WO2022017486A1 - Adjustable resonator and manufacturing method therefor - Google Patents

Adjustable resonator and manufacturing method therefor Download PDF

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Publication number
WO2022017486A1
WO2022017486A1 PCT/CN2021/108055 CN2021108055W WO2022017486A1 WO 2022017486 A1 WO2022017486 A1 WO 2022017486A1 CN 2021108055 W CN2021108055 W CN 2021108055W WO 2022017486 A1 WO2022017486 A1 WO 2022017486A1
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upper electrode
layer
lower electrode
resonant cavity
electrode
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PCT/CN2021/108055
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French (fr)
Chinese (zh)
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吴明
唐兆云
赖志国
杨清华
王家友
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苏州汉天下电子有限公司
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Publication of WO2022017486A1 publication Critical patent/WO2022017486A1/en

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    • HELECTRICITY
    • H03ELECTRONIC CIRCUITRY
    • H03BGENERATION OF OSCILLATIONS, DIRECTLY OR BY FREQUENCY-CHANGING, BY CIRCUITS EMPLOYING ACTIVE ELEMENTS WHICH OPERATE IN A NON-SWITCHING MANNER; GENERATION OF NOISE BY SUCH CIRCUITS
    • H03B5/00Generation of oscillations using amplifier with regenerative feedback from output to input
    • H03B5/30Generation of oscillations using amplifier with regenerative feedback from output to input with frequency-determining element being electromechanical resonator
    • H03B5/32Generation of oscillations using amplifier with regenerative feedback from output to input with frequency-determining element being electromechanical resonator being a piezoelectric resonator
    • HELECTRICITY
    • H03ELECTRONIC CIRCUITRY
    • H03HIMPEDANCE NETWORKS, e.g. RESONANT CIRCUITS; RESONATORS
    • H03H3/00Apparatus or processes specially adapted for the manufacture of impedance networks, resonating circuits, resonators
    • H03H3/007Apparatus or processes specially adapted for the manufacture of impedance networks, resonating circuits, resonators for the manufacture of electromechanical resonators or networks
    • H03H3/02Apparatus or processes specially adapted for the manufacture of impedance networks, resonating circuits, resonators for the manufacture of electromechanical resonators or networks for the manufacture of piezoelectric or electrostrictive resonators or networks
    • HELECTRICITY
    • H03ELECTRONIC CIRCUITRY
    • H03HIMPEDANCE NETWORKS, e.g. RESONANT CIRCUITS; RESONATORS
    • H03H9/00Networks comprising electromechanical or electro-acoustic devices; Electromechanical resonators
    • H03H9/15Constructional features of resonators consisting of piezoelectric or electrostrictive material
    • H03H9/17Constructional features of resonators consisting of piezoelectric or electrostrictive material having a single resonator

Definitions

  • the present invention relates to an adjustable resonator and its manufacturing method, in particular to an adjustable adjustable resonator and its manufacturing method.
  • RF filters are used as an intermediary to filter specific frequency signals to reduce signal interference in different frequency bands, and to implement functions such as image cancellation, spurious filtering, and channel selection in wireless transceivers.
  • the design of RF front-end is developing towards miniaturization, low power consumption and integration, and the market has higher and higher requirements for filtering performance. Due to the small size, high operating frequency, low power consumption, high quality factor (Q value), direct With the characteristics of output frequency signal and compatibility with CMOS process, it has become an important device in the field of radio frequency communication and is widely used.
  • FBAR is a thin film device with an electrode-piezoelectric film-electrode sandwich structure fabricated on a substrate material.
  • the structure of FBAR has cavity type, Bragg reflection type (SMR) and backside etching type.
  • SMR Bragg reflection type
  • the cavity type FBAR has higher Q value, lower loss and higher electromechanical coupling coefficient; compared with the backside etching type FBAR, it does not need to remove a large area of the substrate and has higher mechanical strength. Therefore, cavity-type FBAR is the first choice for integration on CMOS devices.
  • the resonant frequency of the device is determined accordingly.
  • a large number of resonant cavities of different sizes must be fabricated on the same substrate, which unnecessarily increases the size of the system, and in some cases The resonator works while most of the other resonators are idle, resulting in low system utilization.
  • the purpose of the present invention is to provide a tunable resonator and a preparation method thereof that overcome the above technical obstacles.
  • the present invention provides a tunable resonator, comprising:
  • the resonant cavity, in the substrate at least includes a first resonant cavity in the center and a second resonant cavity in the periphery;
  • the first stack structure on the first resonant cavity, sequentially includes a first part of the lower electrode, a first part of the piezoelectric layer and a first part of the upper electrode;
  • the second stack structure on the second resonant cavity, sequentially includes a second part of the lower electrode, a second part of the piezoelectric layer and a second part of the upper electrode;
  • a first insulating layer, on the substrate, is located between the first portion of the lower electrode and the second portion of the lower electrode.
  • the first resonant cavity, the first part of the lower electrode and the first part of the upper electrode are polygonal, circular or elliptical in plan view; preferably, the size of the top of the first resonant cavity is larger than that of the first part of the lower electrode or the first part of the upper electrode , optionally, the size of the top of the second resonant cavity is larger than the size of the second part of the lower electrode or the second part of the upper electrode;
  • the two parts are edge-aligned.
  • the resonance state including at least one of amplitude, frequency, phase or a combination thereof.
  • the substrate material is Si, SOI, Ge, GeOI, compound semiconductor; optionally, the materials of the first part of the piezoelectric layer and the second part of the piezoelectric layer are ZnO, AlN, BST (barium strontium titanate), BT ( barium titanate), PZT (lead zirconate titanate), PBLN (lead barium lithium niobate), PT (lead titanate), and further preferably the piezoelectric material is doped with rare earth elements; optionally, the first or second The material of the insulating layer is nitride, such as silicon nitride, silicon oxynitride, aluminum nitride, boron nitride; optionally, the first part of the lower electrode, the second part of the lower electrode, the first part of the upper electrode, the second part of the upper electrode Any one of the materials is selected from Mo, W, Ru, Al, Cu, Ti, Ta, In, Zn, Zr, Fe, M
  • the present invention also provides a method for manufacturing a tunable resonator, comprising:
  • a sacrificial layer in the substrate including a first sacrificial layer pattern in the center and a second sacrificial layer pattern in the periphery;
  • a lower electrode layer is formed on the sacrificial layer, comprising a first portion of the lower electrode on the first sacrificial layer pattern and a second portion of the lower electrode on the second sacrificial layer pattern;
  • a piezoelectric layer on the first insulating layer and the lower electrode layer, including at least a first part of the piezoelectric layer above the first sacrificial layer pattern and a second part of the piezoelectric layer above the second sacrificial layer pattern;
  • an upper electrode layer on the piezoelectric layer including a first part of the upper electrode on the first part of the piezoelectric layer, and a second part of the upper electrode on the second part of the piezoelectric layer;
  • the sacrificial layer is removed, leaving a cavity in the substrate, including a first cavity in the center and a second cavity in the periphery.
  • the upper electrode layer After forming the upper electrode layer, it further includes, at least forming a second insulating layer between the first part of the upper electrode and the second part of the upper electrode; preferably, the first part of the piezoelectric layer and the second part of the piezoelectric layer are connected, or by the second insulating layer The layers are spaced apart.
  • the first resonant cavity, the first part of the lower electrode and the first part of the upper electrode are polygonal, circular or elliptical in plan view; preferably, the size of the top of the first resonant cavity is larger than that of the first part of the lower electrode or the first part of the upper electrode , optionally, the size of the top of the second resonant cavity is larger than the size of the second part of the lower electrode or the second part of the upper electrode;
  • the two parts are edge-aligned.
  • the substrate material is Si, SOI, Ge, GeOI, compound semiconductor; optionally, the materials of the first part of the piezoelectric layer and the second part of the piezoelectric layer are ZnO, AlN, BST (barium strontium titanate), BT ( barium titanate), PZT (lead zirconate titanate), PBLN (lead barium lithium niobate), PT (lead titanate), and further preferably the piezoelectric material is doped with rare earth elements; optionally, the first or second The material of the insulating layer is nitride, such as silicon nitride, silicon oxynitride, aluminum nitride, boron nitride; optionally, the first part of the lower electrode, the second part of the lower electrode, the first part of the upper electrode, the second part of the upper electrode Any one of the materials is selected from Mo, W, Ru, Al, Cu, Ti, Ta, In, Zn, Zr, Fe, M
  • the auxiliary resonator is added around the main resonator to actively adjust the resonance state, which is beneficial to improve the integration degree and efficiency of the device.
  • FIG. 1 shows a cross-sectional view of a resonator fabrication process according to an embodiment of the present invention
  • FIG. 2 shows a cross-sectional view of a resonator fabrication process according to an embodiment of the present invention
  • FIG. 3 shows a cross-sectional view of a resonator fabrication process according to an embodiment of the present invention
  • FIG. 4 shows a cross-sectional view of a resonator fabrication process according to an embodiment of the present invention
  • FIG. 5 shows a cross-sectional view of a resonator fabrication process according to an embodiment of the present invention
  • FIG. 6 shows a cross-sectional view of a resonator fabrication process according to an embodiment of the present invention
  • FIG. 7 shows a cross-sectional view of a resonator fabrication process according to an embodiment of the present invention
  • FIG. 8 shows a cross-sectional view of a resonator fabrication process according to an embodiment of the present invention
  • FIG. 9 shows a cross-sectional view of a resonator fabrication process according to an embodiment of the present invention.
  • Figure 10 shows a plan view of a resonator top electrode according to an embodiment of the present invention.
  • a sacrificial layer 2 is formed in the substrate 1 .
  • the material can be bulk Si or silicon-on-insulator (SOI) or bulk Ge, GeOI to be compatible with CMOS process and integrated with other digital and analog circuits, and can also be a compound for MEMS, optoelectronic devices, power devices Semiconductors such as GaN, GaAs, SiC, InP, GaP, etc., further preferably, the substrate 1 is a single crystal material.
  • the substrate 1 is etched to form a plurality of cavities (not shown in FIG. 1 ), and a sacrificial layer 2 is deposited to fill it.
  • the etching process is preferably anisotropic dry etching or wet etching, such as reactive ion etching with a fluorocarbon-based etching gas, or wet etching with TMAH.
  • the deposition process is a low temperature process such as LPCVD, APCVD, PECVD (deposition temperature is lower than 500 degrees Celsius, preferably 100 to 400 degrees Celsius), and the sacrificial layer 2 is made of silicon oxide-based materials, such as boron-doped silicon oxide (BSG), phosphorus-doped silicon oxide ( PSG), undoped silicon oxide (USG), porous silicon oxide, etc., so that the residual thermal stress in the substrate 1 can be reduced, and it is beneficial to improve the speed of subsequent etching and removal to save time and cost.
  • BSG boron-doped silicon oxide
  • PSG phosphorus-doped silicon oxide
  • USG undoped silicon oxide
  • porous silicon oxide etc.
  • the sacrificial layer 2 includes at least two parts, that is, the first part 2 a is used to fill the main resonant cavity, and the second part 2 b is used to fill the secondary resonant cavity around the main resonant cavity.
  • the sacrificial layer 2 is processed by a CMP planarization process until the surface of the substrate 1 is exposed.
  • the central part of the cavity formed by etching the substrate 1, that is, the projection of the main resonant cavity in a plan view is a polygon (such as a quadrilateral, pentagon, hexagon, octagon, etc.
  • the 1S is used as a subsequent mechanical support or isolation structure, and the first part 2a and the second part 2b of the filled sacrificial layer also have corresponding morphologies.
  • a patterned lower electrode 3 is formed on the substrate 1 .
  • a conductive material layer is formed, such as Mo, W, Ru, Al, Cu, Ti, Ta, In, Zn, Zr, Fe, Mg and other metal elements or metal alloys , or conductive oxides of these metals, conductive nitrides, and any combination of the above materials.
  • a seed layer (not shown) is further formed on the substrate 1 and the sacrificial layer 2 to improve the crystal orientation of the electrode layer and the upper functional layer.
  • the seed layer is AlN, HfN, HfAlN, TiN, TaN, etc., and preferably can be used as a barrier layer preventing the downward migration of the lower electrode metal material to avoid affecting the top of the resonant cavity and the bottom The interface state between the film layers.
  • a photolithography-etching process is used, such as spin coating photoresist, exposure and development to form a photoresist pattern, and the photoresist pattern is used as a mask to etch the conductive material layer to pattern the conductive material layer, and form Figure 2 Lower electrode 3 shown.
  • the lower electrode 3 includes at least a first portion 3a at the center, and a second portion 3b at the periphery.
  • the first part 3a of the lower electrode is the same as the first part 2a of the sacrificial layer and the main resonant cavity.
  • the projection in the plan view is a polygon (such as a quadrilateral, a pentagon, a hexagon, an octagon, etc.), a circle, an ellipse, etc.
  • the second portion 3b is an annular structure concentric with the first portion 3a with a gap therebetween. It is worth noting that, in order to ensure sufficient insulation isolation between the main resonator and the lower electrode of the adjustment sub-resonator, the distance between the second peripheral part 3b and the central first part 3a should be at least greater than that of the main and auxiliary resonators.
  • the edge of the first portion 3a of the lower electrode is indented inwardly from the edge of the first portion 2a of the sacrificial layer by 0.1-10 microns, preferably 0.05-5 microns, optimally 1-3 microns. Further or similarly, the edge of the second portion 3b of the lower electrode is also retracted inward by the same distance from the edge of the second portion 2b of the sacrificial layer.
  • an insulating layer 4 is filled between the lower electrode patterns.
  • the insulating dielectric material is filled between the first part 3a and the second part 3b of the lower electrode layer to form an annular insulating layer pattern 4 .
  • the material of the insulating layer 4 is different from that of the sacrificial layer 2, so as to avoid excessive erosion during the subsequent process of removing the sacrificial layer 2 to form a resonant cavity.
  • the material of the insulating layer 4 is nitride, such as silicon nitride, silicon oxynitride, aluminum nitride, boron nitride, and the like.
  • the insulating layer is processed by a planarization process of etchback or CMP until the lower electrode patterns 3a and 3b are exposed.
  • the piezoelectric layer 5 is formed on the lower electrode patterns 3 a and 3 b and the insulating layer 4 .
  • a process such as PECVD, UHVCVD, HDPCVD, MOCVD, MBE, ALD, magnetron sputtering, thermal evaporation, etc. is used to form the piezoelectric layer 5 , preferably the material of which is different from the insulating layer 4 .
  • the piezoelectric layer 5 is made of materials such as ZnO, AlN, BST (barium strontium titanate), BT (barium titanate), PZT (lead zirconate titanate), PBLN (lead barium lithium niobate) ), PT (lead titanate) and other piezoelectric ceramic materials, and preferably, the piezoelectric layer 5 is doped with rare earth elements, such as scandium (Sc), yttrium (Y), lanthanum (La), cerium (Ce), Praseodymium (Pr), Neodymium (Nd), Promethium (Pm), Samarium (Sm), Europium (Eu), Gadolinium (Gd), Terbium (Tb), Dysprosium (Dy), Holmium (Ho), Erbium (Er), Any one of thulium (Tm), ytterbium (Yb), and lutetium (Lu) and
  • rare earth elements such as scandium
  • the piezoelectric layer 5 is doped with Sc, or mixed with Sc and Yb, or doped with Sc and Gd, or mixed with Sc, Yb, and Sm.
  • the upper conductive material layer 6 is formed on the piezoelectric layer 5 .
  • the preparation process and materials of the conductive material layer 6 are the same as those of the lower electrode layer 3 , and details are not repeated here.
  • the conductive material layer 6 is patterned to form an upper electrode first portion 6a and an upper electrode second portion 6b.
  • the photoresist is spin-coated, a photoresist pattern is formed through an exposure and development process, and the conductive material layer 6 is etched with the photoresist pattern as a mask to form a first portion 6a of an upper electrode located in the center, and a second annular upper electrode located in the periphery. Section 6b.
  • the edge of the first portion 6a of the upper electrode is aligned with the edge of the first portion 3a of the lower electrode, and the edge of the second portion 6b of the upper electrode is aligned with the edge of the second portion 3b of the lower electrode, so that there is a gap between the first portion 6a and the second portion 6b.
  • the photoresist pattern is preferably removed by a wet etching process.
  • a second insulating layer 7 is formed on the piezoelectric layer 5 and the upper electrode patterns 6a/6b.
  • the material and process of the second insulating layer 7 are the same as or similar to those of the insulating layer 4 , and details are not repeated here.
  • the sacrificial layer pattern 2 is removed, leaving a resonant cavity in the substrate 1 .
  • a wet etchant is applied to remove the sacrificial layer pattern through release holes (not shown) provided at the periphery of the device.
  • an HF-based etching solution such as dHF (diluted HF), dBOE (slow release etchant, a mixture of HF and NH 4 F) to remove the sacrificial layer pattern 2, leaving multiple resonant cavities with at least It comprises a first portion 1c in the center, and a second portion 1c' in an annular shape in the periphery.
  • the width of the insulating layer 4 is larger than the width of the top of the support structure 1S, and the width of the first part 3a and the second part 3b of the lower electrode is smaller than that of the sacrificial layer patterns 2a and 2b, so the width of the main resonant cavity 1c left is larger than that of the first part 3a and the second part 3b of the lower electrode.
  • the width of the sub-resonant cavity 1c' is larger than that of the second portion 3b of the lower electrode.
  • the second insulating layer 7 is processed by a planarization process such as etchback, CMP, etc., until the upper electrode patterns 6a and 6b are exposed.
  • the finally formed resonator structure is shown in FIG. 8 and includes a substrate 1, a first part 1c of the resonator cavity, a second part 1c' of the resonator cavity located in the substrate 1, a first part 3a of the lower electrode above the first part 1c of the resonator cavity,
  • the piezoelectric layer 5 and the first part 6a of the upper electrode constitute the main resonator, and the second part 3b of the lower electrode, the piezoelectric layer 5, and the second part 6b of the upper electrode above the second part 1c' of the resonant cavity constitute the sub-resonator.
  • the distribution morphology of the upper electrodes 6a/6b and the second insulating layer 7 is shown in FIG. 10, which is the same as or conformal or similar to the lower electrodes 3a/3b and the insulating layer pattern 4, and both are concentric polygons or circles, ellipses
  • the second insulating layer 7 is sandwiched between the central part of the upper electrode, that is, the first part 6a and the peripheral second part 6b, and the second part 6b has at least one gap to accommodate the lead-out part of the first part 6a. Pass through the second insulating layer 7 under wrapping to realize external electrical connection.
  • the device by applying a signal different from that of the main resonator to the electrodes (3b, 6b) of the sub-resonator, for example, at least one of amplitude, frequency, and phase is different, so that the sub-resonator around the main resonator generates a different signal from the main resonator.
  • a signal different from that of the main resonator to the electrodes (3b, 6b) of the sub-resonator for example, at least one of amplitude, frequency, and phase is different, so that the sub-resonator around the main resonator generates a different signal from the main resonator.
  • the different vibrations of the resonator and the superposition of two mechanical waves with different states change the final signal waveform.
  • the vibration state of the sub-resonator can be flexibly changed in real time by controlling the input waveform of the sub-resonator, thereby affecting the working state of the entire resonator, so as to adjust the frequency response of the entire resonator system when needed, which is conducive to saving Chip area, improve integration, reduce product cost, and improve device utilization.
  • the piezoelectric layers 5 are no longer connected as a whole, but the second insulating layer 7 penetrates through the support structure 1S directly on the surface of the substrate 1, thereby The insulation isolation effect between the electrodes of the main resonator and the sub-resonator is improved, and the lateral crosstalk of signals between the upper and lower electrodes of different resonators is prevented.
  • the manufacturing process is basically the same as that shown in FIG. 1 to FIG. 8, except that in the process steps shown in FIG. 5, after etching and patterning the upper electrodes 6a and 6b, the photoresist pattern or the upper electrode pattern is used as a mask.
  • the mold continue to etch the piezoelectric layer 5 until the support structure 1S on the surface of the substrate 1 is exposed, and in the process steps shown in FIG. insulating layer 7.
  • the resulting device structure is similar to that shown in FIG. 8, the difference is that the second insulating layer 7 is not only sandwiched between the first part 6a and the second part 6b of the upper electrode, but also penetrates the piezoelectric layer 5 to the surface of the substrate, and is sandwiched therebetween. between the first part 3a and the second part 3b of the lower electrode.
  • the auxiliary resonator is added around the main resonator to actively adjust the resonance state, which is beneficial to improve the integration degree and efficiency of the device.

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Abstract

An adjustable resonator and a manufacturing method therefor. The resonator comprises: resonant cavities in a substrate, the resonant cavities at least including a central first resonant cavity and a peripheral second resonant cavity; a first stacked structure arranged on the first resonant cavity, and sequentially comprising a first portion of a lower electrode, a first portion of a piezoelectric layer, and a first portion of an upper electrode; a second stacked structure arranged on the second resonant cavity, and sequentially comprising a second portion of the lower electrode, a second portion of the piezoelectric layer, and a second portion of the upper electrode; and a first insulating layer disposed on the substrate and located between the first portion of the lower electrode and the second portion of the lower electrode. According to the adjustable resonator and the manufacturing method therefor of the present invention, an additional secondary resonator is arranged at the periphery of a primary resonator to actively adjust a resonant state, thereby facilitating increasing a level of integration and efficiency of a device.

Description

可调式谐振器及其制造方法Tunable resonator and method of making the same 技术领域technical field
本发明涉及一种可调式谐振器及其制造方法,特别是一种可调节的可调式谐振器及其制造方法。The present invention relates to an adjustable resonator and its manufacturing method, in particular to an adjustable adjustable resonator and its manufacturing method.
背景技术Background technique
在无线通讯中,射频滤波器作为过滤特定频率信号的中介,用于减少不同频段的信号干扰,在无线收发器中实现镜像消除、寄生滤波和信道选择等功能。随着4GLTE网络的部署和市场的增长,射频前端的设计朝着小型化、低功耗和集成化的方向发展,市场对滤波性能的要求也越来越高。由于薄膜体声波谐振器(FilmBulkAcousticResonator,简称“FBAR”,也称“体声波”,BulkAcousticWave,简称“BAW”,)具有尺寸小、工作频率高、功耗低、品质因数(Q值)高、直接输出频率信号、与CMOS工艺兼容等特点,目前已经成为射频通讯领域重要的器件被广泛应用。In wireless communications, RF filters are used as an intermediary to filter specific frequency signals to reduce signal interference in different frequency bands, and to implement functions such as image cancellation, spurious filtering, and channel selection in wireless transceivers. With the deployment of 4GLTE network and the growth of the market, the design of RF front-end is developing towards miniaturization, low power consumption and integration, and the market has higher and higher requirements for filtering performance. Due to the small size, high operating frequency, low power consumption, high quality factor (Q value), direct With the characteristics of output frequency signal and compatibility with CMOS process, it has become an important device in the field of radio frequency communication and is widely used.
FBAR是制作在衬底材料上的电极——压电膜——电极的三明治结构的薄膜器件。FBAR的结构有空腔型、布拉格反射型(SMR)和背面刻蚀型。其中空腔型FBAR相对SMR型Q值要高,损耗要小,机电耦合系数要高;相对于背面刻蚀型FBAR不需要去掉大面积的衬底,机械强度较高。因此,空腔型FBAR是集成于CMOS器件上的首选。FBAR is a thin film device with an electrode-piezoelectric film-electrode sandwich structure fabricated on a substrate material. The structure of FBAR has cavity type, Bragg reflection type (SMR) and backside etching type. Compared with the SMR type, the cavity type FBAR has higher Q value, lower loss and higher electromechanical coupling coefficient; compared with the backside etching type FBAR, it does not need to remove a large area of the substrate and has higher mechanical strength. Therefore, cavity-type FBAR is the first choice for integration on CMOS devices.
传统地,在衬底中制备了谐振空腔之后,器件的谐振频率就因此确定。当需要应用于不同频率或者频带范围较宽时,为了提高滤波精度,则必须在同一个衬底上制作大量尺寸不同的谐振空腔,这不必要地增大了系统的尺寸,且在某些谐振器工作同时而其他大部分谐振器处于空闲状态,系统利用率低下。Traditionally, after the resonant cavity is fabricated in the substrate, the resonant frequency of the device is determined accordingly. When it needs to be applied to different frequencies or a wide range of frequency bands, in order to improve the filtering accuracy, a large number of resonant cavities of different sizes must be fabricated on the same substrate, which unnecessarily increases the size of the system, and in some cases The resonator works while most of the other resonators are idle, resulting in low system utilization.
发明内容SUMMARY OF THE INVENTION
因此,本发明的目的在于提供一种克服以上技术障碍的可调式谐振器及其制备方法。Therefore, the purpose of the present invention is to provide a tunable resonator and a preparation method thereof that overcome the above technical obstacles.
本发明提供了一种可调式谐振器,包括:The present invention provides a tunable resonator, comprising:
谐振腔,在衬底中,至少包括中心的第一谐振腔和外围的第二谐 振腔;The resonant cavity, in the substrate, at least includes a first resonant cavity in the center and a second resonant cavity in the periphery;
第一堆叠结构,在第一谐振腔上,依次包括下电极第一部分、压电层第一部分和上电极第一部分;The first stack structure, on the first resonant cavity, sequentially includes a first part of the lower electrode, a first part of the piezoelectric layer and a first part of the upper electrode;
第二堆叠结构,在第二谐振腔上,依次包括下电极第二部分、压电层第二部分和上电极第二部分;The second stack structure, on the second resonant cavity, sequentially includes a second part of the lower electrode, a second part of the piezoelectric layer and a second part of the upper electrode;
第一绝缘层,在衬底上,位于下电极第一部分和下电极第二部分之间。A first insulating layer, on the substrate, is located between the first portion of the lower electrode and the second portion of the lower electrode.
进一步包括第二绝缘层,在压电层第一部分和压电层第二部分上,位于上电极第一部分和上电极第二部分之间;优选地,压电层第一部分和压电层第二部分连接,或者由第二绝缘层间隔开。It further comprises a second insulating layer, on the first part of the piezoelectric layer and the second part of the piezoelectric layer, between the first part of the upper electrode and the second part of the upper electrode; preferably, the first part of the piezoelectric layer and the second part of the piezoelectric layer Partially connected, or separated by a second insulating layer.
其中,第一谐振腔、下电极第一部分、上电极第一部分在平视图中为多边形、圆形或椭圆形;优选地,第一谐振腔顶部尺寸大于下电极第一部分或上电极第一部分的尺寸,任选地,第二谐振腔顶部尺寸大于下电极第二部分或上电极第二部分的尺寸;优选地,下电极第一部分和上电极第一部分边缘对齐,下电极第二部分和上电极第二部分边缘对齐。Wherein, the first resonant cavity, the first part of the lower electrode and the first part of the upper electrode are polygonal, circular or elliptical in plan view; preferably, the size of the top of the first resonant cavity is larger than that of the first part of the lower electrode or the first part of the upper electrode , optionally, the size of the top of the second resonant cavity is larger than the size of the second part of the lower electrode or the second part of the upper electrode; The two parts are edge-aligned.
其中,向第二堆叠结构施加与第一堆叠结构不同的信号以调节谐振器的谐振状态,所述谐振状态包括振幅、频率、相位的至少一个或其组合。Wherein, applying a different signal to the second stack structure than the first stack structure to adjust the resonance state of the resonator, the resonance state including at least one of amplitude, frequency, phase or a combination thereof.
其中,衬底材料为Si、SOI、Ge、GeOI、化合物半导体;任选地,压电层第一部分、压电层第二部分的材料为ZnO、AlN、BST(钛酸锶钡)、BT(钛酸钡)、PZT(锆钛酸铅)、PBLN(铌酸铅钡锂)、PT(钛酸铅),进一步优选地压电材料中掺杂稀土元素;任选地,第一或第二绝缘层的材料为氮化物,诸如氮化硅、氮氧化硅、氮化铝、氮化硼;任选地,下电极第一部分、下电极第二部分、上电极第一部分、上电极第二部分的任一个的材料为选自Mo、W、Ru、Al、Cu、Ti、Ta、In、Zn、Zr、Fe、Mg的金属单质或金属合金、或者这些金属的导电氧化物、或导电氮化物,以及上述材料的任意组合。Wherein, the substrate material is Si, SOI, Ge, GeOI, compound semiconductor; optionally, the materials of the first part of the piezoelectric layer and the second part of the piezoelectric layer are ZnO, AlN, BST (barium strontium titanate), BT ( barium titanate), PZT (lead zirconate titanate), PBLN (lead barium lithium niobate), PT (lead titanate), and further preferably the piezoelectric material is doped with rare earth elements; optionally, the first or second The material of the insulating layer is nitride, such as silicon nitride, silicon oxynitride, aluminum nitride, boron nitride; optionally, the first part of the lower electrode, the second part of the lower electrode, the first part of the upper electrode, the second part of the upper electrode Any one of the materials is selected from Mo, W, Ru, Al, Cu, Ti, Ta, In, Zn, Zr, Fe, Mg metal element or metal alloy, or conductive oxides or conductive nitrides of these metals , and any combination of the above materials.
本发明还提供了一种可调式谐振器制造方法,包括:The present invention also provides a method for manufacturing a tunable resonator, comprising:
在衬底中形成牺牲层,包括中心的第一牺牲层图形和外围的第二牺牲层图形;forming a sacrificial layer in the substrate, including a first sacrificial layer pattern in the center and a second sacrificial layer pattern in the periphery;
在牺牲层上形成下电极层,包括在第一牺牲层图形上的下电极第 一部分、和在第二牺牲层图形上的下电极第二部分;A lower electrode layer is formed on the sacrificial layer, comprising a first portion of the lower electrode on the first sacrificial layer pattern and a second portion of the lower electrode on the second sacrificial layer pattern;
在下电极第一部分和下电极第二部分之间形成第一绝缘层;forming a first insulating layer between the first part of the lower electrode and the second part of the lower electrode;
在第一绝缘层和下电极层上形成压电层,至少包括在第一牺牲层图形之上的压电层第一部分、和在第二牺牲层图形之上的压电层第二部分;forming a piezoelectric layer on the first insulating layer and the lower electrode layer, including at least a first part of the piezoelectric layer above the first sacrificial layer pattern and a second part of the piezoelectric layer above the second sacrificial layer pattern;
在压电层上形成上电极层,包括在压电层第一部分上的上电极第一部分、和在压电层第二部分上的上电极第二部分;forming an upper electrode layer on the piezoelectric layer, including a first part of the upper electrode on the first part of the piezoelectric layer, and a second part of the upper electrode on the second part of the piezoelectric layer;
去除牺牲层,在衬底中留下谐振腔,包括中心的第一谐振腔和外围的第二谐振腔。The sacrificial layer is removed, leaving a cavity in the substrate, including a first cavity in the center and a second cavity in the periphery.
形成上电极层之后进一步包括,至少在上电极第一部分和上电极第二部分之间形成第二绝缘层;优选地,压电层第一部分和压电层第二部分连接,或者由第二绝缘层间隔开。After forming the upper electrode layer, it further includes, at least forming a second insulating layer between the first part of the upper electrode and the second part of the upper electrode; preferably, the first part of the piezoelectric layer and the second part of the piezoelectric layer are connected, or by the second insulating layer The layers are spaced apart.
其中,第一谐振腔、下电极第一部分、上电极第一部分在平视图中为多边形、圆形或椭圆形;优选地,第一谐振腔顶部尺寸大于下电极第一部分或上电极第一部分的尺寸,任选地,第二谐振腔顶部尺寸大于下电极第二部分或上电极第二部分的尺寸;优选地,下电极第一部分和上电极第一部分边缘对齐,下电极第二部分和上电极第二部分边缘对齐。Wherein, the first resonant cavity, the first part of the lower electrode and the first part of the upper electrode are polygonal, circular or elliptical in plan view; preferably, the size of the top of the first resonant cavity is larger than that of the first part of the lower electrode or the first part of the upper electrode , optionally, the size of the top of the second resonant cavity is larger than the size of the second part of the lower electrode or the second part of the upper electrode; The two parts are edge-aligned.
其中,衬底材料为Si、SOI、Ge、GeOI、化合物半导体;任选地,压电层第一部分、压电层第二部分的材料为ZnO、AlN、BST(钛酸锶钡)、BT(钛酸钡)、PZT(锆钛酸铅)、PBLN(铌酸铅钡锂)、PT(钛酸铅),进一步优选地压电材料中掺杂稀土元素;任选地,第一或第二绝缘层的材料为氮化物,诸如氮化硅、氮氧化硅、氮化铝、氮化硼;任选地,下电极第一部分、下电极第二部分、上电极第一部分、上电极第二部分的任一个的材料为选自Mo、W、Ru、Al、Cu、Ti、Ta、In、Zn、Zr、Fe、Mg的金属单质或金属合金、或者这些金属的导电氧化物、或导电氮化物,以及上述材料的任意组合;任选地,牺牲层材料为氧化物,诸如掺硼氧化硅(BSG)、掺磷氧化硅(PSG)、未掺杂氧化硅(USG)、多孔氧化硅。Wherein, the substrate material is Si, SOI, Ge, GeOI, compound semiconductor; optionally, the materials of the first part of the piezoelectric layer and the second part of the piezoelectric layer are ZnO, AlN, BST (barium strontium titanate), BT ( barium titanate), PZT (lead zirconate titanate), PBLN (lead barium lithium niobate), PT (lead titanate), and further preferably the piezoelectric material is doped with rare earth elements; optionally, the first or second The material of the insulating layer is nitride, such as silicon nitride, silicon oxynitride, aluminum nitride, boron nitride; optionally, the first part of the lower electrode, the second part of the lower electrode, the first part of the upper electrode, the second part of the upper electrode Any one of the materials is selected from Mo, W, Ru, Al, Cu, Ti, Ta, In, Zn, Zr, Fe, Mg metal element or metal alloy, or conductive oxides or conductive nitrides of these metals , and any combination of the above materials; optionally, the sacrificial layer material is an oxide, such as boron-doped silicon oxide (BSG), phosphorus-doped silicon oxide (PSG), undoped silicon oxide (USG), porous silicon oxide.
形成上电极层之后、去除牺牲层之前进一步包括,在上电极第一部分和上电极第二部分之间刻蚀压电层形成暴露衬底的开口,在上电极层上以及开口的底部和侧壁上形成第二绝缘层。After forming the upper electrode layer and before removing the sacrificial layer, further comprising, etching the piezoelectric layer between the first part of the upper electrode and the second part of the upper electrode to form an opening exposing the substrate, on the upper electrode layer and the bottom and sidewalls of the opening A second insulating layer is formed thereon.
依照本发明的可调式谐振器及其制造方法,在主谐振器外围增设副谐振器以主动地调节谐振状态,有利于提高器件集成度和效率。According to the tunable resonator and the manufacturing method thereof of the present invention, the auxiliary resonator is added around the main resonator to actively adjust the resonance state, which is beneficial to improve the integration degree and efficiency of the device.
本发明所述目的,以及在此未列出的其他目的,在本申请独立权利要求的范围内得以满足。本发明的实施例限定在独立权利要求中,具体特征限定在其从属权利要求中。The stated objects of the invention, as well as other objects not listed here, are met within the scope of the independent claims of the present application. Embodiments of the invention are defined in the independent claims and specific features are defined in the dependent claims.
附图说明Description of drawings
以下参照附图来详细说明本发明的技术方案,其中:The technical solutions of the present invention are described in detail below with reference to the accompanying drawings, wherein:
图1显示了根据本发明实施例的谐振器制造工艺的剖视图;1 shows a cross-sectional view of a resonator fabrication process according to an embodiment of the present invention;
图2显示了根据本发明实施例的谐振器制造工艺的剖视图;2 shows a cross-sectional view of a resonator fabrication process according to an embodiment of the present invention;
图3显示了根据本发明实施例的谐振器制造工艺的剖视图;3 shows a cross-sectional view of a resonator fabrication process according to an embodiment of the present invention;
图4显示了根据本发明实施例的谐振器制造工艺的剖视图;4 shows a cross-sectional view of a resonator fabrication process according to an embodiment of the present invention;
图5显示了根据本发明实施例的谐振器制造工艺的剖视图;5 shows a cross-sectional view of a resonator fabrication process according to an embodiment of the present invention;
图6显示了根据本发明实施例的谐振器制造工艺的剖视图;6 shows a cross-sectional view of a resonator fabrication process according to an embodiment of the present invention;
图7显示了根据本发明实施例的谐振器制造工艺的剖视图;7 shows a cross-sectional view of a resonator fabrication process according to an embodiment of the present invention;
图8显示了根据本发明实施例的谐振器制造工艺的剖视图;8 shows a cross-sectional view of a resonator fabrication process according to an embodiment of the present invention;
图9显示了根据本发明实施例的谐振器制造工艺的剖视图;以及FIG. 9 shows a cross-sectional view of a resonator fabrication process according to an embodiment of the present invention; and
图10显示了根据本发明实施例的谐振器顶部电极的平视图。Figure 10 shows a plan view of a resonator top electrode according to an embodiment of the present invention.
具体实施方式detailed description
以下参照附图并结合示意性的实施例来详细说明本发明技术方案的特征及其技术效果,公开了有利于提高器件集成度和效率的谐振器及其制备方法。需要指出的是,类似的附图标记表示类似的结构,本申请中所用的术语“第一”、“第二”、“上”、“下”等等可用于修饰各种器件结构。这些修饰除非特别说明并非暗示所修饰器件结构的空间、次序或层级关系。The features and technical effects of the technical solutions of the present invention are described in detail below with reference to the accompanying drawings and in conjunction with the schematic embodiments, and a resonator and a manufacturing method thereof are disclosed which are beneficial to improve the integration degree and efficiency of the device. It should be noted that similar reference numerals denote similar structures, and the terms "first", "second", "upper", "lower", etc. used in this application may be used to modify various device structures. These modifications do not imply a spatial, sequential, or hierarchical relationship of the modified device structures unless specifically stated.
如图1所示,在衬底1中形成牺牲层2。提供衬底1,材质可以是体Si或绝缘体上硅(SOI)或者体Ge、GeOI以与CMOS工艺兼容并与其他数字、模拟电路集成,也可以是用于MEMS、光电器件、功率器件的化合物半导体例如GaN、GaAs、SiC、InP、GaP等,进一步优选地,衬底1是单晶材料。刻蚀衬底1形成多个空腔(图1中未示出),并沉积牺牲层2填充。刻蚀工艺优选各向异性的干法刻蚀或湿法刻蚀,例如碳 氟基刻蚀气体的反应离子刻蚀,或者TMAH的湿法腐蚀。沉积工艺为LPCVD、APCVD、PECVD等低温工艺(沉积温度低于500摄氏度,优选100至400摄氏度),牺牲层2材质为氧化硅基材料,诸如掺硼氧化硅(BSG)、掺磷氧化硅(PSG)、未掺杂氧化硅(USG)、多孔氧化硅等等,如此可以降低衬底1中残留热应力,并有利于提高后续刻蚀去除的速度以节省时间成本。如图1中所示,牺牲层2至少包括两个部分,也即第一部分2a用于填充主谐振腔,以及第二部分2b用于填充主谐振腔外围的副谐振腔。优选地,采用CMP平坦化工艺处理牺牲层2直至暴露衬底1表面。在本发明一个优选实施例中,刻蚀衬底1形成的空腔的中心部分也即主谐振腔在平视图中的投影为多边形(例如四边形、五边形、六边形、八边形等等)、圆形、椭圆等,而外围部分也即副谐振腔在平视图中的投影为与主谐振腔同心的类似图形,因此在主、副谐振腔之间夹设了环形的一部分衬底1S用作后续的机械支撑或隔离结构,且填充的牺牲层第一部分2a、第二部分2b也因此具有相应的形貌。As shown in FIG. 1 , a sacrificial layer 2 is formed in the substrate 1 . Provide a substrate 1, the material can be bulk Si or silicon-on-insulator (SOI) or bulk Ge, GeOI to be compatible with CMOS process and integrated with other digital and analog circuits, and can also be a compound for MEMS, optoelectronic devices, power devices Semiconductors such as GaN, GaAs, SiC, InP, GaP, etc., further preferably, the substrate 1 is a single crystal material. The substrate 1 is etched to form a plurality of cavities (not shown in FIG. 1 ), and a sacrificial layer 2 is deposited to fill it. The etching process is preferably anisotropic dry etching or wet etching, such as reactive ion etching with a fluorocarbon-based etching gas, or wet etching with TMAH. The deposition process is a low temperature process such as LPCVD, APCVD, PECVD (deposition temperature is lower than 500 degrees Celsius, preferably 100 to 400 degrees Celsius), and the sacrificial layer 2 is made of silicon oxide-based materials, such as boron-doped silicon oxide (BSG), phosphorus-doped silicon oxide ( PSG), undoped silicon oxide (USG), porous silicon oxide, etc., so that the residual thermal stress in the substrate 1 can be reduced, and it is beneficial to improve the speed of subsequent etching and removal to save time and cost. As shown in FIG. 1 , the sacrificial layer 2 includes at least two parts, that is, the first part 2 a is used to fill the main resonant cavity, and the second part 2 b is used to fill the secondary resonant cavity around the main resonant cavity. Preferably, the sacrificial layer 2 is processed by a CMP planarization process until the surface of the substrate 1 is exposed. In a preferred embodiment of the present invention, the central part of the cavity formed by etching the substrate 1, that is, the projection of the main resonant cavity in a plan view is a polygon (such as a quadrilateral, pentagon, hexagon, octagon, etc. etc.), circle, ellipse, etc., and the projection of the peripheral part, that is, the secondary resonant cavity in the plan view, is a similar figure concentric with the main resonant cavity, so a part of the annular substrate is sandwiched between the main and secondary resonant cavity. The 1S is used as a subsequent mechanical support or isolation structure, and the first part 2a and the second part 2b of the filled sacrificial layer also have corresponding morphologies.
如图2所示,在衬底1上形成图形化的下电极3。通过磁控溅射、热蒸发、MOCVD等工艺,形成导电材料层,其材质例如Mo、W、Ru、Al、Cu、Ti、Ta、In、Zn、Zr、Fe、Mg等金属单质或金属合金,或者这些金属的导电氧化物、导电氮化物,以及上述材料的任意组合。优选地,形成导电材料层之前,在衬底1和牺牲层2上进一步形成种子层(未示出)以改善电极层与上方功能层的晶向。在本发明一个优选实施例中,种子层为AlN、HfN、HfAlN、TiN、TaN等,且优选地同时可以用作防止下电极金属材料向下迁移的阻挡层以避免影响谐振腔顶部以及与下方膜层之间的界面状态。随后采用光刻-刻蚀工艺,例如旋涂光刻胶、曝光显影形成光刻胶图形并利用光刻胶图形作为掩模蚀刻导电材料层,以对导电材料层进行图形化,而形成图2所示的下电极3。下电极3至少包括位于中心的第一部分3a,和位于外围的第二部分3b。下电极第一部分3a与牺牲层第一部分2a、主谐振腔相同在平视图中的投影为多边形(例如四边形、五边形、六边形、八边形等等)、圆形、椭圆等,而第二部分3b则是与第一部分3a同心的环形结构,两者之间具有间隙。值得注意的是,为了使得主谐振器和调节用的副谐振器的下电极之间保证足够的绝缘隔离,外围的第二部分3b与中心的第一部分3a之间的间距至少要大于主副谐振腔之间所夹设的衬底支撑结构 1S顶部的宽度。优选地,下电极第一部分3a的边缘从牺牲层第一部分2a边缘向内缩进0.1-10微米、优选0.05-5微米、最佳1-3微米。进一步或类似地,下电极第二部分3b的边缘从牺牲层第二部分2b边缘也向内缩进同样的距离。形成图形化的下电极3之后,湿法腐蚀去除光刻胶图形。As shown in FIG. 2 , a patterned lower electrode 3 is formed on the substrate 1 . Through magnetron sputtering, thermal evaporation, MOCVD and other processes, a conductive material layer is formed, such as Mo, W, Ru, Al, Cu, Ti, Ta, In, Zn, Zr, Fe, Mg and other metal elements or metal alloys , or conductive oxides of these metals, conductive nitrides, and any combination of the above materials. Preferably, before forming the conductive material layer, a seed layer (not shown) is further formed on the substrate 1 and the sacrificial layer 2 to improve the crystal orientation of the electrode layer and the upper functional layer. In a preferred embodiment of the present invention, the seed layer is AlN, HfN, HfAlN, TiN, TaN, etc., and preferably can be used as a barrier layer preventing the downward migration of the lower electrode metal material to avoid affecting the top of the resonant cavity and the bottom The interface state between the film layers. Then, a photolithography-etching process is used, such as spin coating photoresist, exposure and development to form a photoresist pattern, and the photoresist pattern is used as a mask to etch the conductive material layer to pattern the conductive material layer, and form Figure 2 Lower electrode 3 shown. The lower electrode 3 includes at least a first portion 3a at the center, and a second portion 3b at the periphery. The first part 3a of the lower electrode is the same as the first part 2a of the sacrificial layer and the main resonant cavity. The projection in the plan view is a polygon (such as a quadrilateral, a pentagon, a hexagon, an octagon, etc.), a circle, an ellipse, etc., and The second portion 3b is an annular structure concentric with the first portion 3a with a gap therebetween. It is worth noting that, in order to ensure sufficient insulation isolation between the main resonator and the lower electrode of the adjustment sub-resonator, the distance between the second peripheral part 3b and the central first part 3a should be at least greater than that of the main and auxiliary resonators. The width of the top of the substrate support structure IS sandwiched between the cavities. Preferably, the edge of the first portion 3a of the lower electrode is indented inwardly from the edge of the first portion 2a of the sacrificial layer by 0.1-10 microns, preferably 0.05-5 microns, optimally 1-3 microns. Further or similarly, the edge of the second portion 3b of the lower electrode is also retracted inward by the same distance from the edge of the second portion 2b of the sacrificial layer. After the patterned lower electrode 3 is formed, the photoresist pattern is removed by wet etching.
如图3所示,在下电极图形之间填充绝缘层4。例如采用LPCVD、PECVD、旋涂、喷涂、丝网印刷等工艺,将绝缘介电材料填充在下电极层的第一部分3a与第二部分3b之间,从而构成环形的绝缘层图形4。绝缘层4材料与牺牲层2不同,以便在后续去除牺牲层2形成谐振腔的过程中避免被过度侵蚀。在本发明一个优选实施例中,绝缘层4材料为氮化物,诸如氮化硅、氮氧化硅、氮化铝、氮化硼等。优选地,采用回刻或CMP的平坦化工艺处理绝缘层直至暴露下电极图形3a和3b。As shown in FIG. 3, an insulating layer 4 is filled between the lower electrode patterns. For example, using LPCVD, PECVD, spin coating, spray coating, screen printing and other processes, the insulating dielectric material is filled between the first part 3a and the second part 3b of the lower electrode layer to form an annular insulating layer pattern 4 . The material of the insulating layer 4 is different from that of the sacrificial layer 2, so as to avoid excessive erosion during the subsequent process of removing the sacrificial layer 2 to form a resonant cavity. In a preferred embodiment of the present invention, the material of the insulating layer 4 is nitride, such as silicon nitride, silicon oxynitride, aluminum nitride, boron nitride, and the like. Preferably, the insulating layer is processed by a planarization process of etchback or CMP until the lower electrode patterns 3a and 3b are exposed.
如图4所示,在下电极图形3a、3b以及绝缘层4上形成压电层5。例如采用PECVD、UHVCVD、HDPCVD、MOCVD、MBE、ALD、磁控溅射、热蒸发等工艺,形成压电层5,优选地其材质不同于绝缘层4。在本发明一个优选实施例中,压电层5的材料例如ZnO、AlN、BST(钛酸锶钡)、BT(钛酸钡)、PZT(锆钛酸铅)、PBLN(铌酸铅钡锂)、PT(钛酸铅)等压电陶瓷材料,且优选地,压电层5中掺杂稀土元素,例如包含钪(Sc)、钇(Y)、镧(La)、铈(Ce)、镨(Pr)、钕(Nd)、钷(Pm)、钐(Sm)、铕(Eu)、钆(Gd)、铽(Tb)、镝(Dy)、钬(Ho)、铒(Er)、铥(Tm)、镱(Yb)及镥(Lu)的任一种及其组合,以提高压电系数。在本发明一个优选实施例中,压电层5采用Sc掺杂,或Sc与Yb混合掺杂,或Sc与Gd混合掺杂,或者Sc、Yb、Sm混合掺杂。随后,在压电层5上形成上部导电材料层6。导电材料层6的制备工艺和材料与下电极层3相同,在此不再赘述。As shown in FIG. 4 , the piezoelectric layer 5 is formed on the lower electrode patterns 3 a and 3 b and the insulating layer 4 . For example, a process such as PECVD, UHVCVD, HDPCVD, MOCVD, MBE, ALD, magnetron sputtering, thermal evaporation, etc. is used to form the piezoelectric layer 5 , preferably the material of which is different from the insulating layer 4 . In a preferred embodiment of the present invention, the piezoelectric layer 5 is made of materials such as ZnO, AlN, BST (barium strontium titanate), BT (barium titanate), PZT (lead zirconate titanate), PBLN (lead barium lithium niobate) ), PT (lead titanate) and other piezoelectric ceramic materials, and preferably, the piezoelectric layer 5 is doped with rare earth elements, such as scandium (Sc), yttrium (Y), lanthanum (La), cerium (Ce), Praseodymium (Pr), Neodymium (Nd), Promethium (Pm), Samarium (Sm), Europium (Eu), Gadolinium (Gd), Terbium (Tb), Dysprosium (Dy), Holmium (Ho), Erbium (Er), Any one of thulium (Tm), ytterbium (Yb), and lutetium (Lu) and combinations thereof to improve the piezoelectric coefficient. In a preferred embodiment of the present invention, the piezoelectric layer 5 is doped with Sc, or mixed with Sc and Yb, or doped with Sc and Gd, or mixed with Sc, Yb, and Sm. Subsequently, the upper conductive material layer 6 is formed on the piezoelectric layer 5 . The preparation process and materials of the conductive material layer 6 are the same as those of the lower electrode layer 3 , and details are not repeated here.
如图5所示,对导电材料层6进行图形化以形成上电极第一部分6a、上电极第二部分6b。旋涂光刻胶,经过曝光显影工序形成光刻胶图形,以光刻胶图形为掩模蚀刻导电材料层6而形成位于中心的上电极第一部分6a,以及位于外围的环形的上电极第二部分6b。优选地,上电极第一部分6a的边缘与下电极第一部分3a边缘对齐,上电极第二部分6b的边缘与下电极第二部分3b边缘对齐,从而在第一部分6a和第二部分6b之间留下空隙,该空隙与下电极图形3a、3b之间的绝缘层4 对齐。之后,优选湿法腐蚀工艺去除光刻胶图形。As shown in FIG. 5, the conductive material layer 6 is patterned to form an upper electrode first portion 6a and an upper electrode second portion 6b. The photoresist is spin-coated, a photoresist pattern is formed through an exposure and development process, and the conductive material layer 6 is etched with the photoresist pattern as a mask to form a first portion 6a of an upper electrode located in the center, and a second annular upper electrode located in the periphery. Section 6b. Preferably, the edge of the first portion 6a of the upper electrode is aligned with the edge of the first portion 3a of the lower electrode, and the edge of the second portion 6b of the upper electrode is aligned with the edge of the second portion 3b of the lower electrode, so that there is a gap between the first portion 6a and the second portion 6b. A lower void aligned with the insulating layer 4 between the lower electrode patterns 3a, 3b. Afterwards, the photoresist pattern is preferably removed by a wet etching process.
如图6所示,在压电层5和上电极图形6a/6b上形成第二绝缘层7。第二绝缘层7的材质和工艺与绝缘层4相同或相似,在此不再赘述。As shown in FIG. 6, a second insulating layer 7 is formed on the piezoelectric layer 5 and the upper electrode patterns 6a/6b. The material and process of the second insulating layer 7 are the same as or similar to those of the insulating layer 4 , and details are not repeated here.
如图7所示,去除牺牲层图形2,在衬底1中留下谐振腔。通过设置在器件外围的释放孔(未示出),施加湿法腐蚀剂去除牺牲层图形。针对氧化硅基材料,采用HF基腐蚀液例如dHF(稀释HF)、dBOE(缓释刻蚀剂,HF与NH 4F的混合物)去除牺牲层图形2,留下多个谐振腔,谐振腔至少包括位于中心的第一部分1c,以及位于外围的环形的第二部分1c’。如前所示,绝缘层4的宽度大于支撑结构1S顶部宽度,下电极第一部分3a、第二部分3b的宽度小于牺牲层图形2a和2b,因此留下的主谐振腔1c宽度大于下电极第一部分3a,副谐振腔1c’宽度大于下电极第二部分3b。 As shown in FIG. 7 , the sacrificial layer pattern 2 is removed, leaving a resonant cavity in the substrate 1 . A wet etchant is applied to remove the sacrificial layer pattern through release holes (not shown) provided at the periphery of the device. For silicon oxide-based materials, use an HF-based etching solution such as dHF (diluted HF), dBOE (slow release etchant, a mixture of HF and NH 4 F) to remove the sacrificial layer pattern 2, leaving multiple resonant cavities with at least It comprises a first portion 1c in the center, and a second portion 1c' in an annular shape in the periphery. As shown before, the width of the insulating layer 4 is larger than the width of the top of the support structure 1S, and the width of the first part 3a and the second part 3b of the lower electrode is smaller than that of the sacrificial layer patterns 2a and 2b, so the width of the main resonant cavity 1c left is larger than that of the first part 3a and the second part 3b of the lower electrode. In a portion 3a, the width of the sub-resonant cavity 1c' is larger than that of the second portion 3b of the lower electrode.
如图8所示,采用回刻、CMP等平坦化工艺处理第二绝缘层7,直至暴露上电极图形6a、6b。最终形成的谐振器结构如图8所示,包括衬底1,位于衬底1中的谐振腔第一部分1c、谐振腔第二部分1c’,谐振腔第一部分1c上方的下电极第一部分3a、压电层5、上电极第一部分6a构成了主谐振器,而谐振腔第二部分1c’上方的下电极第二部分3b、压电层5、上电极第二部分6b构成了副谐振器。上电极6a/6b以及第二绝缘层7的分布形貌如图10中所示,与下电极3a/3b以及绝缘层图形4相同或共形、类似,均为同心的多边形或圆形、椭圆形结构,也即上电极中心部分也即第一部分6a与外围的第二部分6b之间夹设了第二绝缘层7,且第二部分6b存在至少一个缺口,以容纳第一部分6a的引出部分在第二绝缘层7包裹之下穿出而实现对外电连接。在器件工作过程中,通过向副谐振器的电极(3b、6b)施加与主谐振器不同的信号,例如振幅、频率、相位的至少一个不同,使得主谐振器外围的副谐振器产生与主谐振器不同的振动,两个状态不同的机械波叠加,从而改变最终的信号波形。如此,可以实时地通过控制副谐振器的输入波形而灵活地改变副谐振器的振动状态,进而影响整个谐振器的工作状态,以在需要的时候调节整个谐振器系统的频率响应,有利于节省芯片面积、提高集成度、降低产品成本、提高器件的利用率。As shown in FIG. 8 , the second insulating layer 7 is processed by a planarization process such as etchback, CMP, etc., until the upper electrode patterns 6a and 6b are exposed. The finally formed resonator structure is shown in FIG. 8 and includes a substrate 1, a first part 1c of the resonator cavity, a second part 1c' of the resonator cavity located in the substrate 1, a first part 3a of the lower electrode above the first part 1c of the resonator cavity, The piezoelectric layer 5 and the first part 6a of the upper electrode constitute the main resonator, and the second part 3b of the lower electrode, the piezoelectric layer 5, and the second part 6b of the upper electrode above the second part 1c' of the resonant cavity constitute the sub-resonator. The distribution morphology of the upper electrodes 6a/6b and the second insulating layer 7 is shown in FIG. 10, which is the same as or conformal or similar to the lower electrodes 3a/3b and the insulating layer pattern 4, and both are concentric polygons or circles, ellipses The second insulating layer 7 is sandwiched between the central part of the upper electrode, that is, the first part 6a and the peripheral second part 6b, and the second part 6b has at least one gap to accommodate the lead-out part of the first part 6a. Pass through the second insulating layer 7 under wrapping to realize external electrical connection. During the operation of the device, by applying a signal different from that of the main resonator to the electrodes (3b, 6b) of the sub-resonator, for example, at least one of amplitude, frequency, and phase is different, so that the sub-resonator around the main resonator generates a different signal from the main resonator. The different vibrations of the resonator and the superposition of two mechanical waves with different states change the final signal waveform. In this way, the vibration state of the sub-resonator can be flexibly changed in real time by controlling the input waveform of the sub-resonator, thereby affecting the working state of the entire resonator, so as to adjust the frequency response of the entire resonator system when needed, which is conducive to saving Chip area, improve integration, reduce product cost, and improve device utilization.
在本发明的另一优选实施例中,如图9所示,压电层5不再是相连成为一个整体,而是由第二绝缘层7贯穿直达衬底1表面的支撑结构 1S,由此提高主谐振器与副谐振器的电极之间的绝缘隔离效果,防止信号在不同谐振器的上下电极之间横向串扰。其制造工艺与图1至图8所示的基本相同,区别在于图5所示的工艺步骤之中,刻蚀图形化上电极6a、6b之后,进一步以光刻胶图形或上电极图形为掩模,继续刻蚀压电层5直至暴露衬底1表面的支撑结构1S,并在图6所示的工艺步骤之中,采用台阶覆盖良好的PECVD、HDPCVD、磁控溅射等工艺填充第二绝缘层7。最终产生的器件结构与图8所示类似,区别在于第二绝缘层7不仅夹设在上电极第一部分6a和第二部分6b之间,还贯穿压电层5直达衬底表面,并夹设在下电极第一部分3a和第二部分3b之间。In another preferred embodiment of the present invention, as shown in FIG. 9 , the piezoelectric layers 5 are no longer connected as a whole, but the second insulating layer 7 penetrates through the support structure 1S directly on the surface of the substrate 1, thereby The insulation isolation effect between the electrodes of the main resonator and the sub-resonator is improved, and the lateral crosstalk of signals between the upper and lower electrodes of different resonators is prevented. The manufacturing process is basically the same as that shown in FIG. 1 to FIG. 8, except that in the process steps shown in FIG. 5, after etching and patterning the upper electrodes 6a and 6b, the photoresist pattern or the upper electrode pattern is used as a mask. mold, continue to etch the piezoelectric layer 5 until the support structure 1S on the surface of the substrate 1 is exposed, and in the process steps shown in FIG. insulating layer 7. The resulting device structure is similar to that shown in FIG. 8, the difference is that the second insulating layer 7 is not only sandwiched between the first part 6a and the second part 6b of the upper electrode, but also penetrates the piezoelectric layer 5 to the surface of the substrate, and is sandwiched therebetween. between the first part 3a and the second part 3b of the lower electrode.
依照本发明的可调式谐振器及其制造方法,在主谐振器外围增设副谐振器以主动地调节谐振状态,有利于提高器件集成度和效率。According to the tunable resonator and the manufacturing method thereof of the present invention, the auxiliary resonator is added around the main resonator to actively adjust the resonance state, which is beneficial to improve the integration degree and efficiency of the device.
尽管已参照一个或多个示例性实施例说明本发明,本领域技术人员可以知晓无需脱离本发明范围而对器件结构做出各种合适的改变和等价方式。此外,由所公开的教导可做出许多可能适于特定情形或材料的修改而不脱离本发明范围。因此,本发明的目的不在于限定在作为用于实现本发明的最佳实施方式而公开的特定实施例,而所公开的器件结构及其制造方法将包括落入本发明范围内的所有实施例。Although the invention has been described with reference to one or more exemplary embodiments, those skilled in the art will recognize various suitable changes and equivalents in device structure without departing from the scope of the invention. In addition, many modifications, as may be adapted to a particular situation or material, may be made from the disclosed teachings without departing from the scope of the invention. Therefore, the present invention is not intended to be limited to the particular embodiments disclosed as the best mode for carrying out the present invention, and the disclosed device structures and methods of making the same are to include all embodiments that fall within the scope of the present invention .

Claims (10)

  1. 一种可调式谐振器,包括:A tunable resonator comprising:
    谐振腔,在衬底中,至少包括中心的第一谐振腔和外围的第二谐振腔;The resonant cavity, in the substrate, at least includes a first resonant cavity in the center and a second resonant cavity in the periphery;
    第一堆叠结构,在第一谐振腔上,依次包括下电极第一部分、压电层第一部分和上电极第一部分;The first stack structure, on the first resonant cavity, sequentially includes a first part of the lower electrode, a first part of the piezoelectric layer and a first part of the upper electrode;
    第二堆叠结构,在第二谐振腔上,依次包括下电极第二部分、压电层第二部分和上电极第二部分;The second stack structure, on the second resonant cavity, sequentially includes a second part of the lower electrode, a second part of the piezoelectric layer and a second part of the upper electrode;
    第一绝缘层,在衬底上,位于下电极第一部分和下电极第二部分之间。A first insulating layer, on the substrate, is located between the first portion of the lower electrode and the second portion of the lower electrode.
    所述外围的第二谐振腔环绕第一谐振腔设置。The peripheral second resonant cavity is arranged around the first resonant cavity.
  2. 根据权利要求1的谐振器,进一步包括第二绝缘层,在压电层第一部分和压电层第二部分上,位于上电极第一部分和上电极第二部分之间;优选地,压电层第一部分和压电层第二部分连接,或者由第二绝缘层间隔开。The resonator of claim 1, further comprising a second insulating layer, on the piezoelectric layer first portion and the piezoelectric layer second portion, between the upper electrode first portion and the upper electrode second portion; preferably, the piezoelectric layer The first portion and the second portion of the piezoelectric layer are connected or separated by a second insulating layer.
  3. 根据权利要求1的可调式谐振器,其中,第一谐振腔、下电极第一部分、上电极第一部分在平视图中为多边形、圆形或椭圆形;优选地,第一谐振腔顶部尺寸大于下电极第一部分或上电极第一部分的尺寸,任选地,第二谐振腔顶部尺寸大于下电极第二部分或上电极第二部分的尺寸;优选地,下电极第一部分和上电极第一部分边缘对齐,下电极第二部分和上电极第二部分边缘对齐。The tunable resonator according to claim 1, wherein the first resonant cavity, the first part of the lower electrode and the first part of the upper electrode are polygonal, circular or elliptical in plan view; preferably, the size of the top of the first resonant cavity is larger than that of the lower electrode The size of the first part of the electrode or the first part of the upper electrode, optionally, the size of the top of the second resonant cavity is larger than the size of the second part of the lower electrode or the second part of the upper electrode; preferably, the first part of the lower electrode and the first part of the upper electrode are edge-aligned , the edges of the second part of the lower electrode and the second part of the upper electrode are aligned.
  4. 根据权利要求1的可调式谐振器,其中,向第二堆叠结构施加与第一堆叠结构不同的信号以调节谐振器的谐振状态,所述谐振状态包括振幅、频率、相位的至少一个或其组合。The tunable resonator of claim 1, wherein a different signal is applied to the second stack structure than the first stack structure to adjust a resonance state of the resonator, the resonance state comprising at least one of amplitude, frequency, phase, or a combination thereof .
  5. 根据权利要求1至4任一项的可调式谐振器,其中,衬底材料为Si、SOI、Ge、GeOI、化合物半导体;任选地,压电层第一部分、压电层第二部分的材料为ZnO、AlN、BST(钛酸锶钡)、BT(钛酸钡)、PZT(锆钛酸铅)、PBLN(铌酸铅钡锂)、PT(钛酸铅),进一步优选地压电材料中掺杂稀土元素;任选地,第一或第二绝缘层的材料为氮化物,诸如氮化硅、氮氧化硅、氮化铝、氮化硼;任选地,下电极第一部分、下电极第二部分、上电极第一部分、上电极第二部分的任 一个的材料为选自Mo、W、Ru、Al、Cu、Ti、Ta、In、Zn、Zr、Fe、Mg的金属单质或金属合金、或者这些金属的导电氧化物、或导电氮化物,以及上述材料的任意组合。The tunable resonator according to any one of claims 1 to 4, wherein the substrate material is Si, SOI, Ge, GeOI, compound semiconductor; optionally, the material of the first part of the piezoelectric layer and the second part of the piezoelectric layer is ZnO, AlN, BST (barium strontium titanate), BT (barium titanate), PZT (lead zirconate titanate), PBLN (lead barium lithium niobate), PT (lead titanate), further preferably piezoelectric materials doped with rare earth elements; optionally, the material of the first or second insulating layer is nitride, such as silicon nitride, silicon oxynitride, aluminum nitride, boron nitride; optionally, the first part of the lower electrode, the lower The material of any one of the second part of the electrode, the first part of the upper electrode, and the second part of the upper electrode is a metal element selected from Mo, W, Ru, Al, Cu, Ti, Ta, In, Zn, Zr, Fe, Mg or Metal alloys, or conductive oxides of these metals, or conductive nitrides, and any combination of the foregoing.
  6. 一种可调式谐振器制造方法,包括:A method for manufacturing a tunable resonator, comprising:
    在衬底中形成牺牲层,包括中心的第一牺牲层图形和外围的第二牺牲层图形;forming a sacrificial layer in the substrate, including a first sacrificial layer pattern in the center and a second sacrificial layer pattern in the periphery;
    在牺牲层上形成下电极层,包括在第一牺牲层图形上的下电极第一部分、和在第二牺牲层图形上的下电极第二部分;forming a lower electrode layer on the sacrificial layer, including a first part of the lower electrode on the first sacrificial layer pattern and a second part of the lower electrode on the second sacrificial layer pattern;
    在下电极第一部分和下电极第二部分之间形成第一绝缘层;forming a first insulating layer between the first part of the lower electrode and the second part of the lower electrode;
    在第一绝缘层和下电极层上形成压电层,至少包括在第一牺牲层图形之上的压电层第一部分、和在第二牺牲层图形之上的压电层第二部分;forming a piezoelectric layer on the first insulating layer and the lower electrode layer, including at least a first part of the piezoelectric layer above the first sacrificial layer pattern and a second part of the piezoelectric layer above the second sacrificial layer pattern;
    在压电层上形成上电极层,包括在压电层第一部分上的上电极第一部分、和在压电层第二部分上的上电极第二部分;forming an upper electrode layer on the piezoelectric layer, including a first part of the upper electrode on the first part of the piezoelectric layer, and a second part of the upper electrode on the second part of the piezoelectric layer;
    去除牺牲层,在衬底中留下谐振腔,包括中心的第一谐振腔和外围的第二谐振腔;所述外围的第二谐振腔环绕第一谐振腔设置。The sacrificial layer is removed to leave a resonant cavity in the substrate, including a first resonant cavity in the center and a second resonant cavity in the periphery; the second resonant cavity in the periphery is arranged around the first resonant cavity.
  7. 根据权利要求6的可调式谐振器制造方法,形成上电极层之后进一步包括,至少在上电极第一部分和上电极第二部分之间形成第二绝缘层;优选地,压电层第一部分和压电层第二部分连接,或者由第二绝缘层间隔开。The method for manufacturing a tunable resonator according to claim 6, further comprising, after forming the upper electrode layer, forming a second insulating layer between at least the first part of the upper electrode and the second part of the upper electrode; preferably, the first part of the piezoelectric layer and the pressure A second portion of the electrical layer is connected or separated by a second insulating layer.
  8. 根据权利要求6的可调式谐振器制造方法,其中,第一谐振腔、下电极第一部分、上电极第一部分在平视图中为多边形、圆形或椭圆形;优选地,第一谐振腔顶部尺寸大于下电极第一部分或上电极第一部分的尺寸,任选地,第二谐振腔顶部尺寸大于下电极第二部分或上电极第二部分的尺寸;优选地,下电极第一部分和上电极第一部分边缘对齐,下电极第二部分和上电极第二部分边缘对齐。The method for manufacturing a tunable resonator according to claim 6, wherein the first resonant cavity, the first part of the lower electrode, and the first part of the upper electrode are polygonal, circular or elliptical in plan view; preferably, the size of the top of the first resonant cavity is larger than the size of the first part of the lower electrode or the first part of the upper electrode, optionally, the size of the top of the second resonant cavity is larger than the size of the second part of the lower electrode or the second part of the upper electrode; preferably, the first part of the lower electrode and the first part of the upper electrode The edges are aligned, and the second part of the lower electrode and the second part of the upper electrode are edge-aligned.
  9. 根据权利要求6的可调式谐振器制造方法,其中,衬底材料为Si、SOI、Ge、GeOI、化合物半导体;任选地,压电层第一部分、压电层第二部分的材料为ZnO、AlN、BST(钛酸锶钡)、BT(钛酸钡)、PZT(锆钛酸铅)、PBLN(铌酸铅钡锂)、PT(钛酸铅),进一步优选地压电材料中掺杂稀土元素;任选地,第一或第二绝缘层的材料为氮化物,诸如氮化硅、氮氧化硅、氮化铝、氮化硼;任选地,下电极 第一部分、下电极第二部分、上电极第一部分、上电极第二部分的任一个的材料为选自Mo、W、Ru、Al、Cu、Ti、Ta、In、Zn、Zr、Fe、Mg的金属单质或金属合金、或者这些金属的导电氧化物、或导电氮化物,以及上述材料的任意组合;任选地,牺牲层材料为氧化物,诸如掺硼氧化硅(BSG)、掺磷氧化硅(PSG)、未掺杂氧化硅(USG)、多孔氧化硅。The method for manufacturing a tunable resonator according to claim 6, wherein the substrate material is Si, SOI, Ge, GeOI, compound semiconductor; optionally, the materials of the first part of the piezoelectric layer and the second part of the piezoelectric layer are ZnO, AlN, BST (barium strontium titanate), BT (barium titanate), PZT (lead zirconate titanate), PBLN (lead barium lithium niobate), PT (lead titanate), further preferably doped in the piezoelectric material rare earth element; optionally, the material of the first or second insulating layer is nitride, such as silicon nitride, silicon oxynitride, aluminum nitride, boron nitride; optionally, the first part of the lower electrode, the second lower electrode The material of any one of the part, the first part of the upper electrode, and the second part of the upper electrode is a metal element or metal alloy selected from Mo, W, Ru, Al, Cu, Ti, Ta, In, Zn, Zr, Fe, Mg, Or conductive oxides of these metals, or conductive nitrides, and any combination of the above; optionally, the sacrificial layer material is an oxide, such as boron-doped silicon oxide (BSG), phosphorus-doped silicon oxide (PSG), undoped silicon oxide Heterosilica (USG), porous silica.
  10. 根据权利要求7的可调式谐振器制造方法,形成上电极层之后、去除牺牲层之前进一步包括,在上电极第一部分和上电极第二部分之间刻蚀压电层形成暴露衬底的开口,在上电极层上以及开口的底部和侧壁上形成第二绝缘层。The method for manufacturing a tunable resonator according to claim 7, further comprising, after forming the upper electrode layer and before removing the sacrificial layer, etching the piezoelectric layer between the first portion of the upper electrode and the second portion of the upper electrode to form an opening for exposing the substrate, A second insulating layer is formed on the upper electrode layer and on the bottom and sidewalls of the opening.
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