory of claim 1, wherein the magnetic tunnel junction comprises a free ferromagnetic layer, a tunneling layer provided on the free ferromagnetic layer, and a reference provided on the tunneling layer a ferromagnetic layer, the free ferromagnetic layer is disposed at least partially on the dielectric layer; or,
    所述磁隧道结包括设于所述铁电层和所述介电层间的自由铁磁层以及至少部分设于所述介电层上的参考铁磁层。The magnetic tunnel junction includes a free ferromagnetic layer disposed between the ferroelectric layer and the dielectric layer, and a reference ferromagnetic layer disposed at least partially on the dielectric layer.
  3. 根据权利要求2所述的磁性随机存储器,其特征在于,进一步包括与所述参考铁磁层电连接的第一电极和与所述自由铁磁层电连接的第二电极。The magnetic random access memory of claim 2, further comprising a first electrode electrically connected to the reference ferromagnetic layer and a second electrode electrically connected to the free ferromagnetic layer.
  4. 根据权利要求1所述的磁性随机存储器,其特征在于,进一步包括与所述铁电层电连接的底电极。The magnetic random access memory of claim 1, further comprising a bottom electrode electrically connected to the ferroelectric layer.
  5. 根据权利要求4所述的磁性随机存储器,其特征在于,所述底电极包括底电极层和所述底电极层电连接的第三电极,所述铁电层设于所述底电极层上。The magnetic random access memory of claim 4, wherein the bottom electrode comprises a bottom electrode layer and a third electrode electrically connected to the bottom electrode layer, and the ferroelectric layer is provided on the bottom electrode layer.
  6. 根据权利要求1所述的磁性随机存储器,其特征在于,进一步包括设于所述铁电层和所述介电层间的金属层。The magnetic random access memory of claim 1, further comprising a metal layer disposed between the ferroelectric layer and the dielectric layer.
  7. 根据权利要求3所述的磁性随机存储器,其特征在于,所述隧穿层的底面积小于所述自由铁磁层的顶面积,所述第二电极设于所述自由铁磁层上。The magnetic random access memory of claim 3, wherein a bottom area of the tunneling layer is smaller than a top area of the free ferromagnetic layer, and the second electrode is disposed on the free ferromagnetic layer.
  8. 根据权利要求5所述的磁性随机存储器,其特征在于,所述铁电层的底面积小于所述底电极层的顶面积,所述第三电极设于所述底电极层上。The magnetic random access memory of claim 5, wherein the bottom area of the ferroelectric layer is smaller than the top area of the bottom electrode layer, and the third electrode is disposed on the bottom electrode layer.
  9. 一种磁性随机存储装置,其特征在于,包括如权利要求1-8任一项所述的磁性随机存储器以及与所述磁性随机存储器电连接的控制电路;A magnetic random access memory device, characterized by comprising the magnetic random access memory according to any one of claims 1-8 and a control circuit electrically connected to the magnetic random access memory;
    所述控制电路用于在所述磁隧道结上施加读取电压或写入电流,在所述铁电层和介电层形成的负电容结构上施加正向偏置电压或负向偏置电压以降低或提高磁隧道结的磁各向异性。The control circuit is used for applying a read voltage or a write current on the magnetic tunnel junction, and applying a forward bias voltage or a negative bias voltage on the negative capacitance structure formed by the ferroelectric layer and the dielectric layer To reduce or improve the magnetic anisotropy of the magnetic tunnel junction.
  10. 一种磁性随机存储装置的读写控制方法,其特征在于,包括:A read-write control method for a magnetic random access storage device, comprising:
    在写入阶段:During the write phase:
    通过控制电路向铁电层和介电层形成的负电容结构的两端上施加正向偏置电压以降低磁隧道结的磁各向异性;A forward bias voltage is applied to both ends of the negative capacitance structure formed by the ferroelectric layer and the dielectric layer through a control circuit to reduce the magnetic anisotropy of the magnetic tunnel junction;
    通过控制电路在所述磁隧道结的两端施加与待写入的数据对应的写入电流完成数据写入;Data writing is completed by applying a writing current corresponding to the data to be written at both ends of the magnetic tunnel junction by the control circuit;
    在读取阶段:During the read phase:
    通过控制电路在所述磁隧道结的两端施加读取电压,根据所述读取电压的变化确定磁隧道结存储的数据。A read voltage is applied across the magnetic tunnel junction by a control circuit, and data stored in the magnetic tunnel junction is determined according to the change of the read voltage.
  11. 根据权利要求10所述的磁性随机存储装置的读写控制方法,其特征在于,进一步包括:The read-write control method of a magnetic random access storage device according to claim 10, further comprising:
    在写入阶段:During the write phase:
    在通过控制电路在所述磁隧道结的两端施加与待写入的数据对应的写入电流的同时,向铁电层和介电层形成的负电容结构的两端上施加正向偏置电压;A forward bias is applied to both ends of the negative capacitance structure formed by the ferroelectric layer and the dielectric layer while the write current corresponding to the data to be written is applied to both ends of the magnetic tunnel junction through the control circuit Voltage;
    在读取阶段:During the read phase:
    在通过控制电路在所述磁隧道结的两端施加读取电压的同时,向铁电层和介电层形成的负电容结构的两端上施加负向偏置电压。A negative bias voltage is applied to both ends of the negative capacitance structure formed by the ferroelectric layer and the dielectric layer while the read voltage is applied across the magnetic tunnel junction through the control circuit.
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