WO2021090742A1

WO2021090742A1 - Aerosol for metered spraying for space treatment

Info

Publication number: WO2021090742A1
Application number: PCT/JP2020/040410
Authority: WO
Inventors: 悠耶原田; 洋子小林; 由美川尻; 中山　幸治
Original assignee: 大日本除蟲菊株式会社
Priority date: 2019-11-08
Filing date: 2020-10-28
Publication date: 2021-05-14
Also published as: JPWO2021090742A1; JP7427009B2; TW202126171A; TWI772949B; CN114599226A; CN114599226B; JP2022103175A

Abstract

Provided is an aerosol for metered spraying for space treatment, the aerosol enabling a chemical to be uniformly diffused when used in space treatment for pests, in particular, crawling pests and indoor dust mites as pests to be controlled and being able to suppress the occurrence of spraying failure.　The aerosol 100 for metered spraying for space treatment is provided with: a pressure-resistant container 10 in which an aerosol undiluted liquid containing a pest control component and a propellant are sealed and that is provided with a metered spraying valve 12; an actuator 20 provided with a spraying port 21; and a dip tube 30. The leading end 30a of the dip tube 30 is positioned at a height of 6 mm or less from the lowest portion B of the pressure-resistant container 10. When the pressure-resistant container 10 is placed on a horizontal surface H, a spraying axis O of the spraying port 21 forms an elevation angle D of 10-60° with respect to the horizontal surface H.

Description

Fixed-quantity injection aerosol for spatial treatment

The present invention relates to a pressure-resistant container provided with a fixed-quantity injection valve, an actuator provided with an injection port connected to the fixed-quantity injection valve, and a dip tube.

The fixed-quantity injection aerosol that can spray a certain amount of chemicals by one injection is a fixed-quantity injection aerosol for coating that locally treats gaps, etc., a fixed-quantity injection aerosol for direct impact that directly injects into an object, and a space. It is classified as a quantitative injection aerosol for spatial treatment where the drug spreads.

For example, there is an extremely useful quantitative injection aerosol for spatial treatment (see Patent Document 1) that is effective not only for crawling pests and indoor dust mites but also for flying pests on the day of spraying. Based on the recognition that the quantitative injection aerosol for spatial treatment is efficient in easily treating the entire room with the drug, the present inventors have conducted various studies to improve the injection efficiency and efficacy of the drug. As a result, it was found that the quantitative injection aerosol for spatial treatment improves the diffusivity of the drug by spraying the drug diagonally upward with respect to the horizontal plane.

Japanese Patent No. 5517122

In order to use a quantitative injection aerosol for spatial treatment having an actuator provided with an injection port in the horizontal direction or (2) diagonally upward, the injection shaft of the injection port is to be sprayed diagonally upward with respect to the horizontal plane. There is a usage method in which the aerosol can is tilted diagonally with respect to the horizontal plane so that the aerosol can be directed diagonally upward.

However, with conventional products, injection defects may occur in such a usage method. In Patent Document 1, it is not recognized that injection defects may occur when spraying diagonally upward, and no countermeasure is taken for such a problem.

The present invention has been made in view of the above problems, and it is possible to uniformly diffuse the chemicals in the spatial treatment method for pests, particularly crawling pests and indoor dust mites, and the occurrence of injection defects. It is an object of the present invention to provide a quantitative injection aerosol for spatial treatment capable of suppressing.

The characteristic configuration of the quantitative injection aerosol for spatial treatment according to the present invention for solving the above problems is
A pressure-resistant container provided with a fixed-quantity injection valve in which an aerosol stock solution containing a control component and a propellant are sealed, an actuator provided with an injection port connected to the fixed-quantity injection valve, the aerosol stock solution and the propellant. A fixed-quantity injection aerosol for spatial treatment provided with a dip tube for supplying the fixed-quantity injection valve.
The tip of the dip tube is located at a height of 6 mm or less from the bottom of the pressure resistant container.
When the pressure-resistant container is placed on a horizontal plane, the injection shaft of the injection port is to form an elevation angle of 10 to 60 ° with respect to the horizontal plane.

The present inventor has conducted various studies on the injection direction of the quantitative injection aerosol for spatial treatment, and found that when the chemical is sprayed on the horizontal plane toward an obliquely upward direction of 30 to 60 °, the chemical is applied to the treatment space. It was found that the diffusion becomes uniform and the treatment can be performed efficiently.
According to the spatial treatment quantitative injection aerosol of this configuration, when the tip of the dip tube of the spatial treatment quantitative injection aerosol is located at a height of 6 mm or less from the bottom of the pressure-resistant container and the pressure-resistant container is placed on a horizontal surface. By making the injection shaft of the injection port an elevation angle of 10 to 60 ° with respect to the horizontal plane, the control component suitable for controlling pests is set so that the injection shaft of the injection port is 30 to 60 ° with respect to the horizontal plane. When injecting, it is possible to suppress the occurrence of injection defects. In this case, even when the pressure-resistant container is sprayed at a slight angle with respect to the horizontal plane, the tip of the dip tube is located at a height of 6 mm or less from the bottom of the pressure-resistant container, so that the aerosol stock solution and the propellant are quantitatively sprayed. Since it is reliably supplied to the valve, the injection state can be maintained well.

In the quantitative injection aerosol for spatial treatment according to the present invention.
The control component preferably contains a non-volatile control component having a vapor pressure of less than ^{1 × 10 -4 mmHg at 30 ° C.}

According to the quantitative injection aerosol for spatial treatment of this configuration, crawling pests and indoor dust mites can be suitably controlled.

In the quantitative injection aerosol for spatial treatment according to the present invention.
The control component preferably contains a volatilization control component having a vapor pressure of 2 × 10 ^-4 to 1 × 10 ^{−2 mmHg at 30 ° C.}

According to the quantitative injection aerosol for spatial treatment of this configuration, flying pests can be suitably controlled, and in addition, crawling pests and indoor dust mites can also be controlled.

In the quantitative injection aerosol for spatial treatment according to the present invention.
The control components are ^{a refractory control component having a vapor pressure of less than 1 × 10 -4} mmHg at 30 ° C. and a volatilization control component having a vapor pressure of 2 × 10 ^-4 to 1 × 10 ⁻² mmHg at 30 ° C. It is preferable to contain an ingredient.

According to the quantitative injection aerosol for spatial treatment of this configuration, flying pests, crawling pests and indoor dust mites can be controlled at the same time.

In the quantitative injection aerosol for spatial treatment according to the present invention.
The injection shaft of the injection port preferably has an elevation angle of 15 to 50 ° with respect to the horizontal plane.

According to the spatial treatment quantitative injection aerosol of the present configuration, the injection shaft of the injection port of the spatial treatment quantitative injection aerosol forms an elevation angle of 15 to 50 ° with respect to the horizontal plane, so that the injection port is injected with respect to the horizontal plane. When the shaft is injected so as to be 30 to 60 °, the angle at which the pressure-resistant container is tilted is suppressed, so that the occurrence of injection defects is suppressed and a stable injection state can be maintained.

In the quantitative injection aerosol for spatial treatment according to the present invention.
The tip of the dip tube is preferably located at a height of 3 mm or less from the bottom of the pressure resistant container.

According to the quantitative injection aerosol for spatial treatment of this configuration, when the tip of the dip tube is located at a height of 3 mm or less from the bottom of the pressure-resistant container, the pressure-resistant container is injected at a slight angle with respect to the horizontal plane. However, the aerosol stock solution and the propellant can be reliably supplied to the fixed-quantity injection valve, and the occurrence of injection defects can be suppressed.

In the quantitative injection aerosol for spatial treatment according to the present invention.
It is preferable that the injection force at an injection distance of 5 cm is set to 5 to 50 gf.

According to the quantitative injection aerosol for spatial treatment of the present configuration, since the injection force at an injection distance of 5 cm is set to 5 to 50 gf, the injected aerosol stock solution is subjected to an exposed surface in the treatment space (for example, in the treatment space). (Floor surface, wall surface, surface of structures such as furniture, etc.), especially the entire floor surface, which is uniformly settled and adhered to, and is practically sufficient for controlling flying pests, pests, and indoor dust mites. It can be effective.

In the quantitative injection aerosol for spatial treatment according to the present invention.
The dip tube is preferably configured to be bendable inside the pressure resistant container.

According to the quantitative injection aerosol for spatial treatment of this configuration, the dip tube is configured to be bendable inside the pressure-resistant container. Therefore, by appropriately bending the dip tube, the tip thereof can be positioned at an appropriate position in the pressure-resistant container. Can be easily placed in.

FIG. 1 is a cross-sectional view of a quantitative injection aerosol for spatial treatment according to the present invention. FIG. 2 is an explanatory diagram showing (a) an elevation angle of an injection port (injection shaft) and (b) an injection direction in a quantitative injection aerosol for spatial processing. FIG. 3 is an enlarged cross-sectional view of the tip of the dip tube of the quantitative injection aerosol for spatial treatment.

Hereinafter, the quantitative injection aerosol for spatial treatment of the present invention will be described. However, the present invention is not intended to be limited to the configurations and examples described in the embodiments described below.

FIG. 1 is a cross-sectional view of the quantitative injection aerosol 100 for spatial treatment of the present invention. The fixed-quantity injection aerosol 100 for space treatment is provided with a pressure-resistant container 10 provided with a fixed-quantity injection valve 12 in which an aerosol stock solution containing a control component and a propellant are sealed, and an injection port 21 connected to the fixed-quantity injection valve 12. The actuator 20 is provided with a dip tube 30 that supplies the aerosol stock solution and the propellant to the metering valve 12, and by spatial treatment, flying pests such as mosquitoes and flies, pests such as cockroaches, indoor dust mites, etc. It is used to control pests.

[Pressure-resistant container]
The pressure-resistant container 10 includes a storage unit 11 in which the aerosol stock solution and the propellant are stored, and a fixed-quantity injection valve 12 assembled at the mouth of the storage unit 11. The storage portion 11 has a bottomed cylindrical shape or a bottomed substantially cylindrical shape, and is formed of a resin such as polyethylene terephthalate or a metal such as aluminum or tin. The appearance of the storage unit 11 may be transparent, translucent, or opaque. The shape of the bottom may be upright, and examples thereof include a flat shape, a concave shape, and five petal-like shapes. It is preferable that the outer surface of the storage portion 11 is provided with a display for the user to recognize that the dip tube 30 is curved and the opposite side in the direction toward the tip 30a is the front surface. For example, it is used that the dip tube 30 is curved and the opposite side in the direction toward the tip 30a is the front side because a display indicating the front direction F is printed at the position P on the outer surface of the storage unit 11. Can be recognized by others. The display indicating the front direction F can be, for example, a character or a design, but if the design matches the pattern printed on the actuator 20 when the injection port 21 is directed to the front direction F, the display can be used. The user can be made to recognize the front direction F without impairing the design. Here, the front direction F is a direction in which the injection port 21 is preferably directed at the time of use, and is a direction opposite to the bending direction of the dip tube 30 described later. By directing the injection port 21 toward the front direction F indicated by the display P, the pressure-resistant container 10 is tilted slightly upward with respect to the horizontal plane H even when the amount of inclusions is small in the later stage of use of the spatial treatment quantitative injection aerosol 100. Then, the aerosol stock solution and the propellant will be accumulated in the vicinity of the tip 30a of the dip tube 30. As a result, when the quantitative injection aerosol 100 for spatial treatment is injected, the aerosol stock solution and the propellant are sucked up well by the dip tube 30, and the occurrence of injection defects can be suppressed. Here, "injection failure" means a state in which the capacity actually injected by one operation of the actuator 20 is less than 85% of the injection capacity of the fixed quantity injection valve 12. When the storage unit 11 is made of a transparent or translucent resin, it is preferable that the storage unit 11 is further printed with a horizontal display such as a border pattern. The horizontal display is provided to prevent excessive tilting that causes injection failure when the quantitative injection aerosol 100 for spatial treatment is injected. With such a horizontal display, the user psychologically tries to adjust the liquid level of the aerosol stock solution inside the storage unit 11 to the horizontal display, so that the quantitative injection aerosol 100 for spatial treatment is used in an appropriate posture. be able to.

The fixed-quantity injection valve 12 is attached to the mouth of the storage unit 11, is connected to the actuator 20 on the outside of the pressure-resistant container 10, and is connected to the dip tube 30 on the inside of the pressure-resistant container 10. The metering-quantity injection valve 12 has a valve mechanism (not shown), and is usually set so that the injection capacity per injection is 0.2 to 5.0 mL.

[Actuator]
The actuator 20 is an operating unit for injecting the aerosol stock solution, and the actuator 20 is provided with an injection port 21 which is connected to the metering injection valve 12 and ejects the aerosol stock solution from the pressure resistant container 10 to the outside. Here, the angle of the injection port 21 will be described. FIG. 2 is an explanatory diagram showing (a) an elevation angle of an injection port (injection shaft) and (b) an injection direction in the quantitative injection aerosol 100 for spatial processing. In the present invention, the angle of the injection shaft O of the injection port with respect to the horizontal plane H when the pressure-resistant container 10 is placed on the horizontal plane H is defined as an elevation angle D (FIG. 2A), and the quantitative injection aerosol 100 for spatial treatment is actually used. The angle of the injection shaft O of the injection port with respect to the horizontal plane H when the aerosol stock solution is injected toward the space is defined as the injection direction angle E (FIG. 2B). Therefore, the elevation angle D is basically an angle peculiar to the quantitative injection aerosol 100 for spatial processing, and the injection direction angle E is an angle that varies depending on the injection posture. In the present invention, when the pressure-resistant container 10 is placed on the horizontal plane H, the elevation angle D of the injection shaft O with respect to the horizontal plane H is set to 10 to 60 °, and is set to 15 to 50 °. Is preferable. When the elevation angle D is 10 to 60 °, the aerosol stock solution can be easily injected toward the vicinity of diagonally upward 30 to 60 ° (that is, the injection direction angle E is 30 to 60 °). When the elevation angle D is less than 10 °, it is necessary to excessively tilt the pressure-resistant container 10 in order to inject the aerosol stock solution obliquely upward to the vicinity of 30 to 60 ° with respect to the horizontal plane H, and thus the pressure-resistant container 10 is tilted. If the injection is performed at an excessive tilt, injection defects may occur. If the elevation angle D exceeds 60 °, the injected aerosol stock solution may adhere to the fingers or the like that operate the actuator 20. In FIG. 2, (a) the quantitative injection aerosol 100 for spatial treatment in which the elevation angle D is set to 60 °, and (b) the quantitative injection aerosol 100 for spatial treatment are tilted downward by 15 ° to set the injection direction angle E to 45. The state set to ° is illustrated.

The number, shape, and size of the injection ports 21 are not particularly limited. The number of injection ports 21 may be one or two or more, but from the viewpoint of being simple and inexpensive to manufacture, the number of injection ports 21 may be one. preferable. For nozzles or actuators having two injection ports, the perpendicular bisector of the line segment connecting the centers of each injection port 21 is the injection axis O, and for nozzles or actuators having three or more injection ports. The injection shaft O of the injection port 21 is defined as follows. If the injection port 21 is located in the center of the injection portion of the nozzle or actuator, the orthogonal line penetrating the center of the injection port 21 at the center is defined as the injection axis O. If the injection port 21 does not exist in the center of the injection portion of the nozzle or actuator, the orthogonal line penetrating the center of the polygonal circumscribed circle connecting the centers of the injection ports 21 is defined as the injection axis O.

The shape (cross-sectional shape) of the injection port 21 may be a circular shape, an elliptical shape, a polygonal shape, or any other irregular shape. The opening area of the injection port 21 is preferably 0.05 ~ 8.0 mm ^2, more preferably from 0.1 ~ 4.0 mm ^2, further to be 0.2 ~ 3.0 mm ² preferable. For example, when the number of injection ports 21 is one and the shape of the injection port 21 is circular, the size of the injection port 21 (injection port diameter) is preferably 0.3 mm or more, preferably 0.4 mm or more. It is more preferably present, and more preferably 0.6 mm or more. Further, the nozzle diameter is preferably 3.0 mm or less, more preferably 2.0 mm or less, and further preferably 1.8 mm or less.

The actuator 20 may have a nozzle or not. In the case of having a nozzle, the one with a protruding nozzle or the one with a non-protruding nozzle may be used, but the one with a protruding nozzle is preferable. In the case of an actuator with a nozzle, the length of the nozzle is not particularly limited, but is preferably 2.0 to 80 mm, more preferably 3.0 to 70 mm, and particularly preferably 4.0 to 60 mm. As the operation button in the actuator 20, a push-down type or trigger type button can be adopted.

[Dip tube]
The dip tube 30 is a hollow member made of a resin such as polyethylene or polypropylene attached to the fixed-quantity injection valve 12, and when the fixed-quantity injection valve 12 is operated, the aerosol stock solution and the propellant sealed in the pressure-resistant container 10 are quantified. It is supplied to the injection valve 12. Although the dip tube 30 itself has a linear shape, it can be curved when it is attached to the metering injection valve 12 and inserted into the pressure-resistant container 10. Therefore, by appropriately bending the dip tube, the tip 30a thereof can be easily arranged at an appropriate position in the pressure-resistant container 10. The tip 30a of the dip tube 30 is attached to the metering injection valve 12 so that the height h from the lowermost portion B of the pressure resistant container 10 is 6 mm or less, preferably 3 mm or less. Here, the lowermost portion B of the pressure-resistant container 10 is a portion of the inner surface of the pressure-resistant container 10 that is closest to the horizontal surface H when the pressure-resistant container 10 is placed on the horizontal surface H. Even when the bottom surface of the pressure-resistant container 10 has a dome shape as shown in FIG. 1, the aerosol stock solution sealed in the pressure-resistant container 10 exists at the bottom B until the end in the latter stage of use of the quantitative injection aerosol 100 for spatial treatment. Will be done. Therefore, since the tip 30a of the dip tube 30 is located at a position of 6 mm or less from the lowermost portion B of the pressure-resistant container 10, the tip 30a is the aerosol stock solution even when the pressure-resistant container 10 is sprayed at a slight angle with respect to the horizontal plane H. And because it is located below the liquid level of the propellant, the aerosol stock solution and the propellant can be reliably supplied to the fixed quantity injection valve 12. As a result, it is possible to suppress the occurrence of injection defects in the late use of the quantitative injection aerosol 100 for spatial treatment. When the height h of the tip 30a from the bottom B of the pressure-resistant container 10 exceeds 6 mm, the tip of the aerosol stock solution and the propellant tip from the liquid surface when the pressure-resistant container 10 is tilted slightly with respect to the horizontal plane H at the time of injection. 30a tends to be in a high position, and as a result, injection defects may occur. The dip tube 30 has a linear shape that extends in the downward vertical direction with one end attached to the fixed-quantity injection valve 12, and extends in the downward vertical direction with one end attached to the fixed-quantity injection valve 12, and is curved at the curved portion 30b. It is preferable that the shape is curved or the whole is curved. Among them, it is more preferable that the curved portion 30b has a curved shape or a curved shape as a whole so that the tip 30a is located near the inner side surface S of the pressure-resistant container 10. When the dip tube 30 has a curved shape at the curved portion 30b or a curved shape as a whole and the tip 30a is located in the vicinity of the inner side surface S of the pressure-resistant container 10, from the inner side surface S to the tip 30a of the pressure-resistant container 10. The distance d is set to be 25 mm or less, preferably 15 mm or less, more preferably 6 mm or less, still more preferably 3 mm or less. Since the distance d from the inner surface S to the tip 30a is 25 mm or less, the aerosol stock solution and the propellant in the vicinity of the inner surface S are surely secured even when the pressure-resistant container 10 is injected at an angle with respect to the horizontal plane H. It can be supplied to the fixed-quantity injection valve 12 to further suppress the occurrence of injection defects. The tip 30a of the dip tube 30 can be processed into various shapes. FIG. 3 is an enlarged cross-sectional view of the tip of the dip tube of the quantitative injection aerosol for spatial treatment, in which (a) an obliquely cut oblique end portion and (b) a U-shaped (concave) cut U end portion. , (C) The arc end portion cut into an arc shape (convex shape), and (d) the right angle end portion cut at a right angle are illustrated. Of these, (a) an obliquely cut oblique end portion, (b) a U-shaped cut U-end portion, or (c) an arc-shaped arc-shaped end portion are preferable. Since the tip 30a has these shapes, the aerosol stock solution and the propellant can be sucked up well, and the occurrence of injection defects can be further suppressed.

<Aerosol stock solution>
The aerosol stock solution contains (A) ^{a compound having a vapor pressure of less than 1 × 10 -4} mmHg at 30 ° C. (non-volatile control component) and (B) vapor at 30 ° C. Compounds having a pressure of 2 × 10 ^-4 to 1 × 10 ⁻² mmHg (volatile control component) or a mixture of (A) and (B) can be used. Hereinafter, an aerosol stock solution A containing a refractory control component and an aerosol stock solution B containing a volatilization control component will be described.

[Aerosol stock solution A]
As the non-volatile control component, which is one of the main components of the aerosol stock solution A, a compound for controlling mite pests typified by cockroaches, bed bugs, ants, etc., and / or mainly indoor dustiness A mite control compound for controlling mites can be used. Examples of the pest control compound include pyrethroid compounds such as phenothrin, ciphenothrin, permethrin, cypermethrin, cyfluthrin, bifenthrin, phenpropatrin, tralomethrin, etofenprox, and imiprothrin, silicon compounds such as silafluofen, and dichlorbos. , And organic phosphorus compounds such as fenitrothione, carbamate compounds such as propoxul, neonicotinoid compounds such as dinotefuran, imidacloprid, and clothianidin, fipronil, indoxacarb and the like. Among these, phenothrin, cyphenothrin, permethrin, cypermethrin, cyfluthrin, bifentrin, fenpropatrin, tralomethrin, etofenprox, and dinotefuran are preferable. If optical isomers or geometric isomers based on asymmetric carbon are present in the acid component or alcohol portion of the pyrethroid compound, each of them or any mixture thereof is also included in the pest control compound. Examples of the compound for controlling ticks include amidoflumeth, benzyl benzoate, phenyl salicylate, benzyl salicylate, dibutyl sebacate, dipropyl sebacate, dibutyl adipate, diethyl phthalate, dipropyl phthalate, dibutyl phthalate, and p-menthan-3. , 8-diol, 3-iodo-2-propynylbutyl carbamate, phenothrin, DEET and the like. Among these, amidoflumeth, benzyl benzoate, phenyl salicylate, benzyl salicylate, dibutyl sebacate, dipropyl sebacate, dibutyl adipate, diethyl phthalate, dibutyl phthalate, p-menthane-3,8-diol, phenothrin, and DEET. Is preferable. In the quantitative injection aerosol 100 for spatial treatment of the present invention, when a certain amount is injected in an indoor treatment space, the spray particles mainly settle on the floor surface as adhesive particles, but the treatment is carried out by containing a resistant volatilization control component. It shows excellent control effect especially against aerosol pests and indoor dust mites in space. Further, by including the refractory control component, the volatilization of the refractory control component from the adherent particles settled on the floor surface into the air is suppressed. Due to such a mechanism of action, the quantitative injection aerosol 100 for spatial treatment of the present invention is highly safe and can be used even in the presence of a person.

The content of the control component in the aerosol stock solution A is 1 to 90 w / v%, preferably 5 to 80 w / v%, and more preferably 30 to 75 w / v%. When the content of the control component in the aerosol stock solution A is within the above range, the control component is easily dissolved in the organic solvent, and when the aerosol is sprayed, the jet particles are formed in an optimum state.

The aerosol stock solution A contains an organic solvent in addition to the above-mentioned control components. As the organic solvent, an aerosol stock solution A can be prepared by dissolving the above-mentioned control component, and a solvent capable of forming optimum jet particles when the prepared aerosol stock solution A is sprayed is used. In the quantitative injection aerosol 100 for spatial treatment of the present invention, the organic solvent includes, for example, ethanol, a lower alcohol having 2 to 3 carbon atoms such as isopropanol (IPA), a normal paraffin, and a hydrocarbon solvent such as isoparaffin. , Isopropyl myristate (IPM), hexyl laurate and the like, higher fatty acid esters having 16 to 20 carbon atoms, glycol ether solvents having 3 to 10 carbon atoms, ketone solvents and the like. Among these, lower alcohols having 2 to 3 carbon atoms, hydrocarbon solvents, and higher fatty acid esters having 16 to 20 carbon atoms are preferable. In particular, lower alcohols having 2 to 3 carbon atoms have diffusion uniformity of spray particles and exposed surfaces in the treatment space (for example, floors and walls existing in the treatment space, surfaces of structures such as furniture), and the like. This is particularly preferable because it does not easily cause stickiness on the floor surface. It is also possible to use a mixture of two or more of the above organic solvents. Further, as the organic solvent, it is also possible to further mix glycol ethers, hydrocarbon solvents such as normal paraffin and isoparaffin, and ketone solvents.

The specific weight of the aerosol stock solution A is preferably 0.85 to 1.15, more preferably 0.89 to 1.10. When the specific gravity of the aerosol stock solution A is in the range of 0.85 to 1.15, when a fixed amount of the quantitative injection aerosol 100 for spatial treatment of the present invention is injected in an indoor treatment space, the spray particles are mainly used as adhesive particles on the floor. Since it settles and adheres to the surface, an appropriate control effect can be obtained. In addition, if the specific gravity of the aerosol stock solution A is within the above range, the adherent particles also enter gaps and shadows in the process of sedimentation. Therefore, when a pyrethroid compound is used as a control component, cockroaches and the like enter gaps. You can also expect a flushing effect that pops out of the shadows.

In addition to the above components, the aerosol stock solution A contains antifungal agents, antibacterial agents, bactericides, air fresheners, deodorants, stabilizers, antistatic agents, defoaming agents, and additives for fungi and fungi. A shaping agent or the like can be appropriately blended. Examples of fungicides, antibacterial agents and fungicides include hinokitiol, 2-mercaptobenzothiazole, 2- (4-thiazolin) benzimidazole, 5-chloro-2-methyl-4-isothiazolin-3-one, triphorin, 3- Examples thereof include methyl-4-isopropylphenol and ortho-phenylphenol. As fragrances, orange oil, lemon oil, lavender oil, peppermint oil, eucalyptus oil, citronella oil, lime oil, yuzu oil, jasmine oil, cypress oil, green tea essential oil, limonene, α-pinene, linalool, geraniol, Examples include aromatic components such as phenylethyl alcohol, amylcinnamic aldehyde, cumin aldehyde, and benzyl acetate, and fragrance components containing green leaf alcohol and green leaf aldehyde called "green scent".

[Aerosol stock solution B]
Volatile control components that are one of the main components of aerosol stock solution B include flying pests such as mosquitoes and flies, pests such as cockroaches, tokojirami, and ants, and pests such as indoor dust mites. Pest control compounds for controlling flies can be used. Examples of the pest control compound include metoflutrin, profluthrin, transfluthrin, empentrin, terraresrin, flamethrin and the like. Among these, metoflutrin, profluthrin, and transfluthrin are preferable in consideration of vapor pressure, stability, basal insecticidal efficacy, and the like. If optical isomers or geometric isomers based on asymmetric carbon are present in the acid component or alcohol moiety of these compounds, each or any mixture thereof is also included in the volatilization control component. When a fixed amount of the quantitative injection aerosol 100 for spatial treatment of the present invention is injected in an indoor treatment space, the spray particles containing the volatilizing control component are mainly as adhesive particles on an exposed surface in the treatment space (for example, in the treatment space). Excellent control effect against flying pests, pests and indoor dust mites in the treatment space where it settles and adheres to the floor surface, wall surface, surface of structures such as furniture, etc. Is shown.

The content of the control component in the aerosol stock solution B is 1 to 90 w / v%, preferably 5 to 80 w / v%, and more preferably 8 to 75 w / v%. When the content of the control component in the aerosol stock solution B is within the above range, the control component is easily dissolved in the organic solvent, and when the aerosol is sprayed, the jet particles are formed in an optimum state.

The aerosol stock solution B contains an organic solvent in addition to the above-mentioned control components. As the organic solvent, an aerosol stock solution B can be prepared by dissolving the above-mentioned control component, and a solvent capable of forming optimum jet particles when the prepared aerosol stock solution B is sprayed is used. The organic solvent that can be used in the aerosol stock solution B is the same as the organic solvent that can be used in the aerosol stock solution A described above.

The specific weight of the aerosol stock solution B is preferably 0.78 to 1.15, more preferably 0.82 to 1.10. When the specific gravity of the aerosol stock solution B is in the range of 0.78 to 1.15, when a fixed amount of the quantitative injection aerosol 100 for spatial treatment of the present invention is injected in an indoor processing space, the spray particles are mainly exposed as adhesive particles. Since it adheres uniformly to the surface, an appropriate control effect can be obtained.

In addition to the above components, the aerosol stock solution B contains antifungal agents, antibacterial agents, bactericides, air fresheners, deodorants, stabilizers, antistatic agents, defoaming agents, and additives for fungi and fungi. A shaping agent or the like can be appropriately blended. These additional components are the same as those added to the aerosol stock solution A described above.

[Mixture of aerosol stock solution A and aerosol stock solution B]
When a mixture of the above aerosol stock solution A and aerosol stock solution B is used as the aerosol stock solution (A + B), effective control against all flying pests, crawling pests, and indoor dust mites becomes possible, which is wider. It can be used for various purposes. That is, when a fixed amount of the quantitative injection aerosol 100 for spatial treatment of the present invention is injected in an indoor treatment space, the spray particles containing the volatilization control component derived from the aerosol stock solution B are mainly exposed as adhesive particles in the treatment space. Surfaces (for example, floors and walls existing in the treatment space, surfaces of structures such as furniture), especially the floor surface, settles and adheres, and in the treatment space, flying pests, pests and indoor dust mites Shows excellent control effect against. Here, a certain amount of the spray particles remains suspended in the air, but by including a volatilizing control component derived from the aerosol stock solution B as the control component, a control effect can be exerted against flying pests. Further, when the volatilization control component derived from the aerosol stock solution B adheres to a part of the floor surface or the wall surface together with the volatilization control component derived from the aerosol stock solution A, it has a control effect on crawling pests and / or indoor dust mites. Can be increased synergistically.

<Injector>
The propellant used in the quantitative injection aerosol 100 for spatial treatment of the present invention includes liquefied petroleum gas (LPG), dimethyl ether (DME), liquefied gas such as hydrofluoroolefin, and nitrogen gas, carbon dioxide gas, nitrogen borooxide, and the like. Examples thereof include compressed gas such as compressed air. The above propellant can be used alone or in a mixed state, but one containing LPG as a main component is easy to use.

In the quantitative injection aerosol 100 for spatial treatment of the present invention, the volume ratio (a / b) of the aerosol stock solution (a) and the propellant (b) filled in the pressure-resistant container 10 is 10/90 to 50/50 / by volume. It is preferably adjusted to 50. When the volume ratio (a / b) is within the above range, a sufficient amount of the control component can be uniformly diffused over the exposed surface, particularly the entire floor surface.

The quantitative injection aerosol 100 for spatial treatment of the present invention preferably has an injection force of 5 to 50 gf at a distance of 5 cm from the injection port 21. If the injection force is within the above range, the injected aerosol stock solution will be applied to exposed surfaces in the treatment space (for example, floors and walls existing in the treatment space, surfaces of structures such as furniture), especially the entire floor surface. It is uniformly settled and adhered to, and a practically sufficient control effect can be obtained against flying pests, pests and mites. If the injection force is less than 5 gf, the injection force tends to be insufficient and the diffusibility to the entire exposed surface tends to be insufficient. If the injection force exceeds 50 gf, good diffusivity of the injected aerosol stock solution may not be obtained. Such an injection force can be appropriately adjusted depending on the composition of the aerosol stock solution, the internal pressure of the pressure-resistant container 10, the shape of the injection port 21, and the like.

<Pests to be controlled>
The quantitative injection aerosol 100 for spatial treatment of the present invention includes mosquitoes such as bed bugs, bed bugs, bed bugs and bed bugs, flies such as bedbugs and bed bugs, flying insects such as bedbugs, bedbugs, bedbugs and moths. , Bed bugs such as Wamon Gokiburi, Kurogokiburi, Chabanegokiburi, Bed Bugs (Bed Bugs), Bed Bugs (Nettite Bed Bugs), Bed Bugs such as Kusagi Kamemushi, Black Mountain Ali, Amimeari, Tobiiro Keari In addition to ants, bedbugs, bedbugs, bedbugs, bedbugs, bed bugs, bed bugs, bed bugs, bedbugs, bedbugs, bedbugs, bedbugs, bedbugs, bedbugs, bedbugs, bedbugs, bedbugs, bedbugs, bedbugs, bedbugs, bedbugs, bedbugs, bedbugs Controls various pests such as bed bugs such as bed bugs, clothing pests such as bed bugs and bed bugs, bed bugs such as bed bugs, and indoor dust mites such as bed bugs, leopard mites, dust mites, cimex mites, and bedbug mites. Can be used for. In particular, bedbugs such as the American cockroach, black beetle, and chabanegokiburi, bed bugs such as bed bugs and bed bugs, bed bugs such as bed bugs, bed bugs, bed bugs, bed bugs, bed bugs, bed bugs, bed bugs, and bed bugs. It is effective in controlling bedbugs such as spiders such as sea turtle spiders and indoor dust mites such as bedbugs, bedbugs, bedbugs, bedbugs, bedbugs, and bed bugs. , Has an excellent control effect.

<Processing target>
The treatment target of the quantitative injection aerosol 100 for spatial treatment of the present invention is mainly an indoor space. The volume of the treatment space is not particularly limited, but the volume corresponding to a room of 4.5 to 16 tatami mats is 18.8 to 66.6 ^{m 3} (area 7.5 to 26.6 m ² and height 2.2 to 3. 0 m) is preferable, and the volume corresponding to a room of 4.5 to 8 tatami mats is 18.8 to 33.3 m ³ (area 7.5 to 13.3 m ² , height 2.2 to 3.0 m). Is more preferable. However, even in a larger indoor space or a smaller indoor space, the amount of control component released into the air of the indoor space is 0.1 to 50 mg / m ^{3 according to the volume of the indoor space.} By appropriately setting the number of injections, the injection capacity, and the like, the same control effect can be obtained regardless of the volume of the indoor space. The frequency of use of the quantitative injection aerosol for spatial treatment of the present invention may be applied so that the amount of the pest control component released is within the above range at an appropriate time according to the frequency of occurrence of pests and the situation.

Based on Examples 1 to 49 and Comparative Examples 1 to 7, the quantitative injection aerosol for spatial treatment of the present invention was examined in more detail. In order to confirm the effect of the quantitative injection aerosol for spatial treatment of the present invention, the quantitative injection aerosol for spatial treatment (Examples 1 to 49) having the characteristic configuration of the present invention was prepared and an injection test was carried out. Further, for comparison, quantitative injection aerosols for spatial treatment (Comparative Examples 1 to 7) having no characteristic configuration of the present invention were prepared, and the same effect confirmation test was carried out.

[Example 1]
Phenothrin (40 w / v%) was dissolved in ethanol as a resistant volatilization control component to prepare an aerosol stock solution A. 3.5 mL of this aerosol stock solution A and 5.3 mL of liquefied petroleum gas as a propellant were pressure-filled in a pressure-resistant container with a metering spray valve having an injection capacity of 0.4 mL. This filling amount can theoretically carry out quantitative injection up to 22 times. An actuator provided with an injection port so that the injection shaft forms an elevation angle (D) of 60 ° with respect to the horizontal plane when the pressure resistant container is placed on the horizontal plane is attached to the fixed-quantity spray valve of the pressure-resistant container. A fixed-quantity injection aerosol for spatial treatment was obtained. In the quantitative injection aerosol for spatial treatment of Example 1, a dip tube having a U-shaped tip is used, and the height (h) of the tip from the bottom of the pressure-resistant container is 1 mm in the pressure-resistant container. It was attached to the metering injection valve so as to be. The quantitative injection aerosol for spatial treatment of Example 1 had an injection force of 15 gf at an injection distance of 5 cm.

[Examples 2 to 24, Comparative Examples 1 to 5]
According to Example 1, various quantitative injection aerosols for spatial treatment of Examples 2 to 24 and Comparative Examples 1 to 5 were prepared with the configurations shown in Table 1. In the spatial treatment quantitative injection aerosols of Examples 16, 17, 21, 22, 23, and 24, theoretically, quantitative injection is performed even when a quantitative spray valve having an injection capacity of 0.2 mL or 1.0 mL is used. The filling amount in the pressure-resistant container was adjusted so that the above could be carried out up to 22 times.

<Injection test (injection angle 45 °)>
The quantitative injection aerosols for spatial treatment of Examples 1 to 24 and Comparative Examples 1 to 5 were fixed so that the injection axis of the injection port formed an injection angle of 45 ° with respect to the horizontal plane, and the injection was repeated. Before starting the counting of the number of injections, the blank shot was performed twice, and then the number of injections until the injection could not be performed normally was counted. In this embodiment, "cannot inject normally" is synonymous with the above-mentioned "injection failure", and the capacity actually injected by the operation of the actuator is less than 85% of the injection capacity of the fixed quantity injection valve. It means that The same applies to the following examples. The test was repeated four times for each spatial treatment quantitative injection aerosol, and the effect of suppressing injection defects was evaluated according to the following evaluation criteria according to the average value of the number of injections.
(Evaluation criteria)
A: 18 times or more B: 16 times or 17 times C: 14 times or 15 times D: Less than 14 times

In addition, if injection failure occurs at least once in the four tests and by the second time the count starts, it is determined that there is injection failure at the initial stage of use. The test results are shown in Table 1.

As a result of the test, when the drug is sprayed diagonally upward 45 ° with respect to the horizontal plane, the number of injections of the quantitative injection aerosol for spatial treatment of Examples 1 to 24 is 14 or more until it cannot be injected normally. Therefore, the occurrence of injection defects in the latter half of use was suppressed. Among them, an actuator provided with an injection port so that the injection shaft makes an elevation angle of 15 ° or more with respect to the horizontal plane when the pressure-resistant container is placed on the horizontal plane is attached, and the tip is U-shaped or cut diagonally. The quantitative injection aerosols for spatial treatment of Examples 1 to 6, 8 to 19 and 21 to 24 using the dip tube were particularly excellent in the effect of suppressing injection defects in the latter stage of use. Further, in the quantitative injection aerosols for spatial treatment of Examples 1 to 24, injection defects at the initial stage of use did not occur.

On the other hand, the quantitative injection aerosols for spatial treatment of Comparative Examples 1 to 5 had 13 or less injection times until they could not be injected normally, and the occurrence of injection defects in the latter stage of use was not sufficiently suppressed. .. Further, in the quantitative injection aerosols for spatial treatment of Comparative Examples 1 to 3 and 5, injection defects at the initial stage of use also occurred.

[Examples 25 to 32, Comparative Examples 6 and 7]
According to Example 1, various quantitative injection aerosols for spatial treatment of Examples 25 to 32 and Comparative Examples 6 and 7 were prepared with the configurations shown in Table 2.

<Injection test (injection angle 30 °)>
The quantitative injection aerosols for spatial treatment of Examples 25 to 32 and Comparative Examples 6 and 7 were fixed so that the injection axis of the injection port formed an injection angle of 30 ° with respect to the horizontal plane, and the injection was repeated. Before starting the counting of the number of injections, the blank shot was performed twice, and then the number of injections until the injection could not be performed normally was counted. The test was repeated four times for each spatial treatment quantitative injection aerosol, and the effect of suppressing injection defects was evaluated according to the following evaluation criteria according to the average value of the number of injections.
(Evaluation criteria)
A: 18 times or more B: 16 times or 17 times C: 14 times or 15 times D: Less than 14 times

In addition, if injection failure occurs at least once in the four tests and by the second time the count starts, it is determined that there is injection failure at the initial stage of use. The test results are shown in Table 2.

As a result of the test, when the drug is sprayed diagonally upward to 30 ° with respect to the horizontal plane, the number of injections of the quantitative injection aerosol for spatial treatment of Examples 25 to 32 is 15 times or more until it cannot be injected normally. Therefore, the occurrence of injection defects in the latter half of use was suppressed. Among them, the quantitative injection aerosol for spatial treatment of Examples 26 to 32 equipped with an actuator provided with an injection port so that the injection shaft forms an elevation angle of 50 ° or less with respect to the horizontal plane when the pressure-resistant container is placed on the horizontal plane. Was particularly excellent in the effect of suppressing injection defects in the latter period of use. Further, in the quantitative injection aerosols for spatial treatment of Examples 25 to 32, injection defects at the initial stage of use did not occur.

On the other hand, in the quantitative injection aerosols for spatial treatment of Comparative Examples 6 and 7, the number of injections until the aerosol could not be injected normally was 14 times or less, and the effect of suppressing injection defects in the latter stage of use was obtained in Examples 25 to 32. It was inferior to the quantitative injection aerosol for spatial treatment. Further, in the quantitative injection aerosols for spatial treatment of Comparative Examples 6 and 7, injection defects at the initial stage of use also occurred.

[Example 33]
2.7 mL of the aerosol stock solution A and 6.1 mL of liquefied petroleum gas as a propellant were pressure-filled in a pressure-resistant container. Other than that, a quantitative injection aerosol for spatial treatment of Example 33 was obtained by the same procedure as that of the quantitative injection aerosol for spatial treatment of Example 1.

[Examples 34 to 38]
According to Example 33, various spatial treatment quantitative injection aerosols of Examples 34 to 38 were prepared with the configurations shown in Table 3.

<Injection test (injection angle 60 °)>
The quantitative injection aerosol for spatial treatment of Examples 33 to 38 was fixed so that the injection axis of the injection port formed an injection angle of 60 ° with respect to the horizontal plane, and the injection was repeated. Before starting the counting of the number of injections, the blank shot was performed twice, and then the number of injections until the injection could not be performed normally was counted. The test was repeated four times for each spatial treatment quantitative injection aerosol, and the effect of suppressing injection defects was evaluated according to the following evaluation criteria according to the average value of the number of injections.
(Evaluation criteria)
A: 18 times or more B: 16 times or 17 times C: 14 times or 15 times D: Less than 14 times

In addition, if injection failure occurs at least once in the four tests and by the second time the count starts, it is determined that there is injection failure at the initial stage of use. The test results are shown in Table 3.

As a result of the test, when the drug is sprayed diagonally upward to 60 ° with respect to the horizontal plane, the number of injections of the quantitative injection aerosol for spatial treatment of Examples 33 to 38 is 15 times or more until it cannot be injected normally. Therefore, the occurrence of injection defects in the latter half of use was suppressed. Among them, the quantitative injection for spatial processing of Examples 34 to 36 equipped with an actuator provided with an injection port so that the injection shaft makes an elevation angle of 40 to 50 ° with respect to the horizontal plane when the pressure-resistant container is placed on the horizontal plane. The aerosol was particularly excellent in the effect of suppressing injection defects in the latter stage of use. Further, in the quantitative injection aerosols for spatial treatment of Examples 33 to 38, injection defects at the initial stage of use did not occur.

[Examples 39 and 40]
According to Example 1, various spatial treatment quantitative injection aerosols of Examples 39 and 40 were prepared with the configurations shown in Table 4. In the quantitative injection aerosols for spatial treatment of Examples 39 and 40, theoretically, the quantitative injection can be performed up to 22 times even when the quantitative spray valve having an injection capacity of 0.2 mL or 2.0 mL is used. The filling amount in the pressure-resistant container was adjusted so as to be.

<Diffusion uniformity test>
Glass plates of 20 x 20 cm were installed at 6 to 8 places on the floor of a closed room with a volume of 25 m ³ (area 10 m ^{2, height 2.5 m).} The quantitative injection aerosols for spatial treatment of Examples 13 to 17, 39, and 40 were placed in the center of the room at a height of 1.5 m so that the injection axis of the injection port formed an injection angle of 45 ° with respect to the horizontal plane. It was held and sprayed in a fixed amount. One hour after the injection treatment, all the glass plates were taken out, and the control components adhering to each glass plate were washed out with acetone and analyzed by gas chromatography. Regarding the control components adhering to the glass plates, the variation between the glass plates was analyzed, and the diffusion uniformity of the spray particles was evaluated. The results are shown in three stages, A, B, and C, in order from the one with the best diffusion uniformity. Further, for the quantitative injection aerosols for spatial treatment of Examples 39 and 40, the above-mentioned "injection test (injection angle 45 °)" was carried out. Table 4 shows the test results of the injection test (injection angle 45 °) and the diffusion uniformity test.

As a result of the test, when the drug is sprayed obliquely upward to 45 ° with respect to the horizontal plane, the spatial treatment quantitative injection aerosols of Examples 39 and 40 are the same as the spatial treatment quantitative injection aerosols of Examples 13 to 17. , The occurrence of injection defects in both the early and late stages of use was suppressed. However, the spatial treatment quantitative injection aerosols of Examples 39 and 40 were inferior in diffusion uniformity to the spatial treatment quantitative injection aerosols of Examples 13 to 17. From this, in order to improve the diffusion uniformity, it is considered preferable that the injection force at an injection distance of 5 cm is in the range of 5 to 50 gf, as in the quantitative injection aerosol for spatial treatment of Examples 13 to 17.

[Example 41]
The control component of the aerosol stock solution A in the quantitative injection aerosol for spatial treatment of Example 1 was changed to phenothrin (53 w / v%) as a non-volatile control component and metoflutrin (0.7 w / v%) as a volatile control component. Then, the filling amount in the pressure-resistant container was changed to 2.6 mL of the aerosol stock solution (A + B) and 6.2 mL of the propellant. Further, the actuator was changed to one provided with an injection port so that the injection shaft makes an elevation angle of 45 ° with respect to the horizontal plane when the pressure-resistant container is placed on the horizontal plane. Other than that, a quantitative injection aerosol for spatial treatment of Example 41 was obtained in the same manner as the quantitative injection aerosol for spatial treatment of Example 1.

[Example 42]
The control component of the aerosol stock solution A in the quantitative injection aerosol for spatial treatment of Example 1 was cyphenothrin (38 w / v%) as a non-volatile control component and transfluthrin (0.7 w / v%) as a volatile control component. ), And the filling amount in the pressure-resistant container was changed to 1.8 mL of the aerosol stock solution (A + B) and 7.0 mL of the propellant. Further, the actuator was changed to one provided with an injection port so that the injection shaft makes an elevation angle of 45 ° with respect to the horizontal plane when the pressure-resistant container is placed on the horizontal plane. Other than that, a quantitative injection aerosol for spatial treatment of Example 42 was obtained in the same manner as the quantitative injection aerosol for spatial treatment of Example 1.

[Example 43]
The control component of the aerosol stock solution A in the quantitative injection aerosol for spatial treatment of Example 1 was changed to permethrin (60 w / v%) as a non-volatile control component, and the organic solvent was changed to isopropanol, respectively, and the filling amount in the pressure resistant container was changed. The aerosol stock solution A was changed to 2.6 mL and the propellant was changed to 6.2 mL. Further, the actuator was changed to one provided with an injection port so that the injection shaft makes an elevation angle of 45 ° with respect to the horizontal plane when the pressure-resistant container is placed on the horizontal plane. Other than that, a quantitative injection aerosol for spatial treatment of Example 43 was obtained in the same manner as the quantitative injection aerosol for spatial treatment of Example 1.

[Example 44]
The control component of the aerosol stock solution A in the quantitative injection aerosol for spatial treatment of Example 1 was changed to phenothrin (53 w / v%) as a non-volatile control component, and the organic solvent was changed to neothiosol (normal paraffin solvent). The filling amount of the aerosol stock solution A was changed to 2.6 mL and the propellant was changed to 6.2 mL. Further, the actuator was changed to one provided with an injection port so that the injection shaft makes an elevation angle of 45 ° with respect to the horizontal plane when the pressure-resistant container is placed on the horizontal plane. Other than that, a quantitative injection aerosol for spatial treatment of Example 44 was obtained in the same manner as the quantitative injection aerosol for spatial treatment of Example 1.

[Example 45]
The control component of the aerosol stock solution A in the quantitative injection aerosol for spatial treatment of Example 1 was changed to phenothrin (30 w / v%) as a non-volatile control component, and the organic solvent was changed to isopropyl myristate, respectively, and the filling amount in the pressure-resistant container was changed. Was changed to 2.6 mL of aerosol stock solution A and 6.2 mL of propellant. Further, the actuator was changed to one provided with an injection port so that the injection shaft makes an elevation angle of 45 ° with respect to the horizontal plane when the pressure-resistant container is placed on the horizontal plane. Other than that, a quantitative injection aerosol for spatial treatment of Example 45 was obtained in the same manner as the quantitative injection aerosol for spatial treatment of Example 1.

[Example 46]
The control component of the aerosol stock solution A in the quantitative injection aerosol for spatial treatment of Example 1 was changed to permethrin (60 w / v%) as a non-volatile control component, and the organic solvent was changed to IP Clean LX (isoparaffin solvent). The filling amount in the container was changed to 2.2 mL of the aerosol stock solution A and 6.6 mL of the propellant. Further, the actuator was changed to one provided with an injection port so that the injection shaft makes an elevation angle of 45 ° with respect to the horizontal plane when the pressure-resistant container is placed on the horizontal plane. Other than that, a quantitative injection aerosol for spatial treatment of Example 46 was obtained in the same manner as the quantitative injection aerosol for spatial treatment of Example 1.

Using the quantitative injection aerosol for spatial treatment of Examples 41 to 46, the above-mentioned "injection test (injection angle 30 °)", "injection test (injection angle 45 °)", "injection test (injection angle 60 °)" , And a "diffusion uniformity test" was carried out. As a result of the test, the composition of the aerosol stock solution A containing the refractory control component or the aerosol stock solution (A + B) containing the refractory control component and the volatilization control component, and the aerosol stock solution and the propellant filled in the pressure resistant container. The quantitative injection aerosols for spatial treatment of Examples 41 to 46 having different capacity ratios are all good because the occurrence of injection defects in the early and late stages of use is suppressed at the injection angles of 30 °, 45 °, and 60 °. It was confirmed that it showed a good diffusion uniformity. From this, the effect of suppressing injection defects and the effect of improving diffusion uniformity were not obtained by setting the composition of the aerosol stock solution and the volume ratio of the aerosol stock solution filled in the pressure-resistant container and the propellant, but the dip tube. It is considered that this was obtained by appropriately setting the height (h) of the tip of the above and the elevation angle (D) of the injection port (injection shaft).

[Example 47]
The control component of the aerosol stock solution A in the quantitative injection aerosol for spatial treatment of Example 1 was changed to transfluthrin (8 w / v%) as a volatile control component, and the organic solvent was changed to ethanol, respectively, and the filling amount in the pressure-resistant container was changed. , The aerosol stock solution B was changed to 2.6 mL and the propellant was changed to 6.2 mL. Further, the actuator was changed to one provided with an injection port so that the injection shaft makes an elevation angle of 45 ° with respect to the horizontal plane when the pressure-resistant container is placed on the horizontal plane. Other than that, a quantitative injection aerosol for spatial treatment of Example 47 was obtained in the same manner as the quantitative injection aerosol for spatial treatment of Example 1.

[Example 48]
The control component of the aerosol stock solution A in the quantitative injection aerosol for spatial treatment of Example 1 was changed to transfluthrin (40 w / v%) as a volatile control component, and the organic solvent was changed to isopropanol, respectively, and the filling amount in the pressure resistant container was changed. , The aerosol stock solution B was changed to 2.6 mL and the propellant was changed to 6.2 mL. Further, the actuator was changed to one provided with an injection port so that the injection shaft makes an elevation angle of 45 ° with respect to the horizontal plane when the pressure-resistant container is placed on the horizontal plane. Other than that, a quantitative injection aerosol for spatial treatment of Example 48 was obtained in the same manner as the quantitative injection aerosol for spatial treatment of Example 1.

[Example 49]
The control component of the aerosol stock solution A in the quantitative injection aerosol for spatial treatment of Example 1 was changed to metoflutrin (20 w / v%) as a volatile control component, and the organic solvent was changed to neothiosol (normal paraffin solvent), respectively, to a pressure-resistant container. The filling amount of the aerosol stock solution B was changed to 2.6 mL and the propellant was changed to 6.2 mL. Further, the actuator was changed to one provided with an injection port so that the injection shaft makes an elevation angle of 45 ° with respect to the horizontal plane when the pressure-resistant container is placed on the horizontal plane. Other than that, a quantitative injection aerosol for spatial treatment of Example 49 was obtained in the same manner as the quantitative injection aerosol for spatial treatment of Example 1.

"Injection test (injection angle 30 °)", "injection test (injection angle 45 °)", "injection test (injection angle 60 °)" described above using the quantitative injection aerosol for spatial treatment of Examples 47 to 49. , And a "diffusion uniformity test" was carried out. As a result of the test, the quantitative injection aerosols for spatial treatment of Examples 47 to 49 containing the aerosol stock solution B containing the volatilization control component were all used at the initial use and at the injection angles of 30 °, 45 °, and 60 °. It was confirmed that the occurrence of injection defects in the latter stage was suppressed and good diffusion uniformity was exhibited. From this, the effect of suppressing injection defects and the effect of improving diffusion uniformity were not obtained by setting the composition of the aerosol stock solution and the volume ratio of the aerosol stock solution filled in the pressure-resistant container and the propellant, and were not obtained by dipping. It is considered that this was obtained by appropriately setting the height (h) of the tip of the tube and the elevation angle (D) of the injection port (injection shaft).

The quantitative injection aerosol for spatial treatment of the present invention can be used for the purpose of controlling a wide range of pests and mites.

10 Pressure-resistant container 12 Fixed-quantity injection valve 20 Actuator 21 Injection port 30 Dip tube 30a Tip of dip tube 100 Fixed-quantity injection aerosol for spatial treatment D Elevation angle H Horizontal plane O Injection shaft S Inner surface of pressure-resistant container

Claims

A pressure-resistant container provided with a fixed-quantity injection valve in which an aerosol stock solution containing a control component and a propellant are sealed, an actuator provided with an injection port connected to the fixed-quantity injection valve, the aerosol stock solution and the propellant. A fixed-quantity injection aerosol for spatial treatment provided with a dip tube for supplying the fixed-quantity injection valve.
The tip of the dip tube is located at a height of 6 mm or less from the bottom of the pressure resistant container.
When the pressure-resistant container is placed on a horizontal plane, the injection shaft of the injection port is a quantitative injection aerosol for spatial treatment having an elevation angle of 10 to 60 ° with respect to the horizontal plane.
The quantitative injection aerosol for spatial treatment according to claim 1, wherein the control component contains a non-volatile control component having a vapor pressure of less than 1 × 10 -4 mmHg at 30 ° C.
The quantitative injection aerosol for spatial treatment according to claim 1, wherein the control component contains a volatile control component having a vapor pressure of 2 × 10 -4 to 1 × 10 -2 mmHg at 30 ° C.
The control components are a refractory control component having a vapor pressure of less than 1 × 10 -4 mmHg at 30 ° C. and a volatilization control component having a vapor pressure of 2 × 10 -4 to 1 × 10 −2 mmHg at 30 ° C. The quantitative injection aerosol for spatial treatment according to claim 1, which contains an ingredient.
The quantitative injection aerosol for spatial treatment according to any one of claims 1 to 4, wherein the injection shaft of the injection port has an elevation angle of 15 to 50 ° with respect to the horizontal plane.
The quantitative injection aerosol for spatial treatment according to any one of claims 1 to 5, wherein the tip of the dip tube is located at a height of 3 mm or less from the lowermost part of the pressure-resistant container.
The quantitative injection aerosol for spatial treatment according to any one of claims 1 to 6, wherein the injection force at an injection distance of 5 cm is set to 5 to 50 gf.
The quantitative injection aerosol for spatial treatment according to any one of claims 1 to 7, wherein the dip tube is configured to be bendable inside the pressure-resistant container.