WO2021183047A1 - Compositions and methods for forming fat replacement substance for food products - Google Patents
Compositions and methods for forming fat replacement substance for food products Download PDFInfo
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- WO2021183047A1 WO2021183047A1 PCT/SG2021/050110 SG2021050110W WO2021183047A1 WO 2021183047 A1 WO2021183047 A1 WO 2021183047A1 SG 2021050110 W SG2021050110 W SG 2021050110W WO 2021183047 A1 WO2021183047 A1 WO 2021183047A1
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Classifications
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- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L29/00—Foods or foodstuffs containing additives; Preparation or treatment thereof
- A23L29/20—Foods or foodstuffs containing additives; Preparation or treatment thereof containing gelling or thickening agents
- A23L29/206—Foods or foodstuffs containing additives; Preparation or treatment thereof containing gelling or thickening agents of vegetable origin
- A23L29/262—Cellulose; Derivatives thereof, e.g. ethers
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- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L29/00—Foods or foodstuffs containing additives; Preparation or treatment thereof
- A23L29/10—Foods or foodstuffs containing additives; Preparation or treatment thereof containing emulsifiers
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- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L29/00—Foods or foodstuffs containing additives; Preparation or treatment thereof
- A23L29/20—Foods or foodstuffs containing additives; Preparation or treatment thereof containing gelling or thickening agents
- A23L29/206—Foods or foodstuffs containing additives; Preparation or treatment thereof containing gelling or thickening agents of vegetable origin
- A23L29/25—Exudates, e.g. gum arabic, gum acacia, gum karaya or tragacanth
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- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L33/00—Modifying nutritive qualities of foods; Dietetic products; Preparation or treatment thereof
- A23L33/20—Reducing nutritive value; Dietetic products with reduced nutritive value
- A23L33/21—Addition of substantially indigestible substances, e.g. dietary fibres
Definitions
- the present disclosure relates generally to compositions for fat replacement in food products, including fat replacement substances, methods of making or using the compositions or substances, emulsions and food products including the same.
- MCC microcrystalline cellulose
- hydrocolloid namely carboxymethylcellulose sodium orxanthan gum
- Microcrystalline cellulose also known as MCC or cellulose gel
- MCC Microcrystalline cellulose
- cellulose gel is commonly used in the food industry for food products. For example, it has been used as a binder and stabilizer in food applications, including in beverages. It has also been used in pharmaceutical formulations, in industrial applications, in household products such as detergent and/or bleach tablets, in agricultural formulations, and in personal care products such as cosmetics.
- Hydrocolloids are often used as thickeners to enhance viscosity in a range of products including food products.
- a first aspect of the invention relates to a composition for forming a fat replacement emulsion for food products comprising: 5 to 60 weight percent insoluble fibre; at least two hydrocolloid forming polysaccharides each having 0.2 to 10 weight percent; and 20 to 85 weight percent emulsifying agent, the weight percentages being based on the total composition.
- a fat replacement substance for food products comprising: the composition as described herein above, and an aqueous liquid combined under shear force.
- compositions as described herein above or the fat replacement substance as described herein above.
- a method of manufacturing a fat replacement substance for food products comprising: (a) adding the composition as described herein above to an aqueous liquid; and (b) applying shear force until the fat replacement substance forms.
- Figure 1 A schematic of the formation of composition and/or fat reducing substance for food products.
- Figure 2 A photograph comparing vegetarian burgers made with (A) full fat and (B) 69% reduced fat with an embodiment of the invention.
- Figure 3 Photographs of (A) an eggless low fat mayo made with an embodiment using exemplary composition 4 and (B) 50% low fat eggless mayo made with an embodiment using exemplary Composition 5.
- Figure 4 Photographs of (A) 60% substituted vegetable oil - water emulsion (W/O emulsion) made with an embodiment using exemplary composition 6 and (B) 60% substituted butter - water-in-oil emulsion (W/O emulsion) made with an embodiment using exemplary composition 6.
- Figure 5 Photographs of (A) and (B) mayonnaise made with non- substituted sunflower oil and (C) and (D) mayonnaise made with 18% of the sunflower oil substituted with a substance made with an embodiment using exemplary composition 6.
- Figure 6 Photographs of (A) cake made with non-substituted oil and (B) cake made with 50% of the oil substituted with a substance made with an embodiment using exemplary composition 6.
- Figure 7 Photographs of (A) cake made with non-substituted butter and (B) cake made with 60% of the butter substituted with a substance made with an embodiment using exemplary composition 6.
- Figure 8 Photographs of (A) cookies made with non-substituted oil and (B) cookies made with 60% of the oil substituted with a substance made with an embodiment using exemplary composition 6.
- Figure 9 Photographs of (A) cookies made with non-substituted butter and (B) cookies made with 40% of the butter substituted with a made with an embodiment using exemplary composition 6.
- Figure 10 Photographs of (A) bechamel sauce made with non- substituted butter and (B) bechamel sauce made with 60% of the butter substituted with a substance made with an embodiment using exemplary composition 6. (C) Rheological results for the flow of bechamel sauce made with non-substituted butter compared to bechamel sauce made with 60% of the butter substituted with a substance made with an embodiment using exemplary composition 6.
- Figure 11 Photographs of whole croissants, top row, and cross sections, bottom row, for (A) croissant made with non-substituted butter; (B) croissant baked for 35 minutes with 30% of the butter substituted with a substance made with an embodiment using exemplary composition 6; and (C) croissant baked for 40 minutes with 30% of the butter substituted with a substance made with an embodiment using exemplary composition 6.
- composition for forming a fat replacement emulsion for food products comprising: about 5 to 60 weight percent insoluble fibre; at least two hydrocolloid forming polysaccharides each having independently about 0.2 to 10 weight percent; and about 20 to 85 weight percent emulsifying agent, the weight percentages being based on the total composition.
- food products comprise anything that can be eaten or consumed by an animal including a human.
- food products comprise consumables that contain or are meant to contain lipids such as fats or oils.
- food products comprise baked goods such as, bread, biscuits, cookies, brownies, muffins, pastries, pies or cakes; beverages such as nut milks or other emulsions where an oil is added as an ingredient; sauces and condiments such as mayonnaise, bechamel sauce and tartar sauce; plant-based meat products such as plant-based minced meat substitutes, burger patties, sausages or other formed products; dairy or meat based products.
- the weight percent of the insoluble fibre is in the range of about 5 to 60. In various embodiments, the weight percent of the insoluble fibre is in the range of about 5 to 50. In various embodiments, the weight percent of the insoluble fibre is in the range of about 5 to 40. In various embodiments, the weight percent of the insoluble fibre is in the range of about 5 to 30. In various embodiments, the weight percent of the insoluble fibre is in the range of about 5 to 20. In various embodiments, the weight percent of the insoluble fibre is in the range of about 5 to 10. In various embodiments, the weight percent of the insoluble fibre is in the range of about 25 to 60. In various embodiments, the weight percent of the insoluble fibre is in the range of about 25 to 55.
- the weight percent of the insoluble fibre is in the range of about 25 to 50. In various embodiments, the weight percent of the insoluble fibre is in the range of about 25 to 40. In various embodiments, the weight percent of the insoluble fibre is in the range of about 30 to 40. In various embodiments, the weight percent of the insoluble fibre is in the range of about 30 to 35.
- the insoluble fibre is selected from cellulose fibres; and microcrystalline cellulose.
- the cellulose fibre may be purified cellulose fibre from various plant origins such as bamboo, wheat, oat, pea, sugar cane, or wood pulp.
- the microcrystalline cellulose is a partially hydrolyzed cellulose with degree of polymerization of 500 or fewer units.
- microcrystalline cellulose there are various methods for producing microcrystalline cellulose such as treating a source of cellulose, preferably alpha cellulose in the form of pulp from fibrous plant materials, with a mineral acid to attack the less ordered regions of the cellulose polymer chain thereby liberating the crystalline sites which form crystallite aggregates which constitute the microcrystalline cellulose. These are then purified in various different ways. Any microcrystalline cellulose known in the art would be suitable.
- microcrystalline cellulose is better at holding water than other insoluble fibres when it is used in combination with an emulsifying agent these components allow both the water and fat or lipid components of the food stay within an emulsion and are not lost due to evaporation or syneresis. This permits food having reduced fat to remain moist and juicy and have taste and/or texture similar to the food with full fat content.
- the insoluble fibre is MCC (microcrystalline cellulose) co-processed with a hydrocolloid or gum to assist with absorbing water faster.
- MCC microcrystalline cellulose
- the co-processed MCC comprises a microcrystalline cellulose in combination with a hydrocolloid, such as carboxymethylcellulose sodium or xanthan gum.
- the co-processed MCC comprises a microcrystalline cellulose in combination with carboxymethylcellulose sodium.
- the co-processed MCC is in a powered form called “MCC Gel” as it has the ability to absorb water faster than microcrystalline cellulose on its own.
- the microcrystalline cellulose gel or MCC gel is a coprocessed ingredient made up of roughly 88% microcrystalline cellulose with 12% carboxymethylcellulose sodium.
- the weight percent of the at least two hydrocolloid forming polysaccharides are each independently in the range of about 0.5 to 10. In various embodiments, the weight percent of the at least two hydrocolloid forming polysaccharides are each independently in the range of about 1 to 10. In various embodiments, the weight percent of the at least two hydrocolloid forming polysaccharides are each independently in the range of about 1 to 8. In various embodiments, the weight percent of the at least two hydrocolloid forming polysaccharides are each independently in the range of about is 1 to 6. In various embodiments, the weight percent of the at least two hydrocolloid forming polysaccharides are each independently in the range of about is 2 to 6.
- the weight percent of the at least two hydrocolloid forming polysaccharides are each independently in the range of about is 1 to 4. In various embodiments, the weight percent of the at least two hydrocolloid forming polysaccharides are each independently in the range of about is 2 to 4. In various embodiments, the weight percent of the at least two hydrocolloid forming polysaccharides are each independently the same weight percent. In various embodiments, the weight percent of the at least two hydrocolloid forming polysaccharides are different from each other. [0039] In various embodiments, the at least two hydrocolloid forming polysaccharides are a combination of two gums or hydrocolloids, where these may be natural, hydrolyzed or chemically derivatized celluloses. In various embodiments, the at least two hydrocolloid forming polysaccharides are a combination of three gums or hydrocolloids, where these may be natural, hydrolyzed or chemically derivatized celluloses.
- the hydrocolloid forming polysaccharide may comprise derivatized celluloses.
- the derivatized celluloses comprise carboxymethylcellulose and its sodium salt, hydroxypropylcellulose, hydroxypropylmethylcellulose, or methylcellulose.
- the methylcellulose may be selected from any methycellulose grades comprising A4C methycellulose grade, A15C methycellulose grade, A4M methycellulose grade, A100M methycellulose grade, MX methycellulose grade or any other suitable methycellulose grade derivatized cellulose.
- the methycellulose comprises A4C grade.
- the hydrocolloid forming polysaccharide may comprise other components such as protein.
- the hydrocolloid forming polysaccharide may be gums that comprise polysaccharides and protein.
- the gums may be natural gums such as Gum Arabic, guar gum; locust bean gum; beta glucan; Dammar gum; Glucomannan; Psyllium seed gum; Konjac gum; gellan gum; Tara gum; Gum Ghatti; and xanthan gum or other natural gums known in the art.
- Some gums such as Gum Arabic and Gum Ghatti demonstrated slight emulsifying properties that resulted in superior fat replacement substance for emulsions for use in food products with reduced fat content that have similar taste and texture to food products made with natural fats and oils or with a higher fat content.
- the at least two hydrocolloid forming polysaccharides are each selected from carboxymethylcellulose sodium; methylcellulose; Gum Arabica; guar gum; locust bean gum; beta glucan; Dammar gum; Glucomannan; Psyllium seed gum; Konjac gum; gellan gum; Tara gum; Gum Ghatti; and xanthan gum.
- the at least two hydrocolloid forming polysaccharides are uncharged hydrocolloid forming polysaccharides.
- the two uncharged hydrocolloid forming polysaccharides are a combination of two gums or hydrocolloids, where these may be natural, hydrolyzed or chemically derivatized celluloses.
- the two uncharged hydrocolloid forming polysaccharides are each selected from guar gum; locust bean gum; beta glucan; Dammar gum; Glucomannan; Psyllium seed gum; Tara gum; and xanthan gum.
- the derivatized celluloses comprise hydroxypropylcellulose, hydroxypropylmethylcellulose, or methylcellulose.
- the two uncharged hydrocolloid forming polysaccharides are guar gum and xanthan gum.
- Guar gum is a galactomannan polysaccharide.
- Xanthan gum is a pentasaccharide. Any known guar gum and xanthan gum may be used.
- the at least two hydrocolloid forming polysaccharides are selected from carboxymethylcellulose sodium; methylcellulose; Gum Arabica; guar gum; and xanthan gum. In various embodiments, the at least two hydrocolloid forming polysaccharides are a combination of carboxymethylcellulose sodium; methylcellulose; and Gum Arabica. In various embodiments, the at least two hydrocolloid forming polysaccharides are a combination of guargum and xanthan gum.
- a combination of guar gum and xanthan gum has the advantage of acting synergistically to enhance viscosity and stabilize any emulsion formed from the composition.
- the weight percent of the emulsifying agent is in the range of about 20 to 80. In various embodiments, the weight percent of the emulsifying agent is in the range of about 30 to 85. In various embodiments, the weight percent of the emulsifying agent is in the range of about 40 to 85. In various embodiments, the weight percent of the emulsifying agent is in the range of about 50 to 85. In various embodiments, the weight percent of the emulsifying agent is in the range of about 60 to 85. In various embodiments, the weight percent of the emulsifying agent is in the range of about 70 to 85. In various embodiments, the weight percent of the emulsifying agent is in the range of about 80 to 85.
- the weight percent of the emulsifying agent is in the range of about 20 to 60. In various embodiments, the weight percent of the emulsifying agent is in the range of about 20 to 65. In various embodiments, the weight percent of the emulsifying agent is in the range of about 30 to 60. In various embodiments, the weight percent of the emulsifying agent is in the range of about 40 to 60. In various embodiments, the weight percent of the emulsifying agent is in the range of about 50 to 60. In various embodiments, the weight percent of the emulsifying agent is in the range of about 55 to 60. In various embodiments, the weight percent of the emulsifying agent is in the range of about 50 to 55. In various embodiments, the weight percent of the emulsifying agent is in the range of about 55 to 60. In various embodiments, the weight percent of the emulsifying agent is in the range of about 59 to 60.
- the emulsifying agent comprises one emulsifier.
- the emulsifying agent comprises two emulsifiers.
- the emulsifying agent is selected from a sugar ester; a starch esterified with octenylsuccinic compound; a low Hydrophilic-Lipophilic Balance (HLB) emulsifier and acetylated starch.
- the emulsifying agent comprises sodium starch octenylsuccinate which may be added in a dry form or a pregelatinized form.
- the emulsifying agent comprises a low Hydrophilic-Lipophilic Balance (HLB) emulsifier.
- the low Hydrophilic-Lipophilic Balance (HLB) emulsifier comprises at least one of polygycerol polyricinoleate, sucrose esters, mono-diglycerides or lecithins.
- the emulsifying agent is a combination of a HLB emulsifier and sodium starch octenylsuccinate.
- a component with emulsifying or emulsion-stabilising properties such as, sodium starch octenylsuccinate, ensures both the water and fat or lipid components of the food stay within an emulsion and are not lost due to evaporation or syneresis. This permits food having reduced fat to remain moist and juicy and have taste and/or texture similar to the food produced with full fat content.
- the emulsifying agent is an esterified or an acetylated saccharide.
- the esterified or the acetylated saccharide includes an esterified or an acetylated monosaccharide.
- the esterified or the acetylated saccharide includes an esterified or an acetylated polysaccharide.
- esterification or acetylation of saccharides increases the stability of the emulsifying agents emulsifying effect.
- the emulsifying agent makes the composition capable of interacting stably with fat components of food products due to the lipophilic regions of the emulsifying agent at the molecular level.
- the sugar ester comprises a sucrose ester or a glucose ester.
- the starch esterified with octenylsuccinic compound is esterified with octenylsuccinic anhydride.
- the starch esterified with octenylsuccinic compound comprises sodium starch octenylsuccinate or aluminium starch octenylsuccinate.
- the starch esterified with octenylsuccinic compound is esterified or derivatized with octenylsuccinic acid.
- the resulting modified starch is one that has both hydrophilic regions as well as lipophilic regions owing to the octenyl chains.
- the emulsifying agent comprises sodium starch octenylsuccinate.
- the sodium starch octenylsuccinate comprises food grade sodium starch octenylsuccinate E1450.
- the insoluble fibre is microcrystalline cellulose
- the two hydrocolloid forming polysaccharides are guar gum and xanthan gum
- the emulsifying agent is sodium starch octenylsuccinate.
- the weight ratio of microcrystalline cellulose : xanthan gum : guar gum : sodium starch octenylsuccinate is 15.5 : 2 : 1 : 31 .5. In various embodiments, the weight ratio of microcrystalline cellulose : xanthan gum : guar gum : sodium starch octenylsuccinate is 31 :4:2:64.
- the insoluble fibre is microcrystalline cellulose; the at least two hydrocolloid forming polysaccharides are carboxymethylcellulose sodium, methylcellulose and Gum arabic; and the emulsifying agent is a combination of sodium starch octenylsuccinate and a low HLB emulsifier such as polyglycerol polyricinoleate.
- the weight ratio of microcrystalline cellulose : carboxymethylcellulose sodium : methylcellulose : Gum arabic : sodium starch octenylsuccinate : polyglycerol polyricinoleate is 42:6:12:24:383:33.
- a fat replacement substance for food products comprises: the composition of any one of the composition embodiments described herein above, and an aqueous liquid combined under shear force.
- the resultant emulsion is also more stable and does not separate as easily as the prior art when in use in food products.
- the aqueous liquid comprises water, juice, brine, soup or any other aqueous liquids suitable for cooking, baking or food products.
- the aqueous liquid comprises a water based liquid comprising 50% or more water of the total volume of the liquid; 55% or more water of the total volume of the liquid; 60% or more water of the total volume of the liquid; 65% or more water of the total volume of the liquid; 70% or more water of the total volume of the liquid; 75% or more water of the total volume of the liquid; 80% or more water of the total volume of the liquid; 85% or more water of the total volume of the liquid; 90% or more water of the total volume of the liquid; 95% or more water of the total volume of the liquid; or 100% water of the total volume of the liquid.
- the aqueous liquid may comprise a lipid component at a concentration less than the water component.
- the weight ratio of the composition to aqueous liquid is in the range of 1 : 19 to 1 : 4. In various embodiments, the composition is intended to be dosed with aqueous liquid in a weight ratio of 5-20% composition.
- the weight ratio of the composition to aqueous liquid is 1 :6 to 1 :7, 1 : 6.7 or 1 :7.
- the composition is intended to be dosed with aqueous liquid in a weight ratio of 12-13% composition.
- the fat replacement substance for food products may further comprise a lipid such as an oil or a fat.
- the lipid is at a concentration less than the aqueous liquid.
- the fat replacement substance may be used to replace the following:
- Plant source vegetable oils (for example canola, soy, rice bran, sunflower, peanut, palm), hydrogenated vegetable oils, (for example: cocoa butter, palm kernel oil).
- vegetable oils for example canola, soy, rice bran, sunflower, peanut, palm
- hydrogenated vegetable oils for example: cocoa butter, palm kernel oil
- a food product comprising the composition of any one of the composition embodiments described herein above, or the fat replacement substance of any one of the fat replacement substance embodiments described herein above.
- food products comprise anything that can be eaten or consumed by an animal including a human.
- food products comprise consumables that contain or are meant to contain lipids such as fats or oils.
- the food product comprises baked goods.
- the baked goods comprise bakery products, selected from the group comprising or consisting of breads, cakes, cookies, brownies, muffins pastries and pies.
- the food product comprises plant-based meat substitutes.
- the plant-based meat substitutes are selected from the group comprising or consisting of plant-based minced meat substitutes, burger patties, sausages or other formed products.
- the plant- based meat substitutes may comprise fungal base meat substitutes.
- the food product comprises a meat composite.
- the food product comprises a sauce.
- the food product comprises any sauce used with food including but not limited to mayonnaise, hollandaise sauce bechamel sauce or tartar sauce.
- the sauce comprises a condiment selected from the group comprising or consisting of mayonnaise, hollandaise sauce and tartar sauce.
- the food product comprises a drink.
- the drink is selected from the group comprising or consisting of nut milks and other emulsions where an oil is added as an ingredient
- a method of manufacturing a fat replacement substance for food products comprising: (a) adding the composition of any one of the composition embodiments described herein above to an aqueous liquid; and (b) applying shear force until the fat replacement substance forms.
- the aqueous liquid comprises water, juice, brine, soup or any other aqueous liquids suitable for cooking, baking or food products.
- the aqueous liquid comprises a water based liquid comprising 50% or more water of the total volume of the liquid; 55% or more water of the total volume of the liquid; 60% or more water of the total volume of the liquid; 65% or more water of the total volume of the liquid; 70% or more water of the total volume of the liquid; 75% or more water of the total volume of the liquid; 80% or more water of the total volume of the liquid; 85% or more water of the total volume of the liquid; 90% or more water of the total volume of the liquid; 95% or more water of the total volume of the liquid; or 100% water of the total volume of the liquid.
- the aqueous liquid may comprise a lipid component at a concentration less than the water component.
- applying shear force may be affected by means of a high shear cutter, granulator, planetary mixer, food processor, mortar and pestle or any equipment capable of generating strong shearing forces.
- the composition is added to the aqueous liquid at a weight ratio in the range of 1 : 19 to 1 : 4. In various embodiments, the composition is intended to be dosed with aqueous liquid in a weight ratio of 5-20% composition.
- the composition is added to the aqueous liquid at a weight ratio of 1 : 6, 1 : 6.7, 1 :7 or 1 :6 to 1 :7.
- the composition is intended to be dosed with aqueous liquid in a weight ratio of 12 -13% composition.
- the method further comprises adding a lipid to the fat replacement substance such as an oil or a fat to the fat replacement substance either before or during applying shear force to form a fat replacement emulsion.
- a lipid to the fat replacement substance such as an oil or a fat to the fat replacement substance either before or during applying shear force to form a fat replacement emulsion.
- the fat reducing emulsion will allow the fat reducing emulsion to be used as the total substitute for the lipid used in the original recipe. For example, where 100 grams of vegetable oil is called for and a 50% reduction of the oil is required, water and oil can be added in equal parts to the composition either before or during applying shear force. The required amount of 100 grams of the resulting fat reducing emulsion can then be used as a complete replacement of the vegetable oil used in the original recipe.
- the composition is able to emulsify with the remaining fat/oil to form a stable, flowable emulsion that can evoke the mouthfeel of an oily substance or the creaminess of a fat.
- the fat reducing emulsion may be made with the aqueous liquid. Then where 100 grams of vegetable oil is called for and a 50% reduction of the oil is required, 50 grams of the fat reducing emulsion and 50 grams of the vegetable oil may be used in making the food product added in the same way the vegetable oil is instructed to be added.
- Example 1 baked goods [0082] Composition 1 [0083] Composition 1 was used in bakery products, when a banana bread
- Composition 3 was sheared in a weight ratio of 4.6% composition 3 with 95.4% water and subjected to high shear to create a gel-like substance that works as the fat replacement substance.
- Composition 4 was sheared in a weight ratio of 12.75% composition 4 with 87.25% water and subjected to high shear to create a gel-like substance that works as the fat replacement substance.
- composition 3 and 4 were each employed in plant-based burger patty, replacing 60% and 69% of the original oils used in the original formulation. These patties were assessed to be generally moist and juicy, with the 69% replacement version made with composition 3 coming across as less moist than the original. It was also observed to dry up faster on cooling (See table 1). In comparison where composition 4 was used in 69% fat reduction in plant-based burger patties it was able to produce a well-received prototype that stayed moist on cooling.
- Figure 2 depicts two types of vegetarian patties.
- the one on the left ( Figure 2 (a)) is a full fat version.
- the one on the right ( Figure 2 (b)) is made with Composition 4 with 69% fat reduction. No observable visual differences were noted.
- Example 3 Sauces & Condiments
- composition 4 and 5 were employed in mayonnaise. Each composition was dosed with water in a weight-based ratio of 15.3% composition 4 or 5 and 84.7% water. Each mixture was subjected to high shear to create a gel-like substance that works as the fat replacement substance. 50% of the original oil content of the mayonnaise was replaced with fat replacement substances formed with composition 4 or 5. Both the resulting mayonnaises were assessed favorably by testers. The mayonnaise formed with fat replacement substance formed with composition 4 remained stable on storage at 4°C for more than 1 month. The mayonnaise formed with fat replacement substance formed with composition 5 exhibited some syneresis, where water separated from the mayonnaise and collected on top.
- Example 4 Example 4
- microcrystalline cellulose gel Roughly 88% of microcrystalline cellulose was co-processed with 12% carboxymethylcellulose sodium and formed into a powder called microcrystalline cellulose gel or MCC gel.
- composition 6 was dosed with water in a weight-based ratio of 10.5% composition 6 and 89.5% water. Each mixture was subjected to high shear to create a gel-like substance that works as the fat replacement substance. This ratio was maintained whether the substitution of fat/oil was carried out at 50, 60 or 70% substitution. The exact ratios are as follows:
- composition 6 As a general rule an amount of composition 6 was used that corresponds to one-tenth the amount of substitution required. Therefore, should 60 % reduction of fat be desired, the amount of composition 6 can be regarded as 6g per
- a homogenous emulsion with a smooth glossy surface should form.
- Composition 6 has the advantage of being able to create W/O emulsions even in the presence of more water than oil. This is hypothesised to be due to the use of at least two emulsifiers to extend the functionalities of oil even with substantial substitution. Composition 6 was used to make Mayonnaise, cakes, cookies, bechamel sauce and flaky pastries.
- Mayonnaise was made with composition 6 by substituting 18% of vegetable oil with a substance formed with composition 6 or with non-substituted oil.
- the mayonnaise recipe required 70% oil.
- Both mayonnaises were oil-in-water emulsions as is typical of mayonnaise.
- the normal mayonnaise made with non- substituted sunflower oil is depicted in Figures 5A and 5B and the mayonnaise made with 18% of the vegetable oil substituted with a substance formed with composition 6 is depicted in Figure 5C and 5D.
- the mayonnaise formed with 18% of the vegetable oil substituted with a substance formed from composition 6 could not be discerned from the mayonnaise made with non-substituted oil by 3 testers amongst a panel of 8 (37.5%) based on taste and textural differences. Similarly, 4 tasters amongst a panel of 8 (50%) preferred the lower fat mayonnaise (see Table 2).
- Table 3 Firmness of the cakes were assessed by a TA.XT plus texture analyser.
- a model cookie recipe using oil was used to investigate the effects of fat substitution in cookies/biscuits that use oil as the main fat component.
- cookies made with 60% of oil in a cookie recipe substituted with a substance formed with composition 6 was achieved with a slightly extended baking time.
- Cookies made with 50% of oil in a cookie recipe substituted with a substance formed with composition 6 required the same baking time as cookies made with unsubstituted oil.
- the normal cookies made with non-substituted oil is depicted in Figures 8A and the cookies made with 60% of the oil substituted with a substance formed with composition 6 is depicted in Figure 8B.
- the lower fat cookies were found to be slightly harder than the original recipe as analysed by a TA.XT texture analyser (see Table 7).
- Table 7 Firmness of the cookies were assessed by a TA.XT plus texture analyser.
- Table 9 Firmness of the cookies were assessed by a TA.XT plus texture analyser.
- Bechamel sauce is a butter-based sauce commonly used in several dishes. Successful butter substitution of 60% was achieved without large deviations from the original texture. Bechamel sauce was made with 60% of butter in a bechamel sauce recipe substituted with a substance formed with composition 6.
- the normal bechamel sauce made with non-substituted butter is depicted in Figures 10A and the bechamel sauce made with 60% of the butter substituted with a substance formed with composition 6 is depicted in Figure 10B.
- FIG 10C Theologically, the original sauce with no substitution and the lower fat sauce made with 60% of the butter substituted with a substance formed with composition 6 performed similarly. This demonstrates the effectiveness of a substance formed with composition 6 in replicating the flow properties of fat. Consequently, on a panel of 10 testers, almost all preferred the lower fat bechamel sauce citing superior taste and texture (see Table 11).
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Abstract
Compositions for fat replacement in food products, including fat replacement substances, methods of making or using the compositions or substances and food products including the same are disclosed. The composition is employable in sauces and condiments such as mayonnaise and tartar sauce, in plant-based meat products such as plant-based minced meat substitutes, burger patties, sausages or other formed products. It is also employable in bakery products, such as breads, cakes, cookies, brownies, flaky pastries, and other relevant products, as well as drinks such as nut milks or other emulsions where an oil is added as an ingredient.
Description
COMPOSITIONS AND METHODS FOR FORMING FAT REPLACEMENT SUBSTANCE
FOR FOOD PRODUCTS
CROSS REFERENCE TO RELATED APPLICATIONS
[0001] This application claims the priority to Singapore patent application No. 10202002148W, filed 9 March 2020, the contents of which are incorporated herein by reference.
FIELD
[0002] The present disclosure relates generally to compositions for fat replacement in food products, including fat replacement substances, methods of making or using the compositions or substances, emulsions and food products including the same.
BACKGROUND
[0003] The following discussion of the background to the invention is intended to facilitate an understanding of the present invention only. It should be appreciated that the discussion is not an acknowledgement or admission that any of the material referred to was published, known or part of the common general knowledge of the person skilled in the art in any jurisdiction as at the priority date of the invention.
[0004] Most fat replacement technologies offered consist of microcrystalline cellulose (MCC) co-processed or blended with a hydrocolloid, namely carboxymethylcellulose sodium orxanthan gum. Products made with such compositions lack good mouthfeel as they often lose texture over time. Such fat replacement compositions result in products that are inferior with regard to taste and/or texture due to the loss of moistness and juiciness.
[0005] Microcrystalline cellulose, also known as MCC or cellulose gel, is commonly used in the food industry for food products. For example, it has been used as a binder and stabilizer in food applications, including in beverages. It has also been used in pharmaceutical formulations, in industrial applications, in household products such as detergent and/or bleach tablets, in agricultural formulations, and in personal care products such as cosmetics.
[0006] Hydrocolloids are often used as thickeners to enhance viscosity in a range of products including food products.
[0007] There exists a need to provide compositions and methods that alleviate at least one of the aforementioned problems.
SUMMARY
[0008] An improved composition for fat replacement in food products and methods of making or using the same is envisaged.
[0009] Accordingly, a first aspect of the invention relates to a composition for forming a fat replacement emulsion for food products comprising: 5 to 60 weight percent insoluble fibre; at least two hydrocolloid forming polysaccharides each having 0.2 to 10 weight percent; and 20 to 85 weight percent emulsifying agent, the weight percentages being based on the total composition.
[0010] According to another aspect of the invention relates to a fat replacement substance for food products comprising: the composition as described herein above, and an aqueous liquid combined under shear force.
[0011] According to another aspect of the invention relates to a food product comprising the composition as described herein above, or the fat replacement substance as described herein above.
[0012] According to another aspect of the invention relates to a method of manufacturing a fat replacement substance for food products comprising: (a) adding the composition as described herein above to an aqueous liquid; and (b) applying shear force until the fat replacement substance forms.
[0013] Other aspects and features of the present invention will become apparent to those of ordinary skill in the art upon review of the following description of specific embodiments of the invention in conjunction with the accompanying figures.
BRIEF DESCRIPTION OF THE DRAWINGS
[0014] In the figures, which illustrate, by way of non-limiting examples only, embodiments of the present invention,
[0015] Figure 1: A schematic of the formation of composition and/or fat reducing substance for food products.
[0016] Figure 2: A photograph comparing vegetarian burgers made with (A) full fat and (B) 69% reduced fat with an embodiment of the invention.
[0017] Figure 3: Photographs of (A) an eggless low fat mayo made with an embodiment using exemplary composition 4 and (B) 50% low fat eggless mayo made with an embodiment using exemplary Composition 5.
[0018] Figure 4: Photographs of (A) 60% substituted vegetable oil - water emulsion (W/O emulsion) made with an embodiment using exemplary composition 6 and (B) 60% substituted butter - water-in-oil emulsion (W/O emulsion) made with an embodiment using exemplary composition 6.
[0019] Figure 5: Photographs of (A) and (B) mayonnaise made with non- substituted sunflower oil and (C) and (D) mayonnaise made with 18% of the sunflower oil substituted with a substance made with an embodiment using exemplary composition 6.
[0020] Figure 6: Photographs of (A) cake made with non-substituted oil and (B) cake made with 50% of the oil substituted with a substance made with an embodiment using exemplary composition 6.
[0021] Figure 7: Photographs of (A) cake made with non-substituted butter and (B) cake made with 60% of the butter substituted with a substance made with an embodiment using exemplary composition 6.
[0022] Figure 8: Photographs of (A) cookies made with non-substituted oil and (B) cookies made with 60% of the oil substituted with a substance made with an embodiment using exemplary composition 6.
[0023] Figure 9: Photographs of (A) cookies made with non-substituted butter and (B) cookies made with 40% of the butter substituted with a made with an embodiment using exemplary composition 6.
[0024] Figure 10: Photographs of (A) bechamel sauce made with non- substituted butter and (B) bechamel sauce made with 60% of the butter substituted with a substance made with an embodiment using exemplary composition 6. (C) Rheological results for the flow of bechamel sauce made with non-substituted butter compared to bechamel sauce made with 60% of the butter substituted with a substance made with an embodiment using exemplary composition 6.
[0025] Figure 11: Photographs of whole croissants, top row, and cross sections, bottom row, for (A) croissant made with non-substituted butter; (B) croissant baked for 35 minutes with 30% of the butter substituted with a substance made with an embodiment using exemplary composition 6; and (C) croissant baked for 40 minutes with 30% of the butter substituted with a substance made with an embodiment using exemplary composition 6.
DETAILED DESCRIPTION
[0026] Throughout this document, unless otherwise indicated to the contrary, the terms “comprising”, “consisting of’, “having” and the like, are to be construed as non- exhaustive, or in other words, as meaning “including, but not limited to”.
[0027] Furthermore, throughout the document, unless the context requires otherwise, the word “include” or variations such as “includes” or “including” will be understood to imply the inclusion of a stated integer or group of integers but not the exclusion of any other integer or group of integers.
[0028] In various embodiments a composition for forming a fat replacement emulsion for food products comprising: about 5 to 60 weight percent insoluble fibre; at least two hydrocolloid forming polysaccharides each having independently about 0.2 to 10 weight percent; and about 20 to 85 weight percent emulsifying agent, the weight percentages being based on the total composition.
[0029] Food products made by replacing or partially replacing the fats and oils used with the fat replacement substance formed from the composition, allow foods to have a good mouthfeel as the texture is maintained overtime. Such fat replacement compositions result in products that experience little or no loss of moistness and juiciness.
[0030] In various embodiments food products comprise anything that can be eaten or consumed by an animal including a human. In various embodiments food products comprise consumables that contain or are meant to contain lipids such as fats or oils. In various embodiments food products comprise baked goods such as, bread, biscuits, cookies, brownies, muffins, pastries, pies or cakes; beverages such as nut milks or other emulsions where an oil is added as an ingredient; sauces and condiments such as mayonnaise, bechamel sauce and tartar sauce; plant-based meat products such as plant-based minced meat substitutes, burger patties, sausages or
other formed products; dairy or meat based products.
[0031] In various embodiments, the weight percent of the insoluble fibre is in the range of about 5 to 60. In various embodiments, the weight percent of the insoluble fibre is in the range of about 5 to 50. In various embodiments, the weight percent of the insoluble fibre is in the range of about 5 to 40. In various embodiments, the weight percent of the insoluble fibre is in the range of about 5 to 30. In various embodiments, the weight percent of the insoluble fibre is in the range of about 5 to 20. In various embodiments, the weight percent of the insoluble fibre is in the range of about 5 to 10. In various embodiments, the weight percent of the insoluble fibre is in the range of about 25 to 60. In various embodiments, the weight percent of the insoluble fibre is in the range of about 25 to 55. In various embodiments, the weight percent of the insoluble fibre is in the range of about 25 to 50. In various embodiments, the weight percent of the insoluble fibre is in the range of about 25 to 40. In various embodiments, the weight percent of the insoluble fibre is in the range of about 30 to 40. In various embodiments, the weight percent of the insoluble fibre is in the range of about 30 to 35.
[0032] In various embodiments, the insoluble fibre is selected from cellulose fibres; and microcrystalline cellulose.
[0033] In various embodiments, the cellulose fibre may be purified cellulose fibre from various plant origins such as bamboo, wheat, oat, pea, sugar cane, or wood pulp.
[0034] In various embodiments, the microcrystalline cellulose is a partially hydrolyzed cellulose with degree of polymerization of 500 or fewer units.
[0035] There are various methods for producing microcrystalline cellulose such as treating a source of cellulose, preferably alpha cellulose in the form of pulp from fibrous plant materials, with a mineral acid to attack the less ordered regions of the cellulose polymer chain thereby liberating the crystalline sites which form crystallite aggregates which constitute the microcrystalline cellulose. These are then purified in various different ways. Any microcrystalline cellulose known in the art would be suitable.
[0036] As microcrystalline cellulose is better at holding water than other insoluble fibres when it is used in combination with an emulsifying agent these components
allow both the water and fat or lipid components of the food stay within an emulsion and are not lost due to evaporation or syneresis. This permits food having reduced fat to remain moist and juicy and have taste and/or texture similar to the food with full fat content.
[0037] In various embodiments, the insoluble fibre is MCC (microcrystalline cellulose) co-processed with a hydrocolloid or gum to assist with absorbing water faster. In various embodiments the co-processed MCC comprises a microcrystalline cellulose in combination with a hydrocolloid, such as carboxymethylcellulose sodium or xanthan gum. In various embodiments the co-processed MCC comprises a microcrystalline cellulose in combination with carboxymethylcellulose sodium. In various embodiments the co-processed MCC is in a powered form called “MCC Gel” as it has the ability to absorb water faster than microcrystalline cellulose on its own. Thus co-processing MCC with a hydrocolloid or gum makes it much easier to wet in water and form a gel like substance without the requirement of high shear conditions. In various embodiments, the microcrystalline cellulose gel or MCC gel is a coprocessed ingredient made up of roughly 88% microcrystalline cellulose with 12% carboxymethylcellulose sodium.
[0038] In various embodiments, the weight percent of the at least two hydrocolloid forming polysaccharides are each independently in the range of about 0.5 to 10. In various embodiments, the weight percent of the at least two hydrocolloid forming polysaccharides are each independently in the range of about 1 to 10. In various embodiments, the weight percent of the at least two hydrocolloid forming polysaccharides are each independently in the range of about 1 to 8. In various embodiments, the weight percent of the at least two hydrocolloid forming polysaccharides are each independently in the range of about is 1 to 6. In various embodiments, the weight percent of the at least two hydrocolloid forming polysaccharides are each independently in the range of about is 2 to 6. In various embodiments, the weight percent of the at least two hydrocolloid forming polysaccharides are each independently in the range of about is 1 to 4. In various embodiments, the weight percent of the at least two hydrocolloid forming polysaccharides are each independently in the range of about is 2 to 4. In various embodiments, the weight percent of the at least two hydrocolloid forming polysaccharides are each independently the same weight percent. In various embodiments, the weight percent of the at least two hydrocolloid forming polysaccharides are different from each other.
[0039] In various embodiments, the at least two hydrocolloid forming polysaccharides are a combination of two gums or hydrocolloids, where these may be natural, hydrolyzed or chemically derivatized celluloses. In various embodiments, the at least two hydrocolloid forming polysaccharides are a combination of three gums or hydrocolloids, where these may be natural, hydrolyzed or chemically derivatized celluloses.
[0040] In various embodiments, the hydrocolloid forming polysaccharide may comprise derivatized celluloses. In various embodiments, the derivatized celluloses comprise carboxymethylcellulose and its sodium salt, hydroxypropylcellulose, hydroxypropylmethylcellulose, or methylcellulose. In various embodiments the methylcellulose may be selected from any methycellulose grades comprising A4C methycellulose grade, A15C methycellulose grade, A4M methycellulose grade, A100M methycellulose grade, MX methycellulose grade or any other suitable methycellulose grade derivatized cellulose. In various embodiments, the methycellulose comprises A4C grade.
[0041] In various embodiments, the hydrocolloid forming polysaccharide may comprise other components such as protein. In various embodiments the hydrocolloid forming polysaccharide may be gums that comprise polysaccharides and protein. In various embodiments the gums may be natural gums such as Gum Arabic, guar gum; locust bean gum; beta glucan; Dammar gum; Glucomannan; Psyllium seed gum; Konjac gum; gellan gum; Tara gum; Gum Ghatti; and xanthan gum or other natural gums known in the art. Some gums such as Gum Arabic and Gum Ghatti demonstrated slight emulsifying properties that resulted in superior fat replacement substance for emulsions for use in food products with reduced fat content that have similar taste and texture to food products made with natural fats and oils or with a higher fat content.
[0042] In various embodiments, the at least two hydrocolloid forming polysaccharides are each selected from carboxymethylcellulose sodium; methylcellulose; Gum Arabica; guar gum; locust bean gum; beta glucan; Dammar gum; Glucomannan; Psyllium seed gum; Konjac gum; gellan gum; Tara gum; Gum Ghatti; and xanthan gum.
[0043] In various embodiments, the at least two hydrocolloid forming polysaccharides are uncharged hydrocolloid forming polysaccharides. In various
embodiments, the two uncharged hydrocolloid forming polysaccharides are a combination of two gums or hydrocolloids, where these may be natural, hydrolyzed or chemically derivatized celluloses. In various embodiments, the two uncharged hydrocolloid forming polysaccharides are each selected from guar gum; locust bean gum; beta glucan; Dammar gum; Glucomannan; Psyllium seed gum; Tara gum; and xanthan gum. In various embodiments, the derivatized celluloses comprise hydroxypropylcellulose, hydroxypropylmethylcellulose, or methylcellulose.
In various embodiments, the two uncharged hydrocolloid forming polysaccharides are guar gum and xanthan gum. Guar gum is a galactomannan polysaccharide. Xanthan gum is a pentasaccharide. Any known guar gum and xanthan gum may be used.
[0044] In various embodiments, the at least two hydrocolloid forming polysaccharides are selected from carboxymethylcellulose sodium; methylcellulose; Gum Arabica; guar gum; and xanthan gum. In various embodiments, the at least two hydrocolloid forming polysaccharides are a combination of carboxymethylcellulose sodium; methylcellulose; and Gum Arabica. In various embodiments, the at least two hydrocolloid forming polysaccharides are a combination of guargum and xanthan gum.
[0045] A combination of guar gum and xanthan gum has the advantage of acting synergistically to enhance viscosity and stabilize any emulsion formed from the composition.
[0046] In various embodiments, the weight percent of the emulsifying agent is in the range of about 20 to 80. In various embodiments, the weight percent of the emulsifying agent is in the range of about 30 to 85. In various embodiments, the weight percent of the emulsifying agent is in the range of about 40 to 85. In various embodiments, the weight percent of the emulsifying agent is in the range of about 50 to 85. In various embodiments, the weight percent of the emulsifying agent is in the range of about 60 to 85. In various embodiments, the weight percent of the emulsifying agent is in the range of about 70 to 85. In various embodiments, the weight percent of the emulsifying agent is in the range of about 80 to 85. In various embodiments, the weight percent of the emulsifying agent is in the range of about 20 to 60. In various embodiments, the weight percent of the emulsifying agent is in the range of about 20 to 65. In various embodiments, the weight percent of the emulsifying agent is in the range of about 30 to 60. In various embodiments, the weight percent of the emulsifying agent is in the range of about 40 to 60. In various embodiments, the weight percent of the emulsifying agent is in the range of about 50
to 60. In various embodiments, the weight percent of the emulsifying agent is in the range of about 55 to 60. In various embodiments, the weight percent of the emulsifying agent is in the range of about 50 to 55. In various embodiments, the weight percent of the emulsifying agent is in the range of about 55 to 60. In various embodiments, the weight percent of the emulsifying agent is in the range of about 59 to 60.
[0047] In various embodiments, the emulsifying agent comprises one emulsifier.
In various embodiments, the emulsifying agent comprises two emulsifiers.
[0048] In various embodiments, the emulsifying agent is selected from a sugar ester; a starch esterified with octenylsuccinic compound; a low Hydrophilic-Lipophilic Balance (HLB) emulsifier and acetylated starch. In various embodiments, the emulsifying agent comprises sodium starch octenylsuccinate which may be added in a dry form or a pregelatinized form. In various embodiments, the emulsifying agent comprises a low Hydrophilic-Lipophilic Balance (HLB) emulsifier. In various embodiments, the low Hydrophilic-Lipophilic Balance (HLB) emulsifier comprises at least one of polygycerol polyricinoleate, sucrose esters, mono-diglycerides or lecithins. In various embodiments, the emulsifying agent is a combination of a HLB emulsifier and sodium starch octenylsuccinate. The addition of a component with emulsifying or emulsion-stabilising properties, such as, sodium starch octenylsuccinate, ensures both the water and fat or lipid components of the food stay within an emulsion and are not lost due to evaporation or syneresis. This permits food having reduced fat to remain moist and juicy and have taste and/or texture similar to the food produced with full fat content.
[0049] In various embodiments, the emulsifying agent is an esterified or an acetylated saccharide. In various embodiments, the esterified or the acetylated saccharide includes an esterified or an acetylated monosaccharide. In various other embodiments, the esterified or the acetylated saccharide includes an esterified or an acetylated polysaccharide. Advantageously, esterification or acetylation of saccharides increases the stability of the emulsifying agents emulsifying effect. The emulsifying agent makes the composition capable of interacting stably with fat components of food products due to the lipophilic regions of the emulsifying agent at the molecular level. These features help or facilitate stability of the composition to maintain a stable emulsion which in turn helps to retain moisture in the fat replacement substance and in food products when the composition is used to form a
fat replacement substance used in food products.
[0050] In various embodiments, the sugar ester comprises a sucrose ester or a glucose ester.
[0051] In various embodiments, the starch esterified with octenylsuccinic compound is esterified with octenylsuccinic anhydride. In various embodiments, the starch esterified with octenylsuccinic compound comprises sodium starch octenylsuccinate or aluminium starch octenylsuccinate. In various embodiments, the starch esterified with octenylsuccinic compound is esterified or derivatized with octenylsuccinic acid. The resulting modified starch is one that has both hydrophilic regions as well as lipophilic regions owing to the octenyl chains. In various embodiments, the emulsifying agent comprises sodium starch octenylsuccinate. In various embodiments, the sodium starch octenylsuccinate comprises food grade sodium starch octenylsuccinate E1450.
[0052] In various embodiments, the insoluble fibre is microcrystalline cellulose; the two hydrocolloid forming polysaccharides are guar gum and xanthan gum; and the emulsifying agent is sodium starch octenylsuccinate.
[0053] In various embodiments, the weight ratio of microcrystalline cellulose : xanthan gum : guar gum : sodium starch octenylsuccinate is 15.5 : 2 : 1 : 31 .5. In various embodiments, the weight ratio of microcrystalline cellulose : xanthan gum : guar gum : sodium starch octenylsuccinate is 31 :4:2:64.
[0054] In various embodiments, the insoluble fibre is microcrystalline cellulose; the at least two hydrocolloid forming polysaccharides are carboxymethylcellulose sodium, methylcellulose and Gum arabic; and the emulsifying agent is a combination of sodium starch octenylsuccinate and a low HLB emulsifier such as polyglycerol polyricinoleate.
[0055] In various embodiments, the weight ratio of microcrystalline cellulose : carboxymethylcellulose sodium : methylcellulose : Gum arabic : sodium starch octenylsuccinate : polyglycerol polyricinoleate is 42:6:12:24:383:33.
[0056] In various embodiments a fat replacement substance for food products comprises: the composition of any one of the composition embodiments described herein above, and an aqueous liquid combined under shear force.
[0057] Advantageously, the resultant emulsion is also more stable and does not separate as easily as the prior art when in use in food products.
[0058] In various embodiments, the aqueous liquid comprises water, juice, brine, soup or any other aqueous liquids suitable for cooking, baking or food products. In various embodiments, the aqueous liquid comprises a water based liquid comprising 50% or more water of the total volume of the liquid; 55% or more water of the total volume of the liquid; 60% or more water of the total volume of the liquid; 65% or more water of the total volume of the liquid; 70% or more water of the total volume of the liquid; 75% or more water of the total volume of the liquid; 80% or more water of the total volume of the liquid; 85% or more water of the total volume of the liquid; 90% or more water of the total volume of the liquid; 95% or more water of the total volume of the liquid; or 100% water of the total volume of the liquid. In various embodiments, the aqueous liquid may comprise a lipid component at a concentration less than the water component.
[0059] In various embodiments, the weight ratio of the composition to aqueous liquid is in the range of 1 : 19 to 1 : 4. In various embodiments, the composition is intended to be dosed with aqueous liquid in a weight ratio of 5-20% composition.
[0060] In various embodiments, the weight ratio of the composition to aqueous liquid is 1 :6 to 1 :7, 1 : 6.7 or 1 :7. In various embodiments, the composition is intended to be dosed with aqueous liquid in a weight ratio of 12-13% composition.
[0061] In various embodiments, the fat replacement substance for food products may further comprise a lipid such as an oil or a fat. In various embodiments, the lipid is at a concentration less than the aqueous liquid.
[0062] In various embodiments the fat replacement substance may be used to replace the following:
• Animal source: butter, lard, tallow, ghee, clarified butter; or
• Plant source: vegetable oils (for example canola, soy, rice bran, sunflower, peanut, palm), hydrogenated vegetable oils, (for example: cocoa butter, palm kernel oil).
[0063] In various embodiments a food product comprising the composition of any one of the composition embodiments described herein above, or the fat replacement
substance of any one of the fat replacement substance embodiments described herein above.
[0064] In various embodiments food products comprise anything that can be eaten or consumed by an animal including a human. In various embodiments food products comprise consumables that contain or are meant to contain lipids such as fats or oils.
[0065] In various embodiments, the food product comprises baked goods. In various embodiments the baked goods comprise bakery products, selected from the group comprising or consisting of breads, cakes, cookies, brownies, muffins pastries and pies.
[0066] In various embodiments, the food product comprises plant-based meat substitutes. In various embodiments the plant-based meat substitutes are selected from the group comprising or consisting of plant-based minced meat substitutes, burger patties, sausages or other formed products. In various embodiments the plant- based meat substitutes may comprise fungal base meat substitutes.
[0067] In various embodiments, the food product comprises a meat composite.
[0068] In various embodiments, the food product comprises a sauce. In various embodiments, the food product comprises any sauce used with food including but not limited to mayonnaise, hollandaise sauce bechamel sauce or tartar sauce. In various embodiments the sauce comprises a condiment selected from the group comprising or consisting of mayonnaise, hollandaise sauce and tartar sauce.
[0069] In various embodiments, the food product comprises a drink. In various embodiments the drink is selected from the group comprising or consisting of nut milks and other emulsions where an oil is added as an ingredient
[0070] In various embodiments, a method of manufacturing a fat replacement substance for food products comprising: (a) adding the composition of any one of the composition embodiments described herein above to an aqueous liquid; and (b) applying shear force until the fat replacement substance forms.
[0071] In various embodiments, the aqueous liquid comprises water, juice, brine, soup or any other aqueous liquids suitable for cooking, baking or food products. In various embodiments, the aqueous liquid comprises a water based liquid comprising
50% or more water of the total volume of the liquid; 55% or more water of the total volume of the liquid; 60% or more water of the total volume of the liquid; 65% or more water of the total volume of the liquid; 70% or more water of the total volume of the liquid; 75% or more water of the total volume of the liquid; 80% or more water of the total volume of the liquid; 85% or more water of the total volume of the liquid; 90% or more water of the total volume of the liquid; 95% or more water of the total volume of the liquid; or 100% water of the total volume of the liquid. In various embodiments, the aqueous liquid may comprise a lipid component at a concentration less than the water component.
[0072] In various embodiments applying shear force may be affected by means of a high shear cutter, granulator, planetary mixer, food processor, mortar and pestle or any equipment capable of generating strong shearing forces.
[0073] In various embodiments, the composition is added to the aqueous liquid at a weight ratio in the range of 1 : 19 to 1 : 4. In various embodiments, the composition is intended to be dosed with aqueous liquid in a weight ratio of 5-20% composition.
[0074] In various embodiments, the composition is added to the aqueous liquid at a weight ratio of 1 : 6, 1 : 6.7, 1 :7 or 1 :6 to 1 :7. In various embodiments, the composition is intended to be dosed with aqueous liquid in a weight ratio of 12 -13% composition.
[0075] In various embodiments, the method further comprises adding a lipid to the fat replacement substance such as an oil or a fat to the fat replacement substance either before or during applying shear force to form a fat replacement emulsion.
[0076] This will allow the fat reducing emulsion to be used as the total substitute for the lipid used in the original recipe. For example, where 100 grams of vegetable oil is called for and a 50% reduction of the oil is required, water and oil can be added in equal parts to the composition either before or during applying shear force. The required amount of 100 grams of the resulting fat reducing emulsion can then be used as a complete replacement of the vegetable oil used in the original recipe.
[0077] Advantageously, the composition is able to emulsify with the remaining fat/oil to form a stable, flowable emulsion that can evoke the mouthfeel of an oily substance or the creaminess of a fat.
[0078] Alternatively, in various embodiments, the fat reducing emulsion may be made with the aqueous liquid. Then where 100 grams of vegetable oil is called for and a 50% reduction of the oil is required, 50 grams of the fat reducing emulsion and 50 grams of the vegetable oil may be used in making the food product added in the same way the vegetable oil is instructed to be added.
[0079] It should be further appreciated by the person skilled in the art that variations and combinations of features described above, not being alternatives or substitutes, may be combined to form yet further embodiments falling within the intended scope of the invention. [0080] As would be understood by a person skilled in the art, each embodiment, may be used in combination with other embodiment or several embodiments.
Examples
[0081] Example 1 : baked goods [0082] Composition 1
[0083] Composition 1 was used in bakery products, when a banana bread
(dense banana cake) recipe was successfully altered to reduce oil added by 30%, using 10g composition 1 and a mix of 30g vegetable oil and 20g erythritol, a low- calorie sweetener was subjected to high shear and used as a replacement for vegetable oil. This was done concurrently with sugar reduction to create a banana bread that was lower in calories, fat and sugar than the original.
[0085] 20g of Composition 2 and a mix of 70g butter and subjected to high shear was used to substitute 30% of fat (butter and shortening) to good effect in chocolate chip cookies. The products were presented at a food conference and tasters were
impressed that they could not tell that these had been reduced in fat and/or sugar.
[0086] While this was somewhat successful at retaining moisture and mouth feel it required too much inulin. Alternatives that retain moisture and mouth feel are needed. [0087] Example 2: Plant-based meat products
[0088] As plant-based burgers are known to be high in fat, comparable to conventional meat burgers, it made sense to explore ways of reducing the fat content. For this project, the goal was to cut fat by more than 50% while still retaining the moistness and juiciness of a burger patty. Variations of the composition were used to explore ways to retain moistness without affecting taste.
[0089] The currently used fat replacement solutions were compared to fat replacement substances that were formed with compositions that included an emulsifying ingredient. It was hypothesised that an emulsifying ingredient, would be instrumental in retaining water and maintaining a good texture and mouthfeel. An emulsifying ingredient that can be co-processed with fat or at least emulsifiable with fat was chosen and compared.
[0092] Composition 3 was sheared in a weight ratio of 4.6% composition 3 with 95.4% water and subjected to high shear to create a gel-like substance that works as the fat replacement substance.
[0093] Composition 4 was sheared in a weight ratio of 12.75% composition 4 with 87.25% water and subjected to high shear to create a gel-like substance that works as the fat replacement substance.
[0094] Composition 3 and 4 were each employed in plant-based burger patty, replacing 60% and 69% of the original oils used in the original formulation. These patties were assessed to be generally moist and juicy, with the 69% replacement version made with composition 3 coming across as less moist than the original. It was also observed to dry up faster on cooling (See table 1). In comparison where composition 4 was used in 69% fat reduction in plant-based burger patties it was able to produce a well-received prototype that stayed moist on cooling.
Figure 2 depicts two types of vegetarian patties. The one on the left (Figure 2 (a)) is a full fat version. The one on the right (Figure 2 (b)) is made with Composition 4 with 69% fat reduction. No observable visual differences were noted.
[0098] Composition 4 and 5 were employed in mayonnaise. Each composition was dosed with water in a weight-based ratio of 15.3% composition 4 or 5 and 84.7% water. Each mixture was subjected to high shear to create a gel-like substance that works as the fat replacement substance. 50% of the original oil content of the mayonnaise was replaced with fat replacement substances formed with composition 4 or 5. Both the resulting mayonnaises were assessed favorably by testers. The mayonnaise formed with fat replacement substance formed with composition 4 remained stable on storage at 4°C for more than 1 month. The mayonnaise formed with fat replacement substance formed with composition 5 exhibited some syneresis, where water separated from the mayonnaise and collected on top. Without being bound to any theory it is hypothesised that microcrystalline cellulose (MCC)’s better ability to hold water prevented water loss through evaporation or syneresis. Composition 4 also produced a mayonnaise with higher viscosity and closer texture to that of a typical fatted mayonnaise. This can be seen in Figure 3A. [0099] Example 4
[00101] Roughly 88% of microcrystalline cellulose was co-processed with 12% carboxymethylcellulose sodium and formed into a powder called microcrystalline cellulose gel or MCC gel. The powdered co-processed microcrystalline cellulose carboxymethylcellulose sodium MCC gel the emulsifier 1 , sodium starch octenylsuccinate, and the other components were first dry blended as they are all powders, with the exception of polyglycerol polyricinoleate. The latter is added to the dry mix and triturated under shear using a pestle and a mortar to achieve a slightly
clumpy powder.
[00102] The composition 6 was dosed with water in a weight-based ratio of 10.5% composition 6 and 89.5% water. Each mixture was subjected to high shear to create a gel-like substance that works as the fat replacement substance. This ratio was maintained whether the substitution of fat/oil was carried out at 50, 60 or 70% substitution. The exact ratios are as follows:
[00103] As a general rule an amount of composition 6 was used that corresponds to one-tenth the amount of substitution required. Therefore, should 60 % reduction of fat be desired, the amount of composition 6 can be regarded as 6g per
10Og of original fat or oil. Amount of water would be 60g-6g = 54g per 10Og of original fat or oil.
[00104] The procedure for liquid oils substitutions:
1. Disperse Composition 6 in the oil;
2. Transfer the mixture into a food processor;
3. Add water gradually while operating the food processor or blender; and
4. A homogenous emulsion with a smooth glossy surface should form.
[00105] See Figure 4A for an example of a 60% substituted vegetable oil - water emulsion (W/O emulsion).
[00106] The procedure for solid lipid substitutions:
1. Microwave the solid lipid (fat or oil) until liquid;
2. Dissolve Composition 6 in the liquefied oil/fat
3. Transfer the mixture to a food processor;
4. Add water gradually while operating the food processor; and
5. A homogenous whipped butter-like solid should form
[00107] See Figure 4B for an example of a 60% substituted butter - water emulsion (W/O emulsion).
[00108] Composition 6 has the advantage of being able to create W/O emulsions even in the presence of more water than oil. This is hypothesised to be due to the use of at least two emulsifiers to extend the functionalities of oil even with substantial substitution. Composition 6 was used to make Mayonnaise, cakes, cookies, bechamel sauce and flaky pastries.
[00109] Mayonnaise
[00110] Mayonnaise was made with composition 6 by substituting 18% of vegetable oil with a substance formed with composition 6 or with non-substituted oil. The mayonnaise recipe required 70% oil. Both mayonnaises were oil-in-water emulsions as is typical of mayonnaise. The normal mayonnaise made with non- substituted sunflower oil is depicted in Figures 5A and 5B and the mayonnaise made with 18% of the vegetable oil substituted with a substance formed with composition 6 is depicted in Figure 5C and 5D. The mayonnaise formed with 18% of the vegetable oil substituted with a substance formed from composition 6 could not be discerned from the mayonnaise made with non-substituted oil by 3 testers amongst a panel of 8 (37.5%) based on taste and textural differences. Similarly, 4 tasters amongst a panel of 8 (50%) preferred the lower fat mayonnaise (see Table 2).
[00112] Cakes
[00113] Cakes made with 50% of oil in a cake recipe substituted with a substance formed with composition 6. The resulting cake had a texture is close to the
cake made with non-substituted oil. The cake made with 50% of oil in a cake recipe substituted with a substance formed with composition 6 required a longer baking duration. The normal cake made with non-substituted oil is depicted in Figures 6A and the cake made with 50% of the oil substituted with a substance formed with composition 6 is depicted in Figure 6B. Firmness of the cakes were similar as assessed by a TA.XT plus texture analyzer (see Table 3).
[00115] A panel of 5 testers regarded cake made with 50% of oil in a cake recipe substituted with a substance formed with composition 6 favourably, with most agreeing that it could easily pass off as a typical full-fat cake (see Table 4).
[00117] A butter cake recipe was also attempted. Cakes made with 60% of butter in a butter cake recipe substituted with a substance formed with composition 6. There was no change in baking conditions this time round. However, the lower fat cake had a reduced degree of rise, despite its firmness remaining comparable to the original cake (see table 5). The normal cake made with non-substituted butter is depicted in Figures 7 A and the cake made with 60% of the butter substituted with a substance formed with composition 6 is depicted in Figure 7B. [00118] Table 5: Physical parameters of the cake including rise height and
Firmness of the cakes were assessed by a TA.XT
[00119] A panel of 5 testers regarded the butter cake indistinguishable from the control in terms of texture and taste, regardless of the difference in appearance between the cakes (see table 6). [00120] Table 6: Comparison of cakes (n=5)
[00121] Cookies
[00122] A model cookie recipe using oil was used to investigate the effects of fat substitution in cookies/biscuits that use oil as the main fat component. Here, cookies made with 60% of oil in a cookie recipe substituted with a substance formed with composition 6 was achieved with a slightly extended baking time. Cookies made with 50% of oil in a cookie recipe substituted with a substance formed with composition 6 required the same baking time as cookies made with unsubstituted oil. The normal cookies made with non-substituted oil is depicted in Figures 8A and the cookies made with 60% of the oil substituted with a substance formed with composition 6 is depicted in Figure 8B.The lower fat cookies were found to be slightly harder than the original recipe as analysed by a TA.XT texture analyser (see Table 7).
[00124] Nevertheless, a panel of 5 testers, found the lower fat cookies to also judged favourably against the control (see Table 8).
[00126] Similar substitution was achieved for butter cookies, where cookies made with up to 40% of butter in a butter cookie recipe substituted with a substance formed with composition 6. Successful fat reduction of up to 40% was achieved for the butter cookies. The normal cookies made with non-substituted butter is depicted in Figures 9A and the cookies made with 40% of the butter substituted with a substance formed with composition 6 is depicted in Figure 9B. This reduced fat butter cookies also required a slightly extended baking time. They also had slightly increased hardness (see Table 9).
[00128] The texture of the cookies was found to be comparable to the control (non-substituted butter cookie), albeit with some detractions with regard to taste (see
Table 10).
[00130] Sauce
[00131] Bechamel sauce is a butter-based sauce commonly used in several dishes. Successful butter substitution of 60% was achieved without large deviations from the original texture. Bechamel sauce was made with 60% of butter in a bechamel sauce recipe substituted with a substance formed with composition 6. The normal bechamel sauce made with non-substituted butter is depicted in Figures 10A and the bechamel sauce made with 60% of the butter substituted with a substance formed with composition 6 is depicted in Figure 10B. Referring to figure 10C, Theologically, the original sauce with no substitution and the lower fat sauce made with 60% of the butter substituted with a substance formed with composition 6 performed similarly. This demonstrates the effectiveness of a substance formed with composition 6 in replicating the flow properties of fat. Consequently, on a panel of 10 testers, almost all preferred the lower fat bechamel sauce citing superior taste and texture (see Table 11). [00132] Table 11 : Comparison of bechamel sauce (n=10).
[00133] Croissants and other flaky pastries
[00134] One of the most difficult applications to replicate for butter is its use in folded, flaky pastries, including but not limited to croissants, danishes, filo, and puff pastry. Here, croissants were made with 30% of butter in a croissant recipe substituted with a substance formed with composition 6. The normal croissant made with non-substituted butter is depicted in Figures 11 A. Croissants made with 30% of the butter substituted with a substance formed with composition 6 is depicted in Figure 11 B, which was baked for the same time, and Figure 11 C, which was baked for an additional 5 minutes. Although the texture deviated from the control croissant,
the lower fat versions were still similar in appearance and in taste (see Table 12). [00135] Table 12: physical features and comparison of butter croissants
[00136] In the foregoing manner, various embodiments of the disclosure are described for addressing at least one of the foregoing disadvantages. Such embodiments are intended to be encompassed by the following claims, and are not to be limited to specific forms or arrangements of parts so described and it will be apparent to one skilled in the art in view of this disclosure that numerous changes and/or modification can be made, which are also intended to be encompassed by the following claims.
Claims
1 . A composition for forming a fat replacement emulsion for food products comprising: 5 to 60 weight percent insoluble fibre; at least two hydrocolloid forming polysaccharides each having 0.2 to 10 weight percent; and 20 to 85 weight percent emulsifying agent, the weight percentages being based on the total composition.
2. The composition according to claim 1 , wherein the insoluble fibre is selected from cellulose fibres; and microcrystalline cellulose.
3. The composition according to claim 1 or 2, wherein the at least two hydrocolloid forming polysaccharides are selected from carboxymethylcellulose sodium; methylcellulose; Gum Arabica; guar gum; locust bean gum; beta glucan;
Dammar gum; Glucomannan; Psyllium seed gum; Konjac gum; gellan gum; Tara gum; Gum Ghatti; and xanthan gum.
4. The composition according to any one of claims 1-3, wherein the at least two hydrocolloid forming polysaccharides comprise a combination of carboxymethylcellulose sodium; methylcellulose; and Gum Arabica
5. The composition according to any one of claims 1-3, wherein the at least two hydrocolloid forming polysaccharides are each uncharged hydrocolloid forming polysaccharides.
6. The composition according to claim 5, wherein the uncharged hydrocolloid forming polysaccharides are each selected from guar gum; locust bean gum; beta glucan; Dammar gum; Glucomannan; Psyllium seed gum; Tara gum; and xanthan gum.
7. The composition according to any one of claims 5, wherein the uncharged hydrocolloid forming polysaccharides are guar gum and xanthan gum.
8. The composition according to any one of claims 1 to 8, wherein the emulsifying agent is selected from a sugar ester; a starch esterified with octenylsuccinic compound; a low Hydrophilic-Lipophilic Balance (HLB) emulsifier and acetylated starch.
9. The composition according to claim 8, wherein the sugar ester comprises a sucrose ester or a glucose ester.
10. The composition according to claim 8, wherein the starch esterified with octenylsuccinic compound comprises sodium starch octenylsuccinate or aluminium starch octenylsuccinate.
11. The composition according to claim 8, wherein the low Hydrophilic-Lipophilic Balance (HLB) emulsifier is selected from Polyglycerol polyricinoleate, sucrose esters, mono-diglycerides and lecithins.
12. The composition according to claim 8, wherein the low Hydrophilic-Lipophilic Balance (HLB) emulsifier comprises Polyglycerol polyricinoleate.
13. The composition according to claim 1 , wherein the insoluble fibre is microcrystalline cellulose; the at least two hydrocolloid forming polysaccharides are guar gum and xanthan gum; and the emulsifying agent is sodium starch octenylsuccinate.
14. The composition according to claim 13, wherein the weight ratio of microcrystalline cellulose : xanthan gum : guar gum : sodium starch octenylsuccinate is 31 : 4 : 2 : 63.
15. The composition according to claim 1 , wherein: the insoluble fibre is microcrystalline cellulose; the at least two hydrocolloid forming polysaccharides are carboxymethylcellulose sodium, methylcellulose and gum Arabic ; and the emulsifying agent is sodium starch octenylsuccinate and polyglycerol polyricinoleate.
16. The composition according to claim 15, wherein the weight ratio of microcrystalline cellulose : carboxymethylcellulose sodium : methylcellulose : gum Arabic : sodium starch octenylsuccinate : polyglycerol polyricinoleate is 42 : 6 : 12 : 24 : 383 : 33.
17. A fat replacement substance for food products comprising: the composition according to any one of claims 1 to 16, and an aqueous liquid combined under shear force.
18. The fat replacement substance according to claim 17, wherein the weight ratio of the composition to aqueous liquid is in the range of 1 : 19 to 1 : 4.
19. The fat replacement substance according to claim 17, wherein the weight ratio of the composition to aqueous liquid is 1 : 6 to 1 : 7.
20. The fat replacement substance according to any one of claims 17 to 19, further comprising a lipid.
21 . A food product comprising the composition according to any one of claims 1 to 16, or the fat replacement substance according to any one of claims 17 to 20.
22. The food product according to claim 21 , comprising baked goods.
23. The food product according to claim 21 , comprising plant based meat substitutes.
24. The food product according to claim 21 , comprising a meat composite.
25. The food product according to claim 21 , comprising a sauce.
26. The food product according to claim 21 , comprising a drink.
27. A method of manufacturing a fat replacement substance for food products comprising: a. adding the composition of any one of claims 1 to 16 to an aqueous liquid; and b. applying shear force until the fat replacement emulsion forms.
28. The method according to claim 27, wherein the composition is added to the aqueous liquid at a ratio in the range of 1 : 19 to 1 : 4.
29. The method according to claim 27, wherein the composition is added to the aqueous liquid at a ratio of 1 : 6 to 1 : 7.
30. The method according to any one of claims 27 to 29, further comprising adding a lipid to the fat replacement substance either before or during applying shear force.
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Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1575816A (en) * | 1976-03-03 | 1980-10-01 | Kay Cantrell Kitchens Ltd | Oleaginois firbrus simulated food product |
EP0558832A2 (en) * | 1991-11-27 | 1993-09-08 | Unilever N.V. | Dressings with reduced fat content |
US5338562A (en) * | 1992-11-25 | 1994-08-16 | Fmc Corporation | Low fat spread and process for making same |
EP1391154A1 (en) * | 2001-05-30 | 2004-02-25 | Asahi Kasei Kabushiki Kaisha | Composite containing fine cellulose |
-
2020
- 2020-03-09 SG SG10202002148W patent/SG10202002148WA/en unknown
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2021
- 2021-03-04 WO PCT/SG2021/050110 patent/WO2021183047A1/en active Application Filing
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1575816A (en) * | 1976-03-03 | 1980-10-01 | Kay Cantrell Kitchens Ltd | Oleaginois firbrus simulated food product |
EP0558832A2 (en) * | 1991-11-27 | 1993-09-08 | Unilever N.V. | Dressings with reduced fat content |
US5338562A (en) * | 1992-11-25 | 1994-08-16 | Fmc Corporation | Low fat spread and process for making same |
EP1391154A1 (en) * | 2001-05-30 | 2004-02-25 | Asahi Kasei Kabushiki Kaisha | Composite containing fine cellulose |
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