WO2021145837A1 - Dyestuff mixtures including clay - Google Patents

Dyestuff mixtures including clay Download PDF

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Publication number
WO2021145837A1
WO2021145837A1 PCT/TR2020/051131 TR2020051131W WO2021145837A1 WO 2021145837 A1 WO2021145837 A1 WO 2021145837A1 TR 2020051131 W TR2020051131 W TR 2020051131W WO 2021145837 A1 WO2021145837 A1 WO 2021145837A1
Authority
WO
WIPO (PCT)
Prior art keywords
dyestuff
weight
clay
mixture
proportion
Prior art date
Application number
PCT/TR2020/051131
Other languages
French (fr)
Inventor
Ali CIFTCI
Tuncay TOYDEMIR
Original Assignee
Orta Anadolu Ticaret Ve Sanayi Isletmesi Turk A.S.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Orta Anadolu Ticaret Ve Sanayi Isletmesi Turk A.S. filed Critical Orta Anadolu Ticaret Ve Sanayi Isletmesi Turk A.S.
Publication of WO2021145837A1 publication Critical patent/WO2021145837A1/en

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Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/673—Inorganic compounds
    • D06P1/67383—Inorganic compounds containing silicon
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/673—Inorganic compounds
    • D06P1/67333—Salts or hydroxides
    • D06P1/67341—Salts or hydroxides of elements different from the alkaline or alkaline-earth metals or with anions containing those elements
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds
    • C08K3/346—Clay
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/22—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using vat dyestuffs including indigo
    • D06P1/228—Indigo

Definitions

  • the present invention relates to natural or artificial dyestuff mixtures and clays having pluralities of minerals therein and which are a soil type.
  • Clay is a soft material having very tiny particles.
  • the atoms, which exist in clay material, are in the form of a cage or a chain array.
  • the basic substance of clay is aluminum silicate hydrate and there may be the compounds of other elements like sodium (it will be hereafter described as Na), potassium (it will be hereafter described as K), calcium (it will be hereafter described as Ca), magnesium (it will be hereafter described as Mg) and iron (it will be hereafter described as Fe).
  • Clays are formed by two different structure stones with X-rays diffraction studies.
  • the first structure having silicium ion at the center thereof and having oxygen ions at the corners thereof, is in the form of a regular tetrahedron as seen.
  • Tetrahedron structure is formed, in other words, silica layer is formed by means of joining by giving sextet rings with oxygen bridges through the corners thereof such that the bases of these regular tetrahedrons, which have chemical formula that can be written as SiO 4 4 , are in the same plane.
  • Dyestuff used in textile is chemicals obtained in a natural or artificial manner. Natural dyestuff can be herbal and animal sourced. Natural dyestuff has low color fastness and the cost thereof is high.
  • Textile products are product groups which are in the densest relation with human body after food substances.
  • the dye wastes and the chemicals which exist on the clothes worn by humans, penetrate into the human body by means of sweating and breathing and affect the human health in an unfavorable manner.
  • said chemical and dye wastes have allergy and cancer threaten against human health.
  • the dyestuff which shows carcinogenic effect for the human body or the chemicals and the dye wastes which remain during production of the dyestuff must be prevented from contacting the body.
  • novelty requirement occurs in this direction.
  • the present invention relates to a dyestuff mixture, for eliminating the abovementioned disadvantages and for bringing new advantages to the related technical field.
  • An object of the present invention is to provide a dyestuff mixture which stores toxic substances and which prevents penetration to the body.
  • An object of the present invention is to provide a dyestuff mixture which prevents contact of harmful chemical wastes or dyestuff to the human body.
  • An object of the present invention is to provide a dyestuff mixture which has detox effect on the body.
  • the present invention relates to a dyestuff mixture.
  • Said dyestuff mixture comprises clay with specific weight proportions and at least one synthetic or natural dyestuff with specific weight proportions.
  • the clay provided in the dyestuff mixture must have a weight proportion which provides said clay to be effective. Thanks to this, a dyestuff mixture is obtained which is useful for the human body by means of the detox effect and which prevents contact of the toxin substances, which exist on the fabric or which exist in the environment, to the human body.
  • the amount of said dyestuff has a value between 1% and 15% by weight in the dyestuff mixture.
  • the dyestuff mixture comprises clay substance with proportion between 1% and 15% by weight, dyestuff with proportion between 1% and 15% by weight, cross-binding substance with proportion between 5% and 12% by weight, acrylic polymer with proportion between 5% and 12% by weight, dispersing agent with proportion between 2% and 5% by weight and thickener with proportion between 5% and 12% by weight.
  • the subject matter relates to natural or artificial dyestuff mixtures comprising clays having pluralities of minerals therein and which are a soil type and are explained with references to examples without forming any restrictive effect only in order to make the subject more understandable.
  • the clay including substance is one of kaolin, montmorillonite, zeolite or the mixture thereof with specific weight proportions.
  • the clays can purify the body from toxic substances. Since the clay is subjected to hot water pressure for long time underground, the clay is crystallized and charged with negative electricity. Thanks to the negative charges of the clay, the clay attracts the positive charged toxic substances onto the skin surface, and afterwards, the clay absorbs these and realizes the function of removing these from the body. As mentioned in our invention, as clay is used as a component in the dyestuff mixture, the chemical wastes, which exist in the body of the fabrics which are in contact with the human body, are prevented from contacting with the skin.
  • Natural or artificial dyestuffs can be used according to the fabric color desired to be obtained as dyestuff.
  • the dyestuff used in the art has carcinogenic effect for the human body both because of their chemical structures and because of their wastes coming from their production steps. In this form, the contact of the dyestuff to the human body must be reduced.
  • the improvement is the production of dyestuff comprising clay component which will function as a coating against the carcinogenic effects, which exist in the fabric, by means of application of the obtained dyestuff mixture to the fabric.
  • the dyestuff statement can be described as substances applied in making the fabric colored. Said dyestuff is natural or artificial chemical substance according to the color and characteristics desired from the fabric.
  • the dyestuffs to be used in the present invention can be indigo dyestuffs or derivatives.
  • the dyestuff mixture to be obtained by the present invention comprises at least one clay and at least one dyestuff. Accordingly, the dyestuff mixture can also comprise the mixtures of more than one clay group with specific weight proportions.
  • the clay, provided in the dyestuff mixture, is provided at a proportion between 1% and 15% by weight.
  • the dyestuff raw substance provided in the dyestuff mixture is provided at a proportion between 1% and 15% by weight.
  • the dyestuff mixture obtained by means of the present invention, also comprises the following raw substances which provide the desired performance and colors by weight:
  • Dispersing agent which provides homogenous mixture with proportion between 2% and 5%
  • the dyestuff mixture comprises at least one solvent which completes to 100% by weight.
  • the production of dyestuff mixture obtained by means of the present invention is provided by means of forming a homogenous mixture in a solvent by clay and dyestuff. Binders, where cross-bonds are adhered, are added to the formed homogenous mixture. Dispersing agent substance is added for providing increase of homogeneity and for preventing precipitation of the components of the mixture where binder is added.
  • the dyestuff mixtures obtained by means of the present invention can be used as dyeing product in yarns, semi-produced products, woven fabrics, woven fabrics or non-woven fabrics.
  • Dyestuff mixtures can be applied to said textile products by means of coating method, exhaust method or dyeing method or impregnation method in the fiber exhaust melt.
  • Dyestuff mixtures can be applied preferably to textile products by means of coating or impregnation method.
  • the dyestuff mixture obtained by means of the recipe given in the invention is transferred by means of pump to one or more than one surface of the fabric with different viscosities.
  • the mixture is homogeneously coated onto the fabric by means of different blade systems.
  • the coated dyestuff is added at a value between 1 gram and 250 grams preferably in meter square onto the fabric. Afterwards, drying process and fixation processes are applied onto the dyestuff fabric.
  • the fabric is passed through the dyestuff liquor prepared by clay and natural dye and binders, and passes through tightening cylinders and drying is realized simultaneously. Afterwards, the fixation thereof is realized.
  • Method 3- Warp Yarn Dyeing
  • the dyestuff mixture prepared from clay, natural dyestuff and binders can be warp (yarn) dyed to the fabric. Warp dyeing is realized by means of making different combinations of all parameters according to different cloth constructions and the desired color tone in the slasher line.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Cultivation Of Plants (AREA)
  • Fertilizers (AREA)
  • Artificial Fish Reefs (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)

Abstract

The present invention relates to natural or artificial dyestuff mixtures comprising clays having pluralities of minerals therein and which are a soil type, wherein a dyestuff is obtained which encloses toxic substances and which prevents penetration of the toxic substances into the body.

Description

DYESTUFF MIXTURES INCLUDING CLAY
TECHNICAL FIELD
The present invention relates to natural or artificial dyestuff mixtures and clays having pluralities of minerals therein and which are a soil type.
PRIOR ART
Clay is a soft material having very tiny particles. The atoms, which exist in clay material, are in the form of a cage or a chain array. The basic substance of clay is aluminum silicate hydrate and there may be the compounds of other elements like sodium (it will be hereafter described as Na), potassium (it will be hereafter described as K), calcium (it will be hereafter described as Ca), magnesium (it will be hereafter described as Mg) and iron (it will be hereafter described as Fe).
Clays are formed by two different structure stones with X-rays diffraction studies. The first structure, having silicium ion at the center thereof and having oxygen ions at the corners thereof, is in the form of a regular tetrahedron as seen. Tetrahedron structure is formed, in other words, silica layer is formed by means of joining by giving sextet rings with oxygen bridges through the corners thereof such that the bases of these regular tetrahedrons, which have chemical formula that can be written as SiO 4 4, are in the same plane.
Dyestuff used in textile is chemicals obtained in a natural or artificial manner. Natural dyestuff can be herbal and animal sourced. Natural dyestuff has low color fastness and the cost thereof is high.
Synthetic dyestuffs (from ready petro-chemical raw materials) have high color fastness. They have a lower cost and they do not necessitate detailed dyeing processes.
Textile products are product groups which are in the densest relation with human body after food substances. The dye wastes and the chemicals, which exist on the clothes worn by humans, penetrate into the human body by means of sweating and breathing and affect the human health in an unfavorable manner. As also known in the literature, said chemical and dye wastes have allergy and cancer threaten against human health. As a result, as described above, it is seen that the dyestuff which shows carcinogenic effect for the human body or the chemicals and the dye wastes which remain during production of the dyestuff must be prevented from contacting the body. In the related technical field, novelty requirement occurs in this direction.
BRIEF DESCRIPTION OF THE INVENTION
The present invention relates to a dyestuff mixture, for eliminating the abovementioned disadvantages and for bringing new advantages to the related technical field.
An object of the present invention is to provide a dyestuff mixture which stores toxic substances and which prevents penetration to the body.
An object of the present invention is to provide a dyestuff mixture which prevents contact of harmful chemical wastes or dyestuff to the human body.
An object of the present invention is to provide a dyestuff mixture which has detox effect on the body.
In order to realize the abovementioned objects and the objects which are to be deducted from the detailed description below, the present invention relates to a dyestuff mixture. Said dyestuff mixture comprises clay with specific weight proportions and at least one synthetic or natural dyestuff with specific weight proportions. In the invention, in order to provide said advantages, the clay provided in the dyestuff mixture must have a weight proportion which provides said clay to be effective. Thanks to this, a dyestuff mixture is obtained which is useful for the human body by means of the detox effect and which prevents contact of the toxin substances, which exist on the fabric or which exist in the environment, to the human body.
In a possible embodiment of the present invention, the dyestuff mixture moreover comprises at least one clay and at least one artificial or at least one natural dyestuff, cross-binding substance which does not include formaldehyde and which functions as at least one binder, acrylic polymer which functions as at least one binder, dispersing agent which provides at least one homogenous mixture and at least one thickener substance with specific weight proportions. Thanks to this, a dyestuff mixture is provided which prevents contact of harmful chemical wastes or dyestuffs to the human body. In a possible embodiment of the present invention, said cross-binding substance is one of the chemical compounds which do not include formaldehyde.
In a possible embodiment of the present invention, the amount of said clay has a value between 1% and 15% by weight in the dyestuff mixture.
In a possible embodiment of the present invention, the amount of said dyestuff has a value between 1% and 15% by weight in the dyestuff mixture.
In a possible embodiment of the present invention, the dyestuff mixture comprises clay substance with proportion between 1% and 15% by weight, dyestuff with proportion between 1% and 15% by weight, cross-binding substance with proportion between 5% and 12% by weight, acrylic polymer with proportion between 5% and 12% by weight, dispersing agent with proportion between 2% and 5% by weight and thickener with proportion between 5% and 12% by weight.
In a possible embodiment of the present invention, the clay including substance is one of kaolin, montmorillonite, zeolite or the mixture thereof with specific weight proportions.
DETAILED DESCRIPTION OF THE INVENTION
In this detailed description, the subject matter relates to natural or artificial dyestuff mixtures comprising clays having pluralities of minerals therein and which are a soil type and are explained with references to examples without forming any restrictive effect only in order to make the subject more understandable.
In the invention, the clay including substance is one of kaolin, montmorillonite, zeolite or the mixture thereof with specific weight proportions.
As also known from the literature, thanks to the adsorption and absorption characteristics of the clays, the clays can purify the body from toxic substances. Since the clay is subjected to hot water pressure for long time underground, the clay is crystallized and charged with negative electricity. Thanks to the negative charges of the clay, the clay attracts the positive charged toxic substances onto the skin surface, and afterwards, the clay absorbs these and realizes the function of removing these from the body. As mentioned in our invention, as clay is used as a component in the dyestuff mixture, the chemical wastes, which exist in the body of the fabrics which are in contact with the human body, are prevented from contacting with the skin.
In the invention, thanks to the usage of clay in the dyestuff as component, a dyestuff mixture is obtained where the toxic effect is substantially reduced.
Natural or artificial dyestuffs can be used according to the fabric color desired to be obtained as dyestuff. As also known in the literature, the dyestuff used in the art has carcinogenic effect for the human body both because of their chemical structures and because of their wastes coming from their production steps. In this form, the contact of the dyestuff to the human body must be reduced.
The improvement, considered to be provided by the present invention, is the production of dyestuff comprising clay component which will function as a coating against the carcinogenic effects, which exist in the fabric, by means of application of the obtained dyestuff mixture to the fabric.
The dyestuff statement can be described as substances applied in making the fabric colored. Said dyestuff is natural or artificial chemical substance according to the color and characteristics desired from the fabric. The dyestuffs to be used in the present invention can be indigo dyestuffs or derivatives.
The dyestuff mixture to be obtained by the present invention comprises at least one clay and at least one dyestuff. Accordingly, the dyestuff mixture can also comprise the mixtures of more than one clay group with specific weight proportions.
The clay, provided in the dyestuff mixture, is provided at a proportion between 1% and 15% by weight.
The dyestuff raw substance provided in the dyestuff mixture is provided at a proportion between 1% and 15% by weight.
The dyestuff mixture, obtained by means of the present invention, also comprises the following raw substances which provide the desired performance and colors by weight:
• Clay substance with proportion between 1 % and 15%,
• At least one natural or artificial dyestuff with proportion between 1% and 15%, • Cross-binding substance which does not include formaldehyde and which functions as binder with proportion between 5% and 12%,
• Acrylic polymer which functions as binder with proportion between 5% and 12%,
• Dispersing agent which provides homogenous mixture with proportion between 2% and 5%,
• Thickener with proportion between 5% and 12%.
The dyestuff mixture comprises at least one solvent which completes to 100% by weight.
The production of dyestuff mixture obtained by means of the present invention is provided by means of forming a homogenous mixture in a solvent by clay and dyestuff. Binders, where cross-bonds are adhered, are added to the formed homogenous mixture. Dispersing agent substance is added for providing increase of homogeneity and for preventing precipitation of the components of the mixture where binder is added.
The dyestuff mixtures obtained by means of the present invention can be used as dyeing product in yarns, semi-produced products, woven fabrics, woven fabrics or non-woven fabrics.
Dyestuff mixtures can be applied to said textile products by means of coating method, exhaust method or dyeing method or impregnation method in the fiber exhaust melt.
Dyestuff mixtures can be applied preferably to textile products by means of coating or impregnation method.
Method 1- Coating Method
The dyestuff mixture obtained by means of the recipe given in the invention is transferred by means of pump to one or more than one surface of the fabric with different viscosities. The mixture is homogeneously coated onto the fabric by means of different blade systems. The coated dyestuff is added at a value between 1 gram and 250 grams preferably in meter square onto the fabric. Afterwards, drying process and fixation processes are applied onto the dyestuff fabric.
Method 2- Impregnation Method
The fabric is passed through the dyestuff liquor prepared by clay and natural dye and binders, and passes through tightening cylinders and drying is realized simultaneously. Afterwards, the fixation thereof is realized. Method 3- Warp Yarn Dyeing
The dyestuff mixture prepared from clay, natural dyestuff and binders can be warp (yarn) dyed to the fabric. Warp dyeing is realized by means of making different combinations of all parameters according to different cloth constructions and the desired color tone in the slasher line.
The protection scope of the present invention is set forth in the annexed claims and cannot be restricted to the illustrative disclosures given above, under the detailed description. It is because a person skilled in the relevant art can obviously produce similar embodiments under the light of the foregoing disclosures, without departing from the main principles of the present invention.

Claims

1. The present invention relates to a dyestuff mixture which prevents contact of the toxin substances, which exist on the fabric or which exist in the environment, to the body and which is useful for the human body by means of detox effect, wherein the subject matter dyestuff mixture comprises at least one clay mineral with specific weight proportions; at least one synthetic or natural dyestuff with specific weight proportions.
2. The dyestuff mixture according to claim 1 , wherein the dyestuff mixture moreover comprises at least one clay and at least one artificial or at least one natural dyestuff, cross-binding substance which does not include formaldehyde and which functions as at least one binder, acrylic polymer which functions as at least one binder, dispersing agent which provides at least one homogenous mixture and at least one thickener substance with specific weight proportions.
3. The dyestuff mixture according to claim 2, wherein said cross-binding substance is one of the chemical compounds which do not include formaldehyde.
4. The dyestuff mixture according to claim 1 or 2, wherein the amount of said clay has a value between 1% and 15% by weight in the dyestuff mixture.
5. The dyestuff mixture according to claim 1 or 2, wherein the amount of said dyestuff has a value between 1% and 15% by weight in the dyestuff mixture.
6. The dyestuff mixture according to any one of the preceding claims, wherein the dyestuff mixture comprises clay substance with proportion between 1% and 15% by weight, dyestuff with proportion between 1% and 15% by weight, cross-binding substance with proportion between 5% and 12% by weight, acrylic polymer with proportion between 5% and 12% by weight, dispersing agent with proportion between 2% and 5% by weight and thickener with proportion between 5% and 12% by weight.
7. The dyestuff mixture according to claim 1 , wherein the clay including substance is one of kaolin, montmorillonite, zeolite or the mixture thereof with specific weight proportions.
PCT/TR2020/051131 2020-01-16 2020-11-18 Dyestuff mixtures including clay WO2021145837A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
TR2020/00665A TR202000665A1 (en) 2020-01-16 2020-01-16 CLAY-CONTAINING MIXTURES
TR2020/00665 2020-01-16

Publications (1)

Publication Number Publication Date
WO2021145837A1 true WO2021145837A1 (en) 2021-07-22

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3597304A (en) * 1968-03-25 1971-08-03 Gen Mills Inc Dyeing of cellulosic fibers with cationic dye and montmorillonite clay and resulting product
US4097437A (en) * 1977-05-27 1978-06-27 M & T Chemicals Inc. Thixotropic aqueous coating composition of solubilized polymer with dispersion of quaternary ammonium clay in aliphatic hydrocarbon
KR20100008647A (en) * 2008-07-16 2010-01-26 한국세라믹기술원 Composition for coating textile and textile product comprising zeolite

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3597304A (en) * 1968-03-25 1971-08-03 Gen Mills Inc Dyeing of cellulosic fibers with cationic dye and montmorillonite clay and resulting product
US4097437A (en) * 1977-05-27 1978-06-27 M & T Chemicals Inc. Thixotropic aqueous coating composition of solubilized polymer with dispersion of quaternary ammonium clay in aliphatic hydrocarbon
KR20100008647A (en) * 2008-07-16 2010-01-26 한국세라믹기술원 Composition for coating textile and textile product comprising zeolite

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