WO2020017421A1 - Solid cosmetic and production method therefor - Google Patents

Solid cosmetic and production method therefor Download PDF

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Publication number
WO2020017421A1
WO2020017421A1 PCT/JP2019/027462 JP2019027462W WO2020017421A1 WO 2020017421 A1 WO2020017421 A1 WO 2020017421A1 JP 2019027462 W JP2019027462 W JP 2019027462W WO 2020017421 A1 WO2020017421 A1 WO 2020017421A1
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WO
WIPO (PCT)
Prior art keywords
composition
outer layer
solid cosmetic
lipstick
layer
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Application number
PCT/JP2019/027462
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French (fr)
Japanese (ja)
Inventor
彩や香 湊
黒岩 利光
英彦 伏見
祐輔 中野
有喜子 蛭間
Original Assignee
株式会社 資生堂
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Application filed by 株式会社 資生堂 filed Critical 株式会社 資生堂
Publication of WO2020017421A1 publication Critical patent/WO2020017421A1/en

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    • AHUMAN NECESSITIES
    • A45HAND OR TRAVELLING ARTICLES
    • A45DHAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
    • A45D40/00Casings or accessories specially adapted for storing or handling solid or pasty toiletry or cosmetic substances, e.g. shaving soaps or lipsticks
    • A45D40/16Refill sticks; Moulding devices for producing sticks
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/02Cosmetics or similar toiletry preparations characterised by special physical form
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/31Hydrocarbons
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/02Preparations containing skin colorants, e.g. pigments
    • A61Q1/04Preparations containing skin colorants, e.g. pigments for lips
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/02Preparations containing skin colorants, e.g. pigments
    • A61Q1/04Preparations containing skin colorants, e.g. pigments for lips
    • A61Q1/06Lipsticks

Definitions

  • the present invention relates to a solid cosmetic and a method for producing the same, and more particularly, to a solid cosmetic such as a lipstick comprising a plurality of materials having different raw material compositions and a method for producing the same.
  • stick cosmetics such as lipstick have been known as solid cosmetics.
  • a material having a material composition different from that of the material forming the center body and the material forming the outer layer body, for example, a material having a different color tone is used, which includes a center body and an outer layer body covering the outside of the center body.
  • Two-layer lipsticks are known.
  • a conventional two-layer lipstick uses a split mold having a concave portion and a middle core having an outer diameter smaller than the inner diameter of the concave portion of the mold, and the central core is inserted at the center position of the concave portion of the mold. Filling the first material outside the core in the recess, extracting the core after the first material has solidified, filling the cavity after the core has been removed with the second material and solidifying it; It was manufactured by.
  • the central body is exposed at the tip of the lipstick, and when the lipstick is viewed from the tip side, the central body and the outer layer body can be visually recognized as a double circle.
  • Patent Literature 1 and Patent Literature 2 disclose a so-called marble having a pattern in which two materials having different compositions are mixed in a concave portion of a mold at the same time while rotating the mold, and the two materials are mixed unevenly.
  • a method for producing a lipstick in the shape of a lipstick is disclosed.
  • the conventional two-layer lipstick is manufactured by using the mold having the core as described above, and assembling the split mold, inserting the core into the recess, and filling the first material. Then, after the first material has solidified, the core is extracted, and then the hollow material after the core has been removed is filled with the second material and solidified.
  • the work is complicated, the number of manufacturing steps is large, and there has been a demand to simplify the manufacturing.
  • the central body is exposed at the tip of the lipstick, and when the lipstick is viewed from the tip side, the central body and the outer layer body can be visually recognized as a double circle.
  • the object of the present invention is to make it possible for a user to know that the cosmetic is composed of a central body and an outer layer body while the central body is not exposed and used, and to provide the user with unexpected feeling and fun. It is to provide a solid cosmetic that can be given.
  • Another object of the present invention is to provide a method for easily producing a solid cosmetic comprising a central body and an outer layer in view of the above circumstances.
  • the solid cosmetic according to the present invention is characterized by comprising a central body composed of the first composition and an outer layer composed of the second composition covering the entire surface of the central body.
  • covering the entire surface means that 95% or more of the entire outer surface of the solid cosmetic that is exposed when sold as a product is only the second composition.
  • the remaining surface portion may be a first composition or a mixture of a first composition and a second composition. More preferably, 98% or more of the entire outer surface is the second composition only, and more preferably, 100% is the second composition only.
  • the volume ratio between the central body and the outer layer body is 5: 1 to 1: 5.
  • the volume ratio is the volume ratio between the entire central body and the entire outer layer body in a state of being sold as a product.
  • the outer layer body preferably has a hardness of 5 to 100.
  • the hardness is the penetration hardness when the adapter of the rheometer enters the sample, and the peak of the stress when the adapter of 1 mm ⁇ enters the sample from above at a measurement temperature of 25 ° C. at a speed of 30 mm / min. Value (unit is gf).
  • the specific gravity difference between the central body and the outer layer body is preferably 0.05 or less.
  • the specific gravity difference is a specific gravity difference after the first composition and the second composition are solidified, that is, a difference between the specific gravity of the central body and the specific gravity of the outer layer body. Either the central body or the outer layer body may have a higher specific gravity.
  • the outer layer body preferably has an average thickness of 0.1 mm to 3.0 mm. More preferably, the average of the thickness of the outer layer body is 0.5 mm to 1.5 mm.
  • the thickness of the outer layer means the average value of the thickness of the outer layer over the entire outer surface exposed in a state where the solid cosmetic is sold as a product.
  • the shape of the solid cosmetic can be, for example, a stick such as lipstick.
  • a mold having a bottomed concave portion having an upper end opening having a central axis extending in a vertical direction is filled with the second composition, and the mold is rotated around the central axis. Then, the second composition is layered along the inner surface of the bottomed recess to form an outer layer portion having a cavity inside, and then the cavity is filled with the first composition to form a central portion. And solidifying the outer layer portion and the central portion.
  • the “center” and “outer layer” mean those in a molten state before solidification. Further, the first composition may be filled while rotating the mold, or may be filled while the rotation is stopped.
  • the rotation speed of the mold is preferably 500 to 1500 rpm. Further, the rotation speed of the mold is more preferably 700 to 900 rpm.
  • the solid cosmetic according to the present invention covers the entire surface of the central body with the outer layer body, the user can visually recognize only the outer layer body, and the cosmetic is in a state in which it is not known that the central body exists inside.
  • the central body appears, so that it is possible to give the user an unexpected feeling and interest, and to differentiate the product and improve the product value. be able to.
  • the mold is filled with the second composition, the mold is rotated, and the second composition is positioned in a layered manner along the inner surface of the concave portion of the mold by centrifugal force.
  • the first composition is filled and solidified in the cavity inside the second composition layered in this state, so that the manufacturing process is as follows. Only the rotation of the first composition and the filling of the first composition are required, and as in the conventional manufacturing method using a split mold, the work of mold combination, insertion of the core, and removal of the core are unnecessary, and the number of steps is small. The manufacturing process is simplified, and the device can be manufactured at low cost.
  • a perspective view showing a lipstick with a container provided with one embodiment of a solid cosmetic concerning the present invention Partial sectional front view showing a lipstick portion of the lipstick with a container shown in FIG. 1 in a sectional view.
  • Sectional drawing which shows the shaping
  • the figure explaining the 1st manufacturing process in the manufacturing method using the molding die shown in FIG. The figure explaining the 2nd manufacturing process in the manufacturing method using the shaping
  • FIG. 2 is a perspective view showing a two-layer lipstick 1 with a container provided with a two-layer lipstick 2 as one embodiment of the solid cosmetic
  • FIG. 2 is a front view of the two-layer lipstick 1 with a container shown in FIG.
  • FIG. 3 is a partial cross-sectional front view showing a two-layer lipstick 2 in a vertical cross section.
  • the two-layer lipstick 2 includes a central body 2a and an outer layer body 2b covering the entire surface of the central body 2a.
  • the central body 2a is made of a first composition
  • the outer layer body 2b is made of a second composition different in composition from the first composition.
  • the two-layer lipstick 2 is accommodated in a dispensing container 3, and the two-layer lipstick 2 and the dispensing container 3 constitute a two-layer lipstick 1 with a container.
  • FIG. 3 is a cross-sectional view showing a state in which an ogive 4 which is an example of a molding die used for manufacturing the two-layer lipstick 2 and a feeding container 3 are combined.
  • the feeding container 3 includes a cylindrical outer cylinder 10, a cylindrical inner cylinder 11, and a cylindrical middle plate 12.
  • the outer cylinder 10 has an open upper end, a bottom plate 10a at the lower end, a spiral groove 10b on the inner surface, and the bottom plate 10a has a through hole 10c at its center.
  • the inner cylinder body 11 is inserted into the outer cylinder body 10 so as to be rotatable relative to the outer cylinder body 10 so as not to come out of the outer cylinder body 10, and the upper and lower ends are open, and It has a slit 11a that is open at the lower end and extends in the vertical direction in the figure).
  • the inner plate body 12 is open at the upper and lower ends, and has a rib 12a on its inner surface for preventing the two-layer lipstick 2 from slipping out and rotating.
  • the inner plate body 12 has a projection 12b on the outer peripheral surface near the lower end.
  • the diameter of the projection 12b is slightly smaller than the width of the slit 11a of the inner cylinder, and the spiral groove 10b of the outer cylinder is formed. Is slightly smaller than the width of the groove, and is inserted into the spiral groove 10b through the slit 11a.
  • FIG. 3 schematically shows the structure of the feeding container 3 so that the movement of the feeding container 3 can be understood.
  • the ogive 4 is a molding die of resin or silicon, has an opening at the lower end in FIG. 3, has a cylindrical shape in which the upper end is gradually narrowed and closed, and the tip is gradually narrowed inside. It has a substantially bullet-shaped cavity 4a.
  • the production of the two-layer lipstick 2 is performed by a stage A having an A tank for storing the second composition and a stage B having a B tank for storing the first composition. 4 to 7, a part of the rib 12a of the inner plate is omitted.
  • the combined body 5 of the ogive 4 and the feeding container 3 shown in FIG. 3 is held by a holder (not shown) with the ogive 4 down, and the combined body 5 is transferred to the stage A together with the holder, as shown in FIG. As described below.
  • a predetermined amount of the second composition heated and melted and stored in the A tank 6 is fed from the A tank 6 into the ogive 4 through a through hole 10c formed in the bottom plate of the container.
  • the filling of the second composition into the ogive 4 can be performed at an appropriate flow rate, for example, at a flow rate of 3.7 ml / 1.2 seconds.
  • the assembly 5 is transferred to the stage B together with the holder, and is stopped under the B tank 7 as shown in FIG. In this state, the holder is rotated to rotate the combined body 5 at a predetermined rotation speed about its central axis (the central axis extending in the vertical direction of the combined body 5).
  • the second composition in the ogive 4 is positioned in a layer along the inner surface of the ogive 4 by the action of centrifugal force due to the rotation, and a cavity is formed inside the second composition. Let it form. That is, the outer layer portion 2B made of the second composition in a molten state having a cavity inside is formed in a layered shape along the inner surface of the ogive 4. At this time, the upper end of the second composition has risen to the position of the rib 12a of the inner plate.
  • a predetermined amount of the first composition heated and melted from the B tank 7 is injected and filled into the cavity inside the second composition, and the inside of the outer layer portion 2B is filled.
  • a central portion 2A made of the first composition in a molten state is formed to obtain a state shown in FIG.
  • the filling of the first composition can be started after the assembly 5 filled with the second composition in the ogive 4 is rotated, for example for 1-2 seconds.
  • the filling of the first composition can be performed at an appropriate flow rate, for example, at a flow rate of 2.2 ml / 1.2 seconds.
  • the volume ratio between the center body 2a and the outer layer body 2b is preferably 5: 1 to 1: 5.
  • the volume ratio is the volume ratio of the entire two-layer lipstick 2 including the part contained in the inner plate 12 in a solidified state.
  • the hardness of the outer layer body 2b is preferably 5 to 100.
  • the definition of hardness is as described above. If the hardness is 5 or less, it is difficult to cleanly remove the outer layer 2b from the ogive 4 without damaging the outer layer 2b because of its softness, and it becomes difficult to form the outer layer 2 properly. On the other hand, when the hardness is 100 or more, the center body 2a does not easily come out even when applied because it is hard, so that the excitement of the center body 2a is less likely to be felt.
  • the specific gravity difference between the central body 2a and the outer layer body 2b is preferably 0.05 or less, and the specific gravity difference may be zero.
  • the definition of the specific gravity difference is as described above.
  • the specific gravity difference is larger than 0.05, the outer layer body 2b is likely to be formed unevenly.
  • the central body 2a and the outer layer body 2b may have a higher specific gravity, but when the outer layer body 2b has a higher specific gravity, the outer layer body 2a tends to accumulate on the tip side of the two-layer lipstick 2. It is in.
  • the average thickness of the outer layer body 2b is preferably 0.1 mm to 3.0 mm, more preferably 0.5 mm to 1.5 mm.
  • the definition of the average thickness is as described above.
  • the thickness of the outer layer body is limited to about 1.5 mm due to the extraction of the core, and it is difficult to reduce the thickness further.
  • the step of extracting the core is unnecessary, and as a result, the outer layer 2b having an average thickness of 1.5 mm or less can be manufactured.
  • the first composition for the center body 2a is injected and filled at the stage B while the assembly 5 is rotated while being injected and filled.
  • the rotation can be stopped and the first composition can be injected and filled.
  • the rotation speed of the assembly 5 is preferably 500 to 1500 rpm, and 700 rpm. 900900 rpm is more preferable. If the rotation speed is 500 rpm or less, the second composition tends to accumulate on the tip side of the ogive 4 and the outer layer body 2a tends to accumulate on the tip side of the molded two-layer lipstick 2. On the other hand, when the rotation speed is 1500 rpm or more, the first composition moves to the inner surface side of the ogive 4 and overflows from the inner plate body 12, and the central body 2a is exposed on the surface of the formed two-layer lipstick 2. Tend to do it.
  • the two-layer lipstick 2 is manufactured using the combination 5 of the feeding container 3 and the ogive 4 in the above-described embodiment, but the feeding container 3 is not limited to the one having the illustrated structure.
  • a container having any structure may be used.
  • the mold may be positioned in a layer along the inner surface of the bottomed concave portion, and then filled with the second composition.
  • the mold is not limited to the ogive, and various molds can be used.
  • the solid cosmetic of the present invention is not limited to the above-described two-layer lipstick, and may be a lipstick composed of three or more layers of different compositions.
  • the outermost layer becomes the outer layer body
  • the part located inside the outermost layer becomes the central body.
  • the composition constituting the outermost layer is injected and filled into a molding die, and different compositions are sequentially injected and filled while rotating the molding die to form each composition into a layered form, and finally the composition is positioned at the innermost position. It can be produced by injecting and filling the composition of the layer to be cooled and solidifying by cooling.
  • the lipstick may be composed of a plurality of compositions having the same color but different components.
  • the present invention is not limited to lipstick, and may be a stick-shaped cosmetic such as gloss or lip balm, or various cosmetics other than a stick.
  • the shape is not limited to the shape shown in the embodiment, but may be a shape having an inclined surface at a tip portion, for example.
  • first composition and the second composition are not limited to the compositions of the examples described below, and various compositions can be used.
  • the first composition and the second composition Is not limited to the filling conditions of the embodiments described below, and molding can be performed under various filling conditions.
  • the “rotation speed” refers to the temperature of the first composition and the second composition when each of the compositions is filled in the ogive 4, and the “rotation speed” defines the outer layer 2B made of the second composition and the cavity of the outer layer 2B.
  • the rotation speed of the combination 5 at the time of forming the center portion 2A by filling the first composition into the “inner / outer layer distribution state” indicates that the first composition and the second composition are cooled and solidified.
  • the distribution state of the central body 2a and the outer layer body 2b, and "film thickness” means an average of the above-mentioned thickness of the outer layer body 2b.
  • “specific gravity” and “specific gravity difference” in Tables 1 and 2 are specific gravity and specific gravity difference in a state where the first composition and the second composition are solidified (the center body 2a and the outer layer body 2b). .
  • the second composition which is the material of the outer layer body, is heated and melted, and injected and filled into the combination 5 at the above-mentioned stage A, and The second composition is positioned in a layer along the inner surface of the ogive 4 while rotating at B, and then the first composition melted by heating is injected and filled into the cavity inside the second composition positioned in the layer. Then, forced cooling is started and rotation is stopped, and both compositions are solidified to form a two-layer lipstick with a container having a center body 2a made of the first composition and an outer layer body 2b made of the second composition. 1 was produced.
  • Table 1 is composed of Table 1-1 and Table 1-2, and the composition 1 and the composition 2 described in Table 1-2 are respectively applied to the second composition for the outer layer body 2b and the composition for the center body 2a.
  • the thickness of the outer layer body 2b and the distribution of the central body 2a and the outer layer body 2b when used as the first composition and molded under the 17 filling conditions described in Table 1-1 are shown. ing. "-" In the column of film thickness in Table 1-1 indicates that the film thickness was not measured.
  • Table 1-2 also shows the hardness and specific gravity difference between the outer layer body 2b and the center body 2a.
  • the ratio of the first composition to the second composition (the volume ratio between the center body and the outer layer body) is 5: 1 to 1: 5 even at a rotational speed of 800 rpm.
  • the ratio is 9: 1 or 1: 9 out of the range, there is a problem that the central body is not exposed or does not have a two-layer state.
  • the distribution of the central body 2a and the outer layer body 2b in the solidified two-layer lipstick 2 is good, as indicated by a circle in the column of inner / outer layer distribution state.
  • a lipstick 2 having a two-layer structure having a small outer layer 2b was formed.
  • Table 2 consists of Tables 2-1 and 2-2.
  • Table 2-1 compositions 1 and 2; compositions 3 and 4; compositions 5 and 6; Composition 8 and five sets of compositions 9 and 10 (compositions 1, 3, 5, 7, and 9 being the second composition for the outer layer, compositions 2, 4, 6, 8, 10 shows the distribution state of the inner and outer layers when each of the sets is formed under the same filling conditions described in Table 2-2.
  • Table 2-1 shows the hardness after solidification of each composition, the specific gravity after solidification, and the difference in specific gravity after solidification of each set of compositions.
  • the inner and outer layer distribution state is ⁇ , that is, the solidified two-layer lipstick 2
  • the distribution of the central body 2a and the outer layer body 2b is good, and the 2 A lipstick 2 having a layer structure was formed.
  • the distribution state of the inner and outer layers is ⁇ , that is, the distribution between the central body 2a and the outer layer body 2b in the solidified two-layer lipstick 2 has a slightly large specific gravity difference of 0.08. Therefore, the uniformity of the outer layer body 2b was low, and the separation between the central body 2a and the outer layer body 2b was somewhat unclear.
  • the set of compositions 1 and 2, the set of compositions 3 and 4, the set of compositions 5 and 6, and the set of compositions 9 and 10 all have a specific gravity difference of 0.05.
  • the outer layer body 2b has a higher specific gravity than the center body 2a
  • the last set has the center body 2a having a higher specific gravity than the outer layer body 2b. Regardless of the magnitude relationship of the specific gravity of the body 2b, when the specific gravity difference between them is 0.05 or less, the inner and outer layer distribution state is good.
  • the inner / outer layer distribution state is affected by the specific gravity difference between the center body 2a and the outer layer body 2b, and is not particularly affected by the magnitude of the specific gravity itself of the center body 2a and the outer layer body 2b.
  • the inventor has confirmed that the specific gravity difference is 0.05 or less and the inner and outer layer distribution is good, using the center body 2a and the outer layer body 2b having a specific gravity in the range of 0.9-1.1. I have.
  • Table 3 shows further examples of combinations of the first composition for the central body and the second composition for the outer layer body.
  • two different compositions for example, a two-layer lipstick composed of two compositions having different color tones or two different compositions having different feelings of use are used as outer layers.
  • a two-layer lipstick composed of two compositions having different color tones or two different compositions having different feelings of use are used as outer layers.

Abstract

[Problem] To obtain a solid cosmetic with an added element of surprise for the user in that the cosmetic has a center body which is not exposed and the cosmetic is only revealed to be one which comprises a center body and an outer layer body upon use, and to produce such a solid cosmetic easily. [Solution] A solid cosmetic is composed of a center body (2a) comprising a first composition, and an outer layer body (2b) comprising a second composition and covering the entire surface of the center body (2a). The solid cosmetic composed of the center body (2a) and the outer layer body (2b) covering the entire surface of the center body (2a) is produced by filling the second composition into a forming mold (4) having a bottomed recess (4a) with a top end opening and a central axis extending in a vertical direction, rotating the forming mold (4) about the central axis to position the second composition in the form of a layer along the inner surface of the bottomed recess (4a) and thereby form an outer layer portion (2B) having a hollow cavity on the inner side, and then filling the first composition into the hollow cavity to form a center portion (2A), and solidifying the center portion (2A) and the outer layer portion (2B).

Description

固形化粧料およびその製造方法Solid cosmetic and method for producing the same
 本発明は、固形化粧料およびその製造方法に関し、より詳細には、異なる原料組成の複数の材料からなる口紅等の固形化粧料およびその製造方法に関する。 The present invention relates to a solid cosmetic and a method for producing the same, and more particularly, to a solid cosmetic such as a lipstick comprising a plurality of materials having different raw material compositions and a method for producing the same.
 従来より、固形化粧料として例えば口紅等の棒状化粧料が知られている。また、口紅として、中心体と該中心体の外側を覆う外層体とからなり、中心体を構成する材料と外層体を構成する材料とは異なる原料組成の材料、例えば色調が異なる材料を用いた2層口紅が知られている。 棒 Conventionally, stick cosmetics such as lipstick have been known as solid cosmetics. Further, as the lipstick, a material having a material composition different from that of the material forming the center body and the material forming the outer layer body, for example, a material having a different color tone is used, which includes a center body and an outer layer body covering the outside of the center body. Two-layer lipsticks are known.
 従来の2層口紅は、凹部を有する2つ割り金型と該金型の凹部の内径よりも小さい外径の中芯とを用い、金型の凹部の中心位置に中芯を挿入した状態で凹部内の中芯の外側に第1の材料を充填し、第1の材料が固化した後中芯を抜き出し、中芯が抜けた後の空洞部分に第2の材料を充填して固化させることにより製造していた。 A conventional two-layer lipstick uses a split mold having a concave portion and a middle core having an outer diameter smaller than the inner diameter of the concave portion of the mold, and the central core is inserted at the center position of the concave portion of the mold. Filling the first material outside the core in the recess, extracting the core after the first material has solidified, filling the cavity after the core has been removed with the second material and solidifying it; It was manufactured by.
 従来の2層口紅は、口紅の先端に中心体が露出しており、口紅を先端側から見ると中心体と外層体とが二重円状に視認できる形態となっている。 In the conventional two-layer lipstick, the central body is exposed at the tip of the lipstick, and when the lipstick is viewed from the tip side, the central body and the outer layer body can be visually recognized as a double circle.
 なお、口紅を製造する方法としては、成形型に材料を充填して固化させる際、成形型を回転させながら材料を充填して固化させる方法が知られている。例えば特許文献1および特許文献2には、成形型を回転させながら2つの異なる組成の材料を同時に成形型の凹部に充填して、2つの材料が不均一に混在した模様を表面に有する所謂マーブル状の口紅を製造する方法が開示されている。 As a method of manufacturing a lipstick, there is known a method of filling and solidifying a material while rotating the mold when filling and solidifying the material in the mold. For example, Patent Literature 1 and Patent Literature 2 disclose a so-called marble having a pattern in which two materials having different compositions are mixed in a concave portion of a mold at the same time while rotating the mold, and the two materials are mixed unevenly. A method for producing a lipstick in the shape of a lipstick is disclosed.
特開昭59-225108号公報JP-A-59-225108 特開2000-229817号公報JP 2000-229817 A
 しかしながら、従来の2層口紅は、上述の様に中芯を備えた金型を用いて製造されており、2つ割り金型を組み立て、凹部に中芯を挿入して第1の材料を充填し、第1の材料が固化した後中芯を抜き出し、その後中芯が抜けた後の空洞部分に第2の材料を充填して固化させるという、多くの行程を経て製造するものであり、製造作業が煩雑であり、製造工程数が多く、製造をより簡素化したいという要望があった。 However, the conventional two-layer lipstick is manufactured by using the mold having the core as described above, and assembling the split mold, inserting the core into the recess, and filling the first material. Then, after the first material has solidified, the core is extracted, and then the hollow material after the core has been removed is filled with the second material and solidified. The work is complicated, the number of manufacturing steps is large, and there has been a demand to simplify the manufacturing.
 また、従来の2層口紅は、中心体が口紅の先端に露出しており、口紅を先端側から見たときに中心体と外層体とが二重円状に視認できる形態であり、ユーザは使用開始前から中心体と外層体とからなる2層口紅であることを知り得るものであった。 Further, in the conventional two-layer lipstick, the central body is exposed at the tip of the lipstick, and when the lipstick is viewed from the tip side, the central body and the outer layer body can be visually recognized as a double circle. Before the start of use, it was possible to know that it was a two-layer lipstick consisting of a central body and an outer layer body.
 本発明の目的は、上記事情に鑑み、中心体が露出しておらず使用しているうちに中心体と外層体とからなる化粧料であることを知ることができ意外感と面白味をユーザに与えることができる固形化粧料を提供することにある。 In view of the above circumstances, the object of the present invention is to make it possible for a user to know that the cosmetic is composed of a central body and an outer layer body while the central body is not exposed and used, and to provide the user with unexpected feeling and fun. It is to provide a solid cosmetic that can be given.
 本発明の他の目的は、上記事情に鑑み、中心体と外層体とからなる固形化粧料を簡単に製造することができる製造方法を提供することにある。 Another object of the present invention is to provide a method for easily producing a solid cosmetic comprising a central body and an outer layer in view of the above circumstances.
 本発明にかかる固形化粧料は、第1の組成物からなる中心体と、該中心体の全表面を覆う第2の組成物からなる外層体とを備えたことを特徴とする。 固 形 The solid cosmetic according to the present invention is characterized by comprising a central body composed of the first composition and an outer layer composed of the second composition covering the entire surface of the central body.
 ここで「全表面を覆う」とは、商品として販売するときの状態で露出している固形化粧料の外表面全体の95%以上が第2の組成物のみであることを意味する。残りの表面部分は、第1の組成物であっても第1の組成物と第2の組成物との混合物であっても良い。上記外表面全体の98%以上が第2の組成物のみであることがより好ましく、100%第2の組成物のみであることがさらに好ましい。 Here, "covering the entire surface" means that 95% or more of the entire outer surface of the solid cosmetic that is exposed when sold as a product is only the second composition. The remaining surface portion may be a first composition or a mixture of a first composition and a second composition. More preferably, 98% or more of the entire outer surface is the second composition only, and more preferably, 100% is the second composition only.
 前記中心体と前記外層体との体積比が、5:1~1:5であることが望ましい。体積比は、商品として販売される状態での中心体全体と外層体全体との体積比である。 体積 It is desirable that the volume ratio between the central body and the outer layer body is 5: 1 to 1: 5. The volume ratio is the volume ratio between the entire central body and the entire outer layer body in a state of being sold as a product.
 前記外層体の硬度が5~100であることが好ましい。硬度は、試料にレオメーターのアダプターを進入させた時の進入硬度であり、測定温度25℃で、1mmφのアダプターを30mm/minのスピードで上方から試料中に10mm進入させたときの応力のピーク値(単位はgf)である。 硬度 The outer layer body preferably has a hardness of 5 to 100. The hardness is the penetration hardness when the adapter of the rheometer enters the sample, and the peak of the stress when the adapter of 1 mmφ enters the sample from above at a measurement temperature of 25 ° C. at a speed of 30 mm / min. Value (unit is gf).
 前記中心体と前記外層体との比重差が、0.05以下であることが好ましい。比重差は、第1の組成物および第2の組成物が固化した後の比重差、即ち中心体の比重と外層体の比重との差である。比重は中心体と外層体とでどちらが大きくても良い。 比 The specific gravity difference between the central body and the outer layer body is preferably 0.05 or less. The specific gravity difference is a specific gravity difference after the first composition and the second composition are solidified, that is, a difference between the specific gravity of the central body and the specific gravity of the outer layer body. Either the central body or the outer layer body may have a higher specific gravity.
 前記外層体の厚さの平均が、0.1mm~3.0mmであることが好ましい。また、前記外層体の厚さの平均が、0.5mm~1.5mmであることがより好ましい。ここでいう外層体の厚さは、固形化粧料が商品として販売される状態において露出している外表面全体における外層体の厚さの平均値を意味する。 平均 The outer layer body preferably has an average thickness of 0.1 mm to 3.0 mm. More preferably, the average of the thickness of the outer layer body is 0.5 mm to 1.5 mm. Here, the thickness of the outer layer means the average value of the thickness of the outer layer over the entire outer surface exposed in a state where the solid cosmetic is sold as a product.
 前記固形化粧料の形状は、例えば口紅等のスティック状のものとすることができる。 The shape of the solid cosmetic can be, for example, a stick such as lipstick.
 本発明に係る固形化粧料の製造方法は、上下方向に延びる中心軸を有する上端開口の有底凹部を有する成形型に第2の組成物を充填し、前記成形型を前記中心軸周りに回転させて前記第2の組成物を前記有底凹部の内面に沿って層状に位置させて内側に空洞を有する外層部を形成し、次いで前記空洞に第1の組成物を充填して中心部を形成し、前記外層部と前記中心部を固化させることを特徴とする。 In the method for producing a solid cosmetic according to the present invention, a mold having a bottomed concave portion having an upper end opening having a central axis extending in a vertical direction is filled with the second composition, and the mold is rotated around the central axis. Then, the second composition is layered along the inner surface of the bottomed recess to form an outer layer portion having a cavity inside, and then the cavity is filled with the first composition to form a central portion. And solidifying the outer layer portion and the central portion.
 前記「中心部」および「外層部」は固化する前の溶融状態のものを意味する。また、前記第1の組成物は、前記成形型を回転しながら充填しても良いし回転を停止した状態で充填しても良い。 The “center” and “outer layer” mean those in a molten state before solidification. Further, the first composition may be filled while rotating the mold, or may be filled while the rotation is stopped.
 前記成形型の回転の回転速度は、500~1500rpmであることが好ましい。また、前記成形型の回転の回転速度は、700~900rpmであることがより好ましい。 回 転 The rotation speed of the mold is preferably 500 to 1500 rpm. Further, the rotation speed of the mold is more preferably 700 to 900 rpm.
 本発明に係る固形化粧料は、中心体の全表面を外層体が覆っているので、ユーザは外層体のみを視認でき、内側に中心体が存在していることが分からない状態で化粧料の使用を開始し、使用後しばらくして先端部分の外層体が消費されると中心体が出現するので、ユーザに意外感や面白味を与えることができ、商品の差別化および商品価値の向上を図ることができる。 Since the solid cosmetic according to the present invention covers the entire surface of the central body with the outer layer body, the user can visually recognize only the outer layer body, and the cosmetic is in a state in which it is not known that the central body exists inside. When the use is started, and the outer layer body at the tip portion is consumed some time after use, the central body appears, so that it is possible to give the user an unexpected feeling and interest, and to differentiate the product and improve the product value. be able to.
 本発明に係る固形化粧料の製造方法は、成形型に第2の組成物を充填し、成形型を回転させて第2の組成物を遠心力により成形型の凹部内面に沿って層状に位置させ、この状態で層状になった第2の組成物の内側の空洞に第1の組成物を充填して固化させることにより製造するので、製造工程としては第2の組成物の充填、成形型の回転および第1の組成物の充填のみでよく、従来の2つ割り型を使用した製造方法のように、型組み合わせ、中芯挿入、中芯抜き出しの作業が不要であり、工程数が少なく製造工程の簡素化が図られ、安価に製造することができる。 In the method for producing a solid cosmetic according to the present invention, the mold is filled with the second composition, the mold is rotated, and the second composition is positioned in a layered manner along the inner surface of the concave portion of the mold by centrifugal force. In this state, the first composition is filled and solidified in the cavity inside the second composition layered in this state, so that the manufacturing process is as follows. Only the rotation of the first composition and the filling of the first composition are required, and as in the conventional manufacturing method using a split mold, the work of mold combination, insertion of the core, and removal of the core are unnecessary, and the number of steps is small. The manufacturing process is simplified, and the device can be manufactured at low cost.
本発明に係る固形化粧料の一実施の形態を備えた容器付口紅を示す斜視図A perspective view showing a lipstick with a container provided with one embodiment of a solid cosmetic concerning the present invention. 図1に示す容器付口紅の口紅部分を断面で示す部分断面正面図Partial sectional front view showing a lipstick portion of the lipstick with a container shown in FIG. 1 in a sectional view. 本発明に係る固形化粧料の製造方法の一実施の形態に使用する成形型を示す断面図Sectional drawing which shows the shaping | molding die used for one Embodiment of the manufacturing method of the solid cosmetics which concerns on this invention. 図3に示す成形型を用いた製造方法における第1製造工程を説明する図The figure explaining the 1st manufacturing process in the manufacturing method using the molding die shown in FIG. 図3に示す成形型を用いた製造方法における第2製造工程を説明する図The figure explaining the 2nd manufacturing process in the manufacturing method using the shaping | molding die shown in FIG. 図3に示す成形型を用いた製造方法における第3製造工程を説明する図The figure explaining the 3rd manufacturing process in the manufacturing method using the shaping | molding die shown in FIG. 図3に示す成形型を用いた製造方法における第4製造工程を説明する図The figure explaining the 4th manufacturing process in the manufacturing method using the shaping | molding die shown in FIG.
 以下、図面を参照して本発明に係る固形化粧料およびその製造方法の実施の形態について説明する。 Hereinafter, embodiments of a solid cosmetic and a method for producing the same according to the present invention will be described with reference to the drawings.
 以下に説明する実施の形態は、本発明に係る固形化粧料およびその製造方法をスティック状(棒状)の2層口紅体およびその製造方法に適用した例であり、図1は、本発明に係る固形化粧料の一実施の形態である2層口紅体2を備えた容器付2層口紅1を示す斜視図、図2は、図1に示す容器付2層口紅1の正面図であって、2層口紅体2を縦断面にして示す部分断面正面図である。 The embodiment described below is an example in which the solid cosmetic according to the present invention and the method for producing the same are applied to a stick-like (stick-shaped) two-layer lipstick and a method for producing the same. FIG. FIG. 2 is a perspective view showing a two-layer lipstick 1 with a container provided with a two-layer lipstick 2 as one embodiment of the solid cosmetic, and FIG. 2 is a front view of the two-layer lipstick 1 with a container shown in FIG. FIG. 3 is a partial cross-sectional front view showing a two-layer lipstick 2 in a vertical cross section.
 図1,2に示すように、2層口紅体2は、中心体2aと、中心体2aの全表面を覆う外層体2bとで構成されている。中心体2aは第1の組成物からなり、外層体2bは第1の組成物とは組成が異なる第2の組成物からなる。2層口紅体2は繰り出し容器3に収容されており、2層口紅体2と繰り出し容器3とで容器付2層口紅1が構成されている。 1,2As shown in FIGS. 1 and 2, the two-layer lipstick 2 includes a central body 2a and an outer layer body 2b covering the entire surface of the central body 2a. The central body 2a is made of a first composition, and the outer layer body 2b is made of a second composition different in composition from the first composition. The two-layer lipstick 2 is accommodated in a dispensing container 3, and the two-layer lipstick 2 and the dispensing container 3 constitute a two-layer lipstick 1 with a container.
 図3は、2層口紅体2を製造する際に使用する成形型の一例であるオジーブ4と繰り出し容器3とを組み合わせた状態で断面にして示す図である。図示のように、繰り出し容器3は、円筒状の外筒体10と、円筒状の内筒体11と、円筒状の中皿体12とで構成されている。外筒体10は、上端が開口し、下端に底板10aを有し、内面に螺旋溝10bを有し、底板10aはその中央に貫通孔10cを有している。内筒体11は、外筒体10内に、外筒体10から抜け出さないように、外筒体10に対して相対回転可能に挿入されており、かつ、上下端が開口し、軸方向(図中の上下方向)に延びる下端解放のスリット11aを備えている。中皿体12は、上下端が開口しており、内面に2層口紅体2の抜け出しおよび回転を防止するリブ12aを有している。また、中皿体12は、下端近傍の外周面に突起12bを有しており、この突起12bは、その径が内筒体のスリット11aの幅より僅かに小さく、外筒体の螺旋溝10bの溝幅よりも僅かに小さく形成されており、スリット11aを貫通して螺旋溝10b内に嵌入されている。 FIG. 3 is a cross-sectional view showing a state in which an ogive 4 which is an example of a molding die used for manufacturing the two-layer lipstick 2 and a feeding container 3 are combined. As shown in the drawing, the feeding container 3 includes a cylindrical outer cylinder 10, a cylindrical inner cylinder 11, and a cylindrical middle plate 12. The outer cylinder 10 has an open upper end, a bottom plate 10a at the lower end, a spiral groove 10b on the inner surface, and the bottom plate 10a has a through hole 10c at its center. The inner cylinder body 11 is inserted into the outer cylinder body 10 so as to be rotatable relative to the outer cylinder body 10 so as not to come out of the outer cylinder body 10, and the upper and lower ends are open, and It has a slit 11a that is open at the lower end and extends in the vertical direction in the figure). The inner plate body 12 is open at the upper and lower ends, and has a rib 12a on its inner surface for preventing the two-layer lipstick 2 from slipping out and rotating. The inner plate body 12 has a projection 12b on the outer peripheral surface near the lower end. The diameter of the projection 12b is slightly smaller than the width of the slit 11a of the inner cylinder, and the spiral groove 10b of the outer cylinder is formed. Is slightly smaller than the width of the groove, and is inserted into the spiral groove 10b through the slit 11a.
 図示の繰り出し容器3においては、中皿体12は、突起12bが内筒体のスリット11aを貫通していることからスリット11aに沿って軸方向にのみ上下動可能であり、内筒体11に対して外筒体10を相対回転させることにより、螺旋溝10bにガイドされて突起12bが、ひいては中皿体12が内筒体11の中で上下方向に移動する。なお、図3は、繰り出し容器3の動きが理解できる程度に該容器3の構造を概略的に示したものである。 In the illustrated feeding container 3, the inner plate body 12 can move up and down only in the axial direction along the slit 11 a because the projection 12 b penetrates the slit 11 a of the inner cylinder body. On the other hand, when the outer cylinder 10 is relatively rotated, the projection 12b is guided by the spiral groove 10b, and thus the inner plate body 12 moves vertically in the inner cylinder 11. FIG. 3 schematically shows the structure of the feeding container 3 so that the movement of the feeding container 3 can be understood.
 オジーブ4は、樹脂またはシリコンの成形型であり、図3中において下端に開口を有し、上端が徐々に細くなって閉じられた円筒状をなしており、内部に先端が徐々に細くなった略砲弾状の空洞部4aを有している。2層口紅体2を製造するに際しては、図3に示すように、オジーブ4の下端を繰り出し容器3の上端に当接させて両者を組み合わせ、この組合体5を図示しない製造ライン上の保持具に保持させて製造が行われる。 The ogive 4 is a molding die of resin or silicon, has an opening at the lower end in FIG. 3, has a cylindrical shape in which the upper end is gradually narrowed and closed, and the tip is gradually narrowed inside. It has a substantially bullet-shaped cavity 4a. When the two-layer lipstick 2 is manufactured, as shown in FIG. 3, the lower end of the ogive 4 is fed out and brought into contact with the upper end of the container 3, and the two are combined. And manufacturing is performed.
 次に、図4~図7を参照しながら、本発明の一実施の形態である2層口紅体の製造方法の一実施の形態について説明する。2層口紅体2の製造は、第2の組成物を貯留するAタンクを備えたステージAと、第1の組成物を貯留するBタンクを備えたステージBとで行われる。なお、図4~図7においては、中皿体のリブ12aは一部を省略して示している。 Next, an embodiment of a method for manufacturing a two-layer lipstick according to an embodiment of the present invention will be described with reference to FIGS. The production of the two-layer lipstick 2 is performed by a stage A having an A tank for storing the second composition and a stage B having a B tank for storing the first composition. 4 to 7, a part of the rib 12a of the inner plate is omitted.
 まず、図3に示すオジーブ4と繰り出し容器3との組合体5をオジーブ4を下側にして図示しない保持具により保持し、保持具と共に組合体5をステージAに移送し、図4に示すようにAタンク6の下で停止させる。そして、Aタンク6から、Aタンク6内に貯留されている加熱溶融された第2の組成物を繰り出し容器の底板に形成された貫通孔10cを通してオジーブ4内に所定量注入充填する。第2の組成物のオジーブ4への充填は、適宜の流量で行うことができ、例えば流量3.7ml/1.2秒で行うことができる。 First, the combined body 5 of the ogive 4 and the feeding container 3 shown in FIG. 3 is held by a holder (not shown) with the ogive 4 down, and the combined body 5 is transferred to the stage A together with the holder, as shown in FIG. As described below. Then, a predetermined amount of the second composition heated and melted and stored in the A tank 6 is fed from the A tank 6 into the ogive 4 through a through hole 10c formed in the bottom plate of the container. The filling of the second composition into the ogive 4 can be performed at an appropriate flow rate, for example, at a flow rate of 3.7 ml / 1.2 seconds.
 ステージAでオジーブ4に第2の組成物が所定量注入充填された後、組合体5を保持具と共にステージBに移送し、図5に示すように、Bタンク7の下で停止させ、この状態で保持具を回転させて組合体5をその中心軸(組合体5の上下方向に延びる中心軸)を中心として所定の回転速度で回転させる。 After a predetermined amount of the second composition is injected and filled into the ogive 4 at the stage A, the assembly 5 is transferred to the stage B together with the holder, and is stopped under the B tank 7 as shown in FIG. In this state, the holder is rotated to rotate the combined body 5 at a predetermined rotation speed about its central axis (the central axis extending in the vertical direction of the combined body 5).
 この回転により、図6に示すように、回転による遠心力の作用でオジーブ4内の第2の組成物をオジーブ4の内面に沿って層状に位置させ、第2の組成物の内側に空洞を形成させる。つまり、オジーブ4の内面に沿って層状になった内側に空洞を有する溶融状態の第2の組成物からなる外層部2Bを形成する。このとき、第2の組成物の上端部は中皿体のリブ12aの位置まで上昇している。この状態で組合体5の回転を継続させながら、第2の組成物の内側の空洞に、Bタンク7から加熱溶融された第1の組成物を所定量注入充填し、外層部2Bの内側に溶融状態の第1の組成物からなる中心部2Aを形成して図7の状態とする。第1の組成物の充填は、第2の組成物がオジーブ4に充填された組合体5を例えば1~2秒間回転させた後に開始することができる。第1の組成物の充填は、適宜の流量で行うことができ、例えば流量2.2ml/1.2秒で行うことができる。 Due to this rotation, as shown in FIG. 6, the second composition in the ogive 4 is positioned in a layer along the inner surface of the ogive 4 by the action of centrifugal force due to the rotation, and a cavity is formed inside the second composition. Let it form. That is, the outer layer portion 2B made of the second composition in a molten state having a cavity inside is formed in a layered shape along the inner surface of the ogive 4. At this time, the upper end of the second composition has risen to the position of the rib 12a of the inner plate. In this state, while the rotation of the combined body 5 is continued, a predetermined amount of the first composition heated and melted from the B tank 7 is injected and filled into the cavity inside the second composition, and the inside of the outer layer portion 2B is filled. A central portion 2A made of the first composition in a molten state is formed to obtain a state shown in FIG. The filling of the first composition can be started after the assembly 5 filled with the second composition in the ogive 4 is rotated, for example for 1-2 seconds. The filling of the first composition can be performed at an appropriate flow rate, for example, at a flow rate of 2.2 ml / 1.2 seconds.
 第1の組成物がオジーブ4に充填されて図7の状態になった後、回転を継続させながら強制冷却を開始する。回転は、少なくとも第1の組成物および第2の組成物が冷却されて回転させなくても第1の組成物および第2の組成物が図7に示す形状を維持できる状態となるまで継続する。例えば、第1の組成物がオジーブ4に充填された後直ちに強制冷却を開始すると共に、第1の組成物がオジーブ4に充填された後1~2秒間回転を継続し、しかる後組合体5の回転を停止することができる。そして、最終的に第1の組成物(中心部2A)および第2の組成物(外層部2B)が冷却固化して中心体2aおよび外層体2bからなる2層口紅体2が形成された後、組合体5を保持具から取り出し、2層口紅体2からオジーブ4を取り外すことにより、図1に示すような容器付2層口紅1が製造される。 (7) After the first composition is filled in the ogive 4 and the state shown in FIG. 7 is reached, forced cooling is started while continuing rotation. The rotation continues until at least the first composition and the second composition are cooled and the first composition and the second composition can maintain the shape shown in FIG. 7 without being rotated. . For example, immediately after the first composition is filled in the ogive 4, forced cooling is started, and after the first composition is filled in the ogive 4, rotation is continued for 1 to 2 seconds. Rotation can be stopped. Then, after the first composition (center portion 2A) and the second composition (outer layer portion 2B) are finally cooled and solidified to form a two-layer lipstick 2 composed of the center member 2a and the outer layer member 2b. Then, the union 5 is removed from the holder, and the ogive 4 is removed from the two-layer lipstick 2, whereby the two-layer lipstick 1 with a container as shown in FIG. 1 is manufactured.
 中心体2aと外層体2bの体積比は、5:1~1:5であることが好ましい。ここで体積比は、固化した状態での中皿体12内に入っている部分も含めて、2層口紅体2の全体における体積比である。 体積 The volume ratio between the center body 2a and the outer layer body 2b is preferably 5: 1 to 1: 5. Here, the volume ratio is the volume ratio of the entire two-layer lipstick 2 including the part contained in the inner plate 12 in a solidified state.
 外層体2bの硬度は、5~100であることが好ましい。硬度の定義は前述の通りである。硬度が5以下の場合、柔らかいためオジーブ4から外層体2bを損傷させることなく綺麗に抜き出すことが困難であり外層体の良好な成形が難しくなる。一方で硬度が100以上の場合、硬いため塗布してもなかなか中心体2aが露出してこないため、中心体2aが露出してくることでのワクワク感を感じにくい傾向となる。 硬度 The hardness of the outer layer body 2b is preferably 5 to 100. The definition of hardness is as described above. If the hardness is 5 or less, it is difficult to cleanly remove the outer layer 2b from the ogive 4 without damaging the outer layer 2b because of its softness, and it becomes difficult to form the outer layer 2 properly. On the other hand, when the hardness is 100 or more, the center body 2a does not easily come out even when applied because it is hard, so that the excitement of the center body 2a is less likely to be felt.
 中心体2aと外層体2bとの比重差は、0.05以下であることが好ましく、比重差は0であっても良い。比重差の定義は前述の通りである。比重差が0.05より大きいと、外層体2bが不均一に形成されやすい。中心体2aと外層体2bとは、どちらの比重の方が大きくてもよいが、外層体2bの比重の方が大きい場合は、2層口紅体2の先端側に外層体2aが溜まりやすい傾向にある。 比 The specific gravity difference between the central body 2a and the outer layer body 2b is preferably 0.05 or less, and the specific gravity difference may be zero. The definition of the specific gravity difference is as described above. When the specific gravity difference is larger than 0.05, the outer layer body 2b is likely to be formed unevenly. The central body 2a and the outer layer body 2b may have a higher specific gravity, but when the outer layer body 2b has a higher specific gravity, the outer layer body 2a tends to accumulate on the tip side of the two-layer lipstick 2. It is in.
 外層体2bの厚さの平均は0.1mm~3.0mmであることが好ましく、0.5mm~1.5mmであることが更に好ましい。厚さの平均の定義は前述の通りである。従来の前述した中芯を用いる金型成形の場合は、中芯を抜き出す関係上外層体の厚さは1.5mm程度が限度であって、それ以上薄くすることが困難であったが、本発明に係る製造方法によれば、中芯を抜き出す工程が不要であり、その結果、外層体2bの厚さの平均が1.5mm以下のものを製造可能である。 平均 The average thickness of the outer layer body 2b is preferably 0.1 mm to 3.0 mm, more preferably 0.5 mm to 1.5 mm. The definition of the average thickness is as described above. In the case of the conventional mold molding using the above-described core, the thickness of the outer layer body is limited to about 1.5 mm due to the extraction of the core, and it is difficult to reduce the thickness further. According to the manufacturing method of the present invention, the step of extracting the core is unnecessary, and as a result, the outer layer 2b having an average thickness of 1.5 mm or less can be manufactured.
 前記2層口紅体の製造方法において、ステージBで中心体2a用の第1の組成物を注入充填する際に組合体5を回転させながら注入充填したが、先に充填されている第2の組成物が遠心力によりオジーブ4の内面に沿って層状に位置した後その形状を維持し得る状態にある場合は、回転を停止して第1の組成物を注入充填することも可能である。 In the method for producing a two-layer lipstick, the first composition for the center body 2a is injected and filled at the stage B while the assembly 5 is rotated while being injected and filled. When the composition is in a state where it can maintain its shape after being positioned in a layered form along the inner surface of the ogive 4 by centrifugal force, the rotation can be stopped and the first composition can be injected and filled.
 第2の組成物を充填して外層部2Bを成形しかつ第1の組成物を充填して中心部2Aを形成する際の組合体5の回転の回転速度は、500~1500rpmが好ましく、700~900rpmがさらに好ましい。回転速度が500rpm以下の場合には、第2の組成物がオジーブ4の先端側に溜まりやすく、成形された2層口紅体2の先端側に外層体2aが溜まりやすい傾向にある。一方、1500rpm以上の場合には、第1の組成物がオジーブ4の内面側に移動しかつ中皿体12から溢れ出てしまい、成形された2層口紅体2において中心体2aが表面に露出してしまう傾向にある。 When the outer layer portion 2B is formed by filling the second composition and the center portion 2A is formed by filling the first composition, the rotation speed of the assembly 5 is preferably 500 to 1500 rpm, and 700 rpm. 900900 rpm is more preferable. If the rotation speed is 500 rpm or less, the second composition tends to accumulate on the tip side of the ogive 4 and the outer layer body 2a tends to accumulate on the tip side of the molded two-layer lipstick 2. On the other hand, when the rotation speed is 1500 rpm or more, the first composition moves to the inner surface side of the ogive 4 and overflows from the inner plate body 12, and the central body 2a is exposed on the surface of the formed two-layer lipstick 2. Tend to do it.
 本発明の製造方法においては、上記実施の形態では繰り出し容器3とオジーブ4との組合体5を使用して2層口紅体2を製造したが、繰り出し容器3は図示の構造のものに限らず、どのような構造の容器を用いても良い。もちろん、繰り出しタイプの容器である必要もない。また、必ずしも成形型と容器とを組み合わせた組合体を用いる必要もなく、成形型のみを用い、成形型に第1の組成物を充填し、その後成形型を回転させながら第1の組成物を成形型の有底凹部内面に沿わせて層状に位置させ、その後第2の組成物を充填しても良い。さらに、成形型としても、オジーブに限らず、種々の成形型を用いることができる。 In the manufacturing method of the present invention, the two-layer lipstick 2 is manufactured using the combination 5 of the feeding container 3 and the ogive 4 in the above-described embodiment, but the feeding container 3 is not limited to the one having the illustrated structure. A container having any structure may be used. Of course, it is not necessary to be a feeding type container. Further, it is not necessary to use a combination of a mold and a container, and only the mold is used, the mold is filled with the first composition, and then the first composition is rotated while rotating the mold. The mold may be positioned in a layer along the inner surface of the bottomed concave portion, and then filled with the second composition. Further, the mold is not limited to the ogive, and various molds can be used.
 本発明の固形化粧料は、上述の2層口紅に限定されず、3層以上の異なる組成の組成物からなる口紅であっても良い。3層以上の場合は、最外の層が外層体となり、最外の層の内側に位置する部分(最外の層の内側に位置する全ての層からなる部分)が中心体となる。この場合は、最外の層を構成する組成物を成形型に注入充填し、成形型を回転させながら順次異なる組成物を注入充填して各組成物を層状とし、最後に最も内側に位置すべき層の組成物を注入充填して冷却固化させることにより製造することができる。また、色は同じでも成分が異なる複数の組成物からなる口紅であっても良い。また、口紅に限らず、グロス、リップクリーム等の棒状化粧料、あるいは、棒状以外の各種化粧料であっても良い。さらに、口紅の場合、実施の態様に示す形状のものに限らず、例えば先端部分に傾斜面を有する形状のものであってもよい。 The solid cosmetic of the present invention is not limited to the above-described two-layer lipstick, and may be a lipstick composed of three or more layers of different compositions. In the case of three or more layers, the outermost layer becomes the outer layer body, and the part located inside the outermost layer (the part consisting of all the layers located inside the outermost layer) becomes the central body. In this case, the composition constituting the outermost layer is injected and filled into a molding die, and different compositions are sequentially injected and filled while rotating the molding die to form each composition into a layered form, and finally the composition is positioned at the innermost position. It can be produced by injecting and filling the composition of the layer to be cooled and solidifying by cooling. Alternatively, the lipstick may be composed of a plurality of compositions having the same color but different components. Further, the present invention is not limited to lipstick, and may be a stick-shaped cosmetic such as gloss or lip balm, or various cosmetics other than a stick. Further, in the case of a lipstick, the shape is not limited to the shape shown in the embodiment, but may be a shape having an inclined surface at a tip portion, for example.
 また、第1の組成物および第2の組成物も、以下に説明する実施例の組成物に限らず、種々の組成物を使用することができ、第1の組成物および第2の組成物の充填条件も、以下に説明する実施例の充填条件に限らず、種々の充填条件にて成形することができる。 In addition, the first composition and the second composition are not limited to the compositions of the examples described below, and various compositions can be used. The first composition and the second composition Is not limited to the filling conditions of the embodiments described below, and molding can be performed under various filling conditions.
 次に、上記2層口紅体の製造方法の実施例について、表1、表2および表3を参照しながら説明する。表1、表2および表3中の各組成物における各成分(配合量合計100質量%)の数値は全体に対する質量%を示す。また、表1および表2において、「内層」は第1の組成物を、「外層」は第2の組成物を、「比率(内層:外層)」は第1の組成物と第2の組成物が固化した後のそれぞれの全体の体積比率(中心体2a全体と外層体2b全体との体積比率)を、「内層充填温度」および「外層充填温度」は第1の組成物および第2の組成物をそれぞれオジーブ4に充填するときの第1の組成物および第2の組成物の温度を、「回転速度」は第2の組成物からなる外層部2Bを形成すると共に外層部2Bの空洞に第1の組成物を充填して中心部2Aを形成する際の組合体5の回転速度を、「内外層分布状態」は第1の組成物と第2の組成物が冷却固化した後の中心体2aと外層体2bの分布状態を、「膜厚」は外層体2bの上述した厚さの平均を意味する。なお、表1,表2中の「比重」および「比重差」は第1の組成物および第2の組成物が固化した状態(中心体2aと外層体2b)での比重および比重差である。 Next, examples of the method for producing the two-layer lipstick will be described with reference to Tables 1, 2, and 3. The numerical value of each component (total blending amount: 100% by mass) in each composition in Tables 1, 2 and 3 represents% by mass with respect to the whole. In Tables 1 and 2, “inner layer” represents the first composition, “outer layer” represents the second composition, and “ratio (inner layer: outer layer)” represents the first composition and the second composition. The “volume ratio of the entire central body 2a and the entirety of the outer layer body 2b” after solidification of the material is expressed by the “inner layer filling temperature” and the “outer layer filling temperature” of the first composition and the second layer. The "rotation speed" refers to the temperature of the first composition and the second composition when each of the compositions is filled in the ogive 4, and the "rotation speed" defines the outer layer 2B made of the second composition and the cavity of the outer layer 2B. The rotation speed of the combination 5 at the time of forming the center portion 2A by filling the first composition into the “inner / outer layer distribution state” indicates that the first composition and the second composition are cooled and solidified. The distribution state of the central body 2a and the outer layer body 2b, and "film thickness" means an average of the above-mentioned thickness of the outer layer body 2b. In addition, "specific gravity" and "specific gravity difference" in Tables 1 and 2 are specific gravity and specific gravity difference in a state where the first composition and the second composition are solidified (the center body 2a and the outer layer body 2b). .
 表1、表2および表3に示す実施例においては、いずれも、外層体の材料である第2の組成物を加熱溶融して上述のステージAで組合体5に注入充填し、上述のステージBで回転させながら第2の組成物をオジーブ4の内面に沿わせて層状に位置させ、次いで層状に位置した第2の組成物の内側の空洞に加熱溶融した第1の組成物を注入充填し、その後強制冷却を開始して回転を停止し、両組成物を固化させて第1の組成物からなる中心体2aと第2の組成物からなる外層体2bを備えた容器付2層口紅1を製造した。 In each of the examples shown in Tables 1, 2 and 3, the second composition, which is the material of the outer layer body, is heated and melted, and injected and filled into the combination 5 at the above-mentioned stage A, and The second composition is positioned in a layer along the inner surface of the ogive 4 while rotating at B, and then the first composition melted by heating is injected and filled into the cavity inside the second composition positioned in the layer. Then, forced cooling is started and rotation is stopped, and both compositions are solidified to form a two-layer lipstick with a container having a center body 2a made of the first composition and an outer layer body 2b made of the second composition. 1 was produced.
Figure JPOXMLDOC01-appb-T000001
Figure JPOXMLDOC01-appb-T000001
 表1は、表1-1と表1-2からなり、表1-2に記載されている組成物1および組成物2をそれぞれ外層体2b用の第2の組成物および中心体2a用の第1の組成物として使用し、表1-1に記載されている17通りの充填条件で成形を行った場合の外層体2bの膜厚および中心体2aと外層体2bとの分布状態を示している。表1-1の膜厚の欄中の「-」は、膜厚を測定していないことを示す。なお、表1-2には、外層体2bと中心体2aの硬度および比重差も示されている。 Table 1 is composed of Table 1-1 and Table 1-2, and the composition 1 and the composition 2 described in Table 1-2 are respectively applied to the second composition for the outer layer body 2b and the composition for the center body 2a. The thickness of the outer layer body 2b and the distribution of the central body 2a and the outer layer body 2b when used as the first composition and molded under the 17 filling conditions described in Table 1-1 are shown. ing. "-" In the column of film thickness in Table 1-1 indicates that the film thickness was not measured. Table 1-2 also shows the hardness and specific gravity difference between the outer layer body 2b and the center body 2a.
 表1-1に示されているように、回転速度が300rpmの場合第2の組成物からなる外層体が先端側に溜まり、回転速度が2000rpmの場合第1の組成物からなる中心体が表面に一部露出してまだら模様となり、回転速度が800rpmでも、第1の組成物と第2の組成物との比率(中心体と外層体との体積比率)が5:1~1:5の範囲から外れて9:1や1:9である場合、中心体が露出したり2層状態にならないという不都合が生じた。それら以外の充填条件の場合、内外層分布状態の欄に○を記しているように、固化後の2層口紅体2における中心体2aと外層体2bとの分布は良好であり、混じり合いの少ない外層体2bをもつ2層構造の口紅体2が成形された。 As shown in Table 1-1, when the rotation speed was 300 rpm, the outer layer body composed of the second composition was accumulated on the tip side, and when the rotation speed was 2000 rpm, the center body composed of the first composition was on the surface. And the ratio of the first composition to the second composition (the volume ratio between the center body and the outer layer body) is 5: 1 to 1: 5 even at a rotational speed of 800 rpm. When the ratio is 9: 1 or 1: 9 out of the range, there is a problem that the central body is not exposed or does not have a two-layer state. In the case of other filling conditions, the distribution of the central body 2a and the outer layer body 2b in the solidified two-layer lipstick 2 is good, as indicated by a circle in the column of inner / outer layer distribution state. A lipstick 2 having a two-layer structure having a small outer layer 2b was formed.
Figure JPOXMLDOC01-appb-T000002
Figure JPOXMLDOC01-appb-T000002
 表2は、表2-1と表2-2からなり、表2-1中の組成物1と組成物2、組成物3と組成物4、組成物5と組成物6、組成物7と組成物8および組成物9と組成物10の5組の組成物(組成物1,3,5,7,9が外層体用の第2の組成物、組成物2,4,6,8,10が中心体用の第1の組成物)を使用し、各組とも表2-2に記載されている同一の充填条件で成形を行った場合のそれぞれの内外層分布状態を示している。 Table 2 consists of Tables 2-1 and 2-2. In Table 2-1, compositions 1 and 2; compositions 3 and 4; compositions 5 and 6; Composition 8 and five sets of compositions 9 and 10 ( compositions 1, 3, 5, 7, and 9 being the second composition for the outer layer, compositions 2, 4, 6, 8, 10 shows the distribution state of the inner and outer layers when each of the sets is formed under the same filling conditions described in Table 2-2.
 表2-1には、各組成物の固化後の硬度、固化後の比重と共に、各組成物の組の固化後の比重差も示されている。組成物1,2の組、組成物3,4の組、組成物5,6の組および組成物9,10の組の場合、内外層分布状態は○、即ち固化後の2層口紅体2における中心体2aと外層体2bとの分布は良好であり、混じり合いの少ない外層体2bをもつ2
層構造の口紅体2が成形された。また、組成物7,8の組の場合、内外層分布状態は△、即ち固化後の2層口紅体2における中心体2aと外層体2bとの分布は、比重差が0.08と少し大きいことから、外層体2bの均一性が低く、中心体2aと外層体2bとの分離がやや不明瞭であった。
Table 2-1 shows the hardness after solidification of each composition, the specific gravity after solidification, and the difference in specific gravity after solidification of each set of compositions. In the case of the set of the compositions 1 and 2, the set of the compositions 3 and 4, the set of the compositions 5 and 6, and the set of the compositions 9 and 10, the inner and outer layer distribution state is ○, that is, the solidified two-layer lipstick 2 The distribution of the central body 2a and the outer layer body 2b is good, and the 2
A lipstick 2 having a layer structure was formed. In the case of the set of the compositions 7 and 8, the distribution state of the inner and outer layers is △, that is, the distribution between the central body 2a and the outer layer body 2b in the solidified two-layer lipstick 2 has a slightly large specific gravity difference of 0.08. Therefore, the uniformity of the outer layer body 2b was low, and the separation between the central body 2a and the outer layer body 2b was somewhat unclear.
 表2-1から分かるように、組成物1,2の組、組成物3,4の組、組成物5,6の組および組成物9,10の組は、いずれも比重差が0.05以下であり、前3つの組はいずれも外層体2bの方が中心体2aより比重が大きく、最後の組は中心体2aの方が外層体2bより比重が大きいことから、中心体2aと外層体2bの比重の大小関係に関わらず、両者の比重差が0.05以下である場合、内外層分布状態は良好である。内外層分布状態は中心体2aと外層体2bの比重差の影響を受け、中心体2aおよび外層体2bの比重そのものの大きさには特に影響されない。なお、発明者は中心体2aおよび外層体2bとして比重が0.9-1.1の範囲のものを用いて比重差が0.05以下で内外層分布状態が良好であることを確認している。 As can be seen from Table 2-1, the set of compositions 1 and 2, the set of compositions 3 and 4, the set of compositions 5 and 6, and the set of compositions 9 and 10 all have a specific gravity difference of 0.05. In the first three sets, the outer layer body 2b has a higher specific gravity than the center body 2a, and the last set has the center body 2a having a higher specific gravity than the outer layer body 2b. Regardless of the magnitude relationship of the specific gravity of the body 2b, when the specific gravity difference between them is 0.05 or less, the inner and outer layer distribution state is good. The inner / outer layer distribution state is affected by the specific gravity difference between the center body 2a and the outer layer body 2b, and is not particularly affected by the magnitude of the specific gravity itself of the center body 2a and the outer layer body 2b. The inventor has confirmed that the specific gravity difference is 0.05 or less and the inner and outer layer distribution is good, using the center body 2a and the outer layer body 2b having a specific gravity in the range of 0.9-1.1. I have.
Figure JPOXMLDOC01-appb-T000003
Figure JPOXMLDOC01-appb-T000003
 表3に、中心体用の第1の組成物および外層体用の第2の組成物の組み合わせのさらなる例を示す。表3に示されている組成物の各組み合わせを用い、表2-2に記載されている充填条件にて成形することにより、内外層分布状態が良好な2層口紅体を成形することができた。 Table 3 shows further examples of combinations of the first composition for the central body and the second composition for the outer layer body. By using each combination of the compositions shown in Table 3 and molding under the filling conditions shown in Table 2-2, a two-layer lipstick having a good inner and outer layer distribution can be formed. Was.
 本発明に係る固形化粧料の上記実施例によれば、異なる2種類の組成物、例えば色調の異なる2種類の組成物あるいは使用感の異なる2種類の組成物からなる2層口紅体を、外層体が薄い形で、かつ、中心体と外層体との分布が良好な状態で、少ない工程数で容易に成形することができた。 According to the above-mentioned embodiment of the solid cosmetic according to the present invention, two different compositions, for example, a two-layer lipstick composed of two compositions having different color tones or two different compositions having different feelings of use are used as outer layers. In a state where the body was thin and the distribution of the center body and the outer layer body was good, it could be easily formed with a small number of steps.
1   容器付2層口紅
2   2層口紅体(固形化粧料)
2a  中心体
2b  外層体
3   容器
4   オジーブ(成形型)
1 2-layer lipstick with container 2 2-layer lipstick (solid cosmetics)
2a Central body 2b Outer layer body 3 Container 4 Ojibe (mold)

Claims (8)

  1.  第1の組成物からなる中心体と、該中心体の全表面を覆う第2の組成物からなる外層体とを備えたことを特徴とする固形化粧料。 (4) A solid cosmetic comprising: a center body made of the first composition; and an outer layer body made of the second composition covering the entire surface of the center body.
  2.  前記中心体と前記外層体との体積比が、5:1~1:5である請求項1記載の固形化粧料。 固 形 The solid cosmetic according to claim 1, wherein the volume ratio between the central body and the outer layer body is 5: 1 to 1: 5.
  3.  前記外層体の硬度が5~100である請求項1または2記載の固形化粧料。 固 形 The solid cosmetic according to claim 1 or 2, wherein the hardness of the outer layer body is 5 to 100.
  4.  前記中心体と前記外層体との比重差が、0.05以下である請求項1~3いずれか1項記載の固形化粧料。 固 形 The solid cosmetic according to any one of claims 1 to 3, wherein a difference in specific gravity between the central body and the outer layer body is 0.05 or less.
  5.  前記外層体の厚さの平均が、0.1mm~3.0mmである請求項1~4いずれか1項記載の固形化粧料。 The solid cosmetic according to any one of claims 1 to 4, wherein the outer layer body has an average thickness of 0.1 mm to 3.0 mm.
  6.  形状がスティック状である請求項1~5いずれか1項記載の固形化粧料。 固 形 The solid cosmetic according to any one of claims 1 to 5, wherein the shape is a stick.
  7.  上下方向に延びる中心軸を有する上端開口の有底凹部を有する成形型に第2の組成物を充填し、前記成形型を前記中心軸周りに回転させて前記第2の組成物を前記有底凹部の内面に沿って層状に位置させて内側に空洞を有する外層部を形成し、次いで前記空洞に第1の組成物を充填して中心部を形成し、前記外層部と前記中心部を固化させることを特徴とする固形化粧料の製造方法。 A second mold is filled into a mold having a bottomed concave portion having an upper end opening having a central axis extending in the vertical direction, and the mold is rotated around the central axis to allow the second composition to have the bottomed shape. Forming an outer layer portion having a cavity inside by forming a layer along the inner surface of the concave portion, and then filling the cavity with a first composition to form a center portion, and solidifying the outer layer portion and the center portion A method for producing a solid cosmetic comprising:
  8.  前記成形型の回転の回転速度が500~1500rpmである請求項7記載の固形化粧料の製造方法。 (8) The method for producing a solid cosmetic according to (7), wherein the rotation speed of the mold is 500 to 1500 rpm.
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CN113729387A (en) * 2020-05-29 2021-12-03 上海创元化妆品有限公司 Internal and external relief cosmetics, preparation method and mould thereof

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TWI763245B (en) * 2021-01-11 2022-05-01 美帥化學股份有限公司 Lipstick mold device and lipstick manufacturing method

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JPS63139107A (en) * 1986-12-02 1988-06-10 Kobayashi Kooc:Kk Stick-like cosmetic and production thereof
JPH02172904A (en) * 1988-12-26 1990-07-04 Kobayashi Kose Co Ltd Production of double stick cosmetic
JP2008105951A (en) * 2006-10-23 2008-05-08 Doctor Program Kk Stick shape cosmetic for lips
JP5425540B2 (en) * 2009-06-25 2014-02-26 株式会社コーセー Multicolor oily solid cosmetic

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JPS63139107A (en) * 1986-12-02 1988-06-10 Kobayashi Kooc:Kk Stick-like cosmetic and production thereof
JPH02172904A (en) * 1988-12-26 1990-07-04 Kobayashi Kose Co Ltd Production of double stick cosmetic
JP2008105951A (en) * 2006-10-23 2008-05-08 Doctor Program Kk Stick shape cosmetic for lips
JP5425540B2 (en) * 2009-06-25 2014-02-26 株式会社コーセー Multicolor oily solid cosmetic

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113729387A (en) * 2020-05-29 2021-12-03 上海创元化妆品有限公司 Internal and external relief cosmetics, preparation method and mould thereof
CN113729387B (en) * 2020-05-29 2024-03-15 上海创元化妆品有限公司 Internal and external relief cosmetic, preparation method and mold thereof

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