WO2020218834A1 - Complexe d'ions de silicium organisé avec de l'acide carboxylique, procédé de fabrication du complexe et produit l'utilisant - Google Patents

Complexe d'ions de silicium organisé avec de l'acide carboxylique, procédé de fabrication du complexe et produit l'utilisant Download PDF

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WO2020218834A1
WO2020218834A1 PCT/KR2020/005343 KR2020005343W WO2020218834A1 WO 2020218834 A1 WO2020218834 A1 WO 2020218834A1 KR 2020005343 W KR2020005343 W KR 2020005343W WO 2020218834 A1 WO2020218834 A1 WO 2020218834A1
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water
acid
carboxylic acid
silicon
silicate
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PCT/KR2020/005343
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Korean (ko)
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윤종오
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윤종오
유한회사 한국신기술
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Priority claimed from KR1020200025022A external-priority patent/KR102207608B1/ko
Application filed by 윤종오, 유한회사 한국신기술 filed Critical 윤종오
Priority to CA3131085A priority Critical patent/CA3131085C/fr
Priority to AU2020260932A priority patent/AU2020260932B2/en
Priority to CN202080006201.6A priority patent/CN113272255B/zh
Priority to JP2021519651A priority patent/JP2022529754A/ja
Priority to EP20795573.3A priority patent/EP3960714A4/fr
Priority to US17/416,071 priority patent/US20220073541A1/en
Publication of WO2020218834A1 publication Critical patent/WO2020218834A1/fr

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    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L33/00—Modifying nutritive qualities of foods; Dietetic products; Preparation or treatment thereof
    • A23L33/10—Modifying nutritive qualities of foods; Dietetic products; Preparation or treatment thereof using additives
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K33/00—Medicinal preparations containing inorganic active ingredients
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K47/00—Medicinal preparations characterised by the non-active ingredients used, e.g. carriers or inert additives; Targeting or modifying agents chemically bound to the active ingredient
    • A61K47/06—Organic compounds, e.g. natural or synthetic hydrocarbons, polyolefins, mineral oil, petrolatum or ozokerite
    • A61K47/08—Organic compounds, e.g. natural or synthetic hydrocarbons, polyolefins, mineral oil, petrolatum or ozokerite containing oxygen, e.g. ethers, acetals, ketones, quinones, aldehydes, peroxides
    • A61K47/12—Carboxylic acids; Salts or anhydrides thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
    • A61P3/00—Drugs for disorders of the metabolism
    • A61P3/02—Nutrients, e.g. vitamins, minerals
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/68—Treatment of water, waste water, or sewage by addition of specified substances, e.g. trace elements, for ameliorating potable water
    • C—CHEMISTRY; METALLURGY
    • C05—FERTILISERS; MANUFACTURE THEREOF
    • C05D—INORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
    • C05D9/00—Other inorganic fertilisers
    • C—CHEMISTRY; METALLURGY
    • C05—FERTILISERS; MANUFACTURE THEREOF
    • C05F—ORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
    • C05F11/00—Other organic fertilisers

Definitions

  • the present invention relates to a silicon ion complex organically formed with a carboxylic acid, a method for preparing the complex, and a product using the same.
  • the generic term for elements excluding oxygen (O), carbon (C), hydrogen (H), and nitrogen (N) is called mineral or mineral. In the past, it was also referred to as ash ( ⁇ ). About 96% of the elements contained in the human body are the first 4 elements, and only 4% of the total minerals.
  • the relatively large amounts are calcium (Ca), phosphorus (P), potassium (K), sulfur (S), sodium (Na), chlorine (Cl), magnesium (Mg), and iron (Fe ), copper (Cu), manganese (Mn), iodine (I), cobalt (Co), zinc (Zn), molybdenum (Mo), selenium (Se), chromium (Cr), fluorine (F), boron (B ), arsenic (As), tin (Sn), silicon (Si), vanadium (V), nickel (Ni), titanium (Ti), zirconium (Zr), and the like.
  • the present invention relates to silicon among minerals.
  • Silicon is one of the minerals necessary for the human body, and is known to play a certain role in forgetfulness, lack of patience, osteoporosis, aging phenomena, activation of metabolism, anti-aging of cells, and treatment, but not all functions have been fully identified.
  • minerals are easily expressed, minerals that exist in the state of ore are inorganic, and there are about 70 kinds of minerals on the earth.
  • inorganic minerals are absorbed by plants by agriculture and combined with amino acids, and minerals in this state are organic matter. Most of the minerals taken by humans are organic minerals that exist after being absorbed from food.
  • minerals such as selenium are not only not absorbed when ingested as inorganic minerals, but may accumulate and have side effects. Therefore, the inorganic selenium can be absorbed normally only by combining it with amino acids and changing it to an organic state. However, not all minerals do.
  • Silica is also used in the same way, so it is used in the form of making water-soluble silicon from ore and dissolving it in water and drinking it.
  • Such water-soluble silicon is made soluble in water in the form of Na 2 SiO 3, Na 2 SiO 3 ⁇ 5H 2 O, Na 2 SiO 3 ⁇ 9H 2 O, Na 2 SiO 3 ⁇ 10H 2 O, and in some cases phosphorus Compounds containing elements that can be used as minerals such as (P), magnesium (Mg), zinc (Zn) are added, and high-purity silicon dioxide and sodium carbonate are used as the main raw materials at a temperature of 1,500°C to 2,000°C. It is made in powder form.
  • silica as a digestive absorber that can be used by both plants, animals and humans is: (1) providing high-purity silicon oxide as a mineral, and (2) synthesizing the provided silicon oxide with sodium carbonate or sodium hydroxide at high temperature. It has been achieved through a step of reacting to form a water-soluble silicon compound and (3) dissolving the prepared water-soluble silicon compound. However, while reacting with water, the ionic state cannot be maintained continuously, and it takes a colloidal or colloidal form.
  • This water-soluble silicon has a very high alkalinity and is stable in alkali. (If you look at the phenomenon more, it seems to be stable in alkali, but in reality, it begins to form a fine-sized gel, and finally, the particles aggregate with each other. Precipitated.)
  • water-soluble silicon or water-soluble silicon compounds containing water-soluble silicon as a main material are stable only in alkali and cannot be maintained as ions, and are not stable in acids and alcohols.
  • Minerals are mainly minerals contained in ores (especially mica). There are various elements, such as germanium, iron, manganese, etc. that we are well aware of to make semiconductors, and these elements are gradually dissolved in stones or rock masses as groundwater flows through the ground, and they are incorporated into the water and absorbed into the ground.
  • the collapse of the soil mineral cycle is serious due to chemical farming.
  • the soil's mineral cycle is maintained by organic fertilizers such as compost and livestock manure. In this way, agricultural products produced in the soil where the mineral cycle is blocked are bound to be deficient in minerals.
  • the minerals contained in medicines are high in minerals.
  • the purpose is to consume as much mineral as necessary, and it is not harmful to the human body.
  • Minerals absorbed by the human body are temporarily ionized and then recombined into necessary organic substances, acting as enzymes in necessary parts of the body, or being deposited in tissues. That is, it is desirable that at least the human body must be ionized in order to digest (absorb) minerals. Due to the nature of minerals, there are cases in which organic substances have good absorption during absorption.
  • an object of the present invention is to provide a silicon ion complex organically formed with a carboxylic acid using a water-soluble silicon compound.
  • Another object of the present invention is to provide a technology for producing a silicon ion complex organically formed with a carboxylic acid that can be used for animal, human and plant growth by organizing a water-soluble silicon compound.
  • Another object of the present invention is to provide a method of adding titanium, zirconium, and various minerals including the same in the production of a silicon ion complex organically formed with a carboxylic acid stable to change in hydrogen ion (pH).
  • Another object of the present invention is to provide a variety of products using an organic silicon ion complex produced by using the silicon ion complex manufacturing technology organically carboxylic acid.
  • the inventor of the present invention is a person who has been continuously developing a technology for stabilizing ions in an aqueous solution of titanium and zirconium, and has been conducting ionization studies of various materials other than this, and has been conducting various titanium and zirconium related studies since 2011.
  • a patent has been filed for using ions.
  • Patent Document 0015 Korean Patent Application No. 10-2017-0034531 describes a silicate beverage to which zirconium is added and a method of manufacturing the same in the claims and contents.
  • Korean Patent Application No. 10-2002-0071408 describes a liquid composition for promoting plant growth containing titanium dioxide fine particles.
  • Zirconium does not have a known role in living organisms, but it contains about 250mg on average in the human body, and is also contained in small amounts in various foods. In daily life, it is also used in some products or for purifying tap water. (Source: Wiki Encyclopedia)
  • titanium or silicon it is already used as a plant growth accelerator or liquid fertilizer for plants, and is recognized as a mineral in the human body.
  • titanium the role in the human body has not yet been confirmed, but it is at a level that it has been found to exist in trace amounts in the human body.
  • zirconium tends to show a stable appearance at a hydrogen ion concentration lower than pH 4.5 when a water-soluble zirconium compound is dissolved in water, and tends to precipitate in alkali.
  • pH 4.5 a water-soluble zirconium compound
  • At low pH there is a tendency to retain ions without any special additives, but when the pH starts to rise, it becomes rapidly unstable and all precipitates in alkali.
  • titanium reacts with water for a very short time (e.g., less than 1 second) when water-soluble titanium compounds such as titanium tetrachloride or titanium sulfate are added to water. .
  • This titanium reacts very quickly with water, whether it is alkali or acid.
  • it is a material that is more acidic than alkali.
  • the Korean Patent Application No. 10-2016-7021929 describes a stabilized polysilicate.
  • the properties of the stabilized silicate composition according to the present invention are very suitable for use as an antiperspirant, and the safety of this composition is as excellent as polysilicic acid acceptable to the skin, and unlike aluminum salts, there is no safety problem related to systemic toxicity. Are talking.
  • the pH of the initial composition (2.5 or 3.0 to 5.0) and the pH at which gel formation occurs, i.e., pH 6 are physiologically acceptable conditions, and furthermore, the gel-forming reaction is within a short time, typically between 5 and 30 minutes.
  • the gel produced by shifting the pH of the composition is a patent that is odorless and colorless and thus does not leave noticeable stains on the skin or clothing.
  • the invention provides a method for producing stabilized polysilicic acid comprising the steps of:;
  • Korean Patent Application No. 10-2016-7021929 is aimed at causing a gel-forming reaction in the vicinity of pH 2.5 to pH 3.0, pH 5.0, and pH 6.0, which is a physiologically acceptable condition, and has an average of 20 nm or It aims to control the galling of silicates in smaller forms.
  • the invention is a silicate in the form of nanoparticles or colloids of polysilicic acid, and the cluster radius is less than 10 ⁇ , preferably the colloidal dispersion is less than 100 nm, and between 1 nm and 100 nm, preferably Explains that they are polymeric silicic acid nanoparticles with an average diameter of 20 nm.
  • silicic acid has various particle sizes in the aqueous solution is due to the hygroscopicity of the water-soluble silicate in the process of dissolving silicate in water. This hygroscopicity is also the reason silica gel acts as a dehumidifying agent.
  • the silicate reacts with water and begins to gel, and once gelled, it cannot be re-ionized in the aqueous solution.
  • Patent Document 35 Korean Patent Application No. 10-2016-7024827 Looking at the materials and methods related to the stabilized polymer silicate composition in terms of use, it can be seen that the present invention is a similar invention.
  • the carboxylic acid used in the present invention is used.
  • it is also expected to act as a stabilizer for controlling the moisture absorption of the polymer silicate composition with ethanol.
  • the present invention aims to prepare a stabilized polymeric silicate composition comprising polymeric silicic acid and nanosilicate particles having an average diameter of 20 nm or less , wherein stabilization means that the average diameter and size of the particles are continuous. It seems to refer to a form that does not grow larger and is maintained. This is similar to Patent Document 34 in some respects.
  • the invention comprises the steps of (a) providing an aqueous solution of soluble silicate at a pH of 9.5 or higher;
  • a stabilizer containing polyalkylene glycol and or sugar is added to the silicate solution, whereby the stabilizer inhibits the formation of condensed silicate.
  • the present invention describes in that a stabilizer is used for the purpose of causing polymerization to form silicic acid and nano silicate particles and to stabilize the size of the formed particles, and carboxylic acid may be used among the stabilizers. There is.
  • Patent Document 35 The inventors of the above (Patent Document 35) claim that the polymer silicate composition stabilized in [0068] is intended for use as a pharmaceutical or nutritional composition.
  • silicon is a mineral, but those skilled in the art are well aware that the safest way to ingest minerals by humans or animals is to ingest them as ions.
  • inorganic minerals and organic (chelated) minerals are classified, and the fact that ingestion of inorganic minerals can be harmful to the human body, even if it is an ion, is found in data that anyone can easily access through various media. It corresponds. You can easily access inorganic minerals through internet search alone.
  • chelate is a chemical bond that refers to a shape that can hold objects tightly with claws.
  • Mineral is a type of mineral and is also called mineral or inorganic because it is extracted from ore.
  • the minerals that we add to animal feed are also extracted from ore and are called inorganic minerals.
  • minerals exist in a different form. These minerals are called chelate minerals as inorganic minerals are consumed by animals and plants to chelate with organic matter in the body.
  • silicon has a material property that makes it impossible to make inorganic minerals except for the use of non-drinking hydrofluoric acid (HF), so the method of using it as an ion has been completely blocked.
  • HF non-drinking hydrofluoric acid
  • the trace amount of SiO2 present in natural water may not have a major problem with human health, but the fact that silicate polymer particles, a high molecular substance, enter the human body and play a role as a nutrient composition, is the claim of the inventor, and has been studying minerals so far. It may be true that it is difficult for developers to stand up and understand.
  • Amino acids and chelated minerals show a 3 to 4 times higher absorption and utilization rate than various types of minerals that exist in nature.
  • the reason why the absorption and utilization rate of chelated minerals is high is because the mechanism of digestion and absorption is different.
  • inorganic minerals when inorganic minerals are separated into ionic form in the stomach, they exhibit divalent cations. As they become fluorinated substances by combining with phosphoric acid, oxalic acid, phytic acid, and fibrin, which have anions present in the intestine, the absorption and utilization rate is significantly lowered. It becomes.
  • Patent Document 35 is a patent for silicon, and the silicate polymer, which is a high molecular substance, is not separated in an ionic form in the stomach, which is the digestive system, regardless of animal or human body. Therefore, it seems that the inventors developed or insisted that silicon, which is a tetravalent ion, is not separated into ions in the gastric acid solution when it becomes a polymer silicate composition to be used as a nutritional composition.
  • inorganic minerals are separated into ions in the stomach, they are used medically if necessary, or added to animal feed, but using a high molecular substance for such a purpose, even if it is a very small amount, has any effect on the human body or animals. It is not known whether it is crazy, and it is not suitable as a method of ingesting minerals.
  • the inventors of the present invention dissolve titanium tetrachloride and titanium sulfate, which are water-soluble titanium compounds, in a solution in which tricarboxylic acid or dicarboxylic acid is first dissolved in the process of organizing titanium and zirconium to exist as ions.
  • zirconium oxychloride and zirconium sulfate, which are water-soluble zirconium compounds were also dissolved in the same way to maintain the organic zirconium ion state.
  • Experimental Example 1 and Experimental Example 2 were conducted to investigate the ion behavior in aqueous silicate solution through an ion stabilization experiment of tungsten, which is stable in alkali, similar to that of water-soluble silicate.
  • water-soluble silicate appears to be stable in alkali, but in reality, it is not stable in alkali, but it seems that the reaction with water is only slow, and in terms of metal, similar ions as stable in alkali similar to tungsten. It only shows behavior. In reality, it is not an ion, but exists in a colloidal or colloidal form, but it is transparent enough to be indistinguishable with the naked eye, so it looks just like an ion. These can be easily confirmed whether they are ions through a high-purity ethanol reaction test. When added to high-purity ethanol, the colloidal or colloidal silicate aqueous solution shows all its particles in a transparent state.
  • silicate when it encounters water like titanium, it immediately starts to react with water, exhibits endothermic and hygroscopic properties, absorbs water molecules, expands its volume and mass, and once expanded, it is in the solution again. It is not possible to return to the original ionic state by a method such as pH change.
  • zirconium and titanium have similar properties in that the material precipitated in the solution cannot return to its original ionic state. Once the ionic state is broken in water and once precipitated, it cannot be recovered to the ionic state again by pH adjustment in the solution unless a highly toxic substance such as fluorine is used. Tungsten in the previous experimental example was able to dissolve the precipitate in ammonia to make it ionic again, but titanium and zirconium are impossible.
  • water-soluble silicate seems to show a stable appearance in alkali, similar to a metal that is stable to alkali like tungsten, but in reality, the rate of hygroscopicity with moisture is only slightly slowed, and the ionic state is once again like titanium and zirconium. After cracking, it exists in the form of colloidal or colloidal in an aqueous solution, continuously causing a polymerization reaction at a slow rate, and there is a characteristic that it cannot return to an ionic state again.
  • the method that the inventors of the present technology have been able to maintain in an ionic state in an aqueous solution of titanium or zirconium is to prepare an aqueous solution in which dicarboxylic acid or tricarboxylic acid is first dissolved, and then dissolve a water-soluble titanium compound or a water-soluble zirconium compound in the aqueous solution.
  • Water-soluble silicate also, like titanium or zirconium, an aqueous carboxylic acid solution is first prepared using dicarboxylic acid or tricarboxylic acid, and a water-soluble titanium compound or a water-soluble zirconium compound is dissolved in an aqueous carboxylic acid solution.
  • the water-soluble silicate can be organicized to exist as ions by dissolving the water-soluble silicate in an aqueous carboxylic acid solution and combining it with the carboxylic acid in the process of dissolving in an ionic state in the aqueous solution. Knowing that, I came to the present invention.
  • the process of dissolving such carboxylic acid prior to water-soluble silicate is the core of the technology to maintain the ionic state by binding with the carboxylic acid before it becomes a colloidal or colloidal form larger than the ionic state.
  • the solution was adjusted several times with ammonia and sulfuric acid from pH ⁇ 1.0 to pH ⁇ 11.0, but maintained a stable state.
  • a combination of a tricarboxylic acid and a tricarboxylic acid, or a combination of a tricarboxylic acid further including a dicarboxylic acid may further stabilize the material ions in the aqueous solution. That is, for stabilizing ions, tricarboxylic acid is more preferable than dicarboxylic acid.
  • water-soluble silicon compounds, water-soluble titanium compounds, and water-soluble zirconium compounds are organically formed through combination with organic acids through the combination of dicarboxylic acids and tricarboxylic acids such as glycine, citric acid, malic acid, tartaric acid, and succinic acid, and can be stabilized as ions. And, if a single organic acid is used, it is more preferable to use a tricarboxylic acid rather than a dicarboxylic acid.
  • silicon ions become organic and can exist as ions in an aqueous solution.
  • the present invention found that the order of organicization as much as titanium and zirconium is very important in the organic materialization of silicon as well as the order of organicization of titanium and zirconium to maintain the ionic state, and came to the present invention. .
  • water-soluble silicates are already decomposed during digestion in a non-ionic state, making it impossible to exist as ions, and most of them precipitate. Because of this phenomenon, the water-soluble silicate completely dissolved in an alkaline state becomes gelled when the pH is lowered and changes to a silica gel state. Therefore, no matter how completely water-soluble silicate is completely dissolved in alkali, it is impossible to have confidence that it can be maintained in an ionic state in the digestive system from the stomach of an animal or human body.
  • water-soluble silicates react with carboxylic acid immediately (in a short period of time in the presence of ions) in the process of dissolving in water, they may no longer have hygroscopic properties. This means that the water-soluble silicate reacts with water and is dispersed in a colloidal form or does not exist in a colloidal form, but forms a complex with a carboxylic acid and exists in the smallest ionic state.
  • silicon is soluble in hydrofluoric acid, but hydrofluoric acid is a highly toxic substance, which is difficult and dangerous to use industrially. This is also true of titanium and zirconium.
  • titanium can be dissolved in a very small amount in boiling sulfuric acid in addition to hydrofluoric acid, but the inventors of this technology could not find scientific evidence that silicon is soluble in boiling sulfuric acid even at the time of the present invention.
  • silicon becomes soluble in water when it becomes sodium silicate, a synthetic material of sodium-silicon through synthesis with sodium carbonate or sodium hydroxide. (However, although the same tetravalent metal, titanium and zirconium do not dissolve in water even when synthesized with sodium. That is, even with the same tetravalent metal, the properties of each material are different.)
  • silicon This characteristic of silicon is that "sodium” such as sodium carbonate or sodium hydroxide is added and synthesized to make sodium silicate to dissolve silicon in water in the process of obtaining silicon ions as safe ions that can be touched and eaten by humans.
  • sodium silicate thus produced in water
  • at least one selected from tricarboxylic acid and dicarboxylic acid must be first dissolved in water in order to exist as ions, so "sodium", “silicon”, “ Carboxylic acid” and “water” must be included as essential components in order to exist as ions.
  • the term unavoidably chosen is "silicon ion complex" .
  • it is because of the nature of substances that do not exist as ions in water without organic matter, such as sodium chloride.
  • an aqueous carboxylic acid solution is prepared by combining an organic acid selected from dicarboxylic acid and tricarboxylic acid.
  • an organic acid selected from dicarboxylic acid and tricarboxylic acid By dissolving a water-soluble silicate in the prepared aqueous carboxylic acid solution, silicon is an organic acid even when silicon comes into contact with water or at low pH. It exists in the form of organic matter ions combined with.
  • silicon is easy to recognize as a substance that people cannot eat, but the actual surface of the crust was an environment in which a large amount of silicon existed, and humans have been ingesting silicon through plants.
  • Collagen, elastin, mucopolysaccharides, hyaluronic aci, etc. are bound to carbon deficiency, and are involved in crosslinking.
  • prolyhydroxylase an enzyme that functions in the formation of other connective tissues including bone and cartilage.
  • silicon does not exist as an element in nature. It exists as an oxide (silica), and humans were able to ingest silicon, an element that exists in combination with amino acids through the fiber of plants, especially fiber-rich plants.
  • alfalfa is rich in calcium, magnesium, potassium, and silicon, so digestive ulcers, gastritis, liver disease, eczema, hemorrhoids, asthma, high blood pressure, anemia, constipation, bleeding gums, inflammation, It is also used for burns, cancer, and swelling.
  • Silicon supplementation is said to increase the thickness of the dermis and connective tissue support structures just below the skin surface.
  • silicon is organicized and provided as an ionized complex.
  • large-scale compounds are chemically meaningful, and representative ones can be called amino acids and fatty acids.
  • Desired results can be obtained through various types of reactions with various carboxy compounds according to need, such as for promoting plant growth, including fertilizers used in agriculture, for animals, for human medicine, for food, and for cosmetics.
  • carboxylic acids When divided into carboxylic acids in this way, those having one carboxyl group are referred to as monocarboxylic acids, those having two are referred to as dicarboxylic acids, and those having three are referred to as tricarboxylic acids.
  • Chain-shaped monocarboxylic acid is widely distributed as a component of fats or fats and oils, so it is especially called fatty acid, and fatty acids can play a role as additives, but it is difficult to stabilize water-soluble silicate, titanium, and zirconium ions in an aqueous solution. .
  • At least one carboxylic acid selected from tricarboxylic acid and dicarboxylic acid is used as the carboxyl group compound capable of stabilizing the water-soluble silicate compound in an aqueous solution. More preferably, it is a tricarboxylic acid.
  • a water-soluble silicate compound or a water-soluble titanium compound is prepared by stabilizing a water-soluble silicate compound by using one or more tricarboxylic acids, and dissolving one or more dicarboxylic acids or tricarboxylic acids as necessary. And dissolving the water-soluble zirconium compound.
  • the dicarboxylic acid or tricarboxylic acid is characterized in that it further comprises an amino acid.
  • a water-soluble silicate compound is dissolved in an aqueous carboxylic acid solution prepared by dissolving at least one dicarboxylic acid or tricarboxylic acid first and foremost, thereby preparing an organicized silicon ion complex. (At low temperature, the reaction rate of water-soluble silicate with water is reduced as much as possible to form a complex with carboxylic acid)
  • a titanium ion aqueous solution characterized in that to prepare an organic water-soluble titanium ion aqueous solution prepared by dissolving a water-soluble titanium compound in an aqueous carboxylic acid solution prepared by dissolving at least one dicarboxylic acid or tricarboxylic acid;
  • An aqueous solution of zirconium ions characterized by dissolving a water-soluble zirconium compound in an aqueous carboxylic acid solution made by dissolving one or more dicarboxylic acids or tricarboxylic acids, to prepare an organic water-soluble zirconium ion aqueous solution, as needed It is characterized in that it is prepared by adding to ions.
  • step (4) it further comprises the step of adding the organicated titanium ion solution and the organic zirconium ion solution in step (4).
  • steps (1) to (3) ions used as minerals are further added as needed.
  • the ions added at this time are magnesium (Mg), potassium (K), iron (Fe), manganese (Mn), sodium (Na), zinc (Zn), sulfur (S), calcium (Ca), and phosphorus (P). .
  • water-soluble silicates can be ionized to form a silicon ion complex in a drinkable state, and can be used in various industrial fields.
  • it can be used as a source of minerals to plants, animals, and humans lacking minerals, and can be used in medicine and pharmaceutical fields, and solves the problem that it was difficult to expect absorption through the digestive tract in the form of colloidal or colloidal in the past. It was confirmed that it can be prepared in a state capable of digestion and absorption by making it in one ionic form.
  • Fig. 2 Crystal structure diagram according to evaporation of a saturated solution of an organic silicon ion complex prepared with tartaric acid
  • Fig. 3 Crystal structure of an organic silicon ion complex prepared with tartaric acid in a saturated solution.
  • Fig. 4 Plating surface of an accessory product plated by adding an organic silicon ion complex prepared with tartaric acid of Example 3 to a gold plating solution.
  • FIG. 5 A product in which a substitution reaction was tested on the surface of a stainless steel with the organic silicon ion complex prepared with tartaric acid of Example 3 (left substitution reaction not performed product, right substitution reaction surface performed)
  • Citric acid malic acid, tartaric acid, which are organic acids having a tricarboxylic or dicarboxylic group
  • the ionization experiment was conducted through the organicization of the water-soluble silicate.
  • the water-soluble silicate used to describe the present invention is Na 2 SiO 3 ⁇ 9H 2 O, but is not limited thereto, and Na 2 SiO 3 , Na 2 SiO 3 ⁇ 5H 2 O, Na 2 SiO 3 ⁇ 10H 2 O and water-soluble silicate complex materials containing minerals during the manufacturing process of water-soluble silicates are also acceptable. Hydrates containing water molecules in the molecule have some potential to form insoluble precipitates, but when dissolved at a low temperature, it is not unreasonable to make them exist as ions without special problems.
  • a water-soluble silicate composite material including various mineral components including various mineral components is made, and the most commonly used mineral components are magnesium (Mg), potassium (K), iron (Fe), manganese (Mn), and sodium. (Na), zinc (Zn), sulfur (S), calcium (Ca), phosphorus (P).
  • These mineral components are made by adding substances such as sodium carbonate, potassium carbonate, sodium triphosphate, sodium pyrophosphate, sea salt, magnesium carbonate, calcium carbonate, magnesium oxide, calcium oxide, iron oxide, and manganese oxide.
  • the precipitated material cannot be ionized again in the same solution.
  • Example 1 An experiment for preparing a metasilicate organic ion complex using citric acid.
  • the prepared organic silicon ion complex was stable as a transparent solution, and 20 g was sufficiently dissolved in 500 ml to maintain the ionic state. (Converted to the amount of pure silicon ions, it is equivalent to about 3.954 g/L.)
  • a filtering step is required. This filtration is to filter impurities and impurities in the material caused by pH impact that may occur at the time of dissolution. After precipitation, precipitation filtration using the supernatant or filter filtration can be used.
  • sterilization may be required in the manufacturing process.
  • disinfection may be sterilized by one or more of ultraviolet UV sterilization, high temperature sterilization, chlorine sterilization, dioxide gas sterilization, and ozone treatment.
  • the organic silicon ion complex made of citric acid may use carboxylic acid, sodium carbonate, sodium hydrogen carbonate, sodium hydroxide, and amino acids to adjust the pH to weakly acidic or weakly alkaline, and the pH adjustment range is 1 to 13.
  • Example 2 An experiment for preparing a metasilicate organic ion complex using malic acid.
  • the prepared organic silicon ion complex was stable as a transparent solution, and 20 g was sufficiently dissolved in 500 ml to maintain the ionic state. (Converted to the amount of pure silicon ions, it is equivalent to about 3.954 g/L.)
  • Example 3 An experiment for preparing a metasilicate organic ion complex using tartaric acid.
  • the purpose of this experiment is to make a saturated solution at the time of manufacture and to check the gelation phenomenon and crystal structure in the solution.
  • Example 5 An experiment for preparing a metasilicate organic ion complex using glycine.
  • magnesium, potassium, iron, manganese, sodium, zinc, sulfur, calcium, phosphorus, titanium, and zirconium cations may be further added.
  • titanium and zirconium in the form of organicized ions that are stable to pH changes in an aqueous solution, as described above.
  • the remaining mineral components are substances that can be easily ionized in aqueous solutions, such as calcium oxide (CaO), calcium hydroxide (Ca(OH)2), calcium ascorbic acid calcium salt, Ca(C6H7O6)2), calcium carbonate (CaCO3), Calcium chloride (CaCl2), acetic acid calcium magnesium salt, calcium acetate (C4H6CaO4), magnesium acetate (C4H6MgO4), magnesium carbonate-magnesium hydroxide-5 hydrate [(MgCO3)4 ⁇ Mg(OH)2 ⁇ 5H2O] ,Magnesium chloride (MgCl2), magnesium citrate, magnesium hydroxide (Mg(OH)2), magnesium oxide (MgO), potassium acetate (CH3COOK), potassium chloride (KCl), potassium citrate (Potassium citrate), potassium hydroxide (KOH), potassium carbonate (K2CO3), potassium hydrogen carbonate (KHCO3), sodium hydroxide (NaOH), sodium carbonate (
  • These cations are also preferably dissolved in a dicarboxylic acid or tricarboxylic acid aqueous solution and added, more preferably, dissolved in a tricarboxylic acid aqueous solution and added.
  • the silicon ion complex organically prepared with the carboxylic acid thus prepared can be used for various purposes.
  • drinking water suitable for drinking water quality standards amino acid drinks, mineral drinks, amino acid and mineral complex drinks, pharmaceutical compositions for oral administration to supply silicon minerals to animals and humans, pharmaceutical compositions for injection, bakery, confectionery, plant growth promotion It can be used for various purposes such as fertilizers, detergents, cosmetics, and medical ointments.
  • a detergent it can be prepared by adding a certain portion of the silicon ion complex organicated with the carboxylic acid of the present invention to shampoo, conditioner, face wash, soap, dish detergent, laundry soap, toothpaste, etc., and can be used as a detergent for animals and humans. .
  • This experiment was to confirm whether silicon is behaving ionic by texture and color, although silicon cannot be measured with a plating thickness measuring device. The results can be confirmed in FIG. 4 .
  • the gold-plated surface has a slight blue sensation, expressing the texture as if it was coated with a glass film, and the yellow color of gold was slightly darker.
  • the silicon ion composite according to the present invention may be added in the process of reducing and depositing metal in the electrochemical field of plating to additionally obtain the texture of glass, and thus it is likely to be used for various purposes.
  • the substitution experiment was conducted by adding 1 liter of water to the solution prepared in Example 3 and immersing various metals in 250 ml of a solution made of 2 liters.As a result, it was possible to confirm a phenomenon in which stainless steel exhibits surface purification ability and texture such as glass film coating. .
  • FIG. 5 when the surface was viewed from various angles in the sunlight, light scattering phenomenon such as glass fragments could be seen, and a slight texture of glass could be felt as a bar was seen.
  • the surface was hydrophobic to water and was not wet.
  • the present invention not only plays a role as a mineral, but also a variety of industries including electrochemistry (plating), as it was able to be used electrochemically, even though the metals of titanium and zirconium were organically made into ions as metalloid ions. It has been confirmed that it can be used in the field.
  • the organic acid, amino acid, or carboxylic acid used in the present invention does not refer to only the organic acid, amino acid, or carboxylic acid, but includes a sodium compound, potassium compound, or ammonium compound containing such components.

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Abstract

La présente invention concerne une technique liée à l'ionisation de silicium, qui organise et ionise du silicium avec un silicate soluble dans l'eau en utilisant un acide tricarboxylique ou un acide dicarboxylique. Cette technologie permet la fabrication et la fourniture de produits contenant un complexe d'ions silicium organisé dans divers domaines, y compris des champs électrochimiques, ainsi que des produits alimentaires et pharmaceutiques comprenant de l'eau potable et des boissons. En particulier, il est attendu que diverses maladies dues à un manque de minéraux de silicium peuvent être traitées et prévenues en organisant et en fournissant du silicium n'existant pas sous forme d'ion dans la nature.
PCT/KR2020/005343 2019-04-24 2020-04-23 Complexe d'ions de silicium organisé avec de l'acide carboxylique, procédé de fabrication du complexe et produit l'utilisant WO2020218834A1 (fr)

Priority Applications (6)

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CA3131085A CA3131085C (fr) 2019-04-24 2020-04-23 Complexe d'ions de silicium organise avec de l'acide carboxylique, methode de preparation de complexe d'ions de silicium et produisant l'utilisant
AU2020260932A AU2020260932B2 (en) 2019-04-24 2020-04-23 Silicon ion complex organized with carboxylic acid, preparation method for silicon ion complex, and product using the same
CN202080006201.6A CN113272255B (zh) 2019-04-24 2020-04-23 以羧酸有机化的硅离子复合物及复合物的制备方法和利用其的产品
JP2021519651A JP2022529754A (ja) 2019-04-24 2020-04-23 カルボン酸で有機化されたケイ素イオン複合体、複合体の製造方法、及びそれを用いた製品
EP20795573.3A EP3960714A4 (fr) 2019-04-24 2020-04-23 Complexe d'ions de silicium organisé avec de l'acide carboxylique, procédé de fabrication du complexe et produit l'utilisant
US17/416,071 US20220073541A1 (en) 2019-04-24 2020-04-23 Silicon ion complex organized with carboxylic acid, method for manufacturing complex, and product using same

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KR10-2019-0047830 2019-04-24
KR20190047830 2019-04-24
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KR1020200025022A KR102207608B1 (ko) 2019-04-24 2020-02-28 카르복실산으로 유기화된 규소 이온 복합체 및 복합체의 제조방법과 이를 이용한 제품

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EP4039666A1 (fr) * 2021-02-05 2022-08-10 Maxstim Limited Compositions liquides biostimulantes des plantes à base de silicium

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US20110229577A1 (en) * 2008-08-01 2011-09-22 Franz Kerek Biologically active silicic acid
KR20160124797A (ko) * 2014-02-14 2016-10-28 메디칼 리서취 카운실 안정화된 중합체 실리케이트 조성물과 관련된 물질 및 방법
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KR20170034531A (ko) 2015-09-21 2017-03-29 이승욱 통신업자를 위한 가격 자동 추천 방법
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KR20020071408A (ko) 2001-03-06 2002-09-12 한국화학연구원 이속사졸기로 치환된 신규한 광변색성 디아릴에텐계 화합물
US20100006006A1 (en) * 2008-07-10 2010-01-14 Cognis Ip Management Gmbh Water-Soluble Silicates and Use Thereof
US20110229577A1 (en) * 2008-08-01 2011-09-22 Franz Kerek Biologically active silicic acid
US9980489B2 (en) * 2010-03-31 2018-05-29 Taminco Bvba Stabilized bio-available soluble silicate solution
KR20160124797A (ko) * 2014-02-14 2016-10-28 메디칼 리서취 카운실 안정화된 중합체 실리케이트 조성물과 관련된 물질 및 방법
KR20160124762A (ko) * 2014-02-14 2016-10-28 메디칼 리서취 카운실 안정화된 규산염 조성물 및 발한억제 조성물로서 이의 용도
KR20170034531A (ko) 2015-09-21 2017-03-29 이승욱 통신업자를 위한 가격 자동 추천 방법

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP4039666A1 (fr) * 2021-02-05 2022-08-10 Maxstim Limited Compositions liquides biostimulantes des plantes à base de silicium

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