WO2020246692A1 - Inspection device for adhesive stains on polarizing plate and inspection method for adhesive stains on polarizing plate - Google Patents

Inspection device for adhesive stains on polarizing plate and inspection method for adhesive stains on polarizing plate Download PDF

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Publication number
WO2020246692A1
WO2020246692A1 PCT/KR2020/003259 KR2020003259W WO2020246692A1 WO 2020246692 A1 WO2020246692 A1 WO 2020246692A1 KR 2020003259 W KR2020003259 W KR 2020003259W WO 2020246692 A1 WO2020246692 A1 WO 2020246692A1
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WO
WIPO (PCT)
Prior art keywords
polarizing plate
adhesive
light
polarizing
polarizer
Prior art date
Application number
PCT/KR2020/003259
Other languages
French (fr)
Korean (ko)
Inventor
류재일
남택근
최경식
Original Assignee
주식회사 엘지화학
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Application filed by 주식회사 엘지화학 filed Critical 주식회사 엘지화학
Priority to JP2021571884A priority Critical patent/JP2022535095A/en
Priority to CN202080038249.5A priority patent/CN113906287A/en
Publication of WO2020246692A1 publication Critical patent/WO2020246692A1/en

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    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/84Systems specially adapted for particular applications
    • G01N21/88Investigating the presence of flaws or contamination
    • G01N21/94Investigating contamination, e.g. dust
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/84Systems specially adapted for particular applications
    • G01N21/88Investigating the presence of flaws or contamination
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/84Systems specially adapted for particular applications
    • G01N21/88Investigating the presence of flaws or contamination
    • G01N21/8851Scan or image signal processing specially adapted therefor, e.g. for scan signal adjustment, for detecting different kinds of defects, for compensating for structures, markings, edges
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/84Systems specially adapted for particular applications
    • G01N21/88Investigating the presence of flaws or contamination
    • G01N21/95Investigating the presence of flaws or contamination characterised by the material or shape of the object to be examined
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00Optical elements other than lenses
    • G02B5/30Polarising elements
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00Optical elements other than lenses
    • G02B5/30Polarising elements
    • G02B5/3025Polarisers, i.e. arrangements capable of producing a definite output polarisation state from an unpolarised input state
    • G02B5/3033Polarisers, i.e. arrangements capable of producing a definite output polarisation state from an unpolarised input state in the form of a thin sheet or foil, e.g. Polaroid
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/84Systems specially adapted for particular applications
    • G01N21/88Investigating the presence of flaws or contamination
    • G01N21/8806Specially adapted optical and illumination features
    • G01N2021/8848Polarisation of light
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/84Systems specially adapted for particular applications
    • G01N21/88Investigating the presence of flaws or contamination
    • G01N21/8851Scan or image signal processing specially adapted therefor, e.g. for scan signal adjustment, for detecting different kinds of defects, for compensating for structures, markings, edges
    • G01N2021/8887Scan or image signal processing specially adapted therefor, e.g. for scan signal adjustment, for detecting different kinds of defects, for compensating for structures, markings, edges based on image processing techniques
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/84Systems specially adapted for particular applications
    • G01N21/88Investigating the presence of flaws or contamination
    • G01N21/95Investigating the presence of flaws or contamination characterised by the material or shape of the object to be examined
    • G01N2021/9511Optical elements other than lenses, e.g. mirrors

Definitions

  • the present application relates to an apparatus for inspecting adhesive stains on a polarizing plate and a method for inspecting adhesive stains on a polarizing plate.
  • a liquid crystal display includes a polarizing plate to control the state of light.
  • a polarizing plate used in an LCD is manufactured by attaching a polarizer having a polarizing function using an adhesive and a protective substrate on the upper and lower portions of the polarizer.
  • thermosetting adhesive a thermosetting adhesive and a photocurable adhesive.
  • a typical water-based adhesive is mainly composed of PVA, and has the same refractive index as that of the polarizer, so that stains due to thickness variation of the adhesive do not occur.
  • the photocurable adhesive has a different refractive index from that of the PVA polarizer and is cured in a non-uniform thickness, a problem of visible stains occurs.
  • An object of the present application is to provide an adhesive stain inspection apparatus for a polarizing plate and a method for inspecting adhesive stains on a polarizing plate, which can easily inspect adhesive stains generated on a polarizing plate and have excellent visibility.
  • the apparatus for inspecting adhesive stains of the polarizing plate of the present application includes a point light source, a first polarizing member disposed to apply light from the point light source, and the light transmitted through the first polarizing member.
  • a polarizing plate reflecting the applied light, a second polarizing member disposed to apply light reflected from the polarizing plate, and a light transmitted through the second polarizing member are applied to the light transmitted through the second polarizing member.
  • the polarizing plate sequentially includes a polarizer, an adhesive layer including a photocurable adhesive on top and bottom of the polarizer, and a protective material, and the first polarization
  • the light transmitted through the member is applied to the protective substrate of the polarizing plate, and the point light source applies light at a Brewster angle to the polarizing plate.
  • the point light source may emit unpolarized light toward the first polarizing member.
  • the light emitted from the point light source may have an incident angle of 45° to 75° to the polarizing plate.
  • the first polarizing member may have a polarizer and an absorption axis of the polarizing plate perpendicular to each other.
  • the polarizing plate may be a polarizing plate for a liquid crystal display.
  • light applied to the polarizing plate may be reflected by the adhesive layer.
  • the photocurable adhesive may include an adhesive composition containing an acrylic polymer in a cured state.
  • the adhesive layer may have a refractive index of 1.45 to 1.50.
  • the polarizer may have a refractive index of greater than 1.5 to 1.6.
  • the light reflected and emitted from the polarizing plate may have a reflection angle of 45° to 75° with respect to the polarizing plate.
  • the second polarizing member may have a polarizer and an absorption axis of the polarizing plate perpendicular to each other.
  • the method for inspecting adhesive stains on a polarizing plate relates to a method for inspecting adhesive stains on a polarizing plate using an adhesive stain inspection device for the polarizing plate.
  • the first polarizing member, the polarizing plate, and the second polarizing member are And sequentially transmitting, and determining an adhesive stain of the polarizing plate based on the light transmitted through the second polarizing member and applied to the inspection source.
  • light applied to the polarizing plate may be reflected.
  • adhesive stains generated on the polarizing plate can be easily inspected and excellent visibility.
  • FIG. 1 is a view showing an apparatus for inspecting adhesive stains of a polarizing plate according to an exemplary embodiment of the present application.
  • FIG. 2 is a view showing a polarizing plate according to an embodiment of the present application.
  • FIG. 3 is an image photographed by a digital camera of a second polarizing member in order to inspect adhesive stains on a polarizing plate using the apparatus for inspecting adhesive stains on a polarizing plate according to an exemplary embodiment of the present application.
  • FIG. 4 is an image photographed by a digital camera of a second polarizing member in order to inspect adhesive stains on a polarizing plate using an adhesive stain inspection apparatus for a polarizing plate according to an exemplary embodiment of the present application.
  • FIG. 5 is an image photographed by a digital camera of a second polarizing member in order to inspect adhesive stains on a polarizing plate using an adhesive stain inspection apparatus for a polarizing plate according to another exemplary embodiment of the present application.
  • FIG. 6 is an image photographed by a digital camera of a second polarizing member in order to inspect adhesive stains on a polarizing plate using an adhesive stain inspection apparatus for a polarizing plate according to another embodiment of the present application.
  • the apparatus for inspecting adhesive stains of the polarizing plate of the present application includes a point light source 100, a first polarizing member 200, a polarizing plate 300, a second polarizing member 400, and an inspecting source 500. do.
  • the point light source 100 applies light to the polarizing plate 300 at a Brewster angle.
  • 2 is a view showing a polarizing plate according to an embodiment of the present application. As shown in FIG.
  • the polarizing plate 300 sequentially includes a polarizer 310, an adhesive layer 321, 322, and protective substrates 331, 332 on top and bottom of the polarizer 310, respectively.
  • the adhesive layers 321 and 322 include a photocurable adhesive.
  • the light transmitted through the first polarizing member 200 is applied to the protective substrates 331 and 332 of the polarizing plate 300.
  • the apparatus for inspecting adhesive stains of the polarizing plate of the present application may easily inspect adhesive stains generated on the polarizing plate and may have excellent visibility.
  • the term "located in sequence” may mean a state in which each component is located in parallel in a series structure.
  • the term “brewster angle” refers to an incident angle through which only light of a certain polarization component is reflected and all other polarization components are transmitted without reflection when light passes between two media having different refractive indices. For example, when vertically polarized light (TE, s polarized light) is incident, almost all light is reflected. However, when horizontally polarized light (TM. p polarized light) is incident, reflection hardly occurs and most of it is transmitted. At this angle, the electric field of the polarized light is parallel to the incident plane, so it is not reflected.
  • TE vertically polarized light
  • TM. p polarized light horizontally polarized light
  • Brewster's angle there is an incident angle at which the reflection coefficient of horizontally polarized light becomes 0, and this angle is referred to as Brewster's angle. Therefore, when incident near Brewster's angle, the reflected wave has significantly more vertically polarized components than parallel polarized components. Therefore, when light is incident at Brewster's angle, the reflected light is always s-polarized.
  • the point light source 100 is a light source that emits unpolarized light vibrating in various directions, and may emit various white light or use various types of lamps having a continuous spectrum in a spectral range of a visible light region.
  • unpolarized light the manufacturing cost and maintenance cost of the apparatus for inspecting adhesive stains on the polarizing plate may be inexpensive.
  • the point light source may be more advantageous in terms of visibility than the surface light source.
  • the point light source virtually does not have an area and is a geometric one point light source, and can be distinguished from a surface light source in the form of a plane.
  • the point light source 100 may emit unpolarized light toward the first polarizing member 200.
  • the point light source 100 from which the unpolarized light is emitted may be polarized in a direction parallel to the transmission axis of the first polarizing member 200 while passing through the first polarizing member 200.
  • the point light source 100 may control the amount of light.
  • the point light source 100 may improve visibility by increasing the amount of light.
  • the incident angle of light emitted from the point light source 100 may be adjusted.
  • the light emitted from the point light source 100 may have an incident angle of 45° to 75° to the polarizing plate 300.
  • an incident angle of light emitted from the point light source 100 to the polarizing plate 300 may be 45° to 70°, 50° to 70°, or 55° to 65°.
  • the angle of incidence may be specified according to the refractive index of the protective substrate 332 included in the upper portion of the polarizer 310, and the incident angle in the present application is an angle based on the protective substrate having a refractive index of 1.6.
  • the first polarizing member 200 is a portion for polarizing light emitted from the point light source in a specific direction, and may be disposed so that light is applied from the point light source.
  • the term "polarizing member and polarizer” may mean a functional layer having a transmission axis formed in either direction and exhibiting anisotropic transmission characteristics with respect to incident light.
  • the polarizing member and the polarizer may have a function of transmitting light vibrating in one direction from incident light vibrating in various directions, and reflecting or absorbing light vibrating in the other direction.
  • a polarizer may be, for example, a reflective polarizer or an absorption type polarizer, and the first polarizing member, the second polarizing member, and the polarizer of the present application may be absorption type polarizers.
  • the term “absorption polarizer” may refer to a layer that transmits light having a direction parallel to a transmission axis from incident light vibrating in various directions, and absorbs and blocks light vibrating in the other directions.
  • the absorption type polarizer may have a transmission axis and an absorption axis orthogonal to each other in a plane direction.
  • the angle between the transmission axis and the absorption axis may form 85° to 95° or 90°, and light vibrating in a direction parallel to the transmission axis may be transmitted, and parallel to the absorption axis. Light vibrating in a direction can be reflected or absorbed.
  • the absorption type polarizer a conventional absorption type polarizer known in the art may be used.
  • a stretched polymer film dyed with an iodine compound or an organic dye for example, a polyvinyl alcohol (PVA) film may be used.
  • PVA polyvinyl alcohol
  • Such an absorption type polarizer may typically have a transmission axis and an absorption axis orthogonal to the transmission axis.
  • the first polarizing member 200 may have an absorption axis perpendicular to the polarizer 310 of the polarizing plate 300. Specifically, when the first polarizing member 200 has an absorption axis in the second direction (shown by ⁇ ), the polarizer 310 of the polarizing plate 300 is perpendicular to the absorption axis of the first polarizing member 200 The first polarizing member 200 and the polarizer 310 of the polarizing plate 300 may each have a transmission axis in a direction (not shown) orthogonal to the absorption axis. I can.
  • the light linearly polarized in the first direction (shown as ⁇ ) through the first polarizing member is vertically aligned with the transmission axis of the polarizer of the polarizing plate, It may be reflected by the polarizer of the polarizing plate.
  • the absorption axis of the polarizer of the first polarizing member and the polarizing plate is not perpendicular, the light linearly polarized in the first direction (shown as ⁇ ) through the first polarizing member is transmitted to the transmission axis of the polarizer of the polarizing plate.
  • the polarizer of the polarizing plate may be transmitted.
  • the linearly polarized light transmits through the polarizer of the polarizing plate and is reflected from the lower protective substrate.
  • the disadvantage that it is impossible to visually recognize the adhesive stains unless the bottom where the polarizing plate is located, that is, the surface of the inspection unit, shows a dark color. have.
  • the polarizing plate 300 is a sample to be measured for inspecting adhesive stains and may be included in an inspection unit (not shown).
  • the polarizing plate 300 may be disposed on the inspection unit.
  • the polarizing plate 300 is disposed so that the light transmitted through the first polarizing member 200 is applied to reflect the caused light. Specifically, the light applied to the polarizing plate 300 may pass through the adhesive layer 322 formed on the polarizer 310 of the polarizing plate 300 and be reflected by the polarizer 310 of the polarizing plate 300. have. By transmitting the adhesive layer 322 and reflecting light from the polarizer 310, it is possible to inspect adhesive stains on the polarizing plate.
  • the polarizing plate 300 may be a polarizing plate for a liquid crystal display.
  • a liquid crystal display device is a transmission type display device that changes the direction of light or adjusts the intensity of light by using a liquid crystal between two polarizing plates, and includes a polarizer that generates light linearly polarized on the polarizing plate, but a quarter wave plate Do not need.
  • the organic light emitting display device has a disadvantage in that it is vulnerable to reflection of external light such as sunlight and lighting due to the exposure of the electrode, so it blocks the reflection of external light from the surface when the power is off, and makes linearly polarized light on the polarizing plate to have a dark sense of view. It may include a polarizer for and a quarter wave plate for making circularly polarized light.
  • the photocurable adhesive may include an adhesive composition containing an acrylic polymer in a cured state.
  • the term "photocurable adhesive” refers to an adhesive that can be cured by irradiation of electromagnetic waves.
  • the categories of electromagnetic waves include microwaves, infrared (IR), ultraviolet (UV), X-rays and gamma rays, as well as alpha-particle beams, proton beams, and neutron beams. beam) and a particle beam such as an electron beam.
  • the adhesive layers 321 and 322 may be formed by being applied to one surface of the protective substrate 321 and 322 or the polarizer 310 and then cured by irradiation of electromagnetic waves.
  • the term curing refers to a process of allowing the adhesive composition to exhibit adhesive properties through a physical action or a chemical reaction.
  • the curing of the adhesive composition may be performed through free radical polymerization or cationic reaction by irradiation of electromagnetic waves, and preferably, free radical polymerization and cationic reaction may be performed simultaneously or sequentially together.
  • the acrylic polymer may include a (meth)acrylic acid ester monomer.
  • the monomer may be included in the polymer as a polymerized unit.
  • that a monomer is included in a polymer as a polymerized unit may mean a state in which the monomer forms a skeleton, for example, a main chain or a side chain of the polymer through a polymerization reaction or the like.
  • an alkyl (meth)acrylate may be used as the (meth)acrylic acid ester monomer.
  • an alkyl (meth)acrylate having an alkyl group having 1 to 14 carbon atoms may be used in consideration of the cohesive strength of the adhesive and the glass transition temperature.
  • These monomers include methyl (meth)acrylate, ethyl (meth)acrylate, n-propyl (meth)acrylate, isopropyl (meth)acrylate, n-butyl (meth)acrylate, t-butyl (meth) Acrylate, sec-butyl (meth)acrylate, pentyl (meth)acrylate, 2-ethylhexyl (meth)acrylate, 2-ethylbutyl (meth)acrylate, n-octyl (meth)acrylate, isooctyl (Meth) acrylate, isononyl (meth) acrylate, lauryl (meth) acrylate, and tetradecyl (meth) acrylate, etc. may be exemplified, and a mixture of one or more types of the aforementioned monomers may be included in the polymer. I can.
  • the protective substrates 331 and 332 are films attached to protect the polarizer 310 and may be attached to the upper and lower portions of the polarizer 310 through adhesive layers 321 and 322, respectively.
  • a protective substrate for a polarizer known in this field such as a TAC sheet, may be used, but is not limited thereto.
  • the adhesive layers 321 and 322 may have a refractive index of 1.45 to 1.50.
  • the refractive index of the adhesive layers 321 and 322 may be 1.46 to 1.49 or 1.47 to 1.48. Since the adhesive layers 321 and 322 have a refractive index in the above-described range, the polarizer 310 and the refractive index are different and thus have a non-uniform thickness upon curing, and thus adhesive stains may be visually recognized.
  • the refractive index of the polarizer 310 may be greater than 1.5 to 1.6.
  • the refractive index of the polarizer 310 may be 1.51 to 1.57 or 1.52 to 1.54. Since the polarizer 310 has a refractive index in the above-described range, the adhesive layers 321 and 322 and the refractive index are different, so that the thickness is non-uniform when cured, so that adhesive stains may be visually recognized.
  • the light reflected from and emitted from the polarizing plate 300 may have a reflection angle of 45° to 75° with respect to the polarizing plate 300.
  • a reflection angle of light reflected from the polarizing plate 300 and emitted from the polarizing plate 300 may be 45° to 70°, 50° to 70°, or 55° to 65°.
  • the reflection angle of the light reflected and emitted from the polarizing plate 300 satisfies the above-described range, the light transmitted through the first polarizing member 200 and linearly polarized, does not pass through the polarizing plate 300 and the protective substrate 332 Except for the light reflected from, the light transmitted through the adhesive layer 322 of the polarizing plate 300 and reflected by the polarizer 310 may be absorbed by the second polarizing member 400, and thus, the polarizing plate (300) It is possible to inspect the adhesive stain of the adhesive layer 322 from the inside with excellent visibility.
  • the second polarizing member 400 is a part that transmits and/or absorbs light reflected from the polarizing plate 300 according to the presence or absence of adhesive stains on the polarizing plate 300, so that the light reflected from the polarizing plate 300 is applied. Is placed. Specifically, light applied by reflecting a portion of the polarizing plate 300 where adhesive stains exist may pass through the second polarizing member 400. Conversely, light applied by reflecting a portion of the polarizing plate 300 in which adhesive stains do not exist may be absorbed by the second polarizing member 400. As the light reflected from the polarizing plate is applied to the second polarizing member, the adhesive stain of the polarizing plate may be inspected.
  • the second polarizing member 400 may have an absorption axis perpendicular to the polarizer 310 of the polarizing plate 300. That is, the transmission axis of the second polarizing member 400 and the first polarizing member 200 may be parallel. Specifically, when the second polarizing member 400 has an absorption axis in the second direction (shown as ⁇ ), the polarizer 310 of the polarizing plate 300 may have an absorption axis in the first direction (shown as ⁇ ). In addition, the second polarizing member 400 and the polarizer 310 of the polarizing plate 300 may each have a transmission axis in a direction (not shown) orthogonal to an absorption axis.
  • the second polarizing member and the polarizer of the polarizing plate have an absorption axis perpendicular to each other, the light transmitted through the first polarizing member 200 and linearly polarized, does not pass through the polarizing plate 300 and is reflected from the protective substrate 332. Excluding light, light transmitted through the adhesive layer 322 of the polarizing plate 300 and reflected by the polarizer 310 may be absorbed by the second polarizing member 400, and thus, the polarizing plate 300 Adhesive stains of the adhesive layer 322 inside can be inspected with excellent visibility.
  • the inspector 500 is a part for determining the adhesive stain of the polarizing plate 300 based on the light transmitted through the second polarizing member 400, and the light transmitted through the second polarizing member 400 is applied. It is arranged as much as possible. Specifically, the light transmitted through the second polarizing member 400 may exhibit a reddish brown color, which may be determined as the presence of adhesive stains of the polarizing plate 300. In addition, the light that has not passed through the second polarizing member 400 may exhibit a dark color, which may be determined that there is no adhesive stain on the polarizing plate 300.
  • the inspector 500 may directly perform an adhesive stain inspection of the polarizing plate using the naked eye, and in another example, an image obtained by using an imager such as a video camera instead of the naked eye may be converted to a computer. Through this, it is possible to indirectly perform adhesive stain inspection on the polarizing plate.
  • the present application also relates to a method for inspecting adhesive stains on a polarizing plate.
  • An exemplary method for inspecting adhesive stains on a polarizing plate relates to a method for inspecting adhesive stains on a polarizing plate described above. Therefore, specific matters regarding the method for inspecting adhesive stains of a polarizing plate to be described later may be identically applied to the information described in the apparatus for inspecting adhesive stains of the polarizing plate, and thus will be omitted.
  • the method for inspecting adhesive stains on a polarizing plate of the present application includes transmitting and determining.
  • the adhesive stain inspection method of the polarizing plate of the present application it is possible to easily inspect the adhesive stain generated on the polarizing plate, and excellent visibility.
  • the transmitting step is a step of transmitting light using the adhesive stain inspection device of the polarizing plate described above, and the first polarizing member, the polarizing plate, and the second polarizing member are sequentially transmitted by emitting light from a point light source.
  • the point light source applies light to the polarizing plate at a Brewster angle. Details of the point light source, the first polarizing member, the polarizing plate, the second polarizing member, and the progress of light are the same as described above in the apparatus for inspecting adhesive stains of the polarizing plate, and thus will be omitted.
  • the determining step is a step of determining the adhesive stain of the polarizing plate, and the adhesive stain of the polarizing plate is determined based on the light transmitted through the second polarizing member and applied to the inspection source. That is, when light arrives from the point light source to the inspection source and shows reddish brown color, it is determined that adhesive stains exist on the polarizing plate, and when the light does not reach the inspection source from the point light source and shows a dark color, the polarizing plate It can be determined that there are no adhesive stains. Further, the detailed information on the progress of the inspector and the light is the same as described above in the apparatus for inspecting adhesive stains of the polarizing plate, and thus will be omitted.
  • light applied to the polarizing plate may be reflected.
  • light transmitted through the polarizer of the polarizing plate may be reflected by the adhesive layer of the polarizing plate. Since light is reflected from the polarizing plate, it is possible to inspect the adhesive stain of the polarizing plate. Details of the reflection of the light are the same as described above in the apparatus for inspecting adhesive stains of the polarizing plate, and thus will be omitted.
  • An apparatus for inspecting adhesive stains of a polarizing plate according to an exemplary embodiment of the present application an apparatus for inspecting adhesive stains of a polarizing plate according to an exemplary embodiment, an apparatus for inspecting adhesive stains of a polarizing plate according to another exemplary embodiment, and another exemplary embodiment.
  • an inspection was performed to see if adhesive stains on the polarizing plate were detected.
  • the apparatus for inspecting adhesive stains of a polarizing plate applies a point light source to a first polarizing member having a second direction ( ⁇ ) with an absorption axis at an angle of 58° to the polarizing plate to linearly polarize the polarized light,
  • the protective substrate of the polarizing plate, an adhesive layer including a photocurable adhesive, and an absorption axis were applied to a polarizer having a first direction ( ⁇ ). Thereafter, the applied light was reflected by the polarizer at a reflection angle of 58° to the polarizing plate.
  • FIG. 3 is an image photographed by a digital camera of a second polarizing member in order to inspect adhesive stains on a polarizing plate using the apparatus for inspecting adhesive stains on a polarizing plate according to an exemplary embodiment of the present application. As shown in Fig. 3, it was confirmed that reddish brown was clear. That is, when inspecting the adhesive stain of the polarizing plate using the adhesive stain inspection apparatus of the polarizing plate according to an embodiment of the present application, it was confirmed that the adhesive stain of the polarizing plate can be inspected with excellent visibility.
  • the adhesive stain inspection apparatus of the polarizing plate according to the embodiment of the present application does not include the first polarizing member, except that the adhesive of the polarizing plate in the same manner as the adhesive stain inspection apparatus of the polarizing plate according to the embodiment.
  • a stain test was performed, but it was confirmed that the adhesive stain of the polarizing plate was detected but the visibility was weak. It was confirmed that this is because it is difficult to remove p-polarized light at an angle other than around the exact Brewster angle when light is applied to the protective substrate included on the upper part of the polarizer.
  • FIG. 4 is an image photographed by a digital camera of a second polarizing member to inspect adhesive stains of a polarizing plate using an adhesive stain inspection apparatus of a polarizing plate according to an exemplary embodiment of the present application.
  • the apparatus for inspecting adhesive stains of a polarizing plate which is not according to another exemplary embodiment of the present application, inspects adhesive stains of the polarizing plate according to the above embodiment, except that the absorption axes of the first and second polarizing members are rotated by 90°
  • the adhesive stain test of the polarizing plate was performed in the same manner as the apparatus, but it was confirmed that the adhesive stain of the polarizing plate was detected but the visibility was weak.
  • Light transmitted through and reflected by the polarizer 310 may be absorbed by the second polarizing member 400, and thus, the adhesive stain of the adhesive layer 322 inside the polarizing plate 300 can be inspected with excellent visibility. I can.
  • FIG. 5 is an image photographed by a digital camera of a second polarizing member in order to inspect adhesive stains on a polarizing plate using an adhesive stain inspection apparatus for a polarizing plate according to another exemplary embodiment of the present application.
  • FIG. 6 is an image photographed by a digital camera of a second polarizing member in order to inspect adhesive stains on a polarizing plate using an adhesive stain inspection apparatus for a polarizing plate according to another embodiment of the present application.

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  • General Health & Medical Sciences (AREA)
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Abstract

The present application relates to an inspection device for adhesive stains on a polarizing plate, and an inspection method for adhesive stains on a polarizing plate. The present application enables easy inspection of adhesive stains occurring on a polarizing plate, with superior visibility.

Description

편광판의 접착제얼룩 검사장치 및 편광판의 접착제얼룩 검사방법Polarizing plate adhesive stain inspection device and polarizing plate adhesive stain inspection method
본 출원은 편광판의 접착제얼룩 검사장치 및 편광판의 접착제얼룩 검사방법에 관한 것이다.The present application relates to an apparatus for inspecting adhesive stains on a polarizing plate and a method for inspecting adhesive stains on a polarizing plate.
본 출원은 2019년 06월 07일자 한국 특허 출원 제10-2019- 0067544에 기초한 우선권의 이익을 주장하며, 해당 한국 특허 출원의 문헌에 개시된 모든 내용은 본 명세서의 일부로서 포함된다.This application claims the benefit of priority based on Korean Patent Application No. 10-2019-0067544 filed on June 07, 2019, and all contents disclosed in the documents of the Korean patent application are included as part of this specification.
액정표시소자(LCD, Liquid crystal display)는 광의 상태를 제어하기 위하여 편광판을 포함한다. 일반적으로 LCD에 사용되는 편광판은 접착제를 사용하여 편광 기능을 가지는 편광자와 상기 편광자의 상부 및 하부에 보호기재를 부착하여 제조된다.A liquid crystal display (LCD) includes a polarizing plate to control the state of light. In general, a polarizing plate used in an LCD is manufactured by attaching a polarizer having a polarizing function using an adhesive and a protective substrate on the upper and lower portions of the polarizer.
이때 사용되는 접착제의 종류로는 크게 열경화성 접착제 및 광경화성 접착제 2 가지 종류가 사용된다. 일반적인 수계 접착제는 PVA를 주성분으로 하며, 편광자와 굴절률이 같아 접착제의 두께 편차에 따른 얼룩이 발생하지 않는다.At this time, two types of adhesives are used, a thermosetting adhesive and a photocurable adhesive. A typical water-based adhesive is mainly composed of PVA, and has the same refractive index as that of the polarizer, so that stains due to thickness variation of the adhesive do not occur.
그러나, 광경화성 접착제는 PVA 편광자와 굴절률이 달라 두께가 불균일하게 경화될 경우, 얼룩이 시인되는 문제가 발생된다.However, when the photocurable adhesive has a different refractive index from that of the PVA polarizer and is cured in a non-uniform thickness, a problem of visible stains occurs.
이러한 광경화성 접착제얼룩은 시인성이 높지 않아 일반적인 검사방법으로는 확인이 어려우며, 편광판 완제품 상의 보호필름 및/또는 이형필름 부착 시 더욱 확인이 어렵다는 문제가 발생되었다. 따라서, 이러한 문제점을 해결하기 위한 편광판의 접착제얼룩 검사장치 및 편광판의 접착제얼룩 검사방법이 요구되고 있다.Such photocurable adhesive stains are not highly visible, and thus it is difficult to check with a general inspection method, and there is a problem that it is more difficult to check when attaching a protective film and/or a release film on a finished polarizing plate. Accordingly, there is a need for an apparatus for inspecting adhesive stains on a polarizing plate and a method for inspecting adhesive stains on a polarizing plate to solve this problem.
본 출원의 과제는 편광판에 발생되는 접착제얼룩을 용이하게 검사할 수 있고, 시인성이 우수한 편광판의 접착제얼룩 검사장치 및 편광판의 접착제얼룩 검사방법을 제공하는 것이다.An object of the present application is to provide an adhesive stain inspection apparatus for a polarizing plate and a method for inspecting adhesive stains on a polarizing plate, which can easily inspect adhesive stains generated on a polarizing plate and have excellent visibility.
상기 과제를 해결하기 위하여, 본 출원의 편광판의 접착제얼룩 검사장치는 점광원, 상기 점광원으로부터 광이 인가되도록 배치된 제 1 편광부재, 상기 제 1 편광부재를 투과한 광이 인가되도록 배치되어 상기 인가된 광을 반사하는 편광판, 상기 편광판으로부터 반사된 광이 인가되도록 배치된 제 2 편광부재, 및 상기 제 2 편광부재를 투과한 광이 인가되도록 배치되고, 상기 제 2 편광부재를 투과한 광에 기초하여 상기 편광판의 접착제얼룩을 판단하는 검사원을 포함하며, 상기 편광판은 편광자, 상기 편광자의 상부 및 하부 각각에 광경화성 접착제를 포함하는 접착제층, 및 보호기재를 순차로 포함하고, 상기 제 1 편광부재를 투과한 광은 상기 편광판의 보호기재로 인가되며, 상기 점광원은 상기 편광판에 대하여 브루스터 각(brewster angle)으로 광을 인가한다.In order to solve the above problems, the apparatus for inspecting adhesive stains of the polarizing plate of the present application includes a point light source, a first polarizing member disposed to apply light from the point light source, and the light transmitted through the first polarizing member. A polarizing plate reflecting the applied light, a second polarizing member disposed to apply light reflected from the polarizing plate, and a light transmitted through the second polarizing member are applied to the light transmitted through the second polarizing member. And an inspector for determining adhesive stains of the polarizing plate, wherein the polarizing plate sequentially includes a polarizer, an adhesive layer including a photocurable adhesive on top and bottom of the polarizer, and a protective material, and the first polarization The light transmitted through the member is applied to the protective substrate of the polarizing plate, and the point light source applies light at a Brewster angle to the polarizing plate.
또한, 상기 점광원은 상기 제 1 편광부재 측으로 무편광된 광을 방출할 수 있다.In addition, the point light source may emit unpolarized light toward the first polarizing member.
또한, 상기 점광원으로부터 방출되는 광은 상기 편광판에 대한 입사각이 45° 내지 75°일 수 있다.In addition, the light emitted from the point light source may have an incident angle of 45° to 75° to the polarizing plate.
또한, 상기 제 1 편광부재는 상기 편광판의 편광자와 흡수축이 수직일 수 있다.In addition, the first polarizing member may have a polarizer and an absorption axis of the polarizing plate perpendicular to each other.
또한, 상기 편광판은 액정표시장치용 편광판일 수 있다.In addition, the polarizing plate may be a polarizing plate for a liquid crystal display.
또한, 상기 편광판에 인가된 광은 상기 접착제층에서 반사될 수 있다.In addition, light applied to the polarizing plate may be reflected by the adhesive layer.
또한, 상기 광경화성 접착제는 아크릴 중합체를 포함하는 접착제 조성물을 경화된 상태로 포함할 수 있다.In addition, the photocurable adhesive may include an adhesive composition containing an acrylic polymer in a cured state.
또한, 상기 접착제층은 굴절률이 1.45 내지 1.50일 수 있다.In addition, the adhesive layer may have a refractive index of 1.45 to 1.50.
또한, 상기 편광자는 굴절률이 1.5 초과 내지 1.6일 수 있다.In addition, the polarizer may have a refractive index of greater than 1.5 to 1.6.
또한, 상기 편광판으로부터 반사되어 방출되는 광은 상기 편광판에 대한 반사각이 45° 내지 75°일 수 있다.In addition, the light reflected and emitted from the polarizing plate may have a reflection angle of 45° to 75° with respect to the polarizing plate.
또한, 상기 제 2 편광부재는 상기 편광판의 편광자와 흡수축이 수직일 수 있다.In addition, the second polarizing member may have a polarizer and an absorption axis of the polarizing plate perpendicular to each other.
또한, 본 출원의 편광판의 접착제얼룩 검사방법은 상기 편광판의 접착제얼룩 검사장치를 이용한 편광판의 접착제얼룩 검사방법에 관한 것으로, 점광원으로부터 광을 방출시켜 제 1 편광부재, 편광판, 제 2 편광부재를 순차로 투과시키는 단계, 및 상기 제 2 편광부재를 투과하여 상기 검사원에 인가되는 광에 기초하여 상기 편광판의 접착제얼룩을 판단하는 단계를 포함한다.In addition, the method for inspecting adhesive stains on a polarizing plate according to the present application relates to a method for inspecting adhesive stains on a polarizing plate using an adhesive stain inspection device for the polarizing plate. By emitting light from a point light source, the first polarizing member, the polarizing plate, and the second polarizing member are And sequentially transmitting, and determining an adhesive stain of the polarizing plate based on the light transmitted through the second polarizing member and applied to the inspection source.
또한, 상기 편광판에 인가된 광은 반사될 수 있다.In addition, light applied to the polarizing plate may be reflected.
본 출원의 편광판의 접착제얼룩 검사장치 및 편광판의 접착제얼룩 검사방법에 의하면, 편광판에 발생되는 접착제얼룩을 용이하게 검사할 수 있고, 시인성이 우수할 수 있다.According to the apparatus for inspecting adhesive stains on the polarizing plate and the method for inspecting adhesive stains on the polarizing plate of the present application, adhesive stains generated on the polarizing plate can be easily inspected and excellent visibility.
도 1은 본 출원의 일 실시예에 따른 편광판의 접착제얼룩 검사장치를 나타낸 도면이다.1 is a view showing an apparatus for inspecting adhesive stains of a polarizing plate according to an exemplary embodiment of the present application.
도 2는 본 출원의 일 실시예에 따른 편광판을 나타낸 도면이다.2 is a view showing a polarizing plate according to an embodiment of the present application.
도 3은 본 출원의 일 실시예에 따른 편광판의 접착제얼룩 검사장치를 이용하여 편광판의 접착제얼룩을 검사하기 위해 제 2 편광부재를 디지털카메라로 촬영한 이미지이다.FIG. 3 is an image photographed by a digital camera of a second polarizing member in order to inspect adhesive stains on a polarizing plate using the apparatus for inspecting adhesive stains on a polarizing plate according to an exemplary embodiment of the present application.
도 4는 본 출원의 일 실시예에 따르지 않는 편광판의 접착제얼룩 검사장치를 이용하여 편광판의 접착제얼룩을 검사하기 위해 제 2 편광부재를 디지털카메라로 촬영한 이미지이다.FIG. 4 is an image photographed by a digital camera of a second polarizing member in order to inspect adhesive stains on a polarizing plate using an adhesive stain inspection apparatus for a polarizing plate according to an exemplary embodiment of the present application.
도 5는 본 출원의 다른 일 실시예에 따르지 않는 편광판의 접착제얼룩 검사장치를 이용하여 편광판의 접착제얼룩을 검사하기 위해 제 2 편광부재를 디지털카메라로 촬영한 이미지이다. FIG. 5 is an image photographed by a digital camera of a second polarizing member in order to inspect adhesive stains on a polarizing plate using an adhesive stain inspection apparatus for a polarizing plate according to another exemplary embodiment of the present application.
도 6은 본 출원의 또 다른 일 실시예에 따르지 않는 편광판의 접착제얼룩 검사장치를 이용하여 편광판의 접착제얼룩을 검사하기 위해 제 2 편광부재를 디지털카메라로 촬영한 이미지이다.FIG. 6 is an image photographed by a digital camera of a second polarizing member in order to inspect adhesive stains on a polarizing plate using an adhesive stain inspection apparatus for a polarizing plate according to another embodiment of the present application.
이하, 첨부된 도면을 참조로 본 출원의 편광판의 접착제얼룩 검사장치 및 편광판의 접착제얼룩 검사방법을 설명하며, 첨부된 도면은 예시적인 것으로, 본 출원의 편광판의 접착제얼룩 검사장치 및 편광판의 검사방법이 첨부된 도면에 제한되는 것은 아니다.Hereinafter, an adhesive stain inspection apparatus for a polarizing plate and an adhesive stain inspection method for a polarizing plate of the present application will be described with reference to the accompanying drawings, and the accompanying drawings are illustrative, and an adhesive stain inspection apparatus and a polarizing plate inspection method of the present application It is not limited to the accompanying drawings.
도 1은 본 출원의 일 실시예에 따른 편광판의 접착제얼룩 검사장치를 나타낸 도면이다. 도 1에 나타낸 바와 같이, 본 출원의 편광판의 접착제얼룩 검사장치는 점광원(100), 제 1 편광부재(200), 편광판(300), 제 2 편광부재(400) 및 검사원(500)을 포함한다. 상기 점광원(100)은 상기 편광판(300)에 대하여 브루스터 각(brewster angle)으로 광을 인가한다. 도 2는 본 출원의 일 실시예에 따른 편광판을 나타낸 도면이다. 도 2에 나타낸 바와 같이, 상기 편광판(300)은 편광자(310), 상기 편광자(310)의 상부 및 하부 각각에 접착제층(321, 322), 및 보호기재(331, 332)를 순차로 포함한다. 또한, 상기 접착제층(321, 322)은 광경화성 접착제를 포함한다. 또한, 상기 제 1 편광부재(200)를 투과한 광은 상기 편광판(300)의 보호기재(331, 332)로 인가된다. 본 출원의 편광판의 접착제얼룩 검사장치는 편광판에 발생되는 접착제얼룩을 용이하게 검사할 수 있고, 시인성이 우수할 수 있다.1 is a view showing an apparatus for inspecting adhesive stains of a polarizing plate according to an exemplary embodiment of the present application. As shown in FIG. 1, the apparatus for inspecting adhesive stains of the polarizing plate of the present application includes a point light source 100, a first polarizing member 200, a polarizing plate 300, a second polarizing member 400, and an inspecting source 500. do. The point light source 100 applies light to the polarizing plate 300 at a Brewster angle. 2 is a view showing a polarizing plate according to an embodiment of the present application. As shown in FIG. 2, the polarizing plate 300 sequentially includes a polarizer 310, an adhesive layer 321, 322, and protective substrates 331, 332 on top and bottom of the polarizer 310, respectively. . In addition, the adhesive layers 321 and 322 include a photocurable adhesive. In addition, the light transmitted through the first polarizing member 200 is applied to the protective substrates 331 and 332 of the polarizing plate 300. The apparatus for inspecting adhesive stains of the polarizing plate of the present application may easily inspect adhesive stains generated on the polarizing plate and may have excellent visibility.
본 명세서에서 용어 「순차로 위치한다」는 각각의 구성이 직렬 구조로 평행하게 위치한 상태를 의미할 수 있다. 또한, 본 명세서에서 용어 「브루스터 각(brewster angle)」은 광이 굴절률이 다른 두 매질 사이를 지날 때, 어떤 편광 성분의 광만이 반사되고, 다른 편광 성분은 반사 없이 전부 투과하는 입사각을 의미한다. 예를 들어, 수직편광된 광(TE, s 편광)을 입사하면, 거의 모든 광은 반사가 일어난다. 그러나 수평편광된 광(TM. p 편광)을 입사하면, 반사가 거의 일어나지 않고 대부분 투과된다. 이 각도에서는 편광된 광의 전기장이 입사되는 평면과 나란하기 때문에 반사되지 않는 것이다. 즉, 수평편광된 광의 반사계수가 0이 되는 입사각이 존재하게 되는데, 이때, 이 각을 브루스터 각이라고 한다. 따라서 브루스터 각 근처로 입사할 때, 그 반사파는 평행편광 성분보다는 수직편광 성분이 월등히 많게 된다. 따라서 광이 브루스터각으로 입사되면, 반사된 빛은 항상 s 편광 상태가 된다.In the present specification, the term "located in sequence" may mean a state in which each component is located in parallel in a series structure. In addition, in the present specification, the term "brewster angle" refers to an incident angle through which only light of a certain polarization component is reflected and all other polarization components are transmitted without reflection when light passes between two media having different refractive indices. For example, when vertically polarized light (TE, s polarized light) is incident, almost all light is reflected. However, when horizontally polarized light (TM. p polarized light) is incident, reflection hardly occurs and most of it is transmitted. At this angle, the electric field of the polarized light is parallel to the incident plane, so it is not reflected. That is, there is an incident angle at which the reflection coefficient of horizontally polarized light becomes 0, and this angle is referred to as Brewster's angle. Therefore, when incident near Brewster's angle, the reflected wave has significantly more vertically polarized components than parallel polarized components. Therefore, when light is incident at Brewster's angle, the reflected light is always s-polarized.
상기 점광원(100)은 여러 방향으로 진동하는 무편광된 광을 방출하는 광원으로서, 다양한 백색광을 내거나 또는, 가시광선 영역의 스펙트럼 범위에서 연속적인 스펙트럼을 갖는 다양한 유형의 램프들을 사용할 수 있다. 상기 점광원으로 무편광된 광을 사용함으로써, 상기 편광판의 접착제얼룩 검사장치의 제작비 및 유지비가 저렴할 수 있다. 또한, 상기 점광원은 면광원에 비해 시인성 측면에서 더욱 유리할 수 있다.The point light source 100 is a light source that emits unpolarized light vibrating in various directions, and may emit various white light or use various types of lamps having a continuous spectrum in a spectral range of a visible light region. By using unpolarized light as the point light source, the manufacturing cost and maintenance cost of the apparatus for inspecting adhesive stains on the polarizing plate may be inexpensive. In addition, the point light source may be more advantageous in terms of visibility than the surface light source.
상기 점광원은 가상적으로 면적을 갖지 않고, 기하학적인 한 점으로 된 광원으로서, 면 형태의 면광원과 구별될 수 있다.The point light source virtually does not have an area and is a geometric one point light source, and can be distinguished from a surface light source in the form of a plane.
하나의 예시에서, 상기 점광원(100)은 상기 제 1 편광부재(200) 측으로 무편광된 광을 방출할 수 있다. 상기 무편광된 광이 방출된 점광원(100)은 상기 제 1 편광부재(200)를 투과하면서, 상기 제 1 편광부재(200)의 투과축과 평행한 방향으로 편광될 수 있다. In one example, the point light source 100 may emit unpolarized light toward the first polarizing member 200. The point light source 100 from which the unpolarized light is emitted may be polarized in a direction parallel to the transmission axis of the first polarizing member 200 while passing through the first polarizing member 200.
또한, 상기 점광원(100)은 광량을 조절할 수 있다. 예를 들어, 상기 점광원(100)은 광량을 높게 조절함으로써, 시인성을 향상시킬 수 있다.In addition, the point light source 100 may control the amount of light. For example, the point light source 100 may improve visibility by increasing the amount of light.
또한, 상기 점광원(100)으로부터 방출된 광은 입사각을 조절할 수 있다. 하나의 예시에서, 상기 점광원(100)으로부터 방출된 광은 상기 편광판(300)에 대한 입사각이 45° 내지 75°일 수 있다. 예를 들어, 상기 편광판(300)에 대한 상기 점광원(100)으로부터 방출된 광의 입사각은 45° 내지 70°, 50° 내지 70° 또는 55° 내지 65°일 수 있다. 이때, 상기 입사각은 상기 편광자(310)의 상부에 포함되는 보호기재(332)의 굴절률에 따라 특정할 수 있으며, 본 출원에서의 입사각은 굴절률이 1.6인 보호기재를 기준으로 한 각도이다. 상기 점광원으로부터 방출된 광의 입사각이 전술한 범위를 만족함으로써, 편광판에 발생되는 접착제얼룩을 용이하게 검사할 수 있고, 시인성이 우수할 수 있다.In addition, the incident angle of light emitted from the point light source 100 may be adjusted. In one example, the light emitted from the point light source 100 may have an incident angle of 45° to 75° to the polarizing plate 300. For example, an incident angle of light emitted from the point light source 100 to the polarizing plate 300 may be 45° to 70°, 50° to 70°, or 55° to 65°. In this case, the angle of incidence may be specified according to the refractive index of the protective substrate 332 included in the upper portion of the polarizer 310, and the incident angle in the present application is an angle based on the protective substrate having a refractive index of 1.6. When the incident angle of light emitted from the point light source satisfies the above-described range, adhesive stains generated on the polarizing plate can be easily inspected, and visibility can be excellent.
상기 제 1 편광부재(200)는 상기 점광원으로부터 방출된 광을 특정 방향으로 편광시키기 위한 부분으로, 상기 점광원으로부터 광이 인가되도록 배치될 수 있다.The first polarizing member 200 is a portion for polarizing light emitted from the point light source in a specific direction, and may be disposed so that light is applied from the point light source.
본 명세서에서 용어 「편광부재 및 편광자」는 어느 한쪽 방향으로 형성된 투과축을 가지면서 입사 광에 대하여 비등방성 투과 특성을 나타내는 기능성 층을 의미할 수 있다. 예를 들어, 편광부재 및 편광자는 여러 방향으로 진동하는 입사 광으로부터 어느 한쪽 방향으로 진동하는 광은 투과하고, 나머지 방향으로 진동하는 광은 반사 또는 흡수하여 차단하는 기능을 가질 수 있다. 이러한 편광자는 예를 들어, 반사형 편광자 또는 흡수형 편광자일 수 있으며, 본 출원의 제 1 편광부재, 제 2 편광부재 및 편광자는 흡수형 편광자일 수 있다.In the present specification, the term "polarizing member and polarizer" may mean a functional layer having a transmission axis formed in either direction and exhibiting anisotropic transmission characteristics with respect to incident light. For example, the polarizing member and the polarizer may have a function of transmitting light vibrating in one direction from incident light vibrating in various directions, and reflecting or absorbing light vibrating in the other direction. Such a polarizer may be, for example, a reflective polarizer or an absorption type polarizer, and the first polarizing member, the second polarizing member, and the polarizer of the present application may be absorption type polarizers.
본 명세서에서 용어 「흡수형 편광자」는 여러 방향으로 진동하는 입사 광으로부터 투과축과 평행한 방향을 가지는 광은 투과하고, 나머지 방향으로 진동하는 광은 흡수하여 차단하는 층을 의미할 수 있다. 하나의 예시에서, 흡수형 편광자는 면 방향으로 서로 직교하는 투과축 및 흡수축을 가질 수 있다. 예를 들면, 상기 투과축과 흡수축이 이루는 각도가 85° 내지 95° 또는 90°를 형성할 수 있고, 상기 투과축과 평행한 방향으로 진동하는 광은 투과할 수 있으며, 흡수축과 평행한 방향으로 진동하는 광은 반사 또는 흡수할 수 있다.In the present specification, the term “absorption polarizer” may refer to a layer that transmits light having a direction parallel to a transmission axis from incident light vibrating in various directions, and absorbs and blocks light vibrating in the other directions. In one example, the absorption type polarizer may have a transmission axis and an absorption axis orthogonal to each other in a plane direction. For example, the angle between the transmission axis and the absorption axis may form 85° to 95° or 90°, and light vibrating in a direction parallel to the transmission axis may be transmitted, and parallel to the absorption axis. Light vibrating in a direction can be reflected or absorbed.
본 명세서에서 각도를 정의하면서, 수직, 평행, 직교 또는 수평 등의 용어를 사용하는 경우, 이는 목적하는 효과를 손상시키지 않는 범위에서의 실질적인 수직, 평행, 직교 또는 수평을 의미하는 것으로, 예를 들면, 제조 오차(error) 또는 편차(variation) 등을 감안한 오차를 포함하는 것이다. 예를 들면, 상기 각각의 경우는, 약 ±15° 이내의 오차, 약 ±10° 이내의 오차 또는 약 ±5° 이내의 오차를 포함할 수 있다.In the present specification, when the term such as vertical, parallel, orthogonal or horizontal is used while defining an angle, it means substantially vertical, parallel, orthogonal or horizontal within a range that does not impair the desired effect, for example , Manufacturing errors or variations are included. For example, in each of the above cases, an error within about ±15°, an error within about ±10°, or an error within about ±5° may be included.
상기 흡수형 편광자로는 이 분야에서 공지되어 있는 통상적인 흡수형 편광자를 사용할 수 있다. 예를 들어, 상기 흡수형 편광자로는 요오드 화합물 또는 유기 염료로 염색된 연신된 중합체막, 예를 들면, 폴리비닐알코올(PVA) 필름 등을 사용할 수 있다. 이러한 흡수형 편광자는 통상적으로 투과축 및 상기 투과축에 직교하는 흡수축을 가질 수 있다.As the absorption type polarizer, a conventional absorption type polarizer known in the art may be used. For example, as the absorption polarizer, a stretched polymer film dyed with an iodine compound or an organic dye, for example, a polyvinyl alcohol (PVA) film may be used. Such an absorption type polarizer may typically have a transmission axis and an absorption axis orthogonal to the transmission axis.
하나의 예시에서, 상기 제 1 편광부재(200)는 상기 편광판(300)의 편광자(310)와 흡수축이 수직일 수 있다. 구체적으로, 상기 제 1 편광부재(200)가 제 2 방향(↕로 도시)으로 흡수축을 가질 경우, 상기 편광판(300)의 편광자(310)는 상기 제 1 편광부재(200)의 흡수축과 수직하는 제 1 방향(↔로 도시)으로 흡수축을 가질 수 있고, 상기 제 1 편광부재(200) 및 편광판(300)의 편광자(310)는 각각 흡수축과 직교하는 방향(미도시)으로 투과축을 가질 수 있다. 상기 제 1 편광부재 및 편광판의 편광자는 흡수축을 수직하게 가짐으로써, 상기 제 1 편광부재를 거쳐 제 1 방향(↔로 도시)으로 선편광된 광이 상기 편광판의 편광자의 투과축과 수직하게 정렬되므로, 상기 편광판의 편광자에 의해 반사될 수 있다. 이에 반해, 상기 제 1 편광부재와 상기 편광판의 편광자의 흡수축이 수직이 아닐 경우, 상기 제 1 편광부재를 거쳐 제 1 방향(↔로 도시)으로 선편광된 광이 상기 편광판의 편광자의 투과축과 수직하게 정렬되지 않으므로, 상기 편광판의 편광자를 투과할 수 있다. 상기 선편광된 광이 상기 편광판의 편광자를 투과하여 하부 보호기재에서 반사가 일어나며, 이 때 상기 편광판이 위치하는 바닥, 즉, 검사부의 표면이 어두운 색을 나타내지 않으면 접착제 얼룩을 시인하는 것이 불가능하다는 단점이 있다.In one example, the first polarizing member 200 may have an absorption axis perpendicular to the polarizer 310 of the polarizing plate 300. Specifically, when the first polarizing member 200 has an absorption axis in the second direction (shown by ↕), the polarizer 310 of the polarizing plate 300 is perpendicular to the absorption axis of the first polarizing member 200 The first polarizing member 200 and the polarizer 310 of the polarizing plate 300 may each have a transmission axis in a direction (not shown) orthogonal to the absorption axis. I can. Since the first polarizing member and the polarizer of the polarizing plate have an absorption axis perpendicular to each other, the light linearly polarized in the first direction (shown as ↔) through the first polarizing member is vertically aligned with the transmission axis of the polarizer of the polarizing plate, It may be reflected by the polarizer of the polarizing plate. On the other hand, when the absorption axis of the polarizer of the first polarizing member and the polarizing plate is not perpendicular, the light linearly polarized in the first direction (shown as ↔) through the first polarizing member is transmitted to the transmission axis of the polarizer of the polarizing plate. Since it is not vertically aligned, the polarizer of the polarizing plate may be transmitted. The linearly polarized light transmits through the polarizer of the polarizing plate and is reflected from the lower protective substrate. At this time, the disadvantage that it is impossible to visually recognize the adhesive stains unless the bottom where the polarizing plate is located, that is, the surface of the inspection unit, shows a dark color. have.
상기 편광판(300)은 접착제얼룩을 검사하기 위한 측정 대상이 되는 샘플로서, 검사부(미도시)에 포함될 수 있다. 예를 들어, 상기 편광판(300)은 검사부 상에 배치될 수 있다.The polarizing plate 300 is a sample to be measured for inspecting adhesive stains and may be included in an inspection unit (not shown). For example, the polarizing plate 300 may be disposed on the inspection unit.
상기 편광판(300)은 상기 제 1 편광부재(200)를 투과한 광이 인가되도록 배치되어 상기 인과된 광을 반사한다. 구체적으로, 상기 편광판(300)에 인가된 광은 상기 편광판(300)의 편광자(310)의 상부에 형성된 접착제층(322)을 투과하고, 상기 편광판(300)의 편광자(310)에서 반사될 수 있다. 상기 접착제층(322)을 투과하고, 상기 편광자(310)에서 광의 반사가 일어남으로써, 편광판의 접착제얼룩을 검사할 수 있다.The polarizing plate 300 is disposed so that the light transmitted through the first polarizing member 200 is applied to reflect the caused light. Specifically, the light applied to the polarizing plate 300 may pass through the adhesive layer 322 formed on the polarizer 310 of the polarizing plate 300 and be reflected by the polarizer 310 of the polarizing plate 300. have. By transmitting the adhesive layer 322 and reflecting light from the polarizer 310, it is possible to inspect adhesive stains on the polarizing plate.
하나의 예시에서, 상기 편광판(300)은 액정표시장치용 편광판일 수 있다. 구체적으로, 액정표시장치는 두장의 편광판 사이에 액정을 이용하여 광의 진행 방향을 바꾸거나 빛의 세기를 조절하는 투과형 표시장치로서, 상기 편광판에 선편광된 광을 만드는 편광자를 포함하나 1/4 파장판을 필요로 하지 않는다. 그러나, 유기발광표시장치는 전극의 노출로 인해 태양광, 조명 등의 외광 반사에 취약하다는 단점이 있어, 전원 OFF 상태에서 표면의 외광 반사를 차단하고 어두운 시감을 갖기 위하여 편광판에 선편광된 광을 만들기 위한 편광자와 원편광된 광을 만들기 위한 1/4 파장판을 포함할 수 있다. In one example, the polarizing plate 300 may be a polarizing plate for a liquid crystal display. Specifically, a liquid crystal display device is a transmission type display device that changes the direction of light or adjusts the intensity of light by using a liquid crystal between two polarizing plates, and includes a polarizer that generates light linearly polarized on the polarizing plate, but a quarter wave plate Do not need. However, the organic light emitting display device has a disadvantage in that it is vulnerable to reflection of external light such as sunlight and lighting due to the exposure of the electrode, so it blocks the reflection of external light from the surface when the power is off, and makes linearly polarized light on the polarizing plate to have a dark sense of view. It may include a polarizer for and a quarter wave plate for making circularly polarized light.
상기 광경화성 접착제는 아크릴 중합체를 포함하는 접착제 조성물을 경화된 상태로 포함할 수 있다. 본 명세서에서 용어 「광경화성 접착제」는 전자기파의 조사에 의하여 경화될 수 있는 접착제를 의미한다. 상기에서 전자기파의 범주에는 마이크로파(microwaves), 적외선(IR), 자외선(UV), X선 및 감마선은 물론, 알파-입자선(alpha-particle beam), 프로톤빔(proton beam), 뉴트론빔(neutron beam) 및 전자선(electron beam)과 같은 입자빔 등이 포함될 수 있다. 상기 접착제층(321, 322)은 상기 보호기재(321, 322) 또는 상기 편광자(310)의 일면에 도포된 후, 전자기파의 조사에 의해 경화시켜 형성할 수 있다. 상기에서 용어 경화는 물리적 작용 또는 화학적 반응에 의하여 접착제 조성물이 접착 특성을 발현할 수 있도록 하는 과정을 의미한다. 하나의 예시에서 상기 접착제 조성물의 경화는 전자기파의 조사에 의한 자유 라디칼 중합 또는 양이온 반응을 통하여 수행될 수 있고, 바람직하게는 자유 라디칼 중합 및 양이온 반응이 동시 또는 순차로 함께 진행되어 수행할 수 있다.The photocurable adhesive may include an adhesive composition containing an acrylic polymer in a cured state. In the present specification, the term "photocurable adhesive" refers to an adhesive that can be cured by irradiation of electromagnetic waves. In the above, the categories of electromagnetic waves include microwaves, infrared (IR), ultraviolet (UV), X-rays and gamma rays, as well as alpha-particle beams, proton beams, and neutron beams. beam) and a particle beam such as an electron beam. The adhesive layers 321 and 322 may be formed by being applied to one surface of the protective substrate 321 and 322 or the polarizer 310 and then cured by irradiation of electromagnetic waves. In the above, the term curing refers to a process of allowing the adhesive composition to exhibit adhesive properties through a physical action or a chemical reaction. In one example, the curing of the adhesive composition may be performed through free radical polymerization or cationic reaction by irradiation of electromagnetic waves, and preferably, free radical polymerization and cationic reaction may be performed simultaneously or sequentially together.
상기 아크릴 중합체로는 (메타)아크릴산 에스테르 단량체를 포함할 수 있다. 상기 단량체는 중합체에 중합 단위로 포함될 수 있다. 본 명세서에서 단량체가 중합 단위로 중합체에 포함된다는 것은, 그 단량체가 중합 반응 등을 거쳐서 그 중합체의 골격, 예를 들면, 주쇄 또는 측쇄를 형성하고 있는 상태를 의미할 수 있다. 상기 (메타)아크릴산 에스테르 단량체로는 예를 들면, 알킬 (메타)아크릴레이트를 사용할 수 있다. 예를 들면, 접착제의 응집력이나 유리전이온도 등을 고려하여 탄소수 1 내지 14의 알킬기를 가지는 알킬 (메타)아크릴레이트를 사용할 수 있다. 이러한 단량체로는 메틸 (메타)아크릴레이트, 에틸 (메타)아크릴레이트, n-프로필 (메타)아크릴레이트, 이소프로필 (메타)아크릴레이트, n-부틸 (메타)아크릴레이트, t-부틸 (메타)아크릴레이트, sec-부틸 (메타)아크릴레이트, 펜틸 (메타)아크릴레이트, 2-에틸헥실 (메타)아크릴레이트, 2-에틸부틸 (메타)아크릴레이트, n-옥틸 (메타)아크릴레이트, 이소옥틸 (메타)아크릴레이트, 이소노닐 (메타)아크릴레이트, 라우릴 (메타)아크릴레이트 및 테트라데실 (메타)아크릴레이트 등이 예시될 수 있고, 상기 전술한 단량체 중 일종 또는 이종 이상의 혼합이 중합체에 포함될 수 있다.The acrylic polymer may include a (meth)acrylic acid ester monomer. The monomer may be included in the polymer as a polymerized unit. In the present specification, that a monomer is included in a polymer as a polymerized unit may mean a state in which the monomer forms a skeleton, for example, a main chain or a side chain of the polymer through a polymerization reaction or the like. As the (meth)acrylic acid ester monomer, for example, an alkyl (meth)acrylate may be used. For example, an alkyl (meth)acrylate having an alkyl group having 1 to 14 carbon atoms may be used in consideration of the cohesive strength of the adhesive and the glass transition temperature. These monomers include methyl (meth)acrylate, ethyl (meth)acrylate, n-propyl (meth)acrylate, isopropyl (meth)acrylate, n-butyl (meth)acrylate, t-butyl (meth) Acrylate, sec-butyl (meth)acrylate, pentyl (meth)acrylate, 2-ethylhexyl (meth)acrylate, 2-ethylbutyl (meth)acrylate, n-octyl (meth)acrylate, isooctyl (Meth) acrylate, isononyl (meth) acrylate, lauryl (meth) acrylate, and tetradecyl (meth) acrylate, etc. may be exemplified, and a mixture of one or more types of the aforementioned monomers may be included in the polymer. I can.
또한, 상기 보호기재(331, 332)는 상기 편광자(310)를 보호하기 위하여 부착되는 필름으로서, 상기 편광자(310)의 상부 및 하부에 각각 접착제층(321, 322)을 통하여 부착될 수 있다. 상기 보호기재(331, 332)로는 TAC 시트와 같이 이 분야에서 공지되어 있는 편광자용 보호기재를 사용할 수 있으나, 이에 제한되는 것은 아니다.In addition, the protective substrates 331 and 332 are films attached to protect the polarizer 310 and may be attached to the upper and lower portions of the polarizer 310 through adhesive layers 321 and 322, respectively. As the protective substrates 331 and 332, a protective substrate for a polarizer known in this field, such as a TAC sheet, may be used, but is not limited thereto.
하나의 예시에서, 상기 접착제층(321, 322)은 굴절률이 1.45 내지 1.50일 수 있다. 예를 들어, 상기 접착제층(321, 322)의 굴절률은 1.46 내지 1.49 또는 1.47 내지 1.48일 수 있다. 상기 접착제층(321, 322)은 전술한 범위의 굴절률을 가짐으로써, 상기 편광자(310)와 굴절률이 상이하여 경화 시 두께가 불균일하며, 이로 인해 접착제얼룩이 시인될 수 있다.In one example, the adhesive layers 321 and 322 may have a refractive index of 1.45 to 1.50. For example, the refractive index of the adhesive layers 321 and 322 may be 1.46 to 1.49 or 1.47 to 1.48. Since the adhesive layers 321 and 322 have a refractive index in the above-described range, the polarizer 310 and the refractive index are different and thus have a non-uniform thickness upon curing, and thus adhesive stains may be visually recognized.
상기 편광자(310)의 굴절률은 1.5 초과 내지 1.6일 수 있다. 예를 들어, 상기 편광자(310)의 굴절률은 1.51 내지 1.57 또는 1.52 내지 1.54일 수 있다. 상기 편광자(310)는 전술한 범위의 굴절률을 가짐으로써, 상기 접착제층(321, 322)과 굴절률이 상이하여 경화 시 두께가 불균일하며, 이로 인해 접착제얼룩이 시인될 수 있다.The refractive index of the polarizer 310 may be greater than 1.5 to 1.6. For example, the refractive index of the polarizer 310 may be 1.51 to 1.57 or 1.52 to 1.54. Since the polarizer 310 has a refractive index in the above-described range, the adhesive layers 321 and 322 and the refractive index are different, so that the thickness is non-uniform when cured, so that adhesive stains may be visually recognized.
상기 편광판(300)으로부터 반사되어 방출되는 광은 상기 편광판(300)에 대한 반사각이 45° 내지 75°일 수 있다. 예를 들어, 상기 편광판(300)에 대한 상기 편광판(300)으로부터 반사되어 방출되는 광의 반사각은 45° 내지 70°, 50° 내지 70° 또는 55° 내지 65°일 수 있다. 상기 편광판(300)으로부터 반사되어 방출되는 광의 반사각이 전술한 범위를 만족함으로써, 상기 제 1 편광부재(200)를 투과하여 선편광된 광에서, 상기 편광판(300)을 투과하지 못하고 보호기재(332)에서 반사된 광을 제외하고, 상기 편광판(300)의 접착제층(322)을 투과하여 편광자(310)에 의해 반사된 광이 제 2 편광부재(400)에 의해 흡수될 수 있고, 이로 인해, 편광판(300) 내부에서 접착제층(322)의 접착제얼룩을 우수한 시인성으로 검사할 수 있다.The light reflected from and emitted from the polarizing plate 300 may have a reflection angle of 45° to 75° with respect to the polarizing plate 300. For example, a reflection angle of light reflected from the polarizing plate 300 and emitted from the polarizing plate 300 may be 45° to 70°, 50° to 70°, or 55° to 65°. Since the reflection angle of the light reflected and emitted from the polarizing plate 300 satisfies the above-described range, the light transmitted through the first polarizing member 200 and linearly polarized, does not pass through the polarizing plate 300 and the protective substrate 332 Except for the light reflected from, the light transmitted through the adhesive layer 322 of the polarizing plate 300 and reflected by the polarizer 310 may be absorbed by the second polarizing member 400, and thus, the polarizing plate (300) It is possible to inspect the adhesive stain of the adhesive layer 322 from the inside with excellent visibility.
상기 제 2 편광부재(400)는 편광판(300)의 접착제얼룩 유무에 따라 상기 편광판(300)으로부터 반사된 광을 투과 및/또는 흡수하는 부분으로, 상기 편광판(300)으로부터 반사된 광이 인가되도록 배치된다. 구체적으로, 상기 편광판(300) 내에 접착제얼룩이 존재하는 부분을 반사하여 인가된 광은 제 2 편광부재(400)를 투과할 수 있다. 이와 반대로, 상기 편광판(300) 내에 접착제얼룩이 존재하지 않는 부분을 반사하여 인가된 광은 제 2 편광부재(400)에 흡수될 수 있다. 상기 편광판으로부터 반사된 광이 상기 제 2 편광부재에 인가됨으로써, 편광판의 접착제얼룩을 검사할 수 있다.The second polarizing member 400 is a part that transmits and/or absorbs light reflected from the polarizing plate 300 according to the presence or absence of adhesive stains on the polarizing plate 300, so that the light reflected from the polarizing plate 300 is applied. Is placed. Specifically, light applied by reflecting a portion of the polarizing plate 300 where adhesive stains exist may pass through the second polarizing member 400. Conversely, light applied by reflecting a portion of the polarizing plate 300 in which adhesive stains do not exist may be absorbed by the second polarizing member 400. As the light reflected from the polarizing plate is applied to the second polarizing member, the adhesive stain of the polarizing plate may be inspected.
하나의 예시에서, 상기 제 2 편광부재(400)는 상기 편광판(300)의 편광자(310)와 흡수축이 수직일 수 있다. 즉, 상기 제 2 편광부재(400)는 상기 제 1 편광부재(200)와도 투과축이 평행할 수 있다. 구체적으로, 상기 제 2 편광부재(400)가 제 2 방향(↕로 도시)으로 흡수축을 가질 경우, 상기 편광판(300)의 편광자(310)는 제 1 방향(↔로 도시)으로 흡수축을 가질 수 있고, 상기 제 2 편광부재(400) 및 편광판(300)의 편광자(310)는 각각 흡수축과 직교하는 방향(미도시)으로 투과축을 가질 수 있다. 상기 제 2 편광부재 및 편광판의 편광자는 흡수축을 수직하게 가짐으로써, 상기 제 1 편광부재(200)를 투과하여 선편광된 광에서, 상기 편광판(300)을 투과하지 못하고 보호기재(332)에서 반사된 광을 제외하고, 상기 편광판(300)의 접착제층(322)을 투과하여 편광자(310)에 의해 반사된 광이 제 2 편광부재(400)에 의해 흡수될 수 있고, 이로 인해, 편광판(300) 내부에서 접착제층(322)의 접착제얼룩을 우수한 시인성으로 검사할 수 있다. In one example, the second polarizing member 400 may have an absorption axis perpendicular to the polarizer 310 of the polarizing plate 300. That is, the transmission axis of the second polarizing member 400 and the first polarizing member 200 may be parallel. Specifically, when the second polarizing member 400 has an absorption axis in the second direction (shown as ↕), the polarizer 310 of the polarizing plate 300 may have an absorption axis in the first direction (shown as ↔). In addition, the second polarizing member 400 and the polarizer 310 of the polarizing plate 300 may each have a transmission axis in a direction (not shown) orthogonal to an absorption axis. Since the second polarizing member and the polarizer of the polarizing plate have an absorption axis perpendicular to each other, the light transmitted through the first polarizing member 200 and linearly polarized, does not pass through the polarizing plate 300 and is reflected from the protective substrate 332. Excluding light, light transmitted through the adhesive layer 322 of the polarizing plate 300 and reflected by the polarizer 310 may be absorbed by the second polarizing member 400, and thus, the polarizing plate 300 Adhesive stains of the adhesive layer 322 inside can be inspected with excellent visibility.
상기 검사원(500)은 상기 제 2 편광부재(400)를 투과한 광에 기초하여 상기 편광판(300)의 접착제얼룩을 판단하기 위한 부분으로, 상기 제 2 편광부재(400)를 투과한 광이 인가되도록 배치된다. 구체적으로, 제 2 편광부재(400)를 투과한 광은 적갈색을 나타낼 수 있고, 이는 편광판(300)의 접착제얼룩이 존재하는 것으로 판단할 수 있다. 또한, 제 2 편광부재(400)를 투과하지 못한 광은 어두운색을 나타낼 수 있고, 이는 편광판(300)에 접착제얼룩이 존재하지 않는 것으로 판단할 수 있다.The inspector 500 is a part for determining the adhesive stain of the polarizing plate 300 based on the light transmitted through the second polarizing member 400, and the light transmitted through the second polarizing member 400 is applied. It is arranged as much as possible. Specifically, the light transmitted through the second polarizing member 400 may exhibit a reddish brown color, which may be determined as the presence of adhesive stains of the polarizing plate 300. In addition, the light that has not passed through the second polarizing member 400 may exhibit a dark color, which may be determined that there is no adhesive stain on the polarizing plate 300.
하나의 예시에서, 상기 검사원(500)에서는 육안을 이용하여 직접적으로 편광판의 접착제얼룩 검사를 수행할 수 있고, 또 하나의 예시에서, 육안을 대신해 비디오 카메라 등의 촬상기를 이용하여 얻어진 화상을 컴퓨터를 통해 간접적으로 편광판의 접착제얼룩 검사를 수행할 수 있다.In one example, the inspector 500 may directly perform an adhesive stain inspection of the polarizing plate using the naked eye, and in another example, an image obtained by using an imager such as a video camera instead of the naked eye may be converted to a computer. Through this, it is possible to indirectly perform adhesive stain inspection on the polarizing plate.
본 출원은 또한, 편광판의 접착제얼룩 검사방법에 관한 것이다. 예시적인 편광판의 접착제얼룩 검사방법은, 전술한 편광판의 접착제얼룩 검사장치를 이용한 검사방법에 관한 것이다. 따라서, 후술하는 편광판의 접착제얼룩 검사방법에 관한 구체적인 사항은 상기 편광판의 접착제얼룩 검사장치에서 기술한 내용이 동일하게 적용될 수 있으므로, 생략하기로 한다.The present application also relates to a method for inspecting adhesive stains on a polarizing plate. An exemplary method for inspecting adhesive stains on a polarizing plate relates to a method for inspecting adhesive stains on a polarizing plate described above. Therefore, specific matters regarding the method for inspecting adhesive stains of a polarizing plate to be described later may be identically applied to the information described in the apparatus for inspecting adhesive stains of the polarizing plate, and thus will be omitted.
본 출원의 편광판의 접착제얼룩 검사방법은 투과시키는 단계 및 판단하는 단계를 포함한다. 본 출원의 편광판의 접착제얼룩 검사방법을 사용함으로써, 편광판에 발생되는 접착제얼룩을 용이하게 검사할 수 있고, 시인성이 우수할 수 있다.The method for inspecting adhesive stains on a polarizing plate of the present application includes transmitting and determining. By using the adhesive stain inspection method of the polarizing plate of the present application, it is possible to easily inspect the adhesive stain generated on the polarizing plate, and excellent visibility.
상기 투과시키는 단계는 전술한 편광판의 접착제얼룩 검사장치를 이용하여 광을 투과시키는 단계로서, 점광원으로부터 광을 방출하여 제 1 편광부재, 편광판, 제 2 편광부재를 순차로 투과시킨다. 이때, 상기 점광원은 편광판에 대하여 브루스터 각(brewster angle)으로 광을 인가한다. 상기 점광원, 제 1 편광부재, 편광판, 제 2 편광부재 및 광의 진행에 대한 구체적인 내용은 상기 편광판의 접착제얼룩 검사장치에서 전술한 바와 동일하므로 생략하기로 한다.The transmitting step is a step of transmitting light using the adhesive stain inspection device of the polarizing plate described above, and the first polarizing member, the polarizing plate, and the second polarizing member are sequentially transmitted by emitting light from a point light source. At this time, the point light source applies light to the polarizing plate at a Brewster angle. Details of the point light source, the first polarizing member, the polarizing plate, the second polarizing member, and the progress of light are the same as described above in the apparatus for inspecting adhesive stains of the polarizing plate, and thus will be omitted.
상기 판단하는 단계는 상기 편광판의 접착제얼룩을 판단하기 위한 단계로서, 상기 제 2 편광부재를 투과하여 상기 검사원에 인가되는 광에 기초하여 상기 편광판의 접착제얼룩을 판단한다. 즉, 상기 점광원으로부터 상기 검사원으로 광이 도달하여 적갈색을 나타내는 경우, 상기 편광판에 접착제얼룩이 존재하는 것으로 판단하고, 상기 점광원으로부터 상기 검사원으로 광이 도달하지 않아 어두운색을 나타내는 경우, 상기 편광판에 접착제얼룩이 존재하지 않는 것으로 판단할 수 있다. 또한, 상기 검사원 및 광의 진행에 대한 구체적인 내용은 상기 편광판의 접착제얼룩 검사장치에서 전술한 바와 동일하므로 생략하기로 한다.The determining step is a step of determining the adhesive stain of the polarizing plate, and the adhesive stain of the polarizing plate is determined based on the light transmitted through the second polarizing member and applied to the inspection source. That is, when light arrives from the point light source to the inspection source and shows reddish brown color, it is determined that adhesive stains exist on the polarizing plate, and when the light does not reach the inspection source from the point light source and shows a dark color, the polarizing plate It can be determined that there are no adhesive stains. Further, the detailed information on the progress of the inspector and the light is the same as described above in the apparatus for inspecting adhesive stains of the polarizing plate, and thus will be omitted.
하나의 예시에서, 상기 편광판에 인가된 광은 반사될 수 있다. 구체적으로, 상기 편광판의 편광자를 투과한 광이 상기 편광판의 접착제층에 의해 반사될 수 있다. 상기 편광판에서 광의 반사가 일어남으로써, 편광판의 접착제얼룩을 검사할 수 있다. 상기 광의 반사에 대한 구체적인 내용은 상기 편광판의 접착제얼룩 검사장치에서 전술한 바와 동일하므로 생략하기로 한다.In one example, light applied to the polarizing plate may be reflected. Specifically, light transmitted through the polarizer of the polarizing plate may be reflected by the adhesive layer of the polarizing plate. Since light is reflected from the polarizing plate, it is possible to inspect the adhesive stain of the polarizing plate. Details of the reflection of the light are the same as described above in the apparatus for inspecting adhesive stains of the polarizing plate, and thus will be omitted.
본 출원의 일 실시예에 따른 편광판의 접착제얼룩 검사장치, 일 실시예에 따르지 않는 따른 편광판의 접착제얼룩 검사장치, 다른 일 실시예에 따르지 않는 따른 편광판의 접착제얼룩 검사장치 및 또 다른 일 실시예에 따르지 않는 따른 편광판의 접착제얼룩 검사장치를 이용하여, 편광판의 접착제얼룩이 검출되는지 검사를 수행하였다.An apparatus for inspecting adhesive stains of a polarizing plate according to an exemplary embodiment of the present application, an apparatus for inspecting adhesive stains of a polarizing plate according to an exemplary embodiment, an apparatus for inspecting adhesive stains of a polarizing plate according to another exemplary embodiment, and another exemplary embodiment. Using a non-conforming adhesive stain inspection device on the polarizing plate, an inspection was performed to see if adhesive stains on the polarizing plate were detected.
본 출원의 일 실시예에 따른 편광판의 접착제얼룩 검사장치는 점광원을 편광판에 대한 입사각 58°로 흡수축이 제 2 방향(↕)을 갖는 제 1 편광부재에 인가하여 선편광시키고, 선편광된 광을 편광판의 보호기재, 광경화성 접착제를 포함하는 접착제층 및 흡수축이 제 1 방향(↔)을 갖는 편광자에 인가시켰다. 이후, 상기 인가된 광은 상기 편광자에서 편광판에 대한 반사각 58˚로 반사되었다. 이후, 상기 반사된 광을 상기 편광판의 접착제층과 보호기재, 및 흡수축이 제 2 방향(↕)을 갖는 제 2 편광부재에 인가하여 투과시킴으로써, 검사원에서 검사된 광을 통해 편광판의 접착제얼룩이 검출되는 것을 확인하였다. 도 3은 본 출원의 일 실시예에 따른 편광판의 접착제얼룩 검사장치를 이용하여 편광판의 접착제얼룩을 검사하기 위해 제 2 편광부재를 디지털카메라로 촬영한 이미지이다. 도 3에 나타낸 바와 같이, 적갈색이 선명하다는 것을 확인하였다. 즉, 본 출원의 일 실시예에 따른 편광판의 접착제얼룩 검사장치를 이용하여 편광판의 접착제얼룩을 검사하는 경우, 우수한 시인성으로 편광판의 접착제얼룩의 검사가 가능하다는 것을 확인하였다.The apparatus for inspecting adhesive stains of a polarizing plate according to an exemplary embodiment of the present application applies a point light source to a first polarizing member having a second direction (↕) with an absorption axis at an angle of 58° to the polarizing plate to linearly polarize the polarized light, The protective substrate of the polarizing plate, an adhesive layer including a photocurable adhesive, and an absorption axis were applied to a polarizer having a first direction (↔). Thereafter, the applied light was reflected by the polarizer at a reflection angle of 58° to the polarizing plate. Thereafter, by applying the reflected light to the adhesive layer of the polarizing plate, the protective substrate, and the second polarizing member having the absorption axis in the second direction (↕) and transmitting it, adhesive stains of the polarizing plate are detected through the light inspected by the inspector. It was confirmed to be. FIG. 3 is an image photographed by a digital camera of a second polarizing member in order to inspect adhesive stains on a polarizing plate using the apparatus for inspecting adhesive stains on a polarizing plate according to an exemplary embodiment of the present application. As shown in Fig. 3, it was confirmed that reddish brown was clear. That is, when inspecting the adhesive stain of the polarizing plate using the adhesive stain inspection apparatus of the polarizing plate according to an embodiment of the present application, it was confirmed that the adhesive stain of the polarizing plate can be inspected with excellent visibility.
또한, 본 출원의 일 실시예에 따르지 않는 따른 편광판의 접착제얼룩 검사장치는 제 1 편광부재를 포함하지 않는 것을 제외하고, 상기 일 실시예에 따른 편광판의 접착제얼룩 검사장치와 동일한 방법으로 편광판의 접착제얼룩 검사를 수행하였으나, 편광판의 접착제 얼룩이 검출되긴 하나 시인성이 약한 것을 확인하였다. 이는 편광자의 상부에 포함된 보호기재에 광이 인가될 때, 정확한 브루스터 각 부근 이외의 각에서 p편광의 제거가 어렵기 때문인 것을 확인하였다. 도 4는 본 출원의 일 실시예에 따르지 않는 따른 편광판의 접착제얼룩 검사장치를 이용하여 편광판의 접착제얼룩을 검사하기 위해 제 2 편광부재를 디지털카메라로 촬영한 이미지이다.In addition, the adhesive stain inspection apparatus of the polarizing plate according to the embodiment of the present application does not include the first polarizing member, except that the adhesive of the polarizing plate in the same manner as the adhesive stain inspection apparatus of the polarizing plate according to the embodiment. A stain test was performed, but it was confirmed that the adhesive stain of the polarizing plate was detected but the visibility was weak. It was confirmed that this is because it is difficult to remove p-polarized light at an angle other than around the exact Brewster angle when light is applied to the protective substrate included on the upper part of the polarizer. FIG. 4 is an image photographed by a digital camera of a second polarizing member to inspect adhesive stains of a polarizing plate using an adhesive stain inspection apparatus of a polarizing plate according to an exemplary embodiment of the present application.
또한, 본 출원의 다른 일 실시예에 따르지 않는 편광판의 접착제얼룩 검사장치는 제 1 편광부재 및 제 2 편광부재의 흡수축을 90° 회전시킨 것을 제외하고, 상기 일 실시예에 따른 편광판의 접착제얼룩 검사장치와 동일한 방법으로 편광판의 접착제얼룩 검사를 수행하였으나, 편광판의 접착제얼룩이 검출되긴 하나 시인성이 약한 것을 확인하였다. 이는 상기 제 1 편광부재(200)를 투과하여 선편광된 광에서, 상기 편광판(300)을 투과하지 못하고 보호기재(332)에서 반사된 광을 제외하고, 상기 편광판(300)의 접착제층(322)을 투과하여 편광자(310)에 의해 반사된 광이 제 2 편광부재(400)에 의해 흡수될 수 있고, 이로 인해, 편광판(300) 내부에서 접착제층(322)의 접착제얼룩을 우수한 시인성으로 검사할 수 있다.In addition, the apparatus for inspecting adhesive stains of a polarizing plate, which is not according to another exemplary embodiment of the present application, inspects adhesive stains of the polarizing plate according to the above embodiment, except that the absorption axes of the first and second polarizing members are rotated by 90° The adhesive stain test of the polarizing plate was performed in the same manner as the apparatus, but it was confirmed that the adhesive stain of the polarizing plate was detected but the visibility was weak. This is the adhesive layer 322 of the polarizing plate 300, except for the light reflected from the protective substrate 332 without passing through the polarizing plate 300 in the linearly polarized light transmitted through the first polarizing member 200 Light transmitted through and reflected by the polarizer 310 may be absorbed by the second polarizing member 400, and thus, the adhesive stain of the adhesive layer 322 inside the polarizing plate 300 can be inspected with excellent visibility. I can.
편광자의 상부에 포함된 보호기재에 제 1 편광부재를 투과하여 선편광된 광이 인가될 때, 편광자의 상부에 포함된 보호기재의 표면과 공기 사이의 부르스터각 부근에서 p 편광의 표면 반사가 일어나므로 시인성이 약해지는 것을 확인하였다. 도 5는 본 출원의 다른 일 실시예에 따르지 않는 편광판의 접착제얼룩 검사장치를 이용하여 편광판의 접착제얼룩을 검사하기 위해 제 2 편광부재를 디지털카메라로 촬영한 이미지이다.When linearly polarized light through the first polarizing member is applied to the protective substrate included in the upper part of the polarizer, the surface reflection of p-polarized light occurs near the Bourster angle between the surface of the protective substrate included in the upper part of the polarizer and air. Therefore, it was confirmed that the visibility was weakened. FIG. 5 is an image photographed by a digital camera of a second polarizing member in order to inspect adhesive stains on a polarizing plate using an adhesive stain inspection apparatus for a polarizing plate according to another exemplary embodiment of the present application.
또한, 본 출원의 또 다른 일 실시예에 따르지 않는 편광판의 접착제얼룩 검사장치는 점광원 대신 면광원을 사용한 것을 제외하고, 상기 일 실시예에 따른 편광판의 접착제얼룩 검사장치와 동일한 방법으로 편광판의 접착제얼룩 검사를 수행하였으나, 면광원에서는 편광판의 접착제얼룩이 검출되지 않는 것을 확인하였다. 즉, 광원의 경게면에서 접착제얼룩의 검축이 잘되므로 점광원이 면광원에 비해 유리하다는 것을 확인하였다. 도 6은 본 출원의 또 다른 일 실시예에 따르지 않는 편광판의 접착제얼룩 검사장치를 이용하여 편광판의 접착제얼룩을 검사하기 위해 제 2 편광부재를 디지털카메라로 촬영한 이미지이다.In addition, the adhesive stain inspection apparatus of the polarizing plate according to another embodiment of the present application, except that a surface light source instead of a point light source is used, and the adhesive of the polarizing plate is used in the same manner as the adhesive stain inspection apparatus of the polarizing plate according to the above embodiment. Although the stain test was performed, it was confirmed that the adhesive stain of the polarizing plate was not detected in the surface light source. In other words, it was confirmed that the point light source is more advantageous than the surface light source because adhesive stains are well detected on the surface of the light source. FIG. 6 is an image photographed by a digital camera of a second polarizing member in order to inspect adhesive stains on a polarizing plate using an adhesive stain inspection apparatus for a polarizing plate according to another embodiment of the present application.
<부호의 설명><Explanation of code>
100: 점광원100: point light source
200: 제 1 편광부재200: first polarizing member
300: 편광판300: polarizer
310: 편광자310: polarizer
321, 322: 접착제층321, 322: adhesive layer
331, 332: 보호기재331, 332: protective material
400: 제 2 편광부재400: second polarizing member
500: 검사원500: inspector

Claims (13)

  1. 점광원; Point light source;
    상기 점광원으로부터 광이 인가되도록 배치된 제 1 편광부재;A first polarizing member disposed to apply light from the point light source;
    상기 제 1 편광부재를 투과한 광이 인가되도록 배치되어 상기 인가된 광을 반사하는 편광판;A polarizing plate disposed so that the light transmitted through the first polarizing member is applied to reflect the applied light;
    상기 편광판으로부터 반사된 광이 인가되도록 배치된 제 2 편광부재; 및A second polarizing member disposed to apply light reflected from the polarizing plate; And
    상기 제 2 편광부재를 투과한 광이 인가되도록 배치되고, 상기 제 2 편광부재를 투과한 광에 기초하여 상기 편광판의 접착제얼룩을 판단하는 검사원을 포함하며,Arranged so that the light transmitted through the second polarizing member is applied, and includes an inspector for determining adhesive stains of the polarizing plate based on the light transmitted through the second polarizing member,
    상기 편광판은 편광자, 상기 편광자의 상부 및 하부 각각에 광경화성 접착제를 포함하는 접착제층, 및 보호기재를 순차로 포함하고, The polarizing plate sequentially includes a polarizer, an adhesive layer including a photocurable adhesive on each of the upper and lower portions of the polarizer, and a protective material,
    상기 제 1 편광부재를 투과한 광은 상기 편광판의 보호기재로 인가되며,Light transmitted through the first polarizing member is applied as a protective substrate of the polarizing plate,
    상기 점광원은 상기 편광판에 대하여 브루스터 각(brewster angle)으로 광을 인가하는 편광판의 접착제얼룩 검사장치.The point light source is a device for inspecting adhesive stains of a polarizing plate for applying light to the polarizing plate at a Brewster angle.
  2. 제 1 항에 있어서, 상기 점광원은 상기 제 1 편광부재 측으로 무편광된 광을 방출하는 편광판의 접착제얼룩 검사장치.The apparatus of claim 1, wherein the point light source emits unpolarized light toward the first polarizing member.
  3. 제 2 항에 있어서, 상기 점광원으로부터 방출되는 광은 상기 편광판에 대한 입사각이 45° 내지 75°인 편광판의 접착제얼룩 검사장치.The apparatus of claim 2, wherein the light emitted from the point light source has an incident angle of 45° to 75° to the polarizing plate.
  4. 제 1 항에 있어서, 상기 제 1 편광부재는 상기 편광판의 편광자와 흡수축이 수직인 편광판의 접착제얼룩 검사장치.The apparatus of claim 1, wherein the first polarizing member has an absorption axis perpendicular to the polarizer of the polarizing plate.
  5. 제 1 항에 있어서, 상기 편광판은 액정표시장치용 편광판인 편광판의 접착제얼룩 검사장치.The apparatus of claim 1, wherein the polarizing plate is a polarizing plate for a liquid crystal display device.
  6. 제 1 항에 있어서, 상기 편광판에 인가된 광은 상기 접착제층에서 반사되는 편광판의 접착제얼룩 검사장치.The apparatus of claim 1, wherein the light applied to the polarizing plate is reflected by the adhesive layer.
  7. 제 1 항에 있어서, 상기 광경화성 접착제는 아크릴 중합체를 포함하는 접착제 조성물을 경화된 상태로 포함하는 편광판의 접착제얼룩 검사장치The apparatus of claim 1, wherein the photocurable adhesive comprises an adhesive composition containing an acrylic polymer in a cured state.
  8. 제 1 항에 있어서, 상기 접착제층은 굴절률이 1.45 내지 1.50인 편광판의 접착제얼룩 검사장치.The apparatus of claim 1, wherein the adhesive layer has a refractive index of 1.45 to 1.50.
  9. 제 1 항에 있어서, 상기 편광자는 굴절률이 1.5 초과 내지 1.6인 편광판의 접착제얼룩 검사장치.The apparatus of claim 1, wherein the polarizer has a refractive index of greater than 1.5 to 1.6.
  10. 제 7 항에 있어서, 상기 편광판으로부터 반사되어 방출되는 광은 상기 편광판에 대한 반사각이 45° 내지 75°인 편광판의 접착제얼룩 검사장치.The apparatus of claim 7, wherein the light reflected from the polarizing plate has a reflection angle of 45° to 75° with respect to the polarizing plate.
  11. 제 1 항에 있어서, 상기 제 2 편광부재는 상기 편광판의 편광자와 흡수축이 수직인 편광판의 접착제얼룩 검사장치.The apparatus of claim 1, wherein the second polarizing member has an absorption axis perpendicular to a polarizer of the polarizing plate.
  12. 제 1 항에 따른 편광판의 접착제얼룩 검사장치를 이용한 편광판의 접착제얼룩 검사방법에 관한 것으로,It relates to a method for inspecting adhesive stains of a polarizing plate using the adhesive stain inspection device of the polarizing plate according to claim 1,
    점광원으로부터 광을 방출시켜 제 1 편광부재, 편광판, 제 2 편광부재를 순차로 투과시키는 단계; 및Emitting light from a point light source to sequentially transmit the first polarizing member, the polarizing plate, and the second polarizing member; And
    상기 제 2 편광부재를 투과하여 상기 검사원에 인가되는 광에 기초하여 상기 편광판의 접착제얼룩을 판단하는 단계를 포함하는 편광판의 접착제얼룩 검사방법.And determining the adhesive stain of the polarizing plate based on the light transmitted through the second polarizing member and applied to the inspection source.
  13. 제 12 항에 있어서, 상기 편광판에 인가된 광은 반사되는 편광판의 접착제얼룩 검사방법.The method of claim 12, wherein the light applied to the polarizing plate is reflected.
PCT/KR2020/003259 2019-06-07 2020-03-09 Inspection device for adhesive stains on polarizing plate and inspection method for adhesive stains on polarizing plate WO2020246692A1 (en)

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JP2021571884A JP2022535095A (en) 2019-06-07 2020-03-09 Polarizing Plate Adhesive Unevenness Inspection Apparatus and Polarizing Plate Adhesive Unevenness Inspection Method
CN202080038249.5A CN113906287A (en) 2019-06-07 2020-03-09 Device and method for inspecting adhesive stains in polarizing plate

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