WO2021237483A1 - Process method and system for co-production of propane dehydrogenation unit and ethylene unit - Google Patents

Process method and system for co-production of propane dehydrogenation unit and ethylene unit Download PDF

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WO2021237483A1
WO2021237483A1 PCT/CN2020/092435 CN2020092435W WO2021237483A1 WO 2021237483 A1 WO2021237483 A1 WO 2021237483A1 CN 2020092435 W CN2020092435 W CN 2020092435W WO 2021237483 A1 WO2021237483 A1 WO 2021237483A1
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crude
gas
ethanizer
rich gas
outlet
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Chinese (zh)
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姜浩
张锦红
张军
马利峰
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上海卓然工程技术股份有限公司
江苏博颂化工科技有限公司
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    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00Purification; Separation; Use of additives
    • C07C7/005Processes comprising at least two steps in series
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/327Formation of non-aromatic carbon-to-carbon double bonds only
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00Purification; Separation; Use of additives
    • C07C7/04Purification; Separation; Use of additives by distillation

Abstract

Disclosed are a process method and system for co-production of a propane dehydrogenation unit and an ethylene unit, the system comprising a oil and gas water-washing tower (1), a rich gas compressor (2), an outlet cooler (3) of the rich gas compressor, a steam-water separator (4), a rich gas dryer (5), a cold box (6), a gas-liquid separation tank (7), a condensate delivery pump (8), a crude deethanization tower (9), a top condenser (10) of the crude deethanization tower, a top reflux tank (11) of the crude deethanization tower, a top reflux pump (12) of the crude deethanization tower, a bottom delivery pump (13) of the crude deethanization tower, and a propylene rectification tower (14).

Description

一种丙烷脱氢装置与乙烯装置联产的工艺方法及系统Process method and system for co-production of propane dehydrogenation unit and ethylene unit 技术领域Technical field
本发明属于丙烷脱氢与乙烯技术领域,特别是指一种丙烷脱氢装置乙烯装置联产的工艺方法及系统。The invention belongs to the technical field of propane dehydrogenation and ethylene, in particular to a process method and system for co-production of an ethylene device of a propane dehydrogenation device.
背景技术Background technique
乙烯和丙烯是一种重要的石油化学品单体,可用于生产多种聚合物和中间体。随着这些产品市场需求的增加,乙烯和丙烯的需求量也增加。乙烯装置和丙烷脱氢装置是目前主要的制备方法。Ethylene and propylene are important petrochemical monomers that can be used to produce a variety of polymers and intermediates. As the market demand for these products increases, so does the demand for ethylene and propylene. Ethylene plant and propane dehydrogenation plant are currently the main production methods.
丙烷脱氢装置脱丙烷塔顶的干气中含有一部分乙烯,乙烷一般都是随着干气作为燃料气送至丙烷脱氢装置烧掉,这部分乙烯,乙烷就浪费掉了,附加值低,如果单独在丙烷脱氢装置内分离干气中的乙烷,乙烯增加设备投资但获得的收益有限。The dry gas at the top of the propane dehydrogenation unit of the propane dehydrogenation unit contains a part of ethylene. Ethane is generally sent to the propane dehydrogenation unit with the dry gas as fuel gas to be burned. This part of ethylene, ethane is wasted, adding value Low, if the ethane in the dry gas is separated in the propane dehydrogenation unit alone, the ethylene will increase equipment investment but the income will be limited.
针对上述问题,如何通过工艺技术方案的改变来实现乙烯装置与丙烷脱氢装置的联产,回收丙烷脱氢干气中的这部分丙烯、丙烷,成为亟需解决的问题。In view of the above-mentioned problems, how to realize the co-production of the ethylene plant and the propane dehydrogenation unit through the change of the process technical scheme and recover this part of propylene and propane in the propane dehydrogenation dry gas has become an urgent problem to be solved.
发明内容Summary of the invention
本发明的目的是提供一种丙烷脱氢装置与乙烯装置联产的工艺方法及系统,以解决现有丙烷脱氢装置的干气分离问题。The purpose of the present invention is to provide a process method and system for co-production of a propane dehydrogenation unit and an ethylene unit, so as to solve the dry gas separation problem of the existing propane dehydrogenation unit.
本发明是通过以下技术方案实现的:The present invention is realized through the following technical solutions:
一种丙烷脱氢装置与乙烯装置联产的工艺方法,包括以下步骤:A process method for co-production of a propane dehydrogenation unit and an ethylene unit includes the following steps:
S1、来自丙烷脱氢反应单元的PDH产品富气送至油气水洗塔,PDH产品富气经过油气水洗塔洗涤后从油气水洗塔的塔顶排出;S1. The PDH product rich gas from the propane dehydrogenation reaction unit is sent to the oil and gas washing tower, and the PDH product rich gas is washed by the oil and gas washing tower and then discharged from the top of the oil and gas washing tower;
S2、从油气水洗塔的塔顶排出的PDH产品富气进入富气压缩机,经过富气压缩机增压后送至富气压缩机出口冷却器;S2. The PDH product rich gas discharged from the top of the oil and gas washing tower enters the rich gas compressor, and is pressurized by the rich gas compressor and sent to the outlet cooler of the rich gas compressor;
S3、经过富气压缩机出口冷却器冷却后的PDH产品富气送至汽水分离罐分离出今油污水,经过汽水分离后的PDH产品富气从所述汽水分离罐的顶部排出后送至富气干燥器;S3. The PDH product rich gas cooled by the outlet cooler of the rich gas compressor is sent to the steam-water separation tank to separate the oily wastewater, and the PDH product rich gas after the steam-water separation is discharged from the top of the steam-water separation tank and sent to the rich Gas dryer
S4、在所述富气干燥器内,PDH产品富气脱除剩余水分后被送至冷箱,经过进一步冷却后被送至气液分离罐;S4. In the rich gas dryer, the PDH product rich gas is sent to the cold box after removing the remaining moisture, and is sent to the gas-liquid separation tank after further cooling;
S5、在气液分离罐内,PDH产品富气中所包含的轻烃气体从气液分离罐的顶部送至粗脱乙烷塔的上部,气液分离罐底部的第一轻烃凝液通过凝液泵送至所述粗脱乙烷塔的下部;S5. In the gas-liquid separation tank, the light hydrocarbon gas contained in the rich gas of the PDH product is sent from the top of the gas-liquid separation tank to the upper part of the crude deethanizer, and the first light hydrocarbon condensate at the bottom of the gas-liquid separation tank passes The condensate is pumped to the lower part of the crude de-ethanizer;
S6、轻烃气体从所述粗脱乙烷塔顶被送至粗脱乙烷塔顶冷凝器,经过粗脱乙烷塔顶冷凝器冷凝后进入粗脱乙烷回流罐,其中的轻烃凝液作为粗脱乙烷塔顶回流液通过粗脱乙烷塔顶回流泵输送回所述粗脱乙烷塔顶部,其中的干气从粗脱乙烷回流罐采出后送至乙烯装置的第四段裂解气压缩机入口;S6. The light hydrocarbon gas is sent from the top of the crude de-ethanizer to the condenser of the crude de-ethanizer, and then enters the crude de-ethanizer reflux tank after being condensed by the crude de-ethanizer, where the light hydrocarbons are condensed The liquid is used as the reflux liquid from the top of the crude de-ethanizer to be transported back to the top of the crude de-ethanizer by the crude de-ethanizer reflux pump. Entrance of the four-stage pyrolysis gas compressor;
S7、从粗脱乙烷塔底采出的轻烃通过粗脱乙烷塔底输送泵送至丙烯精馏塔,丙烯精馏塔顶采出聚合级的丙烯产品,丙烯精馏塔底采出的丙烷作为循环丙烷返回丙烷脱氢反应单元。S7. The light hydrocarbons extracted from the bottom of the crude de-ethanizer are sent to the propylene rectification tower by the transport pump at the bottom of the crude de-ethanizer. The top of the propylene rectification tower produces polymerized propylene products, and the bottom of the propylene rectification tower The propane is returned to the propane dehydrogenation reaction unit as recycled propane.
进一步的,所述工艺方法还包括:利用乙烯装置的精馏塔系统,将丙烷脱氢的干气与乙烯裂解气一同送至乙烯装置的精馏系统进行分离。Further, the process method further includes: using the rectification tower system of the ethylene plant to send the dry gas of the propane dehydrogenation and the ethylene cracking gas to the rectification system of the ethylene plant for separation.
进一步的,所述油气水洗塔的理论塔板数为4层,操作压力为常压,其塔顶采出的温度为42℃,塔底采出温度为55℃;所述富气压缩机的出口压力为1.15MPaG;所述富气压缩机冷却器的热端出口温度为40℃。Further, the theoretical plate number of the oil-gas washing tower is 4, the operating pressure is normal pressure, the temperature produced at the top of the tower is 42°C, and the temperature produced at the bottom of the tower is 55°C; The outlet pressure is 1.15 MPaG; the hot end outlet temperature of the rich gas compressor cooler is 40°C.
进一步的,所述汽水分离罐的操作压力为1.1MPaG,操作温度为40℃;所述富气干燥器的操作压力为1.05MPaG,操作温度40℃;冷箱的富气端进口温度40℃,出口温度-33℃,所述气液分离罐的操作压力0.9MPaG,操温度-33℃。Further, the operating pressure of the steam-water separator tank is 1.1 MPaG, and the operating temperature is 40°C; the operating pressure of the rich gas dryer is 1.05 MPaG, and the operating temperature is 40°C; the inlet temperature of the rich gas end of the cold box is 40°C, The outlet temperature is -33°C, the operating pressure of the gas-liquid separation tank is 0.9MPaG, and the operating temperature is -33°C.
进一步的,所述粗脱乙烷塔理论板数为48块,操作压力为0.75MPaG,塔顶温度为-23℃,塔底温度为18℃;所述丙烯精馏塔理论板数为200,操作压力为0.8MPaG,塔顶温度为15℃,塔底温度为27℃。Further, the number of theoretical plates of the crude deethanizer is 48, the operating pressure is 0.75MPaG, the temperature at the top of the tower is -23°C, and the temperature at the bottom of the tower is 18°C; the number of theoretical plates of the propylene rectification tower is 200, The operating pressure is 0.8MPaG, the temperature at the top of the tower is 15°C, and the temperature at the bottom of the tower is 27°C.
进一步的,所述PDH产品富气组成为:氢气含量1.57wt%,甲烷含量0.86wt%,乙烯含量0.49wt%,乙烷含量0.84wt%,丙炔含量0.01wt%, 丙烯含量32.11wt%,丙烷含量62.65wt%,重组分杂质0.95wt%。Further, the rich gas composition of the PDH product is as follows: a hydrogen content of 1.57 wt%, a methane content of 0.86 wt%, an ethylene content of 0.49 wt%, an ethane content of 0.84 wt%, a propyne content of 0.01 wt%, and a propylene content of 32.11 wt%, The content of propane is 62.65wt%, and the heavy component impurities are 0.95wt%.
进一步的,粗脱乙烷塔顶回流罐顶部采出的干气组成为:氢气含量24.04wt%,甲烷含量27.34wt%,乙烯含量7.5wt%,乙烷含量12.76wt%,丙烯含量22.59wt%,丙烷含量5.77wt%。Further, the composition of the dry gas extracted from the top of the reflux tank at the top of the crude deethanization tower is: hydrogen content 24.04wt%, methane content 27.34wt%, ethylene content 7.5wt%, ethane content 12.76wt%, propylene content 22.59wt% , Propane content is 5.77wt%.
进一步的,丙烯精馏塔顶采出的丙烯产品中丙烯含量99.6wt%,丙烷含量0.4wt%。Furthermore, in the propylene product produced at the top of the propylene rectification tower, the propylene content is 99.6% by weight, and the propane content is 0.4% by weight.
一种丙烷脱氢装置与乙烯装置联产的系统,用于上述任一项的丙烷脱氢装置与乙烯装置联产的工艺方法,包括:A system for the co-production of a propane dehydrogenation unit and an ethylene unit, which is used in the process method for the co-production of any one of the above-mentioned propane dehydrogenation units and an ethylene unit, comprising:
油气水洗塔、富气压缩机、富气压缩机出口冷却器、汽水分离器、富气干燥器、冷箱、气液分离罐、凝液输送泵、粗脱乙烷塔、粗脱乙烷塔顶冷凝器、粗脱乙烷塔顶回流罐、粗脱乙烷塔顶回流泵、粗脱乙烷塔底输送泵及丙烯精馏塔;Oil and gas washing tower, rich gas compressor, rich gas compressor outlet cooler, steam-water separator, rich gas dryer, cold box, gas-liquid separation tank, condensate transfer pump, crude de-ethanizer, crude de-ethanizer Top condenser, top reflux tank of crude de-ethanizer, top reflux pump of crude de-ethanizer, bottom transfer pump of crude de-ethanizer, and propylene distillation tower;
丙烷脱氢反应单元的PDH产品富气从余热回收设备富气出口通过管道与油气水洗塔的侧下部的进气口连接,洗涤水通过管道与油气水洗塔的侧上部的进水口连接;所述油气水洗塔的顶部出气口通过管道与富气压缩机的入口连接,富气压缩机的出口与富气压缩机出口冷却器的热端的进口通过管道连接;The PDH product rich gas of the propane dehydrogenation reaction unit is connected from the rich gas outlet of the waste heat recovery equipment to the air inlet on the lower side of the oil and gas washing tower through a pipeline, and the washing water is connected to the water inlet on the upper side of the oil and gas washing tower through the pipeline; The gas outlet at the top of the oil-gas washing tower is connected to the inlet of the rich gas compressor through a pipeline, and the outlet of the rich gas compressor is connected to the hot end inlet of the outlet cooler of the rich gas compressor through a pipeline;
富气压缩机出口冷却器的热端的出口通过管道与汽水分离罐的进口相连,汽水分离罐顶部气相出口通过管道与富气干燥器的进口相连,富气干燥器的出口通过管道与冷箱的富气端进口连接,冷箱的富气端出口通过管道与气液分离器的进口相连;The hot end outlet of the rich gas compressor outlet cooler is connected to the inlet of the steam-water separator tank through a pipe, the gas-phase outlet on the top of the steam-water separator tank is connected to the inlet of the rich gas dryer through a pipe, and the outlet of the rich gas dryer is connected to the cold box through a pipe. The inlet of the rich gas end is connected, and the outlet of the rich gas end of the cold box is connected to the inlet of the gas-liquid separator through a pipe;
气液分离罐顶部的气相出口通过管道与粗脱乙烷塔上部的进气口连接,气流分离罐底部的液相出口通过管路与凝液输送泵的进口连接,凝液输送泵的出口通过管道与粗脱乙烷塔的中部进液口连接;The gas-liquid outlet at the top of the gas-liquid separation tank is connected to the air inlet on the upper part of the crude de-ethanizer through a pipeline, the liquid phase outlet at the bottom of the gas-liquid separation tank is connected to the inlet of the condensate transfer pump through a pipeline, and the outlet of the condensate transfer pump passes through The pipeline is connected with the liquid inlet in the middle of the crude de-ethanizer;
粗脱乙烷塔顶部的气相出口通过管道与粗脱乙烷塔顶冷凝器的热端进口连接,粗脱乙烷塔顶冷凝器热出口与粗脱乙烷塔顶回流罐进口连接;The gas phase outlet at the top of the crude de-ethanizer is connected to the hot end inlet of the crude de-ethanizer top condenser through a pipeline, and the hot outlet of the crude de-ethanizer top condenser is connected to the inlet of the crude de-ethanizer top reflux tank;
粗脱乙烷塔顶回流罐顶部的气相出口通过管道连接到乙烯装置的第四段压缩机入口;粗脱乙烷塔顶回流罐底部的液相出口与粗脱乙烷塔顶回流泵的入口连接,粗脱乙烷塔顶回流泵的出口与粗脱乙烷塔顶回流口相连;The gas-phase outlet at the top of the crude de-ethanizer reflux tank is connected to the inlet of the fourth stage compressor of the ethylene plant through a pipeline; the liquid-phase outlet at the bottom of the crude de-ethanizer reflux tank and the inlet of the reflux pump at the top of the crude de-ethanizer Connection, the outlet of the reflux pump at the top of the crude de-ethanizer is connected to the reflux port at the top of the crude de-ethanizer;
粗脱乙烷塔底的液相出口与粗脱乙烷塔底输送泵的入口连接,粗脱乙烷 塔底输送泵的出口与丙烯精馏塔的进口连接;The liquid phase outlet at the bottom of the crude de-ethanizer is connected to the inlet of the crude de-ethanizer bottom transfer pump, and the outlet of the crude de-ethanizer bottom transfer pump is connected to the inlet of the propylene rectification tower;
丙烯精馏塔顶的丙烷产品出口通过管道与深冷单元的入口连接,丙烯精馏塔底的丙烷出口与丙烷脱氢的反应单元入口连接。The propane product outlet at the top of the propylene rectification tower is connected to the inlet of the cryogenic unit through a pipeline, and the propane outlet at the bottom of the propylene rectification tower is connected to the inlet of the reaction unit for propane dehydrogenation.
本发明的有益效果是:The beneficial effects of the present invention are:
1、本发明的丙烷脱氢装置与乙烯装置联产的工艺方法,利用乙烯装置的分离系统分离丙烷脱氢装置干气中的乙烯,乙烷,增加了产品附加值,提高了收益。1. The process method for co-production of the propane dehydrogenation unit and the ethylene unit of the present invention uses the separation system of the ethylene unit to separate ethylene and ethane from the dry gas of the propane dehydrogenation unit, which increases the added value of the product and improves the profit.
2、本发明的丙烷脱氢装置与乙烯装置联产的工艺方法,共用公用工程系统和制冷系统,减少了设备投资和占地。2. The process method of the co-production of the propane dehydrogenation device and the ethylene device of the present invention shares the public engineering system and the refrigeration system, reducing equipment investment and land occupation.
附图说明Description of the drawings
图1为本发明丙烷脱氢装置、乙烯装置联产的工艺流程图。Figure 1 is a process flow diagram of the co-production of the propane dehydrogenation unit and the ethylene unit of the present invention.
附图标记说明Description of Reference Signs
1-油气水洗塔;2-富气压缩机;3-富气压缩机出口冷却器;4-汽水分离罐;5-富气干燥器;6-冷箱;7-气液分离罐;8-凝液输送泵;9-粗脱乙烷塔;10-粗脱乙烷塔顶冷凝器;11-粗脱乙烷塔顶回流罐;12-粗脱乙烷塔顶回流泵;13-粗脱乙烷塔底输送泵;14-丙烯精馏塔。1- Oil-gas washing tower; 2- Rich gas compressor; 3- Rich gas compressor outlet cooler; 4- Steam-water separation tank; 5- Rich gas dryer; 6- Cold box; 7- Gas-liquid separation tank; 8- Condensate transfer pump; 9-crude deethanizer tower; 10-crude deethanizer top condenser; 11-crude deethanizer top reflux tank; 12-crude deethanizer top reflux pump; 13-rough deethanizer Transfer pump at the bottom of ethane tower; 14-propylene distillation tower.
具体实施方式Detailed ways
需要说明的是,在不冲突的情况下,本发明创造中的实施例及实施例中的特征可以相互组合。It should be noted that the embodiments in the invention and the features in the embodiments can be combined with each other if there is no conflict.
在本发明创造的描述中,需要理解的是,术语“上”、“下”、“顶”、“底”等指示的方位或位置关系为基于附图所示的方位或位置关系,仅是为了便于描述本发明创造和简化描述,而不是指示或暗示所指的装置或元件必须具有特定的方位、以特定的方位构造和操作,因此不能理解为对本发明创造的限制。此外,术语“第一”、“第二”等仅用于描述目的,而不能理解为指示或暗示相对重要性或者隐含指明所指示的技术特征的数量。由此,限定有“第一”、“第二”等的特征可以明示或者隐含地包括一个或者更多个该特征。在本发明创造的描述中,除非另有说明,“多个”的含义是两个或两个以上。In the description of the present invention, it should be understood that the orientation or positional relationship indicated by the terms "upper", "lower", "top", "bottom", etc. are based on the orientation or positional relationship shown in the drawings, but In order to facilitate the creation of the present invention and simplify the description, it does not indicate or imply that the device or element referred to must have a specific orientation, be constructed and operated in a specific orientation, and therefore cannot be understood as a limitation on the creation of the present invention. In addition, the terms "first", "second", etc. are only used for descriptive purposes, and cannot be understood as indicating or implying relative importance or implicitly indicating the number of indicated technical features. Thus, the features defined with "first", "second", etc. may explicitly or implicitly include one or more of these features. In the description of the invention, unless otherwise specified, the meaning of "multiple" means two or more.
在本发明创造的描述中,需要说明的是,除非另有明确的规定和限定,术语“安装”、“相连”、“连接”应做广义理解,例如,可以是固定连接,也可以是可拆卸连接,或一体地连接;可以是机械连接,也可以是电连接;可以是直接相连,也可以通过中间媒介间接相连,可以是两个元件内部的连通。对于本领域的普通技术人员而言,可以通过具体情况理解上述术语在本发明创造中的具体含义。In the description of the invention, it should be noted that, unless otherwise clearly defined and limited, the terms "installation", "connection", and "connection" should be understood in a broad sense. For example, it can be a fixed connection or an optional connection. Detachable connection, or integral connection; it can be a mechanical connection or an electrical connection; it can be directly connected or indirectly connected through an intermediate medium, and it can be the internal communication between two components. For those of ordinary skill in the art, the specific meaning of the above-mentioned terms in the creation of the present invention can be understood through specific circumstances.
下面将参考附图并结合实施例来详细说明本发明创造。The invention will be described in detail below with reference to the drawings and in conjunction with the embodiments.
如图1所示,本申请提供一种丙烷脱氢装置与乙烯装置联产的工艺,首先在丙烷脱氢反应单元产生的PDH产品富气送至油气水洗塔1的侧下部。As shown in FIG. 1, the present application provides a process for co-production of a propane dehydrogenation unit and an ethylene unit. First, the PDH product rich gas produced in the propane dehydrogenation reaction unit is sent to the lower side of the oil and gas washing tower 1.
在本实施例中,在反应单元所生产的PDH产品富气的组成为氢气含量1.57wt%,甲烷含量0.86wt%,乙烯含量0.49wt%,乙烷含量0.84wt%,丙炔含量0.01wt%,丙烯含量32.11wt%,丙烷含量62.65wt%,重组分杂质0.95wt%。In this embodiment, the composition of the rich gas of the PDH product produced in the reaction unit is hydrogen content of 1.57% by weight, methane content of 0.86% by weight, ethylene content of 0.49% by weight, ethane content of 0.84% by weight, and propyne content of 0.01% by weight. , The propylene content is 32.11wt%, the propane content is 62.65wt%, and the heavy component impurities are 0.95wt%.
在本实施例中,油气水洗塔的工作参数选为塔顶操作温度为42℃、操作压力为常压、塔底温度为55℃。PDH产品富气经过油气水洗塔的洗涤后从油气水洗塔的塔顶排出,油气水洗塔的塔底的含油污水进入回收或处理系统。In this embodiment, the working parameters of the oil-gas washing tower are selected as the tower top operating temperature at 42°C, the operating pressure at normal pressure, and the tower bottom temperature at 55°C. After being washed by the oil-gas washing tower, the rich gas of the PDH product is discharged from the top of the oil-gas washing tower, and the oily sewage at the bottom of the oil-gas washing tower enters the recovery or treatment system.
从油气水洗塔出来的PDH产品富气被送至富气压缩机2,将PDH产品富气增压到1.15MPaG后送至富气压缩机出口冷却器3,PDH产品富气被富气压缩机出口冷却器冷却到40℃左右,送至汽水分离罐4分离出含油污水,在本实施例中,汽水分离罐的工作参数为操作压力为1.1MPaG,操作温度40℃。The PDH product rich gas from the oil and gas washing tower is sent to the rich gas compressor 2, and the PDH product rich gas is pressurized to 1.15MPaG and then sent to the rich gas compressor outlet cooler 3. The PDH product rich gas is sent to the rich gas compressor The outlet cooler is cooled to about 40°C and sent to the steam-water separation tank 4 to separate oily sewage. In this embodiment, the working parameters of the steam-water separation tank are operating pressure of 1.1 MPaG and operating temperature of 40°C.
PDH产品富气从汽水分离罐顶部排出并送至富气干燥器5,富气干燥器的工作参数为操作压力为1.05MPaG,操作温度40℃,PDH产品富气经过富气干燥器脱除剩余水分后进入冷箱6,在进一步冷却到-33℃后被送至气液分离罐7,在本实施例中,气液分离罐的工作参数为操作压力0.9MpaG,操温度-33℃。The rich gas of PDH product is discharged from the top of the steam-water separation tank and sent to the rich gas dryer 5. The working parameters of the rich gas dryer are the operating pressure of 1.05MPaG and the operating temperature of 40℃. The rich gas of the PDH product passes through the rich gas dryer to remove the remaining After the water enters the cold box 6, it is further cooled to -33°C and then sent to the gas-liquid separation tank 7. In this embodiment, the working parameters of the gas-liquid separation tank are operating pressure 0.9MpaG and operating temperature -33°C.
从气液分离罐中分离出的轻烃气体从气液分离罐的顶部排出后被送至粗脱乙烷塔9的上部,气液分离罐的底部的第一轻烃凝液通过凝液泵8被送至粗脱乙烷塔的下部,在本实施例中,粗脱乙烷塔的工作参数为0.75MpaG, 塔顶温度为-23℃,塔底温度为18℃。The light hydrocarbon gas separated from the gas-liquid separation tank is discharged from the top of the gas-liquid separation tank and sent to the upper part of the crude de-ethanizer 9. The first light hydrocarbon condensate at the bottom of the gas-liquid separation tank is passed through the condensate pump 8 is sent to the lower part of the crude de-ethanizer. In this embodiment, the crude de-ethanizer has a working parameter of 0.75MpaG, a top temperature of -23°C, and a bottom temperature of 18°C.
轻烃气体通过粗脱乙烷塔顶送至粗脱乙烷塔顶冷凝器10冷凝后进入粗脱乙烷塔回流罐11,粗脱乙烷塔回流罐中的第二轻烃凝液作为粗脱乙烷塔顶回流液通过粗脱乙烷塔顶回流泵12输送回粗脱乙烷塔的顶部,粗脱乙烷塔回流罐中的干气从罐顶采出送至乙烯装置的第四段裂解气压缩机入口,在本实施例中,粗脱乙烷塔顶回流罐顶部采出的干气组成为:氢气含量24.04wt%,甲烷含量27.34wt%,乙烯含量7.5wt%,乙烷含量12.76wt%,丙烯含量22.59wt%,丙烷含量5.77wt%。The light hydrocarbon gas is sent through the top of the crude deethanizer to the condenser 10 at the top of the crude deethanizer to be condensed and then enters the crude deethanizer reflux tank 11, and the second light hydrocarbon condensate in the crude deethanizer reflux tank is used as the crude The reflux liquid from the top of the de-ethanizer is sent back to the top of the crude de-ethanizer by the crude de-ethanizer top reflux pump 12, and the dry gas in the crude de-ethanizer reflux tank is extracted from the top of the tank and sent to the fourth part of the ethylene plant. At the inlet of the stage cracked gas compressor, in this embodiment, the composition of the dry gas produced at the top of the reflux tank at the top of the crude de-ethanizer is: hydrogen content 24.04wt%, methane content 27.34wt%, ethylene content 7.5wt%, ethane The content is 12.76wt%, the propylene content is 22.59wt%, and the propane content is 5.77wt%.
粗脱乙烷塔底采出的轻烃通过粗脱乙烷塔底输送泵13送至丙烯精馏塔14,操作压力为0.8MpaG,塔顶温度为15℃,塔底温度为27℃,丙烯精馏塔顶采出聚合级的丙烯产品,塔底采出的丙烷作为循环丙烷返回反应单元。The light hydrocarbons produced at the bottom of the crude de-ethanizer are sent to the propylene rectification tower 14 by the delivery pump 13 at the bottom of the crude de-ethanizer. The operating pressure is 0.8MpaG, the top temperature is 15°C, and the bottom temperature is 27°C. The polymerization-grade propylene product is produced at the top of the rectification tower, and the propane produced at the bottom of the tower is returned to the reaction unit as circulating propane.
本申请还包括用于上述丙烷脱氢装置与乙烯装置联产的工艺的系统,包括油气水洗塔、富气压缩机、富气压缩机出口冷却器、汽水分离器、富气干燥器、冷箱、气液分离罐、凝液输送泵、粗脱乙烷塔、粗脱乙烷塔顶冷凝器、粗脱乙烷塔顶回流罐、粗脱乙烷塔顶回流泵、粗脱乙烷塔底输送泵及丙烯精馏塔。This application also includes systems for the co-production process of the above-mentioned propane dehydrogenation unit and ethylene unit, including oil-gas washing tower, rich gas compressor, rich gas compressor outlet cooler, steam water separator, rich gas dryer, and cold box , Gas-liquid separation tank, condensate transfer pump, crude de-ethanizer, crude de-ethanizer top condenser, crude de-ethanizer top reflux tank, crude de-ethanizer top reflux pump, crude deethanizer bottom Delivery pump and propylene distillation tower.
丙烷脱氢反应单元的PDH产品富气从余热回收设备富气出口通过管道与油气水洗塔的侧下部的进气口连接,洗涤水通过管道与油气水洗塔的侧上部的进水口连接;所述油气水洗塔的顶部出气口通过管道与富气压缩机的入口连接,富气压缩机的出口与富气压缩机出口冷却器的热端的进口通过管道连接。The PDH product rich gas of the propane dehydrogenation reaction unit is connected from the rich gas outlet of the waste heat recovery equipment to the air inlet on the lower side of the oil and gas washing tower through a pipeline, and the washing water is connected to the water inlet on the upper side of the oil and gas washing tower through the pipeline; The top gas outlet of the oil-gas washing tower is connected with the inlet of the rich gas compressor through a pipeline, and the outlet of the rich gas compressor is connected with the hot end inlet of the outlet cooler of the rich gas compressor through a pipeline.
富气压缩机出口冷却器的热端的出口通过管道与汽水分离罐的进口相连,汽水分离罐顶部气相出口通过管道与富气干燥器的进口相连,富气干燥器的出口通过管道与冷箱的富气端进口连接,冷箱的富气端出口通过管道与气液分离器的进口相连。The hot end outlet of the rich gas compressor outlet cooler is connected to the inlet of the steam-water separator tank through a pipe, the gas-phase outlet on the top of the steam-water separator tank is connected to the inlet of the rich gas dryer through a pipe, and the outlet of the rich gas dryer is connected to the cold box through a pipe. The rich gas end inlet is connected, and the rich gas end outlet of the cold box is connected to the inlet of the gas-liquid separator through a pipe.
气液分离罐顶部的气相出口通过管道与粗脱乙烷塔上部的进气口连接,气流分离罐底部的液相出口通过管路与凝液输送泵的进口连接,凝液输送泵的出口通过管道与粗脱乙烷塔的中部进液口连接。The gas-liquid outlet at the top of the gas-liquid separation tank is connected to the air inlet on the upper part of the crude de-ethanizer through a pipeline, the liquid phase outlet at the bottom of the gas-liquid separation tank is connected to the inlet of the condensate transfer pump through a pipeline, and the outlet of the condensate transfer pump passes through The pipeline is connected with the liquid inlet in the middle of the crude de-ethanizer.
粗脱乙烷塔顶部的气相出口通过管道与粗脱乙烷塔顶冷凝器的热端进口连接,粗脱乙烷塔顶冷凝器热出口与粗脱乙烷塔顶回流罐进口连接。The gas phase outlet at the top of the crude de-ethanizer is connected to the hot end inlet of the crude de-ethanizer top condenser through a pipeline, and the hot outlet of the crude de-ethanizer top condenser is connected to the inlet of the crude deethanizer top reflux tank.
粗脱乙烷塔顶回流罐顶部的气相出口通过管道连接到乙烯装置的第四段压缩机入口;粗脱乙烷塔顶回流罐底部的液相出口与粗脱乙烷塔顶回流泵的入口连接,粗脱乙烷塔顶回流泵的出口与粗脱乙烷塔顶回流口相连。The gas-phase outlet at the top of the crude de-ethanizer reflux tank is connected to the inlet of the fourth stage compressor of the ethylene plant through a pipeline; the liquid-phase outlet at the bottom of the crude de-ethanizer reflux tank and the inlet of the reflux pump at the top of the crude de-ethanizer Connect, the outlet of the reflux pump at the top of the crude de-ethanizer is connected with the reflux port at the top of the crude de-ethanizer.
粗脱乙烷塔底的液相出口与粗脱乙烷塔底输送泵的入口连接,粗脱乙烷塔底输送泵的出口与丙烯精馏塔的进口连接。The liquid phase outlet at the bottom of the crude de-ethanizer is connected to the inlet of the crude de-ethanizer bottom transfer pump, and the outlet of the crude de-ethanizer bottom transfer pump is connected to the inlet of the propylene rectification tower.
丙烯精馏塔顶的丙烷产品出口通过管道与深冷单元的入口连接,丙烯精馏塔底的丙烷出口与丙烷脱氢的反应单元入口连接。The propane product outlet at the top of the propylene rectification tower is connected to the inlet of the cryogenic unit through a pipeline, and the propane outlet at the bottom of the propylene rectification tower is connected to the inlet of the reaction unit for propane dehydrogenation.
本发明提出的一种丙烷脱氢装置和乙烯装置联产的工艺及系统,已通过实施例进行了描述,相关技术人员明显能在不脱离本发明的内容、精神和范围内对本文所述的产品和制作方法进行改动或适当变更与组合,来实现本发明的技术。特别需要指出的是,所有相类似的替换和改动对本领域技术人员来说是显而易见的,它们都被视为包括在本发明的精神、范围和内容。The process and system for co-production of a propane dehydrogenation unit and an ethylene unit proposed by the present invention have been described through examples. It is obvious that those skilled in the art can compare what is described herein without departing from the content, spirit and scope of the present invention. Products and manufacturing methods are modified or appropriately modified and combined to realize the technology of the present invention. In particular, it should be pointed out that all similar replacements and modifications are obvious to those skilled in the art, and they are all deemed to be included in the spirit, scope and content of the present invention.

Claims (9)

  1. 一种丙烷脱氢装置与乙烯装置联产的工艺方法,其特征在于,包括以下步骤:A process method for co-production of a propane dehydrogenation unit and an ethylene unit is characterized in that it comprises the following steps:
    S1、来自丙烷脱氢反应单元的PDH产品富气送至油气水洗塔,PDH产品富气经过油气水洗塔洗涤后从油气水洗塔的塔顶排出;S1. The PDH product rich gas from the propane dehydrogenation reaction unit is sent to the oil and gas washing tower, and the PDH product rich gas is washed by the oil and gas washing tower and then discharged from the top of the oil and gas washing tower;
    S2、从油气水洗塔的塔顶排出的PDH产品富气进入富气压缩机,经过富气压缩机增压后送至富气压缩机出口冷却器;S2. The PDH product rich gas discharged from the top of the oil and gas washing tower enters the rich gas compressor, and is pressurized by the rich gas compressor and sent to the outlet cooler of the rich gas compressor;
    S3、经过富气压缩机出口冷却器冷却后的PDH产品富气送至汽水分离罐分离出今油污水,经过汽水分离后的PDH产品富气从所述汽水分离罐的顶部排出后送至富气干燥器;S3. The PDH product rich gas cooled by the outlet cooler of the rich gas compressor is sent to the steam-water separation tank to separate the oily wastewater, and the PDH product rich gas after the steam-water separation is discharged from the top of the steam-water separation tank and sent to the rich Gas dryer
    S4、在所述富气干燥器内,PDH产品富气脱除剩余水分后被送至冷箱,经过进一步冷却后被送至气液分离罐;S4. In the rich gas dryer, the PDH product rich gas is sent to the cold box after removing the remaining moisture, and is sent to the gas-liquid separation tank after further cooling;
    S5、在气液分离罐内,PDH产品富气中所包含的轻烃气体从气液分离罐的顶部送至粗脱乙烷塔的上部,气液分离罐底部的第一轻烃凝液通过凝液泵送至所述粗脱乙烷塔的下部;S5. In the gas-liquid separation tank, the light hydrocarbon gas contained in the rich gas of the PDH product is sent from the top of the gas-liquid separation tank to the upper part of the crude deethanizer, and the first light hydrocarbon condensate at the bottom of the gas-liquid separation tank passes The condensate is pumped to the lower part of the crude de-ethanizer;
    S6、轻烃气体从所述粗脱乙烷塔顶被送至粗脱乙烷塔顶冷凝器,经过粗脱乙烷塔顶冷凝器冷凝后进入粗脱乙烷回流罐,其中的轻烃凝液作为粗脱乙烷塔顶回流液通过粗脱乙烷塔顶回流泵输送回所述粗脱乙烷塔顶部,其中的干气从粗脱乙烷塔回流罐采出后送至乙烯装置的第四段裂解气压缩机入口;S6. The light hydrocarbon gas is sent from the top of the crude de-ethanizer to the condenser of the crude de-ethanizer, and then enters the crude de-ethanizer reflux tank after being condensed by the crude de-ethanizer, where the light hydrocarbons are condensed The liquid is used as the reflux liquid from the top of the crude de-ethanizer to be transported back to the top of the crude de-ethanizer by the crude de-ethanizer top reflux pump, and the dry gas is extracted from the reflux tank of the crude de-ethanizer and sent to the ethylene plant. Entrance of the fourth stage cracked gas compressor;
    S7、从粗脱乙烷塔底采出的轻烃通过粗脱乙烷塔底输送泵送至丙烯精馏塔,丙烯精馏塔顶采出聚合级的丙烯产品,丙烯精馏塔底采出的丙烷作为循环丙烷返回丙烷脱氢反应单元。S7. The light hydrocarbons extracted from the bottom of the crude de-ethanizer are sent to the propylene rectification tower by the transport pump at the bottom of the crude de-ethanizer. The top of the propylene rectification tower produces polymerized propylene products, and the bottom of the propylene rectification tower The propane is returned to the propane dehydrogenation reaction unit as recycled propane.
  2. 根据权利要求1所述的丙烷脱氢装置与乙烯装置联产的工艺方法,其特征在于,所述工艺方法还包括:利用乙烯装置的精馏塔系统,将丙烷脱氢的干气与乙烯裂解气一同送至乙烯装置的精馏系统进行分离。The process method for co-production of a propane dehydrogenation unit and an ethylene plant according to claim 1, wherein the process method further comprises: using a rectification tower system of the ethylene plant to crack the dry gas from the propane dehydrogenation unit with ethylene The gas is sent to the rectification system of the ethylene plant for separation.
  3. 根据权利要求1所述的丙烷脱氢装置与乙烯装置联产的工艺方法,其特征在于,所述油气水洗塔的理论塔板数为层,操作压力为常压,其塔顶采出的温度为42℃,塔底采出温度为55℃;所述富气压缩机的出口压力为 1.15MPaG;所述富气压缩机冷却器的热端出口温度为40℃。The process method for co-production of a propane dehydrogenation unit and an ethylene unit according to claim 1, wherein the theoretical plate number of the oil-gas washing tower is a layer, the operating pressure is normal pressure, and the temperature at the top of the tower is The temperature at the bottom of the tower is 42°C, and the temperature at the bottom of the tower is 55°C; the outlet pressure of the rich gas compressor is 1.15 MPaG; the hot end outlet temperature of the cooler of the rich gas compressor is 40°C.
  4. 根据权利要求1所述的丙烷脱氢装置与乙烯装置联产的工艺方法,其特征在于,所述汽水分离罐的操作压力为1.1MPaG,操作温度为40℃;所述富气干燥器的操作压力为1.05MPaG,操作温度40℃;冷箱的富气端进口温度40℃,出口温度-33℃,所述气液分离罐的操作压力0.9MPaG,操温度-33℃。The process method for co-production of a propane dehydrogenation unit and an ethylene unit according to claim 1, wherein the operating pressure of the steam-water separation tank is 1.1 MPaG, and the operating temperature is 40°C; the operation of the rich gas dryer The pressure is 1.05 MPaG, the operating temperature is 40°C; the inlet temperature of the rich gas end of the cold box is 40°C, the outlet temperature is -33°C, the operating pressure of the gas-liquid separation tank is 0.9 MPaG, and the operating temperature is -33°C.
  5. 根据权利要求1所述的丙烷脱氢装置与乙烯装置联产的工艺方法,其特征在于,所述粗脱乙烷塔理论板数为48块,操作压力为0.75MPaG,塔顶温度为-23℃,塔底温度为18℃;所述丙烯精馏塔理论板数为200,操作压力为0.8MPaG,塔顶温度为15℃,塔底温度为27℃。The process method for co-production of a propane dehydrogenation unit and an ethylene unit according to claim 1, wherein the rough deethanizer has a theoretical plate number of 48, an operating pressure of 0.75 MPaG, and a tower top temperature of -23 The temperature at the bottom of the tower is 18°C; the number of theoretical plates of the propylene rectification tower is 200, the operating pressure is 0.8 MPaG, the temperature at the top of the tower is 15°C, and the temperature at the bottom of the tower is 27°C.
  6. 根据权利要求1所述的丙烷脱氢装置与乙烯装置联产的工艺方法,其特征在于,所述PDH产品富气组成为:氢气含量1.57wt%,甲烷含量0.86wt%,乙烯含量0.49wt%,乙烷含量0.84wt%,丙炔含量0.01wt%,丙烯含量32.11wt%,丙烷含量62.65wt%,重组分杂质0.95wt%。The process method for co-production of a propane dehydrogenation unit and an ethylene unit according to claim 1, wherein the rich gas composition of the PDH product is: a hydrogen content of 1.57 wt%, a methane content of 0.86 wt%, and an ethylene content of 0.49 wt% , The ethane content is 0.84wt%, the propyne content is 0.01wt%, the propylene content is 32.11wt%, the propane content is 62.65wt%, and the heavy component impurities are 0.95wt%.
  7. 根据权利要求1所述的丙烷脱氢装置与乙烯装置联产的工艺方法,其特征在于,粗脱乙烷塔顶回流罐顶部采出的干气组成为:氢气含量24.04wt%,甲烷含量27.34wt%,乙烯含量7.5wt%,乙烷含量12.76wt%,丙烯含量22.59wt%,丙烷含量5.77wt%。The process method for co-production of a propane dehydrogenation unit and an ethylene unit according to claim 1, wherein the composition of the dry gas produced at the top of the reflux tank at the top of the crude deethanization tower is: a hydrogen content of 24.04wt% and a methane content of 27.34 wt%, ethylene content is 7.5 wt%, ethane content is 12.76 wt%, propylene content is 22.59 wt%, and propane content is 5.77 wt%.
  8. 根据权利要求1所述的丙烷脱氢装置与乙烯装置联产的工艺方法,其特征在于,丙烯精馏塔顶采出的丙烯产品中丙烯含量99.6wt%,丙烷含量0.4wt%。The process method for co-production of a propane dehydrogenation unit and an ethylene unit according to claim 1, wherein the propylene product extracted from the top of the propylene rectification tower has a propylene content of 99.6% by weight and a propane content of 0.4% by weight.
  9. 一种丙烷脱氢装置与乙烯装置联产的系统,用于上述权利要求1至8中任一项的丙烷脱氢装置与乙烯装置联产的工艺方法,其特征在于,包括:A system for the co-production of a propane dehydrogenation unit and an ethylene unit, used in the process method for the co-production of a propane dehydrogenation unit and an ethylene unit according to any one of claims 1 to 8, characterized in that it comprises:
    油气水洗塔、富气压缩机、富气压缩机出口冷却器、汽水分离器、富气干燥器、冷箱、气液分离罐、凝液输送泵、粗脱乙烷塔、粗脱乙烷塔顶冷凝器、粗脱乙烷塔顶回流罐、粗脱乙烷塔顶回流泵、粗脱乙烷塔底输送泵及丙烯精馏塔;Oil and gas washing tower, rich gas compressor, rich gas compressor outlet cooler, steam-water separator, rich gas dryer, cold box, gas-liquid separation tank, condensate transfer pump, crude de-ethanizer, crude de-ethanizer Top condenser, top reflux tank of crude de-ethanizer, top reflux pump of crude de-ethanizer, bottom transfer pump of crude de-ethanizer, and propylene distillation tower;
    丙烷脱氢反应单元的PDH产品富气从余热回收设备富气出口通过管道与油气水洗塔的侧下部的进气口连接,洗涤水通过管道与油气水洗塔的侧上部的 进水口连接;所述油气水洗塔的顶部出气口通过管道与富气压缩机的入口连接,富气压缩机的出口与富气压缩机出口冷却器的热端的进口通过管道连接;The PDH product rich gas of the propane dehydrogenation reaction unit is connected from the rich gas outlet of the waste heat recovery equipment to the air inlet on the lower side of the oil and gas washing tower through a pipeline, and the washing water is connected to the water inlet on the upper side of the oil and gas washing tower through the pipeline; The gas outlet at the top of the oil-gas washing tower is connected to the inlet of the rich gas compressor through a pipeline, and the outlet of the rich gas compressor is connected to the hot end inlet of the outlet cooler of the rich gas compressor through a pipeline;
    富气压缩机出口冷却器的热端的出口通过管道与汽水分离罐的进口相连,汽水分离罐顶部气相出口通过管道与富气干燥器的进口相连,富气干燥器的出口通过管道与冷箱的富气端进口连接,冷箱的富气端出口通过管道与气液分离器的进口相连;The hot end outlet of the rich gas compressor outlet cooler is connected to the inlet of the steam-water separator tank through a pipe, the gas-phase outlet on the top of the steam-water separator tank is connected to the inlet of the rich gas dryer through a pipe, and the outlet of the rich gas dryer is connected to the cold box through a pipe. The inlet of the rich gas end is connected, and the outlet of the rich gas end of the cold box is connected to the inlet of the gas-liquid separator through a pipe;
    气液分离罐顶部的气相出口通过管道与粗脱乙烷塔上部的进气口连接,气流分离罐底部的液相出口通过管路与凝液输送泵的进口连接,凝液输送泵的出口通过管道与粗脱乙烷塔的中部进液口连接;The gas-phase outlet on the top of the gas-liquid separation tank is connected to the air inlet on the upper part of the crude deethanizer through a pipeline, the liquid phase outlet at the bottom of the gas-liquid separation tank is connected to the inlet of the condensate transfer pump through a pipeline, and the outlet of the condensate transfer pump passes through The pipeline is connected with the liquid inlet in the middle of the crude de-ethanizer;
    粗脱乙烷塔顶部的气相出口通过管道与粗脱乙烷塔顶冷凝器的热端进口连接,粗脱乙烷塔顶冷凝器热出口与粗脱乙烷塔顶回流罐进口连接;The gas-phase outlet at the top of the crude de-ethanizer is connected to the hot end inlet of the crude de-ethanizer top condenser through a pipeline, and the hot outlet of the crude de-ethanizer top condenser is connected to the inlet of the crude de-ethanizer top reflux tank;
    粗脱乙烷塔顶回流罐顶部的气相出口通过管道连接到乙烯装置的第四段压缩机入口;粗脱乙烷塔顶回流罐底部的液相出口与粗脱乙烷塔顶回流泵的入口连接,粗脱乙烷塔顶回流泵的出口与粗脱乙烷塔顶回流口相连;The gas phase outlet at the top of the crude de-ethanizer reflux tank is connected to the inlet of the fourth stage compressor of the ethylene plant through a pipeline; the liquid phase outlet at the bottom of the crude de-ethanizer reflux tank and the inlet of the reflux pump at the top of the crude de-ethanizer Connect, the outlet of the reflux pump at the top of the crude de-ethanizer is connected to the reflux port at the top of the crude de-ethanizer;
    粗脱乙烷塔底的液相出口与粗脱乙烷塔底输送泵的入口连接,粗脱乙烷塔底输送泵的出口与丙烯精馏塔的进口连接;The liquid phase outlet at the bottom of the crude de-ethanizer is connected to the inlet of the crude de-ethanizer bottom transfer pump, and the outlet of the crude de-ethanizer bottom transfer pump is connected to the inlet of the propylene rectification tower;
    丙烯精馏塔顶的丙烷产品出口通过管道与深冷单元的入口连接,丙烯精馏塔底的丙烷出口与丙烷脱氢的反应单元入口连接。The propane product outlet at the top of the propylene rectification tower is connected to the inlet of the cryogenic unit through a pipeline, and the propane outlet at the bottom of the propylene rectification tower is connected to the inlet of the reaction unit for propane dehydrogenation.
PCT/CN2020/092435 2020-05-25 2020-05-26 Process method and system for co-production of propane dehydrogenation unit and ethylene unit WO2021237483A1 (en)

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