WO2020060506A1 - Composites bois-plastique renforcés par des cordes - Google Patents

Composites bois-plastique renforcés par des cordes Download PDF

Info

Publication number
WO2020060506A1
WO2020060506A1 PCT/TR2018/050518 TR2018050518W WO2020060506A1 WO 2020060506 A1 WO2020060506 A1 WO 2020060506A1 TR 2018050518 W TR2018050518 W TR 2018050518W WO 2020060506 A1 WO2020060506 A1 WO 2020060506A1
Authority
WO
WIPO (PCT)
Prior art keywords
profile
die head
melt
long fibers
ropes
Prior art date
Application number
PCT/TR2018/050518
Other languages
English (en)
Inventor
Nurettin YALCIN
Mehmet YALCIN
Melis YALCIN
Original Assignee
Galiboff Plastik Kompozit Ekstruzyon Teknolojileri Ltd. Şti.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Galiboff Plastik Kompozit Ekstruzyon Teknolojileri Ltd. Şti. filed Critical Galiboff Plastik Kompozit Ekstruzyon Teknolojileri Ltd. Şti.
Priority to PCT/TR2018/050518 priority Critical patent/WO2020060506A1/fr
Priority to EP18934427.8A priority patent/EP3853009A4/fr
Publication of WO2020060506A1 publication Critical patent/WO2020060506A1/fr

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/36Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
    • B29C48/395Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/022Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the choice of material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/03Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
    • B29C48/12Articles with an irregular circumference when viewed in cross-section, e.g. window profiles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/15Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor incorporating preformed parts or layers, e.g. extrusion moulding around inserts
    • B29C48/156Coating two or more articles simultaneously
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/16Articles comprising two or more components, e.g. co-extruded layers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/16Articles comprising two or more components, e.g. co-extruded layers
    • B29C48/18Articles comprising two or more components, e.g. co-extruded layers the components being layers
    • B29C48/21Articles comprising two or more components, e.g. co-extruded layers the components being layers the layers being joined at their surfaces
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/256Exchangeable extruder parts
    • B29C48/2568Inserts
    • B29C48/25686Inserts for dies
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/285Feeding the extrusion material to the extruder
    • B29C48/288Feeding the extrusion material to the extruder in solid form, e.g. powder or granules
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/285Feeding the extrusion material to the extruder
    • B29C48/288Feeding the extrusion material to the extruder in solid form, e.g. powder or granules
    • B29C48/2883Feeding the extrusion material to the extruder in solid form, e.g. powder or granules of preformed parts, e.g. inserts fed and transported generally uninfluenced through the extruder or inserts fed directly to the die
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/30Extrusion nozzles or dies
    • B29C48/304Extrusion nozzles or dies specially adapted for bringing together components, e.g. melts within the die
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/30Extrusion nozzles or dies
    • B29C48/32Extrusion nozzles or dies with annular openings, e.g. for forming tubular articles
    • B29C48/34Cross-head annular extrusion nozzles, i.e. for simultaneously receiving moulding material and the preform to be coated
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/36Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
    • B29C48/49Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using two or more extruders to feed one die or nozzle
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/06Fibrous reinforcements only
    • B29C70/10Fibrous reinforcements only characterised by the structure of fibrous reinforcements, e.g. hollow fibres
    • B29C70/16Fibrous reinforcements only characterised by the structure of fibrous reinforcements, e.g. hollow fibres using fibres of substantial or continuous length
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2105/00Condition, form or state of moulded material or of the material to be shaped
    • B29K2105/06Condition, form or state of moulded material or of the material to be shaped containing reinforcements, fillers or inserts
    • B29K2105/08Condition, form or state of moulded material or of the material to be shaped containing reinforcements, fillers or inserts of continuous length, e.g. cords, rovings, mats, fabrics, strands or yarns
    • B29K2105/10Cords, strands or rovings, e.g. oriented cords, strands or rovings
    • B29K2105/101Oriented
    • B29K2105/105Oriented uni directionally
    • B29K2105/106Oriented uni directionally longitudinally
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2105/00Condition, form or state of moulded material or of the material to be shaped
    • B29K2105/06Condition, form or state of moulded material or of the material to be shaped containing reinforcements, fillers or inserts
    • B29K2105/12Condition, form or state of moulded material or of the material to be shaped containing reinforcements, fillers or inserts of short lengths, e.g. chopped filaments, staple fibres or bristles

Definitions

  • This invention relates to system for manufacturing natural fiber filled thermoplastic and thermoset composite materials and processes for their manufacture.
  • it relates to cellulose fiber filled compositions reinforced by injected ropes which have high strength, elastic modulus and density values inside the profile, and processes for their manufacture.
  • Composite materials are often optimized by selecting components for their strength, stiffness, flexibility, and durability. Current development is focused on improving material qualities ranging from strength to durability, as well as improving the compatibility of matrix components for longer lasting products and examining new manufacturing methods for ropes reinforced wood plastics composites.
  • Wood-plastic composites are a product class that has been developing over the last 40 years resulting in increased applications and expanded market share.
  • Thermoplastics are a class of polymers that can be heated and softened, cooled and hardened, high density polyethylene (HDPE), polypropylene (PP) and polyvinyl chloride (PVC) are the most common thermoplastic polymers used in WPC (Klyosov 2007) (1) .
  • Wood has many advantages to traditional fillers like lower cost, relatively high strength to weight ratio, low density, is relatively soft and easily integrated into existing plastic production lines.
  • Mesh sizes of particles used in WPCs will vary depending upon the desired product properties and finish and are most commonly from 10 to 80 meshes (Patterson 2001 ; Clemons 2002) (2) .
  • WPCs started being produced by the plastics industry which had prior expertise in processing and manufacturing of plastic products (Clemons 2002) i3 ) . This industry had used filler materials in the past and when wood became a viable option; it was integrated into their existing production lines. WPCs starting in a molten state can be formed into highly detailed, linear profiles using extrusion processes. In any thermoplastic composite, the components must first be blended together and then later formed into the desired product.
  • Mixing or compounding is the act of combining the wood and polymer components together. It is also important in this step to wet or encapsulate the wood particles with the polymer. Proper dispersion and wetting allow uniform and more effective load transfer to occur throughout the composite. If not compounded properly, the composite will have reduced mechanical properties compared with an optimally compounded blend and increases the risk of durability issues. After compounding, the material can go directly to shape formation of the final product or can be chipped into pellets for later use.
  • Extruders serve the two main purposes of compounding the wood and filler, and then forming the shape of the extruded profile.
  • the wood and polymer components are metered and fed into the extruder and mixed using single or twin-screw configurations.
  • the screws act to mix and move the material forward.
  • the mix is heated through friction between the barrel, screw, and wood-polymer mix as well as by heated zones along the length.
  • a die At the end of the extruder is a die through which the material is fed, forming the desired profile.
  • Twin screw extruders are sometimes used as compounding units for producing pre -blended pellets.
  • Composite materials are often optimized by selecting components for their strength, stiffness, flexibility, and durability. When compared with individual materials, composites may also offer more consistent performance, lower production costs, and create an avenue for the utilization of renewable resources.
  • WPCs are no different and are formulated to meet the needs of the consumer by finding the right balance of these properties. Mechanical properties and durability are among the most important to WPCs.
  • WPC decking making up the largest share of the WPC market (Clemons 2002) i4) , we can look at mechanical properties important to this market.
  • WPC deck boards are subjected to bending when they span a gap between supports and are being dynamically loaded when walked on and supporting the static loads (e.g. furniture and grills). For decking, this is important for limiting deflection of the product. It should be mentioned that a true elastic response in plastic composites is debatable, and the response of the material is highly dependent on the testing rate, temperature, previous history of the specimen, etc. WPC formulations and specimens from different testing facilities are difficult, but for research and development purposes determining these values as a comparison is helpful. WPCs have found success in a variety of markets including outdoor decking, railings, fences and landscaping timbers, but the number of applications for WPCs is limited to service requiring high -mechanical performance (Clemons 2002) (5) .
  • WPCs When compared with solid wood materials, Table 1, WPCs have lower mechanical properties in strength, stiffness, and creep resistance.
  • Elastic and strength properties are the primary criteria to select materials or to establish design or product specifications. Common applications include decking, railings, window profiles, roof tiles, and siding. These lumber products are generally manufactured using profile extrusion. Flexural and tensile properties of wood plastic composite (WPC) lumber generally fall between those of solid wood lumber. According to Table 1, most commercial wood plastic composites are considerably less stiff than solid wood (Clemons 2002) i6) .
  • thermoplastics-based wood filled composites WPC
  • head and die arrangements to feed ropes into extruded materials to increase flexural properties, impact resistance and tensile properties of extruded profile.
  • Fiber physical properties we can choose reinforcing material, predict how many ropes shall we use according to cross section of the profile and calculate the diameter of ropes for certain profile application. Using different materials with different rope’s diameter we can create materials with whatever mechanical properties we need. According to application of the profile we can choose reinforcing ropes (C) from Table 2 and Table 3 knowing that mechanical properties of polymer rope ⁇ hemp ⁇ steel wire ⁇ carbon nanotubes graphene rope.
  • Reinforcing ropes (C) are injected inside the profile through injectors (5) by extruder (11) together with long fibers and resins materials (B2) composition.
  • Other reinforcing materials are Composite and Textile Straps D materials:
  • Composite Strapping (D) is produced by a co-extrusion where polyester fibers are covered with plastic. Tensile strength of the strapping depends on the number and diameter of the fibers used.
  • Textile Strapping (D) is manufactured by hot-melt gluing polyester fibers together. Physical properties of the strapping are function of the number and the diameter of the fiber used.
  • Textile and Composite Straps are injected inside by extruder (11) together with (B2) composition and outside application by extruder (12) together with long fibers and resins materials (Bl) composition.
  • Reinforcing long fibers and resins materials (B) are extruded with extruder (11) as an intermediate filament formation (B2) and extruder (12) as an outside layer film (Bl) onto the profile (8).
  • Composite materials (B) contains plastic resins from 30% to 70% and long fibers up to 20 mm fiber elongation which content is from 70% to 30% respectively to plastic resins. Reinforced fibers are chosen from materials in Table 2.
  • Reinforcing ropes (C) (9) are forcibly extruded through injectors (5) by extruder (11) with (B2) materials which is surrounding the ropes inside the profile (8).
  • rope reinforced WPC profiles can be used as construction materials. They will replace wood beams and boards so trees will grow in factories. This application is done with adding (injecting) materials with strong Mechanical Properties to the recipe. And with calculating injected material for certain cross section beam, we can reach times better Mechanical Properties by making choice of added material from Table 2 and Table 3 and reach more and more the existing hardest wood beam properties.
  • New ropes reinforced composite profiles, beams, lumbers and deck boards will be resistant to bending according to injected rope material, radius of cross section and quantity.
  • Ultimate tensile stress (UTS) is the maximum stress that a material can be subjected to before breaking.
  • Modulus of elasticity (MOE) refers to a material’s ability to resist deformation and in a general sense is the stiffness of the material. Both the ultimate tensile stress (UTS) and modulus of elasticity (MOE) are increased properties in this case by adding reinforced materials like Polymer ⁇ Hemp ⁇ Steel wire ⁇ Graphene ropes. The number of applications for new rope RWPC is unlimited to service requiring high-mechanical performance of the extruded profile.
  • new rope RWPC When compared with solid wood materials, Table 1, new rope RWPC will have higher mechanical properties in strength, stiffness, and creep resistance by injecting reinforced materials like polymer ⁇ hemp ⁇ steel wire ⁇ graphene ropes. Elastic and strength properties of these materials are the primary criteria to select or to establish design or product specifications for common applications include decking, railings, window profiles, roof tiles, construction timbers and siding profiles. Flexural and tensile properties of new Rope Reinforced Wood Plastic Composites (RRWPC) lumber profile will be increased as much as used ropes number and cross-sectional area of used ropes are.
  • RRWPC Rope Reinforced Wood Plastic Composites
  • Extrusion Process front view is a cross sectional illustration of an exemplary profile extrusion in accordance with an embodiment of the present invention.
  • FIG. 2 Extrusion Process top view is a cross sectional illustration of an exemplary profile extrusion in accordance with Figure 1.
  • FIG. 3 Extrusion Process top view is a cross sectional illustration of an exemplary Complex head with a die (7) connection with Extruder XI (4) for wood plastic composites (WPC) mixture (A) extrusion, Extruder X3 (12) for outside application of long fibers and plastics mixture materials (B l) extrusion, Extruder X2 (11) for inside extrusion of long fibers and plastics mixture materials (B2) extrusion together with injection of reinforcing ropes (C) and composite straps (D).
  • Figure 4 Cross sectional view of extruded profile with materials A, Bl thick outside film and B2 as intermediate filaments with changeable radius applications.
  • Figure 5 Cross sectional view of extruded profile with materials A, Bl and B2 together with reinforcing ropes C.
  • Figure 6 Cross sectional view of extruded profile with materials A, B2 as tube filament and Bl together with composite straps D-outside application.
  • Figure 7 Cross sectional view of extruded profile with materials A, Bl and B2 together with composite straps D-inside application.
  • Figure 8 Cross sectional view of extruded profile with materials A, Bl and B2 together with C and composite straps D-outside application.
  • Figure 9 Cross sectional view of extruded profile with materials A, Bl and B2 together with reinforcing ropes C and composite straps D-inside application.
  • Figure 10 Cross sectional view of Complex head with a die for extrusion of materials A, B 1 thick film and B2 as tube filaments.
  • Figure 11 Cross sectional view of Complex head with a die for extrusion of materials A, B l and B2 together with reinforcing ropes C.
  • Figure 12 Cross sectional view of Complex head with a die for extrusion of materials A, B 1 and B2 together with composite straps D-inside application.
  • Figure 13 Cross sectional view of Complex head with a die for extrusion of materials A, Bl and B2 together with composite straps D outside application.
  • Figure 14 Cross sectional view of Complex head with a die for extrusion of materials A, B 1 and B2 together with reinforcing ropes C and composite straps D inside application.
  • Ropes- Reinforcing materials such as: steel wire rope, hemp fiber rope, polymer fiber rope or carbon nanotubes graphene fiber rope (C) and composite and textile straps (D)
  • reinforcing ropes such as: steel wire rope, hemp fiber rope, polymer fiber rope or carbon nanotubes graphene fiber rope
  • a system for manufacturing ropes reinforced wood plastic composites profiles wherein the system comprises, feeding injectors (5) fixed in complex die head (7) to supply reinforcing ropes and apply them inside and outside surface of the profile (8) and surround them by long fibers and plastics mixture melt (B1 and B2),
  • extruder XI to supply wood plastic composite mixture (A) melt to complex die head
  • extruder X3 to supply long fibers and plastics mixture (Bl) melt to complex die head (7) for profile’s outside film formation and surround reinforcing ropes (C) and straps (D) supplied,
  • extruder X2 to supply long fibers and plastics mixture (B2) melt to complex die head (7) for profile’s inner filament formation and surround reinforcing ropes (C) and straps (D) supplied,
  • complex die head (7) with melt chambers (14, 15 and 17) to receive molten mixture, complex die head (7) with injectors (5.1) to supply long fibers and plastics mixture (B2) melt to complex die head for profile’s inner filament formation,
  • extrusion die (7.1,7.2, 7.3, 7.4, 7.5) design for final shape forming of profiles such as circular, square, rectangular, I, H, U cross sections.
  • wood plastic composites materials which cellulose containing is variable from 30% to 70% by weight or ready to use wood plastic composites (WPC) granules from granules suppliers (A),
  • long fibers and thermoplastic materials composition (Bl, B2) with variable ratio from 40% to 60% respectively.
  • Long fibers which length is up to 20 mm are chosen from materials Hemp, ABS Plastic, Nylon, Carbon steel, Graphene, Aramid HT, Aramid copolymer, Aramid SM, Gel-spun PE, LC polyester, Steel wire, polypropylene, Bexcoline, Polyester, Nylon,
  • continuous reinforcing ropes (C) with variable diameter cross section are chosen from materials Hemp, ABS Plastic, Nylon, Carbon steel, Graphene, Aramid HT, Aramid copolymer, Aramid SM, Gel-spun PE, LC polyester, Steel wire, polypropylene, Bexcoline, Polyester, Nylon,
  • continuous reinforcing textile or composite straps (D) which physical properties are function of the number and the diameter of the fiber used from different suppliers.

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Composite Materials (AREA)
  • Extrusion Moulding Of Plastics Or The Like (AREA)

Abstract

La présente invention concerne un système d'extrusion de composite bois-plastique, le système comprenant trois extrudeuses et une tête complexe avec une matrice de formation de profil. La présente invention comprend un appareil pour extruder en continu un mélange de composites bois-plastique, co-extruder des fibres longues et un mélange de composition de matières thermoplastiques conjointement avec des cordes et des sangles de renforcement en tant que couche externe sur une surface de profil et co-extruder de manière forcée des cordes et des sangles de renforcement conjointement avec des fibres longues et un mélange de composition de matières thermoplastiques à l'intérieur du profil en formant des filaments intermédiaires et entourant en même temps les cordes et les sangles. Le mélange co-extrudé de matière plastique fondue favorise la liaison de cordes et de sangles de renforcement avec un mélange de composites bois-plastique.
PCT/TR2018/050518 2018-09-21 2018-09-21 Composites bois-plastique renforcés par des cordes WO2020060506A1 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
PCT/TR2018/050518 WO2020060506A1 (fr) 2018-09-21 2018-09-21 Composites bois-plastique renforcés par des cordes
EP18934427.8A EP3853009A4 (fr) 2018-09-21 2018-09-21 Composites bois-plastique renforcés par des cordes

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/TR2018/050518 WO2020060506A1 (fr) 2018-09-21 2018-09-21 Composites bois-plastique renforcés par des cordes

Publications (1)

Publication Number Publication Date
WO2020060506A1 true WO2020060506A1 (fr) 2020-03-26

Family

ID=69888824

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/TR2018/050518 WO2020060506A1 (fr) 2018-09-21 2018-09-21 Composites bois-plastique renforcés par des cordes

Country Status (2)

Country Link
EP (1) EP3853009A4 (fr)
WO (1) WO2020060506A1 (fr)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP7023476B1 (ja) * 2020-11-20 2022-02-22 中川産業株式会社 筋金棒体成形用金型およびこれを使用した筋金棒体の製造方法
EP4071560A1 (fr) 2021-04-07 2022-10-12 Patek Philippe SA Genève Pièce d'horlogerie à répétition et alarme
EP4071561A1 (fr) 2021-04-07 2022-10-12 Patek Philippe SA Genève Pièce d'horlogerie à répétition
US11701843B2 (en) 2020-12-28 2023-07-18 Nakagawa Sangyo Co., Ltd. Method and resin impregnating device for producing a reinforcing bar

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB759092A (en) * 1953-06-11 1956-10-10 Eugen Bentz A process for the manufacture of moulded articles of reinforced plastic material
US20030228454A1 (en) * 2002-06-07 2003-12-11 Rayonier, Inc. Cellulose fiber reinforced composites having reduced discoloration and improved dispersion and associated methods of manufacture
WO2014122157A1 (fr) * 2013-02-07 2014-08-14 Lm Wp Patent Holding A/S Corde ayant des fibres de renfort hachées
KR101798468B1 (ko) * 2017-04-28 2017-11-16 주식회사 임성 메쉬판이 일체화된 합성목재 제조장치 및 이를 이용한 메쉬판이 일체화된 합성목재의 제조방법

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS525354B2 (fr) * 1974-02-20 1977-02-12
JPS5211273A (en) * 1975-06-24 1977-01-28 Satsuki Kitani Process for producing synthetic wood
US5393536A (en) * 1993-04-05 1995-02-28 Crane Plastics Company Coextrusion apparatus
JPH09207197A (ja) * 1996-01-31 1997-08-12 Nippon Petrochem Co Ltd 補強条材入り熱可塑性樹脂パイプの成形方法およびそれに用いる装置
WO2004083541A2 (fr) * 2003-03-17 2004-09-30 Tech-Wood International Ltd Profil renforce
CN105313299A (zh) * 2014-06-30 2016-02-10 上海永玺环境科技有限公司 硬质聚氯乙烯结皮发泡建筑模板的挤出模具

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB759092A (en) * 1953-06-11 1956-10-10 Eugen Bentz A process for the manufacture of moulded articles of reinforced plastic material
US20030228454A1 (en) * 2002-06-07 2003-12-11 Rayonier, Inc. Cellulose fiber reinforced composites having reduced discoloration and improved dispersion and associated methods of manufacture
WO2014122157A1 (fr) * 2013-02-07 2014-08-14 Lm Wp Patent Holding A/S Corde ayant des fibres de renfort hachées
KR101798468B1 (ko) * 2017-04-28 2017-11-16 주식회사 임성 메쉬판이 일체화된 합성목재 제조장치 및 이를 이용한 메쉬판이 일체화된 합성목재의 제조방법

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of EP3853009A4 *

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP7023476B1 (ja) * 2020-11-20 2022-02-22 中川産業株式会社 筋金棒体成形用金型およびこれを使用した筋金棒体の製造方法
US11701843B2 (en) 2020-12-28 2023-07-18 Nakagawa Sangyo Co., Ltd. Method and resin impregnating device for producing a reinforcing bar
EP4071560A1 (fr) 2021-04-07 2022-10-12 Patek Philippe SA Genève Pièce d'horlogerie à répétition et alarme
EP4071561A1 (fr) 2021-04-07 2022-10-12 Patek Philippe SA Genève Pièce d'horlogerie à répétition

Also Published As

Publication number Publication date
EP3853009A4 (fr) 2022-05-04
EP3853009A1 (fr) 2021-07-28

Similar Documents

Publication Publication Date Title
WO2020060506A1 (fr) Composites bois-plastique renforcés par des cordes
US7987885B2 (en) System and die for forming a continuous filament reinforced structural plastic profile by pultrusion/coextrusion
US8852475B2 (en) Method of making continuous filament reinforced structural plastic profiles using pultrusion/coextrusion
US11135788B2 (en) System of continuous pultrusion method for manufacturing of bio-composite products; process and products thereof
US11400664B2 (en) Composites product; a pultrusion continuous method for manufacturing thereof
FI97786C (fi) Pitkäkuituvahvisteisten kestomuovien valmistusprosessi
Clemons Wood-plastic composites in the United States: The interfacing of two industries
US20030096096A1 (en) Plastic rail system reinforced with fiberglass thermoplastic composites
US9499688B2 (en) Long fiber thermoplastic formed with recycled and renewable content
EP0820848B1 (fr) Extrusion de matières thermoplastiques renforcées
CN1688428A (zh) 含有纤维增强的热塑性聚合物组合物的制品
EP0447423A1 (fr) Preforme en dechets de matiere synthetique files ou extrudes.
US20040126515A1 (en) Wood-plastic composite having improved strength
CN111621122B (zh) 一种复合材料及其制备方法、挤出设备
US7258913B2 (en) Plastic fencing system reinforced with fiberglass reinforced thermoplastic composites
CN104194123B (zh) 聚丙烯腈纤维/高密度聚乙烯复合材料的制备方法
CN107383517A (zh) 一种塑料板材、型材及生产方法
KR20130124303A (ko) 와이어 케이블용 가요성 강성 부재
Kargar et al. Experimental investigation on mechanical properties of extruded foamed PVC‐wood composites reinforced with continuous glass fibers
US20200385553A1 (en) Composite building materials
CN114991417B (zh) 一种超高性能共挤木塑板材及其制造方法和设备
WO2007065071A2 (fr) Procede et systeme pour la fabrication d'un article a renfort de filaments continus
KR102360985B1 (ko) 장섬유 강화 열가소성 수지 조성물 및 이를 이용하여 제조된 성형품
KR100873982B1 (ko) 장단섬유 강화 수지 및 그 제조방법
KR20120105135A (ko) 컨테이너 바닥재용 성형품 및 그 제조방법

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 18934427

Country of ref document: EP

Kind code of ref document: A1

NENP Non-entry into the national phase

Ref country code: DE

ENP Entry into the national phase

Ref document number: 2018934427

Country of ref document: EP

Effective date: 20210421