WO2020039366A1 - Combinaison herbicide - Google Patents

Combinaison herbicide Download PDF

Info

Publication number
WO2020039366A1
WO2020039366A1 PCT/IB2019/057044 IB2019057044W WO2020039366A1 WO 2020039366 A1 WO2020039366 A1 WO 2020039366A1 IB 2019057044 W IB2019057044 W IB 2019057044W WO 2020039366 A1 WO2020039366 A1 WO 2020039366A1
Authority
WO
WIPO (PCT)
Prior art keywords
herbicide
herbicides
clodinafop
inhibitor
propargyl
Prior art date
Application number
PCT/IB2019/057044
Other languages
English (en)
Inventor
Jaidev Rajnikant Shroff
Vikram Rajnikant Shroff
Original Assignee
Upl Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Upl Ltd filed Critical Upl Ltd
Priority to BR112021003218-5A priority Critical patent/BR112021003218A2/pt
Priority to CN202310016425.0A priority patent/CN116406669A/zh
Priority to CN201980066745.9A priority patent/CN113056198A/zh
Publication of WO2020039366A1 publication Critical patent/WO2020039366A1/fr

Links

Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01P—BIOCIDAL, PEST REPELLANT, PEST ATTRACTANT OR PLANT GROWTH REGULATORY ACTIVITY OF CHEMICAL COMPOUNDS OR PREPARATIONS
    • A01P13/00—Herbicides; Algicides
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/647—Triazoles; Hydrogenated triazoles
    • A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/707—1,2,3- or 1,2,4-triazines; Hydrogenated 1,2,3- or 1,2,4-triazines
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • A01N47/38—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< where at least one nitrogen atom is part of a heterocyclic ring; Thio analogues thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
    • A01N33/16—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds containing nitrogen-to-oxygen bonds
    • A01N33/18—Nitro compounds
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N41/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
    • A01N41/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
    • A01N41/04—Sulfonic acids; Derivatives thereof
    • A01N41/06—Sulfonic acid amides
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings

Definitions

  • the present invention relates to combinations of herbicides for controlling harmful undesirable plants.
  • the present invention more specifically relates to a synergistic combination of herbicides.
  • Weeds are undesirable plants that can severely damage yield in crops. farmers usually control these plants at the pre-plant stage as well as after sowing. Modern herbicides are used to either control or suppress these undesirable plants so as to allow sown crops a greater share of nutrient.
  • ACCase inhibitors are known to control undesired vegetation such as grasses (graminids).
  • ACCase inhibitors were first introduced in 1978 and are widely used to control grass species.
  • APP Aryloxyphenoxypropionates
  • CHD Cylcohexanediones
  • PPZ Phenylpyrazolines
  • APPs are an important class of herbicides due to their high efficiency, broad spectrum, low toxicity and good selectivity.
  • Some of the known APP herbicides are clodinafop- propargyl, cyhalofop-butyl, diclofop-methyl, diclofop-P-methyl, fenoxaprop-P-ethyl, fluazifop-butyl, fluazifop-P-butyl, haloxyfop, haloxyfop-P, haloxyfop-P-methyl, propaquizafop, quizalofop, quizalofop-ethyl, quizalofop-P, quizalofop-P-ethyl and quizalofop-P-tefuryl.
  • Clodinafop-propargyl is 2-Propynyl- (2R)-2-[4-[(5-chlor-3-fluor-2-pyridinyl)oxy]phenoxy]propanoate which is an ester of 2-(4-(3-Chloro-5-fluoro-2-pyridyloxy)-phenoxy-propionic acid. It is a systemic herbicide that acts on post-emergent weeds such as wild oats, rough meadow- grass, green foxtail, barnyard grass, persian darnel and volunteer canary seed.
  • Clodinafop-propargyl possesses herbicidal activity against grassy weeds in winter cereals especially in wheat and barley as well as pulses. Clodinafop-propargyl interacts with and inhibits the Acetyl-CoA carboxylase, which is essential for the production of lipids or fatty acids needed for plant growth. The selectivity of this herbicide is based on the difference in the speed of herbicide breakdown in the crop versus the weeds. Clodinafop-propargyl converts from the ester form to the active acid and then to biologically inactive compounds. Microtubule Inhibitors are generally applied to control annual grasses and some broadleaf weeds in several crops and turf grass.
  • Pendimethalin is a microtubule inhibitor herbicide, which is used both pre and post emergent for control of broadleaf and annual grasses. Pendimethalin is known to be used in combination such as those known from WO2012177860 (Mann et.al.), which is incorporated herein by reference in its entirety.
  • Photosynthetic Inhibitors control many broadleaf and some grass weeds by interfering in the electron transport chain and indirectly membrane leakage and cell damage. These herbicides are excellent tools for controlling pre-emergent weeds.
  • Metribuzin is a photosynthesis inhibitor herbicide that is used for both pre and post emergent control of broadleaf and annual grasses. Metribuzin is known to be combined with other herbicides such as the combinations known from WO2011082958 (Hubert et.al), which is incorporated herein by reference in its entirety. Combinations of herbicides are used to control a broader range of weeds. However, the combination of herbicides may not always result in the desired effect. Combination of herbicides may lead to an additive effect or an antagonistic effect.
  • the present invention may provide a herbicidal combination comprising:
  • At least one acetyl CoA carboxylase inhibitor selected from arylphenoxy- propionate herbicides, cyclohexanedione herbicides, or phenylpyrazoline herbicides;
  • At least one photosynthesis II inhibitor selected from a triazine herbicide, a triazinone herbicide, triazole herbicide, triazolone herbicide, triazolinone herbicide, uracil herbicide, pyridazinone herbicide, a triazolopyrimidine herbicide, or phenyl-carbamate herbicide;
  • the present invention may provide a herbicidal combination comprising:
  • At least one first herbicide selected from clodinafop, clodinafop- propargyl, cyhalofop-butyl, diclofop, diclofop-methyl, fenoxaprop-P- ethyl, fenoxaprop-P, fenoxaprop-ethyl, fenoxaprop, fluazifop, fluazifop- butyl, fluazifop- P-butyl, haloxyfop, haloxyfop-etotyl, haloxyfop-P-methyl, propaquizafop, quizalofop, quizalofop-ethyl, quizalofop-P, quizalofop-P- ethyl, and quizalofop-P-tefuryl, or an agriculturally acceptable salt;
  • At least one second herbicide selected from a triazine herbicide, triazinone herbicide, triazole herbicide, triazolone herbicide, or triazolopyrimidine herbicide;
  • the present invention may provide a method of controlling weeds at a locus, said method comprising applying to the locus a herbicidal combination comprising:
  • At least one acetyl CoA carboxylase inhibitor selected from arylphenoxy- propionate herbicides, cyclohexanedione herbicides, or phenylpyrazoline herbicides;
  • At least one photosynthesis II inhibitor selected from a triazine herbicide, a triazinone herbicide, triazole herbicide, triazolone herbicide, triazolinone herbicide, uracil herbicide, pyridazinone herbicide, a triazolopyrimidine herbicide, or phenyl-carbamate herbicide;
  • At least one microtubule assembly inhibitor herbicide selected from a dinitroaniline herbicide, a phosphoroamidate herbicide, pyridine herbicide, benzamide herbicide, or a benzoic acid herbicide.
  • Another aspect of the present invention may provide a method of controlling weeds at a locus, said method comprising applying to the locus a combination comprising:
  • At least one first herbicide selected from clodinafop, clodinafop- propargyl, cyhalofop-butyl, diclofop, diclofop-methyl, fenoxaprop-P- ethyl, fenoxaprop-P, fenoxaprop-ethyl, fenoxaprop, fluazifop, fluazifop- butyl, fluazifop-P-butyl, haloxyfop, haloxyfop-etotyl, haloxyfop-P-methyl, propaquizafop, quizalofop, quizalofop-ethyl, quizalofop-P, quizalofop-P- ethyl, and quizalofop-P-tefuryl, or an agriculturally acceptable salt;
  • At least one second herbicide selected from a triazine herbicide, triazinone herbicide, triazole herbicide, triazolone herbicide, or triazolopyrimidine herbicide;
  • the present invention may provide a herbicidal composition comprising:
  • At least one acetyl CoA carboxylase inhibitor selected from arylphenoxy- propionate herbicides, cyclohexanedione herbicides, or phenylpyrazoline herbicides;
  • At least one photosynthesis II inhibitor selected from a triazine herbicide, a triazinone herbicide, triazole herbicide, triazolone herbicide, triazolinone herbicide, uracil herbicide, pyridazinone herbicide, a triazolopyrimidine herbicide, or phenyl-carbamate herbicide;
  • At least one microtubule assembly inhibitor herbicide selected from a dinitroaniline herbicide, a phosphoroamidate herbicide, pyridine herbicide, benzamide herbicide, or a benzoic acid herbicide.
  • composition comprising:
  • At least one first herbicide selected from clodinafop, clodinafop- propargyl, cyhalofop-butyl, diclofop, diclofop-methyl, fenoxaprop-P- ethyl, fenoxaprop-P, fenoxaprop-ethyl, fenoxaprop, fluazifop, fluazifop- butyl, fluazifop-P-butyl, haloxyfop, haloxyfop-etotyl, haloxyfop-P-methyl, propaquizafop, quizalofop, quizalofop-ethyl, quizalofop-P, quizalofop-P- ethyl, and quizalofop-P-tefuryl, or an agriculturally acceptable salt;
  • At least one second herbicide selected from a triazine herbicide, triazinone herbicide, triazole herbicide, triazolone herbicide, or triazolopyrimidine herbicide;
  • Yet another aspect of the present invention may provide a method of increasing yield in a crop by application of a combination comprising:
  • At least one acetyl CoA carboxylase inhibitor selected from arylphenoxy- propionate herbicides, cyclohexanedione herbicides, or phenylpyrazoline herbicides;
  • At least one photosynthesis II inhibitor selected from a triazine herbicide, a triazinone herbicide, triazole herbicide, triazolone herbicide, triazolinone herbicide, uracil herbicide, pyridazinone herbicide, a triazolopyrimidine herbicide, or phenyl-carbamate herbicide;
  • At least one microtubule assembly inhibitor herbicide selected from a dinitroaniline herbicide, a phosphoroamidate herbicide, pyridine herbicide, benzamide herbicide, or a benzoic acid herbicide.
  • Another aspect of the present invention may provide a method of improving the plant health, said method comprising application at the locus of the plant a combination comprising:
  • At least one acetyl CoA carboxylase inhibitor selected from arylphenoxy- propionate herbicides, cyclohexanedione herbicides, or phenylpyrazoline herbicides;
  • At least one photosynthesis II inhibitor selected from a triazine herbicide, a triazinone herbicide, triazole herbicide, triazolone herbicide, triazolinone herbicide, uracil herbicide, pyridazinone herbicide, a triazolopyrimidine herbicide, or phenyl-carbamate herbicide;
  • At least one microtubule assembly inhibitor herbicide selected from a dinitroaniline herbicide, a phosphoroamidate herbicide, pyridine herbicide, benzamide herbicide, or a benzoic acid herbicide.
  • herbicide shall mean an active ingredient that kills, controls or otherwise adversely modifies the growth of plants.
  • a herbicidally effective or vegetation controlling amount is an amount of active ingredient that causes a“herbicidal effect,” i.e. , an adversely modifying effect and includes deviations from natural development, killing, regulation, desiccation, retardation.
  • plants and“vegetation” include, but are not limited to, germinant seeds, emerging seedlings, plants emerging from vegetative propagules, and established vegetation.
  • locus as used herein shall denote the vicinity of a desired crop in which weed control, typically selective weed control, of weeds is desired. The locus includes the vicinity of desired crop plants wherein the weed infestation has either emerged or is yet to emerge.
  • crop shall include a multitude of desired crop plants or an individual crop plant growing at a locus.
  • the phrase comprising may be replaced by the phrases “consisting of’ or “consisting essentially of” or “consisting essentially of”.
  • the combination or composition described includes or comprises or consists of or consists essentially of or consists substantially of the specific components recited therein, to the exclusion of other fungicides or insecticide or herbicides or plant growth promoting agents or adjuvants or excipients not specifically recited therein.
  • the present invention may provide a herbicidal combination comprising:
  • At least one acetyl CoA carboxylase inhibitor selected from arylphenoxy- propionate herbicides, cyclohexanedione herbicides, or phenylpyrazoline herbicides;
  • At least one photosynthesis II inhibitor selected from a triazine herbicide, a triazinone herbicide, triazole herbicide, triazolone herbicide, triazolinone herbicide, uracil herbicide, pyridazinone herbicide, a triazolopyrimidine herbicide, or phenyl-carbamate herbicide; and (c) at least one microtubule assembly inhibitor herbicide selected from a dinitroaniline herbicide, a phosphoroamidate herbicide, pyridine herbicide, benzamide herbicide, or a benzoic acid herbicide.
  • the herbicidal combinations of the present invention comprise one herbicide from these three classes of herbicides.
  • the present invention may provide a herbicidal combination comprising:
  • an acetyl CoA carboxylase inhibitor selected from arylphenoxy- propionate herbicides, cyclohexanedione herbicides, or phenylpyrazoline herbicides;
  • a photosystem II inhibitor selected from a triazine herbicide, a triazinone herbicide, triazole herbicide, triazolone herbicide, triazolinone herbicide, uracil herbicide, pyridazinone herbicide, a triazolopyrimidine herbicide, or phenyl-carbamate herbicide; and
  • a microtubule assembly inhibitor herbicide selected from a dinitroaniline herbicide, a phosphoroamidate herbicide, pyridine herbicide, benzamide herbicide, or a benzoic acid herbicide.
  • the present invention provides a method of controlling weeds at a locus by applying the combination of the present invention to the locus.
  • the present invention may provide a method of controlling weeds at a locus, said method comprising applying to the locus a combination comprising:
  • At least one acetyl CoA carboxylase inhibitor selected from arylphenoxy- propionate herbicides, cyclohexanedione herbicides, or phenylpyrazoline herbicides;
  • At least one photosynthesis II inhibitor selected from a triazine herbicide, a triazinone herbicide, triazole herbicide, triazolone herbicide, triazolinone herbicide, uracil herbicide, pyridazinone herbicide, a triazolopyrimidine herbicide, or phenyl-carbamate herbicide;
  • At least one microtubule assembly inhibitor herbicide selected from a dinitroaniline herbicide, a phosphoroamidate herbicide, pyridine herbicide, benzamide herbicide, or a benzoic acid herbicide.
  • the present invention provides a composition comprising the combinations of the present invention, and at least another agrochemically acceptable excipient.
  • the present invention may provide a composition comprising:
  • At least one acetyl CoA carboxylase inhibitor selected from arylphenoxy- propionate herbicides, cyclohexanedione herbicides, or phenylpyrazoline herbicides;
  • At least one photosynthesis II inhibitor selected from a triazine herbicide, a triazinone herbicide, triazole herbicide, triazolone herbicide, triazolinone herbicide, uracil herbicide, pyridazinone herbicide, a triazolopyrimidine herbicide, or phenyl-carbamate herbicide;
  • At least one microtubule assembly inhibitor herbicide selected from a dinitroaniline herbicide, a phosphoroamidate herbicide, pyridine herbicide, benzamide herbicide, or a benzoic acid herbicide.
  • the present invention provides a method for increasing yield in a crop by using the combinations of the present invention.
  • the present invention may provide a method of increasing yield in a crop by application of a combination comprising:
  • acetyl CoA carboxylase inhibitor selected from arylphenoxy- propionate herbicides, cyclohexanedione herbicides, or phenylpyrazoline herbicides
  • photosynthesis II inhibitor selected from a triazine herbicide, a triazinone herbicide, triazole herbicide, triazolone herbicide, triazolinone herbicide, uracil herbicide, pyridazinone herbicide, a triazolopyrimidine herbicide, or phenyl-carbamate herbicide
  • microtubule assembly inhibitor herbicide selected from a dinitroaniline herbicide, a phosphoroamidate herbicide, pyridine herbicide, benzamide herbicide, or a benzoic acid herbicide.
  • the present invention may provide a method of improving the plant health using the combinations of the present invention.
  • the present invention may provide a method of improving the plant health, said method comprising application at the locus of the plant a combination comprising:
  • At least one acetyl CoA carboxylase inhibitor selected from arylphenoxy- propionate herbicides, cyclohexanedione herbicides, or phenylpyrazoline herbicides;
  • At least one photosynthesis II inhibitor selected from a triazine herbicide, a triazinone herbicide, triazole herbicide, triazolone herbicide, triazolinone herbicide, uracil herbicide, pyridazinone herbicide, a triazolopyrimidine herbicide, or phenyl-carbamate herbicide;
  • At least one microtubule assembly inhibitor herbicide selected from a dinitroaniline herbicide, a phosphoroamidate herbicide, pyridine herbicide, benzamide herbicide, or a benzoic acid herbicide.
  • the acetyl CoA carboxylase inhibitor is an arylphenoxy- propionate herbicide.
  • the arylphenoxy-propionate herbicide is selected from the group consisting of clodinafop, clodinafop-propargyl, cyhalofop-butyl, diclofop, diclofop- methyl, fenoxaprop-P-ethyl, fenoxaprop-P, fenoxaprop-ethyl, fenoxaprop, fluazifop, fluazifop-butyl, fluazifop-P-butyl, haloxyfop, haloxyfop-etotyl, haloxyfop- P-methyl, propaquizafop, quizalofop, quizalofop-ethyl, quizalofop-P, quizalofop-P- ethyl, and quizalofop-P-tefuryl, or an agriculturally acceptable salt thereof.
  • the arylphenoxy-propionate herbicide is clodinafop or clodinafop-propargyl. In an embodiment, the arylphenoxy-propionate herbicide is haloxyfop, haloxyfop- etotyl, or haloxyfop-P-methyl.
  • the arylphenoxy-propionate herbicide is quizalofop, quizalofop- ethyl, quizalofop-P, quizalofop-P-ethyl, or quizalofop-P-tefuryl.
  • the acetyl CoA carboxylase inhibitor is a cyclohexanedione herbicide.
  • the cyclohexadione herbicide is a benzoylcyclohexanedione herbicide selected from fenquinotrione, ketospiradox, lancotrione, mesotrione, sulcotrione, tefuryltrione or tembotrione.
  • the cyclohexadione herbicide is mesotrione. In an embodiment, the cyclohexadione herbicide is sulcotrione.
  • the cyclohexadione herbicide is tembotrione.
  • the acetyl CoA carboxylase inhibitor is a phenylpyrazoline herbicide.
  • the phenylpyrazoline herbicide is selected from fluazolate, nipyraclofen, pinoxaden or pyraflufen.
  • the phenylpyrazoline herbicide is pinoxaden.
  • the combination comprises a photosynthesis II inhibitor.
  • the photosynthesis II inhibitor is selected from a triazine herbicide, a triazinone herbicide, triazole herbicide, triazolone herbicide, triazolinone herbicide, uracil herbicide, pyridazinone herbicide, a triazolopyrimidine herbicide, or phenyl-carbamate herbicide.
  • the photosynthesis II inhibitor is a triazine herbicide.
  • the triazine herbicide is selected from the group consisting of dipropetryn, fucaojing, trihydroxytriazine, atrazine, chlorazine, cyanazine, cyprazine, eglinazine, ipazine, mesoprazine, procyazine, proglinazine, propazine, sebuthylazine, simazine, terbuthylazine, trietazine, indaziflam, triaziflam, atraton, methometon, prometon, secbumeton, simeton, terbumeton, ametryn, aziprotryne, cyanatryn, desmetryn, dimethametryn, methoprotryne, prometryn, simetryn, and terbutryn.
  • the triazine herbicide is atrazine.
  • the photosynthesis II inhibitor is a triazinone herbicide.
  • the triazinone herbicide is selected from ametridione, amibuzin, ethiozin, hexazinone, isomethiozin, metamitron, metribuzin and trfludimoxazin.
  • the triazinone herbicide is selected from hexazinone, metamitron and metribuzin.
  • the triazinone herbicide is hexazinone.
  • the triazinone herbicide is metamitron.
  • the triazinone herbicide is metribuzin.
  • the photosynthesis II inhibitor is a triazole herbicide.
  • the triazole herbicide is selected from amitrole, cafenstrole, epronaz and flupoxam.
  • the photosynthesis II inhibitor is a triazolone herbicide.
  • the triazolone herbicide is selected from amicarbazone, bencarbazone, carfentrazone, flucarbazone, ipfencarbazone, propoxycarbazone, sulfentrazone and thiencarbazone.
  • the triazolone herbicide is selected from carfentrazone, flucarbazone and sulfentrazone. In an embodiment, the triazolone herbicide is sulfentrazone.
  • the photosynthesis II inhibitor is a triazolopyrimidine herbicide.
  • the triazolopyrimidine herbicide is selected from cloransulam, diclosulam, florasulam, flumetsulam, metosulam, penoxsulam and pyroxsulam.
  • the triazolopyrimidine herbicide is penoxsulam.
  • the photosynthesis II inhibitor is an uracil herbicide.
  • the uracil herbicide is selected from benzfendizone, bromacil, butafenacil, flupropacil, isocil, lenacil, saflufenacil, terbacil or tiafenacil.
  • the uracil herbicide is saflufenacil.
  • the photosynthesis II inhibitor is a pyridazinone herbicide.
  • the pyridazinone herbicide is selected from brompyrazon, chloridazon, dimidazon, flufenpyr, metflurazon, norflurazon, oxapyrazon or pydanon.
  • the photosystem II inhibitor is a phenyl-carbamate herbicide.
  • the phenyl-carbamate herbicide is desmedipham.
  • the phenyl-carbamate herbicide is phenmedipham.
  • the combination of the present invention comprises at least one microtubule assembly inhibitor.
  • the microtubule assembly inhibitor herbicide is selected from a dinitroaniline herbicide, a phosphoroamidate herbicide, pyridine herbicide, benzamide herbicide, or a benzoic acid herbicide.
  • the microtubule assembly inhibitor is a dinitroaniline herbicide.
  • the dinitroaniline herbicide may be selected from benfluralin, butralin, chlornidine, dinitramine, dipropalin, ethalfluralin, fluchloralin, isopropalin, nitralin, oryzalin, pendimethalin, prodiamine, profluralin and trifluralin.
  • the dinitroaniline herbicide may be selected from oryzalin and pendimethalin.
  • the microtubule assembly inhibitor is a phosphoroamidate herbicide.
  • the phosphoroamidate herbicide is selected from amiprofos- m ethyl or butamifos.
  • the microtubule assembly inhibitor is a pyridine herbicide.
  • the pyridine herbicide is selected from aminopyralid, cliodinate, clopyralid, diflufenican, dithiopyr, florpyrauxifen, flufenican, fluroxypyr, halauxifen, haloxydine, picloram, picolinafen, pyriclor, pyroxsulam, thiazopyr, and triclopyr.
  • the pyridine herbicide is diflufenican.
  • the pyridine herbicide is fluroxypyr.
  • the pyridine herbicide is halauxifen.
  • the pyridine herbicide is picloram. In an embodiment, the pyridine herbicide is pyroxsulam.
  • the microtubule assembly inhibitor is a benzamide herbicide.
  • the benzamide herbicide is selected from pronamide or isoxaben.
  • the microtubule assembly inhibitor is a benzoic acid herbicide.
  • the benzoic acid herbicide is selected from cambendichlor, chloramben, dicamba, 2,3,6-TBA, tricamba, bispyribac, pyriminobac or pyrithiobac.
  • the benzoic acid herbicide is dicamba.
  • the benzoic acid herbicide is bispyribac.
  • the present invention may provide a herbicidal combination comprising:
  • At least one acetyl CoA carboxylase inhibitor selected from clodinafop- propargyl, clodinafop, haloxyfop, haloxyfop-etotyl, haloxyfop-P-methyl, quizalofop, quizalofop-ethyl, quizalofop-P, quizalofop-P-ethyl, or quizalofop-P-tefuryl, mesotrione, sulcotrione, tembotrione, or pinoxaden;
  • Atrazine atrazine, hexazinone, metamitron, metribuzin, flucarbazone, sulfentrazone, penoxsulam, saflufencil, desmedipham or phenmedipham; and
  • At least one microtubule assembly inhibitor herbicide selected from oryzalin, pendimethalin, diflufenican, fluroxypyr, halauxifen, picloram, pyroxsulam, dicamba or bispyribac.
  • the combinations and methods of the present invention comprise clodinafop propargyl, a second herbicide and a third herbicide.
  • the second herbicide is selected from triazine, hexazinone, metamitron, metribuzin, carfentrazone, flucarbazone, sulfentrazone or penoxsulam.
  • the third herbicide is a dinitroaniline herbicide.
  • the dinitroaniline herbicide may be selected from benfluralin, butralin, chlornidine, dinitramine, dipropalin, ethalfluralin, fluchloralin, isopropalin, nitralin, oryzalin, pendimethalin, prodiamine, profluralin and trifluralin.
  • the dinitroaniline herbicide may be selected from oryzalin and pendimethalin.
  • the present invention provides preferred combinations, compositions and methods thereof.
  • the methods of the invention include a method of controlling weeds at a locus by applying to the locus the combination or the composition, a method of increasing yield in a crop by application of the combination or composition, or a method of improving the plant health by application at the locus of the plant the combination or the composition.
  • the embodiments described herein describe the preferred embodiments of all these possible combinations, compositions and methods of the invention.
  • an embodiment of the present invention provides a combination and method comprising clodinafop propargyl; a second herbicide selected from triazine, hexazinone, metamitron, metribuzin, carfentrazone, flucarbazone, sulfentrazone and penoxsulam; and a third herbicide selected from oryzalin and pendimethalin.
  • An embodiment of the present invention provides a combination and method comprising clodinafop propargyl, triazine, and oryzalin.
  • An embodiment of the present invention provides a combination and method comprising clodinafop propargyl, triazine, and pendimethalin.
  • An embodiment of the present invention provides a combination and method comprising clodinafop propargyl, hexazinone, and oryzalin.
  • An embodiment of the present invention provides a combination and method comprising clodinafop propargyl, hexazinone, and pendimethalin.
  • An embodiment of the present invention provides a combination and method comprising clodinafop propargyl, metamitron, and oryzalin.
  • An embodiment of the present invention provides a combination and method comprising clodinafop propargyl, metamitron and pendimethalin.
  • An embodiment of the present invention provides a combination and method comprising clodinafop propargyl, metribuzin and oryzalin.
  • An embodiment of the present invention provides a combination and method comprising clodinafop propargyl, metribuzin, and pendimethalin.
  • An embodiment of the present invention provides a combination and method comprising clodinafop propargyl, carfentrazone, and oryzalin.
  • An embodiment of the present invention provides a combination and method comprising clodinafop propargyl, carfentrazone, and pendimethalin.
  • An embodiment of the present invention provides a combination and method comprising clodinafop propargyl, flucarbazone, and oryzalin.
  • An embodiment of the present invention provides a combination and method comprising clodinafop propargyl, flucarbazone, and pendimethalin.
  • An embodiment of the present invention provides a combination and method comprising clodinafop propargyl, sulfentrazone and oryzalin.
  • An embodiment of the present invention provides a combination and method comprising clodinafop propargyl, sulfentrazone and pendimethalin.
  • An embodiment of the present invention provides a combination and method comprising clodinafop propargyl, penoxsulam, and oryzalin.
  • An embodiment of the present invention provides a combination and method comprising clodinafop propargyl, penoxsulam and pendimethalin.
  • the combinations of the present invention include the following preferred combinations.
  • each individual row appearing in the table below represents the combinations in an embodiment of the present invention.
  • the present invention may provide a combination comprising the three herbicides as listed in each individual row from row 1 to row 594 in the table above.
  • the combination of the present invention may be combined with at least one other active such as those selected from but not limited to herbicide, insecticide, fungicide, biological agent, plant growth activator, fertilizers or combinations thereof.
  • the combination of the present invention may be combined with a herbicide.
  • herbicides that may be combined with the combination of the present invention may be selected from but not limited to herbicides belonging to classes such as ALS inhibitors, EPSP synthase inhibitors, synthetic auxins, auxin transport inhibitors, glutamate synthase inhibitors, HPPD inhibitors, lipid synthesis inhibitors, long chain fatty acid inhibitors, as well as herbicides with unknown modes of action.
  • the total amount of clodinafop propargyl in the composition may typically be in the range of 0.1 to 99% by weight, preferably 0.2 to 90% by weight. In an embodiment, the total amount of pendimethalin in the composition may be in the range of 0.1 to 99% by weight.
  • the total amount of metribuzin in the composition may be in the range of 0.1 to 99% by weight.
  • the constituent herbicides of the combination of the present invention may be admixed in ratio of (1-80): (1-80): (1-80) of the three herbicides respectively.
  • the constituent herbicides of the combination of the present invention may be admixed in ratio of (1-80): (1-80): (1-80) of clodinafop propargyl, metribuzin and pendimethalin respectively.
  • the herbicidal combination of the present invention maybe used to target weeds among the crops such corn, rice, wheat, barley, rye, oat, sorghum, cotton, soybean, peanut, buckwheat, beet, rapeseed, sunflower, sugar cane, tobacco, etc.; vegetables: solanaceous vegetables such as eggplant, tomato, pimento, pepper, potato, etc., cucurbit vegetables such as cucumber, pumpkin, zucchini, water melon, melon, squash, etc., cruciferous vegetables such as radish, white turnip, horseradish, kohlrabi, Chinese cabbage, cabbage, leaf mustard, broccoli, cauliflower, etc., asteraceous vegetables such as burdock, crown daisy, artichoke, lettuce, etc, liliaceous vegetables such as green onion, onion, garlic, and asparagus, ammiaceous vegetables such as carrot, parsley, celery, parsnip, etc., chenopodiaceous vegetables such as spinach, Swiss chard, etc., lami
  • berries such as blueberry, cranberry, blackberry, raspberry, etc., grape, kaki fruit, olive, plum, banana, coffee, date palm, coconuts, etc. , trees other than fruit trees; tea, mulberry, flowering plant, trees such as ash, birch, dogwood, Eucalyptus, Ginkgo biloba, lilac, maple, Quercus, poplar, Judas tree, Liquidambar formosana, plane tree, zelkova, Japanese arborvitae, fir wood, hemlock, juniper, Pinus, Picea, and Taxus cuspidate, etc.
  • the present invention may provide compositions of clodinafop propargyl, pendimethalin and metribuzin.
  • the composition of the present invention may contain agriculturally acceptable adjuvants, carriers, diluents, emulsifiers, fillers, anti foaming agents, thickening agents, anti-freezing agents, freezing agents etc.
  • the compositions may be either solid or liquids. They can be solids, such as, for example, dusts, granules, water-dispersible granules, microcapsules or wettable powders, or liquids, such as, for example, emulsifiable concentrates, solutions, emulsions or suspensions, ZC formulations. They can also be provided as a pre mix or tank mixed.
  • Suitable agricultural adjuvants and carriers may include, but are not limited to, crop oil concentrates; methylated seed oils, emulsified methylated seed oil, nonylphenol ethoxylate; benzylcocoalkyldimethyl quaternary ammonium salt; blend of petroleum hydrocarbon, alkyl esters, organic acid, and anionic surfactant; C9-C1 1 alkylpolyglycoside; phosphated alcohol ethoxylate; natural primary alcohol (C12- C16) ethoxylate; di-sec-butylphenol EO-PO block copolymer; polysiloxane-methyl cap; nonylphenol ethoxylate, urea ammonium nitrate; tridecyl alcohol (synthetic) ethoxylate (8EO); tallow amine ethoxylate ; PEG(400) dioleate-99, alkyl sulfates, such as diethanolammonium lauryl sulfate;
  • Suitable liquid carriers that may be employed in a composition of the present invention may include water or organic solvents.
  • the organic solvents include, but are not limited to, petroleum fractions or hydrocarbons such as mineral oil, aromatic solvents, paraffinic oils, and the like; vegetable oils such as soybean oil, rapeseed oil, olive oil, castor oil, sunflower seed oil, coconut oil, corn oil, cottonseed oil, linseed oil, palm oil, peanut oil, safflower oil, sesame oil, tung oil and the like; esters of the above vegetable oils; esters of monoalcohols or dihydric, trihydric, or other lower polyalcohols (4-6 hydroxy containing), such as 2-ethyl hexyl stearate, n-butyl oleate, isopropyl myristate, propylene glycol dioleate, di-octyl succinate, di-butyl adipate, di-octyl phthalate and the like; est
  • Organic solvents include, but are not limited to toluene, xylene, petroleum naphtha, crop oil, acetone, methyl ethyl ketone, cyclohexanone, trichloroethylene, perchloroethylene, ethyl acetate, amyl acetate, butyl acetate, propylene glycol monomethyl ether and diethylene glycol monomethyl ether, methyl alcohol, ethyl alcohol, isopropyl alcohol, amyl alcohol, ethylene glycol, propylene glycol, glycerine, N-methyl-2-pyrrolidinone, N,N-dimethyl alkylamides, dimethyl sulfoxide.
  • Solid carriers that may be employed in the compositions of the present invention may include but are not limited to attapulgite, pyrophyllite clay, silica, kaolin clay, kieselguhr, chalk, diatomaceous earth, lime, calcium carbonate, bentonite clay, Fuller's earth, talc, cottonseed hulls, wheat flour, soybean flour, pumice, wood flour, walnut shell flour, lignin, cellulose etc.
  • the present invention may provide methods of controlling weeds at a locus, said method comprising application of a combination of clodinafop propargyl, pendimethalin and metribuzin.
  • embodiments of the present invention may provide, method of controlling weeds at a locus, said method comprising application of combinations of clodinafop propargyl, pendimethalin, Metribuzin and optionally a fourth active.
  • the fourth active may selected from herbicide, insecticide, fungicide, biological agent, plant growth activator, fertilizers or combinations thereof.
  • the target weeds may be selected from Alopecurus myosuroides Huds. (blackgrass, ALOMY), Amaranthus palmeri (Palmer amaranth, AMAPA) Amaranthus viridis (slender amaranth, AMAVI), Avena fatua (wild oat, AVEFA), Brachiaria decumbens Stapf. or Urochloa decumbens (Stapf), Brachiaria brizantha or Urochloa brizantha, Brachiaria platyphylla (Groseb.) Nash or Urochloa platyphylla (broadleaf signalgrass, BRAPP), Brachiaria plantaginea.
  • Urochloa plantaginea alexandergrass, BRAPL
  • Cenchrus echinatus sinouthern sandbur, CENEC
  • Digitaria horizontalis Willd. Jamaican crabgrass, DIGHO
  • Digitaria insularis sourgrass, TRCIN
  • Digitaria sanguinalis large crabgrass, DIGSA
  • Echinochloa crus-galli barnyardgrass, ECHCG
  • Echinochloa colonum junglerice, ECHCO
  • Eleusine indica Gaertn. goosegrass, ELEIN
  • Lolium multiflorum Lam. Italian ryegrass, LOLMU
  • Panicum dichotomiflorum Michx Panicum dichotomiflorum Michx.
  • the combinations of the present invention may be applied to the locus either simultaneously or sequentially, such that Clodinafop, the second herbicide and third herbicide may be applied in a tank mix or as a pre-mixed composition.
  • the present invention provides a tank-mix comprising:
  • acetyl CoA carboxylase inhibitor selected from arylphenoxy- propionate herbicides, cyclohexanedione herbicides, or phenylpyrazoline herbicides
  • photosynthesis II inhibitor selected from a triazine herbicide, a triazinone herbicide, triazole herbicide, triazolone herbicide, triazolinone herbicide, uracil herbicide, pyridazinone herbicide, a triazolopyrimidine herbicide, or phenyl-carbamate herbicide
  • microtubule assembly inhibitor herbicide selected from a dinitroaniline herbicide, a phosphoroamidate herbicide, pyridine herbicide, benzamide herbicide, or a benzoic acid herbicide.
  • the present invention may be applied either pre or post emergent.
  • the advantage of the combination is surprisingly good residual effects, when applied in pre-emergent as well as quick knockdown when applied post emergent leading to quick control of weeds.
  • the present invention may be applied for quick burndown of weeds. Another advantage is quick knockdown in the case of burndown.
  • the method of control of the present invention may be carried out by spraying the suggested tank mixes, or the individual herbicides may be formulated as a kit-of- parts containing various components that may be mixed as instructed prior to spraying.
  • the present invention provides a kit-of-parts comprising a plurality of components, wherein said plurality of components comprises:
  • At least a first component comprising an acetyl CoA carboxylase inhibitor selected from arylphenoxy-propionate herbicides, cyclohexanedione herbicides, or phenylpyrazoline herbicides;
  • a second component comprising a photosynthesis II inhibitor selected from a triazine herbicide, a triazinone herbicide, triazole herbicide, triazolone herbicide, triazolinone herbicide, uracil herbicide, pyridazinone herbicide, a triazolopyrimidine herbicide, or phenyl- carbamate herbicide;
  • a third component comprising a microtubule assembly inhibitor herbicide selected from a dinitroaniline herbicide, a phosphoroamidate herbicide, pyridine herbicide, benzamide herbicide, or a benzoic acid herbicide.
  • the kit-of-parts comprises an instructions manual, said instructions manual comprising instructions directing a user to admix the components before being used.
  • the components of the present invention may be packaged such that clodinafop propargyl, the first herbicide and the second herbicide may be packaged separately and then tank mixed before the spraying.
  • the components of the present invention may be packaged such that clodinafop propargyl, the first herbicide and the second herbicide may be packaged separately, whereas other additives are packaged separately, such that the two maybe tank mixed at the time of spraying.
  • the components of the present invention may be packaged as composition such that clodinafop propargyl, the first herbicide and the second herbicide are formulated into one composition and other additives are packaged separately, such that the two maybe tank mixed at the time of spraying.
  • clodinafop propargyl, the first herbicide and the second herbicide of the present invention when applied individually, was ineffective in the control of weeds, but demonstrated excellent synergistic control on when applied together.
  • the combination controlled the weed both pre and post emergently.
  • the combination of clodinafop propargyl, the first herbicide and the second herbicide synergistically controlled broadleaf as well as grasses and sedges at a locus.
  • the current invention therefore provides advantageous methods of controlling weeds both pre and post emergently.
  • the present method also provides a broader spectrum of controlling weeds that helps in resistance management, thus preventing the weed from becoming resistant to either of the herbicides while providing a broader spectrum of control at lower use rates.
  • the present invention provides a combination comprising clodinafop-propargyl in an amount of 60 g/ha, metribuzin in an amount of 252 g/ha and pendimethalin in an amount of 812 g/ha.
  • a microtubule assembly inhibitor to a combination of a photosystem II inhibitor and an acetyl CoA carboxylase inhibitor led to a surprising and unexpected synergistic enhancement in efficacy of the combination of a photosystem II inhibitor and an acetyl CoA carboxylase inhibitor.
  • pendimethalin to a combination of clodinafop-propargyl and metribuzin led to a surprising and unexpected synergistic enhancement in efficacy of the combination of clodinafop- propargyl and metribuzin.
  • the addition of a acetyl CoA carboxylase inhibitor to a combination of a microtubule assembly inhibitor and a photosystem II inhibitor led to a surprising and unexpected synergistic enhancement in efficacy of the combination of a microtubule assembly inhibitor and a photosystem II inhibitor.
  • the addition of clodinafop- propargyl to a combination of metribuzin and pendimethalin led to a surprising and unexpected synergistic enhancement in efficacy of the combination of metribuzin and pendimethalin.
  • the present invention provides a combination comprising clodinafop-propargyl, pendimethalin, and metribuzin wherein pendimethalin and metribuzin are used in a ratio of about 6:1.
  • the present invention provides a combination comprising clodinafop-propargyl, pendimethalin, and metribuzin wherein pendimethalin is used in an amount of about 384.4 g/ha and metribuzin is used in an amount of about 65.6 g/ha.
  • the present invention provides a combination comprising clodinafop-propargyl, pendimethalin, and metribuzin wherein pendimethalin and metribuzin are present as a ZC formulation.
  • the present invention provides a combination comprising clodinafop-propargyl, pendimethalin, and metribuzin wherein pendimethalin and metribuzin are present as a ZC formulation, wherein said ZC formulation comprises encapsulated pendimethalin and a suspension concentrate of metribuzin.
  • the present invention provides a combination comprising clodinafop-propargyl, pendimethalin, and metribuzin wherein pendimethalin and metribuzin are present as a ZC formulation, wherein said ZC formulation comprises capsule suspension (CS) of pendimethalin and a suspension concentrate (SC) of metribuzin.

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Zoology (AREA)
  • Wood Science & Technology (AREA)
  • Plant Pathology (AREA)
  • Environmental Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Pest Control & Pesticides (AREA)
  • General Health & Medical Sciences (AREA)
  • Dentistry (AREA)
  • Agronomy & Crop Science (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

L'invention concerne une combinaison herbicide comprenant au moins un inhibiteur de l'acétyl-CoA carboxylase ; au moins un inhibiteur de la photosynthèse II et au moins un inhibiteur d'assemblage de microtubules.
PCT/IB2019/057044 2018-08-23 2019-08-21 Combinaison herbicide WO2020039366A1 (fr)

Priority Applications (3)

Application Number Priority Date Filing Date Title
BR112021003218-5A BR112021003218A2 (pt) 2018-08-23 2019-08-21 combinação herbicida
CN202310016425.0A CN116406669A (zh) 2018-08-23 2019-08-21 除草组合
CN201980066745.9A CN113056198A (zh) 2018-08-23 2019-08-21 除草组合

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
IN201831031609 2018-08-23
IN201831031609 2018-08-23

Publications (1)

Publication Number Publication Date
WO2020039366A1 true WO2020039366A1 (fr) 2020-02-27

Family

ID=69592693

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/IB2019/057044 WO2020039366A1 (fr) 2018-08-23 2019-08-21 Combinaison herbicide

Country Status (4)

Country Link
CN (2) CN116406669A (fr)
AR (1) AR116012A1 (fr)
BR (1) BR112021003218A2 (fr)
WO (1) WO2020039366A1 (fr)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3884778A1 (fr) * 2020-03-27 2021-09-29 UPL Corporation Limited Combinaison herbicide
WO2022055789A1 (fr) * 2020-09-10 2022-03-17 Monsanto Technology Llc Combinaisons herbicides comprenant du diflufénican et de la mésotrione
EP4295685A1 (fr) * 2022-06-22 2023-12-27 Adama Agan Ltd. Procédé d'application d'ingrédients actifs herbicides à différentes étapes
WO2024083924A1 (fr) * 2022-10-18 2024-04-25 Upl Mauritius Limited Combinaisons d'herbicides avec phytoprotecteur

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2009089165A2 (fr) * 2008-01-07 2009-07-16 Auburn University Combinaisons d'herbicides et de phytoprotecteurs
WO2013186652A1 (fr) * 2012-06-11 2013-12-19 United Phosphorus Limited Composition herbicide et procédé pour celle-ci
WO2016116531A1 (fr) * 2015-01-22 2016-07-28 BASF Agro B.V. Combinaison herbicide ternaire comprenant du saflufénacile
WO2016125188A1 (fr) * 2015-02-03 2016-08-11 Gsp Crop Science Pvt. Ltd. Composition herbicide synergique de pendiméthaline et de métribuzine
CN107810959A (zh) * 2017-10-20 2018-03-20 大千生态环境集团股份有限公司 用于园林灌木杂草综合治理的除草剂及除草方法
CN108041050A (zh) * 2017-12-15 2018-05-18 北京科发伟业农药技术中心 含唑啉草酯和苯嘧磺草胺的除草组合物

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103931625B (zh) * 2014-03-16 2016-09-14 广东中迅农科股份有限公司 一种含有嗪草酮和高效氟吡甲禾灵的除草组合物
CN104542645B (zh) * 2015-01-20 2016-01-20 江苏富鼎化学有限公司 一种含啶磺草胺、炔草酯和氯氟吡氧乙酸的除草组合物

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2009089165A2 (fr) * 2008-01-07 2009-07-16 Auburn University Combinaisons d'herbicides et de phytoprotecteurs
WO2013186652A1 (fr) * 2012-06-11 2013-12-19 United Phosphorus Limited Composition herbicide et procédé pour celle-ci
WO2016116531A1 (fr) * 2015-01-22 2016-07-28 BASF Agro B.V. Combinaison herbicide ternaire comprenant du saflufénacile
WO2016125188A1 (fr) * 2015-02-03 2016-08-11 Gsp Crop Science Pvt. Ltd. Composition herbicide synergique de pendiméthaline et de métribuzine
CN107810959A (zh) * 2017-10-20 2018-03-20 大千生态环境集团股份有限公司 用于园林灌木杂草综合治理的除草剂及除草方法
CN108041050A (zh) * 2017-12-15 2018-05-18 北京科发伟业农药技术中心 含唑啉草酯和苯嘧磺草胺的除草组合物

Non-Patent Citations (8)

* Cited by examiner, † Cited by third party
Title
ABBAS, T. ET AL.: "Role of allelopathic crop mulches and reduced doses of tank-mixed herbicides in managing herbicide-resistant Phalaris minor in wheat", CROP PROTECTION, vol. 110, 2018, pages 245 - 250, XP055687967, [retrieved on 20170623] *
HASSAN, G. ET AL.: "Effect of different herbicides on weed density and some agronomic traits of wheat", PAKISTAN JOURNAL OF WEED SCIENCE RESEARCH, vol. 11, no. 1-2, 2005, pages 17 - 22, XP055687951 *
HUSSAIN, Z. ET AL.: "Evaluation of different herbicides for weed control in onion", SARHAD JOURNAL OF AGRICULTURE, vol. 24, no. 3, 2008, pages 453 - 456, XP055687968 *
JONES, N. E. ET AL.: "Effects of selective herbicide treatment, row width and spring cultivation on weed and arthropod communities in winter wheat", ASPECTS OF APPLIED BIOLOGY, vol. 81, 2007, pages 39 - 46 *
KAUR, S. ET AL.: "Control of mixed weed flora in wheat with sequential application of pre- and post-emergence herbicides", INDIAN JOURNAL OF WEED SCIENCE, vol. 49, no. 1, 2017, pages 29 - 32, XP055687956 *
KHAN, I. A. ET AL.: "Efficacy of some pre and post-emergence herbicides on yield and yield components of canola", PAKISTAN JOURNAL OF BOTANY, vol. 40, no. 5, 2008, pages 1943 - 1947, XP055687969 *
RANA, S. S. ET AL.: "Evaluation of herbicide combinations for controlling complex weed flora in wheat", INDIAN JOURNAL OF WEED SCIENCE, vol. 49, no. 4, 2017, pages 335 - 340, XP055628228, DOI: 10.5958/0974-8164.2017.00088.0 *
SINGH, S. ET AL.: "Assess the effect of different combinations of herbicides on weed population and economic feasibility of treatments in late sown wheat crop", JOURNAL OF PHARMACOGNOSY AND PHYTOCHEMISTRY, vol. 6, no. 5, 2017, pages 648 - 651, XP055687971 *

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3884778A1 (fr) * 2020-03-27 2021-09-29 UPL Corporation Limited Combinaison herbicide
WO2021191618A1 (fr) * 2020-03-27 2021-09-30 UPL Corporation Limited Combinaison herbicide
CN115697061A (zh) * 2020-03-27 2023-02-03 Upl有限责任公司 除草组合
WO2022055789A1 (fr) * 2020-09-10 2022-03-17 Monsanto Technology Llc Combinaisons herbicides comprenant du diflufénican et de la mésotrione
EP4295685A1 (fr) * 2022-06-22 2023-12-27 Adama Agan Ltd. Procédé d'application d'ingrédients actifs herbicides à différentes étapes
WO2023248223A1 (fr) * 2022-06-22 2023-12-28 Adama Agan Ltd. Procédé d'application d'ingrédients actifs herbicides à différents stades
WO2024083924A1 (fr) * 2022-10-18 2024-04-25 Upl Mauritius Limited Combinaisons d'herbicides avec phytoprotecteur

Also Published As

Publication number Publication date
BR112021003218A2 (pt) 2021-05-18
CN116406669A (zh) 2023-07-11
AR116012A1 (es) 2021-03-25
CN113056198A (zh) 2021-06-29

Similar Documents

Publication Publication Date Title
US11419336B2 (en) Herbicidal combination
WO2020039366A1 (fr) Combinaison herbicide
JP6637422B2 (ja) ２，４−ｄコリンとグルホシネートの組合せからの相乗的除草剤雑草防除
WO2021191618A1 (fr) Combinaison herbicide
US20220272979A1 (en) Herbicidal combination
EP3745863A1 (fr) Combinaisons herbicides
AU2020206874A2 (en) Herbicidal combination
CA3119614C (fr) Combinaison herbicide
AU2021379287A1 (en) A method of controlling herbicide resistant weeds
EP4039092A1 (fr) Combinaison herbicide
OA20577A (en) Herbicidal combination.
WO2021064626A2 (fr) Composition herbicide
BR112019015548B1 (pt) Combinação herbicida

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 19852922

Country of ref document: EP

Kind code of ref document: A1

NENP Non-entry into the national phase

Ref country code: DE

REG Reference to national code

Ref country code: BR

Ref legal event code: B01A

Ref document number: 112021003218

Country of ref document: BR

ENP Entry into the national phase

Ref document number: 112021003218

Country of ref document: BR

Kind code of ref document: A2

Effective date: 20210222

122 Ep: pct application non-entry in european phase

Ref document number: 19852922

Country of ref document: EP

Kind code of ref document: A1