WO2020204618A3 - Method for storing and releasing hydrogen by using palladium-supported catalyst - Google Patents

Method for storing and releasing hydrogen by using palladium-supported catalyst Download PDF

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Publication number
WO2020204618A3
WO2020204618A3 PCT/KR2020/004493 KR2020004493W WO2020204618A3 WO 2020204618 A3 WO2020204618 A3 WO 2020204618A3 KR 2020004493 W KR2020004493 W KR 2020004493W WO 2020204618 A3 WO2020204618 A3 WO 2020204618A3
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WO
WIPO (PCT)
Prior art keywords
palladium
storing
releasing hydrogen
supported catalyst
metal
Prior art date
Application number
PCT/KR2020/004493
Other languages
French (fr)
Korean (ko)
Other versions
WO2020204618A2 (en
Inventor
서영웅
오진호
바툴라하리바부
Original Assignee
한양대학교 산학협력단
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Publication date
Application filed by 한양대학교 산학협력단 filed Critical 한양대학교 산학협력단
Publication of WO2020204618A2 publication Critical patent/WO2020204618A2/en
Publication of WO2020204618A3 publication Critical patent/WO2020204618A3/en

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    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/0005—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes
    • C01B3/001—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes characterised by the uptaking medium; Treatment thereof
    • C01B3/0015—Organic compounds; Solutions thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/44—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/633—Pore volume less than 0.5 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/635—0.5-1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/647—2-50 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16—Reducing
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/32—Hydrogen storage

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Catalysts (AREA)
  • Nanotechnology (AREA)

Abstract

The present disclosure discloses a technology capable of reversibly storing and releasing hydrogen with a high selective conversion rate and high efficiency by using a catalyst in which a palladium (Pd) metal having a specific surface as an active metal is dispersed and supported on a mesoporous alumina support.
PCT/KR2020/004493 2019-04-04 2020-04-02 Method for storing and releasing hydrogen by using palladium-supported catalyst WO2020204618A2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR10-2019-0039346 2019-04-04
KR1020190039346A KR102249231B1 (en) 2019-04-04 2019-04-04 Method for Storing and Releasing Hydrogen Using Palladium Supported Catalysts

Publications (2)

Publication Number Publication Date
WO2020204618A2 WO2020204618A2 (en) 2020-10-08
WO2020204618A3 true WO2020204618A3 (en) 2020-11-19

Family

ID=72666230

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/KR2020/004493 WO2020204618A2 (en) 2019-04-04 2020-04-02 Method for storing and releasing hydrogen by using palladium-supported catalyst

Country Status (2)

Country Link
KR (1) KR102249231B1 (en)
WO (1) WO2020204618A2 (en)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR102526670B1 (en) * 2020-11-20 2023-04-27 전남대학교산학협력단 Environment- Friendly Electric Boat Equipped with H2 Evolution Module
KR20220134179A (en) 2021-03-26 2022-10-05 한국과학기술원 Liquid organic hydrogen carrier(LOHC) hydrogenation reaction system and its operation method
KR102557863B1 (en) 2021-03-26 2023-07-24 한국과학기술원 Catalyst structure for Liquid Organic Hydrogen Carrier(LOHC) dehydrogenation reactor
CN113559851A (en) * 2021-07-23 2021-10-29 中国地质大学（武汉） Preparation method and application of palladium catalyst for dehydrogenation
CN113680362A (en) * 2021-08-18 2021-11-23 北京工业大学 Preparation method of palladium hydroxide carbon catalyst for removing N-benzyl
EP4410422A1 (en) * 2021-09-29 2024-08-07 IUCF-HYU (Industry-University Cooperation Foundation Hanyang University) Platinum-supported catalyst with improved hydrogenation/dehydrogenation reversibility and hydrogen storage and release method based on liquid organic hydrogen carrier using same
CN113866044B (en) * 2021-11-23 2024-04-19 云南电网有限责任公司电力科学研究院 Method for testing liquid organic hydrogen storage material
CN114917929B (en) * 2022-04-29 2023-03-21 北京海望氢能科技有限公司 Catalyst for hydrogenation and dehydrogenation of organic liquid hydrogen storage material and preparation method and application thereof
KR20240020980A (en) 2022-08-09 2024-02-16 한국생산기술연구원 Preparation of Catalyst Slurry for Mesoporous Alumina-based Ruthenium Catalyst for Hydrogen Production of Ammonia Decomposition and Metal Monolith Coating Catalyst Prepared by One-pot Coating Method using the same
CN116060137B (en) * 2022-11-23 2023-10-27 中国农业大学 Nano metal catalyst for hydrogenation and dehydrogenation of liquid organic hydrogen storage material, and preparation method and application thereof
KR20240088033A (en) 2022-12-13 2024-06-20 울산과학기술원 Palladium-based catalyst for dehydrogenation reaction, manufacturing method thereof, and hydrogen production method using the same

Citations (3)

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JP2009527365A (en) * 2006-02-16 2009-07-30 ブリガム・ヤング・ユニバーシティ Production of uniform nanoparticles of ultra-high purity metal oxides, mixed metal oxides, metals, and alloys
KR20110078818A (en) * 2009-12-31 2011-07-07 주식회사 효성 Dehydrogenation aerogel catalyst
KR101950701B1 (en) * 2017-08-25 2019-02-21 한양대학교 산학협력단 Method for Storing and Releasing Hydrogen Using Catalysts Based upon Carbon-coated Support

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* Cited by examiner, † Cited by third party
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KR101761500B1 (en) * 2010-02-05 2017-07-25 엑손모빌 케미칼 패턴츠 인코포레이티드 Dehydrogenation process

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009527365A (en) * 2006-02-16 2009-07-30 ブリガム・ヤング・ユニバーシティ Production of uniform nanoparticles of ultra-high purity metal oxides, mixed metal oxides, metals, and alloys
KR20110078818A (en) * 2009-12-31 2011-07-07 주식회사 효성 Dehydrogenation aerogel catalyst
KR101950701B1 (en) * 2017-08-25 2019-02-21 한양대학교 산학협력단 Method for Storing and Releasing Hydrogen Using Catalysts Based upon Carbon-coated Support

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
MAREK SOBOTA, IOANNIS NIKIFORIDIS, MAX AMENDE, BEATRIZ SANMARTÍN ZANÓN, THORSTEN STAUDT, OLIVER HÖFERT, YAROSLAVA LYKHACH, CHRISTI: "Dehydrogenation of Dodecahydro-N-ethylcarbazole on Pd/Al2O3 Model Catalysts", CHEMISTRY – A EUROPEAN JOURNAL, WILEY - V C H VERLAG GMBH & CO. KGAA, DE, vol. 17, no. 41, 4 October 2011 (2011-10-04), DE, pages 11542 - 11552, XP055753390, ISSN: 0947-6539, DOI: 10.1002/chem.201101311 *
ROBERT H. CRABTREE: "Nitrogen-Containing Liquid Organic Hydrogen Carriers: Progress and Prospects", ACS SUSTAINABLE CHEMISTRY & ENGINEERING, AMERICAN CHEMICAL SOCIETY, US, vol. 5, no. 6, 5 June 2017 (2017-06-05), US, pages 4491 - 4498, XP055753391, ISSN: 2168-0485, DOI: 10.1021/acssuschemeng.7b00983 *

Also Published As

Publication number Publication date
WO2020204618A2 (en) 2020-10-08
KR20200117354A (en) 2020-10-14
KR102249231B1 (en) 2021-05-06

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