WO2020130311A1 - Food waste treatment apparatus for improving biogas productivity, and food waste treatment method using same - Google Patents

Food waste treatment apparatus for improving biogas productivity, and food waste treatment method using same Download PDF

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Publication number
WO2020130311A1
WO2020130311A1 PCT/KR2019/013463 KR2019013463W WO2020130311A1 WO 2020130311 A1 WO2020130311 A1 WO 2020130311A1 KR 2019013463 W KR2019013463 W KR 2019013463W WO 2020130311 A1 WO2020130311 A1 WO 2020130311A1
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Prior art keywords
food waste
processing unit
food
catalyst
unit
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PCT/KR2019/013463
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French (fr)
Korean (ko)
Inventor
이진형
구양모
김현욱
Original Assignee
한국세라믹기술원
서울시립대학교 산학협력단
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Publication of WO2020130311A1 publication Critical patent/WO2020130311A1/en

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09BDISPOSAL OF SOLID WASTE
    • B09B3/00Destroying solid waste or transforming solid waste into something useful or harmless
    • B09B3/40Destroying solid waste or transforming solid waste into something useful or harmless involving thermal treatment, e.g. evaporation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F27/00Mixers with rotary stirring devices in fixed receptacles; Kneaders
    • B01F27/80Mixers with rotary stirring devices in fixed receptacles; Kneaders with stirrers rotating about a substantially vertical axis
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B02CRUSHING, PULVERISING, OR DISINTEGRATING; PREPARATORY TREATMENT OF GRAIN FOR MILLING
    • B02CCRUSHING, PULVERISING, OR DISINTEGRATING IN GENERAL; MILLING GRAIN
    • B02C17/00Disintegrating by tumbling mills, i.e. mills having a container charged with the material to be disintegrated with or without special disintegrating members such as pebbles or balls
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B02CRUSHING, PULVERISING, OR DISINTEGRATING; PREPARATORY TREATMENT OF GRAIN FOR MILLING
    • B02CCRUSHING, PULVERISING, OR DISINTEGRATING IN GENERAL; MILLING GRAIN
    • B02C17/00Disintegrating by tumbling mills, i.e. mills having a container charged with the material to be disintegrated with or without special disintegrating members such as pebbles or balls
    • B02C17/007Disintegrating by tumbling mills, i.e. mills having a container charged with the material to be disintegrated with or without special disintegrating members such as pebbles or balls specially adapted for disintegrating refuse
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B02CRUSHING, PULVERISING, OR DISINTEGRATING; PREPARATORY TREATMENT OF GRAIN FOR MILLING
    • B02CCRUSHING, PULVERISING, OR DISINTEGRATING IN GENERAL; MILLING GRAIN
    • B02C18/00Disintegrating by knives or other cutting or tearing members which chop material into fragments
    • B02C18/06Disintegrating by knives or other cutting or tearing members which chop material into fragments with rotating knives
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B02CRUSHING, PULVERISING, OR DISINTEGRATING; PREPARATORY TREATMENT OF GRAIN FOR MILLING
    • B02CCRUSHING, PULVERISING, OR DISINTEGRATING IN GENERAL; MILLING GRAIN
    • B02C19/00Other disintegrating devices or methods
    • B02C19/18Use of auxiliary physical effects, e.g. ultrasonics, irradiation, for disintegrating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09BDISPOSAL OF SOLID WASTE
    • B09B3/00Destroying solid waste or transforming solid waste into something useful or harmless
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/20Waste processing or separation
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/52Mechanical processing of waste for the recovery of materials, e.g. crushing, shredding, separation or disassembly

Definitions

  • the present invention relates to a food waste treatment apparatus and a food waste treatment method using the same, and more specifically, a food waste treatment apparatus capable of improving biogas productivity by simultaneously performing chemical treatment and physical treatment, and food waste using the same. It relates to a processing method.
  • food waste refers to agricultural, water, and livestock waste generated during the production, distribution, processing, and cooking of food, and food waste that is left behind after being eaten and left at home or restaurants.
  • biogas is produced using food wastes by applying physical, chemical, or biological conversion technology.
  • the biogas produced in this way is an energy source that can be replaced with fossil energy.
  • the Korean government has established the 4th Basic Renewable Energy Plan as a policy, and is improving the energy supply rate through efficient use of food waste.
  • 11 domestic food biogasification facilities (1,788 tons/day), 9 wastewater biogasification facilities (1,860 tons/day), 3 sewage sludge solid fuel facilities (2,770 tons/day), combined biogasification facilities 6
  • the additional locations (1,140 tons/day) were additionally expanded to make 33% of the available volume energy-enable at the time of installation completion (Korea Development Institute, 2013).
  • food waste is an energy source, but has high energy density but low solubility, making it difficult to apply it to fermentation processes.
  • food wastes have low fluidity during the winter months, and oxidative stability is poor, resulting in poor supply stability and economics.
  • Republic of Korea Patent Publication No. 10-2009-013483 relates to a waste water treatment apparatus and method for recycling and using food biogas
  • Republic of Korea Patent No. 10-1892241 relates to an oil separation device, to produce biogas using food waste Technology is being presented.
  • the present invention is to solve the above problems, to increase the availability of food waste, and to provide a food waste disposal apparatus and a food waste disposal method using the same, which can improve the productivity of biogas using food waste.
  • the above object is a processing unit for mixing and crushing the food waste supplied to the interior;
  • a food waste supply unit connected to an upper end of the processing unit to supply food waste to the processing unit;
  • a catalyst supply unit connected to the upper end of the processing unit to supply a catalyst for decomposing food waste into the processing unit;
  • It is connected to the lower side of the processing unit, the discharge unit for discharging the decomposed food waste to the outside with a screw therein; includes, the processing unit, a mixer provided inside the processing unit; And a temperature control device connected to the lower portion of the processing unit to control the temperature inside the processing unit.
  • the mixer the rotating shaft formed in the longitudinal direction inside the processing unit; And a plurality of rotating blades provided on the rotating shaft in a direction perpendicular to the rotating shaft, and the rotating shaft may rotate at a speed of 50 to 450 rpm.
  • the processing unit includes an ultrasonic generator provided inside the processing unit.
  • the processing unit may include a ball that pulverizes food wastes by performing translational or rotational movement with a stirrer, and the diameter of such a ball may be 1 to 10 mm.
  • the processing unit may include a heater connected to the lower portion to control the temperature inside the processing unit.
  • the catalyst is preferably an alkali solvent containing at least one selected from the group consisting of ammonia, sodium hydroxide, calcium hydroxide, potassium hydroxide, phosphorus hydroxide and sodium sulfide.
  • the screw provided in the discharge portion may have a diameter on one side larger than the diameter on the other side.
  • the discharge unit may include a backflow prevention member for preventing food waste transported from the processing unit from flowing back to the treatment unit, wherein the backflow prevention member includes a circular member having a plurality of holes; And a gate that opens only in one direction.
  • the object is, food waste supply step of supplying food waste to the inside of the processing unit; A catalyst supply step of supplying a catalyst for decomposing food waste into the processing unit; A food waste treatment step of mixing and pulverizing the food waste and catalyst supplied to the processing unit using a mixer; An ultrasonic treatment step of decomposing food wastes supplied into the processing unit using an ultrasonic generator; And a food waste disposal step of discharging the food waste transferred from the processing unit to the outside using a screw.
  • the catalyst supplied in the catalyst supply step is preferably an alkali solvent containing at least one selected from the group consisting of ammonia, sodium hydroxide, calcium hydroxide, potassium hydroxide, phosphorus hydroxide and sodium sulfide.
  • the mixer provided inside the processing unit is a rotating shaft formed in the longitudinal direction inside the processing unit; And a plurality of rotating blades provided on the rotating shaft in a direction perpendicular to the rotating shaft, and the rotating shaft may rotate at a speed of 50 to 450 rpm.
  • the food waste may be crushed using a ball that is translated or rotated by a stirrer, and the diameter of the ball may be 1 to 10 mm.
  • the food waste treatment step may be performed at a temperature of 60 ⁇ 150 °C.
  • the diameter of one side may be larger than the diameter of the other side.
  • the present invention it is possible to improve the productivity of biogas by pre-treating food wastes using both chemical and physical methods at the same time, and continuous treatment is possible by re-injecting untreated food wastes as much as the amount of food wastes to be treated.
  • FIG. 1 is a view schematically showing a food waste disposal apparatus according to an embodiment of the present invention.
  • FIG. 2 is a view schematically showing a food waste treatment apparatus according to another embodiment of the present invention.
  • 3 is a view for explaining the principle of the wear and tear grinding method.
  • part in the specification means a unit or block that performs a specific function.
  • each step the identification numbers (first, second, etc.) are used for convenience of explanation.
  • the identification numbers do not describe the order of each step, and each step does not explicitly describe a specific order in the context. It may be carried out differently from the order specified above. That is, each step may be performed in the same order as specified, or may be performed substantially simultaneously, or in the reverse order.
  • the food waste treatment apparatus 100 includes a processing unit 10 for stirring and pulverizing the food waste to be supplied therein; A food waste supply unit 20 connected to the upper end of the processing unit 10 to supply food waste to the processing unit 10; A catalyst supply unit 30 connected to an upper end of the processing unit 10 to supply a catalyst for decomposing food waste into the processing unit 10; And a discharge unit 40 connected to the lower end side of the processing unit 10 and having a screw 41 therein to discharge the decomposed food waste to the outside.
  • the present invention can supply food catalysts and catalysts capable of decomposing food wastes together, and then mix and crush them to chemically and physically treat food wastes, thereby increasing availability.
  • food waste is continuously supplied and crushed and decomposed to some extent, it is accumulated in the processing unit 10 and when sufficiently accumulated, it is discharged to the discharge unit 40 formed at the bottom by the accumulated pressure. ) By effectively discharging the processed food waste to the outside, it has the effect of continuously processing the food waste.
  • the food waste refers to both the state before the initial crushing or decomposition, as well as the state after the crushing or decomposition by the catalyst and the mixer 11, and the treatment means through a combined digestion process to mix and ferment from food and waste. It means pre-processing food waste before obtaining biogas.
  • the processing unit 10 is provided with a space and a mixer 11 to accommodate food wastes therein to mix and crush the food wastes supplied to the interior, the upper portion is a supply unit for supplying food wastes 20 and the catalyst supply unit 30 for supplying the catalyst, the lower one side is connected to the discharge unit 40 for discharging the processed food waste to the outside, the overall appearance may be a cylindrical shape, but is limited to this It is not.
  • the mixer 11 is provided inside the processing unit 10 to mix and pulverize food wastes and catalysts supplied and pulverizes, a rotating shaft 12 formed in the longitudinal direction inside the processing unit 10; And a plurality of rotating blades 13 formed on the rotating shaft 12 in a direction perpendicular to the rotating shaft 12.
  • the rotating shaft 12 is connected to the motor and can rotate clockwise or counterclockwise, and it is preferable to rotate at a speed of 50 to 450 rpm for efficient stirring and grinding, and more preferably to rotate at a speed of 150 to 350 rpm.
  • the rotary blade 13 may have a cylindrical shape, but is not limited thereto, and may be manufactured in various shapes according to the purpose.
  • the treatment unit 10 may use a wear and tear grinding method to effectively treat food waste.
  • the processing unit 10 may include a ball 14 that performs translational or rotational movement by the mixer 11 therein.
  • the ball 14 a ball manufactured using a variety of known materials can be used, but it is preferable to use a steel ball, a zirconia ball (ZrO 2 ) ball, or an alumina ball.
  • Do. 3 is a view for explaining the principle of the abrasion and crushing method, and specifically described with reference to this, induces a gradient of force in the processing unit 10 by the mixer 11, and a gradient of force is formed in the processing unit 10
  • the principle is to crush the food waste supplied by inducing friction between the balls (14). Physical treatment may be performed using an attrition mill method, and chemical treatment may be performed by mixing food waste and a catalyst.
  • the rotating shaft 12 of the mixer 11 is preferably rotated at a speed of 50 ⁇ 450rpm, more preferably rotated at a speed of 150 ⁇ 350rpm.
  • the rotational speed is less than 50 rpm, the grinding efficiency is insufficient due to insufficient grinding, and when it exceeds 450 rpm, a high-performance motor is required, and it is difficult to obtain an additional grinding effect, which is uneconomical.
  • the diameter of the ball 14 is preferably 1 to 10 mm, more preferably 3 to 10 mm. If it is less than 1 mm, it cannot have a sufficient crushing effect by the ball 14, and if it exceeds 10 mm, there is a fear that the ball 14 may be damaged by collision between the balls 14 when crushing food waste.
  • the processing unit 10 may include a heater 50 that can adjust the temperature inside the lower portion.
  • a heater 50 that can adjust the temperature inside the lower portion.
  • the processing unit 10 may include a heat medium oil circulation device (not shown) in place of the heater 50.
  • the heat medium oil circulation device is a heat medium oil heating tank that stores and heats the heat medium oil as it heats the heat medium oil and circulates it to supply heat to the processing unit 10;
  • a heat medium oil circulation pump circulating the heat medium oil; And it is formed in a form surrounding the outside of the processing unit 10, a jacket pipe to transfer the heat medium oil; may include.
  • the heating medium oil heating tank may include a heater rod for heating the heating medium oil therein.
  • heat medium oil various heat medium oils known in the art can be used, but as an alkylbenzene-based synthetic heat medium oil (SERIOLA KF 2120, S-OIL Total Lubricant Co., Ltd.), the temperature range of use is preferably -10 to 350°C.
  • the heat medium oil is heated by a heater rod and flows along the inside of the jacket pipe surrounding the process unit 10 by a heat medium oil circulation pump to supply heat to the process unit 10.
  • the processing unit 10 may include an ultrasonic generator 70 provided inside the processing unit.
  • the ultrasonic generator 70 is intended to decompose by vibrating the food wastes supplied into the processing unit 10 using ultrasonics.
  • ultrasonic Ultrasonic
  • it is a phenomenon in which micro-bubble groups are generated and disappeared due to the large pressure change of ultrasonic waves, which is accompanied by very large pressure.
  • This pressure occurs for a short period of time from hundredths of a second to several thousandths of a second, the effect of decomposing food waste is maximized, increasing the availability of food waste.
  • the ultrasonic generator 70 may be installed on the lower or sidewall of the processing unit 10, may be an ultrasonic generator that generates sound waves of 20,000 Hz or more, and preferably ultrasonic waves of 25,000 to 40,000 Hz It can be a generator.
  • the food waste supply unit 20 is connected to the upper end of the treatment unit 10, the other side is connected to the food waste storage tank (not shown), the food waste stored in the food waste storage tank processing unit 10 ) It can be supplied inside.
  • the overall shape may be a cylindrical shape, but is not limited to this, and any shape that can supply food waste to the processing unit 10 is irrelevant.
  • a shutter (not shown) may be provided inside the food waste supply unit 20. That is, when the shutter is opened, food and beverage waste can be supplied from the food and beverage waste supply unit 20 to the processing unit 10, and when the shutter is closed, the supply of food and beverage waste can be stopped.
  • the condition of the food waste to be supplied is not particularly limited. That is, it may be in a solid state or a slurry state.
  • the catalyst supply unit 30 is connected to the upper end of the processing unit 10, the other side is connected to the catalyst storage tank to supply the catalyst stored in the catalyst storage tank (not shown) into the processing unit 10 Can.
  • the catalyst supply unit 30 may be manufactured in various shapes.
  • a shutter (not shown) may be provided inside the catalyst supply unit 30. That is, when the shutter is opened, the catalyst can be supplied from the catalyst supply unit 30 to the processing unit 10, and when the shutter is closed, the catalyst supply can be stopped.
  • an alkali solvent may be used, and for example, an alkali solvent containing at least one selected from the group consisting of ammonia, sodium hydroxide, calcium hydroxide, potassium hydroxide, phosphorus hydroxide, and sodium sulfide may be used.
  • an alkali solvent containing at least one selected from the group consisting of ammonia, sodium hydroxide, calcium hydroxide, potassium hydroxide, phosphorus hydroxide, and sodium sulfide may be used.
  • Such a catalyst changes the pH inside the processing unit 10 to melt the oil contained in the food waste, thereby increasing the availability of the food waste.
  • the shutter control unit may control the opening and closing speed of the shutter. For example, when the opening time of the shutter is set at intervals of 10 seconds, the shutters provided inside the food waste supply unit 20 and the catalyst supply unit 30 are opened at one point, closed, and then opened again after 10 seconds to open the food waste. And a catalyst can be supplied into the processing unit 10.
  • the shutter of the food waste supply unit 20 may be opened at 10 second intervals, and the shutter of the catalyst supply unit 30 may be opened at 20 second intervals.
  • the discharge unit 40 is provided with a screw 41 therein to discharge food wastes decomposed (pre-treated) by the treatment unit 10 to the outside, and be connected to one side of the lower end of the treatment unit 10 Can.
  • the discharge unit 40 becomes the discharge unit 40. It is preferably formed close to the floor height.
  • the screw 41 may use various types of screw 41.
  • a screw 41 having a uniform diameter may be used, a screw 41 having the smallest diameter may be used, and a screw 41 having an irregular diameter may be used.
  • the diameter of the screw 41 means the length to the end of the blade of the screw 41 around the rotation axis of the screw 41.
  • the screw 41 may be used in which the diameter of one side is larger than the diameter of the other side.
  • the diameter of one side adjacent to the processing unit 10 may be large, and the diameter of the other side distant from the processing unit 10 may be relatively small. That is, by forming the diameter of the screw 41 adjacent to the processing unit 10 larger than the diameter of the opposite side, the farther away from the processing unit 10, the better the driving force of the force is designed, so that food waste is not pushed by the screw 41 It can prevent clogging.
  • the discharge unit 40 may include a backflow prevention member 60 for preventing the food waste transported from the treatment unit 10 from flowing back to the treatment unit 10.
  • the backflow prevention member 60 can prevent the balls 14 from being introduced together with the crushed food waste.
  • the backflow prevention member 60 includes a circular member having a plurality of holes; And a gate that opens only in one direction.
  • the circular member having a plurality of holes may be a mesh network such as a mosquito net that is generally used.
  • the hole may be a circular hole, and the size of the hole is preferably formed to a size such that the pulverized food waste is passed, but the ball 14 cannot pass.
  • the hole diameter is preferably 0.3 to 1 mm.
  • the gate may be opened when food waste is moved from the treatment unit 10 to the discharge unit 40, and is not opened in the opposite direction.
  • the discharge unit 40 may include a connecting member 42.
  • 2 is a view schematically showing a food waste treatment apparatus 100 according to an embodiment of the present invention.
  • the connection member 42 is installed between the discharge unit 40 and the treatment unit 10 It is made to be able to move the food and beverage waste, it is preferable to be connected obliquely in the upward direction with respect to the treatment unit (10). For example, it may be connected to the processing unit 10 at an angle of 45 degrees.
  • the backflow prevention member 60 prevents the backflow of food waste, and prevents the inflow of the ball 14, but when the backflow prevention member 60 is damaged by a collision with the ball 14, the ball 14 It may be introduced, and thereby the screw 41 inside the discharge part 40 may be damaged.
  • the connecting member 42 when the connecting member 42 is formed, the food waste is pushed up to the discharge unit 40 by pressure, but the ball 14 is discharged due to the weight (average density of about 8 g/cm 3 , average weight of 4 g). It is restricted to move to the part 40.
  • the food waste treatment method includes a food waste supply step of supplying food waste to the processing unit 10; A catalyst supply step of supplying a catalyst for decomposing food waste into the processing unit 10; A food waste treatment step of mixing and pulverizing food waste and catalyst supplied to the processing unit 10 using a mixer 11; An ultrasonic treatment step of crushing the food waste supplied to the processing unit using an ultrasonic generator 70; And a food waste discharge step of discharging the food waste transported from the processing unit 10 to the outside using a screw 41.
  • the present invention can supply food catalysts and catalysts capable of decomposing food wastes together, and then mix and crush them to chemically and physically treat food wastes, thereby increasing availability.
  • the food waste supply step is a step of supplying the food waste to the interior of the treatment unit 10, the state of the food waste is not particularly limited. That is, the food waste may be in a solid state or a slurry state.
  • the food waste supplying step may include a shutter control step of controlling the shutter provided inside the food waste supplying unit 20.
  • the shutter control step may control the opening/closing time and opening/closing speed of the shutter. For example, when the opening time of the shutter is set at an interval of 10 seconds, the shutter provided inside the food and beverage waste supply unit 20 is opened at one point and then closed, and then opened again after 10 seconds to process the food and beverage waste inside the processing unit 10 Can be supplied.
  • the catalyst supply step is a step of supplying a catalyst for decomposing food waste into the processing unit 10, and an alkali solvent may be used as the catalyst, for example, ammonia, sodium hydroxide, and calcium hydroxide , An alkali solvent containing at least any one selected from the group consisting of potassium hydroxide, phosphorus hydroxide and sodium sulfide may be used. These catalysts change the pH to melt the oil contained in the food waste, thereby increasing the availability of the food waste.
  • an alkali solvent may be used as the catalyst, for example, ammonia, sodium hydroxide, and calcium hydroxide .
  • An alkali solvent containing at least any one selected from the group consisting of potassium hydroxide, phosphorus hydroxide and sodium sulfide may be used.
  • the catalyst supply step may include a shutter control step for controlling the shutter provided inside the catalyst supply unit 30.
  • the shutter control step may control the opening/closing time and opening/closing speed of the shutter. For example, when the shutter opening time is set at an interval of 10 seconds, the shutter provided inside the catalyst supply unit 30 is opened at one point and closed, and then opened again after 10 seconds to supply the catalyst into the processing unit 10. Can.
  • the food waste treatment step is a step of mixing and pulverizing the food waste and catalyst supplied therein using a mixer 11 provided inside the treatment unit 10, the mixer 11 is a treatment unit 10 )
  • a rotating shaft 12 formed in the longitudinal direction inside; And a plurality of rotating blades 13 provided on the rotating shaft 12 in a direction perpendicular to the rotating shaft 12.
  • the rotating shaft 12 is connected to the motor and can rotate clockwise or counterclockwise, and it is preferable to rotate at a speed of 50 to 450 rpm for efficient stirring and grinding, and more preferably to rotate at a speed of 150 to 350 rpm Work
  • the rotary blade 13 may have a cylindrical shape, but is not limited thereto, and may be manufactured in various shapes according to the purpose.
  • the food waste treatment step may use abrasion grinding method to effectively treat the food waste.
  • it may include a ball 14 that performs translational or rotational movement by the mixer 11 provided inside the processing unit 10.
  • a ball 14 a ball manufactured using a variety of known materials can be used, but it is preferable to use a steel ball, a zirconia ball (ZrO 2 ) ball, or an alumina ball.
  • Do. 3 is a view for explaining the principle of the abrasion and crushing method, and specifically described with reference to this, induces a gradient of force in the processing unit 10 by the mixer 11, and a gradient of force is formed in the processing unit 10
  • the principle is to crush the food waste supplied by inducing friction between the balls (14). Physical treatment may be performed using an attrition mill method, and chemical treatment may be performed by mixing food waste and a catalyst.
  • the rotating shaft 12 of the mixer 11 is preferably rotated at a speed of 50 ⁇ 450rpm, more preferably rotated at a speed of 150 ⁇ 350rpm.
  • the rotational speed is less than 50 rpm, the grinding efficiency is insufficient due to insufficient grinding, and when it exceeds 450 rpm, a high-performance motor is required, and it is difficult to obtain an additional grinding effect, which is uneconomical.
  • the diameter of the ball 14 is preferably 1 to 10 mm, more preferably 3 to 10 mm. If it is less than 1 mm, it cannot have a sufficient crushing effect by the ball 14, and if it exceeds 10 mm, there is a fear that the ball 14 may be damaged by collision between the balls 14 when crushing food waste.
  • the food waste treatment step may include a temperature control step that can adjust the temperature inside the treatment unit 10.
  • a temperature control step that can adjust the temperature inside the treatment unit 10.
  • the reaction time is increased due to the slow reaction rate, there is a problem that the synergistic effect of the food waste is falling, and when it exceeds 150 °C, the evaporation effect of water is increased, so the problem of the synergistic effect of the food waste is reduced. have.
  • the ultrasonic treatment step is a step of decomposing the food waste by using an ultrasonic generator (70), using ultrasonic waves (ultrasonic) to decompose the food waste supplied into the processing unit 10 by vibration Can.
  • ultrasonic Ultrasonic
  • it is a phenomenon in which micro-bubble groups are generated and disappeared due to the large pressure change of ultrasonic waves, which is accompanied by very large pressure.
  • the ultrasonic generator 70 an ultrasonic generator that generates sound waves of 20,000 Hz or more can be used.
  • an ultrasonic generator that generates sound waves of 25,000 to 40,000 Hz can be used.
  • the frequency of ultrasonic waves is less than 25,000Hz, the decomposition effect of food waste is negligible.
  • the frequency of ultrasonic waves exceeds 40,000Hz, it is difficult to obtain an additional synergistic effect and requires a lot of power, which is uneconomical.
  • the food waste discharging step is a step of discharging the food waste transported from the processing unit 10 to the outside using a screw 41
  • the screw 41 can use various types of screws (41) have.
  • a screw 41 having a uniform diameter may be used, a screw 41 having the smallest diameter may be used, and a screw 41 having an irregular diameter may be used.
  • the diameter of the screw 41 means the length to the end of the blade of the screw 41 around the rotation axis of the screw 41.
  • the screw 41 may be used in which the diameter of one side is larger than the diameter of the other side. Specifically, the diameter of one side adjacent to the processing unit 10 is large, and the diameter of the other side distant from the processing unit 10 may be relatively small.
  • Food waste was pretreated using a ball as a food waste disposal apparatus (see FIG. 1) of the present invention. At this time, the catalyst and the ultrasonic generator were not used, and the food waste was crushed for 10 minutes using a zirconia ball.
  • the food waste was crushed under the same conditions as in Example 1, but the food waste was crushed for 60 minutes.
  • the food waste was crushed under the same conditions as in Example 1, but the food waste was crushed for 120 minutes.
  • the chemical oxygen demand (COD) of the food wastes pretreated and the food wastes (Comparative Example 1) pretreated by Examples 1 to 3 was measured through potassium dichromate (CODcr). Specifically, after inserting carried diluted food waste of Example 1 to 3 and Comparative Examples 1 to each flask, HgSO 4 5ml added to dissolved the HgSO 4 completely. After completely dissolving HgSO 4 , 25 ml of potassium dichromate solution was added to each flask and bolling stone was added. Thereafter, 70 mL of 5.5 g Ag2SO4 / 1 kg HgSO4 solution was added to each flask, followed by Reflux for 2 hours to measure COD, and the results are shown in Table 1.
  • Example 1 Example 2 Example 3 Comparative Example 1 SCOD/TCOD increase rate (%) 15.63 32.43 0.71 -
  • SCOD/TCOD is increased in Examples 1 to 3, and in particular, in Food Example 2 in which food waste was crushed for 60 minutes using a ball, the greatest increase was found.
  • SCOD Soluble Chemical Oxygen Demand
  • TCOD Total Chemical Oxygen Demand
  • COD soluble in total COD Means that the area where microorganisms can decompose increases. Therefore, it was found that in Examples 1 to 3, where the microorganisms could be decomposed, the biogas productivity was increased in the Examples 1 to 3, which were pretreated, than the food wastes (Comparative Example 1) that were not pretreated.
  • the food waste was pretreated with the food waste disposal apparatus (see FIG. 1) of the present invention. At this time, the catalyst and the ultrasonic generator were not used, and food wastes were crushed using a zirconia ball at 80°C for 10 minutes.
  • the food waste was pretreated with the food waste disposal apparatus (see FIG. 1) of the present invention. At this time, the catalyst was not used, and the food waste was crushed using a zirconia ball for 10 minutes, and the food waste was decomposed for 30 minutes with a sound wave of 30,000 Hz through an ultrasonic generator.
  • Example 1 Example 4
  • Example 5 Example 6 SCOD/TCOD increase rate (%) 15.63 17.80 24.62 38.01
  • Example 2 Under the same conditions as in Example 1, the food waste was pretreated, but a steel ball was used in place of the zirconia ball.
  • Food waste was pre-treated under the same conditions as in Example 1, but instead of a zirconia ball, an alumina ball was used.
  • Example 1 Example 7
  • Example 8 Comparative Example 1 SCOD/TCOD increase rate (%) 15.63 40.29 8.06 -
  • Example 7 As can be seen through the results of Table 3, it was found that SCOD/TCOD is increased in Examples 7 and 8, and in particular, SCOD/TCOD of Example 7 using a steel ball is most increased. That is, it was found that in Example 7 in which the increase rate of SCOD/TCOD is high, the area where microorganisms can decompose is larger, and accordingly, the productivity of biogas in food waste of Example 7 is improved.
  • the present invention is to provide a food waste treatment apparatus and a food waste treatment method using the same, by increasing the solubility of food waste, improving the productivity of biogas using food waste, and using the chemical method and the physical method at the same time It is possible to improve the productivity of biogas by pre-treating the waste, and re-injecting the untreated food waste as much as the amount of food waste to be processed, so that continuous treatment is possible, and thus there is industrial applicability.

Abstract

The present invention relates to a food waste treatment apparatus and a food waste treatment method using same, the food waste treatment apparatus comprising, in order to improve productivity of biogas by simultaneously performing chemical treatment and physical treatment: a treatment unit for mixing and crushing food waste supplied thereinto; a food waste supply unit, connected to an upper end of the treatment unit, for supplying the food waste into the treatment unit; a catalyst supply unit, connected to the upper end of the treatment unit, for supplying, into the treatment unit, a catalyst for decomposing the food waste; and a discharge unit, connected to one side of a lower end of the treatment unit and having a screw therein, for discharging the decomposed food waste to the outside thereof.

Description

바이오가스 생산성을 향상시키는 음식물류 폐기물 처리장치 및 이를 이용한 음식물류 폐기물 처리방법Food waste treatment device to improve biogas productivity and food waste treatment method using same
본 발명은 음식물류 폐기물 처리장치 및 이를 이용한 음식물류 폐기물 처리방법에 관한 것으로서, 보다 상세하게는, 화학적 처리와 물리적 처리를 동시에 수행하여 바이오가스의 생산성을 향상시킬 수 있는 음식물류 폐기물 처리장치 및 이를 이용한 음식물류 폐기물 처리방법에 관한 것이다.The present invention relates to a food waste treatment apparatus and a food waste treatment method using the same, and more specifically, a food waste treatment apparatus capable of improving biogas productivity by simultaneously performing chemical treatment and physical treatment, and food waste using the same. It relates to a processing method.
일반적으로 음식물류 폐기물은 식품의 생산, 유통, 가공, 조리과정에서 발생하는 농, 수, 축산물 쓰레기와 가정이나 식당 등지에서 먹고 남기며 버려지는 음식찌거기 등을 말한다.In general, food waste refers to agricultural, water, and livestock waste generated during the production, distribution, processing, and cooking of food, and food waste that is left behind after being eaten and left at home or restaurants.
최근 신재생에너지의 중요성이 대두 됨에 따라, 물리적, 화학적 또는 생물학적 전환기술을 적용하여 음식물류 폐기물을 활용해 바이오 가스를 생산하고 있다. 이렇게 생산되는 바이오 가스는 화석에너지로 대체할 수 있는 에너지원이다.Recently, as the importance of new and renewable energy has emerged, biogas is produced using food wastes by applying physical, chemical, or biological conversion technology. The biogas produced in this way is an energy source that can be replaced with fossil energy.
세계적으로는 40여개의 상용기술이 240여개의 대형 음식물류 폐기물 바이오 가스화 시설에 적용되고 있으며, 연간 처리량은 2500톤에 달한다(Kellenher, 2007; IEA 2008)Globally, more than 40 commercial technologies are applied to over 240 large food waste biogasification facilities, with annual throughput of 2,500 tons (Kellenher, 2007; IEA 2008).
우리나라 정부는 정책적으로 제4차 신재생에너지 기본계획을 수립하여, 음식물쓰레기의 효율적인 활용을 통해 에너지 보급률 향상시키고 있다. 그 결과, 국내 음식물바이오가스화시설 11개소 (1,788톤/일), 음폐수바이오가스화시설 9개소 (1,860톤/일), 하수슬러지 고형연료시설 3개소 (2,770톤/일), 병합바이오가스화시설 6개소 (1,140톤/일)을 추가 확충하여 시설설치 완료시점에는 가용물량의 33%를 에너지화 하도록 하였다(한국개발연구원, 2013).The Korean government has established the 4th Basic Renewable Energy Plan as a policy, and is improving the energy supply rate through efficient use of food waste. As a result, 11 domestic food biogasification facilities (1,788 tons/day), 9 wastewater biogasification facilities (1,860 tons/day), 3 sewage sludge solid fuel facilities (2,770 tons/day), combined biogasification facilities 6 The additional locations (1,140 tons/day) were additionally expanded to make 33% of the available volume energy-enable at the time of installation completion (Korea Development Institute, 2013).
그러나 음식물류 폐기물은 에너지원으로써 에너지밀도는 높지만 가용성이 낮아서 발효공정에 적용하는데 어려움이 있다. 또한, 음식물류 폐기물은 동절기에는 유동성이 낮으며, 산화안정성이 취약해서 공급 안정성 및 경제성이 떨어진다.However, food waste is an energy source, but has high energy density but low solubility, making it difficult to apply it to fermentation processes. In addition, food wastes have low fluidity during the winter months, and oxidative stability is poor, resulting in poor supply stability and economics.
대한민국 공개특허 제10-2009-013483호는 음식물 바이오가스를 재생이용하는 음폐수 처리장치 및 방법에 관한 것이며, 대한민국 등록특허 10-1892241호는 유분 분리 장치에 관한 것으로, 음식물류 폐기물를 이용해 바이오가스를 생산하는 기술을 제시하고 있다. Republic of Korea Patent Publication No. 10-2009-013483 relates to a waste water treatment apparatus and method for recycling and using food biogas, Republic of Korea Patent No. 10-1892241 relates to an oil separation device, to produce biogas using food waste Technology is being presented.
그러나 이러한 종래 기술들은 음폐수 원수에서 유분만을 따로 분리하여 바이오가스를 생산하는 것으로, 이러한 기존의 유분 혼합소화가 도리어 바이오가스 생산의 효율을 감소시킨다.However, these prior arts produce biogas by separating only oil from raw waste water, and this conventional oil mixing and digestion decreases the efficiency of biogas production.
이에, 음식물류 폐기물의 가용성을 높일 수 있는 음식물류 폐기물 처리장치 및 처리방법에 대한 요구가 이어지고 있다.Accordingly, there is a need for a food waste treatment apparatus and a treatment method capable of increasing the availability of food waste.
본 발명은 상기와 같은 문제점을 해결하기 위한 것으로서, 음식물류 폐기물의 가용성을 높여, 음식물류 폐기물을 이용한 바이오가스의 생산성을 향상시킬 수 있는 음식물류 폐기물 처리장치 및 이를 이용한 음식물류 폐기물 처리방법을 제공하고자 한다.The present invention is to solve the above problems, to increase the availability of food waste, and to provide a food waste disposal apparatus and a food waste disposal method using the same, which can improve the productivity of biogas using food waste.
본 발명의 상기 및 다른 목적과 이점은 바람직한 실시예를 설명한 하기의 설명으로부터 분명해질 것이다.The above and other objects and advantages of the present invention will become apparent from the following description of preferred embodiments.
상기 목적은, 내부로 공급되는 음식물류 폐기물을 혼합 및 분쇄하는 처리부; 상기 처리부의 상단에 연결되어 처리부 내부로 음식물류 폐기물을 공급하는 음식물류 폐기물 공급부; 상기 처리부의 상단에 연결되어 처리부 내부로 음식물류 폐기물을 분해하기 위한 촉매를 공급하는 촉매공급부; 및 상기 처리부의 하단 일측에 연결되고, 내부에 스크류를 구비하여 분해된 음식물류 폐기물을 외부로 배출하는 배출부;를 포함하고, 상기 처리부는, 상기 처리부 내부에 구비되는 혼합기; 및 상기 처리부 하부에 연결되어 처리부 내부의 온도를 조절할 수 있는 온도조절장치;를 포함하는 음식물류 폐기물 처리장치에 의해 달성될 수 있다.The above object is a processing unit for mixing and crushing the food waste supplied to the interior; A food waste supply unit connected to an upper end of the processing unit to supply food waste to the processing unit; A catalyst supply unit connected to the upper end of the processing unit to supply a catalyst for decomposing food waste into the processing unit; And It is connected to the lower side of the processing unit, the discharge unit for discharging the decomposed food waste to the outside with a screw therein; includes, the processing unit, a mixer provided inside the processing unit; And a temperature control device connected to the lower portion of the processing unit to control the temperature inside the processing unit.
이때, 혼합기는, 처리부 내부에 종방향으로 형성된 회전축; 및 회전축과 수직방향으로 회전축에 구비된 복수의 회전날개;를 포함할 수 있고, 회전축은 50~450rpm의 속도로 회전할 수 있다.At this time, the mixer, the rotating shaft formed in the longitudinal direction inside the processing unit; And a plurality of rotating blades provided on the rotating shaft in a direction perpendicular to the rotating shaft, and the rotating shaft may rotate at a speed of 50 to 450 rpm.
상기 처리부는, 처리부 내부에 구비되는 초음파 발생장치를 포함하는 것이 바람직하다.Preferably, the processing unit includes an ultrasonic generator provided inside the processing unit.
또한, 처리부는, 교반기에 의해 병진운동 또는 회전운동을 하여 음식물류 폐기물을 분쇄하는 볼;을 포함할 수 있고, 이러한 볼의 직경은 1~10mm일 수 있다.In addition, the processing unit may include a ball that pulverizes food wastes by performing translational or rotational movement with a stirrer, and the diameter of such a ball may be 1 to 10 mm.
또한, 처리부는, 하부에 연결되어 처리부 내부의 온도를 조절할 수 있는 히터;를 포함할 수 있다.In addition, the processing unit may include a heater connected to the lower portion to control the temperature inside the processing unit.
상기 촉매는, 암모니아, 수산화나트륨, 수산화칼슘, 수산화칼륨, 수산화인 및 황화나트륨으로 이루어진 군에서 선택되는 적어도 어느 하나를 포함하는 알칼리 용매인 것이 바람직하다.The catalyst is preferably an alkali solvent containing at least one selected from the group consisting of ammonia, sodium hydroxide, calcium hydroxide, potassium hydroxide, phosphorus hydroxide and sodium sulfide.
배출부에 구비된 스크류는, 일측의 직경이 타측의 직경보다 큰 것일 수 있다.The screw provided in the discharge portion may have a diameter on one side larger than the diameter on the other side.
또한, 배출부는 처리부로부터 이송된 음식물류 폐기물이 처리부로 역류하는 것을 방지하는 역류방지부재;를 포함할 수 있고, 이때 역류방지부재는 복수의 홀이 형성된 원형 부재; 및 일방향으로만 개방되는 게이트;를 포함할 수 있다.In addition, the discharge unit may include a backflow prevention member for preventing food waste transported from the processing unit from flowing back to the treatment unit, wherein the backflow prevention member includes a circular member having a plurality of holes; And a gate that opens only in one direction.
또한, 상기 목적은, 처리부 내부로 음식물류 폐기물을 공급하는 음식물류 폐기물 공급단계; 처리부 내부로 음식물류 폐기물을 분해하기 위한 촉매를 공급하는 촉매 공급단계; 처리부 내부로 공급되는 음식물류 폐기물 및 촉매를 혼합기를 이용하여 혼합 및 분쇄하는 음식물류 폐기물 처리단계; 처리부 내부로 공급되는 음식물류 폐기물을 초음파 발생장치를 이용하여 분해하는 초음파 처리단계; 및 처리부로부터 이송된 음식물류 폐기물을 스크류를 이용하여 외부로 배출하는 음식물류 폐기물 배출단계;를 포함하는 음식물류 폐기물 처리방법에 의해 달성될 수 있다.In addition, the object is, food waste supply step of supplying food waste to the inside of the processing unit; A catalyst supply step of supplying a catalyst for decomposing food waste into the processing unit; A food waste treatment step of mixing and pulverizing the food waste and catalyst supplied to the processing unit using a mixer; An ultrasonic treatment step of decomposing food wastes supplied into the processing unit using an ultrasonic generator; And a food waste disposal step of discharging the food waste transferred from the processing unit to the outside using a screw.
이때, 촉매 공급단계에서 공급되는 촉매는, 암모니아, 수산화나트륨, 수산화칼슘, 수산화칼륨, 수산화인 및 황화나트륨으로 이루어진 군에서 선택되는 적어도 어느 하나를 포함하는 알칼리 용매인 것이 바람직하다.At this time, the catalyst supplied in the catalyst supply step is preferably an alkali solvent containing at least one selected from the group consisting of ammonia, sodium hydroxide, calcium hydroxide, potassium hydroxide, phosphorus hydroxide and sodium sulfide.
또한, 처리부 내부에 구비된 혼합기는 처리부 내부에 종방향으로 형성된 회전축; 및 회전축과 수직방향으로 회전축에 구비된 복수의 회전날개;를 포함할 수 있고, 회전축은 50~450rpm의 속도로 회전할 수 있다.In addition, the mixer provided inside the processing unit is a rotating shaft formed in the longitudinal direction inside the processing unit; And a plurality of rotating blades provided on the rotating shaft in a direction perpendicular to the rotating shaft, and the rotating shaft may rotate at a speed of 50 to 450 rpm.
또한, 음식물류 폐기물 처리단계는, 교반기에 의해 병진운동 또는 회전운동 하는 볼을 이용하여 음식물류 폐기물를 분쇄할 수 있고, 이때, 볼의 직경은 1~10mm일 수 있다.In addition, in the food waste disposal step, the food waste may be crushed using a ball that is translated or rotated by a stirrer, and the diameter of the ball may be 1 to 10 mm.
또한, 음식물류 폐기물 처리단계는, 60~150℃의 온도에서 수행될 수 있다.In addition, the food waste treatment step may be performed at a temperature of 60 ~ 150 ℃.
한편, 음식물류 폐기물 배출단계에서 사용하는 스크류는, 일측의 직경이 타측의 직경보다 큰 것일 수 있다.On the other hand, the screw used in the food waste discharging step, the diameter of one side may be larger than the diameter of the other side.
본 발명에 따르면, 화학적 방법과 물리적 방법을 동시에 사용하여 음식물류 폐기물을 전처리함으로써 바이오가스의 생산성을 향상시킬 수 있고, 처리되는 음식물류 폐기물 양만큼 미처리된 음식물류 폐기물을 재투입하여 연속적인 처리가 가능하다.According to the present invention, it is possible to improve the productivity of biogas by pre-treating food wastes using both chemical and physical methods at the same time, and continuous treatment is possible by re-injecting untreated food wastes as much as the amount of food wastes to be treated.
또한, 음식물류 폐기물을 처리하여 회수된 음식물류 폐기물로부터 바이오가스를 얻을 수 있는 효과를 가진다.In addition, it has the effect of obtaining biogas from food and waste collected by treating food waste.
다만, 본 발명의 효과들은 이상에서 언급한 효과로 제한되지 않으며, 언급되지 않은 또 다른 효과들은 아래의 기재로부터 당업자에게 명확하게 이해될 수 있을 것이다.However, the effects of the present invention are not limited to the above-mentioned effects, and other effects not mentioned will be clearly understood by those skilled in the art from the following description.
도 1은 본 발명의 일 실시예에 따른 음식물류 폐기물 처리장치를 개략적으로 나타낸 도면이다.1 is a view schematically showing a food waste disposal apparatus according to an embodiment of the present invention.
도 2는 본 발명의 다른 실시예에 따른 음식물류 폐기물 처리장치를 개략적으로 나타낸 도면이다.2 is a view schematically showing a food waste treatment apparatus according to another embodiment of the present invention.
도 3은 마멸분쇄 방식의 원리를 설명하는 도면이다.3 is a view for explaining the principle of the wear and tear grinding method.
[부호의 설명][Description of codes]
100 : 음식물류 폐기물 처리장치 10 : 처리부100: food waste disposal device 10: treatment unit
11 : 혼합기 12 : 회전축11: mixer 12: rotating shaft
13 : 회전날개 14 : 볼13: rotary blade 14: ball
20 : 음식물류 폐기물 공급부 30 : 촉매 공급부20: food waste supply unit 30: catalyst supply unit
40 : 배출부 41 : 스크류40: outlet 41: screw
42 : 연결부재 50 : 히터42: connecting member 50: heater
60 : 역류방지부재 70 : 초음파 발생장치60: backflow prevention member 70: ultrasonic generator
이하에서는 본 발명의 실시예와 도면을 참조하여 본 발명을 상세히 설명한다. 이들 실시예는 오로지 본 발명을 보다 구체적으로 설명하기 위해 예시적으로 제시한 것일 뿐, 본 발명의 범위가 이들 실시예에 의해 제한되지 않는다는 것은 당업계에서 통상의 지식을 가지는 자에 있어서 자명할 것이다.Hereinafter, the present invention will be described in detail with reference to examples and drawings of the present invention. These examples are only provided by way of example to illustrate the present invention in more detail, it will be apparent to those skilled in the art that the scope of the present invention is not limited by these examples. .
또한, 달리 정의하지 않는 한, 본 명세서에서 사용되는 모든 기술적 및 과학적 용어는 본 발명이 속하는 기술 분야의 숙련자에 의해 통상적으로 이해되는 바와 동일한 의미를 가지며, 상충되는 경우에는, 정의를 포함하는 본 명세서의 기재가 우선할 것이다.In addition, unless otherwise defined, all technical and scientific terms used herein have the same meaning as commonly understood by those skilled in the art to which the present invention belongs, and in case of conflict, the present specification including definitions. The description will take precedence.
도면에서 제안된 발명을 명확하게 설명하기 위해서 설명과 관계없는 부분은 생략하였으며, 명세서 전체를 통하여 유사한 부분에 대해서는 유사한 도면 부호를 붙였다. 그리고, 어떤 부분이 어떤 구성 요소를 "포함"한다고 할 때, 이는 특별히 반대되는 기재가 없는 한 다른 구성 요소를 제외하는 것이 아니라 다른 구성 요소를 더 포함할 수 있는 것을 의미한다. 또한, 명세서에서 기술한 "부"란, 특정 기능을 수행하는 하나의 단위 또는 블록을 의미한다.In order to clearly describe the proposed invention in the drawings, parts irrelevant to the description are omitted, and like reference numerals are assigned to similar parts throughout the specification. And, when it is said that a part "includes" a certain component, this means that other components may be further included instead of excluding other components, unless otherwise stated. In addition, "part" described in the specification means a unit or block that performs a specific function.
각 단계들에 있어 식별부호(제1, 제2, 등)는 설명의 편의를 위하여 사용되는 것으로 식별부호는 각 단계들의 순서를 설명하는 것이 아니며, 각 단계들은 문맥상 명백하게 특정 순서를 기재하지 않는 이상 명기된 순서와 다르게 실시될 수 있다. 즉, 각 단계들은 명기된 순서와 동일하게 실시될 수도 있고 실질적으로 동시에 실시될 수도 있으며 반대의 순서대로 실시될 수도 있다.In each step, the identification numbers (first, second, etc.) are used for convenience of explanation. The identification numbers do not describe the order of each step, and each step does not explicitly describe a specific order in the context. It may be carried out differently from the order specified above. That is, each step may be performed in the same order as specified, or may be performed substantially simultaneously, or in the reverse order.
도 1은 본 발명의 일 실시예에 따른 음식물류 폐기물 처리장치(100)를 개략적으로 나타낸 도면이다. 도 1을 참조하여 설명하면, 본 발명의 일 실시예에 따른 음식물류 폐기물 처리장치(100)는 내부로 공급되는 음식물류 폐기물을 교반 및 분쇄하는 처리부(10); 처리부(10)의 상단에 연결되어 처리부(10) 내부로 음식물류 폐기물을 공급하는 음식물류 폐기물 공급부(20); 처리부(10)의 상단에 연결되어 처리부(10) 내부로 음식물류 폐기물을 분해하기 위한 촉매를 공급하는 촉매 공급부(30); 및 처리부(10)의 하단 일측에 연결되고, 내부에 스크류(41)를 구비하여 분해된 음식물류 폐기물을 외부로 배출하는 배출부(40);를 포함한다. 본 발명은 음식물류 폐기물과 음식물류 폐기물을 분해할 수 있는 촉매를 함께 공급한 후, 이들을 혼합 및 분쇄함으로써 음식물류 폐기물을 화학적/물리적으로 처리하여 가용성을 높일 수 있다. 음식물류 폐기물이 지속적으로 공급되어 어느 정도 분쇄 및 분해가 진행되면, 처리부(10) 내부에 축적되고, 충분히 축적되면 축적된 압력에 의해 하부에 형성된 배출부(40)로 배출되는데, 이때, 스크류(41)를 활용하여 처리된 음식물류 폐기물를 효과적으로 외부로 배출함으로써 음식물류 폐기물을 연속적으로 처리할 수 있는 효과를 가진다.1 is a view schematically showing a food waste treatment apparatus 100 according to an embodiment of the present invention. Referring to Figure 1, the food waste treatment apparatus 100 according to an embodiment of the present invention includes a processing unit 10 for stirring and pulverizing the food waste to be supplied therein; A food waste supply unit 20 connected to the upper end of the processing unit 10 to supply food waste to the processing unit 10; A catalyst supply unit 30 connected to an upper end of the processing unit 10 to supply a catalyst for decomposing food waste into the processing unit 10; And a discharge unit 40 connected to the lower end side of the processing unit 10 and having a screw 41 therein to discharge the decomposed food waste to the outside. The present invention can supply food catalysts and catalysts capable of decomposing food wastes together, and then mix and crush them to chemically and physically treat food wastes, thereby increasing availability. When food waste is continuously supplied and crushed and decomposed to some extent, it is accumulated in the processing unit 10 and when sufficiently accumulated, it is discharged to the discharge unit 40 formed at the bottom by the accumulated pressure. ) By effectively discharging the processed food waste to the outside, it has the effect of continuously processing the food waste.
여기에서, 음식물류 폐기물은 최초 분쇄 또는 분해되기 전 상태 뿐만 아니라 촉매 및 혼합기(11)에 의해 분쇄 또는 분해된 이 후의 상태를 모두 의미하고, 처리란, 음식물류 폐기물로부터 혼합하여서 발효시키는 병합소화 공정을 통해 바이오가스를 얻기 위하여 그에 앞서 음식물류 폐기물을 전처리 하는 것을 의미한다.Here, the food waste refers to both the state before the initial crushing or decomposition, as well as the state after the crushing or decomposition by the catalyst and the mixer 11, and the treatment means through a combined digestion process to mix and ferment from food and waste. It means pre-processing food waste before obtaining biogas.
일 실시예에 있어서, 처리부(10)는 내부에 음식물류 폐기물을 수용할 수 있는 공간 및 혼합기(11)를 구비하여 내부로 공급되는 음식물류 폐기물을 혼합 및 분쇄하는 것으로서, 상부는 음식물류 폐기물을 공급하는 공급부(20) 및 촉매를 공급하는 촉매 공급부(30)와 연결되고, 하부 일측은 처리된 음식물류 폐기물을 외부로 배출하는 배출부(40)와 연결되며, 전체적인 외관이 원기둥 형상일 수 있으나, 이에 제한되는 것은 아니다. In one embodiment, the processing unit 10 is provided with a space and a mixer 11 to accommodate food wastes therein to mix and crush the food wastes supplied to the interior, the upper portion is a supply unit for supplying food wastes 20 and the catalyst supply unit 30 for supplying the catalyst, the lower one side is connected to the discharge unit 40 for discharging the processed food waste to the outside, the overall appearance may be a cylindrical shape, but is limited to this It is not.
일 실시예에 있어서, 혼합기(11)는 처리부(10) 내부에 구비되어 공급되는 음식물류 폐기물과 촉매를 혼합하고 분쇄하는 것으로서, 처리부(10) 내부에 종방향으로 형성된 회전축(12); 및 회전축(12)과 수직방향으로 회전축(12)에 형성된 복수의 회전날개(13);를 포함할 수 있다. 회전축(12)은 모터와 연결되어 시계 방향 또는 반시계 방향으로 회전할 수 있고, 효율적인 교반 및 분쇄를 위하여 50~450rpm의 속도로 회전하는 것이 바람직하며, 150~350rpm의 속도로 회전하는 것이 더욱 바람직하다. 또한, 회전날개(13)는 원기둥 형상일 수 있으나, 이에 제한되는 것은 아니고, 목적에 따라 다양한 형상으로 제조할 수 있다.In one embodiment, the mixer 11 is provided inside the processing unit 10 to mix and pulverize food wastes and catalysts supplied and pulverizes, a rotating shaft 12 formed in the longitudinal direction inside the processing unit 10; And a plurality of rotating blades 13 formed on the rotating shaft 12 in a direction perpendicular to the rotating shaft 12. The rotating shaft 12 is connected to the motor and can rotate clockwise or counterclockwise, and it is preferable to rotate at a speed of 50 to 450 rpm for efficient stirring and grinding, and more preferably to rotate at a speed of 150 to 350 rpm. Do. In addition, the rotary blade 13 may have a cylindrical shape, but is not limited thereto, and may be manufactured in various shapes according to the purpose.
일 실시예에 있어서, 처리부(10)는 음식물류 폐기물을 효과적으로 처리하기 위하여 마멸 분쇄 방식을 이용할 수 있다. 이를 위하여 처리부(10)는 내부에 혼합기(11)에 의해 병진운동 또는 회전운동을 하는 볼(14)을 포함할 수 있다. 이러한 볼(14)로는 공지의 다양한 재료를 이용하여 제조된 볼을 사용할 수 있으나, 스틸 볼(Steel ball), 지르코니아(ZrO2) 볼(Zrconia ball) 또는 알루미나 볼(Alumina ball)을 사용하는 것이 바람직하다. 도 3은 마멸분쇄 방식의 원리를 설명하는 도면으로, 이를 참조하여 구체적으로 설명하면, 혼합기(11)에 의해서 처리부(10) 내에 힘의 구배를 유도하고, 힘의 구배가 형성된 처리부(10) 내에서 볼(14) 간의 마찰을 유도하여 공급되는 음식물류 폐기물을 분쇄하는 원리이다. 마멸분쇄(attrition mill) 방식을 이용하여 물리적 처리를 수행함과 동시에 음식물류 폐기물과 촉매를 혼합하여 화학적 처리를 수행할 수 있다.In one embodiment, the treatment unit 10 may use a wear and tear grinding method to effectively treat food waste. To this end, the processing unit 10 may include a ball 14 that performs translational or rotational movement by the mixer 11 therein. As the ball 14, a ball manufactured using a variety of known materials can be used, but it is preferable to use a steel ball, a zirconia ball (ZrO 2 ) ball, or an alumina ball. Do. 3 is a view for explaining the principle of the abrasion and crushing method, and specifically described with reference to this, induces a gradient of force in the processing unit 10 by the mixer 11, and a gradient of force is formed in the processing unit 10 The principle is to crush the food waste supplied by inducing friction between the balls (14). Physical treatment may be performed using an attrition mill method, and chemical treatment may be performed by mixing food waste and a catalyst.
이때, 혼합기(11)의 회전축(12)은 50~450rpm의 속도로 회전하는 것이 바람직하며, 150~350rpm의 속도로 회전하는 것이 더욱 바람직하다. 회전 속도가 50rpm 미만일 경우, 분쇄가 충분히 이루어지지 않아 분쇄 효율이 떨어지고, 450rpm을 초과하는 경우, 고성능의 모터가 필요하고, 추가적인 분쇄 효과를 얻기 어려우므로 비경제적이다.At this time, the rotating shaft 12 of the mixer 11 is preferably rotated at a speed of 50 ~ 450rpm, more preferably rotated at a speed of 150 ~ 350rpm. When the rotational speed is less than 50 rpm, the grinding efficiency is insufficient due to insufficient grinding, and when it exceeds 450 rpm, a high-performance motor is required, and it is difficult to obtain an additional grinding effect, which is uneconomical.
또한, 볼(14)의 직경은 1~10mm인 것이 바람직하며, 더욱 바람직하게는 3~10mm일 수 있다. 1mm 미만인 경우, 볼(14)에 의한 충분한 분쇄 효과를 가질 수 없고, 10mm를 초과하는 경우, 음식물류 폐기물 분쇄시 볼(14) 간의 충돌에 의해 볼(14)이 파손될 우려가 있다.In addition, the diameter of the ball 14 is preferably 1 to 10 mm, more preferably 3 to 10 mm. If it is less than 1 mm, it cannot have a sufficient crushing effect by the ball 14, and if it exceeds 10 mm, there is a fear that the ball 14 may be damaged by collision between the balls 14 when crushing food waste.
일 실시예에 있어서, 처리부(10)는 하단부에 내부의 온도를 조절할 수 있는 히터(50)를 포함할 수 있다. 음식물류 폐기물의 물리적 처리방법과 달리 화학적 처리방법의 경우, 적절한 온도로 유지하는 것이 중요하고, 음식물류 폐기물을 화학적으로 처리하기 위해서 처리부(10)의 내부를 60~150℃로 제어하는 것이 바람직하다. 60℃ 미만의 경우, 음식물류 폐기물의 가용성 상승 효과가 떨어지는 문제점이 있고 150℃를 초과하는 경우 수분 증발 효과가 커져서 음식물류 폐기물의 가용성 상승 효과가 감소되는 문제점이 있다.In one embodiment, the processing unit 10 may include a heater 50 that can adjust the temperature inside the lower portion. Unlike the physical treatment method of food waste, in the case of the chemical treatment method, it is important to maintain an appropriate temperature, and it is preferable to control the inside of the treatment unit 10 to 60 to 150°C to chemically treat the food waste. If less than 60 ℃, there is a problem that the synergistic effect of the food waste is falling, and if it exceeds 150 ℃, there is a problem that the evaporation effect of the water is increased, so that the synergistic effect of the food waste is reduced.
일 실시예에 있어서, 처리부(10)는 히터(50)를 대신하여 열매체유 순환장치(미도시)를 포함할 수도 있다. 열매체유 순환장치는 열매체유를 가열한 후, 이를 순환시켜 처리부(10)에 열을 공급하는 것으로서, 열매체유를 저장 및 가열하는 열매체유 가열탱크; 열매체유를 순환시키는 열매체유 순환펌프; 및 처리부(10)의 외부를 감싸는 형태로 형성되어 열매체유가 이동하는 자켓 파이프;를 포함할 수 있다. 열매체유 가열탱크는 내부에 열매체유를 가열하기 위한 히터봉을 포함할 수 있다. 열매체유는 공지의 다양한 열매체유를 사용할 수 있으나, 알킬벤젠계 합성 열매체유(SERIOLA KF 2120, 에쓰-오일 토탈 윤활유㈜)로서, 사용 온도 범위는 -10 ~ 350℃인 것이 바람직하다. 열매체유는 히터봉에 의해 가열되고, 열매체유 순환펌프에 의해 처리부(10)를 둘러싸는 자켓 파이프 내부를 따라 흐르면서 처리부(10)에 열을 공급한다.In one embodiment, the processing unit 10 may include a heat medium oil circulation device (not shown) in place of the heater 50. The heat medium oil circulation device is a heat medium oil heating tank that stores and heats the heat medium oil as it heats the heat medium oil and circulates it to supply heat to the processing unit 10; A heat medium oil circulation pump circulating the heat medium oil; And it is formed in a form surrounding the outside of the processing unit 10, a jacket pipe to transfer the heat medium oil; may include. The heating medium oil heating tank may include a heater rod for heating the heating medium oil therein. As the heat medium oil, various heat medium oils known in the art can be used, but as an alkylbenzene-based synthetic heat medium oil (SERIOLA KF 2120, S-OIL Total Lubricant Co., Ltd.), the temperature range of use is preferably -10 to 350°C. The heat medium oil is heated by a heater rod and flows along the inside of the jacket pipe surrounding the process unit 10 by a heat medium oil circulation pump to supply heat to the process unit 10.
또한, 상기 처리부(10)는 처리부 내부에 구비되는 초음파 발생장치(70)를 포함할 수 있다. 이러한 초음파 발생장치(70)는 초음파(Ultrasonic)를 이용하여 처리부(10) 내부로 공급된 음식물류 폐기물에 진동을 주어 분해하기 위한 것이다. 음식물류 폐기물에 초음파(Ultrasonic)가 전달될 때 초음파의 큰 압력변화에 의해 미세기포군이 생성되고 소멸되는 현상으로 매우 큰 압력이 동반하게 된다. 이 압력이 수백분의 1초에서 수천분의 1초 단위의 짧은 시간 동안 발생하게 됨에 따라 음식물류 폐기물 분해 효과가 극대화 되어 음식물류 폐기물의 가용성이 상승된다.In addition, the processing unit 10 may include an ultrasonic generator 70 provided inside the processing unit. The ultrasonic generator 70 is intended to decompose by vibrating the food wastes supplied into the processing unit 10 using ultrasonics. When ultrasonic (Ultrasonic) is transmitted to food waste, it is a phenomenon in which micro-bubble groups are generated and disappeared due to the large pressure change of ultrasonic waves, which is accompanied by very large pressure. As this pressure occurs for a short period of time from hundredths of a second to several thousandths of a second, the effect of decomposing food waste is maximized, increasing the availability of food waste.
이러한 초음파 발생장치(70)는 처리부(10)의 하부 또는 측벽에 설치될 수 있고, 2만 Hz이상의 음파를 발생하는 초음파 발생장치일 수 있으며, 바람직하게는 25,000~40,000 Hz의 음파를 발생하는 초음파 발생장치일 수 있다.The ultrasonic generator 70 may be installed on the lower or sidewall of the processing unit 10, may be an ultrasonic generator that generates sound waves of 20,000 Hz or more, and preferably ultrasonic waves of 25,000 to 40,000 Hz It can be a generator.
일 실시예에 있어서, 음식물류 폐기물 공급부(20)는 일측은 처리부(10)의 상단에 연결되고, 타측은 음식물류 폐기물 저장탱크(미도시)에 연결되어 음식물류 폐기물 저장탱크 내에 저장된 음식물류 폐기물을 처리부(10) 내부로 공급할 수 있다. 전체적인 형상은 원기둥 형상일 수 있으나, 이에 제한되는 것은 아니며, 음식물류 폐기물을 처리부(10) 내부로 공급할 수 있는 형상이면 무관하다. 음식물류 폐기물 공급부(20) 내부에는 셔터(미도시)가 구비될 수 있다. 즉, 셔터가 개방되면 음식물류 폐기물 공급부(20)로부터 처리부(10)로 음식물류 폐기물을 공급할 수 있고, 셔터가 폐쇄되면, 음식물류 폐기물의 공급을 중단할 수 있다. 또한, 공급되는 음식물류 폐기물의 상태는 특별히 제한되지 않는다. 즉, 고체 상태일 수도 있고, 슬러리 상태일 수도 있다.In one embodiment, the food waste supply unit 20 is connected to the upper end of the treatment unit 10, the other side is connected to the food waste storage tank (not shown), the food waste stored in the food waste storage tank processing unit 10 ) It can be supplied inside. The overall shape may be a cylindrical shape, but is not limited to this, and any shape that can supply food waste to the processing unit 10 is irrelevant. A shutter (not shown) may be provided inside the food waste supply unit 20. That is, when the shutter is opened, food and beverage waste can be supplied from the food and beverage waste supply unit 20 to the processing unit 10, and when the shutter is closed, the supply of food and beverage waste can be stopped. In addition, the condition of the food waste to be supplied is not particularly limited. That is, it may be in a solid state or a slurry state.
일 실시예에 있어서, 촉매 공급부(30)는 일측은 처리부(10)의 상단에 연결되고, 타측은 촉매 저장탱크에 연결되어 촉매 저장탱크(미도시) 내에 저장된 촉매를 처리부(10) 내부로 공급할 수 있다. 촉매 공급부(30)는 다양한 형상으로 제조될 수 있다. 촉매 공급부(30) 내부에는 셔터(미도시)가 구비될 수 있다. 즉, 셔터가 개방되면 촉매 공급부(30)로부터 처리부(10)로 촉매를 공급할 수 있고, 셔터가 폐쇄되면, 촉매 공급을 중단할 수 있다.In one embodiment, the catalyst supply unit 30 is connected to the upper end of the processing unit 10, the other side is connected to the catalyst storage tank to supply the catalyst stored in the catalyst storage tank (not shown) into the processing unit 10 Can. The catalyst supply unit 30 may be manufactured in various shapes. A shutter (not shown) may be provided inside the catalyst supply unit 30. That is, when the shutter is opened, the catalyst can be supplied from the catalyst supply unit 30 to the processing unit 10, and when the shutter is closed, the catalyst supply can be stopped.
이러한 촉매로는 알칼리 용매를 사용할 수 있으며, 예를 들어, 암모니아, 수산화나트륨, 수산화칼슘, 수산화칼륨, 수산화인 및 황화나트륨으로 이루어진 군에서 선택되는 적어도 어느 하나를 포함하는 알칼리 용매를 사용할 수 있다. 이러한 촉매는 처리부(10) 내부의 pH를 변화시켜 음식물류 폐기물에 포함된 유분을 녹게 하여 음식물류 폐기물의 가용성을 상승 시킨다.As the catalyst, an alkali solvent may be used, and for example, an alkali solvent containing at least one selected from the group consisting of ammonia, sodium hydroxide, calcium hydroxide, potassium hydroxide, phosphorus hydroxide, and sodium sulfide may be used. Such a catalyst changes the pH inside the processing unit 10 to melt the oil contained in the food waste, thereby increasing the availability of the food waste.
일 실시예에 있어서, 음식물류 폐기물 공급부(20) 및 촉매 공급부(30) 내부에 구비된 각각의 셔터를 제어할 수 있는 셔터 제어부(미도시)를 포함할 수 있다. 셔터 제어부는 셔터의 개폐 시간 및 개폐 속도를 제어할 수 있다. 예를 들어, 셔터의 개방 시간을 10초 간격으로 설정할 경우, 음식물류 폐기물 공급부(20)와 촉매 공급부(30) 내부에 구비된 셔터는 일 시점에서 개방되어 폐쇄 후, 10초 후에 다시 개방되어 음식물류 폐기물과 촉매를 처리부(10) 내부로 공급할 수 있다.In one embodiment, it may include a shutter control unit (not shown) that can control each shutter provided in the food waste supply unit 20 and the catalyst supply unit 30. The shutter control unit may control the opening and closing speed of the shutter. For example, when the opening time of the shutter is set at intervals of 10 seconds, the shutters provided inside the food waste supply unit 20 and the catalyst supply unit 30 are opened at one point, closed, and then opened again after 10 seconds to open the food waste. And a catalyst can be supplied into the processing unit 10.
또는, 음식물류 폐기물의 처리 양에 비해 촉매의 양이 많을 경우, 음식물류 폐기물 공급부(20)의 셔터는 10초 간격으로 개방시키고, 촉매 공급부(30)의 셔터는 20초 간격으로 개방시킬 수도 있다.Alternatively, when the amount of catalyst is greater than the amount of food waste treated, the shutter of the food waste supply unit 20 may be opened at 10 second intervals, and the shutter of the catalyst supply unit 30 may be opened at 20 second intervals.
일 실시예에 있어서, 배출부(40)는 내부에 스크류(41)를 구비하여 처리부(10)에 의해 분해(전처리)된 음식물류 폐기물을 외부로 배출하는 것으로서, 처리부(10)의 하단 일측에 연결될 수 있다. 음식물류 폐기물 공급부(20)에 의해 공급되는 음식물류 폐기물의 양이 일정 수준 이상 축적되면 그 압력에 의해 분해된 음식물류 폐기물이 배출부(40)로 이동하므로, 배출부(40)는 되도록 처리부(10)의 바닥 높이에 가깝게 형성되는 것이 바람직하다.In one embodiment, the discharge unit 40 is provided with a screw 41 therein to discharge food wastes decomposed (pre-treated) by the treatment unit 10 to the outside, and be connected to one side of the lower end of the treatment unit 10 Can. When the amount of food wastes supplied by the food wastes supply unit 20 accumulates over a certain level, the food wastes decomposed by the pressure move to the discharge unit 40, so that the discharge unit 40 becomes the discharge unit 40. It is preferably formed close to the floor height.
일 실시예에 있어서, 스크류(41)는 다양한 형태의 스크류(41)를 사용할 수 있다. 스크류(41)의 직경이 균일한 것을 사용할 수 있고, 스크류(41) 중간 부분의 직경이 가장 작은 것을 사용할 수도 있으며, 스크류(41)의 직경이 불규칙한 것을 사용할 수도 있다. 여기에서, 스크류(41)의 직경은 스크류(41)의 회전축을 중심으로 스크류(41) 날의 끝부분까지의 길이를 의미한다.In an embodiment, the screw 41 may use various types of screw 41. A screw 41 having a uniform diameter may be used, a screw 41 having the smallest diameter may be used, and a screw 41 having an irregular diameter may be used. Here, the diameter of the screw 41 means the length to the end of the blade of the screw 41 around the rotation axis of the screw 41.
바람직하게, 스크류(41)는 일측의 직경이 타측의 직경보다 큰 것을 사용할 수 있다. 구체적으로, 도 1에 도시된 것처럼, 처리부(10)와 인접한 일측의 직경이 크고, 처리부(10)와 먼 타측의 직경이 상대적으로 작을 수 있다. 즉, 처리부(10)와 인접한 스크류(41)의 직경을 반대편의 직경보다 크게 형성함으로써 처리부(10)에서 멀어질수록 힘의 구동력이 더 좋게 디자인되어 음식물류 폐기물이 스크류(41)에 의해 밀리지 않아 발생할 수 있는 막힘 현상을 방지할 수 있다.Preferably, the screw 41 may be used in which the diameter of one side is larger than the diameter of the other side. Specifically, as shown in FIG. 1, the diameter of one side adjacent to the processing unit 10 may be large, and the diameter of the other side distant from the processing unit 10 may be relatively small. That is, by forming the diameter of the screw 41 adjacent to the processing unit 10 larger than the diameter of the opposite side, the farther away from the processing unit 10, the better the driving force of the force is designed, so that food waste is not pushed by the screw 41 It can prevent clogging.
일 실시예에 있어서, 배출부(40)는 처리부(10)로부터 이송된 음식물류 폐기물이 처리부(10)로 역류하는 것을 방지하는 역류방지부재(60);를 포함할 수 있다. 역류방지부재(60)는 분쇄된 음식물류 폐기물과 함께 볼(14)이 유입되는 것을 방지할 수 있다. 이를 위해, 역류방지부재(60)는 복수의 홀이 형성된 원형 부재; 및 일방향으로만 개방되는 게이트;를 포함할 수 있다. 복수의 홀이 형성된 원형 부재는 일반적으로 사용하는 모기장과 같은 메쉬망일 수 있다. 이때, 홀은 원형의 홀일 수 있고, 홀의 크기는 분쇄된 음식물류 폐기물은 통과하되, 볼(14)은 통과하지 못할 정도의 크기로 형성하는 것이 바람직하다. 분쇄되는 음식물류 폐기물의 평균 직경은 200㎛ 내외이므로, 홀의 직경은 0.3 ~ 1mm인 것이 바람직하다. 또한, 게이트는 음식물류 폐기물이 처리부(10)로부터 배출부(40)로 이동할 때는 개방될 수 있고, 반대 방향으로는 개방되지 않는다.In one embodiment, the discharge unit 40 may include a backflow prevention member 60 for preventing the food waste transported from the treatment unit 10 from flowing back to the treatment unit 10. The backflow prevention member 60 can prevent the balls 14 from being introduced together with the crushed food waste. To this end, the backflow prevention member 60 includes a circular member having a plurality of holes; And a gate that opens only in one direction. The circular member having a plurality of holes may be a mesh network such as a mosquito net that is generally used. In this case, the hole may be a circular hole, and the size of the hole is preferably formed to a size such that the pulverized food waste is passed, but the ball 14 cannot pass. Since the average diameter of the food waste to be crushed is about 200 µm, the hole diameter is preferably 0.3 to 1 mm. In addition, the gate may be opened when food waste is moved from the treatment unit 10 to the discharge unit 40, and is not opened in the opposite direction.
일 실시예에 있어서, 배출부(40)는 연결부재(42)를 포함할 수 있다. 도 2는 본 발명의 일 실시예에 따른 음식물류 폐기물 처리장치(100)를 개략적으로 나타낸 도면으로, 이를 참조하여 설명하면, 연결부재(42)는 배출부(40)와 처리부(10) 사이에 설치되어 음식물류 폐기물이 이동할 수 있도록 하는 것으로서, 처리부(10)에 대해 상방향으로 비스듬하게 연결되는 것이 바람직하다. 일 예로, 처리부(10)에 대해서 45도 각도로 연결될 수 있다. 역류방지부재(60)가 음식물류 폐기물의 역류를 방지하고, 볼(14)의 유입을 방지하기 위한 것이나, 볼(14)과의 충돌에 의해 역류방지부재(60)가 파손되면 볼(14)이 유입될 수 있고, 이로 인해 배출부(40) 내부의 스크류(41)가 파손될 수 있다. 그러나, 연결부재(42)가 형성될 경우, 음식물류 폐기물은 압력에 의해 배출부(40)로 밀려 올라가되, 볼(14)은 무게로 인해(평균 밀도 약 8g/cm3, 평균 무게 4g) 배출부(40)로 이동하기 제한된다.In one embodiment, the discharge unit 40 may include a connecting member 42. 2 is a view schematically showing a food waste treatment apparatus 100 according to an embodiment of the present invention. Referring to this, the connection member 42 is installed between the discharge unit 40 and the treatment unit 10 It is made to be able to move the food and beverage waste, it is preferable to be connected obliquely in the upward direction with respect to the treatment unit (10). For example, it may be connected to the processing unit 10 at an angle of 45 degrees. The backflow prevention member 60 prevents the backflow of food waste, and prevents the inflow of the ball 14, but when the backflow prevention member 60 is damaged by a collision with the ball 14, the ball 14 It may be introduced, and thereby the screw 41 inside the discharge part 40 may be damaged. However, when the connecting member 42 is formed, the food waste is pushed up to the discharge unit 40 by pressure, but the ball 14 is discharged due to the weight (average density of about 8 g/cm 3 , average weight of 4 g). It is restricted to move to the part 40.
다음으로, 바이오가스의 생산성을 향상시킬 수 있는 음식물류 폐기물 처리방법에 대해 설명한다. 본 발명을 설명하는데 있어 설명의 편의를 위하여 상술한 음식물류 폐기물 처리장치(100)를 예로 들어 설명하나, 이에 한정되는 것은 아니다. 또한, 중복되는 부분에 있어서는 설명을 생략하도록 한다.Next, a method of treating food wastes that can improve the productivity of biogas will be described. For convenience of explanation in describing the present invention, the above-described food waste disposal apparatus 100 will be described as an example, but is not limited thereto. In addition, description is omitted in the overlapping portion.
본 발명의 일 실시예에 따른 음식물류 폐기물 처리방법은 처리부(10) 내부로 음식물류 폐기물을 공급하는 음식물류 폐기물 공급단계; 처리부(10) 내부로 음식물류 폐기물을 분해하기 위한 촉매를 공급하는 촉매 공급단계; 처리부(10) 내부로 공급되는 음식물류 폐기물 및 촉매를 혼합기(11)를 이용하여 혼합 및 분쇄하는 음식물류 폐기물 처리단계; 처리부 내부로 공급되는 음식물류 폐기물을 초음파 발생장치(70)를 이용하여 분쇄하는 초음파 처리단계; 및 처리부(10)로부터 이송된 음식물류 폐기물을 스크류(41)를 이용하여 외부로 배출하는 음식물류 폐기물 배출단계;를 포함한다. 본 발명은 음식물류 폐기물과 음식물류 폐기물을 분해할 수 있는 촉매를 함께 공급한 후, 이들을 혼합 및 분쇄함으로써 음식물류 폐기물을 화학적/물리적으로 처리하여 가용성을 높일 수 있다. 음식물류 폐기물이 지속적으로 공급되어 어느 정도 분쇄 및 분해가 진행되면, 축적된 음식물류 폐기물의 압력에 의해 하부에 분쇄된 음식물류 폐기물이 외부로 배출되는데, 이때, 스크류(41)를 활용하여 처리된 음식물류 폐기물을 효과적으로 배출함으로써 음식물류 폐기물을 연속적으로 처리할 수 있는 효과를 가진다.The food waste treatment method according to an embodiment of the present invention includes a food waste supply step of supplying food waste to the processing unit 10; A catalyst supply step of supplying a catalyst for decomposing food waste into the processing unit 10; A food waste treatment step of mixing and pulverizing food waste and catalyst supplied to the processing unit 10 using a mixer 11; An ultrasonic treatment step of crushing the food waste supplied to the processing unit using an ultrasonic generator 70; And a food waste discharge step of discharging the food waste transported from the processing unit 10 to the outside using a screw 41. The present invention can supply food catalysts and catalysts capable of decomposing food wastes together, and then mix and crush them to chemically and physically treat food wastes, thereby increasing availability. When food wastes are continuously supplied and crushed and decomposed to some extent, the food wastes crushed underneath are discharged to the outside by the pressure of the accumulated food wastes. At this time, the processed food wastes are utilized by using a screw (41). By effectively discharging, it has an effect of continuously processing food wastes.
일 실시예에 있어서, 음식물류 폐기물 공급단계는 음식물류 폐기물을 처리부(10) 내부로 공급하는 단계로, 음식물류 폐기물의 상태는 특별히 제한되지 않는다. 즉, 음식물류 폐기물은 고체 상태일 수도 있고, 슬러리 상태일 수도 있다. 또한, 음식물류 폐기물 공급단계는, 음식물류 폐기물 공급부(20) 내부에 구비된 셔터를 제어하는 셔터 제어단계를 포함할 수 있다. 셔터 제어단계는 셔터의 개폐 시간 및 개폐 속도를 제어할 수 있다. 예를 들어, 셔터의 개방 시간을 10초 간격으로 설정할 경우, 음식물류 폐기물 공급부(20) 내부에 구비된 셔터는 일 시점에서 개방되어 폐쇄 후, 10초 후에 다시 개방되어 음식물류 폐기물을 처리부(10) 내부로 공급할 수 있다.In one embodiment, the food waste supply step is a step of supplying the food waste to the interior of the treatment unit 10, the state of the food waste is not particularly limited. That is, the food waste may be in a solid state or a slurry state. In addition, the food waste supplying step may include a shutter control step of controlling the shutter provided inside the food waste supplying unit 20. The shutter control step may control the opening/closing time and opening/closing speed of the shutter. For example, when the opening time of the shutter is set at an interval of 10 seconds, the shutter provided inside the food and beverage waste supply unit 20 is opened at one point and then closed, and then opened again after 10 seconds to process the food and beverage waste inside the processing unit 10 Can be supplied.
일 실시예에 있어서, 촉매 공급단계는 처리부(10) 내부로 음식물류 폐기물을 분해하기 위한 촉매를 공급하는 단계로, 이러한 촉매로는 알칼리 용매를 사용할 수 있으며, 예를 들어, 암모니아, 수산화나트륨, 수산화칼슘, 수산화칼륨, 수산화인 및 황화나트륨으로 이루어진 군에서 선택되는 적어도 어느 하나를 포함하는 알칼리 용매를 사용할 수 있다. 이러한 촉매는 pH를 변화시켜 음식물류 폐기물에 포함된 유분을 녹게 하여 음식물류 폐기물의 가용성을 상승 시킨다.In one embodiment, the catalyst supply step is a step of supplying a catalyst for decomposing food waste into the processing unit 10, and an alkali solvent may be used as the catalyst, for example, ammonia, sodium hydroxide, and calcium hydroxide , An alkali solvent containing at least any one selected from the group consisting of potassium hydroxide, phosphorus hydroxide and sodium sulfide may be used. These catalysts change the pH to melt the oil contained in the food waste, thereby increasing the availability of the food waste.
또한, 촉매 공급단계는 촉매 공급부(30) 내부에 구비된 셔터를 제어하는 셔터 제어단계를 포함할 수 있다. 셔터 제어단계는 셔터의 개폐 시간 및 개폐 속도를 제어할 수 있다. 예를 들어, 셔터의 개방 시간을 10초 간격으로 설정할 경우, 촉매 공급부(30) 내부에 구비된 셔터는 일 시점에서 개방되어 폐쇄 후, 10초 후에 다시 개방되어 촉매를 처리부(10) 내부로 공급할 수 있다.In addition, the catalyst supply step may include a shutter control step for controlling the shutter provided inside the catalyst supply unit 30. The shutter control step may control the opening/closing time and opening/closing speed of the shutter. For example, when the shutter opening time is set at an interval of 10 seconds, the shutter provided inside the catalyst supply unit 30 is opened at one point and closed, and then opened again after 10 seconds to supply the catalyst into the processing unit 10. Can.
일 실시예에 있어서, 음식물류 폐기물 처리단계는 처리부(10) 내부에 구비된 혼합기(11)를 이용하여 내부로 공급되는 음식물류 폐기물 및 촉매를 혼합 및 분쇄하는 단계로, 혼합기(11)는 처리부(10) 내부에 종방향으로 형성된 회전축(12); 및 회전축(12)과 수직방향으로 회전축(12)에 구비된 복수의 회전날개(13);를 포함할 수 있다. 회전축(12)은 모터와 연결되어 시계 방향 또는 반시계 방향으로 회전할 수 있고, 효율적인 교반 및 분쇄를 위하여 50~450rpm의 속도로 회전하는 것이 바람직하며, 150~350rpm의 속도로 회전하는 것이 더욱 바림직하다. 또한, 회전날개(13)는 원기둥 형상일 수 있으나, 이에 제한되는 것은 아니고, 목적에 따라 다양한 형상으로 제조할 수 있다.In one embodiment, the food waste treatment step is a step of mixing and pulverizing the food waste and catalyst supplied therein using a mixer 11 provided inside the treatment unit 10, the mixer 11 is a treatment unit 10 ) A rotating shaft 12 formed in the longitudinal direction inside; And a plurality of rotating blades 13 provided on the rotating shaft 12 in a direction perpendicular to the rotating shaft 12. The rotating shaft 12 is connected to the motor and can rotate clockwise or counterclockwise, and it is preferable to rotate at a speed of 50 to 450 rpm for efficient stirring and grinding, and more preferably to rotate at a speed of 150 to 350 rpm Work In addition, the rotary blade 13 may have a cylindrical shape, but is not limited thereto, and may be manufactured in various shapes according to the purpose.
일 실시예에 있어서, 음식물류 폐기물 처리단계는 음식물류 폐기물을 효과적으로 처리하기 위하여 마멸 분쇄 방식을 이용할 수 있다. 이를 위하여 처리부(10) 내부에 구비된 혼합기(11)에 의해 병진운동 또는 회전운동을 하는 볼(14)을 포함할 수 있다. 이러한 볼(14)로는 공지의 다양한 재료를 이용하여 제조된 볼을 사용할 수 있으나, 스틸 볼(Steel ball), 지르코니아(ZrO2) 볼(Zrconia ball) 또는 알루미나 볼(Alumina ball)을 사용하는 것이 바람직하다. 도 3은 마멸분쇄 방식의 원리를 설명하는 도면으로, 이를 참조하여 구체적으로 설명하면, 혼합기(11)에 의해서 처리부(10) 내에 힘의 구배를 유도하고, 힘의 구배가 형성된 처리부(10) 내에서 볼(14) 간의 마찰을 유도하여 공급되는 음식물류 폐기물을 분쇄하는 원리이다. 마멸분쇄(attrition mill) 방식을 이용하여 물리적 처리를 수행함과 동시에 음식물류 폐기물과 촉매를 혼합하여 화학적 처리를 수행할 수 있다.In one embodiment, the food waste treatment step may use abrasion grinding method to effectively treat the food waste. To this end, it may include a ball 14 that performs translational or rotational movement by the mixer 11 provided inside the processing unit 10. As the ball 14, a ball manufactured using a variety of known materials can be used, but it is preferable to use a steel ball, a zirconia ball (ZrO 2 ) ball, or an alumina ball. Do. 3 is a view for explaining the principle of the abrasion and crushing method, and specifically described with reference to this, induces a gradient of force in the processing unit 10 by the mixer 11, and a gradient of force is formed in the processing unit 10 The principle is to crush the food waste supplied by inducing friction between the balls (14). Physical treatment may be performed using an attrition mill method, and chemical treatment may be performed by mixing food waste and a catalyst.
이때, 혼합기(11)의 회전축(12)은 50~450rpm의 속도로 회전하는 것이 바람직하며, 150~350rpm의 속도로 회전하는 것이 더욱 바람직하다. 회전 속도가 50rpm 미만일 경우, 분쇄가 충분히 이루어지지 않아 분쇄 효율이 떨어지고, 450rpm을 초과하는 경우, 고성능의 모터가 필요하고, 추가적인 분쇄 효과를 얻기 어려우므로 비경제적이다.At this time, the rotating shaft 12 of the mixer 11 is preferably rotated at a speed of 50 ~ 450rpm, more preferably rotated at a speed of 150 ~ 350rpm. When the rotational speed is less than 50 rpm, the grinding efficiency is insufficient due to insufficient grinding, and when it exceeds 450 rpm, a high-performance motor is required, and it is difficult to obtain an additional grinding effect, which is uneconomical.
또한, 볼(14)의 직경은 1~10mm인 것이 바람직하며, 더욱 바람직하게는 3~10mm일 수 있다. 1mm 미만인 경우, 볼(14)에 의한 충분한 분쇄 효과를 가질 수 없고, 10mm를 초과하는 경우, 음식물류 폐기물 분쇄시 볼(14) 간의 충돌에 의해 볼(14)이 파손될 우려가 있다.In addition, the diameter of the ball 14 is preferably 1 to 10 mm, more preferably 3 to 10 mm. If it is less than 1 mm, it cannot have a sufficient crushing effect by the ball 14, and if it exceeds 10 mm, there is a fear that the ball 14 may be damaged by collision between the balls 14 when crushing food waste.
일 실시예에 있어서, 음식물류 폐기물 처리단계는 처리부(10) 내부의 온도를 조절할 수 있는 온도 제어단계를 포함할 수 있다. 음식물류 폐기물의 물리적 처리방법과 달리 화학적 처리방법의 경우, 적절한 온도로 유지하는 것이 중요하고, 음식물류 폐기물을 화학적으로 처리하기 위해서 처리부(10)의 내부를 60~150℃로 제어하는 것이 바람직하다. 60℃ 미만의 경우, 느린 반응속도로 인해 반응시간 증가되며, 음식물류 폐기물의 가용성 상승 효과가 떨어지는 문제점이 있고, 150℃를 초과하는 경우 수분 증발 효과가 커져서 음식물류 폐기물의 가용성 상승 효과가 감소되는 문제점이 있다.In one embodiment, the food waste treatment step may include a temperature control step that can adjust the temperature inside the treatment unit 10. Unlike the physical treatment method of food waste, in the case of the chemical treatment method, it is important to maintain an appropriate temperature, and it is preferable to control the inside of the treatment unit 10 to 60 to 150°C to chemically treat the food waste. In the case of less than 60 ℃, the reaction time is increased due to the slow reaction rate, there is a problem that the synergistic effect of the food waste is falling, and when it exceeds 150 ℃, the evaporation effect of water is increased, so the problem of the synergistic effect of the food waste is reduced. have.
일 실시예에 있어서, 초음파 처리단계는 음식물류 폐기물을 초음파 발생장치(70)를 이용하여 분해하는 단계로서, 초음파(ultrasonic)를 이용하여 처리부(10) 내부로 공급된 음식물류 폐기물에 진동을 주어 분해할 수 있다. 음식물류 폐기물에 초음파(Ultrasonic)가 전달될 때 초음파의 큰 압력변화에 의해 미세기포군이 생성되고 소멸되는 현상으로 매우 큰 압력이 동반하게 된다. 이 압력이 수백분의 1초에서 수천분의 1초 단위의 짧은 시간 동안 발생하게 됨에 따라 음식물류 폐기물 분해 효과가 극대화 되어 음식물류 폐기물의 가용성이 상승된다. 이러한 초음파 발생장치(70)로는 2만 Hz이상의 음파를 발생하는 초음파 발생장치를 사용할 수 있으며, 바람직하게는 25,000~40,000Hz의 음파를 발생하는 초음파 발생장치를 사용할 수 있다. 초음파의 진동수가 25,000Hz 미만인 경우 음식물류 폐기물의 분해효과가 미미하며, 초음파의 진동수가 40,000Hz 초과인 경우 추가적인 가용성 상승효과를 얻기 어렵고 많은 전력이 필요하여 비경제적이다.In one embodiment, the ultrasonic treatment step is a step of decomposing the food waste by using an ultrasonic generator (70), using ultrasonic waves (ultrasonic) to decompose the food waste supplied into the processing unit 10 by vibration Can. When ultrasonic (Ultrasonic) is transmitted to food waste, it is a phenomenon in which micro-bubble groups are generated and disappeared due to the large pressure change of ultrasonic waves, which is accompanied by very large pressure. As this pressure occurs for a short period of time from hundredths of a second to several thousandths of a second, the effect of decomposing food waste is maximized, increasing the availability of food waste. As the ultrasonic generator 70, an ultrasonic generator that generates sound waves of 20,000 Hz or more can be used. Preferably, an ultrasonic generator that generates sound waves of 25,000 to 40,000 Hz can be used. When the frequency of ultrasonic waves is less than 25,000Hz, the decomposition effect of food waste is negligible. When the frequency of ultrasonic waves exceeds 40,000Hz, it is difficult to obtain an additional synergistic effect and requires a lot of power, which is uneconomical.
일 실시예에 있어서, 음식물류 폐기물 배출단계는 처리부(10)로부터 이송된 음식물류 폐기물을 스크류(41)를 이용하여 외부로 배출하는 단계로서, 스크류(41)는 다양한 형태의 스크류(41)를 사용할 수 있다. 스크류(41)의 직경이 균일한 것을 사용할 수 있고, 스크류(41) 중간 부분의 직경이 가장 작은 것을 사용할 수도 있으며, 스크류(41)의 직경이 불규칙한 것을 사용할 수도 있다. 여기에서, 스크류(41)의 직경은 스크류(41)의 회전축을 중심으로 스크류(41) 날의 끝부분까지의 길이를 의미한다. 바람직하게, 스크류(41)는 일측의 직경이 타측의 직경보다 큰 것을 사용할 수 있다. 구체적으로, 처리부(10)와 인접한 일측의 직경이 크고, 처리부(10)와 먼 타측의 직경이 상대적으로 작을 수 있다. 즉, 처리부(10)와 인접한 스크류(41)의 직경을 반대편의 직경보다 크게 형성함으로써 처리부(10)에서 멀어질수록 힘의 구동력이 더 좋게 디자인되어 음식물류 폐기물이 스크류(41)에 의해 밀리지 않아 발생할 수 있는 막힘 현상을 방지할 수 있다.In one embodiment, the food waste discharging step is a step of discharging the food waste transported from the processing unit 10 to the outside using a screw 41, the screw 41 can use various types of screws (41) have. A screw 41 having a uniform diameter may be used, a screw 41 having the smallest diameter may be used, and a screw 41 having an irregular diameter may be used. Here, the diameter of the screw 41 means the length to the end of the blade of the screw 41 around the rotation axis of the screw 41. Preferably, the screw 41 may be used in which the diameter of one side is larger than the diameter of the other side. Specifically, the diameter of one side adjacent to the processing unit 10 is large, and the diameter of the other side distant from the processing unit 10 may be relatively small. That is, by forming the diameter of the screw 41 adjacent to the processing unit 10 larger than the diameter of the opposite side, the farther away from the processing unit 10, the better the driving force of the force is designed, so that food waste is not pushed by the screw 41 It can prevent clogging.
이하에서는 실시예와 비교예를 통하여 본 발명의 구성 및 그에 따른 효과를 보다 상세히 설명하고자 한다. 하지만, 이러한 실시예들은 본 발명을 보다 구체적으로 설명하기 위한 것이며, 본 발명의 범위가 이들 실시예에 한정되는 것은 아님을 밝혀둔다.Hereinafter, the configuration of the present invention and its effects will be described in more detail through examples and comparative examples. However, these examples are intended to illustrate the present invention in more detail, and it is revealed that the scope of the present invention is not limited to these examples.
[실시예 1][Example 1]
본 발명의 음식물류 폐기물 처리장치(도 1 참조)로 볼을 이용해 음식물류 폐기물을 전처리하였다. 이때, 촉매 및 초음파 발생장치는 사용하지 않았으며, 지르코니아 볼(Zrconia ball)을 이용하여 10분 동안 음식물류 폐기물을 분쇄하였다.Food waste was pretreated using a ball as a food waste disposal apparatus (see FIG. 1) of the present invention. At this time, the catalyst and the ultrasonic generator were not used, and the food waste was crushed for 10 minutes using a zirconia ball.
[실시예 2][Example 2]
실시예 1과 동일한 조건에서 음식물류 폐기물을 분쇄하되, 60분 동안 음식물류 폐기물을 분쇄하였다.The food waste was crushed under the same conditions as in Example 1, but the food waste was crushed for 60 minutes.
[실시예 3][Example 3]
실시예 1과 동일한 조건에서 음식물류 폐기물을 분쇄하되, 120분 동안 음식물류 폐기물을 분쇄하였다.The food waste was crushed under the same conditions as in Example 1, but the food waste was crushed for 120 minutes.
[실험예 1][Experimental Example 1]
실시예 1 내지 3에 의해 전처리 된 음식물류 폐기물 및 전처리 하지 않은 음식물류 폐기물(비교예 1)의 화학적 산소요구량(COD, chemical oxygen demand)를 중크롬산칼륨법(CODcr)을 통해 측정하였다. 구체적으로, 각각의 플라스크에 실시예 1 내지 3 및 비교예 1의 음식물류 폐기물을 희석하여 넣은 후, HgSO4 5ml 투입하여 HgSO4를 완전히 녹였다. HgSO4를 완전히 녹인 후, 각각의 플라스크에 중크롬산칼륨용액 25ml을 투입하고 bolling stone을 넣었다. 그 후, 각각의 플라스크에 5.5g Ag2SO4 / 1kg HgSO4 용액 70mL을 투입한 후 2시간 동안 Reflux하여 COD를 측정하여 그 결과를 표 1에 나타내었다.The chemical oxygen demand (COD) of the food wastes pretreated and the food wastes (Comparative Example 1) pretreated by Examples 1 to 3 was measured through potassium dichromate (CODcr). Specifically, after inserting carried diluted food waste of Example 1 to 3 and Comparative Examples 1 to each flask, HgSO 4 5ml added to dissolved the HgSO 4 completely. After completely dissolving HgSO 4 , 25 ml of potassium dichromate solution was added to each flask and bolling stone was added. Thereafter, 70 mL of 5.5 g Ag2SO4 / 1 kg HgSO4 solution was added to each flask, followed by Reflux for 2 hours to measure COD, and the results are shown in Table 1.
실시예 1Example 1 실시예 2Example 2 실시예 3Example 3 비교예 1Comparative Example 1
SCOD/TCOD 증가율(%)SCOD/TCOD increase rate (%) 15.6315.63 32.4332.43 0.710.71 --
표 1의 결과를 통해 확인할 수 있듯이, SCOD/TCOD가 실시예 1 내지 3에서 증가되며, 특히 볼을 이용해 60분 동안 음식물류 폐기물을 분쇄한 실시예 2에서 가장 크게 증가함을 알 수 있었다. SCOD(Soluble Chemical Oxygen Demand)는 용해성이 있는 화학적 산소 요구량을 의미하며, TCOD(Total Chemical Oxygen Demand)는 전체 화학적 산소 요구량을 의미하는 것으로, SCOD/TCOD가 증가한다는 것은, 전체 COD중에 용해성이 있는 COD가 증가해서 미생물이 분해할 수 있는 영역이 더 커지는 것을 의미한다. 따라서 전처리 하지 않은 음식물류 폐기물(비교예 1) 보다 전처리한 실시예 1 내지 3에서 미생물이 분해할 수 있는 영역이 더 커져 바이오가스의 생산성이 증가됨을 알 수 있었다.As can be seen through the results in Table 1, it was found that SCOD/TCOD is increased in Examples 1 to 3, and in particular, in Food Example 2 in which food waste was crushed for 60 minutes using a ball, the greatest increase was found. SCOD (Soluble Chemical Oxygen Demand) means soluble chemical oxygen demand, TCOD (Total Chemical Oxygen Demand) means total chemical oxygen demand, and SCOD/TCOD increases, COD soluble in total COD Means that the area where microorganisms can decompose increases. Therefore, it was found that in Examples 1 to 3, where the microorganisms could be decomposed, the biogas productivity was increased in the Examples 1 to 3, which were pretreated, than the food wastes (Comparative Example 1) that were not pretreated.
[실시예 4][Example 4]
본 발명의 음식물류 폐기물 처리장치(도 1 참조)로 음식물류 폐기물을 전처리하였다. 이때, 초음파 발생장치는 사용하지 않았으며, 촉매로는 NaOH(pH=11)을 넣고, 지르코니아 볼(Zrconia ball)을 이용하여 10분 동안 음식물류 폐기물을 분쇄하였다.The food waste was pretreated with the food waste disposal apparatus (see FIG. 1) of the present invention. At this time, the ultrasonic generator was not used, and NaOH (pH=11) was added as a catalyst, and food waste was crushed for 10 minutes using a zirconia ball.
[실시예 5][Example 5]
본 발명의 음식물류 폐기물 처리장치(도 1 참조)로 음식물류 폐기물을 전처리하였다. 이때, 촉매 및 초음파 발생장치는 사용하지 않았으며, 80℃에서 10분 동안 지르코니아 볼(Zrconia ball)을 이용하여 음식물류 폐기물을 분쇄하였다.The food waste was pretreated with the food waste disposal apparatus (see FIG. 1) of the present invention. At this time, the catalyst and the ultrasonic generator were not used, and food wastes were crushed using a zirconia ball at 80°C for 10 minutes.
[실시예 6][Example 6]
본 발명의 음식물류 폐기물 처리장치(도 1 참조)로 음식물류 폐기물을 전처리하였다. 이때, 촉매는 사용하지 않았으며, 10분 동안 지르코니아 볼(Zrconia ball)을 이용하여 음식물류 폐기물을 분쇄하고, 초음파 발생장치를 통해 30,000Hz의 음파로 30분 동안 음식물류 폐기물을 분해 하였다.The food waste was pretreated with the food waste disposal apparatus (see FIG. 1) of the present invention. At this time, the catalyst was not used, and the food waste was crushed using a zirconia ball for 10 minutes, and the food waste was decomposed for 30 minutes with a sound wave of 30,000 Hz through an ultrasonic generator.
[실험예 2][Experimental Example 2]
실험예 1과 동일한 방법으로 실시예 4 내지 5에 의해 전처리 된 음식물류 폐기물의 화학적 산소요구량(COD, chemical oxygen demand)를 측정하고 그 결과를 표 2에 나타내었다.In the same manner as in Experimental Example 1, chemical oxygen demand (COD) of food wastes pretreated by Examples 4 to 5 was measured and the results are shown in Table 2.
실시예 1Example 1 실시예 4Example 4 실시예 5Example 5 실시예 6Example 6
SCOD/TCOD 증가율(%)SCOD/TCOD increase rate (%) 15.6315.63 17.8017.80 24.6224.62 38.0138.01
표 2의 결과를 통해 확인할 수 있듯이, 볼밀을 이용해 분쇄만 실시한 실시예 1에 비해 촉매, 초음파 등으로 병합처리한 실시예 4 내지 6에서 SCOD/TCOD가 크게 증가함을 확인할 수 있었다. 특히 초음파를 이용한 실시예 6에서 SCOD/TCOD가 가장 크게 증가하였다. 상술한 것과 같이, SCOD/TCOD의 증가율이 높은 실시예 4 내지 6에서 미생물이 분해할 수 있는 영역이 더 크며, 이에 따라 실시예 4 내지 6의 음식물류 폐기물에서 바이오가스의 생산성이 증가됨었음을 알 수 있었다.As can be seen through the results in Table 2, it was confirmed that SCOD/TCOD was significantly increased in Examples 4 to 6, which were combined with catalyst, ultrasonic waves, etc., compared to Example 1 in which only grinding was performed using a ball mill. In particular, in Example 6 using ultrasound, SCOD/TCOD was the largest increase. As described above, it can be seen that in Examples 4 to 6 in which the increase rate of SCOD/TCOD is high, the area where microorganisms can decompose is larger, and accordingly, the productivity of biogas in food wastes of Examples 4 to 6 was increased. there was.
[실시예 7][Example 7]
실시예 1과 동일한 조건에서 음식물류 폐기물을 전처리 하되, 지르코니아 볼(Zrconia ball)을 대신하여 스틸 볼(Steel ball)을 사용하였다.Under the same conditions as in Example 1, the food waste was pretreated, but a steel ball was used in place of the zirconia ball.
[실시예 8][Example 8]
실시예 1과 동일한 조건에서 음식물류 폐기물을 전처리 하되, 지르코니아 볼(Zrconia ball)을 대신하여 알루미나 볼(Alumina ball)을 사용하였다.Food waste was pre-treated under the same conditions as in Example 1, but instead of a zirconia ball, an alumina ball was used.
[실험예 3][Experimental Example 3]
실험예 1과 동일한 방법으로 실시예 7 및 8에 의해 전처리 된 음식물류 폐기물의 화학적 산소요구량(COD, chemical oxygen demand)를 측정하고 그 결과를 표 3에 나타내었다.In the same manner as in Experimental Example 1, chemical oxygen demand (COD) of food wastes pretreated by Examples 7 and 8 was measured, and the results are shown in Table 3.
실시예 1Example 1 실시예 7Example 7 실시예 8Example 8 비교예 1Comparative Example 1
SCOD/TCOD 증가율(%)SCOD/TCOD increase rate (%) 15.6315.63 40.2940.29 8.068.06 --
표 3의 결과를 통해 확인할 수 있듯이, SCOD/TCOD가 실시예 7 및 8에서 증가되며, 특히 스틸 볼(steel ball)이용한 실시예 7의 SCOD/TCOD가 가장 크게 증가함을 알 수 있었다. 즉, SCOD/TCOD의 증가율이 높은 실시예 7에서 미생물이 분해할 수 있는 영역이 더 크며, 이에 따라 실시예 7의 음식물류 폐기물에서 바이오가스의 생산성이 향상되었음을 알 수 있었다.As can be seen through the results of Table 3, it was found that SCOD/TCOD is increased in Examples 7 and 8, and in particular, SCOD/TCOD of Example 7 using a steel ball is most increased. That is, it was found that in Example 7 in which the increase rate of SCOD/TCOD is high, the area where microorganisms can decompose is larger, and accordingly, the productivity of biogas in food waste of Example 7 is improved.
본 명세서에서는 본 발명자들이 수행한 다양한 실시예 가운데 몇 개의 예만을 들어 설명하는 것이나 본 발명의 기술적 사상은 이에 한정하거나 제한되지 않고, 당업자에 의해 변형되어 다양하게 실시될 수 있음은 물론이다.In this specification, only a few examples of the various embodiments performed by the present inventors are described, but the technical spirit of the present invention is not limited to or limited thereto, and can be variously implemented by a person skilled in the art.
본 발명은 음식물류 폐기물의 가용성을 높여, 음식물류 폐기물을 이용한 바이오가스의 생산성을 향상시킬 수 있는 음식물류 폐기물 처리장치 및 이를 이용한 음식물류 폐기물 처리방법을 제공하기 위한 것으로, 화학적 방법과 물리적 방법을 동시에 사용하여 음식물류 폐기물을 전처리함으로써 바이오가스의 생산성을 향상시킬 수 있고, 처리되는 음식물류 폐기물 양만큼 미처리된 음식물류 폐기물을 재투입하여 연속적인 처리가 가능하므로, 산업상 이용가능성이 있다.The present invention is to provide a food waste treatment apparatus and a food waste treatment method using the same, by increasing the solubility of food waste, improving the productivity of biogas using food waste, and using the chemical method and the physical method at the same time It is possible to improve the productivity of biogas by pre-treating the waste, and re-injecting the untreated food waste as much as the amount of food waste to be processed, so that continuous treatment is possible, and thus there is industrial applicability.

Claims (18)

  1. 내부로 공급되는 음식물류 폐기물을 혼합 및 분쇄하는 처리부;A processing unit for mixing and crushing food wastes supplied to the interior;
    상기 처리부의 상단에 연결되어 처리부 내부로 음식물류 폐기물을 공급하는 음식물류 폐기물 공급부;A food waste supply unit connected to an upper end of the processing unit to supply food waste to the processing unit;
    상기 처리부의 상단에 연결되어 처리부 내부로 음식물류 폐기물을 분해하기 위한 촉매를 공급하는 촉매 공급부; 및A catalyst supply unit connected to the upper end of the processing unit to supply a catalyst for decomposing food waste into the processing unit; And
    상기 처리부의 하단 일측에 연결되고, 내부에 스크류를 구비하여 분해된 음식물류 폐기물을 외부로 배출하는 배출부;를 포함하고,It is connected to one side of the lower end of the processing unit, the discharge unit for discharging the disassembled food waste by having a screw therein; includes,
    상기 처리부는, The processing unit,
    상기 처리부 내부에 구비되는 혼합기; 및 상기 처리부 하부에 연결되어 처리부 내부의 온도를 조절할 수 있는 온도조절장치;를 포함하는 것을 특징으로 하는, 음식물류 폐기물 처리장치.A mixer provided inside the processing unit; And a temperature control device connected to a lower portion of the processing unit to control the temperature inside the processing unit.
  2. 제1항에 있어서,According to claim 1,
    상기 처리부는,The processing unit,
    처리부 내부에 구비되는 초음파 발생장치를 더 포함하는 것을 특징으로 하는, 음식물류 폐기물 처리장치.Characterized in that it further comprises an ultrasonic generator provided inside the processing unit, food waste treatment device.
  3. 제1항에 있어서,According to claim 1,
    상기 혼합기는,The mixer,
    처리부 내부에 종방향으로 형성된 회전축; 및A rotating shaft formed in the longitudinal direction inside the processing unit; And
    회전축과 수직방향으로 회전축에 형성된 복수의 회전날개;를 포함하는 것을 특징으로 하는, 음식물류 폐기물 처리장치.And a plurality of rotating blades formed on the rotating shaft in the vertical direction with the rotating shaft.
  4. 제3항에 있어서,According to claim 3,
    상기 회전축은 50~450rpm의 속도로 회전하는 것을 특징으로 하는, 음식물류 폐기물 처리장치.The rotating shaft is characterized in that rotating at a speed of 50 ~ 450rpm, food waste disposal apparatus.
  5. 제1항에 있어서,According to claim 1,
    상기 처리부는,The processing unit,
    혼합기에 의해 병진운동 또는 회전운동을 하여 음식물류 폐기물을 분쇄하는 볼을 포함하는 것을 특징으로 하는, 음식물류 폐기물 처리장치.A food waste disposal apparatus comprising a ball pulverizing food waste by performing a translational or rotational movement by a mixer.
  6. 제5항에 있어서,The method of claim 5,
    상기 볼의 직경은 1~10mm인 것을 특징으로 하는, 음식물류 폐기물 처리장치.The diameter of the ball is characterized in that 1 to 10mm, food waste disposal apparatus.
  7. 제1항에 있어서, According to claim 1,
    상기 촉매는,The catalyst,
    암모니아, 수산화나트륨, 수산화칼슘, 수산화칼륨, 수산화인 및 황화나트륨으로 이루어진 군에서 선택되는 적어도 어느 하나를 포함하는 알칼리 용매인 것을 특징으로 하는, 음식물류 폐기물 처리장치.A food waste disposal apparatus characterized in that it is an alkali solvent containing at least one selected from the group consisting of ammonia, sodium hydroxide, calcium hydroxide, potassium hydroxide, phosphorus hydroxide and sodium sulfide.
  8. 제1항에 있어서,According to claim 1,
    상기 스크류는,The screw,
    일측의 직경이 타측의 직경보다 큰 것을 특징으로 하는, 음식물류 폐기물 처리장치.A food waste treatment apparatus characterized in that the diameter of one side is larger than the diameter of the other side.
  9. 제1항에 있어서,According to claim 1,
    상기 배출부는,The discharge unit,
    처리부로부터 이송된 음식물류 폐기물이 처리부로 역류하는 것을 방지하는 역류방지부재를 포함하는 것을 특징으로 하는, 음식물류 폐기물 처리장치.And a backflow preventing member for preventing the food waste transported from the processing unit from flowing back to the processing unit.
  10. 제9항에 있어서,The method of claim 9,
    상기 역류방지부재는,The backflow prevention member,
    복수의 홀이 형성된 원형 부재; 및 일방향으로만 개방되는 게이트;를 포함하는 것을 특징으로 하는, 음식물류 폐기물 처리장치.A circular member having a plurality of holes; And a gate that opens only in one direction.
  11. 처리부 내부로 음식물류 폐기물을 공급하는 음식물류 폐기물 공급단계;A food waste supply step of supplying food waste to the processing unit;
    처리부 내부로 음식물류 폐기물을 분해하기 위한 촉매를 공급하는 촉매 공급단계; A catalyst supply step of supplying a catalyst for decomposing food waste into the processing unit;
    처리부 내부로 공급되는 음식물류 폐기물 및 촉매를 혼합기를 이용하여 혼합 및 분쇄하는 음식물류 폐기물 처리단계;A food waste treatment step of mixing and pulverizing the food waste and catalyst supplied to the processing unit using a mixer;
    처리부 내부로 공급되는 음식물류 폐기물을 초음파 발생장치를 이용하여 분해하는 초음파 처리단계; 및An ultrasonic treatment step of decomposing food wastes supplied into the processing unit using an ultrasonic generator; And
    처리부로부터 이송된 음식물류 폐기물을 스크류를 이용하여 외부로 배출하는 음식물류 폐기물 배출단계;를 포함하는 것을 특징으로 하는, 음식물류 폐기물 처리방법.Characterized in that it comprises a; food waste waste discharging step of discharging the food waste transported from the processing unit to the outside by using a screw.
  12. 제11항에 있어서,The method of claim 11,
    상기 촉매는,The catalyst,
    암모니아, 수산화나트륨, 수산화칼슘, 수산화칼륨, 수산화인 및 황화나트륨으로 이루어진 군에서 선택되는 적어도 어느 하나인 것을 특징으로 하는, 음식물류 폐기물 처리방법.Ammonia, sodium hydroxide, calcium hydroxide, potassium hydroxide, characterized in that at least one selected from the group consisting of phosphorus hydroxide and sodium sulfide, food waste treatment method.
  13. 제11항에 있어서,The method of claim 11,
    상기 혼합기는,The mixer,
    처리부 내부에 종방향으로 형성된 회전축; 및A rotating shaft formed in the longitudinal direction inside the processing unit; And
    회전축과 수직방향으로 회전축에 형성된 복수의 회전날개;를 포함하는 것을 특징으로 하는, 음식물류 폐기물 처리방법.And a plurality of rotating blades formed on the rotating shaft in a direction perpendicular to the rotating shaft.
  14. 제13항에 있어서,The method of claim 13,
    상기 회전축은, 50~450rpm의 속도로 회전하는 것을 특징으로 하는, 음식물류 폐기물 처리방법.The rotating shaft, characterized in that rotating at a speed of 50 ~ 450rpm, food waste treatment method.
  15. 제11항에 있어서The method of claim 11
    상기 음식물류 폐기물 처리단계는,The food waste treatment step,
    혼합기에 의해 병진운동 또는 회전운동하는 볼을 이용하여 음식물류 폐기물을 분쇄하는 것을 특징으로 하는, 음식물류 폐기물 처리방법.Method for disposing food waste by using a ball that is translated or rotated by a mixer.
  16. 제15항에 있어서,The method of claim 15,
    상기 볼의 직경은 1~10mm인 것을 특징으로 하는, 음식물류 폐기물 처리방법.The diameter of the ball is characterized in that 1 to 10mm, food waste treatment method.
  17. 제11항에 있어서,The method of claim 11,
    상기 음식물류 폐기물 처리단계는,The food waste treatment step,
    60~150℃의 온도에서 수행되는 것을 특징으로 하는, 음식물류 폐기물 처리방법.Characterized in that performed at a temperature of 60 ~ 150 ℃, food waste treatment method.
  18. 제11항에 있어서,The method of claim 11,
    상기 스크류는,The screw,
    일측의 직경이 타측의 직경보다 큰 것을 특징으로 하는, 음식물류 폐기물 처리방법.Characterized in that the diameter of one side is larger than the diameter of the other, food waste treatment method.
PCT/KR2019/013463 2018-12-21 2019-10-15 Food waste treatment apparatus for improving biogas productivity, and food waste treatment method using same WO2020130311A1 (en)

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