WO2020177400A1 - Full-day imaging detector with multi-functional window, and method for preparing same - Google Patents

Full-day imaging detector with multi-functional window, and method for preparing same Download PDF

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WO2020177400A1
WO2020177400A1 PCT/CN2019/120445 CN2019120445W WO2020177400A1 WO 2020177400 A1 WO2020177400 A1 WO 2020177400A1 CN 2019120445 W CN2019120445 W CN 2019120445W WO 2020177400 A1 WO2020177400 A1 WO 2020177400A1
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filter
sub
array
window
infrared
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PCT/CN2019/120445
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French (fr)
Chinese (zh)
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刘卫国
王卓曼
刘欢
白民宇
韩军
王曦
梁海锋
安妍
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西安工业大学
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L27/00Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate
    • H01L27/14Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation
    • H01L27/144Devices controlled by radiation
    • H01L27/146Imager structures
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/08Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof in which radiation controls flow of current through the device, e.g. photoresistors
    • H01L31/09Devices sensitive to infrared, visible or ultraviolet radiation

Definitions

  • the invention belongs to the technical field of photoelectric detection, and specifically relates to an all-time imaging detector with a multifunctional window and a preparation method thereof.
  • the photodetector detects the change in the conductivity of the irradiated material caused by radiation.
  • Photoelectric detectors have a wide range of uses. In the visible or near-infrared band, they are mainly used for imaging and detection, industrial automatic control, photometric measurement, etc.; in the infrared band, they are mainly used for infrared thermal imaging and infrared remote sensing.
  • Traditional photodetectors are composed of discrete windows, microlens arrays, filter arrays and pixel unit arrays, which need to be assembled separately to form the detectors.
  • the window is designed for the detector to penetrate light waves and isolate the air for vacuum packaging.
  • the microlens array below the window can penetrate the detected light waveband.
  • Below the microlens array is an array of different filters.
  • Below the filter array is an array of pixel units on the substrate.
  • the pixel unit array detects incident light waves. Each pixel unit is composed of a combination of multiple sub-pixel units and regions.
  • the pixel unit of the existing visible light detector consists of three sub-pixel units that can detect red light (R), green light (G), and blue light (B), which are called red light (R) sub-pixel units, and green light (G) Sub-pixel unit, blue light (B) Sub-pixel unit, the filter above each sub-pixel unit filters the incident light waves, and selectively transmits red light, green light, and blue light, respectively, called red light filter Sheet (R), green filter (G), blue filter (B).
  • the three kinds of filters are arranged correspondingly above the three kinds of sub-pixel units, and are aligned up and down.
  • a micro lens array is also arranged above the filter to converge the incident light.
  • the array of three kinds of filters is located directly above the pixel unit array, the red filter (R) is facing the red (R) sub-pixel unit, and the green filter (G) is facing the green (G) sub-pixel unit.
  • Pixel unit, the blue light filter (B) is facing the blue light (B) sub-pixel unit.
  • each micro lens faces the sub-pixel unit directly below.
  • Common photodetector devices are visible light imaging or single-wavelength infrared devices. Windows, microlens arrays and filters can only pass through a single wavelength, and their band coverage is narrow, which cannot be used both day and night.
  • the window, microlens array and filter are discrete devices with low integration.
  • the existing visible light-infrared imaging detector In order to solve the problem of photoelectric detection in the whole day, the existing visible light-infrared imaging detector, the visible light imaging system working during the day and the infrared imaging system working at night are generally separated, and the visible light and infrared are detected independently in two light paths
  • the window can only work in a single visible or infrared band, and then the visible light image and the infrared image are synthesized by a computer using image registration and fusion methods. This method will cause the imaging system to be large in size, heavy in weight, and high in power consumption, which limits the scope of application. Therefore, it fails to meet the demand for a small, light, and low power single chip, all-day imaging detector.
  • the detector window used for all-day imaging devices must meet the requirements of daytime visible light color imaging and night infrared imaging.
  • the window, microlens array, and filter array are integrated to reduce their occupied space, shorten installation steps, and simplify installation Craft.
  • the patent CN201510609809 filed by STMicroelectronics in 2015 proposed a method of using IR sub-pixel unit detection signals to separately correct R, G, and B sub-pixel unit detection signals.
  • R The light of the B filter contains part of the stray light IR.
  • the detection signal of the R, G, B sub-pixel unit is as pure as possible, but the window, microlens array and filter are Discrete devices are not integrated; since the spectral range of the light-transmitting filter is only 1.1 ⁇ m in the infrared band, it cannot cover near infrared, shortwave infrared, midwave infrared and longwave infrared. Therefore, the detector using the filter of the invention can only work in the daytime, and cannot achieve full-time detection.
  • the purpose of the present invention is to provide a full-time imaging detector with multifunctional windows and a preparation method thereof, which integrates the window, microlens array, and filter array to solve the problem that the detector in the prior art can only work during the day. The problem of detection all day long cannot be realized.
  • An all-day imaging detector with a multifunctional window including a multifunctional window and a detection part.
  • the multifunctional window includes a microlens array, a window body and a filter array; the microlens array is integrated on the upper surface of the window body, each The top surface of each microlens unit is a spherical cap structure, the top view projection of the spherical cap is square, and the squares of the top view projection of the adjacent microlens unit spherical caps are connected; the filter array is plated on the lower surface of the window body;
  • the filter array includes four types of filters, which are three kinds of band-pass filters for monochromatic visible light combined with infrared bands and one type of infrared filter;
  • the detection part is composed of an array of pixel units, each pixel unit It includes four sub-pixel units, and the four sub-pixel units are directly opposite to the four filters.
  • the four types of filters are R+IR filters, G+IR filters, B+IR filters, and IR filters, respectively, and the four sub-pixel units are R+IR, respectively.
  • each sub-pixel unit is composed of a wide-spectrum sensitive layer, electrodes, and integrated circuits.
  • the preparation method of the above-mentioned microlens array is as follows. First, the copper is prepared into a copper template with a concave curved surface by a single-point diamond turning method, and then a broad spectrum transmission material layer is chemically vapor deposited on the copper template, and the copper template is removed after the temperature is reduced.
  • the obtained broad-spectrum transmission material layer includes two parts: a microlens array and a window body, and a filter array is plated on the back of the window body in regions to finally obtain a multifunctional window with broad-spectrum transmission performance.
  • the detection method of the above-mentioned detector is as follows.
  • the detection signal of the sub-pixel unit corresponding to the R+IR filter, G+IR filter, and B+IR filter is subtracted from the corresponding IR filter.
  • the sub-pixel unit detects the signal to obtain the true colors of R, G, B; when the detector works at night, the R+IR filter, G+IR filter, B+IR filter and IR filter can transmit infrared ,
  • the four sub-pixel units below them simultaneously detect infrared, and the detectors work normally at night.
  • the present invention has the following beneficial effects:
  • the present invention adopts a microlens array that can transmit light waves in the visible to infrared wavelengths, which has a converging effect on light.
  • the microlens array corresponds to the filter array and the sub-pixel array, and it will originally fall in the gap of the sub-pixel unit and the electrode.
  • the light from the non-light sensitive area converges to the light sensitive area in the middle of the sub-pixel unit, which improves the utilization of incident light waves;
  • the single-piece window of the present invention can realize wide-spectrum transmission and filtering, color separation, convergence and other functions from visible light to infrared.
  • the single-piece structure reduces the optical loss such as scattering and absorption compared with the multi-piece structure;
  • the device takes into account two working modes of daytime color and nighttime infrared, which can realize full-time imaging detection;
  • the front surface of the window of the present invention is processed with a microlens array, and the back surface is coated with a small volume, high integration, can shorten the assembly steps, simplify the installation process, and have good process compatibility;
  • the present invention adopts the way that the microlens array is upward and the filter is downward, which avoids the problem that the film is easy to fall off, and at the same time makes the filter and the detection unit closer.
  • Figure 1 is a schematic diagram of the color pixel layout of the pixel array in the patent of STMicroelectronics
  • Figure 2 is a diagram of the overall structure of an all-sky imaging detector with multifunctional windows
  • Figure 3 is a front view of the multifunctional window
  • Figure 4 is a top view of the multifunctional window
  • Figure 5 is a working principle diagram of an all-day imaging detector with multi-function windows
  • Fig. 6 is a schematic diagram of the working mode of the filter unit in the daytime
  • Figure 7 is a schematic diagram of the working mode of the filter unit at night
  • Figure 8 is a spectrum diagram of the B+IR filter area
  • Figure 9 is a spectral diagram of the G+IR filter area
  • Figure 10 is a spectrum diagram of the R+IR filter area
  • Figure 11 is a spectrum diagram of the IR filter region
  • Figure 12 is a flow chart of the preparation of the multifunctional window.
  • the upper surface of the detector window is a microlens array, which has a condensing effect on light, which can improve light utilization
  • the lower surface of the window is a filter for both visible light color imaging and infrared imaging, which can Both day and night
  • the pixel unit has two working modes, R+IR (red light + infrared light), G+IR (green light + infrared light) and B+IR (blue light + infrared light) three sub-pixel units during daytime work
  • the obtained detection signal can subtract the part of the detection signal obtained by the IR (infrared light) sub-pixel unit, so as to ensure that the detection signal of the R+IR, G+IR, B+IR sub-pixel unit presents true colors
  • the visible light signal is very weak when working at night , Four filters can transmit infrared, and the four sub-pixel units below it can detect infrared at the same time, which can work normally at night;
  • an all-sky imaging detector with a multifunctional window is composed of a multifunctional window 1 and a detection part 2.
  • the upper surface of the multifunctional window 1 is integrated with a microlens array 3, the middle is the window body 4, and the lower surface of the window is plated with four kinds of filter arrays 5, which are three kinds of monochromatic visible light plus infrared Band pass filter and an infrared filter.
  • the structure of each unit in the microlens array 3 is a spherical cap with a square edge, the side length of the square is 20um ⁇ 20um, the radius of curvature of the spherical cap is 150um, and the height of the spherical cap is 3um; the microlens can transmit visible light to infrared Wide spectrum.
  • the working process of the imaging detector of the present invention is as follows:
  • the incident light wave passes through the microlens array 3 and the window body 4 above the detector.
  • Each microlens converges the light beam and sends it to the filter array 5.
  • the four kinds of filter arrays affect the incident light wave.
  • Filter separately, R+IR filter can transmit visible red light and infrared
  • G+IR filter can transmit visible green and infrared
  • B+IR filter can transmit visible blue and infrared
  • IR filter The light sheet can transmit infrared.
  • the microlens condenses the light that originally fell in the non-light sensitive areas such as the gap of the sub-pixel unit and the electrode to the light sensitive area in the middle of the sub-pixel unit, which improves the utilization rate of incident light waves.
  • the microlens adopts a wide-spectrum transmission material from visible light to infrared, which can transmit visible light in the wavelength range of 390nm to 780nm, and the infrared wavelength range is 780nm to 12um;
  • the broad-spectrum transmission material is magnesium fluoride, zinc sulfide, and fluoride Broad-spectrum transmission materials such as beryllium, potassium chloride and zinc selenide.
  • the detection part 2 of the detector is an array of pixel units that can work all day long.
  • Each square pixel unit is composed of four square sub-pixel units, which are R+IR sub-pixel units, G+IR sub-pixel units, and B+IR.
  • the sub-pixel unit and the IR sub-pixel unit are insulated from each other.
  • Each sub-pixel unit is composed of a broad spectrum sensitive layer, electrodes and integrated circuits.
  • the incident light wave passes through the upper electrode that is conductive and transparent to visible light and infrared, and then passes through the photosensitive layer composed of visible light and infrared sensitive materials to excite the detection film of the photosensitive layer for photoelectric conversion, generating photo-generated carriers, under the action of electric field , The photogenerated carriers flow out to form a photocurrent, which is collected by the electrodes and then derived.
  • the detection signal of the sub-pixel unit corresponding to the R+IR, G+IR, and B+IR filter unit can be subtracted from the sub-pixel unit corresponding to the IR filter unit when the detector is working during the day.
  • the detection signal part so as to ensure that the R, G, and B detection signals present true colors, see the spectrograms in Figure 8-11; due to the weak visible light signal during night work, the four filters can transmit infrared, and the four filters below it Two sub-pixel units detect infrared at the same time, which can work normally at night;
  • the preparation method of the multifunctional window 1 is as follows:
  • the copper template 6 is prepared by single-point diamond turning method, and then the zinc sulfide broad-spectrum transmission material layer 7 is chemically vapor deposited on the copper template 6, and the copper template 6 is removed after the temperature is reduced.
  • the broad-spectrum transmission material layer 7 includes the microlens array 3 and the window body 4.
  • a filter array 5 is plated on the lower surface of the window body 4, and finally a multifunctional window 1 meeting the requirements is obtained.
  • the structure of the microlens unit is a spherical cap with a square edge, the square side length is 20um ⁇ 20um, and the spherical cap curvature radius It is 150um and the height of the spherical cap is 3um.
  • the microlens can transmit a broad spectrum from visible light to infrared.
  • the position of the microlens corresponds to the position of the bandpass filter unit, and they all correspond to the pixel unit of the detector when installed, as shown in FIG. 5.
  • the filter is on the lower surface of the window body, three of the four filters are band-pass filter films for both monochromatic visible light and infrared, and one is an infrared film; the number of layers of the film ranges from 2 to 50 layers, including endpoint values; the filter unit is a 2 ⁇ 2 sub-array, including R+IR filters, G+IR filters, B+IR filters, and IR filters.
  • the R+IR filter can transmit visible red and infrared light
  • the G+IR filter can transmit visible green light and infrared
  • the B+IR filter can transmit visible blue and infrared
  • the IR filter can transmit Through infrared.
  • an all-weather imaging detector with a multi-function window of the present invention includes a multi-function window 1 and a detection part 2.
  • the multifunctional window 1 includes a micro lens array 3, a window body 4 and a filter array 5.
  • the invention provides an all-day imaging detector with a multifunctional window, and its preparation includes the preparation of the multifunctional window and the preparation of the detection part.
  • the specific preparation method of the multifunctional window includes the following steps:
  • Step 1 Select window material.
  • Step 2 Prepare the lens part.
  • Broad-spectrum zinc sulfide is grown on the template by chemical vapor deposition.
  • the template material is made of metal copper, and then prepared by single-point diamond turning.
  • the prepared copper template with concave curved surface 6 Shape: spherical crown with square edge, square side length 20um ⁇ 20um, spherical crown shape: curvature Radius: 150um, spherical cap height: 3um.
  • Step 3 Coating the filter array film.
  • step 2 Pre-treating the lower surface of the zinc sulfide broadband transmission material layer finally obtained in step 2. Including the grinding, polishing and cleaning of zinc sulfide glass, the treatment process is strictly in accordance with the cold processing technology of optical components and semiconductor cleaning specifications.
  • Exposure Since the sidewall profile of the photoresist is more sensitive to the exposure dose, the exposure time needs to be calculated according to the light intensity of the mercury lamp light source of the lithography machine and the rated exposure dose during exposure. When the exposure time is short, the pattern size becomes smaller; and when the exposure time increases, the pattern size gradually increases due to the diffraction effect. When the exposure time is 10s and the development time is 55s, the lithography pattern is the best, which meets the requirements of complete pattern, accurate size, and neat edges.
  • the zinc sulfide glass 17 is reverse-baked. Its purpose is to cause cross-linking reaction in the area not covered by the mask and change the dissolving ability of the photoresist in the developer. At the right temperature, the crosslinking reaction can proceed. Choose 115°C as the best reversal baking temperature.
  • Hard film Place the developed zinc sulfide glass 17 on a hot plate, set the temperature of the hot plate to 120°C, harden the film for 20 minutes, and take it out to cool down naturally.
  • the thin film is coated with visible red light and infrared light.
  • the R+IR film system is plated on the flat R+IR area 4 under the window material.
  • G+IR film system is plated on the plane G+IR area 5 under the window material.
  • a G+IR film is formed in the G+IR region.
  • a B+IR film is formed on the B+IR area.
  • the detection part is an array composed of four kinds of pixel units.
  • the pixel unit is composed of a substrate, a metal lower electrode, a photosensitive layer, and an upper electrode.
  • the lower electrode uses metallic copper as the material, and the sensitive layer uses graphene.
  • the preparation of the pixel unit array includes the following steps:
  • Step 1 The metal bottom electrode is a metal copper film, and a metal copper film is prepared on the substrate by chemical vapor deposition or electroless plating, which can conduct electricity.
  • the photosensitive layer is made of materials sensitive to visible light and infrared, and graphene is used for illustration.
  • the quartz plate put the quartz plate into the quartz tube of the vacuum tube furnace, make it at the center of the temperature zone, connect and fix the flanges at both ends of the quartz tube, turn on the vacuum pump and start vacuuming
  • the vacuum of the system drops below 10Pa, start to feed in methane and hydrogen, adjust the methane and hydrogen to 40sccm:40sccm, and continue to mix the two gases for a period of time.
  • the upper electrode is made of a material that is conductive and transparent to visible light to near-infrared, including a grid of one-dimensional conductive nanowire materials in various forms, covering the graphene.
  • the one-dimensional conductive nanowire grid is formed by randomly arranging one-dimensional conductive nanowires, the mesh can transmit visible light and near infrared, and the grid wires can conduct electricity;
  • the one-dimensional conductive nanowires include carbon nanotubes, Silver nanowire and gold nanowire.
  • the carbon nanotubes and ethanol are uniformly mixed by ultrasonic to form a suspension, and the substrate with the graphene film is immersed in the suspension. The immersion depth is below the surface of the liquid. After the ethanol is volatilized, a grid of carbon nanotubes is formed as the upper electrode .
  • Step four etching the upper electrode, the sensitive layer and the metal lower electrode between the sub-pixel units.
  • a 50nm zinc sulfide passivation layer is prepared by chemical vapor deposition, and the passivation layer is carved into a square pattern by photolithography and etching, corresponding to the sub-pixel unit, and the patterned passivation layer is used as a masking layer.
  • the electrode, the sensitive layer and the metal bottom electrode are patterned to form an array of sub-pixel units that are isolated from each other in two vertical directions along the plane. Four adjacent sub-pixel units of R+IR, G+IR, B+IR, and IR form one Pixel array unit, the pixel array can realize the detection function of the detector.
  • an all-day imaging detector with multifunctional window can be prepared.
  • the upper surface of the window body of the present invention is provided with a microlens array corresponding to the position of the filter array.
  • the microlens array condenses the light that originally fell in the non-photosensitive areas such as the gap of the sub-pixel unit and the electrode to the light in the middle of the sub-pixel unit.
  • the sensitive area improves the utilization of incident light waves.
  • the whole structure integrates the window body, the filter and the micro lens array into a whole, has a small volume, a high degree of integration, shortens the assembly steps, simplifies the installation process, and has good process compatibility.

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Abstract

Provided are a full-day imaging detector with a multi-functional window, and a method for preparing same. The full-day imaging detector comprises a multi-functional window (1) and a detection portion (2). The multi-functional window (1) comprises a micro-lens array (3), a window body (4) and an optical filter array (5), wherein the micro-lens array (3) is integrated on an upper surface of the window body (4), a top surface of each micro-lens unit is of a spherical crown structure, the projection of the spherical crown is square from a top view, and the square projections of spherical crowns of adjacent micro-lens units from the top view are connected; the optical filter array (5) is plated on a lower surface of the window body (4); and the optical filter array (5) comprises four types of optical filters, including three types of band-pass optical filters of single-color visible light in combination with an infrared waveband, and an infrared optical filter. The detection portion (2) is constituted of a pixel unit array, wherein each pixel unit comprises four types of sub-pixel units, and the four types of sub-pixel units directly face the four types of optical filters in a one-to-one correspondence mode. Further provided are a method for preparing a micro-lens array and a detection method for a detector. Full-day detection can be realized.

Description

具有多功能窗口的全天时成像探测器及其制备方法All-day imaging detector with multifunctional window and preparation method thereof 技术领域Technical field
本发明属于光电探测技术领域,具体涉及一种具有多功能窗口的全天时成像探测器及其制备方法。The invention belongs to the technical field of photoelectric detection, and specifically relates to an all-time imaging detector with a multifunctional window and a preparation method thereof.
背景技术Background technique
光电探测器是由辐射引起被照射材料电导率发生改变而进行探测。光电探测器具有广泛用途,在可见光或近红外波段主要用于成像和探测、工业自动控制、光度计量等;在红外波段主要用于红外热成像、红外遥感等方面。The photodetector detects the change in the conductivity of the irradiated material caused by radiation. Photoelectric detectors have a wide range of uses. In the visible or near-infrared band, they are mainly used for imaging and detection, industrial automatic control, photometric measurement, etc.; in the infrared band, they are mainly used for infrared thermal imaging and infrared remote sensing.
传统光电探测器由分立的窗口、微透镜阵列、滤光片阵列和像素单元阵列组成,需要分别装配构成探测器。窗口是为探测器透进光波,隔绝空气进行真空封装而设计的。窗口下方的微透镜阵列可透所探测光波波段,微透镜阵列下方是不同的滤光片组成的阵列,滤波片阵列下方是位于基底上的像素单元阵列,由像素单元阵列对入射光波进行探测。每个像素单元又由多种亚像素单元分区域组合构成。现有的可见光探测器的像素单元由可探测红光(R)、绿光(G)、蓝光(B)的3个亚像素单元组成,分别称为红光(R)亚像素单元,绿光(G)亚像素单元,蓝光(B)亚像素单元,各亚像素单元上方的滤光片对入射光波进行滤波,分别选择性透过红光、绿光、蓝光,分别称为红光滤光片(R)、绿光滤光片(G)、蓝光滤光片(B)。三种滤光片在三种亚像素单元上方对应排布,上下对正。在滤光片的上方还设置有微透镜阵列,将入射的光线汇聚。三种滤光片的阵列位于像素单元阵列的正上方,红光滤光片(R)正对红光(R)亚像素单元,绿光滤光片(G)正对绿光(G)亚像素单元,蓝光滤光片(B)正对蓝光(B)亚像素单元。相应地,每个微透镜正对着下方的亚像素单元。通过设计红光(R)、绿光(G)、蓝光(B)亚像素单元不同的排列组合形式,实现可见光波段的彩色探测成像。亚像素单元对入射光波进行光电转换,进行探测,选用可见光或红外的探测材料制作敏感层,由敏感层确定了亚像素单元的工作波段。常见的光电探测器件是可见光成像或者单波段的红外器件,窗口、微透镜阵列及滤光片只能单波段透过,其波段覆盖范围窄,不能实现昼夜兼用。窗口、微透镜阵列及滤光片是分立器件,集成度低。Traditional photodetectors are composed of discrete windows, microlens arrays, filter arrays and pixel unit arrays, which need to be assembled separately to form the detectors. The window is designed for the detector to penetrate light waves and isolate the air for vacuum packaging. The microlens array below the window can penetrate the detected light waveband. Below the microlens array is an array of different filters. Below the filter array is an array of pixel units on the substrate. The pixel unit array detects incident light waves. Each pixel unit is composed of a combination of multiple sub-pixel units and regions. The pixel unit of the existing visible light detector consists of three sub-pixel units that can detect red light (R), green light (G), and blue light (B), which are called red light (R) sub-pixel units, and green light (G) Sub-pixel unit, blue light (B) Sub-pixel unit, the filter above each sub-pixel unit filters the incident light waves, and selectively transmits red light, green light, and blue light, respectively, called red light filter Sheet (R), green filter (G), blue filter (B). The three kinds of filters are arranged correspondingly above the three kinds of sub-pixel units, and are aligned up and down. A micro lens array is also arranged above the filter to converge the incident light. The array of three kinds of filters is located directly above the pixel unit array, the red filter (R) is facing the red (R) sub-pixel unit, and the green filter (G) is facing the green (G) sub-pixel unit. Pixel unit, the blue light filter (B) is facing the blue light (B) sub-pixel unit. Correspondingly, each micro lens faces the sub-pixel unit directly below. By designing different permutations and combinations of red light (R), green light (G), and blue light (B) sub-pixel units, color detection imaging in the visible light band is realized. The sub-pixel unit performs photoelectric conversion on the incident light wave and detects it. The sensitive layer is made of visible light or infrared detection materials, and the working band of the sub-pixel unit is determined by the sensitive layer. Common photodetector devices are visible light imaging or single-wavelength infrared devices. Windows, microlens arrays and filters can only pass through a single wavelength, and their band coverage is narrow, which cannot be used both day and night. The window, microlens array and filter are discrete devices with low integration.
为了解决全天时光电探测的问题,现有的可见光-红外成像探测器,白天工作的可见光成像系统与夜间工作的红外成像系统一般是分开的,在两条光路中对可见光和红外进行独立探测成像,其窗口只能工作于可见或红外单一波段,然后通过计算机采用图像配准与融合的方法将可见光图像和红外图像进行合成。这种方式会导致成像系统体积大、重量重、功耗高,限制了应用范围,因此未能满足对体积小、重量轻、功耗低的单芯片、全天时成像探测器的需求。用于全天时成像器件的探测器窗口要同时满足白天可见光彩色成像及夜间红外成像的要求,将窗口、微透镜阵列、滤波片阵列进行集成,减小其占用空间,缩短安装步骤,简化安装工艺。In order to solve the problem of photoelectric detection in the whole day, the existing visible light-infrared imaging detector, the visible light imaging system working during the day and the infrared imaging system working at night are generally separated, and the visible light and infrared are detected independently in two light paths For imaging, the window can only work in a single visible or infrared band, and then the visible light image and the infrared image are synthesized by a computer using image registration and fusion methods. This method will cause the imaging system to be large in size, heavy in weight, and high in power consumption, which limits the scope of application. Therefore, it fails to meet the demand for a small, light, and low power single chip, all-day imaging detector. The detector window used for all-day imaging devices must meet the requirements of daytime visible light color imaging and night infrared imaging. The window, microlens array, and filter array are integrated to reduce their occupied space, shorten installation steps, and simplify installation Craft.
其中意法半导体公司于2015年申请的专利CN201510609809中提出了一种利用IR亚像素单元探测信号分别校正R、G、B亚像素单元探测信号的方法,如图1所示,透过R、G、B滤光片的光线中含有部分杂光IR,通过校正这一部分的杂光,从而得到尽可能纯的R、G、B亚像 素单元探测信号,但是窗口、微透镜阵列及滤光片是分立器件,没有集成;由于透过滤光片的光谱范围在红外波段只到1.1μm,未能覆盖近红外、短波红外、中波红外及长波红外。因此使用该发明中滤光片的探测器只能在白天工作,不能实现全天时探测。Among them, the patent CN201510609809 filed by STMicroelectronics in 2015 proposed a method of using IR sub-pixel unit detection signals to separately correct R, G, and B sub-pixel unit detection signals. As shown in Figure 1, through R, G The light of the B filter contains part of the stray light IR. By correcting this part of the stray light, the detection signal of the R, G, B sub-pixel unit is as pure as possible, but the window, microlens array and filter are Discrete devices are not integrated; since the spectral range of the light-transmitting filter is only 1.1μm in the infrared band, it cannot cover near infrared, shortwave infrared, midwave infrared and longwave infrared. Therefore, the detector using the filter of the invention can only work in the daytime, and cannot achieve full-time detection.
发明内容Summary of the invention
本发明的目的是提供一种具有多功能窗口的全天时成像探测器及其制备方法,将窗口、微透镜阵列、滤波片阵列进行集成,解决现有技术中探测器只能在白天工作,不能实现全天时探测的问题。The purpose of the present invention is to provide a full-time imaging detector with multifunctional windows and a preparation method thereof, which integrates the window, microlens array, and filter array to solve the problem that the detector in the prior art can only work during the day. The problem of detection all day long cannot be realized.
为了达到上述目的,本发明的技术方案如下:In order to achieve the above objective, the technical scheme of the present invention is as follows:
具有多功能窗口的全天时成像探测器,包括多功能窗口和探测部分,多功能窗口包括微透镜阵列、窗口本体和滤光片阵列;所述微透镜阵列集成在窗口本体的上表面,每个微透镜单元顶面均为球冠结构,球冠的俯视投影为正方形,相邻微透镜单元球冠俯视投影的正方形相接;所述滤光片阵列镀制在窗口本体的下表面;所述滤光片阵列包括四种滤光片,分别为三种单色可见光结合红外波段的带通滤光片和一种红外滤光片;所述探测部分由像素单元阵列构成,每个像素单元包括四种亚像素单元,四种亚像素单元与四种滤光片一一正对。An all-day imaging detector with a multifunctional window, including a multifunctional window and a detection part. The multifunctional window includes a microlens array, a window body and a filter array; the microlens array is integrated on the upper surface of the window body, each The top surface of each microlens unit is a spherical cap structure, the top view projection of the spherical cap is square, and the squares of the top view projection of the adjacent microlens unit spherical caps are connected; the filter array is plated on the lower surface of the window body; The filter array includes four types of filters, which are three kinds of band-pass filters for monochromatic visible light combined with infrared bands and one type of infrared filter; the detection part is composed of an array of pixel units, each pixel unit It includes four sub-pixel units, and the four sub-pixel units are directly opposite to the four filters.
进一步的,所述四种滤光片分别为R+IR滤光片、G+IR滤光片、B+IR滤光片和IR滤光片,所述四个亚像素单元分别为R+IR亚像素单元、G+IR亚像素单元、B+IR亚像素单元和IR亚像素单元。Further, the four types of filters are R+IR filters, G+IR filters, B+IR filters, and IR filters, respectively, and the four sub-pixel units are R+IR, respectively. Sub-pixel unit, G+IR sub-pixel unit, B+IR sub-pixel unit and IR sub-pixel unit.
进一步的,每个亚像素单元分别由宽光谱敏感层、电极和集成电路构成。Further, each sub-pixel unit is composed of a wide-spectrum sensitive layer, electrodes, and integrated circuits.
上述微透镜阵列的制备方法如下,首先将铜采用单点金刚石车削的方法制备成具有凹曲面的铜模板,然后在铜模板上化学气相沉积宽光谱透射材料层,完成后降温脱去铜模板,所得宽光谱透射材料层即包括微透镜阵列和窗口本体两部分,在窗口本体的背面分区域镀制滤光片阵列,最终得到具有宽光谱透射性能的多功能窗口。The preparation method of the above-mentioned microlens array is as follows. First, the copper is prepared into a copper template with a concave curved surface by a single-point diamond turning method, and then a broad spectrum transmission material layer is chemically vapor deposited on the copper template, and the copper template is removed after the temperature is reduced. The obtained broad-spectrum transmission material layer includes two parts: a microlens array and a window body, and a filter array is plated on the back of the window body in regions to finally obtain a multifunctional window with broad-spectrum transmission performance.
上述探测器的探测方法如下,探测器白天工作时,R+IR滤光片、G+IR滤光片、B+IR滤光片所对应的亚像素单元探测信号减掉IR滤光片所对应的亚像素单元探测信号,得到R、G、B真彩色;探测器夜间工作时,R+IR滤光片、G+IR滤光片、B+IR滤光片和IR滤光片可透射红外,它们下方的四个亚像素单元同时探测红外,探测器在夜间正常工作。The detection method of the above-mentioned detector is as follows. When the detector works during the day, the detection signal of the sub-pixel unit corresponding to the R+IR filter, G+IR filter, and B+IR filter is subtracted from the corresponding IR filter. The sub-pixel unit detects the signal to obtain the true colors of R, G, B; when the detector works at night, the R+IR filter, G+IR filter, B+IR filter and IR filter can transmit infrared , The four sub-pixel units below them simultaneously detect infrared, and the detectors work normally at night.
与现有技术相比,本发明具有以下有益效果:Compared with the prior art, the present invention has the following beneficial effects:
1.本发明采用可透射可见光至红外波段光波的微透镜阵列,其对光线有汇聚的作用,微透镜阵列与滤光片阵列及亚像素阵列相对应,将原本落在亚像素单元间隙及电极等非光敏感区域的光线汇聚到亚像素单元中间的光敏感区,提高了入射光波的利用率;1. The present invention adopts a microlens array that can transmit light waves in the visible to infrared wavelengths, which has a converging effect on light. The microlens array corresponds to the filter array and the sub-pixel array, and it will originally fall in the gap of the sub-pixel unit and the electrode. The light from the non-light sensitive area converges to the light sensitive area in the middle of the sub-pixel unit, which improves the utilization of incident light waves;
2.本发明单片窗口可实现从可见光到红外的宽光谱透过和滤波、分色、汇聚等多种功能,同时,单片结构相对于多片结构减少了散射、吸收等光学损耗;探测器兼顾白天彩色和夜间红外两种工作模式,可实现全天时成像探测;2. The single-piece window of the present invention can realize wide-spectrum transmission and filtering, color separation, convergence and other functions from visible light to infrared. At the same time, the single-piece structure reduces the optical loss such as scattering and absorption compared with the multi-piece structure; The device takes into account two working modes of daytime color and nighttime infrared, which can realize full-time imaging detection;
3.本发明窗口正面加工微透镜阵列,背面镀膜,体积小,集成度高,可缩短装配步骤,简化安装工艺,工艺兼容性好;3. The front surface of the window of the present invention is processed with a microlens array, and the back surface is coated with a small volume, high integration, can shorten the assembly steps, simplify the installation process, and have good process compatibility;
4.本发明采用微透镜阵列向上,滤光片向下的方式,避免了膜层易脱落的问题,同时使得滤光片与探测单元距离更近。4. The present invention adopts the way that the microlens array is upward and the filter is downward, which avoids the problem that the film is easy to fall off, and at the same time makes the filter and the detection unit closer.
附图说明Description of the drawings
图1是意法半导体公司专利中像素阵列的颜色像素布局示意图;Figure 1 is a schematic diagram of the color pixel layout of the pixel array in the patent of STMicroelectronics;
图2是具有多功能窗口的全天时成像探测器的总体结构图;Figure 2 is a diagram of the overall structure of an all-sky imaging detector with multifunctional windows;
图3是多功能窗口的正视图;Figure 3 is a front view of the multifunctional window;
图4是多功能窗口的俯视图;Figure 4 is a top view of the multifunctional window;
图5是具有多功能窗口的全天时成像探测器工作原理图;Figure 5 is a working principle diagram of an all-day imaging detector with multi-function windows;
图6是滤光片单元在白天的工作模式示意图;Fig. 6 is a schematic diagram of the working mode of the filter unit in the daytime;
图7是滤光片单元在夜间的工作模式示意图;Figure 7 is a schematic diagram of the working mode of the filter unit at night;
图8是B+IR滤波区域光谱图;Figure 8 is a spectrum diagram of the B+IR filter area;
图9是G+IR滤波区域光谱图;Figure 9 is a spectral diagram of the G+IR filter area;
图10是R+IR滤波区域光谱图;Figure 10 is a spectrum diagram of the R+IR filter area;
图11是IR滤波区域光谱图;Figure 11 is a spectrum diagram of the IR filter region;
图12是多功能窗口的制备流程图。Figure 12 is a flow chart of the preparation of the multifunctional window.
具体实施方式detailed description
下面结合附图和具体实施方式对本发明进行详细说明。The present invention will be described in detail below with reference to the drawings and specific embodiments.
本申请的基本原理和思路是:探测器窗口的上表面为微透镜阵列,对光线具有汇聚作用,可提高光线利用率;窗口的下表面为可见光彩色成像与红外成像兼用的滤光片,能够昼夜兼用;像素单元具有两种工作模式,白天工作时R+IR(红光+红外光)、G+IR(绿光+红外光)和B+IR(蓝光+红外光)三种亚像素单元所得探测信号可以减掉IR(红外光)亚像素单元所得探测信号部分,从而保证R+IR、G+IR、B+IR亚像素单元探测信号呈现出真彩色;夜间工作时由于可见光信号很弱,四个滤光片可透射红外,其下方的四个亚像素单元同时探测红外,可在夜间正常工作;The basic principles and ideas of this application are: the upper surface of the detector window is a microlens array, which has a condensing effect on light, which can improve light utilization; the lower surface of the window is a filter for both visible light color imaging and infrared imaging, which can Both day and night; the pixel unit has two working modes, R+IR (red light + infrared light), G+IR (green light + infrared light) and B+IR (blue light + infrared light) three sub-pixel units during daytime work The obtained detection signal can subtract the part of the detection signal obtained by the IR (infrared light) sub-pixel unit, so as to ensure that the detection signal of the R+IR, G+IR, B+IR sub-pixel unit presents true colors; the visible light signal is very weak when working at night , Four filters can transmit infrared, and the four sub-pixel units below it can detect infrared at the same time, which can work normally at night;
为了实现上述目的,本发明采用如下技术方案:In order to achieve the above objectives, the present invention adopts the following technical solutions:
如图2所示,一种具有多功能窗口的全天时成像探测器,由多功能窗口1和探测部分2构成。As shown in Figure 2, an all-sky imaging detector with a multifunctional window is composed of a multifunctional window 1 and a detection part 2.
如图3、4所示,多功能窗口1上表面集成有微透镜阵列3,中间是窗口本体4,窗口下表面镀制有四种滤光片阵列5,分别为三种单色可见光加红外波段的带通滤光片和一种红外滤光片。所述微透镜阵列3中每个单元的结构为正方形边沿的球冠,正方形边长20um×20um,球冠的曲率半径为150um,球冠高度为3um;所述微透镜可以透射从可见光到红外的宽光谱。As shown in Figures 3 and 4, the upper surface of the multifunctional window 1 is integrated with a microlens array 3, the middle is the window body 4, and the lower surface of the window is plated with four kinds of filter arrays 5, which are three kinds of monochromatic visible light plus infrared Band pass filter and an infrared filter. The structure of each unit in the microlens array 3 is a spherical cap with a square edge, the side length of the square is 20um×20um, the radius of curvature of the spherical cap is 150um, and the height of the spherical cap is 3um; the microlens can transmit visible light to infrared Wide spectrum.
本发明的成像探测器工作过程如下:The working process of the imaging detector of the present invention is as follows:
如图5所示,入射光波透过探测器上方的微透镜阵列3和窗口本体4,每个微透镜对光束进行汇聚,射向滤光片阵列5,四种滤光片的阵列对入射光波分别进行滤波,R+IR滤光片可以透过可见红光和红外,G+IR滤光片可以透过可见绿光和红外,B+IR滤光片可以透过可见蓝光和红外,IR滤光片可以透过红外。微透镜将原本落在亚像素单元间隙及电极等非光敏感区域的光线汇聚到亚像素单元中间的光敏感区,提高了入射光波利用率。As shown in Figure 5, the incident light wave passes through the microlens array 3 and the window body 4 above the detector. Each microlens converges the light beam and sends it to the filter array 5. The four kinds of filter arrays affect the incident light wave. Filter separately, R+IR filter can transmit visible red light and infrared, G+IR filter can transmit visible green and infrared, B+IR filter can transmit visible blue and infrared, IR filter The light sheet can transmit infrared. The microlens condenses the light that originally fell in the non-light sensitive areas such as the gap of the sub-pixel unit and the electrode to the light sensitive area in the middle of the sub-pixel unit, which improves the utilization rate of incident light waves.
所述微透镜采用从可见光到红外的宽光谱透射材料,可透过波长范围为可见光390nm到780nm,红外波长范围为780nm到12um;所述宽光谱透射材料为氟化镁、硫化锌、氟化 铍、氯化钾、硒化锌等宽光谱透过材料。The microlens adopts a wide-spectrum transmission material from visible light to infrared, which can transmit visible light in the wavelength range of 390nm to 780nm, and the infrared wavelength range is 780nm to 12um; the broad-spectrum transmission material is magnesium fluoride, zinc sulfide, and fluoride Broad-spectrum transmission materials such as beryllium, potassium chloride and zinc selenide.
探测器的探测部分2是可全天时工作的像素单元阵列,每个方形像素单元由四个方形亚像素单元组成,分别为R+IR亚像素单元、G+IR亚像素单元、B+IR亚像素单元和IR亚像素单元,亚像素单元间彼此绝缘。每个亚像素单元分别由宽光谱敏感层、电极和集成电路组成。入射的光波透过导电且透可见光和红外的上电极,然后经过对可见光和红外敏感的材料构成的光敏层,激发光敏层的探测薄膜进行光电转化,产生光生载流子,在电场的作用下,光生载流子流出,形成光电流,由电极汇聚后导出。The detection part 2 of the detector is an array of pixel units that can work all day long. Each square pixel unit is composed of four square sub-pixel units, which are R+IR sub-pixel units, G+IR sub-pixel units, and B+IR. The sub-pixel unit and the IR sub-pixel unit are insulated from each other. Each sub-pixel unit is composed of a broad spectrum sensitive layer, electrodes and integrated circuits. The incident light wave passes through the upper electrode that is conductive and transparent to visible light and infrared, and then passes through the photosensitive layer composed of visible light and infrared sensitive materials to excite the detection film of the photosensitive layer for photoelectric conversion, generating photo-generated carriers, under the action of electric field , The photogenerated carriers flow out to form a photocurrent, which is collected by the electrodes and then derived.
如图6、7所示,探测器白天工作时R+IR、G+IR、B+IR滤光片单元所对应的亚像素单元探测信号可以减掉IR滤光片单元所对应的亚像素单元探测信号部分,从而保证R、G、B探测信号呈现出真彩色,参见图8-图11的光谱图;夜间工作时由于可见光信号很弱,四个滤光片可透射红外,其下方的四个亚像素单元同时探测红外,可在夜间正常工作;As shown in Figures 6 and 7, the detection signal of the sub-pixel unit corresponding to the R+IR, G+IR, and B+IR filter unit can be subtracted from the sub-pixel unit corresponding to the IR filter unit when the detector is working during the day. The detection signal part, so as to ensure that the R, G, and B detection signals present true colors, see the spectrograms in Figure 8-11; due to the weak visible light signal during night work, the four filters can transmit infrared, and the four filters below it Two sub-pixel units detect infrared at the same time, which can work normally at night;
多功能窗口1的制备方法如下:The preparation method of the multifunctional window 1 is as follows:
如图12所示,先将铜采用单点金刚石车削的方法制备出铜模板6,然后在铜模板6上化学气相沉积硫化锌宽光谱透射材料层7,完成后降温脱去铜模板6,所得宽光谱透射材料层7即包括微透镜阵列3和窗口本体4。在窗口本体4的下表面镀制滤光片阵列5,最终得到满足要求的多功能窗口1,所述微透镜单元的结构为正方形边沿的球冠,正方形边长20um×20um,球冠曲率半径为150um,球冠高度为3um。所述微透镜可以透射从可见光到红外的宽光谱。所述微透镜的位置与带通滤光片单元位置对应,安装时它们都与探测器像素单元相对应,如图5所示。As shown in Figure 12, the copper template 6 is prepared by single-point diamond turning method, and then the zinc sulfide broad-spectrum transmission material layer 7 is chemically vapor deposited on the copper template 6, and the copper template 6 is removed after the temperature is reduced. The broad-spectrum transmission material layer 7 includes the microlens array 3 and the window body 4. A filter array 5 is plated on the lower surface of the window body 4, and finally a multifunctional window 1 meeting the requirements is obtained. The structure of the microlens unit is a spherical cap with a square edge, the square side length is 20um×20um, and the spherical cap curvature radius It is 150um and the height of the spherical cap is 3um. The microlens can transmit a broad spectrum from visible light to infrared. The position of the microlens corresponds to the position of the bandpass filter unit, and they all correspond to the pixel unit of the detector when installed, as shown in FIG. 5.
所述滤光片在窗口本体的下表面,所述四种滤光片中三种为单色可见光与红外兼用的带通滤波薄膜,一种是红外薄膜;所述薄膜层数为2层到50层,包括端点值;所述滤光片单元为2×2子阵列,包括R+IR滤光片、G+IR滤光片,B+IR滤光片,IR滤光片。其中R+IR滤光片可以透过可见红光和红外,G+IR滤光片可以透过可见绿光和红外,B+IR滤光片可以透过可见蓝光和红外,IR滤光片可以透过红外。The filter is on the lower surface of the window body, three of the four filters are band-pass filter films for both monochromatic visible light and infrared, and one is an infrared film; the number of layers of the film ranges from 2 to 50 layers, including endpoint values; the filter unit is a 2×2 sub-array, including R+IR filters, G+IR filters, B+IR filters, and IR filters. The R+IR filter can transmit visible red and infrared light, the G+IR filter can transmit visible green light and infrared, the B+IR filter can transmit visible blue and infrared, and the IR filter can transmit Through infrared.
请参阅图2所示,本发明一种具有多功能窗口的全天时成像探测器,包括多功能窗口1和探测部分2。Please refer to FIG. 2, an all-weather imaging detector with a multi-function window of the present invention includes a multi-function window 1 and a detection part 2.
请参阅图3所示,多功能窗口1包括微透镜阵列3,窗口本体4和滤光片阵列5。Please refer to FIG. 3, the multifunctional window 1 includes a micro lens array 3, a window body 4 and a filter array 5.
本发明一种具有多功能窗口的全天时成像探测器,其制备包括多功能窗口的制备和探测部分的制备。The invention provides an all-day imaging detector with a multifunctional window, and its preparation includes the preparation of the multifunctional window and the preparation of the detection part.
其中多功能窗口具体的制备方法包括如下步骤:The specific preparation method of the multifunctional window includes the following steps:
步骤一:选取窗口材料。Step 1: Select window material.
为使得390nm~12um宽光谱范围内都具有较高的透过率,选用化学气相沉积的方法生长的宽光谱硫化锌材料。In order to have a higher transmittance in the wide spectrum range of 390nm to 12um, a wide spectrum zinc sulfide material grown by chemical vapor deposition is selected.
步骤二:制备透镜部分。Step 2: Prepare the lens part.
在模板上化学气相沉积生长宽光谱硫化锌。Broad-spectrum zinc sulfide is grown on the template by chemical vapor deposition.
(1)制备模板过程。如图12,模板材料选用金属铜,然后采用单点金刚石车削的方法制备,所制备的具有凹曲面的铜模板6形状:正方形边沿的球冠,正方形边长20um×20um,球冠形状:曲率半径:150um,球冠高度:3um。(1) The process of preparing templates. As shown in Figure 12, the template material is made of metal copper, and then prepared by single-point diamond turning. The prepared copper template with concave curved surface 6 Shape: spherical crown with square edge, square side length 20um×20um, spherical crown shape: curvature Radius: 150um, spherical cap height: 3um.
(2)化学气相沉积硫化锌宽光谱透射材料层7,如图12。(2) Chemical vapor deposition of zinc sulfide broad spectrum transmission material layer 7, as shown in Fig. 12.
(3)降温脱模。利用金属铜与硫化锌膨胀系数的差异进行降温脱模,得到满足要求的硫化锌管光谱透射材料层7,如图12。(3) Cooling and demoulding. The difference between the expansion coefficients of metallic copper and zinc sulfide is used for cooling and demolding to obtain a zinc sulfide tube spectral transmission material layer 7 that meets the requirements, as shown in Figure 12.
步骤三:镀制滤光片阵列膜。Step 3: Coating the filter array film.
(1)对步骤二最终得到的硫化锌宽光谱透射材料层的下表面进行预处理。包括对硫化锌玻璃进行研磨、抛光、清洗,其处理过程严格按照光学元件冷加工工艺和半导体清洗规范进行。(1) Pre-treating the lower surface of the zinc sulfide broadband transmission material layer finally obtained in step 2. Including the grinding, polishing and cleaning of zinc sulfide glass, the treatment process is strictly in accordance with the cold processing technology of optical components and semiconductor cleaning specifications.
(2)匀胶、前烘。采用AZ5214E型光刻胶,使用国产KW-4A型台式匀胶机,在自转离心力的作用下匀胶。将三至四滴光刻胶滴至硫化锌玻璃21的下表面中心,然后设置转速为低速500/15(rpm/s)、高速4500/50(rpm/s),使光刻胶均匀的涂敷在硫化锌玻璃21的下表面。采用MIRAKTMT The molyne型热板,在100℃温度下前烘60s。(2) Glue and pre-baking. Using AZ5214E photoresist, using domestic KW-4A desktop homogenizer, homogenize the glue under the action of centrifugal force of rotation. Drop three to four drops of photoresist onto the center of the lower surface of the zinc sulfide glass 21, and then set the rotating speed to low speed 500/15 (rpm/s) and high speed 4500/50 (rpm/s) to make the photoresist evenly coated. Apply to the lower surface of the zinc sulfide glass 21. Using MIRAKTMT The molyne hot plate, pre-baking at 100℃ for 60s.
(3)曝光。由于光刻胶的侧壁形貌对曝光剂量比较敏感,曝光的时候需要根据光刻机汞灯光源的光强和额定的曝光剂量计算所需要的曝光时间。当曝光时间较短时,图形尺寸偏小;而当曝光时间增大时,由于衍射效应,图形尺寸也逐渐增大。选择曝光时间为10s,显影时间为55s时,光刻图案最好,它满足了图形完整、尺寸准确、边缘整齐的要求。(3) Exposure. Since the sidewall profile of the photoresist is more sensitive to the exposure dose, the exposure time needs to be calculated according to the light intensity of the mercury lamp light source of the lithography machine and the rated exposure dose during exposure. When the exposure time is short, the pattern size becomes smaller; and when the exposure time increases, the pattern size gradually increases due to the diffraction effect. When the exposure time is 10s and the development time is 55s, the lithography pattern is the best, which meets the requirements of complete pattern, accurate size, and neat edges.
(4)反转烘。对硫化锌玻璃17进行反转烘。其目的是使未被掩模版覆盖的区域发生交联反应,改变光刻胶在显影液中的溶解能力。在合适的温度下,交联反应才能进行。选择115℃为最佳的反转烘温度。(4) Reverse baking. The zinc sulfide glass 17 is reverse-baked. Its purpose is to cause cross-linking reaction in the area not covered by the mask and change the dissolving ability of the photoresist in the developer. At the right temperature, the crosslinking reaction can proceed. Choose 115℃ as the best reversal baking temperature.
(5)泛曝光。不使用掩模版,将反转烘后的硫化锌玻璃17放置在Q4000型光刻机下进行曝光,改变未曝光区域的光刻胶的溶解性能。设置泛曝光的时间为11s。(5) Pan exposure. Without using a mask, the zinc sulfide glass 17 after reversal baking is placed in a Q4000 lithography machine for exposure to change the dissolution performance of the photoresist in the unexposed area. Set the pan exposure time to 11s.
(6)显影。对硫化锌玻璃17的下表面进行显影。采用KMP PD238-Ⅱ型显影液,由于显影液对光刻胶有溶解作用,当显影时间不合适时,容易出现显影不足、不完全显影、过显影等现象,因而必须控制好显影时间,最佳的显影时间控制在50-60s之间。(6) Development. The lower surface of the zinc sulfide glass 17 is developed. Using KMP PD238-Ⅱ developer, because the developer has a dissolving effect on the photoresist, when the development time is not appropriate, it is prone to underdevelopment, incomplete development, overdevelopment, etc. Therefore, the development time must be controlled, the best The development time is controlled between 50-60s.
(7)坚膜。将显影好的硫化锌玻璃17放置在热板上,设置热板温度为120℃,坚膜20min,取出自然降温。(7) Hard film. Place the developed zinc sulfide glass 17 on a hot plate, set the temperature of the hot plate to 120°C, harden the film for 20 minutes, and take it out to cool down naturally.
(8)镀透可见红光和红外的薄膜。在窗口材料下平面R+IR区域4上镀R+IR膜系。(8) The thin film is coated with visible red light and infrared light. The R+IR film system is plated on the flat R+IR area 4 under the window material.
(9)去胶、洗光刻胶。图形转移完成后,光刻胶已经完成了它的使命,为了进行新一轮的图形转移需要将光刻胶去除,以为下一次光刻做准备。(9) Remove glue and wash photoresist. After the pattern transfer is completed, the photoresist has completed its mission. In order to carry out a new round of pattern transfer, the photoresist needs to be removed to prepare for the next photolithography.
(10)在R+IR的区域形成R+IR薄膜。(10) An R+IR film is formed in the R+IR region.
(11)重复上述步骤(1)—(7)。(11) Repeat the above steps (1)-(7).
(12)镀可透可见绿光和红外的薄膜。在窗口材料下平面G+IR区域5上镀G+IR膜系。(12) Plating a thin film that can transmit visible green light and infrared light. G+IR film system is plated on the plane G+IR area 5 under the window material.
(13)去胶、洗光刻胶。图形转移完成后,光刻胶已经完成了它的使命,为了进行新一轮的图形转移需要将光刻胶去除,以为下一次光刻做准备。(13) Remove glue and wash photoresist. After the pattern transfer is completed, the photoresist has completed its mission. In order to carry out a new round of pattern transfer, the photoresist needs to be removed to prepare for the next photolithography.
(14)在G+IR的区域形成G+IR薄膜。(14) A G+IR film is formed in the G+IR region.
(15)重复上述步骤(1)—(7)。(15) Repeat the above steps (1)-(7).
(16)镀透可见蓝光和红外的薄膜。在窗口材料下平面B+IR区域6上镀B+IR膜系。(16) Thin film that is transparent to visible blue and infrared. B+IR film system is plated on the flat B+IR area 6 under the window material.
(17)去胶、洗光刻胶。为了进行新一轮的图形转移需要将光刻胶去除,以为下一次光刻做准备。(17) Remove glue and wash photoresist. In order to perform a new round of pattern transfer, the photoresist needs to be removed to prepare for the next photolithography.
(18)在B+IR的区域上形成B+IR薄膜。(18) A B+IR film is formed on the B+IR area.
(19)重复上述步骤(1)—(7)。(19) Repeat the above steps (1)-(7).
(20)镀透红外的薄膜。在窗口材料下平面IR区域7镀IR膜系。(20) Plating infrared film. The flat IR area 7 is plated with IR film under the window material.
(21)去胶、洗光刻胶。图形转移完成后,最后一个区域的镀膜工作完成,洗去多余的光刻胶即可。(21) Remove glue and wash photoresist. After the pattern transfer is completed, the coating of the last area is completed, and the excess photoresist can be washed away.
(22)在IR的区域上形成IR薄膜。(22) An IR film is formed on the IR area.
(23)完成探测窗口的制备。(23) Complete the preparation of the detection window.
探测部分为四种像素单元构成的阵列,像素单元由基底、金属下电极、光敏层、上电极组成。下电极选用金属铜作为材料,敏感层选用的材料为石墨烯。The detection part is an array composed of four kinds of pixel units. The pixel unit is composed of a substrate, a metal lower electrode, a photosensitive layer, and an upper electrode. The lower electrode uses metallic copper as the material, and the sensitive layer uses graphene.
基底的种类及样式繁多,此处不再赘述。There are many types and styles of substrates, so I won't repeat them here.
像素单元阵列的制备包括如下步骤:The preparation of the pixel unit array includes the following steps:
步骤一,金属下电极为金属铜薄膜,采用化学气相沉积或化学镀的方法在基底上制备一层金属铜膜,能够导电。Step 1: The metal bottom electrode is a metal copper film, and a metal copper film is prepared on the substrate by chemical vapor deposition or electroless plating, which can conduct electricity.
步骤二,光敏层是选用对可见光和红外敏感的材料,以石墨烯进行说明。将上序完成的基底放在石英板上,将石英板放入真空管式炉的石英管中,使其处于温区的中央位置,将石英管两端的法兰进行连接固定,打开真空泵开始抽真空,当系统的真空度降到10Pa以下时,开始通入甲烷和氢气,调节甲烷和氢气为40sccm:40sccm,持续一段时间使两种气体混合,压强稳定后,关闭甲烷气体,开启管式炉开关,开始进行阶段升温阶段;当温度升至保温阶段后,对铜进行退火处理,有利于生长阶段中石墨烯的生长,生长阶段通入甲烷气体,生长完毕,关闭甲烷,进入降温阶段,让其自热冷却至室温后,关闭氢气、真空泵,取出基底。铜膜的表面覆盖一层石墨烯。Step two, the photosensitive layer is made of materials sensitive to visible light and infrared, and graphene is used for illustration. Put the finished substrate on the quartz plate, put the quartz plate into the quartz tube of the vacuum tube furnace, make it at the center of the temperature zone, connect and fix the flanges at both ends of the quartz tube, turn on the vacuum pump and start vacuuming When the vacuum of the system drops below 10Pa, start to feed in methane and hydrogen, adjust the methane and hydrogen to 40sccm:40sccm, and continue to mix the two gases for a period of time. After the pressure stabilizes, turn off the methane gas and turn on the tube furnace switch , Start the stage heating stage; when the temperature rises to the holding stage, annealing the copper is beneficial to the growth of graphene in the growth stage. Methane gas is introduced into the growth stage. After the growth is completed, the methane is turned off and enter the cooling stage. After self-heating and cooling to room temperature, turn off the hydrogen and vacuum pump, and take out the substrate. The surface of the copper film is covered with a layer of graphene.
步骤三,上电极为导电且对可见光至近红外透明的材料,包括一维导电纳米线材料以各种形式构成的网格,覆盖在在石墨烯上。所述一维导电纳米线网格,其形状由一维导电纳米线随机排布构成,其网孔能够透过可见光和近红外,网格线能够导电;一维导电纳米线包括碳纳米管、银纳米线和金纳米线。Step 3: The upper electrode is made of a material that is conductive and transparent to visible light to near-infrared, including a grid of one-dimensional conductive nanowire materials in various forms, covering the graphene. The one-dimensional conductive nanowire grid is formed by randomly arranging one-dimensional conductive nanowires, the mesh can transmit visible light and near infrared, and the grid wires can conduct electricity; the one-dimensional conductive nanowires include carbon nanotubes, Silver nanowire and gold nanowire.
将碳纳米管和乙醇通过超声混合均匀形成悬浮液,将制作有石墨烯膜的基底浸入该悬浮液,浸入深度为没入液面以下,待乙醇挥发后,形成碳纳米管网格,作为上电极。The carbon nanotubes and ethanol are uniformly mixed by ultrasonic to form a suspension, and the substrate with the graphene film is immersed in the suspension. The immersion depth is below the surface of the liquid. After the ethanol is volatilized, a grid of carbon nanotubes is formed as the upper electrode .
步骤四,刻蚀亚像素单元之间的上电极、敏感层和金属下电极。Step four, etching the upper electrode, the sensitive layer and the metal lower electrode between the sub-pixel units.
采用化学气相沉积的方法制备50nm的硫化锌钝化层,通过光刻、腐蚀的方法使钝化层刻成正方形图形,与亚像素单元对应,将图形化的钝化层作为掩蔽层,对上电极、敏感层和金属下电极进行图形化,形成沿平面两个垂直方向相互隔离的亚像素单元阵列,相邻的R+IR、G+IR、B+IR、IR四种亚像素单元组成一个像素阵列单元,像素阵列可实现探测器的探测功能。A 50nm zinc sulfide passivation layer is prepared by chemical vapor deposition, and the passivation layer is carved into a square pattern by photolithography and etching, corresponding to the sub-pixel unit, and the patterned passivation layer is used as a masking layer. The electrode, the sensitive layer and the metal bottom electrode are patterned to form an array of sub-pixel units that are isolated from each other in two vertical directions along the plane. Four adjacent sub-pixel units of R+IR, G+IR, B+IR, and IR form one Pixel array unit, the pixel array can realize the detection function of the detector.
将所得的多功能窗口与探测部分装配,可以制备得到一种具有多功能窗口的全天时成像探测器。By assembling the obtained multifunctional window with the detection part, an all-day imaging detector with multifunctional window can be prepared.
本发明窗口本体的上表面设置有与滤光片阵列位置对应的微透镜阵列,该微透镜阵列将原本落在亚像素单元间隙及电极等非光敏感区域的光线汇聚到亚像素单元中间的光敏感区域,提高了入射光波的利用率。整个结构将窗口本体、滤光片和微透镜阵列集成为一体,体积小,集成度高,缩短装配步骤,简化安装工艺,并且工艺兼容性好。The upper surface of the window body of the present invention is provided with a microlens array corresponding to the position of the filter array. The microlens array condenses the light that originally fell in the non-photosensitive areas such as the gap of the sub-pixel unit and the electrode to the light in the middle of the sub-pixel unit. The sensitive area improves the utilization of incident light waves. The whole structure integrates the window body, the filter and the micro lens array into a whole, has a small volume, a high degree of integration, shortens the assembly steps, simplifies the installation process, and has good process compatibility.
以上应用了具体个例对本发明进行阐述,只是用于帮助理解本发明,并不用以限制本发明。对于本发明所属技术领域的技术人员,依据本发明的思想,还可以做出若干简单 推演、变形或替换。The above uses specific examples to illustrate the present invention, which are only used to help understand the present invention and not to limit the present invention. For those skilled in the art to which the present invention belongs, according to the idea of the present invention, several simple deductions, modifications or substitutions can also be made.

Claims (5)

  1. 具有多功能窗口的全天时成像探测器,包括多功能窗口(1)和探测部分(2),其特征在于,多功能窗口(1)包括微透镜阵列(3)、窗口本体(4)和滤光片阵列(5);所述微透镜阵列(3)集成在窗口本体(4)的上表面,每个微透镜单元顶面均为球冠结构,球冠的俯视投影为正方形,相邻微透镜单元球冠俯视投影的正方形相接;所述滤光片阵列(5)镀制在窗口本体(4)的下表面;所述滤光片阵列(5)包括四种滤光片,分别为三种单色可见光结合红外波段的带通滤光片和一种红外滤光片;所述探测部分由像素单元阵列构成,每个像素单元包括四种亚像素单元,四种亚像素单元与四种滤光片一一正对。The all-day imaging detector with multi-function window includes a multi-function window (1) and a detection part (2), characterized in that the multi-function window (1) includes a microlens array (3), a window body (4) and The filter array (5); the micro lens array (3) is integrated on the upper surface of the window body (4), the top surface of each micro lens unit is a spherical cap structure, and the top view projection of the spherical cap is square, adjacent The spherical cap of the microlens unit is connected with the squares projected from above; the filter array (5) is plated on the lower surface of the window body (4); the filter array (5) includes four kinds of filters, respectively It is three kinds of monochromatic visible light combined with infrared band pass filter and one kind of infrared filter; the detection part is composed of an array of pixel units, each pixel unit includes four sub-pixel units, four sub-pixel units and The four kinds of filters are facing one by one.
  2. 根据权利要求1所述具有多功能窗口的全天时成像探测器,其特征在于,所述四种滤光片分别为R+IR滤光片、G+IR滤光片、B+IR滤光片和IR滤光片,所述四个亚像素单元分别为R+IR亚像素单元、G+IR亚像素单元、B+IR亚像素单元和IR亚像素单元。The all-sky imaging detector with multifunctional windows according to claim 1, wherein the four kinds of filters are R+IR filter, G+IR filter, and B+IR filter. The four sub-pixel units are R+IR sub-pixel units, G+IR sub-pixel units, B+IR sub-pixel units, and IR sub-pixel units, respectively.
  3. 根据权利要求1或2所述具有多功能窗口的全天时成像探测器,其特征在于,每个亚像素单元分别由宽光谱敏感层、电极和集成电路构成。The all-sky imaging detector with multifunctional window according to claim 1 or 2, wherein each sub-pixel unit is composed of a broad spectrum sensitive layer, an electrode and an integrated circuit.
  4. 根据权利要求1所述具有多功能窗口的全天时成像探测器,其特征在于,所述微透镜阵列(3)的制备方法如下,首先将铜采用单点金刚石车削的方法制备成具有凹曲面的铜模板(6),然后在铜模板(6)上化学气相沉积宽光谱透射材料层(7),完成后降温脱去铜模板(6),所得宽光谱透射材料层(7)即包括微透镜阵列(3)和窗口本体(4)两部分,在窗口本体(4)的背面分区域镀制滤光片阵列(5),最终得到具有宽光谱透射性能的多功能窗口(1)。The all-day imaging detector with multifunctional window according to claim 1, characterized in that the preparation method of the microlens array (3) is as follows: firstly, the copper is prepared with a concave curved surface by a single point diamond turning method The copper template (6) is then chemically vapor deposited on the copper template (6), and then the broad-spectrum transmission material layer (7) is deposited. After completion, the temperature is lowered to remove the copper template (6). The resulting broad-spectrum transmission material layer (7) includes micro The lens array (3) and the window body (4) are two parts, and the filter array (5) is plated on the back of the window body (4) in different areas, and finally a multifunctional window (1) with broad spectrum transmission performance is obtained.
  5. 根据权利要求2所述具有多功能窗口的全天时成像探测器,其特征在于,所述探测器的探测方法如下,探测器白天工作时,R+IR滤光片、G+IR滤光片、B+IR滤光片所对应的亚像素单元探测信号减掉IR滤光片所对应的亚像素单元探测信号,得到R、G、B真彩色;探测器夜间工作时,R+IR滤光片、G+IR滤光片、B+IR滤光片和IR滤光片都可透射红外,它们下方的四个亚像素单元同时响应红外信号,探测器在夜间正常工作。The all-sky imaging detector with multifunctional windows according to claim 2, characterized in that, the detection method of the detector is as follows: when the detector works during the day, the R+IR filter and the G+IR filter , The detection signal of the sub-pixel unit corresponding to the B+IR filter subtracts the detection signal of the sub-pixel unit corresponding to the IR filter to obtain the true colors of R, G, B; when the detector works at night, the R+IR filter The infrared filter, G+IR filter, B+IR filter and IR filter can all transmit infrared. The four sub-pixel units below them respond to infrared signals simultaneously, and the detector works normally at night.
PCT/CN2019/120445 2019-03-05 2019-11-23 Full-day imaging detector with multi-functional window, and method for preparing same WO2020177400A1 (en)

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