WO2021259376A1 - Method for reducing surface cracks of casting blank by using ferrite phase - Google Patents

Method for reducing surface cracks of casting blank by using ferrite phase Download PDF

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Publication number
WO2021259376A1
WO2021259376A1 PCT/CN2021/102405 CN2021102405W WO2021259376A1 WO 2021259376 A1 WO2021259376 A1 WO 2021259376A1 CN 2021102405 W CN2021102405 W CN 2021102405W WO 2021259376 A1 WO2021259376 A1 WO 2021259376A1
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WIPO (PCT)
Prior art keywords
cast slab
ferrite
temperature
cooling
ferrite phase
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PCT/CN2021/102405
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French (fr)
Chinese (zh)
Inventor
王迎春
徐国栋
徐荣军
范正洁
阮晓明
王妍
Original Assignee
宝山钢铁股份有限公司
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Application filed by 宝山钢铁股份有限公司 filed Critical 宝山钢铁股份有限公司
Priority to EP21829482.5A priority Critical patent/EP4144459A4/en
Priority to JP2022576137A priority patent/JP2023530911A/en
Priority to KR1020227044630A priority patent/KR20230015949A/en
Publication of WO2021259376A1 publication Critical patent/WO2021259376A1/en

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D11/00Continuous casting of metals, i.e. casting in indefinite lengths
    • B22D11/16Controlling or regulating processes or operations
    • B22D11/22Controlling or regulating processes or operations for cooling cast stock or mould
    • B22D11/225Controlling or regulating processes or operations for cooling cast stock or mould for secondary cooling
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D11/00Continuous casting of metals, i.e. casting in indefinite lengths
    • B22D11/12Accessories for subsequent treating or working cast stock in situ
    • B22D11/124Accessories for subsequent treating or working cast stock in situ for cooling
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D11/00Continuous casting of metals, i.e. casting in indefinite lengths
    • B22D11/12Accessories for subsequent treating or working cast stock in situ
    • B22D11/124Accessories for subsequent treating or working cast stock in situ for cooling
    • B22D11/1246Nozzles; Spray heads
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D11/00Continuous casting of metals, i.e. casting in indefinite lengths
    • B22D11/12Accessories for subsequent treating or working cast stock in situ
    • B22D11/128Accessories for subsequent treating or working cast stock in situ for removing
    • B22D11/1287Rolls; Lubricating, cooling or heating rolls while in use
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/84Controlled slow cooling
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D9/00Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
    • C21D9/0081Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for slabs; for billets
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/56General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering characterised by the quenching agents
    • C21D1/60Aqueous agents
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/62Quenching devices
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/62Quenching devices
    • C21D1/667Quenching devices for spray quenching
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00Microstructure comprising significant phases
    • C21D2211/005Ferrite

Definitions

  • the invention belongs to the technical field of continuous casting, and in particular relates to a method for improving surface cracks of a cast slab by using a ferrite phase.
  • the internal and external quality of the slab is a matter of great concern to metallurgical workers.
  • the internal quality problems of the cast slab are mainly manifested in uneven composition, such as looseness, shrinkage, and cracks.
  • the external quality problems are defects such as slag inclusion and cracks. These defects will be inherited into the subsequent rolled products. Therefore, it is hoped to produce products with excellent internal and external structure of the billet.
  • slab cracks are the result of the combined effect of metallurgical and mechanical factors in the continuous casting process. Whether the slab cracks depends on the structure and properties of the steel, solidification metallurgical behavior, casting machine process parameters and equipment operating conditions. Controlling the slab structure is one of the effective ways to improve the overall performance of the material.
  • the method of controlling the subcooling of the molten steel, electromagnetic stirring, adding aluminum titanium or rare earth elements and adding nucleating agents is usually used to control the casting state of the slab organization.
  • the surface layer structure of the cast slab can also be controlled by changing the cooling rate and the heating history of the cast slab.
  • the cast slab is still in the austenite single-phase zone when it exits the mold, so the influence of the mold and cooling strength on the surface structure is very important.
  • the surface cracks of the cast slab generally occur in the straightening section of the casting machine, because the continuous casting slab is subjected to straightening in this area, thereby generating tensile stress on the upper surface of the casting slab, and the low plastic structure of the casting slab is under the action of tensile stress. Cracks are generated, so by controlling the cooling of the billet in the casting machine before the straightening zone of the caster, the structure of the billet can be effectively controlled and the mechanical properties of the billet can be improved.
  • Patent CN 110653352 A In order to eliminate the surface cracks of the cast slab caused by ferrite, a row of cooling water nozzles with a small spray angle is added before the straightening section to provide a narrow area strong cooling belt to eliminate the surface proeutectoid ferrite to control the cast slab Surface cracks.
  • Patent CN107695313 A also uses rapid quenching to eliminate the precipitation of ferrite and carbonitride on the surface of the cast slab, avoid embrittlement, and reduce the surface cracks of the cast slab by improving the plasticity of the cast slab.
  • Patent CN 105478704 B establishes a lifting device for the secondary cold water spray frame, which can realize the dynamic control of the secondary cooling water cooling area and the automatic adjustment of the water volume. This method avoids the direct spray of the secondary cold water on the corners of the casting slab that causes the temperature to be too low or temperature changes Initiated corner cracks.
  • the purpose of the present invention is to provide a method for improving the surface cracks of a cast slab by using the ferrite phase, and to reduce the surface cracks of the cast slab by forming a high proportion of ferrite structure on the surface of the cast slab.
  • the method can control the surface layer structure of the cast slab, improve the surface plasticity of the cast slab, and reduce the surface cracks of the cast slab.
  • a method for improving the surface cracks of cast slabs by using the ferrite phase In the production of metallurgical continuous casting, the surface temperature of the cast slabs is controlled to keep the temperature at the austenite-to-ferrite transformation temperature for a long time to obtain a high proportion The ferrite phase of the cast slab must reach more than 35% before the straightening point of the caster.
  • a method for improving the surface cracks of a cast slab by using the ferrite phase of the present invention In the production of metallurgical continuous casting, a steel grade with a carbon content of 0 ⁇ C ⁇ 0.25% is formed into a cast slab, and the surface layer of the cast slab is controlled. Temperature, keep the surface temperature of the cast slab within the austenite to ferrite transformation temperature range, so that the ferrite ratio of the cast slab surface reaches 35% or more before the straightening point of the caster, and then enter the caster for straightening point.
  • the smelted steel will be solidified in the mold to form a solid cast slab with a certain thickness.
  • the cast slab temperature will be 1000-1250°C.
  • the cast slab will be cooled down.
  • the cast slab will be transported by the support rollers while cooling down.
  • the cast slab will enter the arc-shaped section area, and the continuous transportation will reach the straightening point of the caster.
  • the arc-shaped cast slab will be straightened.
  • the horizontal section of the casting machine is completely solidified and transported out of the casting machine.
  • the present invention controls the surface temperature of the casting slab before the casting slab reaches the straightening point of the casting machine.
  • the temperature of the solid casting slab formed after passing through the crystallizer is relatively high.
  • the temperature of the casting slab can be lowered by cooling water.
  • the surface temperature of the cast slab is within the transformation temperature range of austenite to ferrite, and the cooling rate for cooling can be determined according to the continuous cooling characteristic CCT curve of the steel grade.
  • the present invention focuses on controlling the temperature of the surface layer of the cast slab after cooling to keep it within the austenite-to-ferrite transformation temperature range, so as to realize the transformation from austenite to ferrite.
  • the ferrite phase ratio of the cast slab surface layer needs to be more than 35% before the straightening point of the casting machine. After this condition is met, the casting slab under the phase ratio can enter the straightening point of the casting machine to reduce the arc
  • the shaped cast billet is straightened into a horizontal cast billet.
  • the cast slab when the cast slab starts to cool down, and when to keep the surface temperature of the cast slab within the austenite-to-ferrite transformation temperature range, it can be adjusted according to the production situation, as long as the iron on the surface of the cast slab is straightened before the straightening point of the casting machine.
  • the ratio of the element body should be more than 35%.
  • the surface layer of the cast slab refers to the part whose thickness is within 10 mm.
  • the ferrite phase ratio of the cast slab surface layer is controlled above 35%, and the control of the surface temperature of the cast slab is aimed at the control of the thickness of the cast slab within 10mm.
  • the continuous cooling characteristic CCT curve of the steel grade determines the cooling rate range at which the cast slab of the steel grade can be transformed into the ferrite phase.
  • the cooling rate range cools the cast slab so that the surface layer temperature of the cast slab falls within the austenite-to-ferrite transformation temperature range, and then remains within the above-mentioned temperature range.
  • the present invention controls the surface temperature of the cast slab in the arc section of the caster and keeps it within the austenite to ferrite transformation temperature range.
  • the cooling rate range for obtaining the ferrite phase of the steel grade is 3 to 0.05° C./s.
  • the cooling rate ranges from 3 to 0.1°C/s, and further is 1.5 to 0.08°C/s.
  • the cooling rate can be controlled by parameter settings in the cooling program. The cooling rate is more conducive to maintaining the temperature of the cast slab near the ferrite transformation temperature, which is conducive to the formation of ferrite.
  • the temperature of the surface layer of the cast slab is controlled so that the ferrite ratio of the surface layer of the cast slab reaches 35%-100%, preferably 35%-75%, before the straightening point of the caster.
  • This ferrite ratio can make the cast slab
  • the surface layer is well shaped, and the time for forming the ferrite ratio is easier to satisfy and control.
  • the austenite-to-ferrite transformation temperature range of the cast slab surface layer is 900°C to 600°C, and the holding time is 0.44 to 35 minutes.
  • the surface temperature of the cast slab is controlled by cooling water.
  • the above-mentioned cooling type what is mentioned here is a kind of cooling that maintains the temperature.
  • the above-mentioned cooling that lowers the surface temperature of the cast slab to the transformation temperature of austenite to ferrite can be called the first cooling, and the surface temperature of the cast slab is kept at austenite.
  • the cooling to the ferrite transformation temperature is called the second cooling.
  • the present invention can be sprayed with cooling water (that is, the second cooling mentioned above)
  • the temperature of the surface layer of the cast slab is maintained. This is because the center temperature of the cast slab is relatively high. If cooling is not performed, the transfer of heat from the center to the surface of the cast slab will also increase the temperature of the surface of the cast slab. Therefore, the use of cooling water can control the surface temperature of the cast slab.
  • the continuous casting online model is used to calculate the amount of cooling water required to obtain the surface temperature of the cast slab, so that the surface temperature of the cast slab is maintained within the austenite to ferrite transformation temperature range.
  • the model belongs to a commonly used model in this field, and the continuous casting online model of the present invention is a continuous casting secondary cooling online model.
  • the model can calculate the amount of cooling water required in different areas of the slab according to the target temperature set by the process, so as to achieve the purpose of controlling the temperature of the slab.
  • the spray amount of cooling water used in the second cooling within the range of 0-0.87L/kg (including 0 and 0.87), which can control the surface temperature of the cast slab from austenite to ferrite Within the transition temperature range.
  • the unit of spray water L/kg refers to the amount of water sprayed per unit mass of steel.
  • the surface of the cast slab is maintained at the austenite-to-ferrite transformation temperature for a long time by means of cooling water, and the secondary cooling nozzle is used to move the surface of the cast slab to the surface of the cast slab.
  • Water spray cooling is used to control the surface temperature of the cast slab. Specifically, for the present invention, uniform cooling can be achieved under low water volume (0-0.62L/kg).
  • non-spray cooling can be used, that is, to maintain air cooling, also called dry cooling.
  • dry cooling can also be used if the second cooling rate is lower.
  • the model will reduce the amount of water sprayed to prevent the surface temperature of the slab from falling, and even when the temperature drops too fast, it will control the use of air cooling to maintain the casting The surface temperature of the blank.
  • Air cooling is used to control the surface temperature of the cast slab.
  • the support roll of the arc section of the caster is not cooled by the cooling water, which will easily lead to a higher temperature. Therefore, it is necessary to cool the support roll of the arc section of the casting machine.
  • the present invention performs internal cooling on the support roll of the arc section of the casting machine. Specifically, cooling water can be passed into the support roll to control the surface temperature of the support roll below 550°C to prevent The sector is damaged.
  • the fan-shaped section here can also be called an arc-shaped section.
  • the method of the invention uses cooling water to control the surface temperature of the cast slab before the straightening section of the caster, so that the surface of the cast slab is kept constant for a long time near the phase transition temperature of the steel grade austenite to ferrite.
  • a secondary cooling nozzle with good atomization effect and uniform spraying is required.
  • the nozzle can perform uniform spray cooling with low water volume.
  • the cast slab needs to be dry-cooled for a constant temperature, that is, continuous casting operations are performed without spraying secondary cold water. In this case, good internal cooling of the fan-shaped support roller is required to avoid damage to the fan-shaped support roller and bearings caused by the high temperature of the casting billet.
  • the surface temperature of the cast slab after exiting the mold is in the high temperature zone, generally between 1000 and 1250 °C.
  • the surface structure of the cast slab is in the austenite zone.
  • the steel grade has higher plasticity and is not easy to Cracks occur.
  • the surface layer structure temperature of the cast slab continues to drop.
  • the transformation from austenite to pro-eutectoid ferrite in the cast slab is a diffusion-type phase transition.
  • the pro-eutectoid ferrite first occupies the original austenite grain boundary. It nucleates and grows along the grain boundary.
  • the ferrite within the grain begins to nucleate.
  • a relatively coarse proeutectoid ferrite film has been formed on the original austenite grain boundary.
  • the structure is affected by the straightening tensile stress when the cast slab passes through the straightening zone. The stress will crack at the ferrite film at the austenite grain boundary and will gradually expand in the later stage.
  • the slab is straightened, if the ferrite ratio in the slab structure is low, less than 35%, the film-like proeutectoid ferrite is likely to cause stress concentration and cracks, but if the ferrite ratio exceeds 35%, it will not Strain concentration will occur and cracks can be avoided.
  • thermodynamics and kinetics that is, one is temperature and the other is duration.
  • the phase transition temperature at different cooling rates is obtained.
  • steel grades can form ferrite in the cooling rate range of 3 ⁇ 0.05°C/s and the temperature range of 900°C ⁇ 600°C. If the surface temperature of the cast slab is controlled near the phase transition temperature for a long time, a large amount of ferrite will be formed on the surface of the cast slab.
  • the time range of the present invention is 0.44 to 35 min. When the proportion of ferrite exceeds 35%, the ductility of the cast slab structure will be significantly improved, which can avoid the occurrence of cracks.
  • the arc section adopts a weak cooling method.
  • the cooling method with a cooling strength of less than 3°C/s keeps the surface temperature of the cast slab constant within the temperature range of austenite to ferrite transformation. And keep it until the straightening section. In this way, a high-proportion ferrite layer is formed on the surface of the cast slab, instead of a low-proportion ferrite film with only austenite grain boundaries.
  • the surface cracks of the cast slab will not occur due to the concentration of stress on the grain boundary.
  • the method is that the surface of the cast slab is kept constant for a long time near the phase transition temperature of the steel austenite to ferrite.
  • the key points are: one is constant for a long time, and the other is that the temperature is controlled at the phase transition temperature. nearby.
  • the method of the present invention controls the surface temperature of the cast slab in the arc section of the casting machine to keep the surface temperature of the cast slab constant near the phase transition temperature of the steel grade for a long time. Through this process, a large amount of ferrite phase can be formed on the surface of the cast slab. .
  • the high-proportion ferrite phase cast slab passes through the straightening area of the caster, because there is a large amount of ferrite phase in the structure, the tensile stress of the arc surface of the cast slab will not be concentrated at the grain boundary, so it is not It will tear the grain boundaries, so as to avoid the occurrence of cracks on the surface of the cast slab.
  • This technology is very helpful to improve the surface plasticity of the cast slab, reduce the occurrence of surface cracks of the cast slab, and improve the surface quality of the product.
  • Figure 1A is a physical schematic diagram of the surface layer microstructure of the cast slab of Comparative Example 1;
  • FIG. 1B is a physical schematic diagram of the microstructure of the surface layer of the cast slab in Example 3.
  • FIG. 1B is a physical schematic diagram of the microstructure of the surface layer of the cast slab in Example 3.
  • Fig. 2 shows the CCT curve of the steel grade of the following Example 1, and the figure shows the relationship between the evolution of the steel grade and the temperature and time at several cooling rates. From the figure, the austenite to ferrite transformation temperature of the steel grade at a certain cooling rate can be obtained, as well as the time to obtain a certain proportion of ferrite.
  • the abscissa in the figure represents the cooling time
  • the ordinate represents the temperature
  • many parabolic-like curves in the figure represent the cooling rate.
  • the F zone in the figure is the formation of ferrite
  • the P zone represents pearlite
  • the CCT curve in Figure 2 can also be used to obtain the transformation temperature from austenite to ferrite, which is 560-620°C.
  • the retention time of the austenite to ferrite transformation temperature of Example 1 the present invention obtained according to research and measurement.
  • the retention time maintained at 0.44 to 35 min can ensure that the ferrite ratio on the surface of the cast slab reaches more than 35%.
  • Example 1 The element content of steel type 1 is C: 0.08%, Si: 0.14%, Mn: 1.69%, Cr: 0.41%, Mo: 0.02%, and the balance is iron and unavoidable impurities.
  • the cooling rate range for obtaining ferrite is less than 0.1°C/S.
  • This embodiment uses a cooling rate of 0.1°C/s. At this cooling rate, the austenite-to-ferrite transformation temperature is 620°C, and the surface layer of the cast slab needs to be maintained for 11.67min A ferrite ratio higher than 35% can be formed, and the process is completed before the straightening point. After production, the casting billet sample was observed through a metallographic microscope and calculated to form a ferrite ratio of more than 35%.
  • Example 2 The element content of steel type 2 is C: 0.16%, Si: 0.07%, Mn: 1.04%, Cr: 0.88%, Ti: 0.02%, the balance is iron and inevitable impurities, which can be changed according to the continuous cooling characteristics
  • the cooling rate to obtain ferrite is 0.1 ⁇ 3°C/s
  • the austenite-to-ferrite transformation temperature is 750°C at a cooling rate of 0.1°C/s
  • the austenite-to-ferrite transformation temperature is at a cooling rate of 3°C/s
  • the ferrite transformation temperature is 630°C.
  • Example 2 a cooling rate of 0.2°C/s was used for cooling, and then the surface temperature of the cast slab was maintained at 720°C for 10 minutes, and the process was completed before the straightening point. After production, the casting billet sample was observed through a metallographic microscope and calculated to form a ferrite ratio of more than 35%.
  • Example 3 The element content of steel type 3 is C: 0.077%, Si: 0.09%, Mn: 1.45%, Cr: 0.03%, Mo: 0.01%, the balance is iron and inevitable impurities, which can be determined according to the continuous cooling characteristics.
  • the cooling rate to obtain ferrite is 0.1 ⁇ 3°C/s
  • the transformation temperature of austenite to ferrite at a cooling rate of 0.1°C/S is 790°C
  • the austenite to ferrite is transformed at a cooling rate of 3°C/s
  • the ferrite transformation temperature is 730°C.
  • Example 3 a cooling rate of 0.3°C/s was used for cooling, and then the surface temperature of the cast slab was maintained at 780°C for a holding time of 7.22min, and the process was completed before the straightening point. After production, the casting billet sample was observed through a metallographic microscope and calculated to form a ferrite ratio of more than 35%.
  • Example 4 The element content of steel type 4 is C: 0.09%, Si: 0.17%, Mn: 0.83%, Cr: 0.02%, and the balance is iron and inevitable impurities. According to continuous cooling characteristics, ferrite can be obtained The cooling rate is 0.1 ⁇ 3°C/S, the transformation temperature of austenite to ferrite at a cooling rate of 0.1°C/S is 830°C, and the transformation temperature of austenite to ferrite at a cooling rate of 3°C/S The temperature is 780°C. In Example 3, a cooling rate of 0.5° C./s was used for cooling, and then the surface temperature of the cast slab was kept at 820° C. for a holding time of 5.67 min, and the process was completed before the straightening point. After production, the casting billet sample was observed through a metallographic microscope and calculated to form a ferrite ratio of more than 35%.
  • Comparative Example 1 The element content of the steel of Comparative Example 1 is C: 0.077%, Si: 0.09%, Mn: 1.45%, Cr: 0.03%, Mo: 0.01%, and the balance is iron and inevitable impurities.
  • Conventional The process is for casting. The slab is cooled after it comes out of the mold. The surface of the slab at the exit of the mold is 1200°C. Under the action of the secondary cooling water in the arc zone, the surface temperature of the slab gradually decreases. The surface temperature of the slab is 750°C. At this time, in the structure of the surface of the cast slab, ferrite precipitation occurs at the austenite grain boundary, as shown in Figure 1A. The surface of the cast slab produces tensile stress under the action of straightening, so cracks occur at the precipitated ferrite at the austenite grain boundary.
  • Fig. 1A and Fig. 1B are the cast slabs formed by the steel types in Comparative Example 1 and Example 3 after passing through the straightening point and then cooled to form cast slabs.
  • the surface microstructure percentages of the cast slabs are tested. It can be seen from the figure that the surface microstructure of the casting slab of Comparative Example 1 is mainly austenite, and the ferrite content is only 8%. Therefore, when subjected to external force, stress concentration is easily formed at the ferrite and cracks are generated.
  • Example 3 The cast slab was kept at 780°C at a cooling rate of 0.3°C/s for 7.22 min. The surface of the cast slab will form 95% ferrite when it enters the straightening point. This structure is subject to external force. There will be no stress concentration, and ferrite has better shaping, so no cracks occur.

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Abstract

A method for reducing surface cracks of a casting blank by using a ferrite phase. Cooling water is used to control the surface layer temperature of the casting blank before a straightening section of a casting machine, so that the surface layer of the casting blank is kept constant for a long time in the vicinity of the phase transition temperature of transition of a steel austenite to a ferrite; due to the constant temperature for a long time, a ferrite layer is formed on the surface layer of the casting blank, thereby improving the proportion of ferrite in the surface layer structure of the casting blank, improving the plasticity of the surface layer structure of the casting blank by means of high plasticity of the ferrite, and thus reducing cracks generated on an inner arc surface of the casting blank under the tensile stress of a straightening area. The method can control the surface layer structure of the casting blank, improve the plasticity of the surface layer of the casting blank, and reduce the surface cracks of the casting blank.

Description

一种利用铁素体相改善铸坯表面裂纹的方法Method for improving surface cracks of casting slab by using ferrite phase 技术领域Technical field
本发明属于连铸技术领域,具体涉及一种利用铁素体相改善铸坯表面裂纹的方法。The invention belongs to the technical field of continuous casting, and in particular relates to a method for improving surface cracks of a cast slab by using a ferrite phase.
背景技术Background technique
在冶金连铸的生产过程中,铸坯的内部与外部质量是冶金工作者十分关注的问题。铸坯的内部质量问题主要表现在成分不均匀,有疏松、有缩孔、有裂纹等缺陷,外部质量问题则是有夹渣、有裂纹等缺陷,这些缺陷都会遗传到后续的轧制产品中,因此希望生产出铸坯内部组织和外部组织有优良的的产品。In the production process of metallurgical continuous casting, the internal and external quality of the slab is a matter of great concern to metallurgical workers. The internal quality problems of the cast slab are mainly manifested in uneven composition, such as looseness, shrinkage, and cracks. The external quality problems are defects such as slag inclusion and cracks. These defects will be inherited into the subsequent rolled products. Therefore, it is hoped to produce products with excellent internal and external structure of the billet.
铸坯裂纹形成是连铸过程中冶金因素和力学因素综合作用的结果,铸坯是否产生裂纹决定于钢的组织性能、凝固冶金行为、铸机工艺参数和设备运行状态。控制铸坯组织是提高材料综合性能的有效方式之一,连铸过程中通常采用控制钢液的过冷度、电磁搅拌、加铝钛或稀土元素等增加形核剂的方法控制铸坯铸态组织。连铸过程中也可以通过改变冷却速度及铸坯受热历程控制铸坯的表层组织。铸坯在出结晶器时还处于奥氏体单相区,因此结晶器和冷却强度的大小对表层组织的影响很关键。铸坯普遍发生表面裂纹都是在铸机的矫直段,因为在该区域连铸坯受到矫直作用从而在铸坯的上表面产生拉应力,铸坯的低塑性组织在拉应力的作用下产生裂纹,因此在铸机矫直区之前通过控制铸坯在铸机里冷却可以有效地控制铸坯组织,改善铸坯力学性能。The formation of slab cracks is the result of the combined effect of metallurgical and mechanical factors in the continuous casting process. Whether the slab cracks depends on the structure and properties of the steel, solidification metallurgical behavior, casting machine process parameters and equipment operating conditions. Controlling the slab structure is one of the effective ways to improve the overall performance of the material. In the continuous casting process, the method of controlling the subcooling of the molten steel, electromagnetic stirring, adding aluminum titanium or rare earth elements and adding nucleating agents is usually used to control the casting state of the slab organization. In the continuous casting process, the surface layer structure of the cast slab can also be controlled by changing the cooling rate and the heating history of the cast slab. The cast slab is still in the austenite single-phase zone when it exits the mold, so the influence of the mold and cooling strength on the surface structure is very important. The surface cracks of the cast slab generally occur in the straightening section of the casting machine, because the continuous casting slab is subjected to straightening in this area, thereby generating tensile stress on the upper surface of the casting slab, and the low plastic structure of the casting slab is under the action of tensile stress. Cracks are generated, so by controlling the cooling of the billet in the casting machine before the straightening zone of the caster, the structure of the billet can be effectively controlled and the mechanical properties of the billet can be improved.
专利CN 110653352 A为了消除铁素体引发的铸坯表面裂纹在矫直段前增加一排小喷射角冷却水喷嘴,提供一个窄区域强冷带来消除表面先共析铁素体来控制铸坯表面裂纹。专利CN107695313 A同样采用快冷淬火的方式消除铸坯表层的铁素体和碳氮化物析出,避免脆化,通过提高铸坯塑性的方法来减少铸坯表面裂纹。专利CN 105478704 B建立了二冷水喷淋架升降装置,可实现二冷水冷却面积的动态控制和水量自动调整,通过该方式避免了二冷水直接喷淋在铸坯角部导致温度过低或温度变化引发的角部裂纹。Patent CN 110653352 A In order to eliminate the surface cracks of the cast slab caused by ferrite, a row of cooling water nozzles with a small spray angle is added before the straightening section to provide a narrow area strong cooling belt to eliminate the surface proeutectoid ferrite to control the cast slab Surface cracks. Patent CN107695313 A also uses rapid quenching to eliminate the precipitation of ferrite and carbonitride on the surface of the cast slab, avoid embrittlement, and reduce the surface cracks of the cast slab by improving the plasticity of the cast slab. Patent CN 105478704 B establishes a lifting device for the secondary cold water spray frame, which can realize the dynamic control of the secondary cooling water cooling area and the automatic adjustment of the water volume. This method avoids the direct spray of the secondary cold water on the corners of the casting slab that causes the temperature to be too low or temperature changes Initiated corner cracks.
从上面的专利分析可以看出,当前的解决铸坯表面裂纹的技术路线主要有两个,一个是采用高温运行的方式,提高铸坯表层温度,避免相变以及在晶界析出铁素体膜和碳氮析出物, 该种方式下连铸机设备一直在高温状态下,对设备的精度保证和寿命都会造成很大的影响。另一种方式采用低温路线,避开钢种的第三脆性区,该种方式需要很大的冷却水量,对能源和环境有很大的影响。因此需要从钢种本身角度出发找到一种提高钢种塑性的组织状态。It can be seen from the above patent analysis that there are two main current technical routes to solve the surface cracks of the cast slab. One is to use high-temperature operation to increase the surface temperature of the cast slab, avoid phase transformation and precipitate ferrite film at the grain boundary. With carbon and nitrogen precipitates, the continuous caster equipment has been kept at a high temperature in this way, which will have a great impact on the accuracy and life of the equipment. The other method uses a low temperature route to avoid the third brittle zone of steel grades. This method requires a large amount of cooling water and has a great impact on energy and the environment. Therefore, it is necessary to find a state of organization that improves the plasticity of the steel from the perspective of the steel itself.
发明内容Summary of the invention
本发明目的在于提供一种利用铁素体相改善铸坯表面裂纹的方法,利用在铸坯表层形成高比例的铁素体组织的方法来减少铸坯表面裂纹。该方法可以控制铸坯表层组织,提高铸坯表层塑性,降低铸坯表面裂纹。The purpose of the present invention is to provide a method for improving the surface cracks of a cast slab by using the ferrite phase, and to reduce the surface cracks of the cast slab by forming a high proportion of ferrite structure on the surface of the cast slab. The method can control the surface layer structure of the cast slab, improve the surface plasticity of the cast slab, and reduce the surface cracks of the cast slab.
本发明的技术方案为:The technical scheme of the present invention is:
一种利用铁素体相改善铸坯表面裂纹的方法,在冶金连铸的生产中,通过控制铸坯表层温度,让该温度长时间保持在奥氏体向铁素体转变温度,得到高比例的铁素体相,使铸坯表层的铁素体相比例在铸机矫直点之前需达到35%以上。A method for improving the surface cracks of cast slabs by using the ferrite phase. In the production of metallurgical continuous casting, the surface temperature of the cast slabs is controlled to keep the temperature at the austenite-to-ferrite transformation temperature for a long time to obtain a high proportion The ferrite phase of the cast slab must reach more than 35% before the straightening point of the caster.
具体地,本发明的一种利用铁素体相改善铸坯表面裂纹的方法,在冶金连铸的生产中,将碳含量在0<C≤0.25%的钢种形成铸坯,控制铸坯表层温度,让该铸坯表层温度保持在奥氏体向铁素体转变温度范围内,使得铸坯表层的铁素体相比例在铸机矫直点之前达到35%以上,之后进入铸机矫直点。Specifically, a method for improving the surface cracks of a cast slab by using the ferrite phase of the present invention. In the production of metallurgical continuous casting, a steel grade with a carbon content of 0<C≦0.25% is formed into a cast slab, and the surface layer of the cast slab is controlled. Temperature, keep the surface temperature of the cast slab within the austenite to ferrite transformation temperature range, so that the ferrite ratio of the cast slab surface reaches 35% or more before the straightening point of the caster, and then enter the caster for straightening point.
在冶金连铸的生产中,经过冶炼后的钢种会在结晶器中凝固形成一定厚度的固体铸坯,此时的铸坯温度会在1000~1250℃。之后会对铸坯进行降温,铸坯会一边降温一边由支撑辊运输,经过弯曲过程铸坯进入弧形段区域,继续运输会达到铸机矫直点,对弧形铸坯进行矫直,然后经过铸机水平段进行完全凝固输送出铸机。In the production of metallurgical continuous casting, the smelted steel will be solidified in the mold to form a solid cast slab with a certain thickness. At this time, the cast slab temperature will be 1000-1250°C. Afterwards, the cast slab will be cooled down. The cast slab will be transported by the support rollers while cooling down. After the bending process, the cast slab will enter the arc-shaped section area, and the continuous transportation will reach the straightening point of the caster. The arc-shaped cast slab will be straightened. The horizontal section of the casting machine is completely solidified and transported out of the casting machine.
本发明对铸坯表面温度的控制是在铸坯达到铸机矫直点之前进行,首先通过结晶器后形成固体的铸坯温度较高,可通过冷却水的方式对铸坯进行降温,将至铸坯表层温度在奥氏体向铁素体转变温度范围内,降温的冷却速率可根据钢种的连续冷却特性CCT曲线确定。本发明重点在于对降温后的铸坯的表层温度进行控制,使其保持在奥氏体向铁素体转变温度范围内,从而实现奥氏体向铁素体转变。经研究发现,需要将铸坯表层的铁素体相比例在铸机矫直点之前达到35%以上,满足这一条件后可将该相比例下的铸坯进入铸机矫直点,将弧形铸坯矫直为水平铸坯。The present invention controls the surface temperature of the casting slab before the casting slab reaches the straightening point of the casting machine. The temperature of the solid casting slab formed after passing through the crystallizer is relatively high. The temperature of the casting slab can be lowered by cooling water. The surface temperature of the cast slab is within the transformation temperature range of austenite to ferrite, and the cooling rate for cooling can be determined according to the continuous cooling characteristic CCT curve of the steel grade. The present invention focuses on controlling the temperature of the surface layer of the cast slab after cooling to keep it within the austenite-to-ferrite transformation temperature range, so as to realize the transformation from austenite to ferrite. Research has found that the ferrite phase ratio of the cast slab surface layer needs to be more than 35% before the straightening point of the casting machine. After this condition is met, the casting slab under the phase ratio can enter the straightening point of the casting machine to reduce the arc The shaped cast billet is straightened into a horizontal cast billet.
本发明对于铸坯何时就开始降温,何时开始保持铸坯表层温度在奥氏体向铁素体转变温 度范围内可根据生产状况调整,只要在铸机矫直点之前铸坯表层的铁素体相比例在35%以上即可。其中,铸坯表层是指铸坯厚度在10mm以内的部分。铸坯表层的铁素体相比例控制在35%以上,以及控制铸坯表层温度都是针对铸坯厚度在10mm以内部分的控制。According to the present invention, when the cast slab starts to cool down, and when to keep the surface temperature of the cast slab within the austenite-to-ferrite transformation temperature range, it can be adjusted according to the production situation, as long as the iron on the surface of the cast slab is straightened before the straightening point of the casting machine. The ratio of the element body should be more than 35%. Among them, the surface layer of the cast slab refers to the part whose thickness is within 10 mm. The ferrite phase ratio of the cast slab surface layer is controlled above 35%, and the control of the surface temperature of the cast slab is aimed at the control of the thickness of the cast slab within 10mm.
根据本发明所述一种利用铁素体相改善铸坯表面裂纹的方法,根据钢种的连续冷却特性CCT曲线确定该钢种的铸坯能够转变成铁素体相的冷却速度范围,以所述冷却速度范围对所述铸坯进行冷却,使得所述铸坯表层温度降至奥氏体向铁素体转变温度范围内,并在之后保持在上述温度范围内。具体地,本发明在铸机弧形段区域控制铸坯表层温度,保持在奥氏体向铁素体转变温度范围内。According to the method of the present invention for improving the surface cracks of the cast slab by using the ferrite phase, the continuous cooling characteristic CCT curve of the steel grade determines the cooling rate range at which the cast slab of the steel grade can be transformed into the ferrite phase. The cooling rate range cools the cast slab so that the surface layer temperature of the cast slab falls within the austenite-to-ferrite transformation temperature range, and then remains within the above-mentioned temperature range. Specifically, the present invention controls the surface temperature of the cast slab in the arc section of the caster and keeps it within the austenite to ferrite transformation temperature range.
进一步地,根据钢种的连续冷却特性CCT曲线得到获得钢种铁素体相的冷却速度范围为3~0.05℃/s。优选地,冷却速度范围为3~0.1℃/s,更进一步为1.5~0.08℃/s。冷却速度可在降温程序中通过参数设置得以控制,该冷却速度更加有利于铸坯温度保持在铁素体相变温度附近,利于铁素体生成。Furthermore, according to the continuous cooling characteristic CCT curve of the steel grade, the cooling rate range for obtaining the ferrite phase of the steel grade is 3 to 0.05° C./s. Preferably, the cooling rate ranges from 3 to 0.1°C/s, and further is 1.5 to 0.08°C/s. The cooling rate can be controlled by parameter settings in the cooling program. The cooling rate is more conducive to maintaining the temperature of the cast slab near the ferrite transformation temperature, which is conducive to the formation of ferrite.
进一步地,控制铸坯表层温度,使得铸坯表层的铁素体相比例在铸机矫直点之前达到35%~100%,优选为35%~75%,该铁素体比例能够使得铸坯表层获得很好的塑形,且形成该铁素体比例时间更加容易满足和控制。Further, the temperature of the surface layer of the cast slab is controlled so that the ferrite ratio of the surface layer of the cast slab reaches 35%-100%, preferably 35%-75%, before the straightening point of the caster. This ferrite ratio can make the cast slab The surface layer is well shaped, and the time for forming the ferrite ratio is easier to satisfy and control.
进一步,经研究发现,对于本发明的钢种来说,所述铸坯表层在奥氏体向铁素体转变温度范围为900℃~600℃,保持时间为0.44~35min。Further, it has been found through research that, for the steel grade of the present invention, the austenite-to-ferrite transformation temperature range of the cast slab surface layer is 900°C to 600°C, and the holding time is 0.44 to 35 minutes.
根据所述利用铁素体相改善铸坯表面裂纹的方法,通过冷却水控制铸坯表层温度。与上述降温式冷却不同的是,这里所说的是一种保持温度的冷却。为了与上述降温式冷却区分,可以将上述所说的把铸坯表层温度降温至奥氏体向铁素体转变温度进行的冷却称之为第一冷却,将铸坯表层温度保持在奥氏体向铁素体转变温度所进行的冷却称之为第二冷却。当将铸坯表层降温至设定的温度范围内后,还需要将铸坯表层的温度控制在设定的温度范围内,本发明可通过喷冷却水的方式(也即上述的第二冷却)将铸坯表层的温度保持。这是因为,铸坯中心温度较高,如果不进行冷却,中心的热量传递到铸坯表层还会让铸坯表层的温度升高。因此,采用冷却水能够控制铸坯表层温度。According to the method for improving the surface cracks of the cast slab by using the ferrite phase, the surface temperature of the cast slab is controlled by cooling water. Different from the above-mentioned cooling type, what is mentioned here is a kind of cooling that maintains the temperature. In order to distinguish it from the above-mentioned cooling type, the above-mentioned cooling that lowers the surface temperature of the cast slab to the transformation temperature of austenite to ferrite can be called the first cooling, and the surface temperature of the cast slab is kept at austenite. The cooling to the ferrite transformation temperature is called the second cooling. After the surface layer of the cast slab is cooled to within the set temperature range, the temperature of the surface layer of the cast slab needs to be controlled within the set temperature range. The present invention can be sprayed with cooling water (that is, the second cooling mentioned above) The temperature of the surface layer of the cast slab is maintained. This is because the center temperature of the cast slab is relatively high. If cooling is not performed, the transfer of heat from the center to the surface of the cast slab will also increase the temperature of the surface of the cast slab. Therefore, the use of cooling water can control the surface temperature of the cast slab.
利用连铸在线模型计算获得铸坯表层温度所需的冷却水量,使得铸坯表层温度保持在奥氏体向铁素体转变温度范围内。具体来说,该模型属于本领域常用模型,本发明的连铸在线模型为连铸二冷在线模型。根据传热原理,结合连铸工艺条件,例如钢液温度、铸坯拉速和冷却水等计算铸坯的表面温度。该模型可根据工艺设定的目标温度进行计算铸坯不同区域所 需要的冷却水量,从而达到控制铸坯温度的目的。使用时,只需设定铸坯表层需要保持的温度,利用连铸二冷在线模型即可计算出应该向铸坯表层的喷水量,并进行喷水冷却,控制铸坯表层温度保持在设定的范围内。The continuous casting online model is used to calculate the amount of cooling water required to obtain the surface temperature of the cast slab, so that the surface temperature of the cast slab is maintained within the austenite to ferrite transformation temperature range. Specifically, the model belongs to a commonly used model in this field, and the continuous casting online model of the present invention is a continuous casting secondary cooling online model. According to the principle of heat transfer, combined with continuous casting process conditions, such as molten steel temperature, slab drawing speed and cooling water, the surface temperature of the cast slab is calculated. The model can calculate the amount of cooling water required in different areas of the slab according to the target temperature set by the process, so as to achieve the purpose of controlling the temperature of the slab. When in use, you only need to set the temperature of the surface layer of the cast slab, and use the continuous casting secondary cooling online model to calculate the amount of water that should be sprayed to the surface of the cast slab, and perform water spray cooling to control the surface temperature of the cast slab to be maintained at the set temperature. Within a given range.
经研究,一般第二冷却所使用的冷却水的喷水量控制在0-0.87L/kg(包括0和0.87)范围内较为适宜,能够将铸坯表层温度控制在奥氏体向铁素体转变温度范围内。其中喷水量单位L/kg是指单位质量的钢所需喷水量。After research, it is generally appropriate to control the spray amount of cooling water used in the second cooling within the range of 0-0.87L/kg (including 0 and 0.87), which can control the surface temperature of the cast slab from austenite to ferrite Within the transition temperature range. The unit of spray water L/kg refers to the amount of water sprayed per unit mass of steel.
根据所述利用铁素体相改善铸坯表面裂纹的方法,进一步,通过冷却水的方式让铸坯表层长时间保持在奥氏体向铁素体转变温度,采用二次冷却喷嘴向铸坯表层进行喷水冷却,从而控制铸坯表层温度。具体地,对于本发明来说,在低水量(0-0.62L/kg)下能够实现均匀冷却。According to the method for improving the surface cracks of the cast slab by using the ferrite phase, further, the surface of the cast slab is maintained at the austenite-to-ferrite transformation temperature for a long time by means of cooling water, and the secondary cooling nozzle is used to move the surface of the cast slab to the surface of the cast slab. Water spray cooling is used to control the surface temperature of the cast slab. Specifically, for the present invention, uniform cooling can be achieved under low water volume (0-0.62L/kg).
或者,为了让铸坯表层长时间保持在奥氏体向铁素体转变温度,有时候要求的第一冷却的速度较低,可采用非喷水冷却,即保持空冷状态,也叫干式冷却。同样,为保持铸坯表层温度在奥氏体向铁素体转变的温度范围内,若需要的第二冷却速度较低,也可采用干式冷却。具体应用连铸二冷在线模型时,当第二冷却需要的速度较低时,模型会降低喷水量,避免铸坯表层温度降低,甚至当温度降低过快,会控制采用空冷的方式保持铸坯表面温度。采用空冷的方式控制铸坯表层温度,相应地,铸机弧形段的支撑辊没有冷却水的降温容易导致温度较高。因此需要对铸机弧形段支撑辊进行冷却,本发明对铸机弧形段的支撑辊进行内部冷却,具体可对支撑辊内部通冷却水,将支撑辊表面温度控制在550℃以下,防止扇形段损坏。这里的扇形段也可称为弧形段。Or, in order to keep the surface layer of the cast slab at the austenite-to-ferrite transformation temperature for a long time, sometimes the required first cooling rate is lower, and non-spray cooling can be used, that is, to maintain air cooling, also called dry cooling. . Similarly, in order to keep the surface temperature of the cast slab within the temperature range of the transformation from austenite to ferrite, dry cooling can also be used if the second cooling rate is lower. In the specific application of the continuous casting secondary cooling online model, when the second cooling required speed is low, the model will reduce the amount of water sprayed to prevent the surface temperature of the slab from falling, and even when the temperature drops too fast, it will control the use of air cooling to maintain the casting The surface temperature of the blank. Air cooling is used to control the surface temperature of the cast slab. Correspondingly, the support roll of the arc section of the caster is not cooled by the cooling water, which will easily lead to a higher temperature. Therefore, it is necessary to cool the support roll of the arc section of the casting machine. The present invention performs internal cooling on the support roll of the arc section of the casting machine. Specifically, cooling water can be passed into the support roll to control the surface temperature of the support roll below 550°C to prevent The sector is damaged. The fan-shaped section here can also be called an arc-shaped section.
本发明方法在铸机矫直段前采用冷却水控制铸坯表层温度,使该铸坯表面长时间恒定在钢种奥氏体向铁素体转变的相变温度附近。为了更好地通过冷却水控制铸坯表层温度,需采用雾化效果良好,喷淋均匀的二次冷却喷嘴。尤其是该喷嘴能够在低水量情况下进行均匀的喷雾冷却。在某些实际情况下,铸坯为了温度恒定需要干式冷却,即不喷二冷水进行连铸作业。此种情况下需要扇形段支撑辊有良好的内部冷却,避免铸坯高温导致的扇形段支撑辊和轴承损坏。为了将铸坯表层温度控制在某一温度需要采用连铸模型实时在线控制铸坯表层温度,当前较多的铸机已配置有连铸在线控制模型。通过该模型可设置铸坯表层温度所需要的冷却水量。通过长时间温度恒定在铸坯表层形成一层铁素体层,提高铸坯表层组织中铁素体的比例,利用铁素体高塑性改善铸坯表层组织塑性,从而降低铸坯内弧面在矫直区拉应力作 用下产生的裂纹。The method of the invention uses cooling water to control the surface temperature of the cast slab before the straightening section of the caster, so that the surface of the cast slab is kept constant for a long time near the phase transition temperature of the steel grade austenite to ferrite. In order to better control the surface temperature of the cast slab through the cooling water, a secondary cooling nozzle with good atomization effect and uniform spraying is required. In particular, the nozzle can perform uniform spray cooling with low water volume. In some practical situations, the cast slab needs to be dry-cooled for a constant temperature, that is, continuous casting operations are performed without spraying secondary cold water. In this case, good internal cooling of the fan-shaped support roller is required to avoid damage to the fan-shaped support roller and bearings caused by the high temperature of the casting billet. In order to control the surface temperature of the cast slab at a certain temperature, it is necessary to use a continuous casting model to control the surface temperature of the cast slab on-line in real time. At present, many casters have been equipped with continuous casting online control models. This model can be used to set the amount of cooling water required for the surface temperature of the cast slab. A ferrite layer is formed on the surface of the cast slab through a long-term temperature constant, which increases the proportion of ferrite in the surface structure of the cast slab, and uses the high plasticity of ferrite to improve the plasticity of the surface structure of the cast slab, thereby reducing the straightening of the inner arc of the cast slab. Cracks generated under tensile stress in the zone.
在连铸过程中,铸坯出结晶器后表层温度处于高温区,一般在1000~1250℃,此时铸坯表层组织处于奥氏体区,在单一相的情况下钢种塑性较高,不易产生裂纹。但随着在弧形区受到喷淋水冷却,铸坯表层组织温度不断下降。当温度达到相变温度时,铸坯中奥氏体向先共析铁素体的转变属于扩散型相变,在较低冷却速度下,先共析铁素体首先在原始奥氏体晶界形核并沿着晶界生长,在继续冷却后,晶内的铁素体才开始形核,此时,在原始奥氏体晶界已经形成了较为粗大的先共析铁素体膜。该组织在铸坯过矫直区时受到矫直拉应力的作用,应力会在奥氏体晶界铁素体膜处发生裂纹,并在后期逐渐扩展。铸坯在矫直时,若铸坯组织中铁素体比例较低,低于35%,膜状先共析铁素体易造成应力集中而形成裂纹,但若铁素体比例超过35%则不会发生应变集中,可避免裂纹的发生。影响铁素体析出比例的有热力学和动力学两个方面的因素,也就是一个是温度,一个是持续时间。根据钢种的连续冷却特性CCT曲线得到不同冷却速度下的相变温度。一般钢种可以在冷却速度范围为3~0.05℃/s和温度范围900℃~600℃下形成铁素体。若将铸坯表层温度长时间控制在相变温度附近则会在铸坯表层形成大量的铁素体,本发明的时间范围为0.44~35min。当铁素体比例超过35%铸坯组织塑性会显著提高,可以避免裂纹的发生。因此当铸坯过弯曲段后,也就是弧形段采用弱冷的方式,冷却强度小于3℃/s的冷却方式将铸坯表层温度恒定在奥氏体向铁素体转变的温度范围内,并一直保持到矫直段。如此在铸坯表层形成高比例的铁素体层,而不是只有奥氏体晶界的低比例铁素体膜。高比例铁素体层铸坯过矫直时不会因为应力在晶界集中而发生铸坯表面裂纹。本发明创新之一,即该方法就是铸坯表面长时间恒定在钢种奥氏体向铁素体转变的相变温度附近,关键点:一是长时间恒定,二是温度控制在相变温度附近。In the continuous casting process, the surface temperature of the cast slab after exiting the mold is in the high temperature zone, generally between 1000 and 1250 ℃. At this time, the surface structure of the cast slab is in the austenite zone. In the case of a single phase, the steel grade has higher plasticity and is not easy to Cracks occur. However, as the arc zone is cooled by spray water, the surface layer structure temperature of the cast slab continues to drop. When the temperature reaches the phase transition temperature, the transformation from austenite to pro-eutectoid ferrite in the cast slab is a diffusion-type phase transition. At a lower cooling rate, the pro-eutectoid ferrite first occupies the original austenite grain boundary. It nucleates and grows along the grain boundary. After cooling continues, the ferrite within the grain begins to nucleate. At this time, a relatively coarse proeutectoid ferrite film has been formed on the original austenite grain boundary. The structure is affected by the straightening tensile stress when the cast slab passes through the straightening zone. The stress will crack at the ferrite film at the austenite grain boundary and will gradually expand in the later stage. When the slab is straightened, if the ferrite ratio in the slab structure is low, less than 35%, the film-like proeutectoid ferrite is likely to cause stress concentration and cracks, but if the ferrite ratio exceeds 35%, it will not Strain concentration will occur and cracks can be avoided. There are two factors that affect the ratio of ferrite precipitation: thermodynamics and kinetics, that is, one is temperature and the other is duration. According to the continuous cooling characteristic CCT curve of the steel grade, the phase transition temperature at different cooling rates is obtained. Generally, steel grades can form ferrite in the cooling rate range of 3~0.05℃/s and the temperature range of 900℃~600℃. If the surface temperature of the cast slab is controlled near the phase transition temperature for a long time, a large amount of ferrite will be formed on the surface of the cast slab. The time range of the present invention is 0.44 to 35 min. When the proportion of ferrite exceeds 35%, the ductility of the cast slab structure will be significantly improved, which can avoid the occurrence of cracks. Therefore, when the cast slab passes through the curved section, that is, the arc section adopts a weak cooling method. The cooling method with a cooling strength of less than 3°C/s keeps the surface temperature of the cast slab constant within the temperature range of austenite to ferrite transformation. And keep it until the straightening section. In this way, a high-proportion ferrite layer is formed on the surface of the cast slab, instead of a low-proportion ferrite film with only austenite grain boundaries. When the cast slab with a high proportion of ferrite layer is over-straightened, the surface cracks of the cast slab will not occur due to the concentration of stress on the grain boundary. One of the innovations of the present invention, that is, the method is that the surface of the cast slab is kept constant for a long time near the phase transition temperature of the steel austenite to ferrite. The key points are: one is constant for a long time, and the other is that the temperature is controlled at the phase transition temperature. nearby.
本发明有益技术效果:The beneficial technical effects of the present invention:
本发明方法通过在铸机弧形段区域对铸坯表层温度进行控制,让铸坯表层温度长时间恒定在钢种相变温度附近,通过该工艺可以在铸坯表面形成大量的铁素体相。在该高比例铁素体相铸坯经过铸机矫直区域时,因在组织内有大量的铁素体相,因此铸坯内弧面的拉应力不会在晶界产生集中,也就不会撕裂晶界,从而避免铸坯表面裂纹的发生。该技术对提高铸坯表面塑性,减少铸坯表面裂纹发生,改善产品的表面质量非常有帮助。The method of the present invention controls the surface temperature of the cast slab in the arc section of the casting machine to keep the surface temperature of the cast slab constant near the phase transition temperature of the steel grade for a long time. Through this process, a large amount of ferrite phase can be formed on the surface of the cast slab. . When the high-proportion ferrite phase cast slab passes through the straightening area of the caster, because there is a large amount of ferrite phase in the structure, the tensile stress of the arc surface of the cast slab will not be concentrated at the grain boundary, so it is not It will tear the grain boundaries, so as to avoid the occurrence of cracks on the surface of the cast slab. This technology is very helpful to improve the surface plasticity of the cast slab, reduce the occurrence of surface cracks of the cast slab, and improve the surface quality of the product.
附图说明Description of the drawings
图1A为对比例1的铸坯表层微观组织实物示意图;Figure 1A is a physical schematic diagram of the surface layer microstructure of the cast slab of Comparative Example 1;
图1B为实施例3的铸坯表层微观组织实物示意图。FIG. 1B is a physical schematic diagram of the microstructure of the surface layer of the cast slab in Example 3. FIG.
图2实施例1钢种连铸冷却特性CCT曲线。Figure 2 Example 1 steel type continuous casting cooling characteristics CCT curve.
具体实施方式detailed description
下面结合实施例对本发明作进一步阐述,本领域技术人员应当理解,所述实施例仅用于示例,而不对本发明构成任何限制。The present invention will be further elaborated below in conjunction with the embodiments. Those skilled in the art should understand that the embodiments are only examples and do not constitute any limitation to the present invention.
下面详细说明本发明方法的实施过程:The following describes the implementation process of the method of the present invention in detail:
首先对钢种连续冷却特性CCT曲线进行测试或计算,得到该钢种获得铁素体的第一冷却的速度范围,该范围为3~0.05℃/s,并获得不同冷却速度下的奥氏体向铁素体转变的相变温度,该温度范围为900℃~600℃。冷却后保持900℃~600℃,保持时间为0.44~35min,该过程在矫直点前完成。First, test or calculate the continuous cooling characteristic CCT curve of the steel grade to obtain the first cooling rate range of the steel grade to obtain ferrite, which is 3~0.05℃/s, and obtain austenite at different cooling rates The phase transition temperature for ferrite transformation is in the range of 900°C to 600°C. After cooling, keep at 900℃~600℃, the holding time is 0.44~35min, the process is completed before the straightening point.
如图2所示为下述实施例1的钢种的CCT曲线,图中显示了若干种冷却速度下的钢种组织演化与温度和时间关系。从图中可以获得钢种在某一冷却速度下的奥氏体向铁素体转变温度,以及获得一定比例铁素体的时间。图2中,图中横坐标代表冷却时间,纵坐标代表温度,图中多条类似抛物线的曲线代表冷却速度,图中标注的F区就是形成铁素体区域,P区代表珠光体,B区代表贝氏体。可知,F区内所包含的冷却速度是能够形成铁素体的冷却速度范围。通过图2中CCT曲线还能获得奥氏体向铁素体的转变温度,即在560-620℃。而对于实施例1的奥氏体向铁素体转变温度的保持时间,本发明根据研究测定获得,保持时间保持在0.44~35min能够确保铸坯表面的铁素体相比例达到35%以上。Fig. 2 shows the CCT curve of the steel grade of the following Example 1, and the figure shows the relationship between the evolution of the steel grade and the temperature and time at several cooling rates. From the figure, the austenite to ferrite transformation temperature of the steel grade at a certain cooling rate can be obtained, as well as the time to obtain a certain proportion of ferrite. In Figure 2, the abscissa in the figure represents the cooling time, the ordinate represents the temperature, and many parabolic-like curves in the figure represent the cooling rate. The F zone in the figure is the formation of ferrite, the P zone represents pearlite, and the B zone Represents bainite. It can be seen that the cooling rate contained in the F zone is the range of the cooling rate capable of forming ferrite. The CCT curve in Figure 2 can also be used to obtain the transformation temperature from austenite to ferrite, which is 560-620°C. Regarding the retention time of the austenite to ferrite transformation temperature of Example 1, the present invention obtained according to research and measurement. The retention time maintained at 0.44 to 35 min can ensure that the ferrite ratio on the surface of the cast slab reaches more than 35%.
实施例1:钢种1元素含量为C:0.08%,Si:0.14%,Mn:1.69%,Cr:0.41%,Mo:0.02%,余量为铁及不可避免的杂质,根据连续冷却特性可获得铁素体的冷却速度范围小于0.1℃/S,本实施例采用0.1℃/s的冷却速度,该冷却速度下奥氏体向铁素体转变温度为620℃,需要保持11.67min铸坯表层可形成高于35%的铁素体比例,在矫直点之前完成该过程。生产后通过金相显微镜观察铸坯试样和计算得到形成了高于35%的铁素体比例。Example 1: The element content of steel type 1 is C: 0.08%, Si: 0.14%, Mn: 1.69%, Cr: 0.41%, Mo: 0.02%, and the balance is iron and unavoidable impurities. According to the continuous cooling characteristics, The cooling rate range for obtaining ferrite is less than 0.1°C/S. This embodiment uses a cooling rate of 0.1°C/s. At this cooling rate, the austenite-to-ferrite transformation temperature is 620°C, and the surface layer of the cast slab needs to be maintained for 11.67min A ferrite ratio higher than 35% can be formed, and the process is completed before the straightening point. After production, the casting billet sample was observed through a metallographic microscope and calculated to form a ferrite ratio of more than 35%.
实施例2:钢种2元素含量为C:0.16%,Si:0.07%,Mn:1.04%,Cr:0.88%,Ti:0.02%,余量为铁及不可避免的杂质,根据连续冷却特性可获得铁素体的冷却速度为0.1~3℃/s,在0.1℃/s的冷却速度下奥氏体向铁素体转变温度为750℃,在3℃/s的冷却速度下奥氏体向铁素体转变温度为630℃。实施例2采用0.2℃/s的冷却速度进行冷却,之后将铸坯表层 温度保持在720℃,保持时间为10min,在矫直点之前完成该过程。生产后通过金相显微镜观察铸坯试样和计算得到形成了高于35%的铁素体比例。Example 2: The element content of steel type 2 is C: 0.16%, Si: 0.07%, Mn: 1.04%, Cr: 0.88%, Ti: 0.02%, the balance is iron and inevitable impurities, which can be changed according to the continuous cooling characteristics The cooling rate to obtain ferrite is 0.1~3℃/s, the austenite-to-ferrite transformation temperature is 750℃ at a cooling rate of 0.1℃/s, and the austenite-to-ferrite transformation temperature is at a cooling rate of 3℃/s The ferrite transformation temperature is 630°C. In Example 2, a cooling rate of 0.2°C/s was used for cooling, and then the surface temperature of the cast slab was maintained at 720°C for 10 minutes, and the process was completed before the straightening point. After production, the casting billet sample was observed through a metallographic microscope and calculated to form a ferrite ratio of more than 35%.
实施例3:钢种3元素含量为C:0.077%,Si:0.09%,Mn:1.45%,Cr:0.03%,Mo:0.01%,余量为铁及不可避免的杂质,根据连续冷却特性可获得铁素体的冷却速度为0.1~3℃/s,在0.1℃/S的冷却速度下奥氏体向铁素体转变温度为790℃,在3℃/s的冷却速度下奥氏体向铁素体转变温度为730℃。实施例3采用0.3℃/s的冷却速度进行冷却,之后将铸坯表层温度保持在780℃,保持时间为7.22min,在矫直点之前完成该过程。生产后通过金相显微镜观察铸坯试样和计算得到形成了高于35%的铁素体比例。Example 3: The element content of steel type 3 is C: 0.077%, Si: 0.09%, Mn: 1.45%, Cr: 0.03%, Mo: 0.01%, the balance is iron and inevitable impurities, which can be determined according to the continuous cooling characteristics. The cooling rate to obtain ferrite is 0.1~3℃/s, the transformation temperature of austenite to ferrite at a cooling rate of 0.1℃/S is 790℃, and the austenite to ferrite is transformed at a cooling rate of 3℃/s The ferrite transformation temperature is 730°C. In Example 3, a cooling rate of 0.3°C/s was used for cooling, and then the surface temperature of the cast slab was maintained at 780°C for a holding time of 7.22min, and the process was completed before the straightening point. After production, the casting billet sample was observed through a metallographic microscope and calculated to form a ferrite ratio of more than 35%.
实施例4:钢种4元素含量为C:0.09%,Si:0.17%,Mn:0.83%,Cr:0.02%,余量为铁及不可避免的杂质,根据连续冷却特性可为获得铁素体的冷却速度为0.1~3℃/S,在0.1℃/S的冷却速度下奥氏体向铁素体转变温度为830℃,在3℃/S的冷却速度下奥氏体向铁素体转变温度为780℃。实施例3采用0.5℃/s的冷却速度进行冷却,之后将铸坯表层温度保持在820℃,保持时间为5.67min,在矫直点之前完成该过程。生产后通过金相显微镜观察铸坯试样和计算得到形成了高于35%的铁素体比例。Example 4: The element content of steel type 4 is C: 0.09%, Si: 0.17%, Mn: 0.83%, Cr: 0.02%, and the balance is iron and inevitable impurities. According to continuous cooling characteristics, ferrite can be obtained The cooling rate is 0.1~3℃/S, the transformation temperature of austenite to ferrite at a cooling rate of 0.1℃/S is 830℃, and the transformation temperature of austenite to ferrite at a cooling rate of 3℃/S The temperature is 780°C. In Example 3, a cooling rate of 0.5° C./s was used for cooling, and then the surface temperature of the cast slab was kept at 820° C. for a holding time of 5.67 min, and the process was completed before the straightening point. After production, the casting billet sample was observed through a metallographic microscope and calculated to form a ferrite ratio of more than 35%.
对比例1:对比例1的钢种元素含量为C:0.077%,Si:0.09%,Mn:1.45%,Cr:0.03%,Mo:0.01%,余量为铁及不可避免的杂质,采用常规工艺进行浇铸,铸坯从结晶器出来后进行冷却,结晶器出口处铸坯表面为1200℃,在弧形区二次冷却水的作用下铸坯表面温度逐渐降低,在进入矫直点时铸坯表面温度为750℃,此时在铸坯表面的组织中,奥氏体晶界发生铁素体析出,如图1A所示。铸坯表面在矫直的作用下产生拉应力,因此在奥氏体晶界的析出铁素体处发生裂纹。Comparative Example 1: The element content of the steel of Comparative Example 1 is C: 0.077%, Si: 0.09%, Mn: 1.45%, Cr: 0.03%, Mo: 0.01%, and the balance is iron and inevitable impurities. Conventional The process is for casting. The slab is cooled after it comes out of the mold. The surface of the slab at the exit of the mold is 1200℃. Under the action of the secondary cooling water in the arc zone, the surface temperature of the slab gradually decreases. The surface temperature of the slab is 750°C. At this time, in the structure of the surface of the cast slab, ferrite precipitation occurs at the austenite grain boundary, as shown in Figure 1A. The surface of the cast slab produces tensile stress under the action of straightening, so cracks occur at the precipitated ferrite at the austenite grain boundary.
以上只是列出4个钢种的冷却速度、相变温度和时间组合,并不排除其他钢种的其他工艺参数组合。The above only lists the cooling rate, phase transition temperature and time combination of the 4 steel grades, and does not exclude other process parameter combinations of other steel grades.
图1A和图1B分别是对比例1和实施例3中钢种形成的铸坯在经过矫直点后,经过冷却形成的铸坯,对该铸坯检测其表面微观组织百分比。图中可以看出,对比例1铸坯表面微观组织主要是奥氏体,铁素体含量仅为8%,因此在受到外力的作用时,容易在铁素体处形成应力集中而产生裂纹。实施例3铸坯在0.3℃/s的冷却速度下保持在780℃,持续7.22min,该铸坯表面在进入矫直点时会形成95%的铁素体,该组织在受到外力的情况,不会形成应力集中,而铁素体具有较好的塑形,因此未发生裂纹。Fig. 1A and Fig. 1B are the cast slabs formed by the steel types in Comparative Example 1 and Example 3 after passing through the straightening point and then cooled to form cast slabs. The surface microstructure percentages of the cast slabs are tested. It can be seen from the figure that the surface microstructure of the casting slab of Comparative Example 1 is mainly austenite, and the ferrite content is only 8%. Therefore, when subjected to external force, stress concentration is easily formed at the ferrite and cracks are generated. Example 3 The cast slab was kept at 780°C at a cooling rate of 0.3°C/s for 7.22 min. The surface of the cast slab will form 95% ferrite when it enters the straightening point. This structure is subject to external force. There will be no stress concentration, and ferrite has better shaping, so no cracks occur.
当然,本技术领域内的一般技术人员应当认识到,上述实施例仅是用来说明本发明,而 非用作对本发明的限定,只要在本发明的实质精神范围内,对上述实施例的变换、变形都将落在本发明权利要求的范围内。Of course, those of ordinary skill in the art should realize that the above-mentioned embodiments are only used to illustrate the present invention, not to limit the present invention. As long as the above-mentioned embodiments are changed within the essential spirit of the present invention, All the deformations will fall within the scope of the claims of the present invention.

Claims (10)

  1. 一种利用铁素体相改善铸坯表面裂纹的方法,其特征在于:在冶金连铸的生产中,通过控制铸坯表层温度,让该温度长时间保持在奥氏体向铁素体转变温度,得到高比例的铁素体相,使铸坯表层的铁素体相比例在铸机矫直点之前需达到35%以上。A method for improving the surface cracks of cast slabs by using ferrite phase, which is characterized in that: in the production of metallurgical continuous casting, the surface temperature of the cast slabs is controlled to keep the temperature at the austenite-to-ferrite transformation temperature for a long time , To obtain a high proportion of ferrite phase, so that the ferrite phase ratio of the cast slab surface layer needs to reach 35% or more before the straightening point of the caster.
  2. 根据权利要求1所述一种利用铁素体相改善铸坯表面裂纹的方法,其特征在于:将碳含量在0<C≤0.25%的钢种形成铸坯,控制铸坯表层温度,让所述铸坯表层温度保持在奥氏体向铁素体转变温度范围内,使得铸坯表层的铁素体相比例在铸机矫直点之前达到35%以上,之后进入铸机矫直点。The method for improving the surface cracks of a cast slab by using the ferrite phase according to claim 1, characterized in that: a steel grade with a carbon content of 0<C≦0.25% is formed into a cast slab, and the surface temperature of the cast slab is controlled to allow The surface temperature of the cast slab is kept within the austenite to ferrite transformation temperature range, so that the ferrite phase ratio of the cast slab surface reaches more than 35% before the straightening point of the caster, and then enters the straightening point of the caster.
  3. 根据权利要求1所述一种利用铁素体相改善铸坯表面裂纹的方法,其特征在于:根据钢种的连续冷却特性CCT曲线确定该钢种的铸坯能够转变成铁素体相的冷却速度范围,以所述冷却速度范围对所述铸坯进行冷却,使得所述铸坯表层温度降至奥氏体向铁素体转变温度范围内,并在铸机弧形段区域控制铸坯表层温度。The method for improving the surface cracks of a cast slab by using the ferrite phase according to claim 1, characterized in that: according to the continuous cooling characteristic CCT curve of the steel grade, it is determined that the cast slab of the steel grade can be transformed into the ferrite phase for cooling Speed range, the casting slab is cooled in the cooling speed range, so that the surface temperature of the casting slab is reduced to the austenite to ferrite transformation temperature range, and the surface of the casting slab is controlled in the arc section of the caster temperature.
  4. 根据权利要求1所述一种利用铁素体相改善铸坯表面裂纹的方法,其特征在于:在铸机弧形段区域对铸坯表层温度进行控制,根据钢种的连续冷却特性CCT曲线得到获得钢种铁素体相的冷却速度为3~0.05℃/s。The method for improving the surface cracks of the cast slab by using the ferrite phase according to claim 1, characterized in that: the surface temperature of the cast slab is controlled in the arc section of the caster, and the continuous cooling characteristic CCT curve of the steel is obtained The cooling rate to obtain the ferrite phase of the steel grade is 3 to 0.05°C/s.
  5. 根据权利要求1所述一种利用铁素体相改善铸坯表面裂纹的方法,其特征在于:在铸机弧形段区域对铸坯表层温度进行控制,根据钢种的连续冷却特性CCT曲线得到获得钢种铁素体相的冷却速度为3~0.1℃/s。The method for improving the surface cracks of the cast slab by using the ferrite phase according to claim 1, characterized in that: the surface temperature of the cast slab is controlled in the arc section of the caster, and the continuous cooling characteristic CCT curve of the steel is obtained The cooling rate to obtain the ferrite phase of the steel grade is 3 to 0.1°C/s.
  6. 根据权利要求1所述一种利用铁素体相改善铸坯表面裂纹的方法,其特征在于:控制铸坯表层温度,使得铸坯表层的铁素体相比例在铸机矫直点之前达到35%~75%。The method for improving the surface cracks of a cast slab by using the ferrite phase according to claim 1, characterized in that: the surface temperature of the cast slab is controlled so that the ferrite phase ratio of the cast slab surface reaches 35 before the straightening point of the caster. %~75%.
  7. 根据权利要求1所述一种利用铁素体相改善铸坯表面裂纹的方法,其特征在于:所述铸坯表层在奥氏体向铁素体转变温度范围为900℃~600℃,保持时间为0.44~35min。The method for improving the surface cracks of a cast slab by using the ferrite phase according to claim 1, wherein the surface layer of the cast slab has a transition temperature from austenite to ferrite in the range of 900°C to 600°C, and the holding time For 0.44~35min.
  8. 根据权利要求1-7任一项所述利用铁素体相改善铸坯表面裂纹的方法,其特征在于:通过冷却水控制铸坯表层温度,利用连铸在线模型计算获得铸坯表层温度所需的冷却水量。The method for improving the surface cracks of a cast slab by using the ferrite phase according to any one of claims 1-7, characterized in that: the surface temperature of the cast slab is controlled by cooling water, and the continuous casting online model is used to calculate the required surface temperature of the cast slab. The amount of cooling water.
  9. 根据权利要求8所述利用铁素体相改善铸坯表面裂纹的方法,其特征在于:铸坯表层长时间保持在奥氏体向铁素体转变温度,采用喷雾性能良好的二次冷却喷嘴,其在低水量水量下能够实现均匀冷却。The method for improving the surface cracks of a cast slab by using the ferrite phase according to claim 8, wherein the surface layer of the cast slab is maintained at the austenite-to-ferrite transformation temperature for a long time, and a secondary cooling nozzle with good spray performance is used, It can achieve uniform cooling under low water volume.
  10. 根据权利要求1-7任一项所述利用铁素体相改善铸坯表面裂纹的方法,其特征在 于:铸坯表层长时间保持在奥氏体向铁素体转变温度,采用非喷水冷却,因此铸机扇形段支撑辊需要良好的内部冷却,将支撑辊表面温度控制在550℃以下,防止扇形段损坏。The method for improving the surface cracks of a cast slab by using ferrite phase according to any one of claims 1-7, characterized in that the surface layer of the cast slab is kept at the austenite-to-ferrite transformation temperature for a long time, and non-spray cooling is adopted. Therefore, the fan-shaped support roller of the casting machine needs good internal cooling. The surface temperature of the support roller should be controlled below 550℃ to prevent the fan-shaped segment from being damaged.
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