WO2019230657A1 - Converter blowing method - Google Patents
Converter blowing method Download PDFInfo
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- WO2019230657A1 WO2019230657A1 PCT/JP2019/020925 JP2019020925W WO2019230657A1 WO 2019230657 A1 WO2019230657 A1 WO 2019230657A1 JP 2019020925 W JP2019020925 W JP 2019020925W WO 2019230657 A1 WO2019230657 A1 WO 2019230657A1
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- WIPO (PCT)
- Prior art keywords
- lance
- dust
- converter
- blowing
- amount
- Prior art date
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
- C21C5/00—Manufacture of carbon-steel, e.g. plain mild steel, medium carbon steel or cast steel or stainless steel
- C21C5/52—Manufacture of steel in electric furnaces
- C21C5/527—Charging of the electric furnace
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
- C21C5/00—Manufacture of carbon-steel, e.g. plain mild steel, medium carbon steel or cast steel or stainless steel
- C21C5/28—Manufacture of steel in the converter
- C21C5/30—Regulating or controlling the blowing
- C21C5/32—Blowing from above
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
- C21C5/00—Manufacture of carbon-steel, e.g. plain mild steel, medium carbon steel or cast steel or stainless steel
- C21C5/28—Manufacture of steel in the converter
- C21C5/42—Constructional features of converters
- C21C5/46—Details or accessories
- C21C5/466—Charging device for converters
Definitions
- This disclosure relates to a converter blowing method using an upper blowing lance.
- blowing is performed using an upper blowing lance (hereinafter referred to as “lance” as appropriate).
- oxygen gas is jetted from the nozzle hole provided in the lance toward the hot metal surface (molten metal surface), and the hot metal is stirred and Si, Mn, P, and C are removed by an oxidation reaction.
- dust is generated from the converter due to the rebound and decarburization reaction of the oxygen gas sprayed from the nozzle hole of the lance.
- the generated dust is discharged together with the exhaust gas.
- This dust is mainly composed of iron (iron, iron oxide), and if discharged, it will lead to iron loss, so it is desirable to reduce it.
- the shape of the hot metal surface in the converter changes when oxygen gas collides with the hot metal surface due to the acid feed rate and the lance height (nozzle tip position).
- the lance gap which is the distance between the hot metal surface and the nozzle tip, the hot metal shape when the oxygen gas collides with the hot metal surface becomes a waterfall (reverse ⁇ -shaped cross section). It is known that the amount of dust generated can be reduced because the generated dust does not scatter and is easily taken into the hot metal. This is called hard blow.
- the lance gap has an optimum interval for reducing the amount of dust generated while maintaining the life of the lance, and it is desired to perform blowing by the interval.
- the optimum interval of the lance gap (hereinafter referred to as “optimum lance gap” as appropriate) is set according to the size of the converter and the acid feed rate.
- optimum lance gap In order to set the lance gap to an optimum interval, it is necessary to grasp the height of the hot metal surface, and for example, there is a technique disclosed in Japanese Patent Application Laid-Open No. 11-52049.
- a moving microwave transmission / reception antenna installed in the sublance hole of the upper hood of the converter after charging hot metal and scrap or can alloy (alloy iron in a drum can) in the converter
- microwaves are transmitted toward the furnace, and the height of the hot metal surface (water surface level) is measured from the received signal.
- the measurement of the height of the hot metal surface is performed after the hot metal is charged into the converter and before the start of blowing (before the start of blowing).
- Japanese Patent Laid-Open No. 11-52049 there is no clear description of the time required for the measurement of the hot metal surface height. Therefore, it is difficult to measure the hot metal surface height every time the molten iron or the like is charged into the converter.
- the estimated value of the hot metal surface height (estimated hot metal surface height) for each blowing operation when not actually measured is expressed by the following formula ( 1).
- (Estimated hot metal surface height) ⁇ (WTn ⁇ WT 0 ) / ( ⁇ r 0 2 ) ⁇ + l 0 (1)
- ⁇ is the iron specific gravity
- r 0 is the cross-sectional radius (inner diameter) of the converter near the hot metal surface
- 10 is the measured value of the hot metal surface height with a microwave hot metal surface meter
- WT 0 is with the microwave hot metal surface meter.
- WTn is the amount of iron charged to the converter at the time of calculating the estimated hot metal surface height.
- the cross-sectional radius of the converter changes with each blowing. For this reason, every time when blowing is repeated from the measurement of the hot metal surface height by the microwave hot metal surface meter, a difference occurs between the estimated hot metal surface height and the actual hot metal surface height. For this reason, the lance gap cannot be set to an optimum interval.
- This disclosure has been made in view of such circumstances, and an object thereof is to provide a converter blowing method capable of performing blowing with an appropriate lance gap even when the hot metal surface height is not actually measured.
- the lance gap can be estimated from the dust generation speed by utilizing the fact that the dust generation speed changes due to the fluctuation of the lance gap.
- the flow of oxygen gas oxygen jet
- the dust generation speed changes even if the lance gap is constant. . That is, it is difficult to estimate the lance gap only with the dust generation rate. Therefore, the lance gap is adjusted based on the dust generation speed that also takes into account the influence of the number of times the lance is used. This indication was made based on the above knowledge, and the summary is as follows.
- a converter blowing method is a converter blowing method in which oxygen gas is blown from a nozzle of an upper blowing lance to a hot metal surface in a converter, and the amount of dust in exhaust gas generated during blowing And calculating the dust generation speed in the converter, and the upper limit when the lance gap, which is the distance between the hot metal surface and the tip of the upper blowing lance, is determined in advance, is an optimal interval.
- FIG. 2B is a cross-sectional view of the tip side of the top blowing lance showing a state in which the nozzle is worn by use in the top blowing lance shown in FIG. 2A. It is a graph which shows the relationship between the variation
- the converter blowing method according to an embodiment of the present disclosure is a blowing method used in the refining equipment 9 shown in FIGS. 1A and 1B. First, after describing the refining equipment 9 of the present embodiment, the converter blowing method of the present embodiment will be described.
- the refining equipment 9 includes a converter 10, an upper blow lance 11 (hereinafter referred to as “lance” as appropriate), and an exhaust gas treatment device 17.
- the lance 11 is a member for spraying oxygen gas onto the molten iron surface S in the converter 10 from a nozzle 11A described later.
- the lance 11 has a cylindrical shape and can be moved upward and downward in the vertical direction by a lifting device (not shown). By moving the lance 11 up and down, the lower part (front end side) of the lance 11 can be inserted into or removed from the converter 10. The lance 11 can be stopped at an arbitrary height position by the lifting device.
- the lance gap G described later can be adjusted by the vertical movement of the lance 11. Note that the arrow UP in FIG. 2A indicates the upper side in the vertical direction. An arrow AXL in FIG. 2A indicates the central axis of the lance 11.
- the tip of the lance 11 is a nozzle portion, and a plurality of nozzles 11A are provided in the nozzle portion.
- These nozzles 11 ⁇ / b> A are through holes having a narrowed middle portion, that is, Laval nozzles (De Laval nozzle), and a plurality of nozzles 11 ⁇ / b> A are provided on a concentric circle centered on the central axis AXL of the lance 11 at regular intervals. Yes.
- the nozzle 11A may also be formed on the central axis AXL of the lance 11.
- oxygen gas A supplied to the lance 11 is jetted from the nozzle 11A.
- the jet of the oxygen gas A injected from the nozzle 11 ⁇ / b> A toward the hot metal surface S after forming the jet core, spreads at an angle with a free spread angle ⁇ , and collides with the hot metal in the converter 10.
- a hot spot recessed in a waterfall shape is formed on the hot metal surface S (note that the hot spot is not shown in FIG. 2A).
- the exhaust gas treatment device 17 is a device that treats exhaust gas containing dust generated from the converter 10 (gas mainly composed of CO, CO 2 , and N 2 gas) in a wet process.
- the exhaust gas treatment device 17 includes a furnace port hood 18, an exhaust gas duct 12, a primary dust collector 13, a secondary dust collector 19 and the like.
- the furnace port hood 18 and the exhaust gas duct 12 are provided above the converter 10.
- a primary dust collector 13, a secondary dust collector 19, and an induction blower (not shown) are sequentially provided on the downstream side of the exhaust gas duct 12.
- the exhaust gas from the converter 10 is sucked by an induction blower, passes through the furnace port hood 18 and the exhaust gas duct 12, and is removed by the primary dust collector 13 and the secondary dust collector 19.
- the dust-exhausted exhaust gas passes through an induction blower, and the exhaust gas with a high CO concentration is sent as a valuable gas to a gas holder (not shown), while the exhaust gas with a low CO concentration is burned at the top through a chimney (not shown) and is discharged into the atmosphere. To be dissipated.
- the primary dust collector 13 and the secondary dust collector 19 each collect exhaust gas by wet type, and for example, venturi scrubber is used.
- Dust collection water (indicated by arrow W in FIGS. 1A and 1B) introduced into the primary dust collector 13 takes in dust in the exhaust gas and becomes dust collection water containing dust. Dust collection water is temporarily stored in a lower water tank 14 provided immediately below the primary dust collector 13, and then sent to a dust collection water treatment device (not shown) to remove dust in the dust collection water.
- the exhaust gas treatment device 17 includes a dust concentration measurement device (hereinafter referred to as “measurement device” as appropriate) 20 for measuring the dust concentration.
- the measuring device 20 includes a pump 15 that continuously collects the collected water that has passed through the primary dust collector 13, and a vibratory density meter 16 that measures the density of the collected water.
- the collected water is continuously collected by the pump 15, and the vibration density meter 16 is used to continuously measure the dust concentration in the collected water per unit time according to the relationship with the water temperature at that time. (The amount of dust in the exhaust gas generated during blowing of the converter 10 is continuously measured).
- the dust concentration in the exhaust gas of the converter 10 can be estimated by measuring the dust concentration in the collected water collected by the primary dust collector 13. Note that the collected water after the dust concentration measurement is returned to the lower water tank 14.
- the converter blowing method of this embodiment is demonstrated.
- the tip side of the lance 11 is inserted into the converter 10, and the hot metal surface S in the converter 10 is inserted from the nozzle 11 ⁇ / b> A of the lance 11.
- This is a blowing method in which oxygen gas A is blown onto the steel and decarburized.
- this converter blowing method is characterized by making the lance gap G (see FIG. 2A), which is the distance between the hot metal surface S and the tip of the lance 11, an optimum interval when blowing.
- the blowing may be not only top blowing but also top bottom blowing combined with bottom blowing.
- the converter blowing method described above includes a speed calculating step of calculating a dust generation speed GR by obtaining a dust amount in exhaust gas generated during blowing, Deviation amount calculation for obtaining the deviation amount of the dust generation speed GR calculated in the speed calculation process with respect to the relationship R1 between the number of times the lance 11 is used and the dust generation speed GR when the lance gap G is set to an optimum interval.
- a speed calculating step of calculating a dust generation speed GR by obtaining a dust amount in exhaust gas generated during blowing
- Deviation amount calculation for obtaining the deviation amount of the dust generation speed GR calculated in the speed calculation process with respect to the relationship R1 between the number of times the lance 11 is used and the dust generation speed GR when the lance gap G is set to an optimum interval.
- the speed calculation step, the deviation amount calculation step, and the position adjustment step described above are processed by a computer (calculation means) of an operator who performs the converter operation. Further, the relationship R1 used in the deviation amount calculation step and the relationship R2 used in the position adjustment step are made into a database, for example.
- the above-mentioned computer receives various information for performing the converter operation, and also controls the converter operation (for example, start and stop of blowing, adjustment of the lance gap G) and the like (that is, the computer controls It becomes a means).
- the computer described above is a conventionally known computer including a RAM, a CPU, a ROM, an I / O, and a bus for connecting these elements, but is not limited thereto.
- a lance 11 is inserted into the furnace from above the converter 10, and oxygen gas A is blown onto the molten iron at a high speed, thereby causing impurities such as Si, C, P, and Mn. Is removed (decarburized).
- impurities such as Si, C, P, and Mn.
- fine dust is generated by the rebound of the sprayed oxygen gas A on the hot metal surface S and the bubble breaking of the CO gas on the hot metal surface S accompanying the decarburization reaction.
- the generated dust is sucked into the exhaust gas duct 12 through the furnace port hood 18 together with the exhaust gas generated from the converter 10 and is contained in the dust collection water supplied from the primary dust collector 13 while being collected through the lower water tank 14. It is sent to the processor and separated and recovered. Note that the dust generated from the converter 10 is separated from the exhaust gas by the dust water sprayed by the primary dust collector 13, and the exhaust gas is sent downstream.
- the collected water is continuously collected by the pump 15, and the vibration density meter 16 is used to collect the collected water per unit time according to the relationship with the water temperature at that time. Perform continuous measurement of dust concentration.
- the dust generation rate during blowing of the converter 10 can be calculated from the product of the dust concentration measured by the above method and the amount of water sprayed per unit time (the amount of water sprayed from the primary dust collector 13).
- a hot metal surface S in the converter 10 (for example, about 400 tons of molten iron in the converter) is measured by a microwave hot metal surface meter (not shown), and is removed from the lance gap G for each use of the lance 11 and the acid supply.
- the relationship shown in FIG. 3 is obtained by estimating the relationship with the average dust generation rate GR in the decarburization peak period when charcoal occurs preferentially.
- the number of uses N of the lance 11 corresponds to the number of times the converter 10 is blown (the same applies hereinafter). In FIG. 3, when the lance is used about 50 times (when the number of times of use is low: black circle in FIG. 3) and when it is about 200 times (when the number of uses is high: white circles in FIG.
- the dust generation rate GR increases linearly as the lance gap G (here, in the range of 2500 to 3000 mm) increases. Regardless of the deformation of the nozzle 11A of the lance 11, the inclination is constant.
- the “tilt” is a gradient obtained by dividing the change amount of the dust generation speed GR by the change amount of the lance gap G (that is, the relationship R2).
- FIG. 4 shows the dust generation rate GR at the peak of decarburization with respect to the lance usage number N when the hot metal surface S in the converter 10 is measured with a microwave hot metal surface meter and the lance gap G is set to an optimum interval. It becomes a relationship (that is, relationship R1).
- relationship R1 relationship (that is, relationship R2).
- the dust generation speed GR increases as the lance usage number N increases.
- the dust generation speed GR of the converter 10 is calculated by the above-described method, and the speed calculation process, the deviation amount calculation process, and the position adjustment process are sequentially performed using the relations R1 and R2 obtained in advance.
- the dust generation of the converter 10 calculated in the speed calculation step based on the relationship R1 between the number of times of use of the top blow lance 11 in the optimum lance gap and the dust generation speed of the converter 10 shown in FIG. Find out how much the speed GR deviates. Specifically, the difference (that is, the amount of deviation) between the value of the dust generation speed GR obtained from FIG. 4 and the value of the dust generation speed calculated in the speed calculation step is determined according to the lance usage number N.
- the lance gap G needs to be adjusted largely.
- the calculated dust generation rate GR is higher than the value of the dust generation rate GR corresponding to the lance usage number N shown in FIG. 4, the actual lance gap G is larger than the optimum lance gap G. (It is a soft blow), it is necessary to adjust the lance gap G small.
- the gradient obtained by dividing the change amount of the dust generation speed GR by the change amount of the lance gap G which indicates the relationship R2 between the change amount of the lance gap G and the change amount of the dust generation speed GR, Regardless of whether or not From the relationship between the two, the adjustment amount of the lance gap G for correcting the deviation amount of the dust generation speed GR is obtained, and the lance gap G is adjusted during the blowing of the converter 10.
- the deviation amount of the dust generation speed GR obtained in the deviation amount calculation step is divided by the above-described gradient to obtain an adjustment amount of the lance gap G corresponding to the deviation amount of the dust generation speed GR.
- the lance gap G is adjusted by changing the height position of the lance 11 by the amount.
- the above-described adjustment of the lance gap G (that is, the speed calculation step, the deviation amount calculation step, and the position adjustment step) may be performed once in one blowing, but may be performed multiple times as necessary. You can also
- the lance 11 has a tendency that when the number of uses N increases, the outlet portion of the nozzle 11A wears and the outlet diameter increases.
- the lance gap G is adjusted on the basis of the dust generation rate GR that also considers the influence of the number of times the lance 11 is used N.
- the converter 10 can be blown with an appropriate lance gap G.
- the amount of dust is excessive due to excessive soft blow (the lance gap G is increased), and the life of the lance 11 is significantly increased due to excessive hard blow (the lance gap G is decreased). It is possible to suppress and further prevent the decrease.
- an Example is a result of having performed the speed calculation process of the above-mentioned embodiment of this indication, the deviation
- the example is a result of adjusting the lance gap based on the estimated hot metal height obtained from the above-described equation (1).
- the water leakage from the lance is caused by the water cooling structure of the lance, and is caused by wear resulting from long-term use of the lance.
- the amount of dust generated is calculated by adding the product of the dust concentration in the collected water measured by the dust concentration measuring device and the amount of water sprayed per unit time (1 second) through one charge. The value was divided by 400 tons.
- the average life was about 300 charges in the example with respect to 250 charges in the comparative example, which was superior to 50 charges.
- the amount of dust generated was reduced by 0.3 to 0.7 kg / ton in the average value of the test charge for one lance in the example, compared to the average value of 15 kg / ton in all the test charges in the comparative example.
- blowing can be performed with an appropriate lance gap, and the amount of dust generated can be reduced while maintaining the lance life.
- the gradient obtained by dividing the change amount of the dust generation speed of the converter by the change amount of the lance gap G is used to correct the deviation amount.
- This gradient is used based on the fact that it is constant regardless of the number of lances used N. For example, the amount of deviation can be corrected using the gradient obtained for each number of lances used.
- the measuring apparatus 20 is equipped with the pump 15 and the vibration-type density meter 16, and collects dust collection water continuously with the pump 15, and uses the vibration-type density meter 16 and the time at that time.
- the dust amount is obtained by continuously measuring the dust concentration in the collected water per unit time according to the relationship with the water temperature
- the present invention is not limited to this configuration.
- the measuring device 20 is further equipped with a thermometer, and the collected water from which the exhaust gas has been wet collected is continuously collected, passed through the vibratory density meter 16 and the thermometer, and measured with the vibratory density meter 16.
- the dust amount may be obtained by calculating the dust concentration in the dust collection water from the difference between the density of the dust collection water and the density of pure water predicted from the temperature of the dust collection water measured with a thermometer. Specifically, the dust concentration is calculated using the following formula (2).
- concentration or density in following formula (2) may be kg / m ⁇ 3 > of this embodiment, and may be g / L or kg / L.
- C ( ⁇ measure ⁇ water) ⁇ ⁇ dust / ( ⁇ dust ⁇ water) (2) However, C is estimated from the dust concentration (kg / m 3 ), ⁇ measure: the density of collected dust water (kg / m 3 ) measured by the vibratory density meter 16, and ⁇ water: the temperature of the collected dust water measured by the thermometer. Density of pure water (kg / m 3 ), ⁇ dust: density of dust particles (for example, 7800 kg / m 3 ). Note that either the vibratory density meter 16 or the thermometer may be upstream or downstream. For example, in the case of using a dust concentration measuring device using ultrasonic waves or light, the dust concentration is estimated from the attenuation rate.
- the measuring device 20 provided with the thermometer is used.
- the density of dust in the collected water, that is, the mass can be directly measured, and the dust particle size is not affected. Therefore, the dust concentration in the dust collecting water can be measured accurately and accurately. Thereby, the blowing of the converter 10 can be carried out with a more appropriate lance gap G.
- Appendix 2 The converter blowing method according to appendix 1, wherein a gradient obtained by dividing the amount of change in dust generation speed of the converter by the amount of change in lance gap is used to correct the deviation amount. Alchemy method.
- the dust generation speed calculated in the speed calculation step with respect to the relationship R1 between the number of times the upper blow lance is used and the dust generation speed when the lance gap is set to an optimum interval is obtained. Since the deviation amount is obtained and the lance gap is adjusted so that the deviation amount obtained in the deviation amount calculation step is corrected from the relationship R2 between the lance gap and each change amount of the dust generation speed in the position adjustment step, an appropriate lance gap is obtained. Can be blown. As a result, excessively soft blow (larger lance gap) results in excessive dust, and excessive hard blow (smaller lance gap) significantly reduces the life of the top blow lance. Can be suppressed and further prevented.
Abstract
Description
一定の送酸速度では、溶銑面とノズル先端との距離であるランスギャップを小さくするほど、酸素ガスが溶銑面に衝突するときの溶銑の形状が滝壺状(断面逆Ω状)となり、発生したダストが飛散せず溶銑内に取り込まれやすくなるため、ダストの発生量を低減することができることが知られている。これをハードブローという。
一方、ランスギャップを小さくし過ぎると、ノズルが溶銑面からの熱影響を強く受けるため、ノズルの損耗が激しくなって、ランスの寿命が短くなることが知られている。このようにランスの寿命が短くなることで、ランスの交換頻度が高くなるため操業に悪影響を及ぼす。 When blowing with an upper blowing lance, the shape of the hot metal surface in the converter changes when oxygen gas collides with the hot metal surface due to the acid feed rate and the lance height (nozzle tip position).
At a constant acid feed rate, the smaller the lance gap, which is the distance between the hot metal surface and the nozzle tip, the hot metal shape when the oxygen gas collides with the hot metal surface becomes a waterfall (reverse Ω-shaped cross section). It is known that the amount of dust generated can be reduced because the generated dust does not scatter and is easily taken into the hot metal. This is called hard blow.
On the other hand, it is known that if the lance gap is made too small, the nozzle is strongly affected by the heat from the hot metal surface, and therefore the wear of the nozzle becomes severe and the life of the lance is shortened. Thus, since the life of the lance is shortened, the frequency of lance replacement is increased, which adversely affects the operation.
ランスギャップを最適な間隔に設定するには、溶銑面の高さを把握する必要があり、その方法としては、例えば、特開平11-52049号公報に開示の技術がある。具体的には、転炉内に、溶銑と、スクラップ又は缶合金(ドラム缶等に入れた合金鉄)を装入した後、転炉上部フードのサブランス孔に設置された移動型のマイクロ波送受信アンテナより、炉内に向けてマイクロ波を送信し、受信した信号から溶銑面の高さ(湯面レベル)を測定する方法である。 From the above, the lance gap has an optimum interval for reducing the amount of dust generated while maintaining the life of the lance, and it is desired to perform blowing by the interval. The optimum interval of the lance gap (hereinafter referred to as “optimum lance gap” as appropriate) is set according to the size of the converter and the acid feed rate.
In order to set the lance gap to an optimum interval, it is necessary to grasp the height of the hot metal surface, and for example, there is a technique disclosed in Japanese Patent Application Laid-Open No. 11-52049. Specifically, a moving microwave transmission / reception antenna installed in the sublance hole of the upper hood of the converter after charging hot metal and scrap or can alloy (alloy iron in a drum can) in the converter In this method, microwaves are transmitted toward the furnace, and the height of the hot metal surface (water surface level) is measured from the received signal.
(推定溶銑面高さ)={(WTn-WT0)/(ρπr0 2)}+l0 ・・・(1)
ここで、ρは鉄比重、r0は溶銑面付近の転炉の断面半径(内径)、l0はマイクロ波溶銑面計による溶銑面高さの測定値、WT0はマイクロ波溶銑面計による測定時の転炉への装入鉄量、WTnは推定溶銑面高さ算出時の転炉への装入鉄量、である。 Therefore, based on the measurement value of the hot metal surface height when actually measured with a microwave hot metal surface meter, the estimated value of the hot metal surface height (estimated hot metal surface height) for each blowing operation when not actually measured is expressed by the following formula ( 1).
(Estimated hot metal surface height) = {(WTn−WT 0 ) / (ρπr 0 2 )} + l 0 (1)
Here, ρ is the iron specific gravity, r 0 is the cross-sectional radius (inner diameter) of the converter near the hot metal surface, 10 is the measured value of the hot metal surface height with a microwave hot metal surface meter, and WT 0 is with the microwave hot metal surface meter. The amount of iron charged to the converter at the time of measurement, WTn is the amount of iron charged to the converter at the time of calculating the estimated hot metal surface height.
ランスギャップの変動によりダストの発生速度が変化することを利用して、ダスト発生速度からランスギャップを推定できる。
ただし、上吹きランスの使用回数が増えると、ランス(ノズル形状)の変形によって噴射される酸素ガスの流れ(酸素ジェット)が変化するため、ランスギャップが一定であってもダスト発生速度が変化する。即ち、ダストの発生速度のみではランスギャップの推定は困難である。
そこで、ランスの使用回数の影響も考慮したダスト発生速度をもとに、ランスギャップを調整する。
本開示は、以上の知見をもとになされたものであり、その要旨は以下の通りである。 As a result of earnestly examining a method for setting an optimal lance gap in a method of charging an upper blowing lance into a converter and performing blowing, the present inventors have found the following knowledge.
The lance gap can be estimated from the dust generation speed by utilizing the fact that the dust generation speed changes due to the fluctuation of the lance gap.
However, as the number of times the top blow lance is used increases, the flow of oxygen gas (oxygen jet) changes due to the deformation of the lance (nozzle shape), so the dust generation speed changes even if the lance gap is constant. . That is, it is difficult to estimate the lance gap only with the dust generation rate.
Therefore, the lance gap is adjusted based on the dust generation speed that also takes into account the influence of the number of times the lance is used.
This indication was made based on the above knowledge, and the summary is as follows.
なお、ダスト濃度測定後の集塵水は下部水槽14へ戻されるようになっている。 Further, as shown in FIG. 1B, the exhaust
Note that the collected water after the dust concentration measurement is returned to the
本実施形態の転炉吹錬方法は、図1A及び図1Bに示されるように、転炉10内にランス11の先端側を挿入し、ランス11のノズル11Aから転炉10内の溶銑面Sに酸素ガスAを吹き付けて脱炭処理する吹錬方法である。そして、この転炉吹錬方法は、吹錬を行う際に、溶銑面Sとランス11の先端との距離であるランスギャップG(図2A参照)を最適な間隔にすることを特徴としている。なお、吹錬は、上吹きのみでなく、底吹きを併用した上底吹きでもよい。 Next, the converter blowing method of this embodiment is demonstrated.
In the converter blowing method of the present embodiment, as shown in FIGS. 1A and 1B, the tip side of the
予め求めた、ランスギャップGを最適な間隔にした際の、ランス11の使用回数とダスト発生速度GRとの関係R1に対する、速度算出工程で算出したダスト発生速度GRのずれ量を求めるずれ量算出工程と、
予め求めた、ランスギャップGの変化量とダスト発生速度GRの変化量との関係R2から、ずれ量算出工程で求めたずれ量を補正するために、上記吹錬中にランスギャップGを調整する位置調整工程と、
を有する方法である。 Specifically, the converter blowing method described above includes a speed calculating step of calculating a dust generation speed GR by obtaining a dust amount in exhaust gas generated during blowing,
Deviation amount calculation for obtaining the deviation amount of the dust generation speed GR calculated in the speed calculation process with respect to the relationship R1 between the number of times the
In order to correct the deviation amount obtained in the deviation amount calculating step from the relationship R2 between the variation amount of the lance gap G and the variation amount of the dust generation speed GR obtained in advance, the lance gap G is adjusted during the blowing. Position adjustment process;
It is the method which has.
なお、上記したコンピュータは、RAM、CPU、ROM、I/O、及び、これらの要素を接続するバスを備えた従来公知のものであるが、これに限定されるものではない。 The speed calculation step, the deviation amount calculation step, and the position adjustment step described above are processed by a computer (calculation means) of an operator who performs the converter operation. Further, the relationship R1 used in the deviation amount calculation step and the relationship R2 used in the position adjustment step are made into a database, for example. The above-mentioned computer receives various information for performing the converter operation, and also controls the converter operation (for example, start and stop of blowing, adjustment of the lance gap G) and the like (that is, the computer controls It becomes a means).
The computer described above is a conventionally known computer including a RAM, a CPU, a ROM, an I / O, and a bus for connecting these elements, but is not limited thereto.
発生したダストは、転炉10から発生した排ガスと共に炉口フード18を通して排ガスダクト12内に吸引され、一次集塵機13から供給される集塵水中に含有されながら、下部水槽14を介して集塵水処理装置へ送られ、分離回収される。なお、一次集塵機13での集塵水の散布により、転炉10から発生したダストは排ガスと分離され、排ガスは下流側へ送られる。 In the converter operation, as shown in FIG. 1A, a
The generated dust is sucked into the
図1Bに示されるように、測定装置20では、ポンプ15により集塵水を連続的に採取し、振動式密度計16を用いて、その時の水温との関係により単位時間当たりの集塵水中のダスト濃度の連続測定を行う。上記した方法で測定したダスト濃度と、集塵水の単位時間当たりの散水量(一次集塵機13からの散水量)との積から、転炉10の吹錬中におけるダスト発生速度を算出できる。 (Calculation method of dust generation rate in converter 10)
As shown in FIG. 1B, in the measuring
図示しないマイクロ波溶銑面計により転炉10(例えば、転炉の溶銑量400トン程度)内の溶銑面Sを測定し、ランス11の使用回数ごとのランスギャップGと、送酸に対して脱炭が優先的に起こる時期である脱炭最盛期の平均ダスト発生速度GRとの関係を見積もると、図3に示す関係が得られる。このランス11の使用回数Nは、転炉10の吹錬の回数に対応している(以下同様)。なお、図3では、ランスの使用回数が50回程度の場合(使用回数が少ない場合:図3中の黒丸印)と、200回程度の場合(使用回数が多い場合:図3中の白丸印)について図示しているが、50~200回の範囲内においても、同様の挙動を示している。
図3に示されるように、ダスト発生速度GRは、ランスギャップG(ここでは、2500~3000mmの範囲)の上昇に伴って直線的に増加し、その関係は、ランス使用回数Nの増加に伴うランス11のノズル11Aの変形によらず、傾きが一定となっている。なお、ここでいう「傾き」とは、ダスト発生速度GRの変化量をランスギャップGの変化量で除した勾配である(すなわち、関係R2)。 (Calculation method of relation R2)
A hot metal surface S in the converter 10 (for example, about 400 tons of molten iron in the converter) is measured by a microwave hot metal surface meter (not shown), and is removed from the lance gap G for each use of the
As shown in FIG. 3, the dust generation rate GR increases linearly as the lance gap G (here, in the range of 2500 to 3000 mm) increases. Regardless of the deformation of the
マイクロ波溶銑面計により転炉10内の溶銑面Sを測定し、ランスギャップGを最適な間隔にした際の、ランス使用回数Nに対する脱炭最盛期のダスト発生速度GRは、図4に示す関係(すなわち、関係R1)となる。
図4に示されるように、ランスギャップGを最適値に設定した場合、ランス使用回数Nの増加に伴ってダスト発生速度GRが増加している。なお、図4に示す曲線は、ダスト発生速度をyとし、ランス使用回数をxとすると、y=6.9492x0.0698、となっている。 (Calculation method of relation R1)
FIG. 4 shows the dust generation rate GR at the peak of decarburization with respect to the lance usage number N when the hot metal surface S in the
As shown in FIG. 4, when the lance gap G is set to an optimum value, the dust generation speed GR increases as the lance usage number N increases. The curve shown in FIG. 4 is y = 6.9492x 0.0698 , where y is the dust generation speed and x is the number of times the lance is used.
まず、前記した式(1)によって求めた推定溶銑面高さを基に、最適なランスギャップGになるようにランス高さを設定して、転炉10の吹錬を実施し、前記した吹錬方法を用い、脱炭最盛期に発生する排ガス中の平均ダスト発生量(ダスト量)を求めて、転炉10のダスト発生速度GRを算出する。 (Speed calculation process)
First, based on the estimated hot metal surface height obtained by the above equation (1), the lance height is set so that the optimum lance gap G is obtained, and the
前記した図4に示す、予め求めた、最適ランスギャップでの上吹きランス11の使用回数と、転炉10のダスト発生速度との関係R1から、速度算出工程で算出した転炉10のダスト発生速度GRがどれだけずれているかを求める。具体的には、ランス使用回数Nに応じて図4から求められるダスト発生速度GRの値と、速度算出工程で算出したダスト発生速度の値との差(即ち、ずれ量)を求める。
ここで、算出したダスト発生速度GRの値が、図4に示すランス使用回数Nに応じたダスト発生速度GRの値よりも低位の場合は、最適ランスギャップGに対して実際のランスギャップGが小さい(ハードブローである)ことを示しているため、ランスギャップGを大きく調整する必要がある。一方、算出したダスト発生速度GRの値が、図4に示すランス使用回数Nに応じたダスト発生速度GRの値よりも高位の場合は、最適ランスギャップGに対して実際のランスギャップGが大きい(ソフトブローである)ことを示しているため、ランスギャップGを小さく調整する必要がある。 (Deviation amount calculation process)
The dust generation of the
Here, when the calculated value of the dust generation speed GR is lower than the value of the dust generation speed GR corresponding to the lance usage number N shown in FIG. Since it shows that it is small (hard blow), the lance gap G needs to be adjusted largely. On the other hand, when the calculated dust generation rate GR is higher than the value of the dust generation rate GR corresponding to the lance usage number N shown in FIG. 4, the actual lance gap G is larger than the optimum lance gap G. (It is a soft blow), it is necessary to adjust the lance gap G small.
前記した図3に示す、予め求めた、ランスギャップGの変化量とダスト発生速度GRの変化量との関係R2から、ずれ量算出工程で求めたずれ量を補正するために、吹錬中にランスギャップGを調整する。なお、本実施形態では、吹錬による脱炭最盛期中にダスト発生速度GRを求めると共にランスギャップGが調整される。 (Position adjustment process)
In order to correct the deviation amount obtained in the deviation amount calculation step from the relationship R2 between the variation amount of the lance gap G and the variation amount of the dust generation speed GR, which is obtained in advance as shown in FIG. Adjust the lance gap G. In the present embodiment, the dust generation speed GR is obtained and the lance gap G is adjusted during the maximum decarburization period by blowing.
なお、上記したランスギャップGの調整(即ち、速度算出工程、ずれ量算出工程、及び、位置調整工程)は、1回の吹錬で1回実施すればよいが、必要に応じて複数回実施することもできる。 Specifically, the deviation amount of the dust generation speed GR obtained in the deviation amount calculation step is divided by the above-described gradient to obtain an adjustment amount of the lance gap G corresponding to the deviation amount of the dust generation speed GR. The lance gap G is adjusted by changing the height position of the
The above-described adjustment of the lance gap G (that is, the speed calculation step, the deviation amount calculation step, and the position adjustment step) may be performed once in one blowing, but may be performed multiple times as necessary. You can also
ここでは、溶銑量が400トン、最適ランスギャップGが3000mmの条件で、転炉の吹錬を行うに際し、実施例と比較例の各方法を適用した結果について説明する。
なお、実施例は、本開示の前記した実施形態の速度算出工程、ずれ量算出工程、及び、位置調整工程を順次行い、ダスト発生速度GRに合わせてランスギャップGを調整した結果であり、比較例は、前記した式(1)から得られる推定溶銑高さを基にランスギャップを調整した結果である。 Next, examples performed for confirming the effects of the present disclosure will be described.
Here, the results of applying each method of the example and the comparative example when performing the blowing of the converter under the conditions of the hot metal amount of 400 tons and the optimum lance gap G of 3000 mm will be described.
In addition, an Example is a result of having performed the speed calculation process of the above-mentioned embodiment of this indication, the deviation | shift amount calculation process, and the position adjustment process one by one, and adjusting the lance gap G according to the dust generation speed GR. The example is a result of adjusting the lance gap based on the estimated hot metal height obtained from the above-described equation (1).
平均寿命は、比較例の250チャージに対して、実施例では約300チャージとなり、50チャージ優位となった。
ダスト発生量は、比較例の全試験チャージの平均値15kg/トンに対して、実施例ではランス1本分の試験チャージの平均値で0.3~0.7kg/トン低減できた。 The evaluation is the average value of the number of charges until water leakage from the lance occurs in the number of trials for 10 times (N = 10) where the number of trials for one lance is 1 (N = 1). It was carried out using the lifetime and the measured dust generation amount (dust amount). The water leakage from the lance is caused by the water cooling structure of the lance, and is caused by wear resulting from long-term use of the lance. The amount of dust generated is calculated by adding the product of the dust concentration in the collected water measured by the dust concentration measuring device and the amount of water sprayed per unit time (1 second) through one charge. The value was divided by 400 tons.
The average life was about 300 charges in the example with respect to 250 charges in the comparative example, which was superior to 50 charges.
The amount of dust generated was reduced by 0.3 to 0.7 kg / ton in the average value of the test charge for one lance in the example, compared to the average value of 15 kg / ton in all the test charges in the comparative example.
C=(ρmeasure-ρwater)×ρdust/(ρdust-ρwater) ・・・(2)
但し、C:ダスト濃度(kg/m3)、ρmeasure:振動式密度計16で測定した集塵水の密度(kg/m3)、ρwater:温度計で測定した集塵水の温度から予測される純水の密度(kg/m3)、ρdust:ダスト粒子の密度(例えば7800kg/m3)。
なお、振動式密度計16と温度計は、どちらが上流でも下流でも構わない。
例えば、超音波や光を用いたダスト濃度測定装置を用いる場合、減衰率からダスト濃度を推定するため、ダスト粒径に影響を受けるが、上記温度計を備えさせた測定装置20を用いることで、集塵水中のダストの密度、すなわち質量を直接測定することができ、ダスト粒径に影響を受けることがない。したがって、精度よく正確に集塵水中のダスト濃度を測定することができるようになる。これにより、より適切なランスギャップGで転炉10の吹錬を実施できるようになる。 Furthermore, in the said embodiment, the measuring
C = (ρmeasure−ρwater) × ρdust / (ρdust−ρwater) (2)
However, C is estimated from the dust concentration (kg / m 3 ), ρmeasure: the density of collected dust water (kg / m 3 ) measured by the
Note that either the
For example, in the case of using a dust concentration measuring device using ultrasonic waves or light, the dust concentration is estimated from the attenuation rate. Therefore, although it is affected by the particle size of the dust, the measuring
転炉内に上吹きランスを装入して吹錬を行う方法において、
前記転炉の吹錬中に発生する排ガス中のダスト量を測定してダスト発生速度を算出する速度算出工程と、
予め求めた、前記転炉内の湯面と前記上吹きランスの先端との距離であるランスギャップを最適な間隔にした際の、前記上吹きランスの使用回数と前記転炉のダスト発生速度との関係R1に対する、前記速度算出工程で算出した前記転炉のダスト発生速度のずれ量を求めるずれ量算出工程と、
予め求めた、前記ランスギャップの変化量と前記転炉のダスト発生速度の変化量との関係R2から、前記ずれ量算出工程で求めた前記ずれ量を補正するために、前記転炉の吹錬中における前記ランスギャップを調整する位置調整工程とを有することを特徴とする転炉吹錬方法。 (Appendix 1)
In the method of charging with the top blowing lance in the converter,
A speed calculating step of calculating a dust generation speed by measuring an amount of dust in exhaust gas generated during blowing of the converter;
The number of times of use of the upper blowing lance and the dust generation rate of the converter when the lance gap, which is the distance between the molten metal surface in the converter and the tip of the upper blowing lance, is set to an optimum interval, A deviation amount calculating step for obtaining a deviation amount of the dust generation speed of the converter calculated in the speed calculating step with respect to the relationship R1;
In order to correct the deviation amount obtained in the deviation amount calculation step from the relationship R2 between the change amount of the lance gap and the change amount of dust generation speed of the converter, which is obtained in advance, the blowing of the converter And a position adjusting step for adjusting the lance gap in the converter.
付記1に記載の転炉吹錬方法において、前記ずれ量の補正に、前記転炉のダスト発生速度の変化量を前記ランスギャップの変化量で除した勾配を用いることを特徴とする転炉吹錬方法。 (Appendix 2)
The converter blowing method according to appendix 1, wherein a gradient obtained by dividing the amount of change in dust generation speed of the converter by the amount of change in lance gap is used to correct the deviation amount. Alchemy method.
これにより、過度にソフトブローになる(ランスギャップが大きくなる)ことでダスト量が過多になることや、過度にハードブローになる(ランスギャップが小さくなる)ことで上吹きランスの寿命を著しく低下させることを抑制、更には防止できる。 In the converter blowing method, in the deviation amount calculation step, the dust generation speed calculated in the speed calculation step with respect to the relationship R1 between the number of times the upper blow lance is used and the dust generation speed when the lance gap is set to an optimum interval is obtained. Since the deviation amount is obtained and the lance gap is adjusted so that the deviation amount obtained in the deviation amount calculation step is corrected from the relationship R2 between the lance gap and each change amount of the dust generation speed in the position adjustment step, an appropriate lance gap is obtained. Can be blown.
As a result, excessively soft blow (larger lance gap) results in excessive dust, and excessive hard blow (smaller lance gap) significantly reduces the life of the top blow lance. Can be suppressed and further prevented.
11 上吹きランス
11A ノズル
16 振動式密度計(密度計)
G ランスギャップ
GR ダスト発生速度
N ランス使用回数 DESCRIPTION OF
G Lance gap GR Dust generation speed N Number of lance usage
Claims (3)
- 上吹きランスのノズルから転炉内の溶銑面に酸素ガスを吹き付ける転炉吹錬方法であって、
吹錬中に発生する排ガス中のダスト量を求めて前記転炉におけるダスト発生速度を算出する速度算出工程と、
予め求めた、前記溶銑面と前記上吹きランスの先端との距離であるランスギャップを最適な間隔にした際の、前記上吹きランスの使用回数と前記ダスト発生速度との関係R1に対する、前記速度算出工程で算出した前記ダスト発生速度のずれ量を求めるずれ量算出工程と、
予め求めた、前記ランスギャップの変化量と前記ダスト発生速度の変化量との関係R2から、前記ずれ量算出工程で求めた前記ずれ量を補正するために、前記吹錬中に前記ランスギャップを調整する位置調整工程と、
を有する転炉吹錬方法。 A converter blowing method in which oxygen gas is blown from the nozzle of the top blowing lance to the hot metal surface in the converter,
A speed calculating step of calculating the dust generation speed in the converter by obtaining the amount of dust in the exhaust gas generated during blowing,
The speed with respect to the relationship R1 between the number of times the upper blowing lance is used and the dust generation speed when the lance gap, which is the distance between the hot metal surface and the tip of the upper blowing lance, is set to an optimum interval. A deviation amount calculating step for obtaining a deviation amount of the dust generation speed calculated in the calculating step;
In order to correct the deviation amount obtained in the deviation amount calculation step from the relationship R2 between the change amount of the lance gap and the change amount of the dust generation speed obtained in advance, the lance gap is changed during the blowing. A position adjustment process to be adjusted;
A converter blowing method. - 前記ずれ量の補正に、前記ダスト発生速度の変化量を前記ランスギャップの変化量で除した勾配を用いる、請求項1に記載の転炉吹錬方法。 The converter blowing method according to claim 1, wherein a gradient obtained by dividing the amount of change in the dust generation rate by the amount of change in the lance gap is used to correct the deviation amount.
- 前記速度算出工程では、前記排ガスを湿式集塵した集塵水を連続的に採取し、密度計及び温度計を通過させ、前記密度計で測定した集塵水の密度と、前記温度計で測定した集塵水の温度から予測される純水の密度との差より、集塵水中のダスト濃度を算出して前記ダスト量を求める、請求項1又は請求項2に記載の転炉吹錬方法。 In the speed calculation step, the collected dust obtained by wet collection of the exhaust gas is continuously collected, passed through a density meter and a thermometer, and measured by the density meter and the density of the collected dust. The converter blowing method according to claim 1 or 2, wherein the dust amount is obtained by calculating a dust concentration in the dust collection water from a difference from a density of pure water predicted from a temperature of the collected dust collection water. .
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