WO2020155524A1 - Fully-mechanized coal-mining face mine shaft water resource utilization system and method for using same - Google Patents

Fully-mechanized coal-mining face mine shaft water resource utilization system and method for using same Download PDF

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Publication number
WO2020155524A1
WO2020155524A1 PCT/CN2019/091822 CN2019091822W WO2020155524A1 WO 2020155524 A1 WO2020155524 A1 WO 2020155524A1 CN 2019091822 W CN2019091822 W CN 2019091822W WO 2020155524 A1 WO2020155524 A1 WO 2020155524A1
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water
area
metal ion
sewage
treatment
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PCT/CN2019/091822
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French (fr)
Chinese (zh)
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黄艳利
李巍
翟文
李俊孟
董霁红
马昆
高华东
韩震
阮泽宇
郭亚超
扎伊泽小赛米尔
张吉雄
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中国矿业大学
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Priority to AU2019425968A priority Critical patent/AU2019425968B2/en
Publication of WO2020155524A1 publication Critical patent/WO2020155524A1/en
Priority to ZA2021/05490A priority patent/ZA202105490B/en

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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/28Treatment of water, waste water, or sewage by sorption
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/54Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using organic material
    • C02F1/56Macromolecular compounds

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  • the present invention relates to the field of mine wastewater recycling and utilization, in particular to a system for utilizing water resources in a fully mechanized coal mining face and a use method thereof.
  • the main pollutants in the goaf water and dustfall sewage at the working face are solid particles, suspended tiny particles and heavy metal ions. After the pollutants in the water are removed, the water in the goaf and the sewage from the production work surface are recycled, which not only saves water costs for mine production, but also alleviates the shortage of water resources.
  • the traditional sewage treatment system can only use the water pump to pump the water in the sump to the ground for treatment, which not only takes up a lot of land resources, but also needs to transport clean water to the well when using water, which increases transportation costs.
  • the accumulated water in the mine has not been used, and the accumulated water in the goaf has also brought potential pollution risks to the groundwater body. Therefore, there is a need for a water treatment system that can recycle the water accumulated in the goaf and the dust-fall sewage from the working face.
  • the purpose of the present invention is to provide a comprehensive mining face mine water resources utilization system and its use method, to collect the face sewage and the water in the goaf, and to purify the sewage into a clean water that meets the production water and water standards Water, to realize the utilization of water resources in fully mechanized mining face.
  • a system for utilizing water resources in a fully mechanized coal mining face includes a collection and purification system 5 for working face sewage and goaf water, a silt treatment system and a feedback control system, a domestic water delivery pipeline and a production water delivery pipeline.
  • the sewage and goaf water collection and purification system 5 includes a roadway floor drain 8, an isolation gangue metal grid 13, a horizontal partition plate 21, a vertical partition plate 23, and a filter metal grid 18.
  • One end of the roadway floor channel 8 is located At the stop line, the other end is located at the open cut.
  • the isolation gangue metal grid 13 is covered on the channel 8 of the roadway floor.
  • the horizontal divider 21 is installed horizontally in the tunnel floor of the roadway 8 to divide the tunnel floor of the roadway 8 into upper and lower layers.
  • the upper layer is the sewage collection area 17, and the lower layer is the physical filtration area 14, the suspended solids treatment area 15 and the metal ion treatment area 16. , And leave an opening near the end of the canal.
  • Two vertical partition plates 23 separate the lower layer of the roadway floor drain 8 into three areas: a physical filtration area 14, a suspended matter processing area 15, and a metal ion processing area 16.
  • a number of filter metal grids 18 with different pore diameters are vertically arranged in the physical filter zone 14;
  • a water pump 23 is provided in the physical filtration area 14, and the water pump 23 is used to pump the filtered water in the physical filtration area 14 into the suspended matter processing area into the suspended matter processing area 15.
  • Microporous filter membrane 19, PH value detector 26 and turbidity detector 25 are arranged in the suspended matter treatment area 15.
  • Ion treatment zone 16 A reverse osmosis membrane 20, a metal ion detector one 35 and a metal ion detector two 27 are arranged in the metal ion treatment zone 16.
  • the metal ion detector one 35 is arranged in the water inlet area of the metal ion treatment zone 16, and the metal ion detector two 27 It is arranged in the water outlet area of the metal ion treatment zone 16.
  • the production water outlet pipe 28 is in communication with the outlet area of the suspended solids treatment zone 15.
  • the domestic water storage pipe 29 communicates with the water outlet area of the metal ion treatment zone 16.
  • the sludge treatment system includes a sludge pumping pipe 32, a sludge pump 2 and a mechanical centrifuge 1. One end of the sludge pipe 32 is connected to the water inlet area of the suspended matter treatment area 15 and the water outlet area of the suspended matter treatment area 15 and metal ions through a branch pipe.
  • the water inlet area of the treatment zone 16 is connected, and the other end of the sludge pumping pipe is connected to the sludge pump 2 arranged within the stop line of the mining tunnel; the sludge pump 2 is connected to the mechanical centrifuge 1 through a pipeline, and the sewage discharged from the mechanical centrifuge 1 Enter the sewage collection area 17 through the return pipe 33.
  • the feedback control system includes an automatic console 3, a control line 34, electronically controlled valves and water pumps.
  • the automatic console 3 is arranged in the roadway stop line.
  • the automatic console 3 is connected to the electronic control valve 9 and the electronic control through the control line 34.
  • the detector 25 is connected; the metal ion detector 35 is used to determine the amount of starch xanthate added, the PH detector 26 and the turbidity detector 25 are used to determine whether the water quality meets the water standard, when the water quality in the outlet area does not meet the standard
  • the automatic console automatically closes the electronic control valve 2 10, opens the electronic control valve 4 12 and the water pump 3 4, so that the water in the suspended solids treatment area 15 is returned to the sewage collection area 17; the metal ion detector 2 27 is used to judge the water quality Whether it meets the water
  • the domestic water delivery pipeline is arranged in the underground tunnel.
  • One end of the domestic water delivery pipeline is connected to the water outlet area of the metal ion treatment zone 15 of the working face sewage and goaf water collection and purification system 5, and one end is connected to the domestic water facilities.
  • the production water transmission pipeline is arranged in the underground roadway, one end is connected to the water outlet area of the suspended solids treatment area 15 of the working face sewage and goaf water collection and purification system 5, and one end is respectively connected to the production water location of the underground working face.
  • the width W of the bottom of the roadway 8 is 1/5 of the width of the roadway, and the depth Among them, P is the amount of sewage discharged into the canal within 1 minute from the working face; Y is the amount of water flowing into the goaf within 1 minute.
  • the apertures of the five filter metal grids 18 are 10 6 um, 10 5 um, 10 4 um, 10 3 um, and 10 2 um in order along the water flow direction.
  • the pore size of the microporous filter membrane 19 is 10 um.
  • a method for using a system for utilizing water resources in a fully mechanized mining face including the steps:
  • sequence of adding the treatment agent in the suspended solids treatment zone 15 is:
  • the present invention has the following beneficial effects:
  • Figure 1 is a schematic diagram of the layout of the mine water resource utilization system at a fully mechanized mining face
  • Figure 2 is a vertical section view of the mine water resources utilization system of the fully mechanized mining face in Figure 1;
  • Figure 3 is a horizontal cross-sectional view of the upper layer of the tunnel floor drain in Figure 2;
  • Figure 4 is a horizontal cross-sectional view of the lower layer of the tunnel floor in Figure 2.
  • a comprehensive mining face mine water resource utilization system As shown in Figure 1-4, a comprehensive mining face mine water resource utilization system, a comprehensive mining face mine water resource utilization system, including working face sewage and goaf water collection and purification system 5. Silt Processing system and feedback control system, domestic water delivery pipeline and production water delivery pipeline.
  • the sewage and goaf water collection and purification system 5 includes a roadway floor drain 8, an isolation gangue metal grid 13, a horizontal partition plate 21, a vertical partition plate 23, and a filter metal grid 18.
  • One end of the roadway floor channel 8 is located At the stop line, the other end is located at the open cut.
  • the width W of the tunnel floor drain 8 is 1/5 of the width of the tunnel, and the depth Among them, P is the amount of sewage discharged into the canal within 1 minute from the working face; Y is the amount of water flowing into the goaf within 1 minute.
  • the isolation gangue metal grid 13 is covered on the channel 8 of the roadway floor.
  • the horizontal divider 21 is installed horizontally in the tunnel floor of the roadway 8 to divide the tunnel floor of the roadway 8 into upper and lower layers.
  • the upper layer is the sewage collection area 17, and the lower layer is the physical filtration area 14, the suspended solids treatment area 15 and the metal ion treatment area 16. , And leave an opening near the end of the canal.
  • Two vertical partition plates 23 separate the lower layer of the roadway floor drain 8 into three areas: a physical filtration area 14, a suspended matter processing area 15, and a metal ion processing area 16.
  • a number of filter metal grids 18 with different pore diameters are vertically arranged in the physical filter zone 14, and the pore diameter of the microporous filter membrane 19 is 10um.
  • a water pump 23 is provided in the physical filtration area 14, and the water pump 23 is used to pump the filtered water in the physical filtration area 14 into the suspended matter processing area into the suspended matter processing area 15.
  • Microporous filter membrane 19, PH value detector 26 and turbidity detector 25 are arranged in the suspended matter treatment area 15.
  • Ion treatment zone 16 A reverse osmosis membrane 20, a metal ion detector one 35 and a metal ion detector two 27 are arranged in the metal ion treatment zone 16.
  • the metal ion detector one 35 is arranged in the water inlet area of the metal ion treatment zone 16, and the metal ion detector two 27 It is arranged in the water outlet area of the metal ion treatment zone 16.
  • the production water outlet pipe 28 is in communication with the outlet area of the suspended solids treatment zone 15.
  • the domestic water storage pipe 29 communicates with the water outlet area of the metal ion treatment zone 16.
  • the sludge treatment system includes a sludge pumping pipe 32, a sludge pump 2 and a mechanical centrifuge 1. One end of the sludge pipe 32 is connected to the water inlet area of the suspended matter treatment area 15 and the water outlet area of the suspended matter treatment area 15 and metal ions through a branch pipe.
  • the water inlet area of the treatment zone 16 is connected, and the other end of the sludge pumping pipe is connected to the sludge pump 2 arranged within the stop line of the mining tunnel; the sludge pump 2 is connected to the mechanical centrifuge 1 through a pipeline, and the sewage discharged from the mechanical centrifuge 1 Enter the sewage collection area 17 through the return pipe 33.
  • the feedback control system includes an automatic console 3, a control line 34, electronically controlled valves, and water pumps.
  • the automatic console 3 is arranged in the roadway stop line.
  • the automatic console 3 is connected to the electronic control valve 9 and the electronic control valve through the control line 34.
  • Valve two 10 electronic control valve three 11, electronic control valve four 12, water pump three 4, water pump four 23, water pump five 24, metal ion detector one 35, metal ion detector two 27, PH value detector 26 and turbidity
  • the detector 25 is connected; the metal ion detector 35 is used to determine the amount of starch xanthate added, the PH detector 26 and the turbidity detector 25 are used to determine whether the water quality meets the water standard, when the water quality in the outlet area does not meet the standard
  • the automatic console (3) automatically closes the electronic control valve two 10, opens the electronic control valve four 12 and the water pump three 4, so that the water in the suspended solids treatment area 15 is returned to the sewage collection area 17; the metal ion detector two 27 is used In judging whether the water quality
  • the domestic water delivery pipeline is arranged in the underground tunnel.
  • One end of the domestic water delivery pipeline is connected to the water outlet area of the metal ion treatment zone 15 of the working face sewage and goaf water collection and purification system 5, and one end is connected to domestic water facilities.
  • the production water delivery pipeline is arranged in the underground roadway, one end is connected to the water outlet area of the suspended solids treatment area 15 of the working face sewage and goaf water collection and purification system 5, and one end is respectively connected to the production water location of the underground working face.
  • there are five filter metal grids 18, and the apertures of the five filter metal grids 18 are 10 6 um, 10 5 um, 10 4 um, 10 3 um, and 10 2 um in order along the water flow direction.
  • the method for treating sewage with the system for utilizing water resources in a fully mechanized mining face in embodiment 1, includes the following steps:
  • the sequence of adding the treatment agent in the suspended solids treatment zone 15 is:
  • the method of adding starch xanthate in the metal ion treatment zone 16 is:
  • starch xanthogenate to the metal ion treatment zone 16 through the starch xanthate injection pipe 31.
  • the molecular formula of the injected starch xanthate is It is cross-linked starch-O-CSS-Mg-SSC-cross-linked starch, the sulfur content of starch xanthate is 8.14%, and the quality of starch xanthate is
  • m d represents the quality of starch xanthogenate, g
  • t represents the time interval of starch xanthogenate, h
  • q 1 represents the flow of water in the metal ion treatment zone m 3 /hI; represents the ith Kind of metal ion
  • c i represents the concentration of metal ion in the i-th, g/m 3 .
  • the dust-reducing sewage of the working face After the dust-reducing sewage of the working face enters the collecting and purifying device 22 for the dust-reducing sewage of the working face and the accumulated water in the goaf, after treatment, it enters the working surface water tank through the production water conveying pipe to realize the recycling of working water.
  • Collecting and purifying the water in the goaf through the collection and purification device 22 for collecting and purifying dust and sewage from the working face and the water in the goaf not only basically eliminates the potential pollution risk of groundwater from the water in the goaf, but also realizes the accumulation of the goaf.
  • Water resource utilization Purifying sewage into production water and domestic water, transporting domestic water to the above-well domestic water facilities, and transporting the production water to underground production water points, which improves the efficiency of water purification and eases the shortage of water in the mine.
  • a longwall face, a lower elevation recovery roadway width 5m, the rear goaf water inflow Y is 0.20m 3 / min, the flow rate of waste water to the face P is 0.23m 3 / min, Mining
  • the metal ions contained in the gushing water in the empty area are Cu 2+ , Zn 2+ , Ni 2+ , Cr 2+ , among which the concentration of Cu 2+ is 10 mg/L, the concentration of Zn 2+ is 12 mg/L, and the concentration of Ni 2+ 6mg/L, the concentration of Cr 2+ is 5mg/L.
  • the width of the channel W is 1m, and the depth of the channel
  • the water canal is divided into upper and lower layers by a horizontal partition 21, and the water canal is divided into 3 areas by a vertical partition in the lower layer of the canal.
  • the upper layer of the canal is the sewage treatment area 17, and the lower layer of the canal is followed by the physical filtration area 14, the suspended solids treatment area 15, and the metal ion treatment area 16 along the water flow direction.
  • a starch xanthate injection pipe 31, a PAM and PAC flocculant injection pipe 30, and an acid-base regulator injection pipe 36 are arranged in the sewage collection area 17.
  • the outlet of the starch xanthate injection pipe 31 passes through the horizontal partition plate 21 and enters the metal ion treatment zone 16, and the outlet of the PAM and PAC flocculant injection pipe 30 passes through the horizontal partition plate 21 and enters the suspended matter treatment area 15.
  • the outlet of the regulator injection pipe 36 passes through the horizontal partition 21 and enters the suspended solids processing area 15.
  • the apertures of the metal grids along the water flow direction are 10 6 um, 10 5 um, 10 4 um, 10 3 um, and 10 2 um in order;
  • the filtered water in the physical filtration zone 14 is pumped into the suspended matter treatment zone by a water pump 23.
  • the metal ion treatment zone 16 is arranged with a reverse osmosis membrane 20, a metal ion detector 35 and a metal ion detector 27.
  • a metal ion detector 35 is arranged in the water inlet area of the metal ion treatment area 16, and a metal ion detector 27 is arranged in the water outlet area of the metal ion treatment area 16; the production water outlet pipe 28 and the suspended solids treatment area 15 The water outlet area is connected; the domestic water storage pipe 29 is connected to the water outlet area of the metal ion treatment zone 16.
  • a mechanical centrifuge 1, a sludge pump 2, an automatic console 3 and a water pump 4 are arranged in the stop line of the mining tunnel.
  • the sludge pump 2 is connected to the bottom of the metal ion treatment zone 16, the bottom of the water inlet zone of the suspended matter treatment zone 15 and the bottom of the water outlet zone of the suspended matter treatment zone 15 through a sludge suction pipe 32.
  • the sludge pump 2 is connected to the mechanical centrifuge through a pipeline.
  • the sewage discharged from the mechanical centrifuge 1 flows into the sewage collection area 17 through the return pipe 33.
  • the automatic console 3 is connected to the electronic control valve 9, electronic control valve 10, electronic control valve 11, electronic control valve 12, water pump 4, water pump 23, water pump 24, metal ion detector 35, metal ion detector 27, and Turbidity detector, turbidity detector and PH detector are connected.
  • the flow of water entering the metal ion treatment zone can be controlled by the water pump 24. Assuming that the flow entering the metal ion treatment zone 16 is 1/4 of the flow entering the suspended solids treatment zone 15, the quality of starch xanthate is put in each time
  • the domestic water delivery pipeline is arranged in the underground roadway, one end is connected to the water outlet area of the metal ion treatment zone 15 of the working face sewage and goaf water collection and purification system 5, and one end is connected to domestic water facilities.
  • the production water delivery pipeline is arranged in the underground roadway, one end is connected to the water outlet area of the suspended solids treatment area 15 of the working face sewage and goaf water collection and purification system 5, and one end is respectively connected to the downhole working face spray pump, water tank, and equipment condensation Use water, dust-proof water, ground coal washing water and other production water locations.

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  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Separation Of Suspended Particles By Flocculating Agents (AREA)
  • Water Treatment By Sorption (AREA)
  • Removal Of Specific Substances (AREA)

Abstract

A fully-mechanized coal-mining face mine shaft water resource utilization system, which is constituted by a coal-mining face wastewater and goaf area stagnant water collecting and purification system (5), a sludge treatment system, and a feedback control system. The mining-face wastewater and goaf area stagnant water collection and purification system (5) can be divided into four parts, namely a wastewater collecting area (17), a physical filtration area (14), a suspended matter treatment area (15), and a heavy metal ion treatment area (16). The sludge treatment system comprises a sludge suction pipe (32), a sludge pump (2), and a mechanical centrifuge (1). The feedback control system comprises an automatic control panel (3), a control line (34), an electric control valve, and a water pump. Also provided is a method for using the system, in which the pH of the suspended matter treatment area (15) is adjusted to 6-8, flocculants PAM and PAC are added, and starch xanthate is added to the heavy metal ion treatment area (16). This allows wastewater to be treated into industrial water and household water and achieves the goal of resource recovery and utilization of coal-mining face and goaf area wastewater.

Description

一种综采工作面矿井水资源化利用系统及其使用方法Mine water resources utilization system for fully mechanized mining face and its use method 技术领域Technical field
本发明涉及本发明涉及矿井废水回收利用领域,具体涉及一种综采工作面矿井水资源化利用系统及其使用方法。The present invention relates to the field of mine wastewater recycling and utilization, in particular to a system for utilizing water resources in a fully mechanized coal mining face and a use method thereof.
背景技术Background technique
近年来,煤炭开采中国东部逐步向中国中西部转移,而煤炭开采破坏了地下水的赋存环境,导致地下水资源流失,造成西部缺水地区水资源越发匮乏。长壁采煤法是我国主要的采煤方法,工作面推过后,采空区形成一个充满空隙的空间,岩层中和裂隙中的水容易向采空区聚集,形成采空区积水。In recent years, coal mining in eastern China has gradually shifted to central and western China, and coal mining has destroyed the environment where groundwater is stored, leading to the loss of groundwater resources, resulting in increasingly scarce water resources in water-scarce areas in the west. Longwall mining is the main coal mining method in our country. After the working face is pushed, a void-filled space is formed in the goaf. The water in the rock strata and fissures tends to gather in the goaf and form water accumulation in the goaf.
工作面推过后,采空区顶板和底板不可避免的会有裂隙出现,顶板和底板裂隙使得采空区和临近承压含水层连通,则承压含水层中的水会进入采空区,在采空区中形成积水。工作面在采煤过程中会产生大量的粉尘,工作面采煤机和工作面支架设有喷雾降尘装置,通过喷雾来降低空气中的粉尘,会产生大量的降尘污水。在西北部地区水资源较为匮乏,在矿井生产中不但消耗大量水资源而且对原有水资源造成了破坏。采空区积水及工作面降尘污水中的主要污染物为固体颗粒、悬浮微小颗粒物及重金属离子。将水中的污染物去除后,将采空区积水及生产工作面污水进行回收利用,不仅为矿井生产节约了用水成本,而且缓解了水资源匮乏的局面。传统的污水处理系统,只能通过水泵将水仓中的水抽上地面后进行处理,不仅占用大量土地资源,并且用水时还需将干净水输送到井下,增加了运输成本,采空区中的积水也未得到利用,采空区积水也给地下水体带来了潜在的污染风险。因此,需要一种能将采空区积水及工作面降尘污水进行资源化利用的水处理系统。After the working face is pushed, cracks will inevitably appear in the roof and floor of the goaf. The cracks between the roof and the floor connect the goaf with the adjacent confined aquifer, and the water in the confined aquifer will enter the goaf. Water forms in the goaf. A large amount of dust will be generated in the coal mining process at the working face. The coal shearer and the working face support are equipped with spray dust suppression devices. The dust in the air is reduced by spraying, which will generate a large amount of dust reduction sewage. In the northwestern region, water resources are relatively scarce, which not only consumes a lot of water resources in mine production, but also damages the original water resources. The main pollutants in the goaf water and dustfall sewage at the working face are solid particles, suspended tiny particles and heavy metal ions. After the pollutants in the water are removed, the water in the goaf and the sewage from the production work surface are recycled, which not only saves water costs for mine production, but also alleviates the shortage of water resources. The traditional sewage treatment system can only use the water pump to pump the water in the sump to the ground for treatment, which not only takes up a lot of land resources, but also needs to transport clean water to the well when using water, which increases transportation costs. The accumulated water in the mine has not been used, and the accumulated water in the goaf has also brought potential pollution risks to the groundwater body. Therefore, there is a need for a water treatment system that can recycle the water accumulated in the goaf and the dust-fall sewage from the working face.
发明内容Summary of the invention
本发明的目的在于提供一种综采工作面矿井水资源化利用系统及其使用方法,以将工作面污水及采空区积水收集起来,并将污水净化为符合生产用水和用水标准的干净水,实现综采工作面矿井水资源化利用。The purpose of the present invention is to provide a comprehensive mining face mine water resources utilization system and its use method, to collect the face sewage and the water in the goaf, and to purify the sewage into a clean water that meets the production water and water standards Water, to realize the utilization of water resources in fully mechanized mining face.
为实现上述发明目的,本发明的技术方案具体如下:In order to achieve the above-mentioned purpose of the invention, the technical scheme of the invention is specifically as follows:
一种综采工作面矿井水资源化利用系统,包括工作面污水及采空区积水收集净化系统5、淤泥处理系统和反馈控制系统、生活用水输送管路和生产用水输送管路。A system for utilizing water resources in a fully mechanized coal mining face includes a collection and purification system 5 for working face sewage and goaf water, a silt treatment system and a feedback control system, a domestic water delivery pipeline and a production water delivery pipeline.
工作面污水及采空区积水收集净化系统5包括巷道底板水渠8、隔离矸石金属栅13、水平分隔板21、竖直分隔板23和过滤金属栅18,巷道底板水渠8的一端位于在停采线处, 另一端位于开切眼处。隔离矸石金属栅13盖在巷道底板水渠8上。水平分隔板21水平安装在巷道底板水渠8内,将巷道底板水渠8分隔为上下两层,上层为污水收集区17,下层为物理过滤区14、悬浮物处理区15和金属离子处理区16,并在靠近水渠的端部留一开口。两块竖直分隔板23将巷道底板水渠8的下层分隔为物理过滤区14、悬浮物处理区15、金属离子处理区16三个区域。在物理过滤区14内竖直布置有若干不同孔径的过滤金属栅18;The sewage and goaf water collection and purification system 5 includes a roadway floor drain 8, an isolation gangue metal grid 13, a horizontal partition plate 21, a vertical partition plate 23, and a filter metal grid 18. One end of the roadway floor channel 8 is located At the stop line, the other end is located at the open cut. The isolation gangue metal grid 13 is covered on the channel 8 of the roadway floor. The horizontal divider 21 is installed horizontally in the tunnel floor of the roadway 8 to divide the tunnel floor of the roadway 8 into upper and lower layers. The upper layer is the sewage collection area 17, and the lower layer is the physical filtration area 14, the suspended solids treatment area 15 and the metal ion treatment area 16. , And leave an opening near the end of the canal. Two vertical partition plates 23 separate the lower layer of the roadway floor drain 8 into three areas: a physical filtration area 14, a suspended matter processing area 15, and a metal ion processing area 16. A number of filter metal grids 18 with different pore diameters are vertically arranged in the physical filter zone 14;
物理过滤区14内具有水泵一23,水泵一23用于将在物理过滤区14内过滤后的水抽入悬浮物处理区抽入悬浮物处理区15。悬浮物处理区15内布置有微孔滤膜19、PH值检测仪26和浑浊度检测仪25,悬浮物处理区15内具有水泵二24,水泵二24用以将净化后的水抽入金属离子处理区16。金属离子处理区域内16布置有反渗透膜20、金属离子检测仪一35和金属离子检测仪二27,金属离子检测仪一35布置在金属离子处理区16的入水区域,金属离子检测仪二27布置在金属离子处理区16的出水区域。A water pump 23 is provided in the physical filtration area 14, and the water pump 23 is used to pump the filtered water in the physical filtration area 14 into the suspended matter processing area into the suspended matter processing area 15. Microporous filter membrane 19, PH value detector 26 and turbidity detector 25 are arranged in the suspended matter treatment area 15. There is a water pump 24 in the suspended matter treatment area 15 for pumping purified water into the metal. Ion treatment zone 16. A reverse osmosis membrane 20, a metal ion detector one 35 and a metal ion detector two 27 are arranged in the metal ion treatment zone 16. The metal ion detector one 35 is arranged in the water inlet area of the metal ion treatment zone 16, and the metal ion detector two 27 It is arranged in the water outlet area of the metal ion treatment zone 16.
生产用水出水管28与悬浮物处理区15的出水区域连通。生活用水储水管29与金属离子处理区16的出水区域连通。淤泥处理系统包括抽淤泥管32、污泥泵2和机械离心机1,淤泥管32一端通过分叉管路分别与悬浮物处理区域15的入水区域、悬浮物处理区域15的出水区域和金属离子处理区16的入水区域相连,抽淤泥管的另一端与布置在回采巷道停采线以内的污泥泵2相连;污泥泵2通过管道与机械离心机1相连,机械离心机1排出的污水经回流管33进入污水收集区17。The production water outlet pipe 28 is in communication with the outlet area of the suspended solids treatment zone 15. The domestic water storage pipe 29 communicates with the water outlet area of the metal ion treatment zone 16. The sludge treatment system includes a sludge pumping pipe 32, a sludge pump 2 and a mechanical centrifuge 1. One end of the sludge pipe 32 is connected to the water inlet area of the suspended matter treatment area 15 and the water outlet area of the suspended matter treatment area 15 and metal ions through a branch pipe. The water inlet area of the treatment zone 16 is connected, and the other end of the sludge pumping pipe is connected to the sludge pump 2 arranged within the stop line of the mining tunnel; the sludge pump 2 is connected to the mechanical centrifuge 1 through a pipeline, and the sewage discharged from the mechanical centrifuge 1 Enter the sewage collection area 17 through the return pipe 33.
反馈控制系统包括自动控制台3、控制线34、电控阀门和水泵,自动控制台3布置在巷道停采线内,自动控制台3通过控制线34分别与与电控阀门一9、电控阀门二10、电控阀门三11、电控阀门四12、水泵三4、水泵四23、水泵五24、金属离子检测仪一35、金属离子检测仪二27、PH值检测仪26和浑浊度检测仪25相连;金属离子检测仪一35用于确定投加的淀粉黄原酸酯的量,PH检测仪26及浑浊度检测仪25用于判断水质是否达到用水标准,当出水区域水质不达标时,自动控制台自动关闭电控阀门二10,打开电控阀门四12和水泵三4,使悬浮物处理区内15的水回流至污水收集区17;金属离子检测仪二27用于判断水质是否达到用水标准,当出水区域水质不达标时,自动控制台自动关闭电控阀门一9,打开电控阀门三11和水泵三4,使金属离子处理区内16的水回流至污水收集区17。生活用水输送管路布置在井下巷道内,生活用水输送管路一端连接工作面污水及采空区积水收集净化系统5的金属离子处理区15的出水区域,一端连接生活用水设施。生产用水输送管路布置在井下巷道内,一端连接工作面污水及采空区积水收集净化系统5的悬浮物处理区15的出水区域,一端分别连接至井下工作面的生产用水地点。The feedback control system includes an automatic console 3, a control line 34, electronically controlled valves and water pumps. The automatic console 3 is arranged in the roadway stop line. The automatic console 3 is connected to the electronic control valve 9 and the electronic control through the control line 34. Valve two 10, electronic control valve three 11, electronic control valve four 12, water pump three 4, water pump four 23, water pump five 24, metal ion detector one 35, metal ion detector two 27, PH value detector 26 and turbidity The detector 25 is connected; the metal ion detector 35 is used to determine the amount of starch xanthate added, the PH detector 26 and the turbidity detector 25 are used to determine whether the water quality meets the water standard, when the water quality in the outlet area does not meet the standard When the time, the automatic console automatically closes the electronic control valve 2 10, opens the electronic control valve 4 12 and the water pump 3 4, so that the water in the suspended solids treatment area 15 is returned to the sewage collection area 17; the metal ion detector 2 27 is used to judge the water quality Whether it meets the water standard, when the water quality in the water outlet area does not meet the standard, the automatic console will automatically close the electronic control valve 9 and open the electronic control valve 311 and the water pump 34, so that the water in the metal ion treatment area 16 is returned to the sewage collection area 17 . The domestic water delivery pipeline is arranged in the underground tunnel. One end of the domestic water delivery pipeline is connected to the water outlet area of the metal ion treatment zone 15 of the working face sewage and goaf water collection and purification system 5, and one end is connected to the domestic water facilities. The production water transmission pipeline is arranged in the underground roadway, one end is connected to the water outlet area of the suspended solids treatment area 15 of the working face sewage and goaf water collection and purification system 5, and one end is respectively connected to the production water location of the underground working face.
进一步的,所述巷道底板水渠8的宽度W为巷道宽度的1/5,深度
Figure PCTCN2019091822-appb-000001
其中P为工作面1分钟内排入水渠内的污水量;Y为采空区1分钟内涌水量。
Further, the width W of the bottom of the roadway 8 is 1/5 of the width of the roadway, and the depth
Figure PCTCN2019091822-appb-000001
Among them, P is the amount of sewage discharged into the canal within 1 minute from the working face; Y is the amount of water flowing into the goaf within 1 minute.
进一步的,所述过滤金属栅18为5个,5个过滤金属栅18的孔径沿水流方向依次为10 6um、10 5um、10 4um、10 3um、10 2um。 Further, there are five filter metal grids 18, and the apertures of the five filter metal grids 18 are 10 6 um, 10 5 um, 10 4 um, 10 3 um, and 10 2 um in order along the water flow direction.
进一步的,所述微孔滤膜19的孔径为10um。Further, the pore size of the microporous filter membrane 19 is 10 um.
一种综采工作面矿井水资源化利用系统的使用方法,包括步骤:A method for using a system for utilizing water resources in a fully mechanized mining face, including the steps:
S1:工作面污水及采空区积水在重力作用下自流进入巷道底板水渠8,采空区积水及工作面污水经过隔离矸石金属栅13流入污水收集区17,然后流入物理过滤区14,经过物理分级过滤金属栅18的过滤后,经水泵23抽入悬浮物处理区域15;S1: Working face sewage and goaf water flows into the tunnel floor drain 8 under gravity, and the goaf water and working face sewage flow through the isolation gangue metal grid 13 into the sewage collection area 17, and then into the physical filtration area 14. After being filtered by the physical classification filter metal grid 18, it is pumped into the suspended solids treatment area 15 by the water pump 23;
S2:在悬浮物处理区15内加入酸碱调节剂,调节水中PH值到6~8后,加入PAM及PAC絮凝剂,固体悬浮物与PAM及PAC絮凝剂发生反应,生成沉淀,处理后的水经微孔滤膜19过滤后,部分水进入生产用水输送管28,部分水经水泵24抽入金属离子处理区16;S2: Add acid-base regulator in the suspended solids treatment zone 15, adjust the pH of the water to 6-8, add PAM and PAC flocculants, the solid suspended solids react with PAM and PAC flocculants to form a precipitate. After the water is filtered by the microporous membrane 19, part of the water enters the production water delivery pipe 28, and part of the water is pumped into the metal ion treatment zone 16 by the water pump 24;
S3:在重金属离子处理区16内,水中的重金属离子与淀粉黄原酸酯发生反应,生成沉淀,处理后的水经反渗透膜20后,进入生活用水输送管29。S3: In the heavy metal ion treatment zone 16, heavy metal ions in the water react with starch xanthate to form a precipitate, and the treated water enters the domestic water delivery pipe 29 after passing through the reverse osmosis membrane 20.
进一步的,在悬浮物处理区15内投加处理剂的顺序式是:Further, the sequence of adding the treatment agent in the suspended solids treatment zone 15 is:
B1:通过酸碱调节剂投放管36加入酸碱调节剂,调节水中PH值到6~8,B1: Add the acid-base regulator through the acid-base regulator injection pipe 36 to adjust the pH value of the water to 6-8,
B2:通过PAM及PAC絮凝剂投放管30加入PAC絮凝剂,最后加入PAM处理剂,在投入PAC和PAM絮凝剂的过程中关闭水泵23和水泵24;加入PAC絮凝剂的质量m pac=100q 2t 2,加入PAM絮凝剂的质量为m pam=2q 2t 2,式中,m pac为加入PAC絮凝剂的质量,g;m pam为加入PAM絮凝剂的质量,g;q 2为悬浮物处理区内的水流量,m 3/h;t 2为两次加入PAC絮凝剂的时间间隔,h。 B2: Add the PAC flocculant through the PAM and PAC flocculant injection pipe 30, and finally add the PAM treatment agent, turn off the water pump 23 and the water pump 24 during the process of adding PAC and PAM flocculant; the mass of the added PAC flocculant m pac =100q 2 t 2 , the mass of PAM flocculant added is m pam = 2q 2 t 2 , where m pac is the mass of PAC flocculant added, g; m pam is the mass of PAM flocculant added, g; q 2 is suspended matter The water flow in the treatment zone, m 3 /h; t 2 is the time interval between two additions of PAC flocculant, h.
进一步的,在金属离子处理区16投加淀粉黄原酸酯的方法为:Further, the method of adding starch xanthate in the metal ion treatment zone 16 is:
通过淀粉黄原酸酯投放管31向金属离子处理区16投加淀粉黄原酸酯,在投加淀粉黄原酸酯过程中,关闭水泵23和水泵24,所投放淀粉黄原酸酯的分子式为交联淀粉-O-CSS-Mg-SSC-交联淀粉,淀粉黄原酸酯含硫量为8.14%,投放淀粉黄原酸酯的质量为
Figure PCTCN2019091822-appb-000002
式中m d表示投放淀粉黄原酸酯的质量,g;t表示投放投放淀粉黄原酸酯的时间间隔,h;q 1表示金属离子处理区内水的流量m 3/h,i表示第i种金属离子;c i表示第i中金属离子的浓度,g/m 3
Add starch xanthogenate to the metal ion treatment zone 16 through the starch xanthate injection pipe 31. In the process of adding starch xanthate, turn off the water pump 23 and the water pump 24. The molecular formula of the injected starch xanthate is It is cross-linked starch-O-CSS-Mg-SSC-cross-linked starch, the sulfur content of starch xanthate is 8.14%, and the quality of starch xanthate is
Figure PCTCN2019091822-appb-000002
In the formula, m d represents the quality of starch xanthate, g; t represents the time interval of starch xanthate, h; q 1 represents the flow of water in the metal ion treatment zone m 3 /h, i represents the first i kind of metal ion; c i represents the concentration of metal ion in the i-th, g/m 3 .
与现有技术相比,本发明的有益效果:Compared with the prior art, the present invention has the following beneficial effects:
(1)工作面降尘污水进入工作面降尘污水及采空区积水收集净化装置后,经过处理后,通过生产用水输送管进入工作面水箱,实现了工作用水的循环利用;(1) After the working face dust-reducing sewage enters the working face dust-reducing sewage and the goaf water collection and purification device, after treatment, it enters the working surface water tank through the production water delivery pipe to realize the recycling of working water;
(2)通过工作面降尘污水及采空区积水收集净化装置收集采空区的积水并进行净化处理,不仅基本消除了采空区积水对地下水的潜在污染风险,而且实现了采空区积水的资源化利用。(2) Collecting and purifying the water in the goaf through the collection and purification device for dust and sewage from the working face and the water in the goaf, which not only basically eliminates the potential pollution risk of groundwater from the water in the goaf, but also realizes the goaf Resource utilization of stagnant water in the district.
(3)将污水净化为生产用水及生活用水,将生活用水输送到井上生活用水设施,将生产用水输送到井下生产用水点,提高了水的净化效率,缓解了矿井用水紧张的局面。(3) Purifying sewage into production water and domestic water, transporting domestic water to the above-well domestic water facilities, and transporting the production water to underground production water points, which improves the efficiency of water purification and eases the shortage of water in the mine.
附图说明Description of the drawings
图1是综采工作面矿井水资源化利用系统的布置示意图;Figure 1 is a schematic diagram of the layout of the mine water resource utilization system at a fully mechanized mining face;
图2是图1中的综采工作面矿井水资源化利用系统的竖直剖面图;Figure 2 is a vertical section view of the mine water resources utilization system of the fully mechanized mining face in Figure 1;
图3是图2中的巷道底板水渠上层的水平剖面图;Figure 3 is a horizontal cross-sectional view of the upper layer of the tunnel floor drain in Figure 2;
图4是图2中的巷道底板水渠下层的水平剖面图。Figure 4 is a horizontal cross-sectional view of the lower layer of the tunnel floor in Figure 2.
具体实施方式:detailed description:
下面参照附图对本发明做进一步描述。The present invention will be further described below with reference to the drawings.
实施例1Example 1
如图1-4所示,一种综采工作面矿井水资源化利用系统,一种综采工作面矿井水资源化利用系统,包括工作面污水及采空区积水收集净化系统5、淤泥处理系统和反馈控制系统、生活用水输送管路和生产用水输送管路。As shown in Figure 1-4, a comprehensive mining face mine water resource utilization system, a comprehensive mining face mine water resource utilization system, including working face sewage and goaf water collection and purification system 5. Silt Processing system and feedback control system, domestic water delivery pipeline and production water delivery pipeline.
工作面污水及采空区积水收集净化系统5包括巷道底板水渠8、隔离矸石金属栅13、水平分隔板21、竖直分隔板23和过滤金属栅18,巷道底板水渠8的一端位于在停采线处,另一端位于开切眼处。巷道底板水渠8的宽度W为巷道宽度的1/5,深度
Figure PCTCN2019091822-appb-000003
其中P为工作面1分钟内排入水渠内的污水量;Y为采空区1分钟内涌水量。
The sewage and goaf water collection and purification system 5 includes a roadway floor drain 8, an isolation gangue metal grid 13, a horizontal partition plate 21, a vertical partition plate 23, and a filter metal grid 18. One end of the roadway floor channel 8 is located At the stop line, the other end is located at the open cut. The width W of the tunnel floor drain 8 is 1/5 of the width of the tunnel, and the depth
Figure PCTCN2019091822-appb-000003
Among them, P is the amount of sewage discharged into the canal within 1 minute from the working face; Y is the amount of water flowing into the goaf within 1 minute.
隔离矸石金属栅13盖在巷道底板水渠8上。水平分隔板21水平安装在巷道底板水渠8内,将巷道底板水渠8分隔为上下两层,上层为污水收集区17,下层为物理过滤区14、悬浮物处理区15和金属离子处理区16,并在靠近水渠的端部留一开口。两块竖直分隔板23将巷道底板水渠8的下层分隔为物理过滤区14、悬浮物处理区15、金属离子处理区16三个区域。在物理过滤区14内竖直布置有若干不同孔径的过滤金属栅18,微孔滤膜19的孔径为10um。The isolation gangue metal grid 13 is covered on the channel 8 of the roadway floor. The horizontal divider 21 is installed horizontally in the tunnel floor of the roadway 8 to divide the tunnel floor of the roadway 8 into upper and lower layers. The upper layer is the sewage collection area 17, and the lower layer is the physical filtration area 14, the suspended solids treatment area 15 and the metal ion treatment area 16. , And leave an opening near the end of the canal. Two vertical partition plates 23 separate the lower layer of the roadway floor drain 8 into three areas: a physical filtration area 14, a suspended matter processing area 15, and a metal ion processing area 16. A number of filter metal grids 18 with different pore diameters are vertically arranged in the physical filter zone 14, and the pore diameter of the microporous filter membrane 19 is 10um.
物理过滤区14内具有水泵一23,水泵一23用于将在物理过滤区14内过滤后的水抽入悬浮物处理区抽入悬浮物处理区15。悬浮物处理区15内布置有微孔滤膜19、PH值检测仪26和浑浊度检测仪25,悬浮物处理区15内具有水泵二24,水泵二24用以将净化后的水抽入金属离子处理区16。金属离子处理区域内16布置有反渗透膜20、金属离子检测仪一35和金属离子检测仪二27,金属离子检测仪一35布置在金属离子处理区16的入水区域,金属离子检测仪二27布置在金属离子处理区16的出水区域。A water pump 23 is provided in the physical filtration area 14, and the water pump 23 is used to pump the filtered water in the physical filtration area 14 into the suspended matter processing area into the suspended matter processing area 15. Microporous filter membrane 19, PH value detector 26 and turbidity detector 25 are arranged in the suspended matter treatment area 15. There is a water pump 24 in the suspended matter treatment area 15 for pumping purified water into the metal. Ion treatment zone 16. A reverse osmosis membrane 20, a metal ion detector one 35 and a metal ion detector two 27 are arranged in the metal ion treatment zone 16. The metal ion detector one 35 is arranged in the water inlet area of the metal ion treatment zone 16, and the metal ion detector two 27 It is arranged in the water outlet area of the metal ion treatment zone 16.
生产用水出水管28与悬浮物处理区15的出水区域连通。生活用水储水管29与金属离子处理区16的出水区域连通。淤泥处理系统包括抽淤泥管32、污泥泵2和机械离心机1,淤泥管32一端通过分叉管路分别与悬浮物处理区域15的入水区域、悬浮物处理区域15的出水区域和金属离子处理区16的入水区域相连,抽淤泥管的另一端与布置在回采巷道停采线以内的污泥泵2相连;污泥泵2通过管道与机械离心机1相连,机械离心机1排出的污水经回流管33进入污水收集区17。The production water outlet pipe 28 is in communication with the outlet area of the suspended solids treatment zone 15. The domestic water storage pipe 29 communicates with the water outlet area of the metal ion treatment zone 16. The sludge treatment system includes a sludge pumping pipe 32, a sludge pump 2 and a mechanical centrifuge 1. One end of the sludge pipe 32 is connected to the water inlet area of the suspended matter treatment area 15 and the water outlet area of the suspended matter treatment area 15 and metal ions through a branch pipe. The water inlet area of the treatment zone 16 is connected, and the other end of the sludge pumping pipe is connected to the sludge pump 2 arranged within the stop line of the mining tunnel; the sludge pump 2 is connected to the mechanical centrifuge 1 through a pipeline, and the sewage discharged from the mechanical centrifuge 1 Enter the sewage collection area 17 through the return pipe 33.
反馈控制系统包括自动控制台3、控制线34、电控阀门和水泵,自动控制台3布置在巷道停采线内,自动控制台3通过控制线34分别与与电控阀门一9、电控阀门二10、电控阀门三11、电控阀门四12、水泵三4、水泵四23、水泵五24、金属离子检测仪一35、金属离子检测仪二27、PH值检测仪26和浑浊度检测仪25相连;金属离子检测仪一35用于确定投加的淀粉黄原酸酯的量,PH检测仪26及浑浊度检测仪25用于判断水质是否达到用水标准,当出水区域水质不达标时,自动控制台(3)自动关闭电控阀门二10,打开电控阀门四12和水泵三4,使悬浮物处理区内15的水回流至污水收集区17;金属离子检测仪二27用于判断水质是否达到用水标准,当出水区域水质不达标时,自动控制台自动关闭电控阀门一9,打开电控阀门三11和水泵三4,使金属离子处理区内16的水回流至污水收集区17。生活用水输送管路布置在井下巷道内,生活用水输送管路一端连接工作面污水及采空区积水收集净化系统5的金属离子处理区15的出水区域,一端连接生活用水设施。生产用水输送管路布置在井下巷道内,一端连接工作面污水及采空区积水收集净化系统5的悬浮物处理区15的出水区域,一端分别连接至井下工作面的生产用水地点。进一步的,所述过滤金属栅18为5个,5个过滤金属栅18的孔径沿水流方向依次为10 6um、10 5um、10 4um、10 3um、10 2um。 The feedback control system includes an automatic console 3, a control line 34, electronically controlled valves, and water pumps. The automatic console 3 is arranged in the roadway stop line. The automatic console 3 is connected to the electronic control valve 9 and the electronic control valve through the control line 34. Valve two 10, electronic control valve three 11, electronic control valve four 12, water pump three 4, water pump four 23, water pump five 24, metal ion detector one 35, metal ion detector two 27, PH value detector 26 and turbidity The detector 25 is connected; the metal ion detector 35 is used to determine the amount of starch xanthate added, the PH detector 26 and the turbidity detector 25 are used to determine whether the water quality meets the water standard, when the water quality in the outlet area does not meet the standard When the time, the automatic console (3) automatically closes the electronic control valve two 10, opens the electronic control valve four 12 and the water pump three 4, so that the water in the suspended solids treatment area 15 is returned to the sewage collection area 17; the metal ion detector two 27 is used In judging whether the water quality meets the water standard, when the water quality in the outlet area does not meet the standard, the automatic console will automatically close the electronic control valve 9 and open the electronic control valve 311 and water pump 34, so that the water in the metal ion treatment zone 16 is returned to the sewage Collection area 17. The domestic water delivery pipeline is arranged in the underground tunnel. One end of the domestic water delivery pipeline is connected to the water outlet area of the metal ion treatment zone 15 of the working face sewage and goaf water collection and purification system 5, and one end is connected to domestic water facilities. The production water delivery pipeline is arranged in the underground roadway, one end is connected to the water outlet area of the suspended solids treatment area 15 of the working face sewage and goaf water collection and purification system 5, and one end is respectively connected to the production water location of the underground working face. Further, there are five filter metal grids 18, and the apertures of the five filter metal grids 18 are 10 6 um, 10 5 um, 10 4 um, 10 3 um, and 10 2 um in order along the water flow direction.
实施例2Example 2
实施例1中的综采工作面矿井水资源化利用系统处理污水的方法,包括步骤:The method for treating sewage with the system for utilizing water resources in a fully mechanized mining face in embodiment 1, includes the following steps:
S1:工作面污水及采空区积水在重力作用下自流进入巷道底板水渠8,采空区积水及工作面污水经过隔离矸石金属栅13流入污水收集区17,然后流入物理过滤区14,经过物理 分级过滤金属栅18的过滤后,经水泵23抽入悬浮物处理区域15;S1: Working face sewage and goaf water flows into the tunnel floor drain 8 under gravity, and the goaf water and working face sewage flow through the isolation gangue metal grid 13 into the sewage collection area 17, and then into the physical filtration area 14. After being filtered by the physical classification filter metal grid 18, it is pumped into the suspended solids treatment area 15 by the water pump 23;
S2:在悬浮物处理区15内加入酸碱调节剂,调节水中PH值到6~8后,加入PAM及PAC絮凝剂,固体悬浮物与PAM及PAC絮凝剂发生反应,生成沉淀,处理后的水经微孔滤膜19过滤后,部分水进入生产用水输送管28,部分水经水泵24抽入金属离子处理区16;S2: Add acid-base regulator in the suspended solids treatment zone 15, adjust the pH of the water to 6-8, add PAM and PAC flocculants, the solid suspended solids react with PAM and PAC flocculants to form a precipitate. After the water is filtered by the microporous membrane 19, part of the water enters the production water delivery pipe 28, and part of the water is pumped into the metal ion treatment zone 16 by the water pump 24;
S3:在重金属离子处理区16内,水中的重金属离子与淀粉黄原酸酯发生反应,生成沉淀,处理后的水经反渗透膜20后,进入生活用水输送管29。S3: In the heavy metal ion treatment zone 16, heavy metal ions in the water react with starch xanthate to form a precipitate, and the treated water enters the domestic water delivery pipe 29 after passing through the reverse osmosis membrane 20.
其中,在悬浮物处理区15内投加处理剂的顺序式是:Among them, the sequence of adding the treatment agent in the suspended solids treatment zone 15 is:
B1:通过酸碱调节剂投放管36加入酸碱调节剂,调节水中PH值到6~8,B1: Add the acid-base regulator through the acid-base regulator injection pipe 36 to adjust the pH value of the water to 6-8,
B2:通过PAM及PAC絮凝剂投放管30加入PAC絮凝剂,最后加入PAM处理剂,在投入PAC和PAM絮凝剂的过程中关闭水泵23和水泵24;加入PAC絮凝剂的质量m pac=100q 2t 2,加入PAM絮凝剂的质量为m pam=2q 2t 2,式中,m pac为加入PAC絮凝剂的质量,g;m pam为加入PAM絮凝剂的质量,g;q 2为悬浮物处理区内的水流量,m 3/h;t 2为两次加入PAC絮凝剂的时间间隔,h。 B2: Add the PAC flocculant through the PAM and PAC flocculant injection pipe 30, and finally add the PAM treatment agent, turn off the water pump 23 and the water pump 24 during the process of adding PAC and PAM flocculant; the mass of the added PAC flocculant m pac =100q 2 t 2 , the mass of PAM flocculant added is m pam = 2q 2 t 2 , where m pac is the mass of PAC flocculant added, g; m pam is the mass of PAM flocculant added, g; q 2 is suspended matter The water flow in the treatment zone, m 3 /h; t 2 is the time interval between two additions of PAC flocculant, h.
在金属离子处理区16投加淀粉黄原酸酯的方法为:The method of adding starch xanthate in the metal ion treatment zone 16 is:
通过淀粉黄原酸酯投放管31向金属离子处理区16投加淀粉黄原酸酯,在投加淀粉黄原酸酯过程中,关闭水泵23和水泵24,所投放淀粉黄原酸酯的分子式为交联淀粉-O-CSS-Mg-SSC-交联淀粉,淀粉黄原酸酯含硫量为8.14%,投放淀粉黄原酸酯的质量为
Figure PCTCN2019091822-appb-000004
式中m d表示投放淀粉黄原酸酯的质量,g;t表示投放投放淀粉黄原酸酯的时间间隔,h;q 1表示金属离子处理区内水的流量m 3/hI;表示第i种金属离子;c i表示第i中金属离子的浓度,g/m 3
Add starch xanthogenate to the metal ion treatment zone 16 through the starch xanthate injection pipe 31. In the process of adding starch xanthate, turn off the water pump 23 and the water pump 24. The molecular formula of the injected starch xanthate is It is cross-linked starch-O-CSS-Mg-SSC-cross-linked starch, the sulfur content of starch xanthate is 8.14%, and the quality of starch xanthate is
Figure PCTCN2019091822-appb-000004
In the formula, m d represents the quality of starch xanthogenate, g; t represents the time interval of starch xanthogenate, h; q 1 represents the flow of water in the metal ion treatment zone m 3 /hI; represents the ith Kind of metal ion; c i represents the concentration of metal ion in the i-th, g/m 3 .
工作面降尘污水进入工作面降尘污水及采空区积水收集净化装置22后,经过处理后,通过生产用水输送管进入工作面水箱,实现了工作用水的循环利用。通过工作面降尘污水及采空区积水收集净化装置22收集采空区的积水并进行净化处理,不仅基本消除了采空区积水对地下水的潜在污染风险,而且实现了采空区积水的资源化利用。将污水净化为生产用水及生活用水,将生活用水输送到井上生活用水设施,将生产用水输送到井下生产用水点,提高了水的净化效率,缓解了矿井用水紧张的局面。After the dust-reducing sewage of the working face enters the collecting and purifying device 22 for the dust-reducing sewage of the working face and the accumulated water in the goaf, after treatment, it enters the working surface water tank through the production water conveying pipe to realize the recycling of working water. Collecting and purifying the water in the goaf through the collection and purification device 22 for collecting and purifying dust and sewage from the working face and the water in the goaf, not only basically eliminates the potential pollution risk of groundwater from the water in the goaf, but also realizes the accumulation of the goaf. Water resource utilization. Purifying sewage into production water and domestic water, transporting domestic water to the above-well domestic water facilities, and transporting the production water to underground production water points, which improves the efficiency of water purification and eases the shortage of water in the mine.
实施例3Example 3
本实施例以一走向长壁工作面,高程较低的回采巷道为例进行详细说明:This embodiment takes a mining roadway with a low elevation and a long-wall working face as an example for detailed description:
一走向长壁工作面,高程较低的回采巷道宽度为5m,工作面后方采空区的涌水量Y为0.20m 3/min,工作面所排污水的流量P为0.23m 3/min,采空区涌水中所含有的金属离子有 Cu 2+、Zn 2+、Ni 2+、Cr 2+,其中Cu 2+浓度为10mg/L,Zn 2+浓度为12mg/L,Ni 2+浓度为6mg/L,Cr 2+浓度为5mg/L。 A longwall face, a lower elevation recovery roadway width 5m, the rear goaf water inflow Y is 0.20m 3 / min, the flow rate of waste water to the face P is 0.23m 3 / min, Mining The metal ions contained in the gushing water in the empty area are Cu 2+ , Zn 2+ , Ni 2+ , Cr 2+ , among which the concentration of Cu 2+ is 10 mg/L, the concentration of Zn 2+ is 12 mg/L, and the concentration of Ni 2+ 6mg/L, the concentration of Cr 2+ is 5mg/L.
在高程较低的巷道底板内挖掘巷道底板水渠8。水渠的宽度W为1m,水渠的深度
Figure PCTCN2019091822-appb-000005
用水平分隔板21将水渠分隔为上下两层,在水渠下层用竖直分隔板讲水渠分隔为3个区域。水渠上层为污水处理区17,水渠下层沿水流方向依次为物理过滤区14、悬浮物处理区15和金属离子处理区16。
Excavate the tunnel floor drain 8 in the roadway floor with lower elevation. The width of the channel W is 1m, and the depth of the channel
Figure PCTCN2019091822-appb-000005
The water canal is divided into upper and lower layers by a horizontal partition 21, and the water canal is divided into 3 areas by a vertical partition in the lower layer of the canal. The upper layer of the canal is the sewage treatment area 17, and the lower layer of the canal is followed by the physical filtration area 14, the suspended solids treatment area 15, and the metal ion treatment area 16 along the water flow direction.
在污水收集区17内布置淀粉黄原酸酯投放管31、PAM及PAC絮凝剂投放管30和酸碱调节剂投放管36。淀粉黄原酸酯投放管31的出口穿过水平分隔板21进入金属离子处理区16,PAM及PAC絮凝剂投放管30的出口穿过水平分隔板21进入悬浮物处理区15,酸碱调节剂投放管36的出口穿过水平分隔21板进入悬浮物处理区15。在物理过滤区14内,竖直布置5个不同孔径的过滤金属栅18,沿水流方向金属栅的孔径依次为10 6um、10 5um、10 4um、10 3um、10 2um;在物理过滤区14内过滤后的水经水泵23抽入悬浮物处理区,悬浮物处理区15内布置有1个孔径为10um的微孔滤膜19、1个PH值检测仪26、和1个浑浊度检测仪25;在悬浮物处理区15净化后的水经水泵24抽入金属离子处理区16,金属离子处理区域内16布置有反渗透膜20、金属离子检测仪35和金属离子检测仪27,1个金属离子检测仪35布置在金属离子处理区16的入水区域,1个金属离子检测仪27布置在金属离子处理区16的出水区域;生产用水出水管28与悬浮物处理区15的出水区域连通;生活用水储水管29与金属离子处理区16的出水区域连通。 A starch xanthate injection pipe 31, a PAM and PAC flocculant injection pipe 30, and an acid-base regulator injection pipe 36 are arranged in the sewage collection area 17. The outlet of the starch xanthate injection pipe 31 passes through the horizontal partition plate 21 and enters the metal ion treatment zone 16, and the outlet of the PAM and PAC flocculant injection pipe 30 passes through the horizontal partition plate 21 and enters the suspended matter treatment area 15. The outlet of the regulator injection pipe 36 passes through the horizontal partition 21 and enters the suspended solids processing area 15. In the physical filter zone 14, five filter metal grids 18 with different apertures are vertically arranged, and the apertures of the metal grids along the water flow direction are 10 6 um, 10 5 um, 10 4 um, 10 3 um, and 10 2 um in order; The filtered water in the physical filtration zone 14 is pumped into the suspended matter treatment zone by a water pump 23. In the suspended matter treatment zone 15 are arranged a microporous membrane 19 with a pore size of 10um, a pH value detector 26, and one Turbidity detector 25; the purified water in the suspended solids treatment zone 15 is pumped into the metal ion treatment zone 16 by the water pump 24. The metal ion treatment zone 16 is arranged with a reverse osmosis membrane 20, a metal ion detector 35 and a metal ion detector 27. A metal ion detector 35 is arranged in the water inlet area of the metal ion treatment area 16, and a metal ion detector 27 is arranged in the water outlet area of the metal ion treatment area 16; the production water outlet pipe 28 and the suspended solids treatment area 15 The water outlet area is connected; the domestic water storage pipe 29 is connected to the water outlet area of the metal ion treatment zone 16.
在回采巷道的停采线内布置机械离心机1、污泥泵2、自动控制台3和水泵4。污泥泵2通过抽淤泥管32与金属离子处理区16的底部、悬浮物处理区15的入水区域的底部及悬浮物处理区15的出水区域的底部相连。污泥泵2与机械离心机通过管道相连。机械离心机1排出的污水经回流管33流入污水收集区17。自动控制台3通过控制线34与电控阀门9、电控阀门10、电控阀门11、电控阀门12、水泵4、水泵23、水泵24、金属离子检测仪35、金属离子检测仪27、浑浊度检测仪、浑浊度检测仪和PH检测仪相连。A mechanical centrifuge 1, a sludge pump 2, an automatic console 3 and a water pump 4 are arranged in the stop line of the mining tunnel. The sludge pump 2 is connected to the bottom of the metal ion treatment zone 16, the bottom of the water inlet zone of the suspended matter treatment zone 15 and the bottom of the water outlet zone of the suspended matter treatment zone 15 through a sludge suction pipe 32. The sludge pump 2 is connected to the mechanical centrifuge through a pipeline. The sewage discharged from the mechanical centrifuge 1 flows into the sewage collection area 17 through the return pipe 33. The automatic console 3 is connected to the electronic control valve 9, electronic control valve 10, electronic control valve 11, electronic control valve 12, water pump 4, water pump 23, water pump 24, metal ion detector 35, metal ion detector 27, and Turbidity detector, turbidity detector and PH detector are connected.
若每间隔1h投加一次,每次投入PAC絮凝剂的质量If dosing once every 1h, the quality of PAC flocculant every time
m pac=100q 2t 2=100×(P+Y)×1=100×(0.23+0.20)×60×1=2580g m pac =100q 2 t 2 =100×(P+Y)×1=100×(0.23+0.20)×60×1=2580g
每次投入PAM絮凝剂的质量The quality of each input of PAM flocculant
m pam=2q 2t 2=2×(P+Y)×60×1=41.6g m pam =2q 2 t 2 =2×(P+Y)×60×1=41.6g
进入金属离子处理区的水的流量能通过水泵24控制,假设进入金属离子处理区16的流量为进入悬浮物处理区15流量的1/4,则每次投入淀粉黄原酸酯的质量The flow of water entering the metal ion treatment zone can be controlled by the water pump 24. Assuming that the flow entering the metal ion treatment zone 16 is 1/4 of the flow entering the suspended solids treatment zone 15, the quality of starch xanthate is put in each time
Figure PCTCN2019091822-appb-000006
Figure PCTCN2019091822-appb-000006
生活用水输送管路布置在井下巷道内,一端连接工作面污水及采空区积水收集净化系统5的金属离子处理区15的出水区域,一端连接生活用水设施。生产用水输送管路布置在井下巷道内,一端连接工作面污水及采空区积水收集净化系统5的悬浮物处理区15的出水区域,一端分别连接至井下工作面喷雾泵及水箱、设备冷凝用水、防尘用水、地面洗煤用水等生产用水地点。The domestic water delivery pipeline is arranged in the underground roadway, one end is connected to the water outlet area of the metal ion treatment zone 15 of the working face sewage and goaf water collection and purification system 5, and one end is connected to domestic water facilities. The production water delivery pipeline is arranged in the underground roadway, one end is connected to the water outlet area of the suspended solids treatment area 15 of the working face sewage and goaf water collection and purification system 5, and one end is respectively connected to the downhole working face spray pump, water tank, and equipment condensation Use water, dust-proof water, ground coal washing water and other production water locations.

Claims (7)

  1. 一种综采工作面矿井水资源化利用系统,其特征在于,包括工作面污水及采空区积水收集净化系统(5)、淤泥处理系统和反馈控制系统、生活用水输送管路和生产用水输送管路;A system for the utilization of water resources in a fully mechanized coal mining face, which is characterized in that it includes a collection and purification system (5) for working face sewage and goaf water, a silt treatment system and a feedback control system, a domestic water delivery pipeline, and production water Delivery pipeline
    工作面污水及采空区积水收集净化系统(5)包括巷道底板水渠(8)、隔离矸石金属栅(13)、水平分隔板(21)、竖直分隔板(23)和过滤金属栅(18),巷道底板水渠(8)的一端位于在停采线处,另一端位于开切眼处;The collection and purification system (5) of working face sewage and goaf water collection and purification includes roadway floor drain (8), isolation gangue metal grid (13), horizontal partition plate (21), vertical partition plate (23) and filter metal Grid (18), one end of the roadway floor drain (8) is located at the stop line, and the other end is located at the cut hole;
    隔离矸石金属栅(13)盖在巷道底板水渠(8)上;The isolation gangue metal grid (13) is covered on the channel (8) of the roadway floor;
    水平分隔板(21)水平安装在巷道底板水渠(8)内,将巷道底板水渠(8)分隔为上下两层,上层为污水收集区(17),下层为物理过滤区(14)、悬浮物处理区(15)和金属离子处理区(16),并在靠近水渠的端部留一开口;The horizontal divider (21) is installed horizontally in the tunnel (8) of the roadway floor, and divides the tunnel (8) into the upper and lower layers. The upper layer is the sewage collection area (17), and the lower layer is the physical filtration area (14), suspension Waste treatment area (15) and metal ion treatment area (16), and leave an opening near the end of the canal;
    两块竖直分隔板(23)将巷道底板水渠(8)的下层分隔为物理过滤区(14)、悬浮物处理区(15)、金属离子处理区(16)三个区域;Two vertical partition plates (23) separate the lower layer of the tunnel floor drain (8) into three areas: physical filtration area (14), suspended matter treatment area (15), and metal ion treatment area (16);
    在物理过滤区(14)内竖直布置有若干不同孔径的过滤金属栅(18);物理过滤区(14)内具有水泵一(23),水泵一(23)用于将在物理过滤区(14)内过滤后的水抽入悬浮物处理区抽入悬浮物处理区(15);A number of filter metal grids (18) with different pore diameters are vertically arranged in the physical filter area (14); the physical filter area (14) has a water pump one (23), and water pump one (23) is used to connect the physical filter area ( 14) The internally filtered water is pumped into the suspended solids treatment area and pumped into the suspended solids treatment area (15);
    悬浮物处理区(15)内布置有微孔滤膜(19)、PH值检测仪(26)和浑浊度检测仪(25),悬浮物处理区(15)内具有水泵二(24),水泵二(24)用以将净化后的水抽入金属离子处理区(16);Microporous filter membrane (19), PH value detector (26) and turbidity detector (25) are arranged in the suspended matter treatment zone (15). The suspended matter treatment zone (15) is equipped with water pump two (24) and water pump Two (24) for pumping purified water into the metal ion treatment zone (16);
    金属离子处理区域内(16)布置有反渗透膜(20)、金属离子检测仪一(35)和金属离子检测仪二(27),金属离子检测仪一(35)布置在金属离子处理区(16)的入水区域,金属离子检测仪二(27)布置在金属离子处理区(16)的出水区域;A reverse osmosis membrane (20), a metal ion detector one (35) and a metal ion detector two (27) are arranged in the metal ion treatment area (16), and the metal ion detector one (35) is arranged in the metal ion treatment area ( In the water inlet area of 16), the metal ion detector two (27) is arranged in the water outlet area of the metal ion treatment area (16);
    生产用水出水管(28)与悬浮物处理区(15)的出水区域连通;The production water outlet pipe (28) is connected with the outlet area of the suspended solids treatment area (15);
    生活用水储水管(29)与金属离子处理区(16)的出水区域连通;The domestic water storage pipe (29) is connected with the water outlet area of the metal ion treatment zone (16);
    淤泥处理系统包括抽淤泥管(32)、污泥泵(2)和机械离心机(1),淤泥管(32)一端通过分叉管路分别与悬浮物处理区域(15)的入水区域、悬浮物处理区域(15)的出水区域和金属离子处理区(16)的入水区域相连,抽淤泥管的另一端与布置在回采巷道停采线以内的污泥泵(2)相连;污泥泵(2)通过管道与机械离心机(1)相连,机械离心机(1)排出的污水经回流管(33)进入污水收集区(17);The sludge treatment system includes a sludge suction pipe (32), a sludge pump (2) and a mechanical centrifuge (1). One end of the sludge pipe (32) is connected to the water inlet area and suspension area of the suspended matter treatment area (15) through a branch pipeline. The water outlet area of the waste treatment area (15) is connected to the water inlet area of the metal ion treatment area (16), and the other end of the sludge pumping pipe is connected to the sludge pump (2) arranged within the stop line of the mining roadway; the sludge pump ( 2) Connected to the mechanical centrifuge (1) through a pipeline, and the sewage discharged from the mechanical centrifuge (1) enters the sewage collection area (17) through the return pipe (33);
    反馈控制系统包括自动控制台(3)、控制线(34)、电控阀门和水泵,自动控制台(3)布置在巷道停采线内,自动控制台(3)通过控制线(34)分别与与电控阀门一(9)、电控阀门二(10)、电控阀门三(11)、电控阀门四(12)、水泵三(4)、水泵四(23)、 水泵五(24)、金属离子检测仪一(35)、金属离子检测仪二(27)、PH值检测仪(26)和浑浊度检测仪(25)相连;金属离子检测仪一(35)用于确定投加的淀粉黄原酸酯的量,PH检测仪(26)及浑浊度检测仪(25)用于判断水质是否达到用水标准,当出水区域水质不达标时,自动控制台(3)自动关闭电控阀门二(10),打开电控阀门四(12)和水泵三(4),使悬浮物处理区内(15)的水回流至污水收集区(17);金属离子检测仪二(27)用于判断水质是否达到用水标准,当出水区域水质不达标时,自动控制台(3)自动关闭电控阀门一(9),打开电控阀门三(11)和水泵三(4),使金属离子处理区内(16)的水回流至污水收集区(17);The feedback control system includes an automatic console (3), a control line (34), an electric control valve and a water pump. The automatic console (3) is arranged in the roadway stop line, and the automatic console (3) passes through the control line (34). And electronic control valve one (9), electronic control valve two (10), electronic control valve three (11), electronic control valve four (12), water pump three (4), water pump four (23), water pump five (24) ), metal ion detector one (35), metal ion detector two (27), PH value detector (26) and turbidity detector (25) are connected; metal ion detector one (35) is used to determine the dosage The amount of starch xanthate, the PH detector (26) and turbidity detector (25) are used to judge whether the water quality meets the water standard. When the water quality in the outlet area does not meet the standard, the automatic console (3) automatically turns off the electric control Valve two (10), open the electronic control valve four (12) and water pump three (4), so that the water in the suspended solids treatment area (15) is returned to the sewage collection area (17); the metal ion detector two (27) is used To judge whether the water quality meets the water standard, when the water quality in the water outlet area does not meet the standard, the automatic console (3) automatically closes the electronic control valve one (9), opens the electronic control valve three (11) and the water pump three (4) to make the metal ion The water in the treatment area (16) is returned to the sewage collection area (17);
    生活用水输送管路布置在井下巷道内,生活用水输送管路一端连接工作面污水及采空区积水收集净化系统(5)的金属离子处理区(15)的出水区域,一端连接生活用水设施;The domestic water delivery pipeline is arranged in the underground tunnel. One end of the domestic water delivery pipeline is connected to the water outlet area of the metal ion treatment area (15) of the working face sewage and goaf water collection and purification system (5), and one end is connected to domestic water facilities ;
    生产用水输送管路布置在井下巷道内,一端连接工作面污水及采空区积水收集净化系统(5)的悬浮物处理区(15)的出水区域,一端分别连接至井下工作面的生产用水地点。The production water delivery pipeline is arranged in the underground roadway, one end is connected to the water outlet area of the suspended solids treatment area (15) of the working face sewage and goaf water collection and purification system (5), and one end is connected to the production water of the underground working face. location.
  2. 根据权利要求1所述的一种综采工作面矿井水资源化利用系统,其特征在于,所述巷道底板水渠(8)的宽度W为巷道宽度的1/5,深度
    Figure PCTCN2019091822-appb-100001
    其中P为工作面1分钟内排入水渠内的污水量;Y为采空区1分钟内涌水量。
    The system for utilizing water resources in a fully mechanized mining face according to claim 1, characterized in that the width W of the bottom channel (8) of the roadway is 1/5 of the width of the roadway, and the depth
    Figure PCTCN2019091822-appb-100001
    Among them, P is the amount of sewage discharged into the canal within 1 minute from the working face; Y is the amount of water flowing into the goaf within 1 minute.
  3. 根据权利要求1所述的一种综采工作面矿井水资源化利用系统,其特征在于,所述过滤金属栅(18)为5个,5个过滤金属栅(18)的孔径沿水流方向依次为10 6um、10 5um、10 4um、10 3um、10 2um。 The system for utilizing water resources in a fully mechanized mining face according to claim 1, characterized in that there are five filter metal grids (18), and the apertures of the five filter metal grids (18) are sequentially along the water flow direction. It is 10 6 um, 10 5 um, 10 4 um, 10 3 um, and 10 2 um.
  4. 根据权利要求1所述的一种综采工作面矿井水资源化利用系统,其特征在于,所述微孔滤膜(19)的孔径为10um。The system for utilizing water resources in a fully mechanized coal mining face according to claim 1, wherein the pore size of the microporous filter membrane (19) is 10um.
  5. 一种综采工作面矿井水资源化利用系统的使用方法,其特征在于,包括步骤:A method for using a system for utilizing water resources in a fully mechanized mining face, which is characterized in that it comprises the steps:
    S1:工作面污水及采空区积水在重力作用下自流进入巷道底板水渠(8),采空区积水及工作面污水经过隔离矸石金属栅(13)流入污水收集区(17),然后流入物理过滤区(14),经过物理分级过滤金属栅(18)的过滤后,经水泵(23)抽入悬浮物处理区域(15);S1: Working face sewage and goaf water flows into the tunnel floor drain (8) under gravity, the goaf water and working face sewage flow into the sewage collection area (17) through the isolation gangue metal fence (13), and then Flow into the physical filtration area (14), after being filtered by the physical classification filter metal grid (18), it is pumped into the suspended solids treatment area (15) by the water pump (23);
    S2:在悬浮物处理区(15)内加入酸碱调节剂,调节水中PH值到6~8后,加入PAM及PAC絮凝剂,固体悬浮物与PAM及PAC絮凝剂发生反应,生成沉淀,处理后的水经微孔滤膜(19)过滤后,部分水进入生产用水输送管(28),部分水经水泵(24)抽入金属离子处理区(16);S2: Add acid-base regulator in the suspended solids treatment zone (15), adjust the pH of the water to 6-8, then add PAM and PAC flocculants, the solid suspended solids react with PAM and PAC flocculants to form a precipitate, and treat After the latter water is filtered by the microporous filter membrane (19), part of the water enters the process water delivery pipe (28), and part of the water is pumped into the metal ion treatment zone (16) by the water pump (24);
    S3:在重金属离子处理区(16)内,水中的重金属离子与淀粉黄原酸酯发生反应,生成沉淀,处理后的水经反渗透膜(20)后,进入生活用水输送管(29)。S3: In the heavy metal ion treatment zone (16), heavy metal ions in the water react with starch xanthogenate to form a precipitate, and the treated water enters the domestic water delivery pipe (29) after passing through the reverse osmosis membrane (20).
  6. 根据权利要求5所述的方法,其特征在于,在悬浮物处理区(15)内投加处理剂的顺序式是:The method according to claim 5, characterized in that the sequence of adding the treatment agent in the suspended solids treatment zone (15) is:
    B1:通过酸碱调节剂投放管(36)加入酸碱调节剂,调节水中PH值到6~8,B1: Add the acid-base regulator through the acid-base regulator feed pipe (36) to adjust the pH value of the water to 6-8,
    B2:通过PAM及PAC絮凝剂投放管(30)加入PAC絮凝剂,最后加入PAM处理剂,在投入PAC和PAM絮凝剂的过程中关闭水泵(23)和水泵(24);B2: Add PAC flocculant through the PAM and PAC flocculant injection pipe (30), and finally add the PAM treatment agent, turn off the water pump (23) and water pump (24) during the process of adding PAC and PAM flocculant;
    加入PAC絮凝剂的质量m pac=100q 2t 2,加入PAM絮凝剂的质量为m pam=2q 2t 2,式中,m pac为加入PAC絮凝剂的质量,g;m pam为加入PAM絮凝剂的质量,g;q 2为悬浮物处理区内的水流量,m 3/h;t 2为两次加入PAC絮凝剂的时间间隔,h。 The mass of PAC flocculant added is m pac =100q 2 t 2 , the mass of PAM flocculant added is m pam =2q 2 t 2 , where m pac is the mass of PAC flocculant added, g; m pam is the addition of PAM flocculation The mass of the agent, g; q 2 is the water flow in the suspended solids treatment zone, m 3 /h; t 2 is the time interval between two additions of PAC flocculant, h.
  7. 根据权利要求5所述的方法,其特征在于,在金属离子处理区(16)投加淀粉黄原酸酯的方法为:The method according to claim 5, characterized in that the method of adding starch xanthate in the metal ion treatment zone (16) is:
    通过淀粉黄原酸酯投放管(31)向金属离子处理区(16)投加淀粉黄原酸酯,在投加淀粉黄原酸酯过程中,关闭水泵(23)和水泵(24),所投放淀粉黄原酸酯的分子式为交联淀粉-O-CSS-Mg-SSC-交联淀粉,淀粉黄原酸酯含硫量为8.14%,投放淀粉黄原酸酯的质量为
    Figure PCTCN2019091822-appb-100002
    式中m d表示投放淀粉黄原酸酯的质量,g;t表示投放投放淀粉黄原酸酯的时间间隔,h;q 1表示金属离子处理区内水的流量m 3/h;i表示第i种金属离子;c i表示第i中金属离子的浓度,g/m 3
    Add starch xanthogenate to the metal ion treatment zone (16) through the starch xanthate injection tube (31). During the addition of starch xanthate, turn off the water pump (23) and the water pump (24), so The molecular formula of starch xanthogenate is cross-linked starch-O-CSS-Mg-SSC-cross-linked starch, the sulfur content of starch xanthate is 8.14%, and the quality of starch xanthate is
    Figure PCTCN2019091822-appb-100002
    In the formula, m d represents the quality of starch xanthate, g; t represents the time interval of starch xanthate, h; q 1 represents the flow of water in the metal ion treatment zone m 3 /h; i represents the first i kind of metal ion; c i represents the concentration of metal ion in the i-th, g/m 3 .
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