WO2021217932A1 - Method and apparatus for measuring thermal conductivity coefficient of lithium-ion battery cells - Google Patents

Method and apparatus for measuring thermal conductivity coefficient of lithium-ion battery cells Download PDF

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WO2021217932A1
WO2021217932A1 PCT/CN2020/105685 CN2020105685W WO2021217932A1 WO 2021217932 A1 WO2021217932 A1 WO 2021217932A1 CN 2020105685 W CN2020105685 W CN 2020105685W WO 2021217932 A1 WO2021217932 A1 WO 2021217932A1
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tested
battery
thermal conductivity
battery core
battery cells
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PCT/CN2020/105685
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French (fr)
Chinese (zh)
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刘施阳
云凤玲
栗敬敬
方彦彦
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国联汽车动力电池研究院有限责任公司
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Publication of WO2021217932A1 publication Critical patent/WO2021217932A1/en

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    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N25/00Investigating or analyzing materials by the use of thermal means
    • G01N25/20Investigating or analyzing materials by the use of thermal means by investigating the development of heat, i.e. calorimetry, e.g. by measuring specific heat, by measuring thermal conductivity
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/60Heating or cooling; Temperature control
    • H01M10/61Types of temperature control
    • H01M10/615Heating or keeping warm
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/60Heating or cooling; Temperature control
    • H01M10/65Means for temperature control structurally associated with the cells
    • H01M10/655Solid structures for heat exchange or heat conduction
    • H01M10/6554Rods or plates
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/60Heating or cooling; Temperature control
    • H01M10/65Means for temperature control structurally associated with the cells
    • H01M10/658Means for temperature control structurally associated with the cells by thermal insulation or shielding
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

Definitions

  • the method calculates the thermal conductivity of the battery core to be tested by the following formula:
  • is the thermal conductivity of the battery core to be tested
  • Q is the power of the heating plate
  • L is the thickness of the battery core to be tested
  • A is the plane cross-sectional area of the battery core to be tested
  • ⁇ T is the temperature difference between inside and outside.
  • the method further includes:
  • the planar cross-sectional area of the heating sheet is greater than 80% of the planar cross-sectional area of the battery core to be tested.
  • the method further includes:
  • the stable temperature gradient state includes:
  • the method further includes:
  • the measurement module is configured to select two battery cores to be tested and measure the properties of the battery cores to be tested;
  • a setting module configured to place the two battery cores to be tested between the cold plates, set the temperature of the cold plate, and stand the battery cores to be tested until the temperature is constant;
  • the embodiment of the present application provides a non-transitory computer-readable storage medium on which a computer program is stored.
  • the computer program is executed by a processor, the steps of the method for measuring the thermal conductivity of a lithium ion battery cell are realized.
  • FIG. 1 is a flowchart of a method for measuring thermal conductivity of a lithium ion battery cell in an embodiment of the application
  • FIG. 2 is a structural diagram of a device for measuring thermal conductivity of lithium ion battery cells in an embodiment of the application
  • FIG. 3 is a schematic diagram of the structure of an electronic device in an embodiment of the application.
  • FIG. 1 is a schematic flowchart of a method for measuring the thermal conductivity of a lithium-ion battery cell provided by the first embodiment of the application.
  • an embodiment of the present application provides a method for measuring the thermal conductivity of a lithium-ion battery cell.
  • Step S101 Select two battery cores to be tested, and measure the properties of the battery cores to be tested.
  • the battery cores can be lithium-ion battery cores with good uniformity.
  • the properties of the battery cores to be tested are measured. The properties can include the length, width, and length of the battery cores. High, area, volume, quality, etc.
  • insulating materials can be coated on the tabs of the battery core to be tested to prevent safety problems when the lithium-ion battery is subsequently heated by the heating plate.
  • Step S102 placing a heating sheet between the two battery cores to be tested, stacking the two battery cores to be tested with the heating sheet, and wrapping the heat conduction protection panel in the corresponding stacking direction, Wrap the insulation protection material in other directions.
  • a heating sheet is placed between the two battery cores to be tested, and the two battery cores to be tested and the heating sheet are stacked to form the battery core to be tested- Heater-the stacked structure of the battery core to be tested, and then wrap the battery core in the stacking direction to form a thermally conductive protective panel to form a thermally conductive protective panel-battery core to be tested-heating plate-battery core to be tested-heat conduction
  • the stacking direction is stacked up and down, the other directions can be 4 directions, front, back, left, and right. .
  • two battery cores to be tested are placed between the cold plates to form a structure of cold plate-thermally conductive protective panel-battery core to be tested-heating plate-battery core to be tested-thermally conductive protective panel-cold plate , And then set the cold plate temperature. After setting the cold plate temperature, let the battery core to be tested stand still to make the temperature of the above-mentioned structure constant, that is, the temperature of each component of the above-mentioned structure is consistent.
  • Step S104 Adjust the power of the heating plate several times, and after each adjustment, leave the battery core to be tested until the battery core to be tested enters a stable temperature gradient state, and record several sets of the stable temperature gradients The temperature of the inner and outer sides of the battery core to be tested in the state.
  • the power of the heating plate is adjusted several times, and after the power of the heating plate is adjusted each time, in the cold plate-the heat conduction protection panel-the battery core to be tested-the heating plate-
  • the heat can be transferred from the heating sheet to the cold plate through the battery core to be tested vertically, and it is allowed to stand until the battery core to be tested enters a stable temperature gradient state.
  • Step S105 Perform data fitting based on the attributes, the inner and outer temperatures of the battery cores to be tested, and the heater power corresponding to the inner and outer temperatures, to calculate the thermal conductivity of the battery cores to be tested.
  • the thermal conductivity of the battery to be tested is calculated.
  • the result can be linear fitting method based on least square method.
  • the value of R 2 should be greater than 0.98.
  • the embodiment of the application provides a method for measuring the thermal conductivity of lithium-ion battery cells, by wrapping the thermally conductive protective panel in the stacking direction corresponding to the stacking of the battery core to be tested and the heating sheet, and wrapping the thermally insulating protective material in other directions , To prevent the heat diffusion of the heating plate, and calculate the thermal conductivity of the battery core to be tested by data fitting through the measured properties, the inner and outer temperatures of the battery cores under test, and the heating plate power corresponding to the inner and outer temperatures , That is, the calculation method of thermal conductivity also has the characteristics of repeatability test.
  • the attribute includes:
  • the properties of the battery core to be tested include the thickness of the battery core to be tested, the plane cross-sectional area of the battery core to be tested, and the thickness of the battery core to be tested and the thickness of the battery core to be tested Data fitting is performed on the plane cross-sectional area, the inner and outer temperature values of several groups of battery cores to be tested and the heating plate power corresponding to the inner and outer temperature values, and the thermal conductivity of the battery cores to be tested is calculated.
  • is the thermal conductivity of the battery core to be tested
  • Q is the power of the heating plate
  • L is the thickness of the battery core to be tested
  • A is the plane cross-sectional area of the battery core to be tested
  • ⁇ T is the temperature difference between inside and outside.
  • the thermal conductivity of the battery core to be tested is calculated by fitting the above formula.
  • the calculation method is repeatable and the calculation result has high accuracy.
  • the method for measuring the thermal conductivity of a lithium-ion battery cell further includes:
  • the planar cross-sectional area of the heating sheet is greater than 80% of the planar cross-sectional area of the battery core to be tested.
  • the planar cross-sectional area of the heating plate is greater than 80% of the planar cross-sectional area of the battery core to be tested, because when the plane of the heating plate is The cross-sectional area is set large enough to ensure that during the heat conduction process of the heating plate, the heat will not spread in the non-stacking direction of the electric test core to be tested, and further prevent the influence of heat diffusion in other directions, thereby improving The accuracy of the measurement results is improved.
  • Fig. 2 is a device for measuring the thermal conductivity of lithium ion battery cells provided by an embodiment of the application, including: a measurement module 201, a placement module 202, a setting module 203, an adjustment module 204, and a data fitting module 205, in which:
  • the measurement module 201 is configured to select two battery cores to be tested and measure the properties of the battery cores to be tested.
  • the placing module 202 is configured to place a heating sheet between the two battery cores to be tested, and to stack the two battery cores to be tested with the heating sheet, and wrap the heat conduction protection panel in the corresponding stacking direction, and in other directions It is wrapped with heat-insulating protective material.
  • the setting module 203 is configured to place two battery cores to be tested between the cold plates, set the temperature of the cold plate, and stand the battery cores to be tested until the temperature is constant.
  • the adjustment module 204 is configured to adjust the power of the heating plate several times, and after each adjustment, the battery core to be tested is allowed to stand until the battery core to be tested enters a stable temperature gradient state, and several groups of the battery to be tested in the stable temperature gradient state are recorded The temperature of the inside and outside of the core.
  • the apparatus may further include:
  • the calculation module is configured to calculate the thermal conductivity of the battery core under test by the following formula:
  • is the thermal conductivity of the battery core to be tested
  • Q is the power of the heating plate
  • L is the thickness of the battery core to be tested
  • A is the plane cross-sectional area of the battery core to be tested
  • ⁇ T is the temperature difference between the inner and outer sides.
  • the apparatus may further include:
  • the plane cross-sectional area determination module is configured to determine that the plane cross-sectional area of the heating sheet is greater than 80% of the plane cross-sectional area of the battery core to be tested.
  • each module in the above device for measuring the thermal conductivity of a lithium ion battery cell can be implemented in whole or in part by software, hardware, and a combination thereof.
  • the above-mentioned modules may be embedded in the form of hardware or independent of the processor in the computer equipment, or may be stored in the memory of the computer equipment in the form of software, so that the processor can call and execute the operations corresponding to the above-mentioned modules.
  • FIG. 3 illustrates a schematic diagram of the physical structure of an electronic device.
  • the electronic device may include: a processor 301, a memory 302, a communication interface 303, and a communication bus 304, Among them, the processor 301, the memory 302, and the communication interface 303 communicate with each other through the communication bus 304.
  • the processor 301 can call the logic instructions in the memory 302 to execute the following method: select two battery cores to be tested, and measure the properties of the battery cores to be tested; place between the two battery cores to be tested Heating sheet, and stacking two of the battery cores to be tested with the heating sheet, wrapping the thermally conductive protective panel in the corresponding stacking direction, and wrapping the thermally insulating protective material in other directions;
  • the battery core is placed between the cold plates, the temperature of the cold plate is set, and the battery core to be tested is left to stand until the temperature is constant; the power of the heating plate is adjusted several times, and the heating plate is allowed to stand after each adjustment.
  • the aforementioned logic instructions in the memory 302 can be implemented in the form of computer executable instructions and when sold or used as an independent product, they can be stored in a computer readable storage medium. Therefore, an embodiment of this application provides a form of a computer software product.
  • the computer software product is stored in a storage medium and includes a number of instructions to enable a computer device (for example, a personal computer, a server, or Network equipment, etc.) execute all or part of the steps of the methods described in the embodiments of the present application.
  • the aforementioned storage media include: U disk, mobile hard disk, read-only memory (ROM, Read-Only Memory), random access memory (RAM, Random Access Memory), magnetic disks or optical disks and other media that can store program codes. .
  • the embodiments of the present application also provide a non-transitory computer-readable storage medium on which a computer program is stored.
  • the computer program is executed by a processor, the computer program is implemented to perform the transmission methods provided in the foregoing embodiments, for example, including : Select two battery cores to be tested and measure the properties of the battery cores to be tested; place a heater between the two battery cores to be tested, The heating sheets are stacked, and the heat-conducting protective panel is wrapped in the corresponding stacking direction, and the heat-insulating protective material is wrapped in other directions; the two battery cores to be tested are placed between the cold plates, and the cold plate temperature is set, And let the battery core to be tested until the temperature is constant; adjust the power of the heating plate several times, and after each adjustment, leave the battery core to be tested until the battery core to be tested enters a stable temperature Gradient state, recording the inner and outer temperatures of the battery core under test in several groups of the stable temperature gradient state; through the attribute, the inner and outer temperatures of the
  • the device embodiments described above are merely illustrative.
  • the units described as separate components may or may not be physically separated, and the components displayed as units may or may not be physical units, that is, they may be located in One location, or it can be distributed to multiple network units. Some or all of the modules can be selected according to actual needs to achieve the objectives of the solutions of the embodiments. Those of ordinary skill in the art can understand and implement it without creative work.
  • each implementation manner can be implemented by means of software plus a necessary general hardware platform, and of course, it can also be implemented by hardware.
  • the above technical solution essentially or the part that contributes to the existing technology can be embodied in the form of a software product, and the computer software product can be stored in a computer-readable storage medium, such as ROM/RAM, magnetic A disc, an optical disc, etc., include several instructions to make a computer device (for example, a personal computer, a server, or a network device, etc.) execute the methods described in each embodiment or some parts of the embodiment.

Abstract

Provided are a method and apparatus for measuring the thermal conductivity coefficient of lithium-ion battery cells. The method comprises: selecting two battery cells to be measured, and measuring the properties of said battery cells; placing a heating sheet between said battery cells, stacking said battery cells and the heating sheet, wrapping said battery cells with thermally conductive protective panels in the corresponding stacking direction, and wrapping same with thermal insulation protective materials in other directions; placing said two battery cells between cold plates, setting the temperature of the cold plates, and letting said battery cells stand until the temperature is constant; regulating the power of the heating sheet several times, and letting said battery cells stand after each regulation until said battery cells enter a stable temperature gradient state, and recording the inside and outside temperatures of said battery cells; and performing data fitting according to the properties, several groups of the inside and outside temperatures of said battery cells, and the corresponding heating sheet power, so as to calculate the thermal conductivity coefficient of said battery cells. By using the method, heat diffusion of a heating sheet can be prevented, the precision of a measurement result is improved, and a method for repeatedly measuring a thermal conductivity coefficient is also provided.

Description

测量锂离子电池电芯导热系数的方法及装置Method and device for measuring thermal conductivity of lithium ion battery cell
相关申请的交叉引用Cross-references to related applications
本申请要求于2020年4月30日提交的申请号为2020103672862,发明名称为“测量锂离子电池电芯导热系数的方法及装置”的中国专利申请的优先权,其通过引用方式全部并入本文。This application claims the priority of the Chinese patent application filed on April 30, 2020, with the application number 2020103672862 and the invention titled "Method and Device for Measuring Thermal Conductivity of Lithium Ion Battery Cells", which are fully incorporated herein by reference .
技术领域Technical field
本申请涉及电池参数测试领域,尤其涉及一种测量锂离子电池电芯导热系数的方法及装置。This application relates to the field of battery parameter testing, and in particular to a method and device for measuring the thermal conductivity of a lithium-ion battery cell.
背景技术Background technique
目前,以锂离子电池为主的电池因功率密度高、一致性好等优势,目前越来越多的应用于各个领域,锂电池在运行中,包括以下实际情况,1、动力电池热管理与安全是电池系统集成中的核心技术,热管理系统的优劣能直接影响电池系统的动力性、寿命和整包安全;2、优秀的热管理系统在设计时,离不开仿真分析,利用软件分析的手段,可以有效减少热管理系统设计的时间,降低设计风险,降低后期试验出现问题的概率等等,仿真分析可以显著提高热管理系统设计效率;3、准确的物性输入,是进行准确的仿真的前提条件;对于动力电池热管理系统设计中经常用到的温度场仿真,就需要一个准确的电芯的热物性参数输入;4、热物性包括:各向导热系数(或热扩散系数);5、随着电芯技术和产品不断更新,旧有的经验数据准确程度越来越低,需要更新参数数据库,且不同供应商的电芯产品,其参数存在差别。所以需要测量锂离子电池的导热系数。At present, due to the advantages of high power density and good consistency, lithium-ion batteries are currently more and more used in various fields. The operation of lithium batteries includes the following actual conditions: 1. Power battery thermal management and Safety is the core technology in battery system integration. The pros and cons of the thermal management system can directly affect the power, life and overall safety of the battery system; 2. The design of an excellent thermal management system is inseparable from simulation analysis and the use of software The analysis method can effectively reduce the design time of the thermal management system, reduce the design risk, reduce the probability of problems in the later test, etc. Simulation analysis can significantly improve the design efficiency of the thermal management system; 3. Accurate physical property input is accurate The prerequisite of simulation; for the temperature field simulation often used in the design of power battery thermal management system, an accurate input of the thermophysical parameters of the battery is required; 4. The thermophysical properties include: various thermal conductivity coefficients (or thermal diffusion coefficients) ; 5. With the continuous update of cell technology and products, the accuracy of the old experience data is getting lower and lower, and the parameter database needs to be updated, and the cell products of different suppliers have different parameters. Therefore, it is necessary to measure the thermal conductivity of lithium-ion batteries.
针对上述问题,目前有些技术能够测量锂离子电池的导热系数,比如通过防护热板法、导热系数瞬态法测量等方法,但是,上述方法,前者易受其他两方向热扩散影响,热量扩散进而影响测量结果的精度,后者对仪器设备要求高,且数据重复性较差。In view of the above problems, there are currently some technologies that can measure the thermal conductivity of lithium-ion batteries, such as the protective hot plate method and the transient thermal conductivity method. However, the former is susceptible to thermal diffusion in the other two directions. Affect the accuracy of the measurement results, the latter has high requirements for equipment and poor data repeatability.
发明内容Summary of the invention
针对现有技术中存在的问题,本申请实施例提供一种测量锂离子电池 电芯导热系数的方法及装置。In view of the problems in the prior art, the embodiments of the present application provide a method and device for measuring the thermal conductivity of a lithium ion battery cell.
本申请实施例提供一种测量锂离子电池电芯导热系数的方法,包括:The embodiment of the present application provides a method for measuring the thermal conductivity of a lithium-ion battery cell, including:
选取两块待测电池芯体,测量所述待测电池芯体的属性;Select two battery cores to be tested, and measure the properties of the battery cores to be tested;
在两块所述待测电池芯体之间放置加热片,并将两块所述待测电池芯体与所述加热片叠放,在对应的叠放方向上包裹导热防护面板,在其他方向上包裹绝热防护材质;Place a heating sheet between the two battery cores to be tested, and stack the two battery cores to be tested with the heating sheet, wrap the thermally conductive protective panel in the corresponding stacking direction, and in other directions Thermal insulation protection material for the upper package;
将所述两块待测电池芯体放置于冷板之间,设定冷板温度,并静置所述待测电池芯体直至温度恒定;Place the two battery cores to be tested between the cold plates, set the temperature of the cold plate, and leave the battery cores to be tested until the temperature is constant;
调节若干次所述加热片的功率,并在每次调节后静置所述待测电池芯体直至所述待测电池芯体进入稳定温度梯度状态,记录若干组所述稳定温度梯度状态时所述待测电池芯体的内外侧温度;Adjust the power of the heating plate several times, and after each adjustment, leave the battery core to be tested until the battery core to be tested enters a stable temperature gradient state, and record several sets of the stable temperature gradient state. State the inner and outer temperature of the battery core to be tested;
通过所述属性、若干组所述待测电池芯体的内外侧温度以及内外侧温度对应的加热片功率进行数据拟合,计算所述待测电池芯体的导热系数。The thermal conductivity of the battery core to be tested is calculated by data fitting based on the attributes, the inner and outer temperatures of the battery cores to be tested, and the heater power corresponding to the inner and outer temperatures of the battery cores.
在其中一个实施例中,所述属性,包括:In one of the embodiments, the attribute includes:
所述待测电池芯体的厚度、所述待测电池芯体的平面横截面积。The thickness of the battery core body to be tested, and the plane cross-sectional area of the battery core body to be tested.
在其中一个实施例中,所述方法通过如下公式计算所述待测电池芯体的导热系数:In one of the embodiments, the method calculates the thermal conductivity of the battery core to be tested by the following formula:
Figure PCTCN2020105685-appb-000001
Figure PCTCN2020105685-appb-000001
其中,λ为所述待测电池芯体的导热系数,Q为所述加热片的功率,L为所述待测电池芯体的厚度,A为所述待测电池芯体的平面横截面积,ΔT为内外侧温度差值。Where λ is the thermal conductivity of the battery core to be tested, Q is the power of the heating plate, L is the thickness of the battery core to be tested, and A is the plane cross-sectional area of the battery core to be tested , ΔT is the temperature difference between inside and outside.
在其中一个实施例中,所述方法还包括:In one of the embodiments, the method further includes:
所述加热片的平面横截面积大于所述待测电池芯体的平面横截面积的80%。The planar cross-sectional area of the heating sheet is greater than 80% of the planar cross-sectional area of the battery core to be tested.
在其中一个实施例中,所述方法还包括:In one of the embodiments, the method further includes:
所述冷板为包含循环液体冷却介质的面板。The cold plate is a panel containing a circulating liquid cooling medium.
在其中一个实施例中,所述稳定温度梯度状态,包括:In one of the embodiments, the stable temperature gradient state includes:
所述待测电池芯体的上下表面温度差为恒定值。The temperature difference between the upper and lower surfaces of the battery core to be tested is a constant value.
在其中一个实施例中,所述方法还包括:In one of the embodiments, the method further includes:
所述数据拟合为基于最小二乘法的线性拟合方式。The data fitting is a linear fitting method based on the least square method.
本申请实施例提供一种测量锂离子电池电芯导热系数的装置,包括:The embodiment of the application provides a device for measuring the thermal conductivity of a lithium-ion battery cell, including:
测量模块,配置为选取两块待测电池芯体,测量所述待测电池芯体的属性;The measurement module is configured to select two battery cores to be tested and measure the properties of the battery cores to be tested;
放置模块,配置为在两块所述待测电池芯体之间放置加热片,并将两块所述待测电池芯体与所述加热片叠放,在对应的叠放方向上包裹导热防护面板,在其他方向上包裹绝热防护材质;The placement module is configured to place a heating sheet between the two battery cores to be tested, stack the two battery cores to be tested and the heating sheet, and wrap the heat conduction protection in the corresponding stacking direction Panel, wrapped with heat-insulating protective material in other directions;
设定模块,配置为将所述两块待测电池芯体放置于冷板之间,设定冷板温度,并静置所述待测电池芯体直至温度恒定;A setting module, configured to place the two battery cores to be tested between the cold plates, set the temperature of the cold plate, and stand the battery cores to be tested until the temperature is constant;
调节模块,配置为调节若干次所述加热片的功率,并在每次调节后静置所述待测电池芯体直至所述待测电池芯体进入稳定温度梯度状态,记录若干组所述稳定温度梯度状态时所述待测电池芯体的内外侧温度;The adjustment module is configured to adjust the power of the heating plate several times, and after each adjustment, the battery core to be tested is allowed to stand until the battery core to be tested enters a stable temperature gradient state, and several sets of the stable temperature are recorded. The temperature of the inner and outer sides of the battery core to be tested in a temperature gradient state;
数据拟合模块,配置为通过所述属性、若干组所述待测电池芯体的内外侧温度以及内外侧温度对应的加热片功率进行数据拟合,计算所述待测电池芯体的导热系数。The data fitting module is configured to perform data fitting based on the attributes, several groups of the inner and outer temperatures of the battery core to be tested, and the heater power corresponding to the inner and outer temperatures, to calculate the thermal conductivity of the battery core to be tested .
本申请实施例提供一种电子设备,包括存储器、处理器及存储在存储器上并可在处理器上运行的计算机程序,所述处理器执行所述程序时实现上述测量锂离子电池电芯导热系数的方法的步骤。An embodiment of the present application provides an electronic device including a memory, a processor, and a computer program stored in the memory and capable of running on the processor. The processor executes the program to realize the above-mentioned measurement of the thermal conductivity of a lithium-ion battery cell. Steps of the method.
本申请实施例提供一种非暂态计算机可读存储介质,其上存储有计算机程序,该计算机程序被处理器执行时实现上述测量锂离子电池电芯导热系数的方法的步骤。The embodiment of the present application provides a non-transitory computer-readable storage medium on which a computer program is stored. When the computer program is executed by a processor, the steps of the method for measuring the thermal conductivity of a lithium ion battery cell are realized.
本申请实施例提供的测量锂离子电池电芯导热系数的方法及装置,通过在待测电池芯体与加热片叠放对应的叠放方向上包裹导热防护面板,在其他方向上包裹绝热防护材质,防止了加热片的热量扩散,并且通过测量得到的属性、若干组待测电池芯体的内外侧温度以及内外侧温度对应的加热片功率进行数据拟合,计算待测电池芯体的导热系数,即导热系数的计算方法也具有可重复性测试的特点。The method and device for measuring the thermal conductivity of lithium-ion battery cells provided by the embodiments of the present application are achieved by wrapping the thermal conductivity protection panel in the stacking direction corresponding to the stacking of the battery core to be tested and the heating sheet, and wrapping the thermal insulation protection material in other directions , To prevent the heat diffusion of the heating plate, and calculate the thermal conductivity of the battery core to be tested by data fitting through the measured properties, the inner and outer temperatures of the battery cores under test, and the heating plate power corresponding to the inner and outer temperatures , That is, the calculation method of thermal conductivity also has the characteristics of repeatability test.
附图说明Description of the drawings
为了更清楚地说明本申请实施例或现有技术中的技术方案,下面将对实施例或现有技术描述中所需要使用的附图作一简单地介绍,显而易见地, 下面描述中的附图是本申请的一些实施例,对于本领域普通技术人员来讲,在不付出创造性劳动的前提下,还可以根据这些附图获得其他的附图。In order to more clearly describe the technical solutions in the embodiments of the present application or the prior art, the following will briefly introduce the drawings that need to be used in the description of the embodiments or the prior art. Obviously, the drawings in the following description These are some embodiments of the present application. For those of ordinary skill in the art, other drawings can be obtained based on these drawings without creative work.
图1为本申请实施例中测量锂离子电池电芯导热系数的方法的流程图;FIG. 1 is a flowchart of a method for measuring thermal conductivity of a lithium ion battery cell in an embodiment of the application;
图2为本申请实施例中测量锂离子电池电芯导热系数的装置的结构图;2 is a structural diagram of a device for measuring thermal conductivity of lithium ion battery cells in an embodiment of the application;
图3为本申请实施例中电子设备结构示意图。FIG. 3 is a schematic diagram of the structure of an electronic device in an embodiment of the application.
具体实施方式Detailed ways
为使本申请实施例的目的、技术方案和优点更加清楚,下面将结合本申请实施例中的附图,对本申请实施例中的技术方案进行清楚、完整地描述,显然,所描述的实施例是本申请一部分实施例,而不是全部的实施例。基于本申请中的实施例,本领域普通技术人员在没有作出创造性劳动前提下所获得的所有其他实施例,都属于本申请保护的范围。In order to make the purpose, technical solutions and advantages of the embodiments of the present application clearer, the technical solutions in the embodiments of the present application will be described clearly and completely in conjunction with the accompanying drawings in the embodiments of the present application. Obviously, the described embodiments It is a part of the embodiments of the present application, but not all of the embodiments. Based on the embodiments in this application, all other embodiments obtained by those of ordinary skill in the art without creative work shall fall within the protection scope of this application.
图1为本申请第一实施例提供的测量锂离子电池电芯导热系数的方法的流程示意图,如图1所示,本申请实施例提供了一种测量锂离子电池电芯导热系数的方法,包括:FIG. 1 is a schematic flowchart of a method for measuring the thermal conductivity of a lithium-ion battery cell provided by the first embodiment of the application. As shown in FIG. 1, an embodiment of the present application provides a method for measuring the thermal conductivity of a lithium-ion battery cell. include:
步骤S101,选取两块待测电池芯体,测量所述待测电池芯体的属性。Step S101: Select two battery cores to be tested, and measure the properties of the battery cores to be tested.
具体地,选取两块待测量导热系数的电池芯体,电池芯体可以为均一性良好的锂离子电池芯体,测量待测电池芯体的属性,属性可以包括电池芯体的长、宽、高、面积、体积、质量等等,另外,可以在待测电池芯体的极耳上包覆绝缘材料,防止锂离子电池在后续通过加热片加热时出现安全问题。Specifically, select two battery cores whose thermal conductivity is to be measured. The battery cores can be lithium-ion battery cores with good uniformity. The properties of the battery cores to be tested are measured. The properties can include the length, width, and length of the battery cores. High, area, volume, quality, etc. In addition, insulating materials can be coated on the tabs of the battery core to be tested to prevent safety problems when the lithium-ion battery is subsequently heated by the heating plate.
步骤S102,在两块所述待测电池芯体之间放置加热片,并将两块所述待测电池芯体与所述加热片叠放,在对应的叠放方向上包裹导热防护面板,在其他方向上包裹绝热防护材质。Step S102, placing a heating sheet between the two battery cores to be tested, stacking the two battery cores to be tested with the heating sheet, and wrapping the heat conduction protection panel in the corresponding stacking direction, Wrap the insulation protection material in other directions.
具体地,在选取两块待测电池芯体后,在两块待测电池芯体之间放置加热片,并将两块待测电池芯体与加热片叠放,形成待测电池芯体-加热片-待测电池芯体的叠放结构,然后在叠放的方向上将电池芯体包裹导热防护面板,形成导热防护面板-待测电池芯体-加热片-待测电池芯体-导热防护面板的结构,并将其他方向上包裹绝热防护材质,其中,其他方向上是指叠放方向以外的其他方向,比如叠放方向是上下叠放的,则其他方向可以为前后左右4个方向。Specifically, after selecting two battery cores to be tested, a heating sheet is placed between the two battery cores to be tested, and the two battery cores to be tested and the heating sheet are stacked to form the battery core to be tested- Heater-the stacked structure of the battery core to be tested, and then wrap the battery core in the stacking direction to form a thermally conductive protective panel to form a thermally conductive protective panel-battery core to be tested-heating plate-battery core to be tested-heat conduction The structure of the protective panel, and wrap the heat-insulating protective material in other directions, where the other directions refer to other directions other than the stacking direction. For example, the stacking direction is stacked up and down, the other directions can be 4 directions, front, back, left, and right. .
步骤S103,将所述两块待测电池芯体放置于冷板之间,设定冷板温度,并静置所述待测电池芯体直至温度恒定。In step S103, the two battery cores to be tested are placed between the cold plates, the temperature of the cold plate is set, and the battery cores to be tested are left to stand until the temperature is constant.
具体地,将两块待测电池芯体放置于冷板之间,可以形成冷板-导热防护面板-待测电池芯体-加热片-待测电池芯体-导热防护面板-冷板的结构,然后设定冷板温度,在设置冷板温度后,静置待测电池芯体,使得上述结构的温度恒定,即上述结构各个构件的温度一致。另外,冷板的种类可以为包含循环液体冷却介质的面板,能够具有一定的散热能力,方便后续待测电池芯体进入稳定温度梯度状态,并且为防止电芯过热冷板的循环液体的油浴温度应低于10℃。Specifically, two battery cores to be tested are placed between the cold plates to form a structure of cold plate-thermally conductive protective panel-battery core to be tested-heating plate-battery core to be tested-thermally conductive protective panel-cold plate , And then set the cold plate temperature. After setting the cold plate temperature, let the battery core to be tested stand still to make the temperature of the above-mentioned structure constant, that is, the temperature of each component of the above-mentioned structure is consistent. In addition, the type of the cold plate can be a panel containing a circulating liquid cooling medium, which can have a certain heat dissipation capacity to facilitate the subsequent battery core to be tested to enter a stable temperature gradient state, and to prevent the battery core from overheating the circulating liquid oil bath of the cold plate The temperature should be below 10°C.
步骤S104,调节若干次所述加热片的功率,并在每次调节后静置所述待测电池芯体直至所述待测电池芯体进入稳定温度梯度状态,记录若干组所述稳定温度梯度状态时所述待测电池芯体的内外侧温度。Step S104: Adjust the power of the heating plate several times, and after each adjustment, leave the battery core to be tested until the battery core to be tested enters a stable temperature gradient state, and record several sets of the stable temperature gradients The temperature of the inner and outer sides of the battery core to be tested in the state.
具体地,在待测电池芯体的结构温度恒定后,调节若干次加热片的功率,在每次调节加热片的功率后,在冷板-导热防护面板-待测电池芯体-加热片-待测电池芯体-导热防护面板-冷板的结构中,热量可以由加热片垂直通过待测电池芯体传递到冷板上,将其静置直至待测电池芯体进入稳定温度梯度状态,其中,温度梯度状态可以为待测电池芯体的上下表面温度差为恒定值,即待测电池芯体靠近加热片一侧和靠近冷板一侧的温度之差为恒定值,在待测电池芯体进入稳定温度梯度状态后,记录待测电池芯体的内外侧温度,获取若干组待测电池芯体的内外侧温度数值。Specifically, after the structural temperature of the battery core to be tested is constant, the power of the heating plate is adjusted several times, and after the power of the heating plate is adjusted each time, in the cold plate-the heat conduction protection panel-the battery core to be tested-the heating plate- In the structure of the battery core to be tested-the heat conduction protection panel-the cold plate, the heat can be transferred from the heating sheet to the cold plate through the battery core to be tested vertically, and it is allowed to stand until the battery core to be tested enters a stable temperature gradient state. Among them, the temperature gradient state can be that the temperature difference between the upper and lower surfaces of the battery core to be tested is a constant value, that is, the temperature difference between the side of the battery core to be tested close to the heating plate and the side close to the cold plate is a constant value. After the core body enters a stable temperature gradient state, the inner and outer temperatures of the battery core to be tested are recorded, and the inner and outer temperature values of several groups of battery cores to be tested are obtained.
步骤S105,通过所述属性、若干组所述待测电池芯体的内外侧温度以及内外侧温度对应的加热片功率进行数据拟合,计算所述待测电池芯体的导热系数。Step S105: Perform data fitting based on the attributes, the inner and outer temperatures of the battery cores to be tested, and the heater power corresponding to the inner and outer temperatures, to calculate the thermal conductivity of the battery cores to be tested.
具体地。通过待测电池芯体的属性、若干组待测电池芯体的内外侧温度数值以及内外侧温度数值对应的加热片功率进行数据拟合,计算待测电池芯体的导热系数,其中,数据拟合可以通过基于最小二乘法的线性拟合方式,在通过最小二乘法进行线性拟合时,R 2的值应该大于0.98。 specifically. According to the properties of the battery core to be tested, the inner and outer temperature values of several groups of battery cores to be tested, and the heating plate power corresponding to the inner and outer temperature values, the thermal conductivity of the battery to be tested is calculated. The result can be linear fitting method based on least square method. When linear fitting is carried out by least square method, the value of R 2 should be greater than 0.98.
本申请实施例提供的一种测量锂离子电池电芯导热系数的方法,通过在待测电池芯体与加热片叠放对应的叠放方向上包裹导热防护面板,在其他方向上包裹绝热防护材质,防止了加热片的热量扩散,并且通过测量得 到的属性、若干组待测电池芯体的内外侧温度以及内外侧温度对应的加热片功率进行数据拟合,计算待测电池芯体的导热系数,即导热系数的计算方法也具有可重复性测试的特点。The embodiment of the application provides a method for measuring the thermal conductivity of lithium-ion battery cells, by wrapping the thermally conductive protective panel in the stacking direction corresponding to the stacking of the battery core to be tested and the heating sheet, and wrapping the thermally insulating protective material in other directions , To prevent the heat diffusion of the heating plate, and calculate the thermal conductivity of the battery core to be tested by data fitting through the measured properties, the inner and outer temperatures of the battery cores under test, and the heating plate power corresponding to the inner and outer temperatures , That is, the calculation method of thermal conductivity also has the characteristics of repeatability test.
在上述实施例的基础上,所述测量锂离子电池电芯导热系数的方法,所述属性,包括:On the basis of the foregoing embodiment, in the method for measuring the thermal conductivity of a lithium-ion battery cell, the attribute includes:
所述待测电池芯体的厚度、所述待测电池芯体的平面横截面积。The thickness of the battery core body to be tested, and the plane cross-sectional area of the battery core body to be tested.
在本申请实施例中,待测电池芯体的属性包括待测电池芯体的厚度、待测电池芯体的平面横截面积,并且通过待测电池芯体的厚度以及待测电池芯体的平面横截面积以及若干组待测电池芯体的内外侧温度数值以及内外侧温度数值对应的加热片功率进行数据拟合,计算待测电池芯体的导热系数。In the embodiment of this application, the properties of the battery core to be tested include the thickness of the battery core to be tested, the plane cross-sectional area of the battery core to be tested, and the thickness of the battery core to be tested and the thickness of the battery core to be tested Data fitting is performed on the plane cross-sectional area, the inner and outer temperature values of several groups of battery cores to be tested and the heating plate power corresponding to the inner and outer temperature values, and the thermal conductivity of the battery cores to be tested is calculated.
另外,可以通过如下公式计算所述待测电池芯体的导热系数:In addition, the thermal conductivity of the battery core to be tested can be calculated by the following formula:
Figure PCTCN2020105685-appb-000002
Figure PCTCN2020105685-appb-000002
其中,λ为所述待测电池芯体的导热系数,Q为所述加热片的功率,L为所述待测电池芯体的厚度,A为所述待测电池芯体的平面横截面积,ΔT为内外侧温度差值。Where λ is the thermal conductivity of the battery core to be tested, Q is the power of the heating plate, L is the thickness of the battery core to be tested, and A is the plane cross-sectional area of the battery core to be tested , ΔT is the temperature difference between inside and outside.
具体地,在数据拟合时,通过待测电池芯体的内外侧温度数值以及内外侧温度数值对应的加热片功率进行拟合得到拟合系数,再结合待测电池芯体的厚度、待测电池芯体的平面横截面积计算得到待测电池芯体的导热系数。Specifically, during data fitting, fitting coefficients are obtained by fitting the inner and outer temperature values of the battery core to be tested and the heating plate power corresponding to the inner and outer temperature values, and then combining the thickness of the battery core to be tested and the thickness of the battery to be tested. The plane cross-sectional area of the battery core is calculated to obtain the thermal conductivity of the battery core to be tested.
本申请实施例通过上述公式拟合计算待测电池芯体的导热系数,计算方法具有重复性且计算结果精度较高。In the embodiment of the present application, the thermal conductivity of the battery core to be tested is calculated by fitting the above formula. The calculation method is repeatable and the calculation result has high accuracy.
在上述实施例的基础上,所述测量锂离子电池电芯导热系数的方法,还包括:On the basis of the foregoing embodiment, the method for measuring the thermal conductivity of a lithium-ion battery cell further includes:
所述加热片的平面横截面积大于所述待测电池芯体的平面横截面积的80%。The planar cross-sectional area of the heating sheet is greater than 80% of the planar cross-sectional area of the battery core to be tested.
在本申请实施例中,加热片在与待测电池芯体进行叠放时,加热片的平面横截面积要大于待测电池芯体的平面横截面积的80%,因为当加热片的平面横截面积设置的足够大,才能保证在加热片进行加热的热传导过程中,热量不会在待测电测芯体的非叠放方向上进行传播,进一步防止其它 方向热扩散的影响,进而提高了测量结果的精度。In the embodiment of this application, when the heating plate is stacked with the battery core to be tested, the planar cross-sectional area of the heating plate is greater than 80% of the planar cross-sectional area of the battery core to be tested, because when the plane of the heating plate is The cross-sectional area is set large enough to ensure that during the heat conduction process of the heating plate, the heat will not spread in the non-stacking direction of the electric test core to be tested, and further prevent the influence of heat diffusion in other directions, thereby improving The accuracy of the measurement results is improved.
本申请实施例通过将加热片的平面横截面积设置为大于待测电池芯体的平面横截面积的80%,进一步防止热扩散的影响,进而提高了测量结果的精度。In the embodiment of the present application, by setting the planar cross-sectional area of the heating plate to be greater than 80% of the planar cross-sectional area of the battery core to be tested, the influence of thermal diffusion is further prevented, and the accuracy of the measurement result is improved.
图2为本申请实施例提供的一种测量锂离子电池电芯导热系数的装置,包括:测量模块201、放置模块202、设定模块203、调节模块204、数据拟合模块205,其中:Fig. 2 is a device for measuring the thermal conductivity of lithium ion battery cells provided by an embodiment of the application, including: a measurement module 201, a placement module 202, a setting module 203, an adjustment module 204, and a data fitting module 205, in which:
测量模块201,配置为选取两块待测电池芯体,测量待测电池芯体的属性。The measurement module 201 is configured to select two battery cores to be tested and measure the properties of the battery cores to be tested.
放置模块202,配置为在两块待测电池芯体之间放置加热片,并将两块待测电池芯体与加热片叠放,在对应的叠放方向上包裹导热防护面板,在其他方向上包裹绝热防护材质。The placing module 202 is configured to place a heating sheet between the two battery cores to be tested, and to stack the two battery cores to be tested with the heating sheet, and wrap the heat conduction protection panel in the corresponding stacking direction, and in other directions It is wrapped with heat-insulating protective material.
设定模块203,配置为将两块待测电池芯体放置于冷板之间,设定冷板温度,并静置待测电池芯体直至温度恒定。The setting module 203 is configured to place two battery cores to be tested between the cold plates, set the temperature of the cold plate, and stand the battery cores to be tested until the temperature is constant.
调节模块204,配置为调节若干次加热片的功率,并在每次调节后静置待测电池芯体直至待测电池芯体进入稳定温度梯度状态,记录若干组稳定温度梯度状态时待测电池芯体的内外侧温度。The adjustment module 204 is configured to adjust the power of the heating plate several times, and after each adjustment, the battery core to be tested is allowed to stand until the battery core to be tested enters a stable temperature gradient state, and several groups of the battery to be tested in the stable temperature gradient state are recorded The temperature of the inside and outside of the core.
数据拟合模块205,配置为通过属性、若干组待测电池芯体的内外侧温度以及内外侧温度对应的加热片功率进行数据拟合,计算待测电池芯体的导热系数。The data fitting module 205 is configured to perform data fitting based on attributes, the inner and outer temperatures of several groups of battery cores to be tested, and the heater power corresponding to the inner and outer temperatures, to calculate the thermal conductivity of the battery cores to be tested.
在一个实施例中,装置还可以包括:In an embodiment, the apparatus may further include:
计算模块,配置为通过如下公式计算待测电池芯体的导热系数:The calculation module is configured to calculate the thermal conductivity of the battery core under test by the following formula:
Figure PCTCN2020105685-appb-000003
Figure PCTCN2020105685-appb-000003
其中,λ为待测电池芯体的导热系数,Q为加热片的功率,L为待测电池芯体的厚度,A为待测电池芯体的平面横截面积,ΔT为内外侧温度差值。Among them, λ is the thermal conductivity of the battery core to be tested, Q is the power of the heating plate, L is the thickness of the battery core to be tested, A is the plane cross-sectional area of the battery core to be tested, and ΔT is the temperature difference between the inner and outer sides. .
在一个实施例中,装置还可以包括:In an embodiment, the apparatus may further include:
平面横截面积确定模块,配置为确定加热片的平面横截面积大于待测电池芯体的平面横截面积的80%。The plane cross-sectional area determination module is configured to determine that the plane cross-sectional area of the heating sheet is greater than 80% of the plane cross-sectional area of the battery core to be tested.
关于测量锂离子电池电芯导热系数的装置的具体限定可以参见上文 中对于测量锂离子电池电芯导热系数的方法的限定,在此不再赘述。上述测量锂离子电池电芯导热系数的装置中的各个模块可全部或部分通过软件、硬件及其组合来实现。上述各模块可以硬件形式内嵌于或独立于计算机设备中的处理器中,也可以以软件形式存储于计算机设备中的存储器中,以便于处理器调用执行以上各个模块对应的操作。For the specific definition of the device for measuring the thermal conductivity of the lithium ion battery cell, please refer to the above definition of the method for measuring the thermal conductivity of the lithium ion battery cell, which will not be repeated here. Each module in the above device for measuring the thermal conductivity of a lithium ion battery cell can be implemented in whole or in part by software, hardware, and a combination thereof. The above-mentioned modules may be embedded in the form of hardware or independent of the processor in the computer equipment, or may be stored in the memory of the computer equipment in the form of software, so that the processor can call and execute the operations corresponding to the above-mentioned modules.
图3示例了一种电子设备的实体结构示意图,如图3所示,该电子设备可以包括:处理器(processor)301、存储器(memory)302、通信接口(Communications Interface)303和通信总线304,其中,处理器301,存储器302,通信接口303通过通信总线304实现相互间的通信。处理器301可以调用存储器302中的逻辑指令,以执行如下方法:选取两块待测电池芯体,测量所述待测电池芯体的属性;在两块所述待测电池芯体之间放置加热片,并将两块所述待测电池芯体与所述加热片叠放,在对应的叠放方向上包裹导热防护面板,在其他方向上包裹绝热防护材质;将所述两块待测电池芯体放置于冷板之间,设定冷板温度,并静置所述待测电池芯体直至温度恒定;调节若干次所述加热片的功率,并在每次调节后静置所述待测电池芯体直至所述待测电池芯体进入稳定温度梯度状态,记录若干组所述稳定温度梯度状态时所述待测电池芯体的内外侧温度;通过所述属性、若干组所述待测电池芯体的内外侧温度以及内外侧温度对应的加热片功率进行数据拟合,计算所述待测电池芯体的导热系数。FIG. 3 illustrates a schematic diagram of the physical structure of an electronic device. As shown in FIG. 3, the electronic device may include: a processor 301, a memory 302, a communication interface 303, and a communication bus 304, Among them, the processor 301, the memory 302, and the communication interface 303 communicate with each other through the communication bus 304. The processor 301 can call the logic instructions in the memory 302 to execute the following method: select two battery cores to be tested, and measure the properties of the battery cores to be tested; place between the two battery cores to be tested Heating sheet, and stacking two of the battery cores to be tested with the heating sheet, wrapping the thermally conductive protective panel in the corresponding stacking direction, and wrapping the thermally insulating protective material in other directions; The battery core is placed between the cold plates, the temperature of the cold plate is set, and the battery core to be tested is left to stand until the temperature is constant; the power of the heating plate is adjusted several times, and the heating plate is allowed to stand after each adjustment. The battery core to be tested until the battery core to be tested enters a stable temperature gradient state, and the inner and outer temperatures of the battery core to be tested in several groups of the stable temperature gradient state are recorded; through the attributes, the plurality of groups Data fitting is performed on the inner and outer temperatures of the battery core to be tested and the heating plate power corresponding to the inner and outer temperatures, and the thermal conductivity of the battery core to be tested is calculated.
此外,上述的存储器302中的逻辑指令可以通过计算机可执行指令的形式实现并作为独立的产品销售或使用时,可以存储在一个计算机可读取存储介质中。本申请由此,本申请的一个实施例提供一种计算机软件产品的形式,该计算机软件产品存储在一个存储介质中,包括若干指令用以使得一台计算机设备(例如,个人计算机,服务器,或者网络设备等)执行本申请各个实施例所述方法的全部或部分步骤。而前述的存储介质包括:U盘、移动硬盘、只读存储器(ROM,Read-Only Memory)、随机存取存储器(RAM,Random Access Memory)、磁碟或者光盘等各种可以存储程序代码的介质。In addition, the aforementioned logic instructions in the memory 302 can be implemented in the form of computer executable instructions and when sold or used as an independent product, they can be stored in a computer readable storage medium. Therefore, an embodiment of this application provides a form of a computer software product. The computer software product is stored in a storage medium and includes a number of instructions to enable a computer device (for example, a personal computer, a server, or Network equipment, etc.) execute all or part of the steps of the methods described in the embodiments of the present application. The aforementioned storage media include: U disk, mobile hard disk, read-only memory (ROM, Read-Only Memory), random access memory (RAM, Random Access Memory), magnetic disks or optical disks and other media that can store program codes. .
另一方面,本申请实施例还提供一种非暂态计算机可读存储介质,其上存储有计算机程序,该计算机程序被处理器执行时实现以执行上述各实 施例提供的传输方法,例如包括:选取两块待测电池芯体,测量所述待测电池芯体的属性;在两块所述待测电池芯体之间放置加热片,并将两块所述待测电池芯体与所述加热片叠放,在对应的叠放方向上包裹导热防护面板,在其他方向上包裹绝热防护材质;将所述两块待测电池芯体放置于冷板之间,设定冷板温度,并静置所述待测电池芯体直至温度恒定;调节若干次所述加热片的功率,并在每次调节后静置所述待测电池芯体直至所述待测电池芯体进入稳定温度梯度状态,记录若干组所述稳定温度梯度状态时所述待测电池芯体的内外侧温度;通过所述属性、若干组所述待测电池芯体的内外侧温度以及内外侧温度对应的加热片功率进行数据拟合,计算所述待测电池芯体的导热系数。On the other hand, the embodiments of the present application also provide a non-transitory computer-readable storage medium on which a computer program is stored. When the computer program is executed by a processor, the computer program is implemented to perform the transmission methods provided in the foregoing embodiments, for example, including : Select two battery cores to be tested and measure the properties of the battery cores to be tested; place a heater between the two battery cores to be tested, The heating sheets are stacked, and the heat-conducting protective panel is wrapped in the corresponding stacking direction, and the heat-insulating protective material is wrapped in other directions; the two battery cores to be tested are placed between the cold plates, and the cold plate temperature is set, And let the battery core to be tested until the temperature is constant; adjust the power of the heating plate several times, and after each adjustment, leave the battery core to be tested until the battery core to be tested enters a stable temperature Gradient state, recording the inner and outer temperatures of the battery core under test in several groups of the stable temperature gradient state; through the attribute, the inner and outer temperatures of the battery core under test and the heating corresponding to the inner and outer temperatures Data fitting is performed on the sheet power, and the thermal conductivity of the battery core to be tested is calculated.
以上所描述的装置实施例仅仅是示意性的,其中所述作为分离部件说明的单元可以是或者也可以不是物理上分开的,作为单元显示的部件可以是或者也可以不是物理单元,即可以位于一个位置,或者也可以分布到多个网络单元上。可以根据实际的需要选择其中的部分或者全部模块来实现本实施例方案的目的。本领域普通技术人员在不付出创造性的劳动的情况下,即可以理解并实施。The device embodiments described above are merely illustrative. The units described as separate components may or may not be physically separated, and the components displayed as units may or may not be physical units, that is, they may be located in One location, or it can be distributed to multiple network units. Some or all of the modules can be selected according to actual needs to achieve the objectives of the solutions of the embodiments. Those of ordinary skill in the art can understand and implement it without creative work.
通过以上的实施方式的描述,本领域的技术人员可以清楚地了解到各实施方式可借助软件加必需的通用硬件平台的方式来实现,当然也可以通过硬件。基于这样的理解,上述技术方案本质上或者说对现有技术做出贡献的部分可以以软件产品的形式体现出来,该计算机软件产品可以存储在计算机可读存储介质中,如ROM/RAM、磁碟、光盘等,包括若干指令用以使得一台计算机设备(例如,个人计算机,服务器,或者网络设备等)执行各个实施例或者实施例的某些部分所述的方法。Through the description of the above implementation manners, those skilled in the art can clearly understand that each implementation manner can be implemented by means of software plus a necessary general hardware platform, and of course, it can also be implemented by hardware. Based on this understanding, the above technical solution essentially or the part that contributes to the existing technology can be embodied in the form of a software product, and the computer software product can be stored in a computer-readable storage medium, such as ROM/RAM, magnetic A disc, an optical disc, etc., include several instructions to make a computer device (for example, a personal computer, a server, or a network device, etc.) execute the methods described in each embodiment or some parts of the embodiment.
最后应说明的是:以上实施例仅用以说明本申请的技术方案,而非对其限制;尽管参照前述实施例对本申请进行了详细的说明,本领域的普通技术人员应当理解:其依然可以对前述各实施例所记载的技术方案进行修改,或者对其中部分技术特征进行等同替换;而这些修改或者替换,并不使相应技术方案的本质脱离本申请各实施例技术方案的精神和范围。Finally, it should be noted that the above embodiments are only used to illustrate the technical solutions of the application, not to limit them; although the application has been described in detail with reference to the foregoing embodiments, those of ordinary skill in the art should understand that: The technical solutions recorded in the foregoing embodiments are modified, or some of the technical features are equivalently replaced; these modifications or replacements do not cause the essence of the corresponding technical solutions to deviate from the spirit and scope of the technical solutions of the embodiments of the present application.

Claims (10)

  1. 一种测量锂离子电池电芯导热系数的方法,其特征在于,所述方法包括:A method for measuring the thermal conductivity of a lithium-ion battery cell, characterized in that the method includes:
    选取两块待测电池芯体,测量所述待测电池芯体的属性;Select two battery cores to be tested, and measure the properties of the battery cores to be tested;
    在两块所述待测电池芯体之间放置加热片,并将两块所述待测电池芯体与所述加热片叠放,在对应的叠放方向上包裹导热防护面板,在其他方向上包裹绝热防护材质;Place a heating sheet between the two battery cores to be tested, and stack the two battery cores to be tested with the heating sheet, wrap the thermally conductive protective panel in the corresponding stacking direction, and in other directions Thermal insulation protection material for the upper package;
    将所述两块待测电池芯体放置于冷板之间,设定冷板温度,并静置所述待测电池芯体直至温度恒定;Place the two battery cores to be tested between the cold plates, set the temperature of the cold plate, and leave the battery cores to be tested until the temperature is constant;
    调节若干次所述加热片的功率,并在每次调节后静置所述待测电池芯体直至所述待测电池芯体进入稳定温度梯度状态,记录若干组所述稳定温度梯度状态时所述待测电池芯体的内外侧温度;Adjust the power of the heating plate several times, and after each adjustment, leave the battery core to be tested until the battery core to be tested enters a stable temperature gradient state, and record several sets of the stable temperature gradient state. State the inner and outer temperature of the battery core to be tested;
    通过所述属性、若干组所述待测电池芯体的内外侧温度以及内外侧温度对应的加热片功率进行数据拟合,计算所述待测电池芯体的导热系数。The thermal conductivity of the battery core to be tested is calculated by data fitting based on the attributes, the inner and outer temperatures of the battery cores to be tested, and the heater power corresponding to the temperatures of the inner and outer sides of the battery.
  2. 根据权利要求1所述的测量锂离子电池电芯导热系数的方法,其特征在于,所述属性,包括:The method for measuring the thermal conductivity of a lithium-ion battery cell according to claim 1, wherein the attribute includes:
    所述待测电池芯体的厚度、所述待测电池芯体的平面横截面积。The thickness of the battery core body to be tested, and the plane cross-sectional area of the battery core body to be tested.
  3. 根据权利要求2所述的测量锂离子电池电芯导热系数的方法,其特征在于,通过如下公式计算所述待测电池芯体的导热系数:The method for measuring the thermal conductivity of a lithium-ion battery cell according to claim 2, wherein the thermal conductivity of the battery core to be tested is calculated by the following formula:
    Figure PCTCN2020105685-appb-100001
    Figure PCTCN2020105685-appb-100001
    其中,λ为所述待测电池芯体的导热系数,Q为所述加热片的功率,L为所述待测电池芯体的厚度,A为所述待测电池芯体的平面横截面积,ΔT为内外侧温度差值。Where λ is the thermal conductivity of the battery core to be tested, Q is the power of the heating plate, L is the thickness of the battery core to be tested, and A is the plane cross-sectional area of the battery core to be tested , ΔT is the temperature difference between inside and outside.
  4. 根据权利要求2所述的测量锂离子电池电芯导热系数的方法,其特征在于,所述方法还包括:The method for measuring the thermal conductivity of a lithium-ion battery cell according to claim 2, wherein the method further comprises:
    所述加热片的平面横截面积大于所述待测电池芯体的平面横截面积的80%。The planar cross-sectional area of the heating sheet is greater than 80% of the planar cross-sectional area of the battery core to be tested.
  5. 根据权利要求1所述的测量锂离子电池电芯导热系数的方法,其特征在于,所述方法还包括:The method for measuring the thermal conductivity of a lithium-ion battery cell according to claim 1, wherein the method further comprises:
    所述冷板为包含循环液体冷却介质的面板。The cold plate is a panel containing a circulating liquid cooling medium.
  6. 根据权利要求1所述的测量锂离子电池电芯导热系数的方法,其特征在于,所述稳定温度梯度状态,包括:The method for measuring the thermal conductivity of a lithium-ion battery cell according to claim 1, wherein the stable temperature gradient state comprises:
    所述待测电池芯体的上下表面温度差为恒定值。The temperature difference between the upper and lower surfaces of the battery core to be tested is a constant value.
  7. 根据权利要求1所述的测量锂离子电池电芯导热系数的方法,其特征在于,所述方法还包括:The method for measuring the thermal conductivity of a lithium-ion battery cell according to claim 1, wherein the method further comprises:
    所述数据拟合为基于最小二乘法的线性拟合方式。The data fitting is a linear fitting method based on the least square method.
  8. 一种测量锂离子电池电芯导热系数的装置,其特征在于,包括:A device for measuring the thermal conductivity of a lithium-ion battery cell, which is characterized in that it comprises:
    测量模块,配置为选取两块待测电池芯体,测量所述待测电池芯体的属性;The measurement module is configured to select two battery cores to be tested and measure the properties of the battery cores to be tested;
    放置模块,配置为在两块所述待测电池芯体之间放置加热片,并将两块所述待测电池芯体与所述加热片叠放,在对应的叠放方向上包裹导热防护面板,在其他方向上包裹绝热防护材质;The placement module is configured to place a heating sheet between the two battery cores to be tested, stack the two battery cores to be tested and the heating sheet, and wrap the heat conduction protection in the corresponding stacking direction Panel, wrapped with heat-insulating protective material in other directions;
    设定模块,配置为将所述两块待测电池芯体放置于冷板之间,设定冷板温度,并静置所述待测电池芯体直至温度恒定;A setting module, configured to place the two battery cores to be tested between the cold plates, set the temperature of the cold plate, and leave the battery cores to be tested until the temperature is constant;
    调节模块,配置为调节若干次所述加热片的功率,并在每次调节后静置所述待测电池芯体直至所述待测电池芯体进入稳定温度梯度状态,记录若干组所述稳定温度梯度状态时所述待测电池芯体的内外侧温度;The adjustment module is configured to adjust the power of the heating plate several times, and after each adjustment, the battery core to be tested is allowed to stand until the battery core to be tested enters a stable temperature gradient state, and several sets of the stable temperature are recorded. The temperature of the inner and outer sides of the battery core to be tested in a temperature gradient state;
    数据拟合模块,配置为通过所述属性、若干组所述待测电池芯体的内外侧温度以及内外侧温度对应的加热片功率进行数据拟合,计算所述待测电池芯体的导热系数。The data fitting module is configured to perform data fitting based on the attributes, several groups of the inner and outer temperatures of the battery core to be tested, and the heater power corresponding to the inner and outer temperatures, to calculate the thermal conductivity of the battery core to be tested .
  9. 一种电子设备,包括存储器、处理器及存储在存储器上并可在处理器上运行的计算机程序,其特征在于,所述处理器执行所述程序时实现如权利要求1至7任一项所述测量锂离子电池电芯导热系数的方法的步骤。An electronic device, comprising a memory, a processor, and a computer program stored on the memory and running on the processor, wherein the processor executes the program as described in any one of claims 1 to 7 The steps of the method for measuring the thermal conductivity of lithium-ion battery cells are described.
  10. 一种非暂态计算机可读存储介质,其上存储有计算机程序,其特征在于,该计算机程序被处理器执行时实现如权利要求1至7任一项所述测量锂离子电池电芯导热系数的方法的步骤。A non-transitory computer-readable storage medium with a computer program stored thereon, characterized in that, when the computer program is executed by a processor, the measurement of the thermal conductivity of a lithium-ion battery cell as described in any one of claims 1 to 7 is achieved Steps of the method.
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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1657923A (en) * 2004-02-21 2005-08-24 鸿富锦精密工业(深圳)有限公司 Device for measuring thermal coefficient
CN101949873A (en) * 2010-10-11 2011-01-19 华东师范大学 Device for measuring solid material heat conductivity
JP2013088258A (en) * 2011-10-17 2013-05-13 Nichias Corp Thermal conductivity measurement method
CN107966474A (en) * 2017-12-21 2018-04-27 中国科学院理化技术研究所 A kind of device based on steady state method measurement block thermal conductivity factor
CN108681619A (en) * 2018-04-03 2018-10-19 哈尔滨工业大学 Rectangular soft bag lithium ionic cell Thermophysical parameter identification method

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SU763757A1 (en) * 1978-12-08 1980-09-15 Научно-Исследовательский Институт Строительной Физики Госстроя Ссср Device for measuring heat conductance of materials
CN101556256B (en) * 2009-05-11 2012-06-27 天津科技大学 Dual-flat plate thermal conductivity coefficient measuring instrument of thermal insulation materials
CN202171579U (en) * 2011-05-19 2012-03-21 绍兴文理学院 Double test piece protection hot plate method heat conducting instrument
CN103411996B (en) * 2013-08-05 2016-03-02 电子科技大学 Solid material heat conductivity measurement mechanism and measuring method
CN203758943U (en) * 2014-03-24 2014-08-06 天津科技大学 Material heat conduction coefficient testing and metering device
CN109490355A (en) * 2017-09-13 2019-03-19 大唐移动通信设备有限公司 A kind of method of test device of thermal conductivity coefficient and heat conducting coefficient measuring
CN109001252A (en) * 2018-06-28 2018-12-14 西南电子技术研究所(中国电子科技集团公司第十研究所) Test device of thermal conductivity coefficient
CN109142431A (en) * 2018-07-19 2019-01-04 芜湖籁余新能源科技有限公司 A kind of Guarded hot plate heat conductivity measuring device
CN110333264B (en) * 2019-07-10 2022-03-15 北京工业大学 Method for testing heat conductivity coefficient of phase change material

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1657923A (en) * 2004-02-21 2005-08-24 鸿富锦精密工业(深圳)有限公司 Device for measuring thermal coefficient
CN101949873A (en) * 2010-10-11 2011-01-19 华东师范大学 Device for measuring solid material heat conductivity
JP2013088258A (en) * 2011-10-17 2013-05-13 Nichias Corp Thermal conductivity measurement method
CN107966474A (en) * 2017-12-21 2018-04-27 中国科学院理化技术研究所 A kind of device based on steady state method measurement block thermal conductivity factor
CN108681619A (en) * 2018-04-03 2018-10-19 哈尔滨工业大学 Rectangular soft bag lithium ionic cell Thermophysical parameter identification method

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