WO2020098137A1 - Stereoscopic silk imitation fur fabric - Google Patents

Stereoscopic silk imitation fur fabric Download PDF

Info

Publication number
WO2020098137A1
WO2020098137A1 PCT/CN2019/070922 CN2019070922W WO2020098137A1 WO 2020098137 A1 WO2020098137 A1 WO 2020098137A1 CN 2019070922 W CN2019070922 W CN 2019070922W WO 2020098137 A1 WO2020098137 A1 WO 2020098137A1
Authority
WO
WIPO (PCT)
Prior art keywords
silk
rayon
layer
extract
base layer
Prior art date
Application number
PCT/CN2019/070922
Other languages
French (fr)
Chinese (zh)
Inventor
刘科江
王勇
张来源
张雪峰
侯文峰
邓单
Original Assignee
广州番禺职业技术学院
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 广州番禺职业技术学院 filed Critical 广州番禺职业技术学院
Publication of WO2020098137A1 publication Critical patent/WO2020098137A1/en

Links

Images

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B32B5/06Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer characterised by a fibrous or filamentary layer mechanically connected, e.g. by needling to another layer, e.g. of fibres, of paper
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/22Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
    • B32B5/24Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
    • B32B5/26Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it also being fibrous or filamentary
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04Interconnection of layers
    • B32B7/12Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04BKNITTING
    • D04B1/00Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
    • D04B1/02Pile fabrics or articles having similar surface features
    • D04B1/04Pile fabrics or articles having similar surface features characterised by thread material
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
    • D06M15/03Polysaccharides or derivatives thereof
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M16/00Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00Layers arrangement
    • B32B2250/20All layers being fibrous or filamentary
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/08Animal fibres, e.g. hair, wool, silk
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/40Properties of the layers or laminate having particular optical properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/718Weight, e.g. weight per square meter
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/724Permeability to gases, adsorption
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02Natural fibres, other than mineral fibres
    • D06M2101/10Animal fibres
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2211/00Protein-based fibres, e.g. animal fibres
    • D10B2211/01Natural animal fibres, e.g. keratin fibres
    • D10B2211/04Silk

Definitions

  • the invention relates to the technical field of textiles, in particular to a three-dimensional silk imitation fur fabric.
  • Artificial fur is a plush fabric that looks similar to animal fur. It is an artificial animal fur made by artificial methods. Common manufacturing methods include knitting and weaving. Among them, the knitting weft knitting method has the fastest development and the most wide application. Acrylic fiber, modified acrylic fiber, chlorine fiber and other materials can be used as raw materials for artificial fur. Although artificial fur is not as warm as real fur, it is soft and beautiful, and can be made into coats, hats, collars, carpets, etc. It is widely used. At present, the popular imitation fur on the market is made of polyester or acrylic knitted by circular knitting into a gray fabric, and then brushed and brushed. The resulting product is hard and air-impermeable. Machine washing will lose hair and the gloss is poor. , The feel is poor, and the proportion of chemical raw materials is too large, resulting in poor quality of imitation fur.
  • Silk a type of textile, is woven from silk or synthetic fibers, rayon, staple fiber, etc .; a general term for fabrics woven or interwoven with pure silk or rayon.
  • the material used in this product is mulberry silk.
  • the following silk refers to mulberry silk.
  • Mulberry silk is the only filament fiber in natural fiber that can be mass-produced. It has easy processing characteristics that are unmatched by other fiber products in fabric processing and manufacturing.
  • the existing silk is generally presented with a smooth cloth, which does not have a three-dimensional effect, which reduces the impact of the silk appearance on the human eye and the purchase volume of consumers.
  • the use of single mechanical equipment for construction reduces the efficiency of its production and increases the cost of silk production.
  • This product makes a breakthrough in traditional silk, making silk more than traditional flat fabric, making silk from 2D to 3D three-dimensional effect, and compared with animal fur, it has better breathability and is more environmentally friendly.
  • the purpose of the present invention is to overcome the shortcomings of the prior art and provide a three-dimensional silk imitation fur fabric.
  • a three-dimensional silk imitation fur fabric comprising a silk velvet layer 1, a rayon base layer 2, an adhesive layer 3 and an imitation leather velvet layer 4, the silk velvet layer 1 is knitted above the rayon base layer 1 by knitting With a fixed connection, the rayon base layer 2 and the imitation leather fleece layer 4 are adhered by an adhesive layer 3.
  • mulberry silk is used as the raw material for fluff
  • rayon is used as the raw material for the base layer.
  • the spinning is carried out by using a large circular machine to fix the silk fleece layer on the rayon base layer, and combined with the compound imitation leather fleece layer to form a three-dimensional silk imitation fur fabric.
  • the silk velvet layer has good gloss, good three-dimensional structure and pattern effect, giving the fabric a three-dimensional sense of unevenness, smooth lines and good visual sense.
  • the invention uses rayon as the base layer material, which is lighter in weight and lower in cost than silk.
  • the fabric of the present invention mainly imitates animal fur. Compared with animal fur, the material is protein, but it is a major breakthrough in visual effects, and it has low cost, good breathability, more environmental protection and more humanity.
  • the silk velvet layer 1 uses mulberry silk as the raw material for the velvet;
  • the rayon base layer 2 uses rayon as the raw material, and the silk velvet layer 1 and the artificial
  • the silk base layer 2 is formed by spinning on a large circular machine, and specifically includes the following steps:
  • the large circular knitting machine uses yarns to form coils, which are connected through a longitudinal string and a horizontal direction to form a rayon base layer with a silk velvet layer fixed on the surface.
  • the preparation method of the mulberry silk includes the following steps:
  • step (1b) After step (1b) is completed, the excellent raw silk is selected, and then the raw silk is dipped to remove sericin;
  • step (2b) After the step (2b) is completed, put the raw silk with the sericin removed into the drying room for drying.
  • the drying time is 12 hours;
  • step (3b) After the step (3b) is completed, the dried raw silk is wound, paralleled, twisted, twisted and twisted to obtain the mulberry silk.
  • the dipping time of the raw silk is 8 hours, and the dipping solution is a polyethylene glycol diglycidyl ether solution, and the pH value Under conditions equal to 7.6.
  • the fineness of the mulberry silk is 20-128D.
  • the length of the mulberry silk is 5-20 mm.
  • the process steps of forming a coil are:
  • step (1c) After step (1c) is completed, close the needle mouth of the knitting needle, and then put the old stitch on the hook with the needle mouth closed.
  • the invention can effectively save the amount of raw materials, simplify or cancel the cutting and sewing processes by using a large circular machine for spinning, and can improve the product taking performance. Moreover, the knitting production has a short process, strong adaptability to raw materials, and fast varieties. , The product has a wide range of use, low noise and low energy consumption. By fitting mulberry silk onto rayon, it can effectively increase the three-dimensional effect of the fabric and enhance the impact of the appearance of the fabric on human vision.
  • antibacterial modification treatment is also performed on the mulberry silk and rayon, specifically including the following steps:
  • the invention adopts quaternary ammonium salt chitosan, rhubarb extract and madder extract to carry out antibacterial modification treatment on mulberry silk and rayon, which significantly improves the antibacterial property of the fabric and has good antibacterial durability. Since the addition of quaternary ammonium chitosan, rhubarb extract and madder extract will affect the whiteness of mulberry silk and rayon, the present invention further optimizes the amount of quaternary ammonium chitosan, rhubarb extract and madder extract, While improving the antibacterial properties of mulberry silk and rayon, it should avoid greatly reducing its whiteness.
  • the mass fraction of the quaternary ammonium chitosan in the antibacterial mixture is 1.4%
  • the mass fraction of rhubarb extract in the antibacterial mixture is 2.4%
  • the mass fraction of Rubia cordifolia extract in the antibacterial mixture is 1.2%.
  • the fabric has both high antibacterial properties and whiteness.
  • the adhesive layer is a thermosetting adhesive layer.
  • mulberry silk is used as the raw material for fluff
  • rayon is used as the raw material for the base layer.
  • the spinning is carried out by using a large circular machine to fix the silk velvet layer on the rayon base layer and combined with the imitation leather fleece layer to form a three-dimensional silk imitation fur fabric.
  • the silk velvet layer has good gloss, has a good three-dimensional structure and pattern effect, gives the fabric a three-dimensional sense of unevenness, smooth lines, and good visual sense.
  • the invention uses rayon as the base layer material, which is lighter in weight and lower in cost than silk.
  • the invention can effectively save the amount of raw materials, simplify or cancel the cutting and sewing processes by using a large circular machine for spinning, and can improve the product taking performance. Moreover, the knitting production has a short process, strong adaptability to raw materials, and fast varieties. , The product has a wide range of use, low noise and low energy consumption. By fitting mulberry silk onto rayon, it can effectively increase the three-dimensional effect of the fabric and enhance the impact of the appearance of the fabric on human vision.
  • Fig. 1 is a schematic structural diagram of a three-dimensional silk imitation fur fabric according to the present invention.
  • 1 is a silk velvet layer
  • 2 is a rayon base layer
  • 3 is an adhesive layer
  • 4 is an imitation leather velvet layer.
  • a three-dimensional silk imitation fur fabric includes a silk velvet layer 1, a rayon base layer 2, an adhesive layer 3, and a leather-like velvet layer 4.
  • the silk velvet layer 1 is knitted with the The rayon base layer 1 is fixedly connected above, and the rayon base layer 2 and the imitation leather pile layer 4 are adhered by an adhesive layer 3.
  • the adhesive layer is a thermosetting adhesive layer.
  • the silk velvet layer 1 is made of mulberry silk as the raw material of velvet;
  • the rayon base layer 2 is made of rayon.
  • the silk velvet layer 1 and the rayon base layer 2 are formed by spinning on a large circular machine, and specifically include the following steps:
  • the preparation method of the mulberry silk includes the following steps:
  • step (1b) After step (1b) is completed, the excellent raw silk is selected, and then the raw silk is dipped to remove sericin;
  • step (2b) After the step (2b) is completed, put the raw silk with the sericin removed into the drying room for drying.
  • the drying time is 12 hours;
  • step (3b) After the step (3b) is completed, the dried raw silk is wound, paralleled, twisted, twisted and twisted to obtain the mulberry silk.
  • the raw silk is immersed for 8 hours, and the immersed solution is a polyethylene glycol diglycidyl ether solution, and the pH value is equal to 7.6.
  • the fineness of the mulberry silk is 20D; the length of the mulberry silk is 5 mm.
  • the process steps of forming a coil are:
  • step (1c) After step (1c) is completed, close the needle mouth of the knitting needle, and then put the old stitch on the hook with the needle mouth closed.
  • a three-dimensional silk imitation fur fabric comprising a silk velvet layer 1, a rayon base layer 2, an adhesive layer 3 and an imitation leather velvet layer 4, the silk velvet layer 1 is knitted above the rayon base layer 1 by knitting With a fixed connection, the rayon base layer 2 and the imitation leather fleece layer 4 are adhered by an adhesive layer 3.
  • the adhesive layer is a thermosetting adhesive layer.
  • the preparation method of the mulberry silk is the same as that in Example 1.
  • the fineness of the mulberry silk is 50D; the length of the mulberry silk is 10 mm.
  • the mulberry silk and rayon are also subjected to antibacterial modification treatment, specifically including the following steps:
  • the spinning method of the mulberry silk and the rayon is the same as in Example 1.
  • a three-dimensional silk imitation fur fabric comprising a silk velvet layer 1, a rayon base layer 2, an adhesive layer 3 and an imitation leather velvet layer 4, the silk velvet layer 1 is knitted above the rayon base layer 1 by knitting With a fixed connection, the rayon base layer 2 and the imitation leather fleece layer 4 are adhered by an adhesive layer 3.
  • the adhesive layer is a thermosetting adhesive layer.
  • the preparation method of the mulberry silk is the same as that in Example 1.
  • the fineness of the mulberry silk is 100D; the length of the mulberry silk is 20mm
  • the spinning method of the mulberry silk and the rayon is the same as in Example 1.
  • a three-dimensional silk imitation fur fabric comprising a silk velvet layer 1, a rayon base layer 2, an adhesive layer 3 and an imitation leather velvet layer 4, the silk velvet layer 1 is knitted above the rayon base layer 1 by knitting With a fixed connection, the rayon base layer 2 and the imitation leather fleece layer 4 are adhered by an adhesive layer 3.
  • the adhesive layer is a thermosetting adhesive layer.
  • the preparation method of the mulberry silk is the same as that in Example 1.
  • the fineness of the mulberry silk is 128D; the length of the mulberry silk is 15mm
  • antibacterial modification treatment is performed on the mulberry silk and rayon, specifically including the following steps:
  • the spinning method of the mulberry silk and the rayon is the same as in Example 1.
  • a three-dimensional silk imitation fur fabric comprising a silk velvet layer 1, a rayon base layer 2, an adhesive layer 3 and an imitation leather velvet layer 4, the silk velvet layer 1 is knitted above the rayon base layer 1 by knitting With a fixed connection, the rayon base layer 2 and the imitation leather fleece layer 4 are adhered by an adhesive layer 3.
  • the adhesive layer is a thermosetting adhesive layer.
  • the preparation method of the mulberry silk is the same as that in Example 1.
  • the fineness of the mulberry silk is 128D; the length of the mulberry silk is 15mm
  • antibacterial modification treatment is performed on the mulberry silk and rayon, specifically including the following steps:
  • the spinning method of the mulberry silk and the rayon is the same as in Example 1.
  • a three-dimensional silk imitation fur fabric comprising a silk velvet layer 1, a rayon base layer 2, an adhesive layer 3 and an imitation leather velvet layer 4, the silk velvet layer 1 is knitted above the rayon base layer 1 by knitting With a fixed connection, the rayon base layer 2 and the imitation leather fleece layer 4 are adhered by an adhesive layer 3.
  • the adhesive layer is a thermosetting adhesive layer.
  • the preparation method of the mulberry silk is the same as that in Example 1.
  • the fineness of the mulberry silk is 128D; the length of the mulberry silk is 15mm
  • antibacterial modification treatment is performed on the mulberry silk and rayon, specifically including the following steps:
  • the spinning method of the mulberry silk and the rayon is the same as in Example 1.
  • a three-dimensional silk imitation fur fabric comprising a silk velvet layer 1, a rayon base layer 2, an adhesive layer 3 and an imitation leather velvet layer 4, the silk velvet layer 1 is knitted above the rayon base layer 1 by knitting With a fixed connection, the rayon base layer 2 and the imitation leather fleece layer 4 are adhered by an adhesive layer 3.
  • the adhesive layer is a thermosetting adhesive layer; the fineness of the mulberry silk is 20D; and the length of the mulberry silk is 15mm.
  • the preparation method of the mulberry silk is the same as that in Example 1.
  • antibacterial modification treatment is performed on the mulberry silk and rayon, specifically including the following steps:
  • the spinning method of the mulberry silk and the rayon is the same as in Example 1.
  • a three-dimensional silk imitation fur fabric comprising a silk velvet layer 1, a rayon base layer 2, an adhesive layer 3 and an imitation leather velvet layer 4, the silk velvet layer 1 is knitted above the rayon base layer 1 by knitting With a fixed connection, the rayon base layer 2 and the imitation leather fleece layer 4 are adhered by an adhesive layer 3.
  • the adhesive layer is a thermosetting adhesive layer; the fineness of the mulberry silk is 20D; and the length of the mulberry silk is 15mm.
  • the preparation method of the mulberry silk is the same as that in Example 1.
  • antibacterial modification treatment is performed on the mulberry silk and rayon, specifically including the following steps:
  • the spinning method of the mulberry silk and the rayon is the same as in Example 1.
  • Example 1 to 6 and Comparative Examples 1 to 2 were placed for 1 day and 6 months, cut into 0.3g square pieces, numbered, and placed in test tubes.
  • the mouth of the test tubes was plugged with medical absorbent cotton. Sterilize with 0.1MPa high-pressure steam for 30min.
  • the medium was divided into test tubes, and 2 mL of bacterial solution and 0.3 g of fabric were added.
  • the test tubes were placed in a 37 ° C water bath and shaken for culture. Samples were taken periodically to detect the antibacterial rate of each group of fabrics.
  • the present invention uses quaternary ammonium salt chitosan, rhubarb extract and rubia root extract to carry out antibacterial modification treatment on mulberry silk and rayon. It is antibacterial, and the compound of quaternary ammonium salt chitosan, rhubarb extract and madder extract has synergistic antibacterial effect and has good antibacterial lasting performance.
  • mulberry silk is used as the raw material for fluff
  • rayon is used as the raw material for the base layer.
  • the spinning is carried out by using a large circular machine to fix the silk velvet layer on the rayon base layer, and combined with the composite imitation leather layer to form a three-dimensional Silk imitation fur fabric.
  • the silk velvet layer has good luster, has a good three-dimensional structure and pattern effect, gives the fabric a three-dimensional sense of unevenness, smooth lines, and good visual sense.
  • the finished product is lighter in weight and more firmly combined with the base layer.
  • the bottom layer is torn, and the cost is lower, the production speed is faster, and it is more environmentally friendly.
  • the invention uses rayon as the base layer material, which is lighter in weight and lower in cost than silk.
  • the invention can effectively save the amount of raw materials, simplify or cancel the cutting and sewing processes by using a large circular machine for spinning, and can improve the product taking performance. Moreover, the knitting production has a short process, strong adaptability to raw materials, and fast varieties. , The product has a wide range of use, low noise and low energy consumption. By fitting mulberry silk onto rayon, it can effectively increase the three-dimensional effect of the fabric and enhance the impact of the appearance of the fabric on human vision. Compared with animal fur, the material of the invention is protein, but the material of the invention is a protein, but it is a major breakthrough in visual effect, and has low cost, good breathability, more environmental protection and more humanity.

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Biochemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Microbiology (AREA)
  • Woven Fabrics (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Knitting Of Fabric (AREA)
  • Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)

Abstract

Disclosed is a stereoscopic silk imitation fur fabric, comprising a real silk nap layer (1), a rayon base layer (2), a bonding layer (3), and an imitation leather nap layer (4), wherein the real silk nap layer (1) is fixedly connected with the upper part of the rayon base layer (2) by means of knitting, and the rayon base layer (2) is bonded to the imitation leather nap layer (4) through the bonding layer (3). The stereoscopic silk imitation fur fabric is formed by using a mulberry silk as a nap raw material and a rayon as a base layer raw material, weaving same using a circular machine, fixing a real silk nap layer onto a rayon base layer, and bonding same with an imitation leather nap layer. The real silk nap layer has a good gloss, a good stereoscopic structure and pattern effect, imparts a concave-convex stereoscopic perception to the fabric, has a smooth line, and has a good visual perception. The use of a rayon as a base layer material has a lighter weight and a lower cost compared to a silk. The fabric imitates an animal fur in which a natural silk ingredient is a protein, such that the sense of touch is more ideal on the skin; the air permeability is good; and furthermore, the fabric is more environmentally-friendly.

Description

一种立体丝绸仿毛皮面料Three-dimensional silk imitation fur fabric 技术领域Technical field
本发明涉及纺织品技术领域,具体涉及一种立体丝绸仿毛皮面料。The invention relates to the technical field of textiles, in particular to a three-dimensional silk imitation fur fabric.
背景技术Background technique
人造毛皮是外观类似动物毛皮的长毛绒型织物,是以人工方法制成的仿动物毛皮,常用的制造方法有针织和机织等,其中,针织纬编法发展最快,应用最广。腈纶、改性腈纶、氯纶等材料均可作人造毛皮原料。人造毛皮保暖性虽不及真毛皮,但轻柔、美观,可制成大衣、帽子、衣领和地毯等,应用十分广泛。目前,市场上流行的仿毛皮是以涤纶或腈纶经针织圆机织成坯布,然后去拉毛、拉绒制作而成,制作得到的产品较硬,不透气,机洗会掉毛,光泽较差,手感较差,而且化工原料占比太大,导致仿毛皮品质差。Artificial fur is a plush fabric that looks similar to animal fur. It is an artificial animal fur made by artificial methods. Common manufacturing methods include knitting and weaving. Among them, the knitting weft knitting method has the fastest development and the most wide application. Acrylic fiber, modified acrylic fiber, chlorine fiber and other materials can be used as raw materials for artificial fur. Although artificial fur is not as warm as real fur, it is soft and beautiful, and can be made into coats, hats, collars, carpets, etc. It is widely used. At present, the popular imitation fur on the market is made of polyester or acrylic knitted by circular knitting into a gray fabric, and then brushed and brushed. The resulting product is hard and air-impermeable. Machine washing will lose hair and the gloss is poor. , The feel is poor, and the proportion of chemical raw materials is too large, resulting in poor quality of imitation fur.
丝绸,一种纺织品,用蚕丝或合成纤维、人造纤维、短丝等织成;用蚕丝或人造丝纯织或交织而成的织品的总称。本产品所使用材料为桑蚕丝,下述真丝泛指桑蚕丝。桑蚕丝是天然纤维中唯一能够大量生产的长丝纤维,在面料加工及制成方面具有其它纤维制品无法比拟的易加工特性。然而,现有的丝绸一般都是以一种平滑的面布进行呈现,不具有立体的效果,降低了丝绸外观对人眼视觉的冲击效果和消费者的购买量,而且现有的丝绸一般会使用单体式机械设备来进行构造,降低了其生产的效率,提高了丝绸生产的成本。本产品在传统丝绸上作出突破,让丝绸不止做传统的平面面料,让丝绸从2D变成3D立体效果,且与动物毛皮相比,透气性好,更加环保。Silk, a type of textile, is woven from silk or synthetic fibers, rayon, staple fiber, etc .; a general term for fabrics woven or interwoven with pure silk or rayon. The material used in this product is mulberry silk. The following silk refers to mulberry silk. Mulberry silk is the only filament fiber in natural fiber that can be mass-produced. It has easy processing characteristics that are unmatched by other fiber products in fabric processing and manufacturing. However, the existing silk is generally presented with a smooth cloth, which does not have a three-dimensional effect, which reduces the impact of the silk appearance on the human eye and the purchase volume of consumers. The use of single mechanical equipment for construction reduces the efficiency of its production and increases the cost of silk production. This product makes a breakthrough in traditional silk, making silk more than traditional flat fabric, making silk from 2D to 3D three-dimensional effect, and compared with animal fur, it has better breathability and is more environmentally friendly.
发明内容Summary of the invention
本发明的目的在于克服现有技术的不足之处而提供一种立体丝绸仿毛皮面料。The purpose of the present invention is to overcome the shortcomings of the prior art and provide a three-dimensional silk imitation fur fabric.
为实现上述目的,本发明采取的技术方案如下:To achieve the above objectives, the technical solutions adopted by the present invention are as follows:
一种立体丝绸仿毛皮面料,包括真丝绒毛层1、人造丝基底层2、粘合层3和仿皮绒层4,所述真丝绒毛层1通过针织的方式与所述人造丝基层1的上方固定连接,所述人造丝基底层2和仿皮绒层4通过粘合层3粘合。A three-dimensional silk imitation fur fabric, comprising a silk velvet layer 1, a rayon base layer 2, an adhesive layer 3 and an imitation leather velvet layer 4, the silk velvet layer 1 is knitted above the rayon base layer 1 by knitting With a fixed connection, the rayon base layer 2 and the imitation leather fleece layer 4 are adhered by an adhesive layer 3.
本发明以桑蚕丝作为绒毛原料,以人造丝为基底层原料,通过采用大圆机进行纺织,在人造丝基底层上固定真丝绒毛层,并结合复合仿皮绒层,形成立体丝绸仿毛皮面料。真丝绒毛层光泽好,具有良好的立体结构与图案效果,赋予面料凹凸的立体感,线条流畅,视觉感好。本发明采用人造丝作为基底层材料,与丝绸相比,质轻,成本更低。本发明的面料主要是模仿动物皮草,与动物皮毛相比,材料均为蛋白质,但在视觉效果上是一个重大突破,而且成本低、透气性好、更加环保、更人性。In the present invention, mulberry silk is used as the raw material for fluff, and rayon is used as the raw material for the base layer. The spinning is carried out by using a large circular machine to fix the silk fleece layer on the rayon base layer, and combined with the compound imitation leather fleece layer to form a three-dimensional silk imitation fur fabric. The silk velvet layer has good gloss, good three-dimensional structure and pattern effect, giving the fabric a three-dimensional sense of unevenness, smooth lines and good visual sense. The invention uses rayon as the base layer material, which is lighter in weight and lower in cost than silk. The fabric of the present invention mainly imitates animal fur. Compared with animal fur, the material is protein, but it is a major breakthrough in visual effects, and it has low cost, good breathability, more environmental protection and more humanity.
作为本发明所述的立体丝绸仿毛皮面料的优选实施方式,所述真丝绒毛层1以桑蚕丝作为绒毛原料;所述人造丝基底层2以人造丝为原料,所述真丝绒毛层1和人造丝基底层2通过大圆机纺织形成,具体包括以下步骤:As a preferred embodiment of the three-dimensional silk imitation fur fabric according to the present invention, the silk velvet layer 1 uses mulberry silk as the raw material for the velvet; the rayon base layer 2 uses rayon as the raw material, and the silk velvet layer 1 and the artificial The silk base layer 2 is formed by spinning on a large circular machine, and specifically includes the following steps:
(1a)以桑蚕丝作为绒毛原料,以人造丝作为基底层原料,将桑蚕丝和人造丝放入到大圆机上;(1a) Using mulberry silk as the raw material for fluff and rayon as the raw material for the base layer, put the mulberry silk and rayon on the large circular machine;
(2a)大圆机利用纱线构成线圈,经过纵向串套和横向连接成为表面固定有真丝绒毛层的人造丝基底层。(2a) The large circular knitting machine uses yarns to form coils, which are connected through a longitudinal string and a horizontal direction to form a rayon base layer with a silk velvet layer fixed on the surface.
作为本发明所述的立体丝绸仿毛皮面料的优选实施方式,所述桑蚕丝的制备方法包括以下步骤:As a preferred embodiment of the three-dimensional silk imitation fur fabric of the present invention, the preparation method of the mulberry silk includes the following steps:
(1b)将蚕茧浸在60~80℃的热水中,进行抽丝,并卷绕于丝筐上;(1b) Immerse the silkworm cocoons in hot water at 60 ~ 80 ℃, draw the silk, and wind it on the silk basket;
(2b)待步骤(1b)完成后,再筛选出优良的生丝,接着将生丝进行浸渍去除丝胶;(2b) After step (1b) is completed, the excellent raw silk is selected, and then the raw silk is dipped to remove sericin;
(3b)待步骤(2b)完成后,再将去除丝胶的生丝放入到烘干房内进行烘干,烘干时间为12小时;(3b) After the step (2b) is completed, put the raw silk with the sericin removed into the drying room for drying. The drying time is 12 hours;
(4b)待步骤(3b)完成后,再将烘干的生丝进行络丝、并丝、捻丝、止捻、成绞,得到所述桑蚕丝。(4b) After the step (3b) is completed, the dried raw silk is wound, paralleled, twisted, twisted and twisted to obtain the mulberry silk.
作为本发明所述的立体丝绸仿毛皮面料的优选实施方式,所述步骤(2b)中,生丝浸渍的时间为8小时,浸渍的溶液采用聚乙二醇二缩水甘油醚溶液,并且在pH值等于7.6条件下进行。As a preferred embodiment of the three-dimensional silk imitation fur fabric according to the present invention, in the step (2b), the dipping time of the raw silk is 8 hours, and the dipping solution is a polyethylene glycol diglycidyl ether solution, and the pH value Under conditions equal to 7.6.
作为本发明所述的立体丝绸仿毛皮面料的优选实施方式,所述桑蚕丝的纤度为20~128D。As a preferred embodiment of the three-dimensional silk imitation fur fabric of the present invention, the fineness of the mulberry silk is 20-128D.
作为本发明所述的立体丝绸仿毛皮面料的优选实施方式,所述桑蚕丝的长度为5~20mm。As a preferred embodiment of the three-dimensional silk imitation fur fabric according to the present invention, the length of the mulberry silk is 5-20 mm.
作为本发明所述的立体丝绸仿毛皮面料的优选实施方式,所述构成线圈的过程步骤为:As a preferred embodiment of the three-dimensional silk imitation fur fabric according to the present invention, the process steps of forming a coil are:
(1c)刚形成的线圈从针钩移至针杆,然后把纱线喂到织针上,接着把纱线弯曲成线圈的形状,最后把新垫上的纱线或刚弯成的线圈移至针钩内;(1c) The newly formed stitch is moved from the hook to the needle bar, and then the yarn is fed to the knitting needle, then the yarn is bent into the shape of a stitch, and finally the yarn on the new pad or the newly formed stitch is moved to Inside the hook
(2c)待步骤(1c)完成后,再封闭织针针口,然后把旧线圈套到针口闭合的针钩上。(2c) After step (1c) is completed, close the needle mouth of the knitting needle, and then put the old stitch on the hook with the needle mouth closed.
本发明通过采用大圆机进行纺织,能有效的节约原料的用量,简化或取消裁剪和缝纫工序,并能改善产品的服用性能,而且针织生产因工艺过程短,原料适应性强,翻改品种快,产品使用范围广,噪声小和能源消耗少,通过将桑蚕丝嵌合在人造丝上,能有效的增加了面料的立体效果,增强了面料外观对人眼视觉的冲击效果。The invention can effectively save the amount of raw materials, simplify or cancel the cutting and sewing processes by using a large circular machine for spinning, and can improve the product taking performance. Moreover, the knitting production has a short process, strong adaptability to raw materials, and fast varieties. , The product has a wide range of use, low noise and low energy consumption. By fitting mulberry silk onto rayon, it can effectively increase the three-dimensional effect of the fabric and enhance the impact of the appearance of the fabric on human vision.
作为本发明所述的立体丝绸仿毛皮面料的优选实施方式,所述桑蚕丝和人造丝进行纺织之前,还对桑蚕丝和人造丝进行抗菌改性处理,具体包括以下步骤:As a preferred embodiment of the three-dimensional silk imitation fur fabric of the present invention, before the mulberry silk and rayon are woven, antibacterial modification treatment is also performed on the mulberry silk and rayon, specifically including the following steps:
(1d)将大黄粉碎后按质量比1:10~20的比例加入乙醇溶液中,在65~70℃提取2~3小时后,离心,将上清液浓缩后得到大黄提取物;(1d) After crushing rhubarb, add it to the ethanol solution at a mass ratio of 1: 10-20, extract it at 65-70 ° C for 2-3 hours, centrifuge, and concentrate the supernatant to obtain rhubarb extract;
(2d)将茜草粉碎后按质量比1:10~15的比例加入乙醇溶液中,在50~55℃提取3~6小时后,离心,将上清液浓缩后得到茜草提取物;(2d) After crushing the madder, add it to the ethanol solution at a mass ratio of 1: 10-15, extract it at 50-55 ° C for 3-6 hours, centrifuge, and concentrate the supernatant to obtain the madder extract;
(3d)将季铵盐壳聚糖加入质量分数为0.5%~1%的柠檬酸溶液中,搅拌溶解后,加入大黄提取物和茜草提取物,搅拌均匀,得到抗菌混合液,其中,所述抗菌混合液中季铵盐壳聚糖的质量分数1.2%~1.8%,所述抗菌混合液中大黄提取物的质量分数2%~4%,所述抗菌混合液中茜草提取物的质量分数1%~1.5%;(3d) Add quaternary ammonium salt chitosan to a citric acid solution with a mass fraction of 0.5% to 1%. After stirring and dissolving, add rhubarb extract and madder extract and stir evenly to obtain an antibacterial mixed solution. The mass fraction of the quaternary ammonium salt chitosan in the antibacterial mixed solution is 1.2% to 1.8%, the mass fraction of the rhubarb extract in the antibacterial mixed solution is 2% to 4%, and the mass fraction of the rubia extract in the antibacterial mixed solution is 1 % ~ 1.5%;
(4d)将桑蚕丝和人造丝浸入所述抗菌混合液中,桑蚕丝和人造丝的总质量与抗菌混合液的质量比为1:5~10,在45~50℃水浴振荡3~4小时后,将桑蚕丝和人造丝取出,烘干。(4d) Immerse the mulberry silk and rayon in the antibacterial mixture, the total mass ratio of the mulberry silk and rayon to the antibacterial mixture is 1: 5 ~ 10, and shake in a water bath at 45 ~ 50 ℃ for 3-4 hours After that, the mulberry silk and rayon are taken out and dried.
本发明采用季铵盐壳聚糖、大黄提取物和茜草提取物对桑蚕丝和人造丝进行抗菌改性处理,显著提高了面料的抗菌性,并具有良好的抗菌持久性。由于季铵盐壳聚糖、大黄提取物和茜草提取物的加入会影响桑蚕丝和人造丝的白度,本发明通过进一步优化季铵盐壳聚糖、大黄提取物和茜草提取物的用量,在改善桑蚕丝和人造丝的抗菌性同时,避免大幅降低其白度。The invention adopts quaternary ammonium salt chitosan, rhubarb extract and madder extract to carry out antibacterial modification treatment on mulberry silk and rayon, which significantly improves the antibacterial property of the fabric and has good antibacterial durability. Since the addition of quaternary ammonium chitosan, rhubarb extract and madder extract will affect the whiteness of mulberry silk and rayon, the present invention further optimizes the amount of quaternary ammonium chitosan, rhubarb extract and madder extract, While improving the antibacterial properties of mulberry silk and rayon, it should avoid greatly reducing its whiteness.
作为本发明所述的立体丝绸仿毛皮面料的优选实施方式,所述抗菌混合液中季铵盐壳聚糖的质量分数1.4%,所述抗菌混合液中大黄提取物的质量分数2.4%,所述抗菌混合液中茜草提取物的质量分数1.2%。此时,面料兼具较高的抗菌性和白度。As a preferred embodiment of the three-dimensional silk imitation fur fabric of the present invention, the mass fraction of the quaternary ammonium chitosan in the antibacterial mixture is 1.4%, and the mass fraction of rhubarb extract in the antibacterial mixture is 2.4%. The mass fraction of Rubia cordifolia extract in the antibacterial mixture is 1.2%. At this time, the fabric has both high antibacterial properties and whiteness.
作为本发明所述的立体丝绸仿毛皮面料的优选实施方式,所述粘合层为热固型粘胶层。As a preferred embodiment of the three-dimensional silk imitation fur fabric of the present invention, the adhesive layer is a thermosetting adhesive layer.
与现有技术相比,本发明的有益效果为:Compared with the prior art, the beneficial effects of the present invention are:
本发明以桑蚕丝作为绒毛原料,以人造丝为基底层原料,通过采用大圆机进行纺织,在人造丝基底层上固定真丝绒毛层,并结合仿皮绒层,形成立体丝绸仿毛皮面料。真丝绒毛层光泽好,具有良好的立体结构与图案效果,赋予面料凹凸的立体感,线条流畅,视觉感好,与毛皮相比,透气性更好,成品重量更轻,与基底层结合更牢固,不容易将基底层撕破,且成本更低,生产速度更快,更环保。本发明采用人造丝作为基底层材料,与丝绸相比,质轻,成本更低。In the present invention, mulberry silk is used as the raw material for fluff, and rayon is used as the raw material for the base layer. The spinning is carried out by using a large circular machine to fix the silk velvet layer on the rayon base layer and combined with the imitation leather fleece layer to form a three-dimensional silk imitation fur fabric. The silk velvet layer has good gloss, has a good three-dimensional structure and pattern effect, gives the fabric a three-dimensional sense of unevenness, smooth lines, and good visual sense. Compared with fur, it has better air permeability, lighter finished product weight, and is more firmly combined with the base layer , It is not easy to tear the base layer, and the cost is lower, the production speed is faster, and more environmentally friendly. The invention uses rayon as the base layer material, which is lighter in weight and lower in cost than silk.
本发明通过采用大圆机进行纺织,能有效的节约原料的用量,简化或取消裁剪和缝纫工序,并能改善产品的服用性能,而且针织生产因工艺过程短,原料适应性强,翻改品种快,产品使用范围广,噪声小和能源消耗少,通过将桑蚕丝嵌合在人造丝上,能有效的增加了面料的立体效果,增强了面料外观对人眼视觉的冲击效果。The invention can effectively save the amount of raw materials, simplify or cancel the cutting and sewing processes by using a large circular machine for spinning, and can improve the product taking performance. Moreover, the knitting production has a short process, strong adaptability to raw materials, and fast varieties. , The product has a wide range of use, low noise and low energy consumption. By fitting mulberry silk onto rayon, it can effectively increase the three-dimensional effect of the fabric and enhance the impact of the appearance of the fabric on human vision.
附图说明BRIEF DESCRIPTION
图1为本发明所述的立体丝绸仿毛皮面料结构示意图,图中,1为真丝绒毛层,2为人造丝基底层,3为粘合层,4为仿皮绒层。Fig. 1 is a schematic structural diagram of a three-dimensional silk imitation fur fabric according to the present invention. In the figure, 1 is a silk velvet layer, 2 is a rayon base layer, 3 is an adhesive layer, and 4 is an imitation leather velvet layer.
具体实施方式detailed description
为更好地说明本发明的目的、技术方案和优点,下面将结合具体实施例对本发明进一步说明。本领域技术人员应当理解,此处所描述的具体实施例仅用以解释本发明,并不用于限定本发明。In order to better illustrate the purpose, technical solutions and advantages of the present invention, the present invention will be further described in combination with specific embodiments below. Those skilled in the art should understand that the specific embodiments described here are only used to explain the present invention, and are not intended to limit the present invention.
实施例中,所使用的实验方法如无特殊说明,均为常规方法,所用的材料等,如无特殊说明,均可从商业途径得到。In the examples, the experimental methods used are conventional methods unless otherwise specified, and the materials used, etc., unless otherwise specified, can be obtained from commercial sources.
实施例1Example 1
如图1所示,一种立体丝绸仿毛皮面料,包括真丝绒毛层1、人造丝基底层2、粘合层3和仿皮绒层4,所述真丝绒毛层1通过针织的方式与所述人造丝基层1的上方固定连接,所述人造丝基底层2和仿皮绒层4通过粘合层3粘合。其中,所述粘合层为热固型粘胶层。As shown in FIG. 1, a three-dimensional silk imitation fur fabric includes a silk velvet layer 1, a rayon base layer 2, an adhesive layer 3, and a leather-like velvet layer 4. The silk velvet layer 1 is knitted with the The rayon base layer 1 is fixedly connected above, and the rayon base layer 2 and the imitation leather pile layer 4 are adhered by an adhesive layer 3. Wherein, the adhesive layer is a thermosetting adhesive layer.
所述真丝绒毛层1以桑蚕丝作为绒毛原料;所述人造丝基底层2以人造丝为原料,所述真丝绒毛层1和人造丝基底层2通过大圆机纺织形成,具体包括以下步骤:The silk velvet layer 1 is made of mulberry silk as the raw material of velvet; the rayon base layer 2 is made of rayon. The silk velvet layer 1 and the rayon base layer 2 are formed by spinning on a large circular machine, and specifically include the following steps:
(1a)以桑蚕丝作为绒毛原料,以人造丝作为基底层原料,将桑蚕丝和人造丝放入到大圆机上;(1a) Using mulberry silk as the raw material for fluff and rayon as the raw material for the base layer, put the mulberry silk and rayon on the large circular machine;
(2a)大圆机再利用纱线构成线圈,经过纵向串套和横向连接成为表面固定有真丝绒毛层的人造丝基底层。(2a) The large circular machine reuses the yarn to form a coil, which is connected to the rayon base layer with the silk velvet layer fixed on the surface through longitudinal stringing and lateral connection.
所述桑蚕丝的制备方法包括以下步骤:The preparation method of the mulberry silk includes the following steps:
(1b)将蚕茧浸在60~80℃的热水中,进行抽丝,并卷绕于丝筐上;(1b) Immerse the silkworm cocoons in hot water at 60 ~ 80 ℃, draw the silk, and wind it on the silk basket;
(2b)待步骤(1b)完成后,再筛选出优良的生丝,接着将生丝进行浸渍去除丝胶;(2b) After step (1b) is completed, the excellent raw silk is selected, and then the raw silk is dipped to remove sericin;
(3b)待步骤(2b)完成后,再将去除丝胶的生丝放入到烘干房内进行烘干,烘干时间为12小时;(3b) After the step (2b) is completed, put the raw silk with the sericin removed into the drying room for drying. The drying time is 12 hours;
(4b)待步骤(3b)完成后,再将烘干的生丝进行络丝、并丝、捻丝、止捻、成绞,得到所述桑蚕丝。(4b) After the step (3b) is completed, the dried raw silk is wound, paralleled, twisted, twisted and twisted to obtain the mulberry silk.
所述步骤(2b)中,生丝浸渍的时间为8小时,浸渍的溶液采用聚乙二醇二缩水甘油醚溶液,并且在pH值等于7.6条件下进行。In the step (2b), the raw silk is immersed for 8 hours, and the immersed solution is a polyethylene glycol diglycidyl ether solution, and the pH value is equal to 7.6.
所述桑蚕丝的纤度为20D;所述桑蚕丝的长度为5mm。The fineness of the mulberry silk is 20D; the length of the mulberry silk is 5 mm.
所述构成线圈的过程步骤为:The process steps of forming a coil are:
(1c)刚形成的线圈从针钩移至针杆,然后把纱线喂到织针上,接着把纱线弯曲成线圈的形状,最后把新垫上的纱线或刚弯成的线圈移至针钩内;(1c) The newly formed stitch is moved from the hook to the needle bar, and then the yarn is fed to the knitting needle, then the yarn is bent into the shape of a stitch, and finally the yarn on the new pad or the newly formed stitch is moved to Inside the hook
(2c)待步骤(1c)完成后,再封闭织针针口,然后把旧线圈套到针口闭合的针钩上。(2c) After step (1c) is completed, close the needle mouth of the knitting needle, and then put the old stitch on the hook with the needle mouth closed.
实施例2Example 2
一种立体丝绸仿毛皮面料,包括真丝绒毛层1、人造丝基底层2、粘合层3和仿皮绒层4,所述真丝绒毛层1通过针织的方式与所述人造丝基层1的上方固 定连接,所述人造丝基底层2和仿皮绒层4通过粘合层3粘合。其中,所述粘合层为热固型粘胶层。A three-dimensional silk imitation fur fabric, comprising a silk velvet layer 1, a rayon base layer 2, an adhesive layer 3 and an imitation leather velvet layer 4, the silk velvet layer 1 is knitted above the rayon base layer 1 by knitting With a fixed connection, the rayon base layer 2 and the imitation leather fleece layer 4 are adhered by an adhesive layer 3. Wherein, the adhesive layer is a thermosetting adhesive layer.
所述桑蚕丝的制备方法同实施例1。所述桑蚕丝的纤度为50D;所述桑蚕丝的长度为10mm。The preparation method of the mulberry silk is the same as that in Example 1. The fineness of the mulberry silk is 50D; the length of the mulberry silk is 10 mm.
所述桑蚕丝和人造丝进行纺织之前,还对桑蚕丝和人造丝进行抗菌改性处理,具体包括以下步骤:Before spinning the mulberry silk and rayon, the mulberry silk and rayon are also subjected to antibacterial modification treatment, specifically including the following steps:
(1d)将大黄粉碎后按质量比1:20的比例加入乙醇溶液中,在65~70℃提取2~3小时后,离心,将上清液浓缩后得到大黄提取物;(1d) After crushing rhubarb, add it to the ethanol solution at a mass ratio of 1:20, extract at 65-70 ° C for 2 to 3 hours, centrifuge, and concentrate the supernatant to obtain rhubarb extract;
(2d)将茜草粉碎后按质量比1:15的比例加入乙醇溶液中,在50~55℃提取3~6小时后,离心,将上清液浓缩后得到茜草提取物;(2d) Pulverize the rubia officinalis, add it to the ethanol solution at a mass ratio of 1:15, extract it at 50-55 ° C for 3-6 hours, centrifuge, and concentrate the supernatant to obtain the rubia officinalis extract;
(3d)将季铵盐壳聚糖加入质量分数为0.5%的柠檬酸溶液中,搅拌溶解后,加入大黄提取物和茜草提取物,搅拌均匀,得到抗菌混合液,其中,所述抗菌混合液中季铵盐壳聚糖的质量分数1.5%,所述抗菌混合液中大黄提取物的质量分数2%,所述抗菌混合液中茜草提取物的质量分数1.5%;(3d) Add quaternary ammonium salt chitosan to a citric acid solution with a mass fraction of 0.5%, stir and dissolve, add rhubarb extract and rubia extract, stir well to obtain an antibacterial mixed solution, wherein the antibacterial mixed solution The mass fraction of the medium quaternary ammonium salt chitosan is 1.5%, the mass fraction of the rhubarb extract in the antibacterial mixture is 2%, and the mass fraction of the rubia extract in the antibacterial mixture is 1.5%;
(4d)将桑蚕丝和人造丝浸入所述抗菌混合液中,桑蚕丝和人造丝的总质量与抗菌混合液的质量比为1:5,在45~50℃水浴振荡3~4小时后,将桑蚕丝和人造丝取出,烘干。(4d) Immerse the mulberry silk and rayon in the antibacterial mixture, the total mass ratio of the mulberry silk and rayon to the antibacterial mixture is 1: 5, and shake in a water bath at 45-50 ° C for 3-4 hours. Remove mulberry silk and rayon and dry.
所述桑蚕丝和人造丝的纺织方法同实施例1。The spinning method of the mulberry silk and the rayon is the same as in Example 1.
本实施例中采用的季铵盐壳聚糖的制备方法为:The preparation method of the quaternary ammonium salt chitosan used in this embodiment is:
将壳聚糖、异丙醇和氯化缩水三甲基铵按质量比1:30~40:0.1~0.2的比例混合,在80~90℃水浴加热反应15h,经过滤、洗涤、干燥,得到所述季铵盐壳聚糖。Mix chitosan, isopropanol and trimethylammonium chloride in a ratio of 1: 30-40: 0.1-0.2 by mass, heat and react in a water bath at 80-90 ° C for 15h, filter, wash and dry to obtain The quaternary ammonium salt chitosan.
实施例3Example 3
一种立体丝绸仿毛皮面料,包括真丝绒毛层1、人造丝基底层2、粘合层3和仿皮绒层4,所述真丝绒毛层1通过针织的方式与所述人造丝基层1的上方固定连接,所述人造丝基底层2和仿皮绒层4通过粘合层3粘合。其中,所述粘合层为热固型粘胶层。A three-dimensional silk imitation fur fabric, comprising a silk velvet layer 1, a rayon base layer 2, an adhesive layer 3 and an imitation leather velvet layer 4, the silk velvet layer 1 is knitted above the rayon base layer 1 by knitting With a fixed connection, the rayon base layer 2 and the imitation leather fleece layer 4 are adhered by an adhesive layer 3. Wherein, the adhesive layer is a thermosetting adhesive layer.
所述桑蚕丝的制备方法同实施例1。所述桑蚕丝的纤度为100D;所述桑蚕丝的长度为20mmThe preparation method of the mulberry silk is the same as that in Example 1. The fineness of the mulberry silk is 100D; the length of the mulberry silk is 20mm
所述桑蚕丝和人造丝进行纺织之前,对桑蚕丝和人造丝进行抗菌改性处理, 具体包括以下步骤:Before weaving the mulberry silk and rayon, performing antibacterial modification on the mulberry silk and rayon, specifically including the following steps:
(1d)将大黄粉碎后按质量比1:15的比例加入乙醇溶液中,在65~70℃提取2~3小时后,离心,将上清液浓缩后得到大黄提取物;(1d) After crushing rhubarb, add it to the ethanol solution at a mass ratio of 1:15, extract at 65-70 ° C for 2 to 3 hours, centrifuge, and concentrate the supernatant to obtain rhubarb extract;
(2d)将茜草粉碎后按质量比1:12的比例加入乙醇溶液中,在50~55℃提取3~6小时后,离心,将上清液浓缩后得到茜草提取物;(2d) After crushing the madder, add it to the ethanol solution at a mass ratio of 1:12, extract at 50-55 ° C for 3-6 hours, centrifuge, and concentrate the supernatant to obtain the madder extract;
(3d)将季铵盐壳聚糖加入质量分数为0.8%的柠檬酸溶液中,搅拌溶解后,加入大黄提取物和茜草提取物,搅拌均匀,得到抗菌混合液,其中,所述抗菌混合液中季铵盐壳聚糖的质量分数1.2%,所述抗菌混合液中大黄提取物的质量分数2.8%,所述抗菌混合液中茜草提取物的质量分数1%;(3d) Add quaternary ammonium salt chitosan to a citric acid solution with a mass fraction of 0.8%, stir and dissolve, add rhubarb extract and rubia extract, and stir evenly to obtain an antibacterial mixed solution, wherein The mass fraction of medium quaternary ammonium salt chitosan is 1.2%, the mass fraction of rhubarb extract in the antibacterial mixture is 2.8%, and the mass fraction of rubia extract in the antibacterial mixture is 1%;
(4d)将桑蚕丝和人造丝浸入所述抗菌混合液中,桑蚕丝和人造丝的总质量与抗菌混合液的质量比为1:8,在45~50℃水浴振荡3~4小时后,将桑蚕丝和人造丝取出,烘干。(4d) Immerse the mulberry silk and rayon in the antibacterial mixture, the total mass ratio of the mulberry silk and rayon to the antibacterial mixture is 1: 8, and shake in a water bath at 45-50 ° C for 3-4 hours. Remove mulberry silk and rayon and dry.
所述桑蚕丝和人造丝的纺织方法同实施例1。The spinning method of the mulberry silk and the rayon is the same as in Example 1.
实施例4Example 4
一种立体丝绸仿毛皮面料,包括真丝绒毛层1、人造丝基底层2、粘合层3和仿皮绒层4,所述真丝绒毛层1通过针织的方式与所述人造丝基层1的上方固定连接,所述人造丝基底层2和仿皮绒层4通过粘合层3粘合。其中,所述粘合层为热固型粘胶层。A three-dimensional silk imitation fur fabric, comprising a silk velvet layer 1, a rayon base layer 2, an adhesive layer 3 and an imitation leather velvet layer 4, the silk velvet layer 1 is knitted above the rayon base layer 1 by knitting With a fixed connection, the rayon base layer 2 and the imitation leather fleece layer 4 are adhered by an adhesive layer 3. Wherein, the adhesive layer is a thermosetting adhesive layer.
所述桑蚕丝的制备方法同实施例1。所述桑蚕丝的纤度为128D;所述桑蚕丝的长度为15mmThe preparation method of the mulberry silk is the same as that in Example 1. The fineness of the mulberry silk is 128D; the length of the mulberry silk is 15mm
所述桑蚕丝和人造丝进行纺织之前,对桑蚕丝和人造丝进行抗菌改性处理,具体包括以下步骤:Before spinning the mulberry silk and rayon, antibacterial modification treatment is performed on the mulberry silk and rayon, specifically including the following steps:
(1d)将大黄粉碎后按质量比1:10的比例加入乙醇溶液中,在65~70℃提取2~3小时后,离心,将上清液浓缩后得到大黄提取物;(1d) After crushing rhubarb, add it to ethanol solution at a mass ratio of 1:10, extract at 65-70 ° C for 2 to 3 hours, centrifuge, and concentrate the supernatant to obtain rhubarb extract;
(2d)将茜草粉碎后按质量比1:10的比例加入乙醇溶液中,在50~55℃提取3~6小时后,离心,将上清液浓缩后得到茜草提取物;(2d) Pulverize the rubia officinalis, add it to the ethanol solution at a mass ratio of 1:10, extract at 50-55 ° C for 3-6 hours, centrifuge, and concentrate the supernatant to obtain the rubia officinalis extract;
(3d)将季铵盐壳聚糖加入质量分数为1%的柠檬酸溶液中,搅拌溶解后,加入大黄提取物和茜草提取物,搅拌均匀,得到抗菌混合液,其中,所述抗菌混合液中季铵盐壳聚糖的质量分数1.4%,所述抗菌混合液中大黄提取物的质量分数2.4%,所述抗菌混合液中茜草提取物的质量分数1.2%;(3d) Add quaternary ammonium salt chitosan to a citric acid solution with a mass fraction of 1%, stir and dissolve, add rhubarb extract and rubia extract, and stir evenly to obtain an antibacterial mixed liquid, wherein the antibacterial mixed liquid The mass fraction of medium quaternary ammonium salt chitosan is 1.4%, the mass fraction of rhubarb extract in the antibacterial mixed solution is 2.4%, and the mass fraction of rubia extract in the antibacterial mixed solution is 1.2%;
(4d)将桑蚕丝和人造丝浸入所述抗菌混合液中,桑蚕丝和人造丝的总质量与抗菌混合液的质量比为1:10,在45~50℃水浴振荡3~4小时后,将桑蚕丝和人造丝取出,烘干。(4d) Immerse mulberry silk and rayon in the antibacterial mixture, the total mass ratio of mulberry silk and rayon to the antibacterial mixture is 1:10, and shake in a water bath at 45-50 ° C for 3-4 hours. Remove mulberry silk and rayon and dry.
所述桑蚕丝和人造丝的纺织方法同实施例1。The spinning method of the mulberry silk and the rayon is the same as in Example 1.
实施例5Example 5
一种立体丝绸仿毛皮面料,包括真丝绒毛层1、人造丝基底层2、粘合层3和仿皮绒层4,所述真丝绒毛层1通过针织的方式与所述人造丝基层1的上方固定连接,所述人造丝基底层2和仿皮绒层4通过粘合层3粘合。其中,所述粘合层为热固型粘胶层。A three-dimensional silk imitation fur fabric, comprising a silk velvet layer 1, a rayon base layer 2, an adhesive layer 3 and an imitation leather velvet layer 4, the silk velvet layer 1 is knitted above the rayon base layer 1 by knitting With a fixed connection, the rayon base layer 2 and the imitation leather fleece layer 4 are adhered by an adhesive layer 3. Wherein, the adhesive layer is a thermosetting adhesive layer.
所述桑蚕丝的制备方法同实施例1。所述桑蚕丝的纤度为128D;所述桑蚕丝的长度为15mmThe preparation method of the mulberry silk is the same as that in Example 1. The fineness of the mulberry silk is 128D; the length of the mulberry silk is 15mm
所述桑蚕丝和人造丝进行纺织之前,对桑蚕丝和人造丝进行抗菌改性处理,具体包括以下步骤:Before spinning the mulberry silk and rayon, antibacterial modification treatment is performed on the mulberry silk and rayon, specifically including the following steps:
(1d)将大黄粉碎后按质量比1:10的比例加入乙醇溶液中,在65~70℃提取2~3小时后,离心,将上清液浓缩后得到大黄提取物;(1d) After crushing rhubarb, add it to ethanol solution at a mass ratio of 1:10, extract at 65-70 ° C for 2 to 3 hours, centrifuge, and concentrate the supernatant to obtain rhubarb extract;
(2d)将茜草粉碎后按质量比1:10的比例加入乙醇溶液中,在50~55℃提取3~6小时后,离心,将上清液浓缩后得到茜草提取物;(2d) Pulverize the rubia officinalis, add it to the ethanol solution at a mass ratio of 1:10, extract at 50-55 ° C for 3-6 hours, centrifuge, and concentrate the supernatant to obtain the rubia officinalis extract;
(3d)将季铵盐壳聚糖加入质量分数为1%的柠檬酸溶液中,搅拌溶解后,加入大黄提取物和茜草提取物,搅拌均匀,得到抗菌混合液,其中,所述抗菌混合液中季铵盐壳聚糖的质量分数1.8%,所述抗菌混合液中大黄提取物的质量分数2%,所述抗菌混合液中茜草提取物的质量分数1.2%;(3d) Add quaternary ammonium salt chitosan to a citric acid solution with a mass fraction of 1%, stir and dissolve, add rhubarb extract and rubia extract, and stir evenly to obtain an antibacterial mixed liquid, wherein the antibacterial mixed liquid The mass fraction of medium quaternary ammonium salt chitosan is 1.8%, the mass fraction of rhubarb extract in the antibacterial mixture is 2%, and the mass fraction of rubia extract in the antibacterial mixture is 1.2%;
(4d)将桑蚕丝和人造丝浸入所述抗菌混合液中,桑蚕丝和人造丝的总质量与抗菌混合液的质量比为1:10,在45~50℃水浴振荡3~4小时后,将桑蚕丝和人造丝取出,烘干。(4d) Immerse mulberry silk and rayon in the antibacterial mixture, the total mass ratio of mulberry silk and rayon to the antibacterial mixture is 1:10, and shake in a water bath at 45-50 ° C for 3-4 hours. Remove mulberry silk and rayon and dry.
所述桑蚕丝和人造丝的纺织方法同实施例1。The spinning method of the mulberry silk and the rayon is the same as in Example 1.
实施例6Example 6
一种立体丝绸仿毛皮面料,包括真丝绒毛层1、人造丝基底层2、粘合层3和仿皮绒层4,所述真丝绒毛层1通过针织的方式与所述人造丝基层1的上方固定连接,所述人造丝基底层2和仿皮绒层4通过粘合层3粘合。其中,所述粘合层为热固型粘胶层。A three-dimensional silk imitation fur fabric, comprising a silk velvet layer 1, a rayon base layer 2, an adhesive layer 3 and an imitation leather velvet layer 4, the silk velvet layer 1 is knitted above the rayon base layer 1 by knitting With a fixed connection, the rayon base layer 2 and the imitation leather fleece layer 4 are adhered by an adhesive layer 3. Wherein, the adhesive layer is a thermosetting adhesive layer.
所述桑蚕丝的制备方法同实施例1。所述桑蚕丝的纤度为128D;所述桑蚕丝的长度为15mmThe preparation method of the mulberry silk is the same as that in Example 1. The fineness of the mulberry silk is 128D; the length of the mulberry silk is 15mm
所述桑蚕丝和人造丝进行纺织之前,对桑蚕丝和人造丝进行抗菌改性处理,具体包括以下步骤:Before spinning the mulberry silk and rayon, antibacterial modification treatment is performed on the mulberry silk and rayon, specifically including the following steps:
(1d)将大黄粉碎后按质量比1:10的比例加入乙醇溶液中,在65~70℃提取2~3小时后,离心,将上清液浓缩后得到大黄提取物;(1d) After crushing rhubarb, add it to ethanol solution at a mass ratio of 1:10, extract at 65-70 ° C for 2 to 3 hours, centrifuge, and concentrate the supernatant to obtain rhubarb extract;
(2d)将茜草粉碎后按质量比1:10的比例加入乙醇溶液中,在50~55℃提取3~6小时后,离心,将上清液浓缩后得到茜草提取物;(2d) Pulverize the rubia officinalis, add it to the ethanol solution at a mass ratio of 1:10, extract at 50-55 ° C for 3-6 hours, centrifuge, and concentrate the supernatant to obtain the rubia officinalis extract;
(3d)将季铵盐壳聚糖加入质量分数为1%的柠檬酸溶液中,搅拌溶解后,加入大黄提取物和茜草提取物,搅拌均匀,得到抗菌混合液,其中,所述抗菌混合液中季铵盐壳聚糖的质量分数1.8%,所述抗菌混合液中大黄提取物的质量分数1.5%,所述抗菌混合液中茜草提取物的质量分数5%;(3d) Add quaternary ammonium salt chitosan to a citric acid solution with a mass fraction of 1%, stir and dissolve, add rhubarb extract and rubia extract, and stir evenly to obtain an antibacterial mixed liquid, wherein the antibacterial mixed liquid The mass fraction of medium quaternary ammonium salt chitosan is 1.8%, the mass fraction of rhubarb extract in the antibacterial mixed solution is 1.5%, and the mass fraction of rubia extract in the antibacterial mixed solution is 5%;
(4d)将桑蚕丝和人造丝浸入所述抗菌混合液中,桑蚕丝和人造丝的总质量与抗菌混合液的质量比为1:10,在45~50℃水浴振荡3~4小时后,将桑蚕丝和人造丝取出,烘干。(4d) Immerse mulberry silk and rayon in the antibacterial mixture, the total mass ratio of mulberry silk and rayon to the antibacterial mixture is 1:10, and shake in a water bath at 45-50 ° C for 3-4 hours. Remove mulberry silk and rayon and dry.
所述桑蚕丝和人造丝的纺织方法同实施例1。The spinning method of the mulberry silk and the rayon is the same as in Example 1.
对比例1Comparative Example 1
一种立体丝绸仿毛皮面料,包括真丝绒毛层1、人造丝基底层2、粘合层3和仿皮绒层4,所述真丝绒毛层1通过针织的方式与所述人造丝基层1的上方固定连接,所述人造丝基底层2和仿皮绒层4通过粘合层3粘合。其中,所述粘合层为热固型粘胶层;所述桑蚕丝的纤度为20D;所述桑蚕丝的长度为15mm。A three-dimensional silk imitation fur fabric, comprising a silk velvet layer 1, a rayon base layer 2, an adhesive layer 3 and an imitation leather velvet layer 4, the silk velvet layer 1 is knitted above the rayon base layer 1 by knitting With a fixed connection, the rayon base layer 2 and the imitation leather fleece layer 4 are adhered by an adhesive layer 3. Wherein, the adhesive layer is a thermosetting adhesive layer; the fineness of the mulberry silk is 20D; and the length of the mulberry silk is 15mm.
所述桑蚕丝的制备方法同实施例1。The preparation method of the mulberry silk is the same as that in Example 1.
所述桑蚕丝和人造丝进行纺织之前,对桑蚕丝和人造丝进行抗菌改性处理,具体包括以下步骤:Before spinning the mulberry silk and rayon, antibacterial modification treatment is performed on the mulberry silk and rayon, specifically including the following steps:
(1d)将大黄粉碎后按质量比1:10的比例加入乙醇溶液中,在65~70℃提取2~3小时后,离心,将上清液浓缩后得到大黄提取物;(1d) After crushing rhubarb, add it to ethanol solution at a mass ratio of 1:10, extract at 65-70 ° C for 2 to 3 hours, centrifuge, and concentrate the supernatant to obtain rhubarb extract;
(2d)将茜草粉碎后按质量比1:10的比例加入乙醇溶液中,在50~55℃提取3~6小时后,离心,将上清液浓缩后得到茜草提取物;(2d) Pulverize the rubia officinalis, add it to the ethanol solution at a mass ratio of 1:10, extract at 50-55 ° C for 3-6 hours, centrifuge, and concentrate the supernatant to obtain the rubia officinalis extract;
(3d)将大黄提取物和茜草提取物加入质量分数为1%的柠檬酸溶液,搅拌均匀,得到抗菌混合液,其中,所述抗菌混合液中大黄提取物的质量分数4%, 所述抗菌混合液中茜草提取物的质量分数1%;(3d) Add rhubarb extract and rubia extract to a citric acid solution with a mass fraction of 1%, and stir evenly to obtain an antibacterial mixed liquid, wherein the mass fraction of rhubarb extract in the antibacterial mixed liquid is 4%, and the antibacterial The mass fraction of Rubia cordifolia extract in the mixed solution is 1%;
(4d)将桑蚕丝和人造丝浸入所述抗菌混合液中,桑蚕丝和人造丝的总质量与抗菌混合液的质量比为1:10,在45~50℃水浴振荡3~4小时后,将桑蚕丝和人造丝取出,烘干。(4d) Immerse mulberry silk and rayon in the antibacterial mixture, the total mass ratio of mulberry silk and rayon to the antibacterial mixture is 1:10, and shake in a water bath at 45-50 ° C for 3-4 hours. Remove mulberry silk and rayon and dry.
所述桑蚕丝和人造丝的纺织方法同实施例1。The spinning method of the mulberry silk and the rayon is the same as in Example 1.
对比例2Comparative Example 2
一种立体丝绸仿毛皮面料,包括真丝绒毛层1、人造丝基底层2、粘合层3和仿皮绒层4,所述真丝绒毛层1通过针织的方式与所述人造丝基层1的上方固定连接,所述人造丝基底层2和仿皮绒层4通过粘合层3粘合。其中,所述粘合层为热固型粘胶层;所述桑蚕丝的纤度为20D;所述桑蚕丝的长度为15mm。A three-dimensional silk imitation fur fabric, comprising a silk velvet layer 1, a rayon base layer 2, an adhesive layer 3 and an imitation leather velvet layer 4, the silk velvet layer 1 is knitted above the rayon base layer 1 by knitting With a fixed connection, the rayon base layer 2 and the imitation leather fleece layer 4 are adhered by an adhesive layer 3. Wherein, the adhesive layer is a thermosetting adhesive layer; the fineness of the mulberry silk is 20D; and the length of the mulberry silk is 15mm.
所述桑蚕丝的制备方法同实施例1。The preparation method of the mulberry silk is the same as that in Example 1.
所述桑蚕丝和人造丝进行纺织之前,对桑蚕丝和人造丝进行抗菌改性处理,具体包括以下步骤:Before spinning the mulberry silk and rayon, antibacterial modification treatment is performed on the mulberry silk and rayon, specifically including the following steps:
(1d)将季铵盐壳聚糖加入质量分数为1%的柠檬酸溶液中,搅拌溶解后,得到抗菌混合液,其中,所述抗菌混合液中季铵盐壳聚糖的质量分数5%;(1d) Add quaternary ammonium salt chitosan to a citric acid solution with a mass fraction of 1%, stir and dissolve to obtain an antibacterial mixed liquid, wherein the mass fraction of quaternary ammonium chitosan in the antibacterial mixed liquid is 5% ;
(2d)将桑蚕丝和人造丝浸入所述抗菌混合液中,桑蚕丝和人造丝的总质量与抗菌混合液的质量比为1:10,在45~50℃水浴振荡3~4小时后,将桑蚕丝和人造丝取出,烘干。(2d) Immerse the mulberry silk and rayon in the antibacterial mixture, the total mass ratio of the mulberry silk and rayon to the antibacterial mixture is 1:10, and shake in a water bath at 45-50 ° C for 3-4 hours. Remove mulberry silk and rayon and dry.
所述桑蚕丝和人造丝的纺织方法同实施例1。The spinning method of the mulberry silk and the rayon is the same as in Example 1.
抗菌性试验Antibacterial test
将实施例1~6和对比例1~2的制备好面料分别放置1天和6个月后,剪成0.3g正方形小块,编号后置于试管中,试管口塞上医用脱脂棉,在高压灭菌锅中用0.1MPa高压蒸汽灭菌30min。将培养基分装在试管中,并加入,2mL菌液和0.3g面料,将试管置于37℃水浴振荡培养,定时取样检测各组面料的抑菌率,结果如表1所示。After the prepared fabrics of Examples 1 to 6 and Comparative Examples 1 to 2 were placed for 1 day and 6 months, cut into 0.3g square pieces, numbered, and placed in test tubes. The mouth of the test tubes was plugged with medical absorbent cotton. Sterilize with 0.1MPa high-pressure steam for 30min. The medium was divided into test tubes, and 2 mL of bacterial solution and 0.3 g of fabric were added. The test tubes were placed in a 37 ° C water bath and shaken for culture. Samples were taken periodically to detect the antibacterial rate of each group of fabrics.
表1Table 1
Figure PCTCN2019070922-appb-000001
Figure PCTCN2019070922-appb-000001
Figure PCTCN2019070922-appb-000002
Figure PCTCN2019070922-appb-000002
由表1结果可知,本发明采用季铵盐壳聚糖、大黄提取物和茜草提取物对桑蚕丝和人造丝进行抗菌改性处理,并通过合理调整三者的配比,显著提高了面料的抗菌性,且季铵盐壳聚糖、大黄提取物和茜草提取物复配具有协同抗菌效果,且具有良好的抗菌持久性能。It can be seen from the results in Table 1 that the present invention uses quaternary ammonium salt chitosan, rhubarb extract and rubia root extract to carry out antibacterial modification treatment on mulberry silk and rayon. It is antibacterial, and the compound of quaternary ammonium salt chitosan, rhubarb extract and madder extract has synergistic antibacterial effect and has good antibacterial lasting performance.
白度测定Whiteness determination
将将实施例1~6和对比例1~2的桑蚕丝和人造丝均匀放入试剂盒中,用标准白度板校准WSB-3A白度计进行白度测定,结果如表2所示。Put the mulberry silk and rayon of Examples 1 to 6 and Comparative Examples 1 to 2 into the kit evenly, and calibrate the WSB-3A whiteness meter with a standard whiteness plate to perform whiteness measurement. The results are shown in Table 2.
表2Table 2
 A 白度(%)BaiDu(%)
实施例1Example 1 83.683.6
实施例2Example 2 82.882.8
实施例3Example 3 82.482.4
实施例4Example 4 82.682.6
实施例5Example 5 80.980.9
实施例6Example 6 72.572.5
对比例1Comparative Example 1 70.870.8
对比例2Comparative Example 2 74.274.2
由表2结果可知,由于季铵盐壳聚糖、大黄提取物和茜草提取物的加入会导致桑蚕丝和人造丝的白度降低,本发明通过进一步优化季铵盐壳聚糖、大黄提取物和茜草提取物的用量,在改善桑蚕丝和人造丝的抗菌性同时,避免桑蚕丝和人造丝白度大幅降低。It can be seen from the results in Table 2 that the addition of quaternary ammonium chitosan, rhubarb extract and madder extract will cause the whiteness of mulberry silk and rayon to decrease, and the present invention further optimizes the quaternary ammonium chitosan and rhubarb extract The amount of the extract of Rubia cordifolia can improve the antibacterial properties of mulberry silk and rayon while avoiding a significant decrease in the whiteness of mulberry silk and rayon.
综上所述,本发明以桑蚕丝作为绒毛原料,以人造丝为基底层原料,通过 采用大圆机进行纺织,在人造丝基底层上固定真丝绒毛层,并结合复合仿皮绒层,形成立体丝绸仿毛皮面料。真丝绒毛层光泽好,具有良好的立体结构与图案效果,赋予面料凹凸的立体感,线条流畅,视觉感好,与毛皮相比,成品重量更轻,与基底层结合更牢固,不容易将基底层撕破,且成本更低,生产速度更快,更环保。本发明采用人造丝作为基底层材料,与丝绸相比,质轻,成本更低。In summary, in the present invention, mulberry silk is used as the raw material for fluff, and rayon is used as the raw material for the base layer. The spinning is carried out by using a large circular machine to fix the silk velvet layer on the rayon base layer, and combined with the composite imitation leather layer to form a three-dimensional Silk imitation fur fabric. The silk velvet layer has good luster, has a good three-dimensional structure and pattern effect, gives the fabric a three-dimensional sense of unevenness, smooth lines, and good visual sense. Compared with fur, the finished product is lighter in weight and more firmly combined with the base layer. The bottom layer is torn, and the cost is lower, the production speed is faster, and it is more environmentally friendly. The invention uses rayon as the base layer material, which is lighter in weight and lower in cost than silk.
本发明通过采用大圆机进行纺织,能有效的节约原料的用量,简化或取消裁剪和缝纫工序,并能改善产品的服用性能,而且针织生产因工艺过程短,原料适应性强,翻改品种快,产品使用范围广,噪声小和能源消耗少,通过将桑蚕丝嵌合在人造丝上,能有效的增加了面料的立体效果,增强了面料外观对人眼视觉的冲击效果。本发明的模仿动物皮草,与动物皮毛相比,本发明的材料均为蛋白质,但在视觉效果上是一个重大突破,而且成本低、透气性好、更加环保、更人性。The invention can effectively save the amount of raw materials, simplify or cancel the cutting and sewing processes by using a large circular machine for spinning, and can improve the product taking performance. Moreover, the knitting production has a short process, strong adaptability to raw materials, and fast varieties. , The product has a wide range of use, low noise and low energy consumption. By fitting mulberry silk onto rayon, it can effectively increase the three-dimensional effect of the fabric and enhance the impact of the appearance of the fabric on human vision. Compared with animal fur, the material of the invention is protein, but the material of the invention is a protein, but it is a major breakthrough in visual effect, and has low cost, good breathability, more environmental protection and more humanity.
最后所应当说明的是,以上实施例仅用以说明本发明的技术方案而非对本发明保护范围的限制,尽管参照较佳实施例对本发明作了详细说明,本领域的普通技术人员应当理解,可以对本发明的技术方案进行修改或者等同替换,而不脱离本发明技术方案的实质和范围。Finally, it should be noted that the above embodiments are only for illustrating the technical solutions of the present invention rather than limiting the protection scope of the present invention. Although the present invention has been described in detail with reference to the preferred embodiments, persons of ordinary skill in the art should understand that The technical solutions of the present invention may be modified or equivalently replaced without departing from the spirit and scope of the technical solutions of the present invention.

Claims (10)

  1. 一种立体丝绸仿毛皮面料,其特征在于,包括真丝绒毛层(1)、人造丝基底层(2)粘合层(3)和仿皮绒层(4),所述真丝绒毛层(1)通过针织的方式与所述人造丝基层(1)的上方固定连接,所述人造丝基底层(2)和仿皮绒层(4)通过粘合层(3)粘合。A three-dimensional silk imitation fur fabric, characterized by comprising a silk velvet layer (1), a rayon base layer (2) an adhesive layer (3), and a leather-like velvet layer (4), the silk velvet layer (1) The upper part of the rayon base layer (1) is fixedly connected by knitting, and the rayon base layer (2) and the faux-leather layer (4) are adhered by an adhesive layer (3).
  2. 根据权利要求1所述的立体丝绸仿毛皮面料,其特征在于,所述真丝绒毛层(1)以桑蚕丝作为绒毛原料;所述人造丝基底层(2)以人造丝为原料,所述真丝绒毛层(1)和人造丝基底层(2)通过大圆机纺织形成,具体包括以下步骤:The three-dimensional silk imitation fur fabric according to claim 1, characterized in that the silk down layer (1) uses mulberry silk as the down raw material; the rayon base layer (2) uses rayon as the raw material, the silk The pile layer (1) and the rayon base layer (2) are formed by spinning on a large circular machine, and specifically include the following steps:
    (1a)以桑蚕丝作为绒毛原料,以人造丝作为基底层原料,将桑蚕丝和人造丝放入到大圆机上;(1a) Using mulberry silk as the raw material for fluff and rayon as the raw material for the base layer, put the mulberry silk and rayon on the large circular machine;
    (2a)大圆机利用纱线构成线圈,经过纵向串套和横向连接成为表面固定有真丝绒毛层的人造丝基底层。(2a) The large circular knitting machine uses yarns to form coils, which are connected through a longitudinal string and a horizontal direction to form a rayon base layer with a silk velvet layer fixed on the surface.
  3. 根据权利要求2所述的立体丝绸仿毛皮面料,其特征在于,所述桑蚕丝的纤度为20~128D。The three-dimensional silk imitation fur fabric according to claim 2, wherein the fineness of the mulberry silk is 20-128D.
  4. 根据权利要求3所述的立体丝绸仿毛皮面料,其特征在于,所述桑蚕丝的长度为5~20mm。The three-dimensional silk imitation fur fabric according to claim 3, wherein the length of the mulberry silk is 5-20 mm.
  5. 根据权利要求2所述的立体丝绸仿毛皮面料,其特征在于,所述桑蚕丝的制备方法包括以下步骤:The three-dimensional silk imitation fur fabric according to claim 2, wherein the preparation method of the mulberry silk comprises the following steps:
    (1b)将蚕茧浸在60~80℃的热水中,进行抽丝,并卷绕于丝筐上;(1b) Immerse the silkworm cocoons in hot water at 60 ~ 80 ℃, draw the silk, and wind it on the silk basket;
    (2b)待步骤(1b)完成后,再筛选出优良的生丝,接着将生丝进行浸渍去除丝胶;(2b) After step (1b) is completed, the excellent raw silk is selected, and then the raw silk is dipped to remove sericin;
    (3b)待步骤(2b)完成后,再将去除丝胶的生丝放入到烘干房内进行烘干,烘干时间为12小时;(3b) After the step (2b) is completed, put the raw silk with the sericin removed into the drying room for drying. The drying time is 12 hours;
    (4b)待步骤(3b)完成后,再将烘干的生丝进行络丝、并丝、捻丝、止捻、成绞,得到所述桑蚕丝。(4b) After the step (3b) is completed, the dried raw silk is wound, paralleled, twisted, twisted and twisted to obtain the mulberry silk.
  6. 根据权利要求5所述的立体丝绸仿毛皮面料,其特征在于,所述步骤(2b)中,生丝浸渍的时间为8小时,浸渍的溶液采用聚乙二醇二缩水甘油醚溶液, 并且在pH值等于7.6条件下进行。The three-dimensional silk imitation fur fabric according to claim 5, characterized in that, in the step (2b), the dipping time of the raw silk is 8 hours, the dipping solution is a polyethylene glycol diglycidyl ether solution, and the pH is The value is equal to 7.6.
  7. 根据权利要求2所述的立体丝绸仿毛皮面料,其特征在于,所述构成线圈的过程步骤为:The three-dimensional silk imitation fur fabric according to claim 2, wherein the process steps of forming the coil are:
    (1c)将刚形成的线圈从针钩移至针杆,然后把纱线喂到织针上,接着把纱线弯曲成线圈的形状,最后把新垫上的纱线或刚弯成的线圈移至针钩内;(1c) Move the newly formed stitch from the hook to the needle bar, and then feed the yarn to the knitting needle, then bend the yarn into the shape of a stitch, and finally move the yarn on the new pad or the newly bent stitch Into the hook
    (2c)待步骤(1c)完成后,再封闭织针针口,然后把旧线圈套到针口闭合的针钩上。(2c) After step (1c) is completed, close the needle mouth of the knitting needle, and then put the old stitch on the hook with the needle mouth closed.
  8. 根据权利要求2所述的立体丝绸仿毛皮面料,其特征在于,所述桑蚕丝和人造丝进行纺织之前,还对桑蚕丝和人造丝进行抗菌改性处理,具体包括以下步骤:The three-dimensional silk imitation fur fabric according to claim 2, wherein before the mulberry silk and rayon are woven, antibacterial modification treatment is also performed on the mulberry silk and rayon, specifically including the following steps:
    (1d)将大黄粉碎后按质量比1:10~20的比例加入乙醇溶液中,在65~70℃提取2~3小时后,离心,将上清液浓缩后得到大黄提取物;(1d) After crushing rhubarb, add it to the ethanol solution at a mass ratio of 1: 10-20, extract it at 65-70 ° C for 2-3 hours, centrifuge, and concentrate the supernatant to obtain rhubarb extract;
    (2d)将茜草粉碎后按质量比1:10~15的比例加入乙醇溶液中,在50~55℃提取3~6小时后,离心,将上清液浓缩后得到茜草提取物;(2d) After crushing the madder, add it to the ethanol solution at a mass ratio of 1: 10-15, extract it at 50-55 ° C for 3-6 hours, centrifuge, and concentrate the supernatant to obtain the madder extract;
    (3d)将季铵盐壳聚糖加入质量分数为0.5%~1%的柠檬酸溶液中,搅拌溶解后,加入大黄提取物和茜草提取物,搅拌均匀,得到抗菌混合液,其中,所述抗菌混合液中季铵盐壳聚糖的质量分数1.2%~1.8%,所述抗菌混合液中大黄提取物的质量分数2%~4%,所述抗菌混合液中茜草提取物的质量分数1%~1.5%;(3d) Add quaternary ammonium salt chitosan to a citric acid solution with a mass fraction of 0.5% to 1%. After stirring and dissolving, add rhubarb extract and madder extract and stir evenly to obtain an antibacterial mixed solution. The mass fraction of the quaternary ammonium salt chitosan in the antibacterial mixed solution is 1.2% to 1.8%, the mass fraction of the rhubarb extract in the antibacterial mixed solution is 2% to 4%, and the mass fraction of the rubia extract in the antibacterial mixed solution is 1 % ~ 1.5%;
    (4d)将桑蚕丝和人造丝浸入所述抗菌混合液中,桑蚕丝和人造丝的总质量与抗菌混合液的质量比为1:5~10,在45~50℃水浴振荡3~4小时后,将桑蚕丝和人造丝取出,烘干。(4d) Immerse the mulberry silk and rayon in the antibacterial mixture, the total mass ratio of the mulberry silk and rayon to the antibacterial mixture is 1: 5 ~ 10, and shake in a water bath at 45 ~ 50 ℃ for 3-4 hours After that, the mulberry silk and rayon are taken out and dried.
  9. 根据权利要求8所述的立体丝绸仿毛皮面料,其特征在于,所述抗菌混合液中季铵盐壳聚糖的质量分数1.4%,所述抗菌混合液中大黄提取物的质量分数2.4%,所述抗菌混合液中茜草提取物的质量分数1.2%。The three-dimensional silk imitation fur fabric according to claim 8, wherein the mass fraction of the quaternary ammonium salt chitosan in the antibacterial mixture is 1.4%, and the mass fraction of rhubarb extract in the antibacterial mixture is 2.4%. The mass fraction of Rubia cordifolia extract in the antibacterial mixed solution is 1.2%.
  10. 根据权利要求1~9任一项所述的立体丝绸仿毛皮面料,其特征在于,所述粘合层(3)为热固型粘胶层。The three-dimensional silk imitation fur fabric according to any one of claims 1 to 9, wherein the adhesive layer (3) is a thermosetting adhesive layer.
PCT/CN2019/070922 2018-11-13 2019-01-09 Stereoscopic silk imitation fur fabric WO2020098137A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN201811351567.8A CN109501399B (en) 2018-11-13 2018-11-13 Three-dimensional silk fur-like fabric
CN201811351567.8 2018-11-13

Publications (1)

Publication Number Publication Date
WO2020098137A1 true WO2020098137A1 (en) 2020-05-22

Family

ID=65748408

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/CN2019/070922 WO2020098137A1 (en) 2018-11-13 2019-01-09 Stereoscopic silk imitation fur fabric

Country Status (2)

Country Link
CN (1) CN109501399B (en)
WO (1) WO2020098137A1 (en)

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0342572B2 (en) * 1983-08-15 1991-06-27
JPH04163377A (en) * 1990-10-25 1992-06-08 Toyo Cloth Kk Production of synthetic leather
CN102486010A (en) * 2010-12-06 2012-06-06 常熟市卓辉针纺织有限公司 Method for processing imitation leather fabric
CN102485477A (en) * 2010-12-06 2012-06-06 常熟市卓辉针纺织有限公司 Man-made leather material
CN105538806A (en) * 2016-02-04 2016-05-04 江阴泽万贸易有限公司 Three-dimensional woven and knitted composite flannel
CN108660518A (en) * 2018-04-10 2018-10-16 湖州金玺丝绸有限公司 A kind of solid 3D fur silks

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1296098A (en) * 1999-11-11 2001-05-23 余兴宝 Silk velvet
EP2486920B1 (en) * 2009-09-28 2018-12-26 Toyobo Co., Ltd. Stress-alleviating agent comprising plant-derived polyamine-containing extract as active ingredient
WO2016026723A2 (en) * 2014-08-19 2016-02-25 Cutech Srl Extracts of nannochloropsis sp. and their applications
CN104432590B (en) * 2014-10-31 2016-06-01 湖州吴兴道场城乡建设发展有限公司 A kind of antibacterial underwear fabric and its preparation method

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0342572B2 (en) * 1983-08-15 1991-06-27
JPH04163377A (en) * 1990-10-25 1992-06-08 Toyo Cloth Kk Production of synthetic leather
CN102486010A (en) * 2010-12-06 2012-06-06 常熟市卓辉针纺织有限公司 Method for processing imitation leather fabric
CN102485477A (en) * 2010-12-06 2012-06-06 常熟市卓辉针纺织有限公司 Man-made leather material
CN105538806A (en) * 2016-02-04 2016-05-04 江阴泽万贸易有限公司 Three-dimensional woven and knitted composite flannel
CN108660518A (en) * 2018-04-10 2018-10-16 湖州金玺丝绸有限公司 A kind of solid 3D fur silks

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
MENGMENG GUO ET AL: "Application of the antibacterial agents in fiber and fabric", PROGRESS IN TEXTILE SCIENCE & TECHNOLOGY, no. 1, 25 February 2012 (2012-02-25), pages 14 - 16,25, XP009521241, ISSN: 1673-0356, DOI: 10.19507/j.cnki.1673-0356.2012.01.005 *

Also Published As

Publication number Publication date
CN109501399B (en) 2021-02-09
CN109501399A (en) 2019-03-22

Similar Documents

Publication Publication Date Title
WO2017071198A1 (en) Method for preparing knitted wool-like warm fabric
CN104352121B (en) A kind of method adopting plate cocoon to prepare silkworm silk quilt
CN103835054A (en) Ceiba textile with natural anti-mite function and processing technique thereof
CN103898645A (en) Production method of worsted shell fabric containing polyolefin elastic fibers
CN103898765A (en) Production method of polylactic-acid-fiber-containing spun wool fabric
CN106480577A (en) The production technology of worsted fabric
CN103334314A (en) Bamboo charcoal fiber fabric for underwear, as well as processing method of bamboo charcoal fiber fabric
CN106063659A (en) A kind of production technology of copper ion antibacterial and deodouring fiber raschel blanket
CN103628218A (en) Coffee carbon heat preservation fabric
CN104947223A (en) Low-damage green ecological bacteriostatic down fiber and making method thereof
CN107650448A (en) A kind of underwear antibiotic facing material and preparation method thereof
CN103898646A (en) Production method of worsted shell fabric containing stainless steel fibers
CN103898745A (en) Production method of Newdal-fiber-containing spun wool fabric
CN106480576A (en) The technique of anti pilling worsted fabric
WO2020098137A1 (en) Stereoscopic silk imitation fur fabric
CN110318139B (en) Preparation method of fiber fabric with ultraviolet resistance function
CN110037364A (en) A kind of cashmere sweater clothing technique
CN202820581U (en) Super soft thermal polyester cloud blanket
CN106987970A (en) The manufacture craft of cuprammonium Silk antistatic spinning fancy suiting
CN105167479B (en) Composite blanket
CN103266406A (en) Manufacturing technique of pupa protein silk fiber Raschel blanket
CN103628267B (en) Polyamide fiber and polyester fiber composite synthesis are removed from office and processing technology
CN206396403U (en) A kind of anti-fracture anti pilling double-sided polar fleece fabric
CN106480564A (en) The production method of the worsted fabric containing polyolefin elastic fiber
CN202820582U (en) Soy protein composition fiber cotton blanket

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 19885023

Country of ref document: EP

Kind code of ref document: A1

NENP Non-entry into the national phase

Ref country code: DE

122 Ep: pct application non-entry in european phase

Ref document number: 19885023

Country of ref document: EP

Kind code of ref document: A1