WO2020224436A1 - Support column array having varying elastic modulus, and vacuum glass - Google Patents

Support column array having varying elastic modulus, and vacuum glass Download PDF

Info

Publication number
WO2020224436A1
WO2020224436A1 PCT/CN2020/086070 CN2020086070W WO2020224436A1 WO 2020224436 A1 WO2020224436 A1 WO 2020224436A1 CN 2020086070 W CN2020086070 W CN 2020086070W WO 2020224436 A1 WO2020224436 A1 WO 2020224436A1
Authority
WO
WIPO (PCT)
Prior art keywords
elastic modulus
edge
support column
vacuum glass
glass
Prior art date
Application number
PCT/CN2020/086070
Other languages
French (fr)
Chinese (zh)
Inventor
孙诗兵
刘敏
李要辉
吕锋
王晋珍
田英良
崔素萍
司国栋
金晓冬
Original Assignee
北京工业大学
中国建筑材料科学研究总院有限公司
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 北京工业大学, 中国建筑材料科学研究总院有限公司 filed Critical 北京工业大学
Publication of WO2020224436A1 publication Critical patent/WO2020224436A1/en

Links

Images

Classifications

    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C27/00Joining pieces of glass to pieces of other inorganic material; Joining glass to glass other than by fusing
    • C03C27/06Joining glass to glass by processes other than fusing

Definitions

  • the invention relates to the technical field of vacuum glass, in particular to a differential elastic modulus support column array and vacuum glass, which is suitable for the manufacture of flat vacuum glass.
  • the two plates of vacuum glass are supported by supporting columns arranged in an array to form a gap; the four peripheries of the two plates of plate glass are sealed with edge sealing materials to form an edge; and the vacuum is drawn from the preset holes on the plate glass Sealing, a vacuum is formed between the two plates of glass; the above process and material combination form a flat vacuum glass (referred to as vacuum glass).
  • the edge sealing refers to the process of sealing the surroundings of the vacuum glass, and also refers to the structure formed by the edge sealing material and the glass bonded to it.
  • Vacuum prevents the three basic heat transfer methods of heat conduction and convection heat transfer.
  • the flat glass such as low-e glass will prevent heat radiation and heat transfer. Therefore, vacuum glass has excellent thermal insulation effect and is widely used in building doors, windows and curtain walls. On products such as heat preservation and freezer cold preservation.
  • vacuum glass is used as a whole piece of glass, and another piece of flat glass is used to form hollow glass.
  • the sealing edge of the vacuum glass and the spacer of the insulating glass are hidden in the profile of the door and window, curtain wall, and freezer door frame.
  • Vacuum glass should have a good perspective effect, so the support column should be as small as possible to avoid discomfort in perspective.
  • the diameter of the vacuum glass support column is about 0.15mm, it is difficult to detect the existence of the support column without careful identification.
  • the height of the support column is generally about 0.15mm, because the thin and tall support column is easy to lose stability, and the vacuum heat resistance characteristics have nothing to do with the vacuum thickness.
  • the thermal conductivity of the support column is very high.
  • the thermal conductivity of metal materials is usually around 100W/m ⁇ K, and the thermal conductivity of non-metal materials is usually around 1W/m ⁇ K.
  • the supporting column can be seen as a "bridge pier" between two pieces of flat glass.
  • the arrangement density of the support columns is too large (that is, the spacing of the support column array is small), a large number of support columns will form a "thermal bridge" and reduce the thermal insulation performance of the vacuum glass. If the arrangement density is too small (that is, the spacing between the support column arrays is large), the following two unfavorable effects will occur. First, the bearing capacity per unit area of the support column increases, and correspondingly, the bearing capacity per unit area of the glass in contact with the support column increases. At this time, the support column may pierce the glass, causing damage to the glass, which may burst in severe cases. Second, the span of the glass between the two support columns is increased.
  • the glass Due to the small vacuum gap, the glass will be deformed under force, and the glass itself has a certain degree of unevenness, causing the two plates of glass to contact, that is, "glass bonding" Phenomenon, in this way, direct contact and heat transfer between the glasses lose the effect of vacuum insulation.
  • the above factors determine the arrangement density of the support column has an optimized range. At present, the optimized result is that the spacing of the support column array is 30mm-50mm, and the same material is used, that is, the material with the same elastic modulus is used as the support column, and the material of the support column has no difference in elastic modulus.
  • the vacuum glass After being evacuated, the vacuum glass is generally subjected to 1 atmosphere pressure, and at the same time, it is also subjected to the pressure of the flat glass's own weight (usually 4mm or 5mm glass). In the process of using vacuum glass, it has to withstand wind pressure, stress caused by wind pressure, stress caused by temperature difference deformation, and stress caused by structural deformation. These roles need to be shared by supporting columns and flat glass. Under the action of external force, stress and deformation are generated. Excessive stress or deformation can cause material damage.
  • vacuum glass The failure and damage of vacuum glass are mainly caused by excessive local stress or deformation. It is a recognized problem in the vacuum glass industry to handle the relationship between stress and deformation of vacuum glass.
  • the present invention provides a differential elastic modulus support column array and vacuum glass, aiming to improve the force balance and deformation balance of the glass, so that the vacuum glass material and its structure can be coordinated It can reduce local stress or deformation, and improve the safety and reliability of vacuum glass.
  • the invention discloses a differential elastic modulus support column array, which is applied between two sheets of flat glass of vacuum glass.
  • the first circumferential support column close to the edge of the vacuum glass is a low elastic modulus support column, which is close to the vacuum glass.
  • the support column for the second circumference of the sealing is a high elastic modulus support column;
  • a peripheral ring of low elastic modulus support columns and a peripheral ring of high elastic modulus support columns are alternately arranged until the support columns are all arranged.
  • the ratio of the elastic modulus of the low elastic modulus support column to the elastic modulus of the high elastic modulus support column is (0.15-0.5):1.
  • the height of the low elastic modulus support column and the high elastic modulus support column are the same, and the distance between the two adjacent circumferential support columns is the same.
  • the invention also discloses a vacuum glass, which comprises: two sheets of flat glass and the above-mentioned differential elastic modulus support column array;
  • the differential elastic modulus support column array is placed between two sheets of flat glass, and the four peripheries of the two sheets of flat glass are sealed with an edge sealing material to form an edge seal.
  • An auxiliary edge is arranged at a position close to the edge sealing, and the auxiliary edge is located inside the edge sealing.
  • the elastic modulus of the auxiliary edge is 1 to 1.3 times the elastic modulus of the edge sealing material.
  • the auxiliary edge is arranged parallel to the sealing edge, and the distance between the auxiliary edge and the parallel sealing edge is 1 to 2 mm.
  • the height of the auxiliary edge is the same as the height of the sealing edge, the width of the auxiliary edge is 0.1-0.5mm, and the distance between the two ends of the auxiliary edge and the inner edges of the two vertical sealing edges is 3mm ⁇ 15mm.
  • the differential elastic modulus support column array of the present invention can reduce the maximum stress and maximum deformation of vacuum glass, thereby reducing glass damage and the occurrence of support column vacancies.
  • the effect of the arrangement of the supporting pillars with the differential elastic modulus is valid.
  • the invention can reduce the maximum stress and maximum deformation of the sealing edge by arranging the auxiliary edge in the vacuum glass, especially reducing the tensile stress of the sealing edge, thereby reducing the occurrence of edge sealing failure.
  • Fig. 1 is a schematic structural diagram of a differential elastic modulus support column array disclosed in an embodiment of the present invention
  • FIG. 2 is a schematic diagram of the structure of the vacuum glass disclosed in an embodiment of the present invention.
  • FIG. 3 is a schematic structural diagram of a vacuum glass with auxiliary edges disclosed in an embodiment of the present invention.
  • FIG. 4 is a comparative displacement cloud diagram of a single elastic modulus support column and a differential elastic modulus support column disclosed in an embodiment of the present invention
  • Fig. 5 is a comparison diagram of edge sealing displacement before and after setting auxiliary edges according to an embodiment of the present invention.
  • the failure and damage of vacuum glass are mainly caused by excessive local stress or deformation. It is a recognized problem in the vacuum glass industry to handle the relationship between stress and deformation of vacuum glass.
  • the invention aims to improve the force balance and deformation balance of the glass, so that the vacuum glass material and its structure work together, reduce excessive local stress or deformation, and improve the safety and reliability of the vacuum glass.
  • the improvement effect is mainly evaluated by reducing the maximum stress and maximum deformation.
  • the stress and deformation of vacuum glass are extremely complex, and it is difficult to find these relationships of vacuum glass through physical test methods.
  • the invention utilizes the method of combining simulation calculation and experiment, and the results and conclusions obtained on the basis of a large number of studies.
  • the present invention provides a differential elastic modulus support column array, which is applied between two sheets of flat glass of vacuum glass, including: differential elastic modulus support columns arranged in a circumferential ring ;
  • the first circumferential support column close to the vacuum glass sealing edge 3 is a low elastic modulus support column 1
  • the second circumferential support column close to the vacuum glass sealing 3 is a high elastic modulus support column 2
  • the second circumferential support column It is the nearest inner circumference of the first circumference of the support column; and so on, in the direction away from the edge of the vacuum glass, one circumference of the low elastic modulus support column and one circumference of the high elastic modulus support column are alternately arranged, Until the support columns are all arranged, an array of different elastic modulus support columns is formed.
  • the present invention provides a vacuum glass, including: two sheets of flat glass and a differential elastic modulus support column array;
  • the differential elastic modulus support column array is placed between two pieces of flat glass, and the four peripheries of the two pieces of flat glass are sealed with an edge sealing material to form an edge sealing 3.
  • the design principle of the differential elastic modulus support column array of the present invention is:
  • the modulus of elasticity is the ratio of stress to strain when the material is deformed, reflecting the degree of difficulty of material deformation, and is the basic performance of the material.
  • the second way of expression of the present invention is to use the same elastic modulus material, and use a thinner support column for the support column near the first circumference of the sealing edge;
  • the support column adopts a thicker support column, and so on, in the direction away from the sealing edge, a support column with a thin circumference and a support column with a thick circumference are alternately performed until the support columns are all arranged.
  • support columns with different thicknesses ie, support columns with different thicknesses
  • support columns with different thicknesses are not easy to be compressed and displaced, forming a support column vacancy, which is poor in practicality.
  • the third expression of the present invention is that the same elastic modulus material is used, the support column near the first circumference of the sealing edge adopts a thinner support column; the support column near the second circumference of the sealing edge adopts a thicker support Columns, and so on, move away from the sealing edge.
  • a support column with a thinner circumference and a support column with a thicker circumference alternate until the support columns are all arranged.
  • Support columns with different cross-sectional areas ie, support columns with different cross-sectional areas) are easy to lose stability and have poor practicability.
  • the arrangement of the different elastic modulus support column, the arrangement of the different thickness support column and the arrangement of the different cross-sectional area support column are the same in principle.
  • the differential elastic modulus arrangement has strong practicability, so the present invention adopts this arrangement to express.
  • the high elastic modulus support column of the present invention is made of materials with the same elastic modulus
  • the low elastic modulus support column is made of materials with the same elastic modulus.
  • the advantage of the differential elastic modulus support column array of the present invention is to reduce the maximum stress and maximum deformation of the vacuum glass, thereby reducing glass damage and the occurrence of support column vacancies. Under the condition that the original array spacing of the support pillars of the existing product remains unchanged, or the array spacing of the newly designed support pillars, the effect of the arrangement of the different elastic modulus support pillars is valid. The invention does not restrict the array arrangement pitch of the support columns.
  • the ratio of the elastic modulus of the low elastic modulus support column to the elastic modulus of the high elastic modulus support column of the present invention is (0.15-0.5):1, preferably (0.2-0.5):1;
  • the low elastic modulus support column and the high elastic modulus support column have the same height, the spacing between two adjacent circumferential support columns is the same, and the elastic modulus of the low elastic modulus support column or the high elastic modulus support column of different circumferential rings is the same.
  • the ratio of the low elastic modulus to the high elastic modulus of the support column material is (0.15 ⁇ 0.5):1
  • the effect of significantly reducing the maximum stress and maximum deformation of the flat glass can be obtained.
  • the effect of the different elastic modulus support column layout has a direct and important relationship with the support column array spacing.
  • the embodiment illustrates the implementation effect of the specific support column array spacing. When the present invention is implemented, other specific support column array spacings can be used to correct The elastic modulus ratio of the support column is optimized.
  • the different elastic modulus support columns have the same height, so that during the preparation of vacuum glass, the support columns are not easy to be displaced and form vacancies.
  • the difference in elastic modulus of the support columns can be used to adjust the stress and Deformation, to achieve a balanced force and deformation.
  • the height of the edge-sealing material sandwiched between two sheets of flat glass should be as same as the height of the support column. .
  • the width of the sealing edge should not be too large.
  • the thermal conductivity of the sealing edge is large, forming a heat transfer "thermal bridge"; on the other hand, the sealing edge width is too large to reduce the light transmission area.
  • the currently used edge sealing width is generally between 6mm and 8mm. Practice has proved that this width can ensure the airtightness of the seal, that is, ensure the vacuum or air tightness of the device.
  • the vacuum glass After being evacuated, the vacuum glass is generally subjected to 1 atmosphere pressure, and at the same time, it is also subjected to the pressure of the flat glass's own weight (usually 4mm or 5mm glass). In the process of using vacuum glass, it has to withstand wind pressure, stress caused by wind pressure, stress caused by temperature difference deformation, and stress caused by structural deformation. These functions also need to be shared by the edge banding material and edge banding structure. Under the action of external force, stress and deformation are generated. Excessive stress or deformation can cause material damage.
  • vacuum glass can be seen as a combination of two materials, one is the relationship between the above-mentioned plate glass and the supporting column, and the other is the relationship between the plate glass and the edge sealing material, that is, edge sealing.
  • the relationship between the flat glass and the edge sealing material is: two pieces of flat glass are connected by the edge sealing material to form an edge sealing.
  • Edge sealing is the real physical or chemical connection part of the vacuum glass component, making the vacuum glass a whole.
  • Edge sealing strength is the basic performance of sealing performance. Excessive stress or deformation can cause damage to the sealing edge, including the fracture of the flat glass, the cracking between the edge sealing material and the glass, and the joint cracking between the edge sealing material and the glass. Damage to the edge banding can cause vacuum failure and severe damage to the product.
  • the stress and deformation of the edge-sealing as a whole should not be too large.
  • the present invention adds an auxiliary edge 4 to the vacuum glass shown in Figure 2, that is, an auxiliary edge 4 is arranged near the sealing edge 3, and the auxiliary edge 4 is located at the edge of the sealing edge 3.
  • the auxiliary edge of the present invention is relative to the edge sealing, and has the advantages of reducing the maximum stress and maximum deformation of the sealing edge, especially reducing the tensile stress of the sealing edge, thereby reducing the occurrence of edge sealing damage.
  • the modulus of elasticity of the auxiliary edge of the present invention is 1 to 1.3 times the modulus of elasticity of the edge sealing.
  • the design principle of the elastic modulus of the auxiliary side is:
  • the present invention finds that the elastic modulus of the auxiliary edge material and the elastic modulus of the edge banding material must be coordinated to effectively play the role of the auxiliary edge.
  • the optimized result is that the elastic modulus of the auxiliary edge material is 1 to 1.3 times that of the edge banding material.
  • the elastic modulus of the edge banding material can be obtained through testing.
  • GB/T 34338 "Test Method for the Mechanical Properties of Fusing Glass for Vacuum Glass" gives a test method for the elastic modulus of the edge banding material.
  • the technical personnel in the industry select the specific material of the auxiliary edge according to the relationship between the elastic modulus of the auxiliary edge material being 1 to 1.3 times the elastic modulus of the edge banding material.
  • it is recommended to use metal materials because the size of metal materials is easier to control, easy to install and make. In the relevant material manual, you can easily find the elastic modulus of the material.
  • auxiliary edge of the present invention is arranged parallel to the sealing edge, and the distance between the auxiliary edge and the parallel sealing edge is 1 to 2 mm; the height of the auxiliary edge is the same as the height of the sealing edge, and the width of the auxiliary edge is 0.1 to 0.5 mm.
  • the distance between the two ends and the inner edges of the two vertical sealing edges is 3mm ⁇ 15mm.
  • the design principle of the auxiliary side layout position is:
  • the distance between the auxiliary edge and the sealing edge considers two factors, one of which is to achieve the effect of reducing stress and deformation. Second, the sealing edge and the auxiliary edge should not be too wide to avoid increasing the heat transfer performance. The result of optimization is that the distance between the auxiliary edge and the sealing edge is 1 ⁇ 2mm.
  • the height of the auxiliary side is the same as the height of the edge-sealing material. If the auxiliary side is too high, it will not only bear excessive stress, but also affect the preparation of vacuum glass.
  • the optimized width of the auxiliary side is 0.15 ⁇ 0.5mm, and an excessively wide auxiliary side will increase heat transfer.
  • the length of the auxiliary edge is the length of the distance between the inner edges of the two sealing edges 3mm-15mm.
  • the four auxiliary edges around the vacuum glass can be continuous lines, such as metal wires; they can also be intermittent lines, such as several intermittent metal wires; they can also be lines composed of points, such as metal points like support columns. composition.
  • the present invention provides a differential elastic modulus support column array for vacuum glass.
  • the material of the low elastic modulus support column is YH75 aluminum alloy, the elastic modulus is 75GPa, and the material of the high elastic modulus support column is 301 stainless steel. Its elastic modulus is 210 GPa.
  • the ratio of the low elastic modulus to the high elastic modulus of the support column material is 0.34, and the spacing of the support column array is 30 mm.
  • the height of the aluminum alloy and stainless steel support columns is the same, and the same as the edge banding material, which is 0.2mm.
  • the support column of the first circumferential ring close to the sealing edge is made of aluminum alloy
  • the support column of the second circumferential ring close to the sealing edge is made of stainless steel, and so on, in the direction away from the sealing edge, one circumferential glass support column, one circumferential ring Circle the stainless steel support columns alternately until all the support columns are arranged.
  • the maximum displacement of the plate glass occurs between the first circumferential support column and the second circumferential support column, as shown in the displacement distribution cloud diagram in Figure 4a.
  • the maximum displacement is reduced by 21.7%, as shown in the displacement distribution cloud diagram in Figure 4b.
  • the maximum stress occurs at the support column in the second circle. After alternate use of aluminum alloy support columns and stainless steel support columns, the maximum stress can be reduced by 14.2%.
  • the invention provides a vacuum glass with an auxiliary edge arranged near the edge sealing position.
  • the edge-sealing width is 6mm
  • the edge-sealing material is glass fusion sealing solder
  • its elastic modulus is 75GPa
  • its height is 0.2mm
  • the auxiliary edge material is YH75 aluminum alloy
  • its elastic modulus is 75GPa.
  • the ratio of elastic modulus between the two is 1:1.
  • the distance between the auxiliary edge and the sealing edge is 1mm
  • the height is the same as the height of the edge sealing material
  • its width is 1mm
  • its length is the length of the 4mm distance from the inner edges of the two sealing edges.
  • the displacement comparison before and after the auxiliary edge is set.
  • the maximum deformation of the sealing edge close to the support column unit is about 2.5nm, and the compressive stress; close to the support column unit (curve 2 in Figure 5a), the deformation is small; close to the support column unit ( Curve 3) in Figure 5a, the maximum deformation is about 1.0nm, under tensile stress.
  • the maximum maximum deformation of the sealing edge is about 0.35nm (curve 3 in Figure 5b), under tensile stress.
  • the maximum deformation caused by tensile stress before and after the auxiliary edge is set is reduced by 65.0%.
  • the maximum tensile stress occurs at the outermost side of the sealing edge (the side away from the support column). After the auxiliary edge is set, the maximum tensile stress is reduced by 60.0%.
  • the present invention provides a differential elastic modulus support column array for vacuum glass, the material of the low elastic modulus support column is C97 copper alloy, the elastic modulus is 95 GPa; the material of the high elastic modulus support column is 301 stainless steel, the elastic modulus The volume is 210GPa, and the spacing of the support column array is 40mm.
  • the support column of the first circumference near the sealing edge is made of copper alloy, and the support column of the second circumference near the sealing edge is made of stainless steel, and so on, in the direction away from the sealing edge, one circumference of copper alloy support pillar and one The surrounding stainless steel support columns alternate until all the support columns are arranged.
  • the ratio of the low elastic modulus to the high elastic modulus of the support column material is 0.45, and the height of the copper alloy support column and the stainless steel support column are the same, which is 0.2mm.
  • the maximum displacement of the plate glass occurs between the four support columns at the corners, and the maximum displacement can be reduced by 11.5%.
  • the displacement of the plate glass between every four support columns can be reduced by 23.0%.
  • the invention provides a vacuum glass with an auxiliary edge arranged near the edge sealing position.
  • the edge-sealing width is 2mm
  • the edge-sealing material is glass fusion sealing solder, its elastic modulus is 75GPa, and its height is 0.2mm.
  • the auxiliary side material is YH75 aluminum alloy, and its elastic modulus is 75GPa.
  • the distance between the auxiliary edge and the sealing edge is 1mm
  • the height is the same as the height of the edge sealing material
  • its width is 2mm
  • its length is the length of the distance between the inner edges of the two sealing edges 7mm.
  • the maximum displacement at the sealing edge is reduced by 25%, and the maximum tensile stress at the sealing edge is reduced by 25%.
  • the present invention provides a differential elastic modulus support column array for vacuum glass.
  • the material of the low elastic modulus support column is QMn1.5 (Cu-1.5Mn) manganese bronze alloy, and its elastic modulus is 105 GPa and high elastic modulus.
  • the material of the support column is 301 stainless steel, its elastic modulus is 210 GPa, and the array spacing of the support column is 50 mm.
  • the support column of the first circumference near the sealing edge is made of manganese bronze alloy, the support column of the second circumference near the sealing edge is made of stainless steel, and so on, in the direction away from the sealing edge, one circumference glass support column, one The surrounding stainless steel support columns alternate until all the support columns are arranged.
  • the ratio of the low elastic modulus to the high elastic modulus of the support column material is 0.5, and the height of the aluminum alloy support column and the stainless steel support column are the same, which is 0.2mm.
  • the maximum displacement of the plate glass occurs between the four support columns at the corners, and the maximum displacement can be reduced by 10.19%.
  • the plate glass displacement between every four support columns can be reduced by 27%.
  • the invention provides a vacuum glass with an auxiliary edge arranged near the edge sealing position.
  • the edge sealing width is 10mm
  • the edge sealing material is glass fusion sealing
  • the elastic modulus is 75GPa
  • the height is 0.2mm
  • the auxiliary edge material is YH75 aluminum alloy.
  • the distance between the auxiliary edge and the sealing edge is 1mm
  • the height is the same as the height of the edge sealing material
  • its width is 0.5mm
  • its length is the length of the distance between the inner edges of the two sealing edges 10mm.
  • the maximum displacement at the sealing edge is reduced by 18.2%, and the maximum tensile stress at the sealing edge is reduced by 15.4%.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Joining Of Glass To Other Materials (AREA)
  • Securing Of Glass Panes Or The Like (AREA)

Abstract

A support column array having a variable elastic modulus, and a vacuum glass. A first ring of support columns in the variable elastic modulus support column array close to a sealed edge of the vacuum glass comprises low-elastic modulus support columns. A second ring of support columns close to the sealed edge of the vacuum glass comprises high-elastic modulus support columns. In this manner, rings of low elastic modulus support columns and rings of high elastic modulus support columns are alternately arranged in a direction leading away from the sealed edge of the vacuum glass, until the support columns are all arranged. The vacuum glass is formed from the varying elastic modulus support column array and flat glass. The varying elastic modulus support column array reduces the maximum stress and the maximum deformation sustained by the vacuum glass, thereby reducing glass damage and missing support columns. The arrangement of the varying elastic modulus support columns can be applied without changing the original array spacing of support columns of existing products, or using the array spacing of support columns in novel designs.

Description

一种差异性弹性模量支撑柱阵列及真空玻璃A differential elastic modulus support column array and vacuum glass 技术领域Technical field
本发明涉及真空玻璃技术领域,具体涉及一种差异性弹性模量支撑柱阵列及真空玻璃,适用于平板式真空玻璃的制造。The invention relates to the technical field of vacuum glass, in particular to a differential elastic modulus support column array and vacuum glass, which is suitable for the manufacture of flat vacuum glass.
背景技术Background technique
真空玻璃的两片平板玻璃由阵列排布的支撑柱支撑,形成间隙;两片平板玻璃的四个周边用封边材料密封,形成封边;并从一片平板玻璃上预设的孔抽取真空后密封,则在两片平板玻璃间隙形成真空;上述过程和材料组合构成平板式真空玻璃(简称真空玻璃)。其中,封边既指将真空玻璃四周密封的工艺过程,也指封边材料及其所粘接的玻璃而形成的结构。真空阻止了三种基本热传递方式的导热传热和对流传热,其中的平板玻璃如采用低辐射玻璃将阻止热辐射传热,因此真空玻璃具有优良的绝热效果,广泛用于建筑门窗、幕墙保温和冰柜保冷等产品上。The two plates of vacuum glass are supported by supporting columns arranged in an array to form a gap; the four peripheries of the two plates of plate glass are sealed with edge sealing materials to form an edge; and the vacuum is drawn from the preset holes on the plate glass Sealing, a vacuum is formed between the two plates of glass; the above process and material combination form a flat vacuum glass (referred to as vacuum glass). Among them, the edge sealing refers to the process of sealing the surroundings of the vacuum glass, and also refers to the structure formed by the edge sealing material and the glass bonded to it. Vacuum prevents the three basic heat transfer methods of heat conduction and convection heat transfer. The flat glass such as low-e glass will prevent heat radiation and heat transfer. Therefore, vacuum glass has excellent thermal insulation effect and is widely used in building doors, windows and curtain walls. On products such as heat preservation and freezer cold preservation.
在真空玻璃作为门窗、幕墙、冰柜等实际应用中,是将真空玻璃作为一块玻璃整体,与另一片平板玻璃组成中空玻璃。真空玻璃的封边与中空玻璃的间隔条一起隐藏在门窗、幕墙、冰柜门边框的型材内。In the practical application of vacuum glass as doors and windows, curtain walls, freezers, etc., vacuum glass is used as a whole piece of glass, and another piece of flat glass is used to form hollow glass. The sealing edge of the vacuum glass and the spacer of the insulating glass are hidden in the profile of the door and window, curtain wall, and freezer door frame.
真空玻璃应具有良好的透视效果,因此支撑柱应尽可能地小,以免造成透视的不适感。通常真空玻璃支撑柱的直径在0.15mm左右,不经过仔细辨认很难觉察支撑柱的存在。支撑柱的高度一般也在0.15mm左右,因为细而高的支撑柱容易失稳,且真空阻热特性与真空厚度并无关系。相对于真空,支撑柱的导热性能很高,金属材质的导热系数通常在100W/m·K上下,非金属通常在1W/m·K左右。支撑柱可以看成两片平板玻璃之间的“桥墩”。支撑柱的阵列排布密度过大(即支撑柱阵列间距小),大量的支撑柱将形成“热桥”,降低真空玻璃的绝热性能。排布密度过小(即支撑柱阵列间距大),则产生以下两个不利作用。第一、支撑柱单位面积的承力增大,相应地,与支撑柱接触的玻璃的单位面积承力增加。这时可造成支撑柱刺破玻璃,形成玻璃损坏,严重的会炸裂。第二、两个支撑柱之间玻璃的跨距增加,由于真空间隙很小,玻璃受力会变形,加之玻璃本身有一定的不平整度,造成两片平板玻 璃接触,即“玻璃贴合”现象,这样玻璃之间直接接触传热,丧失了真空绝热的效果。上述因素决定了支撑柱的排布密度有一个优化的范围。目前,优化的结果是支撑柱阵列间距为30mm~50mm,且采用同种材质材料,即具有相同弹性模量的材料作为支撑柱,支撑柱材质不具有弹性模量差异性。Vacuum glass should have a good perspective effect, so the support column should be as small as possible to avoid discomfort in perspective. Usually the diameter of the vacuum glass support column is about 0.15mm, it is difficult to detect the existence of the support column without careful identification. The height of the support column is generally about 0.15mm, because the thin and tall support column is easy to lose stability, and the vacuum heat resistance characteristics have nothing to do with the vacuum thickness. Compared with vacuum, the thermal conductivity of the support column is very high. The thermal conductivity of metal materials is usually around 100W/m·K, and the thermal conductivity of non-metal materials is usually around 1W/m·K. The supporting column can be seen as a "bridge pier" between two pieces of flat glass. If the array arrangement density of the support columns is too large (that is, the spacing of the support column array is small), a large number of support columns will form a "thermal bridge" and reduce the thermal insulation performance of the vacuum glass. If the arrangement density is too small (that is, the spacing between the support column arrays is large), the following two unfavorable effects will occur. First, the bearing capacity per unit area of the support column increases, and correspondingly, the bearing capacity per unit area of the glass in contact with the support column increases. At this time, the support column may pierce the glass, causing damage to the glass, which may burst in severe cases. Second, the span of the glass between the two support columns is increased. Due to the small vacuum gap, the glass will be deformed under force, and the glass itself has a certain degree of unevenness, causing the two plates of glass to contact, that is, "glass bonding" Phenomenon, in this way, direct contact and heat transfer between the glasses lose the effect of vacuum insulation. The above factors determine the arrangement density of the support column has an optimized range. At present, the optimized result is that the spacing of the support column array is 30mm-50mm, and the same material is used, that is, the material with the same elastic modulus is used as the support column, and the material of the support column has no difference in elastic modulus.
抽真空后真空玻璃普遍受到1个大气压作用,同时还要受到平板玻璃自重的压力(通常为4mm或5mm玻璃)。在真空玻璃使用过程中,要承受风压作用、风压引起变形的应力作用、温差变形引起的应力作用、构造变形引起的应力作用等。这些作用需要支撑柱、平板玻璃等共同承担。在外界力的作用下,产生应力和变形,应力或变形过大则可导致材料破坏。After being evacuated, the vacuum glass is generally subjected to 1 atmosphere pressure, and at the same time, it is also subjected to the pressure of the flat glass's own weight (usually 4mm or 5mm glass). In the process of using vacuum glass, it has to withstand wind pressure, stress caused by wind pressure, stress caused by temperature difference deformation, and stress caused by structural deformation. These roles need to be shared by supporting columns and flat glass. Under the action of external force, stress and deformation are generated. Excessive stress or deformation can cause material damage.
平板玻璃与支撑柱之间并无物理连接或化学连接,仅仅靠真空形成的内外压差压紧固定。当变形过大时(包括平板玻璃本身的不平整性),一些支撑柱将不能充分压紧,支撑柱移动到其它位置,造成常见的支撑柱空位现象(即阵列位置无支撑柱)。空位造成其该处玻璃无支撑而变形过大,可形成玻璃贴合。空位同时造成空位周围的支撑柱受到更大应力。平板玻璃的面积很大,但它与支撑柱接触部位可以看成点接触,支撑柱承受过大应力意味着与之接触的玻璃承受更大应力。由于玻璃为脆性材料,此处的应力过大,将造成玻璃产生裂纹。这种裂纹在实际真空玻璃并不罕见,也是引起真空玻璃破坏的重要原因之一。理想的支撑效果是各支撑柱均匀受力,玻璃均匀变形,避免应力集中和过大的变形起伏。以上可见,在平板玻璃与支撑柱的关系中,平板玻璃的应力和变形是造成真空玻璃失效和破坏的主要因素。There is no physical or chemical connection between the flat glass and the support column, and it is only tightly fixed by the pressure difference between the inside and outside formed by the vacuum. When the deformation is too large (including the unevenness of the flat glass itself), some support columns will not be fully compressed, and the support columns will move to other positions, resulting in the common phenomenon of vacancy of the support columns (that is, the array position has no support columns). The vacancy causes the glass at that place to be unsupported and deformed too much, which can form glass bonding. The vacancy also causes greater stress on the support pillars around the vacancy. The area of the flat glass is large, but the contact part of the plate glass can be regarded as a point contact. Excessive stress on the support column means that the glass in contact with it bears greater stress. Since glass is a brittle material, excessive stress here will cause cracks in the glass. This kind of crack is not uncommon in actual vacuum glass, and it is also one of the important reasons for the destruction of vacuum glass. The ideal support effect is that the support columns are uniformly stressed and the glass is uniformly deformed to avoid stress concentration and excessive deformation. It can be seen from the above that in the relationship between the plate glass and the support column, the stress and deformation of the plate glass are the main factors that cause the failure and damage of the vacuum glass.
真空玻璃失效和破坏主要由于局部应力过大或变形过大造成的,处理好真空玻璃应力和变形关系是真空玻璃业内公认的需要解决的难题。The failure and damage of vacuum glass are mainly caused by excessive local stress or deformation. It is a recognized problem in the vacuum glass industry to handle the relationship between stress and deformation of vacuum glass.
发明内容Summary of the invention
针对上述问题中存在的不足之处,本发明提供一种差异性弹性模量支撑柱阵列及真空玻璃,旨在改善玻璃的受力均衡性和变形均衡性,以使真空玻璃材料及其结构协同作用,降低局部应力过大或变形过大,提高真空玻璃的安全性和可靠性。In view of the deficiencies in the above-mentioned problems, the present invention provides a differential elastic modulus support column array and vacuum glass, aiming to improve the force balance and deformation balance of the glass, so that the vacuum glass material and its structure can be coordinated It can reduce local stress or deformation, and improve the safety and reliability of vacuum glass.
本发明公开了一种差异性弹性模量支撑柱阵列,应用在真空玻璃的两片平板玻璃之间,靠近真空玻璃封边的第一周圈支撑柱为低弹性模量支撑柱, 靠近真空玻璃封边的第二周圈支撑柱为高弹性模量支撑柱;The invention discloses a differential elastic modulus support column array, which is applied between two sheets of flat glass of vacuum glass. The first circumferential support column close to the edge of the vacuum glass is a low elastic modulus support column, which is close to the vacuum glass. The support column for the second circumference of the sealing is a high elastic modulus support column;
以此类推,向远离真空玻璃封边的方向,一个周圈的低弹性模量支撑柱、一个周圈的高弹性模量支撑柱交替布设,直至支撑柱全部排布完毕。By analogy, in the direction away from the edge of the vacuum glass, a peripheral ring of low elastic modulus support columns and a peripheral ring of high elastic modulus support columns are alternately arranged until the support columns are all arranged.
作为本发明的进一步改进,所述低弹性模量支撑柱的弹性模量与高弹性模量支撑柱的弹性模量之比为(0.15~0.5):1。As a further improvement of the present invention, the ratio of the elastic modulus of the low elastic modulus support column to the elastic modulus of the high elastic modulus support column is (0.15-0.5):1.
作为本发明的进一步改进,所述低弹性模量支撑柱和高弹性模量支撑柱的高度一致,相邻两周圈支撑柱的间距一致。As a further improvement of the present invention, the height of the low elastic modulus support column and the high elastic modulus support column are the same, and the distance between the two adjacent circumferential support columns is the same.
本发明还公开了一种真空玻璃,包括:两片平板玻璃和上述的差异性弹性模量支撑柱阵列;The invention also discloses a vacuum glass, which comprises: two sheets of flat glass and the above-mentioned differential elastic modulus support column array;
所述差异性弹性模量支撑柱阵列置于两片平板玻璃之间,两片平板玻璃的四个周边用封边材料密封,形成封边。The differential elastic modulus support column array is placed between two sheets of flat glass, and the four peripheries of the two sheets of flat glass are sealed with an edge sealing material to form an edge seal.
作为本发明的进一步改进,还包括辅助边;As a further improvement of the present invention, it also includes auxiliary edges;
在靠近封边的位置处设置一道所述辅助边,所述辅助边位于所述封边的内侧。An auxiliary edge is arranged at a position close to the edge sealing, and the auxiliary edge is located inside the edge sealing.
作为本发明的进一步改进,所述辅助边的弹性模量为封边材料的弹性模量的1~1.3倍。As a further improvement of the present invention, the elastic modulus of the auxiliary edge is 1 to 1.3 times the elastic modulus of the edge sealing material.
作为本发明的进一步改进,所述辅助边与封边平行设置,所述辅助边距平行封边的距离为1~2mm。As a further improvement of the present invention, the auxiliary edge is arranged parallel to the sealing edge, and the distance between the auxiliary edge and the parallel sealing edge is 1 to 2 mm.
作为本发明的进一步改进,所述辅助边的高度与封边的高度相同,所述辅助边的宽度为0.1~0.5mm,所述辅助边的两端距两个垂直封边内边缘的距离为3mm~15mm。As a further improvement of the present invention, the height of the auxiliary edge is the same as the height of the sealing edge, the width of the auxiliary edge is 0.1-0.5mm, and the distance between the two ends of the auxiliary edge and the inner edges of the two vertical sealing edges is 3mm~15mm.
与现有技术相比,本发明的有益效果为:Compared with the prior art, the beneficial effects of the present invention are:
本发明的差异性弹性模量支撑柱阵列可降低真空玻璃的最大应力和最大变形,从而降低玻璃破坏和支撑柱空位发生,在既有产品支撑柱原有阵列间距不变的情况,或新设计的支撑柱的阵列间距的条件下,这种差异性弹性模量支撑柱的排布方式的效果都是成立的。The differential elastic modulus support column array of the present invention can reduce the maximum stress and maximum deformation of vacuum glass, thereby reducing glass damage and the occurrence of support column vacancies. In the case that the original array spacing of the support columns of the existing product remains unchanged, or the new design Under the condition of the array spacing of the supporting pillars, the effect of the arrangement of the supporting pillars with the differential elastic modulus is valid.
本发明通过在真空玻璃中设置辅助边,可降低封边的最大应力和最大变形,特别是降低封边的拉应力,从而降低封边破坏的产生。The invention can reduce the maximum stress and maximum deformation of the sealing edge by arranging the auxiliary edge in the vacuum glass, especially reducing the tensile stress of the sealing edge, thereby reducing the occurrence of edge sealing failure.
附图说明Description of the drawings
图1为本发明一种实施例公开的差异性弹性模量支撑柱阵列的结构示意图;Fig. 1 is a schematic structural diagram of a differential elastic modulus support column array disclosed in an embodiment of the present invention;
图2为本发明一种实施例公开的真空玻璃的结构示意图;2 is a schematic diagram of the structure of the vacuum glass disclosed in an embodiment of the present invention;
图3为本发明一种实施例公开的带辅助边的真空玻璃的结构示意图;3 is a schematic structural diagram of a vacuum glass with auxiliary edges disclosed in an embodiment of the present invention;
图4为本发明一种实施例公开的单一弹性模量支撑柱和差异性弹性模量支撑柱的对比位移云图;4 is a comparative displacement cloud diagram of a single elastic modulus support column and a differential elastic modulus support column disclosed in an embodiment of the present invention;
图5为本发明一种实施例公开的设置辅助边前后封边位移比较图。Fig. 5 is a comparison diagram of edge sealing displacement before and after setting auxiliary edges according to an embodiment of the present invention.
图中:In the picture:
1、低弹性模量支撑柱;2、高弹性模量支撑柱;3、封边;4、辅助边。1. Low elastic modulus support column; 2. High elastic modulus support column; 3. Edge banding; 4. Auxiliary edge.
具体实施方式Detailed ways
为使本发明实施例的目的、技术方案和优点更加清楚,下面将结合本发明实施例中的附图,对本发明实施例中的技术方案进行清楚、完整地描述,显然,所描述的实施例是本发明的一部分实施例,而不是全部的实施例。基于本发明中的实施例,本领域普通技术人员在没有做出创造性劳动的前提下所获得的所有其他实施例,都属于本发明保护的范围。In order to make the objectives, technical solutions, and advantages of the embodiments of the present invention clearer, the technical solutions in the embodiments of the present invention will be described clearly and completely in conjunction with the accompanying drawings in the embodiments of the present invention. Obviously, the described embodiments It is a part of the embodiments of the present invention, but not all the embodiments. Based on the embodiments of the present invention, all other embodiments obtained by those of ordinary skill in the art without creative work shall fall within the protection scope of the present invention.
下面结合附图对本发明做进一步的详细描述:The present invention will be further described in detail below in conjunction with the accompanying drawings:
真空玻璃失效和破坏主要由于局部应力过大或变形过大造成的,处理好真空玻璃应力和变形关系是真空玻璃业内公认的需要解决的难题。本发明旨在改善玻璃的受力均衡性和变形均衡性,以使真空玻璃材料及其结构协同作用,降低局部应力过大或变形过大,提高真空玻璃的安全性和可靠性。改善的效果主要通过降低最大应力和最大变形两个方面评价。然而,真空玻璃的应力与变形又极为复杂,通过实体试验方法很难找到真空玻璃的这些关系。本发明利用模拟计算和实验相结合的方法,在大量的研究基础上获得的结果和结论。The failure and damage of vacuum glass are mainly caused by excessive local stress or deformation. It is a recognized problem in the vacuum glass industry to handle the relationship between stress and deformation of vacuum glass. The invention aims to improve the force balance and deformation balance of the glass, so that the vacuum glass material and its structure work together, reduce excessive local stress or deformation, and improve the safety and reliability of the vacuum glass. The improvement effect is mainly evaluated by reducing the maximum stress and maximum deformation. However, the stress and deformation of vacuum glass are extremely complex, and it is difficult to find these relationships of vacuum glass through physical test methods. The invention utilizes the method of combining simulation calculation and experiment, and the results and conclusions obtained on the basis of a large number of studies.
为此,如图1、2所示,本发明提供一种差异性弹性模量支撑柱阵列,应用在真空玻璃的两片平板玻璃之间,包括:差异性弹性模量周圈排布支撑柱;To this end, as shown in Figures 1 and 2, the present invention provides a differential elastic modulus support column array, which is applied between two sheets of flat glass of vacuum glass, including: differential elastic modulus support columns arranged in a circumferential ring ;
靠近真空玻璃封边3的第一周圈支撑柱为低弹性模量支撑柱1,靠近真空玻璃封边3的第二周圈支撑柱为高弹性模量支撑柱2,第二周圈支撑柱为第一周圈支撑柱的最近内周圈;以此类推,向远离真空玻璃封边的方向,一个周 圈的低弹性模量支撑柱、一个周圈的高弹性模量支撑柱交替布设,直至支撑柱全部排布完毕,从而构成差异性弹性模量支撑柱阵列。The first circumferential support column close to the vacuum glass sealing edge 3 is a low elastic modulus support column 1, the second circumferential support column close to the vacuum glass sealing 3 is a high elastic modulus support column 2, and the second circumferential support column It is the nearest inner circumference of the first circumference of the support column; and so on, in the direction away from the edge of the vacuum glass, one circumference of the low elastic modulus support column and one circumference of the high elastic modulus support column are alternately arranged, Until the support columns are all arranged, an array of different elastic modulus support columns is formed.
如图2所示,本发明提供一种真空玻璃,包括:两片平板玻璃和差异性弹性模量支撑柱阵列;As shown in Figure 2, the present invention provides a vacuum glass, including: two sheets of flat glass and a differential elastic modulus support column array;
差异性弹性模量支撑柱阵列置于两片平板玻璃之间,两片平板玻璃的四个周边用封边材料密封,形成封边3。The differential elastic modulus support column array is placed between two pieces of flat glass, and the four peripheries of the two pieces of flat glass are sealed with an edge sealing material to form an edge sealing 3.
本发明差异性弹性模量支撑柱阵列的设计原理为:The design principle of the differential elastic modulus support column array of the present invention is:
弹性模量是材料变形时应力与应变之比,反映材料变形的难易程度,是材料的基本性能。弹性模量越大则材料变形能力低,表现为刚性大;弹性模量越小则材料变形性增加,表现为柔性大。因此,业内知晓如何根据弹性模量选择支撑柱的具体材料。基于弹性模量基本概念,本发明第二种表达方式是,采用相同弹性模量材料,靠近封边第一周圈的支撑柱采用较薄的支撑柱;靠近封接边的第二周圈的支撑柱采用较厚的支撑柱,以此类推,向远离封接边方向,一个周圈较薄的支撑柱、一个周圈较厚的支撑柱交替进行,直至支撑柱全部排布完毕。由于在真空玻璃制作过程中,厚薄不同支撑柱(即,差异性厚度支撑柱)不易压紧而产生位移,形成支撑柱空位,实用性较差。本发明第三种表达方式是,采用相同弹性模量材料,靠近封边第一周圈的支撑柱采用较细的支撑柱;靠近封接边的第二周圈的支撑柱采用较粗的支撑柱,以此类推,向远离封接边方向,一个周圈较细的支撑柱、一个周圈较粗的支撑柱交替进行,直至支撑柱全部排布完毕。截面积不同支撑柱(即,差异性截面积支撑柱),很容易失稳,实用性也较差。The modulus of elasticity is the ratio of stress to strain when the material is deformed, reflecting the degree of difficulty of material deformation, and is the basic performance of the material. The greater the elastic modulus, the lower the material's deformability, which is represented by greater rigidity; the smaller the elastic modulus, the greater the material's deformability, which is represented by greater flexibility. Therefore, the industry knows how to select the specific material of the support column according to the elastic modulus. Based on the basic concept of elastic modulus, the second way of expression of the present invention is to use the same elastic modulus material, and use a thinner support column for the support column near the first circumference of the sealing edge; The support column adopts a thicker support column, and so on, in the direction away from the sealing edge, a support column with a thin circumference and a support column with a thick circumference are alternately performed until the support columns are all arranged. In the process of manufacturing vacuum glass, support columns with different thicknesses (ie, support columns with different thicknesses) are not easy to be compressed and displaced, forming a support column vacancy, which is poor in practicality. The third expression of the present invention is that the same elastic modulus material is used, the support column near the first circumference of the sealing edge adopts a thinner support column; the support column near the second circumference of the sealing edge adopts a thicker support Columns, and so on, move away from the sealing edge. A support column with a thinner circumference and a support column with a thicker circumference alternate until the support columns are all arranged. Support columns with different cross-sectional areas (ie, support columns with different cross-sectional areas) are easy to lose stability and have poor practicability.
差异性弹性模量支撑柱布置与差异性厚度支撑柱布置、差异性截面积支撑柱布置在原理上是一致的。差异性弹性模量布置具有很强的实用性,故本发明采用了该布置方式表达。为了便于实施,本发明的高弹性模量支撑柱为同一弹性模量的材料,低弹性模量支撑柱为同一弹性模量的材料。The arrangement of the different elastic modulus support column, the arrangement of the different thickness support column and the arrangement of the different cross-sectional area support column are the same in principle. The differential elastic modulus arrangement has strong practicability, so the present invention adopts this arrangement to express. In order to facilitate implementation, the high elastic modulus support column of the present invention is made of materials with the same elastic modulus, and the low elastic modulus support column is made of materials with the same elastic modulus.
本发明的差异性弹性模量支撑柱阵列的优点为:降低真空玻璃的最大应力和最大变形,从而降低玻璃破坏和支撑柱空位发生。在既有产品支撑柱原有阵列间距不变的情况,或新设计的支撑柱的阵列间距的条件下,这种差异性弹性模量支撑柱的排布方式的效果都是成立的,故本发明不对支撑柱的阵列排布间距进行限制性说明。The advantage of the differential elastic modulus support column array of the present invention is to reduce the maximum stress and maximum deformation of the vacuum glass, thereby reducing glass damage and the occurrence of support column vacancies. Under the condition that the original array spacing of the support pillars of the existing product remains unchanged, or the array spacing of the newly designed support pillars, the effect of the arrangement of the different elastic modulus support pillars is valid. The invention does not restrict the array arrangement pitch of the support columns.
进一步,本发明的低弹性模量支撑柱的弹性模量与高弹性模量支撑柱的弹性模量之比为(0.15~0.5):1,优选为(0.2~0.5):1;本发明的低弹性模量支撑柱和高弹性模量支撑柱高度一致,相邻两周圈支撑柱的间距一致,不同周圈的低弹性模量支撑柱或高弹性模量支撑柱的弹性模量一致。Further, the ratio of the elastic modulus of the low elastic modulus support column to the elastic modulus of the high elastic modulus support column of the present invention is (0.15-0.5):1, preferably (0.2-0.5):1; The low elastic modulus support column and the high elastic modulus support column have the same height, the spacing between two adjacent circumferential support columns is the same, and the elastic modulus of the low elastic modulus support column or the high elastic modulus support column of different circumferential rings is the same.
低弹性模量支撑柱与高弹性模量支撑柱的弹性模量之比的设计原理为:The design principle of the ratio of the elastic modulus of the low elastic modulus support column to the high elastic modulus support column is:
业内知晓支撑柱材料的选择的原则,如具有足够的强度、尽可能低的导热系数等。基于差异性弹性模量支撑柱布局,当支撑柱材料的低弹性模量与高弹性模量之比为(0.15~0.5):1时,可以获得明显降低平板玻璃最大应力和最大变形的效果。差异性弹性模量支撑柱布局的效果与支撑柱阵列间距有直接和重要关系,实施例中说明了特定支撑柱阵列间距这种实施效果,本发明实施时可根据其它具体支撑柱阵列间距,对支撑柱的弹性模量比进行优化。同时,差异性弹性模量支撑柱具有相同高度,这样在真空玻璃制备过程中,支撑柱不易产生位移而形成空位,而在服役过程中可以依靠支撑柱弹性模量的差异性,自行调节应力和形变,实现均衡性受力和形变。The industry knows the principles for the selection of support column materials, such as having sufficient strength and as low thermal conductivity as possible. Based on the different elastic modulus support column layout, when the ratio of the low elastic modulus to the high elastic modulus of the support column material is (0.15~0.5):1, the effect of significantly reducing the maximum stress and maximum deformation of the flat glass can be obtained. The effect of the different elastic modulus support column layout has a direct and important relationship with the support column array spacing. The embodiment illustrates the implementation effect of the specific support column array spacing. When the present invention is implemented, other specific support column array spacings can be used to correct The elastic modulus ratio of the support column is optimized. At the same time, the different elastic modulus support columns have the same height, so that during the preparation of vacuum glass, the support columns are not easy to be displaced and form vacancies. In the service process, the difference in elastic modulus of the support columns can be used to adjust the stress and Deformation, to achieve a balanced force and deformation.
除支撑柱阵列设计容易造成玻璃破坏和支撑柱发生空位之外,在现有真空玻璃中,夹在两片平板玻璃之间的封边材料高度(封边高度)与支撑柱的高度应尽量相同。封边宽度不宜过大,一方面封边的导热系数大,形成传热“热桥”;另一方面,封边宽度过大会减少透光面积。目前采用的封边宽度一般在6mm~8mm之间,实践证明该宽度可以保证密封不透气,即保证器件的真空度,或气密性。抽真空后真空玻璃普遍受到1个大气压作用,同时还要受到平板玻璃自重的压力(通常为4mm或5mm玻璃)。在真空玻璃使用过程中,要承受风压作用、风压引起变形的应力作用、温差变形引起的应力作用、构造变形引起的应力作用等。这些作用还需要封边材料、封边结构共同承担。在外界力的作用下,产生应力和变形,应力或变形过大则可导致材料破坏。从构造和受力上,真空玻璃可以看成两种材料组合关系,一是上述平板玻璃与支撑柱的关系,二是平板玻璃与封边材料的关系,即封边。平板玻璃与封边材料的关系为:两片平板玻璃通过封边材料连接,形成封边。封边是真空玻璃组件中真正物理或化学连接的部分,使得真空玻璃成为一个整体。封边强度是封接性能的基本性能。过大的应力或变形,均可造成的封边的破坏,包括平板玻璃的断裂、封边材料与玻璃之间的开裂、封边材料与玻璃的共同 开裂。封边破坏可造成真空失效,严重的造成制品的破坏。在平板玻璃与封边材料的关系中,封边作为一个整体应力和变形不应过大。Except for the support column array design which is likely to cause glass damage and support column vacancies, in the existing vacuum glass, the height of the edge-sealing material sandwiched between two sheets of flat glass (edge-sealing height) should be as same as the height of the support column. . The width of the sealing edge should not be too large. On the one hand, the thermal conductivity of the sealing edge is large, forming a heat transfer "thermal bridge"; on the other hand, the sealing edge width is too large to reduce the light transmission area. The currently used edge sealing width is generally between 6mm and 8mm. Practice has proved that this width can ensure the airtightness of the seal, that is, ensure the vacuum or air tightness of the device. After being evacuated, the vacuum glass is generally subjected to 1 atmosphere pressure, and at the same time, it is also subjected to the pressure of the flat glass's own weight (usually 4mm or 5mm glass). In the process of using vacuum glass, it has to withstand wind pressure, stress caused by wind pressure, stress caused by temperature difference deformation, and stress caused by structural deformation. These functions also need to be shared by the edge banding material and edge banding structure. Under the action of external force, stress and deformation are generated. Excessive stress or deformation can cause material damage. In terms of structure and force, vacuum glass can be seen as a combination of two materials, one is the relationship between the above-mentioned plate glass and the supporting column, and the other is the relationship between the plate glass and the edge sealing material, that is, edge sealing. The relationship between the flat glass and the edge sealing material is: two pieces of flat glass are connected by the edge sealing material to form an edge sealing. Edge sealing is the real physical or chemical connection part of the vacuum glass component, making the vacuum glass a whole. Edge sealing strength is the basic performance of sealing performance. Excessive stress or deformation can cause damage to the sealing edge, including the fracture of the flat glass, the cracking between the edge sealing material and the glass, and the joint cracking between the edge sealing material and the glass. Damage to the edge banding can cause vacuum failure and severe damage to the product. In the relationship between the plate glass and the edge-sealing material, the stress and deformation of the edge-sealing as a whole should not be too large.
为解决上述问题,如图3所示,本发明在图2所示的真空玻璃中增加辅助边4,即在靠近封边3的位置处设置一道辅助边4,辅助边4位于封边3的内侧。本发明的辅助边是相对封边而言的,其优点为:降低封边的最大应力和最大变形,特别是降低封边的拉应力,从而降低封边破坏的产生。In order to solve the above problems, as shown in Figure 3, the present invention adds an auxiliary edge 4 to the vacuum glass shown in Figure 2, that is, an auxiliary edge 4 is arranged near the sealing edge 3, and the auxiliary edge 4 is located at the edge of the sealing edge 3. Inside. The auxiliary edge of the present invention is relative to the edge sealing, and has the advantages of reducing the maximum stress and maximum deformation of the sealing edge, especially reducing the tensile stress of the sealing edge, thereby reducing the occurrence of edge sealing damage.
进一步,本发明的辅助边的弹性模量为封边的弹性模量的1~1.3倍。Further, the modulus of elasticity of the auxiliary edge of the present invention is 1 to 1.3 times the modulus of elasticity of the edge sealing.
辅助边的弹性模量的设计原理为:The design principle of the elastic modulus of the auxiliary side is:
本发明发现,辅助边材料的弹性模量与封边材料弹性模量必须协调,才能有效发挥辅助边的作用。优化的结果是,辅助边材料的弹性模量为封边材料弹性模量的1~1.3倍。封边材料的弹性模量可以通过测试获得,GB/T 34338《真空玻璃用熔封玻璃力学性能试验方法》给出了封边材料弹性模量测试方法。然后,业内技术人员根据辅助边材料的弹性模量为封边材料弹性模量的1~1.3倍关系,选择辅助边的具体材料。作为推荐,建议使用金属材料,因为金属材料尺寸更易于控制,便于安装和制作。在相关材料手册中,可方便查到材料的弹性模量。The present invention finds that the elastic modulus of the auxiliary edge material and the elastic modulus of the edge banding material must be coordinated to effectively play the role of the auxiliary edge. The optimized result is that the elastic modulus of the auxiliary edge material is 1 to 1.3 times that of the edge banding material. The elastic modulus of the edge banding material can be obtained through testing. GB/T 34338 "Test Method for the Mechanical Properties of Fusing Glass for Vacuum Glass" gives a test method for the elastic modulus of the edge banding material. Then, the technical personnel in the industry select the specific material of the auxiliary edge according to the relationship between the elastic modulus of the auxiliary edge material being 1 to 1.3 times the elastic modulus of the edge banding material. As a recommendation, it is recommended to use metal materials, because the size of metal materials is easier to control, easy to install and make. In the relevant material manual, you can easily find the elastic modulus of the material.
进一步,本发明的辅助边与封边平行设置,辅助边距平行封边的距离为1~2mm;辅助边的高度与封边的高度相同,辅助边的宽度为0.1~0.5mm,辅助边的两端距两个垂直封边内边缘的距离为3mm~15mm。Further, the auxiliary edge of the present invention is arranged parallel to the sealing edge, and the distance between the auxiliary edge and the parallel sealing edge is 1 to 2 mm; the height of the auxiliary edge is the same as the height of the sealing edge, and the width of the auxiliary edge is 0.1 to 0.5 mm. The distance between the two ends and the inner edges of the two vertical sealing edges is 3mm~15mm.
辅助边布置位置的设计原理为:The design principle of the auxiliary side layout position is:
辅助边距离封边的距离考虑两个因素,其一,能够达到其降低应力和变形的效果。其二,封边及辅助边不宜过宽,以免增加传热性能,优化的结果是,辅助边距离封边的距离1~2mm。辅助边的高度与封边材料的高度相同,辅助边过高既要承担过大的应力,同时影响真空玻璃的制备。优化的辅助边宽度为0.15~0.5mm,过宽的辅助边将增加传热。辅助边的长度为距离相对两个封边内边缘3mm~15mm间距的长度。效果上,真空玻璃四周的四条辅助边可以是连续的线,如金属丝;也可以是间断的线,如若干间断的金属丝组成;还可以是点组成的线,如类似支撑柱的金属点组成。The distance between the auxiliary edge and the sealing edge considers two factors, one of which is to achieve the effect of reducing stress and deformation. Second, the sealing edge and the auxiliary edge should not be too wide to avoid increasing the heat transfer performance. The result of optimization is that the distance between the auxiliary edge and the sealing edge is 1~2mm. The height of the auxiliary side is the same as the height of the edge-sealing material. If the auxiliary side is too high, it will not only bear excessive stress, but also affect the preparation of vacuum glass. The optimized width of the auxiliary side is 0.15~0.5mm, and an excessively wide auxiliary side will increase heat transfer. The length of the auxiliary edge is the length of the distance between the inner edges of the two sealing edges 3mm-15mm. In effect, the four auxiliary edges around the vacuum glass can be continuous lines, such as metal wires; they can also be intermittent lines, such as several intermittent metal wires; they can also be lines composed of points, such as metal points like support columns. composition.
实施例1Example 1
本发明提供一种真空玻璃的差异性弹性模量支撑柱阵列,低弹性模量支 撑柱的材料为YH75铝合金,其弹性模量为75GPa,高弹性模量支撑柱的材料为301不锈钢材料,其弹性模量为210GPa。支撑柱材料的低弹性模量与高弹性模量之比为0.34,支撑柱阵列间距为30mm。铝合金和不锈钢支撑柱的高度相同,且与封边材料相同,为0.2mm。靠近封边的第一周圈支撑柱采用铝合金,靠近封接边的第二周圈的支撑柱采用不锈钢材料,以此类推,向远离封接边方向,一个周圈玻璃支撑柱、一个周圈不锈钢支撑柱交替进行,直至支撑柱全部排布完毕。The present invention provides a differential elastic modulus support column array for vacuum glass. The material of the low elastic modulus support column is YH75 aluminum alloy, the elastic modulus is 75GPa, and the material of the high elastic modulus support column is 301 stainless steel. Its elastic modulus is 210 GPa. The ratio of the low elastic modulus to the high elastic modulus of the support column material is 0.34, and the spacing of the support column array is 30 mm. The height of the aluminum alloy and stainless steel support columns is the same, and the same as the edge banding material, which is 0.2mm. The support column of the first circumferential ring close to the sealing edge is made of aluminum alloy, and the support column of the second circumferential ring close to the sealing edge is made of stainless steel, and so on, in the direction away from the sealing edge, one circumferential glass support column, one circumferential ring Circle the stainless steel support columns alternately until all the support columns are arranged.
采用单一不锈钢支撑柱,平板玻璃的最大位移发生第一周圈支撑柱和第二周圈支撑柱之间,如图4a位移分布云图所示。采用铝合金支撑柱和不锈钢支撑柱交替使用后,最大位移降低21.7%,如图4b位移分布云图所示。最大应力发生在第二周圈支撑柱处,采用铝合金支撑柱和不锈钢支撑柱交替使用后,最大应力可降低14.2%。With a single stainless steel support column, the maximum displacement of the plate glass occurs between the first circumferential support column and the second circumferential support column, as shown in the displacement distribution cloud diagram in Figure 4a. After alternate use of aluminum alloy support columns and stainless steel support columns, the maximum displacement is reduced by 21.7%, as shown in the displacement distribution cloud diagram in Figure 4b. The maximum stress occurs at the support column in the second circle. After alternate use of aluminum alloy support columns and stainless steel support columns, the maximum stress can be reduced by 14.2%.
本发明提供一种真空玻璃,在靠近封边位置设置一道辅助边。封边宽度为6mm,封边材料为玻璃熔封焊料,其弹性模量为75GPa,高度为0.2mm,辅助边材料为YH75铝合金,其弹性模量为75GPa。二者弹性模量比为1:1。辅助边距离封边的距离1mm,高度与封边材料的高度相同,其宽度为1mm,其长度为距离相对两个封边内边缘4mm间距的长度。The invention provides a vacuum glass with an auxiliary edge arranged near the edge sealing position. The edge-sealing width is 6mm, the edge-sealing material is glass fusion sealing solder, its elastic modulus is 75GPa, and its height is 0.2mm, the auxiliary edge material is YH75 aluminum alloy, and its elastic modulus is 75GPa. The ratio of elastic modulus between the two is 1:1. The distance between the auxiliary edge and the sealing edge is 1mm, the height is the same as the height of the edge sealing material, its width is 1mm, and its length is the length of the 4mm distance from the inner edges of the two sealing edges.
如图5所示设置辅助边前后封边位移比较。无辅助边时,封边靠近支撑柱单元(图5a中曲线1)最大变形约为2.5nm,受压应力;靠近支撑柱单元(图5a中曲线2),变形很小;靠近支撑柱单元(图5a中曲线3),最大变形约为1.0nm,受拉应力。设置辅助边后,封边的最大最大变形约0.35nm(图5b中曲线3),受拉应力。设置辅助边前后的产生拉应力的最大变形减低65.0%。最大拉应力发生在封边处最外侧(远离支撑柱一侧),设置辅助边后,最大拉应力的减小60.0%。As shown in Figure 5, the displacement comparison before and after the auxiliary edge is set. When there is no auxiliary edge, the maximum deformation of the sealing edge close to the support column unit (curve 1 in Figure 5a) is about 2.5nm, and the compressive stress; close to the support column unit (curve 2 in Figure 5a), the deformation is small; close to the support column unit ( Curve 3) in Figure 5a, the maximum deformation is about 1.0nm, under tensile stress. After setting the auxiliary edge, the maximum maximum deformation of the sealing edge is about 0.35nm (curve 3 in Figure 5b), under tensile stress. The maximum deformation caused by tensile stress before and after the auxiliary edge is set is reduced by 65.0%. The maximum tensile stress occurs at the outermost side of the sealing edge (the side away from the support column). After the auxiliary edge is set, the maximum tensile stress is reduced by 60.0%.
实施例2Example 2
本发明提供一种真空玻璃的差异性弹性模量支撑柱阵列,低弹性模量支撑柱的材料为C97铜合金,弹性模量为95GPa;高弹性模量支撑柱的材料为301不锈钢,弹性模量为210GPa,支撑柱阵列间距为40mm。靠近封边的第一周圈支撑柱采用铜合金,靠近封接边的第二周圈的支撑柱采用不锈钢材料,以此类推,向远离封接边方向,一个周圈铜合金支撑柱、一个周圈不锈钢支 撑柱交替进行,直至支撑柱全部排布完毕。支撑柱材料的低弹性模量与高弹性模量之比为0.45,铜合金支撑柱和不锈钢支撑柱的高度相同,为0.2mm。The present invention provides a differential elastic modulus support column array for vacuum glass, the material of the low elastic modulus support column is C97 copper alloy, the elastic modulus is 95 GPa; the material of the high elastic modulus support column is 301 stainless steel, the elastic modulus The volume is 210GPa, and the spacing of the support column array is 40mm. The support column of the first circumference near the sealing edge is made of copper alloy, and the support column of the second circumference near the sealing edge is made of stainless steel, and so on, in the direction away from the sealing edge, one circumference of copper alloy support pillar and one The surrounding stainless steel support columns alternate until all the support columns are arranged. The ratio of the low elastic modulus to the high elastic modulus of the support column material is 0.45, and the height of the copper alloy support column and the stainless steel support column are the same, which is 0.2mm.
平板玻璃的最大位移发生在角部位置的四个支撑柱之间,最大位移可降低11.5%。平板玻璃的其他部分,每四个支撑柱之间的平板玻璃位移可减小23.0%。The maximum displacement of the plate glass occurs between the four support columns at the corners, and the maximum displacement can be reduced by 11.5%. For other parts of the plate glass, the displacement of the plate glass between every four support columns can be reduced by 23.0%.
本发明提供一种真空玻璃,在靠近封边位置设置一道辅助边。封边宽度为2mm,封边材料为玻璃熔封焊料,其弹性模量为75GPa,高度为0.2mm。辅助边材料为YH75铝合金,其弹性模量为75GPa。辅助边距离封边的距离1mm,高度与封边材料的高度相同,其宽度为2mm,其长度为距离相对两个封边内边缘7mm间距的长度。The invention provides a vacuum glass with an auxiliary edge arranged near the edge sealing position. The edge-sealing width is 2mm, and the edge-sealing material is glass fusion sealing solder, its elastic modulus is 75GPa, and its height is 0.2mm. The auxiliary side material is YH75 aluminum alloy, and its elastic modulus is 75GPa. The distance between the auxiliary edge and the sealing edge is 1mm, the height is the same as the height of the edge sealing material, its width is 2mm, and its length is the length of the distance between the inner edges of the two sealing edges 7mm.
设置辅助边后,封边处的最大位移减小25%,封边处的最大拉应力减小25%。After setting the auxiliary edge, the maximum displacement at the sealing edge is reduced by 25%, and the maximum tensile stress at the sealing edge is reduced by 25%.
实施例3Example 3
本发明提供一种真空玻璃的差异性弹性模量支撑柱阵列,低弹性模量支撑柱的材料为QMn1.5(Cu-1.5Mn)锰青铜合金,其弹性模量为105GPa,高弹性模量支撑柱的材料为301不锈钢材料,其弹性模量为210GPa,支撑柱阵列间距为50mm。靠近封边的第一周圈支撑柱采用锰青铜合金,靠近封接边的第二周圈的支撑柱采用不锈钢材料,以此类推,向远离封接边方向,一个周圈玻璃支撑柱、一个周圈不锈钢支撑柱交替进行,直至支撑柱全部排布完毕。支撑柱材料的低弹性模量与高弹性模量之比为0.5,铝合金支撑柱和不锈钢支撑柱的高度相同,为0.2mm。The present invention provides a differential elastic modulus support column array for vacuum glass. The material of the low elastic modulus support column is QMn1.5 (Cu-1.5Mn) manganese bronze alloy, and its elastic modulus is 105 GPa and high elastic modulus. The material of the support column is 301 stainless steel, its elastic modulus is 210 GPa, and the array spacing of the support column is 50 mm. The support column of the first circumference near the sealing edge is made of manganese bronze alloy, the support column of the second circumference near the sealing edge is made of stainless steel, and so on, in the direction away from the sealing edge, one circumference glass support column, one The surrounding stainless steel support columns alternate until all the support columns are arranged. The ratio of the low elastic modulus to the high elastic modulus of the support column material is 0.5, and the height of the aluminum alloy support column and the stainless steel support column are the same, which is 0.2mm.
平板玻璃的最大位移发生在角部位置的四个支撑柱之间,最大位移可降低10.19%,平板玻璃的其他部分,每四个支撑柱之间的平板玻璃位移可减小27%。The maximum displacement of the plate glass occurs between the four support columns at the corners, and the maximum displacement can be reduced by 10.19%. For the other parts of the plate glass, the plate glass displacement between every four support columns can be reduced by 27%.
本发明提供一种真空玻璃,在靠近封边位置设置一道辅助边。封边宽度为10mm,封边材料为玻璃熔封,弹性模量为75GPa,高度为0.2mm,辅助边材料为YH75铝合金。辅助边距离封边的距离1mm,高度与封边材料的高度相同,其宽度为0.5mm,其长度为距离相对两个封边内边缘10mm间距的长度。The invention provides a vacuum glass with an auxiliary edge arranged near the edge sealing position. The edge sealing width is 10mm, the edge sealing material is glass fusion sealing, the elastic modulus is 75GPa, the height is 0.2mm, and the auxiliary edge material is YH75 aluminum alloy. The distance between the auxiliary edge and the sealing edge is 1mm, the height is the same as the height of the edge sealing material, its width is 0.5mm, and its length is the length of the distance between the inner edges of the two sealing edges 10mm.
设置辅助边后,封边处的最大位移减小18.2%,封边处的最大拉应力减小 15.4%。After setting the auxiliary edge, the maximum displacement at the sealing edge is reduced by 18.2%, and the maximum tensile stress at the sealing edge is reduced by 15.4%.
以上仅为本发明的优选实施例而已,并不用于限制本发明,对于本领域的技术人员来说,本发明可以有各种更改和变化。凡在本发明的精神和原则之内,所作的任何修改、等同替换、改进等,均应包含在本发明的保护范围之内。The above are only preferred embodiments of the present invention and are not used to limit the present invention. For those skilled in the art, the present invention can have various modifications and changes. Any modification, equivalent replacement, improvement, etc., made within the spirit and principle of the present invention should be included in the protection scope of the present invention.

Claims (8)

  1. 一种差异性弹性模量支撑柱阵列,应用在真空玻璃的两片平板玻璃之间,其特征在于:A differential elastic modulus support column array, applied between two sheets of flat glass of vacuum glass, characterized by:
    靠近真空玻璃封边的第一周圈支撑柱为低弹性模量支撑柱,靠近真空玻璃封边的第二周圈支撑柱为高弹性模量支撑柱;The first circumferential support column near the vacuum glass edge sealing is a low elastic modulus support column, and the second circumferential support column near the vacuum glass sealing edge is a high elastic modulus support column;
    以此类推,向远离真空玻璃封边的方向,一个周圈的低弹性模量支撑柱、一个周圈的高弹性模量支撑柱交替布设,直至支撑柱全部排布完毕。By analogy, in the direction away from the edge of the vacuum glass, a peripheral ring of low elastic modulus support columns and a peripheral ring of high elastic modulus support columns are alternately arranged until the support columns are all arranged.
  2. 如权利要求1所述的差异性弹性模量支撑柱阵列,其特征在于,所述低弹性模量支撑柱的弹性模量与高弹性模量支撑柱的弹性模量之比为(0.15~0.5):1。The differential elastic modulus support column array according to claim 1, wherein the ratio of the elastic modulus of the low elastic modulus support column to the elastic modulus of the high elastic modulus support column is (0.15~0.5 ):1.
  3. 如权利要求1所述的差异性弹性模量支撑柱阵列,其特征在于,所述低弹性模量支撑柱和高弹性模量支撑柱的高度一致,相邻两周圈支撑柱的间距一致。The differential elastic modulus support column array according to claim 1, wherein the height of the low elastic modulus support column and the high elastic modulus support column are the same, and the distance between the support columns of two adjacent circles is the same.
  4. 一种真空玻璃,其特征在于,包括:两片平板玻璃和如权利要求1-3中任一项所述的差异性弹性模量支撑柱阵列;A vacuum glass, characterized by comprising: two sheets of flat glass and the differential elastic modulus support column array according to any one of claims 1-3;
    所述差异性弹性模量支撑柱阵列置于两片平板玻璃之间,两片平板玻璃的四个周边用封边材料密封,形成封边。The differential elastic modulus support column array is placed between two sheets of flat glass, and the four peripheries of the two sheets of flat glass are sealed with an edge sealing material to form an edge seal.
  5. 如权利要求4所述的真空玻璃,其特征在于,还包括辅助边;The vacuum glass according to claim 4, further comprising an auxiliary edge;
    在靠近封边的位置处设置一道所述辅助边,所述辅助边位于所述封边的内侧。An auxiliary edge is arranged at a position close to the edge sealing, and the auxiliary edge is located inside the edge sealing.
  6. 如权利要求5所述的真空玻璃,其特征在于,所述辅助边的弹性模量为封边材料的弹性模量的1~1.3倍。8. The vacuum glass according to claim 5, wherein the elastic modulus of the auxiliary edge is 1 to 1.3 times the elastic modulus of the edge sealing material.
  7. 如权利要求5所述的真空玻璃,其特征在于,所述辅助边与封边平行设置,所述辅助边距平行封边的距离为1~2mm。The vacuum glass according to claim 5, wherein the auxiliary edge is arranged in parallel with the sealing edge, and the distance between the auxiliary edge and the parallel sealing edge is 1 to 2 mm.
  8. 如权利要求7所述的真空玻璃,其特征在于,所述辅助边的高度与封边的高度相同,所述辅助边的宽度为0.1~0.5mm,所述辅助边的两端距两个垂直封边内边缘的距离为3mm~15mm。The vacuum glass according to claim 7, wherein the height of the auxiliary edge is the same as the height of the sealing edge, the width of the auxiliary edge is 0.1-0.5mm, and the two ends of the auxiliary edge are two perpendicular The distance between the inner edge of the sealing edge is 3mm~15mm.
PCT/CN2020/086070 2019-05-06 2020-04-22 Support column array having varying elastic modulus, and vacuum glass WO2020224436A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN201910370271.9A CN110204222B (en) 2019-05-06 2019-05-06 Differential elasticity modulus support column array and vacuum glass
CN201910370271.9 2019-05-06

Publications (1)

Publication Number Publication Date
WO2020224436A1 true WO2020224436A1 (en) 2020-11-12

Family

ID=67786856

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/CN2020/086070 WO2020224436A1 (en) 2019-05-06 2020-04-22 Support column array having varying elastic modulus, and vacuum glass

Country Status (2)

Country Link
CN (1) CN110204222B (en)
WO (1) WO2020224436A1 (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110204222B (en) * 2019-05-06 2021-05-11 北京工业大学 Differential elasticity modulus support column array and vacuum glass
CN114856383B (en) * 2022-05-13 2023-12-22 南京申威光电技术研究院有限公司 Large-size vacuum glass and preparation method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH07173969A (en) * 1993-12-20 1995-07-11 Nikken Sekkei Ltd Plate-like fastening device
CN105645743A (en) * 2014-11-19 2016-06-08 戴长虹 Vacuum glass with two or a plurality of paths of sealing and a preparing method thereof
CN105669003A (en) * 2014-11-19 2016-06-15 戴长虹 Vacuum glass insulation panel and preparation method thereof
CN108873495A (en) * 2018-07-13 2018-11-23 深圳市华星光电技术有限公司 A kind of liquid crystal display substrate and preparation method thereof, liquid crystal display device
CN110204222A (en) * 2019-05-06 2019-09-06 北京工业大学 A kind of otherness elasticity modulus support column array and vacuum glass

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH07173969A (en) * 1993-12-20 1995-07-11 Nikken Sekkei Ltd Plate-like fastening device
CN105645743A (en) * 2014-11-19 2016-06-08 戴长虹 Vacuum glass with two or a plurality of paths of sealing and a preparing method thereof
CN105669003A (en) * 2014-11-19 2016-06-15 戴长虹 Vacuum glass insulation panel and preparation method thereof
CN108873495A (en) * 2018-07-13 2018-11-23 深圳市华星光电技术有限公司 A kind of liquid crystal display substrate and preparation method thereof, liquid crystal display device
CN110204222A (en) * 2019-05-06 2019-09-06 北京工业大学 A kind of otherness elasticity modulus support column array and vacuum glass

Also Published As

Publication number Publication date
CN110204222A (en) 2019-09-06
CN110204222B (en) 2021-05-11

Similar Documents

Publication Publication Date Title
US20240140075A1 (en) Dimmable window pane with reduced bow and insulated glazing unit comprising the same
JP5908885B2 (en) Vacuum insulated glass unit with a viscous end seal
WO2020224436A1 (en) Support column array having varying elastic modulus, and vacuum glass
EP1506945B1 (en) Translucent glass panel
US9732552B2 (en) Vacuum insulating glass unit with viscous edge seal
GB2469376A (en) Vacuum glazing spacer pillar
WO2008113249A1 (en) Suspended and pressure-balanced weight-bearing evacuated safety glass
AU2002363814A1 (en) Glass panel
CN201933017U (en) Low-emissivity toughened vacuum glass
CN2883364Y (en) Whole transparent vacuum glass
CN101725307B (en) Machining method for manufacturing high-efficiency energy-saving vacuum glass
CN102898007B (en) Tail-free sealing vacuum energy-saving and noise-reducing glass
CN101725306A (en) Vacuum glass with high efficiency and energy saving
CN103288337A (en) Support-free double bent vacuum glass and manufacturing method thereof
Arya et al. Fabrication analysis of flat vacuum enclosures for solar collectors sealed with Cerasolzer 217
JP2007024298A (en) Double glazing pane type vacuum heat insulating plate
CN104341094A (en) Energy-saving sheet material and manufacturing method thereof
CN204281555U (en) Energy-conserving plate material
CN202465495U (en) Upholder-free double-curved vacuum glass
WO2020162551A1 (en) Glass unit
CA2966027C (en) Energy-saving plate and method for manufacturing the same
CN110316978B (en) Photovoltaic vacuum glass with integrated structure and function and manufacturing method thereof
JP6295005B1 (en) Mass production type vacuum low-pressure double-layer glass and method for producing the same
JPH11199279A (en) Vacuum double layer glass
CN110316980B (en) Structure-function integrated toughened vacuum glass and manufacturing method thereof

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 20801147

Country of ref document: EP

Kind code of ref document: A1

NENP Non-entry into the national phase

Ref country code: DE

122 Ep: pct application non-entry in european phase

Ref document number: 20801147

Country of ref document: EP

Kind code of ref document: A1

122 Ep: pct application non-entry in european phase

Ref document number: 20801147

Country of ref document: EP

Kind code of ref document: A1