WO2020050693A1 - Pcm-applied polyurethane foam for car headlining, method for manufacturing same, and pcm-applied polyurethane foam-based car headlining - Google Patents

Pcm-applied polyurethane foam for car headlining, method for manufacturing same, and pcm-applied polyurethane foam-based car headlining Download PDF

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Publication number
WO2020050693A1
WO2020050693A1 PCT/KR2019/011572 KR2019011572W WO2020050693A1 WO 2020050693 A1 WO2020050693 A1 WO 2020050693A1 KR 2019011572 W KR2019011572 W KR 2019011572W WO 2020050693 A1 WO2020050693 A1 WO 2020050693A1
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Prior art keywords
pcm
polyurethane foam
layer
pores
foam
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PCT/KR2019/011572
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French (fr)
Korean (ko)
Inventor
임경섭
조정봉
이재연
고재왕
강태오
Original Assignee
한림인텍 주식회사
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Publication of WO2020050693A1 publication Critical patent/WO2020050693A1/en

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/36After-treatment
    • C08J9/40Impregnation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/066Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of foam
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/06Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/065Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of foam
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/06Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/10Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of paper or cardboard
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/18Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by features of a layer of foamed material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B60VEHICLES IN GENERAL
    • B60RVEHICLES, VEHICLE FITTINGS, OR VEHICLE PARTS, NOT OTHERWISE PROVIDED FOR
    • B60R13/00Elements for body-finishing, identifying, or decorating; Arrangements or adaptations for advertising purposes
    • B60R13/02Internal Trim mouldings ; Internal Ledges; Wall liners for passenger compartments; Roof liners
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B60VEHICLES IN GENERAL
    • B60RVEHICLES, VEHICLE FITTINGS, OR VEHICLE PARTS, NOT OTHERWISE PROVIDED FOR
    • B60R13/00Elements for body-finishing, identifying, or decorating; Arrangements or adaptations for advertising purposes
    • B60R13/08Insulating elements, e.g. for sound insulation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B62LAND VEHICLES FOR TRAVELLING OTHERWISE THAN ON RAILS
    • B62DMOTOR VEHICLES; TRAILERS
    • B62D25/00Superstructure or monocoque structure sub-units; Parts or details thereof not otherwise provided for
    • B62D25/06Fixed roofs
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2205/00Foams characterised by their properties
    • C08J2205/04Foams characterised by their properties characterised by the foam pores
    • C08J2205/05Open cells, i.e. more than 50% of the pores are open
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2375/00Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
    • C08J2375/04Polyurethanes

Definitions

  • the present invention relates to a vehicle headlining PCM-applied polyurethane foam, a method for manufacturing the same and a PCM-applied polyurethane foam-based vehicle headlining, more specifically, a high temperature due to the use of a PCM (Phase Change Material) applied polyurethane foam.
  • the temperature control function of the vehicle headlining is maximized in low temperature conditions, and in particular, the high air permeability is maintained by the PCM vacuum impregnation structure in which the PCM is disposed without closing the pores in the open cell structure under the polyurethane foam surface.
  • PCM applied poly for vehicle headlining where PCM functions smoothly and PCM is placed only inside the polyurethane foam to improve adhesion of the surface of the polyurethane foam so that adhesion of various materials on the surface is smooth without adhesive materials such as hot melt.
  • Urethane foam, its manufacturing method and PCM applied polyurethane foam based vehicle headlining One will.
  • Vehicle head liner is installed on the indoor ceiling of a vehicle to block noise or vibration from entering the vehicle interior from the outside, and stacked in various layers to improve heat insulation to block heat transfer inside or outside the vehicle Is made of
  • the vehicle In general, the vehicle is surrounded by glass on all sides, so heat is introduced into the room during the summer and cold air is easily introduced into the room during the winter.
  • the interior temperature of the vehicle varies by part, but in the case of the seat, it rises to 70 ⁇ 80 °C, and in winter, it goes down to the same level as the outside temperature.
  • ventilation seats and heated seats In order to reduce the hot feeling in the summer and the cold feeling in the winter, there are ventilation seats and heated seats.
  • a ventilated sheet having a grooved hole foreign matter may enter and cause contamination and corrosion, which may cause odor or hygiene problems in the vehicle.
  • the emotional quality of the car seat is not only color and touch, but also the temperature problem due to the high temperature seat in the summer and the cold seat in the winter.
  • Vehicle headliner is a technology that improves the thermal barrier performance of the headliner by providing a heat shielding layer formed by coating a heat shielding material. It is a technology that can block the heat transmitted from the head lining to the car interior through the roof panel by attaching the hot melt film added with.
  • the present invention is to improve the problems of the prior art, by allowing PCM (Phase Change Material) to be vacuum-impregnated in the pores of the polyurethane foam, the temperature control function of the vehicle headlining can be maximized under high or low temperature conditions. It is an object of the present invention to provide a PCM-based polyurethane foam for vehicle headlining, a manufacturing method thereof, and a PCM-based polyurethane foam-based vehicle headlining.
  • PCM Phase Change Material
  • the present invention allows the PCM to be smoothly functioned by maintaining high air permeability of the polyurethane foam even when the PCM is impregnated by allowing the PCM to be disposed inside the pores of the open cell structure of the polyurethane foam without closing the pores. It is an object of the present invention to provide a PCM-based polyurethane foam for vehicle headlining, a manufacturing method thereof, and a PCM-based polyurethane foam-based vehicle headlining.
  • the present invention improves the adhesion of the polyurethane foam surface by allowing the PCM to be placed only in the inner pores below the polyurethane foam surface, so that a new type of vehicle can be smoothly adhered to various materials on the surface without an adhesive material such as a hot melt. It is an object of the present invention to provide a vehicle headlining based on a PCM-applied polyurethane foam for a headlining, a manufacturing method thereof, and a PCM-applied polyurethane foam.
  • the present invention is a polyurethane foam 110 in which pores 111 of an open cell structure are formed;
  • a PCM-applied polyurethane foam for vehicle headlining characterized in that it comprises a configuration comprising; PCM (120) disposed inside the pores (111) without pore closing.
  • the PCM 120 is attached to the inner circumferential surface surrounding the pores 111 disposed under the surface of the polyurethane foam 110, and the pores 111 ) May be formed with a flow path 112 through which air and water can pass.
  • the present invention is a polyurethane foam disposing step in which the polyurethane foam 110 having pores 111 of an open cell structure is disposed; PCM injection step of spraying the liquid PCM (120) to the upper surface of the polyurethane foam (110); While the vacuum pressure of a set size is applied to the lower surface of the polyurethane foam 110, the PCM 120, which is sprayed and distributed to the upper surface of the polyurethane foam 110, is distributed below the surface of the polyurethane foam 110.
  • Vehicle head characterized in that it comprises; a PCM vacuum impregnation step that penetrates into the pores 111 disposed in the pores, and the PCM 120 penetrated into the pores 111 is disposed inside the pores 111 without closing the pores.
  • a method of manufacturing a polyurethane foam applied with PCM for lining is provided.
  • the PCM spraying step melts the solid PCM 120 and sprays the diluted PCM 120, but the liquid PCM. 120 may have a concentration of 20-40%.
  • the present invention forms a lowermost layer, the lower non-woven sheet layer 210 comprising a non-woven fabric; A glass mat layer 220a laminated on an upper surface of the lower nonwoven sheet layer 210 and made of a glass mat; A hard PU FOAM layer 230 which is laminated on the glass mat layer 220 and includes a rigid polyurethane foam, wherein the polyurethane foam is impregnated with PCM; A glass mat layer 220b laminated on the hard PU FOAM layer 230 and formed of a glass mat; The glass mat layer (220b) is laminated on the upper surface, the middle non-woven sheet layer 240 including a non-woven fabric; A film layer 250 laminated on an upper surface of the middle nonwoven sheet layer 240; A flexible PU FOAM layer 260 laminated on the film layer 250 and including a flexible polyurethane foam; And the soft PU FOAM layer 260 is laminated on the upper surface to form the uppermost layer, and exposed to
  • the rigid PU FOAM layer 230 includes a polyurethane foam 110 in which pores 111 having an open cell structure are formed; Provided is a PCM-applied polyurethane foam-based vehicle headlining comprising a configuration comprising a PCM 120 disposed inside the pore 111 without pore closing to perform a temperature control function.
  • the lower nonwoven sheet layer 210, the glass mat layer 220a, the rigid PU FOAM layer 230, the glass mat layer 220b in the vehicle headlining based on PCM-applied polyurethane foam according to an embodiment of the present invention constitutes a base layer, and the film layer 250, the soft PU FOAM layer 260, and the headlining skin layer 270 constitute a skin layer.
  • the vehicle is subjected to high or low temperature conditions by using a polyurethane foam with PCM (Phase Change Material) applied.
  • PCM Phase Change Material
  • the temperature control function of the headlining is maximized.
  • the PCM is smoothly maintained by maintaining high air permeability by the PCM vacuum impregnation structure in which the PCM is disposed without closing the pores in the open cell structure under the polyurethane foam surface.
  • the adhesion of the polyurethane foam surface is improved, so that adhesion of various materials on the surface is smooth without an adhesive material such as hot melt.
  • FIG. 1 is a block diagram of a PCM-applied polyurethane foam for vehicle headlining according to the present invention
  • Figure 2 is a detailed configuration of the internal pores of the polyurethane foam according to an embodiment of the present invention.
  • Figure 3 is a block diagram of a method of manufacturing a polyurethane foam applied to a PCM headlining according to the present invention
  • FIGS. 4 (a) to (c) are views for showing a method of manufacturing a PCM-applied polyurethane foam for vehicle headlining according to an embodiment of the present invention
  • FIG. 5 is an exemplary view showing PCM injection by a PCM injection device in a PCM injection step according to an embodiment of the present invention
  • 6 to 12 is a view for showing the results of the cooling efficiency test according to the PCM concentration
  • FIG. 13 is an exemplary view of PCM vacuum impregnation by a vacuum pressure generating device in a PCM vacuum impregnation step according to an embodiment of the present invention
  • FIG. 14 is a view for showing a configuration in which PCM is disposed only inside a polyurethane foam through a PCM vacuum impregnation step according to an embodiment of the present invention
  • 15 is a view for showing a PCM-applied polyurethane foam-based vehicle headlining according to an embodiment of the present invention.
  • PCM application polyurethane foam 100 for vehicle headlining is made of a configuration comprising a polyurethane foam 110, PCM 120 as shown in FIG.
  • the polyurethane foam 110 is formed with pores 111 having an open cell structure, and components of the vehicle headlining 100, which is a laminate, are used.
  • the PCM 120 is disposed inside the pore 111 without closing the pores to perform a temperature control function, and the PCM 120 according to an embodiment of the present invention is under the surface of the polyurethane foam 110 as shown in FIG. 2. It is attached to the inner circumferential surface surrounding the pores 111 disposed in the pores 111 so as to form a flow path 112 through which air and water can pass.
  • the method of manufacturing a polyurethane foam for PCM application for a vehicle headliner includes a polyurethane foam placement step, a PCM injection step, and a PCM vacuum impregnation step as shown in FIGS. 3 and 4.
  • the polyurethane foam placement step is a step in which the polyurethane foam 110 in which the pores 111 of the open cell structure are formed is disposed as shown in FIG. 4 (a).
  • the PCM spraying step is a step of spraying the liquid PCM 120 to the upper surface of the polyurethane foam 110 as shown in FIG. 4 (b).
  • the PCM injection device 300 disposed in the width direction (w) of the upper surface of the polyurethane foam 110 is advanced in the longitudinal direction (d) at a set speed.
  • the PCM 120 is sprayed while moving. Through this, the PCM 120 is uniformly dispersed in the width direction w of the upper surface of the polyurethane foam 110 to prevent the PCM 120 from being concentrated in a specific area.
  • the PCM injection step melts the solid PCM 120 and then sprays the diluted liquid PCM 120.
  • the liquid PCM 120 may have a concentration of 20 to 40%, and preferably may have a concentration of 30%. This can be confirmed through the results of the cooling efficiency test according to the PCM concentration shown in FIGS. 6 to 12.
  • a PCM 120 diluted with a predetermined concentration was vacuum-impregnated with a heat source of 23 to 30 ° C. for 10 minutes. , It is an experiment to check the temperature equilibrium time.
  • the PCM 120 is sprayed and distributed to the upper surface of the polyurethane foam 110. This is a step of penetrating into the pores 111 disposed under the surface of the polyurethane foam 110 and placing the PCM 120 penetrating into the pores 111 inside the pores 111 without closing the pores.
  • the PCM vacuum impregnation step is simultaneous in all parts in the width direction by the vacuum pressure generating device 400 disposed in the width direction (w) of the lower surface of the polyurethane foam 110 as shown in FIG. 13.
  • the PCM 120 is vacuum impregnated. Through this, the PCM 120 is uniformly dispersed in the pores 111 inside the polyurethane foam 110 to be vacuum impregnated, and PCM 120 is prevented from being concentrated in a specific area.
  • PCM injection in the PCM injection step and vacuum pressure in the PCM vacuum impregnation step are simultaneously performed.
  • PCM 120 is prevented from being distributed on the surface of the foam 110, while the PCM 120 is disposed only in the inner pores 111 below the surface of the polyurethane foam 110. Accordingly, the adhesiveness of the surface of the polyurethane foam 110 is improved, and adhesion of various materials on the surface can be smoothly performed without an adhesive material such as a hot melt.
  • the PCM-applied polyurethane foam-based vehicle headlining 200 has a lower nonwoven sheet layer 210, a glass mat layer 220a, a rigid PU FOAM layer 230, and a glass mat as shown in FIG. It comprises a layer 220b, a middle non-woven sheet layer 240, a film layer 250, a soft PU FOAM layer 260, and a headlining skin layer 270.
  • the lower nonwoven sheet layer 210 forms a lowermost layer of the vehicle headlining 200 and is a layer including a nonwoven fabric.
  • the bottom nonwoven sheet layer 210 according to an embodiment of the present invention is composed of a nonwoven fabric and an upper layer film.
  • the glass mat layer 220a is laminated on the upper surface of the lower nonwoven sheet layer 210, and is made of glass mat (GLASS MAT).
  • the rigid PU FOAM layer 230 is laminated on the top surface of the glass mat layer 220, and includes a hard polyurethane foam, but the polyurethane foam is a layer impregnated with PCM.
  • the rigid PU FOAM layer 230 according to an embodiment of the present invention is a polyurethane foam 110 in which pores 111 having an open cell structure are formed, and is disposed inside the pores 111 without closing the pores It consists of a configuration comprising a PCM (120) that performs a temperature control function.
  • the technical configuration and manufacturing method of such a rigid PU FOAM layer 360 are the above-described PCM-applied polyurethane foam 100 for headlining according to an embodiment of the present invention, a vehicle according to an embodiment of the present invention Refer to the manufacturing method of polyurethane foam applied with PCM for headlining.
  • the glass mat layer 220b is laminated on the upper surface of the rigid PU FOAM layer 230 and is made of glass mat.
  • the middle nonwoven sheet layer 240 is laminated on the top surface of the glass mat layer 220b, and is a layer including the nonwoven fabric.
  • Intermediate nonwoven fabric sheet layer 240 according to an embodiment of the present invention is composed of a single-layer film and a non-woven fabric.
  • the film layer 250 is a layer laminated on the top surface of the middle nonwoven sheet layer 240.
  • the soft PU FOAM layer 260 is laminated on the top surface of the film layer 250 and includes a soft polyurethane foam.
  • the headlining skin layer 270 is stacked on the upper surface of the soft PU FOAM layer 260 to form an uppermost layer, and is a layer that is exposed to the outside to form a skin.
  • the headlining skin layer 270 according to an embodiment of the present invention is composed of a fabric skin.
  • the lower nonwoven sheet layer 210, the glass mat layer 220a, the hard PU FOAM layer 230, the glass mat layer 220b, and the middle nonwoven sheet layer 240 constitute a base layer, and the film layer 250 ),
  • the soft PU FOAM layer 260, and the head lining skin layer 270 constitutes a skin layer.
  • PCM-applied polyurethane foam for vehicle headlining according to an embodiment of the present invention configured as described above, a manufacturing method thereof, and PCM-applied polyurethane foam-based vehicle headlining have a PCM (Phase Change Material) vacuum in the pores of the polyurethane foam. Since it is impregnated, the temperature control function of the vehicle headlining can be maximized in high or low temperature conditions.
  • the PCM-applied polyurethane foam for vehicle headlining according to an embodiment of the present invention, the manufacturing method thereof, and the PCM-applied polyurethane foam-based vehicle headlining have no pore closure inside the pores of the open cell structure of the polyurethane foam.
  • the PCM-applied polyurethane foam for vehicle headlining according to an embodiment of the present invention, the manufacturing method thereof, and the PCM-applied polyurethane foam-based vehicle headlining allow the PCM to be disposed only in the inner pores under the surface of the polyurethane foam.
  • the adhesion of the surface is improved so that adhesion of various materials on the surface can be smoothly performed without an adhesive material such as a hot melt.

Abstract

The present invention provides a phase change material (PCM)-applied polyurethane foam for a car headlining, a method for manufacturing same, and a PCM-applied polyurethane foam-based car headlining. The present invention provides a phase change material (PCM)-applied polyurethane foam for a car headlining, a method for manufacturing same, and a PCM-applied polyurethane foam-based car headlining. In the PCM-applied polyurethane foam for a car headlining, the method for manufacturing same, and the PCM-applied polyurethane foam-based car headlining according to the present invention, the temperature control of the car headlining in the high-temperature or low-temperature conditions is maximized by means of the use of the PCM-applied polyurethane foam, and especially, a PCM vacuum impregnation structure, in which PCM is placed inside pores of an open cell structure under the surface of the polyurethane foam without pore closure, maintains high air permeability, thereby enabling the smooth functioning of the PCM, and also, the placement of the PCM only inside the polyurethane foam enhances the adhesion of the surface of the polyurethane foam, thereby enabling the smooth attachment of various substances onto the surface even without an adhesive, such as a hot-melt adhesive.

Description

차량 헤드라이닝용 PCM 적용 폴리우레탄 폼, 그의 제조방법 및 PCM 적용 폴리우레탄 폼 기반 차량 헤드라이닝PCM-based polyurethane foam for vehicle headlining, manufacturing method and PCM-based polyurethane foam-based vehicle headlining
본 발명은 차량 헤드라이닝용 PCM 적용 폴리우레탄 폼, 그의 제조방법 및 PCM 적용 폴리우레탄 폼 기반 차량 헤드라이닝에 관한 것으로, 좀더 구체적으로는 PCM(Phase Change Material)가 적용된 폴리우레탄 폼의 사용으로 고온이나 저온 조건에서 차량 헤드라이닝의 온도조절 기능이 극대화되고, 특히 폴리우레탄 폼 표면 아래의 오픈 셀(open cell) 구조의 기공 내부에 기공 폐쇄없이 PCM이 배치되는 PCM 진공함침 구조에 의해 높은 통기성을 유지되어 PCM이 원활하게 기능하게 되는 동시에 PCM이 폴리우레탄 폼 내부에만 배치되면서 폴리우레탄 폼 표면의 접착성이 향상되어 핫멜트와 같은 접착물질 없이도 표면에서의 각종 물질 접착이 원활하게 이루어지는 차량 헤드라이닝용 PCM 적용 폴리우레탄 폼, 그의 제조방법 및 PCM 적용 폴리우레탄 폼 기반 차량 헤드라이닝에 관한 것이다.The present invention relates to a vehicle headlining PCM-applied polyurethane foam, a method for manufacturing the same and a PCM-applied polyurethane foam-based vehicle headlining, more specifically, a high temperature due to the use of a PCM (Phase Change Material) applied polyurethane foam. The temperature control function of the vehicle headlining is maximized in low temperature conditions, and in particular, the high air permeability is maintained by the PCM vacuum impregnation structure in which the PCM is disposed without closing the pores in the open cell structure under the polyurethane foam surface. PCM applied poly for vehicle headlining where PCM functions smoothly and PCM is placed only inside the polyurethane foam to improve adhesion of the surface of the polyurethane foam so that adhesion of various materials on the surface is smooth without adhesive materials such as hot melt. Urethane foam, its manufacturing method and PCM applied polyurethane foam based vehicle headlining One will.
차량용 헤드라이너(head liner)는 자동차의 실내 천정에 설치되어 외부로부터 차량의 실내로 유입되는 소음이나 진동을 차단하고, 차량 내부나 외부의 열 전달을 차단하는 단열성의 향상을 위해 다양한 층의 적층 구조로 이루어진다.Vehicle head liner is installed on the indoor ceiling of a vehicle to block noise or vibration from entering the vehicle interior from the outside, and stacked in various layers to improve heat insulation to block heat transfer inside or outside the vehicle Is made of
일반적으로 차량은 사방이 유리로 둘러싸여 있어 여름철에는 열기가 실내로 유입되고 겨울철에는 냉기가 실내로 유입되기 쉬운 구조이다.In general, the vehicle is surrounded by glass on all sides, so heat is introduced into the room during the summer and cold air is easily introduced into the room during the winter.
여름철 차량의 실내 온도는 부품별로 차이가 나지만 시트의 경우 70 ~ 80℃ 까지 상승하고, 겨울이면 외기 온도와 동일 수준으로 내려간다. 이렇게 차량 내부의 여름철 뜨거운 느낌과 겨울철 차가운 느낌을 감소시키기 위하여 통풍시트와 열선시트가 있다. 그러나, 홈이 뚫려 있는 통풍시트의 경우에는 이물질이 들어가게 되어 오염 및 부식이 발생하여 차량내부의 냄새나 위생상의 문제가 발생할 수 있다. 차량용 시트의 감성품질은 색상, 촉감 뿐만 아니라 여름철 상승한 고온의 시트와 겨울철 차가운 시트로 인한 온도 문제도 크게 부각되고 있다.In the summer, the interior temperature of the vehicle varies by part, but in the case of the seat, it rises to 70 ~ 80 ℃, and in winter, it goes down to the same level as the outside temperature. In order to reduce the hot feeling in the summer and the cold feeling in the winter, there are ventilation seats and heated seats. However, in the case of a ventilated sheet having a grooved hole, foreign matter may enter and cause contamination and corrosion, which may cause odor or hygiene problems in the vehicle. The emotional quality of the car seat is not only color and touch, but also the temperature problem due to the high temperature seat in the summer and the cold seat in the winter.
특히 대부분의 외부가 금속 강판으로 제조되는 차량은 여름철에 밀폐 상태로 보관되는 경우 내부 온도가 급격히 올라갈 수 있다. 이러한 온도 상승을 방지하기 위해 유리에 필름을 붙이거나 코팅하여 외부 열기의 실내 유입을 차단하는 방법을 사용하고 있으나, 차량의 넓은 면을 차지하는 루프 패널을 통해 들어오는 열기를 차단할 수 있는 기술이 필요하다. 이에 따라 대한민국 등록특허공보 등록번호 제10-1786700호 "차량용 헤드라이너", 등록번호 제10-1692861호 "열 차단 기능을 가진 자동차용 헤드 라이닝 및 그 제조방법" 등의 기술이 안출되었는데, 상기 "차량용 헤드라이너"는 열 차단 물질이 코팅되어 형성된 열 차단층을 구비함으로써 헤드라이너의 열차단 성능을 향상시킨 기술이며, 상기 "열 차단 기능을 가진 자동차용 헤드 라이닝 및 그 제조방법"은 열 차단 물질을 첨가한 핫멜트 필름을 부착함으로써 헤드 라이닝에서 루프패널을 통해 자동차 실내로 전달되는 열을 차단할 수 있게 한 기술이다.In particular, when most of the exterior is made of a metal steel plate, the internal temperature may increase rapidly when stored in a closed state during the summer. In order to prevent such a rise in temperature, a method is used to block indoor heat from entering the outside by attaching or coating a film on the glass. In accordance with this, technologies such as “Registration of Korean Patent Registration No. 10-1786700” “Headliner for Vehicles” and “Registration No. 10-1692861” of “Head lining for automobiles having heat blocking function and manufacturing method thereof” have been devised. Vehicle headliner "is a technology that improves the thermal barrier performance of the headliner by providing a heat shielding layer formed by coating a heat shielding material. It is a technology that can block the heat transmitted from the head lining to the car interior through the roof panel by attaching the hot melt film added with.
그러나 이와 같은 종래기술들은 열차단 물질이 표면 코팅된 구조에 의해 통기성이 떨어지거나 표피층의 접착을 위해 핫멜트 필름이 구비되어야 하는 단점이 있었다.However, such prior arts have a disadvantage in that a hot melt film must be provided for adhesion of an epidermal layer or air permeability is poor due to a structure in which a heat barrier material is surface-coated.
따라서 본 발명은 이와 같은 종래 기술의 문제점을 개선하여, 폴리우레탄 폼 내부의 기공에 PCM(Phase Change Material)가 진공함침되도록 함으로써 고온이나 저온 조건에서 차량 헤드라이닝의 온도조절 기능이 극대화될 수 있는 새로운 형태의 차량 헤드라이닝용 PCM 적용 폴리우레탄 폼, 그의 제조방법 및 PCM 적용 폴리우레탄 폼 기반 차량 헤드라이닝을 제공하는 것을 목적으로 한다.Therefore, the present invention is to improve the problems of the prior art, by allowing PCM (Phase Change Material) to be vacuum-impregnated in the pores of the polyurethane foam, the temperature control function of the vehicle headlining can be maximized under high or low temperature conditions. It is an object of the present invention to provide a PCM-based polyurethane foam for vehicle headlining, a manufacturing method thereof, and a PCM-based polyurethane foam-based vehicle headlining.
특히 본 발명은 폴리우레탄 폼의 오픈 셀(open cell) 구조의 기공 내부에 기공 폐쇄없이 PCM이 배치되도록 함으로써 PCM이 내부에 함침되어도 폴리우레탄 폼의 높은 통기성을 유지되어 PCM이 원활하게 기능할 수 있는 새로운 형태의 차량 헤드라이닝용 PCM 적용 폴리우레탄 폼, 그의 제조방법 및 PCM 적용 폴리우레탄 폼 기반 차량 헤드라이닝을 제공하는 것을 목적으로 한다.In particular, the present invention allows the PCM to be smoothly functioned by maintaining high air permeability of the polyurethane foam even when the PCM is impregnated by allowing the PCM to be disposed inside the pores of the open cell structure of the polyurethane foam without closing the pores. It is an object of the present invention to provide a PCM-based polyurethane foam for vehicle headlining, a manufacturing method thereof, and a PCM-based polyurethane foam-based vehicle headlining.
또한 본 발명은 폴리우레탄 폼 표면 아래의 내부 기공에만 PCM이 배치되도록 함으로써 폴리우레탄 폼 표면의 접착성이 향상되어 핫멜트와 같은 접착물질 없이도 표면에서의 각종 물질 접착이 원활하게 이루어질 수 있는 새로운 형태의 차량 헤드라이닝용 PCM 적용 폴리우레탄 폼, 그의 제조방법 및 PCM 적용 폴리우레탄 폼 기반 차량 헤드라이닝을 제공하는 것을 목적으로 한다.In addition, the present invention improves the adhesion of the polyurethane foam surface by allowing the PCM to be placed only in the inner pores below the polyurethane foam surface, so that a new type of vehicle can be smoothly adhered to various materials on the surface without an adhesive material such as a hot melt. It is an object of the present invention to provide a vehicle headlining based on a PCM-applied polyurethane foam for a headlining, a manufacturing method thereof, and a PCM-applied polyurethane foam.
상술한 목적을 달성하기 위한 본 발명의 특징에 의하면, 본 발명은 오픈 셀(open cell) 구조의 기공(111)이 형성되어 있는 폴리우레탄 폼(110); 기공 폐쇄없이 상기 기공(111) 내부에 배치되어 온도조절 기능을 수행하는 PCM(120);을 포함하는 구성으로 이루어지는 것을 특징으로 하는 차량 헤드라이닝용 PCM 적용 폴리우레탄 폼을 제공한다.According to a feature of the present invention for achieving the above object, the present invention is a polyurethane foam 110 in which pores 111 of an open cell structure are formed; Provided is a PCM-applied polyurethane foam for vehicle headlining, characterized in that it comprises a configuration comprising; PCM (120) disposed inside the pores (111) without pore closing.
이와 같은 본 발명에 따른 차량 헤드라이닝용 PCM 적용 폴리우레탄 폼에서 상기 PCM(120)은 상기 폴리우레탄 폼(110) 표면 아래측에 배치되어 있는 기공(111)을 둘러싸는 내주면에 부착되어 기공(111)에 공기와 물이 통과할 수 있는 유로(112)가 형성되도록 할 수 있다.In the PCM-applied polyurethane foam for vehicle headlining according to the present invention, the PCM 120 is attached to the inner circumferential surface surrounding the pores 111 disposed under the surface of the polyurethane foam 110, and the pores 111 ) May be formed with a flow path 112 through which air and water can pass.
상술한 목적을 달성하기 위한 본 발명의 다른 특징에 의하면, 본 발명은 오픈 셀 구조의 기공(111)이 형성된 폴리우레탄 폼(110)이 배치되는 폴리우레탄 폼 배치단계; 상기 폴리우레탄 폼(110) 상부표면으로 액상의 PCM(120)을 분사시키는 PCM 분사단계; 상기 폴리우레탄 폼(110)의 하부표면에 설정크기의 진공압이 부여되면서 상기 폴리우레탄 폼(110) 상부표면으로 분사되어 분산배치되는 상기 PCM(120)이 상기 폴리우레탄 폼(110) 표면 아래측에 배치되는 기공(111)으로 침투하고, 기공(111)으로 침투한 상기 PCM(120)이 기공 폐쇄없이 상기 기공(111) 내부에 배치되는 PCM 진공함침단계;를 포함하는 것을 특징으로 하는 차량 헤드라이닝용 PCM 적용 폴리우레탄 폼의 제조방법을 제공한다.According to another feature of the present invention for achieving the above object, the present invention is a polyurethane foam disposing step in which the polyurethane foam 110 having pores 111 of an open cell structure is disposed; PCM injection step of spraying the liquid PCM (120) to the upper surface of the polyurethane foam (110); While the vacuum pressure of a set size is applied to the lower surface of the polyurethane foam 110, the PCM 120, which is sprayed and distributed to the upper surface of the polyurethane foam 110, is distributed below the surface of the polyurethane foam 110. Vehicle head characterized in that it comprises; a PCM vacuum impregnation step that penetrates into the pores 111 disposed in the pores, and the PCM 120 penetrated into the pores 111 is disposed inside the pores 111 without closing the pores. Provided is a method of manufacturing a polyurethane foam applied with PCM for lining.
이와 같은 본 발명에 따른 차량 헤드라이닝용 PCM 적용 폴리우레탄 폼의 제조방법에서 상기 PCM 분사단계는 고체상의 PCM(120)을 융해한 후 희석시킨 액상의 PCM(120)을 분사하되, 상기 액상의 PCM(120)은 20~40%의 농도를 가질 수 있다.In the method of manufacturing a polyurethane foam for PCM application for vehicle headlining according to the present invention, the PCM spraying step melts the solid PCM 120 and sprays the diluted PCM 120, but the liquid PCM. 120 may have a concentration of 20-40%.
상술한 목적을 달성하기 위한 본 발명의 또다른 특징에 의하면, 본 발명은 최하단층을 이루고, 부직포를 포함하는 하단 부직포 시트층(210); 상기 하단 부직포 시트층(210) 상부면에 적층되고, 글라스 매트로 이루어지는 글라스 매트층(220a); 상기 글라스 매트층(220) 상부면에 적층되고, 경질의 폴리우레탄 폼을 포함하되, 상기 폴리우레탄 폼에는 PCM이 내부함침되어 있는 경질 PU FOAM층(230); 상기 경질 PU FOAM층(230) 상부면에 적층되고, 글라스 매트로 이루어지는 글라스 매트층(220b); 상기 글라스 매트층(220b) 상부면에 적층되고, 부직포를 포함하는 중단 부직포 시트층(240); 상기 중단 부직포 시트층(240) 상부면에 적층되는 필름층(250); 상기 필름층(250) 상부면에 적층되고, 연질의 폴리우레탄 폼을 포함하는 연질 PU FOAM층(260); 및 상기 연질 PU FOAM층(260) 상부면에 적층되어 최상단층을 이루고, 외부로 노출되어 표피를 이루는 헤드라이닝 표피층(270)을 포함하는 구성으로 이루어지되,According to another feature of the present invention for achieving the above object, the present invention forms a lowermost layer, the lower non-woven sheet layer 210 comprising a non-woven fabric; A glass mat layer 220a laminated on an upper surface of the lower nonwoven sheet layer 210 and made of a glass mat; A hard PU FOAM layer 230 which is laminated on the glass mat layer 220 and includes a rigid polyurethane foam, wherein the polyurethane foam is impregnated with PCM; A glass mat layer 220b laminated on the hard PU FOAM layer 230 and formed of a glass mat; The glass mat layer (220b) is laminated on the upper surface, the middle non-woven sheet layer 240 including a non-woven fabric; A film layer 250 laminated on an upper surface of the middle nonwoven sheet layer 240; A flexible PU FOAM layer 260 laminated on the film layer 250 and including a flexible polyurethane foam; And the soft PU FOAM layer 260 is laminated on the upper surface to form the uppermost layer, and exposed to the outside to form a skin comprising a head lining epidermal layer 270,
상기 경질 PU FOAM층(230)은, 오픈 셀(open cell) 구조의 기공(111)이 형성되어 있는 폴리우레탄 폼(110); 기공 폐쇄없이 상기 기공(111) 내부에 배치되어 온도조절 기능을 수행하는 PCM(120);을 포함하는 구성으로 이루어지는 것을 특징으로 하는 PCM 적용 폴리우레탄 폼 기반 차량 헤드라이닝을 제공한다.The rigid PU FOAM layer 230 includes a polyurethane foam 110 in which pores 111 having an open cell structure are formed; Provided is a PCM-applied polyurethane foam-based vehicle headlining comprising a configuration comprising a PCM 120 disposed inside the pore 111 without pore closing to perform a temperature control function.
이와 같은 본 발명의 실시예에 따른 PCM 적용 폴리우레탄 폼 기반 차량 헤드라이닝에서 상기 하단 부직포 시트층(210), 글라스 매트층(220a), 경질 PU FOAM층(230), 글라스 매트층(220b), 중단 부직포 시트층(240)는 기재층을 구성하는 것이고, 상기 필름층(250), 연질 PU FOAM층(260), 헤드라이닝 표피층(270)는 표피층을 구성한다.The lower nonwoven sheet layer 210, the glass mat layer 220a, the rigid PU FOAM layer 230, the glass mat layer 220b in the vehicle headlining based on PCM-applied polyurethane foam according to an embodiment of the present invention, The middle layer nonwoven fabric sheet layer 240 constitutes a base layer, and the film layer 250, the soft PU FOAM layer 260, and the headlining skin layer 270 constitute a skin layer.
본 발명에 의한 차량 헤드라이닝용 PCM 적용 폴리우레탄 폼, 그의 제조방법 및 PCM 적용 폴리우레탄 폼 기반 차량 헤드라이닝에 의하면, PCM(Phase Change Material)가 적용된 폴리우레탄 폼의 사용으로 고온이나 저온 조건에서 차량 헤드라이닝의 온도조절 기능이 극대화되고, 특히 폴리우레탄 폼 표면 아래의 오픈 셀(open cell) 구조의 기공 내부에 기공 폐쇄없이 PCM이 배치되는 PCM 진공함침 구조에 의해 높은 통기성을 유지되어 PCM이 원활하게 기능하게 되는 동시에 PCM이 폴리우레탄 폼 내부에만 배치되면서 폴리우레탄 폼 표면의 접착성이 향상되어 핫멜트와 같은 접착물질 없이도 표면에서의 각종 물질 접착이 원활하게 이루어지는 효과가 있다.According to the PCM-applied polyurethane foam for vehicle headlining according to the present invention, a manufacturing method thereof, and a PCM-applied polyurethane foam-based vehicle headlining, the vehicle is subjected to high or low temperature conditions by using a polyurethane foam with PCM (Phase Change Material) applied. The temperature control function of the headlining is maximized. Especially, the PCM is smoothly maintained by maintaining high air permeability by the PCM vacuum impregnation structure in which the PCM is disposed without closing the pores in the open cell structure under the polyurethane foam surface. At the same time, while the PCM is placed only inside the polyurethane foam, the adhesion of the polyurethane foam surface is improved, so that adhesion of various materials on the surface is smooth without an adhesive material such as hot melt.
도 1은 본 발명에 따른 차량 헤드라이닝용 PCM 적용 폴리우레탄 폼의 구성 블록도;1 is a block diagram of a PCM-applied polyurethane foam for vehicle headlining according to the present invention;
도 2는 본 발명의 실시예에 따른 폴리우레탄 폼의 내부 기공 상세 구성도;Figure 2 is a detailed configuration of the internal pores of the polyurethane foam according to an embodiment of the present invention;
도 3은 본 발명에 따른 차량 헤드라이닝용 PCM 적용 폴리우레탄 폼의 제조방법의 순서 블록도;Figure 3 is a block diagram of a method of manufacturing a polyurethane foam applied to a PCM headlining according to the present invention;
도 4의 (a) 내지 (c)는 본 발명의 실시예에 따른 차량 헤드라이닝용 PCM 적용 폴리우레탄 폼의 제조방법을 보여주기 위한 도면;4 (a) to (c) are views for showing a method of manufacturing a PCM-applied polyurethane foam for vehicle headlining according to an embodiment of the present invention;
도 5는 본 발명의 실시예에 따른 PCM 분사단계에서 PCM 분사기기에 의한 PCM 분사 예시도;5 is an exemplary view showing PCM injection by a PCM injection device in a PCM injection step according to an embodiment of the present invention;
도 6 내지 도 12는 PCM 농도에 따른 냉감 효율 실험결과를 보여주기 위한 도면;6 to 12 is a view for showing the results of the cooling efficiency test according to the PCM concentration;
도 13은 본 발명의 실시예에 따른 PCM 진공함침단계에서 진공압 발생기기에 의한 PCM 진공함침 예시도;13 is an exemplary view of PCM vacuum impregnation by a vacuum pressure generating device in a PCM vacuum impregnation step according to an embodiment of the present invention;
도 14는 본 발명의 실시예에 따른 PCM 진공함침단계를 통해 폴리우레탄 폼 내부에만 PCM이 배치되는 구성을 보여주기 위한 도면;14 is a view for showing a configuration in which PCM is disposed only inside a polyurethane foam through a PCM vacuum impregnation step according to an embodiment of the present invention;
도 15는 본 발명의 실시예에 따른 PCM 적용 폴리우레탄 폼 기반 차량 헤드라이닝을 보여주기 위한 도면이다.15 is a view for showing a PCM-applied polyurethane foam-based vehicle headlining according to an embodiment of the present invention.
이하, 본 발명의 실시예를 첨부된 도면 도 1 내지 도 15에 의거하여 상세히 설명한다. 한편, 도면과 상세한 설명에서 일반적인 폴리우레탄 폼(PU FOAM), 오픈 셀(open cell) 구조, PCM(Phase Change Material), 진공함침, 부직포, 글라스 매트, 스웨이드(SUEDE) 등으로부터 이 분야의 종사자들이 용이하게 알 수 있는 구성 및 작용에 대한 도시 및 언급은 간략히 하거나 생략하였다. 특히 도면의 도시 및 상세한 설명에 있어서 본 발명의 기술적 특징과 직접적으로 연관되지 않는 요소의 구체적인 기술적 구성 및 작용에 대한 상세한 설명 및 도시는 생략하고, 본 발명과 관련되는 기술적 구성만을 간략하게 도시하거나 설명하였다.Hereinafter, embodiments of the present invention will be described in detail based on the accompanying drawings FIGS. 1 to 15. On the other hand, in the drawings and detailed description, workers in this field from general polyurethane foam (PU FOAM), open cell structure, PCM (Phase Change Material), vacuum impregnation, non-woven fabric, glass mat, suede, etc. Figures and references to easily understood configurations and acts have been simplified or omitted. In particular, in the illustration and detailed description of the drawings, detailed descriptions and illustrations of elements that are not directly related to the technical features of the present invention are omitted, and only brief descriptions or descriptions of the technical configurations related to the present invention are provided. Did.
본 발명의 실시예에 따른 차량 헤드라이닝용 PCM 적용 폴리우레탄 폼(100)은 도 1에서와 같이 폴리우레탄 폼(110), PCM(120)을 포함하는 구성으로 이루어진다.PCM application polyurethane foam 100 for vehicle headlining according to an embodiment of the present invention is made of a configuration comprising a polyurethane foam 110, PCM 120 as shown in FIG.
폴리우레탄 폼(110)은 오픈 셀(open cell) 구조의 기공(111)이 형성되어 있는 것으로, 적층재인 차량 헤드라이닝(100)의 구성요소가 사용된다.The polyurethane foam 110 is formed with pores 111 having an open cell structure, and components of the vehicle headlining 100, which is a laminate, are used.
PCM(120)은 기공 폐쇄없이 기공(111) 내부에 배치되어 온도조절 기능을 수행하는 것으로, 본 발명의 실시예에 따른 PCM(120)은 도 2에서와 같이 폴리우레탄 폼(110) 표면 아래측에 배치되어 있는 기공(111)을 둘러싸는 내주면에 부착되어 기공(111)에 공기와 물이 통과할 수 있는 유로(112)가 형성되도록 한다.The PCM 120 is disposed inside the pore 111 without closing the pores to perform a temperature control function, and the PCM 120 according to an embodiment of the present invention is under the surface of the polyurethane foam 110 as shown in FIG. 2. It is attached to the inner circumferential surface surrounding the pores 111 disposed in the pores 111 so as to form a flow path 112 through which air and water can pass.
본 발명의 실시예에 따른 차량 헤드라이너용 PCM 적용 폴리우레탄 폼의 제조방법은 도 3과 도 4에서와 같이 폴리우레탄 폼 배치단계, PCM 분사단계, PCM 진공함침단계를 포함한다.The method of manufacturing a polyurethane foam for PCM application for a vehicle headliner according to an embodiment of the present invention includes a polyurethane foam placement step, a PCM injection step, and a PCM vacuum impregnation step as shown in FIGS. 3 and 4.
폴리우레탄 폼 배치단계는 도 4의 (a)에서와 같이 오픈 셀 구조의 기공(111)이 형성된 폴리우레탄 폼(110)이 배치되는 단계이다.The polyurethane foam placement step is a step in which the polyurethane foam 110 in which the pores 111 of the open cell structure are formed is disposed as shown in FIG. 4 (a).
PCM 분사단계는 도 4의 (b)에서와 같이 폴리우레탄 폼(110) 상부표면으로 액상의 PCM(120)을 분사시키는 단계이다. 여기서 본 발명의 실시예에 따른 PCM 분사단계는 도 5에서와 같이 폴리우레탄 폼(110) 상부표면의 폭방향(w) 배치되는 PCM 분사기기(300)가 설정속도로 길이방향(d)으로 전진이동하면서 PCM(120)을 분사하도록 한다. 이를 통해 PCM(120)은 폴리우레탄 폼(110) 상부표면의 폭방향(w)으로 균일하게 분산되어 특정 부위에 PCM(120)이 집중되는 것이 방지된다.The PCM spraying step is a step of spraying the liquid PCM 120 to the upper surface of the polyurethane foam 110 as shown in FIG. 4 (b). Here, in the PCM injection step according to the embodiment of the present invention, as shown in FIG. 5, the PCM injection device 300 disposed in the width direction (w) of the upper surface of the polyurethane foam 110 is advanced in the longitudinal direction (d) at a set speed. The PCM 120 is sprayed while moving. Through this, the PCM 120 is uniformly dispersed in the width direction w of the upper surface of the polyurethane foam 110 to prevent the PCM 120 from being concentrated in a specific area.
또한 본 발명의 실시예에 따른 PCM 분사단계는 고체상의 PCM(120)을 융해한 후 희석시킨 액상의 PCM(120)을 분사시키게 된다. 여기서 액상의 PCM(120)은 20~40%의 농도를 가질 수 있으며, 바람직하게는 30%의 농도를 가질 수 있다. 이는 도 6 내지 도 12에 도시된 PCM 농도에 따른 냉감 효율 실험결과를 통해 확인할 수 있다. 도 6 내지 도 12에 도시된 PCM 농도에 따른 냉감 효율 실험은 아래의 [표 1]에서와 같이 설정 농도로 희석된 PCM(120)이 진공함침된 원단을 10분간 23~30℃의 열원을 가하고, 온도 평형시간을 확인한 실험이다.In addition, the PCM injection step according to an embodiment of the present invention melts the solid PCM 120 and then sprays the diluted liquid PCM 120. Here, the liquid PCM 120 may have a concentration of 20 to 40%, and preferably may have a concentration of 30%. This can be confirmed through the results of the cooling efficiency test according to the PCM concentration shown in FIGS. 6 to 12. In the experiment of cooling efficiency according to the PCM concentration shown in FIGS. 6 to 12, as shown in [Table 1], a PCM 120 diluted with a predetermined concentration was vacuum-impregnated with a heat source of 23 to 30 ° C. for 10 minutes. , It is an experiment to check the temperature equilibrium time.
비고Remarks 최고온도Maximum temperature
10% PCM처리10% PCM treatment 30℃30 ℃
20% PCM처리20% PCM treatment 27℃27 ℃
30% PCM처리30% PCM treatment 25℃25 ℃
40% PCM처리40% PCM treatment 24℃24 ℃
50% PCM처리50% PCM treatment 23℃23 ℃
PCM 진공함침단계는 도 4의 (c)에서와 같이 폴리우레탄 폼(110)의 하부표면에 설정크기의 진공압이 부여되면서 폴리우레탄 폼(110) 상부표면으로 분사되어 분산배치되는 PCM(120)이 폴리우레탄 폼(110) 표면 아래측에 배치되는 기공(111)으로 침투하고, 기공(111)으로 침투한 PCM(120)이 기공 폐쇄없이 기공(111) 내부에 배치되는 단계이다. In the PCM vacuum impregnation step, as shown in FIG. 4 (c), while the vacuum pressure of the set size is applied to the lower surface of the polyurethane foam 110, the PCM 120 is sprayed and distributed to the upper surface of the polyurethane foam 110. This is a step of penetrating into the pores 111 disposed under the surface of the polyurethane foam 110 and placing the PCM 120 penetrating into the pores 111 inside the pores 111 without closing the pores.
여기서 본 발명의 실시예에 따른 PCM 진공함침단계는 도 13에서와 같이 폴리우레탄 폼(110) 하부표면의 폭방향(w) 배치되는 진공압 발생기기(400)에 의해 폭방향 전체부위에서 동시적으로 PCM(120)이 진공함침되도록 한다. 이를 통해 PCM(120)은 폴리우레탄 폼(110) 내부의 기공(111)에 균일하게 분산되어 진공함침되고, 특정 부위에 PCM(120)이 집중되는 것이 방지된다.Here, the PCM vacuum impregnation step according to an embodiment of the present invention is simultaneous in all parts in the width direction by the vacuum pressure generating device 400 disposed in the width direction (w) of the lower surface of the polyurethane foam 110 as shown in FIG. 13. The PCM 120 is vacuum impregnated. Through this, the PCM 120 is uniformly dispersed in the pores 111 inside the polyurethane foam 110 to be vacuum impregnated, and PCM 120 is prevented from being concentrated in a specific area.
한편 본 발명의 실시예에 따른 차량 헤드라이너용 PCM 적용 폴리우레탄 폼의 제조방법에서는 PCM 분사단계의 PCM 분사와 PCM 진공함침단계의 진공압 부여가 동시에 수행되는데, 이를 통해 도 14에서와 같이 폴리우레탄 폼(110) 표면에 PCM(120)이 분포되는 것이 방지되는 한편, 폴리우레탄 폼(110) 표면 아래의 내부 기공(111)에만 PCM(120)이 배치된다. 이에 따라 폴리우레탄 폼(110) 표면의 접착성이 향상되어 핫멜트와 같은 접착물질 없이도 표면에서의 각종 물질 접착이 원활하게 이루어질 수 있게 된다.Meanwhile, in the method of manufacturing a polyurethane foam for PCM application for a vehicle headliner according to an embodiment of the present invention, PCM injection in the PCM injection step and vacuum pressure in the PCM vacuum impregnation step are simultaneously performed. PCM 120 is prevented from being distributed on the surface of the foam 110, while the PCM 120 is disposed only in the inner pores 111 below the surface of the polyurethane foam 110. Accordingly, the adhesiveness of the surface of the polyurethane foam 110 is improved, and adhesion of various materials on the surface can be smoothly performed without an adhesive material such as a hot melt.
본 발명의 실시예에 따른 PCM 적용 폴리우레탄 폼 기반 차량 헤드라이닝(200)은 도 15에서와 같이 하단 부직포 시트층(210), 글라스 매트층(220a), 경질 PU FOAM층(230), 글라스 매트층(220b), 중단 부직포 시트층(240), 필름층(250), 연질 PU FOAM층(260), 헤드라이닝 표피층(270)을 포함하는 구성으로 이루어진다.The PCM-applied polyurethane foam-based vehicle headlining 200 according to an embodiment of the present invention has a lower nonwoven sheet layer 210, a glass mat layer 220a, a rigid PU FOAM layer 230, and a glass mat as shown in FIG. It comprises a layer 220b, a middle non-woven sheet layer 240, a film layer 250, a soft PU FOAM layer 260, and a headlining skin layer 270.
하단 부직포 시트층(210)은 차량 헤드라이닝(200)의 최하단층을 이루는 것으로, 부직포를 포함하는 층이다. 본 발명의 실시예에 따른 하단 부직포 시트층(210)은 부직포와 상층 필름으로 구성되어 있다.The lower nonwoven sheet layer 210 forms a lowermost layer of the vehicle headlining 200 and is a layer including a nonwoven fabric. The bottom nonwoven sheet layer 210 according to an embodiment of the present invention is composed of a nonwoven fabric and an upper layer film.
글라스 매트층(220a)은 하단 부직포 시트층(210) 상부면에 적층되는 것으로, 글라스 매트(GLASS MAT)로 이루어진다.The glass mat layer 220a is laminated on the upper surface of the lower nonwoven sheet layer 210, and is made of glass mat (GLASS MAT).
경질 PU FOAM층(230)은 글라스 매트층(220) 상부면에 적층되는 것으로, 경질의 폴리우레탄 폼을 포함하되, 폴리우레탄 폼에는 PCM이 내부함침되어 있는 층이다. 본 발명의 실시예에 따른 경질 PU FOAM층(230)은 오픈 셀(open cell) 구조의 기공(111)이 형성되어 있는 폴리우레탄 폼(110), 기공 폐쇄없이 상기 기공(111) 내부에 배치되어 온도조절 기능을 수행하는 PCM(120)을 포함하는 구성으로 이루어진다. 이와 같은 경질 PU FOAM층(360)의 기술구성과 제조방법은 전술(前述)되어 있는 본 발명의 실시예에 따른 차량 헤드라이닝용 PCM 적용 폴리우레탄 폼(100), 본 발명의 실시예에 따른 차량 헤드라이닝용 PCM 적용 폴리우레탄 폼의 제조방법을 참조한다.The rigid PU FOAM layer 230 is laminated on the top surface of the glass mat layer 220, and includes a hard polyurethane foam, but the polyurethane foam is a layer impregnated with PCM. The rigid PU FOAM layer 230 according to an embodiment of the present invention is a polyurethane foam 110 in which pores 111 having an open cell structure are formed, and is disposed inside the pores 111 without closing the pores It consists of a configuration comprising a PCM (120) that performs a temperature control function. The technical configuration and manufacturing method of such a rigid PU FOAM layer 360 are the above-described PCM-applied polyurethane foam 100 for headlining according to an embodiment of the present invention, a vehicle according to an embodiment of the present invention Refer to the manufacturing method of polyurethane foam applied with PCM for headlining.
글라스 매트층(220b)은 경질 PU FOAM층(230) 상부면에 적층되는 것으로, 글라스 매트(GLASS MAT)로 이루어진다.The glass mat layer 220b is laminated on the upper surface of the rigid PU FOAM layer 230 and is made of glass mat.
중단 부직포 시트층(240)은 글라스 매트층(220b) 상부면에 적층되는 것으로, 부직포를 포함하는 층이다. 본 발명의 실시예에 따른 중단 부직포 시트층(240)은 단층필름과 부직포로 구성되어 있다.The middle nonwoven sheet layer 240 is laminated on the top surface of the glass mat layer 220b, and is a layer including the nonwoven fabric. Intermediate nonwoven fabric sheet layer 240 according to an embodiment of the present invention is composed of a single-layer film and a non-woven fabric.
필름층(250)은 중단 부직포 시트층(240) 상부면에 적층되는 층이다.The film layer 250 is a layer laminated on the top surface of the middle nonwoven sheet layer 240.
연질 PU FOAM층(260)은 필름층(250) 상부면에 적층되는 것으로, 연질 폴리우레탄 폼을 포함한다.The soft PU FOAM layer 260 is laminated on the top surface of the film layer 250 and includes a soft polyurethane foam.
헤드라이닝 표피층(270)은 연질 PU FOAM층(260) 상부면에 적층되어 최상단층을 이루는 것으로, 외부로 노출되어 표피를 이루는 층이다. 본 발명의 실시예에 따른 헤드라이닝 표피층(270)은 원단 표피로 구성된다.The headlining skin layer 270 is stacked on the upper surface of the soft PU FOAM layer 260 to form an uppermost layer, and is a layer that is exposed to the outside to form a skin. The headlining skin layer 270 according to an embodiment of the present invention is composed of a fabric skin.
여기서 하단 부직포 시트층(210), 글라스 매트층(220a), 경질 PU FOAM층(230), 글라스 매트층(220b), 중단 부직포 시트층(240)는 기재층을 구성하는 것이고, 필름층(250), 연질 PU FOAM층(260), 헤드라이닝 표피층(270)는 표피층을 구성하는 것이다.Here, the lower nonwoven sheet layer 210, the glass mat layer 220a, the hard PU FOAM layer 230, the glass mat layer 220b, and the middle nonwoven sheet layer 240 constitute a base layer, and the film layer 250 ), The soft PU FOAM layer 260, and the head lining skin layer 270 constitutes a skin layer.
상기와 같이 구성된 본 발명의 실시예에 따른 차량 헤드라이닝용 PCM 적용 폴리우레탄 폼, 그의 제조방법 및 PCM 적용 폴리우레탄 폼 기반 차량 헤드라이닝은 폴리우레탄 폼 내부의 기공에 PCM(Phase Change Material)가 진공함침되도록 하므로, 고온이나 저온 조건에서 차량 헤드라이닝의 온도조절 기능이 극대화될 수 있다. 특히 본 발명의 실시예에 따른 차량 헤드라이닝용 PCM 적용 폴리우레탄 폼, 그의 제조방법 및 PCM 적용 폴리우레탄 폼 기반 차량 헤드라이닝은 폴리우레탄 폼의 오픈 셀(open cell) 구조의 기공 내부에 기공 폐쇄없이 PCM이 배치되도록 하므로, PCM이 내부에 함침되어도 폴리우레탄 폼의 높은 통기성을 유지되어 PCM이 원활하게 기능할 수 있게 된다. 또한 본 발명의 실시예에 따른 차량 헤드라이닝용 PCM 적용 폴리우레탄 폼, 그의 제조방법 및 PCM 적용 폴리우레탄 폼 기반 차량 헤드라이닝은 폴리우레탄 폼 표면 아래의 내부 기공에만 PCM이 배치되도록 하므로, 폴리우레탄 폼 표면의 접착성이 향상되어 핫멜트와 같은 접착물질 없이도 표면에서의 각종 물질 접착이 원활하게 이루어질 수 있게 된다.PCM-applied polyurethane foam for vehicle headlining according to an embodiment of the present invention configured as described above, a manufacturing method thereof, and PCM-applied polyurethane foam-based vehicle headlining have a PCM (Phase Change Material) vacuum in the pores of the polyurethane foam. Since it is impregnated, the temperature control function of the vehicle headlining can be maximized in high or low temperature conditions. In particular, the PCM-applied polyurethane foam for vehicle headlining according to an embodiment of the present invention, the manufacturing method thereof, and the PCM-applied polyurethane foam-based vehicle headlining have no pore closure inside the pores of the open cell structure of the polyurethane foam. Since the PCM is arranged, even if the PCM is impregnated therein, the high air permeability of the polyurethane foam is maintained, so that the PCM can function smoothly. In addition, the PCM-applied polyurethane foam for vehicle headlining according to an embodiment of the present invention, the manufacturing method thereof, and the PCM-applied polyurethane foam-based vehicle headlining allow the PCM to be disposed only in the inner pores under the surface of the polyurethane foam. The adhesion of the surface is improved so that adhesion of various materials on the surface can be smoothly performed without an adhesive material such as a hot melt.
상술한 바와 같은, 본 발명의 실시예에 따른 차량 헤드라이닝용 PCM 적용 폴리우레탄 폼, 그의 제조방법 및 PCM 적용 폴리우레탄 폼 기반 차량 헤드라이닝을 상기한 설명 및 도면에 따라 도시하였지만, 이는 예를 들어 설명한 것에 불과하며 본 발명의 기술적 사상을 벗어나지 않는 범위 내에서 다양한 변화 및 변경이 가능하다는 것을 이 분야의 통상적인 기술자들은 잘 이해할 수 있을 것이다.As described above, the PCM-applied polyurethane foam for vehicle headlining according to the embodiment of the present invention, the manufacturing method thereof, and the PCM-applied polyurethane foam-based vehicle headlining are illustrated according to the above description and drawings, but this is for example It is only described, and those skilled in the art will appreciate that various changes and modifications are possible without departing from the technical spirit of the present invention.

Claims (6)

  1. 오픈 셀(open cell) 구조의 기공(111)이 형성되어 있는 폴리우레탄 폼(110);A polyurethane foam 110 in which pores 111 having an open cell structure are formed;
    기공 폐쇄없이 상기 기공(111) 내부에 배치되어 온도조절 기능을 수행하는 PCM(120);을 포함하는 구성으로 이루어지는 것을 특징으로 하는 차량 헤드라이닝용 PCM 적용 폴리우레탄 폼.PCM applied polyurethane foam for vehicle headlining, characterized in that consisting of a configuration comprising a; PCM (120) is disposed inside the pores 111 without pores to perform a temperature control function.
  2. 제 1항에 있어서,According to claim 1,
    상기 PCM(120)은 상기 폴리우레탄 폼(110) 표면 아래측에 배치되어 있는 기공(111)을 둘러싸는 내주면에 부착되어 기공(111)에 공기와 물이 통과할 수 있는 유로(112)가 형성되도록 하는 것을 특징으로 하는 차량 헤드라이닝용 PCM 적용 폴리우레탄 폼.The PCM 120 is attached to an inner circumferential surface surrounding the pores 111 disposed below the surface of the polyurethane foam 110, and thus a flow path 112 through which air and water can pass is formed in the pores 111. PCM applied polyurethane foam for vehicle headlining, characterized in that to be.
  3. 오픈 셀 구조의 기공(111)이 형성된 폴리우레탄 폼(110)이 배치되는 폴리우레탄 폼 배치단계;A polyurethane foam placement step in which the polyurethane foam 110 in which the pore 111 of the open cell structure is formed is disposed;
    상기 폴리우레탄 폼(110) 상부표면으로 액상의 PCM(120)을 분사시키는 PCM 분사단계;PCM injection step of spraying the liquid PCM (120) to the upper surface of the polyurethane foam (110);
    상기 폴리우레탄 폼(110)의 하부표면에 설정크기의 진공압이 부여되면서 상기 폴리우레탄 폼(110) 상부표면으로 분사되어 분산배치되는 상기 PCM(120)이 상기 폴리우레탄 폼(110) 표면 아래측에 배치되는 기공(111)으로 침투하고, 기공(111)으로 침투한 상기 PCM(120)이 기공 폐쇄없이 상기 기공(111) 내부에 배치되는 PCM 진공함침단계;를 포함하는 것을 특징으로 하는 차량 헤드라이닝용 PCM 적용 폴리우레탄 폼의 제조방법.While the vacuum pressure of a set size is applied to the lower surface of the polyurethane foam 110, the PCM 120, which is sprayed and distributed to the upper surface of the polyurethane foam 110, is distributed below the surface of the polyurethane foam 110. Vehicle head characterized in that it comprises; a PCM vacuum impregnation step that penetrates into the pores 111 disposed in the pores, and the PCM 120 penetrated into the pores 111 is disposed inside the pores 111 without closing the pores. Manufacturing method of polyurethane foam with PCM for lining.
  4. 제 3항에 있어서,According to claim 3,
    상기 PCM 분사단계는 The PCM injection step
    고체상의 PCM(120)을 융해한 후 희석시킨 액상의 PCM(120)을 분사하되, 상기 액상의 PCM(120)은 20~40%의 농도를 갖는 것을 특징으로 하는 차량 헤드라이닝용 PCM 적용 폴리우레탄 폼의 제조방법.After dissolving the solid PCM 120 and spraying the diluted liquid PCM 120, the liquid PCM 120 has a concentration of 20 to 40%. Method of manufacturing foam.
  5. 최하단층을 이루고, 부직포를 포함하는 하단 부직포 시트층(210);A bottom nonwoven sheet layer 210 forming a bottommost layer and including a nonwoven fabric;
    상기 하단 부직포 시트층(210) 상부면에 적층되고, 글라스 매트로 이루어지는 글라스 매트층(220a);A glass mat layer 220a laminated on an upper surface of the lower nonwoven sheet layer 210 and made of a glass mat;
    상기 글라스 매트층(220) 상부면에 적층되고, 경질의 폴리우레탄 폼을 포함하되, 상기 폴리우레탄 폼에는 PCM이 내부함침되어 있는 경질 PU FOAM층(230);A hard PU FOAM layer 230 which is laminated on the glass mat layer 220 and includes a rigid polyurethane foam, wherein the polyurethane foam is impregnated with PCM;
    상기 경질 PU FOAM층(230) 상부면에 적층되고, 글라스 매트로 이루어지는 글라스 매트층(220b);A glass mat layer 220b laminated on the hard PU FOAM layer 230 and formed of a glass mat;
    상기 글라스 매트층(220b) 상부면에 적층되고, 부직포를 포함하는 중단 부직포 시트층(240);The glass mat layer (220b) is laminated on the upper surface, the middle non-woven sheet layer 240 including a non-woven fabric;
    상기 중단 부직포 시트층(240) 상부면에 적층되는 필름층(250);A film layer 250 laminated on an upper surface of the middle nonwoven sheet layer 240;
    상기 필름층(250) 상부면에 적층되고, 연질의 폴리우레탄 폼을 포함하는 연질 PU FOAM층(260); 및A flexible PU FOAM layer 260 laminated on the film layer 250 and including a flexible polyurethane foam; And
    상기 연질 PU FOAM층(260) 상부면에 적층되어 최상단층을 이루고, 외부로 노출되어 표피를 이루는 헤드라이닝 표피층(270)을 포함하는 구성으로 이루어지되,The soft PU FOAM layer 260 is stacked on the upper surface to form the uppermost layer, and is made of a configuration including a headlining epidermal layer 270 exposed to the outside to form an epidermis,
    상기 경질 PU FOAM층(230)은,The hard PU FOAM layer 230,
    오픈 셀(open cell) 구조의 기공(111)이 형성되어 있는 폴리우레탄 폼(110);A polyurethane foam 110 in which pores 111 having an open cell structure are formed;
    기공 폐쇄없이 상기 기공(111) 내부에 배치되어 온도조절 기능을 수행하는 PCM(120);을 포함하는 구성으로 이루어지는 것을 특징으로 하는 PCM 적용 폴리우레탄 폼 기반 차량 헤드라이닝.PCM-applied polyurethane foam-based vehicle headlining comprising a configuration comprising; PCM (120) disposed inside the pore (111) without pore closing to perform a temperature control function.
  6. 제 5항에 있어서,The method of claim 5,
    상기 하단 부직포 시트층(210), 글라스 매트층(220a), 경질 PU FOAM층(230), 글라스 매트층(220b), 중단 부직포 시트층(240)는 기재층을 구성하는 것이고, The lower nonwoven sheet layer 210, the glass mat layer 220a, the rigid PU FOAM layer 230, the glass mat layer 220b, and the middle nonwoven sheet layer 240 constitute a base layer,
    상기 필름층(250), 연질 PU FOAM층(260), 헤드라이닝 표피층(270)는 표피층을 구성하는 것을 특징으로 하는 PCM 적용 폴리우레탄 폼 기반 차량 헤드라이닝.The film layer 250, the soft PU FOAM layer 260, the head lining epidermal layer 270 is PCM-applied polyurethane foam-based vehicle headlining comprising a skin layer.
PCT/KR2019/011572 2018-09-06 2019-09-06 Pcm-applied polyurethane foam for car headlining, method for manufacturing same, and pcm-applied polyurethane foam-based car headlining WO2020050693A1 (en)

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