WO2021125194A1 - Antibacterial fabric - Google Patents

Antibacterial fabric Download PDF

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Publication number
WO2021125194A1
WO2021125194A1 PCT/JP2020/046841 JP2020046841W WO2021125194A1 WO 2021125194 A1 WO2021125194 A1 WO 2021125194A1 JP 2020046841 W JP2020046841 W JP 2020046841W WO 2021125194 A1 WO2021125194 A1 WO 2021125194A1
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WO
WIPO (PCT)
Prior art keywords
fiber
antibacterial
antibacterial cloth
sheet
fibers
Prior art date
Application number
PCT/JP2020/046841
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French (fr)
Japanese (ja)
Inventor
辻 雅之
英治 田口
良 藤堂
Original Assignee
株式会社村田製作所
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by 株式会社村田製作所 filed Critical 株式会社村田製作所
Priority to CN202090001001.7U priority Critical patent/CN218203290U/en
Publication of WO2021125194A1 publication Critical patent/WO2021125194A1/en

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    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D11/00Double or multi-ply fabrics not otherwise provided for
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/20Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D3/00Woven fabrics characterised by their shape
    • D03D3/02Tubular fabrics
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04BKNITTING
    • D04B1/00Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04BKNITTING
    • D04B1/00Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
    • D04B1/14Other fabrics or articles characterised primarily by the use of particular thread materials

Definitions

  • the present invention relates to an antibacterial cloth that exhibits an antibacterial effect.
  • Patent Documents 1 to 8 Conventionally, many proposals have been made for fiber materials having antibacterial properties (see Patent Documents 1 to 8).
  • antibacterial materials may cause allergic reactions due to drugs and the like.
  • an object of the present invention is to provide an antibacterial cloth that has a longer lasting effect than a conventional material having antibacterial properties and is safer than a drug or the like.
  • the antibacterial cloth of the present invention is a second fiber composed of a first sheet containing the first fiber and a material which is arranged facing the first fiber and is lower than the first fiber in the charging row.
  • a second sheet containing the above, and at least one of the first fiber and the second fiber is charged by friction or close peeling, and the first fiber and the second fiber are charged.
  • the distance is less than 50 cm.
  • the antibacterial cloth according to the present invention at least one of the first sheet containing the first fiber and the second sheet containing the second fiber is charged by friction or close peeling.
  • the first fiber and the second fiber are made of materials existing at different positions in the charged rows.
  • the first fiber and the second fiber have different potentials. Therefore, an electric field is generated between the first fiber and the second fiber.
  • the antibacterial yarn according to the present invention can exert an antibacterial effect by the generated electric field.
  • first fiber or the second fiber Since the first fiber or the second fiber generates an electric field by friction or close peeling, no power source is required and there is no risk of electric shock. Further, since the first fiber or the second fiber repeatedly generates an electric field by friction or close peeling, it lasts longer than the antibacterial effect of a drug or the like. Also, it is less likely to cause an allergic reaction than a drug.
  • an antibacterial cloth that has a longer lasting effect than a conventional material having antibacterial properties and is safer than a drug or the like.
  • FIG. 1 (A) is a partially enlarged view showing the configuration of the antibacterial thread according to the first embodiment
  • FIG. 1 (B) is a cross-sectional view taken along the line II of FIG. 1 (A).
  • FIG. 2A is a partially enlarged view for explaining the configuration of the antibacterial thread according to the second embodiment
  • FIG. 2B is a sectional view taken along line II-II of FIG. 2A. is there.
  • FIG. 3A is a partially enlarged view for explaining the configuration of the antibacterial thread according to the third embodiment
  • FIG. 3B is a cross section cut along the line III-III of FIG. 3A. It is a figure.
  • FIG. 1 (A) is a partially enlarged view showing the configuration of the antibacterial thread according to the first embodiment
  • FIG. 1 (B) is a cross-sectional view taken along the line II of FIG. 1 (A).
  • FIG. 2A is a partially enlarged view for explaining the configuration of the antibacterial thread according to the second embodiment
  • FIG. 4 (A) is a partially enlarged view for explaining the configuration of the antibacterial cloth according to the fourth embodiment
  • FIG. 4 (B) is a cross section cut along the IV-IV line of FIG. 4 (A).
  • FIG. 5 (A) is a partially enlarged view for explaining the configuration of the antibacterial cloth according to the fifth embodiment
  • FIG. 5 (B) is a cross section cut along the line VV of FIG. 5 (A).
  • FIG. 6 (A) is a partially enlarged cross-sectional view for explaining the configuration of the antibacterial cloth according to the sixth embodiment
  • FIGS. 6 (B) and 6 (C) are antibacterial views according to the sixth embodiment. This is a modified example of cloth.
  • FIG. 1 (A) is a partially enlarged view showing the configuration of the antibacterial thread 100 according to the first embodiment
  • FIG. 1 (B) shows the antibacterial thread 100 cut along the line II of FIG. 1 (A). It is a cross-sectional view.
  • the antibacterial thread 100 includes a first fiber 11 and a second fiber 12.
  • the second fiber 12 is arranged so as to face the first fiber 11.
  • the second fiber 12 is made of a material that is lower in the charging row than the first fiber 11.
  • the material of the second fiber 12 is acrylic.
  • the material of the first fiber 11 may also be, for example, silk, rayon, glass, wool, cotton or the like. Silk, rayon, glass, wool, cotton and the like are relatively positively charged materials.
  • the material of the second fiber 12 may also be, for example, acetate, polyester, urethane, polyethylene, vinyl or the like. Acetate, polyester, urethane, polyethylene, vinyl and the like are materials that are relatively easily negatively charged.
  • the first fiber 11 may be made of a material having a position different from that of the second fiber 12 in the charging row. Further, the material of the first fiber 11 and the second fiber 12 may be a piezoelectric material having piezoelectricity.
  • first fiber 11 and the second fiber 12 are charged by friction.
  • first fiber 11 is rubbed by coming into contact with or away from the second fiber 12.
  • the first fiber 11 and the second fiber 12 are also charged by proximity peeling.
  • the first fiber 11 is a material that is easily charged positively, it is positively charged when rubbed.
  • the second fiber 12 is a material that is easily negatively charged, it is negatively charged when rubbed.
  • the first fiber 11 is also positively charged by being in contact with an object other than the second fiber 12 and being rubbed.
  • the second fiber 12 is also negatively charged by being in contact with and rubbed against an object other than the first fiber 11.
  • the first fiber 11 and the second fiber 12 generate an electric field due to the potential difference between them. Therefore, the antibacterial thread 100 generates an electric field. Further, when the first fiber 11 is close to an object having a predetermined potential, for example, a human body or the like having a predetermined potential (including a ground potential), the first fiber 11 is between the first fiber 11 and the object. Generates an electric field. Similarly, the second fiber 12 creates an electric field between the second fiber 12 and the object when it is in close proximity to an object having a predetermined potential.
  • the first fiber 11 and the second fiber 12 is charged by friction.
  • the first fiber 11 may be positively or negatively charged and the second fiber 12 may not be charged.
  • the first fiber 11 may not be charged and the second fiber 12 may be positively or negatively charged.
  • both the first fiber 11 and the second fiber 12 may be positively charged.
  • both the first fiber 11 and the second fiber 12 may be negatively charged.
  • both the first fiber 11 and the second fiber 12 are charged with the same polarity, a potential difference between the first fiber 11 and the second fiber 12 is required.
  • the potential difference between the first fiber 11 and the second fiber 12 becomes zero.
  • an electric field is generated due to the potential difference.
  • the electric field generated between the first fiber 11 and the second fiber 12 is maintained.
  • electroporation method is known as one of the mechanisms of cell membrane destruction related to such electrical stimulation (cell perforation mechanism by high voltage pulse-gene transfer method).
  • cell perforation mechanism by high voltage pulse-gene transfer method Basics-Michio Kasai and Hiroko Inaba, p. 1595).
  • the condition for electroporation that destroys cell membranes such as bacteria is generally when a potential difference (or voltage) of "1.0 V" is applied to cells, for example, the size of spores is 2 ⁇ m or more. In the case of about 10 ⁇ m, when an electric field with an electric field strength of 0.1 V / ⁇ m or more is generated, a potential difference (or voltage) of 1.0 V or more is applied even in the case of spores having a maximum size of 10 ⁇ m. It can cause electroporation to destroy cell membranes, or disrupt the life-sustaining electron transfer system, weakening or killing cells.
  • the maximum potential generated between the first fiber 11 and the second fiber 12 having different charge trains is 50 to 70 kV (Fiber and Industrial Vol.29, No.9 (1973) Hirakawa). Written by Toshi).
  • the distance between the charged fibers may theoretically be less than 50 cm. The closer the fibers are to each other, the larger the electric field and the higher the potential difference (or voltage) applied to the bacteria. Therefore, the first fiber 11 and the second fiber 12 exhibit higher antibacterial properties.
  • the antibacterial thread 100 directly exerts an antibacterial effect by an electric field formed in the vicinity of the antibacterial thread 100 or by an electric field generated when the antibacterial thread 100 is close to an object having a predetermined potential such as a human body.
  • the antibacterial thread 100 passes an electric current through moisture such as sweat when it is close to another nearby fiber or an object having a predetermined potential such as a human body. This current may also directly exert an antibacterial effect.
  • reactive oxygen species in which oxygen contained in water is changed by the action of current or voltage, radical species generated by interaction or catalysis with additives contained in fibers, or other antibacterial chemical species (amines). Derivatives, etc. may indirectly exert an antibacterial effect.
  • oxygen radicals may be generated in the cells of the bacterium due to the stress environment due to the presence of an electric field or an electric current, whereby the antibacterial thread 100 may indirectly exert an antibacterial effect.
  • generation of superoxide anion radical (active oxygen) or hydroxyl radical can be considered.
  • antibacterial as used in the present embodiment is a concept including both an effect of suppressing the growth of bacteria and an effect of killing the bacteria.
  • FIG. 2 (A) is a partially enlarged view for explaining the configuration of the antibacterial thread 200
  • FIG. 2 (B) is a cross-sectional view of the antibacterial thread 200 cut along the line II-II of FIG. 2 (A). Is.
  • the antibacterial thread 200 only the points different from those of the first embodiment will be described, and the same points will be omitted.
  • the antibacterial thread 200 includes a first fiber 21 and a second fiber 22.
  • the first fiber 21 and the second fiber 22 are long fibers.
  • the antibacterial yarn 200 is a twisted yarn in which the first fiber 21 and the second fiber 22 are twisted together.
  • the second fiber 22 is arranged so as to face the first fiber 21.
  • the first fiber 21 comes into contact with or separates from the second fiber 22. Therefore, the first fiber 21 causes friction with the second fiber 22. Further, the first fiber 21 comes into contact with an object other than the second fiber 22 and is rubbed. The second fiber 22 comes into contact with an object other than the first fiber 21 and is rubbed.
  • the first fiber 21 is positively charged when rubbed.
  • the second fiber 22 is negatively charged when rubbed.
  • the first fiber 21 and the second fiber 22 generate an electric field due to the potential difference between them. Therefore, the antibacterial thread 200 generates an electric field and exhibits antibacterial properties.
  • both the first fiber 21 and the second fiber 22 are long fibers, they are twisted more uniformly than a yarn in which only short fibers are twisted. That is, the shortest distance between the first fiber 21 and the second fiber 22 is substantially uniform. As a result, a uniform and strong electric field is generated between the first fiber 21 and the second fiber 22. Therefore, the antibacterial thread 200 can exhibit high antibacterial properties.
  • At least one of the first fiber 21 and the second fiber 22 is a long fiber.
  • a plurality of second fibers 22 which are short fibers may be twisted around the first fiber 21 which is a long fiber.
  • the shortest distance between the first fiber 21 and the second fiber 22 is to some extent more uniform than that of a yarn obtained by twisting only short fibers. Therefore, the antibacterial thread 200 can exhibit high antibacterial properties.
  • a yarn formed by twisting a plurality of short fibers may be formed, and this yarn may be used as the first fiber 21 and twisted with the second fiber 22 which is a long fiber.
  • the shortest distance between the first fiber 21 and the second fiber 22 is to some extent more uniform than the yarn in which only the short fibers are twisted. Therefore, the antibacterial thread 200 can exhibit high antibacterial properties.
  • FIG. 3 (A) is a partially enlarged view for explaining the configuration of the antibacterial thread 300
  • FIG. 3 (B) is a cross-sectional view of the antibacterial thread 300 cut along the line III-III of FIG. 3 (A). Is. In the description of the antibacterial thread 300, only the points different from those of the first embodiment will be described, and the same points will be omitted.
  • the antibacterial thread 300 includes a plurality of first fibers 31 and a plurality of second fibers 32.
  • the first fiber 31 and the second fiber 32 are short fibers.
  • the antibacterial yarn 300 is a twisted yarn in which a plurality of first fibers 31 and a plurality of second fibers 32 are twisted together.
  • Each first fiber 31 causes friction with a plurality of adjacent first fibers 31 or a plurality of adjacent second fibers 32.
  • each second fiber 32 also causes friction with a plurality of adjacent first fibers 31 or a plurality of other adjacent second fibers 32.
  • the first fiber 31 comes into contact with and is rubbed against an object other than the other first fiber 31 and the second fiber 32.
  • the second fiber 32 comes into contact with and is rubbed against objects other than the first fiber 31 and other second fibers 32.
  • the first fiber 31 is positively charged when rubbed.
  • the second fiber 32 is negatively charged when rubbed.
  • the first fiber 31 and the second fiber 32 generate an electric field due to the potential difference between them. Therefore, the antibacterial thread 300 generates an electric field and exhibits antibacterial properties.
  • the antibacterial yarn 300 Since the first fiber 31 and the second fiber 32 are short fibers, they are intricately intertwined with each other as compared with the case where they are long fibers. Therefore, the antibacterial yarn 300 has a more complicated shape than the yarn obtained by twisting only long fibers. Therefore, the antibacterial yarn 300 is more likely to cause friction than a yarn obtained by twisting only long fibers. Therefore, the antibacterial thread 300 is easily charged and can exhibit high antibacterial properties.
  • the antibacterial thread 300 can exhibit high antibacterial properties.
  • the antibacterial yarn 300 has more voids 34 between the first fibers 31 or the second fibers 32 than the yarn obtained by twisting only long fibers.
  • the antibacterial thread 300 can take in water or bacteria in the void 34. Therefore, the antibacterial yarn 300 is more likely to take in bacteria into a higher electric field space than a yarn obtained by twisting only long fibers, and can exhibit high antibacterial properties.
  • FIG. 4 (A) is a partially enlarged view for explaining the configuration of the antibacterial cloth 400
  • FIG. 4 (B) is a cross-sectional view of the antibacterial cloth 400 cut along the IV-IV line of FIG. 2 (A). Is. In the description of the antibacterial cloth 400, only the points different from those of the first embodiment will be described, and the same points will be omitted.
  • the antibacterial cloth 400 includes a plurality of first fibers 11, a plurality of second fibers 12, and a plurality of non-charged fibers 43.
  • the antibacterial cloth 400 is a woven fabric.
  • the first fiber 11 is the warp of the antibacterial cloth 400.
  • the second fiber 12 is the warp of the antibacterial cloth 400.
  • the non-charged fiber 43 is a weft of the antibacterial cloth 400.
  • Each of the second fibers 12 is arranged so as to alternately face the first fiber 11.
  • the antibacterial cloth 400 is not limited to the woven fabric structure.
  • the antibacterial cloth 400 is not limited to the plain weave as shown in FIG. 4 (A), and may be a twill weave or a satin weave. Further, the antibacterial cloth 400 may be made by stacking two woven fabrics like a double weave.
  • the plurality of first fibers 11 cause friction with the plurality of uncharged fibers 43.
  • the plurality of second fibers 12 cause friction with the plurality of uncharged fibers 43. Further, the first fiber 11 comes into contact with the adjacent second fiber 12 and is rubbed.
  • the second fiber 12 comes into contact with the adjacent first fiber 11 and is rubbed. Further, the first fiber 11 comes into contact with an object other than the antibacterial cloth 400 and is rubbed.
  • the second fiber 12 comes into contact with an object other than the antibacterial cloth 400 and is rubbed.
  • the first fiber 11 is positively charged when rubbed.
  • the second fiber 12 is negatively charged when rubbed.
  • the non-charged fiber 43 is not charged even when rubbed.
  • the first fiber 11 and the second fiber 12 generate an electric field due to a potential difference between them. Therefore, the antibacterial cloth 400 generates an electric field and exhibits antibacterial properties.
  • the antibacterial cloth 400 may be a woven fabric composed of only a plurality of first fibers 11 and second fibers 12.
  • the first fiber 11 is the warp of the antibacterial cloth 400
  • the second fiber 12 is the weft of the antibacterial cloth 400.
  • the first fiber 11 may be the weft of the antibacterial cloth 400
  • the second fiber 12 may be the warp of the antibacterial cloth 400.
  • the first fiber 11 may be contained in both the warp and the weft of the antibacterial cloth 400.
  • the second fiber 12 may be contained in both the warp and the weft of the antibacterial cloth 400.
  • the plurality of first fibers 11 and the plurality of second fibers 12 are rubbed against each other and charged respectively. Therefore, the antibacterial cloth 400 generates electric charges in a wider range, and thus exhibits high antibacterial properties.
  • FIG. 5 (A) is a partially enlarged view for explaining the configuration of the antibacterial cloth 500
  • FIG. 5 (B) is a cross-sectional view of the antibacterial cloth 500 cut along the line VV of FIG. 5 (A). Is. In the description of the antibacterial cloth 500, only the points different from the fourth embodiment will be described, and the same points will be omitted.
  • the antibacterial cloth 500 includes a first fiber 11 and a second fiber 12.
  • the antibacterial cloth 500 is a flat knitted fabric composed of the first fiber 11 and the second fiber 12.
  • the first fiber 11 is woven alternately with the second fiber 12 for each course.
  • the second fiber 12 is arranged alternately in close proximity to the first fiber 11.
  • the antibacterial cloth 500 may include non-charged fibers (not shown) that are not charged by friction in addition to the first fibers 11 and the second fibers 12.
  • the second fiber 12 is arranged close to the first fiber 11.
  • the first fiber 11 comes into contact with or separates from the second fiber 12. Therefore, the first fiber 11 causes friction with the second fiber 12. Further, the first fiber 11 comes into contact with an object other than the second fiber 12 and is rubbed. The second fiber 12 comes into contact with an object other than the first fiber 11 and is rubbed.
  • the first fiber 11 is positively charged when rubbed.
  • the second fiber 12 is negatively charged when rubbed.
  • the first fiber 11 and the second fiber 12 generate an electric field due to a potential difference between them. Therefore, the antibacterial cloth 500 generates an electric field and exhibits antibacterial properties.
  • FIG. 6A is a partially enlarged cross-sectional view for explaining the configuration of the antibacterial cloth 600.
  • the antibacterial cloth 600 only the points different from the fourth embodiment will be described, and the same points will be omitted.
  • the antibacterial cloth 600 includes a first sheet 61 and a second sheet 62.
  • the first sheet 61 includes a plurality of first fibers 11.
  • the second sheet 62 includes a plurality of second fibers 12.
  • the first sheet 61 and the second sheet 62 are not limited to the woven fabric structure shown in the antibacterial cloth 400, and may be knitted as shown in the antibacterial cloth 500.
  • the first sheet 61 is arranged so as to overlap parallel to the second sheet 62 in a plan view.
  • the first fiber 11 contained in the first sheet 61 and the second fiber 12 contained in the second sheet 62 are arranged to face each other.
  • the distance L between the first fiber 11 contained in the first sheet 61 and the second fiber 12 contained in the second sheet 62 is preferably less than 50 cm. The closer the distance L between the first fiber 11 and the second fiber 12 is, the larger the electric field generated between the first fiber 11 and the second fiber 12, and the potential difference (or voltage) applied to the fungus. ) Is also high, so that the antibacterial cloth 600 can exhibit higher antibacterial properties.
  • the first sheet 61 and the second sheet 62 may be arranged so as to have surfaces that rub against each other, and are not limited to a structure in which they overlap each other in parallel in a plan view.
  • a modified example of the antibacterial cloth 600 will be described.
  • FIG. 6B is a partially enlarged cross-sectional view for explaining the configuration of the antibacterial cloth 601 according to the modified example of the antibacterial cloth 600.
  • FIG. 6C is a partially enlarged cross-sectional view for explaining the configuration of the antibacterial cloth 602 according to the modified example of the antibacterial cloth 600.
  • the antibacterial cloth 601 and the antibacterial cloth 602 only the points different from the antibacterial cloth 600 will be described, and the same points will be omitted.
  • the antibacterial cloth 601 includes a first sheet 61 and a second sheet 62.
  • the first sheet 61 and the second sheet 62 are arranged so as to face each other, and the first sheet 61 and the second sheet 62 as a whole are formed in a cylindrical shape.
  • the connecting portion 64 of the first sheet 61 and the second sheet 62 is sewn together.
  • the first sheet 61 and the second sheet 62 have a space 63 between the first sheet 61 and the second sheet 62.
  • the antibacterial cloth 601 can exhibit antibacterial properties by generating an electric field in the space 63 between the first sheet 61 and the second sheet 62.
  • the antibacterial cloth 602 includes a first sheet 61 and a second sheet 62.
  • the first sheet 61 and the second sheet 62 are each formed in a cylindrical shape.
  • the inner diameter of the first sheet 61 is larger than the outer diameter of the second sheet 62.
  • the first sheet 61 is arranged so as to cover the second sheet 62.
  • the first sheet 61 and the second sheet 62 have a space 65 between the first sheet 61 and the second sheet 62.
  • the antibacterial cloth 602 can exhibit antibacterial properties by generating an electric field in the space 65 between the first sheet 61 and the second sheet 62.
  • the antibacterial cloth 400, the antibacterial cloth 500, or the antibacterial cloth 600 is not limited to woven fabrics or knitted fabrics.
  • the antibacterial cloth 400, the antibacterial cloth 500, or the antibacterial cloth 600 may be a non-woven fabric.
  • the antibacterial thread 100, the antibacterial thread 200, the antibacterial thread 300, the antibacterial cloth 400, the antibacterial cloth 500, or the antibacterial cloth 600 as described above can be applied to various clothing or products such as medical members.
  • the antibacterial thread 100, the antibacterial thread 200, the antibacterial thread 300, the antibacterial cloth 400, the antibacterial cloth 500, or the antibacterial cloth 600 includes masks, gloves, clothing, underwear (particularly socks, belly band), towels, headbands, wristbands, etc.
  • Sportswear in general hats, bedding (including cloth, mattresses, sheets, pillows, pillowcases, etc.), water purifiers, air conditioner or air purifier filters, and other pet-related products (pet mats, pet clothes, pets, etc.) Inner clothes), various mats (feet, hands, toilet seats, etc.), bags such as tote bags, laundry nets, packaging materials such as tangerine nets, seats (seats for cars, trains, airplanes, etc.), sofa covers , Bandages, gauze, sutures, clothes for doctors and patients, supporters, sanitary goods, sports goods (inners for clothing and gloves, baskets used in martial arts, etc.), artificial blood vessels, medical parts for surgery, etc. can do.

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Woven Fabrics (AREA)
  • Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)

Abstract

The present invention is characterized by comprising: a first sheet including a first fiber; and a second sheet including a second fiber that is disposed facing the first fiber and is composed of a material that is at a lower level than the first fiber in the triboelectric series, wherein at least one among the first fiber and the second fiber is charged by friction or close peeling, and the distance between the first fiber and the second fiber is less than 50 cm.

Description

抗菌布Antibacterial cloth
 本発明は、抗菌効果を発揮する抗菌布に関する。 The present invention relates to an antibacterial cloth that exhibits an antibacterial effect.
 従来から、抗菌性を有する繊維材料については、多数の提案がなされている(特許文献1乃至特許文献8を参照)。 Conventionally, many proposals have been made for fiber materials having antibacterial properties (see Patent Documents 1 to 8).
特許第3281640号公報Japanese Patent No. 3281640 特開平7-310284号公報Japanese Unexamined Patent Publication No. 7-310284 特許第3165992号公報Japanese Patent No. 3165992 特許第1805853号公報Japanese Patent No. 1805853 特開平8-226078号公報Japanese Unexamined Patent Publication No. 8-226578 特開平9-194304号公報Japanese Unexamined Patent Publication No. 9-194304 特開2004-300650号公報Japanese Unexamined Patent Publication No. 2004-300650 特許第6292368号公報Japanese Patent No. 6292368
 しかし、抗菌性を有する材料は、いずれも効果が長く持続しなかった。 However, none of the antibacterial materials had a long-lasting effect.
 また、抗菌性を有する材料は、薬剤等によるアレルギー反応が生じる場合もある。 In addition, antibacterial materials may cause allergic reactions due to drugs and the like.
 そこで、この発明は、従来の抗菌性を有する材料よりも効果が長く持続し、かつ薬剤等よりも安全性の高い抗菌布を提供することを目的とする。 Therefore, an object of the present invention is to provide an antibacterial cloth that has a longer lasting effect than a conventional material having antibacterial properties and is safer than a drug or the like.
 本発明の抗菌布は、第1の繊維を含む第1のシートと、前記第1の繊維に対面して配置され、帯電列において前記第1の繊維より下位である素材からなる第2の繊維を含む第2のシートと、を備え、前記第1の繊維及び前記第2の繊維の少なくともいずれか一方は、摩擦又は近接剥離により帯電し、前記第1の繊維と前記第2の繊維との距離が50cm未満であることを特徴とする。 The antibacterial cloth of the present invention is a second fiber composed of a first sheet containing the first fiber and a material which is arranged facing the first fiber and is lower than the first fiber in the charging row. A second sheet containing the above, and at least one of the first fiber and the second fiber is charged by friction or close peeling, and the first fiber and the second fiber are charged. The distance is less than 50 cm.
 本発明に係る抗菌布において、第1の繊維を含む第1のシート又は第2の繊維を含む第2のシートの少なくともいずれか一方は、摩擦又は近接剥離により帯電する。第1の繊維及び第2の繊維は互いに帯電列の異なる位置に存在する素材からなる。第1の繊維及び第2の繊維は、異なる電位となる。よって、第1の繊維及び第2の繊維の間で、電場が発生する。本発明に係る抗菌糸は、この発生した電場により抗菌効果を発揮することができる。 In the antibacterial cloth according to the present invention, at least one of the first sheet containing the first fiber and the second sheet containing the second fiber is charged by friction or close peeling. The first fiber and the second fiber are made of materials existing at different positions in the charged rows. The first fiber and the second fiber have different potentials. Therefore, an electric field is generated between the first fiber and the second fiber. The antibacterial yarn according to the present invention can exert an antibacterial effect by the generated electric field.
 第1の繊維又は第2の繊維は、摩擦又は近接剥離により電場を生じさせるため、電源が不要であるし、感電のおそれもない。また、第1の繊維又は第2の繊維は、摩擦又は近接剥離により繰り返し電場を生じさせるため、薬剤等による抗菌効果よりも長く持続する。また、薬剤よりもアレルギー反応が生じるおそれは低い。 Since the first fiber or the second fiber generates an electric field by friction or close peeling, no power source is required and there is no risk of electric shock. Further, since the first fiber or the second fiber repeatedly generates an electric field by friction or close peeling, it lasts longer than the antibacterial effect of a drug or the like. Also, it is less likely to cause an allergic reaction than a drug.
 この発明によれば、従来の抗菌性を有する材料よりも効果が長く持続し、かつ薬剤等よりも安全性の高い抗菌布を実現することができる。 According to the present invention, it is possible to realize an antibacterial cloth that has a longer lasting effect than a conventional material having antibacterial properties and is safer than a drug or the like.
図1(A)は、第1実施形態に係る抗菌糸の構成を示す一部拡大図であり、図1(B)は、図1(A)のI-I線における断面図である。FIG. 1 (A) is a partially enlarged view showing the configuration of the antibacterial thread according to the first embodiment, and FIG. 1 (B) is a cross-sectional view taken along the line II of FIG. 1 (A). 図2(A)は、第2実施形態に係る抗菌糸の構成を説明するための一部拡大図であり、図2(B)は、図2(A)のII-II線における断面図である。FIG. 2A is a partially enlarged view for explaining the configuration of the antibacterial thread according to the second embodiment, and FIG. 2B is a sectional view taken along line II-II of FIG. 2A. is there. 図3(A)は、第3実施形態に係る抗菌糸の構成を説明するための一部拡大図であり、図3(B)は、図3(A)のIII-III線で切断した断面図である。FIG. 3A is a partially enlarged view for explaining the configuration of the antibacterial thread according to the third embodiment, and FIG. 3B is a cross section cut along the line III-III of FIG. 3A. It is a figure. 図4(A)は、第4実施形態に係る抗菌布の構成を説明するための一部拡大図であり、図4(B)は、図4(A)のIV-IV線で切断した断面図である。FIG. 4 (A) is a partially enlarged view for explaining the configuration of the antibacterial cloth according to the fourth embodiment, and FIG. 4 (B) is a cross section cut along the IV-IV line of FIG. 4 (A). It is a figure. 図5(A)は、第5実施形態に係る抗菌布の構成を説明するための一部拡大図であり、図5(B)は、図5(A)のV-V線で切断した断面図である。FIG. 5 (A) is a partially enlarged view for explaining the configuration of the antibacterial cloth according to the fifth embodiment, and FIG. 5 (B) is a cross section cut along the line VV of FIG. 5 (A). It is a figure. 図6(A)は、第6実施形態に係る抗菌布の構成を説明するための一部断面拡大図であり、図6(B)及び図6(C)は、第6実施形態に係る抗菌布の変形例である。FIG. 6 (A) is a partially enlarged cross-sectional view for explaining the configuration of the antibacterial cloth according to the sixth embodiment, and FIGS. 6 (B) and 6 (C) are antibacterial views according to the sixth embodiment. This is a modified example of cloth.
 図1(A)は、第1実施形態に係る抗菌糸100の構成を示す一部拡大図であり、図1(B)は、抗菌糸100を図1(A)のI-I線で切断した断面図である。 FIG. 1 (A) is a partially enlarged view showing the configuration of the antibacterial thread 100 according to the first embodiment, and FIG. 1 (B) shows the antibacterial thread 100 cut along the line II of FIG. 1 (A). It is a cross-sectional view.
 図1(A)に示すように、抗菌糸100は、第1の繊維11及び第2の繊維12を備える。第2の繊維12は、第1の繊維11に対面して配置されている。 As shown in FIG. 1 (A), the antibacterial thread 100 includes a first fiber 11 and a second fiber 12. The second fiber 12 is arranged so as to face the first fiber 11.
 第2の繊維12は、第1の繊維11より帯電列において下位である素材からなる。例えば、第1の繊維11の素材はナイロンであるとき、第2の繊維12の素材はアクリルである。第1の繊維11の素材は、他に例えば、絹、レーヨン、ガラス、羊毛、又は木綿等でもよい。絹、レーヨン、ガラス、羊毛、及び木綿等は、比較的正に帯電し易い素材である。第2の繊維12の素材は、他に例えば、アセテート、ポリエステル、ウレタン、ポリエチレン、又はビニル等でもよい。アセテート、ポリエステル、ウレタン、ポリエチレン、及びビニル等は、比較的負に帯電し易い素材である。なお、第1の繊維11は、第2の繊維12と帯電列において異なる位置である素材からなればよい。また、第1の繊維11と第2の繊維12との素材は、圧電性を有する圧電体でもよい。 The second fiber 12 is made of a material that is lower in the charging row than the first fiber 11. For example, when the material of the first fiber 11 is nylon, the material of the second fiber 12 is acrylic. The material of the first fiber 11 may also be, for example, silk, rayon, glass, wool, cotton or the like. Silk, rayon, glass, wool, cotton and the like are relatively positively charged materials. The material of the second fiber 12 may also be, for example, acetate, polyester, urethane, polyethylene, vinyl or the like. Acetate, polyester, urethane, polyethylene, vinyl and the like are materials that are relatively easily negatively charged. The first fiber 11 may be made of a material having a position different from that of the second fiber 12 in the charging row. Further, the material of the first fiber 11 and the second fiber 12 may be a piezoelectric material having piezoelectricity.
 以下、摩擦により第1の繊維11及び第2の繊維12が帯電する場合について説明する。例えば、第1の繊維11は、第2の繊維12に対して接触したり、離れたりすることで摩擦される。なお、第1の繊維11及び第2の繊維12は、近接剥離によっても帯電する。 Hereinafter, a case where the first fiber 11 and the second fiber 12 are charged by friction will be described. For example, the first fiber 11 is rubbed by coming into contact with or away from the second fiber 12. The first fiber 11 and the second fiber 12 are also charged by proximity peeling.
 図1(B)に示すように、第1の繊維11は、正に帯電し易い素材であるため、摩擦されると正に帯電する。第2の繊維12は、負に帯電し易い素材であるため、摩擦されると負に帯電する。また、第1の繊維11は、第2の繊維12以外の物に接触して摩擦されることによっても、正に帯電する。第2の繊維12は、第1の繊維11以外の物に接触して摩擦されることによっても、負に帯電する。 As shown in FIG. 1B, since the first fiber 11 is a material that is easily charged positively, it is positively charged when rubbed. Since the second fiber 12 is a material that is easily negatively charged, it is negatively charged when rubbed. Further, the first fiber 11 is also positively charged by being in contact with an object other than the second fiber 12 and being rubbed. The second fiber 12 is also negatively charged by being in contact with and rubbed against an object other than the first fiber 11.
 第1の繊維11及び第2の繊維12は、互いの電位差によって電場を生じる。従って、抗菌糸100は、電場を生じる。また、第1の繊維11は、近接する所定の電位、例えば人体等の所定の電位(グランド電位を含む。)を有する物に近接した場合に、第1の繊維11と該物との間に電場を生じさせる。同様に、第2の繊維12は、近接する所定の電位を有する物に近接した場合に、第2の繊維12と該物との間に電場を生じさせる。 The first fiber 11 and the second fiber 12 generate an electric field due to the potential difference between them. Therefore, the antibacterial thread 100 generates an electric field. Further, when the first fiber 11 is close to an object having a predetermined potential, for example, a human body or the like having a predetermined potential (including a ground potential), the first fiber 11 is between the first fiber 11 and the object. Generates an electric field. Similarly, the second fiber 12 creates an electric field between the second fiber 12 and the object when it is in close proximity to an object having a predetermined potential.
 なお、第1の繊維11及び第2の繊維12の少なくとも一方が、摩擦により帯電すればよい。例えば、第1の繊維11が正又は負に帯電し、第2の繊維12が帯電しなくてもよい。また、第1の繊維11が帯電せず、第2の繊維12が正又は負に帯電してもよい。さらに、第1の繊維11及び第2の繊維12は、ともに正に帯電してもよい。また、第1の繊維11及び第2の繊維12は、ともに負に帯電してもよい。ただし、第1の繊維11及び第2の繊維12がともに同じ極性に帯電している場合、第1の繊維11と第2の繊維12との間の電位差が必要となる。 It is sufficient that at least one of the first fiber 11 and the second fiber 12 is charged by friction. For example, the first fiber 11 may be positively or negatively charged and the second fiber 12 may not be charged. Further, the first fiber 11 may not be charged and the second fiber 12 may be positively or negatively charged. Further, both the first fiber 11 and the second fiber 12 may be positively charged. Further, both the first fiber 11 and the second fiber 12 may be negatively charged. However, when both the first fiber 11 and the second fiber 12 are charged with the same polarity, a potential difference between the first fiber 11 and the second fiber 12 is required.
 第1の繊維11が第2の繊維12に対して接触している場合、第1の繊維11及び第2の繊維12の間の電位差は0になる。第1の繊維11が第2の繊維12から離れると、電位差により電場が生じる。第1の繊維11が第2の繊維12に接触していない場合、第1の繊維11及び第2の繊維12の間に生じた電場は維持される。 When the first fiber 11 is in contact with the second fiber 12, the potential difference between the first fiber 11 and the second fiber 12 becomes zero. When the first fiber 11 is separated from the second fiber 12, an electric field is generated due to the potential difference. When the first fiber 11 is not in contact with the second fiber 12, the electric field generated between the first fiber 11 and the second fiber 12 is maintained.
 従来から、電場により細菌及び真菌の増殖を抑制することができる旨が知られている(例えば、土戸哲明,高麗寛紀,松岡英明,小泉淳一著、講談社:微生物制御-科学と工学を参照。また、例えば、高木浩一,高電圧・プラズマ技術の農業・食品分野への応用,J.HTSJ,Vol.51,No.216を参照)。また、この電場を生じさせている電位により、湿気等で形成された電流経路、又は局部的なミクロな放電現象等で形成された回路を電流が流れることがある。この電流により菌が弱体化し、菌の増殖を抑制することが考えられる。なお、本実施形態で言う菌とは、細菌、真菌又はダニやノミ等の微生物を含む。従って、抗菌糸100は、形成される電場によって、直接的に抗菌効果を発揮することができる。 It has long been known that electric fields can suppress the growth of bacteria and fungi (see, for example, Tetsuaki Doto, Hiroki Korai, Hideaki Matsuoka, Junichi Koizumi, Kodansha: Microbial Control-Science and Engineering. Also, see, for example, Koichi Takaki, Application of high-voltage / plasma technology to the agricultural / food field, J.HTSJ, Vol.51, No.216). Further, depending on the potential that generates this electric field, a current may flow through a current path formed by humidity or the like, or a circuit formed by a local micro discharge phenomenon or the like. It is considered that this electric current weakens the bacteria and suppresses the growth of the bacteria. The bacteria referred to in the present embodiment include bacteria, fungi, and microorganisms such as mites and fleas. Therefore, the antibacterial thread 100 can directly exert an antibacterial effect by the formed electric field.
 さらに、このような電気的刺激に関連して、細胞膜破壊のメカニズムの一つとして、電気穿孔法(エレクトロポレーション法)が知られている(高電圧パルスによる細胞穿孔のメカニズム -遺伝子導入法の基礎- 葛西道生・稲葉浩子著、第1595頁)。 Furthermore, the electroporation method is known as one of the mechanisms of cell membrane destruction related to such electrical stimulation (cell perforation mechanism by high voltage pulse-gene transfer method). Basics-Michio Kasai and Hiroko Inaba, p. 1595).
 上記文献によると、菌などの細胞膜を破壊するエレクトロポレーションが起こる条件は、概して、細胞に「1.0V」の電位差(又は電圧)がかかったときであり、例えば胞子の大きさが2μm~10μm程度の場合には、0.1V/μm以上の電界強度の電場が発生すると、最大で10μmの大きさを有する胞子の場合であっても、1.0V以上の電位差(又は電圧)をかけることができ、エレクトロポレーションが生じて細胞膜が破壊されるか、あるいは生命維持のための電子伝達系に支障が生じて、細胞が弱体化又は死滅する。 According to the above literature, the condition for electroporation that destroys cell membranes such as bacteria is generally when a potential difference (or voltage) of "1.0 V" is applied to cells, for example, the size of spores is 2 μm or more. In the case of about 10 μm, when an electric field with an electric field strength of 0.1 V / μm or more is generated, a potential difference (or voltage) of 1.0 V or more is applied even in the case of spores having a maximum size of 10 μm. It can cause electroporation to destroy cell membranes, or disrupt the life-sustaining electron transfer system, weakening or killing cells.
 それぞれ帯電列の異なる第1の繊維11と第2の繊維12の間に生じる電位は最大で50~70kVとなることが報告されている(繊維と工業Vol.29,No.9(1973)平川董著)。抗菌効果が発現する0.1V/μm以上の電場を形成するためには、帯電した繊維同士の距離は理論上50cm未満であればよい。繊維同士の距離が近ければ近いほど電場は大きくなり、菌にかかる電位差(又は電圧)も高くなるため、第1の繊維11及び第2の繊維12は、より高い抗菌性を発現する。 It has been reported that the maximum potential generated between the first fiber 11 and the second fiber 12 having different charge trains is 50 to 70 kV (Fiber and Industrial Vol.29, No.9 (1973) Hirakawa). Written by Toshi). In order to form an electric field of 0.1 V / μm or more at which the antibacterial effect is exhibited, the distance between the charged fibers may theoretically be less than 50 cm. The closer the fibers are to each other, the larger the electric field and the higher the potential difference (or voltage) applied to the bacteria. Therefore, the first fiber 11 and the second fiber 12 exhibit higher antibacterial properties.
 また、抗菌糸100は、抗菌糸100の近傍に形成される電場によって、あるいは人体等の所定の電位を有する物に近接した場合に発生する電場によって、直接的に抗菌効果を発揮する。あるいは、抗菌糸100は、汗等の水分を介して、近接する他の繊維又は人体等の所定の電位を有する物に近接した場合に電流を流す。この電流によっても、直接的に抗菌効果を発揮する場合がある。あるいは、電流又は電圧の作用により水分に含まれる酸素が変化した活性酸素種、さらに繊維中に含まれる添加材との相互作用又は触媒作用によって生じたラジカル種、又はその他の抗菌性化学種(アミン誘導体等)によって間接的に抗菌効果を発揮する場合がある。あるいは、電場又は電流の存在によるストレス環境により菌の細胞内に酸素ラジカルが生成される場合がある、これにより抗菌糸100が、間接的に抗菌効果を発揮する場合がある。ラジカルとしては、スーパーオキシドアニオンラジカル(活性酸素)又はヒドロキシラジカルの発生が考えられる。なお、本実施形態で言う「抗菌」とは、菌の発生を抑制する効果、また菌を死滅する効果の両方を含む概念である。 Further, the antibacterial thread 100 directly exerts an antibacterial effect by an electric field formed in the vicinity of the antibacterial thread 100 or by an electric field generated when the antibacterial thread 100 is close to an object having a predetermined potential such as a human body. Alternatively, the antibacterial thread 100 passes an electric current through moisture such as sweat when it is close to another nearby fiber or an object having a predetermined potential such as a human body. This current may also directly exert an antibacterial effect. Alternatively, reactive oxygen species in which oxygen contained in water is changed by the action of current or voltage, radical species generated by interaction or catalysis with additives contained in fibers, or other antibacterial chemical species (amines). Derivatives, etc.) may indirectly exert an antibacterial effect. Alternatively, oxygen radicals may be generated in the cells of the bacterium due to the stress environment due to the presence of an electric field or an electric current, whereby the antibacterial thread 100 may indirectly exert an antibacterial effect. As the radical, generation of superoxide anion radical (active oxygen) or hydroxyl radical can be considered. The term "antibacterial" as used in the present embodiment is a concept including both an effect of suppressing the growth of bacteria and an effect of killing the bacteria.
 以下、第2実施形態に係る抗菌糸200について説明する。図2(A)は、抗菌糸200の構成を説明するための一部拡大図であり、図2(B)は、抗菌糸200を図2(A)のII-II線で切断した断面図である。抗菌糸200の説明においては、第1実施形態と異なる点についてのみ説明を行い、同様の点については説明を省略する。 Hereinafter, the antibacterial thread 200 according to the second embodiment will be described. FIG. 2 (A) is a partially enlarged view for explaining the configuration of the antibacterial thread 200, and FIG. 2 (B) is a cross-sectional view of the antibacterial thread 200 cut along the line II-II of FIG. 2 (A). Is. In the description of the antibacterial thread 200, only the points different from those of the first embodiment will be described, and the same points will be omitted.
 図2(A)に示すように、抗菌糸200は、第1の繊維21及び第2の繊維22を備える。第1の繊維21及び第2の繊維22は、長繊維である。抗菌糸200は、第1の繊維21及び第2の繊維22を互いに撚り合わせた撚糸である。第2の繊維22は、第1の繊維21に対面して配置されている。 As shown in FIG. 2A, the antibacterial thread 200 includes a first fiber 21 and a second fiber 22. The first fiber 21 and the second fiber 22 are long fibers. The antibacterial yarn 200 is a twisted yarn in which the first fiber 21 and the second fiber 22 are twisted together. The second fiber 22 is arranged so as to face the first fiber 21.
 第1の繊維21は、第2の繊維22と接触したり、離れたりする。従って、第1の繊維21は、第2の繊維22との間で摩擦を生じる。また、第1の繊維21は、第2の繊維22以外の物に接触して摩擦される。第2の繊維22は、第1の繊維21以外の物に接触して摩擦される。 The first fiber 21 comes into contact with or separates from the second fiber 22. Therefore, the first fiber 21 causes friction with the second fiber 22. Further, the first fiber 21 comes into contact with an object other than the second fiber 22 and is rubbed. The second fiber 22 comes into contact with an object other than the first fiber 21 and is rubbed.
 図2(B)に示すように、第1の繊維21は、摩擦されると正に帯電する。第2の繊維22は、摩擦されると負に帯電する。第1の繊維21及び第2の繊維22は、互いの電位差によって電場を生じる。従って、抗菌糸200は電場を生じ、抗菌性を発揮する。 As shown in FIG. 2B, the first fiber 21 is positively charged when rubbed. The second fiber 22 is negatively charged when rubbed. The first fiber 21 and the second fiber 22 generate an electric field due to the potential difference between them. Therefore, the antibacterial thread 200 generates an electric field and exhibits antibacterial properties.
 第1の繊維21及び第2の繊維22はともに長繊維であるため、短繊維のみを撚った糸よりも、均一に撚り合わされている。つまり、第1の繊維21と第2の繊維22との最短距離は、概ね均一である。これにより、第1の繊維21及び第2の繊維22との間に、一様で強い電場が生じる。従って抗菌糸200は、高い抗菌性を発揮することができる。 Since both the first fiber 21 and the second fiber 22 are long fibers, they are twisted more uniformly than a yarn in which only short fibers are twisted. That is, the shortest distance between the first fiber 21 and the second fiber 22 is substantially uniform. As a result, a uniform and strong electric field is generated between the first fiber 21 and the second fiber 22. Therefore, the antibacterial thread 200 can exhibit high antibacterial properties.
 なお、第1の繊維21又は第2の繊維22の少なくとも一方が長繊維であればよい。例えば、長繊維である第1の繊維21に短繊維である複数の第2の繊維22を撚ってもよい。この場合、第1の繊維21と第2の繊維22との最短距離は、短繊維のみを撚った糸よりも、ある程度は均一である。従って、抗菌糸200は、高い抗菌性を発揮することができる。また、複数の短繊維を撚ってなる糸を形成し、この糸を第1の繊維21として、長繊維である第2の繊維22と撚ってもよい。これによっても、第1の繊維21と第2の繊維22との最短距離は、短繊維のみを撚った糸よりも、ある程度は均一である。従って、抗菌糸200は、高い抗菌性を発揮することができる。 It is sufficient that at least one of the first fiber 21 and the second fiber 22 is a long fiber. For example, a plurality of second fibers 22 which are short fibers may be twisted around the first fiber 21 which is a long fiber. In this case, the shortest distance between the first fiber 21 and the second fiber 22 is to some extent more uniform than that of a yarn obtained by twisting only short fibers. Therefore, the antibacterial thread 200 can exhibit high antibacterial properties. Further, a yarn formed by twisting a plurality of short fibers may be formed, and this yarn may be used as the first fiber 21 and twisted with the second fiber 22 which is a long fiber. Again, the shortest distance between the first fiber 21 and the second fiber 22 is to some extent more uniform than the yarn in which only the short fibers are twisted. Therefore, the antibacterial thread 200 can exhibit high antibacterial properties.
 以下、第3実施形態に係る抗菌糸300について説明する。図3(A)は、抗菌糸300の構成を説明するための一部拡大図であり、図3(B)は、抗菌糸300を図3(A)のIII-III線で切断した断面図である。抗菌糸300の説明においては、第1実施形態と異なる点についてのみ説明を行い、同様の点については説明を省略する。 Hereinafter, the antibacterial thread 300 according to the third embodiment will be described. FIG. 3 (A) is a partially enlarged view for explaining the configuration of the antibacterial thread 300, and FIG. 3 (B) is a cross-sectional view of the antibacterial thread 300 cut along the line III-III of FIG. 3 (A). Is. In the description of the antibacterial thread 300, only the points different from those of the first embodiment will be described, and the same points will be omitted.
 図3(A)に示すように、抗菌糸300は、複数の第1の繊維31及び複数の第2の繊維32を備える。第1の繊維31及び第2の繊維32は、短繊維である。抗菌糸300は、複数の第1の繊維31及び複数の第2の繊維32を互いに撚り合わせた撚糸である。 As shown in FIG. 3A, the antibacterial thread 300 includes a plurality of first fibers 31 and a plurality of second fibers 32. The first fiber 31 and the second fiber 32 are short fibers. The antibacterial yarn 300 is a twisted yarn in which a plurality of first fibers 31 and a plurality of second fibers 32 are twisted together.
 各第1の繊維31は、近接する他の複数の第1の繊維31又は近接する複数の第2の繊維32との間で摩擦を生じる。同様に、各第2の繊維32も、近接する複数の第1の繊維31又は近接する他の複数の第2の繊維32との間で摩擦を生じる。また、第1の繊維31は、他の第1の繊維31及び第2の繊維32以外の物に接触して摩擦される。第2の繊維32は、第1の繊維31及び他の第2の繊維32以外の物に接触して摩擦される。 Each first fiber 31 causes friction with a plurality of adjacent first fibers 31 or a plurality of adjacent second fibers 32. Similarly, each second fiber 32 also causes friction with a plurality of adjacent first fibers 31 or a plurality of other adjacent second fibers 32. Further, the first fiber 31 comes into contact with and is rubbed against an object other than the other first fiber 31 and the second fiber 32. The second fiber 32 comes into contact with and is rubbed against objects other than the first fiber 31 and other second fibers 32.
 図3(B)に示すように、第1の繊維31は、摩擦されると正に帯電する。第2の繊維32は、摩擦されると負に帯電する。第1の繊維31及び第2の繊維32は、互いの電位差によって電場を生じる。従って、抗菌糸300は電場を生じ、抗菌性を発揮する。 As shown in FIG. 3B, the first fiber 31 is positively charged when rubbed. The second fiber 32 is negatively charged when rubbed. The first fiber 31 and the second fiber 32 generate an electric field due to the potential difference between them. Therefore, the antibacterial thread 300 generates an electric field and exhibits antibacterial properties.
 第1の繊維31及び第2の繊維32は、短繊維であるため、長繊維である場合に比べて互いに複雑に絡み合っている。このため、抗菌糸300は、長繊維のみを撚った糸よりも複雑な形状になる。従って、抗菌糸300は、長繊維のみを撚った糸よりも摩擦が生じやすい。従って、抗菌糸300は帯電しやすく、高い抗菌性を発揮することができる。 Since the first fiber 31 and the second fiber 32 are short fibers, they are intricately intertwined with each other as compared with the case where they are long fibers. Therefore, the antibacterial yarn 300 has a more complicated shape than the yarn obtained by twisting only long fibers. Therefore, the antibacterial yarn 300 is more likely to cause friction than a yarn obtained by twisting only long fibers. Therefore, the antibacterial thread 300 is easily charged and can exhibit high antibacterial properties.
 また、抗菌糸300の形状が複雑になるほど、抗菌糸300の表面積は大きくなる。このため、抗菌糸300は、長繊維のみを撚った糸よりも、広い面積で菌と接触する。よって、抗菌糸300は、高い抗菌性を発揮することができる。 Further, the more complicated the shape of the antibacterial thread 300, the larger the surface area of the antibacterial thread 300. Therefore, the antibacterial yarn 300 comes into contact with the fungus in a wider area than the yarn obtained by twisting only long fibers. Therefore, the antibacterial thread 300 can exhibit high antibacterial properties.
 抗菌糸300は、長繊維のみを撚った糸よりも、第1の繊維31又は第2の繊維32の間に多くの空隙34を有する。抗菌糸300は、空隙34に水又は菌を取り込むことができる。よって、抗菌糸300は、長繊維のみを撚った糸よりも、高い電場空間に菌を取り込みやすく、高い抗菌性を発揮することができる。 The antibacterial yarn 300 has more voids 34 between the first fibers 31 or the second fibers 32 than the yarn obtained by twisting only long fibers. The antibacterial thread 300 can take in water or bacteria in the void 34. Therefore, the antibacterial yarn 300 is more likely to take in bacteria into a higher electric field space than a yarn obtained by twisting only long fibers, and can exhibit high antibacterial properties.
 以下、第4実施形態に係る抗菌布400について説明する。図4(A)は、抗菌布400の構成を説明するための一部拡大図であり、図4(B)は、抗菌布400を図2(A)のIV-IV線で切断した断面図である。抗菌布400の説明においては、第1実施形態と異なる点についてのみ説明を行い、同様の点については説明を省略する。 Hereinafter, the antibacterial cloth 400 according to the fourth embodiment will be described. FIG. 4 (A) is a partially enlarged view for explaining the configuration of the antibacterial cloth 400, and FIG. 4 (B) is a cross-sectional view of the antibacterial cloth 400 cut along the IV-IV line of FIG. 2 (A). Is. In the description of the antibacterial cloth 400, only the points different from those of the first embodiment will be described, and the same points will be omitted.
 図4(A)に示すように、抗菌布400は、複数の第1の繊維11、複数の第2の繊維12、及び複数の非帯電繊維43を備える。抗菌布400は、織物である。第1の繊維11は、抗菌布400の経糸である。第2の繊維12は、抗菌布400の経糸である。非帯電繊維43は、抗菌布400の緯糸である。各第2の繊維12は、第1の繊維11と交互に対面して配置されている。 As shown in FIG. 4A, the antibacterial cloth 400 includes a plurality of first fibers 11, a plurality of second fibers 12, and a plurality of non-charged fibers 43. The antibacterial cloth 400 is a woven fabric. The first fiber 11 is the warp of the antibacterial cloth 400. The second fiber 12 is the warp of the antibacterial cloth 400. The non-charged fiber 43 is a weft of the antibacterial cloth 400. Each of the second fibers 12 is arranged so as to alternately face the first fiber 11.
 抗菌布400は、織物組織に限定されない。抗菌布400は、例えば図4(A)に示すような平織に限らず、綾織や朱子織などでもよい。さらに、抗菌布400は、二重織のように2枚の織物を重ねたようなものでもよい。 The antibacterial cloth 400 is not limited to the woven fabric structure. The antibacterial cloth 400 is not limited to the plain weave as shown in FIG. 4 (A), and may be a twill weave or a satin weave. Further, the antibacterial cloth 400 may be made by stacking two woven fabrics like a double weave.
 複数の第1の繊維11は、複数の非帯電繊維43との間で摩擦を生じる。複数の第2の繊維12は、複数の非帯電繊維43との間で摩擦を生じる。また、第1の繊維11は、隣り合う第2の繊維12に接触して摩擦される。第2の繊維12は、隣り合う第1の繊維11に接触して摩擦される。さらに、第1の繊維11は、抗菌布400以外の物に接触して摩擦される。第2の繊維12は、抗菌布400以外の物に接触して摩擦される。 The plurality of first fibers 11 cause friction with the plurality of uncharged fibers 43. The plurality of second fibers 12 cause friction with the plurality of uncharged fibers 43. Further, the first fiber 11 comes into contact with the adjacent second fiber 12 and is rubbed. The second fiber 12 comes into contact with the adjacent first fiber 11 and is rubbed. Further, the first fiber 11 comes into contact with an object other than the antibacterial cloth 400 and is rubbed. The second fiber 12 comes into contact with an object other than the antibacterial cloth 400 and is rubbed.
 第1の繊維11は、摩擦されると正に帯電する。第2の繊維12は、摩擦されると負に帯電する。非帯電繊維43は、摩擦されても帯電しない。図4(B)に示すように、第1の繊維11及び第2の繊維12は、互いの電位差によって電場を生じる。従って、抗菌布400は電場を生じ、抗菌性を発揮する。 The first fiber 11 is positively charged when rubbed. The second fiber 12 is negatively charged when rubbed. The non-charged fiber 43 is not charged even when rubbed. As shown in FIG. 4B, the first fiber 11 and the second fiber 12 generate an electric field due to a potential difference between them. Therefore, the antibacterial cloth 400 generates an electric field and exhibits antibacterial properties.
 なお、抗菌布400は、複数の第1の繊維11及び第2の繊維12のみからなる織物であってもよい。例えば、第1の繊維11は抗菌布400の経糸であり、第2の繊維12は抗菌布400の緯糸である。又は、第1の繊維11は抗菌布400の緯糸であり、第2の繊維12は抗菌布400の経糸であってもよい。さらに、第1の繊維11は、抗菌布400の経糸及び緯糸の両方に含まれていてもよい。また、第2の繊維12は、抗菌布400の経糸及び緯糸の両方に含まれていてもよい。これらの場合、複数の第1の繊維11及び複数の第2の繊維12が互いに摩擦されて、それぞれ帯電する。このため、抗菌布400は、より広い範囲で電荷を生じるため、高い抗菌性を発揮する。 The antibacterial cloth 400 may be a woven fabric composed of only a plurality of first fibers 11 and second fibers 12. For example, the first fiber 11 is the warp of the antibacterial cloth 400, and the second fiber 12 is the weft of the antibacterial cloth 400. Alternatively, the first fiber 11 may be the weft of the antibacterial cloth 400, and the second fiber 12 may be the warp of the antibacterial cloth 400. Further, the first fiber 11 may be contained in both the warp and the weft of the antibacterial cloth 400. Further, the second fiber 12 may be contained in both the warp and the weft of the antibacterial cloth 400. In these cases, the plurality of first fibers 11 and the plurality of second fibers 12 are rubbed against each other and charged respectively. Therefore, the antibacterial cloth 400 generates electric charges in a wider range, and thus exhibits high antibacterial properties.
 以下、第5実施形態に係る抗菌布500について説明する。図5(A)は、抗菌布500の構成を説明するための一部拡大図であり、図5(B)は、抗菌布500を図5(A)のV-V線で切断した断面図である。抗菌布500の説明においては、第4実施形態と異なる点についてのみ説明を行い、同様の点については説明を省略する。 Hereinafter, the antibacterial cloth 500 according to the fifth embodiment will be described. FIG. 5 (A) is a partially enlarged view for explaining the configuration of the antibacterial cloth 500, and FIG. 5 (B) is a cross-sectional view of the antibacterial cloth 500 cut along the line VV of FIG. 5 (A). Is. In the description of the antibacterial cloth 500, only the points different from the fourth embodiment will be described, and the same points will be omitted.
 図5(A)に示すように、抗菌布500は、第1の繊維11及び第2の繊維12を備える。抗菌布500は、第1の繊維11及び第2の繊維12からなる平編みの編物である。第1の繊維11は、コース毎に第2の繊維12と交互に編み込まれている。第2の繊維12は、第1の繊維11と交互に近接して配置されている。これにより、複数の第1の繊維11は、複数の第2の繊維12とそれぞれ絡み合っている。なお、抗菌布500は、第1の繊維11及び第2の繊維12以外にも摩擦によって帯電しない不図示の非帯電繊維を備えていてもよい。ただしこの場合でも、第2の繊維12は、第1の繊維11と近接して配置されている。 As shown in FIG. 5A, the antibacterial cloth 500 includes a first fiber 11 and a second fiber 12. The antibacterial cloth 500 is a flat knitted fabric composed of the first fiber 11 and the second fiber 12. The first fiber 11 is woven alternately with the second fiber 12 for each course. The second fiber 12 is arranged alternately in close proximity to the first fiber 11. As a result, the plurality of first fibers 11 are intertwined with the plurality of second fibers 12, respectively. The antibacterial cloth 500 may include non-charged fibers (not shown) that are not charged by friction in addition to the first fibers 11 and the second fibers 12. However, even in this case, the second fiber 12 is arranged close to the first fiber 11.
 第1の繊維11は、第2の繊維12と接触したり、離れたりする。従って、第1の繊維11は、第2の繊維12との間で摩擦を生じる。また、第1の繊維11は、第2の繊維12以外の物に接触して摩擦される。第2の繊維12は、第1の繊維11以外の物に接触して摩擦される。 The first fiber 11 comes into contact with or separates from the second fiber 12. Therefore, the first fiber 11 causes friction with the second fiber 12. Further, the first fiber 11 comes into contact with an object other than the second fiber 12 and is rubbed. The second fiber 12 comes into contact with an object other than the first fiber 11 and is rubbed.
 第1の繊維11は、摩擦されると正に帯電する。第2の繊維12は、摩擦されると負に帯電する。図5(B)に示すように、第1の繊維11及び第2の繊維12は、互いの電位差によって電場を生じる。従って、抗菌布500は電場を生じ、抗菌性を発揮する。 The first fiber 11 is positively charged when rubbed. The second fiber 12 is negatively charged when rubbed. As shown in FIG. 5B, the first fiber 11 and the second fiber 12 generate an electric field due to a potential difference between them. Therefore, the antibacterial cloth 500 generates an electric field and exhibits antibacterial properties.
 以下、第6実施形態に係る抗菌布600について説明する。図6(A)は、抗菌布600の構成を説明するための一部断面拡大図である。抗菌布600の説明においては、第4実施形態と異なる点についてのみ説明を行い、同様の点については説明を省略する。 Hereinafter, the antibacterial cloth 600 according to the sixth embodiment will be described. FIG. 6A is a partially enlarged cross-sectional view for explaining the configuration of the antibacterial cloth 600. In the description of the antibacterial cloth 600, only the points different from the fourth embodiment will be described, and the same points will be omitted.
 図6(A)に示すように、抗菌布600は、第1のシート61と、第2のシート62と、を備える。第1のシート61は、複数の第1の繊維11を備える。第2のシート62は、複数の第2の繊維12を備える。なお、第1のシート61及び第2のシート62は、抗菌布400に示すような織物組織に限定されず、抗菌布500に示すような編み物であってもよい。 As shown in FIG. 6A, the antibacterial cloth 600 includes a first sheet 61 and a second sheet 62. The first sheet 61 includes a plurality of first fibers 11. The second sheet 62 includes a plurality of second fibers 12. The first sheet 61 and the second sheet 62 are not limited to the woven fabric structure shown in the antibacterial cloth 400, and may be knitted as shown in the antibacterial cloth 500.
 第1のシート61は、平面視で第2のシート62と平行に重なるように配置されている。これにより、第1のシート61に含まれる第1の繊維11と第2のシート62に含まれる第2の繊維12は、対面して配置されている。第1のシート61に含まれる第1の繊維11と第2のシート62に含まれる第2の繊維12との距離Lは、50cm未満であることが好ましい。る第1の繊維11と第2の繊維12との距離Lが近ければ近いほど、第1の繊維11と第2の繊維12との間で生じる電場は大きくなり、菌にかかる電位差(又は電圧)も高くなるため、抗菌布600は、より高い抗菌性を発現することができる。 The first sheet 61 is arranged so as to overlap parallel to the second sheet 62 in a plan view. As a result, the first fiber 11 contained in the first sheet 61 and the second fiber 12 contained in the second sheet 62 are arranged to face each other. The distance L between the first fiber 11 contained in the first sheet 61 and the second fiber 12 contained in the second sheet 62 is preferably less than 50 cm. The closer the distance L between the first fiber 11 and the second fiber 12 is, the larger the electric field generated between the first fiber 11 and the second fiber 12, and the potential difference (or voltage) applied to the fungus. ) Is also high, so that the antibacterial cloth 600 can exhibit higher antibacterial properties.
 なお、第1のシート61及び第2のシート62は、互いに擦れ合う面を有する配置であればよく、互いに平面視で平行に重なる構造には限定されない。以下、抗菌布600の変形例について説明する。 The first sheet 61 and the second sheet 62 may be arranged so as to have surfaces that rub against each other, and are not limited to a structure in which they overlap each other in parallel in a plan view. Hereinafter, a modified example of the antibacterial cloth 600 will be described.
 図6(B)は、抗菌布600の変形例に係る抗菌布601の構成を説明するための一部断面拡大図である。図6(C)は、抗菌布600の変形例に係る抗菌布602の構成を説明するための一部断面拡大図である。抗菌布601及び抗菌布602の説明においては、抗菌布600と異なる点についてのみ説明を行い、同様の点については説明を省略する。 FIG. 6B is a partially enlarged cross-sectional view for explaining the configuration of the antibacterial cloth 601 according to the modified example of the antibacterial cloth 600. FIG. 6C is a partially enlarged cross-sectional view for explaining the configuration of the antibacterial cloth 602 according to the modified example of the antibacterial cloth 600. In the description of the antibacterial cloth 601 and the antibacterial cloth 602, only the points different from the antibacterial cloth 600 will be described, and the same points will be omitted.
 図6(B)に示すように、抗菌布601は、第1のシート61と、第2のシート62と、を備える。第1のシート61及び第2のシート62は、互いに向かい合うように配置され、第1のシート61及び第2のシート62全体として円筒状に形成されている。第1のシート61及び第2のシート62の接続部分64は互いに縫い合わされている。第1のシート61及び第2のシート62は、第1のシート61及び第2のシート62の間に空間63を有する。これにより、抗菌布601は、第1のシート61及び第2のシート62の間の空間63で電場を生じ、抗菌性を発現することができる。 As shown in FIG. 6B, the antibacterial cloth 601 includes a first sheet 61 and a second sheet 62. The first sheet 61 and the second sheet 62 are arranged so as to face each other, and the first sheet 61 and the second sheet 62 as a whole are formed in a cylindrical shape. The connecting portion 64 of the first sheet 61 and the second sheet 62 is sewn together. The first sheet 61 and the second sheet 62 have a space 63 between the first sheet 61 and the second sheet 62. As a result, the antibacterial cloth 601 can exhibit antibacterial properties by generating an electric field in the space 63 between the first sheet 61 and the second sheet 62.
 図6(C)に示すように、抗菌布602は、第1のシート61と、第2のシート62と、を備える。第1のシート61及び第2のシート62は、それぞれ円筒状に形成されている。第1のシート61の内径は、第2のシート62の外形より大きい。第1のシート61は、第2のシート62を覆うように配置されている。第1のシート61及び第2のシート62は、第1のシート61及び第2のシート62の間に空間65を有する。これにより、抗菌布602は、第1のシート61及び第2のシート62の間の空間65で電場を生じ、抗菌性を発現することができる。 As shown in FIG. 6C, the antibacterial cloth 602 includes a first sheet 61 and a second sheet 62. The first sheet 61 and the second sheet 62 are each formed in a cylindrical shape. The inner diameter of the first sheet 61 is larger than the outer diameter of the second sheet 62. The first sheet 61 is arranged so as to cover the second sheet 62. The first sheet 61 and the second sheet 62 have a space 65 between the first sheet 61 and the second sheet 62. As a result, the antibacterial cloth 602 can exhibit antibacterial properties by generating an electric field in the space 65 between the first sheet 61 and the second sheet 62.
 なお、抗菌布400、抗菌布500、又は抗菌布600は、織物又は編物に限定されない。例えば、抗菌布400、抗菌布500、又は抗菌布600は、不織布であってもよい。 The antibacterial cloth 400, the antibacterial cloth 500, or the antibacterial cloth 600 is not limited to woven fabrics or knitted fabrics. For example, the antibacterial cloth 400, the antibacterial cloth 500, or the antibacterial cloth 600 may be a non-woven fabric.
 以上の様な、抗菌糸100、抗菌糸200、抗菌糸300、抗菌布400、抗菌布500、又は抗菌布600は、各種の衣料、又は医療部材等の製品に適用可能である。例えば、抗菌糸100、抗菌糸200、抗菌糸300、抗菌布400、抗菌布500、又は抗菌布600は、マスク、手袋、衣類、肌着(特に靴下、腹巻)、タオル、ヘッドバンド、リストバンド、スポーツウェア全般、帽子、寝具(布団、マットレス、シーツ、枕、枕カバー等を含む。)、浄水器、エアコン又は空気清浄器のフィルタ等、ペット関連商品(ペット用マット、ペット用服、ペット用服のインナー)、各種マット品(足、手、又は便座等)、トートバッグ等の袋類、洗濯ネット、蜜柑のネット等の包装資材、シート(車、電車又は飛行機等のシート)、ソファカバー、包帯、ガーゼ、縫合糸、医者及び患者の服、サポータ、サニタリ用品、スポーツ用品(ウェア及びグローブのインナー、又は武道で使用する籠手等)、あるいは人工血管や手術用の医療部材等に適用することができる。 The antibacterial thread 100, the antibacterial thread 200, the antibacterial thread 300, the antibacterial cloth 400, the antibacterial cloth 500, or the antibacterial cloth 600 as described above can be applied to various clothing or products such as medical members. For example, the antibacterial thread 100, the antibacterial thread 200, the antibacterial thread 300, the antibacterial cloth 400, the antibacterial cloth 500, or the antibacterial cloth 600 includes masks, gloves, clothing, underwear (particularly socks, belly band), towels, headbands, wristbands, etc. Sportswear in general, hats, bedding (including cloth, mattresses, sheets, pillows, pillowcases, etc.), water purifiers, air conditioner or air purifier filters, and other pet-related products (pet mats, pet clothes, pets, etc.) Inner clothes), various mats (feet, hands, toilet seats, etc.), bags such as tote bags, laundry nets, packaging materials such as tangerine nets, seats (seats for cars, trains, airplanes, etc.), sofa covers , Bandages, gauze, sutures, clothes for doctors and patients, supporters, sanitary goods, sports goods (inners for clothing and gloves, baskets used in martial arts, etc.), artificial blood vessels, medical parts for surgery, etc. can do.
 最後に、本実施形態の説明は、すべての点で例示であって、制限的なものではないと考えられるべきである。本発明の範囲は、上述の実施形態ではなく、特許請求の範囲によって示される。さらに、本発明の範囲には、特許請求の範囲と均等の意味及び範囲内でのすべての変更が含まれることが意図される。 Finally, the description of this embodiment should be considered to be exemplary in all respects and not restrictive. The scope of the present invention is shown not by the above-described embodiment but by the scope of claims. Furthermore, the scope of the present invention is intended to include all modifications within the meaning and scope equivalent to the claims.
11,21,31…第1の繊維
12,22,32…第2の繊維
100,200,300…抗菌糸
400,500…抗菌布
11,21,31 ... 1st fiber 12,22,32 ... 2nd fiber 100,200,300 ... Antibacterial thread 400,500 ... Antibacterial cloth

Claims (10)

  1.  第1の繊維を含む第1のシートと、
     前記第1の繊維に対面して配置され、帯電列において前記第1の繊維より下位である素材からなる第2の繊維を含む第2のシートと、
     を備え、
     前記第1の繊維及び前記第2の繊維の少なくともいずれか一方は、摩擦又は近接剥離により帯電し、
     前記第1の繊維と前記第2の繊維との距離が50cm未満である、抗菌布。
    The first sheet containing the first fiber and
    A second sheet, which is arranged facing the first fiber and contains a second fiber made of a material lower than the first fiber in the charged row,
    With
    At least one of the first fiber and the second fiber is charged by friction or close peeling, and is charged.
    An antibacterial cloth in which the distance between the first fiber and the second fiber is less than 50 cm.
  2.  前記第1のシート及び前記第2のシートは、円筒状に形成され、重ね合わされ、又は縫い合わされて、互いに擦れ合う面を有する、
     請求項1に記載の抗菌布。
    The first sheet and the second sheet are formed in a cylindrical shape, are overlapped or sewn together, and have surfaces that rub against each other.
    The antibacterial cloth according to claim 1.
  3.  前記第1の繊維は圧電体からなり、
     前記第2の繊維は圧電体からなり、前記第1の繊維より帯電列の下位の材料を含む、
     請求項1又は2に記載の抗菌布。
    The first fiber is made of a piezoelectric material.
    The second fiber is made of a piezoelectric material and contains a material lower in the charging column than the first fiber.
    The antibacterial cloth according to claim 1 or 2.
  4.  前記第1の繊維は外力により正の電荷を発生し、
     前記第2の繊維は外力により負の電荷を発生する、
     請求項1乃至請求項3のいずれかに記載の抗菌布。
    The first fiber generates a positive charge due to an external force,
    The second fiber generates a negative charge due to an external force.
    The antibacterial cloth according to any one of claims 1 to 3.
  5.  前記第1の繊維又は前記第2の繊維は、長繊維である、
     請求項1乃至請求項4のいずれかに記載の抗菌布。
    The first fiber or the second fiber is a long fiber.
    The antibacterial cloth according to any one of claims 1 to 4.
  6.  前記第1の繊維及び前記第2の繊維は、長繊維である、
     請求項5に記載の抗菌布。
    The first fiber and the second fiber are long fibers.
    The antibacterial cloth according to claim 5.
  7.  前記第1の繊維又は前記第2の繊維は、短繊維である、
     請求項1乃至請求項4のいずれかに記載の抗菌布。
    The first fiber or the second fiber is a short fiber.
    The antibacterial cloth according to any one of claims 1 to 4.
  8.  前記第1の繊維及び前記第2の繊維は、短繊維である、
     請求項7に記載の抗菌布。
    The first fiber and the second fiber are short fibers.
    The antibacterial cloth according to claim 7.
  9.  前記第1の繊維又は前記第2の繊維が、コース毎に配置された編物である、
     請求項1乃至請求項8のいずれかに記載の抗菌布。
    The first fiber or the second fiber is a knitted material arranged for each course.
    The antibacterial cloth according to any one of claims 1 to 8.
  10.  前記第1の繊維又は前記第2の繊維が、経糸又は緯糸の少なくとも一方に配置された、
     請求項1乃至請求項8のいずれかに記載の抗菌布。
    The first fiber or the second fiber is arranged on at least one of the warp and the weft.
    The antibacterial cloth according to any one of claims 1 to 8.
PCT/JP2020/046841 2019-12-20 2020-12-16 Antibacterial fabric WO2021125194A1 (en)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003048264A (en) * 2001-05-29 2003-02-18 Toray Ind Inc Fiber structure
WO2018068100A1 (en) * 2016-10-14 2018-04-19 Commonwealth Scientific And Industrial Research Organisation Antimicrobial triboelectric material
CN108796755A (en) * 2017-05-02 2018-11-13 北京纳米能源与系统研究所 Power generation cloth based on electrostatic friction effect and power generation clothing
WO2019239867A1 (en) * 2018-06-12 2019-12-19 花王株式会社 Piezoelectric fiber composite body and piezoelectric garment

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003048264A (en) * 2001-05-29 2003-02-18 Toray Ind Inc Fiber structure
WO2018068100A1 (en) * 2016-10-14 2018-04-19 Commonwealth Scientific And Industrial Research Organisation Antimicrobial triboelectric material
CN108796755A (en) * 2017-05-02 2018-11-13 北京纳米能源与系统研究所 Power generation cloth based on electrostatic friction effect and power generation clothing
WO2019239867A1 (en) * 2018-06-12 2019-12-19 花王株式会社 Piezoelectric fiber composite body and piezoelectric garment

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