WO2022007133A1 - Preparation method for quinoa low gi ingredient - Google Patents
Preparation method for quinoa low gi ingredient Download PDFInfo
- Publication number
- WO2022007133A1 WO2022007133A1 PCT/CN2020/109944 CN2020109944W WO2022007133A1 WO 2022007133 A1 WO2022007133 A1 WO 2022007133A1 CN 2020109944 W CN2020109944 W CN 2020109944W WO 2022007133 A1 WO2022007133 A1 WO 2022007133A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- quinoa
- emulsifier
- cellulase
- low
- pulverization
- Prior art date
Links
- 240000006162 Chenopodium quinoa Species 0.000 title claims abstract description 125
- 239000004615 ingredient Substances 0.000 title claims abstract description 41
- 238000002360 preparation method Methods 0.000 title abstract description 9
- 238000000034 method Methods 0.000 claims abstract description 49
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 41
- 108010059892 Cellulase Proteins 0.000 claims abstract description 38
- 229940106157 cellulase Drugs 0.000 claims abstract description 38
- 238000001125 extrusion Methods 0.000 claims abstract description 26
- 238000002156 mixing Methods 0.000 claims abstract description 20
- 235000013339 cereals Nutrition 0.000 claims abstract description 18
- 239000002994 raw material Substances 0.000 claims abstract description 9
- 235000007319 Avena orientalis Nutrition 0.000 claims abstract description 3
- 244000075850 Avena orientalis Species 0.000 claims abstract description 3
- 240000007594 Oryza sativa Species 0.000 claims abstract description 3
- 235000007164 Oryza sativa Nutrition 0.000 claims abstract description 3
- 241000209140 Triticum Species 0.000 claims abstract description 3
- 235000021307 Triticum Nutrition 0.000 claims abstract description 3
- 240000008042 Zea mays Species 0.000 claims abstract description 3
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 claims abstract description 3
- 235000002017 Zea mays subsp mays Nutrition 0.000 claims abstract description 3
- 235000005822 corn Nutrition 0.000 claims abstract description 3
- 235000009566 rice Nutrition 0.000 claims abstract description 3
- 239000000843 powder Substances 0.000 claims description 31
- 238000010298 pulverizing process Methods 0.000 claims description 31
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 26
- 239000000203 mixture Substances 0.000 claims description 16
- 238000005496 tempering Methods 0.000 claims description 11
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical group CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 claims description 10
- 235000013312 flour Nutrition 0.000 claims description 10
- 230000005070 ripening Effects 0.000 claims description 9
- 238000001035 drying Methods 0.000 claims description 8
- 239000002245 particle Substances 0.000 claims description 8
- 239000002253 acid Substances 0.000 claims description 6
- 125000005456 glyceride group Chemical group 0.000 claims description 6
- 235000019658 bitter taste Nutrition 0.000 claims description 5
- 239000005417 food ingredient Substances 0.000 claims description 5
- YQEMORVAKMFKLG-UHFFFAOYSA-N glycerine monostearate Natural products CCCCCCCCCCCCCCCCCC(=O)OC(CO)CO YQEMORVAKMFKLG-UHFFFAOYSA-N 0.000 claims description 5
- SVUQHVRAGMNPLW-UHFFFAOYSA-N glycerol monostearate Natural products CCCCCCCCCCCCCCCCC(=O)OCC(O)CO SVUQHVRAGMNPLW-UHFFFAOYSA-N 0.000 claims description 5
- 235000019606 astringent taste Nutrition 0.000 claims description 4
- 235000012041 food component Nutrition 0.000 claims description 4
- 150000001875 compounds Chemical class 0.000 claims description 3
- 239000000969 carrier Substances 0.000 claims description 2
- 239000000546 pharmaceutical excipient Substances 0.000 claims description 2
- 238000007602 hot air drying Methods 0.000 claims 1
- 230000002641 glycemic effect Effects 0.000 abstract description 15
- 229920000294 Resistant starch Polymers 0.000 abstract description 7
- 235000021254 resistant starch Nutrition 0.000 abstract description 7
- 230000003750 conditioning effect Effects 0.000 abstract description 2
- 230000001143 conditioned effect Effects 0.000 abstract 1
- 229920002472 Starch Polymers 0.000 description 29
- 235000019698 starch Nutrition 0.000 description 29
- 239000008107 starch Substances 0.000 description 29
- 235000013325 dietary fiber Nutrition 0.000 description 14
- 230000000052 comparative effect Effects 0.000 description 13
- 239000000523 sample Substances 0.000 description 12
- 239000000243 solution Substances 0.000 description 12
- 102000004190 Enzymes Human genes 0.000 description 11
- 108090000790 Enzymes Proteins 0.000 description 11
- 229940088598 enzyme Drugs 0.000 description 11
- 229930182490 saponin Natural products 0.000 description 9
- 150000007949 saponins Chemical class 0.000 description 9
- 235000017709 saponins Nutrition 0.000 description 9
- 230000007062 hydrolysis Effects 0.000 description 8
- 238000006460 hydrolysis reaction Methods 0.000 description 8
- 238000013268 sustained release Methods 0.000 description 7
- 239000012730 sustained-release form Substances 0.000 description 7
- 239000008103 glucose Substances 0.000 description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 5
- 229910052782 aluminium Inorganic materials 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 239000011888 foil Substances 0.000 description 5
- 239000003814 drug Substances 0.000 description 4
- 229940079593 drug Drugs 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- 238000005406 washing Methods 0.000 description 4
- MEAPRSDUXBHXGD-UHFFFAOYSA-N 3-chloro-n-(4-propan-2-ylphenyl)propanamide Chemical compound CC(C)C1=CC=C(NC(=O)CCCl)C=C1 MEAPRSDUXBHXGD-UHFFFAOYSA-N 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 239000008280 blood Substances 0.000 description 3
- 210000004369 blood Anatomy 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 235000005911 diet Nutrition 0.000 description 3
- 230000000378 dietary effect Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 230000007071 enzymatic hydrolysis Effects 0.000 description 3
- 238000006047 enzymatic hydrolysis reaction Methods 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 229960004604 propranolol hydrochloride Drugs 0.000 description 3
- AQHHHDLHHXJYJD-UHFFFAOYSA-N propranolol hydrochloride Natural products C1=CC=C2C(OCC(O)CNC(C)C)=CC=CC2=C1 AQHHHDLHHXJYJD-UHFFFAOYSA-N 0.000 description 3
- 239000006228 supernatant Substances 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 239000005909 Kieselgur Substances 0.000 description 2
- 102000057297 Pepsin A Human genes 0.000 description 2
- 108090000284 Pepsin A Proteins 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 238000004364 calculation method Methods 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000010668 complexation reaction Methods 0.000 description 2
- 206010012601 diabetes mellitus Diseases 0.000 description 2
- 235000013376 functional food Nutrition 0.000 description 2
- 229940111202 pepsin Drugs 0.000 description 2
- 230000035790 physiological processes and functions Effects 0.000 description 2
- 239000001397 quillaja saponaria molina bark Substances 0.000 description 2
- 235000012794 white bread Nutrition 0.000 description 2
- 108010073178 Glucan 1,4-alpha-Glucosidase Proteins 0.000 description 1
- 239000004366 Glucose oxidase Substances 0.000 description 1
- 108010015776 Glucose oxidase Proteins 0.000 description 1
- 229920002907 Guar gum Polymers 0.000 description 1
- 102000001746 Pancreatic alpha-Amylases Human genes 0.000 description 1
- 108010029785 Pancreatic alpha-Amylases Proteins 0.000 description 1
- 108010019160 Pancreatin Proteins 0.000 description 1
- 108091005804 Peptidases Proteins 0.000 description 1
- 239000004365 Protease Substances 0.000 description 1
- 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 description 1
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 1
- 239000007983 Tris buffer Substances 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 102000004139 alpha-Amylases Human genes 0.000 description 1
- 108090000637 alpha-Amylases Proteins 0.000 description 1
- 229940024171 alpha-amylase Drugs 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000012496 blank sample Substances 0.000 description 1
- 230000037396 body weight Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 230000000536 complexating effect Effects 0.000 description 1
- 230000001276 controlling effect Effects 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000001186 cumulative effect Effects 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 230000029087 digestion Effects 0.000 description 1
- 230000001079 digestive effect Effects 0.000 description 1
- 238000007907 direct compression Methods 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 235000020776 essential amino acid Nutrition 0.000 description 1
- 239000003797 essential amino acid Substances 0.000 description 1
- 235000012438 extruded product Nutrition 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- 210000004051 gastric juice Anatomy 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229940116332 glucose oxidase Drugs 0.000 description 1
- 235000019420 glucose oxidase Nutrition 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 239000000665 guar gum Substances 0.000 description 1
- 229960002154 guar gum Drugs 0.000 description 1
- 235000010417 guar gum Nutrition 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 230000007413 intestinal health Effects 0.000 description 1
- 210000000936 intestine Anatomy 0.000 description 1
- 235000015110 jellies Nutrition 0.000 description 1
- 239000008274 jelly Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000035800 maturation Effects 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- 235000016709 nutrition Nutrition 0.000 description 1
- 235000008935 nutritious Nutrition 0.000 description 1
- 229920000620 organic polymer Polymers 0.000 description 1
- 229940055695 pancreatin Drugs 0.000 description 1
- 229940124531 pharmaceutical excipient Drugs 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000002133 sample digestion Methods 0.000 description 1
- 239000001632 sodium acetate Substances 0.000 description 1
- 235000017281 sodium acetate Nutrition 0.000 description 1
- 239000007974 sodium acetate buffer Substances 0.000 description 1
- BHZOKUMUHVTPBX-UHFFFAOYSA-M sodium acetic acid acetate Chemical compound [Na+].CC(O)=O.CC([O-])=O BHZOKUMUHVTPBX-UHFFFAOYSA-M 0.000 description 1
- 210000002784 stomach Anatomy 0.000 description 1
- 238000000967 suction filtration Methods 0.000 description 1
- 239000007939 sustained release tablet Substances 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 235000019640 taste Nutrition 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 208000001072 type 2 diabetes mellitus Diseases 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L7/00—Cereal-derived products; Malt products; Preparation or treatment thereof
- A23L7/10—Cereal-derived products
- A23L7/104—Fermentation of farinaceous cereal or cereal material; Addition of enzymes or microorganisms
- A23L7/107—Addition or treatment with enzymes not combined with fermentation with microorganisms
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L29/00—Foods or foodstuffs containing additives; Preparation or treatment thereof
- A23L29/10—Foods or foodstuffs containing additives; Preparation or treatment thereof containing emulsifiers
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L33/00—Modifying nutritive qualities of foods; Dietetic products; Preparation or treatment thereof
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L5/00—Preparation or treatment of foods or foodstuffs, in general; Food or foodstuffs obtained thereby; Materials therefor
- A23L5/20—Removal of unwanted matter, e.g. deodorisation or detoxification
- A23L5/21—Removal of unwanted matter, e.g. deodorisation or detoxification by heating without chemical treatment, e.g. steam treatment, cooking
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K47/00—Medicinal preparations characterised by the non-active ingredients used, e.g. carriers or inert additives; Targeting or modifying agents chemically bound to the active ingredient
- A61K47/46—Ingredients of undetermined constitution or reaction products thereof, e.g. skin, bone, milk, cotton fibre, eggshell, oxgall or plant extracts
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23V—INDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
- A23V2002/00—Food compositions, function of food ingredients or processes for food or foodstuffs
Abstract
Disclosed is a preparation method for a quinoa low-GI ingredient and an ingredient obtained from the method. In the method, quinoa is used as a raw material. A low GI ingredient with a resistant starch content of 70% and a glycemic index below 45 is obtained by means of steps comprising: preheating quinoa by baking, adding an emulsifier and cellulase thereto, mixing, conditioning and extruding the same, etc. Also disclosed is a method for reducing the GI value of extruded grains. Before extrusion processing, the grains are conditioned by means of adding an emulsifier and cellulase to reduce the GI value of the extruded grains. The grains comprise rice, wheat, oats, quinoa or corn.
Description
本发明涉及一种藜麦质低GI配料的制备方法,应用于药物缓释载体和功能食品配料工业,属于有机高分子化合物制备或加工技术领域。The invention relates to a preparation method of a quinoa low-GI ingredient, which is applied to the pharmaceutical sustained-release carrier and functional food ingredient industry, and belongs to the technical field of organic polymer compound preparation or processing.
藜麦是一种全营养谷物,蛋白质含量可达16%~22%,含有9种人体必需氨基酸,而且氨基酸组成均衡。虽然藜麦营养价值高,但其用于生产加工过程,种子外皮存在的皂苷会产生苦涩味,影响人们食用藜麦的口感和安全性。传统除皂苷方法多采用洗涤冲泡,但与此同时会导致藜麦中营养成分流失。皂苷新型脱除方法的建立为藜麦质低GI配料在医药辅料、食品配料中的应用提供更多可能。Quinoa is a whole nutritious grain, with protein content of 16% to 22%, containing 9 kinds of essential amino acids, and the amino acid composition is balanced. Although quinoa has high nutritional value, when it is used in production and processing, the saponins present in the outer skin of the seeds will produce a bitter and astringent taste, which affects the taste and safety of quinoa. Traditional saponin removal methods mostly use washing and brewing, but at the same time, it will lead to the loss of nutrients in quinoa. The establishment of a new saponin removal method provides more possibilities for the application of quinoa low GI ingredients in pharmaceutical excipients and food ingredients.
藜麦作为一种低GI原料,主要是由于其淀粉中抗消化淀粉(慢消化淀粉和抗性淀粉)含量较高,但藜麦淀粉耐热性差,在加工过程中淀粉颗粒易受热(60-70℃)发生溶胀、破裂,导致其可消化淀粉含量增加,淀粉水解速率加快,从而丧失其低GI特性。基于淀粉-脂质络合体耐酶解的特点,通常采用乳化剂与淀粉络合形成VII-型晶体,提高其淀粉耐热稳定性,但该络合过程通常采用酒精碱法,产生大量工业废水。因此,亟需寻找新技术降低藜麦加工过程中GI特性的损失,对调节人体血糖水平有着非常重要的作用。As a low GI raw material, quinoa is mainly due to the high content of resistant starch (slowly digestible starch and resistant starch) in its starch, but quinoa starch has poor heat resistance, and starch granules are easily heated during processing (60- 70 °C), swelling and rupture occurred, resulting in an increase in the content of digestible starch and an accelerated hydrolysis rate of starch, thereby losing its low GI properties. Based on the characteristics of starch-lipid complexes that are resistant to enzymatic hydrolysis, emulsifiers are usually complexed with starch to form VII-type crystals to improve the heat-resistant stability of starch. waste water. Therefore, it is urgent to find new technologies to reduce the loss of GI properties during the processing of quinoa, which has a very important role in regulating human blood sugar levels.
发明内容SUMMARY OF THE INVENTION
为了解决上述问题,本发明提供了一种藜麦质低GI配料的制备方法,通过将藜麦焙烤后粉碎,与乳化剂混合调质,经加酶挤压制备藜麦质低GI配料。本发明利用皂苷对热不稳定的特性,采用高温焙烤分解皂苷,替代传统的洗涤冲泡法,去除表皮皂苷带来的苦味和潜在安全性,同时对藜麦进行预熟化。进一步地,与乳化剂、纤维素酶混合后进行挤压,不仅利用挤压技术为乳化剂与淀粉提供络合环境,提高乳化剂与藜麦淀粉的络合率,增强藜麦淀粉的耐热稳定性和耐酶解特性,而且挤压同时添加纤维素酶有效提高了藜麦中可溶性膳食纤维含量,两者相互作用,共同降低挤压物的GI值,从而实现藜麦质低GI配料的高效制备。In order to solve the above problems, the present invention provides a preparation method of quinoa low GI ingredients. The quinoa low GI ingredients are prepared by adding enzymes and extruding by pulverizing quinoa after roasting, mixing and tempering with an emulsifier, and adding enzymes. The present invention utilizes the thermal instability property of saponins, adopts high-temperature baking to decompose saponins, replaces the traditional washing and brewing method, removes the bitterness and potential safety brought by epidermal saponins, and pre-ripens quinoa at the same time. Further, it is mixed with emulsifier and cellulase and extruded, which not only uses extrusion technology to provide complex environment for emulsifier and starch, but also improves the complexation rate of emulsifier and quinoa starch, and enhances the heat resistance of quinoa starch. Stability and resistance to enzymatic hydrolysis, and the addition of cellulase at the same time of extrusion effectively increases the content of soluble dietary fiber in quinoa. The interaction of the two reduces the GI value of the extruded product, thereby realizing the quinoa low GI ingredient. Efficient preparation.
本发明披露了一种制备藜麦质低GI配料的方法,以藜麦为原料,通过焙烤预熟化,再添加乳化剂和纤维素酶混合调质,最后经挤压得到藜麦质低GI配料。The invention discloses a method for preparing quinoa low-GI ingredients. The quinoa is used as a raw material, pre-cured by baking, then mixed with an emulsifier and cellulase for conditioning, and finally extruded to obtain quinoa low-GI ingredients .
在本发明一种实施方式中,所述方法包括以下步骤:In one embodiment of the present invention, the method includes the following steps:
(1)烘焙处理:将藜麦进行焙烤处理;(1) Baking treatment: the quinoa is subjected to baking treatment;
(2)粉碎:将步骤(1)所得藜麦进行粉碎,备用;(2) pulverizing: pulverizing the quinoa obtained in step (1), for subsequent use;
(3)混合调质:将步骤(2)所得藜麦粉中添加乳化剂和纤维素酶,混合均匀,加水调配;(3) mixing and tempering: adding emulsifier and cellulase to the quinoa powder obtained in step (2), mixing evenly, and adding water to prepare;
(4)挤压:将步骤(3)所得混合料于螺杆挤压机中挤压加工;(4) extrusion: the compound obtained in step (3) is extruded and processed in a screw extruder;
(5)干燥粉碎:将得到的挤压物干燥后粉碎、过筛,得到藜麦质低GI配料。(5) Drying and pulverization: the obtained extrudate is dried, pulverized and sieved to obtain quinoa low GI ingredients.
在本发明一种实施方式中,步骤(1)中采用焙烤温度为160~180℃,时间为8~10min。In an embodiment of the present invention, in step (1), the baking temperature is 160-180° C., and the time is 8-10 minutes.
在本发明一种实施方式中,步骤(1)藜麦无苦涩味,预熟化度达到30%~35%。In an embodiment of the present invention, in step (1), the quinoa has no bitterness and astringency, and the pre-ripening degree reaches 30% to 35%.
在本发明一种实施方式中,步骤(2)中藜麦粉碎后的粒度要达到100目以上。In an embodiment of the present invention, the particle size of the quinoa after being pulverized in step (2) should reach more than 100 meshes.
在本发明一种实施方式中,步骤(3)中所述乳化剂为单硬脂酸甘油酯,添加量为藜麦粉的0.5%~1%(w/w)。In an embodiment of the present invention, the emulsifier in step (3) is glycerol monostearate, and the addition amount is 0.5% to 1% (w/w) of quinoa flour.
在本发明一种实施方式中,步骤(3)所采用纤维素酶添加量为20~40U/g藜麦粉干基。In an embodiment of the present invention, the amount of cellulase added in step (3) is 20-40 U/g dry basis of quinoa powder.
在本发明一种实施方式中,步骤(3)中加水调节混合料的水分含量为30%~35%。In an embodiment of the present invention, in step (3), water is added to adjust the moisture content of the mixture to 30%-35%.
在本发明一种实施方式中,步骤(4)中所述螺杆挤压机包括五个控温区段,分别为60~70℃、70~80℃、70~80℃、60~70℃、60~70℃,喂料速度为6~8kg/h,螺杆转速为90~110r/min。In an embodiment of the present invention, the screw extruder in step (4) includes five temperature control sections, which are 60-70°C, 70-80°C, 70-80°C, 60-70°C, 60~70℃, the feeding speed is 6~8kg/h, and the screw speed is 90~110r/min.
在本发明一种实施方式中,步骤(5)是将步骤(4)得到的产物在70~80℃下热风干燥40~50min。In an embodiment of the present invention, step (5) is to dry the product obtained in step (4) with hot air at 70-80° C. for 40-50 min.
在本发明一种实施方式中,步骤(5)所得藜麦质低GI配料粒度要达到100目以上。In an embodiment of the present invention, the particle size of the quinoa low-GI ingredients obtained in step (5) should reach more than 100 meshes.
本发明披露了一种上述方法制备得到的藜麦质低GI配料,GI值低于45。The invention discloses a quinoa quality low-GI ingredient prepared by the above method, and the GI value is lower than 45.
本发明披露了一种上述藜麦质低GI配料在药物缓释载体和食品配料领域的应用。The invention discloses the application of the above-mentioned quinoa low-GI ingredient in the field of drug sustained-release carrier and food ingredient.
本发明披露了一种降低挤压谷物GI值的方法,所述方法是在挤压加工前,通过添加乳化剂和纤维素酶对谷物进行调质,以降低挤压谷物的GI值;所述谷物包括大米、小麦、燕麦、藜麦或玉米。The present invention discloses a method for reducing the GI value of extruded grains. The method is to adjust the grains by adding emulsifier and cellulase before extrusion processing, so as to reduce the GI value of the extruded grains; the Grains include rice, wheat, oats, quinoa or corn.
在本发明一种实施方式中,所述乳化剂为单硬脂酸甘油酯,添加量为谷物质量的0.5%~1%。In an embodiment of the present invention, the emulsifier is glycerol monostearate, and the addition amount is 0.5% to 1% of the grain quality.
在本发明一种实施方式中,所述纤维素酶的添加量为20~40U/g谷物。In one embodiment of the present invention, the added amount of the cellulase is 20-40 U/g grains.
本发明的有益效果:Beneficial effects of the present invention:
(1)本发明采用焙烤方式分解藜麦皂苷,去除藜麦表皮皂苷带来的苦涩味,同时对藜麦进行预熟化,预熟化度达到30%~35%;(1) the present invention adopts the baking method to decompose the quinoa saponins, removes the bitterness and astringency brought by the quinoa epidermal saponins, and simultaneously pre-ripens the quinoa, and the pre-ripening degree reaches 30% to 35%;
(2)本发明采用挤压方式为淀粉与乳化剂提供络合环境,提高藜麦淀粉与乳化剂络合率,增强其耐热稳定性和耐酶解特性,降低其水解速率,保持藜麦的低GI特性;另一方面,本发 明采用加酶挤压方式,即在挤压前添加纤维素酶,使原料粉与纤维素酶在挤压机内充分作用,利用挤压机的瞬时作用使纤维素酶在挤压体系中保持“过程活性”,从而有效提高挤压物所含可溶性膳食纤维含量,两者相互作用,共同降低挤压物的GI值;(2) The present invention adopts the extrusion method to provide a complexing environment for starch and emulsifier, improve the complexation rate of quinoa starch and emulsifier, enhance its thermal stability and resistance to enzymatic hydrolysis, reduce its hydrolysis rate, and maintain quinoa On the other hand, the present invention adopts the method of adding enzyme extrusion, that is, adding cellulase before extrusion, so that the raw material powder and cellulase can fully function in the extruder, and the instantaneous action of the extruder is utilized. Keep cellulase in the "process activity" in the extrusion system, thereby effectively increasing the content of soluble dietary fiber contained in the extrudate, and the two interact to reduce the GI value of the extrudate together;
(3)采用上述方法制备得到的藜麦质低GI配料抗消化淀粉含量达70%、可溶性膳食纤维含量6%、血糖生成指数在40~45范围内,有效保持了藜麦在加工中的低GI特性。且本发明的方法生产周期短,生产效率高,成本较低,易于大规模工业化生产;(3) The quinoa low GI ingredients prepared by the above method have an anti-digestive starch content of 70%, a soluble dietary fiber content of 6%, and a glycemic index in the range of 40 to 45, effectively maintaining the low quinoa in processing. GI properties. And the method of the invention has short production period, high production efficiency, low cost, and is easy to large-scale industrial production;
(4)本发明制备得到的该藜麦质低GI配料具有优良的生理功能如改善肠道健康、预防糖尿病、控制体重等,适用于II型糖尿病患者控制血糖食用,在药物缓释和功能食品配料领域有广泛应用。(4) The quinoa low-GI ingredients prepared by the present invention have excellent physiological functions such as improving intestinal health, preventing diabetes, controlling body weight, etc., and are suitable for consumption of type II diabetes patients to control blood sugar, and are used in drug sustained-release and functional foods. It is widely used in the field of ingredients.
以下对本发明的优选实施例进行说明,应当理解实施例是为了更好地解释本发明,不用于限制本发明。The preferred embodiments of the present invention will be described below, and it should be understood that the embodiments are used to better explain the present invention and are not intended to limit the present invention.
1、预熟化度测定1. Determination of pre-curing degree
采用DSC测量样品的预糊化度。分别称取4mg(干基)藜麦原料粉与焙烤藜麦粉置于坩埚中,按质量比1:2的比例加入去离子水,压盖密封后置于室温下,隔夜平衡后测量。以空坩埚为参比,扫描温度范围为20~140℃,扫描速率为10℃/min,观察与淀粉糊化有关的有序-无序相变焓变ΔH,使用以下公式计算样品的淀粉预熟化度:The degree of pregelatinization of the samples was measured by DSC. Weigh 4mg (dry basis) of raw quinoa powder and roasted quinoa powder in a crucible, add deionized water in a mass ratio of 1:2, press the lid and seal, and place at room temperature, and measure after equilibrating overnight. Taking an empty crucible as a reference, the scanning temperature range is 20-140 °C, and the scanning rate is 10 °C/min, and the order-disorder phase transition enthalpy change ΔH related to starch gelatinization is observed, and the starch precipitation of the sample is calculated using the following formula: Maturation:
预熟化度(%)=(ΔH
full-ΔH)/ΔH
full×100
Pre-aging degree (%)=(ΔH full -ΔH)/ΔH full ×100
式中:ΔH
full为未经热处理的样品吸热焓变,ΔH为经热处理样品的吸热焓变。
where ΔH full is the endothermic enthalpy change of the sample without heat treatment, and ΔH is the endothermic enthalpy change of the heat-treated sample.
2、消化性能测定2. Determination of digestive performance
称取200mg样品置于50mL离心管中,加入2mL水,混匀后置于37℃恒温水浴振荡(160r/min)。加入4mL胃蛋白酶溶液(内含0.5g胃蛋白酶,0.5g瓜尔胶分散于100mL的5mol/L的盐酸溶液中)反应30min,后在每个测试离心管中加入5粒玻璃珠和2mL醋酸钠溶液(pH=5.2,0.5mol/L)继续振荡30min。接着加入2mL混酶溶液(8g胰酶与1.96mL糖化酶(260U/mL)分散于44.8mL水中),水解0,20,120min后取样0.1mL加入0.9mL的90%乙醇灭酶。离心5min后取上清液,以不加样品的水为空白样品,采用葡萄糖氧化酶试剂盒(GOD-POD)测定葡萄糖含量,每个样品平行测定3次取平均值。抗消化淀粉含量即为慢消化淀粉(SDS)和抗性淀粉(RS)含量之和。具体计算公式如下:Weigh 200 mg of the sample into a 50 mL centrifuge tube, add 2 mL of water, mix well, and place it in a 37°C constant temperature water bath to shake (160 r/min). Add 4 mL of pepsin solution (containing 0.5 g of pepsin, 0.5 g of guar gum dispersed in 100 mL of 5 mol/L hydrochloric acid solution) to react for 30 min, and then add 5 glass beads and 2 mL of sodium acetate to each test centrifuge tube The solution (pH=5.2, 0.5 mol/L) was continuously shaken for 30 min. Then add 2mL mixed enzyme solution (8g pancreatin and 1.96mL saccharification enzyme (260U/mL) are dispersed in 44.8mL water), after hydrolysis 0,20,120min, sample 0.1mL and add 0.9mL of 90% ethanol to inactivate the enzyme. After centrifugation for 5 min, the supernatant was taken, and the water without the sample was used as the blank sample, and the glucose content was measured by the glucose oxidase kit (GOD-POD). The content of resistant starch is the sum of slowly digestible starch (SDS) and resistant starch (RS). The specific calculation formula is as follows:
RDS(%)=(G20-G0)×0.9×100/TSRDS(%)=(G20-G0)×0.9×100/TS
SDS(%)=(G120-G20)×0.9×100/TSSDS(%)=(G120-G20)×0.9×100/TS
RS(%)=1-RDS(%)-SDS(%)RS(%)=1-RDS(%)-SDS(%)
式中:G0—样品中游离葡萄糖含量(mg);In the formula: G0—free glucose content in the sample (mg);
G20—水解20min后产生的葡萄糖含量(mg);G20—the glucose content (mg) produced after hydrolysis for 20min;
G120—水解120min后产生的葡萄糖含量(mg)。G120—Glucose content (mg) produced after hydrolysis for 120 min.
3、血糖生成指数测定3. Determination of glycemic index
称取100mg样品置于50mL离心管中,加入2mL水,沸水浴10min糊化,再添加13mL乙酸-乙酸钠缓冲液(pH=5.2,0.2mol/L),在37℃恒温水浴下平衡10min,再加0.2mL混合酶液(猪胰α-淀粉酶290U/mL,糖化酶15U/mL),在37℃恒温水浴下振荡(50r/min)并准确计时。振荡反应0min,30min,60min,90min,120min,180min后分别取0.1mL上清液加入至2mL无水乙醇进行灭酶处理,用GOPOD葡萄糖试剂盒在510nm处比色测定葡萄糖含量,每个样品平行测定3次取平均值,绘制淀粉水解曲线,计算水解曲线下的面积(AUC)。Weigh 100 mg of the sample into a 50 mL centrifuge tube, add 2 mL of water, gel in a boiling water bath for 10 min, add 13 mL of acetic acid-sodium acetate buffer (pH=5.2, 0.2 mol/L), and equilibrate under a constant temperature water bath at 37 °C for 10 min. Add 0.2 mL of mixed enzyme solution (porcine pancreatic α-amylase 290 U/mL, saccharification enzyme 15 U/mL), shake under a constant temperature water bath at 37° C. (50 r/min) and accurately time the time. After 0min, 30min, 60min, 90min, 120min, and 180min of the shaking reaction, 0.1 mL of the supernatant was added to 2 mL of absolute ethanol to inactivate the enzyme, and the GOPOD glucose kit was used to colorimetrically measure the glucose content at 510 nm. Measure 3 times to get the average value, draw the starch hydrolysis curve, and calculate the area under the hydrolysis curve (AUC).
样品水解指数(HI)计算公式如下:The formula for calculating the hydrolysis index (HI) of the sample is as follows:
HI=样品消化曲线下面积/白面包消化曲线下面积×100%HI = area under the sample digestion curve/area under the white bread digestion curve x 100%
以白面包作为标准物,其血糖指数(GI)定为100,由HI预测GI的计算公式如下:Taking white bread as the standard, its glycemic index (GI) is set as 100, and the calculation formula for predicting GI from HI is as follows:
GI=0.549×HI+37.91。GI=0.549×HI+37.91.
4、可溶性膳食纤维含量测定4. Determination of soluble dietary fiber content
准确称取双份样品1.00g±0.002g,加入pH 8.2的MES-TRIS缓冲液40mL,搅拌均匀,加入50μL耐高温α-淀粉酶溶液缓慢搅拌,用铝箔将烧杯盖住,置于95~100℃恒温振荡水浴中持续振荡35min。将烧杯从水浴中移出,冷却至60℃,打开铝箔盖,用刮勺将烧杯内壁的环状物和烧杯底部的胶状物刮下,用10mL蒸馏水冲洗烧杯壁和刮勺。在各个烧杯中加入蛋白酶溶液100μL,盖上铝箔,继续在水浴中振荡,在60℃条件下反应30min。然后打开铝箔盖,边搅拌边加入1.5mL乙酸溶液(3mol/L),用酸度计调节溶液pH值为4.5,边搅拌边加入100μL淀粉葡萄糖苷酶溶液,盖上铝箔,持续振荡,在60℃条件下反应30min。取已处理的坩埚,用3mL水润湿硅藻土并展平,抽去水分使坩埚中的硅藻土平铺于滤板上。将试样酶解液全部转移至坩埚中抽滤,残渣用70℃热水10mL洗涤2次,收集并合并滤液,并将液体浓缩到约50mL待测。将上清液浓缩到约50mL时加入预热到60℃的4倍体积的95%乙醇溶液,室温下沉淀1h,过滤后干燥称重,得可溶性膳食纤维的质量。扣除双份样品中蛋白和灰分的质量,即得样品中可溶性膳食纤维的含量。Accurately weigh 1.00g ± 0.002g of a double sample, add 40mL of pH 8.2 MES-TRIS buffer, stir evenly, add 50μL of high temperature resistant α-amylase solution and stir slowly, cover the beaker with aluminum foil, and place it at 95-100 Continue to shake in a constant temperature shaking water bath for 35 min. Remove the beaker from the water bath, cool to 60°C, open the aluminum foil cover, scrape off the ring on the inner wall of the beaker and the jelly at the bottom of the beaker with a spatula, rinse the beaker wall and spatula with 10 mL of distilled water. Add 100 μL of protease solution to each beaker, cover with aluminum foil, continue to shake in a water bath, and react at 60° C. for 30 min. Then open the aluminum foil cover, add 1.5 mL of acetic acid solution (3 mol/L) while stirring, adjust the pH of the solution to 4.5 with a pH meter, add 100 μL amyloglucosidase solution while stirring, cover with aluminum foil, continue to shake, at 60 ℃ Condition reaction for 30min. Take the treated crucible, wet the diatomaceous earth with 3 mL of water and flatten it, and drain the water so that the diatomaceous earth in the crucible is spread on the filter plate. All the sample enzymolysis solution was transferred to the crucible for suction filtration, the residue was washed twice with 10 mL of 70 ℃ hot water, the filtrate was collected and combined, and the liquid was concentrated to about 50 mL to be tested. When the supernatant was concentrated to about 50 mL, 4 times the volume of 95% ethanol solution preheated to 60°C was added, precipitated at room temperature for 1 h, filtered, dried and weighed to obtain the mass of soluble dietary fiber. The content of soluble dietary fiber in the sample was obtained by deducting the mass of protein and ash in the duplicate samples.
5、纤维素酶购于默克试剂平台,酶活为800U/g。5. Cellulase was purchased from Merck reagent platform, and the enzyme activity was 800U/g.
实施例1:一种藜麦质低GI配料的制备方法Embodiment 1: a kind of preparation method of quinoa low GI ingredient
所述方法包括以下步骤:The method includes the following steps:
(1)烘焙处理:将清洗后的藜麦放入烤箱中焙烤,在160℃温度下焙烤10min,预熟化度达到32.9%;(1) Baking treatment: put the cleaned quinoa into an oven for baking, bake at 160°C for 10 minutes, and the pre-curing degree reaches 32.9%;
(2)粉碎:将焙烤后的藜麦放入粉碎机进行粉碎,粉碎后藜麦粉的粒度达到100目以上;(2) pulverization: put the roasted quinoa into a pulverizer for pulverization, and the particle size of the quinoa powder after pulverization reaches more than 100 meshes;
(3)混合调质:将步骤(2)所得焙烤藜麦粉中按一定比例添加乳化剂和纤维素酶,混合均匀,加水调配混合料的水分含量为30%;所述乳化剂为单硬脂酸甘油酯,添加量为藜麦粉的0.5%(w/w);所采用纤维素酶添加量为20U/g藜麦粉干基;(3) Mixing and tempering: adding an emulsifier and cellulase to the baked quinoa powder obtained in step (2) in a certain proportion, mixing evenly, and adding water to prepare the mixture with a moisture content of 30%; the emulsifier is monostearate Acid glyceride, the addition amount is 0.5% (w/w) of the quinoa powder; The adopted cellulase addition amount is 20U/g quinoa powder dry basis;
(4)挤压:将步骤(3)所得混合料送入螺杆挤压机中挤压加工;所述螺杆挤压机包括五个控温区段,分别为60℃、70℃、70℃、60℃、60℃,喂料速度为6kg/h,螺杆转速为90r/min;(4) Extrusion: the mixture obtained in step (3) is sent to a screw extruder for extrusion processing; the screw extruder includes five temperature control sections, which are respectively 60°C, 70°C, 70°C, 60℃, 60℃, the feeding speed is 6kg/h, and the screw speed is 90r/min;
(5)干燥粉碎:将得到的挤压物在70℃下热风干燥50min后粉碎,过100目筛,即得一种藜麦质低GI配料,该配料抗消化淀粉含量为73.1%,可溶性膳食纤维含量为5.6%,血糖生成指数为43.2。(5) Drying and pulverizing: the obtained extrudate is pulverized after being hot-air dried at 70° C. for 50 minutes, and passed through a 100-mesh sieve to obtain a quinoa low GI ingredient, the ingredient’s anti-digestive starch content is 73.1%, and the soluble dietary The fiber content is 5.6% and the glycemic index is 43.2.
实施例2:一种藜麦质低GI配料的制备方法Embodiment 2: a kind of preparation method of quinoa low GI ingredient
所述方法包括以下步骤:The method includes the following steps:
(1)烘焙处理:将清洗后的藜麦放入烤箱中焙烤,在170℃温度下焙烤10min,预熟化度达到33.7%;(1) Baking treatment: put the cleaned quinoa into an oven for baking, and bake at a temperature of 170 ° C for 10 minutes, and the pre-curing degree reaches 33.7%;
(2)粉碎:将焙烤后的藜麦放入粉碎机进行粉碎,粉碎后藜麦粉的粒度达到100目以上;(2) pulverization: put the roasted quinoa into a pulverizer for pulverization, and the particle size of the quinoa powder after pulverization reaches more than 100 meshes;
(3)混合调质:将步骤(2)所得焙烤藜麦粉中按一定比例添加乳化剂和纤维素酶,混合均匀,加水调配混合料的水分含量为32%;所述乳化剂为单硬脂酸甘油酯,添加量为藜麦粉的1%(w/w);所采用纤维素酶添加量为30U/g藜麦粉干基;(3) Mixing and tempering: adding an emulsifier and cellulase to the baked quinoa powder obtained in step (2) in a certain proportion, mixing uniformly, and adding water to prepare the mixture with a moisture content of 32%; the emulsifier is monostearate Acid glyceride, the addition amount is 1% (w/w) of the quinoa powder; The adopted cellulase addition amount is 30U/g quinoa powder dry basis;
(4)挤压:将步骤(3)所得混合料送入螺杆挤压机中挤压加工;所述螺杆挤压机包括五个控温区段,分别为65℃、75℃、75℃、65℃、65℃,喂料速度为7kg/h,螺杆转速为100r/min;(4) Extrusion: the mixture obtained in step (3) is sent to a screw extruder for extrusion processing; the screw extruder includes five temperature control sections, which are respectively 65°C, 75°C, 75°C, 65℃, 65℃, the feeding speed is 7kg/h, and the screw speed is 100r/min;
(5)干燥粉碎:将得到的挤压物在80℃下热风干燥40min后粉碎,过100目筛,即得一种藜麦质低GI配料,该配料抗消化淀粉含量为72.9%,可溶性膳食纤维含量为6.1%,血糖生成指数为44.2。(5) Drying and pulverizing: the obtained extrudate is pulverized after being hot-air dried at 80° C. for 40 min, and passed through a 100-mesh sieve to obtain a quinoa low-GI ingredient, the ingredient has an anti-digestive starch content of 72.9%, and a soluble dietary The fiber content is 6.1% and the glycemic index is 44.2.
实施例3:一种藜麦质低GI配料的制备方法Embodiment 3: a kind of preparation method of quinoa low GI ingredient
所述方法包括以下步骤:The method includes the following steps:
(1)烘焙处理:将清洗后的藜麦放入烤箱中焙烤,在180℃温度下焙烤8min,预熟化度达到33.2%;(1) Baking treatment: put the cleaned quinoa into an oven for baking, and bake it at a temperature of 180 ° C for 8 minutes, and the pre-curing degree reaches 33.2%;
(2)粉碎:将焙烤后的藜麦放入粉碎机进行粉碎,粉碎后藜麦粉的粒度达到100目以上;(2) pulverization: put the roasted quinoa into a pulverizer for pulverization, and the particle size of the quinoa powder after pulverization reaches more than 100 meshes;
(3)混合调质:将步骤(2)所得焙烤藜麦粉中按一定比例添加乳化剂和纤维素酶,混合均匀,加水调配混合料的水分含量为35%;所述乳化剂为单硬脂酸甘油酯,添加量为藜麦粉的1%(w/w);所采用纤维素酶添加量为40U/g藜麦粉干基;(3) Mixing and tempering: adding an emulsifier and a cellulase to the baked quinoa powder obtained in step (2) in a certain proportion, mixing evenly, and adding water to prepare the mixture with a moisture content of 35%; the emulsifier is monostearate Acid glyceride, the addition amount is 1% (w/w) of the quinoa powder; The adopted cellulase addition amount is 40U/g quinoa powder dry basis;
(4)挤压:将步骤(3)所得混合料送入螺杆挤压机中挤压加工;所述螺杆挤压机包括五个控温区段,分别为70℃、80℃、80℃、70℃、70℃,喂料速度为8kg/h,螺杆转速为110r/min;(4) Extrusion: the mixture obtained in step (3) is sent to a screw extruder for extrusion processing; the screw extruder includes five temperature control sections, which are respectively 70°C, 80°C, 80°C, 70℃, 70℃, the feeding speed is 8kg/h, and the screw speed is 110r/min;
(5)干燥粉碎:将得到的挤压物在80℃下热风干燥40min后粉碎,过100目筛,即得一种藜麦质低GI配料,该配料抗消化淀粉含量为73.2%,可溶性膳食纤维含量为5.9%,血糖生成指数为43.4。(5) Drying and pulverizing: the obtained extrudate is pulverized after being hot-air dried at 80° C. for 40 minutes, and passed through a 100-mesh sieve to obtain a quinoa low-GI ingredient, the ingredient’s anti-digestive starch content is 73.2%, and the soluble dietary The fiber content is 5.9% and the glycemic index is 43.4.
实施例4:藜麦质低GI配料在药物缓释中的应用Example 4: Application of Quinoa Low GI Ingredients in Drug Sustained Release
采用实施例1制备得到的藜麦质低GI配料为原料,通过直接压片法制备盐酸普萘洛尔缓释片,在模拟胃液试验中30min累积释放率仅为14.2%,其缓释效应明显强于直接服用该药物(释放率98%),从而可有效延长盐酸普萘洛尔缓释时间,提高盐酸普萘洛尔生物利用度,减少给药频率并减小肠胃负担。Using the quinoa low GI ingredients prepared in Example 1 as raw materials, propranolol hydrochloride sustained-release tablets were prepared by direct compression method. In the simulated gastric juice test, the cumulative release rate in 30 minutes was only 14.2%, and its sustained-release effect was obvious. It is stronger than taking the drug directly (the release rate is 98%), thereby effectively prolonging the sustained release time of propranolol hydrochloride, improving the bioavailability of propranolol hydrochloride, reducing the frequency of administration and reducing the burden on the stomach and intestines.
对比例1Comparative Example 1
参照实施例1的方法处理藜麦,区别在于,省略步骤(1)-(3),即直接将藜麦原料粉进行挤压。藜麦未经熟化直接进行挤压,预熟化度降低至21.7%,抗消化淀粉含量降低至50.7%,可溶性膳食纤维含量降低至2.6%,血糖生成指数升高至55.6。The quinoa is processed with reference to the method of Example 1, the difference is that steps (1)-(3) are omitted, that is, the quinoa raw material powder is directly extruded. The quinoa was directly extruded without being ripened, the pre-ripening degree was reduced to 21.7%, the content of anti-digestible starch was reduced to 50.7%, the content of soluble dietary fiber was reduced to 2.6%, and the glycemic index was increased to 55.6.
对比例2Comparative Example 2
将实施例1中的焙烤处理替换成传统洗涤法除皂苷,其他条件或者参数与实施例1一致。与实施例1相比,洗涤法对藜麦没有预熟化作用,藜麦粉的预熟化度降低至21.8%,抗消化淀粉含量降低至65.8%,可溶性膳食纤维含量降低至5.3%,血糖生成指数升高至49.7。The baking treatment in Example 1 was replaced by a traditional washing method to remove saponins, and other conditions or parameters were the same as those in Example 1. Compared with Example 1, the washing method has no pre-ripening effect on quinoa, the pre-ripening degree of quinoa flour is reduced to 21.8%, the content of anti-digestible starch is reduced to 65.8%, the content of soluble dietary fiber is reduced to 5.3%, and the glycemic index is increased. as high as 49.7.
对比例3Comparative Example 3
将实施例1步骤(3)中乳化剂的添加量调整为藜麦粉的0.4%(w/w),其他条件或者参数与实施例1一致。与实施例1相比,抗消化淀粉含量降低至59.3%,可溶性膳食纤维含量降低至5.2%,血糖生成指数升高至53.0。The amount of emulsifier added in step (3) of Example 1 was adjusted to 0.4% (w/w) of the quinoa flour, and other conditions or parameters were consistent with those of Example 1. Compared with Example 1, the content of antidigestive starch was reduced to 59.3%, the content of soluble dietary fiber was reduced to 5.2%, and the glycemic index was increased to 53.0.
对比例4Comparative Example 4
将实施例1步骤(3)中纤维素酶的添加量调整10U/g藜麦粉干基,其他条件或者参数与实施例1一致。与实施例1相比,抗消化淀粉含量降低至64.6%,可溶性膳食纤维含量降低至3.5%,血糖生成指数升高至50.9。The amount of cellulase added in step (3) of Example 1 was adjusted to 10U/g dry basis of quinoa powder, and other conditions or parameters were consistent with Example 1. Compared with Example 1, the content of anti-digestible starch was reduced to 64.6%, the content of soluble dietary fiber was reduced to 3.5%, and the glycemic index was increased to 50.9.
对比例5Comparative Example 5
将实施例1步骤(4)中的挤压温度调整为75℃、85℃、85℃、75℃,75℃,其他条件或者参数与实施例1一致。与实施例1相比,抗消化淀粉含量降低至63.0%,可溶性膳食纤维含量降低至3.1%,血糖生成指数升高至51.3。The extrusion temperature in step (4) of Example 1 was adjusted to 75°C, 85°C, 85°C, 75°C, and 75°C, and other conditions or parameters were consistent with those of Example 1. Compared with Example 1, the content of anti-digestible starch was reduced to 63.0%, the content of soluble dietary fiber was reduced to 3.1%, and the glycemic index was increased to 51.3.
对比例6Comparative Example 6
参照实施例1的方法处理藜麦,区别在于,省略步骤(3)中的纤维素酶,即仅采用乳化剂,其他参数条件同实施例1。与实施例1相比,抗消化淀粉含量降低至61.2%,可溶性膳食纤维含量降低至2.6%,血糖生成指数升高至53.1。The quinoa was processed with reference to the method of Example 1, the difference was that the cellulase in step (3) was omitted, that is, only the emulsifier was used, and other parameters were the same as those of Example 1. Compared with Example 1, the content of anti-digestible starch was reduced to 61.2%, the content of soluble dietary fiber was reduced to 2.6%, and the glycemic index was increased to 53.1.
对比例7Comparative Example 7
参照实施例1的方法处理藜麦,区别在于,省略步骤(3)中的乳化剂,即仅采用纤维素酶,其他参数条件同实施例1。与实施例1相比,抗消化淀粉含量降低至55.4%,可溶性膳食纤维含量降低至5.2%,血糖生成指数升高至53.9。The quinoa was treated with reference to the method of Example 1, except that the emulsifier in step (3) was omitted, that is, only cellulase was used, and other parameters and conditions were the same as those of Example 1. Compared with Example 1, the content of anti-digestible starch was reduced to 55.4%, the content of soluble dietary fiber was reduced to 5.2%, and the glycemic index was increased to 53.9.
表1实施例与对比例结果测定Table 1 embodiment and comparative example result determination
由表1可见,本发明中采用高温焙烤、添加乳化剂、加酶挤压等手段,制备得到焙烤藜麦粉的预熟化度达到30%-35%,挤压物抗消化淀粉含量达70%、可溶性膳食纤维含量6%、血糖生成指数低于45,相较于藜麦原料粉都有显著改善;本发明中改变上述技术或方法参数,或省去部分发明步骤均会显著影响挤压物的GI值。本发明作为一种藜麦质低GI配料应用于在医药辅料缓释载体、食品配料领域,具有优良的生理功能如控制血糖、预防糖尿病等。As can be seen from Table 1, in the present invention, means such as high-temperature baking, adding emulsifier, adding enzyme extrusion are adopted, and the pre-ripening degree of the prepared baked quinoa powder reaches 30%-35%, and the extruded anti-digestion starch content reaches 70%, The soluble dietary fiber content is 6%, and the glycemic index is lower than 45, which is significantly improved compared with the quinoa raw material powder; in the present invention, changing the above technical or method parameters, or omitting some of the invention steps will significantly affect the extrudate. GI value. As a quinoa quality low GI ingredient, the present invention is applied in the fields of pharmaceutical auxiliary material sustained-release carriers and food ingredients, and has excellent physiological functions such as blood sugar control, diabetes prevention and the like.
另一方面,实施例1和对比例1、6、7的对照结果证明,对比例6单独采用乳化剂得到的产品的GI值为53.1,较对比例1降低了2.5;对比例7单独采用纤维素酶得到的产品的GI值为53.9,较对比例1降低了1.7;而本发明实施例1采用乳化剂和纤维素酶联合使用得到的产品的GI值为43.2,较对比例1降低了12.4,较单独乳化剂和单独纤维素酶的效果之和更优越,说明乳化剂和纤维素酶在降低挤压谷物GI值方面相互作用,具有一定的协同作用。On the other hand, the comparison results of Example 1 and Comparative Examples 1, 6, and 7 prove that the GI value of the product obtained by using the emulsifier alone in Comparative Example 6 is 53.1, which is 2.5 lower than that in Comparative Example 1; The GI value of the product obtained by vegetase is 53.9, which is 1.7 lower than that of Comparative Example 1; while the GI value of the product obtained by using emulsifier and cellulase in combination in Example 1 of the present invention is 43.2, which is 12.4 lower than that of Comparative Example 1. , which is superior to the sum of the effects of single emulsifier and single cellulase, indicating that the emulsifier and cellulase interact with each other in reducing the GI value of extruded grains and have a certain synergistic effect.
虽然本发明已以较佳实施例公开如上,但其并非用以限定本发明,任何熟悉此技术的人,在不脱离本发明的精神和范围内,都可做各种的改动与修饰,因此本发明的保护范围应该以权利要求书所界定的为准。Although the present invention has been disclosed above with preferred embodiments, it is not intended to limit the present invention. Anyone who is familiar with this technology can make various changes and modifications without departing from the spirit and scope of the present invention. Therefore, The protection scope of the present invention should be defined by the claims.
Claims (19)
- 一种制备藜麦质低GI配料的方法,其特征在于,以藜麦为原料,通过焙烤预熟化、再添加乳化剂和纤维素酶混合调质,最后经挤压得到藜麦质低GI配料;所述乳化剂为单硬脂酸甘油酯,添加量为藜麦粉的0.5%~1%;所采用纤维素酶添加量为20~40U/g藜麦粉干基。A method for preparing quinoa low-GI ingredients, characterized in that, using quinoa as a raw material, pre-ripening by baking, adding an emulsifier and cellulase for mixing and tempering, and finally extruding to obtain quinoa low-GI ingredients The emulsifier is glycerol monostearate, and the added amount is 0.5% to 1% of the quinoa powder; the adopted cellulase is added in an amount of 20 to 40 U/g quinoa powder dry basis.
- 一种制备藜麦质低GI配料的方法,其特征在于,以藜麦为原料,通过焙烤预熟化、再添加乳化剂和纤维素酶混合调质,最后经挤压得到藜麦质低GI配料。A method for preparing quinoa low-GI ingredients, characterized in that, using quinoa as a raw material, pre-ripening by baking, adding an emulsifier and cellulase for mixing and tempering, and finally extruding to obtain quinoa low-GI ingredients .
- 根据权利要求1所述的方法,其特征在于,所述方法包括以下步骤:The method of claim 1, wherein the method comprises the steps of:(1)烘焙处理:将藜麦进行焙烤处理;(1) Baking treatment: the quinoa is subjected to baking treatment;(2)粉碎:将步骤(1)所得藜麦进行粉碎,备用;(2) pulverizing: pulverizing the quinoa obtained in step (1), for subsequent use;(3)混合调质:将步骤(2)所得藜麦粉中添加乳化剂和纤维素酶,混合均匀,加水调配;(3) mixing and tempering: adding emulsifier and cellulase to the quinoa powder obtained in step (2), mixing evenly, and adding water to prepare;(4)挤压:将步骤(3)所得混合料于挤压机中挤压加工;(4) extrusion: the compound obtained in step (3) is extruded and processed in an extruder;(5)干燥粉碎:将得到的挤压物干燥后粉碎、过筛,得到藜麦质低GI配料。(5) Drying and pulverization: the obtained extrudate is dried, pulverized and sieved to obtain quinoa low GI ingredients.
- 根据权利要求3所述的方法,其特征在于,步骤(1)中采用焙烤温度为160~180℃,时间为8~10min。The method according to claim 3, characterized in that, in step (1), the baking temperature is 160-180 DEG C, and the time is 8-10 min.
- 根据权利要求3所述的方法,其特征在于,步骤(1)藜麦无苦涩味,预熟化度达到30%~35%。The method according to claim 3, wherein in step (1), the quinoa has no bitterness and astringency, and the pre-ripening degree reaches 30% to 35%.
- 根据权利要求2所述的方法,其特征在于,所述乳化剂为单硬脂酸甘油酯,添加量为藜麦粉质量的0.5%~1%。The method according to claim 2, wherein the emulsifier is glycerol monostearate, and the addition amount is 0.5% to 1% of the mass of the quinoa flour.
- 根据权利要求2所述的方法,其特征在于,所述纤维素酶的添加量为20~40U/g藜麦粉干基。The method according to claim 2, wherein the addition amount of the cellulase is 20-40 U/g dry basis of quinoa powder.
- 根据权利要求3所述的方法,其特征在于,步骤(3)中加水调节混合料的水分含量为30%~35%。The method according to claim 3, characterized in that, in step (3), adding water to adjust the moisture content of the mixture to be 30% to 35%.
- 根据权利要求2所述的方法,其特征在于,所述挤压包括五个控温区段,分别为60~70℃、70~80℃、70~80℃、60~70℃、60~70℃,喂料速度为6~8kg/h,螺杆转速为90~110r/min。The method according to claim 2, wherein the extrusion comprises five temperature control sections, which are respectively 60-70°C, 70-80°C, 70-80°C, 60-70°C, 60-70°C ℃, the feeding speed is 6~8kg/h, and the screw speed is 90~110r/min.
- 根据权利要求3所述的方法,其特征在于,步骤(5)是将步骤(4)得到的产物在70~80℃下热风干燥40~50min。The method according to claim 3, characterized in that, in step (5), the product obtained in step (4) is dried with hot air at 70-80° C. for 40-50 min.
- 根据权利要求3所述的方法,其特征在于,所述方法包括以下步骤:The method of claim 3, wherein the method comprises the steps of:(1)烘焙处理:将清洗后的藜麦放入烤箱中焙烤,在160℃温度下焙烤10min,预熟化度达到32.9%;(1) Baking treatment: put the cleaned quinoa into an oven for baking, bake at 160°C for 10 minutes, and the pre-curing degree reaches 32.9%;(2)粉碎:将焙烤后的藜麦放入粉碎机进行粉碎,粉碎后藜麦粉的粒度达到100目以上;(2) pulverization: put the roasted quinoa into a pulverizer for pulverization, and the particle size of the quinoa powder after pulverization reaches more than 100 meshes;(3)混合调质:将步骤(2)所得焙烤藜麦粉中按一定比例添加乳化剂和纤维素酶,混合均匀,加水调配混合料的水分含量为30%;所述乳化剂为单硬脂酸甘油酯,添加量为藜麦粉的0.5%;所采用纤维素酶添加量为20U/g藜麦粉干基;(3) Mixing and tempering: adding an emulsifier and cellulase to the baked quinoa powder obtained in step (2) in a certain proportion, mixing evenly, and adding water to prepare the mixture with a moisture content of 30%; the emulsifier is monostearate Acid glyceride, the addition amount is 0.5% of the quinoa flour; the amount of cellulase added is 20U/g quinoa flour dry basis;(4)挤压:将步骤(3)所得混合料送入螺杆挤压机中挤压加工;所述螺杆挤压机包括五个控温区段,分别为60℃、70℃、70℃、60℃、60℃,喂料速度为6kg/h,螺杆转速为90r/min;(4) Extrusion: the mixture obtained in step (3) is sent to a screw extruder for extrusion processing; the screw extruder includes five temperature control sections, which are respectively 60°C, 70°C, 70°C, 60℃, 60℃, the feeding speed is 6kg/h, and the screw speed is 90r/min;(5)干燥粉碎:将得到的挤压物在70℃下热风干燥50min后粉碎,过100目筛,即得藜麦质低GI配料。(5) Drying and pulverizing: the obtained extrudate was dried with hot air at 70° C. for 50 min, pulverized, and passed through a 100-mesh sieve to obtain quinoa low-GI ingredients.
- 根据权利要求3所述的方法,其特征在于,所述方法包括以下步骤:The method of claim 3, wherein the method comprises the steps of:(1)烘焙处理:将清洗后的藜麦放入烤箱中焙烤,在170℃温度下焙烤10min,预熟化度达到33.7%;(1) Baking treatment: put the cleaned quinoa into an oven for baking, and bake it at a temperature of 170° C. for 10 minutes, and the pre-curing degree reaches 33.7%;(2)粉碎:将焙烤后的藜麦放入粉碎机进行粉碎,粉碎后藜麦粉的粒度达到100目以上;(2) pulverization: put the roasted quinoa into a pulverizer for pulverization, and the particle size of the quinoa powder after pulverization reaches more than 100 meshes;(3)混合调质:将步骤(2)所得焙烤藜麦粉中按一定比例添加乳化剂和纤维素酶,混合均匀,加水调配混合料的水分含量为32%;所述乳化剂为单硬脂酸甘油酯,添加量为藜麦粉的1%;所采用纤维素酶添加量为30U/g藜麦粉干基;(3) Mixing and tempering: adding an emulsifier and cellulase to the baked quinoa powder obtained in step (2) in a certain proportion, mixing evenly, and adding water to prepare the mixture with a moisture content of 32%; the emulsifier is monostearate Acid glyceride, the addition amount is 1% of quinoa flour; the amount of cellulase added is 30U/g quinoa flour dry basis;(4)挤压:将步骤(3)所得混合料送入螺杆挤压机中挤压加工;所述螺杆挤压机包括五个控温区段,分别为65℃、75℃、75℃、65℃、65℃,喂料速度为7kg/h,螺杆转速为100r/min;(4) Extrusion: the mixture obtained in step (3) is sent to a screw extruder for extrusion processing; the screw extruder includes five temperature control sections, which are respectively 65°C, 75°C, 75°C, 65℃, 65℃, the feeding speed is 7kg/h, and the screw speed is 100r/min;(5)干燥粉碎:将得到的挤压物在80℃下热风干燥40min后粉碎,过100目筛,即得藜麦质低GI配料。(5) Drying and pulverization: the obtained extrudate is dried with hot air at 80° C. for 40 minutes, pulverized, and passed through a 100-mesh sieve to obtain quinoa low-GI ingredients.
- 根据权利要求3所述的方法,其特征在于,所述方法包括以下步骤:The method of claim 3, wherein the method comprises the steps of:(1)烘焙处理:将清洗后的藜麦放入烤箱中焙烤,在180℃温度下焙烤8min,预熟化度达到33.2%;(1) Baking treatment: put the cleaned quinoa into an oven for baking, and bake it at a temperature of 180 ° C for 8 minutes, and the pre-curing degree reaches 33.2%;(2)粉碎:将焙烤后的藜麦放入粉碎机进行粉碎,粉碎后藜麦粉的粒度达到100目以上;(2) pulverization: put the roasted quinoa into a pulverizer for pulverization, and the particle size of the quinoa powder after pulverization reaches more than 100 meshes;(3)混合调质:将步骤(2)所得焙烤藜麦粉中按一定比例添加乳化剂和纤维素酶,混合均匀,加水调配混合料的水分含量为35%;所述乳化剂为单硬脂酸甘油酯,添加量为藜麦粉的1%;所采用纤维素酶添加量为40U/g藜麦粉干基;(3) Mixing and tempering: adding emulsifier and cellulase to the baked quinoa powder obtained in step (2) in a certain proportion, mixing evenly, and adding water to prepare the mixture with a moisture content of 35%; the emulsifier is monostearate Acid glyceride, the addition amount is 1% of quinoa flour; the amount of cellulase added is 40U/g quinoa flour dry basis;(4)挤压:将步骤(3)所得混合料送入螺杆挤压机中挤压加工;所述螺杆挤压机包括五个控温区段,分别为70℃、80℃、80℃、70℃、70℃,喂料速度为8kg/h,螺杆转速为110r/min;(4) Extrusion: the mixture obtained in step (3) is sent to a screw extruder for extrusion processing; the screw extruder includes five temperature control sections, which are respectively 70°C, 80°C, 80°C, 70℃, 70℃, the feeding speed is 8kg/h, and the screw speed is 110r/min;(5)干燥粉碎:将得到的挤压物在80℃下热风干燥40min后粉碎,过100目筛,即得 藜麦质低GI配料。(5) Drying and pulverizing: the obtained extrudate was pulverized after hot air drying at 80°C for 40 min, and passed through a 100-mesh sieve to obtain a quinoa low-GI ingredient.
- 应用权利要求1-13任一项所述的方法制备得到的藜麦质低GI配料。The quinoa low GI ingredient prepared by the method according to any one of claims 1-13.
- 根据权利要求14所述的藜麦质低GI配料,其特征在于,所述GI值低于45。The quinoa low GI ingredient according to claim 14, wherein the GI value is lower than 45.
- 权利要求14或15所述的藜麦质低GI配料在药物辅料载体和食品配料领域的应用。Application of the quinoa low GI ingredient of claim 14 or 15 in the fields of pharmaceutical adjuvant carriers and food ingredients.
- 一种降低挤压谷物GI值的方法,其特征在于,所述方法是在挤压加工前,通过添加乳化剂和纤维素酶对谷物进行调质,以降低挤压谷物的GI值;所述谷物包括大米、小麦、燕麦、藜麦或玉米。A method for reducing the GI value of extruded cereals, characterized in that the method is to adjust the cereals by adding emulsifier and cellulase before extrusion processing, so as to reduce the GI value of extruded cereals; the Grains include rice, wheat, oats, quinoa or corn.
- 根据权利要求17所述的方法,其特征在于,所述乳化剂为单硬脂酸甘油酯,添加量为谷物质量的0.5%~1%。The method according to claim 17, wherein the emulsifier is glycerol monostearate, and the addition amount is 0.5% to 1% of the grain quality.
- 根据权利要求17所述的方法,其特征在于,所述纤维素酶的添加量为20~40U/g谷物。The method according to claim 17, wherein the addition amount of the cellulase is 20-40 U/g grain.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202010655112.6 | 2020-07-09 | ||
CN202010655112.6A CN111838534B (en) | 2020-07-09 | 2020-07-09 | Preparation method of quinoa low-GI ingredient |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2022007133A1 true WO2022007133A1 (en) | 2022-01-13 |
Family
ID=73152628
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/CN2020/109944 WO2022007133A1 (en) | 2020-07-09 | 2020-08-19 | Preparation method for quinoa low gi ingredient |
Country Status (2)
Country | Link |
---|---|
CN (1) | CN111838534B (en) |
WO (1) | WO2022007133A1 (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN115708564A (en) * | 2022-11-21 | 2023-02-24 | 南昌大学 | Low-GI value instant rice paste and production preparation method and application thereof |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113519771A (en) * | 2021-07-30 | 2021-10-22 | 江南大学 | Slowly digestible whole grain food, and processing method and application thereof |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107319302A (en) * | 2017-08-02 | 2017-11-07 | 李志军 | It is a kind of to reconstitute powder and preparation method thereof by the child of major ingredient of brown rice and quinoa |
CN110140860A (en) * | 2019-05-21 | 2019-08-20 | 上海应用技术大学 | Compound brewed powder of a kind of low miscellaneous beans of GI cereal and preparation method thereof |
CN110250414A (en) * | 2019-07-30 | 2019-09-20 | 江南大学 | A kind of preparation method of low-glycemic rice flour |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104381823A (en) * | 2014-11-17 | 2015-03-04 | 福建新顺成食品科技有限公司 | Formula of low glycemic index (GI) food and preparation method thereof |
WO2020019537A1 (en) * | 2018-07-24 | 2020-01-30 | 江南大学 | Method for preparing slowly digestible starch-containing recombinant instant rice having low glycemic index |
CN110692676A (en) * | 2019-11-01 | 2020-01-17 | 博生众康(厦门)医药生物技术股份有限公司 | Quinoa rice meal replacement composite food with low GI (glycemic index) and GL (GL) values as well as preparation method and application thereof |
CN111264867B (en) * | 2020-02-26 | 2022-09-27 | 江南大学 | Preparation method of anti-digestion starch |
CN111165737A (en) * | 2020-03-18 | 2020-05-19 | 河南省金米郎食品有限公司 | Quinoa rice cracker and preparation method thereof |
-
2020
- 2020-07-09 CN CN202010655112.6A patent/CN111838534B/en active Active
- 2020-08-19 WO PCT/CN2020/109944 patent/WO2022007133A1/en active Application Filing
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107319302A (en) * | 2017-08-02 | 2017-11-07 | 李志军 | It is a kind of to reconstitute powder and preparation method thereof by the child of major ingredient of brown rice and quinoa |
CN110140860A (en) * | 2019-05-21 | 2019-08-20 | 上海应用技术大学 | Compound brewed powder of a kind of low miscellaneous beans of GI cereal and preparation method thereof |
CN110250414A (en) * | 2019-07-30 | 2019-09-20 | 江南大学 | A kind of preparation method of low-glycemic rice flour |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN115708564A (en) * | 2022-11-21 | 2023-02-24 | 南昌大学 | Low-GI value instant rice paste and production preparation method and application thereof |
Also Published As
Publication number | Publication date |
---|---|
CN111838534B (en) | 2022-09-27 |
CN111838534A (en) | 2020-10-30 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN107212262B (en) | Brown rice flavored instant nutritional powder and preparation method thereof | |
CN100446672C (en) | Bread made from rice flour and preparation method thereof | |
CN111264840B (en) | Preparation method of slowly digestible starch | |
CN109123605B (en) | Preparation method of low-glycemic-index resistant starch recombinant rice | |
WO2020019537A1 (en) | Method for preparing slowly digestible starch-containing recombinant instant rice having low glycemic index | |
WO2022007133A1 (en) | Preparation method for quinoa low gi ingredient | |
WO2020224170A1 (en) | Method for preparing low gi recombinant highland barley granule | |
WO2022111066A1 (en) | Food raw material rich in slowly digestible and resistant starch, preparation method therefor and application thereof | |
WO2022033546A1 (en) | Cereal carbohydrate matrix for use in food for special medical purpose and preparation method for matrix | |
CN107997178B (en) | Method for preparing resistant starch with high dietary fiber content in extrusion mode | |
CN112390899A (en) | Preparation method of blend of pregelatinized starch and pachyman alkaline hydrolysis fragment and application of blend in weight-reducing meal replacement food | |
Akalu et al. | Physico‐chemical characteristics and functional properties of starch and dietary fibre in grass pea seeds | |
JP4082760B2 (en) | Indigestible starch and method for producing the same | |
CN107279718A (en) | A kind of sweet potato dietary fiber vermicelli and preparation method thereof | |
KR20070103851A (en) | Method for inhibition of digestion rate of cereals by annealing | |
JPS646756B2 (en) | ||
Soltani et al. | Evaluating the effect of different physical pretreatments and cooking methods on nutritional (starch digestibility) and physicochemical properties of white rice grains (Fajr cultivar) | |
CN112544882A (en) | Highland barley puffed food and preparation method thereof | |
CN113826812B (en) | Corn-based nutrition brewing powder with low glycemic index and preparation method thereof | |
CN114098091B (en) | Preparation method of high-resistance starch acorn vermicelli | |
US11155645B2 (en) | Preparation method of slowly digestible starch | |
JP2966898B2 (en) | Food material and method for producing the same | |
CN110537559A (en) | Low-GI light-eating frozen sweet dough and preparation method thereof and frozen sweet dough bread | |
JPH04141055A (en) | Preparation of modified wheat flour | |
CN114158679B (en) | Processing method of instant brown rice brewing powder with high gelatinization degree and low digestion rate |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
121 | Ep: the epo has been informed by wipo that ep was designated in this application |
Ref document number: 20944824 Country of ref document: EP Kind code of ref document: A1 |
|
NENP | Non-entry into the national phase |
Ref country code: DE |
|
122 | Ep: pct application non-entry in european phase |
Ref document number: 20944824 Country of ref document: EP Kind code of ref document: A1 |