WO2020111715A1 - Cosmetic composition carrier - Google Patents

Cosmetic composition carrier Download PDF

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Publication number
WO2020111715A1
WO2020111715A1 PCT/KR2019/016342 KR2019016342W WO2020111715A1 WO 2020111715 A1 WO2020111715 A1 WO 2020111715A1 KR 2019016342 W KR2019016342 W KR 2019016342W WO 2020111715 A1 WO2020111715 A1 WO 2020111715A1
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WO
WIPO (PCT)
Prior art keywords
cosmetic composition
carrier
layer
polyurethane foam
less
Prior art date
Application number
PCT/KR2019/016342
Other languages
French (fr)
Korean (ko)
Inventor
백두현
정해원
이용철
Original Assignee
㈜아모레퍼시픽
(주)영서물산
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Priority claimed from KR1020190116199A external-priority patent/KR20200066158A/en
Application filed by ㈜아모레퍼시픽, (주)영서물산 filed Critical ㈜아모레퍼시픽
Publication of WO2020111715A1 publication Critical patent/WO2020111715A1/en

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Classifications

    • AHUMAN NECESSITIES
    • A45HAND OR TRAVELLING ARTICLES
    • A45DHAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
    • A45D34/00Containers or accessories specially adapted for handling liquid toiletry or cosmetic substances, e.g. perfumes
    • A45D34/04Appliances specially adapted for applying liquid, e.g. using roller or ball

Definitions

  • This specification describes a cosmetic composition carrier.
  • a carrier suitable for such a cushion pact cosmetic should be easily filled with a cosmetic composition, capable of carrying the composition homogeneously for a long time, and when the cosmetic composition is taken from the carrier, an appropriate amount will be uniformly discharged, and the contents can be used to the end. Until then, physical properties such as long-term discharge amount will be kept uniform. In addition, since it is a beauty product, aesthetic needs such as color and design of the exterior must also be satisfied.
  • the carrier may have a layered structure, so that the upper and lower carriers have different physical properties.
  • a generally known adhesive is used for attaching carriers having different materials and/or properties to each other, due to porosity, an actual adhesive is applied and the area to be adhered is reduced, so adhesion durability may not be sufficient.
  • the cosmetic composition may be loaded therein to cause a problem in which the adhered portion falls during long-term storage.
  • the porous structure of the carrier becomes clogged, which may cause a problem of not properly functioning as a carrier.
  • Patent Document 1 Korean Patent Registration No. 10-1738121
  • the problem to be solved by the present invention is to provide a cosmetic composition carrier capable of homogeneous loading of the cosmetic composition.
  • the problem to be solved by the present invention is to provide a cosmetic composition carrier capable of supporting the cosmetic composition homogeneously in an organ.
  • the problem to be solved by the present invention is to provide a cosmetic composition carrier in which an appropriate amount of cosmetic composition is discharged when the cosmetic composition is taken from the carrier.
  • the problem to be solved by the present invention is to provide a cosmetic composition carrier capable of maintaining excellent durability after supporting the cosmetic composition therein.
  • the problem to be solved by the present invention is to provide a cosmetic composition carrier capable of maintaining excellent durability for a long period of time even if the cosmetic composition is repeatedly taken from the carrier.
  • the problem to be solved by the present invention is to provide a cosmetic composition carrier capable of discharging the cosmetic composition in a uniform pattern even if the amount of the cosmetic composition carried in the carrier is reduced.
  • the problem to be solved by the present invention is to provide a cosmetic composition carrier that is easy to fill the cosmetic composition.
  • the problem to be solved by the present invention is to provide a cosmetic composition carrier having excellent bonding strength of a multilayer structure.
  • the problem to be solved by the present invention is to provide a cosmetic composition carrier excellent in appearance of the carrier after the cosmetic composition is supported.
  • the problem to be solved by the present invention is to provide a cosmetic composition carrier that can prevent the overflow of the cosmetic composition from the lower carrier.
  • the present invention is a cosmetic composition carrier formed with a junction at the edge,
  • the carrier includes a laminate in which a plurality of polyurethane foams having different pore sizes, density, thickness, and number of pores are stacked,
  • a cosmetic composition carrier Provided is a cosmetic composition carrier.
  • the present invention can provide a cosmetic composition carrier capable of homogeneous loading of the cosmetic composition.
  • the present invention can provide a cosmetic composition carrier capable of carrying the cosmetic composition homogeneously for a long period of time.
  • the present invention can provide a cosmetic composition carrier in which an appropriate amount of cosmetic composition is discharged when the cosmetic composition is taken from the carrier.
  • the present invention can provide a cosmetic composition carrier capable of maintaining excellent durability after supporting the cosmetic composition therein.
  • the present invention can provide a cosmetic composition carrier capable of maintaining excellent durability for a long period of time even if the cosmetic composition is repeatedly taken from the carrier.
  • the present invention can provide a cosmetic composition carrier capable of discharging the cosmetic composition in a uniform pattern even if the amount of the cosmetic composition carried in the carrier is reduced.
  • the present invention can provide a cosmetic composition carrier that is easy to fill the cosmetic composition.
  • the present invention can provide a cosmetic composition carrier having excellent bonding strength of a multilayer structure.
  • the present invention can provide a cosmetic composition carrier excellent in appearance of the carrier after the cosmetic composition is supported.
  • the present invention can provide a cosmetic composition carrier capable of preventing overflow of the cosmetic composition from the bottom of the carrier.
  • FIG. 1 is a schematic cross-sectional view of a carrier according to an embodiment of the present invention.
  • FIG. 2 is a schematic cross-sectional view of a carrier according to an embodiment of the present invention.
  • FIG 3 is a schematic cross-sectional view of a carrier according to an embodiment of the present invention.
  • Figure 4 is a schematic diagram showing the specifications of the carrier according to an embodiment of the present invention.
  • FIG. 5 is a schematic plan view of a carrier according to an embodiment of the present invention.
  • FIG. 6 is a cross-sectional photograph of a carrier according to an embodiment of the present invention.
  • Example 7 is a comparative picture of the results of carrier bonding of Example 1 and Comparative Example 1.
  • Figure 8 is a photograph of the result of filling the cosmetic composition in the carrier of Comparative Example 2 of Test Example 4.
  • Example 9 is a photograph comparing the appearance of the carrier after filling the cosmetic composition of Example 1 and Comparative Example 3.
  • 10 is a graph showing the amount of cosmetic discharge according to the number of discharges.
  • 11 is a photograph of the applicator according to the number of discharges. The number shown in the first figure indicates the number of discharges.
  • FIG. 12 is a photograph of a carrier according to an embodiment of the present invention.
  • Example 13 is a photograph of the appearance of a carrier in Example 2, wherein the carrier is inclined at 45 degrees relative to a plane parallel to the layer.
  • Example 14 is a photograph of the appearance of the carrier of Example 2, and is a photograph taken on the plane side (top) of the carrier.
  • Example 15 is a photograph of the appearance of the carrier of Example 2, and is a photograph taken from the side of the carrier.
  • 16 is a photograph of the appearance of the carrier of Example 2, and is a photograph taken from the bottom side (bottom) of the carrier.
  • 17 is a photograph of the appearance of the carrier of Example 3, wherein the carrier is inclined at 45 degrees relative to a plane parallel to the layer.
  • Example 18 is a photograph of the appearance of the carrier of Example 3, and is a photograph taken on the plane side (top) of the carrier.
  • Example 19 is a photograph of the appearance of the carrier of Example 3, and is a photograph taken from the side of the carrier.
  • Example 20 is a photograph of the appearance of the carrier of Example 3, and is a photograph taken from the bottom side (bottom) of the carrier.
  • 21 is a photograph of the appearance of the carrier of Example 3, and is a photograph of a state in which a longitudinal section is exposed by cutting the carrier.
  • Example 22 is a photograph of the appearance of the carrier of Example 4, which is a photograph of a state in which a longitudinal section is exposed by cutting the carrier.
  • 23 is a graph showing the amount of cosmetic discharge according to the number of discharges.
  • impregnating material means that the cosmetic composition can be absorbed and supported therein, and may also be expressed as “carrier”, “carrier” or “media”. In one example, the impregnating material may be used by discharging the material supported therein to a separate applicator.
  • applying sphere means used to deliver the cosmetic composition to the skin to be applied, etc., and may also be expressed as “applying means”, “applying sponge”, or “applicator”.
  • the applicator may include puffs, tips, brushes, and the like.
  • the viscosity may be measured by using a Brookfield Viscometer Model DV3T Brookfield Viscometer Model DV3T) at a temperature of 30°C for 64 spindles and 12 rpm for 1 minute.
  • open cell is a cell included in a foam, and means a cell that is entirely open, and "semi-open cell” means that at least a portion of the cell is "Open cell” means "closed cell” means a cell in which at least a portion of the cell is closed, and "reticulated structure” means a closed cell, a semi-open cell, or It is formed through a reticulation process that removes the cell walls in the foam of the open cell, which means that it has the same structure as a net with few cell walls.
  • the closed cell has a structure in which the cell structure as the foam is foamed is maintained in a small balloon shape, so that the air is impermeable.
  • the reticulated structure has a structure in which the membranes (walls) of balloon-shaped pore cells after foaming are removed by reticulation, so that not only air permeation but also absorption and discharge of liquid phases is possible.
  • polyurethane foam is solidified after foaming polyurethane, and may also be referred to as "urethane foam”.
  • pore size may be an average value of pores of a foam, that is, a cell diameter measured by an optical microscope (NIKON ECLIPSE 80i).
  • the number of pores refers to the number of cells in the unit line of the form.
  • the number of pores refers to the number of pores per inch (ppi) per inch of the foam, and means the number of pores present in a line of 1 inch.
  • the "hardness” of the foam is the hardness measured by an asker (ASKER, manufacturer) durometer hardness (F type (F)), the hardness before the cosmetic composition is supported on the foam it means.
  • Physical properties required as an impregnating material include, for example, absorbency, filling capacity, loading capacity, durability, and discharge capacity.
  • Absorption in this specification means that the impregnating material absorbs the cosmetic composition and is uniformly supported throughout the impregnating material.
  • the high water absorption is excellent in compatibility between the impregnating material and the cosmetic composition, and the higher the water absorption, the more it can suppress evaporation of the cosmetic composition when stored under high temperature conditions.
  • the filling ability in the present specification means that the cosmetic composition is easily and uniformly supported throughout the impregnating material when the cosmetic composition is filled into the impregnating material.
  • the excellent filling ability means that the cosmetic composition is uniformly filled at a high speed when the cosmetic composition is filled under the same conditions and pressure.
  • the loading ability refers to the ability of the impregnating material to retain and maintain the cosmetic composition.
  • the excellent holding ability means that the cosmetic composition is uniformly supported for a long period of time.
  • the impregnating ability of the impregnating material is distinguished from being temporarily taken out of the applicator for delivery of the cosmetic composition and temporarily applied to the applicator.
  • Durability herein includes chemical durability and physical durability.
  • Chemical durability refers to a property in which the impregnating material is maintained in an initial state without deformation such as damage or expansion, such as melting or tearing of the impregnating material when the cosmetic composition is left for a certain period of time at a predetermined temperature while the cosmetic composition is supported.
  • Physical durability refers to a property that withstands physical impulses to the impregnating material, for example, pressure and friction applied to the impregnating material when the applicator is repeatedly contacted and pressured to the impregnating material for taking out the cosmetic composition.
  • the high durability means that the impregnating material remains impregnated with the cosmetic composition for a long period of time under a certain condition without deformation or damage, and it can maintain its original state without damaging or deforming the impregnating material even if it is repeatedly subjected to physical friction and pressure by the applicator. it means.
  • the discharge capacity in the present specification means the ability of the cosmetic composition carried inside the impregnating material to be discharged in an appropriate amount when used.
  • the discharge capacity may be represented by the amount of the cosmetic composition on the applicator by contacting the applicator with the impregnating material at a constant pressure. If the discharge capacity is too high or low, it is difficult to use because the cosmetic composition is excessively smeared or only a small amount is applied, so it is preferable to have a proper discharge capacity so that an appropriate amount of the cosmetic composition can be discharged depending on the pressure applied to the impregnating material.
  • the cosmetic composition carrier according to an embodiment of the present invention includes a laminated portion in which a plurality of polyurethane foams are stacked, and may have a junction formed at an edge.
  • the cosmetic composition carrier 100 includes a lamination part including a plurality of polyurethane foams 110 and 120, and a junction 140 marked with a hatch is formed at the edge of the foam to integrally join the lamination part. can do.
  • the laminated portion may include two or more polyurethane foams.
  • the laminate may include a plurality of polyurethane foams having different pore sizes, density, thickness, and number of pores different from each other.
  • the polyurethane may be prepared by reaction of a polyol having two or more hydroxyl groups and a polyisocyanate.
  • the polyol may use polyether polyol, polyester polyol, polycarbonate polyol, polyolefin polyol, and polyether-based polyurethane foam, polyester-based polyurethane foam, polycarbonate-based polyurethane foam, and polyolefin-based depending on the polyol used. It is divided into polyurethane foam.
  • the whole includes a single foam having the same physical properties as a carrier, there is a problem that the discharge amount is uneven depending on the point of use of the supported cosmetic composition. Specifically, compared to the initial use, the amount is reduced according to consumption of the supported cosmetic composition, and after taking the cosmetic composition at least about 50% by weight of the initial use, the degree of discharge may drop rapidly.
  • the degree of discharge may drop rapidly.
  • a single foam is included as a carrier, since the pore size is relatively large, as the number of discharges is repeated, different amounts of cosmetic compositions are discharged at each discharge, so the discharge pattern may not be uniform.
  • Cosmetic composition according to an embodiment of the present invention The single foam described above until the use of a weight of 50% or more compared to the initial use, including a plurality of polyurethane foams having one or more different pore sizes, density, thickness, and number of pores as a layer structure Compared to the case, the discharge degree of the cosmetic composition may be maintained uniformly.
  • the stacked portion may include a multilayer, specifically 2 to 20, more specifically 2 to 10, and even more specifically 2 to 5 polyurethane foams.
  • the stacked portion may include a polycarbonate-based polyurethane foam on the uppermost layer, that is, when the direction in which the cosmetic composition is discharged from the carrier during use is upper.
  • the polyurethane foam 110 in the schematic diagram of FIG. 1 and the polyurethane foam 210 in the schematic diagrams of FIGS. 2 to 4 correspond to this.
  • the polycarbonate-based polyurethane foam has chemical resistance and chemical resistance as compared with polyether-based and polyester-based polyurethane foams, and may exhibit high physical properties such as durability. Since it corresponds to the use portion where the cosmetic composition is discharged during use, it can be used without long-term deformation due to its excellent durability even when physical contact for taking out the cosmetic composition is repeated.
  • the cosmetic composition is impregnated into the pores of the carrier and discharged by external force.
  • the cell structure of the foamed foam is closed cell, impregnation and discharge of the cosmetic composition cannot be made. Therefore, the polycarbonate-based polyurethane foam, except for the case of 100% closed cell, it is preferable to have an open cell, a semi-open cell, a network structure, such cell structure is partially included in the closed cell according to the production of foam It might be.
  • the use of a foamed foam having a network structure can increase the absorption, loading and discharge capacity of the cosmetic composition.
  • the open cell, the half open cell and the foamed foam having a reticular structure can be confirmed by taking a picture by cutting a cross section.
  • the pore size of the polycarbonate-based polyurethane foam is 50 ⁇ m or more, 55 ⁇ m or more, 60 ⁇ m or more, 65 ⁇ m or more, 70 ⁇ m or more, 75 ⁇ m or more, 80 ⁇ m or more, 85 ⁇ m or more, 90 ⁇ m or more, 95 ⁇ m or more , 100 ⁇ m or more, 105 ⁇ m or more, or 110 ⁇ m or more, 500 ⁇ m or less, 450 ⁇ m or less, 400 ⁇ m or less, 350 ⁇ m or less, 300 ⁇ m or less, 250 ⁇ m or less, 200 ⁇ m or less, 190 ⁇ m or less, 180 ⁇ m or less , 170 ⁇ m or less, 160 ⁇ m or less, 150 ⁇ m or less, 140 ⁇ m or less, 130 ⁇ m or less, or 120 ⁇ m or less, for example, 50 to 500 ⁇ m, or 100 to 300 ⁇ m.
  • the fine pore size as described above may be excellent in carrying capacity and discharge power. Since the cosmetic composition is disposed on the surface side to be discharged, it can have a fine pore size as described above for uniform discharge of the cosmetic composition. If the pore size is less than the above range, the supported amount is insufficient and the discharge capacity is lowered, so that a sufficient amount of the cosmetic composition is not discharged. When the pore size exceeds the above range, it is difficult to expect a desired uniform discharge power, and the surface of the foam may be rough, so that the feeling of use in the cosmetic extraction process may not be smooth.
  • the pore size of the polycarbonate-based polyurethane foam may have a smaller size than the polyurethane foam of the lower layer.
  • the density of the polycarbonate-based polyurethane foam is 0.05 g/cm 3 or more, 0.06 g/cm 3 or more, 0.07 g/cm 3 or more, 0.08 g/cm 3 or more, 0.09 g/cm 3 or more, 0.10 g/cm 3 or more, 0.11 g/cm 3 or more Or more, 0.12 g/cm 3 or more, 0.13 g/cm 3 or more, 0.14 g/cm 3 or more, 0.15 g/cm 3 or more, or 0.16 g/cm 3 or more, 0.25 g/cm 3 or less, 0.24 g/cm 3 or less, 0.23 g/cm 3 or less , 0.22 g/cm 3 or less, 0.21 g/cm 3 or less, 0.20 g/cm 3 or less, 0.19 g/cm 3 or less, 0.18 g/cm 3 or less, or 0.17 g/cm 3 or less, for example,
  • the cosmetic composition may be discharged in an excessive amount to deteriorate usability, and when the density is above the above range, filling of the cosmetic composition may be difficult due to insufficient pores in which the cosmetic composition may be impregnated. The composition may not be discharged well.
  • the density of the polycarbonate-based polyurethane foam may be greater than that of the polyurethane foam of the lower layer.
  • the number of pores of the polycarbonate-based polyurethane foam is 80 ppi or more, 85 ppi or more, 90 ppi or more, 95 ppi or more, 100 ppi or more, 105 ppi or more, 110 ppi or more, 115 ppi or more, or 120 ppi or more, 170 ppi or less, 165 ppi or less, 160 ppi or less, 155 ppi or less, 150 ppi or less, 145 ppi or less, 140 ppi or less, 135 ppi or less, or 130 ppi or less, for example, 80 to 170 ppi or 110 to 150 ppi Can be If the number of pores of the foam is less than the above, the elasticity of the foam is poor and it is difficult to control the fluidity of the cosmetic composition, and when the number of pores exceeds the above range, durability may be deteriorated when used.
  • the number of pores of the polycarbonate-based polyurethane foam may be greater than the polyurethane foam of the lower layer.
  • the hardness of the polycarbonate-based polyurethane foam is 50 or more, 55 or more, 60 or more, 61 or more, 62 or more, 63 or more, 64 or more, 65 or more, 66 on the basis of the type F of the ASKER hardness tester. Or more, 67 or more, 68 or more, 69 or more, or 70 or more, and 90 or less, 89 or less, 88 or less, 87 or less, 86 or less, or 85 or less, for example, may have a hardness of 50 to 90. If the hardness is less than the above range, the cosmetic composition impregnated in the polyurethane foam may be excessively discharged when the cosmetic composition is taken out. If the hardness is too hard beyond the above range, the cosmetic composition may not be easily discharged.
  • the polycarbonate-based polyurethane foam may be a wet polycarbonate-based polyurethane foam prepared by wet foaming.
  • the impregnation reticulation may include impregnating a foam block in a container filled with a liquid (chemical), and then reticulating by chemical action.
  • Polyurethane foam reticular by the wet process exhibits soft characteristics, and since fine pores can be formed, the cosmetic composition can be uniformly discharged.
  • wet polyurethane foam produced by a wet process generally exhibits a tendency to be low in durability, chemical resistance, and chemical resistance, and thus, when carrying a cosmetic composition for a long period of time, there is a risk of deformation or damage, and physical damage caused by repeated take-out of the cosmetic composition There is a risk of deformation or damage.
  • the carrier according to the embodiment of the present invention uses a polycarbonate-based polyurethane foam on the top layer, it has excellent chemical resistance, chemical resistance, and excellent physical durability, and can provide a carrier that can be used for a long time without being deformed or damaged while being soft with fine pores. have.
  • the laminate may include one or more polyurethane foams at the bottom of the top layer, hereinafter referred to as the bottom layer.
  • the polyurethane foam 120 in the schematic diagram of FIG. 1 and the polyurethane foam 220 in the schematic diagrams of FIGS. 2 to 4 correspond to this.
  • the lower layer may include a polyether-based polyurethane foam.
  • the lower layer stably supports the cosmetic composition, and can provide excellent elasticity to the entire carrier.
  • the cosmetic composition when filled from the bottom, it can exhibit excellent filling ability, and is excellent in absorbency and loading ability to absorb and maintain a sufficient amount of the cosmetic composition.
  • Polyether-based polyurethane foam is an impregnating material, which is advantageous in terms of absorbency, carrying capacity, and discharging ability, and has a large pore size compared to polyester-based polyurethane foam, providing high air permeability, excellent fluffy feel and softness, flexibility and It is not only good in elasticity, but also excellent in durability, so it does not exhibit the phenomenon of breaking and tearing even in environments with high temperature or high temperature.
  • Polyether-based polyurethane foams have higher compatibility with water-in-oil cosmetic compositions than polyester-based polyurethane foams, and polyether-based polyurethane foams have excellent absorption for water-in-oil cosmetic compositions, so cosmetic compositions do not evaporate easily. , Absorbency, holding ability, and durability may be significantly superior to that of the polyester-based polyurethane foam.
  • the cosmetic composition is impregnated into the pores of the carrier and discharged by external force.
  • the cell structure of the foamed foam is closed cell, impregnation and discharge of the cosmetic composition cannot be made. Therefore, the polyether-based polyurethane foam is excluded from the case of 100% closed cells, and preferably has an open cell, a semi-open cell, a network structure, and such a cell structure includes some closed cells according to the manufacture of a foam. It might be. Most preferably, the use of a foamed foam having a network structure can increase the absorption, loading and discharge capacity of the cosmetic composition.
  • the pore size of the polyether-based polyurethane foam is 200 ⁇ m or more, 250 ⁇ m or more, 300 ⁇ m or more, 310 ⁇ m or more, 320 ⁇ m or more, 330 ⁇ m or more, 340 ⁇ m or more, 350 ⁇ m or more, 360 ⁇ m or more, 370 ⁇ m or more , 380 ⁇ m or more, 390 ⁇ m or more, 400 ⁇ m or more, 410 ⁇ m or more, 420 ⁇ m or more, 430 ⁇ m or more, 440 ⁇ m or more, or 450 ⁇ m or more, 800 ⁇ m or less, 750 ⁇ m or less, 700 ⁇ m or less, 650 ⁇ m or less , 600 ⁇ m or less, 590 ⁇ m or less, 580 ⁇ m or less, 570 ⁇ m or less, 560 ⁇ m or less, 550 ⁇ m or less, 540 ⁇ m or less, 530 ⁇ m or less, 520 ⁇
  • the polyether-based polyurethane foam may have a larger pore size than the top layer. Through the differentiation of the pore size, while the cosmetic composition is stably supported in a sufficient amount in the lower layer, the cosmetic composition in the uppermost layer can be discharged in a uniform and appropriate amount.
  • the density of the polyether-based polyurethane foam is 0.015 g/cm 3 or more, 0.020 g/cm 3 or more, or 0.025 g/cm 3 or more, 0.05 g/cm 3 or less, 0.045 g/cm 3 or less, 0.040 g/cm 3 or less, or 0.035 g/cm 3 or less, for example, 0.01 to 0.05 g/cm 3, or 0.02 to 0.04 g/cm 3.
  • the density is less than the above range, it is difficult to stably support the cosmetic composition, and when the density is above the above range, filling of the cosmetic composition may not be easily achieved.
  • the polyether-based polyurethane foam may have a lower density than the top layer. Due to the difference in density, filling of the cosmetic composition is easily performed in the lower layer, and the cosmetic composition is stably supported in a sufficient amount, and the discharge amount of the cosmetic composition can be appropriately adjusted in the uppermost layer.
  • the number of pores of the polyether-based polyurethane foam is 40 ppi or more, 45 ppi or more, 50 ppi or more, 55 ppi or more, 60 ppi or more, 65 ppi or more, 70 ppi or more, or 75 ppi or more, 120 ppi or less, 115 ppi Or less, 110 ppi or less, 105 ppi or less, 100 ppi or less, 95 ppi or less, 90 ppi or less, 85 ppi or less, or 80 ppi or less, for example, 40 to 120 ppi or 60 to 100 ppi. If the number of pores of the foam is less than the above, the elasticity of the foam is poor and it is difficult to control the fluidity of the cosmetic composition, and when the number of pores exceeds the above range, durability may be deteriorated when used.
  • the polyether-based polyurethane foam may have a smaller number of pores than the top layer. Due to the multi-layered structure having the difference in the number of pores, the lower layer stably supports the cosmetic composition in a sufficient amount, imparting appropriate elasticity to the carrier, and controlling the discharge amount of the cosmetic composition in the uppermost layer is appropriate.
  • the hardness of the polyether-based polyurethane foam is 50 or more, 55 or more, 60 or more, 61 or more, 62 or more, 63 or more, 64 or more, 65 or more, 66 on the basis of the Type F of the ASKER hardness tester.
  • the polyether-based polyurethane foam may be a dry polyether-based polyurethane foam produced by dry foaming.
  • the dry method of manufacturing a polyurethane foam by foaming with the dry blends and mixes the raw materials that are the material of the polyurethane foam, foams the mixture to form a foam block, and gases the foam block It may include reticular injection by injecting gas in a gas chamber.
  • Polyether-based polyurethane foams meshed by a dry process have a larger pore size than wet meshes.
  • the surface properties of the dry polyether-based polyurethane foam exhibit lipophilic properties.
  • the dry method and the wet method may include the following process.
  • the surface of the block formed for the process (more than 3 sides) is sliced (work to peel off the hardened surface).
  • This is a process for discharging the internal heat and gas generated by the chemical reaction in the foaming process, which takes about 18 hours, and the internal cell structure and cell-size may be deformed without a complete aging process. Because there is.
  • the completed form through the aging process can be sold as a finished product in the form of a closed-cell/semi-open cell.
  • the open-cell can be opened through a reticulation process.
  • cell) Products This is the process of popping the cell surface of the foam to make only a frame and easily "delusion".
  • the reticulation method is divided into a gas blasting method and an impregnating quenching method. It is generally classified as "dry-sponge" and "wet-sponge”.
  • the gas blasting (Zapping) method can be used in the production of dry polyurethane foams by placing the foam block in a gas chamber and injecting the gas to detonate it.
  • the impregnation quenching method is a process that is mainly used in the production of soft foam products by impregnating the foam block into a container filled with a liquid (chemical) and then phantomizing with a chemical action.
  • the impregnation network method is a process of obtaining a kneaded product by kneading a mixture of a water-solidifying polyurethane, a solvent, a powder of a water-soluble inorganic salt, and a surfactant as a main component, and defoaming the kneaded product to obtain a defoamed kneaded product Process, forming a defoamed mixture to obtain a molded product, putting the molded product in water or in an aqueous solution, and then solidifying to form a coagulated product, eluting the inorganic salt from water from the coagulated product to form a coagulated product
  • Polyurethane foam having a membrane structure is obtained in the process of elution and removal of the inorganic salt from the coagulation product and drying after removal of the elution, and the polyurethane foam having a network structure is used depending on the use of surfactant. Is obtained.
  • the carrier may further include a mesh structured fiber layer on the lower side of the layered portion, that is, on the back side opposite to the surface side from which the cosmetic composition is discharged.
  • 2 is a schematic cross-sectional view of a carrier according to the present embodiment.
  • the cosmetic composition carrier 200 according to the present embodiment includes a lamination portion including a plurality of polyurethane foams 210 and 220 and a mesh structure fiber layer 230, and a junction portion 240 indicated by hatching on the edge of the foam. Is formed can be integrally bonded to the laminated portion and the mesh structure fiber layer.
  • the mesh-structured fiber layer provides excellent bonding strength when bonded together with the laminated portion, thereby providing a carrier having excellent durability and chemical durability against physical contact or repeated use over time.
  • the mesh structured fiber layer has a sex root mesh structure that does not interfere with absorption of the cosmetic composition unlike the porous foam when the cosmetic composition is filled from the bottom while increasing the bonding strength when disposed at the bottom, the cosmetic composition of the lower layer Filling can be facilitated.
  • the mesh structure fiber layer may include a fiber fabric having a mesh structure that forms a hole with fibers.
  • the fibers may include one or more of natural fibers or synthetic fibers.
  • the fiber is a natural fiber, but is not limited thereto, antibacterial cellulose, natural pulp, loofah, ramie, ramie (plant), ayate (rough agave of agave or palm trees), algae, bamboo, sisal, sisal terry, a cloth woven to absorb moisture like a towel with sisal, konjac, tencel(TM) fiber fabric (tencel with natural antibacterial function made from eucalyptus wood) Fiber), cotton, and manila hemp (abaca fiber).
  • the hole shape of the mesh structure fiber layer may be circular, triangular, square, pentagonal, hexagonal, and the like, but is not limited.
  • the hole size of the mesh structure fiber layer is 0.3 mm or more, 0.4 mm or more, 0.5 mm or more, 0.6 mm or more, 0.7 mm or more, 0.8 mm or more, 0.9 mm or more, or 1.0 mm or more, 1.8 mm or less, 1.7 mm or less, It may be 1.6 mm or less, 1.5 mm or less, 1.4 mm or less, or 1.3 mm or less, for example, 0.3 to 1.8 mm or 0.5 to 1.5 mm.
  • the hole size may be an average value of the longest diameter of a single hole. When the hole size is less than the above range, filling of the cosmetic material from the lower part is not easy, and when it exceeds the above range, bonding of the edge joint may not be performed or the bonding strength may be weakened.
  • the fiber thickness of the fiber layer of the mesh structure is at least 10 denier, at least 15 denier, at least 20 denier, at least 25 denier, at least 30 denier, at least 35 denier, at least 40 denier, at least 45 denier, at least 50 denier, at least 55 denier, in 60 Denier or more, 65 denier or more, or 70 denier or more, 200 denier or less, 190 denier or less, 180 denier or less, 170 denier or less, 160 denier or less, 150 denier or less, 140 denier or less, 130 denier or less, 120 denier or less, 110 Denier or less, 100 denier or less, 95 denier or less, 90 denier or less, 85 denier or less, 80 denier or less, or 75 denier or less, for example 10 to 200 denier, for example 20 to 100 denier.
  • the thickness t3 of the mesh structure fiber layer may be 0.1 mm or more, 0.15 mm or more, 0.2 mm or more, 0.25 mm or more, or 0.3 mm or more, 0.5 mm or less, 0.45 mm or less, 0.4 mm or less, or 0.35 mm or less, , For example 0.1 to 0.5 mm, specifically 0.2 to 0.4 mm. Filling the cosmetic composition may be easy while achieving the bonding strength of the bonding portion within the above range. 4 shows the thickness t3 of the mesh structure fiber layer.
  • the carrier may include junctions 140, 240, and 340 that bond layers included in the carrier to the edges.
  • FIG. 3 is another schematic cross-sectional view of a cosmetic composition carrier according to an embodiment of the present invention.
  • the mesh structure is described as a structure including the fiber layer 230, but is not limited thereto.
  • the cosmetic composition carrier 200 according to the present embodiment may be in a form in which the bonding portion 240 indicated by hatching formed on the edge of the foam is compressed compared to the central portion by bonding.
  • FIG. 5 is a schematic plan view of a cosmetic composition carrier 300 according to an embodiment of the present invention, and shows a junction 340 at an edge indicated by hatching.
  • the bonding may be performed by ultrasonic bonding.
  • ultrasonic bonding disadvantages associated with the use of the adhesive can be excluded, and excellent durability can be exhibited by stable bonding of the multilayer structure.
  • the ultrasonic bonding may include remarkably excellent bonding strength, including the above-described mesh structure fiber layer.
  • the bonding can be performed by thermal bonding.
  • thermal bonding disadvantages associated with the use of the adhesive can be excluded, and excellent durability can be exhibited by stable bonding of the multilayer structure.
  • the thermal bonding may include the above-described mesh structure fiber layer, the bonding strength may be remarkably excellent.
  • the joint may be formed on the edge of the carrier, the width (Wd) of the joint is 0.05 mm or more, 0.10 mm or more, 0.15 mm or more, 0.20 mm or more, 0.25 mm or more, 0.30 mm or more, 0.35 mm or more, 0.40 mm or more , 0.45 mm or more, 0.50 mm or more, 0.55 mm or more, 0.60 mm or more, 0.65 mm or more, 0.70 mm or more, 0.75 mm or more, 0.80 mm or more, 0.85 mm or more, 0.90 mm or more, 0.95 mm or more, or 1.00 or more, 5.0 mm or less, 4.5 mm or less, 4.0 mm or less, 3.5 mm or less, 3.0 mm or less, 2.5 mm or less, 2.0 mm or less, or 1.5 mm or less, for example, 0.05 to 5 mm, or 0.1 to 3 mm have.
  • the width of the bonding portion is less than the above range, the bonding
  • the joining portion may form a wing-like structure as exemplarily shown in FIGS. 6 and 12 on the edge by joining.
  • Figure 4 shows the specifications of the carrier according to an embodiment of the present invention.
  • the thickness of the foam may be a measure of the layer thickness on the basis of bonding prior to bonding.
  • the layer structure of FIG. 4 is shown as a structure including the mesh structure fiber layer 230 to comprehensively illustrate the carrier of the embodiments of the present invention, but is not limited thereto.
  • the effect of the present invention according to the multi-layer structure of the lamination part may be reduced by reducing the influence of the presence of the lower layer, and the top layer may be used for the discharge capacity of the carrier. Since the effect will be greater, it may be important to control the thickness of the top layer.
  • the thickness (t1) of the polycarbonate-based polyurethane foam is 0.1 mm or more, 0.2 mm or more, 0.3 mm or more, 0.4 mm or more, 0.5 mm or more, 0.6 mm or more, 0.7 mm or more, 0.8 mm or more, or 0.9 mm or more, Or 1.0 mm or more, 5.0 mm or less, 4.5 mm or less, 4.0 mm or less, 3.5 mm or less, 3.0 mm or less, 2.5 mm or less, 2.0 mm or less, or 1.5 mm or less, for example, 0.1 to 5 mm, or 0.5 To 2 mm.
  • the thickness is less than 0.1mm, it is difficult to expect the desired uniform discharge power, there may be a problem in durability, and if it is more than 5mm, cosmetic discharge may be difficult, and stable support and elasticity and soft feeling in the lower layer are given. The effect can be halved.
  • the thickness (t1) of the polycarbonate-based polyurethane foam may be thin compared to the thickness (t2) of the polyurethane foam of the lower layer.
  • the thickness (t2) of the polyether-based polyurethane foam is 3 mm or more, 4 mm or more, 5 mm or more, 6 mm or more, or 7 mm or more, 15 mm or less, 14 mm or less, 13 mm or less, 12 mm or less , 11 mm or less, 10 mm or less, or 9 mm or less, for example, 3 to 15 mm, or 5 to 10 mm. If the thickness is less than the above range, there is little value as a product because the capacity to carry the cosmetic composition is small, and if the thickness exceeds the above range, the container becomes thick and the portability becomes poor, and until the end, the use of the cosmetic composition is difficult. The remaining amount can remain.
  • the thickness (t2) of the polyurethane foam of the lower layer may be thick compared to the thickness (t1) of the top layer. Due to the thickness difference, a sufficient amount of the cosmetic composition is stably supported in the lower layer, and an appropriate elasticity and soft feeling are given to the entire carrier, and at the same time, proper discharge control of the uppermost layer is implemented to maximize the effect as a multi-layer structure.
  • the carrier may further include a primer layer disposed between at least one of the layers of the laminated portion and between the laminated portion and the mesh structure fiber layer.
  • the primer layer may include one or more of a hot melt nonwoven web, a hot melt mesh, a spray adhesive layer, an oily adhesive layer, and an aqueous adhesive layer.
  • a hot melt film When a hot melt film is used, it is possible to prevent the absorption or discharge of the cosmetic composition by blocking the pores of the carrier, so a non-woven hot melt web is suitable.
  • the material of the hot melt web may be at least one of polyester, polyethylene, and polyurethane, and the temperature to be melted may be 80°C to 120°C.
  • the oily adhesive may be a mixture of a urethane-based adhesive and a solvent acetic acid, and the aqueous adhesive may be a urethane-based but is not limited thereto.
  • the thickness of the primer layer may be 0.01 to 1.0mm. Within the above range, the interlayer bonding strength can be improved without inhibiting absorption and discharge of the cosmetic composition.
  • the diameter (Wt) and the total thickness (T) of the carrier may vary depending on the makeup container.
  • the diameter (Wt) of the carrier may be 30 mm to 70 mm or 40 mm to 60 mm, and the discharge amount of the cosmetic composition impregnated within the above range may be appropriate.
  • the total thickness (T) of the carrier may be 1 mm to 50 mm, for example, 5 mm to 30 mm, 6 mm to 29 mm, 7 mm to 28 mm, 8 mm to 27 mm, 9 mm to 26 mm, or 10 mm to 25 mm. If the thickness is less than the above range, the supported amount of the cosmetic composition may be small, and if it exceeds the above range, the discharge may be difficult without the remaining amount of the content when discharging the content during use.
  • the carrier may further include an incision in the interior.
  • the incision may be formed in a plane parallel to the layer of the carrier.
  • the incision may be formed in a plane perpendicular to the thickness direction of the carrier.
  • the incision may be formed parallel to the layer of the carrier to form an internal void.
  • the incision may be formed by incising a part of the carrier, or may be formed by a laminated layer that is not joined, and the method of forming the incision is not limited to incision.
  • FIG. 22 is a photograph of an example of a carrier according to the present embodiment. Specifically, FIG. 22 is a photograph of a state in which a longitudinal section is exposed by cutting a carrier including an incision according to this embodiment, and it can be confirmed that a cavity was formed inside the carrier.
  • the incision may be formed in a laminate including a plurality of polyurethane foams in the carrier.
  • the incision may be formed on one or more of the inside of the foam of the top layer, the inside of the foam of the bottom layer, between the plurality of foams of the top layer, between the plurality of foams of the bottom layer, or between the top layer and the bottom layer foam.
  • the incision may be formed to a length excluding the junction (Wd) from the diameter (Wt) based on the cross-section of the carrier.
  • the length may be represented by the diameter of the region where the incision is formed based on the cross section with reference to FIG. 3.
  • the incision may serve to store and/or store the cosmetic composition carried by the carrier.
  • a large amount of the cosmetic composition may be supported on the cavity of the incision. It can be more stably discharged from the carrier to the cosmetic composition including the incision.
  • the incision may include an air layer by a cavity.
  • the carrier may recover more slowly when the pressure is removed after applying pressure to the carrier including the incision. In this way, the incision may affect the elasticity felt when the carrier is pressed to provide a soft cushion feeling.
  • the cosmetic composition carrier may be for impregnating and supporting a cosmetic composition having flowability.
  • the cosmetic composition carrier has a viscosity of 5000 cps or more, 6000 cps or more, 7000 cps or more, 8000 cps or more, 9000 cps or more, 10000 cps or more, 11000 cps or more, 12000 cps or more, 13000 cps or more, 14000 cps or more, 15000 cps or more, 16000 cps or more Above, 17000 cps or more, 18000 cps or more, 19000 cps or more, or 20000 cps or more, 30000 cps or less, 29000 cps or less, 28000 cps or less, 27000 cps or less, 26000 cps or less, 25000 cps or less, 24000 cps or less, 23000 cps or less, 22000 cps Or less, or may be for supporting a cosmetic composition of 21000
  • the cosmetic composition is an emulsion type composition, specifically, water-in-oil-in-water (W/O/W) type emulsion composition, water-in-oil-in-water type (O/W/O) type emulsion composition, water-in-oil (W/O) type It may be an emulsifying composition, an oil-in-water (O/W) type emulsifying composition, a dispersing composition, or specifically, an oil dispersion or water dispersion composition.
  • W/O/W water-in-oil-in-water
  • dispersing composition specifically, an oil dispersion or water dispersion composition.
  • the composition according to the present embodiment may be a water-in-oil (W/O) type emulsifying composition.
  • the cosmetic composition is a water-in-oil type cosmetic that can be applied to various types of cosmetics, such as makeup primer, makeup base, skin cover, foundation, lipstick, lip gloss, liquid eyeshadow, eyebrow, liquid concealer, and liquid blusher. Can be.
  • the cosmetic composition may be delivered to the target skin through a hand or applicator.
  • the water-in-oil type emulsifying composition may be prepared by any emulsifying method used in the art.
  • the emulsification may include preparing the oil phase and the water phase and mixing them.
  • the mixing is not particularly limited, and a conventional mixer, homogenizer, homogenizer, or high pressure homogenizer used in the cosmetic manufacturing field may be used.
  • the stirring speed at the time of mixing can be variously changed according to the device used and the composition content.
  • a cosmetic composition comprising a cosmetic composition carrier according to an embodiment of the present invention described above and a cosmetic composition impregnated in the carrier.
  • the cosmetic may further include a container for receiving a carrier impregnated with the cosmetic composition.
  • the container may be a fact type container.
  • the carrier may be separable from the container, and the user may fill and use the cosmetic composition in a container in which the carrier is separated, and then use the carrier in combination. In addition, the user can also use it by replacing only the carrier.
  • the cosmetic may further include a carrier and a separate applicator.
  • the container can accommodate the carrier and the applicator.
  • the cosmetic may be used in a manner that a cosmetic composition impregnated in a carrier is applied to an application object by being buried in an applicator.
  • the cosmetic composition does not get on the hand, so it is easy to use and hygienic.
  • the material and the shape of the applicator are not limited, but when the cosmetic composition is applied to the skin, lines or lighting marks must be applied smoothly, so the pores are fine, and it is preferable to have a soft and cushion feeling because it directly touches the skin. .
  • the applicator may use a foam material.
  • the applicator temporarily absorbs the cosmetic composition, and may give a moist discomfort during application, and the cosmetic composition that has been exposed to the outside while temporarily absorbed by the applicator will be applied to the skin again. There is a possibility. Therefore, it is advantageous that the applicator does not excessively absorb the cosmetic composition, and a material that does not expand when the cosmetic composition is buried is preferable.
  • the applicator requires that the cosmetic composition impregnated into the carrier is easily taken out, is easily applied to the skin, and exhibits an excellent feeling of use when applied to the skin.
  • the applicator is acrylonitrile butadiene rubber (NBR), styrene-butadiene rubber (SBR), natural rubber (NR), polyvinyl chloride, polyethylene, ethylene-vinyl acetate butyl rubber (EVA), latex, silicone, Selected from the group consisting of styrene-isoprene-styrene (SIS), styrene-ethylene-butylene-styrene (SEBS), polyvinyl alcohol (PVA), nitrile rubber, butyl rubber, chloroprene rubber (neoprene®), polyolefin and polyurethane. It may be a foam made of one or more.
  • a W/O emulsion composition for foundation was prepared by a conventional method in the art and used in the carrier experiment of the present invention.
  • the prepared cosmetic composition had a viscosity of 12,500 cps.
  • Emollient Phenyl trimethicone 7 Sunscreen Ethylhexylmethoxycinnamate 7 Emulsifier PG-10 Dimethicone 4 Emulsifier Laurylpage-9 polydimethylsiloxyethyldimethicone 2 Dispersant Acrylate/ethylhexyl acrylate/dimethicone methacrylate copolymer 4 Powder Thickener Disteadimonium hectorite 0.7 coloring agent Titanium dioxide * zinc oxide * iron oxide * methyl methacrylate cross polymer 20 Awards solvent Purified water 30 Moisturizer Butylene glycol 5 Ion blocker Disodium LED 0.05 Emulsifier Sodium chloride 0.8 Preservative Phenoxyethanol 0.3
  • wet polycarbonate-based polyurethane foam was purchased and used by Technophorus Korea Co., Ltd. 256-W1 grade. The properties of the wet polycarbonate-based polyurethane foam used for preparing the carrier are described below.
  • Top floor Pore size ( ⁇ m) 110 Density (g/cm3) 0.17 Pore number (ppi) 120 Hardness (ASKER type F) 70 Diameter (mm) 55 Thickness (mm) One
  • the dry polyether-based polyurethane foam was purchased and used from Foamtec's EZ93N grade. The properties of the dry polyether-based polyurethane foam used for preparing the carrier are described below.
  • the mesh structure fiber layer was purchased from Ilsong Tex Co., Ltd., and was used in detail.
  • Example 1-1 is a carrier comprising a wet polycarbonate-based polyurethane foam and a dry polyether-based polyurethane foam from the top layer without a mesh structured fiber layer.
  • Comparative Example 3 is a dry polyether-based polyurethane foam of Test Example 2 without a layer structure. A single layer was used.
  • Example 1 Example 1-1 Comparative Example 1 Comparative Example 2 Comparative Example 3 (Top layer) Wet polycarbonate polyurethane foam Top floor Top floor Top floor Top floor (No layer structure) (Lower layer) dry polyether based polyurethane foam Lower layer Lower layer Lower layer Mesh structure fiber layer Mesh 1 Mesh 2 Mesh 3
  • the cosmetic composition carrier of Example 1 was prepared using a mesh structure fiber layer having a hole size of 1 mm, whereas in Comparative Example 1, a mesh structure fiber layer having a hole size of 2 mm was used. 6 shows a photograph of the cosmetic composition carrier.
  • Cosmetics were prepared by filling the carriers of Example 1 and Comparative Example 3 with 15 g of the cosmetic prepared in Test Example 1.
  • Example 1 and Comparative Example 3 filled with the cosmetic composition were taken out and used by 20 women 25 to 35 years old with puffs of air cell (wet polyurethane foam), and preference and take-out of appearance
  • the average value is shown in Table 6 below by evaluating whether the feeling of soft use and the appropriateness of the discharged amount are on a 5-point scale (1 point: very bad to 5 points: very good).
  • the carrier according to the present invention exhibits an excellent effect by not only improving a bright appearance preference but also discharging a soft feeling of use and an appropriate amount of the cosmetic composition in terms of use.
  • Example 1 Place the air cell (wet polyurethane foam) applicator (puff) on the carriers of Example 1 and Comparative Example 3 prepared by filling the cosmetic composition in Test Example 5, and utilize 1.0 kgf/ using a press machine (push-pull gauge). Pressed for 3 seconds with cm 2 to allow the composition to drain into the puff.
  • air cell wet polyurethane foam
  • Fig. 9 shows the results of comparing the discharge amount using a scale.
  • Example 1 showed a uniform discharge pattern.
  • Figure 11 shows a picture of the puff according to the number of discharges.
  • the composition discharged through the carrier in Example 1 was uniformly deposited on a large area of the applicator than Comparative Example 3. From this, it can be seen that the carrier according to the embodiment of the present invention exhibits a uniform discharge pattern not only in the discharge amount of the composition, but also in the discharged surface, thereby exhibiting the effect of uniform application when used.
  • Example 2 The same material as in Example 1 of Test Example 2 was used to stack wet polycarbonate-based polyurethane foam, dry polyether-based polyurethane foam, and mesh-structured fiber layers in order from the upper layer, and the edge of 1 mm was ultrasonic of Kyungil Ultrasonic Industry Co., Ltd. Using a device to bond at a frequency of 26.5 to 39khz to prepare a cosmetic composition carrier of Example 2. The appearance of the prepared Example 2 carrier is shown in FIGS. 13 to 16.
  • Example 3 the dry polyether-based polyurethane foam had a thickness of 6 mm, and the wet polycarbonate-based polyurethane foam and the dry polyether-based polyurethane foam were adhered to each other using an oil-based adhesive (urethane-based + acetic acid (solvent)).
  • oil-based adhesive urethane-based + acetic acid (solvent)
  • Example 4 was prepared in the same manner as in Example 3, but was prepared by laminating a dry polyether-based polyurethane foam having a thickness of 3 mm in two layers.
  • the appearance of the prepared Example 4 carrier is shown in FIG. 22, and it is an image in which a longitudinal section is exposed by cutting the carrier, and it can be seen that an incision was formed therein.
  • Cosmetics were prepared by filling the carriers of Examples 3 and 4 with 15 g of the cosmetic prepared in Test Example 1 above.
  • Example 3 Example 4 One 0.4 0.52 2 0.24 0.36 3 0.26 0.26 4 0.32 0.32 5 0.22 0.24 6 0.18 0.22 7 0.16 0.2 8 0.14 0.18 9 0.1 0.14 10 0.1 0.14 11 0.08 0.14 12 0.08 0.06 13 0.06 0.08 14 0.08 0.06 15 0.04 0.08 16 0.04 0.1 17 0.06 0.1 18 0.08 0.06 19 0.04 0.04 20 0.02 0.04

Abstract

The present specification describes a cosmetic composition carrier. The cosmetic composition carrier comprises a carrier with a layer-stacked structure, and thus can provide a carrier, which has superb bonding strength by means of ultrasonic or thermal bonding portions and is easily filled with contents.

Description

화장료 조성물 담체Cosmetic composition carrier
본 출원은 2018년 11월 30일자로 출원된 대한민국 특허출원 제10-2018-0152845호에 대한 우선권을 주장하며, 이 출원 내용 전체가 본 출원에 참조로서 통합된다. 또한, 본 출원은 2019년 9월 20일자로 출원된 대한민국 특허출원 제10-2019-0116199호에 대한 우선권을 주장하며, 이 출원 내용 전체가 본 출원에 참조로서 통합된다.This application claims priority to Korean Patent Application No. 10-2018-0152845 filed on November 30, 2018, the entire contents of which are incorporated herein by reference. In addition, this application claims priority to Korean Patent Application No. 10-2019-0116199 filed on September 20, 2019, the entire contents of which are incorporated herein by reference.
본 명세서는 화장료 조성물 담체에 관하여 기술한다.This specification describes a cosmetic composition carrier.
액상 화장료 조성물을 담체에 담지하여 팩트 타입의 용기에 넣은 이른바쿠션 팩트 화장품의 전 세계적 시장 확대가 진행되고 있다. 이러한 쿠션 팩트 화장품에 적합한 담체는 화장료 조성물이 용이하게 충진 될 것, 그 조성물을 장기간 균질하게 담지할 수 있을 것, 담체로부터 화장료 조성물을 취하고자 할 때 적당량이 균일하게 배출될 것, 내용물을 끝까지 사용할 때까지 장기간 배출양이 균일하게 유지될 것 등의 물성이 요구된다. 또한 미용제품이기 때문에 외관의 컬러감, 디자인 등의 심미적인 요구 또한 만족되어야 한다.A global market expansion of so-called cushion fact cosmetics in which a liquid cosmetic composition is loaded onto a carrier and placed in a fact type container is underway. A carrier suitable for such a cushion pact cosmetic should be easily filled with a cosmetic composition, capable of carrying the composition homogeneously for a long time, and when the cosmetic composition is taken from the carrier, an appropriate amount will be uniformly discharged, and the contents can be used to the end. Until then, physical properties such as long-term discharge amount will be kept uniform. In addition, since it is a beauty product, aesthetic needs such as color and design of the exterior must also be satisfied.
이러한 요구를 만족시키기 위해 담체를 층구조를 가지도록 하여 상부와 하부의 담체가 서로 다른 물성을 가지는 구성을 고려할 수 있다. 그러나 서로 다른 재질 및/또는 물성을 가지는 담체를 서로 붙이기 위해 일반적으로 알려진 접착제를 사용할 경우, 다공성으로 인하여 실제 접착제가 도포되어 접착되는 면적이 적어져 접착 내구성이 충분하지 않을 수 있다. 또한, 접착력이 충분하지 않을 경우 내부에 화장료 조성물을 담지하여 장기간 보관 시 접착된 부위가 떨어지는 문제가 발생할 수 있다. 나아가 충분한 접착력을 위해 다량의 접착제를 사용할 경우, 담체의 다공성 구조가 막히게 되어 담체로서의 기능을 제대로 발휘하지 못하는 문제가 발생할 수 있다.In order to satisfy these needs, the carrier may have a layered structure, so that the upper and lower carriers have different physical properties. However, when a generally known adhesive is used for attaching carriers having different materials and/or properties to each other, due to porosity, an actual adhesive is applied and the area to be adhered is reduced, so adhesion durability may not be sufficient. In addition, when the adhesive strength is not sufficient, the cosmetic composition may be loaded therein to cause a problem in which the adhered portion falls during long-term storage. Furthermore, if a large amount of adhesive is used for sufficient adhesion, the porous structure of the carrier becomes clogged, which may cause a problem of not properly functioning as a carrier.
[선행기술문헌][Advanced technical literature]
[특허문헌][Patent Document]
(특허문헌 1) 대한민국 등록특허공보 제10-1738121호(Patent Document 1) Korean Patent Registration No. 10-1738121
일 관점에서, 본 발명이 해결하고자 하는 과제는 화장료 조성물의 균질한 담지가 가능한 화장료 조성물 담체를 제공하는 것이다.In one aspect, the problem to be solved by the present invention is to provide a cosmetic composition carrier capable of homogeneous loading of the cosmetic composition.
다른 관점에서, 본 발명이 해결하고자 하는 과제는 화장료 조성물을 장기가 균질하게 담지할 수 있는 화장료 조성물 담체를 제공하는 것이다.In another aspect, the problem to be solved by the present invention is to provide a cosmetic composition carrier capable of supporting the cosmetic composition homogeneously in an organ.
또 다른 관점에서, 본 발명이 해결하고자 하는 과제는 담체로부터 화장료 조성물을 취할 때 적당량의 화장료 조성물이 배출되는 화장료 조성물 담체를 제공하는 것이다.In another aspect, the problem to be solved by the present invention is to provide a cosmetic composition carrier in which an appropriate amount of cosmetic composition is discharged when the cosmetic composition is taken from the carrier.
또 다른 관점에서, 본 발명이 해결하고자 하는 과제는 화장료 조성물을 내부에 담지한 후에 우수한 내구성을 유지할 수 있는 화장료 조성물 담체를 제공하는 것이다.In another aspect, the problem to be solved by the present invention is to provide a cosmetic composition carrier capable of maintaining excellent durability after supporting the cosmetic composition therein.
또 다른 관점에서, 본 발명이 해결하고자 하는 과제는 담체로부터 반복적으로 화장료 조성물을 취하여도 장기간 우수한 내구성을 유지할 수 있는 화장료 조성물 담체를 제공하는 것이다.In another aspect, the problem to be solved by the present invention is to provide a cosmetic composition carrier capable of maintaining excellent durability for a long period of time even if the cosmetic composition is repeatedly taken from the carrier.
또 다른 관점에서, 본 발명이 해결하고자 하는 과제는 담체 내에 담지된 화장료 조성물의 양이 줄어들어도 균일한 패턴으로 화장료 조성물이 배출될 수 있는 화장료 조성물 담체를 제공하는 것이다.In another aspect, the problem to be solved by the present invention is to provide a cosmetic composition carrier capable of discharging the cosmetic composition in a uniform pattern even if the amount of the cosmetic composition carried in the carrier is reduced.
또 다른 관점에서, 본 발명이 해결하고자 하는 과제는 화장료 조성물의 충진이 용이한 화장료 조성물 담체를 제공하는 것이다.In another aspect, the problem to be solved by the present invention is to provide a cosmetic composition carrier that is easy to fill the cosmetic composition.
또 다른 관점에서, 본 발명이 해결하고자 하는 과제는 다층 구조의 접합강도가 우수한 화장료 조성물 담체를 제공하는 것이다.In another aspect, the problem to be solved by the present invention is to provide a cosmetic composition carrier having excellent bonding strength of a multilayer structure.
또 다른 관점에서, 본 발명이 해결하고자 하는 과제는 화장료 조성물의 담지 후 담체의 외관이 우수한 화장료 조성물 담체를 제공하는 것이다.In another aspect, the problem to be solved by the present invention is to provide a cosmetic composition carrier excellent in appearance of the carrier after the cosmetic composition is supported.
또 다른 관점에서, 본 발명이 해결하고자 하는 과제는 담체 하부로부터의 화장료 조성물의 오버플로우를 방지할 수 있는 화장료 조성물 담체를 제공하는 것이다.In another aspect, the problem to be solved by the present invention is to provide a cosmetic composition carrier that can prevent the overflow of the cosmetic composition from the lower carrier.
일 실시예에서, 본 발명은 가장자리에 접합부가 형성된 화장료 조성물 담체로서,In one embodiment, the present invention is a cosmetic composition carrier formed with a junction at the edge,
상기 담체는, 포어사이즈, 밀도, 두께, 포어수 중 하나 이상이 서로 다른 복수의 폴리우레탄 폼이 적층된 적층부를 포함하는, The carrier includes a laminate in which a plurality of polyurethane foams having different pore sizes, density, thickness, and number of pores are stacked,
화장료 조성물 담체를 제공한다.Provided is a cosmetic composition carrier.
일 관점에서, 본 발명은 화장료 조성물의 균질한 담지가 가능한 화장료 조성물 담체를 제공할 수 있다.In one aspect, the present invention can provide a cosmetic composition carrier capable of homogeneous loading of the cosmetic composition.
다른 관점에서, 본 발명은 화장료 조성물을 장기간 균질하게 담지할 수 있는 화장료 조성물 담체를 제공할 수 있다.In another aspect, the present invention can provide a cosmetic composition carrier capable of carrying the cosmetic composition homogeneously for a long period of time.
또 다른 관점에서, 본 발명은 담체로부터 화장료 조성물을 취할 때 적당량의 화장료 조성물이 배출되는 화장료 조성물 담체를 제공할 수 있다.In another aspect, the present invention can provide a cosmetic composition carrier in which an appropriate amount of cosmetic composition is discharged when the cosmetic composition is taken from the carrier.
또 다른 관점에서, 본 발명은 화장료 조성물을 내부에 담지한 후에 우수한 내구성을 유지할 수 있는 화장료 조성물 담체를 제공할 수 있다.In another aspect, the present invention can provide a cosmetic composition carrier capable of maintaining excellent durability after supporting the cosmetic composition therein.
또 다른 관점에서, 본 발명은 담체로부터 반복적으로 화장료 조성물을 취하여도 장기간 우수한 내구성을 유지할 수 있는 화장료 조성물 담체를 제공할 수 있다.In another aspect, the present invention can provide a cosmetic composition carrier capable of maintaining excellent durability for a long period of time even if the cosmetic composition is repeatedly taken from the carrier.
또 다른 관점에서, 본 발명은 담체 내에 담지된 화장료 조성물의 양이 줄어들어도 균일한 패턴으로 화장료 조성물이 배출될 수 있는 화장료 조성물 담체를 제공할 수 있다.In another aspect, the present invention can provide a cosmetic composition carrier capable of discharging the cosmetic composition in a uniform pattern even if the amount of the cosmetic composition carried in the carrier is reduced.
또 다른 관점에서, 본 발명은 화장료 조성물의 충진이 용이한 화장료 조성물 담체를 제공할 수 있다.In another aspect, the present invention can provide a cosmetic composition carrier that is easy to fill the cosmetic composition.
또 다른 관점에서, 본 발명은 다층 구조의 접합강도가 우수한 화장료 조성물 담체를 제공할 수 있다.In another aspect, the present invention can provide a cosmetic composition carrier having excellent bonding strength of a multilayer structure.
또 다른 관점에서, 본 발명은 화장료 조성물의 담지 후 담체의 외관이 우수한 화장료 조성물 담체를 제공할 수 있다.In another aspect, the present invention can provide a cosmetic composition carrier excellent in appearance of the carrier after the cosmetic composition is supported.
또 다른 관점에서, 본 발명은 담체 하부로부터의 화장료 조성물의 오버플로우를 방지할 수 있는 화장료 조성물 담체를 제공할 수 있다.In another aspect, the present invention can provide a cosmetic composition carrier capable of preventing overflow of the cosmetic composition from the bottom of the carrier.
도 1은 본 발명 일실시예에 따른 담체의 단면 모식도이다.1 is a schematic cross-sectional view of a carrier according to an embodiment of the present invention.
도 2는 본 발명 일실시예에 따른 담체의 단면 모식도이다.2 is a schematic cross-sectional view of a carrier according to an embodiment of the present invention.
도 3은 본 발명 일실시예에 따른 담체의 단면 모식도이다.3 is a schematic cross-sectional view of a carrier according to an embodiment of the present invention.
도 4는 본 발명 일실시예에 따른 담체의 규격을 표시한 모식도이다.Figure 4 is a schematic diagram showing the specifications of the carrier according to an embodiment of the present invention.
도 5는 본 발명 일실시예에 따른 담체의 평면 모식도이다.5 is a schematic plan view of a carrier according to an embodiment of the present invention.
도 6은 본 발명 일실시예에 따른 담체의 단면 절단 사진이다.6 is a cross-sectional photograph of a carrier according to an embodiment of the present invention.
도 7은 실시예 1과 비교예 1의 담체 접합 결과 비교 사진이다.7 is a comparative picture of the results of carrier bonding of Example 1 and Comparative Example 1.
도 8은 시험예 4의 비교예 2의 담체에 화장료 조성물을 충진한 결과 사진이다.Figure 8 is a photograph of the result of filling the cosmetic composition in the carrier of Comparative Example 2 of Test Example 4.
도 9는 실시예 1과 비교예 3의 화장료 조성물 충진 후 담체 외관을 비교한 사진이다.9 is a photograph comparing the appearance of the carrier after filling the cosmetic composition of Example 1 and Comparative Example 3.
도 10은 토출 횟수에 따른 화장료 토출양을 나타낸 그래프이다.10 is a graph showing the amount of cosmetic discharge according to the number of discharges.
도 11은 토출 횟수에 따른 도포구 사진이다. 첫번째 그림에 표시된 숫자가 토출 횟수를 나타낸다.11 is a photograph of the applicator according to the number of discharges. The number shown in the first figure indicates the number of discharges.
도 12는 본 발명 일실시예에 따른 담체의 사진이다.12 is a photograph of a carrier according to an embodiment of the present invention.
도 13은 실시예 2 담체의 외관 사진으로, 담체를 층에 평행한 평면을 기준으로 45도 기울인 것이다.13 is a photograph of the appearance of a carrier in Example 2, wherein the carrier is inclined at 45 degrees relative to a plane parallel to the layer.
도 14는 실시예 2의 담체의 외관 사진으로, 담체의 평면측(상단)에서 찍은사진이다.14 is a photograph of the appearance of the carrier of Example 2, and is a photograph taken on the plane side (top) of the carrier.
도 15는 실시예 2의 담체의 외관 사진으로, 담체의 측면에서 찍은 사진이다.15 is a photograph of the appearance of the carrier of Example 2, and is a photograph taken from the side of the carrier.
도 16은 실시예 2의 담체의 외관 사진으로, 담체의 저면측(하단)에서 찍은 사진이다.16 is a photograph of the appearance of the carrier of Example 2, and is a photograph taken from the bottom side (bottom) of the carrier.
도 17은 실시예 3의 담체의 외관 사진으로, 담체를 층에 평행한 평면을 기준으로 45도 기울인 것이다.17 is a photograph of the appearance of the carrier of Example 3, wherein the carrier is inclined at 45 degrees relative to a plane parallel to the layer.
도 18은 실시예 3의 담체의 외관 사진으로, 담체의 평면측(상단)에서 찍은사진이다.18 is a photograph of the appearance of the carrier of Example 3, and is a photograph taken on the plane side (top) of the carrier.
도 19는 실시예 3의 담체의 외관 사진으로, 담체의 측면에서 찍은 사진이다.19 is a photograph of the appearance of the carrier of Example 3, and is a photograph taken from the side of the carrier.
도 20은 실시예 3의 담체의 외관 사진으로, 담체의 저면측(하단)에서 찍은 사진이다.20 is a photograph of the appearance of the carrier of Example 3, and is a photograph taken from the bottom side (bottom) of the carrier.
도 21은 실시예 3의 담체의 외관 사진으로, 담체를 절단하여 종단면이 노출되도록 한 상태의 사진이다.21 is a photograph of the appearance of the carrier of Example 3, and is a photograph of a state in which a longitudinal section is exposed by cutting the carrier.
도 22는 실시예 4의 담체의 외관 사진으로, 담체를 절단하여 종단면이 노출되도록 한 상태의 사진이다.22 is a photograph of the appearance of the carrier of Example 4, which is a photograph of a state in which a longitudinal section is exposed by cutting the carrier.
도 23은 토출 횟수에 따른 화장료 토출양을 나타낸 그래프이다.23 is a graph showing the amount of cosmetic discharge according to the number of discharges.
이하, 첨부한 도면들을 참조하여, 본 출원의 실시예들을 보다 상세하게 설명하고자 한다. 그러나 본 출원에 개시된 기술은 여기서 설명되는 실시예들에 한정되지 않고 다른 형태로 구체화될 수도 있다. 단지, 여기서 소개되는 실시예들은 개시된 내용이 철저하고 완전해질 수 있도록 그리고 당업자에게 본 출원의 사상이 충분히 전달될 수 있도록 하기 위해 제공되는 것이다. 도면에서 각 구성요소를 명확하게 표현하기 위하여 구성요소의 폭이나 두께 등의 크기를 다소 확대하여 나타내었다. 또한, 설명의 편의를 위하여 구성요소의 일부만을 도시하기도 하였으나, 당업자라면 구성요소의 나머지 부분에 대하여도 용이하게 파악할 수 있을 것이다. 또한, 해당 분야에서 통상의 지식을 가진 자라면 본 출원의 기술적 사상을 벗어나지 않는 범위 내에서 본 출원의 사상을 다양한 다른 형태로 구현할 수 있을 것이다.Hereinafter, exemplary embodiments of the present application will be described in detail with reference to the accompanying drawings. However, the technology disclosed in the present application is not limited to the embodiments described herein and may be embodied in other forms. However, the embodiments introduced herein are provided to ensure that the disclosed contents are thorough and complete and that the spirit of the present application is sufficiently conveyed to those skilled in the art. In order to clearly express each component in the drawings, the size of the component, such as width or thickness, is slightly enlarged. Also, for convenience of description, only a part of components are illustrated, but those skilled in the art will be able to easily grasp the rest of the components. In addition, those of ordinary skill in the art may implement the spirit of the present application in various other forms without departing from the technical spirit of the present application.
본 명세서에서 "함침재"란 화장료 조성물을 내부에 흡수하여 담지할 수 있는 것을 의미하며, "담지체", "담체" 또는 "매개체"로도 표현될 수 있다. 일 예에서, 함침재는 내부에 담지된 물질을 별도의 도포구에 배출하여 사용될 수 있다.As used herein, "impregnating material" means that the cosmetic composition can be absorbed and supported therein, and may also be expressed as "carrier", "carrier" or "media". In one example, the impregnating material may be used by discharging the material supported therein to a separate applicator.
본 명세서에서 "도포구"란 화장료 조성물을 도포 대상인 피부 등에 전달하기 위하여 사용되는 것을 의미하며, "도포수단", "도포용 스펀지", 또는 "어플리케이터(applicator)"라고도 표현할 수 있다. 일 예에서, 도포구는 퍼프, 팁, 브러쉬 등을 포함할 수 있다.In the present specification, the term “applying sphere” means used to deliver the cosmetic composition to the skin to be applied, etc., and may also be expressed as “applying means”, “applying sponge”, or “applicator”. In one example, the applicator may include puffs, tips, brushes, and the like.
본 명세서에서 상기 점도는 브룩필드 점도계 모델 DV3T Brookfield Viscometer Model DV3T)를 사용하여 온도 30℃에서 64번 스핀들, 12rpm으로 1분간 측정한 것일 수 있다. In the present specification, the viscosity may be measured by using a Brookfield Viscometer Model DV3T Brookfield Viscometer Model DV3T) at a temperature of 30°C for 64 spindles and 12 rpm for 1 minute.
본 명세서에서 "오픈 셀(open cell)"은 발포폼 내에 포함되는 셀로서, 전체가 개방(open)되어 있는 셀을 의미하며, "세미오픈 셀(semi-open cell)"은 셀의 적어도 일부분이 개방되어 있는 셀을 의미하며, "클로즈드 셀(closed cell)"은 셀의 적어도 일부분이 밀폐(closed)되어 있는 셀을 의미하며, "망상형 구조(reticulated structure)"는 클로즈드 셀, 세미오픈 셀 또는 오픈 셀의 발포폼 내 셀 벽을 제거시키는 망상화 공정(reticulation)을 거쳐 형성되는 것으로, 셀 벽이 거의 없는 그물망과 같은 구조를 가지는 것을 의미한다. 클로즈드 셀은 포어가 발포된 상태 대로의 셀 구조가 작은 풍선형태로 유지된 것이므로, 공기가 투과되지 않는 구조이다. 망상형 구조는 발포후 풍선형태의 포어 셀들의 막(벽)이 망상화(reticulation)에 의해 제거되어 공기 투과만이 아니라 액상들의 흡수 배출이 가능한 구조를 가진다.In this specification, "open cell" is a cell included in a foam, and means a cell that is entirely open, and "semi-open cell" means that at least a portion of the cell is "Open cell" means "closed cell" means a cell in which at least a portion of the cell is closed, and "reticulated structure" means a closed cell, a semi-open cell, or It is formed through a reticulation process that removes the cell walls in the foam of the open cell, which means that it has the same structure as a net with few cell walls. The closed cell has a structure in which the cell structure as the foam is foamed is maintained in a small balloon shape, so that the air is impermeable. The reticulated structure has a structure in which the membranes (walls) of balloon-shaped pore cells after foaming are removed by reticulation, so that not only air permeation but also absorption and discharge of liquid phases is possible.
본 명세서에서 "폴리우레탄 폼"은 폴리우레탄을 발포시킨 후 고화한 것으로, "우레탄 폼"으로 표현할 수도 있다.In the present specification, "polyurethane foam" is solidified after foaming polyurethane, and may also be referred to as "urethane foam".
본 명세서에서 "포어 사이즈"는 폼의 포어, 즉 셀의 직경을 광학 현미경(NIKON ECLIPSE 80i)으로 측정한 평균치일 수 있다.In this specification, "pore size" may be an average value of pores of a foam, that is, a cell diameter measured by an optical microscope (NIKON ECLIPSE 80i).
본 명세서에서 "포어 수"는 폼의 단위선 내의 셀의 개수를 의미한다. 상기 포어 수는 폼의 1 인치 당 포어 수(ppi, pores per inch)를 말하는 것으로, 1 인치 선 안에 존재하는 포어의 개수를 의미한다. In the present specification, “the number of pores” refers to the number of cells in the unit line of the form. The number of pores refers to the number of pores per inch (ppi) per inch of the foam, and means the number of pores present in a line of 1 inch.
본 명세서에서 폼의 "경도"는 애스커(ASKER, 제조원) 듀로미터 경도(DUROMETER HARDNESS) 측정기(F 형(Type F))로 측정했을 때의 경도로서, 화장료 조성물이 폼에 담지되기 전의 경도를 의미한다. In this specification, the "hardness" of the foam is the hardness measured by an asker (ASKER, manufacturer) durometer hardness (F type (F)), the hardness before the cosmetic composition is supported on the foam it means.
함침재로서 요구되는 물성은 예를 들어 흡수성, 충진능, 담지능, 내구성, 배출능 등을 들 수 있다.Physical properties required as an impregnating material include, for example, absorbency, filling capacity, loading capacity, durability, and discharge capacity.
본 명세서에서 흡수성은 함침재가 화장료 조성물을 흡수하여 함침재 내부 전체를 통하여 균일하게 담지하는 것을 의미한다. 흡수성이 높다는 것은 함침재와 화장료 조성물 간의 상용성이 우수한 것이며, 흡수성이 높을수록 고온 조건 보관 시 화장료 조성물 증발을 억제할 수 있다.Absorption in this specification means that the impregnating material absorbs the cosmetic composition and is uniformly supported throughout the impregnating material. The high water absorption is excellent in compatibility between the impregnating material and the cosmetic composition, and the higher the water absorption, the more it can suppress evaporation of the cosmetic composition when stored under high temperature conditions.
본 명세서에서 충진능은 화장료 조성물을 함침재 내부로 충진시킬 때에 화장료 조성물이 용이하게 함침재 내부 전체로 균일하게 담지되는 것을 의미한다. 충진능이 우수하다는 것은 화장료 조성물을 동일 조건과 압력으로 충진시킬 때에 화장료 조성물이 빠른 속도로 균일하게 충진되는 것을 의미한다.The filling ability in the present specification means that the cosmetic composition is easily and uniformly supported throughout the impregnating material when the cosmetic composition is filled into the impregnating material. The excellent filling ability means that the cosmetic composition is uniformly filled at a high speed when the cosmetic composition is filled under the same conditions and pressure.
본 명세서에서 담지능은 함침재가 화장료 조성물을 보유하여 유지할 수 있는 능력을 의미한다. 담지능이 우수하다는 것은 화장료 조성물을 장기간 동안 균일하게 담지한 상태를 유지하는 것을 의미한다. 이러한 함침재의 담지능은 화장료 조성물을 전달을 위해 도포구에 일시적으로 취출되는 것, 도포구에 일시적으로 묻히는 것과는 구분되는 것이다.In this specification, the loading ability refers to the ability of the impregnating material to retain and maintain the cosmetic composition. The excellent holding ability means that the cosmetic composition is uniformly supported for a long period of time. The impregnating ability of the impregnating material is distinguished from being temporarily taken out of the applicator for delivery of the cosmetic composition and temporarily applied to the applicator.
본 명세서에서 내구성은 화학적 내구성과 물리적 내구성을 포함한다. 화학적 내구성은 함침재가 화장료 조성물이 담지된 상태로 일정 온도에서 일정 시간 방치한 경우 함침재가 녹거나 찢어지는 등의 손상이나 팽창과 같은 변형이 일어나지 않고 초기 상태를 유지하는 성질을 의미한다. 물리적 내구성은 함침재에 물리적 자극, 예를 들어 화장료 조성물의 취출을 위해 도포구를 함침재에 반복적으로 접촉 및 압력을 가하는 경우에 함침재에 인가된 압력 및 마찰에 대하여 견디는 성질을 의미한다. 따라서 내구성이 높다는 것은 함침재가 화장료 조성물을 함침한 상태로 일정 조건에서 장기간 변형 또는 손상 없이 유지되며, 도포구에 의해 반복적으로 물리적 마찰과 압력을 받더라도 함침재의 손상 또는 변형 없이 원 상태를 유지할 수 있는 것을 의미한다.Durability herein includes chemical durability and physical durability. Chemical durability refers to a property in which the impregnating material is maintained in an initial state without deformation such as damage or expansion, such as melting or tearing of the impregnating material when the cosmetic composition is left for a certain period of time at a predetermined temperature while the cosmetic composition is supported. Physical durability refers to a property that withstands physical impulses to the impregnating material, for example, pressure and friction applied to the impregnating material when the applicator is repeatedly contacted and pressured to the impregnating material for taking out the cosmetic composition. Therefore, the high durability means that the impregnating material remains impregnated with the cosmetic composition for a long period of time under a certain condition without deformation or damage, and it can maintain its original state without damaging or deforming the impregnating material even if it is repeatedly subjected to physical friction and pressure by the applicator. it means.
본 명세서에서 배출능은 함침재 내부에 담지된 화장료 조성물이 사용 시에 적절한 양으로 배출되는 능력을 의미한다. 예를 들어 상기 배출능은 일정 압력으로 함침재에 도포구를 접촉하여 화장료 조성물이 도포구에 묻어나는 양으로 나타낼 수 있다. 배출능이 너무 높거나 낮을 경우 화장료 조성물이 과도하게 묻어나거나 지나치게 소량 만이 묻어나 사용이 불편하므로, 함침재에 인가되는 압력에 따라 적당량의 화장료 조성물이 배출될 수 있도록 적절한 배출능을 갖는 것이 바람직하다.The discharge capacity in the present specification means the ability of the cosmetic composition carried inside the impregnating material to be discharged in an appropriate amount when used. For example, the discharge capacity may be represented by the amount of the cosmetic composition on the applicator by contacting the applicator with the impregnating material at a constant pressure. If the discharge capacity is too high or low, it is difficult to use because the cosmetic composition is excessively smeared or only a small amount is applied, so it is preferable to have a proper discharge capacity so that an appropriate amount of the cosmetic composition can be discharged depending on the pressure applied to the impregnating material.
본 발명 일 실시예에 따른 화장료 조성물 담체는 복수의 폴리우레탄 폼이 적층된 적층부를 포함하며, 가장자리에 접합부가 형성된 것일 수 있다. The cosmetic composition carrier according to an embodiment of the present invention includes a laminated portion in which a plurality of polyurethane foams are stacked, and may have a junction formed at an edge.
도 1에 본 발명 일 실시예에 따른 화장료 조성물 담체의 단면 모식도를 예시적으로 도시한다. 본 실시예에 따른 화장료 조성물 담체(100)는 복수의 폴리우레탄 폼(110, 120)을 포함하는 적층부를 포함하고, 폼의 가장자리에 빗금으로 표시한 접합부(140)가 형성되어 적층부를 일체로 접합할 수 있다.1 schematically illustrates a cross-sectional schematic view of a cosmetic composition carrier according to an embodiment of the present invention. The cosmetic composition carrier 100 according to the present embodiment includes a lamination part including a plurality of polyurethane foams 110 and 120, and a junction 140 marked with a hatch is formed at the edge of the foam to integrally join the lamination part. can do.
상기 적층부는 2 이상의 폴리우레탄 폼을 포함할 수 있다. 일 예에서, 상기 적층부는 포어사이즈, 밀도, 두께, 포어수 중 하나 이상이 서로 다른 복수의 폴리우레탄 폼이 적층된 것을 포함할 수 있다. The laminated portion may include two or more polyurethane foams. In one example, the laminate may include a plurality of polyurethane foams having different pore sizes, density, thickness, and number of pores different from each other.
상기 폴리우레탄은 2개 이상의 수산기를 갖는 폴리올과 폴리이소시아네이트의 반응에 의해 제조될 수 있다. 상기 폴리올은 폴리에테르 폴리올, 폴리에스테르 폴리올, 폴리카보네이트 폴리올, 폴리올레핀 폴리올을 사용할 수 있으며, 사용되는 폴리올에 따라 폴리에테르계 폴리우레탄 폼, 폴리에스테르계 폴리우레탄 폼, 폴리카보네이트계 폴리우레탄 폼, 폴리올레핀계 폴리우레탄 폼으로 구분된다.The polyurethane may be prepared by reaction of a polyol having two or more hydroxyl groups and a polyisocyanate. The polyol may use polyether polyol, polyester polyol, polycarbonate polyol, polyolefin polyol, and polyether-based polyurethane foam, polyester-based polyurethane foam, polycarbonate-based polyurethane foam, and polyolefin-based depending on the polyol used. It is divided into polyurethane foam.
전체가 동일한 물성을 갖는 단일 폼을 담체로 포함하는 경우, 담지되어 있는 화장료 조성물이 사용 시점에 따라 배출양이 불균일해지는 문제가 있다. 구체적으로, 사용 초기 대비, 담지되어 있는 화장료 조성물의 소비에 따라 양이 줄어들어, 화장료 조성물을 사용 초기의 약 50중량% 이상 취하고 나면 배출되는 정도가 급격히 떨어질 수 있다. 또한 단일 폼을 담체로 포함하는 경우 비교적 포어 사이즈가 크기 때문에 배출 횟수가 반복될 수록 배출시 마다 상이한 양의 화장료 조성물이 배출되어 배출 패턴이 균일하지 않을 수 있다. 본 발명에 실시예에 따른 화장료 조성물 포어사이즈, 밀도, 두께, 포어수 중 하나 이상이 서로 다른 복수의 폴리우레탄 폼을 층구조로 포함하여 사용 초기 대비 50% 이상의 중량을 사용할 때까지 상술한 단일 폼의 경우에 비하여 화장료 조성물의 배출 정도가 균일하게 유지될 수 있다.When the whole includes a single foam having the same physical properties as a carrier, there is a problem that the discharge amount is uneven depending on the point of use of the supported cosmetic composition. Specifically, compared to the initial use, the amount is reduced according to consumption of the supported cosmetic composition, and after taking the cosmetic composition at least about 50% by weight of the initial use, the degree of discharge may drop rapidly. In addition, when a single foam is included as a carrier, since the pore size is relatively large, as the number of discharges is repeated, different amounts of cosmetic compositions are discharged at each discharge, so the discharge pattern may not be uniform. Cosmetic composition according to an embodiment of the present invention The single foam described above until the use of a weight of 50% or more compared to the initial use, including a plurality of polyurethane foams having one or more different pore sizes, density, thickness, and number of pores as a layer structure Compared to the case, the discharge degree of the cosmetic composition may be maintained uniformly.
상기 적층부는 다층, 구체적으로 2 내지 20개, 더 구체적으로 2 내지 10개, 보다 더 구체적으로 2 내지 5개의 폴리우레탄 폼을 포함할 수 있다.The stacked portion may include a multilayer, specifically 2 to 20, more specifically 2 to 10, and even more specifically 2 to 5 polyurethane foams.
상기 적층부는 표면측, 즉 사용 시 담체로부터 화장료 조성물이 배출되는 방향을 상부라 할 때, 최상층에 폴리카보네이트계 폴리우레탄 폼을 포함할 수 있다. 도 1의 모식도에서 폴리우레탄 폼(110)과 도 2 내지 도 4의 모식도에서 폴리우레탄 폼(210)이 여기에 해당한다.The stacked portion may include a polycarbonate-based polyurethane foam on the uppermost layer, that is, when the direction in which the cosmetic composition is discharged from the carrier during use is upper. The polyurethane foam 110 in the schematic diagram of FIG. 1 and the polyurethane foam 210 in the schematic diagrams of FIGS. 2 to 4 correspond to this.
상기 폴리카보네이트계 폴리우레탄 폼은 폴리에테르계 및 폴리에스테르계 폴리우레탄 폼과 비교하여 내약품성, 내화학성을 가지고, 내구성과 같은 높은 물리적 성질을 나타낼 수 있다. 사용 시 화장료 조성물이 배출되는 사용부에 해당하기 때문에 화장료 조성물을 취출하기 위한 물리적 접촉이 반복되어도 우수한 내구성으로 인하여 장기간 변형 없이 사용이 가능하다.The polycarbonate-based polyurethane foam has chemical resistance and chemical resistance as compared with polyether-based and polyester-based polyurethane foams, and may exhibit high physical properties such as durability. Since it corresponds to the use portion where the cosmetic composition is discharged during use, it can be used without long-term deformation due to its excellent durability even when physical contact for taking out the cosmetic composition is repeated.
상기 화장료 조성물은 담체의 기공 내에 함침되고, 외력에 의하여 배출 되는데, 이때 기공이 형성된 발포폼의 셀 구조가 클로즈드 셀인 경우 화장료 조성물의 함침 및 배출이 이루어질 수 없다. 따라서, 상기 폴리카보네이트계 폴리우레탄 폼은 100% 클로즈드 셀인 경우를 제외하며, 오픈 셀, 세미오픈 셀, 망상형 구조를 갖는 것이 바람직하고, 이러한 셀 구조는 발포폼의 제조에 따라 클로즈드 셀이 일부 포함될 수도 있다. 가장 바람직하기로는, 망상형 구조의 발포폼을 사용함으로써 화장료 조성물의 흡수능, 담지능 및 배출능을 높일 수 있다. 상기 오픈 셀, 반오픈 셀 및 망상형 구조의 발포폼은 단면을 잘라서 사진 촬영을 통해 확인이 가능하다.The cosmetic composition is impregnated into the pores of the carrier and discharged by external force. In this case, if the cell structure of the foamed foam is closed cell, impregnation and discharge of the cosmetic composition cannot be made. Therefore, the polycarbonate-based polyurethane foam, except for the case of 100% closed cell, it is preferable to have an open cell, a semi-open cell, a network structure, such cell structure is partially included in the closed cell according to the production of foam It might be. Most preferably, the use of a foamed foam having a network structure can increase the absorption, loading and discharge capacity of the cosmetic composition. The open cell, the half open cell and the foamed foam having a reticular structure can be confirmed by taking a picture by cutting a cross section.
상기 폴리카보네이트계 폴리우레탄 폼의 포어 사이즈는 50 ㎛ 이상, 55㎛ 이상, 60 ㎛ 이상, 65㎛ 이상, 70㎛ 이상, 75㎛ 이상, 80㎛ 이상, 85㎛ 이상, 90㎛ 이상, 95㎛ 이상, 100㎛ 이상, 105㎛ 이상, 또는 110㎛ 이상이고, 500㎛ 이하, 450㎛ 이하, 400㎛ 이하, 350㎛ 이하, 300㎛ 이하, 250㎛ 이하, 200㎛ 이하, 190㎛ 이하, 180㎛ 이하, 170㎛ 이하, 160㎛ 이하, 150㎛ 이하, 140㎛ 이하, 130㎛ 이하, 또는 120㎛ 이하일 수 있으며, 예를 들어 50 내지 500㎛, 또는 100 내지 300㎛일 수 있다. 상기와 같은 미세 포어 사이즈를 가져 담지능과 배출력이 우수할 수 있다. 화장료 조성물이 배출되는 표면측에 배치되므로 화장료 조성물의 균일한 배출을 위하여 상기와 같은 미세 포어 사이즈를 가질 수 있다. 포어 사이즈가 상기 범위 미만인 경우에는 담지되는 양이 불충분하며 배출능이 저하되어 충분한 양의 화장료 조성물이 배출되지 못한다. 포어 사이즈가 상기 범위 초과인 경우에는 목적하는 균일한 토출력을 기대하기 어렵고, 폼의 표면이 거칠어질 수 있어 화장료 취출 과정에서의 사용감이 부드럽지 않을 수 있다. The pore size of the polycarbonate-based polyurethane foam is 50 μm or more, 55 μm or more, 60 μm or more, 65 μm or more, 70 μm or more, 75 μm or more, 80 μm or more, 85 μm or more, 90 μm or more, 95 μm or more , 100 µm or more, 105 µm or more, or 110 µm or more, 500 µm or less, 450 µm or less, 400 µm or less, 350 µm or less, 300 µm or less, 250 µm or less, 200 µm or less, 190 µm or less, 180 µm or less , 170 µm or less, 160 µm or less, 150 µm or less, 140 µm or less, 130 µm or less, or 120 µm or less, for example, 50 to 500 µm, or 100 to 300 µm. Having the fine pore size as described above may be excellent in carrying capacity and discharge power. Since the cosmetic composition is disposed on the surface side to be discharged, it can have a fine pore size as described above for uniform discharge of the cosmetic composition. If the pore size is less than the above range, the supported amount is insufficient and the discharge capacity is lowered, so that a sufficient amount of the cosmetic composition is not discharged. When the pore size exceeds the above range, it is difficult to expect a desired uniform discharge power, and the surface of the foam may be rough, so that the feeling of use in the cosmetic extraction process may not be smooth.
일 예에서, 상기 폴리카보네이트계 폴리우레탄 폼의 포어 사이즈는 하부 층의 폴리우레탄 폼에 비하여 작은 사이즈를 가질 수 있다. In one example, the pore size of the polycarbonate-based polyurethane foam may have a smaller size than the polyurethane foam of the lower layer.
상기 폴리카보네이트계 폴리우레탄 폼의 밀도는 0.05 g/㎤ 이상, 0.06 g/㎤ 이상, 0.07 g/㎤ 이상, 0.08 g/㎤ 이상, 0.09 g/㎤ 이상, 0.10 g/㎤ 이상, 0.11 g/㎤ 이상, 0.12 g/㎤ 이상, 0.13 g/㎤ 이상, 0.14 g/㎤ 이상, 0.15 g/㎤ 이상 또는 0.16g/㎤ 이상이고, 0.25 g/㎤ 이하, 0.24 g/㎤ 이하, 0.23 g/㎤ 이하, 0.22 g/㎤ 이하, 0.21 g/㎤ 이하, 0.20 g/㎤ 이하, 0.19 g/㎤ 이하, 0.18 g/㎤ 이하, 또는 0.17 g/㎤ 이하일 수 있으며, 예를 들어 0.05 내지 0.25g/㎤, 또는 0.1 내지 0.2g/㎤ 일 수 있다. 밀도가 상기 범위 미만일 경우 화장료 조성물이 너무 많은 양 배출되어 사용성이 저하될 수 있으며, 밀도가 상기 범위 초과일 경우에는 화장료 조성물이 함침될 수 있는 기공이 부족하여 화장료 조성물의 충진이 어려울 수 있으며, 화장료 조성물의 배출이 잘 이루어지지 않을 수 있다.The density of the polycarbonate-based polyurethane foam is 0.05 g/cm 3 or more, 0.06 g/cm 3 or more, 0.07 g/cm 3 or more, 0.08 g/cm 3 or more, 0.09 g/cm 3 or more, 0.10 g/cm 3 or more, 0.11 g/cm 3 or more Or more, 0.12 g/cm 3 or more, 0.13 g/cm 3 or more, 0.14 g/cm 3 or more, 0.15 g/cm 3 or more, or 0.16 g/cm 3 or more, 0.25 g/cm 3 or less, 0.24 g/cm 3 or less, 0.23 g/cm 3 or less , 0.22 g/cm 3 or less, 0.21 g/cm 3 or less, 0.20 g/cm 3 or less, 0.19 g/cm 3 or less, 0.18 g/cm 3 or less, or 0.17 g/cm 3 or less, for example, 0.05 to 0.25 g/cm 3, Or 0.1 to 0.2 g/cm 3. If the density is less than the above range, the cosmetic composition may be discharged in an excessive amount to deteriorate usability, and when the density is above the above range, filling of the cosmetic composition may be difficult due to insufficient pores in which the cosmetic composition may be impregnated. The composition may not be discharged well.
일 예에서, 상기 폴리카보네이트계 폴리우레탄 폼의 밀도는 하부 층의 폴리우레탄 폼에 비하여 클 수 있다. In one example, the density of the polycarbonate-based polyurethane foam may be greater than that of the polyurethane foam of the lower layer.
상기 폴리카보네이트계 폴리우레탄 폼의 포어 수는 80 ppi 이상, 85 ppi 이상, 90 ppi 이상, 95 ppi 이상, 100 ppi 이상, 105 ppi 이상, 110 ppi 이상, 115 ppi 이상, 또는 120 ppi 이상이고, 170 ppi 이하, 165 ppi 이하, 160 ppi 이하, 155 ppi 이하, 150 ppi 이하, 145 ppi 이하, 140 ppi 이하, 135 ppi 이하, 또는 130 ppi 이하일 수 있으며, 예를 들어 80 내지 170 ppi또는 110 내지 150 ppi일 수 있다. 상기 발포폼의 포어 수가 상기 미만이면 폼의 탄성이 떨어지며 화장료 조성물의 유동성을 제어하기가 어렵고, 포어 수가 상기 범위를 초과할 경우에는 사용 시 내구성이 떨어질 수 있다.The number of pores of the polycarbonate-based polyurethane foam is 80 ppi or more, 85 ppi or more, 90 ppi or more, 95 ppi or more, 100 ppi or more, 105 ppi or more, 110 ppi or more, 115 ppi or more, or 120 ppi or more, 170 ppi or less, 165 ppi or less, 160 ppi or less, 155 ppi or less, 150 ppi or less, 145 ppi or less, 140 ppi or less, 135 ppi or less, or 130 ppi or less, for example, 80 to 170 ppi or 110 to 150 ppi Can be If the number of pores of the foam is less than the above, the elasticity of the foam is poor and it is difficult to control the fluidity of the cosmetic composition, and when the number of pores exceeds the above range, durability may be deteriorated when used.
일 예에서, 상기 폴리카보네이트계 폴리우레탄 폼의 포어 수는 하부 층의 폴리 우레탄 폼에 비하여 클 수 있다.In one example, the number of pores of the polycarbonate-based polyurethane foam may be greater than the polyurethane foam of the lower layer.
상기 폴리카보네이트계 폴리우레탄 폼의 경도는 애스커(ASKER) 경도기 F 형(Type F) 기준으로 50 이상, 55 이상, 60 이상, 61 이상, 62 이상, 63 이상, 64 이상, 65 이상, 66 이상, 67 이상, 68 이상, 69 이상, 또는 70 이상이고, 90 이하, 89 이하, 88 이하, 87 이하, 86 이하, 또는 85 이하일 수 있으며, 예를 들어 50 내지 90의 경도를 가질 수 있다. 만일, 경도가 상기 범위 미만인 경우 화장료 조성물을 취출할 때에 폴리우레탄 폼에 함침시킨 화장료 조성물이 과도하게 배출될 수 있으며, 경도가 상기 범위 초과로 너무 딱딱하면 화장료 조성물이 쉽게 배출되지 않을 수 있다.The hardness of the polycarbonate-based polyurethane foam is 50 or more, 55 or more, 60 or more, 61 or more, 62 or more, 63 or more, 64 or more, 65 or more, 66 on the basis of the type F of the ASKER hardness tester. Or more, 67 or more, 68 or more, 69 or more, or 70 or more, and 90 or less, 89 or less, 88 or less, 87 or less, 86 or less, or 85 or less, for example, may have a hardness of 50 to 90. If the hardness is less than the above range, the cosmetic composition impregnated in the polyurethane foam may be excessively discharged when the cosmetic composition is taken out. If the hardness is too hard beyond the above range, the cosmetic composition may not be easily discharged.
상기 폴리카보네이트계 폴리우레탄 폼은 습식으로 발포하여 제조된 습식 폴리카보네이트계 폴리우레탄 폼일 수 있다. The polycarbonate-based polyurethane foam may be a wet polycarbonate-based polyurethane foam prepared by wet foaming.
일예에서, 상기 습식으로 발포하여 폴리우레탄 폼을 제조하는 습식 공법은 폴리우레탄 폼의 재료가 되는 원료를 배합하여 혼합하고, 상기 혼합물을 발포(foaming)하여 폼 블럭을 형성하고, 상기 폼 블록을 함침망상화(quenching)하는 것을 포함할 수 있다. 상기 함침망상화는 액상(화학물)이 채워진 컨테이너 내에 폼 블록을 함침한 후, 화학적 작용으로 망상화하는 것을 포함할 수 있다.In one example, the wet method of manufacturing a polyurethane foam by foaming with wet blends and mixes the raw materials that are the material of the polyurethane foam, forms a foam block by foaming the mixture, and impregnates the foam block And quenching. The impregnation reticulation may include impregnating a foam block in a container filled with a liquid (chemical), and then reticulating by chemical action.
습식 공정으로 망상화된 폴리우레탄 폼은 부드러운 특징을 나타내며, 미세한 포어 형성이 가능하므로 화장료 조성물이 균일하게 배출될 수 있다.Polyurethane foam reticular by the wet process exhibits soft characteristics, and since fine pores can be formed, the cosmetic composition can be uniformly discharged.
일반적으로 습식 공정으로 제조되는 습식 폴리우레탄 폼은 통상적으로 내구성, 내약품성, 내화학성이 낮은 경향을 나타내어, 장기간 화장료 조성물을 담지할 경우 변형 내지 손상의 우려가 있으며, 반복적 화장료 조성물의 취출에 따른 물리적 변형 내지 손상의 우려가 있다. 본 발명 실시예에 따른 담체는 최상층에 폴리카보네이트계 폴리우레탄 폼을 사용하므로 우수한 내약품성, 내화학성 및 우수한 물리적 내구성을 가져, 미세한 포어를 가지고 부드러운 동시에 변형 또는 손상 없이 장기간 사용 가능한 담체를 제공할 수 있다.In general, wet polyurethane foam produced by a wet process generally exhibits a tendency to be low in durability, chemical resistance, and chemical resistance, and thus, when carrying a cosmetic composition for a long period of time, there is a risk of deformation or damage, and physical damage caused by repeated take-out of the cosmetic composition There is a risk of deformation or damage. Since the carrier according to the embodiment of the present invention uses a polycarbonate-based polyurethane foam on the top layer, it has excellent chemical resistance, chemical resistance, and excellent physical durability, and can provide a carrier that can be used for a long time without being deformed or damaged while being soft with fine pores. have.
상기 적층부는 상기 최상층의 하부에 하나 이상의 폴리우레탄 폼을 포함할 수 있으며, 이하에서 이를 하부층이라 한다. 도 1의 모식도에서 폴리우레탄 폼(120)과 도 2 내지 도 4의 모식도에서 폴리우레탄 폼(220)이 여기에 해당한다.The laminate may include one or more polyurethane foams at the bottom of the top layer, hereinafter referred to as the bottom layer. The polyurethane foam 120 in the schematic diagram of FIG. 1 and the polyurethane foam 220 in the schematic diagrams of FIGS. 2 to 4 correspond to this.
상기 하부층은 폴리에테르계 폴리우레탄 폼을 포함할 수 있다. 상기 하부층은 화장료 조성물을 안정적으로 담지하며, 담체 전체에 우수한 탄력성을 부여할 수 있다. 또한 하부로부터 화장료 조성물이 충진되는 경우 우수한 충진능을 나타낼 수 있으며, 충분한 양의 화장료 조성물을 흡수하여 유지하는 흡수성과 담지능이 우수하다. 폴리에테르계 폴리우레탄 폼이 함침재로서 흡수성, 담지능 및 배출능 면에서 유리하고, 폴리에스테르계 폴리우레탄 폼 대비 기공 사이즈가 커 공기 투과성이 높으며, 보다 푹신한 느낌 및 부드러운 정도가 우수하고, 유연성 및 탄력성이 좋을 뿐만 아니라 내구성이 우수하여 고온 또는 온도 변화가 큰 환경에서도 부서지고 찢어지는 현상을 나타내지 않는다. The lower layer may include a polyether-based polyurethane foam. The lower layer stably supports the cosmetic composition, and can provide excellent elasticity to the entire carrier. In addition, when the cosmetic composition is filled from the bottom, it can exhibit excellent filling ability, and is excellent in absorbency and loading ability to absorb and maintain a sufficient amount of the cosmetic composition. Polyether-based polyurethane foam is an impregnating material, which is advantageous in terms of absorbency, carrying capacity, and discharging ability, and has a large pore size compared to polyester-based polyurethane foam, providing high air permeability, excellent fluffy feel and softness, flexibility and It is not only good in elasticity, but also excellent in durability, so it does not exhibit the phenomenon of breaking and tearing even in environments with high temperature or high temperature.
폴리에테르계 폴리우레탄 폼은 폴리에스테르계 폴리우레탄 폼에 비해 유중수형 화장료 조성물과의 상용성이 높아, 폴리에테르계 폴리우레탄 폼은 유중수형 화장료 조성물에 대한 흡수력이 우수하여 화장료 조성물이 쉽게 증발되지 않아, 흡수성, 담지능, 내구성이 폴리에스테르계 폴리우레탄 폼에 비해 현저히 우수할 수 있다.Polyether-based polyurethane foams have higher compatibility with water-in-oil cosmetic compositions than polyester-based polyurethane foams, and polyether-based polyurethane foams have excellent absorption for water-in-oil cosmetic compositions, so cosmetic compositions do not evaporate easily. , Absorbency, holding ability, and durability may be significantly superior to that of the polyester-based polyurethane foam.
상기 화장료 조성물은 담체의 기공 내에 함침되고, 외력에 의하여 배출 되는데, 이때 기공이 형성된 발포폼의 셀 구조가 클로즈드 셀인 경우 화장료 조성물의 함침 및 배출이 이루어질 수 없다. 따라서, 상기 폴리에테르계 폴리우레탄 폼은 100% 클로즈드 셀인 경우를 제외하며, 오픈 셀, 세미오픈 셀, 망상형 구조를 갖는 것이 바람직하고, 이러한 셀 구조는 발포폼의 제조에 따라 클로즈드 셀이 일부 포함될 수도 있다. 가장 바람직하기로는, 망상형 구조의 발포폼을 사용함으로써 화장료 조성물의 흡수능, 담지능 및 배출능을 높일 수 있다. The cosmetic composition is impregnated into the pores of the carrier and discharged by external force. In this case, if the cell structure of the foamed foam is closed cell, impregnation and discharge of the cosmetic composition cannot be made. Therefore, the polyether-based polyurethane foam is excluded from the case of 100% closed cells, and preferably has an open cell, a semi-open cell, a network structure, and such a cell structure includes some closed cells according to the manufacture of a foam. It might be. Most preferably, the use of a foamed foam having a network structure can increase the absorption, loading and discharge capacity of the cosmetic composition.
상기 폴리에테르계 폴리우레탄 폼의 포어 사이즈는 200㎛ 이상, 250㎛ 이상, 300㎛ 이상, 310㎛ 이상, 320㎛ 이상, 330㎛ 이상, 340㎛ 이상, 350㎛ 이상, 360㎛ 이상, 370㎛ 이상, 380㎛ 이상, 390㎛ 이상, 400㎛ 이상, 410㎛ 이상, 420㎛ 이상, 430㎛ 이상, 440㎛ 이상, 또는 450㎛ 이상이고, 800㎛ 이하, 750㎛ 이하, 700㎛ 이하, 650㎛ 이하, 600㎛ 이하, 590㎛ 이하, 580㎛ 이하, 570㎛ 이하, 560㎛ 이하, 550㎛ 이하, 540㎛ 이하, 530㎛ 이하, 520㎛ 이하, 510㎛ 이하, 500㎛ 이하, 490㎛ 이하, 480㎛ 이하, 470㎛ 이하, 또는 460㎛ 이하일 수 있으며, 예를 들어 200 내지 800㎛, 또는 300 내지 600㎛일 수 있다. 포어 사이즈가 상기 범위 미만인 경우에는 담지력이 떨어지고, 상기 범위 초과인 경우에는 화장료 조성물을 오랫동안 안정적으로 담지하기 어렵다.The pore size of the polyether-based polyurethane foam is 200 µm or more, 250 µm or more, 300 µm or more, 310 µm or more, 320 µm or more, 330 µm or more, 340 µm or more, 350 µm or more, 360 µm or more, 370 µm or more , 380 µm or more, 390 µm or more, 400 µm or more, 410 µm or more, 420 µm or more, 430 µm or more, 440 µm or more, or 450 µm or more, 800 µm or less, 750 µm or less, 700 µm or less, 650 µm or less , 600 μm or less, 590 μm or less, 580 μm or less, 570 μm or less, 560 μm or less, 550 μm or less, 540 μm or less, 530 μm or less, 520 μm or less, 510 μm or less, 500 μm or less, 490 μm or less, 480 It may be µm or less, 470 µm or less, or 460 µm or less, for example, 200 to 800 µm, or 300 to 600 µm. If the pore size is less than the above range, the holding power is poor, and if it is more than the above range, it is difficult to stably support the cosmetic composition for a long time.
일 예에서, 상기 폴리에테르계 폴리우레탄 폼은 최상층에 비해 포어 사이즈가 클 수 있다. 이러한 포어 사이즈의 차별화를 통하여 하부층에서 화장료 조성물을 충분한 양으로 안정적으로 담지하면서, 최상층에서는 화장료 조성물이 균일하고 적절한 양으로 배출할 수 있다.In one example, the polyether-based polyurethane foam may have a larger pore size than the top layer. Through the differentiation of the pore size, while the cosmetic composition is stably supported in a sufficient amount in the lower layer, the cosmetic composition in the uppermost layer can be discharged in a uniform and appropriate amount.
상기 폴리에테르계 폴리우레탄 폼의 밀도는 0.015 g/㎤ 이상, 0.020 g/㎤ 이상, 또는 0.025 g/㎤ 이상이고, 0.05 g/㎤ 이하, 0.045 g/㎤ 이하, 0.040 g/㎤ 이하, 또는 0.035 g/㎤ 이하일 수 있으며, 예를 들어 0.01 내지 0.05 g/㎤, 또는 0.02 내지 0.04 g/㎤ 일 수 있다. 밀도가 상기 범위 미만일 경우 화장료 조성물을 안정하게 담지하기 어려우며, 밀도가 상기 범위 초과일 경우에는 화장료 조성물의 충진이 용이하게 이루어지지 않을 수 있다.The density of the polyether-based polyurethane foam is 0.015 g/cm 3 or more, 0.020 g/cm 3 or more, or 0.025 g/cm 3 or more, 0.05 g/cm 3 or less, 0.045 g/cm 3 or less, 0.040 g/cm 3 or less, or 0.035 g/cm 3 or less, for example, 0.01 to 0.05 g/cm 3, or 0.02 to 0.04 g/cm 3. When the density is less than the above range, it is difficult to stably support the cosmetic composition, and when the density is above the above range, filling of the cosmetic composition may not be easily achieved.
일 예에서, 상기 폴리에테르계 폴레우레탄 폼은 최상층에 비해 밀도가 낮을 수 있다. 이와 같은 밀도 차이에 의하여 하부층에서는 화장료 조성물의 충진이 용이하게 이루어지고, 화장료 조성물을 충분한 양으로 안정적으로 담지하면서, 최상층에서는 화장료 조성물의 배출양 조절이 적절하게 이루어질 수 있다.In one example, the polyether-based polyurethane foam may have a lower density than the top layer. Due to the difference in density, filling of the cosmetic composition is easily performed in the lower layer, and the cosmetic composition is stably supported in a sufficient amount, and the discharge amount of the cosmetic composition can be appropriately adjusted in the uppermost layer.
상기 폴리에테르계 폴리우레탄 폼의 포어 수는 40 ppi 이상, 45 ppi 이상, 50 ppi 이상, 55 ppi 이상, 60 ppi 이상, 65 ppi 이상, 70 ppi 이상 또는 75 ppi 이상이고, 120 ppi 이하, 115 ppi 이하, 110 ppi 이하, 105 ppi 이하, 100 ppi 이하, 95 ppi 이하, 90 ppi 이하, 85 ppi 이하, 또는 80 ppi 이하일 수 있으며, 예를 들어 40 내지 120 ppi또는 60 내지 100 ppi일 수 있다. 상기 발포폼의 포어 수가 상기 미만이면 폼의 탄성이 떨어지며 화장료 조성물의 유동성을 제어하기가 어렵고, 포어 수가 상기 범위를 초과할 경우에는 사용 시 내구성이 떨어질 수 있다.The number of pores of the polyether-based polyurethane foam is 40 ppi or more, 45 ppi or more, 50 ppi or more, 55 ppi or more, 60 ppi or more, 65 ppi or more, 70 ppi or more, or 75 ppi or more, 120 ppi or less, 115 ppi Or less, 110 ppi or less, 105 ppi or less, 100 ppi or less, 95 ppi or less, 90 ppi or less, 85 ppi or less, or 80 ppi or less, for example, 40 to 120 ppi or 60 to 100 ppi. If the number of pores of the foam is less than the above, the elasticity of the foam is poor and it is difficult to control the fluidity of the cosmetic composition, and when the number of pores exceeds the above range, durability may be deteriorated when used.
일예에서, 상기 폴리에테르계 폴레우레탄 폼은 최상층에 비해 포어 수가 작을 수 있다. 이와 같은 포어 수 차이를 갖는 다층구조에 의하여 하부층에서는 화장료 조성물을 충분한 양으로 안정적으로 담지하면서, 담체에 적절한 탄성을 부여하고, 최상층에서는 화장료 조성물의 배출양 조절이 적절하게 이루어질 수 있다.In one example, the polyether-based polyurethane foam may have a smaller number of pores than the top layer. Due to the multi-layered structure having the difference in the number of pores, the lower layer stably supports the cosmetic composition in a sufficient amount, imparting appropriate elasticity to the carrier, and controlling the discharge amount of the cosmetic composition in the uppermost layer is appropriate.
상기 폴리에테르계 폴리우레탄 폼의 경도는 애스커(ASKER) 경도기 F 형(Type F) 기준으로 50 이상, 55 이상, 60 이상, 61 이상, 62 이상, 63 이상, 64 이상, 65 이상, 66 이상, 67 이상, 68 이상, 69 이상, 70 이상, 71 이상, 72 이상 또는 73 이상이고, 90 이하, 89 이하, 88 이하, 87 이하, 86 이하, 85 이하, 84 이하, 83 이하, 82 이하, 81 이하, 80 이하, 79 이하, 78 이하, 또는 77 이하일 수 있으며, 예를 들어 50 내지 90의 경도를 가질 수 있다. 만일, 경도가 상기 범위 미만인 경우 화장료 조성물을 취출할 때에 폴리우레탄 폼에 함침시킨 화장료 조성물이 과도하게 배출될 수 있으며, 경도가 상기 범위 초과로 너무 딱딱하면 화장료 조성물이 쉽게 배출되지 않을 수 있다.The hardness of the polyether-based polyurethane foam is 50 or more, 55 or more, 60 or more, 61 or more, 62 or more, 63 or more, 64 or more, 65 or more, 66 on the basis of the Type F of the ASKER hardness tester. Above, 67 above, 68 above, 69 above, 70 above, 71 above, 72 above or 73 above, 90 below, 89 below, 88 below, 87 below, 86 below, 85 below, 84 below, 83 below, 82 below , 81 or less, 80 or less, 79 or less, 78 or less, or 77 or less, and for example, may have a hardness of 50 to 90. If the hardness is less than the above range, the cosmetic composition impregnated in the polyurethane foam may be excessively discharged when the cosmetic composition is taken out. If the hardness is too hard beyond the above range, the cosmetic composition may not be easily discharged.
상기 폴리에테르계 폴리우레탄 폼은 건식으로 발포하여 제조된 건식 폴리에테르계 폴리우레탄 폼일 수 있다.The polyether-based polyurethane foam may be a dry polyether-based polyurethane foam produced by dry foaming.
일예에서, 상기 건식으로 발포하여 폴리우레탄 폼을 제조하는 건식 공법은 폴리우레탄 폼의 재료가 되는 원료를 배합하여 혼합하고, 상기 혼합물을 발포(foaming)하여 폼 블럭을 형성하고, 상기 폼블럭을 가스챔버(gas chamber) 내에서 가스를 주입하여 망상화하는 것을 포함할 수 있다.In one example, the dry method of manufacturing a polyurethane foam by foaming with the dry blends and mixes the raw materials that are the material of the polyurethane foam, foams the mixture to form a foam block, and gases the foam block It may include reticular injection by injecting gas in a gas chamber.
건식 공정에 의하여 망상화된 폴리에테르계 폴리우레탄 폼은 습식 망상화된 것에 비하여 포어 사이즈가 크다. 또한 건식 폴리에테르계 폴리우레탄 폼의 표면 물성은 친유성을 나타낸다. Polyether-based polyurethane foams meshed by a dry process have a larger pore size than wet meshes. In addition, the surface properties of the dry polyether-based polyurethane foam exhibit lipophilic properties.
일 구체예에서, 상기 건식 공법 및 습식 공법은 아래의 공정을 포함할 수 있다.In one embodiment, the dry method and the wet method may include the following process.
1. 원료 작성 및 원료를 설정1. Preparation of raw materials and setting of raw materials
생산하려는 제품의 특성에 맞는 원료, 배합성분(formulation)을 설정한 후 필요한 원료들을 준비하는 과정으로, 일반적으로는 제품의 특성에 따라 10~40가지의 원료들이 첨가되는 것으로, 각 원료들의 극세한 투입량 차이로 제품의 성질이 다양화 되기 때문에 정밀함이 요구되는 과정이다.This is a process of preparing the necessary raw materials after setting the raw materials and formulations suitable for the characteristics of the product to be produced. In general, 10 to 40 kinds of raw materials are added depending on the characteristics of the product. This is a process that requires precision because the properties of the product are diversified due to the difference in input.
2. 설정된 원료들의 혼합 및 배출2. Mixing and discharge of set raw materials
설정된 원료들이 각자의 탱크에서 계산된 수량만큼 믹서기(Mixing Head)에서 혼합된 후 배출되는 과정이며, 위에서 상기된 원료들의 정밀한 투입량과 혼합과정(시간)을 요구한다.It is a process in which the set raw materials are mixed and discharged from the mixing head as much as the amount calculated in each tank, and the precise input amount and mixing process (time) of the above-mentioned raw materials are required.
3. 배출된 혼합물의 발포 및 숙성3. Foaming and aging of the discharged mixture
믹서기(Mixing head)에서 트레이(발포선반)에 배출된 혼합물이 발포되고 숙성되는 과정으로, 배출된 혼합물은 약 2~3분의 시간을 통해 계획한 사이즈의 블록형태로 발포(Foaming)되며, 숙성과정을 위해 형성된 블록의 겉표면을(3면이상) 슬라이스(굳어진 겉면을 벗겨내는 작업) 한다. 이는 발포과정에서 화학작용으로 생긴 내부의 열기와 가스를 배출시키기 위한 과정으로 약 18시간정도 소요되며, 완전한 숙성과정을 거치지 않으면 내부 셀구조(Cell structure)및 사이즈(Cell-size)가 변형될 수 있기 때문이다.This is the process in which the mixture discharged from the mixing head to the tray (foaming shelf) is foamed and aged, and the discharged mixture is foamed in a block shape of the planned size through a time of about 2-3 minutes, and aged The surface of the block formed for the process (more than 3 sides) is sliced (work to peel off the hardened surface). This is a process for discharging the internal heat and gas generated by the chemical reaction in the foaming process, which takes about 18 hours, and the internal cell structure and cell-size may be deformed without a complete aging process. Because there is.
4. 완성된 발포체(Foam block)의 망상화(Reticulation)작업4. Reticulation of the completed foam block
숙성과정을 거쳐 완성된 폼은 클로즈드 셀(Closed-cell)/세미오픈 셀(Semi-open cell) 형태로서 완제품으로 판매될 수 있으며, 용도에 따라 망상화(Reticulation)과정을 통해 오픈셀(Open-cell) 제품으로 성형한다. 이는 폼의 셀표면을 터트려 프레임(Frame)만 남게 만드는 과정으로 쉽게 "망상화"시키는 과정으로, 일반적으로 망상화(Reticulation)방식은 가스폭파(Zapping)방식과 함침망상화(Quenching)방식 둘로 나뉘어지며 이를 통상적으로 "건식-스폰지"와 "습식-스폰지"라는 표명으로 분류한다.The completed form through the aging process can be sold as a finished product in the form of a closed-cell/semi-open cell. Depending on the application, the open-cell can be opened through a reticulation process. cell) Products. This is the process of popping the cell surface of the foam to make only a frame and easily "delusion". In general, the reticulation method is divided into a gas blasting method and an impregnating quenching method. It is generally classified as "dry-sponge" and "wet-sponge".
4-1. 가스폭파(Zapping)방식은 폼블럭을 가마(Gas Chamber)에 넣고 가스를 주입후 폭파하여 망상화하는 방식으로 건식 폴리우레탄 폼의 제조에 사용될 수 있다.4-1. The gas blasting (Zapping) method can be used in the production of dry polyurethane foams by placing the foam block in a gas chamber and injecting the gas to detonate it.
4-2. 함침망상화(Quenching)방식은 폼블럭을 액상(화학물)이 채워진 컨테이너 안으로 함침후, 화학적 작용으로 망상화하는 방식으로 주로 부드러운 폼제품의 생산시에 사용되는 과정이다.4-2. The impregnation quenching method is a process that is mainly used in the production of soft foam products by impregnating the foam block into a container filled with a liquid (chemical) and then phantomizing with a chemical action.
즉, 상기 함침망상화방식은 수응고성 폴리우레탄, 용제, 수용성 무기염의 분립체, 및 계면활성제를 주성분으로 하는 배합물을 혼련하여 혼련물을 얻는 공정, 상기 혼련물을 탈포하여 탈포 혼련물을 얻는 공정, 상기 탈포혼련물을 성형하여 성형물을 얻는 공정, 상기 성형물을 수중 또는 수용액 중에 투입한 후 응고하여 응고물을 형성하는 공정, 상기 응고물로부터 상기 무기염을 물에 용출시켜 응고물을 형성하는 공정, 상기 응고물로부터 상기 무기염을 용출시켜 제거하는 공정 및 상기 용출 제거 후 건조시키는 공정에서 막구조를 가지는 폴리우레탄 폼이 얻어지며 또한, 계면활성제의 사용여부에 따라 망상구조의 폴리우레탄 폼이 얻어진다.That is, the impregnation network method is a process of obtaining a kneaded product by kneading a mixture of a water-solidifying polyurethane, a solvent, a powder of a water-soluble inorganic salt, and a surfactant as a main component, and defoaming the kneaded product to obtain a defoamed kneaded product Process, forming a defoamed mixture to obtain a molded product, putting the molded product in water or in an aqueous solution, and then solidifying to form a coagulated product, eluting the inorganic salt from water from the coagulated product to form a coagulated product Polyurethane foam having a membrane structure is obtained in the process of elution and removal of the inorganic salt from the coagulation product and drying after removal of the elution, and the polyurethane foam having a network structure is used depending on the use of surfactant. Is obtained.
폼자재의 특성별(폴리카보네이트계, formulation 등) 사용되는 액상이 다양하기 때문에 매우 비용적으로 고가의 과정이라고 볼 수 있으며, 일부 극소수의 소프트한 제품들에 한해서만 생산될 수 있다.It can be regarded as a very expensive process due to the variety of liquids used by the characteristics of the foam material (polycarbonate type, formulation, etc.), and can be produced only for some very soft products.
일 실시예에서, 상기 담체는 상기 적층부의 하부, 즉 화장료 조성물이 배출되는 표면측의 반대 방향인 이면측에 메쉬구조 섬유층을 더 포함할 수 있다. 도 2에 본 실시예에 따른 담체의 단면 모식도를 나타낸다. 본 실시예에 따른 화장료 조성물 담체(200)는 복수의 폴리우레탄 폼(210, 220)을 포함하는 적층부 및 메쉬구조 섬유층(230)을 포함하고, 폼의 가장자리에 빗금으로 표시한 접합부(240)가 형성되어 적층부 및 메쉬구조 섬유층을 일체로 접합할 수 있다.In one embodiment, the carrier may further include a mesh structured fiber layer on the lower side of the layered portion, that is, on the back side opposite to the surface side from which the cosmetic composition is discharged. 2 is a schematic cross-sectional view of a carrier according to the present embodiment. The cosmetic composition carrier 200 according to the present embodiment includes a lamination portion including a plurality of polyurethane foams 210 and 220 and a mesh structure fiber layer 230, and a junction portion 240 indicated by hatching on the edge of the foam. Is formed can be integrally bonded to the laminated portion and the mesh structure fiber layer.
상기 메쉬구조 섬유층은 상기 적층부와 함께 접합될 때 우수한 접합강도를 제공하여 경시적으로, 물리적 접촉이나 반복 사용에 대한 내구성과 화학적 내구성이 우수한 담체를 제공할 수 있다. The mesh-structured fiber layer provides excellent bonding strength when bonded together with the laminated portion, thereby providing a carrier having excellent durability and chemical durability against physical contact or repeated use over time.
일 예에서, 상기 메쉬구조 섬유층은 최하부에 배치되는 경우 접합강도를 증진시키면서도, 하부로부터 화장료 조성물이 충진되는 경우 다공성 폼과 달리 화장료 조성물의 흡수를 방해하지 않는 성근 메쉬구조를 가지므로 하부층의 화장료 조성물 충진을 용이하게 할 수 있다.In one example, the mesh structured fiber layer has a sex root mesh structure that does not interfere with absorption of the cosmetic composition unlike the porous foam when the cosmetic composition is filled from the bottom while increasing the bonding strength when disposed at the bottom, the cosmetic composition of the lower layer Filling can be facilitated.
상기 메쉬구조 섬유층은 섬유로 홀(hole)을 형성하는 메쉬구조의 섬유 원단을 포함할 수 있다. 예를 들어 상기 섬유는 천연 섬유 또는 합성 섬유 중 하나 이상을 포함할 수 있다. 상기 섬유는 천연 섬유로는, 이에 한정되지 않으나, 항균 셀룰로오스, 천연펄프, 수세미(loofah), 모시, 라미(식물), 아야테(ayate, 용설란 또는 야자나무의 거친 피륙), 조류(algae), 대나무(Bamboo), 사이잘(sisal), 사이잘 테리(sisal terry, 사이잘로 타월처럼 수분 흡수가 잘 되도록 짠 천), 곤약, 텐셀(TM) 파이버 원단(유칼립투스 나무로 만든 천연 항균 기능의 텐셀 섬유), 코튼, 및 마닐라 삼(abaca fiber) 중 적어도 어느 하나로 마련되거나, 적어도 어느 하나를 포함되어 이루어질 수 있다.The mesh structure fiber layer may include a fiber fabric having a mesh structure that forms a hole with fibers. For example, the fibers may include one or more of natural fibers or synthetic fibers. The fiber is a natural fiber, but is not limited thereto, antibacterial cellulose, natural pulp, loofah, ramie, ramie (plant), ayate (rough agave of agave or palm trees), algae, Bamboo, sisal, sisal terry, a cloth woven to absorb moisture like a towel with sisal, konjac, tencel(TM) fiber fabric (tencel with natural antibacterial function made from eucalyptus wood) Fiber), cotton, and manila hemp (abaca fiber).
합성 섬유로는, 이에 한정되지는 않으나, 나일론, 스판덱스, 폴리에스터, 폴리아세테이트, 카시미론 파이버(아크릴로니트릴CH2=CH-CN 섬유를 주요구성 성분으로 하는 합성섬유 즉 아크릴 섬유), 컴포트 파이버, 폴리트리메틸렌테레프탈레이트 섬유, 폴리에틸렌, 폴리프로필렌, 폴리아크릴레이트, PLA(polylactic acid), 및 폴리유산계 복합 섬유(친환경 생분해성) 중 적어도 어느 하나로 이루어질 수 있다.Synthetic fibers include, but are not limited to, nylon, spandex, polyester, polyacetate, casimiron fibers (acrylonitrile CH2=synthetic fibers comprising CH-CN fibers as a major component, namely acrylic fibers), comfort fibers, Polytrimethylene terephthalate fiber, polyethylene, polypropylene, polyacrylate, polylactic acid (PLA), and polylactic acid-based composite fiber (eco-friendly biodegradable) may be made of at least any one.
상기 메쉬구조 섬유층의 홀(hole) 모양은 원형, 삼각형, 사각형, 오각형, 육각형(hexagonal) 등일 수 있으나, 제한되지 않는다.The hole shape of the mesh structure fiber layer may be circular, triangular, square, pentagonal, hexagonal, and the like, but is not limited.
상기 메쉬구조 섬유층의 홀 사이즈는 0.3 mm 이상, 0.4 mm 이상, 0.5 mm 이상, 0.6 mm 이상, 0.7 mm 이상, 0.8 mm 이상, 0.9 mm 이상, 또는 1.0 mm 이상이고, 1.8 mm 이하, 1.7 mm 이하, 1.6 mm 이하, 1.5 mm 이하, 1.4 mm 이하, 또는 1.3 mm 이하일 수 있으며, 예를 들어, 0.3 내지 1.8mm 또는 0.5 내지 1.5mm일 수 있다. 상기 홀 사이즈는 단일 홀의 최장 직경을 측정한 것의 평균 값일 수 있다. 상기 홀 사이즈가 상기 범위 미만인 경우 하부로부터의 화장료의 충진이 용이하지 않으며, 상기 범위 초과일 경우 가장자리 접합부의 접합이 안되거나 접합강도가 약해질 수 있다.The hole size of the mesh structure fiber layer is 0.3 mm or more, 0.4 mm or more, 0.5 mm or more, 0.6 mm or more, 0.7 mm or more, 0.8 mm or more, 0.9 mm or more, or 1.0 mm or more, 1.8 mm or less, 1.7 mm or less, It may be 1.6 mm or less, 1.5 mm or less, 1.4 mm or less, or 1.3 mm or less, for example, 0.3 to 1.8 mm or 0.5 to 1.5 mm. The hole size may be an average value of the longest diameter of a single hole. When the hole size is less than the above range, filling of the cosmetic material from the lower part is not easy, and when it exceeds the above range, bonding of the edge joint may not be performed or the bonding strength may be weakened.
상기 메쉬구조의 섬유층의 섬유 굵기는 10 데니어 이상, 15 데니어 이상, 20 데니어 이상, 25 데니어 이상, 30 데니어 이상, 35 데니어 이상, 40 데니어 이상, 45 데니어 이상, 50 데니어 이상, 55 데니어 이상, 60 데니어 이상, 65 데니어 이상, 또는 70 데니어 이상이고, 200 데니어 이하, 190 데니어 이하, 180 데니어 이하, 170 데니어 이하, 160 데니어 이하, 150 데니어 이하, 140 데니어 이하, 130 데니어 이하, 120 데니어 이하, 110 데니어 이하, 100 데니어 이하, 95 데니어 이하, 90 데니어 이하, 85 데니어 이하, 80 데니어 이하, 또는 75 데니어 이하, 예를 들어 10 내지 200 데니어(denier), 예를 들어 20 내지 100 데니어 일 수 있다. The fiber thickness of the fiber layer of the mesh structure is at least 10 denier, at least 15 denier, at least 20 denier, at least 25 denier, at least 30 denier, at least 35 denier, at least 40 denier, at least 45 denier, at least 50 denier, at least 55 denier, in 60 Denier or more, 65 denier or more, or 70 denier or more, 200 denier or less, 190 denier or less, 180 denier or less, 170 denier or less, 160 denier or less, 150 denier or less, 140 denier or less, 130 denier or less, 120 denier or less, 110 Denier or less, 100 denier or less, 95 denier or less, 90 denier or less, 85 denier or less, 80 denier or less, or 75 denier or less, for example 10 to 200 denier, for example 20 to 100 denier.
상기 메쉬구조 섬유층의 두께(t3)는 0.1 mm 이상, 0.15 mm 이상, 0.2 mm 이상, 0.25 mm 이상, 또는 0.3 mm 이상이고, 0.5 mm 이하, 0.45 mm 이하, 0.4 mm 이하, 또는 0.35 mm 이하일 수 있으며, 예를 들어 0.1 내지 0.5 mm, 구체적으로 0.2 내지 0.4 mm 일 수 있다. 상기 범위 내에서 접합부의 접합강도를 달성하면서 화장료 조성물의 충진이 용이할 수 있다. 도 4는 메쉬구조 섬유층의 두께(t3)을 도시한다.The thickness t3 of the mesh structure fiber layer may be 0.1 mm or more, 0.15 mm or more, 0.2 mm or more, 0.25 mm or more, or 0.3 mm or more, 0.5 mm or less, 0.45 mm or less, 0.4 mm or less, or 0.35 mm or less, , For example 0.1 to 0.5 mm, specifically 0.2 to 0.4 mm. Filling the cosmetic composition may be easy while achieving the bonding strength of the bonding portion within the above range. 4 shows the thickness t3 of the mesh structure fiber layer.
상기 담체는 가장자리에 담체에 포함되는 층을 접합하는 접합부(140, 240, 340)를 포함할 수 있다. The carrier may include junctions 140, 240, and 340 that bond layers included in the carrier to the edges.
도 3은 본 발명 일 실시예에 따른 화장료 조성물 담체의 또 다른 단면 모식도이다. 예시로 메쉬구조 섬유층(230)이 포함되는 구조로 기재하였으나, 이에 제한되는 것은 아니다. 본 실시예에 따른 화장료 조성물 담체(200)는 폼의 가장자리에 형성되는 빗금으로 표시한 접합부(240)가 접합에 의하여 중앙부에 비하여 압축된 형태일 수 있다.3 is another schematic cross-sectional view of a cosmetic composition carrier according to an embodiment of the present invention. For example, the mesh structure is described as a structure including the fiber layer 230, but is not limited thereto. The cosmetic composition carrier 200 according to the present embodiment may be in a form in which the bonding portion 240 indicated by hatching formed on the edge of the foam is compressed compared to the central portion by bonding.
도 5는 본 발명 일 실시예에 따른 화장료 조성물 담체(300)의 평면 모식도이며, 빗금으로 표시한 가장자리의 접합부(340)를 나타낸다.5 is a schematic plan view of a cosmetic composition carrier 300 according to an embodiment of the present invention, and shows a junction 340 at an edge indicated by hatching.
일 구체예에서, 상기 접합은 초음파 접합에 의하여 수행 할 수 있다. 상기 초음파 접합에 의하여 접착제 사용에 따른 단점을 배제할 수 있으며, 다층구조의 안정적인 접합으로 우수한 내구성을 나타낼 수 있다. In one embodiment, the bonding may be performed by ultrasonic bonding. By using the ultrasonic bonding, disadvantages associated with the use of the adhesive can be excluded, and excellent durability can be exhibited by stable bonding of the multilayer structure.
일 구체예에서, 상기 초음파 접합은 상술한 메쉬구조 섬유층을 포함하여 접합강도가 현저하게 우수할 수 있다.In one embodiment, the ultrasonic bonding may include remarkably excellent bonding strength, including the above-described mesh structure fiber layer.
일 구체예에서, 상기 접합은 열접합에 의하여 수행 할 수 있다. 상기 열접합에 의하여 접착제 사용에 따른 단점을 배제할 수 있으며, 다층구조의 안정적인 접합으로 우수한 내구성을 나타낼 수 있다. In one embodiment, the bonding can be performed by thermal bonding. By the thermal bonding, disadvantages associated with the use of the adhesive can be excluded, and excellent durability can be exhibited by stable bonding of the multilayer structure.
일 구체예에서, 상기 열접합은 상술한 메쉬구조 섬유층을 포함하여 접합강도가 현저하게 우수할 수 있다.In one embodiment, the thermal bonding may include the above-described mesh structure fiber layer, the bonding strength may be remarkably excellent.
상기 접합부는 담체의 가장자리에 형성될 수 있으며, 접합부의 폭(Wd)은 0.05 mm 이상, 0.10 mm 이상, 0.15 mm 이상, 0.20 mm 이상, 0.25 mm 이상, 0.30 mm 이상, 0.35 mm 이상, 0.40 mm 이상, 0.45 mm 이상, 0.50 mm 이상, 0.55 mm 이상, 0.60 mm 이상, 0.65 mm 이상, 0.70 mm 이상, 0.75 mm 이상, 0.80 mm 이상, 0.85 mm 이상, 0.90 mm 이상, 0.95 mm 이상, 또는 1.00 이상이고, 5.0 mm 이하, 4.5 mm 이하, 4.0 mm 이하, 3.5 mm 이하, 3.0 mm 이하, 2.5 mm 이하, 2.0 mm 이하, 또는 1.5 mm 이하일 수 있으며, 예를 들어 0.05 내지 5 mm, 또는 0.1 내지 3 mm 일 수 있다. 접합부의 폭이 상기 범위 미만일 경우에는 접합강도가 약할 수 있고, 접합부의 폭이 상기 범위 초과일 경우에는 화장료 조성물을 담지할 수 있는 용량이 적어 제품으로서의 가치가 없다. The joint may be formed on the edge of the carrier, the width (Wd) of the joint is 0.05 mm or more, 0.10 mm or more, 0.15 mm or more, 0.20 mm or more, 0.25 mm or more, 0.30 mm or more, 0.35 mm or more, 0.40 mm or more , 0.45 mm or more, 0.50 mm or more, 0.55 mm or more, 0.60 mm or more, 0.65 mm or more, 0.70 mm or more, 0.75 mm or more, 0.80 mm or more, 0.85 mm or more, 0.90 mm or more, 0.95 mm or more, or 1.00 or more, 5.0 mm or less, 4.5 mm or less, 4.0 mm or less, 3.5 mm or less, 3.0 mm or less, 2.5 mm or less, 2.0 mm or less, or 1.5 mm or less, for example, 0.05 to 5 mm, or 0.1 to 3 mm have. When the width of the bonding portion is less than the above range, the bonding strength may be weak, and when the width of the bonding portion exceeds the above range, the capacity to support the cosmetic composition is small, and thus has no value as a product.
상기 접합부는 접합에 의해 가장자리에 도 6 및 도 12 등에 예시적으로 도시되는 바와 같이 날개와 같은 구조를 형성할 수 있다. 용기에 화장료 조성물을 배치하고, 이후 담체를 용기에 넣어 담체 하부로부터 화장료 조성물을 흡수하여 충진하는 경우, 용기 벽면과 담체 사이의 공백을 접합부에 의해 밀착시켜 하부로부터 흡수되지 않은 화장료 조성물이 담체 상부로 흘러넘치는 오버플로우 현상을 방지 또는 개선할 수 있다.The joining portion may form a wing-like structure as exemplarily shown in FIGS. 6 and 12 on the edge by joining. When the cosmetic composition is placed in the container, and then the carrier is placed in the container to absorb and fill the cosmetic composition from the lower portion of the carrier, the gap between the container wall and the carrier is brought into close contact with the bonding portion so that the cosmetic composition that is not absorbed from the bottom is transferred to the upper portion of the carrier. It can prevent or improve overflow overflow.
도 4는 본 발명 일실시예에 따른 담체의 규격을 도시한다. 상기 폼의 두께는 접합부의 접합 전 기준으로 층 두께를 측정한 것일 수 있다. 도 4의 층 구조는 본 발명 실시예들의 담체에 관하여 포괄적으로 도시하기 위하여 메쉬 구조 섬유층(230)을 포함하는 구조로 도시되나, 이에 제한되는 것은 아니다.Figure 4 shows the specifications of the carrier according to an embodiment of the present invention. The thickness of the foam may be a measure of the layer thickness on the basis of bonding prior to bonding. The layer structure of FIG. 4 is shown as a structure including the mesh structure fiber layer 230 to comprehensively illustrate the carrier of the embodiments of the present invention, but is not limited thereto.
일 예에서, 상기 최상층에 사용되는 폴리카보네이트계 폴리우레탄 폼의 두께가 너무 두꺼우면 하부층 존재에 의한 영향이 감소하여 적층부의 다층 구조에 따른 본원 발명의 효과가 낮아질 수 있고, 최상층이 담체의 배출능에 보다 영향이 클 것이므로, 상층의 두께를 조절하는 것이 중요할 수 있다.In one example, if the thickness of the polycarbonate-based polyurethane foam used in the top layer is too thick, the effect of the present invention according to the multi-layer structure of the lamination part may be reduced by reducing the influence of the presence of the lower layer, and the top layer may be used for the discharge capacity of the carrier. Since the effect will be greater, it may be important to control the thickness of the top layer.
상기 폴리카보네이트계 폴리우레탄 폼의 두께(t1)는 0.1 mm 이상, 0.2 mm 이상, 0.3 mm 이상, 0.4 mm 이상, 0.5 mm 이상, 0.6 mm 이상, 0.7 mm 이상, 0.8 mm 이상, 또는 0.9 mm 이상, 또는 1.0 mm 이상이고, 5.0 mm 이하, 4.5 mm 이하, 4.0 mm 이하, 3.5 mm 이하, 3.0 mm 이하, 2.5 mm 이하, 2.0 mm 이하, 또는 1.5 mm 이하일 수 있으며, 예를 들어 0.1 내지 5mm, 또는 0.5 내지 2mm일 수 있다. 상기 두께가 0.1mm 미만인 경우에는 목적하는 균일한 배출력을 기대하기 어렵고, 내구성에 문제가 있을 수 있으며, 5mm 초과인 경우에는 화장료 배출이 어려울 수 있으며, 하부층에서의 안정적 담지 및 탄성과 푹신한 사용감 부여 효과를 반감시킬 수 있다.The thickness (t1) of the polycarbonate-based polyurethane foam is 0.1 mm or more, 0.2 mm or more, 0.3 mm or more, 0.4 mm or more, 0.5 mm or more, 0.6 mm or more, 0.7 mm or more, 0.8 mm or more, or 0.9 mm or more, Or 1.0 mm or more, 5.0 mm or less, 4.5 mm or less, 4.0 mm or less, 3.5 mm or less, 3.0 mm or less, 2.5 mm or less, 2.0 mm or less, or 1.5 mm or less, for example, 0.1 to 5 mm, or 0.5 To 2 mm. If the thickness is less than 0.1mm, it is difficult to expect the desired uniform discharge power, there may be a problem in durability, and if it is more than 5mm, cosmetic discharge may be difficult, and stable support and elasticity and soft feeling in the lower layer are given. The effect can be halved.
일 예에서, 상기 폴리카보네이트계 폴리우레탄 폼의 두께(t1)은 하부 층의 폴리 우레탄 폼의 두께(t2)에 비하여 얇을 수 있다.In one example, the thickness (t1) of the polycarbonate-based polyurethane foam may be thin compared to the thickness (t2) of the polyurethane foam of the lower layer.
상기 폴리에테르계 폴리우레탄 폼의 두께(t2)는 3 mm 이상, 4 mm 이상, 5 mm 이상, 6 mm 이상, 또는 7 mm 이상이고, 15 mm 이하, 14 mm 이하, 13 mm 이하, 12 mm 이하, 11 mm 이하, 10 mm 이하, 또는 9 mm 이하일 수 있으며, 예를 들어 3 내지 15mm, 또는 5 내지 10mm일 수 있다. 두께가 상기 범위 미만인 경우에는 화장료 조성물을 담지할 수 있는 용량이 적어 제품으로서의 가치가 없고, 상기 범위 초과인 경우 용기가 두꺼워져 휴대편의성이 안 좋아지고, 마지막까지 화장료 조성물의 사용이 어려워 화장료 조성물의 잔량이 많이 남을 수 있다. The thickness (t2) of the polyether-based polyurethane foam is 3 mm or more, 4 mm or more, 5 mm or more, 6 mm or more, or 7 mm or more, 15 mm or less, 14 mm or less, 13 mm or less, 12 mm or less , 11 mm or less, 10 mm or less, or 9 mm or less, for example, 3 to 15 mm, or 5 to 10 mm. If the thickness is less than the above range, there is little value as a product because the capacity to carry the cosmetic composition is small, and if the thickness exceeds the above range, the container becomes thick and the portability becomes poor, and until the end, the use of the cosmetic composition is difficult. The remaining amount can remain.
일 예에서, 상기 하부층의 폴리 우레탄 폼의 두께(t2)는 최상층 두께(t1)에 비하여 두꺼울 수 있다. 상기 두께 차이에 의하여 하부층에서 충분한 양의 화장료 조성물을 안정적으로 담지하며, 담체 전체에 적절한 탄성력과 푹신한 사용감을 부여하는 동시에, 최상층의 적절한 배출 조절을 구현하여 다층 구조로서의 효과를 극대화할 수 있다.In one example, the thickness (t2) of the polyurethane foam of the lower layer may be thick compared to the thickness (t1) of the top layer. Due to the thickness difference, a sufficient amount of the cosmetic composition is stably supported in the lower layer, and an appropriate elasticity and soft feeling are given to the entire carrier, and at the same time, proper discharge control of the uppermost layer is implemented to maximize the effect as a multi-layer structure.
일 예에서, 상기 담체는 적층부의 층간 및 상기 적층부와 메쉬구조 섬유층 사이 중 하나 이상에 배치되는 프라이머층을 더 포함할 수 있다.In one example, the carrier may further include a primer layer disposed between at least one of the layers of the laminated portion and between the laminated portion and the mesh structure fiber layer.
상기 프라이머층은 핫멜트 부직포 웹, 핫멜트 메쉬, 스프레이 접착 층, 유성 접착제 층 및 수성 접착제 층 중 하나 이상을 포함할 수 있다. 핫멜트 필름이 사용될 경우 담체의 포어를 막아 화장료 조성물의 흡수나 배출을 저해할 수 있으므로 부직포 형태의 핫멜트 웹이 적합하다. 상기 핫멜트 웹의 재질로는 폴리에스터, 폴리에틸렌, 폴리우레탄 중 하나 이상일 수 있으며, 멜팅되는 온도는 80℃내지 120℃일 수 있다. 상기 범위 미만에서 멜팅이 될 경우 추후 제품의 고온 안정성에 영향을 미칠 수 있으며, 상기 범위 초과인 경우 핫멜트 공정을 거치면서 담체의 적층부 및 메쉬구조 섬유층이 열 스트레스를 받아 물리화학적인 변형이 일어날 수 있다. 일예에서 유성 접착제는 우레탄계 접착제와 용제인 아세트산의 혼합물일 수 있으며, 수성 접착제는 우레탄 계일 수 있으나 이에 제한되지 않는다.The primer layer may include one or more of a hot melt nonwoven web, a hot melt mesh, a spray adhesive layer, an oily adhesive layer, and an aqueous adhesive layer. When a hot melt film is used, it is possible to prevent the absorption or discharge of the cosmetic composition by blocking the pores of the carrier, so a non-woven hot melt web is suitable. The material of the hot melt web may be at least one of polyester, polyethylene, and polyurethane, and the temperature to be melted may be 80°C to 120°C. If it is melted below the above range, it may affect the high temperature stability of the product in the future, and if it is above the above range, a physicochemical deformation may occur due to heat stress of the lamination part and the mesh structure fiber layer of the carrier during the hot-melting process. have. In one example, the oily adhesive may be a mixture of a urethane-based adhesive and a solvent acetic acid, and the aqueous adhesive may be a urethane-based but is not limited thereto.
상기 프라이머층의 두께는 0.01 내지 1.0mm일 수 있다. 상기 범위 내에서 화장료 조성물의 흡수 및 배출을 저해하지 않으면서, 층간 접합 강도를 향상시킬 수 있다.The thickness of the primer layer may be 0.01 to 1.0mm. Within the above range, the interlayer bonding strength can be improved without inhibiting absorption and discharge of the cosmetic composition.
일 예에서, 상기 담체의 지름(Wt)과 총 두께(T)는 화장 용기에 따라 달라질 수 있다. 상기 담체의 지름(Wt)은 30mm 내지 70mm 또는 40mm 내지 60mm일 수 있으며, 상기 범위 내에서 함침된 화장료 조성물의 토출량이 적절할 수 있다. 상기 담체의 총 두께(T)는 1mm 내지 50mm, 예를 들어 5mm 내지 30mm, 6mm 내지 29 mm, 7mm 내지 28 mm, 8mm 내지 27 mm, 9mm 내지 26 mm 또는 10mm 내지 25 mm일 수 있다. 두께가 상기 범위 미만이면 화장료 조성물의 담지량이 적을 수 있으며, 상기 범위를 초과하면 사용시 내용물의 배출에 있어서 그 내용물의 잔량 없이는 배출이 어려울 수 있다.In one example, the diameter (Wt) and the total thickness (T) of the carrier may vary depending on the makeup container. The diameter (Wt) of the carrier may be 30 mm to 70 mm or 40 mm to 60 mm, and the discharge amount of the cosmetic composition impregnated within the above range may be appropriate. The total thickness (T) of the carrier may be 1 mm to 50 mm, for example, 5 mm to 30 mm, 6 mm to 29 mm, 7 mm to 28 mm, 8 mm to 27 mm, 9 mm to 26 mm, or 10 mm to 25 mm. If the thickness is less than the above range, the supported amount of the cosmetic composition may be small, and if it exceeds the above range, the discharge may be difficult without the remaining amount of the content when discharging the content during use.
일 예에서, 상기 담체는 내부에 절개부를 더 포함할 수 있다. 예를 들어, 상기 절개부는 담체의 층에 평행한 평면에 형성될 수 있다. 예를 들어, 상기 절개부는 담체의 두께 방향에 대하여 수직인 평면에 형성될 수 있다. 예를 들어 상기 절개부는 담체의 층에 대하여 평행하게 형성되어 내부 공동(void)이 형성된 형태일 수 있다. In one example, the carrier may further include an incision in the interior. For example, the incision may be formed in a plane parallel to the layer of the carrier. For example, the incision may be formed in a plane perpendicular to the thickness direction of the carrier. For example, the incision may be formed parallel to the layer of the carrier to form an internal void.
본 명세서에서 절개부는 담체의 일부를 절개하여 형성되거나, 접합되지 않은 적층된 층에 의해 형성될 수 있으며, 절개부라는 표현에 의하여 형성 방법이 절개로 한정되는 것은 아니다.In this specification, the incision may be formed by incising a part of the carrier, or may be formed by a laminated layer that is not joined, and the method of forming the incision is not limited to incision.
도 22는 본 실시예에 따른 담체의 일예의 사진이다. 구체적으로 도 22는 본 실시예에 따른 절개부를 포함하는 담체를 절단하여 종단면을 노출한 상태의 사진으로, 담체 내부에 공동이 형성된 것을 확인할 수 있다.22 is a photograph of an example of a carrier according to the present embodiment. Specifically, FIG. 22 is a photograph of a state in which a longitudinal section is exposed by cutting a carrier including an incision according to this embodiment, and it can be confirmed that a cavity was formed inside the carrier.
일 구체예에서, 상기 절개부는 상기 담체 중 복수의 폴리우레탄 폼을 포함하는 적층부에 형성될 수 있다. 예를 들어, 상기 절개부는 상기 최상층의 폼의 내부, 상기 하부층의 폼의 내부, 상기 최상층의 복수개의 폼 사이, 상기 하부층의 복수개의 폼 사이 또는 상기 최상층과 하부층 폼의 사이 중 하나 이상에 형성될 수 있다.In one embodiment, the incision may be formed in a laminate including a plurality of polyurethane foams in the carrier. For example, the incision may be formed on one or more of the inside of the foam of the top layer, the inside of the foam of the bottom layer, between the plurality of foams of the top layer, between the plurality of foams of the bottom layer, or between the top layer and the bottom layer foam. Can be.
일 구체예에서, 상기 절개부는 상기 담체의 단면을 기준으로 지름(Wt)에서 접합부(Wd)를 제외한 길이로 형성될 수 있다. 상기 길이는 도 3을 참조하여 단면을 기준으로 하여 절개부가 형성되어 있는 영역의 지름으로 나타낼 수 있다.In one embodiment, the incision may be formed to a length excluding the junction (Wd) from the diameter (Wt) based on the cross-section of the carrier. The length may be represented by the diameter of the region where the incision is formed based on the cross section with reference to FIG. 3.
일 구체예에서, 상기 절개부는 상기 담체가 담지하는 화장료 조성물을 보관 및/또는 저장하는 역할을 할 수 있다. 상기 절개부의 공동에 화장료 조성물을 다량으로 담지할 수 있다. 상기 절개부를 포함하여 화장료 조성물에 담체로부터 보다 안정적으로 토출될 수 있다. 상기 절개부를 포함하여 화장료 조성물의 담체 내의 화장료 조성물의 담지량 및/또는 토출량을 조절할 수 있다. 상기 절개부를 포함하여 원하는 범위 내에서 적절한 화장료 조성물 토출량을 갖도록 조절할 수 있다. 예를 들어 상기 절개부를 포함하여 화장료 조성물의 토출량을 절개부가 없는 경우 보다 다량이 되도록 할 수 있다. In one embodiment, the incision may serve to store and/or store the cosmetic composition carried by the carrier. A large amount of the cosmetic composition may be supported on the cavity of the incision. It can be more stably discharged from the carrier to the cosmetic composition including the incision. It is possible to adjust the loading amount and/or the discharge amount of the cosmetic composition in the carrier of the cosmetic composition including the incision. It may be adjusted to have a suitable cosmetic composition discharge amount within a desired range including the incision. For example, the discharge amount of the cosmetic composition including the incision may be made to be larger than in the case where there is no incision.
일 구체예에서, 상기 절개부는 공동에 의해 공기층을 포함할 수 있다. In one embodiment, the incision may include an air layer by a cavity.
일 구체예에서, 상기 담체는 절개부를 포함하여 담체에 압력을 가한 뒤 압력을 제거할 때에 압축된 담체가 보다 천천히 회복될 수 있다. 이와 같이 상기 절개부는 담체를 눌러 사용할 때 느껴지는 탄성에 영향을 주어 부드러운 쿠션감을 부여할 수 있다.In one embodiment, the carrier may recover more slowly when the pressure is removed after applying pressure to the carrier including the incision. In this way, the incision may affect the elasticity felt when the carrier is pressed to provide a soft cushion feeling.
상기 화장료 조성물 담체는 흐름성이 있는 화장료 조성물을 함침하여 담지하기 위한 것일 수 있다.The cosmetic composition carrier may be for impregnating and supporting a cosmetic composition having flowability.
일 구체예에서, 상기 화장료 조성물 담체는 점도가 5000cps 이상, 6000 cps 이상, 7000 cps 이상, 8000 cps 이상, 9000 cps 이상, 10000cps 이상, 11000cps 이상, 12000cps 이상, 13000cps 이상, 14000cps 이상, 15000cps 이상, 16000cps 이상, 17000cps 이상, 18000 cps 이상, 19000 cps 이상, 또는 20000 cps 이상이고, 30000 cps 이하, 29000 cps 이하, 28000 cps 이하, 27000 cps 이하, 26000 cps 이하, 25000 cps 이하, 24000cps 이하, 23000cps 이하, 22000cps 이하, 또는 21000cps 이하인 화장료 조성물의 담지용일 수 있다. 예를 들어 상기 조성물은 5000 cps 내지 30000 cps, 또는 8000 cps 내지 25000 cps 의 점도를 나타낼 수 있다. In one embodiment, the cosmetic composition carrier has a viscosity of 5000 cps or more, 6000 cps or more, 7000 cps or more, 8000 cps or more, 9000 cps or more, 10000 cps or more, 11000 cps or more, 12000 cps or more, 13000 cps or more, 14000 cps or more, 15000 cps or more, 16000 cps or more Above, 17000 cps or more, 18000 cps or more, 19000 cps or more, or 20000 cps or more, 30000 cps or less, 29000 cps or less, 28000 cps or less, 27000 cps or less, 26000 cps or less, 25000 cps or less, 24000 cps or less, 23000 cps or less, 22000 cps Or less, or may be for supporting a cosmetic composition of 21000cps or less. For example, the composition may exhibit a viscosity of 5000 cps to 30000 cps, or 8000 cps to 25000 cps.
일 예에서, 상기 화장료 조성물은 유화형 조성물, 구체적으로 수중유중수(W/O/W)형 유화 조성물, 유중수중유형(O/W/O)형 유화 조성물, 유중수(W/O)형 유화 조성물, 수중유(O/W)형 유화 조성물, 분산형 조성물이거나 구체적으로는 유분산 또는 수분산 조성물일 수 있다.In one example, the cosmetic composition is an emulsion type composition, specifically, water-in-oil-in-water (W/O/W) type emulsion composition, water-in-oil-in-water type (O/W/O) type emulsion composition, water-in-oil (W/O) type It may be an emulsifying composition, an oil-in-water (O/W) type emulsifying composition, a dispersing composition, or specifically, an oil dispersion or water dispersion composition.
일 구체예에서, 본 실시예에 따른 조성물은 유중수(W/O)형 유화 조성물일 수 있다. 상기 화장료 조성물은 유중수형으로 흐름성 있는 화장료, 예를 들어 메이크업 프라이머, 메이크업베이스, 스킨커버, 파운데이션, 립스틱, 립글로스, 리퀴드 아이섀도우, 아이브라우, 리퀴드 컨실러, 리퀴드 블러셔 등의 다양한 제형의 화장품에 적용될 수 있다. 일 예에서, 상기 화장료 조성물은 손이나 도포구를 통해 도포 대상인 피부에 전달될 수 있다.In one embodiment, the composition according to the present embodiment may be a water-in-oil (W/O) type emulsifying composition. The cosmetic composition is a water-in-oil type cosmetic that can be applied to various types of cosmetics, such as makeup primer, makeup base, skin cover, foundation, lipstick, lip gloss, liquid eyeshadow, eyebrow, liquid concealer, and liquid blusher. Can be. In one example, the cosmetic composition may be delivered to the target skin through a hand or applicator.
상기 유중수형 유화 조성물은, 당업계에서 사용하는 임의의 유화 방법에 의하여 제조될 수 있다. 일 구체예에서, 상기 유화는 유상부 및 수상부를 제조하고 이들을 혼합하는 것을 포함할 수 있다. 상기 혼합은 특별히 한정되지 않으나, 화장품 제조 분야에서 사용하는 통상의 혼합기, 균일화기, 호모게나이저, 또는 고압 호모게나이저 등을 사용할 수 있다. 상기 혼합 시 교반 속도는 사용하는 장치 및 조성 함량에 따라 다양하게 변경 가능하다.The water-in-oil type emulsifying composition may be prepared by any emulsifying method used in the art. In one embodiment, the emulsification may include preparing the oil phase and the water phase and mixing them. The mixing is not particularly limited, and a conventional mixer, homogenizer, homogenizer, or high pressure homogenizer used in the cosmetic manufacturing field may be used. The stirring speed at the time of mixing can be variously changed according to the device used and the composition content.
본 발명 일 실시예에 있어서, 상술한 본 발명 일 실시예에 따른 화장료 조성물 담체 및 상기 담체에 함침된 화장료 조성물을 포함하는 화장품을 제공할 수 있다.In one embodiment of the present invention, it is possible to provide a cosmetic composition comprising a cosmetic composition carrier according to an embodiment of the present invention described above and a cosmetic composition impregnated in the carrier.
상기 화장품은 상기 화장료 조성물이 함침된 담체를 수납하는 용기를 더 포함할 수 있다. 상기 용기는 팩트타입 용기일 수 있다. The cosmetic may further include a container for receiving a carrier impregnated with the cosmetic composition. The container may be a fact type container.
상기 담체는 용기와 분리 가능한 것일 수 있으며 사용자가 담체가 분리된 용기에 화장료 조성물을 원하는 대로 채워 넣은 후 담체를 결합시켜 사용할 수 있다. 또한, 사용자는 담체만 교체하여 사용할 수도 있다.The carrier may be separable from the container, and the user may fill and use the cosmetic composition in a container in which the carrier is separated, and then use the carrier in combination. In addition, the user can also use it by replacing only the carrier.
상기 화장품은 담체와 별도의 도포구를 더 포함할 수 있다. The cosmetic may further include a carrier and a separate applicator.
일 구체예에서, 상기 용기는 상기 담체 및 도포구를 수납할 수 있다. In one embodiment, the container can accommodate the carrier and the applicator.
일 구체예에서, 상기 화장품은 담체에 함침된 화장료 조성물을 도포구에 묻혀 도포대상에 도포하는 방식으로 사용될 수 있다. 이 경우, 화장료 조성물의 도포 시 화장료 조성물이 손에 묻지 않아 사용이 간편하며, 위생적이다.In one embodiment, the cosmetic may be used in a manner that a cosmetic composition impregnated in a carrier is applied to an application object by being buried in an applicator. In this case, when applying the cosmetic composition, the cosmetic composition does not get on the hand, so it is easy to use and hygienic.
상기 도포구의 재질 및 형태는 한정되지 않으나, 화장료 조성물을 피부에 도포할 때 선이나 점등의 자국이 생기지 않고 매끈하게 도포되어야 하므로 포어가 미세하고, 피부에 직접 닿기 때문에 부드럽고 쿠션감이 있는 것이 바람직하다. 일 예에서 상기 도포구는 발포폼 재질을 사용할 수 있다. 상기 도포구로 피부에 화장료 조성물을 도포할 때 도포구는 화장료 조성물을 일시적으로 머금어, 도포시 축축한 불쾌감을 줄 수 있으며, 도포구에 일시적으로 흡수된 상태로 외부에 노출되었던 화장료 조성물이 재차 피부에 도포될 가능성이 있다. 따라서 도포구는 화장료 조성물을 과도하게 흡수하지 않는 것이 유리하고, 화장료 조성물이 묻혀졌을 때 팽창되지 않는 재질이 바람직하다. 또한, 상기 도포구는 담체에 함침된 화장료 조성물을 용이하게 취출하고, 피부에 용이하게 도포되고, 피부 도포시 우수한 사용감을 나타낼 것을 요한다.The material and the shape of the applicator are not limited, but when the cosmetic composition is applied to the skin, lines or lighting marks must be applied smoothly, so the pores are fine, and it is preferable to have a soft and cushion feeling because it directly touches the skin. . In one example, the applicator may use a foam material. When applying the cosmetic composition to the skin with the applicator, the applicator temporarily absorbs the cosmetic composition, and may give a moist discomfort during application, and the cosmetic composition that has been exposed to the outside while temporarily absorbed by the applicator will be applied to the skin again. There is a possibility. Therefore, it is advantageous that the applicator does not excessively absorb the cosmetic composition, and a material that does not expand when the cosmetic composition is buried is preferable. In addition, the applicator requires that the cosmetic composition impregnated into the carrier is easily taken out, is easily applied to the skin, and exhibits an excellent feeling of use when applied to the skin.
일 구체예에서, 상기 도포구는 아크릴로니트릴부타디엔 고무(NBR), 스티렌부타디엔 고무(SBR), 천연 고무(NR), 폴리염화비닐, 폴리에틸렌, 에틸렌-비닐아세테이트부틸 고무(EVA), 라텍스, 실리콘, 스티렌-이소프렌-스티렌(SIS), 스티렌-에틸렌-부틸렌-스티렌(SEBS), 폴리비닐알코올(PVA), 니트릴 고무, 부틸 고무, 클로로프렌 고무(네오프렌®), 폴리올레핀 및 폴리우레탄으로 이루어진 군에서 선택된 하나 이상으로 제조된 폼일 수 있다. In one embodiment, the applicator is acrylonitrile butadiene rubber (NBR), styrene-butadiene rubber (SBR), natural rubber (NR), polyvinyl chloride, polyethylene, ethylene-vinyl acetate butyl rubber (EVA), latex, silicone, Selected from the group consisting of styrene-isoprene-styrene (SIS), styrene-ethylene-butylene-styrene (SEBS), polyvinyl alcohol (PVA), nitrile rubber, butyl rubber, chloroprene rubber (neoprene®), polyolefin and polyurethane. It may be a foam made of one or more.
이하, 실시예, 비교예 및 시험예를 참조하여 본 발명을 상세히 설명한다. 이들은 오로지 본 발명을 보다 구체적으로 설명하기 위해 예시적으로 제시한 것일 뿐, 본 발명의 범위가 이 실시예, 비교예 및 시험예에 의해 제한되지 않는다는 것은 당업계에서 통상의 지식을 가지는 자에 있어서 자명할 것이다.Hereinafter, the present invention will be described in detail with reference to Examples, Comparative Examples and Test Examples. These are only provided by way of example to illustrate the present invention in more detail, the scope of the present invention is not limited by these examples, comparative examples and test examples for those skilled in the art It will be self-evident.
[시험예 1] 유중수(W/O)형 유화 조성물의 제조[Test Example 1] Preparation of water-in-oil (W/O) type emulsion composition
하기 표 1의 조성으로 당업계의 통상적인 방법으로 파운데이션용 W/O 유화 조성물을 제조하여 본 발명의 담체 실험에 사용하였다. 제조된 화장료 조성물의 점도는 12,500cps였다.With the composition of Table 1 below, a W/O emulsion composition for foundation was prepared by a conventional method in the art and used in the carrier experiment of the present invention. The prepared cosmetic composition had a viscosity of 12,500 cps.
구분division 기능function 원료명Raw material name 함량content
유상Paid 에몰리언트Emollient 사이클로펜타실록산*사이클로헥사실록산Cyclopentasiloxane*cyclohexasiloxane 잔량Balance
에몰리언트 Emollient 페닐트리메치콘Phenyl trimethicone 77
자외선차단제 Sunscreen 에칠헥실메톡시신나메이트Ethylhexylmethoxycinnamate 77
유화제Emulsifier 피이지-10디메치콘PG-10 Dimethicone 44
유화제Emulsifier 라우릴피이지-9폴리디메칠실록시에칠디메치콘Laurylpage-9 polydimethylsiloxyethyldimethicone 22
분산제Dispersant 아크릴레이트/에칠헥실아크릴레이트/디메치콘메타크릴레이트코폴리머Acrylate/ethylhexyl acrylate/dimethicone methacrylate copolymer 44
파우더상Powder 점증제Thickener 디스테아디모늄헥토라이트Disteadimonium hectorite 0.70.7
착색제coloring agent 티타늄다이옥사이드*징크옥사이드*아이런옥사이드*메칠메타크릴레이트크로스폴리머Titanium dioxide * zinc oxide * iron oxide * methyl methacrylate cross polymer 2020
수상Awards 용제solvent 정제수Purified water 3030
보습제 Moisturizer 부틸렌글리콜Butylene glycol 55
이온봉쇄제Ion blocker 디소듐이디티에이Disodium LED 0.050.05
유화안정제Emulsifier 소듐클로라이드Sodium chloride 0.80.8
보존제Preservative 페녹시에탄올Phenoxyethanol 0.30.3
[시험예 2] 화장료 조성물 담체의 제조[Test Example 2] Preparation of cosmetic composition carrier
1. 습식 폴리카보네이트계 폴리우레탄 폼1. Wet polycarbonate-based polyurethane foam
습식 폴리카보네이트계 폴리우레탄 폼은 테크노포러스코리아㈜의 256-W1 그레이드를 구매하여 사용하였다. 담체 제조에 사용한 습식 폴리카보네이트계 폴리우레탄 폼의 특성을 아래에 기술한다.Wet polycarbonate-based polyurethane foam was purchased and used by Technophorus Korea Co., Ltd. 256-W1 grade. The properties of the wet polycarbonate-based polyurethane foam used for preparing the carrier are described below.
최상층Top floor
포어사이즈 (㎛)Pore size (㎛) 110110
밀도 (g/㎤)Density (g/cm3) 0.170.17
포어수 (ppi)Pore number (ppi) 120120
경도 (ASKER type F)Hardness (ASKER type F) 7070
지름 (mm)Diameter (mm) 5555
두께 (mm)Thickness (mm) 1One
2. 건식 폴리에테르계 폴리우레탄폼2. Dry Polyether Polyurethane Foam
건식 폴리에테르계 폴리우레탄폼은 Foamtec의 EZ93N 그레이드를 구매하여 사용하였다. 담체 제조에 사용한 건식 폴리에테르계 폴리우레탄 폼의 특성을 아래에 기술한다.The dry polyether-based polyurethane foam was purchased and used from Foamtec's EZ93N grade. The properties of the dry polyether-based polyurethane foam used for preparing the carrier are described below.
하부층Lower layer
포어사이즈 (㎛)Pore size (㎛) 450450
밀도 (g/㎤)Density (g/cm3) 0.030.03
포어수 (ppi)Pore number (ppi) 8080
경도 (ASKER type F)Hardness (ASKER type F) 7575
지름 (mm)Diameter (mm) 5555
두께 (mm)Thickness (mm) 88
3. 메쉬구조 섬유층3. Mesh structure fiber layer
메쉬구조 섬유층은 ㈜일송텍스의 원단을 구매하여 사용하였으며, 구체적으로 아래와 같은 특성을 가지는 것을 사용하였다.The mesh structure fiber layer was purchased from Ilsong Tex Co., Ltd., and was used in detail.
메쉬 1 Mesh 1 메쉬 2 Mesh 2 메쉬 3 Mesh 3
아이템 No.Item No. IST-1363IST-1363 IST-1250IST-1250 IST-1436IST-1436
재질material Nylon 85%,Spandex 15%Nylon 85%, Spandex 15% Nylon 83%,Spandex 17%83% Nylon, 17% Spandex Polyester 100%Polyester 100%
홀 사이즈 (mm)Hole size (mm) 1One 22 0.10.1
섬유 굵기 (denier)Fiber thickness (denier) 7070 100100 5050
지름 (mm)Diameter (mm) 5555 5555 5555
두께 (mm)Thickness (mm) 0.30.3 0.40.4 0.20.2
상기 표 2 내지 표 4의 폼과 섬유층을 사용하여 상층부터 습식 폴리카보네이트계 폴리우레탄 폼, 건식 폴리에테르계 폴리우레탄 폼 및 메쉬구조 섬유층의 순서로 적층하여, 가장자리 1mm를 경일초음파공업㈜의 초음파 기기를 이용하여 26.5 내지 39khz의 주파수로 접합하여 하기 표 5에 따른 화장료 조성물 담체를 제조하였다. 실시예 1-1은 메쉬구조 섬유층 없이 상층부터 습식 폴리카보네이트계 폴리우레탄 폼 및 건식 폴리에테르계 폴리우레탄 폼을 포함하는 담체이다. 습식 폴리카보네이트계 폴리우레탄 폼과 건식 폴리에테르계 폴리우레탄 폼은 유성접착제(우레탄계 + 아세트산(용제))를 사용하여 접착하였다.비교예 3은 층구조 없이 시험예 2의 건식 폴리에테르계 폴리우레탄 폼 단일층을 사용하였다. Using the foams and fiber layers of Tables 2 to 4, laminating from the upper layer in the order of wet polycarbonate-based polyurethane foam, dry polyether-based polyurethane foam and mesh-structured fiber layer, the edge of 1 mm is ultrasonic device of Kyungil Ultrasonic Industry Co., Ltd. It was bonded at a frequency of 26.5 to 39khz using to prepare a cosmetic composition carrier according to Table 5 below. Example 1-1 is a carrier comprising a wet polycarbonate-based polyurethane foam and a dry polyether-based polyurethane foam from the top layer without a mesh structured fiber layer. The wet polycarbonate-based polyurethane foam and the dry polyether-based polyurethane foam were adhered using an oil-based adhesive (urethane-based + acetic acid (solvent)). Comparative Example 3 is a dry polyether-based polyurethane foam of Test Example 2 without a layer structure. A single layer was used.
실시예 1Example 1 실시예 1-1Example 1-1 비교예 1Comparative Example 1 비교예 2Comparative Example 2 비교예 3Comparative Example 3
(최상층)습식 폴리카보네이트계 폴리우레탄 폼(Top layer) Wet polycarbonate polyurethane foam 최상층Top floor 최상층Top floor 최상층Top floor 최상층Top floor (층구조 없음)(No layer structure)
(하부층)건식 폴리에테르계 폴리우레탄 폼(Lower layer) dry polyether based polyurethane foam 하부층Lower layer 하부층Lower layer 하부층Lower layer 하부층 Lower layer
메쉬구조 섬유층Mesh structure fiber layer 메쉬 1Mesh 1 메쉬 2 Mesh 2 메쉬 3 Mesh 3
[시험예 3] 메쉬구조 섬유층의 홀 사이즈에 따른 접합 평가[Test Example 3] Bond evaluation according to the hole size of the mesh structure fiber layer
상기 실시예 1의 화장료 조성물 담체는 메쉬구조 섬유층으로 홀 사이즈 1mm인 것을 사용한 반면, 비교예 1의 경우 메쉬구조 섬유층으로 홀 사이즈 2mm인 것을 사용하여 제조하였다. 화장료 조성물 담체의 사진을 도 6에 나타낸다.The cosmetic composition carrier of Example 1 was prepared using a mesh structure fiber layer having a hole size of 1 mm, whereas in Comparative Example 1, a mesh structure fiber layer having a hole size of 2 mm was used. 6 shows a photograph of the cosmetic composition carrier.
도 7에 나타나는 바와 같이 메쉬 홀의 사이즈가 2mm 이상으로 크게 되면 가장자리 초음파 접합시 접합되는 영역이 적게 되어 접합이 제대로 되지 않고, 접합된 부위도 쉽게 떨어지는 문제가 발생하는 것을 확인할 수 있다.As shown in FIG. 7, when the size of the mesh hole is increased to 2 mm or more, it can be confirmed that the joining area is lessened when the edge is ultrasonically joined, and the joining part is easily detached.
[시험예 4] 화장료 조성물의 충진 평가[Test Example 4] Filling evaluation of cosmetic composition
두께 10mm, 지름 54mm의 용기 내에 상기 시험예 1에서 제조한 화장료 15g을 넣고, 상기 비교예 2의 담체를 용기 위에 올려놓고 실린더 타입의 흡습도구를 사용하여 화장료 조성물을 충진하였다.15 g of the cosmetic prepared in Test Example 1 was placed in a container having a thickness of 10 mm and a diameter of 54 mm, and the carrier of Comparative Example 2 was placed on the container, and the cosmetic composition was filled using a cylinder type moisture absorbing tool.
도 8에 나타나는 바와 같이 메쉬 홀의 사이즈가 0.1mm로 지나치게 작은 경우 하부로부터의 화장료 조성물의 충진이 잘 되지 않는 문제가 발생한다. As shown in FIG. 8, when the size of the mesh hole is too small to 0.1 mm, a problem arises in that the filling of the cosmetic composition from the lower part is not performed well.
[시험예 5] 화장료 조성물이 담지된 담체의 외관 평가[Test Example 5] Evaluation of the appearance of the carrier carrying the cosmetic composition
실시예 1과 비교예 3의 담체에 상기 시험예 1에서 제조한 화장료 15g을 충진한 화장품을 제조하였다.Cosmetics were prepared by filling the carriers of Example 1 and Comparative Example 3 with 15 g of the cosmetic prepared in Test Example 1.
도 9에 나타나는 바와 같이 비교예 3은 큰 포어 사이즈에 의해 기공이 음영으로 보여 표면이 매끈하지 않게 보이는 반면, 실시예 1의 경우 포어 사이즈가 작아 음영효과가 줄어들어 화장료 조성물의 색상이 더 밝고 화사하게 보임을 알 수 있다.As shown in FIG. 9, in Comparative Example 3, the pores were shaded due to the large pore size, and the surface was not smooth, whereas in Example 1, the pore size was small and the shading effect was reduced to make the color of the cosmetic composition brighter and brighter. You can see it.
[시험예 6] 관능평가[Test Example 6] Sensory evaluation
상기 시험예 5에서와 같이 화장료 조성물을 충진한 실시예 1 및 비교예 3의 화장품을 25~35세 여성 20명에게 에어셀(습식 폴리우레탄 폼) 퍼프로 취출 사용하게 하고, 외관의 선호도 및 취출시 부드러운 사용감 여부, 및 배출되는 양의 적정도를 5점 척도로 (1점: 매우나쁨~5점: 매우좋음) 평가하여 평균값을 아래 표 6에 나타낸다. As in the test example 5, the cosmetics of Example 1 and Comparative Example 3 filled with the cosmetic composition were taken out and used by 20 women 25 to 35 years old with puffs of air cell (wet polyurethane foam), and preference and take-out of appearance The average value is shown in Table 6 below by evaluating whether the feeling of soft use and the appropriateness of the discharged amount are on a 5-point scale (1 point: very bad to 5 points: very good).
외관 선호도Appearance preference 취출시 부드러움Softness when taken out 배출양 적정도Appropriate amount of discharge
실시예 1Example 1 4.64.6 4.74.7 4.54.5
비교예 3Comparative Example 3 1.81.8 2.42.4 2.92.9
상기 결과에 따라, 본 발명에 따른 담체는 화사한 외관 선호도 개선뿐 아니라 사용감에 있어서도 부드러운 취출 사용감과 적정양의 화장료 조성물이 배출되어 우수한 효과를 나타냄을 확인할 수 있다.According to the above results, it can be seen that the carrier according to the present invention exhibits an excellent effect by not only improving a bright appearance preference but also discharging a soft feeling of use and an appropriate amount of the cosmetic composition in terms of use.
[시험예 7] 화장료 조성물의 배출 패턴 평가[Test Example 7] Evaluation of cosmetic composition discharge pattern
상기 시험예 5에서 화장료 조성물을 충진하여 제조한 실시예 1 및 비교예 3의 담체 위에 에어셀(습식 폴리우레탄 폼) 도포구(퍼프)를 올려놓고, 프레스기(푸쉬풀게이지)를 활용하여 1.0kgf/㎠로 3초간 눌러 조성물이 퍼프로 배출되게 하였다. Place the air cell (wet polyurethane foam) applicator (puff) on the carriers of Example 1 and Comparative Example 3 prepared by filling the cosmetic composition in Test Example 5, and utilize 1.0 kgf/ using a press machine (push-pull gauge). Pressed for 3 seconds with cm 2 to allow the composition to drain into the puff.
저울을 이용하여 토출양을 비교해본 결과를 도 9에 나타낸다.Fig. 9 shows the results of comparing the discharge amount using a scale.
도 10의 결과와 같이 비교예 3의 경우 토출되는 횟수에 따라 편차가 심한 반면, 실시예 1의 경우 균일하게 토출되는 양상을 보이는 것을 알 수 있다.As shown in FIG. 10, it can be seen that, in the case of Comparative Example 3, the variation was severe according to the number of discharges, whereas Example 1 showed a uniform discharge pattern.
또한 도 11은 토출 횟수에 따른 퍼프의 사진을 나타낸다. 도 11의 사진으로부터 확인할 수 있는 바와 같이 토출된 도포구의 표면에 있어서도, 비교예 3보다 실시예 1 담체를 통해 토출된 조성물이 도포구의 넓은 면적에 균일하게 묻어있는 것을 확인할 수 있다. 이로부터 본 발명 실시예에 따른 담체는 조성물의 배출양뿐 아니라 배출되는 면에 있어서도 균일한 배출 패턴을 나타내어 사용시 균일한 도포가 가능한 효과를 나타내는 것을 확인할 수 있다.In addition, Figure 11 shows a picture of the puff according to the number of discharges. As can be seen from the photograph of FIG. 11, it can be seen that even on the surface of the discharged applicator, the composition discharged through the carrier in Example 1 was uniformly deposited on a large area of the applicator than Comparative Example 3. From this, it can be seen that the carrier according to the embodiment of the present invention exhibits a uniform discharge pattern not only in the discharge amount of the composition, but also in the discharged surface, thereby exhibiting the effect of uniform application when used.
[시험예 8] 화장료 조성물 담체의 제조[Test Example 8] Preparation of cosmetic composition carrier
상기 시험예 2의 실시예 1과 동일한 소재를 사용하여 상층부터 습식 폴리카보네이트계 폴리우레탄 폼, 건식 폴리에테르계 폴리우레탄 폼 및 메쉬구조 섬유층의 순서로 적층하고, 가장자리 1mm를 경일초음파공업㈜의 초음파 기기를 이용하여 26.5 내지 39khz의 주파수로 접합하여 실시예 2의 화장료 조성물 담체를 제조하였다. 제조된 실시예 2 담체의 외관을 도 13 내지 도 16에 나타낸다.The same material as in Example 1 of Test Example 2 was used to stack wet polycarbonate-based polyurethane foam, dry polyether-based polyurethane foam, and mesh-structured fiber layers in order from the upper layer, and the edge of 1 mm was ultrasonic of Kyungil Ultrasonic Industry Co., Ltd. Using a device to bond at a frequency of 26.5 to 39khz to prepare a cosmetic composition carrier of Example 2. The appearance of the prepared Example 2 carrier is shown in FIGS. 13 to 16.
실시예 3은 건식 폴리에테르계 폴리우레탄 폼의 두께를 6mm이며, 습식 폴리카보네이트계 폴리우레탄 폼과 건식 폴리에테르계 폴리우레탄 폼을 유성접착제(우레탄계 + 아세트산(용제))를 사용하여 서로 접착한 것을 제외하고는 상기 시험예 2의 실시예 1과 동일한 소재를 사용하여 제조하였다. 구체적으로 상층부터 습식 폴리카보네이트계 폴리우레탄 폼, 건식 폴리에테르계 폴리우레탄 폼 및 메쉬구조 섬유층의 순서로 적층하고, 가장자리 0.3mm를 선진정밀의 유압 프레스(Heating)를 사용하여 유압 60~100 kg/㎠, 온도 180~200℃ 조건 하에서 열접합하여 실시예 3의 화장료 조성물 담체를 제조하였다. 제조된 실시예 3 담체의 외관을 도 17 내지 도 20에 나타낸다. 도 21은 실시예 3의 담체를 절단하여 종단면을 노출시킨 상태의 사진이다.In Example 3, the dry polyether-based polyurethane foam had a thickness of 6 mm, and the wet polycarbonate-based polyurethane foam and the dry polyether-based polyurethane foam were adhered to each other using an oil-based adhesive (urethane-based + acetic acid (solvent)). It was prepared using the same material as in Example 1 of Test Example 2 except for. Specifically, from the upper layer, wet polycarbonate-based polyurethane foam, dry polyether-based polyurethane foam, and mesh-structured fiber layers are stacked in order, and the edge of 0.3mm is hydraulic 60~100 kg/ using advanced precision hydraulic press. Thermal bonding was performed under the condition of cm 2 and temperature of 180 to 200° C. to prepare the cosmetic composition carrier of Example 3. The appearance of the prepared Example 3 carrier is shown in FIGS. 17 to 20. 21 is a photograph of a state in which a longitudinal cross-section is exposed by cutting the carrier of Example 3.
실시예 4는 실시예 3과 동일한 방법으로 제조하되, 다만 두께 3mm의 건식 폴리에테르계 폴리우레탄 폼을 2층으로 적층 포함하여 제조하였다. 제조된 실시예 4 담체의 외관을 도 22에 나타내며, 담체를 절단하여 종단면을 노출시킨 상태의 이미지이며, 내부에 절개부가 형성된 것을 확인할 수 있다.Example 4 was prepared in the same manner as in Example 3, but was prepared by laminating a dry polyether-based polyurethane foam having a thickness of 3 mm in two layers. The appearance of the prepared Example 4 carrier is shown in FIG. 22, and it is an image in which a longitudinal section is exposed by cutting the carrier, and it can be seen that an incision was formed therein.
[시험예 9] 화장료 조성물의 배출 패턴 평가[Test Example 9] Evaluation of cosmetic composition discharge pattern
실시예 3과 실시예 4의 담체에 상기 시험예 1에서 제조한 화장료 15g을 충진하여 화장품을 제조하였다.Cosmetics were prepared by filling the carriers of Examples 3 and 4 with 15 g of the cosmetic prepared in Test Example 1 above.
담체 위에 에어셀(습식 폴리우레탄 폼) 도포구(퍼프)를 올려놓고, 프레스기(푸쉬풀게이지)를 활용하여 1.0kgf/㎠로 3초간 눌러 조성물이 퍼프로 배출되게 하였다. 저울을 이용하여 토출양을 비교한 결과를 표 7 및 도 23에 나타낸다.An air cell (wet polyurethane foam) applicator (puff) was placed on the carrier, and a press machine (push-pull gauge) was utilized to press the composition at 1.0 kgf/cm 2 for 3 seconds to discharge the composition into the puff. Table 7 and FIG. 23 show the results of comparing the discharge amount using a scale.
표 7 및 도 23의 결과에서, 실시예 4의 절개부를 포함하는 담체의 경우 좀 더 많은 양이 고르게 토출되는 것을 확인할 수 있다.From the results of Table 7 and Figure 23, it can be seen that in the case of the carrier including the incision of Example 4, a larger amount is evenly discharged.
토출횟수Discharge count 토출량(g)Discharge amount (g)
실시예 3Example 3 실시예 4Example 4
1One 0.40.4 0.520.52
22 0.240.24 0.360.36
33 0.260.26 0.260.26
44 0.320.32 0.320.32
55 0.220.22 0.240.24
66 0.180.18 0.220.22
77 0.160.16 0.20.2
88 0.140.14 0.180.18
99 0.10.1 0.140.14
1010 0.10.1 0.140.14
1111 0.080.08 0.140.14
1212 0.080.08 0.060.06
1313 0.060.06 0.080.08
1414 0.080.08 0.060.06
1515 0.040.04 0.080.08
1616 0.040.04 0.10.1
1717 0.060.06 0.10.1
1818 0.080.08 0.060.06
1919 0.040.04 0.040.04
2020 0.020.02 0.040.04

Claims (17)

  1. 가장자리에 접합부가 형성된 화장료 조성물 담체로서,As a carrier of the cosmetic composition formed with a junction at the edge,
    상기 담체는,The carrier,
    포어사이즈, 밀도, 두께, 포어수 중 하나 이상이 서로 다른 복수의 폴리우레탄 폼이 적층된 적층부를 포함하는, A laminate comprising a plurality of polyurethane foams having different pore sizes, density, thickness, and number of pores stacked,
    화장료 조성물 담체.Cosmetic composition carrier.
  2. 제1항에 있어서,According to claim 1,
    상기 접합부는 화장료 조성물 담체의 가장자리를 초음파 접합 또는 열접합하여 형성되는 것인, 화장료 조성물 담체.The bonding portion is formed by ultrasonic bonding or thermal bonding the edge of the cosmetic composition carrier, the cosmetic composition carrier.
  3. 제1항에 있어서,According to claim 1,
    상기 접합부의 폭(Wd)은 0.05 내지 5mm인 화장료 조성물 담체. The width (Wd) of the bonding portion is 0.05 to 5mm cosmetic composition carrier.
  4. 제1항에 있어서,According to claim 1,
    상기 적층부는 최상층에 습식 폴리카보네이트계 폴리우레탄 폼을 포함하는, 화장료 조성물 담체.The layered portion comprises a wet polycarbonate-based polyurethane foam on the top layer, a cosmetic composition carrier.
  5. 제1항에 있어서,According to claim 1,
    상기 적층부는 최상층과 최상층의 하부에 배치되는 하부층을 포함하고,The stacked portion includes a top layer and a bottom layer disposed under the top layer,
    상기 하부층은 건식 폴리에테르계 폴리우레탄 폼을 포함하는, 화장료 조성물 담체.The lower layer comprises a dry polyether-based polyurethane foam, a cosmetic composition carrier.
  6. 제1항에 있어서,According to claim 1,
    상기 적층부의 최상층의 폴리우레탄 폼은 50 내지 500㎛의 포어사이즈를 갖는, 화장료 조성물 담체.The polyurethane foam of the uppermost layer of the laminated portion has a pore size of 50 to 500㎛, the cosmetic composition carrier.
  7. 제1항에 있어서,According to claim 1,
    상기 적층부의 폴리우레탄 폼은 망상형 구조를 갖는 것인, 화장료 조성물 담체.The polyurethane foam of the laminated portion is to have a network structure, the cosmetic composition carrier.
  8. 제1항에 있어서,According to claim 1,
    상기 적층부는 최상층과 최상층의 하부에 배치되는 하부층을 포함하고,The stacked portion includes a top layer and a bottom layer disposed under the top layer,
    상기 최상층과 하부층의 폴리우레탄 폼은 하기 (a) 내지 (d)의 조건 중 하나 이상을 만족하는 것인, 화장료 조성물 담체:The polyurethane foam of the top layer and the bottom layer will satisfy at least one of the following conditions (a) to (d), the cosmetic composition carrier:
    (a) 상기 최상층의 폴리우레탄 폼은 하부층의 폴리우레탄 폼 보다 포어사이즈가 작거나,(a) The polyurethane foam of the uppermost layer has a smaller pore size than the polyurethane foam of the lower layer,
    (b) 상기 최상층의 폴리우레탄 폼은 하부층의 폴리우레탄 폼 보다 밀도가 크거나,(b) the polyurethane foam of the top layer has a greater density than the polyurethane foam of the bottom layer,
    (c) 상기 최상층의 폴리우레탄 폼은 하부층의 폴리우레탄 폼 보다 두께가 얇거나,(c) the polyurethane foam of the uppermost layer is thinner than the polyurethane foam of the lower layer,
    (d) 상기 최상층의 폴리우레탄 폼은 하부층의 폴리우레탄 폼 보다 인치 당 포어 수 (ppi)가 크다.(d) The polyurethane foam of the top layer has a larger number of pores per inch (ppi) than the polyurethane foam of the bottom layer.
  9. 제1항에 있어서,According to claim 1,
    상기 담체는 메쉬구조 섬유층을 더 포함하는, 화장료 조성물 담체.The carrier further comprises a mesh structure fiber layer, cosmetic composition carrier.
  10. 제9항에 있어서,The method of claim 9,
    상기 메쉬구조 섬유층은 상기 적층부의 하부에 배치되는 것인, 화장료 조성물 담체.The mesh structure fiber layer is to be disposed under the layered portion, the cosmetic composition carrier.
  11. 제8항에 있어서,The method of claim 8,
    상기 메쉬구조 섬유층은 항균 셀룰로오스, 천연펄프, 수세미(loofah), 모시, 라미(식물), 아야테(ayate), 조류(algae), 대나무(Bamboo), 사이잘(sisal), 사이잘 테리(sisal terry), 곤약, 텐셀(TM) 파이버 원단, 코튼, 마닐라 삼(abaca fiber), 나일론, 스판덱스, 폴리에스터, 폴리아세테이트, 카시미론 파이버, 컴포트 파이버, 폴리트리메틸렌테레프탈레이트 섬유, 폴리에틸렌, 폴리프로필렌, 폴리아크릴레이트, PLA(polylactic acid), 및 폴리유산계 복합 섬유 중 하나 이상의 섬유를 포함하는, 화장료 조성물 담체.The mesh structure fiber layer is an antibacterial cellulose, natural pulp, loofah, ramie, ramie (plant), ayate, algae, bamboo, sisal, sisal sisal terry), konjac, tencel(TM) fiber fabric, cotton, manila hemp (abaca fiber), nylon, spandex, polyester, polyacetate, casimiron fiber, comfort fiber, polytrimethylene terephthalate fiber, polyethylene, polypropylene, A carrier for a cosmetic composition comprising one or more of polyacrylate, polylactic acid (PLA), and polylactic acid-based composite fibers.
  12. 제8항에 있어서,The method of claim 8,
    상기 메쉬구조 섬유층은 0.3mm 내지 1.8mm의 홀 사이즈를 갖는, 화장료 조성물 담체.The mesh structure fiber layer has a hole size of 0.3mm to 1.8mm, a cosmetic composition carrier.
  13. 제9항에 있어서,The method of claim 9,
    상기 메쉬구조 섬유층은 10 내지 200 데니어(denier)의 섬유굵기를 갖는, 화장료 조성물 담체.The mesh structure fiber layer has a fiber thickness of 10 to 200 denier (denier), the cosmetic composition carrier.
  14. 제1항에 있어서,According to claim 1,
    상기 담체는 담체의 층에 대하여 평행한 방향으로 내부 공동(void)을 형성하는 절개부를 더 포함하는, 화장료 조성물 담체.The carrier further comprises an incision to form an inner void in a direction parallel to the layer of the carrier, the cosmetic composition carrier.
  15. 제1항에 있어서,According to claim 1,
    상기 담체는 상기 적층부의 층간 및 상기 적층부와 메쉬구조 섬유층 사이 중 하나 이상에 배치되는 프라이머층을 더 포함하는, 화장료 조성물 담체.The carrier further comprises a primer layer disposed on at least one of the interlayer of the laminated portion and between the laminated portion and the mesh structure fiber layer, the cosmetic composition carrier.
  16. 제14항에 있어서,The method of claim 14,
    상기 프라이머층은 핫멜트 부직포 웹, 핫멜트 메쉬 및 스프레이 접착층 중 하나 이상을 포함하는, 화장료 조성물 담체.The primer layer comprises at least one of a hot melt nonwoven web, a hot melt mesh and a spray adhesive layer, the cosmetic composition carrier.
  17. 제1항에 있어서,According to claim 1,
    상기 화장료 조성물은 유화형 조성물인, 화장료 조성물 담체. The cosmetic composition is an emulsion-type composition, a cosmetic composition carrier.
PCT/KR2019/016342 2018-11-30 2019-11-26 Cosmetic composition carrier WO2020111715A1 (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
KR20180152845 2018-11-30
KR10-2018-0152845 2018-11-30
KR10-2019-0116199 2019-09-20
KR1020190116199A KR20200066158A (en) 2018-11-30 2019-09-20 Cosmetic composition carrier

Publications (1)

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WO2020111715A1 true WO2020111715A1 (en) 2020-06-04

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WO (1) WO2020111715A1 (en)

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20130083852A (en) * 2012-01-13 2013-07-23 (주)아모레퍼시픽 Carrier for cosmetic composition comprising foamed urethane layer structure
KR20130134604A (en) * 2012-05-31 2013-12-10 주식회사 코스텍 Puff for makeup and the manufacturing method
KR20160120585A (en) * 2015-04-08 2016-10-18 (주)아모레퍼시픽 Cosmetic composition container having muti-layered one-piece sponge
KR101756788B1 (en) * 2009-03-03 2017-07-11 패드테크 에이에스 Soft edged pad
KR20180094399A (en) * 2017-02-15 2018-08-23 (주)아모레퍼시픽 Carrier unit having adhesive layer and method of manufacturing carrier unit

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101756788B1 (en) * 2009-03-03 2017-07-11 패드테크 에이에스 Soft edged pad
KR20130083852A (en) * 2012-01-13 2013-07-23 (주)아모레퍼시픽 Carrier for cosmetic composition comprising foamed urethane layer structure
KR20130134604A (en) * 2012-05-31 2013-12-10 주식회사 코스텍 Puff for makeup and the manufacturing method
KR20160120585A (en) * 2015-04-08 2016-10-18 (주)아모레퍼시픽 Cosmetic composition container having muti-layered one-piece sponge
KR20180094399A (en) * 2017-02-15 2018-08-23 (주)아모레퍼시픽 Carrier unit having adhesive layer and method of manufacturing carrier unit

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