WO2021088612A1 - Lpso phase fortified high-damping rare earth magnesium alloy and preparation method therefor - Google Patents

Lpso phase fortified high-damping rare earth magnesium alloy and preparation method therefor Download PDF

Info

Publication number
WO2021088612A1
WO2021088612A1 PCT/CN2020/121107 CN2020121107W WO2021088612A1 WO 2021088612 A1 WO2021088612 A1 WO 2021088612A1 CN 2020121107 W CN2020121107 W CN 2020121107W WO 2021088612 A1 WO2021088612 A1 WO 2021088612A1
Authority
WO
WIPO (PCT)
Prior art keywords
rare earth
magnesium alloy
magnesium
damping
alloy
Prior art date
Application number
PCT/CN2020/121107
Other languages
French (fr)
Chinese (zh)
Inventor
房大庆
张晓茹
周玉美
付伟
丁向东
孙军
杨军
刘鹏
Original Assignee
西安交通大学
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 西安交通大学 filed Critical 西安交通大学
Publication of WO2021088612A1 publication Critical patent/WO2021088612A1/en

Links

Images

Classifications

    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C1/00Making non-ferrous alloys
    • C22C1/02Making non-ferrous alloys by melting
    • C22C1/03Making non-ferrous alloys by melting using master alloys
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C1/00Making non-ferrous alloys
    • C22C1/06Making non-ferrous alloys with the use of special agents for refining or deoxidising
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C23/00Alloys based on magnesium
    • C22C23/06Alloys based on magnesium with a rare earth metal as the next major constituent

Definitions

  • the invention belongs to the technical field of non-ferrous metal materials, and specifically relates to an LPSO phase strengthened high damping rare earth magnesium alloy and a preparation method thereof.
  • the general standard for judging the damping value of a metal alloy is that: when the damping value is Q -1 ⁇ 0.01, the metal alloy is considered to be a high damping alloy.
  • Currently developed relatively mature high-damping magnesium alloy systems include Mg-Zr, Mg-Ni and Mg-Cu-Mn systems, and most of them are cast magnesium alloys. Although they all have excellent damping properties, the damping value can reach more than 0.05. However, its mechanical properties are poor, and its tensile strength is only about 150MPa. For example, the damping internal friction value Q -1 of Mg-3Cu-1Mn alloy can reach 0.1, but its tensile strength is only 149MPa. In addition, the poor corrosion resistance of Mg-Ni alloy limits its application prospects.
  • AZ magnesium alloys While the currently widely used AZ magnesium alloys have higher mechanical properties and better corrosion resistance, their damping performance is nearly 10 times lower than that of other high-damping magnesium alloys.
  • the AZ80+0.4% Ce magnesium alloy studied by Yang Yaqin et al. the tensile strength of the alloy can reach more than 250MPa, while the damping internal friction value is only about 0.012.
  • Rare earth magnesium alloys have the advantages of good casting performance, excellent corrosion resistance and better mechanical properties.
  • the research on high damping rare earth magnesium alloys is still in its infancy. Therefore, the development of high performance rare earth magnesium alloys with excellent mechanical properties and damping properties is very important Enriching the types of damping magnesium alloys and expanding the functionality of magnesium alloys is of great significance, and at the same time can provide a way out for expanding the application fields of magnesium alloys.
  • the purpose of the present invention is to provide an LPSO phase-strengthened high-damping rare earth magnesium alloy and a preparation method thereof.
  • the storage capacity of the alloy can improve the damping performance of the alloy, and achieve the characteristics of both excellent mechanical properties and damping performance;
  • the magnesium alloy obtained by the preparation method of the magnesium alloy has a high yield, good processing and formability, easy to realize industrialization, and can be widely used in In sound transmission equipment such as speakers and earpieces.
  • the invention discloses a LPSO phase strengthened high damping rare earth magnesium alloy.
  • the raw material composition and weight percentage content of the magnesium alloy are as follows:
  • Rare earth elements 2.7-3.8%, Zn: 0.8-1.2%, Mn: 0.5-1.0%, the balance is Mg.
  • the rare earth element includes:
  • the weight percentage content of Y in the magnesium alloy is 2.2-2.8%
  • the weight percentage content of Ce in the magnesium alloy is 0.5-1.0%.
  • the mass ratio of Y to Zn is 2.3 to 2.8.
  • the invention discloses a preparation method of the above-mentioned LPSO phase strengthened high damping rare earth magnesium alloy, which comprises the following steps:
  • Step 1 Take magnesium ingots, Zn ingots, magnesium rare earth master alloys and MnCl 2 particles as raw materials, weigh and prepare materials according to mass percentage;
  • Step 2 Preheat and dry the magnesium ingot in Step 1, and then heat and melt the magnesium ingot to form a magnesium liquid. Add the preheated Zn ingot, magnesium rare earth intermediate alloy and MnCl 2 particles to the magnesium liquid in sequence, and add them while stirring The refining agent is smelted, the slag is removed after smelting, and finally the ingot is obtained by semi-continuous casting process, which is the LPSO phase strengthened high damping rare earth magnesium alloy.
  • the mass percentage in step one is:
  • Rare earth elements 2.7-3.8%, Zn: 0.8-1.2%, Mn: 0.5-1.0%, the balance is Mg.
  • the magnesium rare earth master alloy in step 1 is one or a combination of Mg-25Y master alloy and Mg-20Ce master alloy.
  • the weight percentage content of Y in the magnesium alloy in the magnesium rare earth master alloy is 2.2-2.8%, and the weight percentage content of Ce in the magnesium alloy is 0.5-1.0%.
  • the temperature of the smelting process in step 2 is 650 to 720°C, and the temperature is maintained for 20 to 30 minutes.
  • the addition amount of the refining agent in the smelting process of step two is 1 kg and 75-125 g of the refining agent is added to the raw material of step one.
  • the content of magnesium in the magnesium ingot is greater than 99.5 wt%, and the content of Zn in the Zn ingot is greater than 99.5 wt%.
  • the present invention has the following beneficial effects:
  • the invention discloses a LPSO phase reinforced high damping rare earth magnesium alloy.
  • the magnesium alloy adopts a Mg-RE (rare earth element)-Zn series alloy formula.
  • RE mostly exists as a hard and brittle phase at the network grain boundary.
  • the RE element and Zn are adjusted.
  • the ratio of the elements obtains a rare earth magnesium alloy with high strength and high damping; on the one hand, the addition of trace Mn element can remove the harmful impurity element Fe, on the other hand, it can refine the grain.
  • the comprehensive strengthening effect of the light and heavy rare earths is exerted. Due to the difference in the solid solubility of light and heavy rare earths, light rare earth elements with smaller solid solubility can preferentially gather at the front of the solidification interface to refine the grains and achieve the effect of fine-grain strengthening.
  • the solid solubility of heavy rare earth elements is large, and they can be dissolved in the magnesium matrix to improve the ratio of lattice constant c/a, and increase the probability of starting other slip systems outside the base surface, so as to achieve solid solution strengthening while improving Alloy plasticity.
  • the type of eutectic phase formed in the magnesium alloy during solidification depends on the ratio of Y element to Zn element.
  • the main precipitated phase in the microstructure obtained is the LPSO phase. Therefore, by controlling the mass ratio of heavy rare earth elements Y and Zn in the range of 2.3 to 2.8, a rare earth magnesium alloy with LPSO phase (also called X-phase) as the main precipitation phase can be obtained. While the LPSO phase exerts the strengthening of the second phase by hindering the movement of dislocations, its own plastic deformation ability can slow down the stress concentration and improve the plasticity of the alloy.
  • the LPSO phase has been recognized as an effective strengthening phase for improving the comprehensive mechanical properties of magnesium alloys in recent years. While improving the strength, it is also beneficial to improve the plasticity of the alloy.
  • the damping mechanism of magnesium alloy is a dislocation type damping mechanism, and the increase in the number of movable dislocations in the alloy can improve the damping performance. Because the LPSO phase has the ability to store dislocations, its own deformation can effectively increase the number of movable dislocations, which is beneficial to energy absorption, increases the internal friction value, and can improve the damping performance of the magnesium alloy.
  • the Y element solid dissolved in the magnesium matrix can form a dislocation hysteresis loop through the process of pinning and unpinning by hindering the movable dislocation, thereby improving the damping performance of the alloy.
  • the alloy Through the mechanical performance and damping performance test results, it is known that the alloy not only exhibits excellent comprehensive mechanical properties, but also has high damping performance.
  • the invention also discloses a preparation method of LPSO phase-strengthened high-damping rare-earth magnesium alloy.
  • the method obtains a series of high-damping rare-earth magnesium alloys with LPSO structure through reasonable heating and melting and semi-continuous casting processes.
  • the tensile strength of the magnesium alloy is Engineering stress can reach 180MPa, the elongation Engineering strain can reach more than 10%, and the internal friction value of damping Up to 0.065.
  • the magnesium alloy of the present invention can efficiently exert the high damping functionality of rare earth elements in the magnesium alloy, and at the same time has excellent comprehensive mechanical properties, is easy to realize industrialization, and can be widely used in sound transmission equipment components.
  • Figure 1a is an SEM image of a magnesium alloy in Example 1;
  • Figure 1b is an SEM image of the magnesium alloy in Example 2;
  • Figure 1c is an SEM image of the magnesium alloy of Example 3.
  • Figure 1d is an SEM image of a magnesium alloy in Comparative Example 1;
  • Figure 1e is an SEM image of a comparative example of two magnesium alloys
  • Figure 2 is a graph showing the damping performance test curve of the magnesium alloy of the embodiment and the comparative example
  • Fig. 3 is a graph showing the tensile properties of magnesium alloys of Examples and Comparative Examples.
  • composition of the raw material of the refining agent and its weight percentage content are: 55%-60% KCl, 2%-5% CaF 2 , the rest is BaCl 2 , the amount of refining agent added is 75 per kg of raw material -125g.
  • This embodiment provides an LPSO phase strengthened high damping rare earth magnesium alloy.
  • the raw material composition and weight percentage content are: rare earth element: 2.7%, Zn: 0.8%, Mn: 0.5%, and the balance is Mg.
  • the rare earth elements in this embodiment include Y and Ce, the weight percentage of Y in the magnesium alloy is 2.2%, and the weight percentage of Ce in the magnesium alloy is 0.5%.
  • the mass ratio of Y and Zn is 2.75.
  • the preparation method of the LPSO phase strengthened high damping rare earth magnesium alloy includes the following steps:
  • Step 1 Use pure magnesium ingot (99.5wt% or more), pure Zn ingot (99.5wt% or more), Mg-25Y master alloy (that is, the composition content of the master alloy is: 25wt% Y, the balance is Mg) and Mg- 20Ce master alloy and MnCl 2 particles as raw materials, weigh and prepare the materials according to the mass percentage of Y 2.2wt%, Ce 0.5wt%, Zn 0.8wt%, Mn 0.5wt%, and the balance Mg, the total amount of raw materials is 1kg;
  • Step 2 Preheat and dry the pure magnesium ingots in step 1 at 180°C, then heat the pure magnesium ingots in a crucible in a resistance furnace to 650°C and gradually melt them. After the magnesium ingots are completely melted, a magnesium liquid will be formed.
  • the pure Zn ingot preheated at 180°C, Mg-25Y master alloy, Mg-20Ce master alloy and MnCl 2 particles are added to the magnesium liquid for smelting. While stirring, slowly add 75g of refining agent, control the smelting temperature at 720°C, and keep warm. 30min, after removing the slag, the semi-continuous casting process is used to cast the ingot, which is an LPSO phase strengthened high damping rare earth magnesium alloy.
  • the LPSO phase-strengthened high-damping rare earth magnesium alloy obtained in this example is scanned as shown in Fig. 1a.
  • the damping performance of the alloy is tested by DMA850, and the damping value of the alloy can reach 0.065 at room temperature; the MTS810 mechanical test system is used for the alloy mechanics
  • the performance is tested, the tensile strength of the alloy is 187MPa, and the elongation is 10.0%.
  • This embodiment provides an LPSO phase strengthened high damping rare earth magnesium alloy.
  • the raw material composition and weight percentage content are: rare earth element: 3.2%, Zn: 1.0%, Mn: 0.6%, and the balance is Mg.
  • the rare earth elements in this embodiment include Y and Ce, the weight percentage of Y in the magnesium alloy is 2.5%, and the weight percentage of Ce in the magnesium alloy is 0.8%.
  • the mass ratio of Y and Zn is 2.5.
  • the preparation method of the LPSO phase strengthened high damping rare earth magnesium alloy includes the following steps:
  • Step 1 Use pure magnesium ingot (99.5wt% or more), pure Zn ingot (99.5wt% or more), Mg-25Y master alloy, Mg-20Ce master alloy and MnCl 2 particles as raw materials, according to Y 2.5wt%, Ce 0.8wt %, Zn 1.0wt%, Mn 0.6wt%, and the balance is the weight percentage of Mg.
  • the total amount of raw materials is 1kg;
  • Step 2 Preheat and dry the pure magnesium ingots in step one at 230°C, then heat the pure magnesium ingots in a crucible in a resistance furnace to 680°C and gradually melt them, and form magnesium liquid after the magnesium ingots are completely melted.
  • the pure Zn ingots, Mg-25Y master alloy, Mg-20Ce master alloy and MnCl 2 particles preheated at 230°C are added to the magnesium liquid for smelting. While stirring, the refining agent is added to smelt 100g, the smelting temperature is 680°C, and the holding time is 25min. After slag removal, a semi-continuous casting process is used to cast an ingot, which is an LPSO phase strengthened high damping rare earth magnesium alloy.
  • the LPSO phase-strengthened high-damping rare earth magnesium alloy obtained in this example is scanned as shown in Fig. 1b.
  • the damping performance of the alloy is tested by DMA850, and the damping value of the alloy can reach 0.068 at room temperature; the MTS810 mechanical test system is used for the alloy mechanics
  • the performance was tested, the alloy's tensile strength was 185MPa, and the elongation was 10.2%.
  • This embodiment provides an LPSO phase strengthened high damping rare earth magnesium alloy.
  • the raw material composition and weight percentage content are: rare earth element: 3.8%, Zn: 1.2%, Mn: 1.0%, and the balance is Mg.
  • the rare earth elements in this embodiment include Y and Ce, the weight percentage of Y in the magnesium alloy is 2.8%, and the weight percentage of Ce in the magnesium alloy is 1.0%.
  • the mass ratio of Y and Zn is about 2.33.
  • the preparation method of the LPSO phase strengthened high damping rare earth magnesium alloy includes the following steps:
  • Step 1 Use pure magnesium ingot (99.5wt% or more), pure Zn ingot (99.5wt% or more), Mg-25Y master alloy, Mg-20Ce master alloy and MnCl 2 particles as raw materials, according to Y 2.8wt%, Ce 1.0wt %, Zn 1.2wt%, Mn 1.0wt%, and the balance is the weight percentage of Mg.
  • the total amount of raw materials is 1kg;
  • Step 2 Preheat and dry the pure magnesium ingots in step one at 230°C, then heat the pure magnesium ingots in a crucible in a resistance furnace to 680°C and gradually melt them, and form magnesium liquid after the magnesium ingots are completely melted.
  • the pure Zn ingots, Mg-25Y master alloy, Mg-20Ce master alloy and MnCl 2 particles preheated at 230°C are added to the magnesium liquid for smelting. Slowly add 125g refining agent while stirring. The smelting temperature is 650°C and the temperature is kept for 20min. After slag removal, a semi-continuous casting process is used to cast an ingot, which is an LPSO phase strengthened high damping rare earth magnesium alloy.
  • the LPSO phase-strengthened high damping rare earth magnesium alloy obtained in this example is scanned as shown in Fig. 1c.
  • the damping performance of the alloy is tested by DMA850, and the damping value of the alloy can reach 0.071 at room temperature; the MTS810 mechanical test system is used for the alloy mechanics
  • the performance was tested, the alloy's tensile strength was 181MPa, and the elongation was 10.9%.
  • the first comparative example provides a W-phase reinforced rare earth magnesium alloy.
  • the raw material composition and weight percentage content are: rare earth element: 3.5%, Zn: 4.6%, Mn: 0.6%, and the balance is Mg.
  • the rare earth elements in this embodiment include Y and Ce, the weight percentage of Y in the magnesium alloy is 2.5%, and the weight percentage of Ce in the magnesium alloy is 1.0%.
  • the mass ratio of Y and Zn is 0.54.
  • the preparation method of the W-containing phase strengthened rare earth magnesium alloy includes the following steps:
  • Step 1 Use pure magnesium ingot (99.5wt% or more), pure Zn ingot (99.5wt% or more), Mg-25Y master alloy, Mg-20Ce master alloy and MnCl 2 particles as raw materials, according to Y 2.5wt%, Ce 1.0wt %, Zn 4.6wt%, Mn 0.6wt%, and the balance is the weight percentage of Mg for weighing and preparing materials, the total amount of raw materials is 1kg;
  • Step 2 Preheat and dry the pure magnesium ingots in step 1 at 180°C, then heat the pure magnesium ingots in a crucible in a resistance furnace to 650°C and gradually melt them. After the magnesium ingots are completely melted, a magnesium liquid will be formed.
  • the pure Zn ingot, Mg-25Y master alloy, Mg-20Ce master alloy and MnCl 2 particles preheated at 180°C are added to the magnesium liquid for smelting. Slowly add 120g of refining agent while stirring. The smelting temperature is 700°C and the temperature is kept for 25min. After slag removal, a semi-continuous casting process is used to cast to obtain an ingot, which is a W-phase reinforced rare earth magnesium alloy.
  • the scan diagram of the W-phase reinforced rare earth magnesium alloy obtained in this example is shown in Figure 1d.
  • the damping performance of the alloy is tested by DMA850, and the damping value of the alloy can reach 0.027 at room temperature; the mechanical properties of the alloy are measured by the MTS810 mechanical test system When tested, the alloy has a tensile strength of 196MPa and an elongation of 8.7%.
  • the second comparative example provides a rare earth magnesium alloy containing Mg-RE phase.
  • the raw material composition and weight percentage content are: rare earth element: 3.8%, Mn: 1.0%, and the balance is Mg.
  • the rare earth elements in this embodiment include Y and Ce, the weight percentage of Y in the magnesium alloy is 2.8%, and the weight percentage of Ce in the magnesium alloy is 1.0%.
  • the mass ratio of Y and Zn is 0.54.
  • the preparation method of the rare earth magnesium alloy containing Mg-RE phase includes the following steps:
  • Step 1 Take pure magnesium ingot (above 99.5wt%), Mg-25Y master alloy, Mg-20Ce master alloy and MnCl 2 particles as raw materials, according to Y 2.8wt%, Ce 1.0wt%, Mn 1.0wt%, the balance is The weight percentage of Mg is weighed and prepared, and the total amount of raw materials is 1kg;
  • Step 2 Preheat and dry the pure magnesium ingots in step one at 230°C, then heat the pure magnesium ingots in a crucible in a resistance furnace to 680°C and gradually melt them, and form magnesium liquid after the magnesium ingots are completely melted.
  • Mg-25Y master alloy, Mg-20Ce master alloy and MnCl 2 particles preheated at 230°C were added to the magnesium liquid for smelting. While stirring, slowly add 110g refining agent. The smelting temperature was 650°C and the temperature was kept for 20 minutes. The semi-continuous casting process is cast to obtain an ingot, which is a rare earth magnesium alloy containing Mg-RE phase.
  • the Mg-RE phase-strengthened rare earth magnesium alloy obtained in this example is scanned as shown in Fig. 1e.
  • the damping performance of the alloy is tested by DMA850, and the damping value of the alloy can reach 0.060 at room temperature; the MTS810 mechanical test system is used for the alloy
  • the mechanical properties were tested, and the alloy's tensile strength was 138MPa, and the elongation was 6.9%.
  • Table 1 The main chemical components and preparation parameters of the magnesium alloy of the embodiment
  • Example 1 2.2 0.5 0.8 0.5 margin 720 30
  • Example 2 2.5 0.8 1.0 0.6 margin 680 25
  • Example 3 2.8 1.0 1.2 1.0 margin 650 20 Comparative example 1 2.5 1.0 4.6 0.6 margin 680 25
  • Comparative example 2 2.8 1.0 0 1.0 margin 650 20
  • Example 2 compare Example 2 with Comparative Example 1.
  • the magnesium alloy contains LPSO phase, while the magnesium alloy in Comparative Example 1 does not contain LPSO phase and contains W-phase. While the alloys in Example 2 and Comparative Example 1 have considerable comprehensive mechanical properties, the damping of the magnesium alloy in Example 2 The performance is much higher than that of the W-phase strengthened rare earth magnesium alloy in Comparative Example 1.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Powder Metallurgy (AREA)
  • Vibration Dampers (AREA)

Abstract

Disclosed are an LPSO phase fortified high-damping rare earth magnesium alloy and a preparation method therefor. The magnesium alloy comprises, in weight percent, 2.7-3.8% of rare earth elements, 0.8-1.5% of Zn, 0.5-1.0% of Mn, and the balance being Mg. The magnesium alloy comprises an LPSO phase having a special long period structure. The LPSO phase can enhance damping performance of the alloy while increasing comprehensive mechanical properties thereof, thus offering a tough and high-damping rare earth magnesium alloy. The LPSO phase fortified high-damping rare earth magnesium alloy is prepared by a method in which a semi-continuous casting process is employed. The rare earth magnesium alloy obtained has high mechanical properties and high damping performance, with a tensile strength of 180 MPa or higher, an elongation rate of 10% or higher and a damping value of 0.065 or higher. The magnesium alloy boasts a high product yield rate and a good machining and forming properties, is easy to industrialize, and can be widely used in sound transmission apparatuses, such as speakers and earpieces.

Description

一种LPSO相强化高阻尼稀土镁合金及其制备方法LPSO phase strengthened high damping rare earth magnesium alloy and preparation method thereof 技术领域Technical field
本发明属于有色金属材料技术领域,具体涉及一种LPSO相强化高阻尼稀土镁合金及其制备方法。The invention belongs to the technical field of non-ferrous metal materials, and specifically relates to an LPSO phase strengthened high damping rare earth magnesium alloy and a preparation method thereof.
背景技术Background technique
随着现代科学技术的迅猛发展,振动和噪音已成为三大公害之一,阻尼材料的开发及应用是解决振动失效及噪音干扰的重要途径。镁合金作为一种新型轻质结构材料越来越引起专家学者及各大企业的广泛关注。镁合金具有密度低,比强度及比刚度高,易于回收,能耗低而且减震抗噪性能优异等特点。当应变振幅为10 -4时,纯镁的阻尼内耗值Q -1可达到0.11。轻质减震高性能镁合金结构件用于音箱及听筒的减震元件中,可减小震动所带来的不利影响,有益于音频信号的高质量输送。 With the rapid development of modern science and technology, vibration and noise have become one of the three major public hazards. The development and application of damping materials is an important way to solve vibration failure and noise interference. As a new type of lightweight structural material, magnesium alloy has attracted more and more attention from experts, scholars and major companies. Magnesium alloy has the characteristics of low density, high specific strength and specific rigidity, easy recycling, low energy consumption and excellent shock and noise resistance. When the strain amplitude is 10 -4 , the damping internal friction value Q -1 of pure magnesium can reach 0.11. Lightweight and shock-absorbing high-performance magnesium alloy structural parts are used in the shock-absorbing components of speakers and earpieces, which can reduce the adverse effects of vibration and are beneficial to the high-quality transmission of audio signals.
一般判定金属合金阻尼值标准认为:当阻尼值为Q -1≥0.01时,认为该金属合金为高阻尼合金。当前开发较为成熟的高阻尼镁合金体系有Mg-Zr,Mg-Ni及Mg-Cu-Mn体系,且多为铸造镁合金,虽然它们均具有较优异的阻尼性能,阻尼值可达0.05以上,但其力学性能较差,抗拉强度仅为150MPa左右,例如,Mg-3Cu-1Mn合金的阻尼内耗值Q -1可达0.1,但其抗拉强度仅为149MPa。另外Mg-Ni合金耐蚀性能较差限制了其应用前景。而当前应用较广泛的AZ系镁合金,其力学性能虽较高,耐蚀性能较好,但阻尼性能相比于其他高阻尼镁合金偏低近10倍。例如杨亚琴等人研究的AZ80+0.4%Ce镁合金,合金的抗拉强度可达250MPa以上,而阻尼内耗值仅为0.012左右。 The general standard for judging the damping value of a metal alloy is that: when the damping value is Q -1 ≥0.01, the metal alloy is considered to be a high damping alloy. Currently developed relatively mature high-damping magnesium alloy systems include Mg-Zr, Mg-Ni and Mg-Cu-Mn systems, and most of them are cast magnesium alloys. Although they all have excellent damping properties, the damping value can reach more than 0.05. However, its mechanical properties are poor, and its tensile strength is only about 150MPa. For example, the damping internal friction value Q -1 of Mg-3Cu-1Mn alloy can reach 0.1, but its tensile strength is only 149MPa. In addition, the poor corrosion resistance of Mg-Ni alloy limits its application prospects. While the currently widely used AZ magnesium alloys have higher mechanical properties and better corrosion resistance, their damping performance is nearly 10 times lower than that of other high-damping magnesium alloys. For example, the AZ80+0.4% Ce magnesium alloy studied by Yang Yaqin et al., the tensile strength of the alloy can reach more than 250MPa, while the damping internal friction value is only about 0.012.
稀土镁合金具有铸造性能好、耐蚀性能优异、力学性能较佳等优势,但高阻 尼稀土镁合金的研究还处于起步阶段,因此开发兼具优异力学性能及阻尼性能的高性能稀土镁合金对于丰富阻尼镁合金的种类及拓展镁合金的功能性具有重要的意义,同时可以为扩展镁合金的应用领域提供出路。Rare earth magnesium alloys have the advantages of good casting performance, excellent corrosion resistance and better mechanical properties. However, the research on high damping rare earth magnesium alloys is still in its infancy. Therefore, the development of high performance rare earth magnesium alloys with excellent mechanical properties and damping properties is very important Enriching the types of damping magnesium alloys and expanding the functionality of magnesium alloys is of great significance, and at the same time can provide a way out for expanding the application fields of magnesium alloys.
发明内容Summary of the invention
为了克服上述现有技术的缺点,本发明的目的在于提供一种LPSO相强化高阻尼稀土镁合金及其制备方法,该镁合金的LPSO相具有特殊的长周期结构,同时LPSO相对可动位错的存储能力可以提高合金的阻尼性能,达到优异力学性能和阻尼性能兼备的特性;通过该镁合金的制备方法获得的镁合金成品率高,加工成型性好,易于实现产业化,可以广泛应用在音箱及听筒等声音传播设备中。In order to overcome the above-mentioned shortcomings of the prior art, the purpose of the present invention is to provide an LPSO phase-strengthened high-damping rare earth magnesium alloy and a preparation method thereof. The storage capacity of the alloy can improve the damping performance of the alloy, and achieve the characteristics of both excellent mechanical properties and damping performance; the magnesium alloy obtained by the preparation method of the magnesium alloy has a high yield, good processing and formability, easy to realize industrialization, and can be widely used in In sound transmission equipment such as speakers and earpieces.
为了达到上述目的,本发明采用以下技术方案予以实现:In order to achieve the above objectives, the present invention adopts the following technical solutions to achieve:
本发明公开了一种LPSO相强化高阻尼稀土镁合金,所述镁合金原料组成及其重量百分比含量为:The invention discloses a LPSO phase strengthened high damping rare earth magnesium alloy. The raw material composition and weight percentage content of the magnesium alloy are as follows:
稀土元素:2.7~3.8%,Zn:0.8~1.2%,Mn:0.5~1.0%,余量为Mg。Rare earth elements: 2.7-3.8%, Zn: 0.8-1.2%, Mn: 0.5-1.0%, the balance is Mg.
优选地,所述稀土元素包括:Preferably, the rare earth element includes:
Y、Ce中的一种或两者的组合,Y在所述镁合金中的重量百分比含量为2.2~2.8%,Ce在所述镁合金中的重量百分比含量为0.5~1.0%。One of Y and Ce or a combination of the two, the weight percentage content of Y in the magnesium alloy is 2.2-2.8%, and the weight percentage content of Ce in the magnesium alloy is 0.5-1.0%.
优选地,所述Y和Zn的质量比为2.3~2.8。Preferably, the mass ratio of Y to Zn is 2.3 to 2.8.
本发明公开了一种上述LPSO相强化高阻尼稀土镁合金的制备方法,包括以下步骤:The invention discloses a preparation method of the above-mentioned LPSO phase strengthened high damping rare earth magnesium alloy, which comprises the following steps:
步骤一:以镁锭、Zn锭、镁稀土中间合金及MnCl 2颗粒为原料,按质量百分比进行称量备料; Step 1: Take magnesium ingots, Zn ingots, magnesium rare earth master alloys and MnCl 2 particles as raw materials, weigh and prepare materials according to mass percentage;
步骤二:将步骤一中的镁锭先预热干燥,然后将镁锭加热熔化形成镁液,将预热的Zn锭、镁稀土中间合金和MnCl 2颗粒依次加入镁液中,搅拌的同时添加 精炼剂熔炼,熔炼后除渣,最后采用半连续铸造工艺浇铸得到铸锭,即为LPSO相强化高阻尼稀土镁合金。 Step 2: Preheat and dry the magnesium ingot in Step 1, and then heat and melt the magnesium ingot to form a magnesium liquid. Add the preheated Zn ingot, magnesium rare earth intermediate alloy and MnCl 2 particles to the magnesium liquid in sequence, and add them while stirring The refining agent is smelted, the slag is removed after smelting, and finally the ingot is obtained by semi-continuous casting process, which is the LPSO phase strengthened high damping rare earth magnesium alloy.
优选地,步骤一中所述质量百分比为:Preferably, the mass percentage in step one is:
稀土元素:2.7~3.8%,Zn:0.8~1.2%,Mn:0.5~1.0%,余量为Mg。Rare earth elements: 2.7-3.8%, Zn: 0.8-1.2%, Mn: 0.5-1.0%, the balance is Mg.
优选地,步骤一中所述镁稀土中间合金为Mg-25Y中间合金和Mg-20Ce中间合金中的一种或两种的组合。Preferably, the magnesium rare earth master alloy in step 1 is one or a combination of Mg-25Y master alloy and Mg-20Ce master alloy.
优选地,所述镁稀土中间合金中Y在所述镁合金中的重量百分比含量为2.2~2.8%,Ce在所述镁合金中的重量百分比含量为0.5~1.0%。Preferably, the weight percentage content of Y in the magnesium alloy in the magnesium rare earth master alloy is 2.2-2.8%, and the weight percentage content of Ce in the magnesium alloy is 0.5-1.0%.
优选地,步骤二中所述熔炼工艺的温度为650~720℃,保温20~30min。Preferably, the temperature of the smelting process in step 2 is 650 to 720°C, and the temperature is maintained for 20 to 30 minutes.
优选地,步骤二所述熔炼工艺中所述精炼剂的添加量为1kg步骤一所述原料中添加精炼剂75~125g。Preferably, the addition amount of the refining agent in the smelting process of step two is 1 kg and 75-125 g of the refining agent is added to the raw material of step one.
优选地,步骤一中所述镁锭中镁的含量大于99.5wt%,所述Zn锭中Zn的含量大于99.5wt%。Preferably, in step 1, the content of magnesium in the magnesium ingot is greater than 99.5 wt%, and the content of Zn in the Zn ingot is greater than 99.5 wt%.
与现有技术相比,本发明具有以下有益效果:Compared with the prior art, the present invention has the following beneficial effects:
本发明公开了一种LPSO相强化高阻尼稀土镁合金,该镁合金采用Mg-RE(稀土元素)-Zn系合金配方,RE多以网状晶界硬脆相存在,通过调整RE元素和Zn元素的比例,获得了具有高强度、高阻尼的稀土镁合金;微量Mn元素的添加一方面可以去除有害杂质元素Fe,另一方面可以细化晶粒。The invention discloses a LPSO phase reinforced high damping rare earth magnesium alloy. The magnesium alloy adopts a Mg-RE (rare earth element)-Zn series alloy formula. RE mostly exists as a hard and brittle phase at the network grain boundary. The RE element and Zn are adjusted. The ratio of the elements obtains a rare earth magnesium alloy with high strength and high damping; on the one hand, the addition of trace Mn element can remove the harmful impurity element Fe, on the other hand, it can refine the grain.
进一步地,通过组合轻稀土元素Ce和重稀土元素Y,发挥轻重稀土的综合强化效果。由于轻重稀土固溶度的不同,固溶度较小的轻稀土元素可以优先聚集于凝固界面前沿,细化晶粒,实现细晶强化的效果。重稀土元素的固溶度较大,可以固溶于镁基体中,改善晶格常数c/a的比例,增加基面外其他滑移系的启动概率,从而在发挥固溶强化的同时,改善合金塑性。Furthermore, by combining the light rare earth element Ce and the heavy rare earth element Y, the comprehensive strengthening effect of the light and heavy rare earths is exerted. Due to the difference in the solid solubility of light and heavy rare earths, light rare earth elements with smaller solid solubility can preferentially gather at the front of the solidification interface to refine the grains and achieve the effect of fine-grain strengthening. The solid solubility of heavy rare earth elements is large, and they can be dissolved in the magnesium matrix to improve the ratio of lattice constant c/a, and increase the probability of starting other slip systems outside the base surface, so as to achieve solid solution strengthening while improving Alloy plasticity.
进一步地,镁合金在凝固过程中形成共晶相的种类取决于Y元素和Zn元素 的比例,当合金中的Y/Zn的质量比大于2.2时,获得微观组织中的主要析出相为LPSO相,因此通过控制重稀土元素Y和Zn的质量比在2.3~2.8范围内,可以获得LPSO相(也称为X-相)为主要析出相的稀土镁合金。LPSO相在通过阻碍位错运动发挥第二相强化的同时,其自身塑性变形的能力可以减缓应力集中,提高合金塑性,因此LPSO相近年来被公认为是改善镁合金综合力学性能的有效强化相,在提高强度的同时也有益于改善合金的塑性。镁合金的阻尼机制为位错型阻尼机制,合金中可动位错数量的增加可以提高阻尼性能。因LPSO相具有存储位错的能力,其自身的变形可以有效增加可动位错的数量,有益于能量的吸收,增加内耗值,可以提升镁合金的阻尼性能。另外,固溶于镁基体中的Y元素可以通过阻碍可动位错,经过钉扎、脱钉的过程,形成位错滞后环,进而提高合金的阻尼性能。通过力学行能及阻尼性能测试结果得知,该合金不仅展示出优异的综合力学性能,同时也具有较高的阻尼性能。Furthermore, the type of eutectic phase formed in the magnesium alloy during solidification depends on the ratio of Y element to Zn element. When the mass ratio of Y/Zn in the alloy is greater than 2.2, the main precipitated phase in the microstructure obtained is the LPSO phase. Therefore, by controlling the mass ratio of heavy rare earth elements Y and Zn in the range of 2.3 to 2.8, a rare earth magnesium alloy with LPSO phase (also called X-phase) as the main precipitation phase can be obtained. While the LPSO phase exerts the strengthening of the second phase by hindering the movement of dislocations, its own plastic deformation ability can slow down the stress concentration and improve the plasticity of the alloy. Therefore, the LPSO phase has been recognized as an effective strengthening phase for improving the comprehensive mechanical properties of magnesium alloys in recent years. While improving the strength, it is also beneficial to improve the plasticity of the alloy. The damping mechanism of magnesium alloy is a dislocation type damping mechanism, and the increase in the number of movable dislocations in the alloy can improve the damping performance. Because the LPSO phase has the ability to store dislocations, its own deformation can effectively increase the number of movable dislocations, which is beneficial to energy absorption, increases the internal friction value, and can improve the damping performance of the magnesium alloy. In addition, the Y element solid dissolved in the magnesium matrix can form a dislocation hysteresis loop through the process of pinning and unpinning by hindering the movable dislocation, thereby improving the damping performance of the alloy. Through the mechanical performance and damping performance test results, it is known that the alloy not only exhibits excellent comprehensive mechanical properties, but also has high damping performance.
本发明还公开了一种LPSO相强化高阻尼稀土镁合金的制备方法,该方法通过合理的加热熔化及半连续铸造工艺获得一系列具有LPSO结构的高阻尼稀土镁合金,该镁合金抗拉强度Engineering stress可达180MPa,伸长率Engineering strain可达10%以上,阻尼内耗值
Figure PCTCN2020121107-appb-000001
可达0.065。
The invention also discloses a preparation method of LPSO phase-strengthened high-damping rare-earth magnesium alloy. The method obtains a series of high-damping rare-earth magnesium alloys with LPSO structure through reasonable heating and melting and semi-continuous casting processes. The tensile strength of the magnesium alloy is Engineering stress can reach 180MPa, the elongation Engineering strain can reach more than 10%, and the internal friction value of damping
Figure PCTCN2020121107-appb-000001
Up to 0.065.
本发明的镁合金可以高效发挥稀土元素在镁合金中高阻尼的功能性,同时也具有优异的综合力学性能,易于实现产业化,可以广泛应用于声音传播设备元件中。The magnesium alloy of the present invention can efficiently exert the high damping functionality of rare earth elements in the magnesium alloy, and at the same time has excellent comprehensive mechanical properties, is easy to realize industrialization, and can be widely used in sound transmission equipment components.
附图说明Description of the drawings
图1a为实施例一镁合金的SEM图;Figure 1a is an SEM image of a magnesium alloy in Example 1;
图1b为实施例二镁合金的SEM图;Figure 1b is an SEM image of the magnesium alloy in Example 2;
图1c为实施例三镁合金的SEM图;Figure 1c is an SEM image of the magnesium alloy of Example 3;
图1d为对比例一镁合金的SEM图;Figure 1d is an SEM image of a magnesium alloy in Comparative Example 1;
图1e为对比例二镁合金的SEM图;Figure 1e is an SEM image of a comparative example of two magnesium alloys;
图2为实施例和对比例镁合金的阻尼性能测试曲线图;Figure 2 is a graph showing the damping performance test curve of the magnesium alloy of the embodiment and the comparative example;
图3为实施例和对比例镁合金的拉伸性能测试曲线图。Fig. 3 is a graph showing the tensile properties of magnesium alloys of Examples and Comparative Examples.
具体实施方式Detailed ways
为了使本技术领域的人员更好地理解本发明方案,下面将结合本发明实施及附图,对本发明实施例中的技术方案进行清楚、完整地描述,显然,所描述的实施例仅仅是本发明一部分的实施例,而不是全部的实施例。基于本发明中的实施例,本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例,都应当属于本发明保护的范围。In order to enable those skilled in the art to better understand the solutions of the present invention, the technical solutions in the embodiments of the present invention will be clearly and completely described below in conjunction with the implementation of the present invention and the accompanying drawings. Obviously, the described embodiments are only the present invention. Invented a part of the embodiments, but not all the embodiments. Based on the embodiments of the present invention, all other embodiments obtained by those of ordinary skill in the art without creative work shall fall within the protection scope of the present invention.
需要说明的是,本发明的说明书和权利要求书及上述附图中的术语“第一”、“第二”等是用于区别类似的对象,而不必用于描述特定的顺序或先后次序。应该理解这样使用的数据在适当情况下可以互换,以便这里描述的本发明的实施例能够以除了在这里图示或描述的那些以外的顺序实施。此外,术语“包括”和“具有”以及他们的任何变形,意图在于覆盖不排他的包含,例如,包含了一系列步骤或单元的过程、方法、系统、产品或设备不必限于清楚地列出的那些步骤或单元,而是可包括没有清楚地列出的或对于这些过程、方法、产品或设备固有的其它步骤或单元。It should be noted that the terms “first” and “second” in the description and claims of the present invention and the above-mentioned drawings are used to distinguish similar objects, and not necessarily used to describe a specific sequence or sequence. It should be understood that the data used in this way can be interchanged under appropriate circumstances so that the embodiments of the present invention described herein can be implemented in a sequence other than those illustrated or described herein. In addition, the terms "including" and "having" and any variations of them are intended to cover non-exclusive inclusions. For example, a process, method, system, product, or device that includes a series of steps or units is not necessarily limited to those clearly listed. Those steps or units may include other steps or units that are not clearly listed or are inherent to these processes, methods, products, or equipment.
下面结合附图对本发明做进一步详细描述:The present invention will be further described in detail below in conjunction with the accompanying drawings:
实施例中所述精炼剂原料组成及其重量百分比含量为:55%~60%的KCl、2%~5%的CaF 2,其余为BaCl 2,精炼剂的添加量为每1kg原料中添加75-125g。 The composition of the raw material of the refining agent and its weight percentage content are: 55%-60% KCl, 2%-5% CaF 2 , the rest is BaCl 2 , the amount of refining agent added is 75 per kg of raw material -125g.
实施例一Example one
本实施例提供了一种LPSO相强化高阻尼稀土镁合金,原料组成及其重量百分比含量为:稀土元素:2.7%,Zn:0.8%,Mn:0.5%,余量为Mg。This embodiment provides an LPSO phase strengthened high damping rare earth magnesium alloy. The raw material composition and weight percentage content are: rare earth element: 2.7%, Zn: 0.8%, Mn: 0.5%, and the balance is Mg.
本实施例的稀土元素包括Y和Ce,Y在镁合金中的重量百分比含量为2.2%,Ce在镁合金中的重量百分比含量为0.5%。其中Y和Zn的质量比为2.75。The rare earth elements in this embodiment include Y and Ce, the weight percentage of Y in the magnesium alloy is 2.2%, and the weight percentage of Ce in the magnesium alloy is 0.5%. The mass ratio of Y and Zn is 2.75.
该LPSO相强化高阻尼稀土镁合金的制备方法,包括以下步骤:The preparation method of the LPSO phase strengthened high damping rare earth magnesium alloy includes the following steps:
步骤一:以纯镁锭(99.5wt%以上)、纯Zn锭(99.5wt%以上)、Mg-25Y中间合金(即该中间合金的成分含量为:25wt%Y,余量为Mg)和Mg-20Ce中间合金及MnCl 2颗粒为原料,按Y 2.2wt%、Ce 0.5wt%、Zn 0.8wt%、Mn 0.5wt%、余量为Mg的质量百分比进行称量备料,原料总量为1kg; Step 1: Use pure magnesium ingot (99.5wt% or more), pure Zn ingot (99.5wt% or more), Mg-25Y master alloy (that is, the composition content of the master alloy is: 25wt% Y, the balance is Mg) and Mg- 20Ce master alloy and MnCl 2 particles as raw materials, weigh and prepare the materials according to the mass percentage of Y 2.2wt%, Ce 0.5wt%, Zn 0.8wt%, Mn 0.5wt%, and the balance Mg, the total amount of raw materials is 1kg;
步骤二:将步骤一中的纯镁锭先在180℃下预热干燥,然后将纯镁锭置于电阻炉内的坩埚中加热到650℃逐渐熔化,待镁锭完全熔化后形成镁液,将180℃预热的纯Zn锭、Mg-25Y中间合金、Mg-20Ce中间合金和MnCl 2颗粒依次加入镁液中熔炼,搅拌的同时缓慢添加精炼剂75g,将熔炼温度控制在720℃,保温30min,除渣后采用半连续铸造工艺浇铸得到铸锭,即为LPSO相强化高阻尼稀土镁合金。 Step 2: Preheat and dry the pure magnesium ingots in step 1 at 180°C, then heat the pure magnesium ingots in a crucible in a resistance furnace to 650°C and gradually melt them. After the magnesium ingots are completely melted, a magnesium liquid will be formed. The pure Zn ingot preheated at 180℃, Mg-25Y master alloy, Mg-20Ce master alloy and MnCl 2 particles are added to the magnesium liquid for smelting. While stirring, slowly add 75g of refining agent, control the smelting temperature at 720℃, and keep warm. 30min, after removing the slag, the semi-continuous casting process is used to cast the ingot, which is an LPSO phase strengthened high damping rare earth magnesium alloy.
本实施例获得的LPSO相强化高阻尼稀土镁合金,扫描图如图1a所示,采用DMA850对合金阻尼性能进行测试,该合金在室温下阻尼值可达0.065;采用MTS810力学测试系统对合金力学性能进行测试,合金抗拉强度为187MPa,伸长率为10.0%。The LPSO phase-strengthened high-damping rare earth magnesium alloy obtained in this example is scanned as shown in Fig. 1a. The damping performance of the alloy is tested by DMA850, and the damping value of the alloy can reach 0.065 at room temperature; the MTS810 mechanical test system is used for the alloy mechanics The performance is tested, the tensile strength of the alloy is 187MPa, and the elongation is 10.0%.
实施例二Example two
本实施例提供了一种LPSO相强化高阻尼稀土镁合金,原料组成及其重量百分比含量为:稀土元素:3.2%,Zn:1.0%,Mn:0.6%,余量为Mg。This embodiment provides an LPSO phase strengthened high damping rare earth magnesium alloy. The raw material composition and weight percentage content are: rare earth element: 3.2%, Zn: 1.0%, Mn: 0.6%, and the balance is Mg.
本实施例的稀土元素包括Y和Ce,Y在镁合金中的重量百分比含量为2.5%,Ce在镁合金中的重量百分比含量为0.8%。其中Y和Zn的质量比为2.5。The rare earth elements in this embodiment include Y and Ce, the weight percentage of Y in the magnesium alloy is 2.5%, and the weight percentage of Ce in the magnesium alloy is 0.8%. The mass ratio of Y and Zn is 2.5.
该LPSO相强化高阻尼稀土镁合金的制备方法,包括以下步骤:The preparation method of the LPSO phase strengthened high damping rare earth magnesium alloy includes the following steps:
步骤一:以纯镁锭(99.5wt%以上)、纯Zn锭(99.5wt%以上)、Mg-25Y中 间合金和Mg-20Ce中间合金及MnCl 2颗粒为原料,按Y 2.5wt%、Ce 0.8wt%、Zn 1.0wt%、Mn 0.6wt%、余量为Mg的重量百分比进行称量备料,原料总量为1kg; Step 1: Use pure magnesium ingot (99.5wt% or more), pure Zn ingot (99.5wt% or more), Mg-25Y master alloy, Mg-20Ce master alloy and MnCl 2 particles as raw materials, according to Y 2.5wt%, Ce 0.8wt %, Zn 1.0wt%, Mn 0.6wt%, and the balance is the weight percentage of Mg. The total amount of raw materials is 1kg;
步骤二:将步骤一中的纯镁锭先在230℃下预热干燥,然后将纯镁锭置于电阻炉内的坩埚中加热到680℃逐渐熔化,待镁锭完全熔化后形成镁液,将230℃预热的纯Zn锭、Mg-25Y中间合金、Mg-20Ce中间合金和MnCl 2颗粒依次加入镁液中熔炼,搅拌的同时添加精炼剂熔炼100g,熔炼温度为680℃,保温25min,除渣后采用半连续铸造工艺浇铸得到铸锭,即为LPSO相强化高阻尼稀土镁合金。 Step 2: Preheat and dry the pure magnesium ingots in step one at 230°C, then heat the pure magnesium ingots in a crucible in a resistance furnace to 680°C and gradually melt them, and form magnesium liquid after the magnesium ingots are completely melted. The pure Zn ingots, Mg-25Y master alloy, Mg-20Ce master alloy and MnCl 2 particles preheated at 230℃ are added to the magnesium liquid for smelting. While stirring, the refining agent is added to smelt 100g, the smelting temperature is 680℃, and the holding time is 25min. After slag removal, a semi-continuous casting process is used to cast an ingot, which is an LPSO phase strengthened high damping rare earth magnesium alloy.
本实施例获得的LPSO相强化高阻尼稀土镁合金,扫描图如图1b所示,采用DMA850对合金阻尼性能进行测试,该合金在室温下阻尼值可达0.068;采用MTS810力学测试系统对合金力学性能进行测试,合金抗拉强度为185MPa,伸长率为10.2%。The LPSO phase-strengthened high-damping rare earth magnesium alloy obtained in this example is scanned as shown in Fig. 1b. The damping performance of the alloy is tested by DMA850, and the damping value of the alloy can reach 0.068 at room temperature; the MTS810 mechanical test system is used for the alloy mechanics The performance was tested, the alloy's tensile strength was 185MPa, and the elongation was 10.2%.
实施例三Example three
本实施例提供了一种LPSO相强化高阻尼稀土镁合金,原料组成及其重量百分比含量为:稀土元素:3.8%,Zn:1.2%,Mn:1.0%,余量为Mg。This embodiment provides an LPSO phase strengthened high damping rare earth magnesium alloy. The raw material composition and weight percentage content are: rare earth element: 3.8%, Zn: 1.2%, Mn: 1.0%, and the balance is Mg.
本实施例的稀土元素包括Y和Ce,Y在镁合金中的重量百分比含量为2.8%,Ce在镁合金中的重量百分比含量为1.0%。其中Y和Zn的质量比约为2.33。The rare earth elements in this embodiment include Y and Ce, the weight percentage of Y in the magnesium alloy is 2.8%, and the weight percentage of Ce in the magnesium alloy is 1.0%. The mass ratio of Y and Zn is about 2.33.
该LPSO相强化高阻尼稀土镁合金的制备方法,包括以下步骤:The preparation method of the LPSO phase strengthened high damping rare earth magnesium alloy includes the following steps:
步骤一:以纯镁锭(99.5wt%以上)、纯Zn锭(99.5wt%以上)、Mg-25Y中间合金和Mg-20Ce中间合金及MnCl 2颗粒为原料,按Y 2.8wt%、Ce 1.0wt%、Zn 1.2wt%、Mn 1.0wt%、余量为Mg的重量百分比进行称量备料,原料总量为1kg; Step 1: Use pure magnesium ingot (99.5wt% or more), pure Zn ingot (99.5wt% or more), Mg-25Y master alloy, Mg-20Ce master alloy and MnCl 2 particles as raw materials, according to Y 2.8wt%, Ce 1.0wt %, Zn 1.2wt%, Mn 1.0wt%, and the balance is the weight percentage of Mg. The total amount of raw materials is 1kg;
步骤二:将步骤一中的纯镁锭先在230℃下预热干燥,然后将纯镁锭置于电阻炉内的坩埚中加热到680℃逐渐熔化,待镁锭完全熔化后形成镁液,将230℃预热的纯Zn锭、Mg-25Y中间合金、Mg-20Ce中间合金和MnCl 2颗粒依次加入镁液中熔炼,搅拌的同时缓慢添加精炼剂125g,熔炼温度为650℃,保温20min, 除渣后采用半连续铸造工艺浇铸得到铸锭,即为LPSO相强化高阻尼稀土镁合金。 Step 2: Preheat and dry the pure magnesium ingots in step one at 230°C, then heat the pure magnesium ingots in a crucible in a resistance furnace to 680°C and gradually melt them, and form magnesium liquid after the magnesium ingots are completely melted. The pure Zn ingots, Mg-25Y master alloy, Mg-20Ce master alloy and MnCl 2 particles preheated at 230℃ are added to the magnesium liquid for smelting. Slowly add 125g refining agent while stirring. The smelting temperature is 650℃ and the temperature is kept for 20min. After slag removal, a semi-continuous casting process is used to cast an ingot, which is an LPSO phase strengthened high damping rare earth magnesium alloy.
本实施例获得的LPSO相强化高阻尼稀土镁合金,扫描图如图1c所示,采用DMA850对合金阻尼性能进行测试,该合金在室温下阻尼值可达0.071;采用MTS810力学测试系统对合金力学性能进行测试,合金抗拉强度为181MPa,伸长率为10.9%。The LPSO phase-strengthened high damping rare earth magnesium alloy obtained in this example is scanned as shown in Fig. 1c. The damping performance of the alloy is tested by DMA850, and the damping value of the alloy can reach 0.071 at room temperature; the MTS810 mechanical test system is used for the alloy mechanics The performance was tested, the alloy's tensile strength was 181MPa, and the elongation was 10.9%.
对比例一Comparative example one
本对比例一提供了一种含W相强化稀土镁合金,原料组成及其重量百分比含量为:稀土元素:3.5%,Zn:4.6%,Mn:0.6%,余量为Mg。The first comparative example provides a W-phase reinforced rare earth magnesium alloy. The raw material composition and weight percentage content are: rare earth element: 3.5%, Zn: 4.6%, Mn: 0.6%, and the balance is Mg.
本实施例的稀土元素包括Y和Ce,Y在镁合金中的重量百分比含量为2.5%,Ce在镁合金中的重量百分比含量为1.0%。其中Y和Zn的质量比为0.54。The rare earth elements in this embodiment include Y and Ce, the weight percentage of Y in the magnesium alloy is 2.5%, and the weight percentage of Ce in the magnesium alloy is 1.0%. The mass ratio of Y and Zn is 0.54.
该含W相强化稀土镁合金的制备方法,包括以下步骤:The preparation method of the W-containing phase strengthened rare earth magnesium alloy includes the following steps:
步骤一:以纯镁锭(99.5wt%以上)、纯Zn锭(99.5wt%以上),Mg-25Y中间合金和Mg-20Ce中间合金及MnCl 2颗粒为原料,按Y 2.5wt%、Ce 1.0wt%、Zn 4.6wt%、Mn 0.6wt%、余量为Mg的重量百分比进行称量备料,原料总量为1kg; Step 1: Use pure magnesium ingot (99.5wt% or more), pure Zn ingot (99.5wt% or more), Mg-25Y master alloy, Mg-20Ce master alloy and MnCl 2 particles as raw materials, according to Y 2.5wt%, Ce 1.0wt %, Zn 4.6wt%, Mn 0.6wt%, and the balance is the weight percentage of Mg for weighing and preparing materials, the total amount of raw materials is 1kg;
步骤二:将步骤一中的纯镁锭先在180℃下预热干燥,然后将纯镁锭置于电阻炉内的坩埚中加热到650℃逐渐熔化,待镁锭完全熔化后形成镁液,将180℃预热的纯Zn锭、Mg-25Y中间合金、Mg-20Ce中间合金和MnCl 2颗粒依次加入镁液中熔炼,搅拌的同时缓慢添加精炼剂120g,熔炼温度为700℃,保温25min,除渣后采用半连续铸造工艺浇铸得到铸锭,即为含W相强化稀土镁合金。 Step 2: Preheat and dry the pure magnesium ingots in step 1 at 180°C, then heat the pure magnesium ingots in a crucible in a resistance furnace to 650°C and gradually melt them. After the magnesium ingots are completely melted, a magnesium liquid will be formed. The pure Zn ingot, Mg-25Y master alloy, Mg-20Ce master alloy and MnCl 2 particles preheated at 180℃ are added to the magnesium liquid for smelting. Slowly add 120g of refining agent while stirring. The smelting temperature is 700℃ and the temperature is kept for 25min. After slag removal, a semi-continuous casting process is used to cast to obtain an ingot, which is a W-phase reinforced rare earth magnesium alloy.
本实施例获得的W相强化的稀土镁合金,扫描图如图1d所示,采用DMA850对合金阻尼性能进行测试,该合金在室温下阻尼值可达0.027;采用MTS810力学测试系统对合金力学性能进行测试,合金抗拉强度为196MPa,伸长率为8.7%。The scan diagram of the W-phase reinforced rare earth magnesium alloy obtained in this example is shown in Figure 1d. The damping performance of the alloy is tested by DMA850, and the damping value of the alloy can reach 0.027 at room temperature; the mechanical properties of the alloy are measured by the MTS810 mechanical test system When tested, the alloy has a tensile strength of 196MPa and an elongation of 8.7%.
对比例二Comparative example two
本对比例二提供了一种含Mg-RE相的稀土镁合金,原料组成及其重量百分 比含量为:稀土元素:3.8%,Mn:1.0%,余量为Mg。The second comparative example provides a rare earth magnesium alloy containing Mg-RE phase. The raw material composition and weight percentage content are: rare earth element: 3.8%, Mn: 1.0%, and the balance is Mg.
本实施例的稀土元素包括Y和Ce,Y在镁合金中的重量百分比含量为2.8%,Ce在镁合金中的重量百分比含量为1.0%。其中Y和Zn的质量比为0.54。The rare earth elements in this embodiment include Y and Ce, the weight percentage of Y in the magnesium alloy is 2.8%, and the weight percentage of Ce in the magnesium alloy is 1.0%. The mass ratio of Y and Zn is 0.54.
该含Mg-RE相的稀土镁合金的制备方法,包括以下步骤:The preparation method of the rare earth magnesium alloy containing Mg-RE phase includes the following steps:
步骤一:以纯镁锭(99.5wt%以上)、Mg-25Y中间合金和Mg-20Ce中间合金及MnCl 2颗粒为原料,按Y 2.8wt%、Ce 1.0wt%、Mn 1.0wt%、余量为Mg的重量百分比进行称量备料,原料总量为1kg; Step 1: Take pure magnesium ingot (above 99.5wt%), Mg-25Y master alloy, Mg-20Ce master alloy and MnCl 2 particles as raw materials, according to Y 2.8wt%, Ce 1.0wt%, Mn 1.0wt%, the balance is The weight percentage of Mg is weighed and prepared, and the total amount of raw materials is 1kg;
步骤二:将步骤一中的纯镁锭先在230℃下预热干燥,然后将纯镁锭置于电阻炉内的坩埚中加热到680℃逐渐熔化,待镁锭完全熔化后形成镁液,将230℃预热的Mg-25Y中间合金、Mg-20Ce中间合金和MnCl 2颗粒依次加入镁液中熔炼,搅拌的同时缓慢添加精炼剂110g,熔炼温度为650℃,保温20min,除渣后采用半连续铸造工艺浇铸得到铸锭,即为含Mg-RE相的稀土镁合金。 Step 2: Preheat and dry the pure magnesium ingots in step one at 230°C, then heat the pure magnesium ingots in a crucible in a resistance furnace to 680°C and gradually melt them, and form magnesium liquid after the magnesium ingots are completely melted. Mg-25Y master alloy, Mg-20Ce master alloy and MnCl 2 particles preheated at 230℃ were added to the magnesium liquid for smelting. While stirring, slowly add 110g refining agent. The smelting temperature was 650℃ and the temperature was kept for 20 minutes. The semi-continuous casting process is cast to obtain an ingot, which is a rare earth magnesium alloy containing Mg-RE phase.
本实施例获得的Mg-RE相强化的稀土镁合金,扫描图如图1e所示,采用DMA850对合金阻尼性能进行测试,该合金在室温下阻尼值可达0.060;采用MTS810力学测试系统对合金力学性能进行测试,合金抗拉强度为138MPa,伸长率为6.9%。The Mg-RE phase-strengthened rare earth magnesium alloy obtained in this example is scanned as shown in Fig. 1e. The damping performance of the alloy is tested by DMA850, and the damping value of the alloy can reach 0.060 at room temperature; the MTS810 mechanical test system is used for the alloy The mechanical properties were tested, and the alloy's tensile strength was 138MPa, and the elongation was 6.9%.
所有实施例的主要化学组分及制备参数如表1:The main chemical components and preparation parameters of all the examples are shown in Table 1:
表1实施例镁合金主要化学组分及制备参数Table 1 The main chemical components and preparation parameters of the magnesium alloy of the embodiment
合金alloy Y/%Y/% Ce/%Ce/% Zn/%Zn/% Mn/%Mn/% MgMg 熔炼温度/℃Melting temperature/℃ 保温时间Holding time
实施例1Example 1 2.22.2 0.50.5 0.80.8 0.50.5 余量margin 720720 3030
实施例2Example 2 2.52.5 0.80.8 1.01.0 0.60.6 余量margin 680680 2525
实施例3Example 3 2.82.8 1.01.0 1.21.2 1.01.0 余量margin 650650 2020
对比例1Comparative example 1 2.52.5 1.01.0 4.64.6 0.60.6 余量margin 680680 2525
对比例2Comparative example 2 2.82.8 1.01.0 00 1.01.0 余量margin 650650 2020
综上所述,参照图1a、图1b、图1c、图1d、图1e和图2,比较实施例二和对比例一,当原料配比中配方发生改变时,得到的实施例二中的镁合金含有LPSO相,而对比例一中的镁合金不含有LPSO相,含有W-相,实施例二和对比例一在合金具有相当的综合力学性能的同时,实施例二中镁合金的阻尼性能远高于对比例一中的W相强化的稀土镁合金。To sum up, referring to Figure 1a, Figure 1b, Figure 1c, Figure 1d, Figure 1e and Figure 2, compare Example 2 with Comparative Example 1. When the formulation of the raw materials is changed, the obtained Example 2 The magnesium alloy contains LPSO phase, while the magnesium alloy in Comparative Example 1 does not contain LPSO phase and contains W-phase. While the alloys in Example 2 and Comparative Example 1 have considerable comprehensive mechanical properties, the damping of the magnesium alloy in Example 2 The performance is much higher than that of the W-phase strengthened rare earth magnesium alloy in Comparative Example 1.
参照图1a、图1b、图1c、图1d、图1e、图2和图3,比较实施例三和对比例二,当原料配比中配方发生改变时,得到的实施例三中的镁合金含有LPSO相,而对比例二中的镁合金不含有LPSO相,含有少量Mg-RE相,实施例三和对比例二在合金具有相当的阻尼性能时,实施例三中镁合金的抗拉强度和伸长率远高于对比例二中含有Mg-RE相的稀土镁合金。Referring to Figure 1a, Figure 1b, Figure 1c, Figure 1d, Figure 1e, Figure 2 and Figure 3, compare Example 3 and Comparative Example 2. When the formula in the raw material ratio is changed, the magnesium alloy in Example 3 is obtained Contains LPSO phase, while the magnesium alloy in Comparative Example 2 does not contain LPSO phase and contains a small amount of Mg-RE phase. The tensile strength of the magnesium alloy in Example 3 and Comparative Example 2 when the alloy has comparable damping properties And the elongation is much higher than that of the rare earth magnesium alloy containing Mg-RE phase in Comparative Example 2.
以上内容仅为说明本发明的技术思想,不能以此限定本发明的保护范围,凡是按照本发明提出的技术思想,在技术方案基础上所做的任何改动,均落入本发明权利要求书的保护范围之内。The above content is only to illustrate the technical ideas of the present invention, and cannot be used to limit the scope of protection of the present invention. Any changes made on the basis of the technical solutions based on the technical ideas proposed by the present invention fall into the claims of the present invention. Within the scope of protection.

Claims (10)

  1. 一种LPSO相强化高阻尼稀土镁合金,其特征在于,所述镁合金原料组成及其重量百分比含量为:An LPSO phase strengthened high damping rare earth magnesium alloy, characterized in that the raw material composition of the magnesium alloy and its weight percentage content are:
    稀土元素:2.7~3.8%,Zn:0.8~1.2%,Mn:0.5~1.0%,余量为Mg。Rare earth elements: 2.7-3.8%, Zn: 0.8-1.2%, Mn: 0.5-1.0%, the balance is Mg.
  2. 根据权利要求1所述的一种LPSO相强化高阻尼稀土镁合金,其特征在于,所述稀土元素包括:The LPSO phase strengthened high damping rare earth magnesium alloy according to claim 1, wherein the rare earth element comprises:
    Y、Ce中的一种或两者的组合,Y在所述镁合金中的重量百分比含量为2.2~2.8%,Ce在所述镁合金中的重量百分比含量为0.5~1.0%。One of Y and Ce or a combination of the two, the weight percentage content of Y in the magnesium alloy is 2.2-2.8%, and the weight percentage content of Ce in the magnesium alloy is 0.5-1.0%.
  3. 根据权利要求2所述的一种LPSO相强化高阻尼稀土镁合金,其特征在于,所述Y和Zn的质量比为2.3~2.8。The LPSO phase strengthened high damping rare earth magnesium alloy according to claim 2, wherein the mass ratio of Y to Zn is 2.3 to 2.8.
  4. 一种制备权利要求1-3任意一项所述的LPSO相强化高阻尼稀土镁合金的方法,其特征在于,包括以下步骤:A method for preparing the LPSO phase strengthened high damping rare earth magnesium alloy according to any one of claims 1 to 3, characterized in that it comprises the following steps:
    步骤一:以镁锭、Zn锭、镁稀土中间合金及MnCl 2颗粒为原料,按质量百分比进行称量备料; Step 1: Take magnesium ingots, Zn ingots, magnesium rare earth master alloys and MnCl 2 particles as raw materials, weigh and prepare materials according to mass percentage;
    步骤二:将步骤一中的镁锭先预热干燥,然后将镁锭加热熔化形成镁液,将预热的Zn锭、镁稀土中间合金和MnCl 2颗粒依次加入镁液中,搅拌的同时添加精炼剂熔炼,熔炼后除渣,最后采用半连续铸造工艺浇铸得到铸锭,即为LPSO相强化高阻尼稀土镁合金。 Step 2: Preheat and dry the magnesium ingot in Step 1, and then heat and melt the magnesium ingot to form a magnesium liquid. Add the preheated Zn ingot, magnesium rare earth intermediate alloy and MnCl 2 particles to the magnesium liquid in sequence, and add them while stirring The refining agent is smelted, the slag is removed after smelting, and finally the ingot is obtained by semi-continuous casting process, which is the LPSO phase strengthened high damping rare earth magnesium alloy.
  5. 根据权利要求4所述的一种LPSO相强化高阻尼稀土镁合金的制备方法,其特征在于,步骤一中所述质量百分比为:The method for preparing an LPSO phase-strengthened high-damping rare earth magnesium alloy according to claim 4, wherein the mass percentage in step one is:
    稀土元素:2.7~3.8%,Zn:0.8~1.2%,Mn:0.5~1.0%,余量为Mg。Rare earth elements: 2.7-3.8%, Zn: 0.8-1.2%, Mn: 0.5-1.0%, the balance is Mg.
  6. 根据权利要求4所述的一种LPSO相强化高阻尼稀土镁合金的制备方法,其特征在于,步骤一中所述镁稀土中间合金为Mg-25Y中间合金和Mg-20Ce中间合金中的一种或两种的组合。The method for preparing an LPSO phase strengthened high damping rare earth magnesium alloy according to claim 4, wherein the magnesium rare earth master alloy in step one is one of Mg-25Y master alloy and Mg-20Ce master alloy Or a combination of the two.
  7. 根据权利要求6所述的一种LPSO相强化高阻尼稀土镁合金的制备方法, 其特征在于,所述镁稀土中间合金中Y在所述镁合金中的重量百分比含量为2.2~2.8%,Ce在所述镁合金中的重量百分比含量为0.5~1.0%。The method for preparing LPSO phase-strengthened high damping rare earth magnesium alloy according to claim 6, wherein the weight percentage content of Y in the magnesium alloy in the magnesium rare earth master alloy is 2.2 to 2.8%, and Ce The weight percentage content in the magnesium alloy is 0.5-1.0%.
  8. 根据权利要求4所述的一种LPSO相强化高阻尼稀土镁合金的制备方法,其特征在于,步骤二中熔炼工艺的温度为650~720℃,保温20~30min。The method for preparing an LPSO phase-strengthened high-damping rare earth magnesium alloy according to claim 4, characterized in that the temperature of the smelting process in step two is 650-720°C, and the holding time is 20-30 minutes.
  9. 根据权利要求4所述的一种LPSO相强化高阻尼稀土镁合金的制备方法,其特征在于,步骤二熔炼工艺中所述精炼剂的添加量为1kg步骤一所述原料中添加精炼剂75~125g。The method for preparing an LPSO phase-strengthened high-damping rare earth magnesium alloy according to claim 4, wherein the amount of the refining agent added in the smelting process of step 2 is 1 kg and the raw material of step 1 is added with a refining agent 75~ 125g.
  10. 根据权利要求4所述的一种LPSO相强化高阻尼稀土镁合金的制备方法,其特征在于,所述镁锭中镁的含量大于99.5wt%,所述Zn锭中Zn的含量大于99.5wt%。The method for preparing an LPSO phase-strengthened high-damping rare earth magnesium alloy according to claim 4, wherein the content of magnesium in the magnesium ingot is greater than 99.5% by weight, and the content of Zn in the Zn ingot is greater than 99.5% by weight .
PCT/CN2020/121107 2019-11-07 2020-10-15 Lpso phase fortified high-damping rare earth magnesium alloy and preparation method therefor WO2021088612A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN201911082720.6 2019-11-07
CN201911082720.6A CN110629090A (en) 2019-11-07 2019-11-07 LPSO phase-reinforced high-damping rare earth magnesium alloy and preparation method thereof

Publications (1)

Publication Number Publication Date
WO2021088612A1 true WO2021088612A1 (en) 2021-05-14

Family

ID=68979123

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/CN2020/121107 WO2021088612A1 (en) 2019-11-07 2020-10-15 Lpso phase fortified high-damping rare earth magnesium alloy and preparation method therefor

Country Status (2)

Country Link
CN (1) CN110629090A (en)
WO (1) WO2021088612A1 (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110629090A (en) * 2019-11-07 2019-12-31 西安交通大学 LPSO phase-reinforced high-damping rare earth magnesium alloy and preparation method thereof
CN111235450B (en) * 2020-01-16 2021-06-08 西安交通大学 LPSO phase reinforced degradable high-temperature magnesium alloy and preparation method thereof
CN112795827A (en) * 2020-12-15 2021-05-14 上大新材料(泰州)研究院有限公司 Rare earth high-thermal-conductivity magnesium alloy containing long-period stacking ordered phase and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101805864A (en) * 2010-04-06 2010-08-18 重庆大学 High-damping and high-strength Mg-Cu-Mn-Zn-Y alloy and manufacturing method thereof
CN106521278A (en) * 2016-12-29 2017-03-22 湘潭大学 High-strength magnesium-zinc-manganese-yttrium-cerium magnesium alloy and preparation method thereof
KR20190098880A (en) * 2018-02-14 2019-08-23 서울대학교산학협력단 Magnesium alloy plate and manufacturing method for the same
CN110629090A (en) * 2019-11-07 2019-12-31 西安交通大学 LPSO phase-reinforced high-damping rare earth magnesium alloy and preparation method thereof

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105220045A (en) * 2014-06-27 2016-01-06 朱丽兰 A kind of AZ91 magnesium alloy and preparation technology thereof adding Rare Earth Y or Ce
CN105316550B (en) * 2015-03-12 2019-01-25 华东交通大学 One kind high resistant damping magnesium alloy of phase containing long-periodic structure and preparation method thereof
WO2018083998A1 (en) * 2016-11-02 2018-05-11 国立大学法人 熊本大学 Bioabsorbable medical device and method for producing same

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101805864A (en) * 2010-04-06 2010-08-18 重庆大学 High-damping and high-strength Mg-Cu-Mn-Zn-Y alloy and manufacturing method thereof
CN106521278A (en) * 2016-12-29 2017-03-22 湘潭大学 High-strength magnesium-zinc-manganese-yttrium-cerium magnesium alloy and preparation method thereof
KR20190098880A (en) * 2018-02-14 2019-08-23 서울대학교산학협력단 Magnesium alloy plate and manufacturing method for the same
CN110629090A (en) * 2019-11-07 2019-12-31 西安交通大学 LPSO phase-reinforced high-damping rare earth magnesium alloy and preparation method thereof

Also Published As

Publication number Publication date
CN110629090A (en) 2019-12-31

Similar Documents

Publication Publication Date Title
WO2021088612A1 (en) Lpso phase fortified high-damping rare earth magnesium alloy and preparation method therefor
WO2020113713A1 (en) High strength and ductility casted aluminum-silicon alloy, manufacturing method for same, and applications thereof
CN111411247B (en) Composite treatment method for regenerated wrought aluminum alloy melt
CN111235450B (en) LPSO phase reinforced degradable high-temperature magnesium alloy and preparation method thereof
CN113584365B (en) Low-cost high-performance magnesium alloy and preparation method thereof
CN106676357B (en) A kind of high plastic magnesium alloy and preparation method thereof
CN110453115B (en) Novel automobile transmission shell die-casting aluminum alloy and preparation process thereof
CN108330360B (en) high-Zn-content high-strength-toughness extrusion deformation aluminum-lithium alloy and preparation method thereof
CN113061787A (en) High-strength high-toughness Al-Si-Cu-Mg-Cr-Mn-Ti series casting alloy and preparation method thereof
CN102002617B (en) Cast aluminum alloy for automobile and preparation method thereof
CN102296219A (en) Mg-Sn-Sr-based magnesium alloy with high strength and toughness and heat resistance
CN104928550A (en) High-strength and high-elasticity-modulus casting Mg alloy and preparation method thereof
CN104099502A (en) Magnesium lithium alloy, preparation method thereof and preparation method for magnesium lithium alloy plate
CN110819873A (en) High Nb-TiAl alloy added with nano yttrium oxide and preparation method thereof
CN111168054B (en) Special scandium-free Al-Mg-Mn alloy powder for high-strength aluminum alloy 3D printing and preparation method thereof
CN113684408B (en) High-strength and high-toughness cast magnesium alloy and preparation method thereof
CN114231800A (en) High-performance low-carbon aluminum alloy and preparation method thereof
CN107177764A (en) A kind of high strength and low cost cast magnesium alloy and preparation method thereof
CN114381628B (en) Refining agent and preparation method and application thereof
CN113652619A (en) Heat treatment strengthening and toughening method for low-energy hypoeutectic high-copper-content Al-Si-Cu-Mg cast alloy
CN106011567A (en) Magnesium alloy casting and preparation method thereof
CN110343921B (en) Multi-element multi-scale hybrid reinforced magnesium-lithium-based composite material and preparation method thereof
CN113862529A (en) Aluminum alloy and preparation method thereof
CN115261693B (en) High-strength high-heat-conductivity rare earth magnesium alloy
CN103695740A (en) High-plasticity heat-resistant magnesium alloy

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 20884684

Country of ref document: EP

Kind code of ref document: A1

NENP Non-entry into the national phase

Ref country code: DE

122 Ep: pct application non-entry in european phase

Ref document number: 20884684

Country of ref document: EP

Kind code of ref document: A1

32PN Ep: public notification in the ep bulletin as address of the adressee cannot be established

Free format text: NOTING OF LOSS OF RIGHTS PURSUANT TO RULE 112(1) EPC (EPO FORM 1205N DATED 29/06/2022)

122 Ep: pct application non-entry in european phase

Ref document number: 20884684

Country of ref document: EP

Kind code of ref document: A1