WO2021065520A1 - Agent for improving loosening properties of noodles - Google Patents

Agent for improving loosening properties of noodles Download PDF

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Publication number
WO2021065520A1
WO2021065520A1 PCT/JP2020/035132 JP2020035132W WO2021065520A1 WO 2021065520 A1 WO2021065520 A1 WO 2021065520A1 JP 2020035132 W JP2020035132 W JP 2020035132W WO 2021065520 A1 WO2021065520 A1 WO 2021065520A1
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WO
WIPO (PCT)
Prior art keywords
noodles
mass
less
loosening improver
component
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PCT/JP2020/035132
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French (fr)
Japanese (ja)
Inventor
海 山縣
采香 佐藤
千弘 石川
三四郎 齋藤
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株式会社J-オイルミルズ
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Application filed by 株式会社J-オイルミルズ filed Critical 株式会社J-オイルミルズ
Priority to JP2021550590A priority Critical patent/JPWO2021065520A1/ja
Publication of WO2021065520A1 publication Critical patent/WO2021065520A1/en

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    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L7/00Cereal-derived products; Malt products; Preparation or treatment thereof
    • A23L7/10Cereal-derived products
    • A23L7/109Types of pasta, e.g. macaroni or noodles
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L7/00Cereal-derived products; Malt products; Preparation or treatment thereof
    • A23L7/10Cereal-derived products
    • A23L7/109Types of pasta, e.g. macaroni or noodles
    • A23L7/113Parboiled or instant pasta

Definitions

  • the present invention relates to a loosening improver for noodles.
  • Patent Document 1 Japanese Unexamined Patent Publication No. 2018-85959.
  • the document describes that an aqueous dispersion containing modified starch and glycerin fatty acid ester having a viscosity of 100 mPa ⁇ s or less in a 10 mass% aqueous solution is adhered to the surface of noodles to improve the looseness of noodles. ing.
  • a loosening improver for noodles containing the following ingredient (A) as an active ingredient.
  • the low molecular weight starch of starch having an amylose content of 5% by mass or more is contained in an amount of 3% by mass or more and 45% by mass or less, and the peak molecular weight of the low molecular weight starch is 3 ⁇ 10 3 or more and 5 ⁇ 10 4 or less [6].
  • the content of the fraction under the sieve with a mesh opening of 0.5 mm is 40% by mass or more and 100% by mass or less [7]
  • Noodles are one kind selected from instant noodles and chilled noodles [1].
  • the loosening improver for noodles according to any one of the items.
  • Component (B) The loosening improver for noodles according to any one of [1] to [7], which further contains acetylated tapioca starch. [9] The loosening improver for noodles according to [8], wherein the content of the component (B) with respect to the content of the component (A) is 0.2 or more and 5 or less in terms of mass ratio. [10] The loosening improver for noodles according to [8] or [9], which is for instant noodles. [11] Ingredient (C): The loosening improver for noodles according to any one of [1] to [7], which further contains egg white.
  • a method for producing noodles which comprises a step of applying the loosening improver for noodles according to any one of [1] to [13] to noodles.
  • the step of applying the noodle loosening improver to noodles is a step of blending the noodle loosening improver into the noodle dough.
  • the method for producing noodles according to [14], wherein the step of applying the noodle loosening improver to noodles is a step of adding the noodle loosening improver to the surface of the noodles.
  • a method for improving noodle loosening which comprises applying the noodle loosening improver according to any one of [1] to [13] to noodles.
  • a method for shortening the reconstitution time of noodles at the time of eating which comprises applying the loosening improver for noodles according to any one of [1] to [13] to the noodles.
  • any combination of these configurations and the conversion of the expression of the present invention between methods, devices and the like are also effective as aspects of the present invention.
  • the noodles obtained by the method for producing noodles in the present invention are provided.
  • the use of the loosening improver for noodles in the present invention for producing noodles is provided.
  • noodles having excellent looseness can be obtained.
  • composition may contain each component alone or in combination of two or more.
  • the loosening improver for noodles contains the following component (A) as an active ingredient.
  • the component (A) is a powdery substance that satisfies the following conditions (1) and (2).
  • (1) Starch content is 75% by mass or more
  • Cold water swelling degree at 25 ° C is 5 or more and 40 or less
  • the component (A) is a powdery substance containing starch as a main component.
  • the powdery granular material includes at least one of the powdery material and the granular material, and may include both the powdery material and the granular material.
  • the component (A) contains 75% by mass or more of starch, preferably 80% by mass or more, more preferably 85% by mass, based on the whole noodle loosening improver, from the viewpoint of improving the loosening property of the noodles. Contains% by mass or more. Further, there is no limit to the upper limit of the starch content in the component (A), which is 100% by mass or less based on the total amount of the loosening improver for noodles, but 99.5% by mass or less depending on the properties of the noodles. It may be 99% by mass or less.
  • the cold water swelling degree of the component (A) is 5 or more, preferably 6 or more, and more preferably 6.5 or more. From the same viewpoint, the cold water swelling degree of the component (A) is 40 or less, preferably 35 or less, more preferably 20 or less, still more preferably 17 or less, still more preferably 13 or less, and even more preferably 12. Hereinafter, it is particularly preferably 11 or less.
  • the method for measuring the cold water swelling degree of the component (A) will be described in the section of Examples.
  • the starch is, for example, starch for foods, and various-derived starches can be used.
  • starch one or more kinds are appropriately selected from starches such as corn starch, potato starch, tapioca starch, wheat starch, rice starch; and processed starch obtained by chemically, physically or enzymatically processing these starches. be able to.
  • the starch is preferably one or more selected from tapioca starch, corn starch and rice starch, and more preferably one or more selected from tapioca starch and corn starch.
  • the raw material from which starch is derived is preferably one or more selected from the group consisting of cassava, corn and rice.
  • the component (A) preferably further satisfies the following condition (3) from the viewpoint of improving the looseness of the noodles and shortening the reconstitution time.
  • the peak molecular weight of the low molecular weight starch is preferably 3 ⁇ 10 3 or more, and more preferably 8 ⁇ 10 3 or more, from the viewpoint of improving the looseness of the noodles. From the same viewpoint, the peak molecular weight of the low molecular weight starch, preferably at 5 ⁇ 10 4 or less, more preferably 3 ⁇ 10 4 or less, more preferably 1.5 ⁇ 10 4 or less.
  • the method for measuring the peak molecular weight of the low molecular weight starch will be described in the section of Examples.
  • the amylose content in the raw material starch of the low molecular weight starch is preferably 5% by mass or more, more preferably 12% by mass or more, still more preferably 22% by mass or more, from the viewpoint of improving the looseness of the noodles. It is even more preferably 40% by mass or more, even more preferably 45% by mass or more, still more preferably 55% by mass or more, and particularly preferably 65% by mass or more.
  • the upper limit of the amylose content in the raw material starch of the low molecular weight starch is not limited, and is 100% by mass or less, preferably 90% by mass or less, and more preferably 80% by mass or less.
  • starch having an amylose content of 5% by mass or more which is a raw material of low molecular weight starch
  • corn starch such as high amylose corn starch and corn starch, tapioca starch, sweet potato starch, horse belly starch, wheat starch, high amylose wheat starch, rice starch, and
  • One or more selected from the group consisting of processed starch obtained by chemically, physically or enzymatically processing these raw materials can be used.
  • the starch having an amylose content of 5% by mass or more is one or more selected from high amylose cornstarch, cornstarch, and tapioca starch, and more preferably high amylose cornstarch. is there.
  • high amylose cornstarch for example, one having an amylose content of 40% by mass or more is available. Starch having an amylose content of 5% by mass or more is more preferably cornstarch having an amylose content of 40% by mass or more.
  • the content of the low molecular weight starch in the component (A) is preferably 3% by mass or more, more preferably 8% by mass or more, still more preferably 13% by mass or more, from the viewpoint of improving the looseness of the noodles. is there. From the same viewpoint, the content of the low molecular weight starch in the component (A) is preferably 45% by mass or less, more preferably 35% by mass or less, and further preferably 25% by mass or less.
  • the low molecular weight starch is preferably one or more selected from the group consisting of acid-treated starch, oxidation-treated starch and enzyme-treated starch from the viewpoint of excellent production stability, and more preferably. Is an acid-treated starch.
  • the conditions of acid treatment for obtaining acid-treated starch are not limited, and for example, the treatment can be carried out as follows. First, starch and water having an amylose content of 5% by mass or more, which are raw materials, are added to the reactor, and then an acid is further added. Alternatively, acid water in which an inorganic acid is previously dissolved in water and starch as a raw material are added to the reactor. From the viewpoint of more stable acid treatment, it is desirable that the total amount of starch in the reaction is uniformly dispersed in the aqueous phase or in a slurry state.
  • the concentration of the starch slurry in the acid treatment is adjusted to be, for example, 10% by mass or more and 50% by mass or less, preferably 20% by mass or more and 40% by mass or less. If the slurry concentration is too high, the slurry viscosity may increase, making it difficult to stir a uniform slurry.
  • the acid used for acid treatment include inorganic acids such as hydrochloric acid, sulfuric acid, and nitric acid, which can be used regardless of the type and purity.
  • the inorganic acid concentration during the acid treatment is preferably 0.05 normality (N) or more and 4N or less, and more preferably 0.1N or more and 4N or less, from the viewpoint of stably obtaining the acid-treated starch. It is preferably 0.2N or more and 3N or less, more preferably.
  • the reaction temperature is preferably 30 ° C. or higher and 70 ° C. or lower, more preferably 35 ° C. or higher and 70 ° C. or lower, further preferably 35 ° C. or higher and 65 ° C. or lower, and the reaction time is 0 from the same viewpoint. .5 hours or more and 120 hours or less is preferable, 1 hour or more and 72 hours or less is more preferable, and 1 hour or more and 48 hours or less is further preferable.
  • the component (A) contains low-molecular-weight starch
  • the component (A) contains low-molecular-weight starch and starch other than low-molecular-weight starch.
  • starch other than the low molecular weight starch in the component (A) for example, it can be selected and used from the above-mentioned starches.
  • the starch other than the low molecular weight starch in the component (A) is one or more selected from the group consisting of corn starch, wheat starch, potato starch, tapioca starch and cross-linked starch thereof.
  • component (A) one kind or two or more kinds selected from the group consisting of pregelatinized cornstarch and pregelatinized high amylose cornstarch can be mentioned.
  • the component (A) is preferably a granulated product or a pulverized product of the granulated product from the viewpoint of improving the looseness of the noodles.
  • the component (A) preferably further satisfies the following condition (4) from the viewpoint of improving the texture of the tongue.
  • the content of the fraction under the sieve of a sieve having an opening of 0.5 mm is 40% by mass or more and 100% by mass or less.
  • the content of the fraction under the sieve of the sieve having an opening of 0.5 mm in the component (A) is preferably 40% by mass or more with respect to the entire component (A) from the viewpoint of improving the texture of the tongue. It is more preferably 60% by mass or more, still more preferably 80% by mass or more. From the same viewpoint, the content of the fraction under the sieve of the sieve having an opening of 0.5 mm is, for example, 100% by mass or less with respect to the entire component (A).
  • the content of the fraction on the sieve of the sieve having a mesh size of 0.038 mm in the component (A) is preferably 50 mass by mass with respect to the entire component (A) from the viewpoint of making the texture of the noodles preferable. % Or more, more preferably 60% by mass or more, still more preferably 70% by mass or more, even more preferably 80% by mass or more, and even more preferably 90% by mass or more. From the same viewpoint, the content of the fraction on the sieve of the sieve having a mesh size of 0.038 mm in the component (A) is, for example, 100% by mass or less, and is, for example, 99% by mass with respect to the entire component (A). It may be% or less, preferably 97% by mass or less, and more preferably 95% by mass or less.
  • the content of the component (A) in the noodle loosening improver is preferably 15% by mass or more with respect to the entire noodle loosening improver from the viewpoint of improving the loosening property of the noodles. It is preferably 20% by mass or more, more preferably 30% by mass or more, still more preferably 40% by mass or more, and even more preferably 46% by mass or more. Further, there is no limit to the upper limit of the content of the component (A) in the noodle loosening improver, which is 100% by mass or less, but may be 99% by mass or less, for example, from the viewpoint of making the texture preferable.
  • the loosening improver for noodles may be composed of the component (A) or may contain a component other than the component (A).
  • the loosening improver for noodles preferably further contains component (B): acetylated tapioca starch.
  • the loosening improver for noodles is preferably for instant noodles.
  • the component (B) those having various acetyl group contents can be used, but from the viewpoint of improving the loosening property of the noodles, the acetyl group content of the modified starch is preferably 0.2% by mass or more, and more. It is preferably 0.3% by mass or more, preferably 2.5% by mass or less, more preferably 2.0% by mass or less, still more preferably 1.5% by mass or less, still more preferably 1. It is 0% by mass or less.
  • the method for measuring the acetyl group content of modified starch will be described later in the section of Examples.
  • the content of the component (B) in the noodle loosening improver is preferably 1% by mass or more, more preferably 5% by mass, based on the entire noodle loosening improver from the viewpoint of improving the texture of the noodles. As mentioned above, it is more preferably 10% by mass or more, even more preferably 20% by mass or more, and even more preferably 30% by mass or more. From the viewpoint of improving the looseness of the noodles, the content of the component (B) is, for example, 85% by mass or less, preferably 80% by mass or less, more preferably 80% by mass or less, based on the total amount of the loosening improver for noodles. It is 70% by mass or less.
  • the content of the component (B) with respect to the content of the component (A) is preferably 0.2 or more, more preferably 0.3 or more, still more preferably 0.3 or more in terms of mass ratio from the viewpoint of improving the texture of the noodles. It is 0.5 or more, and even more preferably 1.2 or more. Further, from the viewpoint of improving the looseness of the noodles, the content of the component (B) with respect to the content of the component (A) is preferably 5 or less, more preferably 4 or less.
  • the loosening improver for noodles preferably further contains the component (C): egg white.
  • the loosening improver for noodles is preferably for chilled noodles.
  • Raw egg white, powdered egg white, or the like can be used as the component (C), and it is preferable to use powdered egg white from the viewpoint of improving ease of handling.
  • the content of the component (C) in the noodle loosening improver is preferably 0.5% by mass or more, more preferably 1% or more, based on the whole noodle loosening improver from the viewpoint of improving the texture of the noodles. It is by mass% or more, more preferably 2% by mass or more, and even more preferably 4% by mass or more. From the same viewpoint, the content of the component (C) is, for example, 85% by mass or less, preferably 30% by mass or less, more preferably 20% by mass or less, still more preferably 20% by mass or less, based on the total amount of the loosening improver for noodles.
  • the content of the component (C) with respect to the content of the component (A) is preferably 0.005 or more, more preferably 0.01 or more, still more preferably 0.01 or more in terms of mass ratio from the viewpoint of improving the texture of the noodles. It is 0.02 or more. From the same viewpoint, the content of the component (C) with respect to the content of the component (A) is preferably 0.5 or less, more preferably 0.3 or less, still more preferably 0.2 or less in terms of mass ratio. is there.
  • the loosening improver for noodles preferably further contains component (D): gluten.
  • the loosening improver for noodles is preferably for chilled noodles or buckwheat noodles.
  • the gluten of the component (D) is obtained from grains such as wheat and rye, but is preferably derived from wheat.
  • active gluten obtained by extracting wheat protein from wheat flour into a dry powder is preferable. Examples of active gluten include those produced by a flash-drying method in which raw gluten is cut into small pieces and dried in an air stream, or raw gluten is added with an acid or alkali to prepare a gluten dispersion, which is then sprayed into dry hot air. Examples thereof include those manufactured by a spray-drying method of drying.
  • the content of the component (D) in the noodle loosening improver is preferably 5% by mass or more, more preferably 10% by mass, based on the entire noodle loosening improver from the viewpoint of improving the texture of the noodles. As mentioned above, it is more preferably 15% by mass or more, and even more preferably 20% by mass or more. From the viewpoint of improving the looseness of the noodles, the content of the component (D) is, for example, 85% by mass or less, preferably 60% by mass or less, more preferably 60% by mass or less, based on the total amount of the loosening improver for noodles. It is 40% by mass or less, more preferably 25% by mass or less.
  • the content of the component (D) with respect to the content of the component (A) is preferably 0.05 or more, more preferably 0.1 or more, still more preferably 0.1 or more in terms of mass ratio from the viewpoint of improving the texture of the noodles. It is 0.2 or more. Further, from the viewpoint of improving the looseness of the noodles, the content of the component (D) with respect to the content of the component (A) is preferably 5 or less, more preferably 3 or less, still more preferably 2 or less, and even more. It is preferably 1.5 or less, more preferably 1.0 or less, and particularly preferably 0.35 or less.
  • the loosening improver for noodles includes various flours such as strong flour, semi-strong flour, and medium-strength flour, and buckwheat flour as raw materials for flour, as long as the effects of the present invention are not impaired.
  • various flours such as strong flour, semi-strong flour, and medium-strength flour, and buckwheat flour as raw materials for flour, as long as the effects of the present invention are not impaired.
  • Corn flour, rye flour, barley flour, oats flour, rice flour may be blended.
  • examples of wheat flour include durum wheat flour in addition to the above.
  • the unraveling improver for noodles may be blended with unprocessed starch other than the above-mentioned starch and modified starch which has been subjected to processing such as esterification, etherification, and cross-linking.
  • the loosening improver for noodles includes salt; kansui; egg powder other than the component (C) such as egg yolk powder and whole egg powder; material powder such as yam powder, matcha, seaweed powder, and vegetable powder: Dietary fibers such as refractory starch, konjak, glucomannan; thickeners such as xanthan gum, guar gum, locust bean gum, alginic acid and its salts, agar, gelatin, pectin; fats and oils such as animal and vegetable fats and oils, emulsified fats and oils, shortening; Emulsifiers such as lecithin, glycerin fatty acid ester, sucrose fatty acid ester; inorganic salts such as carbonate and phosphate; proteins other than component (D) such as soybean protein and casein; other sorbit, ethyl alcohol, transglutaminase and the like Enzyme agents and the like can also be blended
  • the method for producing the loosening improver for noodles includes, for example, a step of preparing the component (A). Further, when the loosening improver for noodles contains a component other than the component (A), a step of mixing the component (A) with the other component may be further included.
  • the component (A) when the component (A) contains low-molecular-weight starch, the component (A) can be obtained by, for example, a production method including the following steps.
  • Step of preparing low molecular weight starch A step of reducing the molecular weight of starch having an amylose content of 5% by mass or more to obtain a low molecular weight starch having a peak molecular weight of 3 ⁇ 10 3 or more and 5 ⁇ 10 4 or less.
  • the raw material contains 3% by mass or more and 45% by mass or less of low-molecular-weight starch, and the total amount of low-molecular-weight starch and starch other than low-molecular-weight starch is 75% by mass or more.
  • the process of granulating A step of reducing the molecular weight of starch having an amylose content of 5% by mass or more to obtain a low molecular weight starch having a peak molecular weight of 3 ⁇ 10 3 or more and 5 ⁇ 10 4 or
  • the step of preparing low molecular weight starch is a step of decomposing starch having an amylose content of 5% by mass or more into low molecular weight starch.
  • the decomposition referred to here refers to decomposition accompanied by a reduction in the molecular weight of starch, and typical decomposition methods include decomposition by acid treatment, oxidation treatment, and enzyme treatment. Among these, acid treatment is preferable from the viewpoint of decomposition rate, cost, and reproducibility of decomposition reaction.
  • a general method used for granulating starch can be used, but it is generally used for heat gelatinization of starch in terms of achieving a predetermined degree of swelling in cold water. It is preferable to use the above method.
  • a method using a machine such as a drum dryer, a jet cooker, an extruder, or a spray dryer is known, but in the present embodiment, the component (A) in which the degree of swelling of cold water satisfies the above-mentioned specific condition. From the viewpoint of more reliably obtaining the above, heat gelatinization with an extruder or a drum dryer is preferable, and an extruder is more preferable.
  • extruder treatment usually, after adding water to a raw material containing starch to adjust the water content to about 10 to 60% by mass, for example, a barrel temperature of 30 to 200 ° C., an outlet temperature of 80 to 180 ° C., and a screw rotation speed of 100 to 100 to It is heated and expanded under the conditions of 1,000 rpm and a heat treatment time of 5 to 60 seconds.
  • the component (A) having a cold water swelling degree satisfying a specific condition can be obtained.
  • the granulated product obtained by heat gelatinization is pulverized, sieved, and appropriately adjusted in size, if necessary, to satisfy the above-mentioned particle size conditions such as condition (4).
  • A) granules, powders or mixtures thereof may be obtained.
  • the unraveling improver for noodles contains the ingredient (A) as an active ingredient, it is possible to obtain noodles having excellent unraveling properties. Further, by using the loosening improver for noodles in the present embodiment, it is possible to shorten the time for reconstitution of noodles at the time of eating, for example. Further, according to the present embodiment, for example, it is possible to make the balance between the looseness of the noodles and the texture preferable.
  • the method for improving the loosening of noodles includes applying a loosening improving agent for noodles to noodles. Further, in the present embodiment, the method for shortening the reconstitution time of noodles at the time of eating includes applying a loosening improver for noodles to noodles. Next, the noodles will be described.
  • noodles examples of the types of noodles to which the loosening improver for noodles of the present embodiment is applied include buckwheat noodles, udon noodles, Chinese noodles, pasta, cold wheat, and plain noodles, and are preferably selected from buckwheat noodles, udon noodles, and Chinese noodles. It is a seed, more preferably one selected from buckwheat noodles and Chinese noodles.
  • raw noodles, dried noodles (including semi-dried noodles), boiled noodles, steamed noodles, instant noodles, and refrigerated noodles that are stored and distributed after being boiled or steamed are refrigerated.
  • (Chilled noodles) may be used, but it is preferably one selected from instant noodles and chilled noodles.
  • the noodles are preferably one type selected from instant noodles and chilled noodles from the viewpoint of stably improving the looseness.
  • the noodles are preferably frozen noodles that are frozen after noodle making, before heating or after heating, more preferably frozen pasta, and even more preferably frozen pasta that is frozen after noodle making and heating.
  • Examples of the method for heating the noodles include boiling, steaming, and heating in a microwave oven.
  • Examples of the method for heating the frozen noodles after freezing include boiling, steaming, and microwave heating, and microwave heating is preferable.
  • the method for producing noodles includes, for example, a step of applying the above-mentioned loosening improver for noodles to noodles.
  • the timing of applying the noodle loosening improver there is no limitation on the timing of applying the noodle loosening improver.
  • the noodle loosening improver may be kneaded into the dough.
  • the unraveling improver for noodles may be applied to the noodle strings after the noodles are made.
  • the step of applying the noodle loosening improver to the noodles is the step of blending the noodle loosening improver into the noodle dough.
  • the method for producing noodles further includes a step of making dough.
  • the noodle loosening improver may be mixed with other raw materials before the dough is prepared, or after the dough is prepared, the noodle loosening improver is added. It may be kneaded into the dough.
  • the blending amount is preferably 0.5% by mass or more, more preferably 1% by mass or more, based on the whole dough from the viewpoint of improving the loosening property of the noodles. More preferably, it is 5% by mass or more. Further, from the viewpoint of improving the texture of the noodles, when the loosening improver for noodles is blended in the noodle dough, the blending amount is preferably 30% by mass or less, more preferably 16% by mass or less, based on the whole dough. It is even more preferably 10% by mass or less, and even more preferably 9% by mass or less.
  • the loosening improver for noodles is applied to the noodle wire after the noodles are made, for example, in the method of manufacturing noodles, in the step of applying the loosening improver for noodles to the noodles, the loosening improver for noodles is added to the surface of the noodles. This is a step of adhering the noodles to the surface of the noodles. Examples of the method of adding the loosening improver for noodles to the surface of noodles include spraying and dropping. Further, after the noodle loosening agent is added to the surface of the noodles, the noodle loosening agent may be uniformly distributed, so that the whole may be softened.
  • the peak molecular weight was measured using an HPLC unit manufactured by Tosoh Corporation (pump DP-8020, RI detector RS-8021, degassing device SD-8022).
  • the sample was pulverized, and the fraction under the sieve with a mesh opening of 0.15 mm was collected with a sieve of JIS-Z8801-1 standard.
  • the recovered fraction was suspended in the mobile phase at 1 mg / mL, and the suspension was heated at 100 ° C. for 3 minutes to completely dissolve it. Filtration was performed using a 0.45 ⁇ m filtration filter (DISMIC-25HP PTFE 0.45 ⁇ m manufactured by ADVANTEC), and the filtrate was used as an analysis sample.
  • Raw material supply 450 g / min Water: 17% by mass Barrel temperature: 50 ° C, 70 ° C and 100 ° C from the raw material inlet to the outlet Outlet temperature: 100-110 ° C Screw rotation speed 250 rpm
  • the heated paste obtained by the extruder treatment in this manner was dried at 110 ° C. to adjust the water content to about 10% by mass.
  • the dried heated paste was crushed with a desktop cutter crusher and then sieved with a JIS-Z8801-1 standard sieve.
  • the sieved heated pastes were mixed at the blending ratios shown in Table 1 to prepare powder granules 1 to 3.
  • the degree of swelling of each powder and granular material in cold water was measured by the method described later.
  • the "acetyl group content” was measured by the following method. (1) After the starch sample is heated and dried at 130 ° C., the moisture content is measured using a moisture meter (manufactured by Kensei Kogyo Co., Ltd., electromagnetic moisture meter: model number MX-50), and the amount of dried substance is determined from the obtained moisture value. Calculated. (2) 50 mL of water and several drops of a 1.0 w / v% phenolphthalein ethanol solution were added to a starch sample of 5 g in terms of dry mass.
  • a moisture meter manufactured by Kensei Kogyo Co., Ltd., electromagnetic moisture meter: model number MX-50
  • Examples 1 to 6 control example 1
  • Instant noodles (Chinese noodles) of each example were produced and evaluated according to the formulations shown in Table 2. The evaluation was conducted by two specialized panelists, and the score was decided by consensus.
  • the obtained noodles were cooked by the following procedure, such as heating and seasoning.
  • Steaming Convection oven (Maruzen, SSC-03), steam mode, 98 ° C, 2 minutes
  • Seasoning Add 26 g of flavored water to 70 g of steamed noodles and mix until the noodles absorb all the flavored water. ..
  • the composition of the seasoning water is shown below.
  • Fry Canola oil at 150 ° C, 2 min
  • Reconstitution with hot water Instant noodles were placed in a plastic container, hot water was poured into the container, the lid was closed, and the noodles were allowed to stand for a predetermined time as described below before being evaluated.
  • the instant noodles obtained in the examples had a shorter rehydration time and were excellent in loosening property of the noodles as compared with those of the control example.
  • the loosening after steaming is superior from Examples 2 and 4 to 6 when it is 25% by mass or more and 100% by mass or less, and is 75% by mass or more. It was better when it was 100% by mass or less.
  • the loosening after reconstitution with hot water it was excellent when it was 25% by mass or more and 100% by mass or less, and it was more excellent when it was 50% by mass or more and 100% by mass or less.
  • the texture was excellent when it was 25% by mass or more and 100% by mass or less, better than when it was 25% by mass or more and 75% by mass or less, and further excellent when it was 25% by mass or more and 50% by mass or less.
  • the loosening after steaming is superior when it is 25% by mass or more and 75% by mass or less, and when it is 25% by mass, It was better.
  • the loosening after reconstitution with hot water it was excellent when it was 25% by mass or more and 75% by mass or less, and it was more excellent when it was 25% by mass or more and 50% by mass or less.
  • the texture was excellent when it was 25% by mass or more and 75% by mass or less, and was superior to that when it was 50% by mass or more and 75% by mass or less.
  • the mass ratio is 0.333 or more. It was excellent when it was 3,000 or less, and it was better when it was 0.333.
  • the unraveling after reconstitution with hot water was excellent when it was 0.333 or more and 3.000 or less, and more excellent when it was 0.333 or more and 1.000 or less.
  • the texture was excellent when it was 0.333 or more and 3.000 or less, and more excellent when it was 1.000 or more and 3.000 or less.
  • Examples 7-14 Control Example 2
  • the chilled noodles (soba) of each example were produced and evaluated according to the formulations shown in Table 3. The evaluation was conducted by two specialized panelists, and the score was decided by consensus.
  • a loosening improver was prepared according to the formulation shown in Table 3. All the ingredients including the loosening improver were mixed to produce chilled noodles under the following conditions.
  • the obtained buckwheat was cooked by the following procedure.
  • Boiled Convection, water containing 0.10% pH adjuster formulation for boiling tank, 98 ° C, 1.5 minutes
  • Cooling Tap water 30 seconds, then ice water 30 seconds Draining: 10 times
  • Storage After boiling 30 g of buckwheat was placed in a plastic cup having a diameter of 10.5 cm, covered, and stored at 4 ° C. overnight. The loosening and texture of buckwheat noodles after storage were evaluated by the following methods.
  • the chilled noodles obtained in the examples had an excellent balance between the looseness of the noodles and the favorable texture as compared with those of the control example.
  • the blending amount of the noodle loosening improver when blended in the noodle dough is 4.0% by mass or more and 14.2% by mass or less with respect to the entire dough from the viewpoint of the loosening property of the noodles. When it was excellent, it was superior when it was 9.4% by mass or more and 14.2% by mass or less. From the viewpoint of texture, it was excellent when it was 4.0% by mass or more and 14.2% by mass or less, and it was more excellent when it was 9.4% by mass or more and 9.9% by mass or less.
  • the content of the component (A) in the noodle loosening improver is excellent when it is 45.5% by mass or more and 75.5% by mass or less, and 71.4% by mass or more and 75. It was better when it was 5% by mass or less. From the viewpoint of texture, it was excellent when it was 45.5% by mass or more and 75.5% by mass or less, and it was more excellent when it was 71.4% by mass or more and 74.1% by mass or less.
  • the content of the component (C) in the noodle loosening improver was excellent when it was 1.9% by mass or more and 7.1% by mass or less from the viewpoint of the loosening property of the noodles.
  • the content of the component (D) in the noodle loosening improver is excellent when it is 21.4% by mass or more and 54.5% by mass or less from the viewpoint of the loosening property of the noodles, and is 21.4% by mass or more and 28. It was better when it was 6% by mass or less. From the viewpoint of texture, it is excellent when it is 21.4% by mass or more and 54.5% by mass or less, and it is better when it is 21.4% by mass or more and 22.6% by mass or less, and it is 21.4% by mass or more.
  • the content of the component (C) with respect to the content of the component (A) was excellent when the mass ratio was 0.025 or more and 0.1 or less from the viewpoint of the looseness of the noodles. From the viewpoint of texture, it was excellent when it was 0.025 or more and 0.1 or less, and it was more excellent when it was 0.05 or more and 0.1 or less.
  • the content of the component (D) with respect to the content of the component (A) is excellent when the mass ratio is 0.300 or more and 1.200 or less, and 0.300 or more and 0.400 or less, from the viewpoint of the looseness of the noodles. At that time, it was better. From the viewpoint of texture, it was excellent when it was 0.300 or more and 1.200 or less, and it was better when it was 0.300.
  • Powder granules 1 were used as the component (A), powdered egg white was used as the component (C), and gluten was used as the component (D). 1200 parts by mass of powder granule 1, 75 parts by mass of powdered egg white, 350 parts by mass of gluten, and 375 parts by mass of Yamaimo powder (Yamaimo powder, manufactured by Otafuku Sauce Co., Ltd.) were mixed to obtain the loosening improver for noodles of this example. It was.
  • Powder granules 2 were used as the component (A), and powdered egg white was used as the component (C).
  • the powder granule 2 was mixed by 100 parts by mass, the powdered egg white by 7 parts by mass, and the strong flour by 300 parts by mass to obtain the loosening improver for noodles of this example.
  • Example 15 Example 15, control example 3
  • Pasta sustained release of raw pasta
  • Table 4 The evaluation was conducted by three specialized panelists, and the score was decided by consensus.
  • Boiled Convection, water containing 0.10% pH adjuster formulation for boiling tank, 98 ° C, 3 minutes to 3 minutes 30 seconds 6. 5. Above. The noodles obtained in the above section were vacuum cooled to 25 ° C. or lower. 7. Then, the noodles were frozen at ⁇ 30 ° C. for 4 hours. 8. The frozen noodles were microwaved at 700 W for 2 minutes.
  • Example 15 the pasta was excellent in loosening property, and the pasta after boiling was excellent in crispness and chewyness.
  • the above step 4 Adhesion to the noodle maker in the noodle maker was also suppressed as compared with Control Example 3, and the workability was excellent.

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Abstract

An agent for improving the loosening properties of noodles, said agent comprising, as an active ingredient, component (A) that is a granular material satisfying the following requirements: (1) having a starch content of 75 mass% or more; and (2) showing a degree of swelling in cold water at 25°C of 5-40 inclusive.

Description

麺用ほぐれ向上剤Unraveling agent for noodles
 本発明は、麺用ほぐれ向上剤に関する。 The present invention relates to a loosening improver for noodles.
 麺類のほぐれ性を向上しようとする技術として、特許文献1(特開2018-85959号公報)に記載のものがある。同文献には、10質量%水溶液における粘度が100mPa・s以下である加工澱粉及びグリセリン脂肪酸エステルを含有する水分散液を麺の表面に付着させて、麺類のほぐれ性を改良することが記載されている。 As a technique for improving the looseness of noodles, there is one described in Patent Document 1 (Japanese Unexamined Patent Publication No. 2018-85959). The document describes that an aqueous dispersion containing modified starch and glycerin fatty acid ester having a viscosity of 100 mPa · s or less in a 10 mass% aqueous solution is adhered to the surface of noodles to improve the looseness of noodles. ing.
特開2018-85959号公報JP-A-2018-85959
 しかしながら、本発明者らが検討したところ、麺のほぐれ性を向上させるという点で依然として改善の余地があることが明らかになった。 However, as a result of the examination by the present inventors, it became clear that there is still room for improvement in terms of improving the looseness of the noodles.
 本発明によれば、以下の麺用ほぐれ向上剤、麺の製造方法、麺のほぐれ向上方法および喫食時の麺の湯戻し時間短縮方法が提供される。
[1] 以下の成分(A)を有効成分として含む、麺用ほぐれ向上剤。
 成分(A):条件(1)および(2)を満たす粉粒状物
(1)澱粉含量が75質量%以上
(2)25℃における冷水膨潤度が5以上40以下
[2] 前記成分(A)を当該麺用ほぐれ向上剤全体に対して15質量%以上100質量%以下含有する、[1]に記載の麺用ほぐれ向上剤。
[3] 前記澱粉の由来原料が、キャッサバ、とうもろこしおよびコメからなる群から選ばれる1種または2種以上である、[1]または[2]に記載の麺用ほぐれ向上剤。
[4] 前記成分(A)が、造粒物または前記造粒物の粉砕物である、[1]乃至[3]いずれか1項に記載の麺用ほぐれ向上剤。
[5] 前記成分(A)が、以下の条件(3)をさらに満たす、[1]乃至[4]いずれか1項に記載の麺用ほぐれ向上剤。
(3)アミロース含量5質量%以上である澱粉の低分子化澱粉を3質量%以上45質量%以下含み、前記低分子化澱粉のピーク分子量が3×103以上5×104以下
[6] 前記成分(A)が、以下の条件(4)をさらに満たす、[1]乃至[5]いずれか1項に記載の麺用ほぐれ向上剤。
(4)目開き0.5mmの篩の篩下の画分の含有量が40質量%以上100質量%以下
[7] 麺が、即席麺およびチルド麺から選ばれる1種である、[1]乃至[6]いずれか1項に記載の麺用ほぐれ向上剤。
[8] 成分(B):アセチル化タピオカ澱粉をさらに含む、[1]乃至[7]いずれか1項に記載の麺用ほぐれ向上剤。
[9] 前記成分(A)の含有量に対する成分(B)の含有量が、質量比で0.2以上5以下である、[8]に記載の麺用ほぐれ向上剤。
[10] 即席麺用である、[8]または[9]に記載の麺用ほぐれ向上剤。
[11] 成分(C):卵白をさらに含む、[1]乃至[7]いずれか1項に記載の麺用ほぐれ向上剤。
[12] 前記成分(A)の含有量に対する前記成分(C)の含有量が、質量比で0.005以上0.5以下である、[11]に記載の麺用ほぐれ向上剤。
[13] チルド麺用である、[11]または[12]に記載の麺用ほぐれ向上剤。
[14] [1]乃至[13]いずれか1項に記載の麺用ほぐれ向上剤を麺に適用する工程を含む、麺の製造方法。
[15] 麺用ほぐれ向上剤を麺に適用する前記工程が、前記麺用ほぐれ向上剤を前記麺の生地に配合する工程であり、
 前記生地を製麺する工程をさらに含む、[14]に記載の麺の製造方法。
[16] 麺用ほぐれ向上剤を麺に適用する前記工程が、前記麺用ほぐれ向上剤を前記麺の表面に添加する工程である、[14]に記載の麺の製造方法。
[17] [1]乃至[13]いずれか1項に記載の麺用ほぐれ向上剤を麺に適用することを含む、麺のほぐれ向上方法。
[18] [1]乃至[13]いずれか1項に記載の麺用ほぐれ向上剤を麺に適用することを含む、喫食時の麺の湯戻し時間短縮方法。
According to the present invention, the following unraveling improver for noodles, a method for producing noodles, a method for improving unraveling of noodles, and a method for shortening the reconstitution time of noodles at the time of eating are provided.
[1] A loosening improver for noodles containing the following ingredient (A) as an active ingredient.
Component (A): Powder granules satisfying conditions (1) and (2) (1) Starch content is 75% by mass or more (2) Cold water swelling degree at 25 ° C is 5 or more and 40 or less [2] The component (A) The loosening improver for noodles according to [1], which contains 15% by mass or more and 100% by mass or less of the whole loosening improving agent for noodles.
[3] The loosening improver for noodles according to [1] or [2], wherein the raw material from which the starch is derived is one or more selected from the group consisting of cassava, corn and rice.
[4] The loosening improver for noodles according to any one of [1] to [3], wherein the component (A) is a granulated product or a pulverized product of the granulated product.
[5] The loosening improver for noodles according to any one of [1] to [4], wherein the component (A) further satisfies the following condition (3).
(3) The low molecular weight starch of starch having an amylose content of 5% by mass or more is contained in an amount of 3% by mass or more and 45% by mass or less, and the peak molecular weight of the low molecular weight starch is 3 × 10 3 or more and 5 × 10 4 or less [6]. The unraveling improver for starch according to any one of [1] to [5], wherein the component (A) further satisfies the following condition (4).
(4) The content of the fraction under the sieve with a mesh opening of 0.5 mm is 40% by mass or more and 100% by mass or less [7] Noodles are one kind selected from instant noodles and chilled noodles [1]. To [6] The loosening improver for noodles according to any one of the items.
[8] Component (B): The loosening improver for noodles according to any one of [1] to [7], which further contains acetylated tapioca starch.
[9] The loosening improver for noodles according to [8], wherein the content of the component (B) with respect to the content of the component (A) is 0.2 or more and 5 or less in terms of mass ratio.
[10] The loosening improver for noodles according to [8] or [9], which is for instant noodles.
[11] Ingredient (C): The loosening improver for noodles according to any one of [1] to [7], which further contains egg white.
[12] The loosening improver for noodles according to [11], wherein the content of the component (C) with respect to the content of the component (A) is 0.005 or more and 0.5 or less in terms of mass ratio.
[13] The loosening improver for noodles according to [11] or [12], which is for chilled noodles.
[14] A method for producing noodles, which comprises a step of applying the loosening improver for noodles according to any one of [1] to [13] to noodles.
[15] The step of applying the noodle loosening improver to noodles is a step of blending the noodle loosening improver into the noodle dough.
The method for producing noodles according to [14], further comprising a step of producing the dough.
[16] The method for producing noodles according to [14], wherein the step of applying the noodle loosening improver to noodles is a step of adding the noodle loosening improver to the surface of the noodles.
[17] A method for improving noodle loosening, which comprises applying the noodle loosening improver according to any one of [1] to [13] to noodles.
[18] A method for shortening the reconstitution time of noodles at the time of eating, which comprises applying the loosening improver for noodles according to any one of [1] to [13] to the noodles.
 なお、これらの各構成の任意の組み合わせや、本発明の表現を方法、装置などの間で変換したものもまた本発明の態様として有効である。
 たとえば、本発明によれば、前記本発明における麺の製造方法により得られる麺が提供される。
 また、本発明によれば、前記本発明における麺用ほぐれ向上剤の麺の製造のための使用が提供される。
It should be noted that any combination of these configurations and the conversion of the expression of the present invention between methods, devices and the like are also effective as aspects of the present invention.
For example, according to the present invention, the noodles obtained by the method for producing noodles in the present invention are provided.
Further, according to the present invention, the use of the loosening improver for noodles in the present invention for producing noodles is provided.
 本発明によれば、ほぐれ性に優れた麺を得ることができる。 According to the present invention, noodles having excellent looseness can be obtained.
 以下、本発明の実施形態について説明する。なお、数値範囲の「~」は、断りがなければ、以上から以下を表し、両端の数値をいずれも含む。また、本実施形態において、組成物は、各成分を単独でまたは2種以上組み合わせて含むことができる。 Hereinafter, embodiments of the present invention will be described. Unless otherwise specified, "-" in the numerical range represents the following from the above, and includes all the numerical values at both ends. Further, in the present embodiment, the composition may contain each component alone or in combination of two or more.
 (麺用ほぐれ向上剤)
 本実施形態において、麺用ほぐれ向上剤は、以下の成分(A)を有効成分として含む。成分(A)は、以下の条件(1)および(2)を満たす粉粒状物である。
(1)澱粉含量が75質量%以上
(2)25℃における冷水膨潤度が5以上40以下
(Unraveling agent for noodles)
In the present embodiment, the loosening improver for noodles contains the following component (A) as an active ingredient. The component (A) is a powdery substance that satisfies the following conditions (1) and (2).
(1) Starch content is 75% by mass or more (2) Cold water swelling degree at 25 ° C is 5 or more and 40 or less
(成分(A))
 成分(A)は、具体的には、澱粉を主成分としてなる粉粒状物である。ここで、粉粒状物とは、粉状物および粒状物のうち少なくとも一方を含むものであり、粉状物および粒状物の両方を含むものであってもよい。
(Ingredient (A))
Specifically, the component (A) is a powdery substance containing starch as a main component. Here, the powdery granular material includes at least one of the powdery material and the granular material, and may include both the powdery material and the granular material.
 条件(1)に関し、成分(A)は、麺のほぐれ性を向上させる観点から、麺用ほぐれ向上剤全体に対して澱粉を75質量%以上含み、好ましくは80質量%以上、さらに好ましくは85質量%以上含む。
 また、成分(A)中の澱粉の含有量の上限に制限はなく、麺用ほぐれ向上剤全体に対して100質量%以下であるが、麺の性状等に応じて99.5質量%以下、99質量%以下等としてもよい。
Regarding the condition (1), the component (A) contains 75% by mass or more of starch, preferably 80% by mass or more, more preferably 85% by mass, based on the whole noodle loosening improver, from the viewpoint of improving the loosening property of the noodles. Contains% by mass or more.
Further, there is no limit to the upper limit of the starch content in the component (A), which is 100% by mass or less based on the total amount of the loosening improver for noodles, but 99.5% by mass or less depending on the properties of the noodles. It may be 99% by mass or less.
 条件(2)に関し、麺のほぐれ性を向上させる観点から、成分(A)の冷水膨潤度は5以上であり、好ましくは6以上であり、さらに好ましくは6.5以上である。
 また、同様の観点から、成分(A)の冷水膨潤度は40以下であり、好ましくは35以下、より好ましくは20以下、さらに好ましくは17以下、さらにより好ましくは13以下、よりいっそう好ましくは12以下、殊更好ましくは11以下である。
 ここで、成分(A)の冷水膨潤度の測定方法については、実施例の項に記載する。
Regarding the condition (2), from the viewpoint of improving the looseness of the noodles, the cold water swelling degree of the component (A) is 5 or more, preferably 6 or more, and more preferably 6.5 or more.
From the same viewpoint, the cold water swelling degree of the component (A) is 40 or less, preferably 35 or less, more preferably 20 or less, still more preferably 17 or less, still more preferably 13 or less, and even more preferably 12. Hereinafter, it is particularly preferably 11 or less.
Here, the method for measuring the cold water swelling degree of the component (A) will be described in the section of Examples.
 成分(A)において、澱粉は、たとえば食品用の澱粉であり、各種由来のものを用いることができる。たとえば、澱粉として、とうもろこし澱粉、馬鈴薯澱粉、タピオカ澱粉、小麦澱粉、コメ澱粉などの澱粉;およびこれらの澱粉を化学的、物理的または酵素的に加工した加工澱粉などから、1種以上を適宜選ぶことができる。麺のほぐれ性を向上させる観点から、澱粉は、好ましくはタピオカ澱粉、とうもろこし澱粉、コメ澱粉から選ばれる1種または2種以上であり、より好ましくは、タピオカ澱粉およびとうもろこし澱粉から選ばれる1種または2種である。
 同様の観点から、澱粉の由来原料は、好ましくはキャッサバ、とうもろこしおよびコメからなる群から選ばれる1種または2種以上である。
In the component (A), the starch is, for example, starch for foods, and various-derived starches can be used. For example, as starch, one or more kinds are appropriately selected from starches such as corn starch, potato starch, tapioca starch, wheat starch, rice starch; and processed starch obtained by chemically, physically or enzymatically processing these starches. be able to. From the viewpoint of improving the looseness of noodles, the starch is preferably one or more selected from tapioca starch, corn starch and rice starch, and more preferably one or more selected from tapioca starch and corn starch. There are two types.
From the same viewpoint, the raw material from which starch is derived is preferably one or more selected from the group consisting of cassava, corn and rice.
 成分(A)は、麺のほぐれ性を向上させ、湯戻し時間を短縮する観点から、好ましくは以下の条件(3)をさらに満たす。
(3)アミロース含量5質量%以上である澱粉の低分子化澱粉を3質量%以上45質量%以下含み、低分子化澱粉のピーク分子量が3×103以上5×104以下
The component (A) preferably further satisfies the following condition (3) from the viewpoint of improving the looseness of the noodles and shortening the reconstitution time.
(3) Low molecular weight starch having an amylose content of 5% by mass or more is contained in an amount of 3% by mass or more and 45% by mass or less, and the peak molecular weight of the low molecular weight starch is 3 × 10 3 or more and 5 × 10 4 or less.
 まず、低分子化澱粉のピーク分子量は、麺のほぐれ性を向上させる観点から、好ましくは3×103以上であり、より好ましくは8×103以上である。
 同様の観点から、低分子化澱粉のピーク分子量は、好ましくは5×104以下であり、より好ましくは3×104以下であり、さらに好ましくは1.5×104以下である。なお、低分子化澱粉のピーク分子量の測定方法については、実施例の項に記載する。
First, the peak molecular weight of the low molecular weight starch is preferably 3 × 10 3 or more, and more preferably 8 × 10 3 or more, from the viewpoint of improving the looseness of the noodles.
From the same viewpoint, the peak molecular weight of the low molecular weight starch, preferably at 5 × 10 4 or less, more preferably 3 × 10 4 or less, more preferably 1.5 × 10 4 or less. The method for measuring the peak molecular weight of the low molecular weight starch will be described in the section of Examples.
 また、低分子化澱粉の原料澱粉中のアミロース含量は、麺のほぐれ性を向上させる観点から、好ましくは5質量%以上であり、より好ましくは12質量%以上、さらに好ましくは22質量%以上、さらにより好ましくは40質量%以上、よりいっそう好ましくは45質量%以上、さらにまた好ましくは55質量%以上、とりわけ好ましくは65質量%以上である。なお、低分子化澱粉の原料澱粉中のアミロース含量の上限に制限はなく、100質量%以下であり、好ましくは90質量%以下、より好ましくは80質量%以下である。 The amylose content in the raw material starch of the low molecular weight starch is preferably 5% by mass or more, more preferably 12% by mass or more, still more preferably 22% by mass or more, from the viewpoint of improving the looseness of the noodles. It is even more preferably 40% by mass or more, even more preferably 45% by mass or more, still more preferably 55% by mass or more, and particularly preferably 65% by mass or more. The upper limit of the amylose content in the raw material starch of the low molecular weight starch is not limited, and is 100% by mass or less, preferably 90% by mass or less, and more preferably 80% by mass or less.
 低分子化澱粉の原料であるアミロース含量5質量%以上の澱粉として、ハイアミロースコーンスターチ、コーンスターチ等のとうもろこし澱粉、タピオカ澱粉、甘藷澱粉、馬鈴薯澱粉、小麦澱粉、ハイアミロース小麦澱粉、米澱粉、および、これらの原料を化学的、物理的または酵素的に加工した加工澱粉からなる群から選択される1種または2種以上を用いることができる。麺のほぐれ性を向上させる観点から、アミロース含量5質量%以上の澱粉は、ハイアミロースコーンスターチ、コーンスターチ、および、タピオカ澱粉から選択される1種または2種以上であり、より好ましくはハイアミロースコーンスターチである。ハイアミロースコーンスターチとしては、たとえばアミロース含量40質量%以上のものが入手可能である。アミロース含量5質量%以上の澱粉は、より好ましくはアミロース含量が40質量%以上のコーンスターチである。 As starch having an amylose content of 5% by mass or more, which is a raw material of low molecular weight starch, corn starch such as high amylose corn starch and corn starch, tapioca starch, sweet potato starch, horse belly starch, wheat starch, high amylose wheat starch, rice starch, and One or more selected from the group consisting of processed starch obtained by chemically, physically or enzymatically processing these raw materials can be used. From the viewpoint of improving the looseness of noodles, the starch having an amylose content of 5% by mass or more is one or more selected from high amylose cornstarch, cornstarch, and tapioca starch, and more preferably high amylose cornstarch. is there. As the high amylose cornstarch, for example, one having an amylose content of 40% by mass or more is available. Starch having an amylose content of 5% by mass or more is more preferably cornstarch having an amylose content of 40% by mass or more.
 成分(A)中の低分子化澱粉の含有量は、麺のほぐれ性を向上させる観点から、好ましくは3質量%以上であり、より好ましくは8質量%以上、さらに好ましくは13質量%以上である。
 同様の観点から、成分(A)中の低分子化澱粉の含有量は、好ましくは45質量%以下であり、より好ましくは35質量%以下、さらに好ましくは25質量%以下である。
The content of the low molecular weight starch in the component (A) is preferably 3% by mass or more, more preferably 8% by mass or more, still more preferably 13% by mass or more, from the viewpoint of improving the looseness of the noodles. is there.
From the same viewpoint, the content of the low molecular weight starch in the component (A) is preferably 45% by mass or less, more preferably 35% by mass or less, and further preferably 25% by mass or less.
 ここで、低分子化澱粉は、その製造安定性に優れる観点から、好ましくは、酸処理澱粉、酸化処理澱粉および酵素処理澱粉からなる群から選択される1種または2種以上であり、より好ましくは酸処理澱粉である。 Here, the low molecular weight starch is preferably one or more selected from the group consisting of acid-treated starch, oxidation-treated starch and enzyme-treated starch from the viewpoint of excellent production stability, and more preferably. Is an acid-treated starch.
 酸処理澱粉を得る際の酸処理の条件は問わないが、たとえば、以下のように処理することができる。
 まず、原料であるアミロース含量5質量%以上の澱粉と水を反応装置に投入した後、さらに酸を投入する。あるいは水に無機酸をあらかじめ溶解させた酸水と原料の澱粉を反応装置に投入する。酸処理をより安定的におこなう観点からは、反応中の澱粉の全量が水相内に均質に分散した状態、またはスラリー化した状態にあることが望ましい。そのためには、酸処理をおこなう上での澱粉スラリーの濃度を、たとえば10質量%以上50質量%以下、好ましくは20質量%以上40質量%以下の範囲になるように調整する。スラリー濃度が高すぎると、スラリー粘度が上昇し、均一なスラリーの攪拌が難しくなる場合がある。
The conditions of acid treatment for obtaining acid-treated starch are not limited, and for example, the treatment can be carried out as follows.
First, starch and water having an amylose content of 5% by mass or more, which are raw materials, are added to the reactor, and then an acid is further added. Alternatively, acid water in which an inorganic acid is previously dissolved in water and starch as a raw material are added to the reactor. From the viewpoint of more stable acid treatment, it is desirable that the total amount of starch in the reaction is uniformly dispersed in the aqueous phase or in a slurry state. For that purpose, the concentration of the starch slurry in the acid treatment is adjusted to be, for example, 10% by mass or more and 50% by mass or less, preferably 20% by mass or more and 40% by mass or less. If the slurry concentration is too high, the slurry viscosity may increase, making it difficult to stir a uniform slurry.
 酸処理に用いられる酸として、具体的には塩酸、硫酸、硝酸などの無機酸が挙げられ、種類、純度などを問わず利用できる。 Specific examples of the acid used for acid treatment include inorganic acids such as hydrochloric acid, sulfuric acid, and nitric acid, which can be used regardless of the type and purity.
 酸処理反応条件については、たとえば酸処理時の無機酸濃度は、酸処理澱粉を安定的に得る観点から、0.05規定度(N)以上4N以下が好ましく、0.1N以上4N以下がより好ましく、0.2N以上3N以下がさらに好ましい。また、同様の観点から、反応温度は、30℃以上70℃以下が好ましく、35℃以上70℃以下がより好ましく、35℃以上65℃以下がさらに好ましく、反応時間は、同様の観点から、0.5時間以上120時間以下が好ましく、1時間以上72時間以下がより好ましく、1時間以上48時間以下がさらに好ましい。 Regarding the acid treatment reaction conditions, for example, the inorganic acid concentration during the acid treatment is preferably 0.05 normality (N) or more and 4N or less, and more preferably 0.1N or more and 4N or less, from the viewpoint of stably obtaining the acid-treated starch. It is preferably 0.2N or more and 3N or less, more preferably. From the same viewpoint, the reaction temperature is preferably 30 ° C. or higher and 70 ° C. or lower, more preferably 35 ° C. or higher and 70 ° C. or lower, further preferably 35 ° C. or higher and 65 ° C. or lower, and the reaction time is 0 from the same viewpoint. .5 hours or more and 120 hours or less is preferable, 1 hour or more and 72 hours or less is more preferable, and 1 hour or more and 48 hours or less is further preferable.
 成分(A)が低分子化澱粉を含むとき、具体的には、成分(A)は低分子化澱粉と低分子化澱粉以外の澱粉とを含む。成分(A)中の低分子化澱粉以外の澱粉としては、たとえば前述した澱粉の中から選択して使用することができる。好ましくは、成分(A)中の低分子化澱粉以外の澱粉は、コーンスターチ、小麦澱粉、馬鈴薯澱粉、タピオカ澱粉およびこれらの架橋澱粉からなる群から選択される1種または2種以上である。 When the component (A) contains low-molecular-weight starch, specifically, the component (A) contains low-molecular-weight starch and starch other than low-molecular-weight starch. As the starch other than the low molecular weight starch in the component (A), for example, it can be selected and used from the above-mentioned starches. Preferably, the starch other than the low molecular weight starch in the component (A) is one or more selected from the group consisting of corn starch, wheat starch, potato starch, tapioca starch and cross-linked starch thereof.
 また、成分(A)の他の好ましい例として、α化コーンスターチおよびα化ハイアミロースコーンスターチからなる群から選択される1種または2種以上が挙げられる。 Further, as another preferable example of the component (A), one kind or two or more kinds selected from the group consisting of pregelatinized cornstarch and pregelatinized high amylose cornstarch can be mentioned.
 成分(A)は、麺のほぐれ性を向上させる観点から、好ましくは造粒物または造粒物の粉砕物である。 The component (A) is preferably a granulated product or a pulverized product of the granulated product from the viewpoint of improving the looseness of the noodles.
 また、成分(A)の粒度については、成分(A)は、舌ざわりを向上させる観点から、好ましくは以下の条件(4)をさらに満たす。
(4)目開き0.5mmの篩の篩下の画分の含有量が40質量%以上100質量%以下
Regarding the particle size of the component (A), the component (A) preferably further satisfies the following condition (4) from the viewpoint of improving the texture of the tongue.
(4) The content of the fraction under the sieve of a sieve having an opening of 0.5 mm is 40% by mass or more and 100% by mass or less.
 すなわち、成分(A)中の目開き0.5mmの篩の篩下の画分の含有量は、舌ざわりを向上させる観点から、成分(A)全体に対して好ましくは40質量%以上であり、より好ましくは60質量%以上、さらに好ましくは80質量%以上である。
 同様の観点から、目開き0.5mmの篩の篩下の画分の含有量は、成分(A)全体に対してたとえば100質量%以下である。
That is, the content of the fraction under the sieve of the sieve having an opening of 0.5 mm in the component (A) is preferably 40% by mass or more with respect to the entire component (A) from the viewpoint of improving the texture of the tongue. It is more preferably 60% by mass or more, still more preferably 80% by mass or more.
From the same viewpoint, the content of the fraction under the sieve of the sieve having an opening of 0.5 mm is, for example, 100% by mass or less with respect to the entire component (A).
 また、成分(A)中の目開き0.038mmの篩の篩上の画分の含有量は、麺の食感を好ましいものとする観点から、成分(A)全体に対して好ましくは50質量%以上であり、より好ましくは60質量%以上、さらに好ましくは70質量%以上、さらにより好ましくは80質量%以上、よりいっそう好ましくは90質量%以上である。
 同様の観点から、成分(A)中の目開き0.038mmの篩の篩上の画分の含有量は、成分(A)全体に対してたとえば100質量%以下であり、また、たとえば99質量%以下であってもよく、好ましくは97質量%以下であり、より好ましくは95質量%以下である。
Further, the content of the fraction on the sieve of the sieve having a mesh size of 0.038 mm in the component (A) is preferably 50 mass by mass with respect to the entire component (A) from the viewpoint of making the texture of the noodles preferable. % Or more, more preferably 60% by mass or more, still more preferably 70% by mass or more, even more preferably 80% by mass or more, and even more preferably 90% by mass or more.
From the same viewpoint, the content of the fraction on the sieve of the sieve having a mesh size of 0.038 mm in the component (A) is, for example, 100% by mass or less, and is, for example, 99% by mass with respect to the entire component (A). It may be% or less, preferably 97% by mass or less, and more preferably 95% by mass or less.
 本実施形態において、麺用ほぐれ向上剤中の成分(A)の含有量は、麺のほぐれ性を向上させる観点から、麺用ほぐれ向上剤全体に対して好ましくは15質量%以上であり、より好ましくは20質量%以上、さらに好ましくは30質量%以上、さらにより好ましくは40質量%以上、よりいっそう好ましくは46質量%以上である。
 また、麺用ほぐれ向上剤中の成分(A)の含有量の上限に制限はなく、100質量%以下であるが、たとえば99質量%以下であってもよく、食感を好ましいものとする観点から、好ましくは85質量%以下であり、より好ましくは80質量%以下、さらに好ましくは75質量%以下である。
 また、麺用ほぐれ向上剤は、成分(A)から構成されてもよいし、成分(A)以外の成分を含んでもよい。
In the present embodiment, the content of the component (A) in the noodle loosening improver is preferably 15% by mass or more with respect to the entire noodle loosening improver from the viewpoint of improving the loosening property of the noodles. It is preferably 20% by mass or more, more preferably 30% by mass or more, still more preferably 40% by mass or more, and even more preferably 46% by mass or more.
Further, there is no limit to the upper limit of the content of the component (A) in the noodle loosening improver, which is 100% by mass or less, but may be 99% by mass or less, for example, from the viewpoint of making the texture preferable. Therefore, it is preferably 85% by mass or less, more preferably 80% by mass or less, and further preferably 75% by mass or less.
Further, the loosening improver for noodles may be composed of the component (A) or may contain a component other than the component (A).
 たとえば、麺用ほぐれ向上剤は好ましくは成分(B):アセチル化タピオカ澱粉をさらに含む。このとき、麺用ほぐれ向上剤は好ましくは即席麺用である。
 成分(B)として、様々なアセチル基含量のものが使用可能であるが、麺のほぐれ性を向上させる観点から、加工澱粉のアセチル基含量は、好ましくは0.2質量%以上であり、より好ましくは0.3質量%以上であり、また、好ましくは2.5質量%以下であり、より好ましくは2.0質量%以下、さらに好ましくは1.5質量%以下、さらにより好ましくは1.0質量%以下である。加工澱粉のアセチル基含量の測定方法は実施例の項で後述する。
For example, the loosening improver for noodles preferably further contains component (B): acetylated tapioca starch. At this time, the loosening improver for noodles is preferably for instant noodles.
As the component (B), those having various acetyl group contents can be used, but from the viewpoint of improving the loosening property of the noodles, the acetyl group content of the modified starch is preferably 0.2% by mass or more, and more. It is preferably 0.3% by mass or more, preferably 2.5% by mass or less, more preferably 2.0% by mass or less, still more preferably 1.5% by mass or less, still more preferably 1. It is 0% by mass or less. The method for measuring the acetyl group content of modified starch will be described later in the section of Examples.
 麺用ほぐれ向上剤中の成分(B)の含有量は、麺の食感を向上する観点から、麺用ほぐれ向上剤全体に対して好ましくは1質量%以上であり、より好ましくは5質量%以上、さらに好ましくは10質量%以上、さらにより好ましくは20質量%以上、よりいっそう好ましくは30質量%以上である。
 また、麺のほぐれ性を向上させる観点から、成分(B)の含有量は、麺用ほぐれ向上剤全体に対してたとえば85質量%以下であり、好ましくは80質量%以下であり、より好ましくは70質量%以下である。
The content of the component (B) in the noodle loosening improver is preferably 1% by mass or more, more preferably 5% by mass, based on the entire noodle loosening improver from the viewpoint of improving the texture of the noodles. As mentioned above, it is more preferably 10% by mass or more, even more preferably 20% by mass or more, and even more preferably 30% by mass or more.
From the viewpoint of improving the looseness of the noodles, the content of the component (B) is, for example, 85% by mass or less, preferably 80% by mass or less, more preferably 80% by mass or less, based on the total amount of the loosening improver for noodles. It is 70% by mass or less.
 成分(A)の含有量に対する成分(B)の含有量は、麺の食感を向上する観点から、質量比で好ましくは0.2以上であり、より好ましくは0.3以上、さらに好ましくは0.5以上、さらにより好ましくは1.2以上である。
 また、麺のほぐれ性を向上させる観点から、成分(A)の含有量に対する成分(B)の含有量は、好ましくは5以下であり、より好ましくは4以下である。
The content of the component (B) with respect to the content of the component (A) is preferably 0.2 or more, more preferably 0.3 or more, still more preferably 0.3 or more in terms of mass ratio from the viewpoint of improving the texture of the noodles. It is 0.5 or more, and even more preferably 1.2 or more.
Further, from the viewpoint of improving the looseness of the noodles, the content of the component (B) with respect to the content of the component (A) is preferably 5 or less, more preferably 4 or less.
 また、麺用ほぐれ向上剤は、好ましくは成分(C):卵白をさらに含む。このとき、麺用ほぐれ向上剤は好ましくはチルド麺用である。
 成分(C)として、生卵白、粉末卵白等を用いることができ、取り扱い容易性向上の観点から、粉末卵白を用いることが好ましい。
In addition, the loosening improver for noodles preferably further contains the component (C): egg white. At this time, the loosening improver for noodles is preferably for chilled noodles.
Raw egg white, powdered egg white, or the like can be used as the component (C), and it is preferable to use powdered egg white from the viewpoint of improving ease of handling.
 麺用ほぐれ向上剤中の成分(C)の含有量は、麺の食感を向上する観点から、麺用ほぐれ向上剤全体に対して好ましくは0.5質量%以上であり、より好ましくは1質量%以上、さらに好ましくは2質量%以上、さらにより好ましくは4質量%以上である。
 同様の観点から、成分(C)の含有量は、麺用ほぐれ向上剤全体に対してたとえば85質量%以下であり、好ましくは30質量%以下であり、より好ましくは20質量%以下、さらに好ましくは15質量%以下、さらにより好ましくは10質量%以下、よりいっそう好ましくは8質量%以下、殊更好ましくは6質量%以下である。
 成分(A)の含有量に対する成分(C)の含有量は、麺の食感を向上する観点から、質量比で好ましくは0.005以上であり、より好ましくは0.01以上、さらに好ましくは0.02以上である。
 同様の観点から、成分(A)の含有量に対する成分(C)の含有量は、質量比で好ましくは0.5以下であり、より好ましくは0.3以下、さらに好ましくは0.2以下である。
The content of the component (C) in the noodle loosening improver is preferably 0.5% by mass or more, more preferably 1% or more, based on the whole noodle loosening improver from the viewpoint of improving the texture of the noodles. It is by mass% or more, more preferably 2% by mass or more, and even more preferably 4% by mass or more.
From the same viewpoint, the content of the component (C) is, for example, 85% by mass or less, preferably 30% by mass or less, more preferably 20% by mass or less, still more preferably 20% by mass or less, based on the total amount of the loosening improver for noodles. Is 15% by mass or less, more preferably 10% by mass or less, even more preferably 8% by mass or less, and particularly preferably 6% by mass or less.
The content of the component (C) with respect to the content of the component (A) is preferably 0.005 or more, more preferably 0.01 or more, still more preferably 0.01 or more in terms of mass ratio from the viewpoint of improving the texture of the noodles. It is 0.02 or more.
From the same viewpoint, the content of the component (C) with respect to the content of the component (A) is preferably 0.5 or less, more preferably 0.3 or less, still more preferably 0.2 or less in terms of mass ratio. is there.
 また、麺用ほぐれ向上剤は好ましくは成分(D):グルテンをさらに含む。このとき、麺用ほぐれ向上剤は、好ましくはチルド麺用またはそば用である。
 成分(D)のグルテンは、小麦、ライ麦などの穀物から得られるものであるが、好ましくは小麦由来のものである。また、グルテンとしては小麦粉から小麦タンパクを抽出して乾燥粉末にした活性グルテンが好ましい。活性グルテンとしては、たとえば、生グルテンを細かく裁断しながら気流中で乾燥させるフラッシュドライ製法で製造されたもの、生グルテンに酸やアルカリを加えてグルテン分散液を調製した後、乾熱気中に噴霧して乾燥させるスプレードライ製法で製造されたもの等が挙げられる。
In addition, the loosening improver for noodles preferably further contains component (D): gluten. At this time, the loosening improver for noodles is preferably for chilled noodles or buckwheat noodles.
The gluten of the component (D) is obtained from grains such as wheat and rye, but is preferably derived from wheat. Further, as the gluten, active gluten obtained by extracting wheat protein from wheat flour into a dry powder is preferable. Examples of active gluten include those produced by a flash-drying method in which raw gluten is cut into small pieces and dried in an air stream, or raw gluten is added with an acid or alkali to prepare a gluten dispersion, which is then sprayed into dry hot air. Examples thereof include those manufactured by a spray-drying method of drying.
 麺用ほぐれ向上剤中の成分(D)の含有量は、麺の食感を向上する観点から、麺用ほぐれ向上剤全体に対して好ましくは5質量%以上であり、より好ましくは10質量%以上、さらに好ましくは15質量%以上、さらにより好ましくは20質量%以上である。
 また、麺のほぐれ性を向上させる観点から、成分(D)の含有量は、麺用ほぐれ向上剤全体に対してたとえば85質量%以下であり、好ましくは60質量%以下であり、より好ましくは40質量%以下、さらに好ましくは25質量%以下である。
The content of the component (D) in the noodle loosening improver is preferably 5% by mass or more, more preferably 10% by mass, based on the entire noodle loosening improver from the viewpoint of improving the texture of the noodles. As mentioned above, it is more preferably 15% by mass or more, and even more preferably 20% by mass or more.
From the viewpoint of improving the looseness of the noodles, the content of the component (D) is, for example, 85% by mass or less, preferably 60% by mass or less, more preferably 60% by mass or less, based on the total amount of the loosening improver for noodles. It is 40% by mass or less, more preferably 25% by mass or less.
 成分(A)の含有量に対する成分(D)の含有量は、麺の食感を向上する観点から、質量比で好ましくは0.05以上であり、より好ましくは0.1以上、さらに好ましくは0.2以上である。
 また、麺のほぐれ性を向上させる観点から、成分(A)の含有量に対する成分(D)の含有量は、好ましくは5以下であり、より好ましくは3以下、さらに好ましくは2以下、さらにより好ましくは1.5以下、よりいっそう好ましくは1.0以下、殊更好ましくは0.35以下である。
The content of the component (D) with respect to the content of the component (A) is preferably 0.05 or more, more preferably 0.1 or more, still more preferably 0.1 or more in terms of mass ratio from the viewpoint of improving the texture of the noodles. It is 0.2 or more.
Further, from the viewpoint of improving the looseness of the noodles, the content of the component (D) with respect to the content of the component (A) is preferably 5 or less, more preferably 3 or less, still more preferably 2 or less, and even more. It is preferably 1.5 or less, more preferably 1.0 or less, and particularly preferably 0.35 or less.
 麺用ほぐれ向上剤には、本発明の効果を妨げない範囲で、前述の成分(A)~(D)以外に、穀粉原料として、強力粉、準強力粉、中力粉等の各種小麦粉、そば粉、コーンフラワー、ライ麦粉、大麦粉、オーツ粉、米粉を配合してもよい。穀粉原料のうち、小麦粉の例として、上記のものの他、デュラム小麦粉が挙げられる。
 また、麺用ほぐれ向上剤には、前述の澱粉以外の未加工澱粉およびこれらにエステル化、エーテル化、架橋等の加工を施した加工澱粉等を配合してもよい。また、麺用ほぐれ向上剤には、副原料として、食塩;かんすい;卵黄粉、全卵粉等の成分(C)以外の卵粉;山芋粉、抹茶、海藻粉末、野菜粉末等の素材パウダー:難消化性澱粉、コンニャク、グルコマンナン等の食物繊維;キサンタンガム、グァーガム、ローカストビーンガム、アルギン酸およびその塩、寒天、ゼラチン、ペクチン等の増粘剤;動植物油脂、乳化油脂、ショートニング等の油脂類;レシチン、グリセリン脂肪酸エステル、ショ糖脂肪酸エステル等の乳化剤;炭酸塩、リン酸塩等の無機塩類;大豆蛋白質、カゼイン等の成分(D)以外の蛋白類;その他ソルビット、エチルアルコール、トランスグルタミナーゼ等の酵素剤等を配合することもできる。
In addition to the above-mentioned components (A) to (D), the loosening improver for noodles includes various flours such as strong flour, semi-strong flour, and medium-strength flour, and buckwheat flour as raw materials for flour, as long as the effects of the present invention are not impaired. , Corn flour, rye flour, barley flour, oats flour, rice flour may be blended. Among the flour raw materials, examples of wheat flour include durum wheat flour in addition to the above.
Further, the unraveling improver for noodles may be blended with unprocessed starch other than the above-mentioned starch and modified starch which has been subjected to processing such as esterification, etherification, and cross-linking. In addition, as an auxiliary raw material, the loosening improver for noodles includes salt; kansui; egg powder other than the component (C) such as egg yolk powder and whole egg powder; material powder such as yam powder, matcha, seaweed powder, and vegetable powder: Dietary fibers such as refractory starch, konjak, glucomannan; thickeners such as xanthan gum, guar gum, locust bean gum, alginic acid and its salts, agar, gelatin, pectin; fats and oils such as animal and vegetable fats and oils, emulsified fats and oils, shortening; Emulsifiers such as lecithin, glycerin fatty acid ester, sucrose fatty acid ester; inorganic salts such as carbonate and phosphate; proteins other than component (D) such as soybean protein and casein; other sorbit, ethyl alcohol, transglutaminase and the like Enzyme agents and the like can also be blended.
 次に、麺用ほぐれ向上剤の製造方法を説明する。
 麺用ほぐれ向上剤の製造方法は、たとえば成分(A)を準備する工程を含む。また、麺用ほぐれ向上剤が成分(A)以外の成分を含むとき、成分(A)と他の成分とを混合する工程をさらに含んでもよい。
Next, a method for producing a loosening improver for noodles will be described.
The method for producing the loosening improver for noodles includes, for example, a step of preparing the component (A). Further, when the loosening improver for noodles contains a component other than the component (A), a step of mixing the component (A) with the other component may be further included.
 ここで、成分(A)が低分子化澱粉を含むとき、たとえば以下の工程を含む製造方法により成分(A)を得ることができる。
(低分子化澱粉の調製工程)アミロース含量5質量%以上の澱粉を低分子化処理してピーク分子量が3×103以上5×104以下の低分子化澱粉を得る工程。
(造粒工程)原料に低分子化澱粉を3質量%以上45質量%以下含み、かつ低分子化澱粉と低分子化澱粉以外の澱粉の合計が75質量%以上である、原料を加熱糊化して造粒する工程。
Here, when the component (A) contains low-molecular-weight starch, the component (A) can be obtained by, for example, a production method including the following steps.
(Step of preparing low molecular weight starch) A step of reducing the molecular weight of starch having an amylose content of 5% by mass or more to obtain a low molecular weight starch having a peak molecular weight of 3 × 10 3 or more and 5 × 10 4 or less.
(Granulation step) The raw material contains 3% by mass or more and 45% by mass or less of low-molecular-weight starch, and the total amount of low-molecular-weight starch and starch other than low-molecular-weight starch is 75% by mass or more. The process of granulating.
 低分子化澱粉の調製工程は、アミロース含量5質量%以上の澱粉を分解して低分子化澱粉とする工程である。ここでいう分解とは、澱粉の低分子化を伴う分解をいい、代表的な分解方法として酸処理や酸化処理、酵素処理による分解が挙げられる。この中でも、分解速度やコスト、分解反応の再現性の観点から、好ましくは酸処理である。 The step of preparing low molecular weight starch is a step of decomposing starch having an amylose content of 5% by mass or more into low molecular weight starch. The decomposition referred to here refers to decomposition accompanied by a reduction in the molecular weight of starch, and typical decomposition methods include decomposition by acid treatment, oxidation treatment, and enzyme treatment. Among these, acid treatment is preferable from the viewpoint of decomposition rate, cost, and reproducibility of decomposition reaction.
 また、造粒工程には、澱粉の造粒に使用されている一般的な方法を用いることができるが、所定の冷水膨潤度とする点で、澱粉の加熱糊化に使用されている一般的な方法を用いることが好ましい。具体的には、ドラムドライヤー、ジェットクッカー、エクストルーダー、スプレードライヤーなどの機械を使用した方法が知られているが、本実施形態において、冷水膨潤度が上述した特定の条件を満たす成分(A)をより確実に得る観点から、エクストルーダーやドラムドライヤーによる加熱糊化が好ましく、エクストルーダーがより好ましい。
 エクストルーダー処理する場合は通常、澱粉を含む原料に加水して水分含量を10~60質量%程度に調整した後、たとえばバレル温度30~200℃、出口温度80~180℃、スクリュー回転数100~1,000rpm、熱処理時間5~60秒の条件で、加熱膨化させる。
Further, in the granulation step, a general method used for granulating starch can be used, but it is generally used for heat gelatinization of starch in terms of achieving a predetermined degree of swelling in cold water. It is preferable to use the above method. Specifically, a method using a machine such as a drum dryer, a jet cooker, an extruder, or a spray dryer is known, but in the present embodiment, the component (A) in which the degree of swelling of cold water satisfies the above-mentioned specific condition. From the viewpoint of more reliably obtaining the above, heat gelatinization with an extruder or a drum dryer is preferable, and an extruder is more preferable.
In the case of extruder treatment, usually, after adding water to a raw material containing starch to adjust the water content to about 10 to 60% by mass, for example, a barrel temperature of 30 to 200 ° C., an outlet temperature of 80 to 180 ° C., and a screw rotation speed of 100 to 100 to It is heated and expanded under the conditions of 1,000 rpm and a heat treatment time of 5 to 60 seconds.
 たとえば上記特定の原料を加熱糊化する工程により、冷水膨潤度が特定の条件を満たす成分(A)を得ることができる。
 また、加熱糊化して得られた造粒物を、必要に応じて、粉砕し、篩い分けをし、大きさを適宜調整して、条件(4)等の前述の粒度の条件を満たす成分(A)の粒状物、粉状物またはこれらの混合物を得るとよい。
For example, by the step of heat-gelatinizing the specific raw material, the component (A) having a cold water swelling degree satisfying a specific condition can be obtained.
Further, the granulated product obtained by heat gelatinization is pulverized, sieved, and appropriately adjusted in size, if necessary, to satisfy the above-mentioned particle size conditions such as condition (4). A) granules, powders or mixtures thereof may be obtained.
 本実施形態においては、麺用ほぐれ向上剤が有効成分として成分(A)を含むため、ほぐれ性に優れる麺を得ることができる。また、本実施形態における麺用ほぐれ向上剤を用いることにより、たとえば喫食時の麺の湯戻し時間を短縮することも可能となる。また、本実施形態によれば、たとえば麺のほぐれ性と食感とのバランスを好ましいものとすることも可能となる。 In the present embodiment, since the unraveling improver for noodles contains the ingredient (A) as an active ingredient, it is possible to obtain noodles having excellent unraveling properties. Further, by using the loosening improver for noodles in the present embodiment, it is possible to shorten the time for reconstitution of noodles at the time of eating, for example. Further, according to the present embodiment, for example, it is possible to make the balance between the looseness of the noodles and the texture preferable.
 また、本実施形態において、麺のほぐれ向上方法は、麺用ほぐれ向上剤を麺に適用することを含む。
 また、本実施形態において、喫食時の麺の湯戻し時間短縮方法は、麺用ほぐれ向上剤を麺に適用することを含む。
 次に、麺について説明する。
Further, in the present embodiment, the method for improving the loosening of noodles includes applying a loosening improving agent for noodles to noodles.
Further, in the present embodiment, the method for shortening the reconstitution time of noodles at the time of eating includes applying a loosening improver for noodles to noodles.
Next, the noodles will be described.
 (麺)
 本実施形態の麺用ほぐれ向上剤が適用される麺類の種類としては、そば、うどん、中華麺、パスタ類、冷や麦、素麺等が挙げられ、好ましくは、そば、うどんおよび中華麺から選ばれる1種であり、より好ましくはそばおよび中華麺から選ばれる1種である。また、麺類の形態としては、生麺、乾麺(半乾燥麺を含む。)、茹で麺、蒸し麺、即席麺、茹でまたは蒸し処理された後に保存および流通の少なくとも1つが冷蔵でなされる冷蔵麺(チルド麺)のいずれでもよいが、好ましくは即席麺およびチルド麺から選ばれる1種である。
(noodles)
Examples of the types of noodles to which the loosening improver for noodles of the present embodiment is applied include buckwheat noodles, udon noodles, Chinese noodles, pasta, cold wheat, and plain noodles, and are preferably selected from buckwheat noodles, udon noodles, and Chinese noodles. It is a seed, more preferably one selected from buckwheat noodles and Chinese noodles. As for the forms of noodles, raw noodles, dried noodles (including semi-dried noodles), boiled noodles, steamed noodles, instant noodles, and refrigerated noodles that are stored and distributed after being boiled or steamed are refrigerated. (Chilled noodles) may be used, but it is preferably one selected from instant noodles and chilled noodles.
 麺は、ほぐれ性を安定的に向上する観点から、好ましくは即席麺およびチルド麺から選ばれる1種である。
 同様の観点から、麺は、製麺後、加熱前または加熱後に冷凍される、冷凍麺であることも好ましく、より好ましくは冷凍パスタであり、さらに好ましくは製麺および加熱後に冷凍される冷凍パスタである。
 麺の加熱方法としては、茹で、蒸し、電子レンジ加熱等が挙げられる。
 また、冷凍麺の冷凍後の加熱方法としては、茹で、蒸し、電子レンジ加熱等が挙げられ、好ましくは電子レンジ加熱である。
The noodles are preferably one type selected from instant noodles and chilled noodles from the viewpoint of stably improving the looseness.
From the same viewpoint, the noodles are preferably frozen noodles that are frozen after noodle making, before heating or after heating, more preferably frozen pasta, and even more preferably frozen pasta that is frozen after noodle making and heating. Is.
Examples of the method for heating the noodles include boiling, steaming, and heating in a microwave oven.
Examples of the method for heating the frozen noodles after freezing include boiling, steaming, and microwave heating, and microwave heating is preferable.
 次に、麺の製造方法を説明する。本実施形態において、麺の製造方法は、たとえば前述した麺用ほぐれ向上剤を麺に適用する工程を含む。
 ここで、麺用ほぐれ向上剤を適用するタイミングに制限はなく、たとえば麺の生地の調製段階で麺用ほぐれ向上剤を適用することにより、生地中に麺用ほぐれ向上剤を練り込んでもよいし、製麺後の麺線に麺用ほぐれ向上剤を適用してもよい。
Next, a method for producing noodles will be described. In the present embodiment, the method for producing noodles includes, for example, a step of applying the above-mentioned loosening improver for noodles to noodles.
Here, there is no limitation on the timing of applying the noodle loosening improver. For example, by applying the noodle loosening improver at the stage of preparing the noodle dough, the noodle loosening improver may be kneaded into the dough. , The unraveling improver for noodles may be applied to the noodle strings after the noodles are made.
 麺の生地の調製段階で麺用ほぐれ向上剤を適用する場合、たとえば麺の製造方法において、麺用ほぐれ向上剤を麺に適用する工程は、麺用ほぐれ向上剤を麺の生地に配合する工程であり、麺の製造方法は生地を製麺する工程をさらに含む。
 麺用ほぐれ向上剤を麺の生地に配合する工程において、麺用ほぐれ向上剤は、生地の調製前に他の原材料と混合されていてもよいし、生地の調製後、麺用ほぐれ向上剤を生地中に練り込んでもよい。
When applying the noodle loosening improver at the stage of preparing the noodle dough, for example, in the noodle manufacturing method, the step of applying the noodle loosening improver to the noodles is the step of blending the noodle loosening improver into the noodle dough. The method for producing noodles further includes a step of making dough.
In the process of blending the noodle loosening improver into the noodle dough, the noodle loosening improver may be mixed with other raw materials before the dough is prepared, or after the dough is prepared, the noodle loosening improver is added. It may be kneaded into the dough.
 麺用ほぐれ向上剤を麺の生地に配合する場合の配合量は、麺のほぐれ性を向上させる観点から生地全体に対し好ましくは0.5質量%以上であり、より好ましくは1質量%以上、さらに好ましくは5質量%以上である。
 また、麺の食感を向上する観点から、麺用ほぐれ向上剤を麺の生地に配合する場合の配合量は生地全体に対し好ましくは30質量%以下であり、より好ましくは16質量%以下、さらに好ましくは10質量%以下、さらにより好ましくは9質量%以下である。
When the loosening improver for noodles is blended in the noodle dough, the blending amount is preferably 0.5% by mass or more, more preferably 1% by mass or more, based on the whole dough from the viewpoint of improving the loosening property of the noodles. More preferably, it is 5% by mass or more.
Further, from the viewpoint of improving the texture of the noodles, when the loosening improver for noodles is blended in the noodle dough, the blending amount is preferably 30% by mass or less, more preferably 16% by mass or less, based on the whole dough. It is even more preferably 10% by mass or less, and even more preferably 9% by mass or less.
 また、製麺後の麺線に麺用ほぐれ向上剤を適用する場合、たとえば麺の製造方法において、麺用ほぐれ向上剤を麺に適用する工程は、麺用ほぐれ向上剤を麺の表面に添加する工程であり、好ましくは麺の表面に付着させる工程である。
 麺用ほぐれ向上剤を麺の表面に添加する方法として、たとえば、噴霧、滴下が挙げられる。また、麺用ほぐれ向上剤を麺の表面に添加した後、麺用ほぐれ剤を一様に行き渡らせるため、全体を和える操作をおこなってもよい。
Further, when the loosening improver for noodles is applied to the noodle wire after the noodles are made, for example, in the method of manufacturing noodles, in the step of applying the loosening improver for noodles to the noodles, the loosening improver for noodles is added to the surface of the noodles. This is a step of adhering the noodles to the surface of the noodles.
Examples of the method of adding the loosening improver for noodles to the surface of noodles include spraying and dropping. Further, after the noodle loosening agent is added to the surface of the noodles, the noodle loosening agent may be uniformly distributed, so that the whole may be softened.
 以下に本発明の実施例を示すが、本発明の趣旨はこれらに限定されるものではない。 Examples of the present invention are shown below, but the gist of the present invention is not limited thereto.
 原材料として、主に以下のものを使用した。
準強力粉:特ナンバーワン、日清製粉社製
強力粉:オーション、日清製粉社製
そば粉:富沢商店社製
デュラム粉:デュラムセモリナ粉、富澤商店社製
コーンスターチ:J-オイルミルズ社製、コーンスターチY
ハイアミロースコーンスターチ:J-オイルミルズ社製、HS-7、アミロース含量70質量%
粉粒状物1:製造例1で得られた粉粒状物
粉粒状物2:製造例1で得られた粉粒状物
粉粒状物3:製造例1で得られた粉粒状物
アセチル化タピオカ澱粉:製造例2で得られた澱粉
グルテン:A-グルGB、グリコ栄養食品社製
粉末卵白:サンキララRS、太陽化学社製
茹で槽用pH調整剤製剤:ニューメンソルト、扶桑化学工業社製
The following materials were mainly used as raw materials.
Semi-strong flour: Special number one, Nisshin Flour Mills Strong flour: Aution, Nisshin Flour Mills buckwheat flour: Tomizawa Shoten durum flour: Durum semolina flour, Tomizawa Shoten cornstarch: J-Oil Mills, cornstarch Y
High amylose cornstarch: J-Oil Mills, HS-7, amylose content 70% by mass
Powder Granules 1: Powder Granules Obtained in Production Example 1 Powder Granules 2: Powder Granules Obtained in Production Example 1 Powder Granules 3: Powder Granules Obtained in Production Example 1 Acetylated Tapioca Starch: Starch gluten obtained in Production Example 2: A-glu GB, powdered egg white manufactured by Glyco Nutrition Foods Co., Ltd .: Sankirara RS, pH adjuster formulation for boiling tank manufactured by Taiyo Kagaku Co., Ltd .: New Men Salt, manufactured by Fuso Chemical Industry Co., Ltd.
 (製造例1)
 以下の方法で低分子化澱粉として酸処理澱粉を含む粉粒状物を製造した。
(Manufacturing Example 1)
A powdery granule containing acid-treated starch was produced as low-molecular-weight starch by the following method.
(酸処理ハイアミロースコーンスターチの製造方法)
 ハイアミロースコーンスターチを水に懸濁して35.6%(w/w)スラリーを調製し、50℃に加温した。そこへ、攪拌しながら4.25Nに調製した塩酸水溶液をスラリー質量比で1/9倍量加え反応を開始した。16時間反応後、3%NaOHで中和し、水洗、脱水、乾燥し、酸処理ハイアミロースコーンスターチを得た。
 得られた酸処理ハイアミロースコーンスターチのピーク分子量を以下の方法で測定したところ、ピーク分子量は1.2×104であった。
(Manufacturing method of acid-treated high amylose cornstarch)
High amylose cornstarch was suspended in water to prepare a 35.6% (w / w) slurry, which was heated to 50 ° C. A hydrochloric acid aqueous solution prepared at 4.25 N was added thereto with stirring in an amount of 1/9 times the mass ratio of the slurry, and the reaction was started. After the reaction for 16 hours, the mixture was neutralized with 3% NaOH, washed with water, dehydrated and dried to obtain acid-treated high amylose cornstarch.
The peak molecular weight of the resulting acid-treated high-amylose cornstarch was measured by the following method, the peak molecular weight was 1.2 × 10 4.
(ピーク分子量の測定方法)
 ピーク分子量の測定は、東ソー社製HPLCユニットを使用しておこなった(ポンプDP-8020、RI検出器RS-8021、脱気装置SD-8022)。
(1)試料を粉砕し、JIS-Z8801-1規格の篩で、目開き0.15mm篩下の画分を回収した。この回収画分を移動相に1mg/mLとなるように懸濁し、懸濁液を100℃3分間加熱して完全に溶解した。0.45μmろ過フィルター(ADVANTEC社製、DISMIC-25HP PTFE 0.45μm)を用いてろ過をおこない、ろ液を分析試料とした。
(2)以下の分析条件で分子量を測定した。
カラム:TSKgel α-M(7.8mmφ、30cm)(東ソー社製)2本
流速:0.5mL/min
移動相:5mM NaNO3含有90%(v/v)ジメチルスルホキシド溶液
カラム温度:40℃
分析量:0.2mL
(3)検出器データを、ソフトウェア(マルチステーションGPC-8020modelIIデータ収集ver5.70、東ソー社製)にて収集し、分子量ピークを計算した。
 検量線には、分子量既知のプルラン(Shodex Standard P-82、昭和電工社製)を使用した。
(Measurement method of peak molecular weight)
The peak molecular weight was measured using an HPLC unit manufactured by Tosoh Corporation (pump DP-8020, RI detector RS-8021, degassing device SD-8022).
(1) The sample was pulverized, and the fraction under the sieve with a mesh opening of 0.15 mm was collected with a sieve of JIS-Z8801-1 standard. The recovered fraction was suspended in the mobile phase at 1 mg / mL, and the suspension was heated at 100 ° C. for 3 minutes to completely dissolve it. Filtration was performed using a 0.45 μm filtration filter (DISMIC-25HP PTFE 0.45 μm manufactured by ADVANTEC), and the filtrate was used as an analysis sample.
(2) The molecular weight was measured under the following analytical conditions.
Column: TSKgel α-M (7.8 mmφ, 30 cm) (manufactured by Tosoh Corporation) 2 Flow velocities: 0.5 mL / min
Mobile phase: 90% (v / v) dimethyl sulfoxide solution containing 5 mM NaNO 3 Column temperature: 40 ° C.
Analytical volume: 0.2 mL
(3) The detector data was collected by software (multi-station GPC-8020modelII data collection ver5.70, manufactured by Tosoh Corporation), and the molecular weight peak was calculated.
For the calibration curve, pullulan having a known molecular weight (Shodex Standard P-82, manufactured by Showa Denko KK) was used.
(粉粒状物の製造方法)
 β澱粉(コーンスターチ)79質量%、上述の方法で得られた酸処理ハイアミロースコーンスターチ20質量%、および、炭酸カルシウム1質量%を充分に均一になるまで袋内で混合した。2軸エクストルーダー(幸和工業社製KEI-45)を用いて、混合物を加圧加熱処理した。処理条件は、以下の通りである。
原料供給:450g/分
加水:17質量%
バレル温度:原料入口から出口に向かって50℃、70℃および100℃
出口温度:100~110℃
スクリューの回転数250rpm
 このようにしてエクストルーダー処理により得られた加熱糊化物を110℃にて乾燥し、水分含量を約10質量%に調整した。
(Manufacturing method of powder and granules)
79% by mass of β-starch (cornstarch), 20% by mass of acid-treated high amylose cornstarch obtained by the above method, and 1% by mass of calcium carbonate were mixed in a bag until sufficiently uniform. The mixture was heat-treated under pressure using a twin-screw extruder (KEI-45 manufactured by Kowa Kogyo Co., Ltd.). The processing conditions are as follows.
Raw material supply: 450 g / min Water: 17% by mass
Barrel temperature: 50 ° C, 70 ° C and 100 ° C from the raw material inlet to the outlet
Outlet temperature: 100-110 ° C
Screw rotation speed 250 rpm
The heated paste obtained by the extruder treatment in this manner was dried at 110 ° C. to adjust the water content to about 10% by mass.
 次いで、乾燥した加熱糊化物を、卓上カッター粉砕機で粉砕した後、JIS-Z8801-1規格の篩で篩分けした。篩分けした加熱糊化物を、表1に示す配合割合で混合し、粉粒状物1~3を調製した。また、各粉粒状物の冷水膨潤度を後述の方法で測定した。 Next, the dried heated paste was crushed with a desktop cutter crusher and then sieved with a JIS-Z8801-1 standard sieve. The sieved heated pastes were mixed at the blending ratios shown in Table 1 to prepare powder granules 1 to 3. In addition, the degree of swelling of each powder and granular material in cold water was measured by the method described later.
(冷水膨潤度の測定方法)
(1)試料を、水分計(研精工業社製、型番MX-50)を用いて、125℃で加熱乾燥させて水分測定し、得られた水分値から乾燥物質量を算出した。
(2)この乾燥物質量換算で試料1gを25℃の水50mLに分散した状態にし、30分間25℃の恒温槽の中でゆるやかに撹拌した後、3000rpmで10分間遠心分離(遠心分離機:日立工機社製、日立卓上遠心機CT6E型;ローター:T4SS型スイングローター;アダプター:50TC×2Sアダプタ)し、沈殿層と上澄層に分けた。
(3)上澄層を取り除き、沈殿層質量を測定し、これをB(g)とした。
(4)沈殿層を乾固(105℃、恒量)したときの質量をC(g)とした。
(5)BをCで割った値を冷水膨潤度とした。
(Measuring method of cold water swelling degree)
(1) The sample was heated and dried at 125 ° C. using a moisture meter (manufactured by Kensei Kogyo Co., Ltd., model number MX-50) to measure the moisture content, and the amount of dried substance was calculated from the obtained moisture value.
(2) In terms of the amount of dry substance, 1 g of the sample is dispersed in 50 mL of water at 25 ° C., gently stirred in a constant temperature bath at 25 ° C. for 30 minutes, and then centrifuged at 3000 rpm for 10 minutes (centrifuge: Hitachi Desktop Centrifuge CT6E type; rotor: T4SS type swing rotor; adapter: 50TC x 2S adapter) manufactured by Hitachi Koki Co., Ltd., and separated into a precipitation layer and a supernatant layer.
(3) The supernatant layer was removed, the mass of the precipitate layer was measured, and this was designated as B (g).
(4) The mass when the precipitated layer was dried to dryness (105 ° C., constant weight) was defined as C (g).
(5) The value obtained by dividing B by C was defined as the degree of cold water swelling.
Figure JPOXMLDOC01-appb-T000001
Figure JPOXMLDOC01-appb-T000001
 (製造例2)
 以下の方法でアセチル化タピオカ澱粉を製造した。
 500mLセパラブルフラスコに、タピオカ澱粉(J-オイルミルズ社製)を用い、澱粉160gにスラリー質量に対する澱粉乾物換算質量濃度が38%(dry starch weight/slurry weight)となるよう水を加えたスラリーを調製した。得られたスラリーの温度を30℃にした後、pH8.4で酢酸ビニル2.2gを加え、その後、適時水酸化ナトリウム水溶液を滴下して、反応終了までpHを設定値±0.03以内に維持し、60分間反応させた。その後、スラリーに3質量%水酸化ナトリウムを添加してpH6まで中和し、洗浄脱水したのち乾燥させ、アセチル化タピオカ澱粉を得た。後述の方法でアセチル基含量を測定したところ、得られたアセチル化タピオカ澱粉のアセチル基含量は0.5質量%であった。
(Manufacturing Example 2)
Acetylated tapioca starch was produced by the following method.
In a 500 mL separable flask, tapioca starch (manufactured by J-Oil Mills) was used, and water was added to 160 g of starch so that the starch dry matter equivalent mass concentration with respect to the slurry mass was 38% (dry starch weight / slurry weight). Prepared. After adjusting the temperature of the obtained slurry to 30 ° C., 2.2 g of vinyl acetate was added at pH 8.4, and then an aqueous sodium hydroxide solution was added dropwise at appropriate times to keep the pH within the set value of ± 0.03 until the reaction was completed. It was maintained and reacted for 60 minutes. Then, 3% by mass sodium hydroxide was added to the slurry to neutralize it to pH 6, washed and dehydrated, and then dried to obtain acetylated tapioca starch. When the acetyl group content was measured by the method described later, the acetyl group content of the obtained acetylated tapioca starch was 0.5% by mass.
 ここで、「アセチル基含量」は、以下の方法により測定した。
(1)澱粉試料を130℃で加熱乾燥させた後、水分計(研精工業社製、電磁水分計:型番MX-50)を用いて水分測定し、得られた水分値から乾燥物質量を算出した。
(2)乾燥質量換算で5gの澱粉試料に水50mLおよび数滴の1.0w/v%フェノールフタレインエタノール溶液を加えた。
(3)0.1N水酸化ナトリウム水溶液を、(2)の液の赤色が消えなくなるまで加えた後、0.45N水酸化ナトリウム水溶液8mLを加え、室温で30分間激しく撹拌した。
(4)0.2N塩酸にて液の赤色が消失するまで滴定し、滴定値A(mL)を求めた。
(5)ブランクとして25mLの0.45N水酸化ナトリウム水溶液を同様に0.2N塩酸にて液の赤色が消失するまで滴定し、滴定値B(mL)を求めた。
(6)アセチル基含量は次式より算定した。
アセチル基含量=[(滴定値B-滴定値A)×塩酸規定度×0.43×100]÷試料質量
(上記式中、試料質量=5g、塩酸規定度=0.2Nである。)
Here, the "acetyl group content" was measured by the following method.
(1) After the starch sample is heated and dried at 130 ° C., the moisture content is measured using a moisture meter (manufactured by Kensei Kogyo Co., Ltd., electromagnetic moisture meter: model number MX-50), and the amount of dried substance is determined from the obtained moisture value. Calculated.
(2) 50 mL of water and several drops of a 1.0 w / v% phenolphthalein ethanol solution were added to a starch sample of 5 g in terms of dry mass.
(3) A 0.1 N aqueous sodium hydroxide solution was added until the red color of the liquid (2) did not disappear, then 8 mL of a 0.45 N aqueous sodium hydroxide solution was added, and the mixture was vigorously stirred at room temperature for 30 minutes.
(4) Titration was carried out with 0.2N hydrochloric acid until the red color of the solution disappeared, and the titration value A (mL) was determined.
(5) As a blank, 25 mL of a 0.45N sodium hydroxide aqueous solution was similarly titrated with 0.2N hydrochloric acid until the red color of the solution disappeared, and a titration value B (mL) was determined.
(6) The acetyl group content was calculated from the following formula.
Acetyl group content = [(titration value B-titration value A) x hydrochloric acid normality x 0.43 x 100] ÷ sample mass (in the above formula, sample mass = 5 g, hydrochloric acid normality = 0.2N).
 (実施例1~6、対照例1)
 表2に記載の配合で各例の即席麺(中華麺)を製造し、評価した。評価は専門パネラー2名でおこない、合議により評点を決定した。
(Examples 1 to 6, control example 1)
Instant noodles (Chinese noodles) of each example were produced and evaluated according to the formulations shown in Table 2. The evaluation was conducted by two specialized panelists, and the score was decided by consensus.
(即席麺の製造方法)
 各例について、表2に記載の配合であらかじめほぐれ向上剤を準備した。そして、以下の手順および条件で即席麺を製造した。
(Manufacturing method of instant noodles)
For each example, a loosening improver was prepared in advance according to the formulation shown in Table 2. Then, instant noodles were produced according to the following procedure and conditions.
(製麺)
以下の条件で麺を製造した。
[ミキシング]
 ヌードルメーカーHR2365/01(フィリップス社製)を用いて、以下の手順でミキシングをおこなった。
1.準強力粉とほぐれ向上剤を袋内で混合し、ヌードルメーカーへ投入した。
2.水に食塩、炭酸K、炭酸Na、トリポリリン酸Naを溶解し、水溶液を得た。
3.ヌードルメーカー内の上記1.をミキシングしつつ、上記2.で得られた水溶液を1分かけてヌードルメーカーへ投入した。
4.上記水溶液投入完了後、さらに1分間ミキシングした。
5.壁面に付着した生地を落とし、さらに8分間ミキシングした。
(Marugame)
Noodles were produced under the following conditions.
[mixing]
Mixing was performed by the following procedure using a noodle maker HR2365 / 01 (manufactured by Philips).
1. 1. The semi-strong powder and the loosening improver were mixed in a bag and put into a noodle maker.
2. Salt, potassium carbonate, Na carbonate, and Na tripolyphosphate were dissolved in water to obtain an aqueous solution.
3. 3. Above 1. in the noodle maker. While mixing the above 2. The aqueous solution obtained in 1 was put into a noodle maker over 1 minute.
4. After the addition of the aqueous solution was completed, mixing was performed for another 1 minute.
5. The dough adhering to the wall surface was removed and mixed for another 8 minutes.
[圧延~切り出し]
 製麺機(Terauchi Co.,LTD製)にて以下の条件でおこなった。
・複合1回
・生地休め15分
・圧延4回
・最終厚み1.0~1.4mm
・切り出し:角刃20(刃の後に続く数字は幅30mmに対して麺線が何本あるかを意味する。)
[Rolling-cutting]
The noodle making machine (Terauchi Co., manufactured by LTD) was used under the following conditions.
・ Composite 1 time ・ Dough rest 15 minutes ・ Rolling 4 times ・ Final thickness 1.0-1.4 mm
-Cut out: Square blade 20 (The number following the blade means how many noodle strings there are for a width of 30 mm.)
 得られた麺について、以下の手順で加熱、調味等の調理工程をおこなった。
蒸し:コンベクションオーブン(Maruzen社製、SSC-03)、スチームモード、98℃、2分
着味:着味水26gを蒸し後の麺70gに加え、麺が着味水をすべて吸水するまで和えた。着味水の配合を以下に示す。
The obtained noodles were cooked by the following procedure, such as heating and seasoning.
Steaming: Convection oven (Maruzen, SSC-03), steam mode, 98 ° C, 2 minutes Seasoning: Add 26 g of flavored water to 70 g of steamed noodles and mix until the noodles absorb all the flavored water. .. The composition of the seasoning water is shown below.
(着味水の配合)
 成分        質量部  
塩           5
グルタミン酸Na    5
クエン酸        1
水        1000
(Mixing of seasoning water)
Component mass part
Salt 5
Na 5 glutamate
Citric acid 1
Water 1000
フライ:キャノーラ油で150℃、2min
湯戻し:プラスチック容器に即席麺を入れ、熱湯を注いでフタをして、以下に記載の所定時間静置後に評価に供した。
Fry: Canola oil at 150 ° C, 2 min
Reconstitution with hot water: Instant noodles were placed in a plastic container, hot water was poured into the container, the lid was closed, and the noodles were allowed to stand for a predetermined time as described below before being evaluated.
(評価)
(湯戻し時間)
 製麺、蒸し、着味およびフライまでの各工程を前述の条件でおこなった即席麺をプラスチック容器に入れて、熱湯を即席麺が十分に浸かるように加え、フタをして湯切りした。湯切り後、湯戻し前の麺質量に対する歩留まりが200以上となる時間を以下の基準で評価し、2点以上を合格とした。
3:4分0秒以上4分30秒未満
2:4分30秒以上5分0秒未満
1:5分0秒以上
(Evaluation)
(Rehydration time)
Instant noodles that had undergone each process from noodle making, steaming, seasoning, and frying under the above conditions were placed in a plastic container, boiling water was added so that the instant noodles were sufficiently immersed, and the noodles were covered and drained. The time for the yield to be 200 or more with respect to the mass of noodles after the hot water was drained and before the hot water was rehydrated was evaluated according to the following criteria, and 2 points or more were passed.
3: 4 minutes 0 seconds or more and less than 4 minutes 30 seconds 2: 4 minutes 30 seconds or more and less than 5 minutes 0 seconds 1: 5 minutes 0 seconds or more
(蒸し後のほぐれ)
 製麺した即席麺80gをコンベクションオーブンのスチームモード(98℃、2分)で蒸し、蒸し後の麺70gと26gの着味水を混合した。着味水吸水後の麺を手でほぐした際のほぐれ性を以下の基準で評価し、2点以上を合格とした。
4:よくほぐれる
3:僅かに付着するがほぐれる
2:付着するが軽い力でほぐれる
1:付着してほぐれにくい
(Unraveling after steaming)
80 g of the instant noodles made was steamed in a steam mode (98 ° C., 2 minutes) of a convection oven, and 70 g of the steamed noodles and 26 g of seasoning water were mixed. The loosening property when the noodles were loosened by hand after absorbing the flavored water was evaluated according to the following criteria, and 2 points or more were passed.
4: Well loosened 3: Slightly adhered but loosened 2: Adhered but loosened with light force 1: Adhered and hard to loosen
(湯戻し後のほぐれ)
 製麺、蒸し、着味およびフライまでの各工程を前述の条件でおこなった即席麺をプラスチック容器に入れて、熱湯を即席麺が十分に浸かるように加え、フタをして湯切りした。湯切り後5分静置したあとに箸でほぐした際のほぐれ性を以下の基準で評価し、2点以上を合格とした。
4:よくほぐれる
3:僅かに付着するがほぐれる
2:付着するが軽い力でほぐれる
1:付着してほぐれにくい
(Unraveling after rehydration)
Instant noodles that had undergone each process from noodle making, steaming, seasoning, and frying under the above conditions were placed in a plastic container, boiling water was added so that the instant noodles were sufficiently immersed, and the noodles were covered and drained. The looseness when loosened with chopsticks after being allowed to stand for 5 minutes after draining the water was evaluated according to the following criteria, and 2 points or more were passed.
4: Well loosened 3: Slightly adhered but loosened 2: Adhered but loosened with light force 1: Adhered and hard to loosen
(官能評価)
 製麺、蒸し、着味およびフライまでの各工程を前述の条件でおこなった即席麺をプラスチック容器に入れて、熱湯を即席麺が十分に浸かるように加え、フタをして湯切りした。湯切り後、湯戻し前の麺質量に対する歩留まりが200~205となるまで湯戻しした。湯戻しした麺の食感を基準で評価し、2点以上を合格とした。
4:良好な硬さと粘りがある
3:適度な硬さと粘りがある
2:やや硬く、やや粘りが弱いが麺としては許容範囲
1:硬く粘りが弱く、麺として不適
(sensory evaluation)
Instant noodles that had undergone each process from noodle making, steaming, seasoning, and frying under the above conditions were placed in a plastic container, boiling water was added so that the instant noodles were sufficiently immersed, and the noodles were covered and drained. After draining the water, the noodles were rehydrated until the yield with respect to the mass of the noodles before reconstitution was 200 to 205. The texture of the noodles rehydrated in hot water was evaluated based on the criteria, and a score of 2 or more was passed.
4: Good hardness and stickiness 3: Moderate hardness and stickiness 2: Slightly hard and slightly weak but acceptable for noodles 1: Hard and weak and unsuitable for noodles
Figure JPOXMLDOC01-appb-T000002
Figure JPOXMLDOC01-appb-T000002
 表2より、実施例で得られた即席麺は、対照例のものに比べて、湯戻し時間が短く、麺のほぐれ性に優れていた。
 麺用ほぐれ向上剤中の成分(A)の含有量について、実施例2および4~6より、蒸し後のほぐれにおいては、25質量%以上100質量%以下の時優れており、75質量%以上100質量%以下の時、より優れていた。湯戻し後のほぐれにおいては25質量%以上100質量%以下の時優れており、50質量%以上100質量%以下の時、より優れていた。食感においては25質量%以上100質量%以下の時優れており、25質量%以上75質量%以下の時より優れており、25質量%以上50質量%以下の時さらに優れていた。
 麺用ほぐれ向上剤中の成分(B)の含有量について、実施例4~6より、蒸し後のほぐれにおいては、25質量%以上75質量%以下の時優れており、25質量%の時、より優れていた。湯戻し後のほぐれにおいては25質量%以上75質量%以下の時優れており、25質量%以上50質量%以下の時、より優れていた。食感においては25質量%以上75質量%以下の時優れており、50質量%以上75質量%以下の時より優れていた。
 成分(A)の含有量に対する成分(B)の含有量(表中の(B)/(A))について、実施例4~6より、蒸し後のほぐれにおいては、質量比で0.333以上3.000以下の時優れており、0.333の時、より優れていた。湯戻し後のほぐれにおいては0.333以上3.000以下の時優れており、0.333以上1.000以下の時、より優れていた。食感においては0.333以上3.000以下の時優れており、1.000以上3.000以下の時、より優れていた。
From Table 2, the instant noodles obtained in the examples had a shorter rehydration time and were excellent in loosening property of the noodles as compared with those of the control example.
Regarding the content of the component (A) in the noodle loosening improver, the loosening after steaming is superior from Examples 2 and 4 to 6 when it is 25% by mass or more and 100% by mass or less, and is 75% by mass or more. It was better when it was 100% by mass or less. In the loosening after reconstitution with hot water, it was excellent when it was 25% by mass or more and 100% by mass or less, and it was more excellent when it was 50% by mass or more and 100% by mass or less. The texture was excellent when it was 25% by mass or more and 100% by mass or less, better than when it was 25% by mass or more and 75% by mass or less, and further excellent when it was 25% by mass or more and 50% by mass or less.
Regarding the content of the component (B) in the noodle loosening improver, from Examples 4 to 6, the loosening after steaming is superior when it is 25% by mass or more and 75% by mass or less, and when it is 25% by mass, It was better. In the loosening after reconstitution with hot water, it was excellent when it was 25% by mass or more and 75% by mass or less, and it was more excellent when it was 25% by mass or more and 50% by mass or less. The texture was excellent when it was 25% by mass or more and 75% by mass or less, and was superior to that when it was 50% by mass or more and 75% by mass or less.
Regarding the content of the component (B) ((B) / (A) in the table) with respect to the content of the component (A), from Examples 4 to 6, in the loosening after steaming, the mass ratio is 0.333 or more. It was excellent when it was 3,000 or less, and it was better when it was 0.333. The unraveling after reconstitution with hot water was excellent when it was 0.333 or more and 3.000 or less, and more excellent when it was 0.333 or more and 1.000 or less. The texture was excellent when it was 0.333 or more and 3.000 or less, and more excellent when it was 1.000 or more and 3.000 or less.
 (実施例7~14、対照例2)
 表3に記載の配合で各例のチルド麺(そば)を製造し、評価した。評価は専門パネラー2名でおこない、合議により評点を決定した。
(Examples 7-14, Control Example 2)
The chilled noodles (soba) of each example were produced and evaluated according to the formulations shown in Table 3. The evaluation was conducted by two specialized panelists, and the score was decided by consensus.
(チルド麺の製造方法)
 各例について、表3に記載の配合でほぐれ向上剤を準備した。かかるほぐれ向上剤を含むすべての成分を混合し、以下の条件でチルド麺を製造した。
(Manufacturing method of chilled noodles)
For each example, a loosening improver was prepared according to the formulation shown in Table 3. All the ingredients including the loosening improver were mixed to produce chilled noodles under the following conditions.
(製麺)
 以下の条件で麺を製造した。
[ミキシング]
 ヌードルメーカーHR2365/01(フィリップス社製)を用いて、以下の手順でミキシングをおこなった。
1.準強力粉とほぐれ向上剤を袋内で混合し、ヌードルメーカーへ投入した。
2.食塩水を調製した。
3.ヌードルメーカー内の上記1.をミキシングしつつ、上記2.で得られた食塩水を1分かけてヌードルメーカーへ投入した。
4.食塩水投入完了後、さらに1分ミキシングした。
5.壁面に付着した生地を落とし、さらに8分間ミキシングした。
(Marugame)
Noodles were produced under the following conditions.
[mixing]
Mixing was performed by the following procedure using a noodle maker HR2365 / 01 (manufactured by Philips).
1. 1. The semi-strong powder and the loosening improver were mixed in a bag and put into a noodle maker.
2. A saline solution was prepared.
3. 3. Above 1. in the noodle maker. While mixing the above 2. The saline solution obtained in 1 was put into a noodle maker over 1 minute.
4. After the completion of the saline solution, mixing was performed for another 1 minute.
5. The dough adhering to the wall surface was removed and mixed for another 8 minutes.
[圧延~切り出し]
 製麺機(Terauchi Co.,LTD製)にて以下の条件でおこなった。
・複合1回
・生地休め15分
・圧延4回
・最終厚み1.0~1.4mm
・切り出し:角刃22(刃の後に続く数字は幅30mmに対して麺線が何本あるかを意味する。)
[Rolling-cutting]
The noodle making machine (Terauchi Co., manufactured by LTD) was used under the following conditions.
・ Composite 1 time ・ Dough rest 15 minutes ・ Rolling 4 times ・ Final thickness 1.0-1.4 mm
-Cut out: Square blade 22 (The number following the blade means how many noodle strings there are for a width of 30 mm.)
 得られたそばを以下の手順で加熱調理した。
茹で:対流状態、茹で槽用pH調整剤製剤0.10%を含む水、98℃、1.5分
冷却:水道水30秒、その後氷水30秒
水切り:10回
保管:得られたゆで後のそば30gを直径10.5cmのプラスチックカップに入れ、フタをして4℃で一晩保管した。保管後のそばのほぐれおよび食感を以下の方法で評価した。
The obtained buckwheat was cooked by the following procedure.
Boiled: Convection, water containing 0.10% pH adjuster formulation for boiling tank, 98 ° C, 1.5 minutes Cooling: Tap water 30 seconds, then ice water 30 seconds Draining: 10 times Storage: After boiling 30 g of buckwheat was placed in a plastic cup having a diameter of 10.5 cm, covered, and stored at 4 ° C. overnight. The loosening and texture of buckwheat noodles after storage were evaluated by the following methods.
(評価)
(チルド保管後のほぐれ)
 保管後のそばを箸で持ち上げた際のほぐれを以下の基準で評価し、2点以上を合格とした。
4:よくほぐれる
3:僅かに付着するがほぐれる
2:付着するが軽い力でほぐれる
1:かなり付着しほぐれない
(Evaluation)
(Unraveling after chilled storage)
The loosening when the buckwheat was lifted with chopsticks after storage was evaluated according to the following criteria, and 2 points or more were passed.
4: Well loosened 3: Slightly adhered but loosened 2: Adhered but loosened with light force 1: Very adhered and not loosened
(チルド保管後の官能評価)
 保管後のそばの食感を以下の基準で評価し、2点以上を合格とした。
4:カドがあり歯切れが良い
3:ややカドがあり歯切れが良い
2:僅かにカドがあり歯切れがやや良い
1:カドがなく歯切れが悪い
(Sensory evaluation after chilled storage)
The texture of buckwheat noodles after storage was evaluated according to the following criteria, and 2 points or more were passed.
4: There is a kudzu and the crispness is good 3: There is a little kudzu and the crispness is good 2: There is a slight kudzu and the crispness is a little good 1: There is no kudzu and the crispness is bad
Figure JPOXMLDOC01-appb-T000003
Figure JPOXMLDOC01-appb-T000003
 表3より、実施例で得られたチルド麺は、対照例のものに比べて、麺のほぐれ性と好ましい食感とのバランスに優れていた。
 麺用ほぐれ向上剤を麺の生地に配合する場合の配合量は、実施例7~14より、麺のほぐれ性の観点から、生地全体に対し4.0質量%以上14.2質量%以下の時、優れており、9.4質量%以上14.2質量%以下の時、より優れていた。食感の観点からは4.0質量%以上14.2質量%以下の時、優れており、9.4質量%以上9.9質量%以下の時、より優れていた。
 麺用ほぐれ向上剤中の成分(A)の含有量は、麺のほぐれ性の観点から、45.5質量%以上75.5質量%以下の時優れており、71.4質量%以上75.5質量%以下の時、より優れていた。食感の観点からは45.5質量%以上75.5質量%以下の時優れており、71.4質量%以上74.1質量%以下の時、より優れていた。
 麺用ほぐれ向上剤中の成分(C)の含有量は、麺のほぐれ性の観点から、1.9質量%以上7.1質量%以下の時優れていた。食感の観点からは1.9質量%以上7.1質量%以下の時優れており、3.7質量%以上7.1質量%以下の時、より優れていた。
 麺用ほぐれ向上剤中の成分(D)の含有量は、麺のほぐれ性の観点から、21.4質量%以上54.5質量%以下の時優れており、21.4質量%以上28.6質量%以下の時、より優れていた。食感の観点からは21.4質量%以上54.5質量%以下の時優れており、21.4質量%以上22.6質量%以下の時、より優れており、21.4質量%以上22.2質量%以下の時、より優れていた。
 成分(A)の含有量に対する成分(C)の含有量は、麺のほぐれ性の観点から、質量比で0.025以上0.1以下の時優れていた。食感の観点からは0.025以上0.1以下の時優れており、0.05以上0.1以下の時、より優れていた。
 成分(A)の含有量に対する成分(D)の含有量は、麺のほぐれ性の観点から、質量比で0.300以上1.200以下の時優れており、0.300以上0.400以下の時、より優れていた。食感の観点からは0.300以上1.200以下の時優れており、0.300の時、より優れていた。
From Table 3, the chilled noodles obtained in the examples had an excellent balance between the looseness of the noodles and the favorable texture as compared with those of the control example.
From Examples 7 to 14, the blending amount of the noodle loosening improver when blended in the noodle dough is 4.0% by mass or more and 14.2% by mass or less with respect to the entire dough from the viewpoint of the loosening property of the noodles. When it was excellent, it was superior when it was 9.4% by mass or more and 14.2% by mass or less. From the viewpoint of texture, it was excellent when it was 4.0% by mass or more and 14.2% by mass or less, and it was more excellent when it was 9.4% by mass or more and 9.9% by mass or less.
The content of the component (A) in the noodle loosening improver is excellent when it is 45.5% by mass or more and 75.5% by mass or less, and 71.4% by mass or more and 75. It was better when it was 5% by mass or less. From the viewpoint of texture, it was excellent when it was 45.5% by mass or more and 75.5% by mass or less, and it was more excellent when it was 71.4% by mass or more and 74.1% by mass or less.
The content of the component (C) in the noodle loosening improver was excellent when it was 1.9% by mass or more and 7.1% by mass or less from the viewpoint of the loosening property of the noodles. From the viewpoint of texture, it was excellent when it was 1.9% by mass or more and 7.1% by mass or less, and it was more excellent when it was 3.7% by mass or more and 7.1% by mass or less.
The content of the component (D) in the noodle loosening improver is excellent when it is 21.4% by mass or more and 54.5% by mass or less from the viewpoint of the loosening property of the noodles, and is 21.4% by mass or more and 28. It was better when it was 6% by mass or less. From the viewpoint of texture, it is excellent when it is 21.4% by mass or more and 54.5% by mass or less, and it is better when it is 21.4% by mass or more and 22.6% by mass or less, and it is 21.4% by mass or more. It was better when it was 22.2% by mass or less.
The content of the component (C) with respect to the content of the component (A) was excellent when the mass ratio was 0.025 or more and 0.1 or less from the viewpoint of the looseness of the noodles. From the viewpoint of texture, it was excellent when it was 0.025 or more and 0.1 or less, and it was more excellent when it was 0.05 or more and 0.1 or less.
The content of the component (D) with respect to the content of the component (A) is excellent when the mass ratio is 0.300 or more and 1.200 or less, and 0.300 or more and 0.400 or less, from the viewpoint of the looseness of the noodles. At that time, it was better. From the viewpoint of texture, it was excellent when it was 0.300 or more and 1.200 or less, and it was better when it was 0.300.
(麺用ほぐれ向上剤の調製例1)
 成分(A)として粉粒状物3を、成分(B)として製造例2で得られたアセチル化タピオカ澱粉を用いた。粉粒状物3を40質量部、アセチル化タピオカ澱粉を40質量部、馬鈴薯澱粉(BP-200、J-オイルミルズ社製)を40質量部混合し、本例の麺用ほぐれ向上剤を得た。
(Preparation Example 1 of Unraveling Improver for Noodles)
The powder granules 3 were used as the component (A), and the acetylated tapioca starch obtained in Production Example 2 was used as the component (B). 40 parts by mass of powder granules 3, 40 parts by mass of acetylated tapioca starch, and 40 parts by mass of potato starch (BP-200, manufactured by J-Oil Mills) were mixed to obtain the loosening improver for noodles of this example. ..
(麺用ほぐれ向上剤の調製例2)
 成分(A)として粉粒状物1、成分(C)として粉末卵白、成分(D)としてグルテンを用いた。粉粒状物1を1200質量部、粉末卵白を75質量部、グルテンを350質量部、山芋粉(山芋パウダー、オタフクソース社製)を375質量部混合し、本例の麺用ほぐれ向上剤を得た。
(Preparation example 2 of loosening improver for noodles)
Powder granules 1 were used as the component (A), powdered egg white was used as the component (C), and gluten was used as the component (D). 1200 parts by mass of powder granule 1, 75 parts by mass of powdered egg white, 350 parts by mass of gluten, and 375 parts by mass of Yamaimo powder (Yamaimo powder, manufactured by Otafuku Sauce Co., Ltd.) were mixed to obtain the loosening improver for noodles of this example. It was.
(麺用ほぐれ向上剤の調製例3)
 成分(A)として粉粒状物2、成分(C)として粉末卵白を用いた。粉粒状物2を100質量部、粉末卵白を7質量部、強力粉を300質量部混合し、本例の麺用ほぐれ向上剤を得た。
(Preparation Example 3 of Unraveling Improver for Noodles)
Powder granules 2 were used as the component (A), and powdered egg white was used as the component (C). The powder granule 2 was mixed by 100 parts by mass, the powdered egg white by 7 parts by mass, and the strong flour by 300 parts by mass to obtain the loosening improver for noodles of this example.
 (実施例15、対照例3)
 表4に記載の配合で各例のパスタ(生パスタのスパゲッティ)を製造し、評価した。評価は専門パネラー3名でおこない、合議により評点を決定した。
(Example 15, control example 3)
Pasta (spaghetti of raw pasta) of each example was produced and evaluated by the formulation shown in Table 4. The evaluation was conducted by three specialized panelists, and the score was decided by consensus.
(パスタの製造方法)
1.ヌードルメーカー(フィリップス社製、HR2365/01)のミキサーに表4に記載の成分のうち、粉原料を入れ、その後、30秒かけて液体原料を投入した。
2.合計5分ミキシングし、生地を得た。
3.2mm丸麺の製麺キャップで生地を押し出し、麺を得た。
4.製麺後のミキサー内への生地の付着状態を確認(作業性評価)した。また、得られた麺の麺同士の付着状態すなわちほぐれ性を評価した。
5.以下の条件にて麺を茹でた。得られた麺の歯切れ及び歯ごたえを官能評価した。
茹で:対流状態、茹で槽用pH調整剤製剤0.10%を含む水、98℃、3分~3分30秒
6.上記5.で得られた麺を25℃以下まで真空冷却した。
7.その後、麺を-30℃、4時間冷凍した。
8.冷凍後の麺を700Wで2分間電子レンジ加熱した。
(Pasta manufacturing method)
1. 1. Of the ingredients shown in Table 4, the powder raw material was put into a mixer of a noodle maker (manufactured by Philips, HR2365 / 01), and then the liquid raw material was put over for 30 seconds.
2. The dough was obtained by mixing for a total of 5 minutes.
The dough was extruded with a noodle making cap of 3.2 mm round noodles to obtain noodles.
4. The state of adhesion of the dough into the mixer after noodle making was confirmed (workability evaluation). In addition, the state of adhesion between the obtained noodles, that is, the looseness, was evaluated.
5. The noodles were boiled under the following conditions. The crispness and texture of the obtained noodles were sensory-evaluated.
Boiled: Convection, water containing 0.10% pH adjuster formulation for boiling tank, 98 ° C, 3 minutes to 3 minutes 30 seconds 6. 5. Above. The noodles obtained in the above section were vacuum cooled to 25 ° C. or lower.
7. Then, the noodles were frozen at −30 ° C. for 4 hours.
8. The frozen noodles were microwaved at 700 W for 2 minutes.
(評価)
(ほぐれ性)
 上記4.で得られた麺を手でほぐした際のほぐれ性を以下の基準で評価し、2点以上を合格とした。評価結果を表4に示す。
4:よくほぐれる
3:僅かに付着するがほぐれる
2:付着するが軽い力でほぐれる
1:付着してほぐれにくい
(Evaluation)
(Unraveling)
Above 4. The loosening property of the noodles obtained in 1) when loosened by hand was evaluated according to the following criteria, and 2 points or more were passed. The evaluation results are shown in Table 4.
4: Well loosened 3: Slightly adhered but loosened 2: Adhered but loosened with light force 1: Adhered and hard to loosen
(官能評価)
 上記5.における麺の歯切れおよび歯ごたえを以下の基準で評価し、3点以上を合格とした。評価結果を表4に示す。
<歯切れ>
4:とても歯切れが良い
3:やや歯切れが良い
2:あまり歯切れが良くない
1:歯切れが悪い
 上記5.における麺の歯切れを以下の基準で評価し、3点以上を合格とした。評価結果を表4に示す。
<歯ごたえ>
4:とても歯ごたえがあり好ましい
3:やや歯ごたえがありやや好ましい
2:あまり歯ごたえがなく好ましくない
1:柔らかくて歯ごたえがなく全く好ましくない
(sensory evaluation)
5. Above. The crispness and chewyness of the noodles in the above were evaluated according to the following criteria, and a score of 3 or more was passed. The evaluation results are shown in Table 4.
<Crisp>
4: Very crisp 3: Slightly crisp 2: Not very crisp 1: Poor crisp Above 5. The crispness of the noodles in the above was evaluated according to the following criteria, and a score of 3 or more was passed. The evaluation results are shown in Table 4.
<Cheerful>
4: Very chewy and preferable 3: Somewhat chewy and somewhat preferable 2: Not very chewy and unfavorable 1: Soft and not chewy and totally unfavorable
Figure JPOXMLDOC01-appb-T000004
Figure JPOXMLDOC01-appb-T000004
 実施例15においては、パスタのほぐれ性に優れており、また、茹で後のパスタの歯切れおよび歯ごたえに優れていた。また、上記工程4.におけるヌードルメーカー内への付着性も対照例3より抑制されており、作業性に優れていた。 In Example 15, the pasta was excellent in loosening property, and the pasta after boiling was excellent in crispness and chewyness. In addition, the above step 4. Adhesion to the noodle maker in the noodle maker was also suppressed as compared with Control Example 3, and the workability was excellent.
<即席麺(中華麺)の製造例>
 実施例2と実施例4のうち、成分(A)として粉粒状物1の代わりにα化ハイアミロースコーンスターチ(J-オイルミルズ社製、ジェルコールAH-F、冷水膨潤度6.5)に置き換えた以外は、同じ製造方法で即席麺を得た。
<Production example of instant noodles (Chinese noodles)>
In Examples 2 and 4, the component (A) was replaced with pregelatinized high amylose cornstarch (manufactured by J-Oil Mills, Gelcol AHF, cold water swelling degree 6.5) instead of powder granular material 1. Except for the above, instant noodles were obtained by the same manufacturing method.
 この出願は、2019年9月30日に出願された日本出願特願2019-178450号を基礎とする優先権を主張し、その開示のすべてをここに取り込む。 This application claims priority based on Japanese Application Japanese Patent Application No. 2019-178450 filed on September 30, 2019, and incorporates all of its disclosures herein.

Claims (18)

  1.  以下の成分(A)を有効成分として含む、麺用ほぐれ向上剤。
     成分(A):条件(1)および(2)を満たす粉粒状物
    (1)澱粉含量が75質量%以上
    (2)25℃における冷水膨潤度が5以上40以下
    A loosening improver for noodles containing the following ingredient (A) as an active ingredient.
    Ingredient (A): Powder granules satisfying conditions (1) and (2) (1) Starch content is 75% by mass or more (2) Cold water swelling degree at 25 ° C is 5 or more and 40 or less
  2.  前記成分(A)を当該麺用ほぐれ向上剤全体に対して15質量%以上100質量%以下含有する、請求項1に記載の麺用ほぐれ向上剤。 The noodle loosening improver according to claim 1, which contains the component (A) in an amount of 15% by mass or more and 100% by mass or less based on the total amount of the noodle loosening improver.
  3.  前記澱粉の由来原料が、キャッサバ、とうもろこしおよびコメからなる群から選ばれる1種または2種以上である、請求項1または2に記載の麺用ほぐれ向上剤。 The loosening improver for noodles according to claim 1 or 2, wherein the raw material from which the starch is derived is one or more selected from the group consisting of cassava, corn and rice.
  4.  前記成分(A)が、造粒物または前記造粒物の粉砕物である、請求項1乃至3いずれか1項に記載の麺用ほぐれ向上剤。 The loosening improver for noodles according to any one of claims 1 to 3, wherein the component (A) is a granulated product or a pulverized product of the granulated product.
  5.  前記成分(A)が、以下の条件(3)をさらに満たす、請求項1乃至4いずれか1項に記載の麺用ほぐれ向上剤。
    (3)アミロース含量5質量%以上である澱粉の低分子化澱粉を3質量%以上45質量%以下含み、前記低分子化澱粉のピーク分子量が3×103以上5×104以下
    The loosening improver for noodles according to any one of claims 1 to 4, wherein the component (A) further satisfies the following condition (3).
    (3) Low molecular weight starch of starch having an amylose content of 5% by mass or more is contained in an amount of 3% by mass or more and 45% by mass or less, and the peak molecular weight of the low molecular weight starch is 3 × 10 3 or more and 5 × 10 4 or less.
  6.  前記成分(A)が、以下の条件(4)をさらに満たす、請求項1乃至5いずれか1項に記載の麺用ほぐれ向上剤。
    (4)目開き0.5mmの篩の篩下の画分の含有量が40質量%以上100質量%以下
    The loosening improver for noodles according to any one of claims 1 to 5, wherein the component (A) further satisfies the following condition (4).
    (4) The content of the fraction under the sieve of a sieve having an opening of 0.5 mm is 40% by mass or more and 100% by mass or less.
  7.  麺が、即席麺およびチルド麺から選ばれる1種である、請求項1乃至6いずれか1項に記載の麺用ほぐれ向上剤。 The loosening improver for noodles according to any one of claims 1 to 6, wherein the noodles are one selected from instant noodles and chilled noodles.
  8.  成分(B):アセチル化タピオカ澱粉をさらに含む、請求項1乃至7いずれか1項に記載の麺用ほぐれ向上剤。 Ingredient (B): The loosening improver for noodles according to any one of claims 1 to 7, further comprising acetylated tapioca starch.
  9.  前記成分(A)の含有量に対する成分(B)の含有量が、質量比で0.2以上5以下である、請求項8に記載の麺用ほぐれ向上剤。 The loosening improver for noodles according to claim 8, wherein the content of the component (B) with respect to the content of the component (A) is 0.2 or more and 5 or less in terms of mass ratio.
  10.  即席麺用である、請求項8または9に記載の麺用ほぐれ向上剤。 The loosening improver for noodles according to claim 8 or 9, which is for instant noodles.
  11.  成分(C):卵白をさらに含む、請求項1乃至7いずれか1項に記載の麺用ほぐれ向上剤。 Ingredient (C): The loosening improver for noodles according to any one of claims 1 to 7, further containing egg white.
  12.  前記成分(A)の含有量に対する前記成分(C)の含有量が、質量比で0.005以上0.5以下である、請求項11に記載の麺用ほぐれ向上剤。 The loosening improver for noodles according to claim 11, wherein the content of the component (C) with respect to the content of the component (A) is 0.005 or more and 0.5 or less in terms of mass ratio.
  13.  チルド麺用である、請求項11または12に記載の麺用ほぐれ向上剤。 The loosening improver for noodles according to claim 11 or 12, which is for chilled noodles.
  14.  請求項1乃至13いずれか1項に記載の麺用ほぐれ向上剤を麺に適用する工程を含む、麺の製造方法。 A method for producing noodles, which comprises a step of applying the loosening improver for noodles according to any one of claims 1 to 13 to noodles.
  15.  麺用ほぐれ向上剤を麺に適用する前記工程が、前記麺用ほぐれ向上剤を前記麺の生地に配合する工程であり、
     前記生地を製麺する工程をさらに含む、請求項14に記載の麺の製造方法。
    The step of applying the noodle loosening improver to the noodles is a step of blending the noodle loosening improver into the noodle dough.
    The method for producing noodles according to claim 14, further comprising a step of producing the dough.
  16.  麺用ほぐれ向上剤を麺に適用する前記工程が、前記麺用ほぐれ向上剤を前記麺の表面に添加する工程である、請求項14に記載の麺の製造方法。 The method for producing noodles according to claim 14, wherein the step of applying the noodle loosening improver to noodles is a step of adding the noodle loosening improver to the surface of the noodles.
  17.  請求項1乃至13いずれか1項に記載の麺用ほぐれ向上剤を麺に適用することを含む、麺のほぐれ向上方法。 A method for improving noodle loosening, which comprises applying the noodle loosening improver according to any one of claims 1 to 13 to noodles.
  18.  請求項1乃至13いずれか1項に記載の麺用ほぐれ向上剤を麺に適用することを含む、喫食時の麺の湯戻し時間短縮方法。 A method for shortening the reconstitution time of noodles at the time of eating, which comprises applying the loosening improver for noodles according to any one of claims 1 to 13 to the noodles.
PCT/JP2020/035132 2019-09-30 2020-09-16 Agent for improving loosening properties of noodles WO2021065520A1 (en)

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Publication number Priority date Publication date Assignee Title
CN113397102A (en) * 2021-07-01 2021-09-17 贵州金炜食品有限公司 Matcha fine dried noodles

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH05211851A (en) * 1992-02-03 1993-08-24 Matsutani Kagaku Kogyo Kk Production of nonfried precooked noodle
JPH06276972A (en) * 1993-03-26 1994-10-04 Taiyo Kagaku Co Ltd Agent for improving quality of noodles and production of noodles
JP2000083610A (en) * 1998-09-11 2000-03-28 Nisshin Flour Milling Co Ltd Production of noodle
JP2000125792A (en) * 1998-10-20 2000-05-09 Nisshin Flour Milling Co Ltd Production of dried noodle
WO2014132534A1 (en) * 2013-02-26 2014-09-04 株式会社J-オイルミルズ Composition, and batter material, food, drink and feed, using same, and process for manufacturing composition
JP6408732B1 (en) * 2018-03-20 2018-10-17 日清製粉株式会社 Flour composition for noodles and method for producing noodles

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH05211851A (en) * 1992-02-03 1993-08-24 Matsutani Kagaku Kogyo Kk Production of nonfried precooked noodle
JPH06276972A (en) * 1993-03-26 1994-10-04 Taiyo Kagaku Co Ltd Agent for improving quality of noodles and production of noodles
JP2000083610A (en) * 1998-09-11 2000-03-28 Nisshin Flour Milling Co Ltd Production of noodle
JP2000125792A (en) * 1998-10-20 2000-05-09 Nisshin Flour Milling Co Ltd Production of dried noodle
WO2014132534A1 (en) * 2013-02-26 2014-09-04 株式会社J-オイルミルズ Composition, and batter material, food, drink and feed, using same, and process for manufacturing composition
JP6408732B1 (en) * 2018-03-20 2018-10-17 日清製粉株式会社 Flour composition for noodles and method for producing noodles

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