WO2020110853A1 - Water purification device and household water purifier - Google Patents

Water purification device and household water purifier Download PDF

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Publication number
WO2020110853A1
WO2020110853A1 PCT/JP2019/045388 JP2019045388W WO2020110853A1 WO 2020110853 A1 WO2020110853 A1 WO 2020110853A1 JP 2019045388 W JP2019045388 W JP 2019045388W WO 2020110853 A1 WO2020110853 A1 WO 2020110853A1
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Prior art keywords
water
filter
reverse osmosis
osmosis membrane
membrane
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PCT/JP2019/045388
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French (fr)
Japanese (ja)
Inventor
宗郷 熊谷
哲也 門馬
Original Assignee
シャープ株式会社
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Publication date
Application filed by シャープ株式会社 filed Critical シャープ株式会社
Priority to JP2020557586A priority Critical patent/JP7346447B2/en
Priority to CN201980074224.8A priority patent/CN113039007A/en
Publication of WO2020110853A1 publication Critical patent/WO2020110853A1/en

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D61/00Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/02Reverse osmosis; Hyperfiltration ; Nanofiltration
    • B01D61/12Controlling or regulating
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/28Treatment of water, waste water, or sewage by sorption
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/42Treatment of water, waste water, or sewage by ion-exchange
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/44Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis

Definitions

  • the present invention relates to a water purifier and a household water purifier.
  • RO membrane reverse osmosis membrane
  • Patent Document 1 Since it is very difficult to completely separate water molecules and impurities by the RO membrane, when further purification is required, for example, in Patent Document 1, a plurality of purification mechanisms using the RO membrane are provided and purification is performed. A technique for increasing the purity by repeating is disclosed.
  • a method using an ion exchange resin has been adopted as a new means for increasing the purity of purified water.
  • a filter hereinafter referred to as a DI filter
  • a case for water flow is filled with an ion exchange resin is arranged in the latter stage of the RO membrane, and the purified water that has passed through the RO membrane is passed through the DI filter to leave impurities.
  • High purification performance is obtained by further removing (for example, Patent Document 2).
  • the above-mentioned purified water using the DI filter has an advantage that its structure is simple as compared with the method of repeating purification using an RO membrane, but the purification function of the DI filter is limited, and a certain amount of water is used. There is a problem in that the function is lost when the impurities in are removed. Therefore, in the purification of water using the DI filter, it is required to maintain its function for a longer period of time, and it is necessary to devise a means for suppressing the consumption of its performance. This can be said not only for the DI filter but also for an adsorption/removal member that generally adsorbs and removes impurities having a limited purification function.
  • An aspect of the present invention is to realize a water purification apparatus that can reduce the consumption of the adsorption removal member and suppress the deterioration of the function when the RO membrane and the adsorption removal member that adsorbs and removes impurities are used together. To do.
  • a water purification device is a water purification device that purifies water using a reverse osmosis membrane and an adsorption removal member that adsorbs and removes impurities
  • the adsorption/removal member is arranged on a path from the osmosis membrane to the intake of purified water purified by the reverse osmosis membrane, and the water passage is provided on a water passage from the reverse osmosis membrane to the adsorption/removal member. It is characterized in that a first blocking mechanism for blocking the passage of water in the route is provided.
  • a water purifier that can reduce the consumption of the adsorption/removal member and can suppress the deterioration of the function.
  • the water purifier 1 is a household water purifier that uses a reverse osmosis membrane (RO membrane) and a filter (DI filter) filled with an ion exchange resin.
  • the water purification device 1 includes a main path 50 that takes in raw water from an intake port 50a on one end side and discharges purified water from an intake port 50b on the other end side.
  • the intake port 50a is connected to tap water (raw water)
  • the extraction port 50b is connected to an outlet opening/closing mechanism such as a faucet.
  • a first drainage path (discarding path) 51 described later is connected to, for example, a drainage pipe under a sink.
  • a pressure switch 10 a solenoid valve 31, a pressure reducing valve 11, a PP (polypropylene) filter 12, a front TDS 13, a water temperature meter 14, a front flow meter 15, an AC (activated carbon) filter 16, a Pump 17, in order from the most upstream side of the main path 50.
  • An RO membrane (reverse osmosis membrane) 18, an opening/closing mechanism (first blocking mechanism) 32, a DI filter (impurity adsorption/removal member) 19, a rear flow meter 20, and a rear TDS 21 are arranged.
  • the pressure switch 10 is a switch that turns on at a certain pressure or higher, and turns on when raw water is supplied to the main path 50 and the pressure of the raw water (tap water pressure) can be detected.
  • the pressure reducing valve 11 keeps the water pressure of the tap water flowing through the main path 50 constant.
  • the PP (polypropylene) filter 12 is a relatively coarse non-woven fabric made of polypropylene (PP) and removes relatively large impurities such as rust contained in raw water.
  • the material is not limited and may be polyethylene (PE). By removing the relatively large impurities before reaching them, it is possible to suppress the deterioration of the reverse osmosis membrane (hereinafter, RO membrane) described later.
  • the front-side TDS 13 and the rear-side TDS 21 are water quality sensors that measure indicators of water quality, and measure the electrical conductivity of water to detect the concentration of impurities in the water.
  • the front TDS 13 measures the water quality of the raw water taken in through the intake port 50a
  • the rear TDS 21 measures the water quality of the purified water taken out through the intake port 50b.
  • the water temperature gauge 14 is used for calibration of the front TDS 13 and the rear TDS 21. This is because the electric conductivity measured by the front TDS 13 and the rear TDS 21 has temperature dependence. The detection result is output to the control unit.
  • the AC filter 16 removes free substances such as free chlorine compounds contained in raw water with activated carbon.
  • the RO film 18 is deteriorated by the free chlorine compound (so-called chlorine) contained in the tap water that is the raw water. Therefore, by removing the free chlorine compound with the AC filter 16 before reaching, the deterioration of the RO film 18 can be suppressed.
  • the Pump 17 is for sending water to the RO membrane 18 in the subsequent stage while applying a predetermined pressure, and is used to realize a cross flow method using the RO membrane 18 described later.
  • the front flow meter 15 and the rear flow meter 20 are sensors that measure the flow rate of water flowing through the main path 50.
  • the measurement result is output to the control unit, and the control unit calculates the raw water intake amount (use amount), which is the measurement value of the front flow meter 15, and the purified water generation amount, which is the measurement value of the rear flow meter 20, Calculate the recovery rate.
  • the front flow meter 15 is preferably arranged between the PP filter 12 and the AC filter 16 as the arrangement position of the front flow meter 15, as shown in FIG. This is because by arranging the PP filter 12 at the subsequent stage (downstream side), it is possible to prevent the adhesion of dirt to the front flow meter 15.
  • the pressure reducing valve 11, the PP filter 12, the front TDS 13, the water temperature meter 14, the AC filter 16, the rear flow meter 20, and the rear TDS 21 described above may be provided as necessary.
  • RO membrane 18 separates water molecules and impurities.
  • the purification target water is caused to flow on the surface of the RO membrane 18 while applying water pressure by the Pump 17, thereby separating the treated water that has permeated the RO membrane 18 and the wastewater that has not permeated.
  • the RO membrane 18 is separated into treated water (purified water) and waste water (concentrated water) by a so-called cross flow method.
  • the treated water flows through the main path 50 and flows into the DI filter 19 in the latter stage of the RO membrane 18, and the waste water is discharged from the waste port of the first drain path 51.
  • the waste port is connected to, for example, the drain pipe under the sink.
  • a flash solenoid valve 22 is provided in the first drainage path 51.
  • the flash solenoid valve 22 is a flow rate limiting valve that limits the flow rate of the wastewater flowing through the first drainage path 51.
  • the flush solenoid valve 22 limits the flow rate in the closed state (power-off state (non-energized)) and opens the flow path as much as possible in the open state (power-on state (energized)) to allow water to flow. It functions to flush.
  • the RO film 18 removes almost all impurities dissolved in water, both harmful and harmless, to obtain pure water of high purity.
  • the RO film 18 is made of a network-like polymer film formed by cross-linking, and basically only water molecules permeate the polymer film due to the size of the network, so that the RO film 18 may not be mixed with impurities. The separation is performed and the above-mentioned purification performance can be obtained.
  • water to be purified is passed over the surface of the RO membrane 18 while applying a constant water pressure, and at this time, the water that has passed through the RO membrane 18 due to water pressure is taken out as purified water and passed through the RO membrane 18. The remaining water is discarded as waste water. Therefore, in the cross-flow method, impurities are separated from water molecules by constantly passing the surface of the RO film 18. In the process of flowing water on the surface of the RO film 18, only water molecules permeate through the RO film 18 to be lost in the water on the drainage side. Then, the impurities are relatively concentrated and the concentration is increased, and the product is discarded. As described above, the purified water using the RO membrane 18 is accompanied by a certain amount of waste water (concentrated water).
  • the flush solenoid valve 22 has a function of limiting the flow rate in the closed state as described above and opening the flow path as much as possible to allow water to flow in the open state.
  • a large amount of water is passed as necessary to wash away the surface of the RO membrane 18 electrically.
  • a filter referred to as a sediment filter or the like: PP filter 12
  • PP filter 12 mainly made of fibers such as PP (polypropylene) and PE (polyethylene) is used to remove deposits, fine particles, sticky substances, etc., and activated carbon as the main material. This is the adsorption and removal of chlorine, organic substances and the like used in the sterilization treatment of water supply by the filter (AC filter 16).
  • the DI filter 19 is a filter in which a case for water flow is filled with an ion exchange resin.
  • the ion exchange resin it is preferable to use a resin having a function of removing both cations and anions that are components of impurities for purification of water. That is, in the DI filter 19, cations are exchanged for hydrogen ions and anions are exchanged for hydroxide ions, and the released hydrogen ions and hydroxide ions are neutralized in water to return to water. Is purified. Therefore, the DI filter 19 can be said to be an impurity adsorption/removal member that adsorbs and removes the impurities contained in the water purified by the RO film 18.
  • the opening/closing mechanism 32 is provided along the path (main path 50) that connects the RO film 18 and the DI filter 19, and is a mechanism that blocks the diffusion of impurities dissolved in water.
  • the opening/closing mechanism 32 opens the main path 50 during the cleaning operation to allow water to pass therethrough, and shuts off the main path 50 when the cleaning operation is stopped to cut off water coming and going across the opening/closing mechanism 32.
  • the total amount of impurities removed by the DI filter 19 is suppressed while the purification operation is stopped, and unnecessary purification performance is prevented from being consumed, so that the purification function of the DI filter 19 is used for a longer period of time.
  • the purified water and the wastewater in which the impurities are concentrated are separated with the RO membrane 18 interposed therebetween, and the DI filter 19 contains few impurities. Only purified water from the RO membrane 18 is supplied. However, when the purifying operation is stopped and the water in the water purifier 1 is no longer supplied, the impurities contained in the water left in the front-stage region that permeates the RO membrane 18 are transferred to the purified water side that has passed through the RO membrane 18. A phenomenon occurs in which a certain water permeates the RO film 18 and diffuses with time.
  • the path blocking mechanism opening/closing mechanism 32
  • the impurities thus permeated through the RO film 18 gradually diffuse to the DI filter 19, and the ions in the DI filter 19 are diffused. Purified by exchange resin. Since this phenomenon continues until the concentration of impurities in the water sandwiching the RO film 18 becomes equal, finally the impurities of water staying in all regions on the front side of the RO film 18 are absorbed by the DI filter 19. It will be continued until it is purified. Therefore, the impurities that should originally be discarded as concentrated water by the RO membrane 18 are also purified by the DI filter 19, and the purification performance of the DI filter 19 is greatly consumed and wasted.
  • the opening/closing mechanism 32 for blocking the diffusion of impurities dissolved in water on the path connecting the RO film 18 and the DI filter 19 the above-mentioned substance diffusion can be achieved. It is possible to prevent the accompanying impurities from reaching the DI filter 19.
  • the opening/closing mechanism 32 is as close as possible to the RO film. It is desirable to install it near 18.
  • the opening/closing mechanism 32 is installed as close to the RO membrane 18 as possible (immediately after the RO membrane 18), diffusion of concentrated water drifting near the RO membrane 18 when the purification operation is stopped is prevented from reaching the DI filter 19 as much as possible. be able to. As a result, the functional life of the DI filter 19 can be extended.
  • the opening/closing mechanism 32 provided on the way of connecting the RO membrane 18 and the DI filter 19 is one that opens and closes without power (for example, a manual opening/closing mechanism (valve), a check valve). Alternatively, it may be one that opens and closes with electric power (for example, a solenoid valve).
  • the water purifier 1A according to the present embodiment is different from the water purifier 1 of the first embodiment in that a forward direction (here, instead of the opening/closing mechanism 32 between the RO membrane 18 and the DI filter 19) is used.
  • a forward direction here, instead of the opening/closing mechanism 32 between the RO membrane 18 and the DI filter 19
  • the check valve 33 that allows water to pass only to the outlet 50b side is used.
  • the water purifier 1A has the same configuration as the water purifier 1 of the first embodiment except that a check valve 33 is used instead of the opening/closing mechanism 32.
  • the check valve 33 operates without power, it operates even during a power failure. Moreover, since it is not expensive like a solenoid valve, the water purifier 1A can be manufactured at low cost.
  • the water purification apparatus 1B flushes the electromagnetic valve (second shutoff mechanism) 31 arranged between the pressure switch 10 and the pressure reducing valve 11 in the water purification apparatus 1A shown in FIG.
  • An example is shown in which the solenoid valve 22 is arranged on the downstream side.
  • the outlet 50b of the main path 50 is provided with a faucet as a kind of opening/closing mechanism for opening and closing the outlet 50b.
  • the power of the water purifier 1 is turned on by the operation of opening the faucet, and the power of the water purifier 1 is turned off by the operation of closing the faucet.
  • the outlet 50b is provided with a faucet which is a kind of an outlet opening/closing mechanism, and the opening/closing of the faucet is linked to the cleaning operation.
  • the solenoid valve 31 may be arranged between the RO membrane 18 and the flash solenoid valve 22. Also in this case, the same effect as when the solenoid valve 31 is arranged on the downstream side of the flash solenoid valve 22 can be obtained.
  • check valve 33 of the water purifying apparatus 1A shown in FIG. 2 may be an electromagnetic valve as an opening/closing mechanism linked with the purification operation.
  • an electromagnetic valve 34 may be provided between the RO membrane 18 and the DI filter 19.
  • check valve 33 of the water purifier 1B shown in FIG. 3 may be replaced with a solenoid valve 34 as shown in the water purifier 1D shown in FIG.
  • the solenoid valve 34 is turned on during the cleaning operation, opens the main path 50 to allow water to flow from the RO membrane 18 to the DI filter 19, is turned off when the cleaning operation is stopped, and closes the main path 50 from the RO membrane 18. Prevent water from flowing through the DI filter 19. That is, the solenoid valve 34 shuts off the water passage in association with the stop of the purification operation, and opens the water passage in association with the restart of the purification operation.
  • the solenoid valve 34 is turned off in conjunction with the stoppage of the purifying operation, so that the purification is possible without providing the tap 50b unlike the water purifier 1B shown in FIG.
  • the pressure can be maintained during shutdown.
  • the electromagnetic valve 31 as a new opening/closing mechanism that is linked with the purifying operation is provided in the first drainage which is the latter stage of the RO membrane 18.
  • the first drainage path 51 may be provided on the path 51 and opened during the purification operation, and the first drainage path 51 may be shut off during the purification operation stop.
  • the water purifier 1E according to the present embodiment is different from the water purifier 1 of the first embodiment, in place of the opening/closing mechanism 32 between the RO membrane 18 and the DI filter 19, the flow path switching mechanism 35. Is used.
  • the water purifier 1E has the same configuration as the water purifier 1 of the first embodiment except that the flow path switching mechanism 35 is used instead of the opening/closing mechanism 32.
  • the flow path switching mechanism 35 is configured to switch between the first flow path (1) from the RO membrane 18 to the DI filter 19 and the second flow path (2) from the RO membrane 18 to the second drainage path 52. There is.
  • the flow path switching mechanism 35 switches to the first flow path (1) so that the water that has permeated the RO membrane 18 flows to the DI filter 19 during the purification operation, and the water that has permeated the RO membrane 18 when the purification operation is stopped.
  • the second flow path (2) is switched so as not to flow into the DI filter 19. Accordingly, the flow path switching mechanism 35 has the same function as a check valve or a solenoid valve.
  • the water purifier 1E according to the present embodiment can obtain the same effects as the water purifier 1 of the first embodiment and the water purifiers 1A and 1C of the second embodiment.
  • the channel switching mechanism 35 switches the concentrated water that permeates the RO membrane 18 by switching to the second channel (2) so that the water that has permeated the RO membrane 18 does not flow into the DI filter 19 when the purification operation is stopped. It can be discarded from the second drainage path 52.
  • concentrated water does not collect between the RO membrane 18 and the DI filter 19, so that when the purification operation is restarted, impurities contained in the initial water flowing from the RO membrane 18 to the DI filter 19 are removed. Therefore, the load on the DI filter 19 can be reduced.
  • the flow path switching mechanism 35 does not immediately switch from the second flow path (2) to the first flow path (1), but after the predetermined time has elapsed, the second flow path (2) is switched to the first flow path (1). It is preferable to switch to the channel (1).
  • the water that has accumulated in the vicinity of the RO membrane 18 without passing through the DI filter 19, especially the water on the rear side that has permeated the RO membrane 18 (the water whose impurity concentration has increased during the operation stop) ) Is discarded from the second channel (2).
  • the water appropriately purified by the RO membrane 18 can be sent to the DI filer 19. As a result, the life of the DI filter 19 can be further extended.
  • the concentrated water may be discarded as it is from the second drainage path 52
  • the second drainage path 52 is connected to the latter stage of the flush solenoid valve 22 of the first drainage path 51, for example, as in the water purifier 1F shown in FIG. 7. You may do it.
  • the concentrated water to be discarded can be collectively flowed in one path.
  • the second drainage path is connected to the latter stage of the flush electromagnetic valve 22 of the first drainage path 51, and the latter stage of the confluence of the first drainage path 51 and the second drainage path.
  • a solenoid valve 31 is provided as a new opening/closing mechanism linked with the cleaning operation. The solenoid valve 31 may open the first drainage path 51 during the purification operation and shut off the first drainage path 51 while the purification operation is stopped. In this case, the same effects as those of the water purifiers 1B and 1D of the second embodiment are achieved.
  • the DI filter 19 is arranged at the subsequent stage of the RO membrane 18.
  • the filter is not limited to the DI filter 19 and may be an AC (activated carbon) filter or any filter that can adsorb and remove other impurities.
  • the effect of the present invention is particularly exerted by the adsorption removal filter having a limited purification function.

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  • Engineering & Computer Science (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Environmental & Geological Engineering (AREA)
  • Organic Chemistry (AREA)
  • Nanotechnology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
  • Water Treatment By Sorption (AREA)
  • Treatment Of Water By Ion Exchange (AREA)

Abstract

The purpose of the present invention is to realize a water purification device capable of reducing consumption of an adsorption removal member and suppressing deterioration in the function. Provided is a water purification device (1) that purifies water by using an RO membrane (18) and a DI filter (19). In a water passage from the RO membrane (18) to the DI filter (19), an opening/closing mechanism (32) for blocking a water flow in the water passage is provided.

Description

浄水装置および家庭用浄水器Water purifier and household water purifier
 本発明は、浄水装置および家庭用浄水器に関する。 The present invention relates to a water purifier and a household water purifier.
 近年、逆浸透膜(RO膜)を用いた浄水装置が提案されている。 Recently, a water purification device using a reverse osmosis membrane (RO membrane) has been proposed.
 RO膜によって、水分子と不純物とを完全に分離することは非常に難しいため、更なる浄化を求める場合には、例えば特許文献1には、RO膜を用いた複数の浄化機構を備え、浄化を繰り返すことで純度を高める技術が開示されている。 Since it is very difficult to completely separate water molecules and impurities by the RO membrane, when further purification is required, for example, in Patent Document 1, a plurality of purification mechanisms using the RO membrane are provided and purification is performed. A technique for increasing the purity by repeating is disclosed.
 浄水の純度を高める為の新たな手段として、近年、イオン交換樹脂を用いる方法が採用されている。具体的には、通水用のケースにイオン交換樹脂を充填したフィルタ(以下、DIフィルタ)をRO膜の後段に配し、RO膜を透過した浄水をDIフィルタに通水して残った不純物を更に除去することで高い浄化性能を得ている(例えば特許文献2)。 ㆍIn recent years, a method using an ion exchange resin has been adopted as a new means for increasing the purity of purified water. Specifically, a filter (hereinafter referred to as a DI filter) in which a case for water flow is filled with an ion exchange resin is arranged in the latter stage of the RO membrane, and the purified water that has passed through the RO membrane is passed through the DI filter to leave impurities. High purification performance is obtained by further removing (for example, Patent Document 2).
日本国公開特許公報「特開2006-263542号公報」Japanese Patent Laid-Open Publication "JP 2006-263542 A" 日本国公開特許公報「特開2013-107031号公報」Japanese Patent Publication “JP 2013-107031”
 ところで、上述のDIフィルタを利用した浄水はRO膜を用いて浄化を繰り返す手法と比較して、その構造が簡便であるといった利点がある一方、DIフィルタの浄化機能には限界があり、一定量の不純物を除去するとその機能が失われてしまうという問題がある。このため、DIフィルタを用いた水の浄化では、その機能をより長く維持することが求められており、その性能の消費を抑えるための工夫が必要となっている。このことは、DIフィルタだけでなく、浄化機能に限界がある不純物の吸着除去を行う吸着除去部材一般に言える。 By the way, the above-mentioned purified water using the DI filter has an advantage that its structure is simple as compared with the method of repeating purification using an RO membrane, but the purification function of the DI filter is limited, and a certain amount of water is used. There is a problem in that the function is lost when the impurities in are removed. Therefore, in the purification of water using the DI filter, it is required to maintain its function for a longer period of time, and it is necessary to devise a means for suppressing the consumption of its performance. This can be said not only for the DI filter but also for an adsorption/removal member that generally adsorbs and removes impurities having a limited purification function.
 本発明の一態様は、RO膜と不純物の吸着除去を行う吸着除去部材とを併用する場合、吸着除去部材の消耗を少なくし、機能の低下を抑制し得る浄水装置を実現することを目的とする。 An aspect of the present invention is to realize a water purification apparatus that can reduce the consumption of the adsorption removal member and suppress the deterioration of the function when the RO membrane and the adsorption removal member that adsorbs and removes impurities are used together. To do.
 上記の課題を解決するために、本発明の一態様に係る浄水装置は、逆浸透膜と、不純物の吸着除去を行う吸着除去部材とを用いて水を浄化する浄水装置であって、上記逆浸透膜から、当該逆浸透膜によって浄化された浄水の取水口に至る経路上に、上記吸着除去部材が配され、上記逆浸透膜から上記吸着除去部材に至る通水経路上に、当該通水経路における水の往来を遮断する第1遮断機構が設けられていることを特徴としている。 In order to solve the above problems, a water purification device according to an aspect of the present invention is a water purification device that purifies water using a reverse osmosis membrane and an adsorption removal member that adsorbs and removes impurities, The adsorption/removal member is arranged on a path from the osmosis membrane to the intake of purified water purified by the reverse osmosis membrane, and the water passage is provided on a water passage from the reverse osmosis membrane to the adsorption/removal member. It is characterized in that a first blocking mechanism for blocking the passage of water in the route is provided.
 本発明の一態様によれば、吸着除去部材の消耗を少なくし、機能の低下を抑制し得る浄水装置を実現できる。 According to one aspect of the present invention, it is possible to realize a water purifier that can reduce the consumption of the adsorption/removal member and can suppress the deterioration of the function.
本発明の実施形態1に係る浄水装置の概略的な構成を示す模式図である。It is a schematic diagram which shows the schematic structure of the water purifier which concerns on Embodiment 1 of this invention. 本発明の実施形態2に係る浄水装置の概略的な構成を示す模式図である。It is a schematic diagram which shows the schematic structure of the water purifier which concerns on Embodiment 2 of this invention. 図2に示す浄水装置の変形例を示す模式図である。It is a schematic diagram which shows the modification of the water purifier shown in FIG. 本発明の実施形態3に係る浄水装置の概略的な構成を示す模式図である。It is a schematic diagram which shows the schematic structure of the water purifier which concerns on Embodiment 3 of this invention. 図4に示す浄水装置の変形例を示す模式図である。It is a schematic diagram which shows the modification of the water purifier shown in FIG. 本発明の実施形態4に係る浄水装置の概略的な構成を示す模式図である。It is a schematic diagram which shows the schematic structure of the water purifier which concerns on Embodiment 4 of this invention. 図6に示す浄水装置の変形例を示す模式図である。It is a schematic diagram which shows the modification of the water purifier shown in FIG. 図6に示す浄水装置の他の変形例を示す模式図である。It is a schematic diagram which shows the other modification of the water purifier shown in FIG.
 〔実施形態1〕
 以下、本発明の一実施形態について、詳細に説明する。
[Embodiment 1]
Hereinafter, one embodiment of the present invention will be described in detail.
 (浄水装置の構成)
 図1に示すように、浄水装置1は、逆浸透膜(RO膜)およびイオン交換樹脂を充填したフィルタ(DIフィルタ)を利用した生活用水の浄化装置である。この浄水装置1は、一端側の取込口50aより原水を取り込み、他端側の取出口50bより浄水を吐出する主経路(経路)50を備えている。浄水装置1が家庭用浄水器である場合、取込口50aは水道(原水)と接続され、取出口50bには蛇口等の取出口開閉機構が接続される。また、後述する第1排水経路(廃棄経路)51は、例えばシンク下の排水管に接続される。
(Structure of water purification device)
As shown in FIG. 1, the water purifier 1 is a household water purifier that uses a reverse osmosis membrane (RO membrane) and a filter (DI filter) filled with an ion exchange resin. The water purification device 1 includes a main path 50 that takes in raw water from an intake port 50a on one end side and discharges purified water from an intake port 50b on the other end side. When the water purifier 1 is a household water purifier, the intake port 50a is connected to tap water (raw water), and the extraction port 50b is connected to an outlet opening/closing mechanism such as a faucet. A first drainage path (discarding path) 51 described later is connected to, for example, a drainage pipe under a sink.
 主経路50の最上流側から順に、圧力スイッチ10、電磁弁31、減圧弁11、PP(ポリプロピレン)フィルタ12、前側TDS13、水温計14、前側流量計15、AC(活性炭)フィルタ16、Pump17、RO膜(逆浸透膜)18、開閉機構(第1遮断機構)32、DIフィルタ(不純物吸着除去部材)19、後側流量計20、および後側TDS21が配置されている。 A pressure switch 10, a solenoid valve 31, a pressure reducing valve 11, a PP (polypropylene) filter 12, a front TDS 13, a water temperature meter 14, a front flow meter 15, an AC (activated carbon) filter 16, a Pump 17, in order from the most upstream side of the main path 50. An RO membrane (reverse osmosis membrane) 18, an opening/closing mechanism (first blocking mechanism) 32, a DI filter (impurity adsorption/removal member) 19, a rear flow meter 20, and a rear TDS 21 are arranged.
 圧力スイッチ10は、一定圧力以上でオンするスイッチであり、主経路50に原水が供給され、原水の圧(水道圧)が検出できる場合にオンする。減圧弁11は、主経路50を流れる水道水の水圧を一定にする。 The pressure switch 10 is a switch that turns on at a certain pressure or higher, and turns on when raw water is supplied to the main path 50 and the pressure of the raw water (tap water pressure) can be detected. The pressure reducing valve 11 keeps the water pressure of the tap water flowing through the main path 50 constant.
 PP(ポリプロピレン)フィルタ12は、ポリプロピレン(PP)からなる比較的目の粗い不織布であり、原水に含まれる錆などの比較的大きな不純物を除去する。なお、材質は限定されず、ポリエチレン(PE)よりなるものであってもよい。比較的大きな不純物を到達前に除去しておくことで、後述する逆浸透膜(以下、RO膜)の劣化を抑制することができる。 The PP (polypropylene) filter 12 is a relatively coarse non-woven fabric made of polypropylene (PP) and removes relatively large impurities such as rust contained in raw water. The material is not limited and may be polyethylene (PE). By removing the relatively large impurities before reaching them, it is possible to suppress the deterioration of the reverse osmosis membrane (hereinafter, RO membrane) described later.
 前側TDS13および後側TDS21は、水質を示す指標を測る水質センサであり、水の電気伝導率を測って水の不純物の濃度を検出する。前側TDS13は、取込口50aより取り込まれた原水の水質を測定し、後側TDS21は、取出口50bより取り出される浄水の水質を測定する。これらの測定結果は、図示しない制御部に送信され、制御部は、前側TDS13の測定値と後側TDS21の測定値から浄化率を算出する。 The front-side TDS 13 and the rear-side TDS 21 are water quality sensors that measure indicators of water quality, and measure the electrical conductivity of water to detect the concentration of impurities in the water. The front TDS 13 measures the water quality of the raw water taken in through the intake port 50a, and the rear TDS 21 measures the water quality of the purified water taken out through the intake port 50b. These measurement results are transmitted to a control unit (not shown), and the control unit calculates the purification rate from the measured values of the front TDS 13 and the rear TDS 21.
 水温計14は、前側TDS13および後側TDS21の較正に用いられる。前側TDS13および後側TDS21が測定する電気伝導率は、温度依存性を有しているためである。検出結果は制御部に出力される。 The water temperature gauge 14 is used for calibration of the front TDS 13 and the rear TDS 21. This is because the electric conductivity measured by the front TDS 13 and the rear TDS 21 has temperature dependence. The detection result is output to the control unit.
 ACフィルタ16は、原水に含まれる遊離塩素化合物などの遊離物を活性炭にて除去する。なお、RO膜18は、原水となる水道水に含まれる遊離塩素化合物(いわゆる塩素)で劣化する。このため、到達前にACフィルタ16で遊離塩素化合物を除いておくことで、RO膜18の劣化を抑制することができる。 The AC filter 16 removes free substances such as free chlorine compounds contained in raw water with activated carbon. The RO film 18 is deteriorated by the free chlorine compound (so-called chlorine) contained in the tap water that is the raw water. Therefore, by removing the free chlorine compound with the AC filter 16 before reaching, the deterioration of the RO film 18 can be suppressed.
 Pump17は、所定の圧力を掛けながら水を後段のRO膜18に送るためのものであり、後述するRO膜18によるクロスフロー方式を実現するために用いられる。 The Pump 17 is for sending water to the RO membrane 18 in the subsequent stage while applying a predetermined pressure, and is used to realize a cross flow method using the RO membrane 18 described later.
 前側流量計15および後側流量計20は、主経路50に流れる水の流量を測るセンサである。測定結果は、制御部に出力され、制御部は、前側流量計15の測定値である原水の取込量(使用量)と後側流量計20の測定値である浄水の生成量とから、回収率を算出する。 The front flow meter 15 and the rear flow meter 20 are sensors that measure the flow rate of water flowing through the main path 50. The measurement result is output to the control unit, and the control unit calculates the raw water intake amount (use amount), which is the measurement value of the front flow meter 15, and the purified water generation amount, which is the measurement value of the rear flow meter 20, Calculate the recovery rate.
 前側流量計15の配置位置としては、図1に示すように、前側流量計15をPPフィルタ12とACフィルタ16との間とすることが好ましい。これは、PPフィルタ12の後段(下流側)に配置することで、前側流量計15への汚れの付着を防止することができるためである。 The front flow meter 15 is preferably arranged between the PP filter 12 and the AC filter 16 as the arrangement position of the front flow meter 15, as shown in FIG. This is because by arranging the PP filter 12 at the subsequent stage (downstream side), it is possible to prevent the adhesion of dirt to the front flow meter 15.
 なお、上述した減圧弁11、PPフィルタ12、前側TDS13、水温計14、ACフィルタ16、後側流量計20、および後側TDS21は、必要に応じて備えられていればよい。 The pressure reducing valve 11, the PP filter 12, the front TDS 13, the water temperature meter 14, the AC filter 16, the rear flow meter 20, and the rear TDS 21 described above may be provided as necessary.
 RO膜18は、水分子と不純物とを分離する。ここでは、Pump17によって水圧を掛けながらRO膜18の表面に浄化対象水を流すことによって、当該RO膜18を透過した処理水と、透過しなかった排水とに分離する。所謂クロスフロー方式によりRO膜18が処理水(浄水)と排水(濃縮水)とに分離している。 RO membrane 18 separates water molecules and impurities. Here, the purification target water is caused to flow on the surface of the RO membrane 18 while applying water pressure by the Pump 17, thereby separating the treated water that has permeated the RO membrane 18 and the wastewater that has not permeated. The RO membrane 18 is separated into treated water (purified water) and waste water (concentrated water) by a so-called cross flow method.
 処理水は、主経路50を流れRO膜18の後段のDIフィルタ19に流され、排水は、第1排水経路51の廃棄口から排出される。廃棄口は、上述したように、例えばシンク下の排水管に接続される。 The treated water flows through the main path 50 and flows into the DI filter 19 in the latter stage of the RO membrane 18, and the waste water is discharged from the waste port of the first drain path 51. As described above, the waste port is connected to, for example, the drain pipe under the sink.
 第1排水経路51にはフラッシュ電磁弁22が設けられている。フラッシュ電磁弁22は、第1排水経路51に流れる排水の流量を制限する流量制限弁である。例えばフラッシュ電磁弁22は、閉じた状態(電源オフ状態(非通電時))では流量を制限し、開けた状態(電源オン状態(通電時))では可能な限り流路を解放して水を流すように機能する。 A flash solenoid valve 22 is provided in the first drainage path 51. The flash solenoid valve 22 is a flow rate limiting valve that limits the flow rate of the wastewater flowing through the first drainage path 51. For example, the flush solenoid valve 22 limits the flow rate in the closed state (power-off state (non-energized)) and opens the flow path as much as possible in the open state (power-on state (energized)) to allow water to flow. It functions to flush.
 (RO膜18による浄化)
 RO膜18によれば、有害・無害を問わず水に溶解しているほぼ全ての不純物を取り除いて高純度の純水が得られる。RO膜18は、架橋による網の目状の高分子膜でできており、この網の目の大きさによって、基本的には水分子のみがこの高分子膜を透過することから、不純物との分離が行われ、先述の浄化性能を得ることができている。
(Purification by RO film 18)
The RO film 18 removes almost all impurities dissolved in water, both harmful and harmless, to obtain pure water of high purity. The RO film 18 is made of a network-like polymer film formed by cross-linking, and basically only water molecules permeate the polymer film due to the size of the network, so that the RO film 18 may not be mixed with impurities. The separation is performed and the above-mentioned purification performance can be obtained.
 クロスフロー方式は、一定の水圧を掛けながらRO膜18の表面上に浄化対象の水を通液し、この際、水圧によりRO膜18を透過した水を浄水として取り出し、RO膜18を透過せず残った方の水を排水として廃棄する方式である。従って、クロスフロー方式は、常時、RO膜18の表面を通液させることで不純物と水分子との分離を行う。排水側の水は、RO膜18の表面上を流れていく過程で、水分子のみがRO膜18を透過して失われてゆく為、RO膜18の表面上を通水される前と比較して相対的に不純物が濃縮され、濃度が上がった状態となって廃棄される。このように、RO膜18を利用した浄水においては一定量の排水(濃縮水)を伴う。 In the cross-flow method, water to be purified is passed over the surface of the RO membrane 18 while applying a constant water pressure, and at this time, the water that has passed through the RO membrane 18 due to water pressure is taken out as purified water and passed through the RO membrane 18. The remaining water is discarded as waste water. Therefore, in the cross-flow method, impurities are separated from water molecules by constantly passing the surface of the RO film 18. In the process of flowing water on the surface of the RO film 18, only water molecules permeate through the RO film 18 to be lost in the water on the drainage side. Then, the impurities are relatively concentrated and the concentration is increased, and the product is discarded. As described above, the purified water using the RO membrane 18 is accompanied by a certain amount of waste water (concentrated water).
 ここで、水圧を掛けながらRO膜18表面上を通水する為に、RO膜18の前段に配したPump17(電動ポンプ)と、RO膜18の後段となる第1排水経路51上に配した流量制限機構としてのフラッシュ電磁弁22が用いられる。Pump17が送液する水量に対してRO膜18の後段で流量を制限することで、Pump17からRO膜18表面を通じフラッシュ電磁弁22に至るまでの経路内がPump17の力を借りて増圧される。この圧力が高くなる程、RO膜18を透過する浄化水の水量も増加することから、実際には、これらのバランスを考慮して、目的の圧力および浄化水が得られるよう、Pump17の送液性能と流量制限量とを定める。 Here, in order to pass water on the surface of the RO membrane 18 while applying water pressure, it was arranged on the Pump 17 (electric pump) arranged in the front stage of the RO membrane 18 and in the first drainage path 51 which is the rear stage of the RO membrane 18. A flash solenoid valve 22 is used as a flow rate limiting mechanism. By limiting the flow rate in the latter stage of the RO film 18 with respect to the amount of water pumped by the Pump 17, the inside of the path from the Pump 17 through the surface of the RO film 18 to the flash solenoid valve 22 is boosted by the power of the Pump 17. .. As the pressure increases, the amount of purified water that permeates the RO membrane 18 also increases. Therefore, in consideration of these balances, the pump 17 is pumped so as to obtain the desired pressure and purified water. Determine performance and flow restriction.
 そして、フラッシュ電磁弁22は、上述したように、閉じた状態では先述のように流量を制限し、開けた状態では可能な限り流路を解放して水を流すといった機能を備えている。これにより、RO膜18表面上に圧力を掛けて浄水を生成する機能に加え、必要に応じて大量の通水を行ってRO膜18の表面上を洗い流すという2つの機能を電気的に切り替える。 As described above, the flush solenoid valve 22 has a function of limiting the flow rate in the closed state as described above and opening the flow path as much as possible to allow water to flow in the open state. As a result, in addition to the function of applying pressure on the surface of the RO membrane 18 to generate purified water, a large amount of water is passed as necessary to wash away the surface of the RO membrane 18 electrically.
 また、先述のようにRO膜18は微細な構造を有する事から、この性能を維持することを目的として、浄化対象の水の前処理を行うことが一般となっている。例えば、PP(ポリプロピレン)やPE(ポリエチレン)等の繊維を主材料としたフィルタ(セディメントフィルタ等と呼ばれる:PPフィルタ12)による、堆積物や微粒子、粘着物質等の除去、活性炭を主材料としたフィルタ(ACフィルタ16)による、水道の殺菌処理等で用いられる塩素や有機物質等の吸着除去がこれにあたる。 Further, as described above, since the RO film 18 has a fine structure, it is common to perform pretreatment of water to be purified for the purpose of maintaining this performance. For example, a filter (referred to as a sediment filter or the like: PP filter 12) mainly made of fibers such as PP (polypropylene) and PE (polyethylene) is used to remove deposits, fine particles, sticky substances, etc., and activated carbon as the main material. This is the adsorption and removal of chlorine, organic substances and the like used in the sterilization treatment of water supply by the filter (AC filter 16).
 (DIフィルタ19による浄化)
 DIフィルタ19は、通水用のケースにイオン交換樹脂を充填したフィルタである。イオン交換樹脂としては、水の浄化には不純物の成分となる陽イオンと陰イオンの両方を除去する機能を有したものを利用することが好ましい。すなわち、DIフィルタ19では、陽イオンを水素イオンに、陰イオンを水酸化物イオンにそれぞれ交換され、放出された水素イオンと水酸化物イオンが水中で中和して水に戻ることで、水の浄化がなされる。従って、DIフィルタ19は、RO膜18により浄化された水に含まれる不純物を吸着除去する不純物吸着除去部材とも言える。
(Purification with DI filter 19)
The DI filter 19 is a filter in which a case for water flow is filled with an ion exchange resin. As the ion exchange resin, it is preferable to use a resin having a function of removing both cations and anions that are components of impurities for purification of water. That is, in the DI filter 19, cations are exchanged for hydrogen ions and anions are exchanged for hydroxide ions, and the released hydrogen ions and hydroxide ions are neutralized in water to return to water. Is purified. Therefore, the DI filter 19 can be said to be an impurity adsorption/removal member that adsorbs and removes the impurities contained in the water purified by the RO film 18.
 (開閉機構32の機能および効果)
 開閉機構32は、RO膜18とDIフィルタ19とを繋ぐ経路(主経路50)の途上に設けられており、水に溶解している不純物の拡散を遮断する機構である。この場合、開閉機構32は、浄化運転時には主経路50を開放して通水可能な状態とし、浄化運転停止時には主経路50を遮断して当該開閉機構32を挟んだ水の行き来を遮断する。
(Function and effect of opening/closing mechanism 32)
The opening/closing mechanism 32 is provided along the path (main path 50) that connects the RO film 18 and the DI filter 19, and is a mechanism that blocks the diffusion of impurities dissolved in water. In this case, the opening/closing mechanism 32 opens the main path 50 during the cleaning operation to allow water to pass therethrough, and shuts off the main path 50 when the cleaning operation is stopped to cut off water coming and going across the opening/closing mechanism 32.
 これにより、浄化運転を停止している期間に、DIフィルタ19が除去する不純物の総量が抑制され、不要な浄化性能の消費を防止することにより、DIフィルタ19の浄化機能をより長く利用することができる。 As a result, the total amount of impurities removed by the DI filter 19 is suppressed while the purification operation is stopped, and unnecessary purification performance is prevented from being consumed, so that the purification function of the DI filter 19 is used for a longer period of time. You can
 通常、水の浄化運転を継続して実施している場合には、浄化された水と不純物が濃縮された排水とがRO膜18を挟んで分離されており、DIフィルタ19には不純物の少ないRO膜18による浄化水のみが供給されている。しかしながら、浄化運転を停止して浄水装置1内の通水が行われなくなると、RO膜18を透過する前段の領域に残された水中に含まれる不純物が、RO膜18を通過した浄水側にある水の中に、当該RO膜18を透過して時間と共に拡散するといった現象が生じる。そこで、上記のような経路の遮断機構(開閉機構32)を設けなかった場合には、このようにしてRO膜18を透過した不純物は次第にDIフィルタ19まで拡散し、当該DIフィルタ19内のイオン交換樹脂によって浄化される。この現象は、RO膜18を挟んだ水の中の不純物濃度が等しくなるまで続く為、最終的にはRO膜18の手前側の全ての領域に滞留している水の不純物がDIフィルタ19によって浄化されるまで継続されることとなる。このため、本来、RO膜18による濃縮水として廃棄されるべき不純物までDIフィルタ19で浄化することなり、DIフィルタ19の浄化性能が多大に消費されて無駄となってしまう。従って、上述したように、RO膜18とDIフィルタ19とを繋ぐ経路上に、水に溶解している不純物の拡散を遮断する為の開閉機構32を設けることで、上記のような物質拡散に伴う不純物がDIフィルタ19に至ることを防止することができる。 Normally, when the water purification operation is continuously performed, the purified water and the wastewater in which the impurities are concentrated are separated with the RO membrane 18 interposed therebetween, and the DI filter 19 contains few impurities. Only purified water from the RO membrane 18 is supplied. However, when the purifying operation is stopped and the water in the water purifier 1 is no longer supplied, the impurities contained in the water left in the front-stage region that permeates the RO membrane 18 are transferred to the purified water side that has passed through the RO membrane 18. A phenomenon occurs in which a certain water permeates the RO film 18 and diffuses with time. Therefore, if the path blocking mechanism (opening/closing mechanism 32) as described above is not provided, the impurities thus permeated through the RO film 18 gradually diffuse to the DI filter 19, and the ions in the DI filter 19 are diffused. Purified by exchange resin. Since this phenomenon continues until the concentration of impurities in the water sandwiching the RO film 18 becomes equal, finally the impurities of water staying in all regions on the front side of the RO film 18 are absorbed by the DI filter 19. It will be continued until it is purified. Therefore, the impurities that should originally be discarded as concentrated water by the RO membrane 18 are also purified by the DI filter 19, and the purification performance of the DI filter 19 is greatly consumed and wasted. Therefore, as described above, by providing the opening/closing mechanism 32 for blocking the diffusion of impurities dissolved in water on the path connecting the RO film 18 and the DI filter 19, the above-mentioned substance diffusion can be achieved. It is possible to prevent the accompanying impurities from reaching the DI filter 19.
 なお、上記のようにRO膜18を挟んだ不純物の物質拡散の拡散範囲を極力狭くして浄化運転再開時にDIフィルタ19が浄化する不純物量を少なくするために、開閉機構32は出来る限りRO膜18に近いところに設置するのが望ましい。 As described above, in order to narrow the diffusion range of the substance diffusion of the impurities sandwiching the RO film 18 as much as possible to reduce the amount of impurities to be purified by the DI filter 19 when the purification operation is restarted, the opening/closing mechanism 32 is as close as possible to the RO film. It is desirable to install it near 18.
 (効果)
 上記構成によれば、浄化運転停止時に、RO膜18から染み出た不純物の拡散を開閉機構32によって抑制することができる。これにより、DIフィルタ19に到達する不純物が少なく、浄化運転停止時における不要な不純物の除去を行わなくて済むので、当該DIフィルタ19の劣化の抑制、すなわち長寿命化を図ることができる。すなわち、浄水装置1によれば、RO膜18で浄化した後、さらにDIフィルタ19で浄化を行う浄化機構において、そのDIフィルタ19の不要な浄化性能の消費を防止して、機能寿命を長く維持することができる。
(effect)
According to the above configuration, when the cleaning operation is stopped, the diffusion of impurities that have exuded from the RO film 18 can be suppressed by the opening/closing mechanism 32. As a result, the amount of impurities that reach the DI filter 19 is small, and unnecessary impurities need not be removed when the purification operation is stopped. Therefore, deterioration of the DI filter 19 can be suppressed, that is, the life of the DI filter 19 can be extended. That is, according to the water purifier 1, in the purification mechanism that performs purification by the DI filter 19 after purification by the RO membrane 18, consumption of unnecessary purification performance of the DI filter 19 is prevented, and the functional life is maintained long. can do.
 また、開閉機構32を出来る限りRO膜18に近いところ(直後の位置)に設置すれば、浄化運転停止時におけるRO膜18付近に漂う濃縮水の拡散をDIフィルタ19にできるだけ及ばないようにすることができる。これにより、よりDIフィルタ19の機能寿命を長くすることができる。 Also, if the opening/closing mechanism 32 is installed as close to the RO membrane 18 as possible (immediately after the RO membrane 18), diffusion of concentrated water drifting near the RO membrane 18 when the purification operation is stopped is prevented from reaching the DI filter 19 as much as possible. be able to. As a result, the functional life of the DI filter 19 can be extended.
 なお、本実施形態において、RO膜18とDIフィルタ19との間を繋ぐ途上に設けた開閉機構32は、無電力で開閉するもの(例えば手動開閉機構(バルブ)、逆止弁)であってもよいし、電力で開閉するもの(例えば電磁弁等)であてもよい。 In the present embodiment, the opening/closing mechanism 32 provided on the way of connecting the RO membrane 18 and the DI filter 19 is one that opens and closes without power (for example, a manual opening/closing mechanism (valve), a check valve). Alternatively, it may be one that opens and closes with electric power (for example, a solenoid valve).
 〔実施形態2〕
 本発明の他の実施形態について、以下に説明する。なお、説明の便宜上、上記実施形態にて説明した部材と同じ機能を有する部材については、同じ符号を付記し、その説明を繰り返さない。
[Embodiment 2]
Another embodiment of the present invention will be described below. For convenience of description, members having the same functions as the members described in the above embodiment are designated by the same reference numerals, and the description thereof will not be repeated.
 (浄水装置の構成)
 図2に示すように、本実施形態にかかる浄水装置1Aは、前記実施形態1の浄水装置1と異なり、RO膜18とDIフィルタ19との間の開閉機構32の代わりに、順方向(ここでは、取出口50b側)にのみ通水可能な逆止弁33を用いている。浄水装置1Aは、開閉機構32の代わりに逆止弁33を用いる以外は、前記実施形態1の浄水装置1と同じ構成である。
(Structure of water purification device)
As shown in FIG. 2, the water purifier 1A according to the present embodiment is different from the water purifier 1 of the first embodiment in that a forward direction (here, instead of the opening/closing mechanism 32 between the RO membrane 18 and the DI filter 19) is used. In this case, the check valve 33 that allows water to pass only to the outlet 50b side is used. The water purifier 1A has the same configuration as the water purifier 1 of the first embodiment except that a check valve 33 is used instead of the opening/closing mechanism 32.
 (効果)
 開閉機構32として逆止弁33を用いた場合、浄化運転が行われている期間中は、その順方向の水圧により弁が開いて通水が行われる。しかしながら、運転停止中には水圧が失われて弁が閉じる為に、これを挟んでの不純物の拡散を遮断することができると共に、開閉機構の動作を浄化運転と自動的に連動できるという利便性が生まれる。
(effect)
When the check valve 33 is used as the opening/closing mechanism 32, the valve is opened by water pressure in the forward direction to allow water to pass during the period during which the purification operation is performed. However, since the water pressure is lost and the valve closes while the operation is stopped, it is possible to block the diffusion of impurities with the water pressure in between, and the operation of the opening/closing mechanism can be automatically linked with the purification operation. Is born.
 しかも、逆止弁33は無電力で動作するため、停電時にも作動する。また、電磁弁のように高価でないため、安価に浄水装置1Aを作ることができる。 Moreover, since the check valve 33 operates without power, it operates even during a power failure. Moreover, since it is not expensive like a solenoid valve, the water purifier 1A can be manufactured at low cost.
 〔変形例〕
 図3に示すように、本変形例にかかる浄水装置1Bは、図2に示す浄水装置1Aにおいて圧力スイッチ10と減圧弁11との間に配置された電磁弁(第2遮断機構)31をフラッシュ電磁弁22の下流側に配置した例を示している。なお、浄水装置1Bでは、主経路50の取出口50bに、当該取出口50bを開閉するための開閉機構の一種として蛇口が設けられている。この場合、蛇口を開ける動作によって、浄水装置1の電源をオンし、蛇口を閉める動作によって、浄水装置1の電源をオフするようにする。
[Modification]
As shown in FIG. 3, the water purification apparatus 1B according to the present modification flushes the electromagnetic valve (second shutoff mechanism) 31 arranged between the pressure switch 10 and the pressure reducing valve 11 in the water purification apparatus 1A shown in FIG. An example is shown in which the solenoid valve 22 is arranged on the downstream side. In the water purifier 1B, the outlet 50b of the main path 50 is provided with a faucet as a kind of opening/closing mechanism for opening and closing the outlet 50b. In this case, the power of the water purifier 1 is turned on by the operation of opening the faucet, and the power of the water purifier 1 is turned off by the operation of closing the faucet.
 従って、蛇口を閉じることで浄化運転を停止させることが可能となる。これにより、浄化運転停止時において、電磁弁31をオフ状態にして第1排水経路51を閉じることができるので、フラッシュ電磁弁22から流れる濃縮水は廃棄されない。しかも、浄化運転停止時において、主経路50の取出口50bに設けられた蛇口が閉じているため、逆止弁33とオフ状態の電磁弁31とによってRO膜18付近の圧力が維持されることになる。これにより、浄化運転再開時には、タイムラグ無く浄水を取り出すことが可能となる。つまり、逆止弁33に加えて、取出口50bに取出口開閉機構の一種である蛇口を設け、この蛇口の開閉を浄化運転に連動させる。これにより、浄化運転再開時にタイムラグ無く浄水を取り出すことが可能となるという効果に加えて、浄化運転の停止と合わせて、直ちに浄水の吐出を止めることができるという効果も奏する。 Therefore, it is possible to stop the purification operation by closing the faucet. Thereby, when the purification operation is stopped, the electromagnetic valve 31 can be turned off and the first drainage path 51 can be closed, so that the concentrated water flowing from the flush electromagnetic valve 22 is not discarded. Moreover, since the faucet provided at the outlet 50b of the main path 50 is closed when the cleaning operation is stopped, the pressure near the RO membrane 18 is maintained by the check valve 33 and the solenoid valve 31 in the off state. become. As a result, when the purification operation is restarted, it becomes possible to take out purified water without a time lag. That is, in addition to the check valve 33, the outlet 50b is provided with a faucet which is a kind of an outlet opening/closing mechanism, and the opening/closing of the faucet is linked to the cleaning operation. As a result, in addition to the effect that the purified water can be taken out without a time lag when the purification operation is restarted, there is an effect that the discharge of the purified water can be immediately stopped when the purification operation is stopped.
 なお、電磁弁31は、RO膜18とフラッシュ電磁弁22の間に配置してもよい。この場合も、電磁弁31をフラッシュ電磁弁22の下流側に配置した場合と同様の効果を得ることができる。 The solenoid valve 31 may be arranged between the RO membrane 18 and the flash solenoid valve 22. Also in this case, the same effect as when the solenoid valve 31 is arranged on the downstream side of the flash solenoid valve 22 can be obtained.
 なお、図2に示す浄水装置1Aの逆止弁33を、浄化運転と連動した開閉機構として電磁弁を用いてよい。例えば、図4に示す浄水装置1Cに示すように、RO膜18とDIフィルタ19との間に電磁弁34を設けてもよい。 Note that the check valve 33 of the water purifying apparatus 1A shown in FIG. 2 may be an electromagnetic valve as an opening/closing mechanism linked with the purification operation. For example, as shown in the water purifier 1C shown in FIG. 4, an electromagnetic valve 34 may be provided between the RO membrane 18 and the DI filter 19.
 同様に、図3に示す浄水装置1Bの逆止弁33を、図5に示す浄水装置1Dに示すように、電磁弁34に置き換えてもよい。 Similarly, the check valve 33 of the water purifier 1B shown in FIG. 3 may be replaced with a solenoid valve 34 as shown in the water purifier 1D shown in FIG.
 電磁弁34は、浄化運転時にはオン状態となり、主経路50を開いてRO膜18からDIフィルタ19に水を流すようにし、浄化運転停止時にはオフ状態となり、主経路50を閉じてRO膜18からDIフィルタ19に水が流れないようにする。つまり、電磁弁34は、浄化運転停止に連動して通水路を遮断し、浄化運転再開時に連動して通水路を開放する。 The solenoid valve 34 is turned on during the cleaning operation, opens the main path 50 to allow water to flow from the RO membrane 18 to the DI filter 19, is turned off when the cleaning operation is stopped, and closes the main path 50 from the RO membrane 18. Prevent water from flowing through the DI filter 19. That is, the solenoid valve 34 shuts off the water passage in association with the stop of the purification operation, and opens the water passage in association with the restart of the purification operation.
 なお、図5に示す浄水装置1Dでは、浄化運転停止時に連動して電磁弁34がオフ状態となるので、図3に示す浄水装置1Bのように取出口50bに蛇口を設けなくても、浄化運転停止時に圧力を維持することができる。 In the water purifier 1D shown in FIG. 5, the solenoid valve 34 is turned off in conjunction with the stoppage of the purifying operation, so that the purification is possible without providing the tap 50b unlike the water purifier 1B shown in FIG. The pressure can be maintained during shutdown.
 つまり、逆止弁33の場合は経路内の水圧が失われるまで順方向の通水が継続してしまうことから、浄化運転の停止と共に浄水の吐出を時差なく止める為には、取水口に蛇口などを設け、その開栓機構と浄化運転とを連動させる必要があるためである。 That is, in the case of the check valve 33, forward water flow continues until the water pressure in the path is lost. Therefore, in order to stop the purifying operation without stopping the purifying water discharge at the same time as the purifying operation is stopped, It is because it is necessary to interlock the opening mechanism with the purifying operation.
 さらに、図3に示す浄水装置1B、或いは、図5に示す浄水装置1Dに示すように、浄化運転と連動する新たな開閉機構としての電磁弁31を、RO膜18の後段となる第1排水経路51上に設け、浄化運転中には第1排水経路51を開放し、浄化運転停止中には第1排水経路51を遮断する構成にしても良い。これにより、先述の効果に加えて、例えば水道水のように常時水圧の掛かった水を原水とする場合には、浄化運転停止時に当該第1排水経路51を通じて水が常時廃棄されることを防止すると共に、運転再開時の浄水の吐出を時間差なく即座に行うことができる。これは、浄化運転停止時に電磁弁31を閉じることで第1排水経路51内の水圧が維持されることによる。 Further, as shown in the water purifying apparatus 1B shown in FIG. 3 or the water purifying apparatus 1D shown in FIG. 5, the electromagnetic valve 31 as a new opening/closing mechanism that is linked with the purifying operation is provided in the first drainage which is the latter stage of the RO membrane 18. The first drainage path 51 may be provided on the path 51 and opened during the purification operation, and the first drainage path 51 may be shut off during the purification operation stop. With this, in addition to the effects described above, when water that is constantly under pressure, such as tap water, is used as raw water, it is prevented that the water is always discarded through the first drainage route 51 when the purification operation is stopped. At the same time, the purified water can be immediately discharged when the operation is restarted without any time difference. This is because the water pressure in the first drainage path 51 is maintained by closing the solenoid valve 31 when the purification operation is stopped.
 なお、前記実施形態1,2では、RO膜18とDIフィルタ19との間に設けた開閉機構として、逆止弁、電磁弁を用いた例について説明したが、下記の実施形態3では、流路を切替える流路切替機構を用いた例について説明する。 In the first and second embodiments, an example in which a check valve and a solenoid valve are used as the opening/closing mechanism provided between the RO membrane 18 and the DI filter 19 has been described. An example using a flow path switching mechanism for switching the path will be described.
 〔実施形態3〕
 本発明の他の実施形態について、以下に説明する。なお、説明の便宜上、上記実施形態にて説明した部材と同じ機能を有する部材については、同じ符号を付記し、その説明を繰り返さない。
[Embodiment 3]
Another embodiment of the present invention will be described below. For convenience of description, members having the same functions as the members described in the above embodiment are designated by the same reference numerals, and the description thereof will not be repeated.
 (浄水装置の構成)
 図6に示すように、本実施形態にかかる浄水装置1Eは、前記実施形態1の浄水装置1と異なり、RO膜18とDIフィルタ19との間の開閉機構32の代わりに流路切替機構35を用いている。浄水装置1Eは、開閉機構32の代わりに流路切替機構35を用いる以外は、前記実施形態1の浄水装置1と同じ構成である。
(Structure of water purification device)
As shown in FIG. 6, the water purifier 1E according to the present embodiment is different from the water purifier 1 of the first embodiment, in place of the opening/closing mechanism 32 between the RO membrane 18 and the DI filter 19, the flow path switching mechanism 35. Is used. The water purifier 1E has the same configuration as the water purifier 1 of the first embodiment except that the flow path switching mechanism 35 is used instead of the opening/closing mechanism 32.
 流路切替機構35は、RO膜18からDIフィルタ19に至る第1流路(1)と、RO膜18から第2排水経路52に至る第2流路(2)とを切替えるようになっている。ここで、流路切替機構35は、浄化運転時にはRO膜18を透過した水がDIフィルタ19に流れるように第1流路(1)に切替え、浄化運転停止時にはRO膜18を透過した水がDIフィルタ19に流れ込まないように第2流路(2)に切替える。これにより、流路切替機構35は、逆止弁や電磁弁と同様の機能を奏する。 The flow path switching mechanism 35 is configured to switch between the first flow path (1) from the RO membrane 18 to the DI filter 19 and the second flow path (2) from the RO membrane 18 to the second drainage path 52. There is. Here, the flow path switching mechanism 35 switches to the first flow path (1) so that the water that has permeated the RO membrane 18 flows to the DI filter 19 during the purification operation, and the water that has permeated the RO membrane 18 when the purification operation is stopped. The second flow path (2) is switched so as not to flow into the DI filter 19. Accordingly, the flow path switching mechanism 35 has the same function as a check valve or a solenoid valve.
 従って、本実施形態にかかる浄水装置1Eは、前記実施形態1の浄水装置1、前記実施形態2の浄水装置1A、1Cと同じ効果を得ることができる。 Therefore, the water purifier 1E according to the present embodiment can obtain the same effects as the water purifier 1 of the first embodiment and the water purifiers 1A and 1C of the second embodiment.
 しかも、流路切替機構35は、浄化運転停止時にはRO膜18を透過した水がDIフィルタ19に流れ込まないように第2流路(2)に切替えることで、RO膜18を透過する濃縮水を第2排水経路52から廃棄することができる。これにより、浄化運転停止時に、RO膜18とDIフィルタ19との間で濃縮水が溜ることがないので、浄化運転再開時には、RO膜18からDIフィルタ19に流れる初期の水に含まれる不純物が少なく、当該DIフィルタ19への負担を軽減することができる。 Moreover, the channel switching mechanism 35 switches the concentrated water that permeates the RO membrane 18 by switching to the second channel (2) so that the water that has permeated the RO membrane 18 does not flow into the DI filter 19 when the purification operation is stopped. It can be discarded from the second drainage path 52. As a result, when the purification operation is stopped, concentrated water does not collect between the RO membrane 18 and the DI filter 19, so that when the purification operation is restarted, impurities contained in the initial water flowing from the RO membrane 18 to the DI filter 19 are removed. Therefore, the load on the DI filter 19 can be reduced.
 なお、浄化運転再開時に、流路切替機構35によって第2流路(2)から第1流路(1)に直ぐに切替えるのではなく、所定の時間経過後に第2流路(2)から第1流路(1)に切替えることが好ましい。この場合、浄化運転再開時に、DIフィルタ19に通水することなく、RO膜18近傍に滞留した水、とりわけ、RO膜18を透過した後段側の水(運転停止中に不純物濃度が上がった水)を第2流路(2)から廃棄する。その後、第1流路(1)に切替えることで、適正にRO膜18で浄化された水をDIファイルタ19に送ることができる。これにより、DIフィルタ19の更なる長寿命化を図ることができる。 It should be noted that when the purification operation is restarted, the flow path switching mechanism 35 does not immediately switch from the second flow path (2) to the first flow path (1), but after the predetermined time has elapsed, the second flow path (2) is switched to the first flow path (1). It is preferable to switch to the channel (1). In this case, when the purification operation is restarted, the water that has accumulated in the vicinity of the RO membrane 18 without passing through the DI filter 19, especially the water on the rear side that has permeated the RO membrane 18 (the water whose impurity concentration has increased during the operation stop) ) Is discarded from the second channel (2). Then, by switching to the first flow path (1), the water appropriately purified by the RO membrane 18 can be sent to the DI filer 19. As a result, the life of the DI filter 19 can be further extended.
 第2排水経路52から濃縮水をそのまま廃棄してもよいが、例えば図7に示す浄水装置1Fのように、第2排水経路52を第1排水経路51のフラッシュ電磁弁22の後段に接続するようにしてもよい。この場合、廃棄すべき濃縮水を一本の経路にまとめて流すことができる。 Although the concentrated water may be discarded as it is from the second drainage path 52, the second drainage path 52 is connected to the latter stage of the flush solenoid valve 22 of the first drainage path 51, for example, as in the water purifier 1F shown in FIG. 7. You may do it. In this case, the concentrated water to be discarded can be collectively flowed in one path.
 さらに、図8に示す浄水装置1Gのように、第2排水経路を第1排水経路51のフラッシュ電磁弁22の後段に接続し、第1排水経路51と第2排水経路との合流部の後段に浄化運転と連動する新たな開閉機構としての電磁弁31を設ける。この電磁弁31によって、浄化運転中には第1排水経路51を開放し、浄化運転停止中には第1排水経路51を遮断する構成にしても良い。この場合、前記実施形態2の浄水装置1B、1Dと同様の効果を奏する。すなわち、例えば水道水のように常時水圧の掛かった水を原水とする場合には、浄化運転停止時に第1排水経路51を通じて水が常時廃棄されることを防止すると共に、運転再開時の浄水の吐出を時間差なく即座に行うことができる。 Further, as in the water purifying apparatus 1G shown in FIG. 8, the second drainage path is connected to the latter stage of the flush electromagnetic valve 22 of the first drainage path 51, and the latter stage of the confluence of the first drainage path 51 and the second drainage path. In addition, a solenoid valve 31 is provided as a new opening/closing mechanism linked with the cleaning operation. The solenoid valve 31 may open the first drainage path 51 during the purification operation and shut off the first drainage path 51 while the purification operation is stopped. In this case, the same effects as those of the water purifiers 1B and 1D of the second embodiment are achieved. That is, for example, when raw water is water that is constantly subjected to water pressure, such as tap water, it is prevented that the water is always discarded through the first drainage route 51 when the purification operation is stopped, and the purified water is used when the operation is restarted. Discharging can be performed immediately without a time difference.
 なお、各実施形態において説明した浄水装置では、RO膜18の後段にDIフィルタ19を配置されている。しかしながら、DIフィルタ19に限定されるものではなく、AC(活性炭)フィルタであってもよいし、他の不純物を吸着除去できるフィルタであればどのようなものでもよい。今回の発明によって効果を特に奏するのは、浄化機能に限界がある吸着除去フィルタである。 In addition, in the water purifier described in each embodiment, the DI filter 19 is arranged at the subsequent stage of the RO membrane 18. However, the filter is not limited to the DI filter 19 and may be an AC (activated carbon) filter or any filter that can adsorb and remove other impurities. The effect of the present invention is particularly exerted by the adsorption removal filter having a limited purification function.
 本発明は上述した各実施形態に限定されるものではなく、請求項に示した範囲で種々の変更が可能であり、異なる実施形態にそれぞれ開示された技術的手段を適宜組み合わせて得られる実施形態についても本発明の技術的範囲に含まれる。さらに、各実施形態にそれぞれ開示された技術的手段を組み合わせることにより、新しい技術的特徴を形成することができる。 The present invention is not limited to the above-described embodiments, and various modifications can be made within the scope of the claims, and the embodiments obtained by appropriately combining the technical means disclosed in the different embodiments. Is also included in the technical scope of the present invention. Furthermore, new technical features can be formed by combining the technical means disclosed in each of the embodiments.
1、1A、1B、1C、1D、1E、1F、1G 浄水装置
10 圧力スイッチ
11 減圧弁
12 PPフィルタ
13 前側TDS
14 水温計
15 前側流量計
16 ACフィルタ
17 Pump
18 RO膜
19 DIフィルタ(吸着除去部材)
20 後側流量計
21 後側TDS
22 フラッシュ電磁弁
31、34 電磁弁
32 開閉機構
33 逆止弁
35 流路切替機構
50 主経路
50a 取込口
50b、51b 取出口
51 第1排水経路(廃棄経路)
52 第2排水経路
1, 1A, 1B, 1C, 1D, 1E, 1F, 1G Water purifier 10 Pressure switch 11 Pressure reducing valve 12 PP filter 13 Front TDS
14 Water Temperature Meter 15 Front Flow Meter 16 AC Filter 17 Pump
18 RO film 19 DI filter (adsorption removing member)
20 Rear flow meter 21 Rear TDS
22 Flash Solenoid Valve 31, 34 Solenoid Valve 32 Opening/Closing Mechanism 33 Check Valve 35 Flow Path Switching Mechanism 50 Main Path 50a Intake Ports 50b, 51b Outlet 51 First Drainage Path (Disposal Path)
52 Second drainage route

Claims (9)

  1.  逆浸透膜と、不純物の吸着除去を行う吸着除去部材とを用いて水を浄化する浄水装置であって、
     上記逆浸透膜から、当該逆浸透膜によって浄化された浄水の取出口に至る経路上に、上記吸着除去部材が配され、
     上記逆浸透膜から上記吸着除去部材に至る通水経路上に、当該通水経路における水の往来を遮断する第1遮断機構が設けられていることを特徴とする浄水装置。
    A water purification device for purifying water using a reverse osmosis membrane and an adsorption removal member for adsorbing and removing impurities,
    From the reverse osmosis membrane, on the path from the reverse osmosis membrane to the outlet of purified water, the adsorption removal member is arranged,
    A water purifying device comprising a first blocking mechanism for blocking water from flowing in the water passage, on the water passage extending from the reverse osmosis membrane to the adsorption/removal member.
  2.  上記第1遮断機構は、上記吸着除去部材よりも上記逆浸透膜に近い位置に設けられていることを特徴とする請求項1に記載の浄水装置。 The water purifier according to claim 1, wherein the first blocking mechanism is provided at a position closer to the reverse osmosis membrane than the adsorption/removal member.
  3.  上記第1遮断機構は、順方向にのみ通水可能な逆止弁であることを特徴とする請求項1または2に記載の浄水装置。 The water purifier according to claim 1 or 2, wherein the first shutoff mechanism is a check valve capable of passing water only in a forward direction.
  4.  上記逆浸透膜から当該逆浸透膜の浄化処理によって生じる濃縮水の廃棄口に至る廃棄経路上に、電源オン状態よりも電源オフ状態の流量を少なくする流量制限弁を設け、
     上記廃棄経路上に、当該廃棄経路の水の往来を遮断する第2遮断機構が設けられていることを特徴とする請求項1~3の何れか1項に記載の浄水装置。
    A flow rate limiting valve that reduces the flow rate in the power-off state than in the power-on state is provided on the waste path from the reverse osmosis membrane to the wastewater outlet of the concentrated water generated by the purification process of the reverse osmosis membrane,
    The water purifier according to any one of claims 1 to 3, wherein a second cutoff mechanism that cuts off water passing through the waste path is provided on the waste path.
  5.  上記第1遮断機構および上記第2遮断機構は、浄化運転停止に連動して上記通水経路を遮断し、浄化運転再開時に連動して上記通水経路を開放することを特徴とする請求項4に記載の浄水装置。 5. The first shutoff mechanism and the second shutoff mechanism shut off the water passage in association with a stop of the purification operation, and open the water passage in association with restart of the purification operation. Water purification device described in.
  6.  上記吸着除去部材は、イオン交換樹脂を充填したフィルタであることを特徴とする請求項1~5の何れか1項に記載の浄水装置。 The water purification device according to any one of claims 1 to 5, wherein the adsorption/removal member is a filter filled with an ion exchange resin.
  7.  上記逆浸透膜から上記第1遮断機構に至る経路上の水を排水するための排水経路が設けられていることを特徴とする請求項1~6の何れか1項に記載の浄水装置。 The water purification device according to any one of claims 1 to 6, wherein a drainage route for draining water on a route from the reverse osmosis membrane to the first blocking mechanism is provided.
  8.  上記第1遮断機構は、上記逆浸透膜から上記吸着除去部材に至る第1流路と、上記逆浸透膜から上記排水経路に至る第2流路とを切替える流路切替機構であることを特徴とする請求項7に記載の浄水装置。 The first blocking mechanism is a flow path switching mechanism that switches a first flow path from the reverse osmosis membrane to the adsorption removal member and a second flow path from the reverse osmosis membrane to the drainage path. The water purification apparatus according to claim 7.
  9.  請求項1~8の何れか1項に記載の浄水装置を備えることを特徴とする家庭用浄水器。 A household water purifier comprising the water purifier according to any one of claims 1 to 8.
PCT/JP2019/045388 2018-11-27 2019-11-20 Water purification device and household water purifier WO2020110853A1 (en)

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