WO2020244353A1 - Non-electrolytic slightly acidic hypochlorous water generation apparatus, and generation method - Google Patents

Non-electrolytic slightly acidic hypochlorous water generation apparatus, and generation method Download PDF

Info

Publication number
WO2020244353A1
WO2020244353A1 PCT/CN2020/088929 CN2020088929W WO2020244353A1 WO 2020244353 A1 WO2020244353 A1 WO 2020244353A1 CN 2020088929 W CN2020088929 W CN 2020088929W WO 2020244353 A1 WO2020244353 A1 WO 2020244353A1
Authority
WO
WIPO (PCT)
Prior art keywords
water
hypochlorous acid
slightly acidic
storage tank
additive
Prior art date
Application number
PCT/CN2020/088929
Other languages
French (fr)
Chinese (zh)
Inventor
照那木拉
戴竹君
山本善和
李建昭
Original Assignee
上海万籁环保科技股份有限公司
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 上海万籁环保科技股份有限公司 filed Critical 上海万籁环保科技股份有限公司
Publication of WO2020244353A1 publication Critical patent/WO2020244353A1/en

Links

Images

Classifications

    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/0053Details of the reactor
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00Multistage treatment of water, waste water or sewage
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/001Processes for the treatment of water whereby the filtration technique is of importance
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/02Treatment of water, waste water, or sewage by heating
    • C02F1/04Treatment of water, waste water, or sewage by heating by distillation or evaporation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/44Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
    • C02F1/441Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by reverse osmosis
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/44Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
    • C02F1/444Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by ultrafiltration or microfiltration
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/469Treatment of water, waste water, or sewage by electrochemical methods by electrochemical separation, e.g. by electro-osmosis, electrodialysis, electrophoresis
    • C02F1/4691Capacitive deionisation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/06Controlling or monitoring parameters in water treatment pH
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/40Liquid flow rate
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F5/00Softening water; Preventing scale; Adding scale preventatives or scale removers to water, e.g. adding sequestering agents

Definitions

  • the present invention relates to a water generating device, in particular to a slightly acidic hypochlorous acid water generating device and a generating method capable of producing various types of water.
  • hypochlorous acid water production equipment and production methods there are many hypochlorous acid water production equipment and production methods in the world, but the safety (low concentration, stable pH) control method of the produced hypochlorous acid water has not been mentioned, and the food specified by the US FDA can be contacted
  • concentration of hypochlorous acid water is not higher than 60ppm. Only low-concentration hypochlorous acid water can be used in large quantities in a human environment. It is widely used in industries with high safety requirements such as medical treatment, food processing, and public health.
  • the purpose of this application is to provide a slightly acidic hypochlorous acid water generating device that can simultaneously produce various grades of purified water and slightly acidic hypochlorous acid water, and is provided with at least one water supply port that can provide users with Provide purified water or slightly acidic hypochlorous water that meets different levels of standards, and can switch the type of water intake according to user needs.
  • the concentration of hypochlorous acid water generated in the present application can be less than 200 ppm, preferably less than 60 ppm, and the pH value range is controlled between 6.20 to 6.80, and at any value in between, its pH fluctuates The range is controlled within a narrow range of ⁇ 0.05, and can be stored stably for 18 months.
  • the present invention proposes a slightly acidic hypochlorous acid water generating device, which includes:
  • the purification device is used to purify raw water from the raw water supply system, and each level of purification device is provided with a corresponding water outlet;
  • the hypochlorous acid water generating device is located downstream of the purification device and has a reaction device, a water inlet and an additive injection device, wherein the water inlet is selectively connected to the water outlet of one of the purification devices Connected, the additive injection device is used to contain the additive and add the additive to the reaction device, and the reaction device is used to process the additive and the water from the purification device into hypochlorous water;
  • a control system that is electrically connected to the hypochlorous acid water generating device and arranged to be able to control the amount of water entering the hypochlorous acid water generating device and the addition amount of additives;
  • a water supply port, the water outlet of the purification device and the water outlet of the hypochlorous acid water generating device are switchably connected to the water supply port through corresponding pipes.
  • the reaction device is provided with at least two reactors in sequence from upstream to downstream, and the additive injection device is provided with at least two additive injection parts, wherein each reactor has a parallel phase fluid part and a phase An interface reaction part and a fluid homogenization part, wherein at least the parallel phase fluid part of the first-stage reactor is arranged to diffuse the additive into another liquid to form a solution and has a water inlet, an additive injection port and a water outlet;
  • the phase interface reaction part is arranged to enable the solution from the parallel phase fluid part to be sputtered in the phase interface reaction part and has a water inlet and a water outlet;
  • the fluid homogenizing part is arranged to enable the solution from the The solution of the phase interface reaction part is homogenized and has a water inlet and a water outlet; wherein each of the additive injection ports is connected to the corresponding additive injection part, and the water outlet of the parallel phase fluid part is connected to the phase interface
  • the water inlet of the reaction part is connected, the water outlet of the phase interface reaction part is
  • the reaction device is provided with at least two reactors in sequence from upstream to downstream, and each of the reactors has a parallel phase fluid part, a phase interface reaction part and a fluid homogenization part, wherein the parallel phase fluid
  • the part is a pipeline with no internal obstacles and has an inlet connected to the additive injection device
  • the phase interface reaction part is a pipeline with interfering sheets arranged inside and connected to the parallel phase fluid part
  • the fluid The homogenization part is a pipeline with no internal objects and is connected to the phase interface reaction part.
  • a jet flow part is further provided between the two reactors, and the jet flow part is arranged to increase the flow rate of the solution from the reactor of the previous stage.
  • the jet flow portion is formed by a pipe whose inner diameter is changed from a larger to smaller diameter.
  • the additive injection part of the last stage of the additive injection device is connected to the jet stream part, so that the additive is added to the jet stream part.
  • a filter is provided between the phase interface reaction part and the fluid homogenizing part.
  • the additive injection device is provided with at least two additive injection parts, and the reaction device from upstream to downstream is the first parallel phase fluid part, the first phase interface reaction part, the filter, and the first fluid.
  • the additive of the additive injection device is sprayed into another liquid to form a diluted solution;
  • the phase interface reaction part is arranged such that the solution from the parallel phase fluid part can be sputtered in the phase interface reaction part;
  • the filter and the fluid homogenizing part are arranged to be capable of homogenizing the solution from the phase interface reaction part; and the jet stream part is arranged so that the additive from the additive injection device is injected into the second parallel phase fluid unit.
  • the reaction device is configured to sputter additives and water from the purification device to increase the specific surface area of the solution, thereby generating a quantum chemical reaction, and controlling H hydration protons in stages to achieve stable saturation of H ions.
  • pH stability includes two meanings. On the one hand, it refers to stable production, that is, for any pH value within a certain pH range (for example, 6.20 to 6.80), the pH fluctuation of the slightly acidic hypochlorous acid water during the generation process is small. , Strictly controlled within the narrow interval of plus or minus 0.05. On the other hand, it refers to stable storage.
  • the effective chlorine concentration drop rate does not exceed 10% .
  • the range of pH change is very small, for example, 3 months after hypochlorous acid water is generated, the pH changes from 6.50 to 6.70, which can maintain its original effect for a long time.
  • the effective period of the existing slightly acidic hypochlorous acid is generally only 7-30 days. This is because the existing slightly acidic hypochlorous acid water cannot be stored stably. After a short period of time, the pH changes very much. It loses its original effect. Further, the slightly acidic hypochlorous acid water generated in the present application has almost the same effective chlorine concentration during the storage period (the validity period, for example, 3-6 months), while other existing hypochlorous acid water is within 1 month , The available chlorine concentration varies greatly.
  • the purification device and the reaction device are connected by a pipeline, and a flow regulating valve and a first flow sensor are arranged on the pipeline, and the flow regulating valve and the first flow sensor are both connected to the A control system is electrically connected, and the control system is arranged to control the flow regulating valve according to a value sampled by the first flow sensor.
  • a pH sensor is provided downstream of the last-stage reactor, and the pH sensor is electrically connected to the control system, and the control system is further arranged to detect the pH value according to the pH sensor.
  • the pH value is used to simultaneously control the flow control valve and the additive injection amount of the additive injection part.
  • a pH sensor is provided downstream of the last-stage reactor, and the pH sensor is electrically connected to the control system; the additive injection part is provided with a container, a second flow sensor and a pump, wherein The container is connected to the pump via a pipeline, the pump is connected to the reaction device via a pipeline, the second flow sensor is arranged on the pipeline between the container and the pump, and the control system further It is arranged to simultaneously control the flow regulating valve and the pump based on the pH value detected by the pH value sensor and the value detected by the second flow sensor.
  • the reaction device has two reactors, and the additive injection device has two additive injection parts, wherein the first additive injection part is used to inject NaClO into the first reactor, and the second additive The injection device is used to inject HCl into the second reactor.
  • the concentration of the NaClO is less than 12%, and the concentration of the HCl is less than 12%.
  • the water generating equipment includes a softened water purification device, a drinking water purification device, an RO water purification device, and an EDI respectively used to make softened water, drinking water, RO water, EDI water, and distilled water.
  • a softened water purification device At least two of the water purification device and the distillation device, wherein the softened water purification device, the drinking water purification device, the RO water purification device, the EDI water purification device, and the distillation device are all connected to each other through pipes and valves
  • the reaction device is connected, and the control system is further arranged to control the opening and closing of the valve according to water production requirements.
  • the softened water purification device is arranged to perform at least one of sand filtration, carbon filtration, softening and precision filtration on the raw water, wherein the water outlet of the softened water purification device is switchable through a pipe Connected to the water supply port and the hypochlorous water generating device;
  • the drinking water purification device includes an ultrafiltration membrane group filter arranged to further filter the demineralized water purification device Water, wherein the water outlet of the ultrafiltration membrane group filter is switchably connected to the water supply port and the hypochlorous acid water production device through a pipe;
  • the RO water purification device includes a reverse osmosis membrane filter, the The reverse osmosis membrane filter is located downstream of the ultrafiltration membrane set filter and is used to further filter the water from the ultrafiltration membrane set filter, wherein the water outlet of the reverse osmosis membrane filter is switchably connected to all the filters through a pipe The water supply port and the hypochlorous acid water production device; wherein the EDI water purification device includes an
  • the slightly acidic hypochlorous acid water generating equipment further includes at least one water storage tank, and at least one water outlet of the purification device is connected to a corresponding water storage tank through a pipe, and the hypochlorous water The water outlet of the generating device is connected to a corresponding water storage tank via a pipe, and the water outlet of each water storage tank is connected to the water supply port via a pipe.
  • the slightly acidic hypochlorous acid water generating device has two water supply ports, and the water outlet of the water storage tank connected to the water outlet of the purification device is connected to one of the water supply ports, and is connected to the hypochlorous acid The outlet of the water storage tank connected to the outlet of the water generating device is connected to another water supply outlet.
  • the water storage tank includes one or more of a deionized water storage tank, a drinking water storage tank, a high-purity water storage tank, an ultra-pure water storage tank, and a distilled water storage tank, wherein the The deionized water storage tank is located downstream of the softened water purification device and used to store deionized water from the softened water purification device; the drinking water storage tank is located downstream of the ultrafiltration membrane group filter and is The water outlet of the ultrafiltration membrane set filter is connected to store drinking water from the ultrafiltration membrane set filter; the high-purity water storage tank is located downstream of the reverse osmosis membrane filter and is connected to the reverse osmosis membrane filter.
  • the water outlet of the membrane filter is connected to store high-purity water from the reverse osmosis membrane filter;
  • the ultra-pure water storage tank is located downstream of the electrodeionization device and connected to the water outlet of the electrodeionization device , For storing ultrapure water from the electrodeionization device;
  • the distilled water storage tank is located downstream of the distillation device and connected to the water outlet of the distillation device, for storing distilled water from the distillation device;
  • the outlets of the deionized water storage tank, the drinking water storage tank, the high-purity water storage tank, the ultra-pure water storage tank, and the distilled water storage tank are switchably connected to The water supply port.
  • control system is arranged such that the pH range of the hypochlorous acid water generated by the slightly acidic hypochlorous acid water generating device is between 6.20 and 6.80, and at any value in between, its pH
  • the fluctuation range is strictly controlled within a narrow range of plus or minus 0.05.
  • the pH of the slightly acidic hypochlorous acid water produced is 6.50.
  • control system is further arranged such that the concentration of hypochlorous acid water produced by the slightly acidic hypochlorous acid water generating device is lower than 200 ppm, preferably lower than 60 ppm.
  • This application also provides a method for generating slightly acidic hypochlorous acid water, which includes the following steps:
  • the solution formed by mixing water and the first additive is sequentially subjected to sputtering and homogenization treatments to form a first mixed solution;
  • the solution obtained by mixing the first mixed liquid and the second additive is subjected to sputtering and homogenization treatments in sequence.
  • step S1 the water is purified.
  • the range of the set flow rate is 1 to 1.5 m/s.
  • the inclination angle ranges from 60 to 110 degrees.
  • the first additive is NaClO
  • the second additive is HCl
  • the concentration of the NaClO is less than 12%, and the concentration of the HCl is less than 12%.
  • the concentration of the generated slightly acidic hypochlorous acid water is controlled below 200ppm, preferably below 60ppm, the pH range is between 6.20-6.80, and at any value in between, the pH fluctuation range Control within ⁇ 0.05, and can be stored stably for 18 months.
  • stable storage refers to the reduction rate of the effective chlorine concentration within 18 months of storage not exceeding 10%.
  • This application further provides a method for generating slightly acidic hypochlorous acid water, which includes the following steps:
  • the first additive is NaClO
  • the second additive is HCl
  • the concentration of the NaClO is less than 12%, and the concentration of the HCl is less than 12%.
  • the concentration of the generated slightly acidic hypochlorous acid water is controlled below 200ppm, preferably below 60ppm, the pH range is between 6.20-6.80, and at any value in between, the pH fluctuation range Control within ⁇ 0.05, and can be stored stably for 18 months.
  • the slightly acidic hypochlorous acid water generating equipment of the present application can produce water for various purposes, including purified water of various grades and standards and hypochlorous acid water of various pH values, especially the concentration of slightly acidic hypochlorous acid water is 60ppm Below, the pH range is between 6.20 and 6.80, and at any value in between, the pH fluctuation range is controlled within ⁇ 0.05, and it can be stored stably for 18 months.
  • the hypochlorous acid water has strong weather resistance, and its stability does not decay in the range of 0-80°C.
  • the slightly acidic hypochlorous acid water generating device of the present application utilizes a hydrodynamic reaction method to generate an acidic aqueous solution with slightly acidic hypochlorous acid water as the main sterilizing component.
  • the slightly acidic hypochlorous acid aqueous solution presents a stable and slightly acidic, and has a strong inhibitory effect on bacteria and viruses and other organic substances. Its antibacterial effect is the same as the hypochlorous acid produced by human white blood cells. It is harmless to the human body and can be used for external sterilization .
  • the slightly acidic hypochlorous acid water can also be used to remove air odors such as smoke, musty, and sweat.
  • the slightly acidic hypochlorous acid water generating device of the present invention has at least one water supply port, which can provide at least one of purified water or slightly acidic hypochlorous acid water meeting different grade standards according to user needs.
  • Fig. 1 is a system diagram of a slightly acidic hypochlorous acid water generating device according to an embodiment of the present invention.
  • Fig. 2 is a system diagram of a slightly acidic hypochlorous acid water generating device according to an embodiment of the present invention.
  • FIG. 1 shows a slightly acidic hypochlorous acid water generating device 100 according to an embodiment of the present application as a whole.
  • the slightly acidic hypochlorous acid water generating device of the present application produces slightly acidic hypochlorous acid water in a non-electrolytic manner.
  • the slightly acidic hypochlorous acid water generating device 100 includes at least a primary purification device 1, a hypochlorous acid water generating device 2, a control system 3 and a water output branch 4.
  • the purification device is used to perform various levels of purification treatment on the raw water from the raw water supply system to generate one or more of softened water, drinking water, RO water, EDI water, and distilled water. Each stage of the purification device is provided with a corresponding water outlet.
  • the water outlet can be connected to the water output branch 4 through a pipe for direct water supply to the outside, or it can lead to the hypochlorous acid water generating device 2 for corresponding treatment to form a secondary Chloric acid water, such as slightly acidic hypochlorous water.
  • each level of purification device may be switchably connected to the hypochlorous acid water generating device 2 through an electronically controlled three-way valve, so as to process the water treated by the each level of purification device into hypochlorous acid water.
  • raw water refers to water that has not been treated by the equipment of this application, such as tap water from a municipal water supply system.
  • slightly acidic hypochlorous water refers to hypochlorous water with a pH value ranging from 6.20 to 6.80.
  • the pH of slightly acidic hypochlorous acid water is 6.50.
  • the fluctuation range of its pH value is controlled within plus or minus 0.05.
  • the required pH value can be selected, and under the selected pH value, the pH fluctuation range is controlled within plus or minus 0.05.
  • the hypochlorous acid water generating device 2 of the present application is located downstream of the purification device and has reaction devices 21 and 22, a water inlet (not shown), and additive injection devices 23 and 24.
  • the water inlet is selectively connected with the water outlet of the primary purification device, so that the hypochlorous acid water generating device 2 can use various types of water to produce hypochlorous acid water.
  • the additive injection devices 23 and 24 are used to contain the additives and add the additives, such as NaClO and HCl, to the water from the purification device, so that hypochlorous acid water with a desired pH value can be generated.
  • two additive injection devices 23 and 24 are provided. In other embodiments, more additive injection devices can also be provided, so that the required additives can be added as needed.
  • the reaction devices 21 and 22 are used to process the additives and the water from the purification device into hypochlorous water.
  • the reaction device and the additive injection device are electrically connected to the control system, so that the control system can control the amount of water entering the hypochlorous acid water generating device and the amount of additives added to prepare hypochlorous acid water that meets the requirements.
  • the reaction device of the present application can continuously produce slightly acidic hypochlorous acid water with strong cohesion, low intermolecular adsorption and high activity, and maintain the water shelf life for up to two years.
  • the reaction principle of the reaction device of the present application is to use the horizontal fluid interaction reaction of hydrodynamics.
  • the water and additives By changing the pressure, density, and velocity of the fluid, which includes changing the surface tension of water, the water and additives together form a strong cohesive force and low intermolecular adsorption force. And has high activity, multi-functionality and low concentration small molecular cluster water.
  • the reaction device adopts a phase-parallel jet flow quantum inorganic chemical reaction. Through the geometric design of quantum reaction, the low-concentration inorganic salt phase is entrained with a high-speed flowing water phase to produce a non-linear oscillating reaction. Homogenization and orderly arrangement and integration, and then by adding a hydrogen bond compound solution, intelligently control H ions to reach saturation solubility in the wave-particle duality quantum reaction.
  • the slightly acidic hypochlorous acid generating device of the present application also has a water supply port.
  • the water outlets of the purification devices at all levels and the water outlets of the hypochlorous water generating devices can be switchably connected to the water supply outlets through corresponding pipes, so as to provide users with various water.
  • the purification device includes, from upstream to downstream, a softened water purification device 11, a drinking water purification device 12, and an RO water purification device for making softened water, drinking water, RO water, EDI water, and distilled water.
  • the above-mentioned purification devices at all levels can be switchably connected to the water storage tank, the water supply port or the hypochlorous water generating device through corresponding valves and pipes.
  • demineralized water refers to the water formed after filtering and removing calcium and magnesium ions from raw water.
  • the softened water purification device 11 is arranged to perform at least one of sand filtration, carbon filtration, softening and precision filtration on raw water.
  • Drinking water refers to water that can be directly consumed by people.
  • the drinking water purification device 12 usually includes an ultrafiltration membrane group filter, which is arranged to further filter the water from the softened water purification device, wherein the water outlet of the ultrafiltration membrane group filter is switchably connected to the water supply through a pipe mouth.
  • RO water is further filtered on the basis of drinking water and can be used for drinking or medical purposes.
  • the RO water purification device includes a reverse osmosis membrane filter. The reverse osmosis membrane filter is located downstream of the ultrafiltration membrane filter and is used to further filter the water from the ultrafiltration membrane filter.
  • the water outlet of the reverse osmosis membrane filter can be passed through the pipeline. Switch to connect to the water supply port.
  • EDI water is also called ultrapure water.
  • the EDI water purification device includes an electrodeionization device.
  • the electrodeionization device is located downstream of the reverse osmosis membrane filter and is used to further filter the water from the reverse osmosis membrane filter.
  • the water outlet of the electrodeionization device It is switchably connected to the water supply port through a pipe. Distilled water is further distilled on the basis of ultrapure water, and can be used for injection, hemodialysis, etc.
  • the distillation device is located downstream of the electrodeionization device and is used to further distill ultrapure water, wherein the water outlet of the distillation device is switchably connected to the water supply port through a pipe.
  • the demineralized water purification device 11 has a booster pump 11a, a pressure sensor 11b, a filter 11c and an electronically controlled three-way valve 11d.
  • the booster pump 11a is installed on the pipeline upstream of the filter 11c, and is used to pump raw water to the filter 11c.
  • the pressure sensor 11b is arranged to turn on the booster pump 11a when detecting that the pressure of the water entering the filter 11c is too low.
  • the electronically controlled three-way valve 11d is an electronically controlled L-shaped three-way valve, which is electrically connected to the control system 3 and controlled by the control system 3 according to the requirements of water production.
  • the control system 3 controls the electronically controlled three-way valve 11d, which is connected to the water output branch 4 or connected to the hypochlorous water generating device 2 .
  • the control system 3 controls the electronically controlled three-way valve 11d to connect to the next-stage purification device.
  • the filter 11c is arranged to perform at least one of sand filtration, carbon filtration, softening, and precision filtration.
  • the filter 11c includes at least softening filtration and forming deionized water.
  • the filter 11c may include any one or a combination of two of a sand charcoal filter, a softening filter, and a precision filter.
  • the sand charcoal filter is used to remove large particles and impurities in tap water and improve the taste of water.
  • the softening filter is used to remove calcium and magnesium ions in the water and adjust the hardness of the water.
  • the precision filter can remove the fine suspended solids or colloidal particles that usually cannot be removed by sand filtration and carbon filtration.
  • the drinking water purification device 12 has a filter 12a and an electronically controlled three-way valve 12b at the outlet of the filter.
  • the filter 12a is connected to the upper-level demineralized water purification device 11 and is arranged to filter demineralized water.
  • the electronically controlled three-way valve 12b is an electronically controlled L-type three-way valve, which is electrically connected to the control system 3 and controlled by the control system 3 according to the requirements of water production.
  • the control system 3 controls the electronically controlled three-way valve 12b to connect to the water output branch 4 or to the hypochlorous water generating device 2.
  • the filter 12a is an ultrafiltration membrane group filter, which has a melt blown filter element for further filtering the water from the softened water purification device.
  • the water treated by the ultrafiltration membrane group filter is ultrafiltration water.
  • the filter pore size of the melt-blown filter element is about 0.01 microns.
  • the ultrafiltration water is further removed from impurities such as bacteria, rust, colloids and organic matter, but it retains dissolved oxygen in the water and nutrients such as trace minerals required by the human body. The water quality reaches the current level of my country. Drinking water standards can be used in kindergartens, hospitals, nursing homes, hotels, catering and other industries, and play an important role in many aspects such as sterilization and preservation, food processing, anti-virus, and washing.
  • the RO water purification device 13 has a booster pump 13a, a pressure sensor 13b, a filter 13c, and an electronically controlled three-way valve 13d.
  • the booster pump 13a is installed on the pipeline upstream of the filter 13c, and is used to pump the water from the upper-level purification device to the filter 13c.
  • the pressure sensor 13b is arranged to turn on the booster pump 13a when it detects that the pressure of the water entering the filter 13c is too low.
  • the electronically controlled three-way valve 13d is an electronically controlled L-type three-way valve, which is electrically connected to the control system 3, and is controlled by the control system according to the requirements of water production.
  • the control system 3 controls the electronically controlled three-way valve 13d, which is connected to the water output branch 4 or connected to the hypochlorous acid water generating device 2 .
  • the control system 3 controls the electronically controlled three-way valve 13d to connect to the next-stage purification device.
  • the filter 13c includes a reverse osmosis membrane module.
  • the water treated by the reverse osmosis membrane module is high-purity water (also known as RO water), which can reach the standard of high-purity water. It basically does not retain minerals in the water, and the pH value is between 6-7.
  • the membrane pore size of the reverse osmosis membrane module is smaller than that of the ultrafiltration membrane, and can be used to further filter the water treated by the filter 11c or the ultrafiltration membrane group filter.
  • the EDI water purification device 14 has a booster pump 14a, a pressure sensor 14b, an electrodeionization device 14c (also called an EDI device) and at least one electronically controlled three-way valve 14d.
  • the booster pump 14a is installed on the pipeline upstream of the electrodeionization device 14c, and is used to pump the water from the previous purification device to the electrodeionization device 14c.
  • the pressure sensor 14b is arranged to turn on the booster pump 14a when it detects that the pressure of the water entering the electrodeionization device 14c is too low.
  • the electronically controlled three-way valve 14d is an electronically controlled L-type three-way valve, which is electrically connected to the control system 3, and is controlled by the control system according to the requirements of water production.
  • the control system 3 controls the electronically controlled three-way valve 14d, which is connected to the water output branch 4 or connected to the hypochlorous water generation Device 2.
  • the control system 3 controls the electronically controlled three-way valve 14d to connect to the next-level purification device.
  • the EDI device the directional migration of ions in the water is realized under the action of the electric field, so as to achieve the deep purification and desalination of water. Therefore, EDI water is called ultrapure water (EDI water), which can be widely used in electricity, electronics, medicine, Chemical, optical instruments and laboratory fields.
  • the water treated by the EDI device is mainly used to produce distilled water for injection, hemodialysis, etc.
  • the distillation device 15 has a booster pump 15a, a pressure sensor 15b, and a distillation device 15c.
  • the booster pump 15a is installed on the pipeline upstream of the distillation device 15c, and is used to pump the water from the upper-level purification device to the distillation device 15c.
  • the pressure sensor 15b is arranged to turn on the booster pump 15a when it detects that the pressure of the water entering the distillation device 15c is too low.
  • the distillation device 15c is connected to the water output branch 4 or to the hypochlorous acid water generating device 2.
  • the purification device 1 can be connected to the hypochlorous acid water generating device 2 and the water output branch 4 via a pressure reducing valve 41 and an electronically controlled three-way valve 42.
  • the control system 3 controls the electronically controlled three-way valve 42 so that the outlet of the purification device 1 is connected to the hypochlorous acid water generating device 2.
  • the control system 3 controls the electronically controlled three-way valve 42 so that the outlet of the purification device 1 is connected to the water output branch 4.
  • the corresponding water is supplied to the water supply port of the slightly acidic hypochlorous acid water generating device.
  • the water output branch 4 has a water storage tank 43 for storing water from the purification device.
  • the number of water storage tanks 43 may be one or more.
  • the water outlet of each purification device is connected with a corresponding water storage tank through a pipe.
  • the water outlet of the water storage tank 43 finally leads to the water supply port via a pipe or the like.
  • the storage tank may include one or more of a deionized water storage tank, a drinking water storage tank, a high-purity water storage tank, and an ultra-pure water storage tank, wherein the deionized water storage tank is located downstream of the softened water purification device and used To store deionized water from the demineralized water purification device.
  • the drinking water storage tank is located downstream of the ultrafiltration membrane filter and is connected to the outlet of the ultrafiltration membrane filter of the drinking water purification device, and is used to store drinking water from the ultrafiltration membrane filter.
  • the high-purity water storage tank is located downstream of the reverse osmosis membrane filter and is connected to the water outlet of the reverse osmosis membrane filter for storing high-purity water (RO water) from the reverse osmosis membrane filter.
  • the ultrapure water storage tank is located downstream of the electrodeionization device and is connected to the water outlet of the electrodeionization device, and is used to store the ultrapure water from the electrodeionization device.
  • the distilled water storage tank is located downstream of the distillation device and connected to the water outlet of the distillation device for storing distilled water from the distillation device.
  • the outlets of deionized water storage tanks, drinking water storage tanks, high-purity water storage tanks, ultra-pure water storage tanks, and distilled water storage tanks can be switchably connected to the water supply ports through pipes.
  • a liquid level sensor 44 is provided in the water storage tank 43.
  • the control system 3 can judge the current production process according to the current level of the water storage tank detected by the current level sensor 44 and control the electronically controlled three-way valve 42.
  • the water output branch 4 may be provided with a water heater 45 located downstream of the water storage tank.
  • the water heater 45 is provided with a temperature sensor 46.
  • the control system 3 controls the switch of the water heater 45 according to the set value and the current water temperature sampled by the temperature sensor 46.
  • a sterilizer 47 may be provided downstream of the water heater 45. According to the water production control requirements, the control system 3 controls the sterilizer 47 to open when the water is discharged, and controls the sterilizer 47 to close when the water is stopped.
  • the outlet of the sterilizer 47 can be connected with corresponding electronically controlled three-way valves, such as softened water electronically controlled three-way valves 48, drinking water electronically controlled three-way valves 49, RO water electronically controlled three-way valves 50, EDI water electronically controlled three-way valves A through valve 51 and a distilled water electronically controlled three-way valve 52.
  • the control system 3 controls the opening and closing of the electronically controlled three-way valves 48, 49, 50, 51 and 52 in accordance with the water production control requirements.
  • Each electronically controlled three-way valve can lead to its own water supply ports 53, 54, 55, 56 and 57.
  • the above-mentioned electronically controlled three-way valves 48, 49, 50, 51 and 52 can be shared, that is, only one electric three-way valve is provided.
  • the aforementioned water supply ports 53, 54, 55, 56 and 57 can also be shared, that is, only one water supply port is provided. In an embodiment, one or more of the above-mentioned water storage tank, water heater and sterilizer
  • the water inlet of the hypochlorous acid water generating device 2 is provided with a flow regulating valve 2a, a solenoid valve 2b and a first flow sensor 2c.
  • the control system 3 controls the opening degree of the flow regulating valve 2a according to the value sampled by the first flow sensor 2c and the process requirements.
  • the control system 3 controls the opening and closing of the solenoid valve 2b according to system settings and other parameters, which will be described in further detail below.
  • the reaction device of the hypochlorous acid water generator 2 is provided with two reactors 21 and 22 in sequence from upstream to downstream.
  • the additive injection device is provided with two additive injection parts 23 and 24. The additive from the additive injection part is added to the corresponding reactor to carry out the corresponding reaction to produce the required solution, such as slightly acidic hypochlorous water.
  • the hypochlorous acid water generator 2 has two reactors 21 and 22.
  • the reactor 21 has a parallel phase fluid part 21a, a phase interface reaction part 21b, and a fluid homogenizing part 21d.
  • the parallel phase fluid portion 21a of the reactor 21 is arranged to diffuse the first additive (for example, NaClO) into another liquid to form a solution, and has a water inlet, an additive injection port, and a water outlet.
  • the parallel phase fluid part 21a is arranged such that the first additive from the first additive injection part, such as sodium hypochlorite, naturally diffuses in the water from the purification device by virtue of its own diffusive force.
  • the parallel phase fluid part 21a may be a section of pipeline without any obstacles inside.
  • the direction in which the first additive is added to the water forms an oblique angle with the flow direction of the water, and the oblique angle may be any suitable angle, for example, 60 to 110 degrees.
  • the phase interface reaction part 21b is arranged to enable the solution from the parallel phase fluid part 21a to be sputtered in the phase interface reaction part 21b and has a water inlet and a water outlet.
  • the water inlet of the phase interface reaction part 21b is connected to the water outlet of the parallel phase fluid part 21a.
  • the phase interface reaction part 21b is arranged to promote further diffusion of the additive in the phase interface reaction part.
  • the phase interface reaction part may be a pipeline with interference sheets arranged inside. When the mixed liquid formed by the water and the additive flows through the phase interface reaction part, it will collide with the interference plate, thereby promoting the diffusion of the additive in the water.
  • the fluid homogenizing part 21d is arranged to be able to homogenize the solution from the phase interface reaction part 21b and has a water inlet and a water outlet, and the water inlet of the fluid homogenizing part is connected with the water outlet of the phase interface reaction part.
  • the fluid homogenizing part 21d may be a section of pipeline without any obstacles in it.
  • a filter 21c is also provided between the phase interface reaction part 21b and the fluid homogenizing part 21d of the reactor 21.
  • the filter 21c can prevent garbage and air, and can also homogenize the solution, and at the same time make molecules from large to small, and can also homogenize the flow rate of the generated water to stabilize it. If necessary, the filter 21c may not be provided.
  • the liquid coming out of the reactor 21 is the first mixed liquid.
  • the reactor 22 has a parallel phase fluid part 22a, a phase interface reaction part 22b, and a fluid homogenizing part 22c.
  • the parallel phase fluid portion 22a of the reactor 22 is arranged to diffuse the second additive (for example, HCl) into another liquid (for example, the first mixed liquid) to form a solution, and has a water inlet and a water outlet.
  • the parallel phase fluid part is arranged so that the second additive from the second additive injection part, such as hydrochloric acid, naturally diffuses in the solution from the reactor 21 by virtue of its own diffusion force.
  • the parallel phase fluid part can be a section of pipeline without any obstacles inside. In this way, the additive stock solution with high concentration can first diffuse naturally and reduce the concentration, thereby preventing useless reactions.
  • the direction in which the second additive is added to the first mixed liquid forms an oblique angle with the flow direction of the first mixed liquid, and the oblique angle may be any suitable angle, for example, 60 to 110 degrees.
  • the phase interface reaction part 22b is arranged to enable the solution from the parallel phase fluid part to be sputtered in the phase interface reaction part and has a water inlet and a water outlet.
  • the water inlet of the phase interface reaction part 22b is connected to the water outlet of the parallel phase fluid part 21a.
  • the phase interface reaction part 22b is arranged to promote further diffusion of the second additive in the phase interface reaction part 22b.
  • the phase interface reaction part 22b may be a pipe in which interference pieces are arranged. When the mixed liquid of water, the first additive and the second additive flows through the phase interface reaction part, it will collide with the interference plate, thereby promoting the diffusion of the additive in the water.
  • the fluid homogenizing part 22c is arranged to be able to homogenize the solution from the phase interface reaction part 22b and has a water inlet and a water outlet, and the water inlet of the fluid homogenizing part is connected with the water outlet of the phase interface reaction part.
  • the fluid homogenizing part 22c may be a section of pipeline without any obstacles inside.
  • phase interface reaction part 2d and a jet flow part 2e are sequentially provided between the reactor 21 and the reactor 22.
  • the phase interface reaction part 2d is similar in structure and function to the phase interface reaction part 21b, both of which promote the further diffusion of additives, and can be constituted by a pipe with interfering sheets inside.
  • the injection stream portion 2e is provided with an additive injection port.
  • the additive from the additive injection part can enter the jet stream part through the additive injection port.
  • the jet stream portion is arranged so that the flow rate of the solution from the previous-stage reactor increases.
  • the additive such as hydrochloric acid
  • the jet portion 2e may be a section of pipe whose inner diameter changes from large to small. When water flows through the pipe, the speed becomes faster.
  • the jet flow part may also have another structure that can accelerate the water flow.
  • the jet portion 2e may not be provided. If the jet stream part 2e and the reactor 22 are provided at the same time, the additive from the additive injection part is first added to the jet stream part and mixed with the solution from the previous reactor before entering the reactor 22. If only the reactor 22 is provided without the jet stream part, the additive from the additive injection part directly enters the parallel phase fluid part of the reactor 22 and is mixed with the solution from the previous stage reactor.
  • the above-mentioned reaction device is composed of a plurality of reactors, optional filters and jets. Corresponding inlets and outlets are provided between the various parts within each reactor and between the reactors. These interconnected inlets and outlets can be separate inlets and outlets, or they can be the same part, that is, the inlet and outlet are actually the same part. For example, when the reactor is composed of a pipe, the gap between adjacent parts The entrance and exit are actually the same part.
  • the reaction device from upstream to downstream is the first parallel phase fluid part, the first phase interface reaction part, the filter, the first fluid homogenization part, the second phase interface reaction part, the jet flow part, and the second The parallel phase fluid part, the third phase interface reaction part and the second fluid homogenization part, wherein each of the parallel phase fluid parts is arranged to spray the additive from the corresponding additive injection device into another liquid to form a dilution
  • the phase interface reaction part is arranged so that the solution from the parallel phase fluid part can be sputtered in the phase interface reaction part;
  • the filter and the fluid homogenizing part are arranged so that the solution from the phase interface The solution in the reaction part is homogenized;
  • the jet stream part is arranged so that the additive from the additive injection device is jetted into the second parallel phase fluid part.
  • a pH sensor 58 is provided downstream of the last-stage reactor 22.
  • the pH sensor is electrically connected to the control system 3.
  • the control system 3 is arranged to simultaneously control the flow regulating valve 2a and the additive injection amount of the additive injection part according to the pH value detected by the pH sensor, so as to obtain a solution with a desired pH value. Further, the controller receives the flow rate detected by the first flow sensor 2c and the pH value detected by the pH value sensor to control the additive injection amount of the additive injection part, and adjust the pH value to within the set pH value range,
  • the pH range can be 6.20 to 6.80.
  • a shutdown alarm signal will be issued.
  • the additive injection parts 23 and 24 are used to inject two different additives, respectively.
  • the additive injection part 23 has a first container 23a for containing additives such as sodium hypochlorite.
  • the additive injection part 23 is provided with a second flow sensor 23b, which is used to measure the additive amount of the additive and is electrically connected to the control system.
  • the additive injection part 23 is also provided with a pump 23c and an injection unit 23d for injecting the additive into the reactor.
  • the control system controls the pump 23c according to the data sampled by the pH sensor 58 and the second flow sensor 23b, and according to the water production requirements, so as to add the required amount of additives to the reactor.
  • the additive injection part 24 has a second container 24a for containing additives such as hydrochloric acid.
  • the additive injection part 24 is provided with a second flow sensor 24b, which is used to measure the additive amount and is electrically connected to the control system.
  • the additive injection part 24 is also provided with a pump 24c and an injection unit 24d for injecting the additive into the reactor.
  • the control system controls the pump 24c according to the water production requirements, so as to add the required amount of additives to the reactor.
  • the water outlet of the last-stage reactor is connected with a water storage tank 59 through a pipe.
  • a liquid level sensor 60 is provided in the water storage tank 59.
  • the control system 3 judges the current production process based on the current readings of the liquid level sensor 44 and the liquid level sensor 60, and controls the electronically controlled three-way valve 42.
  • a hypochlorous water supply port 61 is provided downstream of the storage tank for supplying hypochlorous water to users.
  • FIG. 2 shows a slightly acidic hypochlorous acid water generating device 200 according to an embodiment of the present invention as a whole.
  • the slightly acidic hypochlorous acid water generating device 200 includes at least one level of purification device for purifying raw water from the raw water supply system.
  • raw water refers to water that has not been treated by the equipment of this application, such as tap water from a municipal water supply system.
  • a hypochlorous acid water generating device 106 is provided downstream of the purification devices at all levels, which is used to process the water treated by the purification devices at all levels into slightly acidic hypochlorous water.
  • slightly acidic hypochlorous water refers to hypochlorous water with a pH value ranging from 6.20 to 6.80.
  • the fluctuation range of its pH value is controlled within a narrow range of plus or minus 0.05.
  • the required pH value can be selected, and the pH fluctuation range is controlled within plus or minus 0.05 under the selected pH value.
  • the slightly acidic hypochlorous acid water generating device 200 includes a pre-filter 101 and a raw water tank 102, and the pre-filter 101 is connected to a water source through a pipe 301.
  • the pre-filter 101 and the raw water tank 102 are connected by a pipe 302.
  • the raw water from the raw water supply system is filtered by the pre-filter 101 and stored in the raw water tank 102.
  • a valve 303 is provided upstream of the pre-filter 101, and the raw water can be controlled to flow into the slightly acidic hypochlorous acid water generating device 200 through the valve switch.
  • the valve is set as a manual valve.
  • the valve can also be configured as a solenoid valve.
  • the raw water tank 102 is connected to the first-stage filtering device 103 through a pipeline.
  • the raw water from the raw water supply system is subjected to at least one of sand filtration, carbon filtration, softening, and precision filtration by the first-stage filtration device 103.
  • the first-stage filtration device 103 includes at least softening filtration and forming deionized water.
  • the first-stage filtering device 103 includes a sand charcoal filter 1031, a softening filter 1032, and a precision filter 1033.
  • the first-stage filtering device 103 may include any one of a sand charcoal filter 1031, a softening filter 1032, and a precision filter 1033 or a combination of two.
  • the sand charcoal filter 1031 is used to remove large particles and impurities in tap water and improve the taste of water.
  • the softening filter 1032 is used to remove calcium and magnesium ions from the water and adjust the softness and hardness of the water.
  • the precision filter 1033 can remove fine suspended solids or colloidal particles that cannot be removed by sand filtration and carbon filtration in water.
  • a salt regeneration device 10321 for regenerating the softening filter 1032 is usually provided for regenerating the softening filter 1032.
  • the water treated by the first-stage filtering device 103 can be divided into two branches, one of which leads to a water supply port (not shown), which can provide deionized water to users.
  • the deionized water treated by the first-stage filter device 103 can be used as water for laboratories, laboratories, boilers, etc.
  • the other branch is connected to the ultrafiltration membrane pack filter and/or the reverse osmosis membrane module 104 through a pipeline 304.
  • the ultrafiltration membrane group filter has a melt blown filter element for further filtering the water from the first stage filter device 103.
  • the water treated by the ultrafiltration membrane group filter is ultrafiltration water.
  • the filter pore size of the melt-blown filter element is about 0.01 microns.
  • the ultrafiltration water is further removed from impurities such as bacteria, rust, colloids and organic matter, but it retains dissolved oxygen in the water and nutrients such as trace minerals required by the human body.
  • the water quality reaches the current level of my country. Drinking water standards can be used in kindergartens, hospitals, nursing homes, hotels, catering and other industries, and play an important role in many aspects such as sterilization and preservation, food processing, anti-virus, and washing.
  • the water treated by the ultrafiltration membrane group filter can be divided into two branches, one of which leads to the first water supply port 204, and the water quality standard of this branch meets the current drinking water standards in my country.
  • the water treated by the reverse osmosis membrane module is high-purity water, which can reach the standard of high-purity water. It basically does not retain minerals in the water.
  • the pH value is between 6-7 and is weakly acidic. It can be used as a raw liquid or raw material to produce sanitary products and skin Disinfecting products such as mucosal disinfectant and mouthwash.
  • the membrane pore size of the reverse osmosis membrane module is smaller than that of the ultrafiltration membrane, and can be used to further filter the water treated by the first-stage filtration device 103 or the ultrafiltration membrane set filter.
  • the water treated by the reverse osmosis membrane module can be divided into two branches. One branch leads to the first water supply port 204, which can provide users with high-purity water, and the other branch leads to the generation of hypochlorous acid water. ⁇ 106 ⁇ Device 106.
  • the water treated by the reverse osmosis membrane module is connected to an electrodeionization (EDI) device (not shown in the figure) through another branch.
  • EDI electrodeionization
  • the EDI device the directional migration of ions in the water is realized under the action of the electric field, so as to achieve the deep purification and desalination of water. Therefore, EDI water is called ultrapure water (EDI water), which can be widely used in electricity, electronics, medicine, Chemical, optical instruments and laboratory fields.
  • the water treated by the EDI device is mainly used to produce distilled water for injection, hemodialysis, etc.
  • the water treated by the EDI device can be divided into two branches, one of which leads to an equipment water supply port, which can provide users with ultra-pure water, and the other branch leads to the hypochlorous acid water generator 106 .
  • the ultrapure water treated by the electrodeionization (EDI) device is also connected to the distillation purification device (not shown in the figure) through another branch (not shown in the figure).
  • the purity of the water treated by the distillation purification device is higher and can reach the standard of medical distilled water.
  • the water treated by the distillation purification device can be divided into two branches, one of which leads to the first water outlet 204, which can provide users with medical distilled water, and the other branch leads to hypochlorous acid
  • the water processing device 106 is used to make medical distilled water into slightly acidic hypochlorous acid water; the slightly acidic hypochlorous acid water made by using the medical distilled water can be used as a stock solution or raw material to produce skin and mucous membrane disinfectants, scald wound disinfectants and other products.
  • a sterilization system 105 is provided between the ultrafiltration membrane group filter and/or reverse osmosis membrane assembly 104 and the hypochlorous acid water generator 106 for sterilizing water.
  • the sterilization system 105 may adopt an ultraviolet sterilization system.
  • the ultraviolet sterilization system may include an outer sleeve and a quartz ultraviolet lamp tube arranged in the outer sleeve, and an annular flow channel is formed between the outer sleeve and the quartz ultraviolet lamp for water flow through the pipeline.
  • the sterilization method is not limited to the above method, and other sterilization methods can be used.
  • the hypochlorous acid water generating device 106 is located downstream of the purification devices of each stage and is selectively connected to one of the purification devices for processing the above-mentioned deionized water, ultra-filtered water/drinking water, high-purity water, ultra-pure water, and medical distilled water into The slightly acidic hypochlorous water, in which the branch connected with the first-stage filter device 103, the EDI device and the distillation purification device are not shown in the figure.
  • the hypochlorous acid water generating device 106 of this embodiment adopts a jet flow reaction method, and its composition structure is the same as that shown in FIG. 1, and will not be described in detail here.
  • the hypochlorous acid water obtained by the hypochlorous acid water generating device 106 is stable and slightly acidic, the pH value can be stabilized between 6.20-6.80, and it can be stored for more than 18 months under dark conditions.
  • the hypochlorous acid water has strong weather resistance, and its stability does not decay in the range of 0-80°C.
  • the hypochlorous acid water only has a strong inhibitory effect on organic matter such as bacteria and viruses, and its antibacterial active ingredients are the same as hypochlorous acid produced by human leukocytes. It has strong sterilization ability and is non-toxic and harmless to the human body.
  • the hypochlorous acid water can also remove space smoke, odor, food odor, sweat, etc. to improve air quality.
  • the water outlet of the hypochlorous water generating device 106 is connected to the second water supply port 205 via a pipeline for supplying water to the user.
  • a slightly acidic hypochlorous acid water storage tank 108 is provided between the hypochlorous acid water generator 106 and the second water supply port 205 for storing the slightly acidic hypochlorous acid water from the hypochlorous acid water generator.
  • a slightly acidic hypochlorous acid water transfer storage tank 109 is provided between the hypochlorous acid water generating device 106 and the slightly acidic hypochlorous acid water storage tank 108, and the hypochlorous acid water transfer storage tank 109 is used for Storage during transfer in hypochlorous acid water.
  • the slightly acidic hypochlorous acid water generating device 200 is provided with a bypass pipeline 201.
  • the inlet of the bypass pipeline 201 is connected to the raw water supply system through a three-way valve 305.
  • the three-way valve 305 is configured to selectively connect the raw water supply system with the bypass line 201 or the first-stage filter device 103.
  • the outlet of the bypass pipe 201 is connected to the water supply pipe of the slightly acidic hypochlorous acid water generating device 200 via another three-way valve 306.
  • the three-way valve is an electromagnetic three-way valve.
  • the three-way valve can also be replaced by a solenoid valve installed on the bypass pipe and another solenoid valve installed on the outlet branch of the hypochlorous acid water generator.
  • the slightly acidic hypochlorous acid water generating device 200 is further provided with a controller (not shown in the figure).
  • the controller receives the failure alarm signal, sends out an alarm, and controls the switching of the three-way valve To the bypass pipeline 201 to ensure a stable supply of daily water.
  • a deionized water storage tank (not shown in the figure) is provided in the downstream pipeline of the first-stage filtering device 103, and the outlet of the deionized water storage tank is connected to the equipment water supply via a pipe. mouth.
  • the downstream pipeline of the ultrafiltration membrane module filter is provided with a drinking water storage tank
  • the downstream pipeline of the reverse osmosis membrane module is provided with a high-purity water storage tank, a drinking water storage tank and a water outlet of the high-purity water storage tank Connect to the water supply port of the equipment via a pipe.
  • an ultrapure water storage tank (not shown in the figure) is provided in the downstream pipeline of the electrodeionization (EDI) device, and the water outlet of the ultrapure water storage tank is connected to the equipment water supply port via a pipe.
  • the first water supply port 204, the second water supply port 205, and other possible water supply ports are all connected with deionized water branch, drinking water branch, high-purity water branch, ultra-pure water branch, and medical distilled water as required.
  • the controller is arranged to be able to switch the water supply type of the water supply port according to user settings.
  • the slightly acidic hypochlorous acid water generating equipment is provided with a drain line 202, which is connected to the outlet of each water storage tank through a corresponding valve.
  • the valve is set as a solenoid valve, which is controlled by the controller to open and close.
  • the embodiment of Fig. 2 is set as an electromagnetic three-way valve 4025, which is controlled by the controller to switch.
  • the downstream pipeline of each storage tank is provided with a delivery pump and a pressure switch. When the pipeline pressure is low, the pressure switch controls the delivery pump to open to increase the pressure of the downstream water supply. When the pipeline pressure is too high, the pressure switch controls the delivery pump to close.
  • Each water storage tank is provided with a liquid level detector. The liquid level detector extends along the height of the storage tank to detect the height of the liquid level in the corresponding storage tank.
  • the controller controls the opening of the drain pipeline inlet valve to drain water and closes the corresponding delivery pump of the downstream pipeline of the water storage tank.
  • the water in the water storage tank is periodically discharged.
  • the downstream water supply pipeline of each storage tank is provided with a flow meter, and the water supply amount of the corresponding storage tank can be calculated according to the indication of the flow meter.
  • the controller controls to open the inlet valve of the drainage pipeline to drain water and close the corresponding delivery pump of the downstream pipeline of the water storage tank.
  • the controller has the function of adjusting the predetermined liquid level according to the water consumption of the corresponding storage tank.
  • an electromagnetic three-way valve 4025a is provided at the outlet of the raw water storage tank 102.
  • One outlet of the three-way valve is connected to the drainage pipe 202, and the other outlet is connected to the first-stage filter device 103 through a pipe 307.
  • a liquid level detector 4021a is installed in the raw water storage tank 102 along the height of the storage tank, and a delivery pump 4023a, a pressure switch 4027a, a flow meter 4022a and a pressure sensor 4024a are provided on the pipeline 307.
  • the pressure sensor 4024a is arranged at the inlet of the sand charcoal filter 1031 to monitor the pressure of its water inlet.
  • the electromagnetic three-way valve 4025a is switched to be connected to the pipe 307, and the raw water storage tank 102 supplies water to the first-stage filter device 103, and the pressure sensor 4024a detects the water flow pressure at the water inlet of the pipe.
  • the pressure switch 4027a controls the delivery pump 4023a to increase the pressure to deliver water downstream, and when the pressure is too high, the delivery pump 4023a is stopped.
  • the controller controls to close the corresponding delivery pump 4023a of the downstream pipeline 307 of the raw water storage tank 102 and switch the electromagnetic three-way valve 4025a Drain water to the drain line 202.
  • the controller controls to close the delivery on the pipeline 307
  • the pump 4023a switches the electromagnetic three-way valve 4025a to the drainage pipe 202 for drainage to ensure the quality of the water supplied.
  • the controller recalculates and controls the water filling level according to the water consumption in the time interval, and changes other preset values accordingly, such as changing the preset level and the preset flow rate.
  • the sand charcoal filter 1031 is connected to the softening filter 1032 through a pipe 308.
  • a pressure sensor 4024b is provided on the pipe 308, and a delivery pump, a pressure switch, and a flow meter can also be provided on the pipe 308.
  • the softening filter 1032 is connected to the precision filter 1033 through a pipe 309.
  • the pipe 309 can also be provided with a delivery pump, a pressure switch, and a flow meter.
  • the precision filter 1033 is also provided with a pressure sensor 4024c to monitor the position of the precision filter 1033. Water flow pressure.
  • the first-stage filtration device 103 is connected to the ultrafiltration membrane group filter and/or the reverse osmosis membrane module 104 through a pipeline 304.
  • the bottom outlet of the ultrafiltration membrane set filter and/or the reverse osmosis membrane module 104 is also connected to the drain line 202, and the bottom outlet is provided with a concentrated discharge diaphragm manual valve 4029 and a flow meter 4022i, which can manually control the discharge of concentrated water.
  • the pipeline 304 is provided with a delivery pump 4023c, a pressure switch 4027c, a flow meter (not shown), a pressure sensor 4024c, and a manual valve 4026c.
  • a deionized water storage tank (not shown in the figure) is provided on the pipeline 304, and an electromagnetic three-way valve is provided at the outlet of the deionized water storage tank.
  • An outlet of the three-way valve is connected to the ultrafiltration membrane filter.
  • the filter and/or the reverse osmosis membrane module 104 are connected, and the other outlet is connected to the drainage pipeline 202.
  • the ultrafiltration membrane set filter and/or the reverse osmosis membrane module 104 can be equipped with an ultrafiltration membrane set filter or a reverse osmosis membrane module alone, or an ultrafiltration membrane set filter and a reverse osmosis membrane module can be set at the same time, wherein the reverse osmosis membrane module Set at the downstream of the ultrafiltration membrane group filter.
  • a drinking water storage tank for storing drinking water can be arranged downstream of the ultrafiltration membrane group filter.
  • a high-purity water storage tank for storing high-purity water can be installed downstream of the reverse osmosis membrane module.
  • Electromagnetic three-way valves are provided at the outlets of the drinking water storage tank and the high-purity water storage tank. One outlet of the three-way valve is connected to the drainage pipeline 202, and the other outlet is connected to the downstream pipeline for further treatment of water.
  • the ultrafiltration membrane set filter and/or the reverse osmosis membrane module 104 are connected to the hypochlorous acid water generating device 106 through the pipe 310, and the pipe 310 is provided with a sterilizing device 105 for sterilizing water.
  • a flow meter 4022d is provided at the entrance of the sterilization device 105.
  • the pipeline 310 is also provided with a drinking water/high-purity water storage tank 107.
  • the drinking water/high-purity water storage tank 107 is provided with a liquid level sensor 4021e along the height.
  • a three-way valve 4025e is provided at the outlet of the drinking water/high-purity water storage tank 107.
  • One outlet of the three-way valve is connected to the drain pipeline 202.
  • the branch of the other outlet of the three-way valve is provided with a delivery pump 4023e, a pressure switch 4027e, and another three-way valve 4025f.
  • One outlet of the three-way valve is connected to the hypochlorous acid water generating device 106, and a flowmeter 4022e is installed on the branch to monitor the pipeline flow.
  • the other outlet is connected to the first water supply port 204.
  • a flowmeter 4022f is provided on the branch to monitor the pipeline flow.
  • the hypochlorous acid water generator 106 is connected to the slightly acidic hypochlorous acid water transfer storage tank 109 through a pipe 311, and the slightly acidic hypochlorous acid water transfer storage tank 109 is provided with a liquid level sensor 4021g along the height.
  • An electromagnetic three-way valve 4025g is provided at the outlet of the slightly acidic hypochlorous acid water transfer storage tank 109.
  • One of the outlets of the three-way valve is connected to the drainage pipe 202, and the other outlet is connected to the slightly acidic hypochlorous acid water storage tank 108 through the pipe 312.
  • the slightly acidic hypochlorous acid water storage tank 108 is provided with a liquid level sensor 4021h.
  • the pipe 312 is provided with a delivery pump 4023g.
  • the outlet of the slightly acidic hypochlorous acid water storage tank 108 is provided with an electromagnetic three-way valve 4025h.
  • One outlet of the three-way valve is connected to the drainage pipe 202, and the other outlet is connected to the second water supply port 205 through a pipe 313.
  • a delivery pump 4023h, a pressure switch 4027h, and a flow meter 4022h are provided on the pipeline 313 to monitor the pressure and flow, and control the actions of the delivery pump and the electromagnetic three-way valve according to the pressure and flow.
  • a solenoid valve is provided at the inlet of the corresponding water storage tank, and when the water storage tank is emptied and refilled, when the liquid level is higher than a predetermined liquid level, the controller closes the solenoid valve of the inlet.
  • a manual valve 4026 is also provided at the inlet of the corresponding water storage tank, which can manually close the water inlet of the water storage tank.
  • the slightly acidic hypochlorous acid water generating equipment is provided with a cleaning pipeline, which includes a cleaning main circuit 203 and a cleaning branch 206.
  • the cleaning main road 203 has at least one inlet and at least one outlet, each inlet is openably connected to the outlet of the corresponding water storage tank via a pipeline, and each outlet is openably connected to the corresponding purification device via a pipeline .
  • one inlet of the cleaning main road 203 is connected to the slightly acidic hypochlorous acid water storage tank, the other inlet is connected to the drinking water and/or high purity water storage tank, and one outlet thereof is connected to the inlet of the first-stage filter device 103.
  • the other inlet of the cleaning main road 203 is connected to the raw water storage tank 102, and its outlet is connected to the ultrafiltration membrane set filter and/or reverse osmosis membrane module 104 through a pipe, which is used for the ultrafiltration membrane set filter and/or The reverse osmosis membrane module 104 is flushed.
  • the pipeline is provided with a solenoid valve 4031.
  • the cleaning branch 206 is used to clean the water storage tank.
  • a delivery pump 4023 is provided on the pipeline connected to the water outlet of the water storage tank.
  • the inlet of the cleaning branch 206 is connected to the outlet of the delivery pump 4023, and the outlet thereof is connected to the inlet of the water storage tank.
  • the controller can control the opening of the delivery pump 4023 and form the flushing pressure of the cleaning pipeline.
  • the outlet of the cleaning branch 206 is connected to a flushing nozzle (not shown in the figure) inside the water storage tank through a pipe, and the flushing nozzle is arranged at an angle with the inner wall of the water storage tank.
  • the controller is arranged to be able to control the rotation of the flushing nozzle to flush the water storage tank in all directions.
  • the outlet of the cleaning branch 206 can be selectively combined with the water inlet of the water storage tank into the same one.
  • the cleaning main circuit 203 and the cleaning branch 206 are provided with solenoid valves, which are controlled to be opened or closed by the controller.
  • the water generating equipment of the present application includes a multi-stage purification device and a hypochlorous acid water generating device using the principle of quantization reaction.
  • the purification device is used to perform multi-stage purification treatment on the raw water, and each stage of the purification device is provided with a corresponding water outlet.
  • the hypochlorous acid water generating device sputters the water from the purification device to increase the specific surface area of the water, thereby generating a quantized chemical reaction, and can control H hydration protons in stages to achieve stable saturated solubility of H ions.
  • the water generating device of the present invention can be processed into slightly acidic hypochlorous acid water with stable pH, and can switch the water intake type selection according to user needs.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Plant Pathology (AREA)
  • Inorganic Chemistry (AREA)
  • Agronomy & Crop Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Water Treatment By Electricity Or Magnetism (AREA)

Abstract

Disclosed are a non-electrolytic generation of slightly acidic hypochlorous water generation apparatus, and a generation method. The generation apparatus comprises a purification device, a hypochlorous water generation device, a control system and a water outlet. The purification device performs purification treatment on raw water, the hypochlorous water generation device is disposed downstream of the purification device and comprises a reaction device, a water inlet and an additive injection device, and the control system is electrically connected to the generation device configured to precisely control the whole generation process. The generation apparatus can provide a various kinds of purified water according to user needs, and can manufacture slightly acidic hypochlorous water having a strong cohesive force, a small intermolecular adsorption force, and a very high activity by taking advantage of the nonlinear oscillation and quantum response between the purified water solution and the additive. The slightly acidic hypochlorous water has a hypochlorous acid concentration of below 200 ppm, particularly below 60 ppm, has a controlled pH in the range of 6.20 to 6.80 in which any pH fluctuations during the generation process being controlled in a narrow range of ±0.05, and can be stably stored for 18 months.

Description

非电解微酸性次氯酸水生成设备及生成方法Non-electrolytic slightly acidic hypochlorous acid water generating equipment and method
相关申请交叉引用Cross reference to related applications
本专利申请要求于2019年06月06日提交的、申请号为2019104918250、发明名称为“pH稳定的低浓度微酸性次氯酸水生产设备及生成方法”的中国专利申请,以及2019年07月29日提交的、申请号为2019106890480、发明名称为“非电解微酸性次氯酸水生成设备及生成方法”的中国专利申请的优先权,上述申请的全文以引用的方式并入本文中。This patent application requires a Chinese patent application filed on June 6, 2019, with application number 2019104918250, and invention titled "pH stable low-concentration slightly acidic hypochlorous acid water production equipment and production method", and July 2019 The priority of the Chinese patent application filed on the 29th with the application number 2019106890480 and the invention title is "Non-electrolytic slightly acidic hypochlorous acid water generation equipment and production method", the full text of the above application is incorporated herein by reference.
技术领域Technical field
本发明涉及水生成设备,具体涉及可生产各种水的微酸性次氯酸水生成设备及生成方法。The present invention relates to a water generating device, in particular to a slightly acidic hypochlorous acid water generating device and a generating method capable of producing various types of water.
背景技术Background technique
目前市售的净水设备通常采用砂滤、炭滤、软化过滤、精密过滤、超滤、反渗透过滤(RO过滤)等中一种或者少数几种方法作为水处理方法,一般只能提供某种特定类型的净化水,而不能满足在不同应用环境下对于不同水质的需求。另外,目前市售的净水设备都不能生产微酸性次氯酸水。At present, commercially available water purification equipment usually uses one or a few of sand filtration, carbon filtration, softening filtration, precision filtration, ultrafiltration, reverse osmosis filtration (RO filtration), etc. as water treatment methods. Generally, only certain A specific type of purified water cannot meet the requirements for different water quality in different application environments. In addition, none of the currently commercially available water purification equipment can produce slightly acidic hypochlorous water.
目前世界上有很多次氯酸水的生成设备和生成方法,但是生成的次氯酸水在安全性上(低浓度、pH稳定)的控制方法未见提及,而美国FDA指定的食品可接触的次氯酸水的浓度为不高于60ppm,只有低浓度的次氯酸水才可在有人的环境下大量使用,广泛应用于医疗、食品加工、公共卫生等安全性要求高的行业。At present, there are many hypochlorous acid water production equipment and production methods in the world, but the safety (low concentration, stable pH) control method of the produced hypochlorous acid water has not been mentioned, and the food specified by the US FDA can be contacted The concentration of hypochlorous acid water is not higher than 60ppm. Only low-concentration hypochlorous acid water can be used in large quantities in a human environment. It is widely used in industries with high safety requirements such as medical treatment, food processing, and public health.
发明内容Summary of the invention
本申请的目的是提供一种微酸性次氯酸水生成设备,其能够同时生产各种等级标准的净化水和微酸性次氯酸水,并设置有至少一个供水口,该供水口能够向用户提供达到不同等级标准的净化水或者微酸性次氯酸水,并能按用户需求切换取水类型。进一步地,本申请所生成的次氯酸水的浓度可以为低于200ppm,优 选地低于60ppm,pH值范围控制在6.20~6.80之间,且在此之间的任何数值上,其pH波动范围控制在±0.05的狭窄范围之内,并能稳定保存18个月。The purpose of this application is to provide a slightly acidic hypochlorous acid water generating device that can simultaneously produce various grades of purified water and slightly acidic hypochlorous acid water, and is provided with at least one water supply port that can provide users with Provide purified water or slightly acidic hypochlorous water that meets different levels of standards, and can switch the type of water intake according to user needs. Further, the concentration of hypochlorous acid water generated in the present application can be less than 200 ppm, preferably less than 60 ppm, and the pH value range is controlled between 6.20 to 6.80, and at any value in between, its pH fluctuates The range is controlled within a narrow range of ±0.05, and can be stored stably for 18 months.
为了实现上述目的,本发明提出一种微酸性次氯酸水生成设备,所述微酸性次氯酸水生成设备包括:In order to achieve the above objective, the present invention proposes a slightly acidic hypochlorous acid water generating device, which includes:
至少一级净化装置,所述净化装置用于对来自原水供应系统的原水进行净化处理且每级净化装置设置有对应的出水口;At least one level of purification device, the purification device is used to purify raw water from the raw water supply system, and each level of purification device is provided with a corresponding water outlet;
次氯酸水生成装置,所述次氯酸水生成装置位于所述净化装置下游并具有反应装置、进水口和添加剂注入装置,其中所述进水口选择性地与其中一级净化装置的出水口连接,所述添加剂注入装置用于容纳添加剂并将添加剂加入反应装置,以及所述反应装置用于将所述添加剂和来自所述净化装置的水一起加工成次氯酸水;The hypochlorous acid water generating device is located downstream of the purification device and has a reaction device, a water inlet and an additive injection device, wherein the water inlet is selectively connected to the water outlet of one of the purification devices Connected, the additive injection device is used to contain the additive and add the additive to the reaction device, and the reaction device is used to process the additive and the water from the purification device into hypochlorous water;
控制系统,所述控制系统与所述次氯酸水生成装置电连接并布置成能够控制进入所述次氯酸水生成装置的进水量和添加剂的添加量;以及A control system that is electrically connected to the hypochlorous acid water generating device and arranged to be able to control the amount of water entering the hypochlorous acid water generating device and the addition amount of additives; and
供水口,所述净化装置的出水口和所述次氯酸水生成装置的出水口通过对应的管道可切换地连接至所述供水口。A water supply port, the water outlet of the purification device and the water outlet of the hypochlorous acid water generating device are switchably connected to the water supply port through corresponding pipes.
一实施例中,所述反应装置从上游到下游依次设有至少两个反应器,所述添加剂注入装置设有至少两个添加剂注入部,其中每个所述反应器具有平行相流体部、相界面反应部和流体均质部,其中至少第一级所述反应器的平行相流体部布置成将添加剂扩散至另一液体中而形成溶液并具有进水口、添加剂注入口和出水口;所述相界面反应部布置成能够使得来自所述平行相流体部的溶液能够在所述相界面反应部内发生溅射并具有进水口和出水口;以及所述流体均质部布置成能够使得来自所述相界面反应部的溶液的均质化并具有进水口和出水口;其中每个所述添加剂注入口与对应的所述添加剂注入部连接,所述平行相流体部的出水口与所述相界面反应部的进水口连接,所述相界面反应部的出水口与所述流体均质部的进水口连接,第一级所述反应器的所述平行相流体部的进水口连接于所述净化装置的出水口,最后一级所述反应器的所述流体均质部的出水口与所述次氯酸水生成装置的出水口连接。In one embodiment, the reaction device is provided with at least two reactors in sequence from upstream to downstream, and the additive injection device is provided with at least two additive injection parts, wherein each reactor has a parallel phase fluid part and a phase An interface reaction part and a fluid homogenization part, wherein at least the parallel phase fluid part of the first-stage reactor is arranged to diffuse the additive into another liquid to form a solution and has a water inlet, an additive injection port and a water outlet; The phase interface reaction part is arranged to enable the solution from the parallel phase fluid part to be sputtered in the phase interface reaction part and has a water inlet and a water outlet; and the fluid homogenizing part is arranged to enable the solution from the The solution of the phase interface reaction part is homogenized and has a water inlet and a water outlet; wherein each of the additive injection ports is connected to the corresponding additive injection part, and the water outlet of the parallel phase fluid part is connected to the phase interface The water inlet of the reaction part is connected, the water outlet of the phase interface reaction part is connected to the water inlet of the fluid homogenizing part, and the water inlet of the parallel phase fluid part of the first-stage reactor is connected to the purification The water outlet of the device and the water outlet of the fluid homogenizing part of the reactor at the last stage are connected to the water outlet of the hypochlorous acid water generating device.
一实施例中,所述反应装置从上游到下游依次设有至少两个反应器,每个所述反应器具有平行相流体部、相界面反应部和流体均质部,其中所述平行相流体部为内部无障碍物的管路并具有与所述添加剂注入装置连接的入口,所述相界面反应部为内部布置有干扰片的管路并连接于所述平行相流体部,以及所述流体均质部为内 部无障碍物的管路并连接于所述相界面反应部。In one embodiment, the reaction device is provided with at least two reactors in sequence from upstream to downstream, and each of the reactors has a parallel phase fluid part, a phase interface reaction part and a fluid homogenization part, wherein the parallel phase fluid The part is a pipeline with no internal obstacles and has an inlet connected to the additive injection device, the phase interface reaction part is a pipeline with interfering sheets arranged inside and connected to the parallel phase fluid part, and the fluid The homogenization part is a pipeline with no internal objects and is connected to the phase interface reaction part.
一实施例中,在两个所述反应器之间还设有喷射流部,所述喷射流部布置成使得来自前一级的反应器的溶液的流速加快。In an embodiment, a jet flow part is further provided between the two reactors, and the jet flow part is arranged to increase the flow rate of the solution from the reactor of the previous stage.
一实施例中,所述喷射流部由内径由大变小的管路形成。In an embodiment, the jet flow portion is formed by a pipe whose inner diameter is changed from a larger to smaller diameter.
一实施例中,所述添加剂注入装置的最后一级所述添加剂注入部连接于所述喷射流部,从而将添加剂添加至所述喷射流部。In an embodiment, the additive injection part of the last stage of the additive injection device is connected to the jet stream part, so that the additive is added to the jet stream part.
一实施例中,所述反应装置的第一级所述反应器中,所述相界面反应部与所述流体均质部之间设有过滤器。In one embodiment, in the reactor of the first stage of the reaction device, a filter is provided between the phase interface reaction part and the fluid homogenizing part.
一实施例中,所述添加剂注入装置设有至少两个添加剂注入部,所述反应装置从上游到下游依次为第1平行相流体部、第1相界面反应部、过滤器、第1流体均质部、第2相界面反应部、喷射流部、第2平行相流体部、第3相界面反应部和第2流体均质部,其中每个所述平行相流体部布置成将来自对应的所述添加剂注入装置的添加剂喷射至另一液体中而形成稀释溶液;所述相界面反应部布置成使得来自所述平行相流体部的溶液能够在所述相界面反应部内发生溅射;所述过滤器和流体均质部布置成能够使得来自所述相界面反应部的溶液均质化;以及所述喷射流部布置成使得来自所述添加剂注入装置的添加剂喷射入所述第2平行相流体部。In one embodiment, the additive injection device is provided with at least two additive injection parts, and the reaction device from upstream to downstream is the first parallel phase fluid part, the first phase interface reaction part, the filter, and the first fluid. The mass part, the second phase interface reaction part, the jet stream part, the second parallel phase fluid part, the third phase interface reaction part and the second fluid homogenization part, wherein each of the parallel phase fluid parts is arranged to be from the corresponding The additive of the additive injection device is sprayed into another liquid to form a diluted solution; the phase interface reaction part is arranged such that the solution from the parallel phase fluid part can be sputtered in the phase interface reaction part; The filter and the fluid homogenizing part are arranged to be capable of homogenizing the solution from the phase interface reaction part; and the jet stream part is arranged so that the additive from the additive injection device is injected into the second parallel phase fluid unit.
一实施例中,所述反应装置设置成将添加剂和来自所述净化装置的水进行溅射,增加溶液的比表面积,从而产生量子化学反应,并且分级控制H水合质子,达到H离子稳定的饱和溶解度,从而加工成pH稳定的微酸性次氯酸水。这里pH稳定包含有两方面的意思,一方面是指生产稳定,即对于某个pH范围(例如6.20~6.80)内的任何一个pH值,生成过程中的微酸性次氯酸水的pH波动小,严格控制在正负0.05的狭窄区间之内。另一方面是指稳定地保存,本申请的微酸性次氯酸水在60天以上,优选地100天以上,更优选地180天以上的存储时间之后,其有效氯浓度下降率不超过10%,pH值变化范围很小,例如,在次氯酸水生成后3个月,pH从6.50变化到6.70,由此能够长时间保持其原有功效。与之对比,现有的微酸性次氯酸的有效期一般只有7~30天,这是因为现有的微酸性次氯酸水不能稳定地保存,在经过不长的一段时间后,pH变化很大,由此失去原有功效。进一步地,本申请生成的微酸性次氯酸水在存放期间(有效期内,例如3-6个月),其有效氯浓度几乎不变,而现有的其他次氯酸水在1个月内,有效氯浓度就变化很大。In one embodiment, the reaction device is configured to sputter additives and water from the purification device to increase the specific surface area of the solution, thereby generating a quantum chemical reaction, and controlling H hydration protons in stages to achieve stable saturation of H ions. Solubility, and processed into slightly acidic hypochlorous water with stable pH. Here, pH stability includes two meanings. On the one hand, it refers to stable production, that is, for any pH value within a certain pH range (for example, 6.20 to 6.80), the pH fluctuation of the slightly acidic hypochlorous acid water during the generation process is small. , Strictly controlled within the narrow interval of plus or minus 0.05. On the other hand, it refers to stable storage. After the slightly acidic hypochlorous acid water of the present application is stored for more than 60 days, preferably more than 100 days, more preferably more than 180 days, the effective chlorine concentration drop rate does not exceed 10% , The range of pH change is very small, for example, 3 months after hypochlorous acid water is generated, the pH changes from 6.50 to 6.70, which can maintain its original effect for a long time. In contrast, the effective period of the existing slightly acidic hypochlorous acid is generally only 7-30 days. This is because the existing slightly acidic hypochlorous acid water cannot be stored stably. After a short period of time, the pH changes very much. It loses its original effect. Further, the slightly acidic hypochlorous acid water generated in the present application has almost the same effective chlorine concentration during the storage period (the validity period, for example, 3-6 months), while other existing hypochlorous acid water is within 1 month , The available chlorine concentration varies greatly.
一实施例中,所述净化装置与所述反应装置之间通过管道连接,该管道上布置 有流量调节阀和第一流量传感器,所述流量调节阀和所述第一流量传感器均与所述控制系统电连接,所述控制系统布置成根据所述第一流量传感器采样的值来控制所述流量调节阀。In an embodiment, the purification device and the reaction device are connected by a pipeline, and a flow regulating valve and a first flow sensor are arranged on the pipeline, and the flow regulating valve and the first flow sensor are both connected to the A control system is electrically connected, and the control system is arranged to control the flow regulating valve according to a value sampled by the first flow sensor.
一实施例中,所述最后一级反应器的下游设有pH值传感器,所述pH值传感器与所述控制系统电连接,以及所述控制系统进一步布置成根据所述pH值传感器检测到的pH值来同时控制所述流量调节阀和所述添加剂注入部的添加剂注入量。In an embodiment, a pH sensor is provided downstream of the last-stage reactor, and the pH sensor is electrically connected to the control system, and the control system is further arranged to detect the pH value according to the pH sensor. The pH value is used to simultaneously control the flow control valve and the additive injection amount of the additive injection part.
一实施例中,所述最后一级反应器的下游设有pH值传感器,所述pH值传感器与所述控制系统电连接;所述添加剂注入部设有容器、第二流量传感器和泵,其中所述容器经由管道连接至所述泵,所述泵经由管道连接至所述反应装置,所述第二流量传感器布置于所述容器与所述泵之间的管路上,以及所述控制系统进一步布置成根据所述pH值传感器检测到的pH值和所述第二流量传感器检测到的值来同时控制所述流量调节阀和所述泵。In an embodiment, a pH sensor is provided downstream of the last-stage reactor, and the pH sensor is electrically connected to the control system; the additive injection part is provided with a container, a second flow sensor and a pump, wherein The container is connected to the pump via a pipeline, the pump is connected to the reaction device via a pipeline, the second flow sensor is arranged on the pipeline between the container and the pump, and the control system further It is arranged to simultaneously control the flow regulating valve and the pump based on the pH value detected by the pH value sensor and the value detected by the second flow sensor.
一实施例中,所述反应装置具有两个反应器,且所述添加剂注入装置具有两个添加剂注入部,其中第一个添加剂注入部用于将NaClO注入第一个反应器,第二个添加剂注入装置用于将HCl注入第二个反应器。In one embodiment, the reaction device has two reactors, and the additive injection device has two additive injection parts, wherein the first additive injection part is used to inject NaClO into the first reactor, and the second additive The injection device is used to inject HCl into the second reactor.
一实施例中,所述NaClO的浓度为12%以下,所述HCl的浓度为12%以下。In one embodiment, the concentration of the NaClO is less than 12%, and the concentration of the HCl is less than 12%.
一实施例中,所述水生成设备从上游到下游依次包括分别用于制作软化水、饮用水、RO水、EDI水以及蒸馏水的软化水净化装置、饮用水净化装置、RO水净化装置、EDI水净化装置以及蒸馏装置中至少两个,其中所述软化水净化装置、所述饮用水净化装置、所述RO水净化装置、所述EDI水净化装置以及所述蒸馏装置均通过管道和阀门与所述反应装置连接,所述控制系统进一步布置成根据水的生产要求来控制该阀门的启闭。In an embodiment, from upstream to downstream, the water generating equipment includes a softened water purification device, a drinking water purification device, an RO water purification device, and an EDI respectively used to make softened water, drinking water, RO water, EDI water, and distilled water. At least two of the water purification device and the distillation device, wherein the softened water purification device, the drinking water purification device, the RO water purification device, the EDI water purification device, and the distillation device are all connected to each other through pipes and valves The reaction device is connected, and the control system is further arranged to control the opening and closing of the valve according to water production requirements.
一实施例中,所述软化水净化装置布置成对所述原水进行砂滤、炭滤、软化和精密过滤中的至少一种处理,其中所述软化水净化装置的出水口通过管道可切换地连接至所述供水口和所述次氯酸水生成装置;所述饮用水净化装置包括超滤膜组过滤器,所述超滤膜组过滤器布置成进一步过滤来自所述软化水净化装置的水,其中所述超滤膜组过滤器的出水口通过管道可切换地连接至所述供水口和所述次氯酸水生产装置;所述RO水净化装置包括反渗透膜过滤器,所述反渗透膜过滤器位于所述超滤膜组过滤器下游并用于进一步过滤来自所述超滤膜组过滤器的水,其中所述反渗透膜过滤器的出水口通过管道可切换地连接至所述供水口和所述次氯酸 水生产装置;其中所述EDI水净化装置包括电去离子装置,所述电去离子装置位于所述反渗透膜过滤器下游并用于进一步过滤来自所述反渗透膜过滤器的水,所述电去离子装置的出水口通过管道可切换地连接至所述供水口和所述次氯酸水生成装置;所述蒸馏装置位于所述电去离子装置下游并用于进一步蒸馏来自所述电去离子装置的水,其中所述蒸馏装置的出水口通过管道可切换地连接至所述供水口和所述次氯酸水生成装置。In an embodiment, the softened water purification device is arranged to perform at least one of sand filtration, carbon filtration, softening and precision filtration on the raw water, wherein the water outlet of the softened water purification device is switchable through a pipe Connected to the water supply port and the hypochlorous water generating device; the drinking water purification device includes an ultrafiltration membrane group filter arranged to further filter the demineralized water purification device Water, wherein the water outlet of the ultrafiltration membrane group filter is switchably connected to the water supply port and the hypochlorous acid water production device through a pipe; the RO water purification device includes a reverse osmosis membrane filter, the The reverse osmosis membrane filter is located downstream of the ultrafiltration membrane set filter and is used to further filter the water from the ultrafiltration membrane set filter, wherein the water outlet of the reverse osmosis membrane filter is switchably connected to all the filters through a pipe The water supply port and the hypochlorous acid water production device; wherein the EDI water purification device includes an electrodeionization device, the electrodeionization device is located downstream of the reverse osmosis membrane filter and used for further filtering from the reverse osmosis Membrane filter water, the water outlet of the electrodeionization device is switchably connected to the water supply port and the hypochlorous acid water generating device through a pipe; the distillation device is located downstream of the electrodeionization device and is used for Further distilling water from the electrodeionization device, wherein the water outlet of the distillation device is switchably connected to the water supply port and the hypochlorous acid water generating device through a pipe.
一实施例中,所述微酸性次氯酸水生成设备进一步包括至少一个蓄水罐,至少一级所述净化装置的出水口通过管道连接有对应的蓄水罐,以及所述次氯酸水生成装置的出水口通过管道连接有对应的蓄水罐,其中各所述蓄水罐的出水口经由管道连接于所述供水口。In an embodiment, the slightly acidic hypochlorous acid water generating equipment further includes at least one water storage tank, and at least one water outlet of the purification device is connected to a corresponding water storage tank through a pipe, and the hypochlorous water The water outlet of the generating device is connected to a corresponding water storage tank via a pipe, and the water outlet of each water storage tank is connected to the water supply port via a pipe.
一实施例中,所述微酸性次氯酸水生成设备具有两个供水口,与所述净化装置的出水口连接的蓄水罐的出水口连接至其中一个供水口,与所述次氯酸水生成装置的出水口连接的蓄水罐的出水口连接至另一个供水口。In one embodiment, the slightly acidic hypochlorous acid water generating device has two water supply ports, and the water outlet of the water storage tank connected to the water outlet of the purification device is connected to one of the water supply ports, and is connected to the hypochlorous acid The outlet of the water storage tank connected to the outlet of the water generating device is connected to another water supply outlet.
一实施例中,所述蓄水罐包括去离子水蓄水罐、饮用水蓄水罐、高纯水蓄水罐、超纯水蓄水罐和蒸馏水蓄水罐中的一个或多个,其中所述去离子水蓄水罐位于所述软化水净化装置下游并用于存储来自所述软化水净化装置的去离子水;所述饮用水蓄水罐位于所述超滤膜组过滤器的下游并与所述超滤膜组过滤器的出水口连接,用于存储来自所述超滤膜组过滤器的饮用水;所述高纯水蓄水罐位于所述反渗透膜过滤器的下游并与所述反渗透膜过滤器的出水口连接,用于存储来自所述反渗透膜过滤器的高纯水;所述超纯水蓄水罐位于所述电去离子装置下游并与所述电去离子装置的出水口连接,用于存储来自所述电去离子装置的超纯水;所述蒸馏水蓄水罐位于所述蒸馏装置下游并与所述蒸馏装置的出水口连接,用于存储来自所述蒸馏装置的蒸馏水;其中所述去离子水蓄水罐、所述饮用水蓄水罐、所述高纯水蓄水罐、所述超纯水蓄水罐和所述蒸馏水蓄水罐的出水口通过管道可切换地连接至所述供水口。In an embodiment, the water storage tank includes one or more of a deionized water storage tank, a drinking water storage tank, a high-purity water storage tank, an ultra-pure water storage tank, and a distilled water storage tank, wherein the The deionized water storage tank is located downstream of the softened water purification device and used to store deionized water from the softened water purification device; the drinking water storage tank is located downstream of the ultrafiltration membrane group filter and is The water outlet of the ultrafiltration membrane set filter is connected to store drinking water from the ultrafiltration membrane set filter; the high-purity water storage tank is located downstream of the reverse osmosis membrane filter and is connected to the reverse osmosis membrane filter. The water outlet of the membrane filter is connected to store high-purity water from the reverse osmosis membrane filter; the ultra-pure water storage tank is located downstream of the electrodeionization device and connected to the water outlet of the electrodeionization device , For storing ultrapure water from the electrodeionization device; the distilled water storage tank is located downstream of the distillation device and connected to the water outlet of the distillation device, for storing distilled water from the distillation device; The outlets of the deionized water storage tank, the drinking water storage tank, the high-purity water storage tank, the ultra-pure water storage tank, and the distilled water storage tank are switchably connected to The water supply port.
一实施例中,所述控制系统布置成使得所述微酸性次氯酸水生成设备生成的次氯酸水的pH范围在6.20~6.80之间,且在此之间的任何数值上,其pH波动范围严格控制在正负0.05的狭窄范围之内。优选地,所生产的微酸性次氯酸水的pH为6.50。In an embodiment, the control system is arranged such that the pH range of the hypochlorous acid water generated by the slightly acidic hypochlorous acid water generating device is between 6.20 and 6.80, and at any value in between, its pH The fluctuation range is strictly controlled within a narrow range of plus or minus 0.05. Preferably, the pH of the slightly acidic hypochlorous acid water produced is 6.50.
一实施例中,所述控制系统进一步布置成使得所述微酸性次氯酸水生成设备生 产的次氯酸水的浓度低于200ppm,优选地低于60ppm。In an embodiment, the control system is further arranged such that the concentration of hypochlorous acid water produced by the slightly acidic hypochlorous acid water generating device is lower than 200 ppm, preferably lower than 60 ppm.
本申请还提供了一种微酸性次氯酸水生成方法,所述生成方法包括以下步骤:This application also provides a method for generating slightly acidic hypochlorous acid water, which includes the following steps:
S1、水以设定流速沿第一方向流动;S1. Water flows in the first direction at a set flow rate;
S2、沿与水的流动方向成倾斜角度的方向将含有次氯酸根的第一添加剂添加至水中;S2. Add the first additive containing hypochlorite to the water along a direction at an oblique angle to the flow direction of the water;
S3、使水和第一添加剂混合而成的溶液依次进行溅射和均质化处理而形成第一混合液;S3. The solution formed by mixing water and the first additive is sequentially subjected to sputtering and homogenization treatments to form a first mixed solution;
S4、沿与所述第一混合液的流动方向成倾斜角度的方向将含有氢离子的第二添加剂添加至第一混合液中;以及S4. Add a second additive containing hydrogen ions to the first mixed liquid along a direction at an oblique angle to the flow direction of the first mixed liquid; and
S5、使第一混合液和第二添加剂混合而成的溶液依次进行溅射和均质化处理。S5. The solution obtained by mixing the first mixed liquid and the second additive is subjected to sputtering and homogenization treatments in sequence.
一实施例中,在步骤S1之前,对水进行净化处理。In one embodiment, before step S1, the water is purified.
一实施例中,所述设定流速的范围为1~1.5m/s。In an embodiment, the range of the set flow rate is 1 to 1.5 m/s.
一实施例中,所述倾斜角度的范围为60~110度。In an embodiment, the inclination angle ranges from 60 to 110 degrees.
一实施例中,所述第一添加剂为NaClO,以及所述第二添加剂为HCl。In one embodiment, the first additive is NaClO, and the second additive is HCl.
一实施例中,所述NaClO的浓度为12%以下,所述HCl的浓度为12%以下。In one embodiment, the concentration of the NaClO is less than 12%, and the concentration of the HCl is less than 12%.
一实施例中,将所生成的微酸性次氯酸水的浓度控制在200ppm以下,优选地60ppm以下,pH范围在6.20~6.80之间,且在此之间的任何数值上,其pH波动范围控制在±0.05之内,并能稳定保存18个月。这里,稳定保存指的是18个月保存期间内,其有效氯浓度下降率不超过10%。In one embodiment, the concentration of the generated slightly acidic hypochlorous acid water is controlled below 200ppm, preferably below 60ppm, the pH range is between 6.20-6.80, and at any value in between, the pH fluctuation range Control within ±0.05, and can be stored stably for 18 months. Here, stable storage refers to the reduction rate of the effective chlorine concentration within 18 months of storage not exceeding 10%.
本申请进一步提供了一种微酸性次氯酸水生成方法,所述生成方法包括以下步骤:This application further provides a method for generating slightly acidic hypochlorous acid water, which includes the following steps:
S1.使水和含有次氯酸根的第一添加剂形成的溶液产生非线性的震荡反应,压制流体多次波动,再经均质化有序化排列整合而形成第一混合液;S1. Make the solution formed by water and the first additive containing hypochlorite produce a non-linear oscillating reaction, suppress the fluid to fluctuate many times, and then homogenize and orderly arrange and integrate to form the first mixed liquid;
S2.使得所述第一混合液和含有氢离子的第二添加剂形成的溶液进行波粒二重性的量子反应,达到H离子稳定的饱和溶解度,从而加工成pH稳定的微酸性次氯酸水。S2. Make the solution formed by the first mixed solution and the second additive containing hydrogen ions undergo a wave-particle duality quantum reaction to achieve a stable saturated solubility of H ions, thereby processing it into slightly acidic hypochlorous acid water with stable pH.
一实施例中,所述第一添加剂为NaClO,以及所述第二添加剂为HCl。In one embodiment, the first additive is NaClO, and the second additive is HCl.
一实施例中,所述NaClO的浓度为12%以下,所述HCl的浓度为12%以下。In one embodiment, the concentration of the NaClO is less than 12%, and the concentration of the HCl is less than 12%.
一实施例中,将所生成的微酸性次氯酸水的浓度控制在200ppm以下,优选地60ppm以下,pH范围在6.20~6.80之间,且在此之间的任何数值上,其pH波动 范围控制在±0.05之内,并能稳定保存18个月。In one embodiment, the concentration of the generated slightly acidic hypochlorous acid water is controlled below 200ppm, preferably below 60ppm, the pH range is between 6.20-6.80, and at any value in between, the pH fluctuation range Control within ±0.05, and can be stored stably for 18 months.
上述的生成方法均是通过非电解的方式进行。The above-mentioned production methods are all carried out in a non-electrolytic manner.
本发明带来的有益效果为:The beneficial effects brought by the present invention are:
本申请的微酸性次氯酸水生成设备能够生产多种用途的水,包括各种等级标准的净化水和各种pH值的次氯酸水,尤其是微酸性次氯酸水的浓度为60ppm以下,pH值范围在6.20~6.80之间,且在此之间的任何数值上,其pH波动范围控制在±0.05之内,并能稳定保存18个月。该次氯酸水的耐候性强,0~80℃的范围内,稳定性不衰减。本申请的微酸性次氯酸水生成设备利用流体力学反应法,能够生成以微酸性次氯酸水为主要杀菌成分的酸性水溶液。该微酸性次氯酸水溶液呈现出稳定的微酸性,对细菌和病毒等有机物具有强抑制作用,其抗抑菌效果与人体白血球产生的次氯酸一样,对人体无害,可用于外用除菌。该微酸性次氯酸水还可用于去除烟味、霉味、汗味等空气异味。此外,本发明微酸性次氯酸水生成设备具有至少一个供水口,该供水口能够根据用户需求提供达到不同等级标准的净化水或微酸性次氯酸水中的至少一种。The slightly acidic hypochlorous acid water generating equipment of the present application can produce water for various purposes, including purified water of various grades and standards and hypochlorous acid water of various pH values, especially the concentration of slightly acidic hypochlorous acid water is 60ppm Below, the pH range is between 6.20 and 6.80, and at any value in between, the pH fluctuation range is controlled within ±0.05, and it can be stored stably for 18 months. The hypochlorous acid water has strong weather resistance, and its stability does not decay in the range of 0-80°C. The slightly acidic hypochlorous acid water generating device of the present application utilizes a hydrodynamic reaction method to generate an acidic aqueous solution with slightly acidic hypochlorous acid water as the main sterilizing component. The slightly acidic hypochlorous acid aqueous solution presents a stable and slightly acidic, and has a strong inhibitory effect on bacteria and viruses and other organic substances. Its antibacterial effect is the same as the hypochlorous acid produced by human white blood cells. It is harmless to the human body and can be used for external sterilization . The slightly acidic hypochlorous acid water can also be used to remove air odors such as smoke, musty, and sweat. In addition, the slightly acidic hypochlorous acid water generating device of the present invention has at least one water supply port, which can provide at least one of purified water or slightly acidic hypochlorous acid water meeting different grade standards according to user needs.
附图说明Description of the drawings
图1是本发明的一实施例的微酸性次氯酸水生成设备的系统图。Fig. 1 is a system diagram of a slightly acidic hypochlorous acid water generating device according to an embodiment of the present invention.
图2是本发明的一实施例的微酸性次氯酸水生成设备的系统图。Fig. 2 is a system diagram of a slightly acidic hypochlorous acid water generating device according to an embodiment of the present invention.
具体实施方式Detailed ways
以下将结合附图对本发明的较佳实施例进行详细说明,以便更清楚理解本发明的目的、特点和优点。应理解的是,附图所示的实施例并不是对本发明范围的限制,而只是为了说明本发明技术方案的实质精神。Hereinafter, the preferred embodiments of the present invention will be described in detail with reference to the accompanying drawings in order to understand the purpose, features and advantages of the present invention more clearly. It should be understood that the embodiments shown in the drawings do not limit the scope of the present invention, but merely illustrate the essential spirit of the technical solution of the present invention.
在下文的描述中,出于说明各种公开的实施例的目的阐述了某些具体细节以提供对各种公开实施例的透彻理解。但是,相关领域技术人员将认识到可在无这些具体细节中的一个或多个细节的情况来实践实施例。在其它情形下,与本申请相关联的熟知的装置、结构和技术可能并未详细地示出或描述从而避免不必要地混淆实施例的描述。In the following description, for the purpose of illustrating various disclosed embodiments, certain specific details are set forth to provide a thorough understanding of various disclosed embodiments. However, those skilled in the relevant art will recognize that the embodiments may be practiced without one or more of these specific details. In other situations, well-known devices, structures, and technologies associated with this application may not be shown or described in detail to avoid unnecessarily obscuring the description of the embodiments.
除非语境有其它需要,在整个说明书和权利要求中,词语“包括”和其变 型,诸如“包含”和“具有”应被理解为开放的、包含的含义,即应解释为“包括,但不限于”。Unless the context requires otherwise, throughout the specification and claims, the word "including" and its variants, such as "including" and "having" should be understood as an open and inclusive meaning, that is, should be interpreted as "including, but not limited to".
在整个说明书中对“一个实施例”或“一实施例”的提及表示结合实施例所描述的特定特点、结构或特征包括于至少一个实施例中。因此,在整个说明书的各个位置“在一个实施例中”或“在一实施例”中的出现无需全都指相同实施例。另外,特定特点、结构或特征可在一个或多个实施例中以任何方式组合。Throughout the specification, reference to "one embodiment" or "an embodiment" means that a specific feature, structure, or characteristic described in combination with the embodiment is included in at least one embodiment. Therefore, the appearances of "in one embodiment" or "in an embodiment" in various places throughout the specification need not all refer to the same embodiment. In addition, specific features, structures, or characteristics can be combined in any manner in one or more embodiments.
如该说明书和所附权利要求中所用的单数形式“一”和“所述”包括复数指代物,除非文中清楚地另外规定。应当指出的是术语“或”通常以其包括“和/或”的含义使用,除非文中清楚地另外规定。As used in this specification and appended claims, the singular forms "a" and "the" include plural referents unless the context clearly dictates otherwise. It should be pointed out that the term "or" is usually used in its meaning including "and/or", unless the context clearly specifies otherwise.
在以下描述中,为了清楚展示本发明的结构及工作方式,将借助诸多方向性词语进行描述,但是应当将“前”、“后”、“左”、“右”、“外”、“内”、“向外”、“向内”、“上”、“下”等词语理解为方便用语,而不应当理解为限定性词语。In the following description, in order to clearly show the structure and working mode of the present invention, many directional words will be used for description, but the words "front", "rear", "left", "right", "outer", "inner" should be used. "," "outward", "inward", "上", "下" and other words are understood as convenient terms and should not be understood as restrictive terms.
图1中整体示出了本申请的一实施例的微酸性次氯酸水生成设备100。本申请的微酸性次氯酸水生成设备通过非电解的方式生产微酸性次氯酸水。微酸性次氯酸水生成设备100包括至少一级净化装置1、次氯酸水生成装置2、控制系统3以及水输出支路4。净化装置用于对来自原水供应系统的原水进行各种级别的净化处理,从而分别生成软化水、饮用水、RO水、EDI水以及蒸馏水等的一种或多种。每级净化装置设置有对应的出水口,出水口可通过管道连接于水输出支路4,用于向外部直接供水,也可以通向次氯酸水生成装置2从而进行相应的处理以形成次氯酸水,例如微酸性次氯酸水。例如,各级净化装置可以通过电控三通阀可切换地连接至次氯酸水生成装置2,以将经各级净化装置处理过的水加工成为次氯酸水。这里,原水指的是未经本申请的设备处理过的水,例如来自市政供水系统的自来水。这里,微酸性次氯酸水是指pH值范围在6.20~6.80之间的次氯酸水。优选地,微酸性次氯酸水pH为6.50。当微酸性次氯酸水的pH值在6.20~6.80之间的某个值时,其pH值的波动范围控制在正负0.05内。优选地,可以选定所需的pH值,在选定pH值下,其pH波动范围控制在正负0.05之内。FIG. 1 shows a slightly acidic hypochlorous acid water generating device 100 according to an embodiment of the present application as a whole. The slightly acidic hypochlorous acid water generating device of the present application produces slightly acidic hypochlorous acid water in a non-electrolytic manner. The slightly acidic hypochlorous acid water generating device 100 includes at least a primary purification device 1, a hypochlorous acid water generating device 2, a control system 3 and a water output branch 4. The purification device is used to perform various levels of purification treatment on the raw water from the raw water supply system to generate one or more of softened water, drinking water, RO water, EDI water, and distilled water. Each stage of the purification device is provided with a corresponding water outlet. The water outlet can be connected to the water output branch 4 through a pipe for direct water supply to the outside, or it can lead to the hypochlorous acid water generating device 2 for corresponding treatment to form a secondary Chloric acid water, such as slightly acidic hypochlorous water. For example, each level of purification device may be switchably connected to the hypochlorous acid water generating device 2 through an electronically controlled three-way valve, so as to process the water treated by the each level of purification device into hypochlorous acid water. Here, raw water refers to water that has not been treated by the equipment of this application, such as tap water from a municipal water supply system. Here, slightly acidic hypochlorous water refers to hypochlorous water with a pH value ranging from 6.20 to 6.80. Preferably, the pH of slightly acidic hypochlorous acid water is 6.50. When the pH value of slightly acidic hypochlorous acid water is between 6.20 and 6.80, the fluctuation range of its pH value is controlled within plus or minus 0.05. Preferably, the required pH value can be selected, and under the selected pH value, the pH fluctuation range is controlled within plus or minus 0.05.
本申请的次氯酸水生成装置2位于净化装置下游并具有反应装置21和22、进 水口(图未示)以及添加剂注入装置23和24。进水口选择性地与其中一级净化装置的出水口连接,从而次氯酸水生成装置2可以采用各种水来制作次氯酸水。添加剂注入装置23和24用于容纳添加剂并将添加剂,诸如NaClO和HCl,加入来自净化装置的水,从而能够生成所需pH值的次氯酸水。本实施例中,设置了2个添加剂注入装置23和24。其他实施例中,也可以设置更多的添加剂注入装置,从而根据需要加入所需的添加剂。The hypochlorous acid water generating device 2 of the present application is located downstream of the purification device and has reaction devices 21 and 22, a water inlet (not shown), and additive injection devices 23 and 24. The water inlet is selectively connected with the water outlet of the primary purification device, so that the hypochlorous acid water generating device 2 can use various types of water to produce hypochlorous acid water. The additive injection devices 23 and 24 are used to contain the additives and add the additives, such as NaClO and HCl, to the water from the purification device, so that hypochlorous acid water with a desired pH value can be generated. In this embodiment, two additive injection devices 23 and 24 are provided. In other embodiments, more additive injection devices can also be provided, so that the required additives can be added as needed.
反应装置21和22用于将添加剂和来自净化装置的水一起加工成次氯酸水。反应装置和添加剂注入装置均与控制系统电连接,从而控制系统能够控制进入次氯酸水生成装置的进水量和添加剂的添加量,以制备出符合要求的次氯酸水。本申请的反应装置能连续化制造出内聚力强、分子间吸附力小并具有很高活性的微酸性次氯酸水,并维持水保质期达二年。The reaction devices 21 and 22 are used to process the additives and the water from the purification device into hypochlorous water. The reaction device and the additive injection device are electrically connected to the control system, so that the control system can control the amount of water entering the hypochlorous acid water generating device and the amount of additives added to prepare hypochlorous acid water that meets the requirements. The reaction device of the present application can continuously produce slightly acidic hypochlorous acid water with strong cohesion, low intermolecular adsorption and high activity, and maintain the water shelf life for up to two years.
本申请的反应装置的反应原理是用流体力学的横向流体互动反应,通过改变流体的压力、密度、速度,从而包括改变水的表面张力,使得水和添加剂共同形成内聚力强、分子间吸附力小并具有很高活性的多功能性低浓度小分子团水。具体地,反应装置采用相平行射流量子无机化学反应,通过量子反应的几何学设计,用高速流动水相卷吸低浓度无机盐相,产生非线性的震荡反应,压制流体多次波动,再经均质化有序化排列整合,再通过添加含氢键化合物溶液,在波粒二重性的量子反应中智能地控制H离子达到饱和溶解度。The reaction principle of the reaction device of the present application is to use the horizontal fluid interaction reaction of hydrodynamics. By changing the pressure, density, and velocity of the fluid, which includes changing the surface tension of water, the water and additives together form a strong cohesive force and low intermolecular adsorption force. And has high activity, multi-functionality and low concentration small molecular cluster water. Specifically, the reaction device adopts a phase-parallel jet flow quantum inorganic chemical reaction. Through the geometric design of quantum reaction, the low-concentration inorganic salt phase is entrained with a high-speed flowing water phase to produce a non-linear oscillating reaction. Homogenization and orderly arrangement and integration, and then by adding a hydrogen bond compound solution, intelligently control H ions to reach saturation solubility in the wave-particle duality quantum reaction.
本申请的微酸性次氯酸生成设备还具有供水口。各级净化装置的出水口和次氯酸水生成装置的出水口可通过对应的管道可切换地连接至供水口,从而能够为用户提供各种水。The slightly acidic hypochlorous acid generating device of the present application also has a water supply port. The water outlets of the purification devices at all levels and the water outlets of the hypochlorous water generating devices can be switchably connected to the water supply outlets through corresponding pipes, so as to provide users with various water.
如图1的实施例所示,净化装置从上游到下游依次包括分别用于制作软化水、饮用水、RO水、EDI水以及蒸馏水的软化水净化装置11、饮用水净化装置12、RO水净化装置13、EDI水净化装置14以及蒸馏装置15。上述各级净化装置可以通过相应的阀门和管道可切换地连接至蓄水罐、供水口或者次氯酸水生成装置。这里,软化水指的是原水经由过滤和去钙、镁离子等处理之后形成的水。软化水净化装置11布置成对原水进行砂滤、炭滤、软化和精密过滤中的至少一种处理。饮用水指的是可以供人们直接饮用的水。饮用水净化装置12通常包括超滤膜组过滤器,超滤膜组过滤器布置成进一步过滤来自软化水净化装置的水,其中超滤膜组过滤器的出水口通过管道可切换地连接至供水口。RO水是在饮用水的基础上进一步过滤,可 以用于饮用或者医用。RO水净化装置包括反渗透膜过滤器,反渗透膜过滤器位于超滤膜组过滤器下游并用于进一步过滤来自超滤膜组过滤器的水,其中反渗透膜过滤器的出水口通过管道可切换地连接至供水口。EDI水又称超纯水,EDI水净化装置包括电去离子装置,电去离子装置位于反渗透膜过滤器下游并用于进一步过滤来自反渗透膜过滤器的水,其中电去离子装置的出水口通过管道可切换地连接至供水口。蒸馏水是在超纯水的基础上进一步蒸馏,可以用于注射、血液透析等。蒸馏装置位于电去离子装置下游并用于进一步蒸馏超纯水,其中蒸馏装置的出水口通过管道可切换地连接至供水口。As shown in the embodiment of FIG. 1, the purification device includes, from upstream to downstream, a softened water purification device 11, a drinking water purification device 12, and an RO water purification device for making softened water, drinking water, RO water, EDI water, and distilled water. Device 13, EDI water purification device 14, and distillation device 15. The above-mentioned purification devices at all levels can be switchably connected to the water storage tank, the water supply port or the hypochlorous water generating device through corresponding valves and pipes. Here, demineralized water refers to the water formed after filtering and removing calcium and magnesium ions from raw water. The softened water purification device 11 is arranged to perform at least one of sand filtration, carbon filtration, softening and precision filtration on raw water. Drinking water refers to water that can be directly consumed by people. The drinking water purification device 12 usually includes an ultrafiltration membrane group filter, which is arranged to further filter the water from the softened water purification device, wherein the water outlet of the ultrafiltration membrane group filter is switchably connected to the water supply through a pipe mouth. RO water is further filtered on the basis of drinking water and can be used for drinking or medical purposes. The RO water purification device includes a reverse osmosis membrane filter. The reverse osmosis membrane filter is located downstream of the ultrafiltration membrane filter and is used to further filter the water from the ultrafiltration membrane filter. The water outlet of the reverse osmosis membrane filter can be passed through the pipeline. Switch to connect to the water supply port. EDI water is also called ultrapure water. The EDI water purification device includes an electrodeionization device. The electrodeionization device is located downstream of the reverse osmosis membrane filter and is used to further filter the water from the reverse osmosis membrane filter. The water outlet of the electrodeionization device It is switchably connected to the water supply port through a pipe. Distilled water is further distilled on the basis of ultrapure water, and can be used for injection, hemodialysis, etc. The distillation device is located downstream of the electrodeionization device and is used to further distill ultrapure water, wherein the water outlet of the distillation device is switchably connected to the water supply port through a pipe.
具体地,图1所示的实施例中,软化水净化装置11具有增压泵11a、压力传感器11b、过滤器11c和电控三通阀11d。增压泵11a安装于过滤器11c上游的管道上,用于将原水泵至过滤器11c。压力传感器11b布置成在检测到进入过滤器11c的水压力过低时,开启增压泵11a。电控三通阀11d为电控L型三通阀,其与控制系统3电连接,由控制系统3根据水生产的要求来控制。当水生产要求为软化水直接输出和利用软化水来制作次氯酸水时,则控制系统3控制电控三通阀11d,连通到水输出支路4或者连通到次氯酸水生成装置2。当水生产要求是要对软化水进一步过滤时,则控制系统3控制电控三通阀11d连通至下一级净化装置。这里,过滤器11c布置成进行砂滤、炭滤、软化以及精密过滤中的至少一种处理。较佳地,过滤器11c至少包括软化过滤,并形成去离子水。根据原水的水质状况,过滤器11c可包括砂炭过滤器、软化过滤器以及精密过滤器中的任意一个或两个的组合。砂炭过滤器用于去除自来水中的大颗粒物质和杂质及改善水的口感。软化过滤器则用于去除水中的钙镁离子,调节水的软硬度。精密过滤器可去除水中通常砂滤和炭滤所不能去除的微细悬浮物或胶体粒子。Specifically, in the embodiment shown in FIG. 1, the demineralized water purification device 11 has a booster pump 11a, a pressure sensor 11b, a filter 11c and an electronically controlled three-way valve 11d. The booster pump 11a is installed on the pipeline upstream of the filter 11c, and is used to pump raw water to the filter 11c. The pressure sensor 11b is arranged to turn on the booster pump 11a when detecting that the pressure of the water entering the filter 11c is too low. The electronically controlled three-way valve 11d is an electronically controlled L-shaped three-way valve, which is electrically connected to the control system 3 and controlled by the control system 3 according to the requirements of water production. When water production requires direct output of softened water and the use of softened water to produce hypochlorous water, the control system 3 controls the electronically controlled three-way valve 11d, which is connected to the water output branch 4 or connected to the hypochlorous water generating device 2 . When the water production requirement is to further filter the softened water, the control system 3 controls the electronically controlled three-way valve 11d to connect to the next-stage purification device. Here, the filter 11c is arranged to perform at least one of sand filtration, carbon filtration, softening, and precision filtration. Preferably, the filter 11c includes at least softening filtration and forming deionized water. According to the water quality of the raw water, the filter 11c may include any one or a combination of two of a sand charcoal filter, a softening filter, and a precision filter. The sand charcoal filter is used to remove large particles and impurities in tap water and improve the taste of water. The softening filter is used to remove calcium and magnesium ions in the water and adjust the hardness of the water. The precision filter can remove the fine suspended solids or colloidal particles that usually cannot be removed by sand filtration and carbon filtration.
饮用水净化装置12具有过滤器12a和过滤器出口处的电控三通阀12b。过滤器12a连接于上一级软化水净化装置11并布置成对软化水进行过滤。电控三通阀12b为电控L型三通阀,其与控制系统3电连接,由控制系统3根据水生产的要求来控制。当水生产要求为饮用水直接输出和利用饮用水来制作次氯酸水时,则控制系统3控制该电控三通阀12b,连通到水输出支路4或者连通到次氯酸水生成装置2。当水生产要求是要对饮用水进一步过滤时,则控制系统3控制电控三通阀12b连通至下一级净化装置。过滤器12a为超滤膜组过滤器,其具有熔喷滤芯,用于进一步过滤来自软化水净化装置的水。经超滤膜组过滤器处理过的水为超滤水。熔喷滤芯的 过滤孔径为约0.01微米,超滤水中被进一步去除了细菌、铁锈、胶体及有机物等杂质,但保留了水中溶解氧及人体所需微量矿物质等营养成分,水质达到我国当前直饮水标准可用于幼儿园、医院、养老院、酒店餐饮等行业,具体在除菌保鲜、食品加工、抗病毒、洗漱等多方面具有重要作用。The drinking water purification device 12 has a filter 12a and an electronically controlled three-way valve 12b at the outlet of the filter. The filter 12a is connected to the upper-level demineralized water purification device 11 and is arranged to filter demineralized water. The electronically controlled three-way valve 12b is an electronically controlled L-type three-way valve, which is electrically connected to the control system 3 and controlled by the control system 3 according to the requirements of water production. When water production requires direct output of drinking water and the use of drinking water to produce hypochlorous acid water, the control system 3 controls the electronically controlled three-way valve 12b to connect to the water output branch 4 or to the hypochlorous water generating device 2. When the water production requirement is to further filter the drinking water, the control system 3 controls the electronically controlled three-way valve 12b to connect to the next-stage purification device. The filter 12a is an ultrafiltration membrane group filter, which has a melt blown filter element for further filtering the water from the softened water purification device. The water treated by the ultrafiltration membrane group filter is ultrafiltration water. The filter pore size of the melt-blown filter element is about 0.01 microns. The ultrafiltration water is further removed from impurities such as bacteria, rust, colloids and organic matter, but it retains dissolved oxygen in the water and nutrients such as trace minerals required by the human body. The water quality reaches the current level of my country. Drinking water standards can be used in kindergartens, hospitals, nursing homes, hotels, catering and other industries, and play an important role in many aspects such as sterilization and preservation, food processing, anti-virus, and washing.
RO水净化装置13具有增压泵13a、压力传感器13b、过滤器13c和电控三通阀13d。增压泵13a安装于过滤器13c上游的管道上,用于将上一级净化装置出来的水泵至过滤器13c。压力传感器13b布置成在检测到进入过滤器13c的水压力过低时,开启增压泵13a。电控三通阀13d为电控L型三通阀,其与控制系统3电连接,由控制系统根据水生产的要求来控制。当水生产要求为RO水直接输出和利用RO水来制作次氯酸水时,则控制系统3控制电控三通阀13d,连通到水输出支路4或者连通到次氯酸水生成装置2。当水生产要求是要对RO水进一步过滤或处理时,则控制系统3控制电控三通阀13d连通至下一级净化装置。过滤器13c包括反渗透膜组件,经反渗透膜组件处理过的水为高纯水(又称RO水),可达到高纯水标准,其基本不保留水中的矿物质,pH值在6-7之间,为弱酸性,可以作为原液或者原材生产卫生用品、皮肤黏膜消毒剂、漱口水等消毒产品。反渗透膜组件膜孔径比超滤膜更小,可用于进一步过滤来自过滤器11c或者超滤膜组过滤器处理过的水。The RO water purification device 13 has a booster pump 13a, a pressure sensor 13b, a filter 13c, and an electronically controlled three-way valve 13d. The booster pump 13a is installed on the pipeline upstream of the filter 13c, and is used to pump the water from the upper-level purification device to the filter 13c. The pressure sensor 13b is arranged to turn on the booster pump 13a when it detects that the pressure of the water entering the filter 13c is too low. The electronically controlled three-way valve 13d is an electronically controlled L-type three-way valve, which is electrically connected to the control system 3, and is controlled by the control system according to the requirements of water production. When the water production requirement is the direct output of RO water and the use of RO water to produce hypochlorous acid water, the control system 3 controls the electronically controlled three-way valve 13d, which is connected to the water output branch 4 or connected to the hypochlorous acid water generating device 2 . When the water production requirement is to further filter or process the RO water, the control system 3 controls the electronically controlled three-way valve 13d to connect to the next-stage purification device. The filter 13c includes a reverse osmosis membrane module. The water treated by the reverse osmosis membrane module is high-purity water (also known as RO water), which can reach the standard of high-purity water. It basically does not retain minerals in the water, and the pH value is between 6-7. It is weakly acidic and can be used as a stock solution or raw material to produce sanitary products, skin and mucous membrane disinfectants, mouthwashes and other disinfectants. The membrane pore size of the reverse osmosis membrane module is smaller than that of the ultrafiltration membrane, and can be used to further filter the water treated by the filter 11c or the ultrafiltration membrane group filter.
EDI水净化装置14具有增压泵14a、压力传感器14b、电去离子装置14c(又称EDI装置)和至少一个电控三通阀14d。增压泵14a安装于电去离子装置14c上游的管道上,用于将上一级净化装置出来的水泵至电去离子装置14c。压力传感器14b布置成在检测到进入电去离子装置14c的水压力过低时,开启增压泵14a。电控三通阀14d为电控L型三通阀,其与控制系统3电连接,由控制系统根据水生产的要求来控制。当水生产要求为超纯水直接输出和利用超纯水来制作次氯酸水时,则控制系统3控制电控三通阀14d,连通到水输出支路4或者连通到次氯酸水生成装置2。当水生产要求是要对EDI水作进一步其他处理时,则控制系统3控制电控三通阀14d连通至下一级净化装置。在EDI装置中,在电场的作用下实现水中离子的定向迁移,从而达到水的深度净化除盐,因此,EDI水称为超纯水(EDI水),可广泛应用于电力、电子、医药、化工、光学仪器和实验室领域。被EDI装置处理过的水主要用于生成蒸馏水,用于注射、血液透析等。The EDI water purification device 14 has a booster pump 14a, a pressure sensor 14b, an electrodeionization device 14c (also called an EDI device) and at least one electronically controlled three-way valve 14d. The booster pump 14a is installed on the pipeline upstream of the electrodeionization device 14c, and is used to pump the water from the previous purification device to the electrodeionization device 14c. The pressure sensor 14b is arranged to turn on the booster pump 14a when it detects that the pressure of the water entering the electrodeionization device 14c is too low. The electronically controlled three-way valve 14d is an electronically controlled L-type three-way valve, which is electrically connected to the control system 3, and is controlled by the control system according to the requirements of water production. When water production requires direct output of ultrapure water and the use of ultrapure water to produce hypochlorous water, the control system 3 controls the electronically controlled three-way valve 14d, which is connected to the water output branch 4 or connected to the hypochlorous water generation Device 2. When the water production requirement is to further process the EDI water, the control system 3 controls the electronically controlled three-way valve 14d to connect to the next-level purification device. In the EDI device, the directional migration of ions in the water is realized under the action of the electric field, so as to achieve the deep purification and desalination of water. Therefore, EDI water is called ultrapure water (EDI water), which can be widely used in electricity, electronics, medicine, Chemical, optical instruments and laboratory fields. The water treated by the EDI device is mainly used to produce distilled water for injection, hemodialysis, etc.
蒸馏装置15具有增压泵15a、压力传感器15b和蒸馏装置15c。增压泵15a安装于蒸馏装置15c上游的管道上,用于将上一级净化装置出来的水泵至蒸馏装置 15c。压力传感器15b布置成在检测到进入蒸馏装置15c的水压力过低时,开启增压泵15a。蒸馏装置15c连通到水输出支路4或者连通到次氯酸水生成装置2。The distillation device 15 has a booster pump 15a, a pressure sensor 15b, and a distillation device 15c. The booster pump 15a is installed on the pipeline upstream of the distillation device 15c, and is used to pump the water from the upper-level purification device to the distillation device 15c. The pressure sensor 15b is arranged to turn on the booster pump 15a when it detects that the pressure of the water entering the distillation device 15c is too low. The distillation device 15c is connected to the water output branch 4 or to the hypochlorous acid water generating device 2.
如图1所示,较佳地,净化装置1可经由减压阀41和电控三通阀42连接至次氯酸水生成装置2和水输出支路4。具体地,当需要制作次氯酸水时,则控制系统3控制电控三通阀42,使得净化装置1的出口连通于次氯酸水生成装置2。当需要将来自净化装置的水直接输入至微酸性次氯酸水生成设备的供水口时,则控制系统3控制电控三通阀42,使得净化装置1的出口连通于水输出支路4,并通过水输出支路4将相应的水供应至微酸性次氯酸水生成设备的供水口。As shown in FIG. 1, preferably, the purification device 1 can be connected to the hypochlorous acid water generating device 2 and the water output branch 4 via a pressure reducing valve 41 and an electronically controlled three-way valve 42. Specifically, when hypochlorous acid water needs to be produced, the control system 3 controls the electronically controlled three-way valve 42 so that the outlet of the purification device 1 is connected to the hypochlorous acid water generating device 2. When it is necessary to directly input the water from the purification device to the water supply port of the slightly acidic hypochlorous acid water generating equipment, the control system 3 controls the electronically controlled three-way valve 42 so that the outlet of the purification device 1 is connected to the water output branch 4. And through the water output branch 4, the corresponding water is supplied to the water supply port of the slightly acidic hypochlorous acid water generating device.
水输出支路4具有蓄水罐43,用于存储从净化装置出来的水。蓄水罐43的数量可以是一个或多个。各净化装置的出水口通过管道连接有对应的蓄水罐。蓄水罐43的出水口经由管道等最终通向供水口。蓄水罐可包括去离子水蓄水罐、饮用水蓄水罐、高纯水蓄水罐和超纯水蓄水罐中的一个或多个,其中去离子水蓄水罐位于软化水净化装置下游并用于存储来自软化水净化装置的去离子水。饮用水蓄水罐位于超滤膜组过滤器的下游并与饮用水净化装置的超滤膜组过滤器的出水口连接,用于存储来自超滤膜组过滤器的饮用水。高纯水蓄水罐位于反渗透膜过滤器的下游并与反渗透膜过滤器的出水口连接,用于存储来自反渗透膜过滤器的高纯水(RO水)。超纯水蓄水罐位于电去离子装置下游并与电去离子装置的出水口连接,用于存储来自电去离子装置的超纯水。蒸馏水蓄水罐位于蒸馏装置下游并与蒸馏装置的出水口连接,用于存储来自蒸馏装置的蒸馏水。去离子水蓄水罐、饮用水蓄水罐、高纯水蓄水罐、超纯水蓄水罐和蒸馏水蓄水罐的出水口可通过管道可切换地连接至供水口。The water output branch 4 has a water storage tank 43 for storing water from the purification device. The number of water storage tanks 43 may be one or more. The water outlet of each purification device is connected with a corresponding water storage tank through a pipe. The water outlet of the water storage tank 43 finally leads to the water supply port via a pipe or the like. The storage tank may include one or more of a deionized water storage tank, a drinking water storage tank, a high-purity water storage tank, and an ultra-pure water storage tank, wherein the deionized water storage tank is located downstream of the softened water purification device and used To store deionized water from the demineralized water purification device. The drinking water storage tank is located downstream of the ultrafiltration membrane filter and is connected to the outlet of the ultrafiltration membrane filter of the drinking water purification device, and is used to store drinking water from the ultrafiltration membrane filter. The high-purity water storage tank is located downstream of the reverse osmosis membrane filter and is connected to the water outlet of the reverse osmosis membrane filter for storing high-purity water (RO water) from the reverse osmosis membrane filter. The ultrapure water storage tank is located downstream of the electrodeionization device and is connected to the water outlet of the electrodeionization device, and is used to store the ultrapure water from the electrodeionization device. The distilled water storage tank is located downstream of the distillation device and connected to the water outlet of the distillation device for storing distilled water from the distillation device. The outlets of deionized water storage tanks, drinking water storage tanks, high-purity water storage tanks, ultra-pure water storage tanks, and distilled water storage tanks can be switchably connected to the water supply ports through pipes.
在蓄水罐43内设有液位传感器44。控制系统3可根据目前液位传感器44检测到的蓄水罐液位,判断目前生产流程,对电控三通阀42进行控制。水输出支路4可设有位于蓄水罐下游的热水器45。热水器45设有温度传感器46。控制系统3根据设定值以及温度传感器46采样的当前水温,来控制热水器45的开关。在热水器45下游可设有灭菌器47。控制系统3按照水生产控制要求,在出水时控制灭菌器47打开,停止出水时控制灭菌器47关闭。灭菌器47的出口可连接有相应的电控三通阀,例如软化水电控三通阀48、饮用水电控三通阀49、RO水电控三通阀50、EDI水电控三通阀51以及蒸馏水电控三通阀52。控制系统3按照水生产控制要求,控制各电控三通阀48、49、50、51和52的开启和关闭。各电控三通阀均可通向各 自的供水口53、54、55、56和57。上述的电控三通阀48、49、50、51和52可以共用,即仅设置一个电动三通阀。上述的供水口53、54、55、56和57也可以共用,即仅设置一个供水口。一实施例中,也可以不设置上述的蓄水罐、热水器和灭菌器中的一个或多个。A liquid level sensor 44 is provided in the water storage tank 43. The control system 3 can judge the current production process according to the current level of the water storage tank detected by the current level sensor 44 and control the electronically controlled three-way valve 42. The water output branch 4 may be provided with a water heater 45 located downstream of the water storage tank. The water heater 45 is provided with a temperature sensor 46. The control system 3 controls the switch of the water heater 45 according to the set value and the current water temperature sampled by the temperature sensor 46. A sterilizer 47 may be provided downstream of the water heater 45. According to the water production control requirements, the control system 3 controls the sterilizer 47 to open when the water is discharged, and controls the sterilizer 47 to close when the water is stopped. The outlet of the sterilizer 47 can be connected with corresponding electronically controlled three-way valves, such as softened water electronically controlled three-way valves 48, drinking water electronically controlled three-way valves 49, RO water electronically controlled three-way valves 50, EDI water electronically controlled three-way valves A through valve 51 and a distilled water electronically controlled three-way valve 52. The control system 3 controls the opening and closing of the electronically controlled three- way valves 48, 49, 50, 51 and 52 in accordance with the water production control requirements. Each electronically controlled three-way valve can lead to its own water supply ports 53, 54, 55, 56 and 57. The above-mentioned electronically controlled three- way valves 48, 49, 50, 51 and 52 can be shared, that is, only one electric three-way valve is provided. The aforementioned water supply ports 53, 54, 55, 56 and 57 can also be shared, that is, only one water supply port is provided. In an embodiment, one or more of the above-mentioned water storage tank, water heater and sterilizer may not be provided.
进一步参见图1,次氯酸水生成装置2的进水口处设有流量调节阀2a,电磁阀2b和第一流量传感器2c。控制系统3根据第一流量传感器2c采样的值,按照工艺要求,控制流量调节阀2a的开启程度。控制系统3按照系统设定以及其他一些参数来控制电磁阀2b的启闭,下面将进一步详细说明。次氯酸水生成装置2的反应装置从上游到下游依次设有两个反应器21、22。添加剂注入装置设有两个添加剂注入部23和24。来自添加剂注入部的添加剂被添加至相应的反应器,以进行相应的反应,从而生产所需的溶液,比如微酸性次氯酸水。Further referring to FIG. 1, the water inlet of the hypochlorous acid water generating device 2 is provided with a flow regulating valve 2a, a solenoid valve 2b and a first flow sensor 2c. The control system 3 controls the opening degree of the flow regulating valve 2a according to the value sampled by the first flow sensor 2c and the process requirements. The control system 3 controls the opening and closing of the solenoid valve 2b according to system settings and other parameters, which will be described in further detail below. The reaction device of the hypochlorous acid water generator 2 is provided with two reactors 21 and 22 in sequence from upstream to downstream. The additive injection device is provided with two additive injection parts 23 and 24. The additive from the additive injection part is added to the corresponding reactor to carry out the corresponding reaction to produce the required solution, such as slightly acidic hypochlorous water.
本实施例中,次氯酸水生成装置2具有两个反应器21和22。反应器21具有平行相流体部21a、相界面反应部21b和流体均质部21d。反应器21的平行相流体部21a布置成将第一添加剂(例如NaClO)扩散至另一液体中而形成溶液并具有进水口、添加剂注入口和出水口。具体地,平行相流体部21a布置成使得来自第一添加剂注入部的第一添加剂,诸如次氯酸钠,凭借自身的扩散力在来自净化装置的水中自然扩散。平行相流体部21a可以是一段管路,其内部没有设置任何障碍物。通过这种方式,可以将浓度高的添加剂原液首先自然扩散并使浓度降低,从而防止无用的反应。第一添加剂添加至水的方向与水的流动方向成倾斜角度,该倾斜角度可以是任何合适的角度,例如60~110度。In this embodiment, the hypochlorous acid water generator 2 has two reactors 21 and 22. The reactor 21 has a parallel phase fluid part 21a, a phase interface reaction part 21b, and a fluid homogenizing part 21d. The parallel phase fluid portion 21a of the reactor 21 is arranged to diffuse the first additive (for example, NaClO) into another liquid to form a solution, and has a water inlet, an additive injection port, and a water outlet. Specifically, the parallel phase fluid part 21a is arranged such that the first additive from the first additive injection part, such as sodium hypochlorite, naturally diffuses in the water from the purification device by virtue of its own diffusive force. The parallel phase fluid part 21a may be a section of pipeline without any obstacles inside. In this way, the additive stock solution with high concentration can first diffuse naturally and reduce the concentration, thereby preventing useless reactions. The direction in which the first additive is added to the water forms an oblique angle with the flow direction of the water, and the oblique angle may be any suitable angle, for example, 60 to 110 degrees.
相界面反应部21b布置成能够使得来自平行相流体部21a的溶液能够在相界面反应部21b内发生溅射并具有进水口和出水口。相界面反应部21b的进水口与平行相流体部21a的出水口连接。相界面反应部21b布置成促使添加剂在相界面反应部中进一步扩散。相界面反应部可以是内部布置有干扰片的管路。水和添加剂形成的混合液在流经相界面反应部时,会碰撞干扰片,由此促进添加剂在水中的扩散。The phase interface reaction part 21b is arranged to enable the solution from the parallel phase fluid part 21a to be sputtered in the phase interface reaction part 21b and has a water inlet and a water outlet. The water inlet of the phase interface reaction part 21b is connected to the water outlet of the parallel phase fluid part 21a. The phase interface reaction part 21b is arranged to promote further diffusion of the additive in the phase interface reaction part. The phase interface reaction part may be a pipeline with interference sheets arranged inside. When the mixed liquid formed by the water and the additive flows through the phase interface reaction part, it will collide with the interference plate, thereby promoting the diffusion of the additive in the water.
流体均质部21d布置成能够使得来自相界面反应部21b的溶液均质化并具有进水口和出水口,流体均质部的进水口与相界面反应部的出水口连接。流体均质部21d可以是一段管路,其内部没有设置任何障碍物。The fluid homogenizing part 21d is arranged to be able to homogenize the solution from the phase interface reaction part 21b and has a water inlet and a water outlet, and the water inlet of the fluid homogenizing part is connected with the water outlet of the phase interface reaction part. The fluid homogenizing part 21d may be a section of pipeline without any obstacles in it.
如图1所示,本实施例中,反应器21的相界面反应部21b与流体均质部21d之间还设有过滤器21c。过滤器21c可以阻止垃圾、空气,还可以使得溶液均质化, 同时使得分子由大变小,也可以使生成水的流速均质化,使其趋于稳定。根据需要,也可以不设置过滤器21c。从反应器21出来的液体为第一混合液。As shown in FIG. 1, in this embodiment, a filter 21c is also provided between the phase interface reaction part 21b and the fluid homogenizing part 21d of the reactor 21. The filter 21c can prevent garbage and air, and can also homogenize the solution, and at the same time make molecules from large to small, and can also homogenize the flow rate of the generated water to stabilize it. If necessary, the filter 21c may not be provided. The liquid coming out of the reactor 21 is the first mixed liquid.
类似地,反应器22具有平行相流体部22a、相界面反应部22b和流体均质部22c。反应器22的平行相流体部22a布置成将第二添加剂(例如HCl)扩散至另一液体(例如第一混合液)中而形成溶液并具有进水口和出水口。具体地,平行相流体部布置成使得来自第二添加剂注入部的第二添加剂,诸如盐酸,凭借自身的扩散力在来自反应器21的溶液中自然扩散。平行相流体部可以是一段管路,其内部没有设置任何障碍物。通过这种方式,可以将浓度高的添加剂原液首先自然扩散并使浓度降低,从而防止无用的反应。第二添加剂添加至第一混合液的方向与第一混合液的流动方向成倾斜角度,该倾斜角度可以是任何合适的角度,例如60~110度。Similarly, the reactor 22 has a parallel phase fluid part 22a, a phase interface reaction part 22b, and a fluid homogenizing part 22c. The parallel phase fluid portion 22a of the reactor 22 is arranged to diffuse the second additive (for example, HCl) into another liquid (for example, the first mixed liquid) to form a solution, and has a water inlet and a water outlet. Specifically, the parallel phase fluid part is arranged so that the second additive from the second additive injection part, such as hydrochloric acid, naturally diffuses in the solution from the reactor 21 by virtue of its own diffusion force. The parallel phase fluid part can be a section of pipeline without any obstacles inside. In this way, the additive stock solution with high concentration can first diffuse naturally and reduce the concentration, thereby preventing useless reactions. The direction in which the second additive is added to the first mixed liquid forms an oblique angle with the flow direction of the first mixed liquid, and the oblique angle may be any suitable angle, for example, 60 to 110 degrees.
相界面反应部22b布置成能够使得来自平行相流体部的溶液能够在相界面反应部内发生溅射并具有进水口和出水口。相界面反应部22b的进水口与平行相流体部21a的出水口连接。相界面反应部22b布置成促使第二添加剂在相界面反应部22b中进一步扩散。相界面反应部22b可以是内部布置有干扰片的管路。水、第一添加剂和第二添加剂的混合液在流经相界面反应部时,会碰撞干扰片,由此促进添加剂在水中的扩散。The phase interface reaction part 22b is arranged to enable the solution from the parallel phase fluid part to be sputtered in the phase interface reaction part and has a water inlet and a water outlet. The water inlet of the phase interface reaction part 22b is connected to the water outlet of the parallel phase fluid part 21a. The phase interface reaction part 22b is arranged to promote further diffusion of the second additive in the phase interface reaction part 22b. The phase interface reaction part 22b may be a pipe in which interference pieces are arranged. When the mixed liquid of water, the first additive and the second additive flows through the phase interface reaction part, it will collide with the interference plate, thereby promoting the diffusion of the additive in the water.
流体均质部22c布置成能够使得来自相界面反应部22b的溶液均质化并具有进水口和出水口,流体均质部的进水口与相界面反应部的出水口连接。流体均质部22c可以是一段管路,其内部没有设置任何障碍物。The fluid homogenizing part 22c is arranged to be able to homogenize the solution from the phase interface reaction part 22b and has a water inlet and a water outlet, and the water inlet of the fluid homogenizing part is connected with the water outlet of the phase interface reaction part. The fluid homogenizing part 22c may be a section of pipeline without any obstacles inside.
如图1所示,本实施例中,在反应器21与反应器22之间还依次设有相界面反应部2d和喷射流部2e。相界面反应部2d与相界面反应部21b结构和功能类似,都是促使添加剂进一步扩散,并且可以由内部设有干扰片的管道构成。As shown in FIG. 1, in this embodiment, a phase interface reaction part 2d and a jet flow part 2e are sequentially provided between the reactor 21 and the reactor 22. The phase interface reaction part 2d is similar in structure and function to the phase interface reaction part 21b, both of which promote the further diffusion of additives, and can be constituted by a pipe with interfering sheets inside.
该喷射流部2e设置了添加剂注入口。来自添加剂注入部的添加剂可以通过该添加剂注入口进入喷射流部。喷射流部布置成使得来自前一级反应器的溶液的流速增加。由此,添加剂,例如盐酸,可被迅速稀释,从而该添加剂与前一级反应器的溶液中的第一添加剂,例如次氯酸钠,几乎没有反应的余地。喷射流部2e可以是管内径由大变小的一段管道。水流经该管道时,速度变快。喷射流部还可以是能够使得水流加快的其他结构。The injection stream portion 2e is provided with an additive injection port. The additive from the additive injection part can enter the jet stream part through the additive injection port. The jet stream portion is arranged so that the flow rate of the solution from the previous-stage reactor increases. Thus, the additive, such as hydrochloric acid, can be quickly diluted, so that the additive has little room for reaction with the first additive in the solution of the previous stage reactor, such as sodium hypochlorite. The jet portion 2e may be a section of pipe whose inner diameter changes from large to small. When water flows through the pipe, the speed becomes faster. The jet flow part may also have another structure that can accelerate the water flow.
在一些情况下,也可以不设置喷射流部2e。如果同时设置有喷射流部2e和反应器22,则来自添加剂注入部的添加剂先加入至喷射流部并与来自前一级反应器的 溶液混合后,再进入反应器22。如果仅设置反应器22,而不设置喷射流部,则来自添加剂注入部的添加剂直接进入反应器22的平行相流体部,并与来自前一级反应器的溶液混合。In some cases, the jet portion 2e may not be provided. If the jet stream part 2e and the reactor 22 are provided at the same time, the additive from the additive injection part is first added to the jet stream part and mixed with the solution from the previous reactor before entering the reactor 22. If only the reactor 22 is provided without the jet stream part, the additive from the additive injection part directly enters the parallel phase fluid part of the reactor 22 and is mixed with the solution from the previous stage reactor.
上述的反应装置由多个反应器以及可选的过滤器和喷射流部等构成。各个反应器内部的各个部分及反应器之间具有相应的入口和出口。这些相互连接的入口和出口可以是分开的入口和出口,也可以是相同的部分,即入口和出口实际上是同一部位,例如反应器由一根管子构成时,相邻各部分之间的入口和出口实际上是同一部位。一实施例中,反应装置从上游到下游依次为第1平行相流体部、第1相界面反应部、过滤器、第1流体均质部、第2相界面反应部、喷射流部、第2平行相流体部、第3相界面反应部和第2流体均质部,其中每个所述平行相流体部布置成将来自对应的所述添加剂注入装置的添加剂喷射至另一液体中而形成稀释溶液;所述相界面反应部布置成使得来自所述平行相流体部的溶液能够在所述相界面反应部内发生溅射;所述过滤器和流体均质部布置成能够使得来自所述相界面反应部的溶液均质化;以及所述喷射流部布置成使得来自所述添加剂注入装置的添加剂喷射入所述第2平行相流体部。The above-mentioned reaction device is composed of a plurality of reactors, optional filters and jets. Corresponding inlets and outlets are provided between the various parts within each reactor and between the reactors. These interconnected inlets and outlets can be separate inlets and outlets, or they can be the same part, that is, the inlet and outlet are actually the same part. For example, when the reactor is composed of a pipe, the gap between adjacent parts The entrance and exit are actually the same part. In one embodiment, the reaction device from upstream to downstream is the first parallel phase fluid part, the first phase interface reaction part, the filter, the first fluid homogenization part, the second phase interface reaction part, the jet flow part, and the second The parallel phase fluid part, the third phase interface reaction part and the second fluid homogenization part, wherein each of the parallel phase fluid parts is arranged to spray the additive from the corresponding additive injection device into another liquid to form a dilution The phase interface reaction part is arranged so that the solution from the parallel phase fluid part can be sputtered in the phase interface reaction part; the filter and the fluid homogenizing part are arranged so that the solution from the phase interface The solution in the reaction part is homogenized; and the jet stream part is arranged so that the additive from the additive injection device is jetted into the second parallel phase fluid part.
最后一级反应器22的下游设有pH值传感器58。pH值传感器与控制系统3电连接。控制系统3布置成根据pH值传感器检测到的pH值来同时控制流量调节阀2a和添加剂注入部的添加剂注入量,从而得到所需pH值的溶液。进一步地,控制器接收来自第一流量传感器2c检测到的流量和pH值传感器检测到的pH值,来控制添加剂注入部的添加剂注入量,将pH值调节到所设定的pH值区间内,该pH值区间可以是6.20~6.80。在调节之后,所得到的微酸性次氯酸水的pH值为该pH值区间中的某个值(该值可以不是预先设定的),例如pH=6.30,并且在达到该pH值后,微酸性次氯酸水的pH值波动范围控制在正负0.05之内。当无法调节到所设定区间(6.20~6.80)的pH时,则发出停机报警信号。A pH sensor 58 is provided downstream of the last-stage reactor 22. The pH sensor is electrically connected to the control system 3. The control system 3 is arranged to simultaneously control the flow regulating valve 2a and the additive injection amount of the additive injection part according to the pH value detected by the pH sensor, so as to obtain a solution with a desired pH value. Further, the controller receives the flow rate detected by the first flow sensor 2c and the pH value detected by the pH value sensor to control the additive injection amount of the additive injection part, and adjust the pH value to within the set pH value range, The pH range can be 6.20 to 6.80. After the adjustment, the pH value of the obtained slightly acidic hypochlorous acid water is a certain value in the pH value range (the value may not be preset), for example, pH=6.30, and after reaching the pH value, The pH fluctuation range of slightly acidic hypochlorous acid water is controlled within plus or minus 0.05. When the pH cannot be adjusted to the set interval (6.20~6.80), a shutdown alarm signal will be issued.
添加剂注入部23和24分别用于注入两种不同的添加剂。添加剂注入部23具有第一容器23a,其用于容纳添加剂,诸如次氯酸钠。添加剂注入部23设有第二流量传感器23b,其用于测量添加剂的添加量并与控制系统电连接。添加剂注入部23还设有泵23c和注入单元23d,用于将添加剂注入到反应器。控制系统根据pH值传感器58和第二流量传感器23b所采样的数据,根据水的生产要求来控制泵23c,从而将所需数量的添加剂添加至反应器。The additive injection parts 23 and 24 are used to inject two different additives, respectively. The additive injection part 23 has a first container 23a for containing additives such as sodium hypochlorite. The additive injection part 23 is provided with a second flow sensor 23b, which is used to measure the additive amount of the additive and is electrically connected to the control system. The additive injection part 23 is also provided with a pump 23c and an injection unit 23d for injecting the additive into the reactor. The control system controls the pump 23c according to the data sampled by the pH sensor 58 and the second flow sensor 23b, and according to the water production requirements, so as to add the required amount of additives to the reactor.
添加剂注入部24具有第二容器24a,其用于容纳添加剂,诸如盐酸。添加剂注入部24设有第二流量传感器24b,其用于测量添加剂的添加量并与控制系统电连接。添加剂注入部24还设有泵24c和注入单元24d,用于将添加剂注入到反应器。控制系统根据pH值传感器58和第二流量传感器24b所采样的数据,根据水的生产要求来控制泵24c,从而将所需数量的添加剂添加至反应器。The additive injection part 24 has a second container 24a for containing additives such as hydrochloric acid. The additive injection part 24 is provided with a second flow sensor 24b, which is used to measure the additive amount and is electrically connected to the control system. The additive injection part 24 is also provided with a pump 24c and an injection unit 24d for injecting the additive into the reactor. According to the data sampled by the pH sensor 58 and the second flow sensor 24b, the control system controls the pump 24c according to the water production requirements, so as to add the required amount of additives to the reactor.
最后一级反应器的出水口通过管道连接有蓄水罐59。蓄水罐59内设有液位传感器60。控制系统3根据目前液位传感器44和液位传感器60的读数,判断目前生产流程,对电控三通阀42进行控制。在蓄水罐下游设有次氯酸水供水口61,用于向用户供应次氯酸水。The water outlet of the last-stage reactor is connected with a water storage tank 59 through a pipe. A liquid level sensor 60 is provided in the water storage tank 59. The control system 3 judges the current production process based on the current readings of the liquid level sensor 44 and the liquid level sensor 60, and controls the electronically controlled three-way valve 42. A hypochlorous water supply port 61 is provided downstream of the storage tank for supplying hypochlorous water to users.
图2中整体示出了根据本发明的一实施例的微酸性次氯酸水生成设备200。微酸性次氯酸水生成设备200包括至少一级净化装置,用于对来自原水供应系统的原水进行净化处理。这里,原水指的是未经本申请的设备处理过的水,例如来自市政供水系统的自来水。在各级净化装置下游设有次氯酸水生成装置106,用于将经各级净化装置处理过的水加工成为微酸性次氯酸水。这里,微酸性次氯酸水是指pH值范围在6.20~6.80之间的次氯酸水。当微酸性次氯酸水的pH值在6.20~6.80之间的某个值时,其pH值的波动范围控制在正负0.05的狭窄区间内。一实施例中,可以选定所需的pH值,在选定pH值下,其pH波动范围控制在正负0.05之内。FIG. 2 shows a slightly acidic hypochlorous acid water generating device 200 according to an embodiment of the present invention as a whole. The slightly acidic hypochlorous acid water generating device 200 includes at least one level of purification device for purifying raw water from the raw water supply system. Here, raw water refers to water that has not been treated by the equipment of this application, such as tap water from a municipal water supply system. A hypochlorous acid water generating device 106 is provided downstream of the purification devices at all levels, which is used to process the water treated by the purification devices at all levels into slightly acidic hypochlorous water. Here, slightly acidic hypochlorous water refers to hypochlorous water with a pH value ranging from 6.20 to 6.80. When the pH value of slightly acidic hypochlorous acid water is between 6.20 and 6.80, the fluctuation range of its pH value is controlled within a narrow range of plus or minus 0.05. In one embodiment, the required pH value can be selected, and the pH fluctuation range is controlled within plus or minus 0.05 under the selected pH value.
具体地,微酸性次氯酸水生成设备200包括前置过滤器101和原水罐102,前置过滤器101通过管道301连接于水源。前置过滤器101和原水罐102之间通过管道302连接。来自原水供应系统的原水经由前置过滤器101过滤后存储于原水罐102中。前置过滤器101上游位置设置有阀门303,可以通过阀门开关控制原水流入微酸性次氯酸水生成设备200。该阀门设置为手动阀。较佳地,该阀门也可设置为电磁阀。Specifically, the slightly acidic hypochlorous acid water generating device 200 includes a pre-filter 101 and a raw water tank 102, and the pre-filter 101 is connected to a water source through a pipe 301. The pre-filter 101 and the raw water tank 102 are connected by a pipe 302. The raw water from the raw water supply system is filtered by the pre-filter 101 and stored in the raw water tank 102. A valve 303 is provided upstream of the pre-filter 101, and the raw water can be controlled to flow into the slightly acidic hypochlorous acid water generating device 200 through the valve switch. The valve is set as a manual valve. Preferably, the valve can also be configured as a solenoid valve.
还如图2所示,原水罐102通过管路连接到第一级过滤装置103。来自原水供应系统的原水被第一级过滤装置103进行砂滤、炭滤、软化以及精密过滤中的至少一种处理。较佳地,所述第一级过滤装置103至少包括软化过滤,并形成去离子水。具体地,第一级过滤装置103包括砂炭过滤器1031、软化过滤器1032以及精密过滤器1033。但根据原水的水质状况,第一级过滤装置103可包括砂炭过滤器1031、软化过滤器1032以及精密过滤器1033中的任意一个或两个的组合。砂炭过滤器1031用于去除自来水中的大颗粒物质和杂质及改善水的口感。软化过滤器1032则 用于去除水中的钙镁离子,调节水的软硬度。精密过滤器1033可去除水中通常砂滤和炭滤所不能去除的微细悬浮物或胶体粒子。此外,通常还设置用于对软化过滤器1032进行再生的盐再生装置10321,用于对软化过滤器1032进行再生。As also shown in FIG. 2, the raw water tank 102 is connected to the first-stage filtering device 103 through a pipeline. The raw water from the raw water supply system is subjected to at least one of sand filtration, carbon filtration, softening, and precision filtration by the first-stage filtration device 103. Preferably, the first-stage filtration device 103 includes at least softening filtration and forming deionized water. Specifically, the first-stage filtering device 103 includes a sand charcoal filter 1031, a softening filter 1032, and a precision filter 1033. However, according to the water quality of the raw water, the first-stage filtering device 103 may include any one of a sand charcoal filter 1031, a softening filter 1032, and a precision filter 1033 or a combination of two. The sand charcoal filter 1031 is used to remove large particles and impurities in tap water and improve the taste of water. The softening filter 1032 is used to remove calcium and magnesium ions from the water and adjust the softness and hardness of the water. The precision filter 1033 can remove fine suspended solids or colloidal particles that cannot be removed by sand filtration and carbon filtration in water. In addition, a salt regeneration device 10321 for regenerating the softening filter 1032 is usually provided for regenerating the softening filter 1032.
被第一级过滤装置103处理过的水可分为两个支路,其中一个支路通向一供水口(图未示),该供水口能向用户提供去离子水。被第一级过滤装置103处理过的去离子水可作为实验室、化验室用水、锅炉用水等。另一个支路则通过管路304连接至超滤膜组过滤器和/或反渗透膜组件104。The water treated by the first-stage filtering device 103 can be divided into two branches, one of which leads to a water supply port (not shown), which can provide deionized water to users. The deionized water treated by the first-stage filter device 103 can be used as water for laboratories, laboratories, boilers, etc. The other branch is connected to the ultrafiltration membrane pack filter and/or the reverse osmosis membrane module 104 through a pipeline 304.
超滤膜组过滤器具有熔喷滤芯,用于进一步过滤来自第一级过滤装置103的水。经超滤膜组过滤器处理过的水为超滤水。熔喷滤芯的过滤孔径为约0.01微米,超滤水中被进一步去除了细菌、铁锈、胶体及有机物等杂质,但保留了水中溶解氧及人体所需微量矿物质等营养成分,水质达到我国当前直饮水标准可用于幼儿园、医院、养老院、酒店餐饮等行业,具体在除菌保鲜、食品加工、抗病毒、洗漱等多方面具有重要作用。被超滤膜组过滤器处理过的水可分为两个支路,其中一个支路通向第一供水口204,该支路水质标准达到我国当前饮用水标准。经反渗透膜组件处理过的水为高纯水,可达到高纯水标准,其基本不保留水中的矿物质,pH值在6-7之间,为弱酸性,可以作为原液或者原材生产卫生用品、皮肤黏膜消毒剂、漱口水等消毒产品。The ultrafiltration membrane group filter has a melt blown filter element for further filtering the water from the first stage filter device 103. The water treated by the ultrafiltration membrane group filter is ultrafiltration water. The filter pore size of the melt-blown filter element is about 0.01 microns. The ultrafiltration water is further removed from impurities such as bacteria, rust, colloids and organic matter, but it retains dissolved oxygen in the water and nutrients such as trace minerals required by the human body. The water quality reaches the current level of my country. Drinking water standards can be used in kindergartens, hospitals, nursing homes, hotels, catering and other industries, and play an important role in many aspects such as sterilization and preservation, food processing, anti-virus, and washing. The water treated by the ultrafiltration membrane group filter can be divided into two branches, one of which leads to the first water supply port 204, and the water quality standard of this branch meets the current drinking water standards in my country. The water treated by the reverse osmosis membrane module is high-purity water, which can reach the standard of high-purity water. It basically does not retain minerals in the water. The pH value is between 6-7 and is weakly acidic. It can be used as a raw liquid or raw material to produce sanitary products and skin Disinfecting products such as mucosal disinfectant and mouthwash.
反渗透膜组件膜孔径比超滤膜更小,可用于进一步过滤来自第一级过滤装置103或者超滤膜组过滤器处理过的水。被反渗透膜组件处理过的水可分为两个支路,其中一个支路通向第一供水口204,该供水口204能向用户提供高纯水,另一个支路通向次氯酸水生成装置106。The membrane pore size of the reverse osmosis membrane module is smaller than that of the ultrafiltration membrane, and can be used to further filter the water treated by the first-stage filtration device 103 or the ultrafiltration membrane set filter. The water treated by the reverse osmosis membrane module can be divided into two branches. One branch leads to the first water supply port 204, which can provide users with high-purity water, and the other branch leads to the generation of hypochlorous acid water.装置106。 Device 106.
一实施例中,被反渗透膜组件处理过的水通过另一个支路连接至电去离子(EDI)装置(图中未示出)。在EDI装置中,在电场的作用下实现水中离子的定向迁移,从而达到水的深度净化除盐,因此,EDI水称为超纯水(EDI水),可广泛应用于电力、电子、医药、化工、光学仪器和实验室领域。被EDI装置处理过的水主要用于生成蒸馏水,用于注射、血液透析等。被EDI装置处理过的水可分为两个支路,其中一个支路通向一设备供水口,该供水口能向用户提供超纯水,另一个支路通向次氯酸水生成装置106。In one embodiment, the water treated by the reverse osmosis membrane module is connected to an electrodeionization (EDI) device (not shown in the figure) through another branch. In the EDI device, the directional migration of ions in the water is realized under the action of the electric field, so as to achieve the deep purification and desalination of water. Therefore, EDI water is called ultrapure water (EDI water), which can be widely used in electricity, electronics, medicine, Chemical, optical instruments and laboratory fields. The water treated by the EDI device is mainly used to produce distilled water for injection, hemodialysis, etc. The water treated by the EDI device can be divided into two branches, one of which leads to an equipment water supply port, which can provide users with ultra-pure water, and the other branch leads to the hypochlorous acid water generator 106 .
一实施例中,被电去离子(EDI)装置处理过的超纯水还通过另一支路(图中未示出)连接至蒸馏净化装置(图中未示出)。经蒸馏净化装置处理的水纯度更高, 可达到医药蒸馏水标准。被蒸馏净化装置处理过的水可分为两个支路,其中一个支路通向第一出水口204,该第一出水口204能向用户提供医药蒸馏水,另一个支路通向次氯酸水加工装置106,用于将医药蒸馏水制作成微酸性次氯酸水;使用该医药蒸馏水制作的微酸性次氯酸水可作为原液或原材生产皮肤黏膜消毒剂、烫伤伤口消毒剂等产品。In one embodiment, the ultrapure water treated by the electrodeionization (EDI) device is also connected to the distillation purification device (not shown in the figure) through another branch (not shown in the figure). The purity of the water treated by the distillation purification device is higher and can reach the standard of medical distilled water. The water treated by the distillation purification device can be divided into two branches, one of which leads to the first water outlet 204, which can provide users with medical distilled water, and the other branch leads to hypochlorous acid The water processing device 106 is used to make medical distilled water into slightly acidic hypochlorous acid water; the slightly acidic hypochlorous acid water made by using the medical distilled water can be used as a stock solution or raw material to produce skin and mucous membrane disinfectants, scald wound disinfectants and other products.
本实施例中,在超滤膜组过滤器和/或反渗透膜组件104与次氯酸水生成装置106之间设置有灭菌系统105,用于对水进行灭菌处理。灭菌系统105可采用紫外线灭菌系统。该紫外线灭菌系统可包括外部套管和设置在外部套管内的石英紫外线灯管,在外部套管与石英紫外线灯管之间形成环形流道,用于管路水流通过。但应理解,灭菌方式不限于上述方式,可以采用其它灭菌方式。In this embodiment, a sterilization system 105 is provided between the ultrafiltration membrane group filter and/or reverse osmosis membrane assembly 104 and the hypochlorous acid water generator 106 for sterilizing water. The sterilization system 105 may adopt an ultraviolet sterilization system. The ultraviolet sterilization system may include an outer sleeve and a quartz ultraviolet lamp tube arranged in the outer sleeve, and an annular flow channel is formed between the outer sleeve and the quartz ultraviolet lamp for water flow through the pipeline. However, it should be understood that the sterilization method is not limited to the above method, and other sterilization methods can be used.
次氯酸水生成装置106位于各级净化装置下游并选择性地与其中一级净化装置连接,用于将上述去离子水、超滤水/饮用水、高纯水、超纯水、医药蒸馏水加工成微酸性次氯酸水,其中与第一级过滤装置103、EDI装置及蒸馏净化装置连接的支路未在图中示出。本实施例的次氯酸水生成装置106采用喷射流式反应法,其组成结构与图1所示的组成结构相同,在此不再详述。该次氯酸水生成装置106所得的次氯酸水呈现稳定的微酸性,pH值能够稳定在6.20-6.80之间,在避光条件能够储存18个月以上。该次氯酸水的耐候性强,0~80℃的范围内,稳定性不衰减。该次氯酸水只对细菌和病毒等有机物产生强抑制作用,其抗抑菌有效成分与人体白血球产生的次氯酸一样,具有很强的除菌能力,且对人体无毒无害。该次氯酸水还能去除空间烟味、臭味、食物气味、汗味等改善空气质量。The hypochlorous acid water generating device 106 is located downstream of the purification devices of each stage and is selectively connected to one of the purification devices for processing the above-mentioned deionized water, ultra-filtered water/drinking water, high-purity water, ultra-pure water, and medical distilled water into The slightly acidic hypochlorous water, in which the branch connected with the first-stage filter device 103, the EDI device and the distillation purification device are not shown in the figure. The hypochlorous acid water generating device 106 of this embodiment adopts a jet flow reaction method, and its composition structure is the same as that shown in FIG. 1, and will not be described in detail here. The hypochlorous acid water obtained by the hypochlorous acid water generating device 106 is stable and slightly acidic, the pH value can be stabilized between 6.20-6.80, and it can be stored for more than 18 months under dark conditions. The hypochlorous acid water has strong weather resistance, and its stability does not decay in the range of 0-80°C. The hypochlorous acid water only has a strong inhibitory effect on organic matter such as bacteria and viruses, and its antibacterial active ingredients are the same as hypochlorous acid produced by human leukocytes. It has strong sterilization ability and is non-toxic and harmless to the human body. The hypochlorous acid water can also remove space smoke, odor, food odor, sweat, etc. to improve air quality.
次氯酸水生成装置106的出水口经由管路连接至第二供水口205用于向用户供水。在次氯酸水生成装置106和第二供水口205之间设置有微酸性次氯酸水蓄水罐108,用于存储来自次氯酸水生成装置的微酸性次氯酸水。较佳地,在次氯酸水生成装置106和微酸性次氯酸水蓄水罐108之间设置有微酸性次氯酸水中转蓄水罐109,该次氯酸水中转蓄水罐109用于次氯酸水中转过程中的存储。The water outlet of the hypochlorous water generating device 106 is connected to the second water supply port 205 via a pipeline for supplying water to the user. A slightly acidic hypochlorous acid water storage tank 108 is provided between the hypochlorous acid water generator 106 and the second water supply port 205 for storing the slightly acidic hypochlorous acid water from the hypochlorous acid water generator. Preferably, a slightly acidic hypochlorous acid water transfer storage tank 109 is provided between the hypochlorous acid water generating device 106 and the slightly acidic hypochlorous acid water storage tank 108, and the hypochlorous acid water transfer storage tank 109 is used for Storage during transfer in hypochlorous acid water.
进一步地,在图示实施例中,该微酸性次氯酸水生成设备200设置有旁通管路201。旁通管路201的入口通过三通阀305与原水供应系统连接。该三通阀305构造成将原水供应系统选择性地与旁通管路201或者第一级过滤装置103连接。旁通管路201的出口经由另一三通阀306连接到微酸性次氯酸水生成设备200的供水管道。这里,三通阀为电磁三通阀。一实施例中,三通阀也可以由分别安装在旁通管 路上的一电磁阀和安装在次氯酸水生成装置的出水支路上的另一电磁阀来替代。Further, in the illustrated embodiment, the slightly acidic hypochlorous acid water generating device 200 is provided with a bypass pipeline 201. The inlet of the bypass pipeline 201 is connected to the raw water supply system through a three-way valve 305. The three-way valve 305 is configured to selectively connect the raw water supply system with the bypass line 201 or the first-stage filter device 103. The outlet of the bypass pipe 201 is connected to the water supply pipe of the slightly acidic hypochlorous acid water generating device 200 via another three-way valve 306. Here, the three-way valve is an electromagnetic three-way valve. In one embodiment, the three-way valve can also be replaced by a solenoid valve installed on the bypass pipe and another solenoid valve installed on the outlet branch of the hypochlorous acid water generator.
微酸性次氯酸水生成设备200进一步设置有控制器(图未示出),当净化装置或次氯酸水生成装置发生故障时,控制器接受故障报警信号、发出警报并控制三通阀切换到旁通管路201,以保证日常用水稳定供应。The slightly acidic hypochlorous acid water generating device 200 is further provided with a controller (not shown in the figure). When the purification device or the hypochlorous water generating device fails, the controller receives the failure alarm signal, sends out an alarm, and controls the switching of the three-way valve To the bypass pipeline 201 to ensure a stable supply of daily water.
进一步地,如图所示,在第一级过滤装置103下游管路设置有去离子水蓄水罐(图中未示出),该去离子水蓄水罐的出水口经由管道连接至设备供水口。较佳地,在超滤膜组过滤器下游管路设置有饮用水蓄水罐,在反渗透膜组件下游管路设置有高纯水蓄水罐,饮用水蓄水罐和高纯水蓄水罐的出水口经由管道连接至设备供水口。较佳地,在电去离子(EDI)装置下游管路设置有超纯水蓄水罐(图中未示出),该超纯水蓄水罐的出水口经由管道连接至设备供水口。Further, as shown in the figure, a deionized water storage tank (not shown in the figure) is provided in the downstream pipeline of the first-stage filtering device 103, and the outlet of the deionized water storage tank is connected to the equipment water supply via a pipe. mouth. Preferably, the downstream pipeline of the ultrafiltration membrane module filter is provided with a drinking water storage tank, and the downstream pipeline of the reverse osmosis membrane module is provided with a high-purity water storage tank, a drinking water storage tank and a water outlet of the high-purity water storage tank Connect to the water supply port of the equipment via a pipe. Preferably, an ultrapure water storage tank (not shown in the figure) is provided in the downstream pipeline of the electrodeionization (EDI) device, and the water outlet of the ultrapure water storage tank is connected to the equipment water supply port via a pipe.
较佳地,第一供水口204、第二供水口205和其它可能设置的供水口按照需求均连接有去离子水支路、饮用水支路、高纯水支路、超纯水支路、医药蒸馏水支路和次氯酸水支路中的一种或几种。控制器布置成能够按照用户设置切换供水口的供水类型。Preferably, the first water supply port 204, the second water supply port 205, and other possible water supply ports are all connected with deionized water branch, drinking water branch, high-purity water branch, ultra-pure water branch, and medical distilled water as required. One or more of branch roads and hypochlorous acid water branch roads. The controller is arranged to be able to switch the water supply type of the water supply port according to user settings.
更进一步地,微酸性次氯酸水生成设备设置有排水管路202,该排水管路通过相应的阀门与各蓄水罐的出口连接。较佳地,该阀门设置为电磁阀,由控制器控制开启和关闭。图2实施例设置为电磁三通阀4025,由控制器控制切换。各蓄水罐下游管路设置有输送泵和压力开关,当管道压力较小时,压力开关控制该输送泵开启以增加向下游供水的压力,当管道压力过大时,压力开关控制输送泵关闭。各蓄水罐设置有液位探测器。该液位探测器沿蓄水罐的高度延伸以探测相应蓄水罐内的液位高度。Furthermore, the slightly acidic hypochlorous acid water generating equipment is provided with a drain line 202, which is connected to the outlet of each water storage tank through a corresponding valve. Preferably, the valve is set as a solenoid valve, which is controlled by the controller to open and close. The embodiment of Fig. 2 is set as an electromagnetic three-way valve 4025, which is controlled by the controller to switch. The downstream pipeline of each storage tank is provided with a delivery pump and a pressure switch. When the pipeline pressure is low, the pressure switch controls the delivery pump to open to increase the pressure of the downstream water supply. When the pipeline pressure is too high, the pressure switch controls the delivery pump to close. Each water storage tank is provided with a liquid level detector. The liquid level detector extends along the height of the storage tank to detect the height of the liquid level in the corresponding storage tank.
在设定期限内,当所述液位探测器探测到的液位高于预定液位时,则控制器控制开启排水管路入口阀门排水并关闭蓄水罐下游管路相应输送泵。由此,将蓄水罐内的水定期排出。进一步地,各蓄水罐下游供水管路设置有流量计,根据该流量计示数可计算相应蓄水罐供水量。在设定时间间隔中,若所述流量计净流量小于预设流量,则控制器控制开启排水管路入口阀门排水并关闭蓄水罐下游管路相应输送泵。由此,可以将蓄水罐内的水定期排出,由此保证水的质量。较佳地,控制器具有根据相应蓄水罐用水量调整预定液位的功能。Within the set time limit, when the liquid level detected by the liquid level detector is higher than the predetermined liquid level, the controller controls the opening of the drain pipeline inlet valve to drain water and closes the corresponding delivery pump of the downstream pipeline of the water storage tank. As a result, the water in the water storage tank is periodically discharged. Further, the downstream water supply pipeline of each storage tank is provided with a flow meter, and the water supply amount of the corresponding storage tank can be calculated according to the indication of the flow meter. In the set time interval, if the net flow of the flow meter is less than the preset flow, the controller controls to open the inlet valve of the drainage pipeline to drain water and close the corresponding delivery pump of the downstream pipeline of the water storage tank. As a result, the water in the water storage tank can be regularly discharged, thereby ensuring the quality of the water. Preferably, the controller has the function of adjusting the predetermined liquid level according to the water consumption of the corresponding storage tank.
具体来说,例如,原水蓄水罐102出口设置有电磁三通阀4025a。该三通阀一个出口与排水管路202相连,另一个出口通过管道307与第一级过滤装置103相连。 原水蓄水罐102内沿蓄水罐高度设置有液位探测器4021a,在管道307上设置有输送泵4023a、压力开关4027a、流量计4022a和压力传感器4024a。其中压力传感器4024a设置于砂炭过滤器1031入口处,用于监测其入水口的压力。工作时,电磁三通阀4025a切换为与管道307相连,由原水蓄水罐102向第一级过滤装置103供水,压力传感器4024a探测管道进水口水流压力。当压力过低时,压力开关4027a控制输送泵4023a增加向下游输送水的压力,当压力过高时,停止输送泵4023a。在设定期限内,当液位探测器4021a探测到的液位高于预定液位时,则控制器控制关闭原水蓄水罐102下游管路307的相应输送泵4023a并切换电磁三通阀4025a至排水管路202进行排水。Specifically, for example, an electromagnetic three-way valve 4025a is provided at the outlet of the raw water storage tank 102. One outlet of the three-way valve is connected to the drainage pipe 202, and the other outlet is connected to the first-stage filter device 103 through a pipe 307. A liquid level detector 4021a is installed in the raw water storage tank 102 along the height of the storage tank, and a delivery pump 4023a, a pressure switch 4027a, a flow meter 4022a and a pressure sensor 4024a are provided on the pipeline 307. The pressure sensor 4024a is arranged at the inlet of the sand charcoal filter 1031 to monitor the pressure of its water inlet. During operation, the electromagnetic three-way valve 4025a is switched to be connected to the pipe 307, and the raw water storage tank 102 supplies water to the first-stage filter device 103, and the pressure sensor 4024a detects the water flow pressure at the water inlet of the pipe. When the pressure is too low, the pressure switch 4027a controls the delivery pump 4023a to increase the pressure to deliver water downstream, and when the pressure is too high, the delivery pump 4023a is stopped. Within the set time limit, when the liquid level detected by the liquid level detector 4021a is higher than the predetermined liquid level, the controller controls to close the corresponding delivery pump 4023a of the downstream pipeline 307 of the raw water storage tank 102 and switch the electromagnetic three-way valve 4025a Drain water to the drain line 202.
在设定时间间隔中,若所述流量计净流量小于预设流量,例如在设定的三天时间间隔内,若未用水或者用水量低于预期,则控制器控制关闭管道307上的输送泵4023a并将电磁三通阀4025a切换至排水管路202进行排水,以保证供水水质。此外,控制器根据该段时间间隔内的用水量重新计算并控制加水液位,并相应更改其它预设值,比如更改预定液位和预设流量。In the set time interval, if the flow meter net flow is less than the preset flow rate, for example, within the set three-day time interval, if there is no water or the water consumption is lower than expected, the controller controls to close the delivery on the pipeline 307 The pump 4023a switches the electromagnetic three-way valve 4025a to the drainage pipe 202 for drainage to ensure the quality of the water supplied. In addition, the controller recalculates and controls the water filling level according to the water consumption in the time interval, and changes other preset values accordingly, such as changing the preset level and the preset flow rate.
砂炭过滤器1031通过管道308与软化过滤器1032相连,在管道308上设置有压力传感器4024b,管道308上还可设置输送泵、压力开关、流量计。软化过滤器1032通过管道309与精密过滤器1033相连,在管道309上还可以设置输送泵、压力开关、流量计,其中精密过滤器1033还设置有压力传感器4024c,用于监测精密过滤器1033处水流压力。The sand charcoal filter 1031 is connected to the softening filter 1032 through a pipe 308. A pressure sensor 4024b is provided on the pipe 308, and a delivery pump, a pressure switch, and a flow meter can also be provided on the pipe 308. The softening filter 1032 is connected to the precision filter 1033 through a pipe 309. The pipe 309 can also be provided with a delivery pump, a pressure switch, and a flow meter. The precision filter 1033 is also provided with a pressure sensor 4024c to monitor the position of the precision filter 1033. Water flow pressure.
第一级过滤装置103通过管道304与超滤膜组过滤器和/或反渗透膜组件104连接。超滤膜组过滤器和/或反渗透膜组件104的底端出口也与排水管路202连接,在底端出口设置有浓排隔膜手动阀4029和流量计4022i,可以手动控制浓水排出。在管道304上设置有输送泵4023c、压力开关4027c、流量计(图未示出)、压力传感器4024c,还设置有手动阀4026c。The first-stage filtration device 103 is connected to the ultrafiltration membrane group filter and/or the reverse osmosis membrane module 104 through a pipeline 304. The bottom outlet of the ultrafiltration membrane set filter and/or the reverse osmosis membrane module 104 is also connected to the drain line 202, and the bottom outlet is provided with a concentrated discharge diaphragm manual valve 4029 and a flow meter 4022i, which can manually control the discharge of concentrated water. The pipeline 304 is provided with a delivery pump 4023c, a pressure switch 4027c, a flow meter (not shown), a pressure sensor 4024c, and a manual valve 4026c.
较佳地,在管道304上设置有去离子水蓄水罐(图未示出),在去离子水蓄水罐的出口设置电磁三通阀,该三通阀一个出口与超滤膜组过滤器和/或反渗透膜组件104连接,另一个出口与排水管路202连接。超滤膜组过滤器和/或反渗透膜组件104可单设超滤膜组过滤器或者反渗透膜组件,也可以同时设置超滤膜组过滤器和反渗透膜组件,其中反渗透膜组件设置于超滤膜组过滤器下游。Preferably, a deionized water storage tank (not shown in the figure) is provided on the pipeline 304, and an electromagnetic three-way valve is provided at the outlet of the deionized water storage tank. An outlet of the three-way valve is connected to the ultrafiltration membrane filter. The filter and/or the reverse osmosis membrane module 104 are connected, and the other outlet is connected to the drainage pipeline 202. The ultrafiltration membrane set filter and/or the reverse osmosis membrane module 104 can be equipped with an ultrafiltration membrane set filter or a reverse osmosis membrane module alone, or an ultrafiltration membrane set filter and a reverse osmosis membrane module can be set at the same time, wherein the reverse osmosis membrane module Set at the downstream of the ultrafiltration membrane group filter.
超滤膜组过滤器下游可设置有储蓄饮用水的饮用水蓄水罐。反渗透膜组件下游 可设置有储蓄高纯水的高纯水蓄水罐。在饮用水蓄水罐和高纯水蓄水罐出口设置有电磁三通阀。该三通阀一个出口与排水管路202连接,另一个出口与下游管路连接,用于对水进一步处理。A drinking water storage tank for storing drinking water can be arranged downstream of the ultrafiltration membrane group filter. A high-purity water storage tank for storing high-purity water can be installed downstream of the reverse osmosis membrane module. Electromagnetic three-way valves are provided at the outlets of the drinking water storage tank and the high-purity water storage tank. One outlet of the three-way valve is connected to the drainage pipeline 202, and the other outlet is connected to the downstream pipeline for further treatment of water.
超滤膜组过滤器和/或反渗透膜组件104通过管道310与次氯酸水生成装置106连接,在管道310设置有灭菌装置105,用于对水进行灭菌。在灭菌装置105入口处设置有流量计4022d。管道310还设置有饮用水/高纯水蓄水罐107。饮用水/高纯水蓄水罐107沿高度设置有液位传感器4021e。The ultrafiltration membrane set filter and/or the reverse osmosis membrane module 104 are connected to the hypochlorous acid water generating device 106 through the pipe 310, and the pipe 310 is provided with a sterilizing device 105 for sterilizing water. A flow meter 4022d is provided at the entrance of the sterilization device 105. The pipeline 310 is also provided with a drinking water/high-purity water storage tank 107. The drinking water/high-purity water storage tank 107 is provided with a liquid level sensor 4021e along the height.
在饮用水/高纯水蓄水罐107出口处设置有三通阀4025e。该三通阀一个出口与排水管路202连接。该三通阀的另一个出口的支路上设置有输送泵4023e、压力开关4027e以及另一个三通阀4025f。该三通阀的一个出口与次氯酸水生成装置106连接,该支路上设置有流量计4022e,用于监测管道流量。另一个出口与第一供水口204连接。在该支路上设有流量计4022f,用于监测管道流量。A three-way valve 4025e is provided at the outlet of the drinking water/high-purity water storage tank 107. One outlet of the three-way valve is connected to the drain pipeline 202. The branch of the other outlet of the three-way valve is provided with a delivery pump 4023e, a pressure switch 4027e, and another three-way valve 4025f. One outlet of the three-way valve is connected to the hypochlorous acid water generating device 106, and a flowmeter 4022e is installed on the branch to monitor the pipeline flow. The other outlet is connected to the first water supply port 204. A flowmeter 4022f is provided on the branch to monitor the pipeline flow.
次氯酸水生成装置106通过管道311与微酸性次氯酸水中转蓄水罐109连接,微酸性次氯酸水中转蓄水罐109沿高度设置有液位传感器4021g。在微酸性次氯酸水中转蓄水罐109出口处设置有电磁三通阀4025g。该三通阀其中一个出口与排水管路202连接,另一个出口通过管道312与微酸性次氯酸水蓄水罐108连接。微酸性次氯酸水蓄水罐108设置有液位传感器4021h。管道312上设置有输送泵4023g。微酸性次氯酸水蓄水罐108出口设置有电磁三通阀4025h,该三通阀一个出口与排水管路202连接,另一个出口通过管道313与第二供水口205连接。在管道313上设置有输送泵4023h、压力开关4027h和流量计4022h,以监测压力、流量,并根据压力和流量来控制输送泵和电磁三通阀的动作。The hypochlorous acid water generator 106 is connected to the slightly acidic hypochlorous acid water transfer storage tank 109 through a pipe 311, and the slightly acidic hypochlorous acid water transfer storage tank 109 is provided with a liquid level sensor 4021g along the height. An electromagnetic three-way valve 4025g is provided at the outlet of the slightly acidic hypochlorous acid water transfer storage tank 109. One of the outlets of the three-way valve is connected to the drainage pipe 202, and the other outlet is connected to the slightly acidic hypochlorous acid water storage tank 108 through the pipe 312. The slightly acidic hypochlorous acid water storage tank 108 is provided with a liquid level sensor 4021h. The pipe 312 is provided with a delivery pump 4023g. The outlet of the slightly acidic hypochlorous acid water storage tank 108 is provided with an electromagnetic three-way valve 4025h. One outlet of the three-way valve is connected to the drainage pipe 202, and the other outlet is connected to the second water supply port 205 through a pipe 313. A delivery pump 4023h, a pressure switch 4027h, and a flow meter 4022h are provided on the pipeline 313 to monitor the pressure and flow, and control the actions of the delivery pump and the electromagnetic three-way valve according to the pressure and flow.
进一步地,在相应蓄水罐入口设置有电磁阀,在蓄水罐排空重新加水时,当液位高于预定液位时,控制器关闭该入口的电磁阀。较佳地,相应蓄水罐入口还设置一手动阀4026,可以手动关闭蓄水罐的入水口。Further, a solenoid valve is provided at the inlet of the corresponding water storage tank, and when the water storage tank is emptied and refilled, when the liquid level is higher than a predetermined liquid level, the controller closes the solenoid valve of the inlet. Preferably, a manual valve 4026 is also provided at the inlet of the corresponding water storage tank, which can manually close the water inlet of the water storage tank.
进一步地,微酸性次氯酸水生成设备设置有清洗管路,该清洗管路包括清洗总路203和清洗支路206。其中,清洗总路203具有至少一个入口和至少一个出口,每个入口经由管道与对应蓄水罐的出水口可启闭地连接,每个出口经由管路与对应的净化装置可启闭地连接。图中清洗总路203一个入口与微酸性次氯酸水蓄水罐连接,另一个入口与饮用水和/或高纯水蓄水罐连接,其一个出口连接至第一级过滤装置103的入口。Further, the slightly acidic hypochlorous acid water generating equipment is provided with a cleaning pipeline, which includes a cleaning main circuit 203 and a cleaning branch 206. Wherein, the cleaning main road 203 has at least one inlet and at least one outlet, each inlet is openably connected to the outlet of the corresponding water storage tank via a pipeline, and each outlet is openably connected to the corresponding purification device via a pipeline . In the figure, one inlet of the cleaning main road 203 is connected to the slightly acidic hypochlorous acid water storage tank, the other inlet is connected to the drinking water and/or high purity water storage tank, and one outlet thereof is connected to the inlet of the first-stage filter device 103.
清洗总路203的另一个入口与原水蓄水罐102连接,其出口通过一管道连接至超滤膜组过滤器和/或反渗透膜组件104,用于对超滤膜组过滤器和/或反渗透膜组件104进行冲洗。该管道设置有电磁阀4031。The other inlet of the cleaning main road 203 is connected to the raw water storage tank 102, and its outlet is connected to the ultrafiltration membrane set filter and/or reverse osmosis membrane module 104 through a pipe, which is used for the ultrafiltration membrane set filter and/or The reverse osmosis membrane module 104 is flushed. The pipeline is provided with a solenoid valve 4031.
清洗支路206用于清洗蓄水罐。在蓄水罐出水口连接的管路上设置有输送泵4023。清洗支路206的入口与输送泵4023的出口连接,其出口连接至蓄水罐入口。控制器能够控制输送泵4023的开启并形成清洗管道的冲洗压力。清洗支路206的出口通过管道连接至蓄水罐内部的冲洗喷头(图未示出),冲洗喷头与蓄水罐内壁成角度设置。控制器布置成能够控制冲洗喷头转动,对蓄水罐进行全方位冲洗。应该理解地是,冲洗喷头根据需要可设置不止一个,清洗支路206的出口可以选择性地与蓄水罐入水口合并为同一个。此外,清洗总路203和清洗支路206设置有电磁阀,由控制器控制开启或关闭。The cleaning branch 206 is used to clean the water storage tank. A delivery pump 4023 is provided on the pipeline connected to the water outlet of the water storage tank. The inlet of the cleaning branch 206 is connected to the outlet of the delivery pump 4023, and the outlet thereof is connected to the inlet of the water storage tank. The controller can control the opening of the delivery pump 4023 and form the flushing pressure of the cleaning pipeline. The outlet of the cleaning branch 206 is connected to a flushing nozzle (not shown in the figure) inside the water storage tank through a pipe, and the flushing nozzle is arranged at an angle with the inner wall of the water storage tank. The controller is arranged to be able to control the rotation of the flushing nozzle to flush the water storage tank in all directions. It should be understood that more than one flushing nozzle can be provided as required, and the outlet of the cleaning branch 206 can be selectively combined with the water inlet of the water storage tank into the same one. In addition, the cleaning main circuit 203 and the cleaning branch 206 are provided with solenoid valves, which are controlled to be opened or closed by the controller.
本申请的水生成设备含有多级净化装置以及采用量子化反应原理的次氯酸水生成装置。净化装置用于对原水进行多级净化处理,而且每级净化装置设置有对应的出水口。该次氯酸水生成装置将来自所述净化装置的水进行溅射,增加水的比表面积,从而产生量子化化学反应,并且可以分级控制H水合质子,达到H离子稳定的饱和溶解度。本发明的水生成设备能够加工成pH稳定的微酸性次氯酸水,并能按用户需求切换取水类型选择。The water generating equipment of the present application includes a multi-stage purification device and a hypochlorous acid water generating device using the principle of quantization reaction. The purification device is used to perform multi-stage purification treatment on the raw water, and each stage of the purification device is provided with a corresponding water outlet. The hypochlorous acid water generating device sputters the water from the purification device to increase the specific surface area of the water, thereby generating a quantized chemical reaction, and can control H hydration protons in stages to achieve stable saturated solubility of H ions. The water generating device of the present invention can be processed into slightly acidic hypochlorous acid water with stable pH, and can switch the water intake type selection according to user needs.
以上已详细描述了本发明的较佳实施例,但应理解到,若需要,能修改实施例的方面来采用各种专利、申请和出版物的方面、特征和构思来提供另外的实施例。The preferred embodiments of the present invention have been described in detail above, but it should be understood that, if necessary, aspects of the embodiments can be modified to adopt aspects, features and concepts of various patents, applications, and publications to provide additional embodiments.
考虑到上文的详细描述,能对实施例做出这些和其它变化。一般而言,在权利要求中,所用的术语不应被认为限制在说明书和权利要求中公开的具体实施例,而是应被理解为包括所有可能的实施例连同这些权利要求所享有的全部等同范围。Considering the detailed description above, these and other changes can be made to the embodiments. Generally speaking, in the claims, the terms used should not be construed as limiting the specific embodiments disclosed in the specification and claims, but should be construed as including all possible embodiments together with all equivalents enjoyed by these claims. range.

Claims (32)

  1. 一种微酸性次氯酸水生成设备,其特征在于,所述微酸性次氯酸水生成设备包括:A slightly acidic hypochlorous acid water generating equipment, characterized in that the slightly acidic hypochlorous acid water generating equipment comprises:
    至少一级净化装置,所述净化装置用于对来自原水供应系统的原水进行净化处理且每级净化装置设置有对应的出水口;At least one level of purification device, the purification device is used to purify raw water from the raw water supply system, and each level of purification device is provided with a corresponding water outlet;
    次氯酸水生成装置,所述次氯酸水生成装置位于所述净化装置下游并具有反应装置、进水口和添加剂注入装置,其中所述进水口选择性地与其中一级净化装置的出水口连接,所述添加剂注入装置用于容纳添加剂并将添加剂加入反应装置,以及所述反应装置用于将所述添加剂和来自所述净化装置的水一起加工成次氯酸水;The hypochlorous acid water generating device is located downstream of the purification device and has a reaction device, a water inlet and an additive injection device, wherein the water inlet is selectively connected to the water outlet of one of the purification devices Connected, the additive injection device is used to contain the additive and add the additive to the reaction device, and the reaction device is used to process the additive and the water from the purification device into hypochlorous water;
    控制系统,所述控制系统与所述次氯酸水生成装置电连接并布置成能够控制进入所述次氯酸水生成装置的进水量和添加剂的添加量;以及A control system that is electrically connected to the hypochlorous acid water generating device and arranged to be able to control the amount of water entering the hypochlorous acid water generating device and the addition amount of additives; and
    供水口,所述净化装置的出水口和所述次氯酸水生成装置的出水口通过对应的管道可切换地连接至所述供水口。A water supply port, the water outlet of the purification device and the water outlet of the hypochlorous acid water generating device are switchably connected to the water supply port through corresponding pipes.
  2. 根据权利要求1所述的微酸性次氯酸水生成设备,其特征在于,所述反应装置从上游到下游依次设有至少两个反应器,所述添加剂注入装置设有至少两个添加剂注入部,其中每个所述反应器具有平行相流体部、相界面反应部和流体均质部,其中至少第一级所述反应器的平行相流体部布置成将添加剂扩散至另一液体中而形成溶液并具有进水口、添加剂注入口和出水口;所述相界面反应部布置成能够使得来自所述平行相流体部的溶液能够在所述相界面反应部内发生溅射并具有进水口和出水口;以及所述流体均质部布置成能够使得来自所述相界面反应部的溶液的均质化并具有进水口和出水口;其中每个所述添加剂注入口与对应的所述添加剂注入部连接,所述平行相流体部的出水口与所述相界面反应部的进水口连接,所述相界面反应部的出水口与所述流体均质部的进水口连接,第一级所述反应器的所述平行相流体部的进水口连接于所述净化装置的出水口,最后一级所述反应器的所述流体均质部的出水口与所述次氯酸水生成装置的出水口连接。The slightly acidic hypochlorous acid water generating equipment according to claim 1, wherein the reaction device is provided with at least two reactors in sequence from upstream to downstream, and the additive injection device is provided with at least two additive injection parts , Wherein each of the reactors has a parallel phase fluid part, a phase interface reaction part, and a fluid homogenizing part, wherein at least the parallel phase fluid part of the first stage of the reactor is arranged to diffuse additives into another liquid to form The solution also has a water inlet, an additive injection port and a water outlet; the phase interface reaction part is arranged to enable the solution from the parallel phase fluid part to be sputtered in the phase interface reaction part and has a water inlet and a water outlet And the fluid homogenizing part is arranged to enable homogenization of the solution from the phase interface reaction part and has a water inlet and a water outlet; wherein each of the additive injection ports is connected to the corresponding additive injection part , The water outlet of the parallel phase fluid part is connected with the water inlet of the phase interface reaction part, the water outlet of the phase interface reaction part is connected with the water inlet of the fluid homogenizing part, the first stage of the reactor The water inlet of the parallel phase fluid part is connected to the water outlet of the purification device, and the water outlet of the fluid homogenizing part of the last stage of the reactor is connected to the water outlet of the hypochlorous acid water generating device .
  3. 根据权利要求1所述的微酸性次氯酸水生成设备,其特征在于,所述反应装置从上游到下游依次设有至少两个反应器,每个所述反应器具有平行相流体部、相界面反应部和流体均质部,其中所述平行相流体部为内部无障碍物的管路并具有与所述添加剂注入装置连接的入口,所述相界面反应部为内部布置有干扰片的管路并 连接于所述平行相流体部,以及所述流体均质部为内部无障碍物的管路并连接于所述相界面反应部。The slightly acidic hypochlorous acid water production equipment according to claim 1, wherein the reaction device is provided with at least two reactors in sequence from upstream to downstream, and each of the reactors has a parallel phase fluid part, a phase The interface reaction part and the fluid homogenization part, wherein the parallel phase fluid part is a pipeline with no internal obstacles and has an inlet connected to the additive injection device, and the phase interface reaction part is a tube with an interference sheet arranged inside The path is connected to the parallel phase fluid part, and the fluid homogenizing part is a pipeline with no internal objects and connected to the phase interface reaction part.
  4. 根据权利要求2-3任一项所述的微酸性次氯酸水生成设备,其特征在于,在两个所述反应器之间还设有喷射流部,所述喷射流部布置成使得来自前一级的反应器的溶液的流速加快。The slightly acidic hypochlorous acid water generating equipment according to any one of claims 2-3, characterized in that, a jet flow part is further provided between the two reactors, and the jet flow part is arranged so that The flow rate of the solution in the previous reactor is increased.
  5. 根据权利要求4所述的微酸性次氯酸水生成设备,其特征在于,所述喷射流部由内径由大变小的管路形成。4. The slightly acidic hypochlorous acid water production equipment according to claim 4, wherein the jet flow portion is formed by a pipe whose inner diameter is changed from a larger to smaller diameter.
  6. 根据权利要求4所述的微酸性次氯酸水生成设备,其特征在于,所述添加剂注入装置的最后一级所述添加剂注入部连接于所述喷射流部,从而将添加剂添加至所述喷射流部。The slightly acidic hypochlorous acid water generating equipment according to claim 4, wherein the additive injection part of the last stage of the additive injection device is connected to the jet stream part, thereby adding additives to the jet Stream Department.
  7. 根据权利要求2-3任一项所述的微酸性次氯酸水生成设备,其特征在于,所述反应装置的第一级所述反应器中,所述相界面反应部与所述流体均质部之间设有过滤器。The slightly acidic hypochlorous acid water generating equipment according to any one of claims 2-3, wherein in the first stage of the reactor of the reaction device, the phase interface reaction part and the fluid are both There is a filter between the quality parts.
  8. 根据权利要求1所述的微酸性次氯酸水生成设备,其特征在于,所述添加剂注入装置设有至少两个添加剂注入部,所述反应装置从上游到下游依次为第1平行相流体部、第1相界面反应部、过滤器、第1流体均质部、第2相界面反应部、喷射流部、第2平行相流体部、第3相界面反应部和第2流体均质部,其中每个所述平行相流体部布置成将来自对应的所述添加剂注入装置的添加剂喷射至另一液体中而形成稀释溶液;所述相界面反应部布置成使得来自所述平行相流体部的溶液能够在所述相界面反应部内发生溅射;所述过滤器和流体均质部布置成能够使得来自所述相界面反应部的溶液均质化;以及所述喷射流部布置成使得来自所述添加剂注入装置的添加剂喷射入所述第2平行相流体部。The slightly acidic hypochlorous acid water generating equipment according to claim 1, wherein the additive injection device is provided with at least two additive injection parts, and the reaction device is a first parallel phase fluid part in turn from upstream to downstream , The first phase interface reaction part, the filter, the first fluid homogenization part, the second phase interface reaction part, the jet stream part, the second parallel phase fluid part, the third phase interface reaction part and the second fluid homogenization part, Wherein each of the parallel phase fluid parts is arranged to inject the additive from the corresponding additive injection device into another liquid to form a diluted solution; the phase interface reaction part is arranged so that the The solution can be sputtered in the phase interface reaction part; the filter and the fluid homogenizing part are arranged to be able to homogenize the solution from the phase interface reaction part; and the jet stream part is arranged so that the The additive of the additive injection device is injected into the second parallel phase fluid portion.
  9. 根据权利要求1所述的微酸性次氯酸水生成设备,其特征在于,所述反应装置设置成将添加剂和来自所述净化装置的水进行溅射,增加溶液的比表面积,从而产生量子化学反应,并且分级控制H水合质子,达到H离子稳定的饱和溶解度,从而加工成pH稳定的微酸性次氯酸水。The slightly acidic hypochlorous acid water generating equipment according to claim 1, wherein the reaction device is configured to sputter additives and water from the purification device to increase the specific surface area of the solution, thereby generating quantum chemistry It reacts and controls the H hydration protons in stages to achieve the stable saturated solubility of H ions, thereby processing it into slightly acidic hypochlorous water with stable pH.
  10. 根据权利要求2所述的微酸性次氯酸水生成设备,其特征在于,所述净化装置与所述反应装置之间通过管道连接,该管道上布置有流量调节阀和第一流量传感器,所述流量调节阀和所述第一流量传感器均与所述控制系统电连接,所述控制系统布置成根据所述第一流量传感器采样的值来控制所述流量调节阀。The slightly acidic hypochlorous acid water generating equipment according to claim 2, wherein the purification device and the reaction device are connected by a pipeline, and the pipeline is arranged with a flow regulating valve and a first flow sensor, so Both the flow regulating valve and the first flow sensor are electrically connected to the control system, and the control system is arranged to control the flow regulating valve according to a value sampled by the first flow sensor.
  11. 根据权利要求10所述的微酸性次氯酸水生成设备,其特征在于,所述最后一级反应器的下游设有pH值传感器,所述pH值传感器与所述控制系统电连接,以及所述控制系统进一步布置成根据所述pH值传感器检测到的pH值来同时控制所述流量调节阀和所述添加剂注入部的添加剂注入量。The slightly acidic hypochlorous acid water production equipment according to claim 10, wherein a pH sensor is provided downstream of the last-stage reactor, and the pH sensor is electrically connected to the control system, and The control system is further arranged to simultaneously control the flow control valve and the additive injection amount of the additive injection part according to the pH value detected by the pH sensor.
  12. 根据权利要求10所述的微酸性次氯酸水生成设备,其特征在于,所述最后一级反应器的下游设有pH值传感器,所述pH值传感器与所述控制系统电连接;所述添加剂注入部设有容器、第二流量传感器和泵,其中所述容器经由管道连接至所述泵,所述泵经由管道连接至所述反应装置,所述第二流量传感器布置于所述容器与所述泵之间的管路上,以及所述控制系统进一步布置成根据所述pH值传感器检测到的pH值和所述第二流量传感器检测到的值来同时控制所述流量调节阀和所述泵。The slightly acidic hypochlorous acid water generating equipment according to claim 10, wherein a pH sensor is provided downstream of the last-stage reactor, and the pH sensor is electrically connected to the control system; The additive injection part is provided with a container, a second flow sensor and a pump, wherein the container is connected to the pump via a pipe, the pump is connected to the reaction device via a pipe, and the second flow sensor is arranged between the container and the pump. The pipeline between the pumps and the control system are further arranged to simultaneously control the flow regulating valve and the flow control valve according to the pH value detected by the pH value sensor and the value detected by the second flow sensor. Pump.
  13. 根据权利要求1所述的微酸性次氯酸水生成设备,其特征在于,所述反应装置具有两个反应器,且所述添加剂注入装置具有两个添加剂注入部,其中第一个添加剂注入部用于将NaClO注入第一个反应器,第二个添加剂注入装置用于将HCl注入第二个反应器。The slightly acidic hypochlorous acid water generating equipment according to claim 1, wherein the reaction device has two reactors, and the additive injection device has two additive injection parts, wherein the first additive injection part It is used to inject NaClO into the first reactor, and the second additive injection device is used to inject HCl into the second reactor.
  14. 根据权利要求13所述的微酸性次氯酸水生成设备,其特征在于,所述NaClO的浓度为12%以下,所述HCl的浓度为12%以下。The slightly acidic hypochlorous acid water generating equipment according to claim 13, wherein the concentration of the NaClO is 12% or less, and the concentration of the HCl is 12% or less.
  15. 根据权利要求1所述的微酸性次氯酸水生成设备,其特征在于,所述水生成设备从上游到下游依次包括分别用于制作软化水、饮用水、RO水、EDI水以及蒸馏水的软化水净化装置、饮用水净化装置、RO水净化装置、EDI水净化装置以及蒸馏装置中至少两个,其中所述软化水净化装置、所述饮用水净化装置、所述RO水净化装置、所述EDI水净化装置以及所述蒸馏装置均通过管道和阀门与所述反应装置连接,所述控制系统进一步布置成根据水的生产要求来控制该阀门的启闭。The slightly acidic hypochlorous acid water generating equipment according to claim 1, wherein the water generating equipment includes softeners for making softened water, drinking water, RO water, EDI water, and distilled water in sequence from upstream to downstream. At least two of the water purification device, the drinking water purification device, the RO water purification device, the EDI water purification device, and the distillation device, wherein the softened water purification device, the drinking water purification device, the RO water purification device, the Both the EDI water purification device and the distillation device are connected to the reaction device through pipes and valves, and the control system is further arranged to control the opening and closing of the valve according to the water production requirements.
  16. 根据权利要求15所述的微酸性次氯酸水生成设备,其特征在于,所述软化水净化装置布置成对所述原水进行砂滤、炭滤、软化和精密过滤中的至少一种处理,其中所述软化水净化装置的出水口通过管道可切换地连接至所述供水口和所述次氯酸水生成装置;所述饮用水净化装置包括超滤膜组过滤器,所述超滤膜组过滤器布置成进一步过滤来自所述软化水净化装置的水,其中所述超滤膜组过滤器的出水口通过管道可切换地连接至所述供水口和所述次氯酸水生产装置;所述RO水净化装置包括反渗透膜过滤器,所述反渗透膜过滤器位于所述超滤膜组过滤器下游并用 于进一步过滤来自所述超滤膜组过滤器的水,其中所述反渗透膜过滤器的出水口通过管道可切换地连接至所述供水口和所述次氯酸水生产装置;其中所述EDI水净化装置包括电去离子装置,所述电去离子装置位于所述反渗透膜过滤器下游并用于进一步过滤来自所述反渗透膜过滤器的水,所述电去离子装置的出水口通过管道可切换地连接至所述供水口和所述次氯酸水生成装置;所述蒸馏装置位于所述电去离子装置下游并用于进一步蒸馏来自所述电去离子装置的水,其中所述蒸馏装置的出水口通过管道可切换地连接至所述供水口和所述次氯酸水生成装置。The slightly acidic hypochlorous acid water generating device according to claim 15, wherein the softened water purification device is arranged to perform at least one of sand filtration, carbon filtration, softening and precision filtration on the raw water, The water outlet of the softened water purification device is switchably connected to the water supply port and the hypochlorous acid water generating device through a pipe; the drinking water purification device includes an ultrafiltration membrane group filter, and the ultrafiltration membrane The group of filters is arranged to further filter the water from the softened water purification device, wherein the water outlet of the ultrafiltration membrane group filter is switchably connected to the water supply port and the hypochlorous acid water production device through a pipe; The RO water purification device includes a reverse osmosis membrane filter, the reverse osmosis membrane filter is located downstream of the ultrafiltration membrane set filter and used to further filter the water from the ultrafiltration membrane set filter, wherein the reverse osmosis membrane filter The water outlet of the permeable membrane filter is switchably connected to the water supply port and the hypochlorous acid water production device through a pipe; wherein the EDI water purification device includes an electrodeionization device, and the electrodeionization device is located in the Downstream of the reverse osmosis membrane filter and used to further filter the water from the reverse osmosis membrane filter, the water outlet of the electrodeionization device is switchably connected to the water supply port and the hypochlorous acid water generating device through a pipe The distillation device is located downstream of the electrodeionization device and is used to further distill water from the electrodeionization device, wherein the water outlet of the distillation device is switchably connected to the water supply port and the secondary through a pipe Chloric acid water generator.
  17. 根据权利要求15所述的微酸性次氯酸水生成设备,其特征在于,所述微酸性次氯酸水生成设备进一步包括至少一个蓄水罐,至少一级所述净化装置的出水口通过管道连接有对应的蓄水罐,以及所述次氯酸水生成装置的出水口通过管道连接有对应的蓄水罐,其中各所述蓄水罐的出水口经由管道连接于所述供水口。The slightly acidic hypochlorous acid water generating equipment according to claim 15, wherein the slightly acidic hypochlorous acid water generating equipment further comprises at least one water storage tank, and at least one water outlet of the purification device passes through a pipeline The corresponding water storage tank is connected, and the water outlet of the hypochlorous acid water generating device is connected to the corresponding water storage tank through a pipe, wherein the water outlet of each water storage tank is connected to the water supply port via a pipe.
  18. 根据权利要求17所述的微酸性次氯酸水生成设备,其特征在于,所述微酸性次氯酸水生成设备具有两个供水口,与所述净化装置的出水口连接的蓄水罐的出水口连接至其中一个供水口,与所述次氯酸水生成装置的出水口连接的蓄水罐的出水口连接至另一个供水口。The slightly acidic hypochlorous acid water generating device according to claim 17, wherein the slightly acidic hypochlorous acid water generating device has two water supply ports, and the water storage tank connected to the water outlet of the purification device The water outlet is connected to one of the water supply ports, and the water outlet of the water storage tank connected to the water outlet of the hypochlorous acid water generating device is connected to the other water supply port.
  19. 根据权利要求18所述的微酸性次氯酸水生成设备,其特征在于,所述蓄水罐包括去离子水蓄水罐、饮用水蓄水罐、高纯水蓄水罐、超纯水蓄水罐和蒸馏水蓄水罐中的一个或多个,其中所述去离子水蓄水罐位于所述软化水净化装置下游并用于存储来自所述软化水净化装置的去离子水;所述饮用水蓄水罐位于所述超滤膜组过滤器的下游并与所述超滤膜组过滤器的出水口连接,用于存储来自所述超滤膜组过滤器的饮用水;所述高纯水蓄水罐位于所述反渗透膜过滤器的下游并与所述反渗透膜过滤器的出水口连接,用于存储来自所述反渗透膜过滤器的高纯水;所述超纯水蓄水罐位于所述电去离子装置下游并与所述电去离子装置的出水口连接,用于存储来自所述电去离子装置的超纯水;所述蒸馏水蓄水罐位于所述蒸馏装置下游并与所述蒸馏装置的出水口连接,用于存储来自所述蒸馏装置的蒸馏水;其中所述去离子水蓄水罐、所述饮用水蓄水罐、所述高纯水蓄水罐、所述超纯水蓄水罐和所述蒸馏水蓄水罐的出水口通过管道可切换地连接至所述供水口。The slightly acidic hypochlorous acid water generating equipment according to claim 18, wherein the storage tank comprises a deionized water storage tank, a drinking water storage tank, a high-purity water storage tank, and an ultra-pure water storage tank And one or more of the distilled water storage tanks, wherein the deionized water storage tank is located downstream of the softened water purification device and is used to store the deionized water from the softened water purification device; the drinking water storage tank The tank is located downstream of the ultrafiltration membrane set filter and is connected to the outlet of the ultrafiltration membrane set filter, and is used to store drinking water from the ultrafiltration membrane set filter; the high-purity water storage tank is located The downstream of the reverse osmosis membrane filter is connected with the water outlet of the reverse osmosis membrane filter, and is used to store the high-purity water from the reverse osmosis membrane filter; the ultra-pure water storage tank is located in the electric to Downstream of the ionization device and connected to the water outlet of the electrodeionization device for storing ultrapure water from the electrodeionization device; the distilled water storage tank is located downstream of the distillation device and is connected to the water outlet of the distillation device The water outlet is connected to store distilled water from the distillation device; wherein the deionized water storage tank, the drinking water storage tank, the high-purity water storage tank, the ultra-pure water storage tank and the The water outlet of the distilled water storage tank is switchably connected to the water supply port through a pipe.
  20. 根据权利要求1所述的微酸性次氯酸水生成设备,其特征在于,所述控制系统布置成使得所述微酸性次氯酸水生成设备生成的次氯酸水的pH范围在6.20~6.80之间,且在此之间的任何数值上,其pH波动范围控制在正负0.05之 内。The slightly acidic hypochlorous acid water generating device according to claim 1, wherein the control system is arranged so that the pH of the hypochlorous acid water generated by the slightly acidic hypochlorous acid water generating device is in the range of 6.20 to 6.80 And at any value in between, the pH fluctuation range is controlled within plus or minus 0.05.
  21. 根据权利要求1所述的微酸性次氯酸水生成设备,其特征在于,所述控制系统进一步布置成使得所述微酸性次氯酸水生成设备生成的次氯酸水的浓度低于200ppm。The slightly acidic hypochlorous acid water generating device according to claim 1, wherein the control system is further arranged such that the concentration of hypochlorous acid water generated by the slightly acidic hypochlorous acid water generating device is less than 200 ppm.
  22. 根据权利要求1所述的微酸性次氯酸水生成设备,其特征在于,所述控制系统进一步布置成使得所述微酸性次氯酸水生成设备生成的次氯酸水的浓度低于60ppm。The slightly acidic hypochlorous acid water generating device according to claim 1, wherein the control system is further arranged such that the concentration of the hypochlorous acid water generated by the slightly acidic hypochlorous acid water generating device is lower than 60 ppm.
  23. 一种微酸性次氯酸水生成方法,其特征在于,所述生成方法包括以下步骤:A method for generating slightly acidic hypochlorous acid water, characterized in that the generating method comprises the following steps:
    S1、水以设定流速沿第一方向流动;S1. Water flows in the first direction at a set flow rate;
    S2、沿与水的流动方向成倾斜角度的方向将含有次氯酸根的第一添加剂添加至水中;S2. Add the first additive containing hypochlorite to the water along a direction at an oblique angle to the flow direction of the water;
    S3、使水和第一添加剂混合而成的溶液依次进行溅射和均质化处理而形成第一混合液;S3. The solution formed by mixing water and the first additive is sequentially subjected to sputtering and homogenization treatments to form a first mixed solution;
    S4、沿与所述第一混合液的流动方向成倾斜角度的方向将含有氢离子的第二添加剂添加至第一混合液中;以及S4. Add a second additive containing hydrogen ions to the first mixed liquid along a direction at an oblique angle to the flow direction of the first mixed liquid; and
    S5、使第一混合液和第二添加剂混合而成的溶液依次进行溅射和均质化处理。S5. The solution obtained by mixing the first mixed liquid and the second additive is subjected to sputtering and homogenization treatments in sequence.
  24. 根据权利要求23所述的生成方法,其特征在于,在步骤S1之前,对水进行净化处理。The production method according to claim 23, wherein the water is purified before step S1.
  25. 根据权利要求23所述的生成方法,其特征在于,所述倾斜角度的范围为60~110度。The generating method according to claim 23, wherein the inclination angle ranges from 60 to 110 degrees.
  26. 根据权利要求23所述的生成方法,其特征在于,所述第一添加剂为NaClO,以及所述第二添加剂为HCl。The production method according to claim 23, wherein the first additive is NaClO, and the second additive is HCl.
  27. 根据权利要求26所述的生成方法,其特征在于,所述NaClO的浓度为12%以下,所述HCl的浓度为12%以下。The production method according to claim 26, wherein the concentration of the NaClO is 12% or less, and the concentration of the HCl is 12% or less.
  28. 根据权利要求23所述的生成方法,其特征在于,将所生成的微酸性次氯酸水的浓度控制在200ppm以下,优选地60ppm以下,pH范围在6.20~6.80之间,且在此之间的任何数值上,其pH波动范围控制在±0.05之内,并能稳定保存18个月。The production method according to claim 23, wherein the concentration of the produced slightly acidic hypochlorous acid water is controlled below 200 ppm, preferably below 60 ppm, and the pH range is between 6.20 and 6.80, and between For any value, the pH fluctuation range is controlled within ±0.05, and can be stored stably for 18 months.
  29. 一种微酸性次氯酸水生成方法,其特征在于,所述生成方法包括以下步骤:A method for generating slightly acidic hypochlorous acid water, characterized in that the generating method comprises the following steps:
    S1.使水和含有次氯酸根的第一添加剂形成的溶液产生非线性的震荡反应,压制 流体多次波动,再经均质化有序化排列整合而形成第一混合液;S1. Make the solution formed by water and the first additive containing hypochlorite produce a nonlinear oscillating reaction, suppress the fluid's multiple fluctuations, and then homogenize and orderly arrange and integrate to form the first mixed liquid;
    S2.使得所述第一混合液和含有氢离子的第二添加剂形成的溶液进行波粒二重性的量子反应,达到H离子稳定的饱和溶解度,从而加工成pH稳定的微酸性次氯酸水。S2. Make the solution formed by the first mixed solution and the second additive containing hydrogen ions undergo a wave-particle duality quantum reaction to achieve a stable saturated solubility of H ions, thereby processing it into slightly acidic hypochlorous acid water with stable pH.
  30. 根据权利要求29所述的生成方法,其特征在于,所述第一添加剂为NaClO,以及所述第二添加剂为HCl。The production method according to claim 29, wherein the first additive is NaClO, and the second additive is HCl.
  31. 根据权利要求30所述的生成方法,其特征在于,所述NaClO的浓度为12%以下,所述HCl的浓度为12%以下。The production method according to claim 30, wherein the concentration of the NaClO is 12% or less, and the concentration of the HCl is 12% or less.
  32. 根据权利要求29所述的生成方法,其特征在于,将所生成的微酸性次氯酸水的浓度控制在200ppm以下,优选地60ppm以下,pH范围在6.20~6.80之间,且在此之间的任何数值上,其pH波动范围控制在±0.05之内,并能稳定保存18个月。The production method according to claim 29, wherein the concentration of the slightly acidic hypochlorous acid water produced is controlled to be 200 ppm or less, preferably 60 ppm or less, and the pH range is between 6.20 and 6.80. For any value, the pH fluctuation range is controlled within ±0.05, and can be stored stably for 18 months.
PCT/CN2020/088929 2019-06-06 2020-05-07 Non-electrolytic slightly acidic hypochlorous water generation apparatus, and generation method WO2020244353A1 (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
CN201910491825 2019-06-06
CN201910491825.0 2019-06-06
CN201910689048.0 2019-07-29
CN201910689048.0A CN110282807A (en) 2019-06-06 2019-07-29 Non-electrolytic subacidity hypochloric acid water generating device and generation method

Publications (1)

Publication Number Publication Date
WO2020244353A1 true WO2020244353A1 (en) 2020-12-10

Family

ID=68024115

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/CN2020/088929 WO2020244353A1 (en) 2019-06-06 2020-05-07 Non-electrolytic slightly acidic hypochlorous water generation apparatus, and generation method

Country Status (2)

Country Link
CN (3) CN110282808A (en)
WO (1) WO2020244353A1 (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110282808A (en) * 2019-06-06 2019-09-27 上海万籁环保科技股份有限公司 Application of the non-electrolytic subacidity hypochloric acid water in fresh-cut fruit and vegetable is fresh-keeping
CN111264615A (en) * 2020-03-16 2020-06-12 四川天星智能包装股份有限公司 Bacteriostasis method for vegetable and fruit processing
CN111232929A (en) * 2020-03-24 2020-06-05 乔卫峰 Equipment for preparing hypochlorous acid solution and hypochlorous acid solution preparation process
CN115474626B (en) * 2021-07-23 2023-10-24 上海万籁环保科技股份有限公司 Cold fresh preservation method of pork

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001327975A (en) * 2000-05-22 2001-11-27 Sepikkusu:Kk Residual chlorine correction apparatus for dental tap water
KR20140103414A (en) * 2013-02-18 2014-08-27 동서대학교산학협력단 Apparatus for manufacturing of hypochlorous acid sloution and thereby aparatus for disinfect medical suction
US20150119245A1 (en) * 2013-10-25 2015-04-30 EIJ Industries, Inc. Method for Producing Shelf Stable Hypochlorous Acid Solutions
CN206447622U (en) * 2017-01-22 2017-08-29 沈阳溢源生物科技有限公司 A kind of simple manufacture device of hypochlorous acid disinfectant
CN109368898A (en) * 2018-11-14 2019-02-22 上海万籁环保科技股份有限公司 Water correction plant
CN110282807A (en) * 2019-06-06 2019-09-27 上海万籁环保科技股份有限公司 Non-electrolytic subacidity hypochloric acid water generating device and generation method
CN209507869U (en) * 2018-11-14 2019-10-18 上海万籁环保科技股份有限公司 Mixing tank and water correction plant for water correction plant
CN110482755A (en) * 2018-11-23 2019-11-22 上海万籁环保科技股份有限公司 Subacidity hypochloric acid water production equipment

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4413983B1 (en) * 2008-10-21 2010-02-10 善和 山本 Sterilization and deodorant water production device, solution tank loading structure, solution tank cap
JP2015104719A (en) * 2013-12-02 2015-06-08 Ebisuya 株式会社 Production method of weakly-acidic hypochlorous acid aqueous solution
CN106386850A (en) * 2016-11-23 2017-02-15 沐康源科技(北京)有限公司 Preparation method and preparation apparatus of slightly-acidic hypochlorous acid water

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001327975A (en) * 2000-05-22 2001-11-27 Sepikkusu:Kk Residual chlorine correction apparatus for dental tap water
KR20140103414A (en) * 2013-02-18 2014-08-27 동서대학교산학협력단 Apparatus for manufacturing of hypochlorous acid sloution and thereby aparatus for disinfect medical suction
US20150119245A1 (en) * 2013-10-25 2015-04-30 EIJ Industries, Inc. Method for Producing Shelf Stable Hypochlorous Acid Solutions
CN206447622U (en) * 2017-01-22 2017-08-29 沈阳溢源生物科技有限公司 A kind of simple manufacture device of hypochlorous acid disinfectant
CN109368898A (en) * 2018-11-14 2019-02-22 上海万籁环保科技股份有限公司 Water correction plant
CN209507869U (en) * 2018-11-14 2019-10-18 上海万籁环保科技股份有限公司 Mixing tank and water correction plant for water correction plant
CN110482755A (en) * 2018-11-23 2019-11-22 上海万籁环保科技股份有限公司 Subacidity hypochloric acid water production equipment
CN110282807A (en) * 2019-06-06 2019-09-27 上海万籁环保科技股份有限公司 Non-electrolytic subacidity hypochloric acid water generating device and generation method

Also Published As

Publication number Publication date
CN110282807A (en) 2019-09-27
CN210796076U (en) 2020-06-19
CN110282808A (en) 2019-09-27

Similar Documents

Publication Publication Date Title
WO2020244353A1 (en) Non-electrolytic slightly acidic hypochlorous water generation apparatus, and generation method
US6146524A (en) Multi-stage ozone injection water treatment system
US20180370826A1 (en) Method and apparatus for providing re-mineralized water
US20080023400A1 (en) Water treatment system and method with a continuous partial flow bypass path
US10071402B2 (en) Method for sterilizing water treatment apparatus having plurality of tanks
US20120267298A1 (en) Water purification system
CN209128238U (en) Subacidity hypochloric acid water production equipment
CN209507869U (en) Mixing tank and water correction plant for water correction plant
JP2005279614A (en) Water cleaning device
KR101446127B1 (en) Water treatment apparatus
RU2758346C1 (en) Method for obtaining and selling alkaline water
EP1801078B1 (en) Apparatus for purification treatment of drinking water and process therefor
KR101459001B1 (en) Water treatment apparatus and water treatment method
CN209128236U (en) Water correction plant
CN110482755A (en) Subacidity hypochloric acid water production equipment
CN209135230U (en) Subacidity hypochloric acid water production equipment
CN209128237U (en) Subacidity hypochloric acid water production equipment
WO2023032305A1 (en) Drinking water supply system
RU2281256C1 (en) Method of fine cleaning of water
CN109368898A (en) Water correction plant
KR101447963B1 (en) Water treatment method
CN216890474U (en) Water treatment device
JPH078996A (en) Method and system for producing aseptic aqueous solution
CN209128226U (en) Water correction plant with disinfection system
RU2758347C1 (en) Automatic machine for production and sale of alkaline water

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 20817726

Country of ref document: EP

Kind code of ref document: A1

NENP Non-entry into the national phase

Ref country code: DE

122 Ep: pct application non-entry in european phase

Ref document number: 20817726

Country of ref document: EP

Kind code of ref document: A1

122 Ep: pct application non-entry in european phase

Ref document number: 20817726

Country of ref document: EP

Kind code of ref document: A1