WO2021049457A1 - Method for producing food composition - Google Patents

Method for producing food composition Download PDF

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Publication number
WO2021049457A1
WO2021049457A1 PCT/JP2020/033777 JP2020033777W WO2021049457A1 WO 2021049457 A1 WO2021049457 A1 WO 2021049457A1 JP 2020033777 W JP2020033777 W JP 2020033777W WO 2021049457 A1 WO2021049457 A1 WO 2021049457A1
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WIPO (PCT)
Prior art keywords
milk
composition
condensed milk
powder
weight
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PCT/JP2020/033777
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French (fr)
Japanese (ja)
Inventor
卓治 朝日
真理子 福嶋
森繁 直樹
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雪印メグミルク株式会社
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Application filed by 雪印メグミルク株式会社 filed Critical 雪印メグミルク株式会社
Priority to JP2021545523A priority Critical patent/JPWO2021049457A1/ja
Priority to CN202080063720.6A priority patent/CN114375160A/en
Publication of WO2021049457A1 publication Critical patent/WO2021049457A1/en

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    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23CDAIRY PRODUCTS, e.g. MILK, BUTTER OR CHEESE; MILK OR CHEESE SUBSTITUTES; MAKING THEREOF
    • A23C9/00Milk preparations; Milk powder or milk powder preparations
    • A23C9/18Milk in dried and compressed or semi-solid form
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23CDAIRY PRODUCTS, e.g. MILK, BUTTER OR CHEESE; MILK OR CHEESE SUBSTITUTES; MAKING THEREOF
    • A23C9/00Milk preparations; Milk powder or milk powder preparations
    • A23C9/152Milk preparations; Milk powder or milk powder preparations containing additives
    • A23C9/1526Amino acids; Peptides; Protein hydrolysates; Nucleic acids; Derivatives thereof
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23CDAIRY PRODUCTS, e.g. MILK, BUTTER OR CHEESE; MILK OR CHEESE SUBSTITUTES; MAKING THEREOF
    • A23C9/00Milk preparations; Milk powder or milk powder preparations
    • A23C9/152Milk preparations; Milk powder or milk powder preparations containing additives
    • A23C9/156Flavoured milk preparations ; Addition of fruits, vegetables, sugars, sugar alcohols or sweeteners

Definitions

  • the present invention relates to a food composition, more particularly a condensed milk-like composition.
  • the present invention also relates to a method for producing a food composition, and more particularly to a method for producing a condensed milk-like composition.
  • Sweetened condensed milk is generally produced by dissolving sucrose in raw milk, then evaporating the water content and concentrating it 2-3 times.
  • the water activity of sweetened condensed milk is reduced to about 0.8 to 0.9 by increasing the solid content, the growth of microorganisms is suppressed, and the storage stability is improved, so that it can be distributed at room temperature.
  • general sweetened condensed milk there are many steps such as acceptance of raw milk, storage of milk, standardization, simmering, homogenization, sterilization, concentration, cooling, and seeding.
  • equipment corresponding to these is required, and large-scale equipment / equipment may be required especially in the process of receiving raw milk, storing milk, and concentrating.
  • Condensed milk that is concentrated under reduced pressure or heated by adding sucrose and vegetable oil as a substitute for milk fat to reduced milk obtained by dissolving full-fat milk powder or skim milk powder in water without using raw milk for the purpose of reducing raw material costs.
  • Dairy products are on the market at home and abroad.
  • Various manufacturing methods have been proposed for condensed milk-like dairy products. For example, a condensed milk-like whey composition obtained by adding water, sucrose, dextrin, milk protein concentrate, and coconut-hardening oil to liquid whey obtained as a by-product of dairy product production has been proposed.
  • Patent Document 1 As a method of simplifying the manufacturing process, skim milk concentrate, skim milk powder, full-fat milk powder, and sucrose are used as raw materials and mixed with high-concentration raw materials in a multifunction tank, etc. to reduce the concentration process and be equivalent to sweetened condensed milk. A method for producing a condensed milk-like dairy product having sensory and physical properties has been proposed.
  • Patent Document 2 Patent Document 3
  • Patent Document 4 As a method for reducing the seeding process, a production method using concentrated milk obtained by membrane-treating raw milk and removing lactose has been proposed.
  • Patent Document 4 As a method for reducing the seeding process, a production method using concentrated milk obtained by membrane-treating raw milk and removing lactose has been proposed.
  • Japanese Patent No. 6012177 Japanese Patent Application Laid-Open No. 2003-199492 Japanese Patent Application Laid-Open No. 2014-226139 Japanese Patent Application Laid-Open No. 9-224566
  • An object to be solved by the present invention is to provide a condensed milk-like composition having the same flavor, viscosity characteristics, and storage stability by a simpler production method than the conventional condensed milk-like composition.
  • a high-concentration raw material mixing method with a reduced concentration process is applied, but if the solid content concentration similar to that of sweetened condensed milk is maintained, the amount of dissolved water decreases and powder dissolution becomes difficult. Insufficient dissolution causes poor flavor, poor structure, increased viscosity, and burning during heating. Therefore, it is necessary to use concentrated milk or skim milk concentrated milk in which milk protein is hydrated in advance, or to prepare a high-performance dissolving machine for improving solubility.
  • the amount of dissolved water is increased for the purpose of improving the solubility, the solid concentration is lowered, and the flavor and properties are light and poor as compared with the conventional sweetened condensed milk.
  • the increase in water activity promotes the growth of microorganisms and impairs storage stability. By increasing the amount of dissolved water while maintaining an appropriate solid concentration while maintaining low water activity, powder dissolution becomes easy while maintaining a condensed milk-like flavor.
  • the present inventors have diligently studied in order to solve the above problems, and by using sugar alcohol and concentrated milk protein powder which has been previously treated to remove lactose, the manufacturing process is simplified and the same flavor and viscosity characteristics are exhibited. They have found that a condensed milk-like composition having good storage stability at the time of refrigeration and at room temperature can be provided, and have completed the present invention.
  • the present invention is as follows.
  • the ratio of the milk protein derived from the concentrated milk protein powder to the milk protein derived from the milk powder is 1: 4 to 4: 1, ⁇ 1> or ⁇ . 2> The condensed milk-like composition.
  • ⁇ 5> Includes a step of adding and mixing sugar alcohol, concentrated lactose protein powder, and milk powder to dissolved water to obtain a condensed milk-like mix, and a step of sterilizing the condensed milk-like mix to obtain a condensed milk-like composition.
  • ⁇ 6> The method for producing a condensed milk-like composition according to ⁇ 5>, wherein 18% by weight or more of the milk protein contained in the condensed milk-like composition is derived from concentrated milk protein powder.
  • the ratio of the milk protein derived from the concentrated milk protein powder to the milk protein derived from the milk powder is 1: 4 to 4: 1, ⁇ 5> or ⁇ .
  • 6> The method for producing a condensed milk-like composition.
  • ⁇ 8> The method for producing a condensed milk-like composition according to any one of ⁇ 5> to ⁇ 7>, which does not include a seeding step.
  • the present invention also comprises the following embodiments.
  • ⁇ 1> A condensed milk-like composition containing sugar alcohol, concentrated milk protein powder, and milk powder, wherein the content of lactose is 21% by weight or less in water lactose concentration.
  • ⁇ 2> The condensed milk-like composition according to ⁇ 1>, wherein 18% by weight or more of the milk protein contained in the condensed milk-like composition is derived from concentrated milk protein powder.
  • the ratio of the milk protein derived from the concentrated milk protein powder to the milk protein derived from the milk powder is 1: 4 to 4: 1, ⁇ 1> or ⁇ . 2> The condensed milk-like composition.
  • ⁇ 4> The condensed milk-like composition according to any one of ⁇ 1> to ⁇ 3>, further containing a vegetable oil and / or sugar.
  • ⁇ 5> A condensed milk-like composition containing 1 to 30% by weight of sugar alcohol, 1 to 20% by weight of concentrated milk protein powder, 1 to 30% by weight of milk powder, and 20 to 60% by weight of water based on the condensed milk-like composition.
  • ⁇ 6> The condensed milk according to any one of ⁇ 1> to ⁇ 5>, wherein the concentrated milk protein powder contains 50 to 99% by weight of milk protein, 0.01 to 8% by weight of lactose, and 0 to 8% by weight of water.
  • Composition. ⁇ 7> The condensed milk-like composition according to any one of ⁇ 1> to ⁇ 6>, wherein the milk powder contains 10 to 50% by weight of milk protein, 10 to 80% by weight of lactose, and 0 to 8% by weight of water.
  • the sugar alcohol is selected from the group consisting of glycerin, erythreitol, mannitol, martitol, sorbitol, xylitol, ribitol, inositol, D-threitol, L-threitol, D-arabinitol, and L-arabinitol 1
  • the condensed milk-like composition according to any one of ⁇ 1> to ⁇ 3> which is one or more.
  • ⁇ 9> The condensed milk-like composition according to any one of ⁇ 1> to ⁇ 3>, wherein the content of condensed milk is 50% by weight or less, preferably 30% by weight or less based on the condensed milk-like composition.
  • the condensed milk-like composition according to. ⁇ 11> Includes a step of adding and mixing sugar alcohol, concentrated lactose protein powder, and milk powder to dissolved water to obtain a condensed milk-like mix, and a step of sterilizing the condensed milk-like mix to obtain a condensed milk-like composition.
  • ⁇ 12> The method for producing a condensed milk-like composition according to ⁇ 11>, wherein 18% by weight or more of the milk protein contained in the condensed milk-like composition is derived from concentrated milk protein powder.
  • the ratio of the milk protein derived from the concentrated milk protein powder to the milk protein derived from the milk powder is 1: 4 to 4: 1, ⁇ 11> or ⁇ . 12>
  • the method for producing a condensed milk-like composition is 1: 4 to 4: 1, ⁇ 11> or ⁇ .
  • the method for producing a condensed milk-like composition ⁇ 14> The method for producing a condensed milk-like composition according to any one of ⁇ 11> to ⁇ 13>, which does not include a seeding step.
  • the condensed milk-like composition contains 1 to 30% by weight of sugar alcohol, 1 to 20% by weight of concentrated milk protein powder, 1 to 30% by weight of powdered milk, and 20 to 60% by weight of water based on the condensed milk-like composition.
  • the method for producing a condensed milk-like composition according to any one of ⁇ 11> to ⁇ 14> which comprises.
  • the sugar alcohol is selected from the group consisting of glycerin, erythreitol, mannitol, martitol, sorbitol, xylitol, ribitol, inositol, D-threitol, L-threitol, D-arabinitol, and L-arabinitol 1
  • the method for producing a condensed milk-like composition according to any one of ⁇ 11> to ⁇ 17>, which is one or more.
  • the condensed milk-like composition according to any one of ⁇ 11> to ⁇ 18>, wherein the content of condensed milk in the condensed milk-like composition is 50% by weight or less, preferably 30% by weight or less based on the condensed milk-like composition. Manufacturing method of things.
  • the sugar alcohol means a sugar having an alcohol group (OH group), which is produced by reducing a saccharide (for example, a monosaccharide, a disaccharide, etc.).
  • OH group an alcohol group
  • sugar alcohol By adding sugar alcohol to the condensed milk-like composition, it is possible to increase the water content while reducing the water activity, so that the solubility of the powder raw material can be improved. Further, by adding sugar alcohol to the condensed milk-like composition, it is possible to raise the water value while reducing the water activity, so that the generation of microorganisms can be prevented, and therefore the storage at room temperature becomes possible.
  • the solid content concentration is the same as that of sweetened condensed milk, the sugar concentration becomes high and the food becomes a high-calorie food. However, by using sugar alcohol, the total solid content can be reduced to reduce the calories. ..
  • the sugar alcohols that can be used in the condensed milk-like composition of the present invention are not limited to the following, but are not limited to glycerin, erythreitol, mannitol, maltitol, sorbitol, xylitol, ribitol, inositol, D-threitol, and L. -Threitol, D-arabinitol, L-arabinitol and the like can be mentioned. Considering the high solubility in water and the effect of reducing water activity, it is preferable to use one or more selected from the group consisting of sorbitol, xylitol, erythritol, and glycerin. Two or more of these sugar alcohols can be used in combination.
  • the amount of the sugar alcohol to be blended is not limited to the following, but is preferably 1 to 30% by weight based on the condensed milk-like composition in consideration of the flavor and physical properties of the condensed milk-like composition and the operability during production. Is 2 to 20% by weight, more preferably 3 to 15% by weight, and most preferably 5 to 10% by weight.
  • the concentrated milk protein powder is a powder raw material containing lactose as a main component from which lactose has been removed.
  • lactose is removed by means or operations such as membrane treatment.
  • the milk protein content can be, for example, 50-99% by weight, 60-99% by weight, 70-99% by weight, or 80-99% by weight.
  • the lactose content can be, for example, 0.01-8% by weight, more preferably 0.1-4% by weight.
  • the water content of the concentrated milk protein powder can be 0-8% by weight.
  • Concentrated milk protein powder may contain ash, lipids and the like. However, it is preferable that the content of ash and lipid is low. In this case, the milk protein content can be preferably 70-99% by weight, more preferably 80-99% by weight.
  • the concentrated milk protein powder that can be used in the condensed milk-like composition of the present invention is not limited to the following, but is not limited to the following, but is not limited to the following, but is not limited to the following, but is not limited to the following, but is not limited to the following.
  • Concentrate isolated whey protein (WPI: Whey Protein Isolate) and isolated milk protein (MPI: Milk Protein Isolate). Two or more kinds of these concentrated milk protein powders can be used in combination. It is preferable to use MPC and / or WPC.
  • MPC is obtained by concentrating milk or skim milk with a filtration membrane such as an ultrafiltration membrane, and pulverizing milk protein in the milk.
  • lactose is removed by filtration treatment.
  • MPC is sometimes called TMP (Total Milk Protein).
  • MPI is prepared by the same process as MPC, but MPI is obtained by further concentrating and separating only milk protein in milk by ion exchange chromatography or the like, and generally has a higher milk protein content than MPC. high.
  • WPC is obtained by separating lactose, minerals, and vitamins from whey and recovering and powdering whey protein.
  • WPC concentrates and dries whey protein by treating milk-derived liquids containing whey protein, such as cheese whey and acid whey, with a filtration membrane such as an ultrafiltration membrane or a dia-filtration membrane.
  • whey protein such as cheese whey and acid whey
  • a filtration membrane such as an ultrafiltration membrane or a dia-filtration membrane.
  • WPI is prepared by the same process as WPC, but WPI is obtained by concentrating and separating only the protein in whey by ion exchange chromatography or the like, and generally has a higher protein content than WPC.
  • the blending amount of the concentrated milk protein powder is not limited to the following, but in consideration of the flavor and physical characteristics of the condensed milk-like composition, 1 to 20% by weight, preferably 1 to 15 by weight based on the condensed milk-like composition. By weight%, more preferably 1 to 10% by weight, even more preferably 1.8 to 10% by weight.
  • the concentrated milk protein powder is not limited to the following, but the milk protein derived from the condensed milk protein powder in the condensed milk-like composition is 1.5 to 15 in consideration of the flavor and physical properties of the condensed milk-like composition. It can be added to the condensed milk-like composition in an amount of% by weight, preferably 1.5 to 10% by weight, more preferably 1.5 to 8% by weight.
  • Concentrated milk, skim milk powder, whey powder, etc. that have not been treated with lactose have a high lactose content, and when the general sweetened condensed milk and solid content are combined, the lactose concentration in water is high. Therefore, when these raw materials are used, coarse crystallization of lactose becomes a problem. Therefore, a seeding step is required to suppress the coarse crystallization of lactose. Seeding is the addition of ground lactose to pre-precipitate fine lactose crystals. Lactose used in the seeding process needs to be pulverized (micronized) as a pretreatment. Further, since lactose is added at a predetermined temperature, temperature control is required and the operation is performed in an open system. Therefore, process control becomes complicated, and there is a risk of foreign matter contamination and microbial contamination. By using the powdered milk raw material, the raw material cost is relatively low, and the raw material procurement, raw material storage, and handleability are also simplified.
  • concentrated milk protein powder By using concentrated milk protein powder together and adjusting the lactose concentration, the seeding process can be eliminated. Further, by using the concentrated milk protein powder which is a powder raw material instead of the liquid milk raw material, the concentration step can be reduced. Further, by using the concentrated milk protein powder, the process can be simplified. In addition, concentrated milk protein powder is relatively inexpensive, easy to procure, and can be stored at room temperature.
  • the milk powder is a powder raw material made from milk that has not been treated to remove lactose, and examples thereof include full-fat milk powder, skim milk powder, and whey powder.
  • the milk protein content can be, for example, 10-50% by weight, 10-45% by weight, 10-40% by weight, or 10-38% by weight.
  • the lactose content can be, for example, 10-80% by weight, 20-65% by weight, 30-65% by weight, or 35-60% by weight.
  • the water content of the milk powder can be 0-8% by weight.
  • Milk powder may contain ash, lipids and the like. However, it is preferable that the content of ash and lipid is low.
  • the lactose content can be preferably 35 to 80% by weight, more preferably 40 to 70% by weight, and even more preferably 50 to 60% by weight.
  • the blending amount of milk powder is not limited to the following, but is preferably 1 to 30% by weight based on the condensed milk-like composition in consideration of the flavor and physical properties of the condensed milk-like composition and the amount of lactose brought in from the milk powder. Is 2 to 20% by weight, more preferably 3 to 20% by weight.
  • the milk powder is not limited to the following, but the milk protein derived from the milk powder in the condensed milk-like composition is 3.0 to 3, considering the flavor and physical properties of the condensed milk-like composition and the amount of lactose brought in from the condensed milk. It can be added to the condensed milk-like composition of the present invention in an amount of 20% by weight, preferably 3.0 to 18% by weight, more preferably 3.0 to 15% by weight.
  • the amount of milk protein contained in the condensed milk-like composition of the present invention is not limited to the following, but is, for example, 1 to 30% by weight, preferably 2 to 20% by weight, more preferably based on the condensed milk-like composition. Is 3 to 15% by weight, most preferably 5.0 to 10% by weight.
  • the Kjeldahl method can be used to measure the amount of milk protein contained in the condensed milk-like composition.
  • the Kjeldahl method is one of the nitrogen quantitative conversion methods, and is an analytical method for determining the amount of nitrogen contained in a sample by chemical treatment.
  • 18% by weight or more, more preferably 18% by weight or more of the contained milk protein, in consideration of the flavor and physical properties of the condensed milk-like composition and the amount of lactose brought in from the milk powder 18% to 80% by weight, more preferably 18% to 60% by weight, even more preferably 20% to 50% by weight is derived from concentrated milk protein powder.
  • the ratio of milk protein derived from concentrated milk protein powder to milk protein derived from powdered milk (milk protein derived from concentrated milk protein powder: milk protein derived from powdered milk).
  • milk protein derived from concentrated milk protein powder milk protein derived from powdered milk
  • the condensed milk-like composition of the present invention may, if necessary, contain a protein source other than milk protein, for example, a plant-derived protein such as soybean, but preferably does not contain it.
  • a protein source other than milk protein for example, a plant-derived protein such as soybean, but preferably does not contain it.
  • the amount of protein other than milk protein is 10% by weight or less, preferably 5% by weight or less in the amount of protein in the condensed milk-like composition of the present invention.
  • Liquid milk liquid milk such as milk, skim milk, and concentrated milk
  • lactose is a disaccharide contained in milk and has a structure in which D-glucose (dextrose) and D-galactose are bound.
  • the lactose concentration in water is 21% by weight or less, preferably 20% by weight or less, more preferably 18% by weight or less, and most preferably 15% by weight or less.
  • the lower limit of the lactose concentration in water can be 0.01% by weight or more, or 0.1% by weight or more.
  • the lactose concentration in water in the condensed milk-like composition can be measured by the rain-Ainon method.
  • the condensed milk-like composition of the present invention is characterized in that the lactose content is 21% by weight or less in terms of the lactose concentration in water.
  • lactose exists in a state of being dissolved in water in the condensed milk-like composition, and the solubility of lactose is related to the amount of water and the amount of lactose. Represents.
  • lactose concentration in water (% by weight) is calculated by [weight of lactose in composition / (weight of lactose in composition + weight of water in composition) x 100].
  • the fat content in condensed milk contributes to the richness and physical properties peculiar to condensed milk, but milk fat derived from raw milk is expensive.
  • inexpensive oil and fat raw materials preferably vegetable oil and fat raw materials
  • Milk fat can also be used as a raw material for imparting fat content. It is preferable to use salad oil such as rapeseed salad oil and soybean salad oil in consideration of the fact that it is relatively inexpensive, has a low melting point, does not crystallize even at low temperatures, and has no peculiar taste or odor.
  • the oil and fat raw material is preferably contained in the condensed milk-like composition of the present invention in an amount of 0 to 10% by weight, more preferably 1 to 10% by weight, and even more preferably 2 to 8% by weight. It should be noted that the lower the amount of fat, the lower the calories, but it may cause lack of richness and thickening phenomenon.
  • the condensed milk-like composition of the present invention can contain saccharides, preferably 5 to 60% by weight based on the condensed milk-like composition.
  • the "sugar" contained in the condensed milk-like composition means a monosaccharide, a disaccharide, and a polysaccharide excluding the above-mentioned lactose.
  • Sugar alcohols are not included in sugars.
  • the monosaccharide glucose (dextrose), galactose, mannose, fructose and the like can be used.
  • As the disaccharide sucrose, maltose, trehalose, cellobiose and the like can be used.
  • raffinose maltotriose and the like
  • polysaccharide dextrin or the like
  • dextrin it is preferable to add dextrin for sweetening and adjusting viscosity.
  • a sugar dextrin or the like
  • DE10 to 25 one or more dextrins with DE10 to 25 can be selected.
  • DE is the equivalent of dextrose and refers to the saccharification rate of starch.
  • the condensed milk-like composition of the present invention it is preferable to combine various sugars such as trehalose. By combining various sugars, it is possible to impart a refreshing sweetness and appropriate physical properties.
  • one kind or two or more kinds of emulsifiers can be blended in order to stabilize the emulsification of fats and oils. As the emulsifier, one used for food can be appropriately adopted.
  • the blending amount of the emulsifier in the condensed milk-like composition can be appropriately selected in consideration of the emulsification stability of fats and oils.
  • sugars such as sucrose, dextrin, and trehalose are preferably 10 to 60% by weight, more preferably 20 to 50% by weight, still more preferably 30 to 50% by weight, most preferably. Is contained in an amount of 35 to 45% by weight.
  • the condensed milk-like composition of the present invention contains 20 to 60% by weight, preferably 20 to 50% by weight, more preferably 25 to 45% by weight, still more preferably 30 to 45% by weight, based on the condensed milk-like composition. be able to.
  • Condensed milk is concentrated milk, skim milk, and the like. Condensed milk is classified into unsweetened condensed milk, sweetened condensed milk, unsweetened skim milk, and sweetened skim condensed milk in the "Ministry Ordinance on Ingredient Standards for Milk and Milk Products" (abbreviated as the Ministry Ordinance for Milk, etc.).
  • the condensed milk-like composition of the present invention contains concentrated milk protein powder, milk powder and the like as raw materials. Therefore, the condensed milk-like composition of the present invention is a "condensed milk-like composition" that does not correspond to condensed milk under the Ordinance of the Ministry of Milk, etc., but has the same flavor, appearance, and physical characteristics as condensed milk.
  • the condensed milk-like composition of the present invention may contain condensed milk as a raw material, but it is preferably not contained or substantially not contained from the viewpoint of flavor and calories.
  • the content of condensed milk in the condensed milk-like composition of the present invention is 50% by weight or less, 40% by weight or less, 30% by weight or less, 20% by weight or less, 10% by weight or less, or based on the condensed milk-like composition. It can be 5% by weight or less.
  • the condensed milk-like composition of the present invention uses HAAKE VT550 (manufactured by HAAKE) and a rotor VIIst at a viscosity of 20 ° C., and has a shear rate of 0s -1 ⁇ (2min) ⁇ 200s -1 ⁇ (2min) ⁇ 0s -1.
  • the maximum value is preferably 500 mPa ⁇ s to 5000 mPa ⁇ s.
  • the condensed milk-like composition of the present invention is preferably a sweetened condensed milk-like or a sweetened skim condensed milk-like composition.
  • the condensed milk-like composition of the present invention preferably has a water activity of 0.8 to 0.9.
  • the condensed milk-like composition of the present invention can maintain a low water activity and can be distributed at room temperature.
  • the condensed milk-like composition of the present invention can prevent the generation of coarse crystals of lactose even during low-temperature storage.
  • the solubility of lactose dissolved in a solvent decreases as the temperature decreases. Therefore, when stored at a low temperature, the texture is more likely to deteriorate due to the formation of coarse crystals of lactose.
  • Condensed milk and condensed milk-like compositions are convenient if they can be distributed at room temperature, but after being opened at home or in a store, they are often stored in a refrigerator or the like to improve storage stability. Even if it can be distributed at room temperature, it may be distributed in a refrigerated state depending on the circumstances of stores and delivery vehicles. Therefore, condensed milk and condensed milk-like compositions are required to have storage stability both at room temperature and at low temperature.
  • storage at "normal temperature” means storage at 25 ⁇ 1 ° C.
  • storage at "low temperature” means storage at 5 ⁇ 1 ° C.
  • the condensed milk-like composition of the present invention can have good storage stability at both normal temperature and low temperature. “Having good storage stability” means that no coarse crystals of lactose are detected in any environment, for example, at 25 ⁇ 1 ° C. for 7 days or at 5 ⁇ 1 ° C. for 7 days.
  • the method for producing a condensed milk-like composition of the present invention includes a step of adding sugar alcohol, concentrated milk protein powder, and milk powder to dissolved water and mixing them to obtain a condensed milk-like mix.
  • dissolved water, sugar alcohol, concentrated milk protein powder, and milk powder are mixed so that the lactose content of the condensed milk-like mix is 21% by weight or less in water lactose concentration.
  • the melting temperature can be appropriately adjusted according to the production amount, production equipment, type of raw material, and the like.
  • the sugar alcohol, concentrated milk protein powder, and milk powder the above-mentioned ones can be used.
  • powdered sugar alcohol may be used, or liquid sugar alcohol may be used.
  • the order of addition of sugar alcohol, concentrated milk protein powder, and milk powder is not particularly limited, and can be appropriately adjusted according to the production amount, production equipment, type of raw material, and the like.
  • the premix may be prepared, i.e., sugar alcohol, concentrated milk protein powder, and milk powder, and if necessary, other ingredients may be premixed before addition to the dissolved water.
  • sugar alcohol, concentrated milk protein powder, and milk powder may be added to the manufacturing equipment first, and then dissolved water may be added.
  • a solution may be prepared by dissolving some raw materials in water in advance, and the solution may be added to the solution.
  • the dissolved water does not have to be pure water, and may contain other components as long as the effects of the present invention can be obtained and the above-mentioned raw materials can be dissolved.
  • the method for producing a condensed milk-like composition of the present invention includes a step of sterilizing the condensed milk-like mix to obtain a condensed milk-like composition.
  • sterilizing means reducing or completely killing microorganisms present in a condensed milk-like mix by heating or the like.
  • emulsifying machine mixed powder raw materials, vegetable oils and fats, sugar alcohols, water and the like can be added and premixed and emulsified. Prior to sterilization, it is preferable to premix and emulsify under a temperature condition of 50 to 60 ° C. The premixed and emulsified mix can be sterilized at 85-95 ° C.
  • the sterilization treatment can be performed with a plate type heat exchanger, a tube type heat exchanger, a steam injection type sterilizer, a steam infusion type sterilizer, an energization heating type sterilizer, or the like.
  • Retort sterilization can also be performed after filling.
  • the sterilization method, sterilization time, and sterilization temperature are examples, and those skilled in the art should appropriately adjust the sterilization method, sterilization time, and sterilization temperature in consideration of the composition of the condensed milk-like composition, the container, and the like. Can be done. After sterilization, it can be cooled to obtain a condensed milk composition.
  • the seeding step is a process of precipitating fine lactose crystals by adding core lactose from the outside to prevent the formation of coarse crystals during storage or distribution process. ..
  • the seeding step can be carried out by adding pulverized lactose to the condensed milk-like composition at a predetermined temperature and cooling to the lactose precipitation temperature (20 to 35 ° C.).
  • concentrated milk protein powder By using concentrated milk protein powder together and adjusting the lactose concentration, the seeding process can be eliminated. Further, by using the concentrated milk protein powder which is a powder raw material instead of the liquid milk raw material, the concentration step can be reduced. Further, by using the concentrated milk protein powder, the process can be simplified. In addition, concentrated milk protein powder is relatively inexpensive, easy to procure, and can be stored at room temperature.
  • the solubility of lactose is temperature-dependent, but if it exceeds the solubility, crystallization is promoted, and if this treatment is not performed, it leads to the formation of coarse crystals.
  • the method for producing a condensed milk-like composition of the present invention may include a seeding step, but it is preferable not to include the seeding step from the viewpoint of simplification of the manufacturing step.
  • liquid milk is a dairy raw material to be added to the composition for condensed milk in a liquid state, and includes milk, skim milk, and concentrated milk.
  • Liquid milk is relatively expensive due to restrictions on the source. Furthermore, refrigeration equipment is required for acceptance and storage, and capital investment and transportation are extremely costly. In addition, since it contains a large amount of water, a concentration step may be indispensable.
  • the method for producing a condensed milk composition of the present invention may include a step of adding liquid milk to dissolved water, but it is preferable not to include the step from the viewpoint of cost reduction and process simplification.
  • the product produced by the production method of the present invention contains concentrated milk protein powder, milk powder and the like as raw materials. Therefore, what is produced by the production method of the present invention is a "condensed milk-like composition" which does not correspond to condensed milk under the Ordinance of the Ministry of Milk, etc., but has the same flavor, appearance, and physical characteristics as condensed milk.
  • the method for producing a condensed milk composition of the present invention may include a step of adding condensed milk, but it is preferable not to include it from the viewpoint of cost reduction and process simplification.
  • the general manufacturing process of sweetened condensed milk is complicated and has a large number of processes, and it is necessary to install a large-scale production line. In addition, the manufacturing cost tends to increase due to the above reasons. Therefore, a manufacturing method with a simpler process is required.
  • the method for producing a condensed milk-like composition of the present invention fills a metal can, a paper container compounded with a metal foil or a plastic film, a pouch such as an aluminum pouch, a plastic container, a vinyl container, and a normal packaging container such as a glass bottle.
  • the capacity is not particularly limited.
  • Examples of the manufacturing equipment used in the method for producing the condensed milk-like composition of the present invention include an emulsifier having a heating function and a stirring function.
  • Example 1 (simple manufacturing method) Skim milk powder 420 g, milk protein concentrate (MPC) 158 g, sucrose 385 g, dextrin 595 g, trehalose 350 g, and emulsifier (sucrose stearic acid ester and sucrose fatty acid monoglyceride) 8 g were mixed in a powder state to obtain a powder raw material.
  • the powder raw material, 140 g of rapeseed salad oil, 280 g of glycerin, and 760 g of water were put into an emulsifier, heated by steam injection, and dissolved for 10 minutes after reaching 60 ° C.
  • the sweetened condensed milk-like composition prepared by the method of Example 1 had the same flavor, color and viscosity as the sweetened condensed milk-like composition prepared by the concentration method of Comparative Example 1. there were. Further, even when stored at room temperature (25 ° C.) and cold temperature (5 ° C.) for 7 days, lactose crystals were not generated, and neither flavor nor color was changed.
  • Example 2 Skim milk powder 420 g, milk protein concentrate (MPC) 70 g, sucrose 438 g, dextrin 630 g, trehalose 350 g, and emulsifier (sucrose stearic acid ester and sucrose fatty acid monoglyceride) 8 g were mixed in a powder state to obtain a powder raw material. 140 g of rapeseed salad oil, 280 g of glycerin, and 720 g of water were put into an emulsifier, heated by steam injection, and dissolved for 10 minutes after reaching 60 ° C. After dissolution, a flavor was added, and the mixture was further heat-treated by steam injection and sterilized at 88 to 95 ° C.
  • MPC milk protein concentrate
  • sucrose 438 g sucrose 438 g
  • dextrin 630 g trehalose 350 g
  • emulsifier sucrose stearic acid ester and sucrose fatty acid monoglyceride 8 g
  • the sweetened condensed milk-like composition prepared by the method of Example 2 had a better texture than the sweetened condensed milk-like composition prepared by the concentration method of Comparative Example 1. there were. It was acceptable, but the flavor was a little lacking in milkiness and richness, and the color was a little lean. Further, even when stored at room temperature (25 ° C.) and cold temperature (5 ° C.) for 7 days, lactose crystals were not generated, and neither flavor nor color was changed.
  • Example 3 420 g of defatted milk powder, 158 g of whey protein concentrate (WPC), 427 g of sucrose, 543 g of dextrin, 350 g of trehalose, and 8 g of emulsifier (sucrose stearic acid ester and monoglyceride sucrose) were mixed in a powder state to obtain a powder raw material.
  • the powder raw material, 140 g of rapeseed salad oil, 280 g of glycerin, and 720 g of water were put into an emulsifier, heated by steam injection, and dissolved for 10 minutes after reaching 60 ° C.
  • the sweetened condensed milk-like composition prepared by the method of Example 3 was slightly whey-derived glassy as compared with the sweetened condensed milk-like composition prepared by the concentration method of Comparative Example 1. It had a good flavor, but it was an acceptable flavor as a sweetened condensed milk-like composition.
  • the color and viscosity were at the same level as sweetened condensed milk. Further, even when stored at room temperature (25 ° C.) and cold temperature (5 ° C.) for 7 days, lactose crystals were not generated, and neither flavor nor color was changed.
  • Comparative Example 1 (conventional manufacturing method (concentration method)) 167 g of defatted milk powder, 41 g of sucrose, 80 g of dextrin, 67 g of trehalose, and 1.3 g of emulsifiers (sucrose stearic acid ester, glycerin fatty acid ester and soy lecithin) were mixed in a powder state to obtain a powder raw material.
  • the powder raw material, 33 g of rapeseed salad oil, and 53 g of glycerin were dissolved in 1557 g of water at 60 ° C.
  • a homogeneous treatment (homogeneous pressure 50 kgf) was performed, and a sterilization treatment was performed at 80 to 90 ° C. for 10 minutes.
  • the mixture was cooled with water, the water content was evaporated under reduced pressure conditions, and the Brix was concentrated from 21.5 to 63.9.
  • flavoring and seeding operations were carried out to obtain a sweetened condensed milk-like composition.
  • the obtained sweetened condensed milk-like composition had a good flavor with a refreshing sweetness and a milky feeling.
  • the color and viscosity were at the same level as sweetened condensed milk.
  • Comparative Example 2 770 g of skim milk powder, 1,330 g of sucrose, 350 g of trehalose, and 8 g of emulsifiers (sucrose stearic acid ester and sucrose fatty acid monoglyceride) were mixed in a powder state to obtain a powder raw material. 140 g of rapeseed salad oil and 500 g of water were put into an emulsifier, heated by steam injection, and dissolved for 10 minutes after reaching 60 ° C. After dissolution, a flavor was added, and the mixture was further heat-treated by steam injection and sterilized at 88 to 95 ° C. for 120 seconds to obtain a sweetened condensed milk-like composition.
  • emulsifiers sucrose stearic acid ester and sucrose fatty acid monoglyceride
  • the total amount of water added was adjusted to 900 to 950 g, and the rotation speed of the stirrer was 1800 rpm.
  • the obtained sweetened condensed milk-like dairy product had a sweetened condensed milk-like color.
  • the viscosity was 19,900 mPa ⁇ s, which was extremely high as compared with sweetened condensed milk.
  • Comparative Example 3 770 g of defatted milk powder, 385 g of sucrose, 385 g of dextrin, 350 g of trehalose, and 8 g of an emulsifier (sucrose stearic acid ester and monoglyceride sucrose) were mixed in a powder state to obtain a powder raw material. 140 g of rapeseed salad oil, 280 g of glycerin, and 720 g of water were put into an emulsifier, heated by steam injection, and dissolved for 10 minutes after reaching 60 ° C. After dissolution, a flavor was added, and the mixture was further heat-treated by steam injection and sterilized at 88 to 95 ° C.
  • an emulsifier sucrose stearic acid ester and monoglyceride sucrose
  • the obtained sweetened condensed milk-like composition had a good flavor with a refreshing sweetness and a milky feeling.
  • the color and viscosity were at the same level as sweetened condensed milk.
  • Comparative Example 4 648 g of skim milk powder, 56 g of milk protein concentrate (MPC), 420 g of sucrose, 434 g of dextrin, 350 g of trehalose, and 8 g of emulsifier (sucrose stearic acid ester and monoglyceride sucrose) were mixed in a powder state to obtain a powder raw material. 140 g of rapeseed salad oil, 280 g of glycerin, and 720 g of water were put into an emulsifier, heated by steam injection, and dissolved for 10 minutes after reaching 60 ° C. After dissolution, a flavor was added, and the mixture was further heat-treated by steam injection and sterilized at 88 to 95 ° C.
  • the obtained sweetened condensed milk-like composition had a good flavor with a refreshing sweetness and a milky feeling.
  • the color and viscosity were at the same level as sweetened condensed milk.
  • the texture at room temperature was good, but under refrigeration, some coarse crystals of lactose were observed, and poor texture was observed. It was.
  • Table 1 shows the raw material blending ratios of each example and comparative example.
  • Table 2 shows the protein content in each Example and Comparative Example.
  • Table 3 shows the proportion of skim milk powder-derived protein and the proportion of MPC-derived protein in the proteins in each Example and Comparative Example. Skim milk powder contains about 36% protein, MPC contains about 82% protein, and WPC contains about 81% protein.
  • Table 4 shows the concentration of lactose in water calculated from the raw material mixing ratios of each Example and Comparative Example. The lactose content of the MPC used is about 2.3% and the lactose content of the WPC used is about 4.0%. The lactose content of the skim milk powder used is about 51.5%.
  • Table 5 shows a list of evaluation results of each example and comparative example.

Abstract

A condensed milk-like composition comprising a sugar alcohol, a concentrated milk protein powder and a milk powder, wherein the content of lactose is 21 wt% or less expressed in lactose concentration in water.

Description

食品組成物の製造方法Manufacturing method of food composition
 本発明は、食品組成物、より詳細には練乳様組成物に関する。また、本発明は、食品組成物の製造方法、より詳細には練乳様組成物の製造方法に関する。 The present invention relates to a food composition, more particularly a condensed milk-like composition. The present invention also relates to a method for producing a food composition, and more particularly to a method for producing a condensed milk-like composition.
 加糖練乳は一般的に生乳にショ糖を溶解し、その後水分を蒸発させ、2~3倍に濃縮することにより製造される。また加糖練乳は固形分を上げることで水分活性が0.8~0.9程度に低下し、微生物の繁殖を抑え、保存性を高めることで常温流通を可能としている。
 一般的な加糖練乳の製造においては生乳の受入れ、貯乳、標準化、荒煮、均質化、殺菌、濃縮、冷却、シーディング等の多数の工程を有する。また、これらに対応する設備が各々必要であり、特に生乳の受入れ、貯乳、濃縮工程においては大規模な設備・機器が必要になることがある。
Sweetened condensed milk is generally produced by dissolving sucrose in raw milk, then evaporating the water content and concentrating it 2-3 times. In addition, the water activity of sweetened condensed milk is reduced to about 0.8 to 0.9 by increasing the solid content, the growth of microorganisms is suppressed, and the storage stability is improved, so that it can be distributed at room temperature.
In the production of general sweetened condensed milk, there are many steps such as acceptance of raw milk, storage of milk, standardization, simmering, homogenization, sterilization, concentration, cooling, and seeding. In addition, equipment corresponding to these is required, and large-scale equipment / equipment may be required especially in the process of receiving raw milk, storing milk, and concentrating.
 原材料コストを抑える目的で、生乳を使用せず、全脂粉乳、脱脂粉乳を水に溶解した還元乳にショ糖、及び乳脂肪の代替としての植物油脂を加え、減圧濃縮あるいは加熱濃縮した練乳様乳製品が国内外で上市されている。練乳様乳製品では、種々の製造方法が提案されている。
 例えば、乳製品製造の副産物として得られた液状ホエイに水、ショ糖、デキストリン、ミルクタンパク質濃縮物、ヤシ硬化油を加え、濃縮した練乳様ホエイ組成物が提案されている。(特許文献1)
 製造工程を簡略化する方法として、脱脂濃縮乳、脱脂粉乳、全脂粉乳、ショ糖を原料として、多機能タンク等で高濃度原料混合することで、濃縮工程を削減し、加糖練乳と同等の官能特性、物性特性を有する練乳様乳製品の製造方法が提案されている。(特許文献2、特許文献3)
 シーディング工程を削減する方法として、原料乳を膜処理し、乳糖を除去した濃縮乳を用いた製造方法が提案されている。(特許文献4)
Condensed milk that is concentrated under reduced pressure or heated by adding sucrose and vegetable oil as a substitute for milk fat to reduced milk obtained by dissolving full-fat milk powder or skim milk powder in water without using raw milk for the purpose of reducing raw material costs. Dairy products are on the market at home and abroad. Various manufacturing methods have been proposed for condensed milk-like dairy products.
For example, a condensed milk-like whey composition obtained by adding water, sucrose, dextrin, milk protein concentrate, and coconut-hardening oil to liquid whey obtained as a by-product of dairy product production has been proposed. (Patent Document 1)
As a method of simplifying the manufacturing process, skim milk concentrate, skim milk powder, full-fat milk powder, and sucrose are used as raw materials and mixed with high-concentration raw materials in a multifunction tank, etc. to reduce the concentration process and be equivalent to sweetened condensed milk. A method for producing a condensed milk-like dairy product having sensory and physical properties has been proposed. (Patent Document 2, Patent Document 3)
As a method for reducing the seeding process, a production method using concentrated milk obtained by membrane-treating raw milk and removing lactose has been proposed. (Patent Document 4)
日本国特許第6012177号公報Japanese Patent No. 6012177 日本国特開2003-199492号公報Japanese Patent Application Laid-Open No. 2003-199492 日本国特開2014-226139号公報Japanese Patent Application Laid-Open No. 2014-226139 日本国特開平9-224566号公報Japanese Patent Application Laid-Open No. 9-224566
 本発明が解決しようとする課題は、従来の練乳様組成物よりも簡便な製造方法で同様の風味、粘度特性、保存性を有する練乳様組成物を提供することである。 An object to be solved by the present invention is to provide a condensed milk-like composition having the same flavor, viscosity characteristics, and storage stability by a simpler production method than the conventional condensed milk-like composition.
 製造工程の簡略化を目的として、濃縮工程を削減した高濃度原料混合法が適用されるが、加糖練乳と同様の固形分濃度を維持すると溶解水が少なくなり、粉末溶解が困難となる。溶解が不十分になると、風味不良、組織不良、粘度上昇、加熱時のこげつきの原因となる。そのため、予め乳タンパク質が水和状態である濃縮乳や脱脂濃縮乳を使用すること、又は溶解性を向上させるための高性能な溶解機を用意することが必要となる。
 溶解性を向上させることを目的とし、溶解水の量を多くすると、固形濃度が低下し、従来の加糖練乳と比較して、風味、性状が薄く貧弱なものとなる。また、水分活性が上昇することにより、微生物の増殖が促進され、保存性を損なう。低水分活性を維持した状態で適正な固形濃度を維持しつつ且つ溶解水を増やすことにより、練乳様の風味を保持したまま粉末溶解が容易になる。
For the purpose of simplifying the manufacturing process, a high-concentration raw material mixing method with a reduced concentration process is applied, but if the solid content concentration similar to that of sweetened condensed milk is maintained, the amount of dissolved water decreases and powder dissolution becomes difficult. Insufficient dissolution causes poor flavor, poor structure, increased viscosity, and burning during heating. Therefore, it is necessary to use concentrated milk or skim milk concentrated milk in which milk protein is hydrated in advance, or to prepare a high-performance dissolving machine for improving solubility.
When the amount of dissolved water is increased for the purpose of improving the solubility, the solid concentration is lowered, and the flavor and properties are light and poor as compared with the conventional sweetened condensed milk. In addition, the increase in water activity promotes the growth of microorganisms and impairs storage stability. By increasing the amount of dissolved water while maintaining an appropriate solid concentration while maintaining low water activity, powder dissolution becomes easy while maintaining a condensed milk-like flavor.
 本発明者らは上記課題を解決するために鋭意検討し、糖アルコール及び予め乳糖除去処理をした濃縮乳タンパク質粉末を使用することで、製造工程を簡便化するとともに、同様の風味、粘度特性、冷蔵時及び常温時における良好な保存性を有する練乳様組成物を提供できることを見出し、本発明を完成するに至った。 The present inventors have diligently studied in order to solve the above problems, and by using sugar alcohol and concentrated milk protein powder which has been previously treated to remove lactose, the manufacturing process is simplified and the same flavor and viscosity characteristics are exhibited. They have found that a condensed milk-like composition having good storage stability at the time of refrigeration and at room temperature can be provided, and have completed the present invention.
 本発明は具体的には以下の通りである。
<1>糖アルコール、濃縮乳タンパク質粉末、及び粉乳を含む練乳様組成物であって、乳糖の含量が、水中乳糖濃度で21重量%以下である、前記練乳様組成物。
<2>前記練乳様組成物に含まれる乳タンパク質の18重量%以上が、濃縮乳タンパク質粉末由来である、<1>に記載の練乳様組成物。
<3>前記練乳様組成物に含まれる乳タンパク質において、濃縮乳タンパク質粉末に由来する乳タンパク質と粉乳に由来する乳タンパク質の比率が、1:4~4:1である、<1>又は<2>に記載の練乳様組成物。
<4>植物油脂及び/又は糖類をさらに含む、<1>~<3>のいずれかに記載の練乳様組成物。
<5>溶解水に糖アルコール、濃縮乳タンパク質粉末、及び粉乳を添加して混合し、練乳様ミックスを得る工程と、前記練乳様ミックスを殺菌し、練乳様組成物を得る工程と、を含む練乳様組成物の製造方法であって、前記練乳様組成物の乳糖の含量が、水中乳糖濃度で21重量%以下である、前記製造方法。
<6>前記練乳様組成物に含まれる乳タンパク質の18重量%以上が、濃縮乳タンパク質粉末由来である、<5>に記載の練乳様組成物の製造方法。
<7>前記練乳様組成物に含まれる乳タンパク質において、濃縮乳タンパク質粉末に由来する乳タンパク質と粉乳に由来する乳タンパク質の比率が、1:4~4:1である、<5>又は<6>に記載の練乳様組成物の製造方法。
<8>シーディング工程を含まない、<5>~<7>のいずれかに記載の練乳様組成物の製造方法。
Specifically, the present invention is as follows.
<1> A condensed milk-like composition containing sugar alcohol, concentrated milk protein powder, and milk powder, wherein the content of lactose is 21% by weight or less in water lactose concentration.
<2> The condensed milk-like composition according to <1>, wherein 18% by weight or more of the milk protein contained in the condensed milk-like composition is derived from concentrated milk protein powder.
<3> In the milk protein contained in the condensed milk-like composition, the ratio of the milk protein derived from the concentrated milk protein powder to the milk protein derived from the milk powder is 1: 4 to 4: 1, <1> or <. 2> The condensed milk-like composition.
<4> The condensed milk-like composition according to any one of <1> to <3>, further containing a vegetable oil and / or sugar.
<5> Includes a step of adding and mixing sugar alcohol, concentrated lactose protein powder, and milk powder to dissolved water to obtain a condensed milk-like mix, and a step of sterilizing the condensed milk-like mix to obtain a condensed milk-like composition. A method for producing a condensed milk-like composition, wherein the content of lactose in the condensed milk-like composition is 21% by weight or less in terms of lactose concentration in water.
<6> The method for producing a condensed milk-like composition according to <5>, wherein 18% by weight or more of the milk protein contained in the condensed milk-like composition is derived from concentrated milk protein powder.
<7> In the milk protein contained in the condensed milk-like composition, the ratio of the milk protein derived from the concentrated milk protein powder to the milk protein derived from the milk powder is 1: 4 to 4: 1, <5> or <. 6> The method for producing a condensed milk-like composition.
<8> The method for producing a condensed milk-like composition according to any one of <5> to <7>, which does not include a seeding step.
 本発明は、また、以下の実施形態を備えるものである。
<1>糖アルコール、濃縮乳タンパク質粉末、及び粉乳を含む練乳様組成物であって、乳糖の含量が、水中乳糖濃度で21重量%以下である、前記練乳様組成物。
<2>前記練乳様組成物に含まれる乳タンパク質の18重量%以上が、濃縮乳タンパク質粉末由来である、<1>に記載の練乳様組成物。
<3>前記練乳様組成物に含まれる乳タンパク質において、濃縮乳タンパク質粉末に由来する乳タンパク質と粉乳に由来する乳タンパク質の比率が、1:4~4:1である、<1>又は<2>に記載の練乳様組成物。
<4>植物油脂及び/又は糖類をさらに含む、<1>~<3>のいずれかに記載の練乳様組成物。
<5>練乳様組成物基準で、糖アルコール1~30重量%、濃縮乳タンパク質粉末1~20重量%、粉乳1~30重量%、及び水分20~60重量%を含む練乳様組成物であって、乳糖の含量が、水中乳糖濃度で21重量%以下である、<1>~<4>のいずれかに記載の練乳様組成物。
<6>濃縮乳タンパク質粉末が、乳タンパク質50~99重量%、乳糖0.01~8重量%、及び水分0~8重量%を含む、<1>~<5>のいずれかに記載の練乳様組成物。
<7>粉乳が、乳タンパク質10~50重量%、乳糖10~80重量%、及び水分0~8重量%を含む、<1>~<6>のいずれかに記載の練乳様組成物。
<8>糖アルコールが、グリセリン、エリスリトール、マンニトール、マルチトール、ソルビトール、キシリトール、リビトール、イノシトール、D-トレイトール、L-トレイトール、D-アラビニトール、及びL-アラビニトールから成る群から選択される1つ以上である、<1>~<3>のいずれかに記載の練乳様組成物。
<9>練乳の含量が、練乳様組成物基準で50重量%以下、好ましくは30重量%以下である、<1>~<3>のいずれかに記載の練乳様組成物。
<10>濃縮乳タンパク質粉末が、乳タンパク質濃縮物、ホエイタンパク質濃縮物、分離ホエイタンパク質、及び分離乳タンパク質から成る群から選択される1つ以上である、<1>~<9>のいずれかに記載の練乳様組成物。
<11>溶解水に糖アルコール、濃縮乳タンパク質粉末、及び粉乳を添加して混合し、練乳様ミックスを得る工程と、前記練乳様ミックスを殺菌し、練乳様組成物を得る工程と、を含む練乳様組成物の製造方法であって、前記練乳様組成物の乳糖の含量が、水中乳糖濃度で21重量%以下である、前記製造方法。
<12>前記練乳様組成物に含まれる乳タンパク質の18重量%以上が、濃縮乳タンパク質粉末由来である、<11>に記載の練乳様組成物の製造方法。
<13>前記練乳様組成物に含まれる乳タンパク質において、濃縮乳タンパク質粉末に由来する乳タンパク質と粉乳に由来する乳タンパク質の比率が、1:4~4:1である、<11>又は<12>に記載の練乳様組成物の製造方法。
<14>シーディング工程を含まない、<11>~<13>のいずれかに記載の練乳様組成物の製造方法。
<15>前記練乳様組成物が、練乳様組成物基準で、糖アルコール1~30重量%、濃縮乳タンパク質粉末1~20重量%、粉乳1~30重量%、及び水分20~60重量%を含む、<11>~<14>のいずれかに記載の練乳様組成物の製造方法。
<16>濃縮乳タンパク質粉末が、乳タンパク質50~99重量%、乳糖0.01~8重量%、及び水分0~8重量%を含む、<11>~<15>のいずれかに記載の練乳様組成物の製造方法。
<17>粉乳が、乳タンパク質10~50重量%、乳糖10~80重量%、及び水分0~8重量%を含む、<11>~<16>のいずれかに記載の練乳様組成物の製造方法。
<18>糖アルコールが、グリセリン、エリスリトール、マンニトール、マルチトール、ソルビトール、キシリトール、リビトール、イノシトール、D-トレイトール、L-トレイトール、D-アラビニトール、及びL-アラビニトールから成る群から選択される1つ以上である、<11>~<17>のいずれかに記載の練乳様組成物の製造方法。
<19>前記練乳様組成物における練乳の含量が、練乳様組成物基準で50重量%以下、好ましくは30重量%以下である、<11>~<18>のいずれかに記載の練乳様組成物の製造方法。
The present invention also comprises the following embodiments.
<1> A condensed milk-like composition containing sugar alcohol, concentrated milk protein powder, and milk powder, wherein the content of lactose is 21% by weight or less in water lactose concentration.
<2> The condensed milk-like composition according to <1>, wherein 18% by weight or more of the milk protein contained in the condensed milk-like composition is derived from concentrated milk protein powder.
<3> In the milk protein contained in the condensed milk-like composition, the ratio of the milk protein derived from the concentrated milk protein powder to the milk protein derived from the milk powder is 1: 4 to 4: 1, <1> or <. 2> The condensed milk-like composition.
<4> The condensed milk-like composition according to any one of <1> to <3>, further containing a vegetable oil and / or sugar.
<5> A condensed milk-like composition containing 1 to 30% by weight of sugar alcohol, 1 to 20% by weight of concentrated milk protein powder, 1 to 30% by weight of milk powder, and 20 to 60% by weight of water based on the condensed milk-like composition. The condensed milk-like composition according to any one of <1> to <4>, wherein the lactose content is 21% by weight or less in water lactose concentration.
<6> The condensed milk according to any one of <1> to <5>, wherein the concentrated milk protein powder contains 50 to 99% by weight of milk protein, 0.01 to 8% by weight of lactose, and 0 to 8% by weight of water. Composition.
<7> The condensed milk-like composition according to any one of <1> to <6>, wherein the milk powder contains 10 to 50% by weight of milk protein, 10 to 80% by weight of lactose, and 0 to 8% by weight of water.
<8> The sugar alcohol is selected from the group consisting of glycerin, erythreitol, mannitol, martitol, sorbitol, xylitol, ribitol, inositol, D-threitol, L-threitol, D-arabinitol, and L-arabinitol 1 The condensed milk-like composition according to any one of <1> to <3>, which is one or more.
<9> The condensed milk-like composition according to any one of <1> to <3>, wherein the content of condensed milk is 50% by weight or less, preferably 30% by weight or less based on the condensed milk-like composition.
<10> Any one of <1> to <9>, wherein the concentrated milk protein powder is one or more selected from the group consisting of milk protein concentrate, whey protein concentrate, separated whey protein, and separated milk protein. The condensed milk-like composition according to.
<11> Includes a step of adding and mixing sugar alcohol, concentrated lactose protein powder, and milk powder to dissolved water to obtain a condensed milk-like mix, and a step of sterilizing the condensed milk-like mix to obtain a condensed milk-like composition. A method for producing a condensed milk-like composition, wherein the content of lactose in the condensed milk-like composition is 21% by weight or less in terms of lactose concentration in water.
<12> The method for producing a condensed milk-like composition according to <11>, wherein 18% by weight or more of the milk protein contained in the condensed milk-like composition is derived from concentrated milk protein powder.
<13> In the milk protein contained in the condensed milk-like composition, the ratio of the milk protein derived from the concentrated milk protein powder to the milk protein derived from the milk powder is 1: 4 to 4: 1, <11> or <. 12> The method for producing a condensed milk-like composition.
<14> The method for producing a condensed milk-like composition according to any one of <11> to <13>, which does not include a seeding step.
<15> The condensed milk-like composition contains 1 to 30% by weight of sugar alcohol, 1 to 20% by weight of concentrated milk protein powder, 1 to 30% by weight of powdered milk, and 20 to 60% by weight of water based on the condensed milk-like composition. The method for producing a condensed milk-like composition according to any one of <11> to <14>, which comprises.
<16> The condensed milk according to any one of <11> to <15>, wherein the concentrated milk protein powder contains 50 to 99% by weight of milk protein, 0.01 to 8% by weight of lactose, and 0 to 8% by weight of water. Method for producing similar composition.
<17> Production of the condensed milk-like composition according to any one of <11> to <16>, wherein the milk powder contains 10 to 50% by weight of milk protein, 10 to 80% by weight of lactose, and 0 to 8% by weight of water. Method.
<18> The sugar alcohol is selected from the group consisting of glycerin, erythreitol, mannitol, martitol, sorbitol, xylitol, ribitol, inositol, D-threitol, L-threitol, D-arabinitol, and L-arabinitol 1 The method for producing a condensed milk-like composition according to any one of <11> to <17>, which is one or more.
<19> The condensed milk-like composition according to any one of <11> to <18>, wherein the content of condensed milk in the condensed milk-like composition is 50% by weight or less, preferably 30% by weight or less based on the condensed milk-like composition. Manufacturing method of things.
 従来の練乳様組成物よりも簡便な製造方法で同様の風味、粘度特性、冷蔵時及び常温時における保存性を有する練乳様組成物を提供することができる。 It is possible to provide a condensed milk-like composition having the same flavor, viscosity characteristics, and storage stability at the time of refrigeration and normal temperature by a simpler manufacturing method than the conventional condensed milk-like composition.
1.練乳様組成物
(糖アルコール)
 本明細書において糖アルコールとは、糖類(例えば、単糖類、二糖類など)を還元することにより生成される、アルコール基(OH基)をもつ糖質を意味する。糖アルコールを練乳様組成物に添加することで、水分活性を減少させつつ水分値を上げることが可能となるため、粉末原料の溶解性を向上させることができる。また、糖アルコールを練乳様組成物に添加することで、水分活性を減少させつつ水分値を上げることが可能となるため、微生物の発生を防止することができ、したがって常温保存が可能となる。また、加糖練乳と同等の固形分濃度の場合、糖質濃度が高くなり、高カロリー食品となるが、糖アルコールを使用することで全体の固形分を減少させてカロリーの低下を図ることができる。
1. 1. Condensed milk-like composition (sugar alcohol)
As used herein, the sugar alcohol means a sugar having an alcohol group (OH group), which is produced by reducing a saccharide (for example, a monosaccharide, a disaccharide, etc.). By adding sugar alcohol to the condensed milk-like composition, it is possible to increase the water content while reducing the water activity, so that the solubility of the powder raw material can be improved. Further, by adding sugar alcohol to the condensed milk-like composition, it is possible to raise the water value while reducing the water activity, so that the generation of microorganisms can be prevented, and therefore the storage at room temperature becomes possible. In addition, when the solid content concentration is the same as that of sweetened condensed milk, the sugar concentration becomes high and the food becomes a high-calorie food. However, by using sugar alcohol, the total solid content can be reduced to reduce the calories. ..
 本発明の練乳様組成物において使用することができる糖アルコールは、以下に限定されるものではないが、グリセリン、エリスリトール、マンニトール、マルチトール、ソルビトール、キシリトール、リビトール、イノシトール、D-トレイトール、L-トレイトール、D-アラビニトール、及びL-アラビニトール等が挙げられる。水への溶解性が高さ及び水分活性減少効果を考慮して、ソルビトール、キシリトール、エリスリトール、及びグリセリンから成る群から選択される1つ以上を使用することが好ましい。これらの糖アルコールは、二種以上を併用することもできる。 The sugar alcohols that can be used in the condensed milk-like composition of the present invention are not limited to the following, but are not limited to glycerin, erythreitol, mannitol, maltitol, sorbitol, xylitol, ribitol, inositol, D-threitol, and L. -Threitol, D-arabinitol, L-arabinitol and the like can be mentioned. Considering the high solubility in water and the effect of reducing water activity, it is preferable to use one or more selected from the group consisting of sorbitol, xylitol, erythritol, and glycerin. Two or more of these sugar alcohols can be used in combination.
 糖アルコールの配合量は、以下に限定されるものではないが、練乳様組成物の風味及び物性並びに製造時の操作性を考慮して、練乳様組成物基準で、1~30重量%、好ましくは2~20重量%、より好ましくは3~15重量%、最も好ましくは5~10重量%である。 The amount of the sugar alcohol to be blended is not limited to the following, but is preferably 1 to 30% by weight based on the condensed milk-like composition in consideration of the flavor and physical properties of the condensed milk-like composition and the operability during production. Is 2 to 20% by weight, more preferably 3 to 15% by weight, and most preferably 5 to 10% by weight.
(濃縮乳タンパク質粉末)
 本明細書において濃縮乳タンパク質粉末とは、乳糖が除去された、乳タンパク質を主成分とする粉末原料である。濃縮乳タンパク質粉末においては、膜処理等の手段又は操作により、乳糖が除去されている。濃縮乳タンパク質粉末において、乳タンパク質含量は、例えば、50~99重量%、60~99重量%、70~99重量%、又は80~99重量%であることができる。濃縮乳タンパク質粉末において、乳糖含量は、例えば、0.01~8重量%、より好ましくは0.1~4重量%であることができる。濃縮乳タンパク質粉末の水分は、0~8重量%であることができる。濃縮乳タンパク質粉末は、灰分、脂質分等を含みうる。ただし、灰分や脂質分の含有量が少ない方が好ましい。この場合において、乳タンパク質含量は、好ましくは70~99重量%、より好ましくは80~99重量%であることができる。
(Concentrated milk protein powder)
In the present specification, the concentrated milk protein powder is a powder raw material containing lactose as a main component from which lactose has been removed. In the concentrated milk protein powder, lactose is removed by means or operations such as membrane treatment. In the concentrated milk protein powder, the milk protein content can be, for example, 50-99% by weight, 60-99% by weight, 70-99% by weight, or 80-99% by weight. In the concentrated milk protein powder, the lactose content can be, for example, 0.01-8% by weight, more preferably 0.1-4% by weight. The water content of the concentrated milk protein powder can be 0-8% by weight. Concentrated milk protein powder may contain ash, lipids and the like. However, it is preferable that the content of ash and lipid is low. In this case, the milk protein content can be preferably 70-99% by weight, more preferably 80-99% by weight.
 本発明の練乳様組成物において使用することができる濃縮乳タンパク質粉末は、以下に限定されるものではないが、乳タンパク質濃縮物(MPC:Milk Protein Concentrate)、ホエイタンパク質濃縮物(WPC:Whey Protein Concentrate)、分離ホエイタンパク質(WPI:Whey Protein Isolate)及び分離乳タンパク質(MPI:Milk Protein Isolate)が挙げられる。これらの濃縮乳タンパク質粉末は、二種以上を併用することもできる。MPC及び/又はWPCを使用することが好ましい。 The concentrated milk protein powder that can be used in the condensed milk-like composition of the present invention is not limited to the following, but is not limited to the following, but is not limited to the following, but is not limited to the following, but is not limited to the following, but is not limited to the following. Concentrate), isolated whey protein (WPI: Whey Protein Isolate) and isolated milk protein (MPI: Milk Protein Isolate). Two or more kinds of these concentrated milk protein powders can be used in combination. It is preferable to use MPC and / or WPC.
 MPCは、牛乳やスキムミルクを限外濾過膜(ultrafiltration membrane)等の濾過膜で濃縮し、そして牛乳中の乳タンパク質を粉末化したものである。MPCでは、濾過処理により、乳糖が除去されている。MPCは、TMP(Total Milk Protein)と呼ばれることもある。MPIはMPCと同様の工程で調製されるが、MPIは、イオン交換クロマトグラフィー等によって乳中の乳タンパク質のみをさらに濃縮して分離したものであり、一般的にMPCよりも乳タンパク質含有量が高い。
 WPCは、ホエイから乳糖、ミネラル、及びビタミンを分離してホエイタンパク質を回収・粉末化したものである。WPCは、チーズホエイや酸ホエイ等の、ホエイタンパク質を含む乳由来の液体を限外濾過膜や透析濾過膜(Dia-filtration)等の濾過膜で処理することにより、ホエイタンパク質を濃縮及び乾燥することで製造される。WPIはWPCと同様の工程で調製されるが、WPIは、イオン交換クロマトグラフィー等によってホエイ中のタンパク質のみを濃縮して分離したものであり、一般的にWPCよりもタンパク質含有量が高い。
MPC is obtained by concentrating milk or skim milk with a filtration membrane such as an ultrafiltration membrane, and pulverizing milk protein in the milk. In MPC, lactose is removed by filtration treatment. MPC is sometimes called TMP (Total Milk Protein). MPI is prepared by the same process as MPC, but MPI is obtained by further concentrating and separating only milk protein in milk by ion exchange chromatography or the like, and generally has a higher milk protein content than MPC. high.
WPC is obtained by separating lactose, minerals, and vitamins from whey and recovering and powdering whey protein. WPC concentrates and dries whey protein by treating milk-derived liquids containing whey protein, such as cheese whey and acid whey, with a filtration membrane such as an ultrafiltration membrane or a dia-filtration membrane. Manufactured by WPI is prepared by the same process as WPC, but WPI is obtained by concentrating and separating only the protein in whey by ion exchange chromatography or the like, and generally has a higher protein content than WPC.
 濃縮乳タンパク質粉末の配合量は、以下に限定されるものではないが、練乳様組成物の風味及び物性を考慮して、練乳様組成物基準で、1~20重量%、好ましくは1~15重量%、より好ましくは1~10重量%、さらに好ましくは1.8~10重量%である。
 濃縮乳タンパク質粉末は、以下に限定されるものではないが、練乳様組成物の風味及び物性を考慮して、練乳様組成物中の濃縮乳タンパク質粉末由来の乳タンパク質が、1.5~15重量%、好ましくは1.5~10重量%、より好ましくは1.5~8重量%となるように、練乳様組成物に添加することができる。
The blending amount of the concentrated milk protein powder is not limited to the following, but in consideration of the flavor and physical characteristics of the condensed milk-like composition, 1 to 20% by weight, preferably 1 to 15 by weight based on the condensed milk-like composition. By weight%, more preferably 1 to 10% by weight, even more preferably 1.8 to 10% by weight.
The concentrated milk protein powder is not limited to the following, but the milk protein derived from the condensed milk protein powder in the condensed milk-like composition is 1.5 to 15 in consideration of the flavor and physical properties of the condensed milk-like composition. It can be added to the condensed milk-like composition in an amount of% by weight, preferably 1.5 to 10% by weight, more preferably 1.5 to 8% by weight.
 乳糖処理をしていない濃縮乳、脱脂粉乳、及びホエイパウダー等は乳糖含量が高く、一般的な加糖練乳と固形分を合わせた場合、水中乳糖濃度が高くなる。したがって、これらの原料を使用した場合、乳糖の粗大結晶化が課題となる。そのため、乳糖の粗大結晶化の抑制のために、シーディング工程が必要となる。シーディングとは粉砕乳糖を添加して、微細な乳糖結晶をあらかじめ析出させることである。シーディング工程に用いる乳糖は前処理として粉砕(微粉化)が必要である。また、所定の温度での乳糖添加となるため、温度管理が必要であり、且つ開放系での操作となる。したがって、工程管理が煩雑となり、異物混入や微生物汚染のリスクも発生する。
 粉末乳原料を使用することにより、原料コストが比較的安価となり、原料調達、原料保管、及びハンドリング性も簡便となる。
Concentrated milk, skim milk powder, whey powder, etc. that have not been treated with lactose have a high lactose content, and when the general sweetened condensed milk and solid content are combined, the lactose concentration in water is high. Therefore, when these raw materials are used, coarse crystallization of lactose becomes a problem. Therefore, a seeding step is required to suppress the coarse crystallization of lactose. Seeding is the addition of ground lactose to pre-precipitate fine lactose crystals. Lactose used in the seeding process needs to be pulverized (micronized) as a pretreatment. Further, since lactose is added at a predetermined temperature, temperature control is required and the operation is performed in an open system. Therefore, process control becomes complicated, and there is a risk of foreign matter contamination and microbial contamination.
By using the powdered milk raw material, the raw material cost is relatively low, and the raw material procurement, raw material storage, and handleability are also simplified.
 濃縮乳タンパク質粉末を併用し、乳糖濃度を調整することでシーディング工程を不要とすることができる。また、液状乳原料ではなく粉末原料である濃縮乳タンパク質粉末を使用することで、濃縮工程を削減することができる。また、濃縮乳タンパク質粉末を使用することにより、工程の簡略化を実現することができる。また、濃縮乳タンパク質粉末は比較的安価で、調達が容易であり、且つ、常温保管が可能である。 By using concentrated milk protein powder together and adjusting the lactose concentration, the seeding process can be eliminated. Further, by using the concentrated milk protein powder which is a powder raw material instead of the liquid milk raw material, the concentration step can be reduced. Further, by using the concentrated milk protein powder, the process can be simplified. In addition, concentrated milk protein powder is relatively inexpensive, easy to procure, and can be stored at room temperature.
(粉乳)
 本明細書において粉乳とは、乳糖除去処理をされていない、乳を原料とする粉末原料であり、全脂粉乳、脱脂粉乳、及びホエイパウダー等が挙げられる。
 粉乳において、乳タンパク質含量は、例えば、10~50重量%、10~45重量%、10~40重量%、又は10~38重量%であることができる。粉乳において、乳糖含量は、例えば、10~80重量%、20~65重量%、30~65重量%、又は35~60重量%であることができる。粉乳の水分は、0~8重量%であることができる。粉乳は、灰分、脂質分等を含みうる。ただし、灰分や脂質分の含有量が少ない方が好ましい。この場合において、乳糖含量は、好ましくは35~80重量%、より好ましくは40~70重量%、さらに好ましくは50~60重量%であることができる。
 粉乳の配合量は、以下に限定されるものではないが、練乳様組成物の風味及び物性並びに粉乳からの乳糖持ち込み量を考慮して、練乳様組成物基準で、1~30重量%、好ましくは2~20重量%、より好ましくは3~20重量%である。
 粉乳は、以下に限定されるものではないが、練乳様組成物の風味及び物性並びに粉乳からの乳糖持ち込み量を考慮して、練乳様組成物中の粉乳由来の乳タンパク質が、3.0~20重量%、好ましくは3.0~18重量%、より好ましくは3.0~15重量%となるように、本発明の練乳様組成物に添加することができる。
(Powdered milk)
In the present specification, the milk powder is a powder raw material made from milk that has not been treated to remove lactose, and examples thereof include full-fat milk powder, skim milk powder, and whey powder.
In milk powder, the milk protein content can be, for example, 10-50% by weight, 10-45% by weight, 10-40% by weight, or 10-38% by weight. In milk powder, the lactose content can be, for example, 10-80% by weight, 20-65% by weight, 30-65% by weight, or 35-60% by weight. The water content of the milk powder can be 0-8% by weight. Milk powder may contain ash, lipids and the like. However, it is preferable that the content of ash and lipid is low. In this case, the lactose content can be preferably 35 to 80% by weight, more preferably 40 to 70% by weight, and even more preferably 50 to 60% by weight.
The blending amount of milk powder is not limited to the following, but is preferably 1 to 30% by weight based on the condensed milk-like composition in consideration of the flavor and physical properties of the condensed milk-like composition and the amount of lactose brought in from the milk powder. Is 2 to 20% by weight, more preferably 3 to 20% by weight.
The milk powder is not limited to the following, but the milk protein derived from the milk powder in the condensed milk-like composition is 3.0 to 3, considering the flavor and physical properties of the condensed milk-like composition and the amount of lactose brought in from the condensed milk. It can be added to the condensed milk-like composition of the present invention in an amount of 20% by weight, preferably 3.0 to 18% by weight, more preferably 3.0 to 15% by weight.
(練乳様組成物に含まれる乳タンパク質)
 本発明の練乳様組成物に含まれる乳タンパク質の量は、以下に限定されるものではないが、練乳様組成物基準で、例えば1~30重量%、好ましくは2~20重量%、より好ましくは3~15重量%、最も好ましくは5.0~10重量%である。練乳様組成物に含まれる乳タンパク質の量の測定には、ケルダール法を用いることができる。ケルダール法は窒素定量換算法の一つで、試料に含まれる窒素の量を化学的処理により求める分析方法である。
 本発明の製造方法により製造される練乳様組成物では、練乳様組成物の風味及び物性並びに粉乳からの乳糖持ち込み量を考慮して、好ましくは含まれる乳タンパク質の18重量%以上、より好ましくは18重量%~80重量%、さらに好ましくは18重量%~60重量%、さらに一層好ましくは20重量%~50重量%が濃縮乳タンパク質粉末由来である。
(Milk protein contained in condensed milk-like composition)
The amount of milk protein contained in the condensed milk-like composition of the present invention is not limited to the following, but is, for example, 1 to 30% by weight, preferably 2 to 20% by weight, more preferably based on the condensed milk-like composition. Is 3 to 15% by weight, most preferably 5.0 to 10% by weight. The Kjeldahl method can be used to measure the amount of milk protein contained in the condensed milk-like composition. The Kjeldahl method is one of the nitrogen quantitative conversion methods, and is an analytical method for determining the amount of nitrogen contained in a sample by chemical treatment.
In the condensed milk-like composition produced by the production method of the present invention, 18% by weight or more, more preferably 18% by weight or more of the contained milk protein, in consideration of the flavor and physical properties of the condensed milk-like composition and the amount of lactose brought in from the milk powder. 18% to 80% by weight, more preferably 18% to 60% by weight, even more preferably 20% to 50% by weight is derived from concentrated milk protein powder.
(乳タンパク質の比率)
 本発明の練乳様組成物に含まれる乳タンパク質において、濃縮乳タンパク質粉末に由来する乳タンパク質と粉乳に由来する乳タンパク質の比率(濃縮乳タンパク質粉末に由来する乳タンパク質:粉乳に由来する乳タンパク質)は、練乳様組成物の風味、色調、及び物性並びに粉乳からの乳糖持ち込み量を考慮して、重量換算で、好ましくは1:4~4:1であり、より好ましくは1:3~3:1であり、さらに好ましくは1:3~2:1であり、最も好ましくは1:3~1:1である。
(Ratio of milk protein)
In the milk protein contained in the condensed milk-like composition of the present invention, the ratio of milk protein derived from concentrated milk protein powder to milk protein derived from powdered milk (milk protein derived from concentrated milk protein powder: milk protein derived from powdered milk). Is preferably 1: 4 to 4: 1 and more preferably 1: 3 to 3: 1 in terms of weight in consideration of the flavor, color and physical properties of the condensed milk-like composition and the amount of lactose brought in from the milk powder. It is 1, more preferably 1: 3 to 2: 1, and most preferably 1: 3 to 1: 1.
 (その他のタンパク質)
 本発明の練乳様組成物は、必要に応じて、乳タンパク質以外のタンパク質源、例えば大豆等の植物由来タンパク質を含むことができるが、含まないことが好ましい。具体的には、乳タンパク質以外のタンパク質が、本発明の練乳様組成物中のタンパク質の量において10重量%以下、好ましくは5重量%以下である。
 本発明の練乳様組成物には、液状乳(牛乳、脱脂乳、及び濃縮乳などの液状の乳)を原料として添加してもよいが、添加しない方が好ましい。
(Other proteins)
The condensed milk-like composition of the present invention may, if necessary, contain a protein source other than milk protein, for example, a plant-derived protein such as soybean, but preferably does not contain it. Specifically, the amount of protein other than milk protein is 10% by weight or less, preferably 5% by weight or less in the amount of protein in the condensed milk-like composition of the present invention.
Liquid milk (liquid milk such as milk, skim milk, and concentrated milk) may be added to the condensed milk-like composition of the present invention as a raw material, but it is preferable not to add it.
(乳糖)
 本明細書において乳糖とは、乳の中に含まれている二糖類であり、D-グルコース(ブドウ糖)とD-ガラクトースが結合した構造を有する。本発明の製造方法により製造される練乳様組成物では、水中乳糖濃度が21重量%以下、好ましくは20重量%以下、より好ましくは18重量%以下、最も好ましくは15重量%以下である。水中乳糖濃度の下限は、0.01重量%以上、又は0.1重量%以上であることができる。練乳様組成物中の水中乳糖濃度は、レイン-エイノン法により測定することができる。具体的な手順としては、「乳及び乳製品の成分規格等に関する省令」の「(七)乳等の成分規格の試験法」の「7 乳製品の糖分の定量法」の「a 乳糖の定量法」に記載のレイン・エイノン法に従い行うことができる。
 本発明の練乳様組成物では、乳糖含量が、水中乳糖濃度で21重量%以下であることを特徴とする。練乳様組成物中で、乳糖は、練乳様組成物中の水分に溶解した状態で存在しており、乳糖の溶解度には水分量と乳糖量とが関係するため、水分を基準とした濃度で表している。なお、「水中乳糖濃度(重量%)」は、[組成物中の乳糖の重量/(組成物中の乳糖の重量+組成物中の水の重量)×100]により算出される。
(lactose)
As used herein, lactose is a disaccharide contained in milk and has a structure in which D-glucose (dextrose) and D-galactose are bound. In the condensed milk-like composition produced by the production method of the present invention, the lactose concentration in water is 21% by weight or less, preferably 20% by weight or less, more preferably 18% by weight or less, and most preferably 15% by weight or less. The lower limit of the lactose concentration in water can be 0.01% by weight or more, or 0.1% by weight or more. The lactose concentration in water in the condensed milk-like composition can be measured by the rain-Ainon method. As a specific procedure, "a Quantification of lactose" in "7 Quantification method of sugar content of dairy products" of "(7) Test method of ingredient standards of milk etc." of "Ministerial Ordinance on Ingredient Standards of Milk and Dairy Products" It can be done according to the Rain-Ainon method described in "Law".
The condensed milk-like composition of the present invention is characterized in that the lactose content is 21% by weight or less in terms of the lactose concentration in water. In the condensed milk-like composition, lactose exists in a state of being dissolved in water in the condensed milk-like composition, and the solubility of lactose is related to the amount of water and the amount of lactose. Represents. The "lactose concentration in water (% by weight)" is calculated by [weight of lactose in composition / (weight of lactose in composition + weight of water in composition) x 100].
(その他の原料)
 練乳における脂肪分は練乳特有の濃厚感、物性付与に寄与しているが、生乳由来の乳脂肪は高価である。その代替として、安価な油脂原料、好ましくは植物油脂原料を使用することができる。乳脂を脂肪分を付与する原料として使用することもできる。比較的安価で、融点が低く、低温化でも結晶化しない、且つ、味や臭いにクセのないことを考慮して、菜種サラダ油及び大豆サラダ油などのサラダ油を使用することが好ましい。
 上記油脂原料は、本発明の練乳様組成物に0~10重量%含まれることが好ましく、1~10重量%含まれることがより好ましく、2~8重量%含まれることがさらに好ましい。脂質量が少ないほどカロリーの低減につながるが、濃厚感の欠如、増粘現象の原因となりうることに留意する必要がある。
(Other raw materials)
The fat content in condensed milk contributes to the richness and physical properties peculiar to condensed milk, but milk fat derived from raw milk is expensive. As an alternative, inexpensive oil and fat raw materials, preferably vegetable oil and fat raw materials, can be used. Milk fat can also be used as a raw material for imparting fat content. It is preferable to use salad oil such as rapeseed salad oil and soybean salad oil in consideration of the fact that it is relatively inexpensive, has a low melting point, does not crystallize even at low temperatures, and has no peculiar taste or odor.
The oil and fat raw material is preferably contained in the condensed milk-like composition of the present invention in an amount of 0 to 10% by weight, more preferably 1 to 10% by weight, and even more preferably 2 to 8% by weight. It should be noted that the lower the amount of fat, the lower the calories, but it may cause lack of richness and thickening phenomenon.
(糖類)
 本発明の練乳様組成物は、糖類を、好ましくは練乳様組成物基準で5~60重量%含むことができる。本明細書において練乳様組成物に含まれる「糖類」とは、前述の乳糖を除く、単糖類、二糖類、及び多糖類を意味する。糖アルコールは、糖類には含まれない。単糖類としては、グルコース(ブドウ糖)、ガラクトース、マンノース、又はフルクトースなどを使用することができる。二糖類としては、スクロース、マルトース、トレハロース、又はセロビオースなどを使用することができる。三糖類としては、ラフィノースおよびマルトトリオースなどを使用することができる。多糖類としてはデキストリン等を使用することができる。甘味付与及び粘度調整のためにデキストリンを配合することが好ましい。ショ糖と比較して甘味度の低い糖質(デキストリン等)を併用することで、甘さを抑えたすっきりとした風味を有することが可能となる。また、デキストリンは、デキストリンはDE10~25のものを1種あるいは2種以上選択することができる。DEとはデキストロース当量のことであり、デンプンの糖化率を指す。グルコースを100とした値であり、この値が小さいほど甘味度が小さく、粘度が高くなる傾向がある。デキストリンは1種あるいは2種以上配合することで、適正な甘味度、粘度、濃厚感を調整することが可能である。
 本発明の練乳様組成物では、トレハロースなど種々の糖類を組み合わせることが好ましい。種々の糖類を組み合わせることで、すっきりとした甘みや適正な物性を付与することができる。
 本発明の練乳様組成物では、油脂の乳化安定のために、1種あるいは2種以上の乳化剤を配合することができる。乳化剤としては食品に用いられるものを適宜採用できる。乳化剤の練乳様組成物における配合量は、油脂の乳化安定を考慮して適宜選択できる。
 本発明の練乳様組成物には、ショ糖、デキストリン、及びトレハロースなどの糖類が、好ましくは10~60重量%、より好ましくは20~50重量%、さらに好ましくは30~50重量%、最も好ましくは35~45重量%含まれる。
(Sugar)
The condensed milk-like composition of the present invention can contain saccharides, preferably 5 to 60% by weight based on the condensed milk-like composition. In the present specification, the "sugar" contained in the condensed milk-like composition means a monosaccharide, a disaccharide, and a polysaccharide excluding the above-mentioned lactose. Sugar alcohols are not included in sugars. As the monosaccharide, glucose (dextrose), galactose, mannose, fructose and the like can be used. As the disaccharide, sucrose, maltose, trehalose, cellobiose and the like can be used. As the trisaccharide, raffinose, maltotriose and the like can be used. As the polysaccharide, dextrin or the like can be used. It is preferable to add dextrin for sweetening and adjusting viscosity. By using a sugar (dextrin or the like) having a lower sweetness than sucrose in combination, it is possible to have a refreshing flavor with suppressed sweetness. Further, as the dextrin, one or more dextrins with DE10 to 25 can be selected. DE is the equivalent of dextrose and refers to the saccharification rate of starch. It is a value with glucose as 100, and the smaller this value is, the smaller the sweetness tends to be and the higher the viscosity tends to be. By blending one or more dextrins, it is possible to adjust the appropriate sweetness, viscosity, and richness.
In the condensed milk-like composition of the present invention, it is preferable to combine various sugars such as trehalose. By combining various sugars, it is possible to impart a refreshing sweetness and appropriate physical properties.
In the condensed milk-like composition of the present invention, one kind or two or more kinds of emulsifiers can be blended in order to stabilize the emulsification of fats and oils. As the emulsifier, one used for food can be appropriately adopted. The blending amount of the emulsifier in the condensed milk-like composition can be appropriately selected in consideration of the emulsification stability of fats and oils.
In the condensed milk-like composition of the present invention, sugars such as sucrose, dextrin, and trehalose are preferably 10 to 60% by weight, more preferably 20 to 50% by weight, still more preferably 30 to 50% by weight, most preferably. Is contained in an amount of 35 to 45% by weight.
(水分)
 本発明の練乳様組成物は、練乳様組成物基準で、水分を20~60重量%、好ましくは20~50重量%、より好ましくは25~45重量%、さらに好ましくは30~45重量%含むことができる。
(moisture)
The condensed milk-like composition of the present invention contains 20 to 60% by weight, preferably 20 to 50% by weight, more preferably 25 to 45% by weight, still more preferably 30 to 45% by weight, based on the condensed milk-like composition. be able to.
(練乳)
 練乳とは牛乳及び脱脂乳などを濃縮したものである。練乳は、「乳及び乳製品の成分規格等に関する省令」(略して乳等省令)では無糖練乳、加糖練乳、無糖脱脂練乳、及び加糖脱脂練乳に分類される。
 本発明の練乳様組成物は、原料として濃縮乳タンパク質粉末及び粉乳等を含んでいる。したがって、本発明の練乳様組成物は、乳等省令上の練乳には該当しないが、練乳と同様の風味、外観、及び物性を有する「練乳様組成物」である。
 本発明の練乳様組成物は、原料として練乳を含むことができるが、風味及びカロリーの関係から、含まないあるいは実質的に含まないことが好ましい。具体的には、本発明の練乳様組成物における練乳の含量は、練乳様組成物基準で50重量%以下、40重量%以下、30重量%以下、20重量%以下、10重量%以下、又は5重量%以下であることができる。
(condensed milk)
Condensed milk is concentrated milk, skim milk, and the like. Condensed milk is classified into unsweetened condensed milk, sweetened condensed milk, unsweetened skim milk, and sweetened skim condensed milk in the "Ministry Ordinance on Ingredient Standards for Milk and Milk Products" (abbreviated as the Ministry Ordinance for Milk, etc.).
The condensed milk-like composition of the present invention contains concentrated milk protein powder, milk powder and the like as raw materials. Therefore, the condensed milk-like composition of the present invention is a "condensed milk-like composition" that does not correspond to condensed milk under the Ordinance of the Ministry of Milk, etc., but has the same flavor, appearance, and physical characteristics as condensed milk.
The condensed milk-like composition of the present invention may contain condensed milk as a raw material, but it is preferably not contained or substantially not contained from the viewpoint of flavor and calories. Specifically, the content of condensed milk in the condensed milk-like composition of the present invention is 50% by weight or less, 40% by weight or less, 30% by weight or less, 20% by weight or less, 10% by weight or less, or based on the condensed milk-like composition. It can be 5% by weight or less.
(練乳様組成物)
 本発明の練乳様組成物は、粘度が、20℃においてHAAKE VT550(HAAKE社製)、ローターVIIStを用い、せん断速度を0s-1→(2min)→200s-1→(2min)→0s-1とした時の最大値が、500mPa・s~5000mPa・sとなることが好ましい。
 本発明の練乳様組成物は、好ましくは、加糖練乳様又は加糖脱脂練乳様組成物である。
(Condensed milk-like composition)
The condensed milk-like composition of the present invention uses HAAKE VT550 (manufactured by HAAKE) and a rotor VIIst at a viscosity of 20 ° C., and has a shear rate of 0s -1 → (2min) → 200s -1 → (2min) → 0s -1. The maximum value is preferably 500 mPa · s to 5000 mPa · s.
The condensed milk-like composition of the present invention is preferably a sweetened condensed milk-like or a sweetened skim condensed milk-like composition.
 本発明の練乳様組成物は、水分活性が0.8~0.9となることが好ましい。本発明の練乳様組成物は、水分活性を低く維持することができ、常温流通が可能である。
 本発明の練乳様組成物は、低温保存時においても乳糖の粗大結晶の発生を防止することができる。溶媒に溶解した乳糖の溶解度は、低温になるほど小さくなる。したがって、低温保存時の方が、乳糖の粗大結晶の生成により、食感が悪化しやすい。練乳及び練乳様組成物では、常温流通が可能であれば便利であるが、家庭や店舗において開封された後は、保存性向上のために冷蔵庫等において保存されることが多い。また、常温流通が可能ではあっても、店舗や配送車の事情により、冷蔵状態で流通することもある。したがって、練乳及び練乳様組成物では、常温保存時及び低温保存時の両方における保存性が要求される。
 本明細書において、「常温」で保存するとは、25±1℃で保存することを意味する。
 本明細書において、「低温」で保存するとは、5±1℃で保存することを意味する。
 本発明の練乳様組成物は、常温及び低温のいずれにおいても良好な保存性を有することができる。「良好な保存性を有する」とは、例えば、25±1℃で7日間又は5±1℃で7日間のいずれの環境においても、乳糖の粗大結晶を検出しないことである。
The condensed milk-like composition of the present invention preferably has a water activity of 0.8 to 0.9. The condensed milk-like composition of the present invention can maintain a low water activity and can be distributed at room temperature.
The condensed milk-like composition of the present invention can prevent the generation of coarse crystals of lactose even during low-temperature storage. The solubility of lactose dissolved in a solvent decreases as the temperature decreases. Therefore, when stored at a low temperature, the texture is more likely to deteriorate due to the formation of coarse crystals of lactose. Condensed milk and condensed milk-like compositions are convenient if they can be distributed at room temperature, but after being opened at home or in a store, they are often stored in a refrigerator or the like to improve storage stability. Even if it can be distributed at room temperature, it may be distributed in a refrigerated state depending on the circumstances of stores and delivery vehicles. Therefore, condensed milk and condensed milk-like compositions are required to have storage stability both at room temperature and at low temperature.
In the present specification, storage at "normal temperature" means storage at 25 ± 1 ° C.
In the present specification, storage at "low temperature" means storage at 5 ± 1 ° C.
The condensed milk-like composition of the present invention can have good storage stability at both normal temperature and low temperature. “Having good storage stability” means that no coarse crystals of lactose are detected in any environment, for example, at 25 ± 1 ° C. for 7 days or at 5 ± 1 ° C. for 7 days.
2.練乳様組成物の製造方法
(練乳様ミックスを得る工程)
 本発明の練乳様組成物の製造方法は、溶解水に糖アルコール、濃縮乳タンパク質粉末、及び粉乳を添加して混合し、練乳様ミックスを得る工程を含む。練乳様ミックスを得る工程では、練乳様ミックスの乳糖含量が、水中乳糖濃度で21重量%以下となるように、溶解水、糖アルコール、濃縮乳タンパク質粉末、及び粉乳を混合する。溶解温度は、製造量、製造設備、原料の種類等に応じて適宜調整することができる。糖アルコール、濃縮乳タンパク質粉末、及び粉乳としては、前述のものを使用することができる。本発明の練乳様組成物の製造方法では、粉末の糖アルコールを用いてもよく、液体の糖アルコールを用いてもよい。
2. Method for producing condensed milk-like composition (step of obtaining condensed milk-like mix)
The method for producing a condensed milk-like composition of the present invention includes a step of adding sugar alcohol, concentrated milk protein powder, and milk powder to dissolved water and mixing them to obtain a condensed milk-like mix. In the step of obtaining a condensed milk-like mix, dissolved water, sugar alcohol, concentrated milk protein powder, and milk powder are mixed so that the lactose content of the condensed milk-like mix is 21% by weight or less in water lactose concentration. The melting temperature can be appropriately adjusted according to the production amount, production equipment, type of raw material, and the like. As the sugar alcohol, concentrated milk protein powder, and milk powder, the above-mentioned ones can be used. In the method for producing a condensed milk-like composition of the present invention, powdered sugar alcohol may be used, or liquid sugar alcohol may be used.
 糖アルコール、濃縮乳タンパク質粉末、及び粉乳の添加順は、特に限定されることはなく、製造量、製造設備、原料の種類等に応じて適宜調整することができる。プレミックスを調製してから、すなわち、糖アルコール、濃縮乳タンパク質粉末、及び粉乳、必要であればさらに他の原料を事前に混合してから溶解水に添加してもよい。また、糖アルコール、濃縮乳タンパク質粉末、及び粉乳を先に製造機器に投入して、その後で溶解水を投入してもよい。一部の原料を予め水に溶かして溶解液を調製し、この溶解液を溶解水に添加してもよい。溶解水は、純水である必要はなく、本発明の効果が得られ且つ上記原料を溶解することができる限りにおいて、他の成分を含むことができる。 The order of addition of sugar alcohol, concentrated milk protein powder, and milk powder is not particularly limited, and can be appropriately adjusted according to the production amount, production equipment, type of raw material, and the like. The premix may be prepared, i.e., sugar alcohol, concentrated milk protein powder, and milk powder, and if necessary, other ingredients may be premixed before addition to the dissolved water. Alternatively, sugar alcohol, concentrated milk protein powder, and milk powder may be added to the manufacturing equipment first, and then dissolved water may be added. A solution may be prepared by dissolving some raw materials in water in advance, and the solution may be added to the solution. The dissolved water does not have to be pure water, and may contain other components as long as the effects of the present invention can be obtained and the above-mentioned raw materials can be dissolved.
(殺菌工程)
 本発明の練乳様組成物の製造方法は、練乳様ミックスを殺菌し、練乳様組成物を得る工程を含む。本明細書において「殺菌」とは、加熱等により、練乳様ミックス中に存在する微生物を減少させる又は完全に死滅させることを意味する。乳化機では、混合粉末原料、植物油脂、糖アルコール、及び水等を投入し、予備混合・乳化することができる。殺菌前に、50~60℃の温度条件下で予備混合・乳化することが好ましい。
 予備混合・乳化したミックスは85~95℃下で90~150秒殺菌することができる。殺菌処理は、混合・乳化後、プレート式熱交換器、チューブ式熱交換器、スチームインジェクション式殺菌機、スチームインフュージョン式殺菌機、通電加熱式殺菌機等で行うことができる。充填した後にレトルト殺菌を行うこともできる。なお、前記殺菌方法、殺菌時間、及び殺菌温度は一例であり、当業者であれば練乳様組成物の配合、容器等を考慮して、適宜殺菌方法、殺菌時間、及び殺菌温度を調整することができる。殺菌後、冷却して練乳用組成物を得ることができる。
(Sterilization process)
The method for producing a condensed milk-like composition of the present invention includes a step of sterilizing the condensed milk-like mix to obtain a condensed milk-like composition. As used herein, "sterilization" means reducing or completely killing microorganisms present in a condensed milk-like mix by heating or the like. In the emulsifying machine, mixed powder raw materials, vegetable oils and fats, sugar alcohols, water and the like can be added and premixed and emulsified. Prior to sterilization, it is preferable to premix and emulsify under a temperature condition of 50 to 60 ° C.
The premixed and emulsified mix can be sterilized at 85-95 ° C. for 90-150 seconds. After mixing and emulsifying, the sterilization treatment can be performed with a plate type heat exchanger, a tube type heat exchanger, a steam injection type sterilizer, a steam infusion type sterilizer, an energization heating type sterilizer, or the like. Retort sterilization can also be performed after filling. The sterilization method, sterilization time, and sterilization temperature are examples, and those skilled in the art should appropriately adjust the sterilization method, sterilization time, and sterilization temperature in consideration of the composition of the condensed milk-like composition, the container, and the like. Can be done. After sterilization, it can be cooled to obtain a condensed milk composition.
(シーディング工程)
 本明細書においてシーディング工程とは、核となる乳糖を外部から添加することにより、微細な乳糖結晶をあらかじめ析出させ、保存中や流通過程において粗大結晶が生成しないようにする処理のことである。シーディング工程は、粉砕乳糖を所定の温度で練乳様組成物に添加して、乳糖析出温度(20~35℃)まで冷却することにより行うことができる。
(Seeding process)
In the present specification, the seeding step is a process of precipitating fine lactose crystals by adding core lactose from the outside to prevent the formation of coarse crystals during storage or distribution process. .. The seeding step can be carried out by adding pulverized lactose to the condensed milk-like composition at a predetermined temperature and cooling to the lactose precipitation temperature (20 to 35 ° C.).
 濃縮乳タンパク質粉末を併用し、乳糖濃度を調整することでシーディング工程を不要とすることができる。また、液状乳原料ではなく粉末原料である濃縮乳タンパク質粉末を使用することで、濃縮工程を削減することができる。また、濃縮乳タンパク質粉末を使用することにより、工程の簡略化を実現することができる。また、濃縮乳タンパク質粉末は比較的安価で、調達が容易であり、且つ、常温保管が可能である。 By using concentrated milk protein powder together and adjusting the lactose concentration, the seeding process can be eliminated. Further, by using the concentrated milk protein powder which is a powder raw material instead of the liquid milk raw material, the concentration step can be reduced. Further, by using the concentrated milk protein powder, the process can be simplified. In addition, concentrated milk protein powder is relatively inexpensive, easy to procure, and can be stored at room temperature.
 乳糖の溶解度は温度依存性があるが、溶解度を超えると結晶化が促進され、この処理を実施しないと粗大結晶の生成に繋がる。粗大結晶が生成すると、摂取したときに舌にザラツキ感が生じ、非常に食感が悪くなる。
 本発明の練乳様組成物の製造方法では、シーディング工程を含んでもよいが、製造工程の簡略化の観点から、含まないことが好ましい。
The solubility of lactose is temperature-dependent, but if it exceeds the solubility, crystallization is promoted, and if this treatment is not performed, it leads to the formation of coarse crystals. When coarse crystals are formed, the tongue becomes rough when ingested, and the texture becomes very poor.
The method for producing a condensed milk-like composition of the present invention may include a seeding step, but it is preferable not to include the seeding step from the viewpoint of simplification of the manufacturing step.
(液状乳)
 本明細書において液状乳とは、液体の状態で練乳用組成物に添加するための乳原料であり、牛乳、脱脂乳、及び濃縮乳が含まれる。
 液状乳は調達元に制約があり、比較的高価である。また、更には受入れや保管に冷蔵設備が必要であり、設備投資及び輸送に非常にコストがかかる。また、水分を多量に含むことから、濃縮工程が必須となる可能性もある。
 本発明の練乳用組成物の製造方法では、液状乳を溶解水に添加する工程を含んでもよいが、コスト削減及び工程簡略化の観点から、含まないことが好ましい。
(Liquid milk)
In the present specification, the liquid milk is a dairy raw material to be added to the composition for condensed milk in a liquid state, and includes milk, skim milk, and concentrated milk.
Liquid milk is relatively expensive due to restrictions on the source. Furthermore, refrigeration equipment is required for acceptance and storage, and capital investment and transportation are extremely costly. In addition, since it contains a large amount of water, a concentration step may be indispensable.
The method for producing a condensed milk composition of the present invention may include a step of adding liquid milk to dissolved water, but it is preferable not to include the step from the viewpoint of cost reduction and process simplification.
(練乳)
 本発明の製造方法により製造されるものは、原料として濃縮乳タンパク質粉末及び粉乳等を含んでいる。したがって、本発明の製造方法により製造されるものは、乳等省令上の練乳には該当しないが、練乳と同様の風味、外観、及び物性を有する「練乳様組成物」である。
 本発明の練乳用組成物の製造方法では、練乳を添加する工程を含んでもよいが、コスト削減及び工程簡略化の観点から、含まないことが好ましい。
 一般的な加糖練乳の製造工程は複雑且つ、非常に多数の工程を有しており、大規模な製造ラインの設置が必要である。また、上記事由により製造コストが高くなる傾向にある。そのため、より工程を簡略化した製造方法が求められる。
(condensed milk)
The product produced by the production method of the present invention contains concentrated milk protein powder, milk powder and the like as raw materials. Therefore, what is produced by the production method of the present invention is a "condensed milk-like composition" which does not correspond to condensed milk under the Ordinance of the Ministry of Milk, etc., but has the same flavor, appearance, and physical characteristics as condensed milk.
The method for producing a condensed milk composition of the present invention may include a step of adding condensed milk, but it is preferable not to include it from the viewpoint of cost reduction and process simplification.
The general manufacturing process of sweetened condensed milk is complicated and has a large number of processes, and it is necessary to install a large-scale production line. In addition, the manufacturing cost tends to increase due to the above reasons. Therefore, a manufacturing method with a simpler process is required.
 本発明の練乳様組成物の製造方法は、金属缶、金属箔又はプラスチックフィルムと複合された紙容器、アルミパウチなどのパウチ、プラスチック容器、ビニール容器、及びガラス瓶などの通常の包装容器に充填して提供することができ、その容量についても特に限定されない。 The method for producing a condensed milk-like composition of the present invention fills a metal can, a paper container compounded with a metal foil or a plastic film, a pouch such as an aluminum pouch, a plastic container, a vinyl container, and a normal packaging container such as a glass bottle. The capacity is not particularly limited.
 本発明の練乳様組成物の製造方法に用いられる製造用設備としては加熱機能及び、撹拌機能を有する例えば乳化機が挙げられる。 Examples of the manufacturing equipment used in the method for producing the condensed milk-like composition of the present invention include an emulsifier having a heating function and a stirring function.
 以下、実施例によって本発明を具体的に説明するが、これらは本発明の範囲を限定するものではない。なお、本明細書において特に説明のない場合は、「%」は重量%を示す。 Hereinafter, the present invention will be specifically described with reference to Examples, but these do not limit the scope of the present invention. Unless otherwise specified in the present specification, "%" indicates weight%.
実施例1(簡易製造法)
 脱脂粉乳420g、乳タンパク質濃縮物(MPC)158g、ショ糖385g、デキストリン595g、トレハロース350g、乳化剤(ショ糖ステアリン酸エステルおよびコハク酸脂肪酸モノグリセライド)8gを粉末状態で混合し、粉末原料を得た。粉末原料、菜種サラダ油140g、グリセリン280g、水760gを乳化機に投入し、スチームインジェクションにて加熱し、60℃到達後、10分間溶解した。溶解後、香料を添加し、更にスチームインジェクションによる加熱処理を行い、88~95℃で120秒間殺菌し、加糖練乳様組成物を得た。尚、トータル加水量は1150~1200gに調整し、撹拌機の回転数は1800rpmとした。
 パネラー5人で官能検査を実施したところ、実施例1の方法で調製した加糖練乳様組成物は、比較例1の濃縮法で調製した加糖練乳様組成物と同等の風味、色沢及び粘度であった。また、常温(25℃)及び冷温(5℃)で7日間保存しても、乳糖の結晶は発生しておらず、風味と色沢に関しても、いずれも変化がなかった。
Example 1 (simple manufacturing method)
Skim milk powder 420 g, milk protein concentrate (MPC) 158 g, sucrose 385 g, dextrin 595 g, trehalose 350 g, and emulsifier (sucrose stearic acid ester and sucrose fatty acid monoglyceride) 8 g were mixed in a powder state to obtain a powder raw material. The powder raw material, 140 g of rapeseed salad oil, 280 g of glycerin, and 760 g of water were put into an emulsifier, heated by steam injection, and dissolved for 10 minutes after reaching 60 ° C. After dissolution, a flavor was added, and the mixture was further heat-treated by steam injection and sterilized at 88 to 95 ° C. for 120 seconds to obtain a sweetened condensed milk-like composition. The total amount of water added was adjusted to 1150 to 1200 g, and the rotation speed of the stirrer was 1800 rpm.
When a sensory test was carried out by five panelists, the sweetened condensed milk-like composition prepared by the method of Example 1 had the same flavor, color and viscosity as the sweetened condensed milk-like composition prepared by the concentration method of Comparative Example 1. there were. Further, even when stored at room temperature (25 ° C.) and cold temperature (5 ° C.) for 7 days, lactose crystals were not generated, and neither flavor nor color was changed.
実施例2
 脱脂粉乳420g、乳タンパク質濃縮物(MPC)70g、ショ糖438g、デキストリン630g、トレハロース350g、乳化剤(ショ糖ステアリン酸エステルおよびコハク酸脂肪酸モノグリセライド)8gを粉末状態で混合し、粉末原料を得た。菜種サラダ油140g、グリセリン280g、水720gを乳化機に投入し、スチームインジェクションにて加熱し、60℃到達後、10分間溶解した。溶解後、香料を添加し、更にスチームインジェクションによる加熱処理を行い、88~95℃で120秒間殺菌し、加糖練乳様組成物を得た。尚、トータル加水量は1150~1200gに調整し、撹拌機の回転数は1800rpmとした。
 パネラー5人で官能検査を実施したところ、実施例2の方法で調製した加糖練乳様組成物は、比較例1の濃縮法で調製した加糖練乳様組成物と比較して、食感は良好であった。許容可能な範囲であるが、風味は少しミルク感とコクに欠け、色沢は少し希薄であった。また、常温(25℃)及び冷温(5℃)で7日間保存しても、乳糖の結晶は発生しておらず、風味と色沢に関しても、いずれも変化がなかった。
Example 2
Skim milk powder 420 g, milk protein concentrate (MPC) 70 g, sucrose 438 g, dextrin 630 g, trehalose 350 g, and emulsifier (sucrose stearic acid ester and sucrose fatty acid monoglyceride) 8 g were mixed in a powder state to obtain a powder raw material. 140 g of rapeseed salad oil, 280 g of glycerin, and 720 g of water were put into an emulsifier, heated by steam injection, and dissolved for 10 minutes after reaching 60 ° C. After dissolution, a flavor was added, and the mixture was further heat-treated by steam injection and sterilized at 88 to 95 ° C. for 120 seconds to obtain a sweetened condensed milk-like composition. The total amount of water added was adjusted to 1150 to 1200 g, and the rotation speed of the stirrer was 1800 rpm.
When a sensory test was carried out by five panelists, the sweetened condensed milk-like composition prepared by the method of Example 2 had a better texture than the sweetened condensed milk-like composition prepared by the concentration method of Comparative Example 1. there were. It was acceptable, but the flavor was a little lacking in milkiness and richness, and the color was a little lean. Further, even when stored at room temperature (25 ° C.) and cold temperature (5 ° C.) for 7 days, lactose crystals were not generated, and neither flavor nor color was changed.
実施例3
 脱脂粉乳420g、ホエイタンパク質濃縮物(WPC)158g、ショ糖427g、デキストリン543g、トレハロース350g、乳化剤(ショ糖ステアリン酸エステルおよびコハク酸脂肪酸モノグリセライド)8gを粉末状態で混合し、粉末原料を得た。粉末原料、菜種サラダ油140g、グリセリン280g、水720gを乳化機に投入し、スチームインジェクションにて加熱し、60℃到達後、10分間溶解した。溶解後、香料添加し、更にスチームインジェクションによる加熱処理を行い、88~95℃で120秒間殺菌し、加糖練乳様組成物を得た。尚、トータル加水量は1150~1200gに調整し、撹拌機の回転数は1800rpmとした。
 パネラー5人で官能検査を実施したところ、実施例3の方法で調製した加糖練乳様組成物は、比較例1の濃縮法で調製した加糖練乳様組成物と比較して、ややホエイ由来のグラッシーな風味を有していたが、加糖練乳様組成物として許容可能な風味であった。色沢、粘度は加糖練乳と同等のレベルであった。また、常温(25℃)及び冷温(5℃)で7日間保存しても、乳糖の結晶は発生しておらず、風味と色沢に関しても、いずれも変化がなかった。
Example 3
420 g of defatted milk powder, 158 g of whey protein concentrate (WPC), 427 g of sucrose, 543 g of dextrin, 350 g of trehalose, and 8 g of emulsifier (sucrose stearic acid ester and monoglyceride sucrose) were mixed in a powder state to obtain a powder raw material. The powder raw material, 140 g of rapeseed salad oil, 280 g of glycerin, and 720 g of water were put into an emulsifier, heated by steam injection, and dissolved for 10 minutes after reaching 60 ° C. After dissolution, a flavor was added, and the mixture was further heat-treated by steam injection and sterilized at 88 to 95 ° C. for 120 seconds to obtain a sweetened condensed milk-like composition. The total amount of water added was adjusted to 1150 to 1200 g, and the rotation speed of the stirrer was 1800 rpm.
When a sensory test was carried out by five panelists, the sweetened condensed milk-like composition prepared by the method of Example 3 was slightly whey-derived glassy as compared with the sweetened condensed milk-like composition prepared by the concentration method of Comparative Example 1. It had a good flavor, but it was an acceptable flavor as a sweetened condensed milk-like composition. The color and viscosity were at the same level as sweetened condensed milk. Further, even when stored at room temperature (25 ° C.) and cold temperature (5 ° C.) for 7 days, lactose crystals were not generated, and neither flavor nor color was changed.
比較例1(従来の製造方法(濃縮法))
 脱脂粉乳167g、ショ糖41g、デキストリン80g、トレハロース67g、乳化剤(ショ糖ステアリン酸エステル、グリセリン脂肪酸エステルおよび大豆レシチン)1.3gを粉末状態で混合し、粉末原料を得た。粉末原料、菜種サラダ油33g、グリセリン53gを水1557gに60℃で溶解した。溶解後、均質処理(均質圧50kgf)を行い、80~90℃下で10分間殺菌処理を実施した。殺菌処理後、水冷し、減圧条件下で水分を蒸発させ、Brixが21.5から63.9になるまで濃縮した。濃縮後、香料添加とシーディング操作を実施し、加糖練乳様組成物を得た。
 パネラー5人で官能検査を実施したところ、得られた加糖練乳様組成物はすっきりとした甘さと乳感を有した良好な風味であった。
 色沢、粘度も加糖練乳と同等のレベルであった。
 シーディング操作を実施することで、常温(25℃)及び冷温(5℃)で7日間保存しても、乳糖の粗大結晶は認められなかった。
Comparative Example 1 (conventional manufacturing method (concentration method))
167 g of defatted milk powder, 41 g of sucrose, 80 g of dextrin, 67 g of trehalose, and 1.3 g of emulsifiers (sucrose stearic acid ester, glycerin fatty acid ester and soy lecithin) were mixed in a powder state to obtain a powder raw material. The powder raw material, 33 g of rapeseed salad oil, and 53 g of glycerin were dissolved in 1557 g of water at 60 ° C. After dissolution, a homogeneous treatment (homogeneous pressure 50 kgf) was performed, and a sterilization treatment was performed at 80 to 90 ° C. for 10 minutes. After the sterilization treatment, the mixture was cooled with water, the water content was evaporated under reduced pressure conditions, and the Brix was concentrated from 21.5 to 63.9. After concentration, flavoring and seeding operations were carried out to obtain a sweetened condensed milk-like composition.
When a sensory test was carried out by five panelists, the obtained sweetened condensed milk-like composition had a good flavor with a refreshing sweetness and a milky feeling.
The color and viscosity were at the same level as sweetened condensed milk.
By performing the seeding operation, no coarse crystals of lactose were observed even after storage at room temperature (25 ° C.) and cold temperature (5 ° C.) for 7 days.
比較例2
 脱脂粉乳770g、ショ糖1,330g、トレハロース350g、乳化剤(ショ糖ステアリン酸エステルおよびコハク酸脂肪酸モノグリセライド)8gを粉末状態で混合し、粉末原料を得た。菜種サラダ油140g、水500gを乳化機に投入し、スチームインジェクションにて加熱し、60℃到達後、10分間溶解した。溶解後、香料添加し、更にスチームインジェクションによる加熱処理を行い、88~95℃で120秒間殺菌し、加糖練乳様組成物を得た。尚、トータル加水量は900~950gになるように調整し、撹拌機の回転数は1800rpmとした。
 パネラー5人で官能検査を実施したところ、得られた加糖練乳様乳製品は加糖練乳様の色沢を有していた。また、許容可能な範囲ではあるが、甘味が強く、濃厚な風味を有していた。粘度は19900mPa・sであり、加糖練乳と比較すると非常に高粘度であった。常温(25℃)及び冷温(5℃)で7日間保存すると、多量の乳糖の粗大結晶が発生しており、口中でのざらつきが強く、食感が損なわれていた。
Comparative Example 2
770 g of skim milk powder, 1,330 g of sucrose, 350 g of trehalose, and 8 g of emulsifiers (sucrose stearic acid ester and sucrose fatty acid monoglyceride) were mixed in a powder state to obtain a powder raw material. 140 g of rapeseed salad oil and 500 g of water were put into an emulsifier, heated by steam injection, and dissolved for 10 minutes after reaching 60 ° C. After dissolution, a flavor was added, and the mixture was further heat-treated by steam injection and sterilized at 88 to 95 ° C. for 120 seconds to obtain a sweetened condensed milk-like composition. The total amount of water added was adjusted to 900 to 950 g, and the rotation speed of the stirrer was 1800 rpm.
When a sensory test was carried out by five panelists, the obtained sweetened condensed milk-like dairy product had a sweetened condensed milk-like color. In addition, although it was within an acceptable range, it had a strong sweetness and a rich flavor. The viscosity was 19,900 mPa · s, which was extremely high as compared with sweetened condensed milk. When stored at room temperature (25 ° C.) and cold temperature (5 ° C.) for 7 days, a large amount of coarse crystals of lactose were generated, and the texture was impaired due to the strong roughness in the mouth.
比較例3
 脱脂粉乳770g、ショ糖385g、デキストリン385g、トレハロース350g、乳化剤(ショ糖ステアリン酸エステルおよびコハク酸脂肪酸モノグリセライド)8gを粉末状態で混合し、粉末原料を得た。菜種サラダ油140g、グリセリン280g、水720gを乳化機に投入し、スチームインジェクションにて加熱し、60℃到達後、10分間溶解した。溶解後、香料添加し、更にスチームインジェクションによる加熱処理を行い、88~95℃で120秒間殺菌し、加糖練乳様組成物を得た。尚、トータル加水量は1150~1200gに調整し、撹拌機の回転数は1800rpmとした。
 パネラー5人で官能検査を実施したところ、得られた加糖練乳様組成物はすっきりとした甘さと乳感を有した良好な風味であった。色沢、粘度は加糖練乳と同等のレベルであった。
 常温(25℃)及び冷温(5℃)で7日間保存すると、一部、乳糖の粗大結晶が認められ、食感不良が認められた。
Comparative Example 3
770 g of defatted milk powder, 385 g of sucrose, 385 g of dextrin, 350 g of trehalose, and 8 g of an emulsifier (sucrose stearic acid ester and monoglyceride sucrose) were mixed in a powder state to obtain a powder raw material. 140 g of rapeseed salad oil, 280 g of glycerin, and 720 g of water were put into an emulsifier, heated by steam injection, and dissolved for 10 minutes after reaching 60 ° C. After dissolution, a flavor was added, and the mixture was further heat-treated by steam injection and sterilized at 88 to 95 ° C. for 120 seconds to obtain a sweetened condensed milk-like composition. The total amount of water added was adjusted to 1150 to 1200 g, and the rotation speed of the stirrer was 1800 rpm.
When a sensory test was carried out by five panelists, the obtained sweetened condensed milk-like composition had a good flavor with a refreshing sweetness and a milky feeling. The color and viscosity were at the same level as sweetened condensed milk.
When stored at room temperature (25 ° C.) and cold temperature (5 ° C.) for 7 days, some coarse crystals of lactose were observed, and poor texture was observed.
比較例4
 脱脂粉乳648g、乳タンパク質濃縮物(MPC)56g、ショ糖420g、デキストリン434g、トレハロース350g、乳化剤(ショ糖ステアリン酸エステルおよびコハク酸脂肪酸モノグリセライド)8gを粉末状態で混合し、粉末原料を得た。菜種サラダ油140g、グリセリン280g、水720gを乳化機に投入し、スチームインジェクションにて加熱し、60℃到達後、10分間溶解した。溶解後、香料添加し、更にスチームインジェクションによる加熱処理を行い、88~95℃で120秒間殺菌し、加糖練乳様組成物を得た。尚、トータル加水量は1150~1200gに調整し、撹拌機の回転数は1800rpmとした。
 パネラー5人で官能検査を実施したところ、得られた加糖練乳様組成物はすっきりとした甘さと乳感を有した良好な風味であった。色沢、粘度は加糖練乳と同等のレベルであった。
 常温(25℃)及び冷温(5℃)で7日間保存すると、常温下での食感は良好であったが、冷蔵下では一部、乳糖の粗大結晶が認められ、食感不良が認められた。
Comparative Example 4
648 g of skim milk powder, 56 g of milk protein concentrate (MPC), 420 g of sucrose, 434 g of dextrin, 350 g of trehalose, and 8 g of emulsifier (sucrose stearic acid ester and monoglyceride sucrose) were mixed in a powder state to obtain a powder raw material. 140 g of rapeseed salad oil, 280 g of glycerin, and 720 g of water were put into an emulsifier, heated by steam injection, and dissolved for 10 minutes after reaching 60 ° C. After dissolution, a flavor was added, and the mixture was further heat-treated by steam injection and sterilized at 88 to 95 ° C. for 120 seconds to obtain a sweetened condensed milk-like composition. The total amount of water added was adjusted to 1150 to 1200 g, and the rotation speed of the stirrer was 1800 rpm.
When a sensory test was carried out by five panelists, the obtained sweetened condensed milk-like composition had a good flavor with a refreshing sweetness and a milky feeling. The color and viscosity were at the same level as sweetened condensed milk.
When stored at room temperature (25 ° C) and cold temperature (5 ° C) for 7 days, the texture at room temperature was good, but under refrigeration, some coarse crystals of lactose were observed, and poor texture was observed. It was.
 各実施例及び比較例の原料配合率を表1に示す。各実施例及び比較例中のタンパク質の含量を表2に示す。各実施例及び比較例中のタンパク質における、脱脂粉乳由来タンパク質の割合及びMPC由来タンパク質の割合を表3に示す。脱脂粉乳中にタンパク質は約36%含まれており、MPC中にタンパク質は約82%含まれており、WPC中にタンパク質は約81%含まれている。各実施例及び比較例の原料配合率から計算した乳糖の水中濃度を表4に示す。使用したMPCの乳糖含量は約2.3%であり、使用したWPCの乳糖含量は約4.0%である。使用した脱脂粉乳の乳糖含量は約51.5%である。各実施例及び比較例の評価結果の一覧を表5に示す。 Table 1 shows the raw material blending ratios of each example and comparative example. Table 2 shows the protein content in each Example and Comparative Example. Table 3 shows the proportion of skim milk powder-derived protein and the proportion of MPC-derived protein in the proteins in each Example and Comparative Example. Skim milk powder contains about 36% protein, MPC contains about 82% protein, and WPC contains about 81% protein. Table 4 shows the concentration of lactose in water calculated from the raw material mixing ratios of each Example and Comparative Example. The lactose content of the MPC used is about 2.3% and the lactose content of the WPC used is about 4.0%. The lactose content of the skim milk powder used is about 51.5%. Table 5 shows a list of evaluation results of each example and comparative example.
Figure JPOXMLDOC01-appb-T000001
Figure JPOXMLDOC01-appb-T000001
Figure JPOXMLDOC01-appb-T000002
Figure JPOXMLDOC01-appb-T000002
Figure JPOXMLDOC01-appb-T000003
Figure JPOXMLDOC01-appb-T000003
Figure JPOXMLDOC01-appb-T000004
Figure JPOXMLDOC01-appb-T000004
Figure JPOXMLDOC01-appb-T000005
Figure JPOXMLDOC01-appb-T000005
 本発明を特定の態様を参照して詳細に説明したが、本発明の精神と範囲を離れることなく様々な変更および修正が可能であることは、当業者にとって明らかである。
 なお、本願は、2019年9月11日付で出願された日本国特許出願(特願2019-165012)に基づいており、その全体が引用により援用される。また、ここに引用されるすべての参照は全体として取り込まれる。
Although the present invention has been described in detail with reference to specific embodiments, it will be apparent to those skilled in the art that various modifications and modifications can be made without departing from the spirit and scope of the invention.
This application is based on a Japanese patent application (Japanese Patent Application No. 2019-165012) filed on September 11, 2019, and the entire application is incorporated by reference. Also, all references cited here are taken in as a whole.
 従来の加糖練乳よりも簡便な製造方法で同様の風味、粘度特性、保存性を有すると共に、低カロリーですっきりとした練乳様組成物を提供できる。 It is possible to provide a low-calorie, clean condensed milk-like composition while having the same flavor, viscosity characteristics, and storage stability by a simpler manufacturing method than conventional sweetened condensed milk.

Claims (8)

  1.  糖アルコール、濃縮乳タンパク質粉末、及び粉乳を含む練乳様組成物であって、乳糖の含量が、水中乳糖濃度で21重量%以下である、前記練乳様組成物。 The condensed milk-like composition containing sugar alcohol, concentrated milk protein powder, and milk powder, wherein the lactose content is 21% by weight or less in water lactose concentration.
  2.  前記練乳様組成物に含まれる乳タンパク質の18重量%以上が、濃縮乳タンパク質粉末由来である、請求項1に記載の練乳様組成物。 The condensed milk-like composition according to claim 1, wherein 18% by weight or more of the milk protein contained in the condensed milk-like composition is derived from concentrated milk protein powder.
  3.  前記練乳様組成物に含まれる乳タンパク質において、濃縮乳タンパク質粉末に由来する乳タンパク質と粉乳に由来する乳タンパク質の比率が、1:4~4:1である、請求項1又は2に記載の練乳様組成物。 The milk protein contained in the condensed milk-like composition, according to claim 1 or 2, wherein the ratio of the milk protein derived from the concentrated milk protein powder to the milk protein derived from the milk powder is 1: 4 to 4: 1. Condensed milk-like composition.
  4.  植物油脂及び/又は糖類をさらに含む、請求項1~3のいずれか一項に記載の練乳様組成物。 The condensed milk-like composition according to any one of claims 1 to 3, further comprising vegetable oil and / or sugar.
  5.  溶解水に糖アルコール、濃縮乳タンパク質粉末、及び粉乳を添加して混合し、練乳様ミックスを得る工程と、前記練乳様ミックスを殺菌し、練乳様組成物を得る工程と、を含む練乳様組成物の製造方法であって、前記練乳様組成物の乳糖の含量が、水中乳糖濃度で21重量%以下である、前記製造方法。 A condensed milk-like composition including a step of adding and mixing sugar alcohol, concentrated milk protein powder, and powdered milk to dissolved water to obtain a condensed milk-like mix, and a step of sterilizing the condensed milk-like mix to obtain a condensed milk-like composition. A method for producing a product, wherein the content of lactose in the condensed milk-like composition is 21% by weight or less in terms of lactose concentration in water.
  6.  前記練乳様組成物に含まれる乳タンパク質の18重量%以上が、濃縮乳タンパク質粉末由来である、請求項5に記載の練乳様組成物の製造方法。 The method for producing a condensed milk-like composition according to claim 5, wherein 18% by weight or more of the milk protein contained in the condensed milk-like composition is derived from concentrated milk protein powder.
  7.  前記練乳様組成物に含まれる乳タンパク質において、濃縮乳タンパク質粉末に由来する乳タンパク質と粉乳に由来する乳タンパク質の比率が、1:4~4:1である、請求項5又は6に記載の練乳様組成物の製造方法。 The milk protein contained in the condensed milk-like composition, according to claim 5 or 6, wherein the ratio of the milk protein derived from the concentrated milk protein powder to the milk protein derived from the milk powder is 1: 4 to 4: 1. A method for producing a condensed milk-like composition.
  8.  シーディング工程を含まない、請求項5~7のいずれか一項に記載の練乳様組成物の製造方法。 The method for producing a condensed milk-like composition according to any one of claims 5 to 7, which does not include a seeding step.
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JPH0919261A (en) * 1995-07-06 1997-01-21 Snow Brand Milk Prod Co Ltd Sugar added condensed milk like composition
JPH09224566A (en) * 1996-02-21 1997-09-02 Snow Brand Milk Prod Co Ltd Dairy products like sugar added condensed milk and its producing method
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WO2006103210A1 (en) * 2005-03-29 2006-10-05 Nestec S.A. Shelf-stable condensed milk with reduced sugar content
CN109662148A (en) * 2018-12-26 2019-04-23 光明乳业股份有限公司 A kind of low fat high protein sweet condensed milk and preparation method thereof
WO2019169424A1 (en) * 2018-03-05 2019-09-12 Agritechnology Pty Ltd Lactose free milk products

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JPS5112707B1 (en) * 1969-07-13 1976-04-21
JPH07264978A (en) * 1994-03-29 1995-10-17 Snow Brand Milk Prod Co Ltd Sugar-added condensed milk-like composition
JPH0919261A (en) * 1995-07-06 1997-01-21 Snow Brand Milk Prod Co Ltd Sugar added condensed milk like composition
JPH09224566A (en) * 1996-02-21 1997-09-02 Snow Brand Milk Prod Co Ltd Dairy products like sugar added condensed milk and its producing method
FR2780617A1 (en) * 1998-07-01 2000-01-07 Reffuveille Ind Production of storage-stable sweetened concentrated dairy product
WO2006103210A1 (en) * 2005-03-29 2006-10-05 Nestec S.A. Shelf-stable condensed milk with reduced sugar content
WO2019169424A1 (en) * 2018-03-05 2019-09-12 Agritechnology Pty Ltd Lactose free milk products
CN109662148A (en) * 2018-12-26 2019-04-23 光明乳业股份有限公司 A kind of low fat high protein sweet condensed milk and preparation method thereof

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