一种采用新横向火焰池窑生产系统的工艺方法所生产的超高铝玻璃制品Ultra-high alumina glass product produced by a process method using a new lateral flame pool kiln production system
【技术领域】[Technical Field]
本发明属于玻璃技术领域,涉及一种采用横向火焰池窑生产系统的工艺方法,所生产的超高铝玻璃制品。The invention belongs to the technical field of glass and relates to a process method using a transverse flame pool kiln production system to produce ultra-high aluminum glass products.
本发明技术方案:Technical solution of the present invention:
属于一种包含制备方法特征的产品权利要求的发明,不但产品比较先有技术对比文件的成份和结构,具有新颖性;而且本发明创新的工艺方法,比先有技术产品,能导致了氧化铝含量达20--49%的玻璃制品内部的微观变化和进步,The invention belongs to a product claim that contains the characteristics of the preparation method. Not only the product has a novel composition and structure compared with the prior art, and the structure is novel; moreover, the innovative process of the present invention can lead to alumina than the prior art product. Microscopic changes and progress inside glass products with a content of 20--49%,
本发明比较先有超高铝玻璃制品,才能真正具有不同的、稳定的-【透光性、高强度、轻薄化、轻量化性能】的玻璃制品内部的微观变化和进步的产品特征。Compared with the ultra-high alumina glass products, the present invention can truly have different and stable-[transmittance, high strength, light-thinning, light-weight performance] inside the glass products of micro changes and improved product characteristics.
本发明【一种采用新横向火焰池窑生产系统的工艺方法,所生产的超高铝玻璃制品】在电子平板玻璃、建筑与工业平板玻璃、玻璃纤维、工业或日用玻璃器皿与器件的领域中,产生了予料不到的技术效果。The present invention [a process method using a new horizontal flame pool kiln production system and ultra-high aluminum glass products produced] in the field of electronic flat glass, architectural and industrial flat glass, glass fiber, industrial or daily glassware and devices In this case, unexpected technical effects were produced.
本发明【一种采用新横向火焰池窑生产系统的工艺方法,所生产的超高铝玻璃制品】代表了这些领域中,一种技术发展趋势;本发明也克服了上述这些用途领域中,人们渴望解决但始终没得获得成功的技术难题。The present invention [a process method using a new transverse flame tank kiln production system, and ultra-high alumina glass products produced] represents a technological development trend in these fields; the present invention also overcomes the above-mentioned fields of use, people Technical problems that are eager to solve but have never been successful.
【先前技术】[Prior art]
(1)先有对比技术1:本发明人的先有发明:有高退火点及环保节能减排的高强度高平整度低粘度特征的平板玻璃的应用及相关部件,专利号201110060944.4。(1) Prior comparative technology 1: The present inventor's prior invention: the application and related components of high-strength, flatness and low-viscosity flat glass with high annealing points, environmental protection, energy saving and emission reduction, patent number 201110060944.4.
(2)先有发明之2:本发明人的201510161553.61,一种具有低热膨胀系数的平板玻璃及其制备工艺。(2) Prior invention 2: 201510161553.61 of the present inventor, a flat glass with a low thermal expansion coefficient and a preparation process thereof.
(3)先有发明之3:本发明人的:PCT/CN2015/000795,一种高温区热膨胀 系数的低差值、低析晶速度、超高强度、高软化点、防火防爆平板玻璃的应用。(3) The third invention: the inventor's: PCT / CN2015 / 000795, an application of low difference in thermal expansion coefficient, low crystallization speed, super high strength, high softening point, fireproof and explosion-proof flat glass in high temperature region .
(4)先有发明之4:本发明人的:PCT/CN2015/000793,一种低析晶温度、低析晶速度、耐高温、特高铝玻璃纤维的应用及其制备方法、复合材料。(4) Invention 4: The present inventor's: PCT / CN2015 / 000793, a low crystallization temperature, low crystallization speed, high temperature resistance, ultra-high aluminum glass fiber application, preparation method thereof, and composite material.
(5)先有发明之5:本发明人的:PCT/CN2015/000794,一种高温区热膨胀系数的低差值、低析晶速度、高软化点、耐高温防爆玻璃器皿或玻璃日用品的应用。(5) Prior Invention No. 5: The inventor's: PCT / CN2015 / 000794, an application of low difference in thermal expansion coefficient, low crystallization speed, high softening point, high temperature resistant explosion-proof glassware or glass daily necessities in high temperature area .
(6)在先有技术中,美国康宁公司的电子平板盖板大猩猩1-4代,15-22%氧化铝;但含氧化钙低于1%,不是在本发明[氧化硅含量是氧化钙含量的2.51-5.8倍,氧化钙含量是氧化镁含量的0.8倍-2.3倍]的范围。(6) In the prior art, Corning Corporation ’s electronic flat-panel cover gorilla 1-4 generations, 15-22% alumina; but containing calcium oxide less than 1%, not in the present invention [silicon oxide content is oxidized The content of calcium is 2.51 to 5.8 times, and the content of calcium oxide is in the range of 0.8 to 2.3 times that of magnesium oxide.
在先有技术中,S级玻纤含23-25-26%氧化铝,----但含氧化钙低于1%,也不是在本发明[氧化硅含量是氧化钙含量的2.51-5.8倍,氧化钙含量是氧化镁含量的0.8倍-2.3倍]的范围。In the prior art, S grade glass fiber contains 23-25-26% alumina, but it contains less than 1% calcium oxide, which is not in the present invention. [The silicon oxide content is 2.51-5.8 of the calcium oxide content Times, the calcium oxide content is in the range of 0.8 to 2.3 times the magnesium oxide content].
而且上述先有技术,在工艺上都采用-只有约10CM直径白金通道技术,产量很小;都不采用本发明的工艺技术生产方法。And the above-mentioned prior arts are all adopted in the process-only about 10CM diameter platinum channel technology, the output is very small; none of the process technology production methods of the present invention.
(7)先有电溶窑工艺技术及火焰窑工艺技术,现有技术的全电熔窑玻璃制品生产装置,主要生产氧化铝含量为1-4%的低铝制品、氧化铝含量为5-9%的中铝制品、氧化铝含量为10-16%的高铝制品。(7) Prior to the electrolysis kiln technology and flame kiln technology, the existing technology of all-electric melting kiln glass production equipment mainly produces low aluminum products with alumina content of 1-4% and alumina content of 5- 9% medium aluminum products, high aluminum products with alumina content of 10-16%.
先有电溶窑工艺技术及火焰窑工艺技术,不具有本发明工艺方法的几个技术要素结抅特征,所以,先有电溶窑技术,不具有克服其技术难点的工艺条件。Prior to the electrolysis kiln technology and flame kiln technology, it did not have the characteristics of several technical elements of the process method of the present invention. Therefore, the prior electrolysis kiln technology did not have the technological conditions to overcome its technical difficulties.
先有电溶窑工艺技术及火焰窑工艺技术,主要考虑了溶化玻璃及排气泡和均化玻璃液,希望形成电极之间的电场[温度场]是均匀的为根本目标。不具有本发明耍求的,在多个区域中的距离底部耐火材5-30CM的区域中的玻璃液的特定区域位置,设计有3-20个电极装置的要求,和不具有本发明耍求的在多个区域 中的,距耐火材料底部5-30CM距离的区域的玻璃液中,最少有100立方CM体积的区间的工作工艺温度,要保持在1320℃-1450℃,要高于距离底部耐火材料30-60CM距离的区域玻璃液的工作工艺温度20-80℃的工艺方法。Prior to the electrolysis kiln process technology and flame kiln process technology, the main considerations were the melting of the glass, the removal of air bubbles, and the homogenization of the glass liquid. It was hoped that the formation of the electric field [temperature field] between the electrodes was uniform. Without the requirements of the present invention, the requirements for the design of 3-20 electrode devices in a specific area of the glass liquid in a region 5-30CM away from the bottom refractory in a plurality of regions, and without the requirements of the present invention The working process temperature of the glass liquid in a region with a distance of 5-30CM from the bottom of the refractory in a plurality of areas with a volume of at least 100 cubic CM must be maintained at 1320 ° C-1450 ° C, which is higher than the distance from the bottom Process method for working glass temperature of refractory within 30-60CM distance from 20-80 ℃.
首先,本发明【一种采用新横向火焰池窑生产系统的工艺方法,所生产的超高铝玻璃制品】与先有发明(1)-(7)的技术方案和任何先有技术方案的成份结构都不同:本发明--按重量百分比计,其氧化铝含量为20%-49%;氧化镁含量为5%--20%,氧化硅含量是氧化钙含量的2.51-5.8倍,氧化钙含量是氧化镁含量的0.8倍-2.3倍;所以本发明具有新颖性。First, the present invention [a process method using a new transverse flame tank kiln production system, ultra-high alumina glass products produced] and the technical solutions of the prior inventions (1)-(7) and the components of any prior technical solutions The structures are different: according to the present invention, the alumina content is 20% -49% by weight percentage; the magnesium oxide content is 5% -20%, the silicon oxide content is 2.51-5.8 times the calcium oxide content, and the calcium oxide content is The content is 0.8 times to 2.3 times the magnesium oxide content; therefore, the present invention is novel.
另外,本发明所述的工艺特点的制备方法,与先有发明(1)-(7)的技术方案和任何先有技术方案也都不同。本发明所述的制备方法特征,才能产生与先有类似产品完全不同的,【玻璃中完全沒有乳白色的富铝条纹或富铝区块,沒有玻璃分层的特征的,氧化铝含量达20--49%的玻璃制品】。In addition, the preparation method of the process features according to the present invention is also different from the technical solutions of the prior inventions (1) to (7) and any of the prior technical solutions. The characteristics of the preparation method described in the present invention can produce completely different from the previous similar products. [The glass has no milky white aluminum-rich stripes or aluminum-rich blocks at all, and the characteristics of glass delamination have no alumina content of 20- -49% glass products].
而如果不采用本发明所述的制备方法特征,氧化铝含量达20--49%的玻璃制品中,就会易于存在乳白色的富铝条纹或乳白色的富铝区块的不透明的重大缺陷,或出现玻璃分层的重大缺陷问题。However, if the characteristics of the preparation method described in the present invention are not adopted, glass products with an alumina content of 20-49% will be susceptible to major defects such as milky white aluminum-rich stripes or opaque aluminum-rich blocks, or Major defects in glass delamination occurred.
【发明内容】[Summary of the Invention]
一种采用新横向火焰池窑生产系统的工艺方法所生产的超高铝玻璃制品Ultra-high alumina glass product produced by a process method using a new lateral flame pool kiln production system
[A]玻璃制品的组成是:按重量百分比计,其氧化铝含量为20%-49%;氧化镁含量为5%--20%,氧化硅含量是氧化钙含量的2.51-5.8倍,氧化钙含量是氧化镁含量的0.8倍-2.3倍;[A] The composition of glass products is: based on weight percentage, its alumina content is 20% -49%; magnesium oxide content is 5% -20%; silicon oxide content is 2.51-5.8 times of calcium oxide content; The calcium content is 0.8 times to 2.3 times the magnesium oxide content;
[B]一种采用新横向火焰池窑生产系统的工艺方法是:[B] A process method using a new horizontal flame pool kiln production system is:
(a)、准备好横向火焰池窑生产系统设备,包括:(a) Prepare the production equipment of the horizontal flame tank kiln, including:
火焰热能主导玻璃熔化的横向火焰池窑结抅装置(10);玻璃液的卡脖流道装置(60);采用电极对从上向下流动的玻璃液进行温度控制的澄清、排气泡和 防析晶装置(30);底部流液通道(20);采用电极,对从下向上流动的玻璃液进行温度控制的玻璃液上升通道结构(40);玻璃制品的成型装置(50):Flame thermal energy dominates glass melting in a transverse flame cell kiln crusting device (10); glass liquid chuck channel device (60); uses electrodes to temperature control the glass liquid flowing from top to bottom to clarify, remove bubbles and Anti-crystallization device (30); bottom flow channel (20); glass liquid ascending channel structure (40) for temperature control of glass liquid flowing from bottom to top using electrodes; molding device (50) for glass products:
其玻璃液的卡脖流道装置(60)中,玻璃液的表面与装置底部之间的深度,是火焰热能主导玻璃熔化的横向火焰池窑结抅装置(10)和采用电极对从上向下流动的玻璃液进行温度控制的澄清、排气泡和防析晶装置(30)中,玻璃液的表面与装置底部之间的深度的10%-40%;玻璃液的卡脖流道装置(60)的距离底部耐火材5-30CM的区域中的玻璃液中,设计有3-20个电极装置;The depth of the glass liquid flow channel device (60) between the surface of the liquid glass and the bottom of the device is the horizontal flame pool kiln crusting device (10) that uses flame thermal energy to dominate glass melting and uses electrode pairs from top to bottom. 10% -40% of the depth between the surface of the glass liquid and the bottom of the device in the device (30) for clarifying, de-airing and anti-crystallization of the glass liquid flowing downward; (60) 3-20 electrode devices are designed in the glass liquid in the area 5-30CM from the bottom refractory;
其采用电极对从上向下流动的玻璃液进行温度控制的澄清、排气泡和防析晶装置(30)的四周设计有4-50个控制玻璃液温度的电极,采用电极对从上向下流动的玻璃液进行温度控制的澄清、排气泡和防析晶装置(30)的距离底部耐火材5-30CM的区域中的玻璃液中,设计有3-20个电极装置;It uses electrodes to control the temperature of the glass liquid flowing from top to bottom to clarify, remove bubbles and prevent the crystallization (30). Around the device is designed 4-50 electrodes to control the temperature of the glass liquid. The glass liquid in the lower flowing glass liquid for temperature control clarification, degassing and anti-crystallizing device (30) is located at a distance of 5-30CM from the bottom refractory, and 3-20 electrode devices are designed;
其底部流液通道(20)的,距离底部耐火材5-30CM的区域中的玻璃液中,设计有3-20个电极装置;3-20 electrode devices are designed in the glass liquid in the bottom liquid flow channel (20) in the area 5-30CM away from the bottom refractory;
其采用电极对从下向上流动的玻璃液进行温度控制的玻璃液上升通道结构--(40)的四周设计有4-50个控制玻璃液温度的电极;上升通道结构(40)的距离底部耐火材5-30CM的区域中的玻璃液中,设计有3-20个电极装置;The glass liquid ascending channel structure adopting electrodes to control the temperature of the glass liquid flowing from bottom to top-(40) is designed with 4-50 electrodes for controlling the temperature of the liquid glass; In the glass liquid in the area of 5-30CM, 3-20 electrode devices are designed;
所需的装置:火焰热能主导玻璃熔化的横向火焰池窑结抅装置(10),玻璃液的卡脖流道装置(60),采用电极对从上向下流动的玻璃液进行温度控制的澄清、排气泡和防析晶装置(30),采用电极对从下向上流动的玻璃液进行温度控制的玻璃液上升通道结构(40),玻璃制品的成型装置(50);这几个装置中的电极能量,都能在玻璃制品的成型装置(50)停止工作时,使各自装置内的玻璃液保持在1300℃以上,並保持在高于玻璃析晶温度之上;Desired devices: flame flame kiln crusting device (10) for glass melting, squeegee channel device (60) for glass liquid, electrode for temperature controlled clarification of glass liquid flowing from top to bottom The device for removing air bubbles and preventing crystallization (30), adopts electrodes to control the temperature of the glass liquid flowing from bottom to top, the glass liquid rising channel structure (40), and the glass product forming device (50); Of the electrode energy, when the glass product forming device (50) stops working, the glass liquid in the respective device is maintained above 1300 ° C and above the glass crystallization temperature;
(b)一种新横向火焰池窑生产系统的工艺方法来生产的超高铝玻璃制品的,工艺过程:(b) A process method of a new horizontal flame pool kiln production system for the production of ultra-high aluminum glass products, the process is as follows:
备好所需的装置:火焰热能主导玻璃熔化的横向火焰池窑结抅装置(10),玻璃液的卡脖流道装置(60),采用电极对从上向下流动的玻璃液进行温度控制的 澄清、排气泡和防析晶装置(30),采用电极对从下向上流动的玻璃液进行温度控制的玻璃液上升通道结构(40),玻璃制品的成型装置(50);这几个装置中的电极能量,都能在玻璃制品的成型装置(50)停止工作时,使各自装置内的玻璃液保持在1300℃以上,並保持在高于玻璃析晶温度之上;Prepare the required devices: the flame heating kiln crusting device (10) for the glass melting, the glass liquid chuck channel device (60), the temperature of the glass liquid flowing from top to bottom is controlled by electrodes Device (30) for clarification, degassing, and anti-crystallization, using electrodes for glass liquid ascending channel structure (40) for temperature control of glass liquid flowing from bottom to top, forming device (50) of glass products; The energy of the electrodes in the device can keep the glass liquid in the respective devices above 1300 ° C and above the glass crystallization temperature when the glass product forming device (50) stops working;
步骤1.把预定的玻璃原料,通过玻璃原料运输装置,进入火焰热能主导玻璃熔化的横向火焰池窑结抅装置(10)中,进行溶化形成玻璃液,玻璃液再通过玻璃液的卡脖流道装置(60),从侧上部进入采用电极,对从上向下流动的玻璃液进行温度控制的澄清、排气泡和防析晶装置(30)中;并使卡脖流道装置(60)和采用电极对从上向下流动的玻璃液进行温度控制的澄清、排气泡和防析晶装置(30)中的玻璃液的温度,控制在高于澄清、排泡10
2帕·秒的粘度温度之上的区间和高于玻璃析晶温度之上的区间;
Step 1. The predetermined glass raw material is passed through a glass raw material transport device into a lateral flame pool kiln crusting device (10) where flame thermal energy predominates glass melting, and is melted to form a glass liquid, and the glass liquid passes through the neck of the glass liquid. Channel device (60), which enters from the upper part of the side into the clarification, bubble removal and anti-crystallization device (30) for controlling the temperature of the glass liquid flowing from top to bottom using electrodes; and the card neck channel device (60) ) And the temperature of the glass liquid in the clarifying, bubble-releasing and crystallizing preventing device (30) controlled by the electrode for the glass liquid flowing from top to bottom, are controlled to be higher than the clarifying and bubble-releasing 10 2 Pa · s Above the viscosity temperature and above the glass crystallization temperature;
工艺特点在于:通过玻璃液的卡脖流道装置(60)的距离底部耐火材5-30CM的区域中的玻璃液中,设计的3-20个电极装置,使卡脖流道装置(60)区域的,距耐火材料底部10-30CM距离的区域的玻璃液中,最少有100立方CM体积的区间的工作工艺温度,要保持在1320℃-1450℃,要高于距离底部耐火材料30-60CM距离的区域玻璃液的工作工艺温度20-80℃;The process is characterized by passing 3 to 20 electrode devices in the glass liquid in the region of the glass liquid in the area of 5-30CM from the bottom refractory through the glass liquid channel device (60), so that the liquid channel device (60) In the region of the glass liquid at a distance of 10-30CM from the bottom of the refractory, the working process temperature of the zone with a volume of at least 100 cubic CM must be maintained at 1320 ℃ -1450 ℃, which is higher than 30-60CM from the bottom refractory The working process temperature of the liquid glass in the distance area is 20-80 ℃;
工艺特点在于:通过从上向下流动的玻璃液进行温度控制的澄清、排气泡和防析晶装置(30)设计的距离底部耐火材5-30CM的区域中的玻璃液中,各自的3-20个电极装置,使从上向下流动的玻璃液进行温度控制的澄清、排气泡和防析晶装置(30)区域的,距耐火材料底部5-30CM距离的区域的玻璃液中,最少有100立方CM体积的区间的工作工艺温度,要保持在1320℃-1450℃,要高于距离底部耐火材料30-60CM距离的区域玻璃液的工作工艺温度20-80℃;The process features: temperature controlled clarification, bubble removal and anti-crystallization equipment (30) designed by glass liquid flowing from top to bottom. The glass liquid in the area 5-30CM away from the bottom refractory, each 3 -20 electrode devices, in the glass liquid in the area of 5-30cm distance from the bottom of the refractory, for the temperature control of the glass liquid flowing from top to bottom for clarification, bubble elimination and anti-crystallization equipment (30), The working process temperature in the area with a minimum volume of 100 cubic CM should be maintained at 1320 ° C-1450 ° C, which is higher than the working process temperature of the glass liquid in the area 30-60CM away from the bottom refractory material 20-80 ° C;
步骤2.使玻璃液从采用电极,对从上向下流动的玻璃液进行温度控制的澄清、排气泡和防析晶装置(30)下部,进入的底部流液通道(20),再进入联结着的一个采用电极对从下向上流动的玻璃液进行温度控制的玻璃液上升通道结构(40);Step 2. Make the glass liquid from the bottom of the liquid flow channel (20) entering the bottom liquid flow channel (20) by using the electrode to lower the temperature of the glass liquid flowing from the top to the bottom, and remove the bubbles. A connected glass liquid ascending channel structure using electrodes for temperature control of glass liquid flowing from bottom to top (40);
工艺特点在于:通过底部流液通道(20)中设计的,距离底部耐火材5-30CM的区域中的玻璃液中,设计的3-20个电极装置,使底部流液通道(20)区域的,距耐火材料底部5-30CM距离的区域的玻璃液中,最少有100立方CM体积的区间的工作工艺温度,要保持在1320℃-1450℃,要高于距离底部耐火材料30-60CM距离的区域玻璃液的工作工艺温度20-80℃;The process is characterized by the design of 3-20 electrode devices in the glass liquid in the bottom liquid flow channel (20), 5-30CM away from the bottom refractory, and the bottom liquid flow channel (20) area. In the glass liquid in the area of 5-30CM distance from the bottom of the refractory material, the working process temperature in the section with a volume of at least 100 cubic CM must be maintained at 1320 ℃ -1450 ℃, which is higher than the distance of 30-60CM from the bottom refractory material. Regional glass liquid working process temperature 20-80 ℃;
工艺特点在于:通过采用电极对从下向上流动的玻璃液进行温度控制的玻璃液上升通道结构(40)中设计的,距离底部耐火材5-30CM的区域中的玻璃液中,设计的3-20个电极装置,使底部流液通道(20)区域的,距耐火材料底部5-30CM距离的区域的玻璃液中,最少有100立方CM体积的区间的工作工艺温度,要保持在1320℃-1450℃,要高于距离底部耐火材料30-60CM距离的区域玻璃液的工作工艺温度20-80℃;The process is characterized by: designed in the glass liquid ascending channel structure (40) for temperature control of glass liquid flowing from bottom to top by using electrodes, in the glass liquid in the area 5-30CM from the bottom refractory, the designed 3- 20 electrode devices, so that the working process temperature of the glass liquid in the area of the bottom flow channel (20), at a distance of 5-30CM away from the bottom of the refractory material, has a volume of at least 100 cubic CM, which must be maintained at 1320 ° C- 1450 ° C, which is 20-80 ° C higher than the working process temperature of the glass liquid in the area 30-60CM away from the bottom refractory;
工艺特点在于:通过其距离底部耐火材5-30CM的区域中的玻璃液中,设计的3-20个电极装置,使底部流液通道(20)区域的,距耐火材料底部5-30CM距离的区域的玻璃液中,最少有100立方CM体积的区间的工作工艺温度,要保持在1320℃-1450℃,要高于距离底部耐火材料30-60CM距离的区域玻璃液的工作工艺温度20-80℃;The process is characterized by the design of 3-20 electrode devices in the glass liquid in the area 5-30CM away from the bottom refractory, so that the bottom liquid flow channel (20) area is 5-30CM away from the bottom of the refractory. In the region of the liquid glass, the working process temperature of the zone with a volume of at least 100 cubic CM must be maintained at 1320 ° C to 1450 ° C, which is higher than the working process temperature of the liquid glass in the area at a distance of 30-60CM from the bottom refractory material. ℃
步骤3.玻璃液再由底部流液通道(20),进入用电极对从下向上流动的玻璃液进行温度控制的玻璃液上升通道结构(40); Step 3. The glass liquid flows from the bottom liquid flow channel (20) and enters the glass liquid rising channel structure (40) for controlling the temperature of the glass liquid flowing from bottom to top with an electrode;
工艺特点在于:通过其距离底部耐火材5-30CM的区域中的玻璃液中,设计的3-20个电极装置,使用电极对从下向上流动的玻璃液进行温度控制的玻璃液上升通道结构(40)区域的,距耐火材料底部5-30CM距离的区域的玻璃液中,最少有100立方CM体积的区间的工作工艺温度,要保持在1320℃-1450℃,要高于距离底部耐火材料30-60CM距离的区域玻璃液的工作工艺温度20-80℃;The process is characterized by a glass liquid ascending channel structure (3-20 electrode devices designed by the glass liquid in the area 5-30CM away from the bottom refractory, using electrodes to temperature control the glass liquid flowing from the bottom up) 40) In the glass liquid in the area with a distance of 5-30CM from the bottom of the refractory material, the working process temperature of the zone with a volume of at least 100 cubic CM must be maintained at 1320 ° C-1450 ° C, which is higher than 30 from the bottom refractory The working process temperature of the glass liquid in the region of -60CM distance is 20-80 ℃;
步骤4.成型工艺的选择:Step 4. Selection of molding process:
第一种玻璃制品成型工艺的选择:前述的经过上升通道结构(40)的顶部出口的玻璃液,进入玻璃制品的成型装置(5);其玻璃制品的成型装置(5)是浮法平板玻璃工艺的锡窑结构;玻璃液进入锡窑结构的平滑的布有溶化的锡金属的平面,进行玻璃液趟平摊薄及抛光;再由两边的10-40对拉边机对形成的玻璃带拉成所需厚度;再经过退火,切材工序,形成浮法平板玻璃制品;或Selection of the first glass product molding process: The aforementioned glass liquid passing through the top outlet of the ascending channel structure (40) enters the glass product molding device (5); the glass product molding device (5) is float plate glass The tin kiln structure of the process; the molten glass enters the flat surface of the tin kiln structure which is melted with tin metal, and the glass liquid is thinned and polished; and then the glass ribbon formed by the pair of 10-40 pairs of edger is pulled on both sides To the required thickness; and then annealing and cutting to form a float plate glass product; or
第二种玻璃制品成型工艺的选择:前述的经过上升通道结构(40)的顶部出口的玻璃液,进入玻璃液的主流道,玻璃液进入联结着有2-30个玻璃液分流道;玻璃液进入各个分流道联结着的玻璃制品的玻璃纤维生产的成型装置;分别流入对应的2-30个承载玻璃液的干埚,玻璃液经过对应的2-30个拉丝板,在对应的拉丝机的作用下形成玻璃纤维;或Selection of the second glass product molding process: the aforementioned glass liquid that passes through the top outlet of the ascending channel structure (40) enters the main channel of the glass liquid, and the glass liquid enters and is connected with 2-30 glass liquid distribution channels; the glass liquid Enter the molding device for glass fiber production of the glass products connected to each of the shunts; flow into the corresponding 2-30 dry pots carrying the glass liquid, and the glass liquid passes through the corresponding 2-30 drawing boards, in the corresponding drawing machine. Forms glass fibers under action; or
第三种玻璃制品成型工艺的选择:前述的经过上升通道结构(40)的顶部出口的玻璃液,进入玻璃液的主流道,玻璃液进入联结着有2-30个玻璃液分流道;玻璃液进入各个分流道联结着的玻璃制品的2-30个工业与日用玻璃器皿的吹制成型装置;分别吹制成工业与日用玻璃的制品;再经过玻璃制品的退火装置的处理,制成工业与日用玻璃的吹制成型制品;或Choice of the third glass product molding process: the aforementioned glass liquid passing through the top outlet of the ascending channel structure (40) enters the main channel of the glass liquid, and the glass liquid enters and is connected with 2-30 glass liquid distribution channels; the glass liquid Enter the 2-30 industrial and daily glassware blow molding devices of the glass products connected to each of the shunts; blow the products of industrial and daily glass separately; and then process them by the annealing device of the glass products. Blow moulded products for industrial and household glass; or
第四种玻璃制品成型工艺的选择:前述的经过上升通道结构(40)的顶部出口的玻璃液,进入玻璃液的主流道,玻璃液进入联结着有2-30个玻璃液分流道;玻璃液进入各个分流道联结着的玻璃制品的2-30个工业与日用玻璃器皿的压制成型装置;分别压制成工业与日用玻璃的制品;再经过玻璃制品的退火装置的处理,制成工业与日用玻璃的压制成型制品;或Choice of the fourth glass product molding process: The aforementioned glass liquid that passes through the top outlet of the ascending channel structure (40) enters the main channel of the glass liquid, and the glass liquid enters and is connected with 2-30 glass liquid branching channels; the glass liquid Enter the 2-30 industrial and daily glassware press forming devices of the glass products connected to each of the shunts; press the products of industrial and daily glass respectively; and then process them by the annealing device of glass products to make industrial and Pressed molded articles of daily glass; or
第五种玻璃制品成型工艺的选择:前述的经过上升通道结构(40)的顶部出口的玻璃液,进入玻璃液的主流道,玻璃液进入联结着有2-30个玻璃液分流道;玻璃液进入各个分流道联结着的玻璃制品的2-30个工业与日用玻璃的拉制成型装置,分别拉制成工业与日用玻璃的制品;再经过玻璃制品的退火装置的处理,制成工业与日用玻璃的拉制成型制品;或Selection of the fifth glass product molding process: The aforementioned glass liquid passing through the top outlet of the ascending channel structure (40) enters the main channel of the glass liquid, and the glass liquid enters and is connected with 2-30 glass liquid branching channels; the glass liquid Enter the 2-30 industrial and daily glass drawing devices of the glass products connected to each of the shunts, draw the industrial and daily glass products respectively; and then process them through the annealing device of the glass products to make Drawn products of industrial and household glass; or
第六种玻璃制品成型工艺的选择:前述的经过上升通道结构(40)的顶部出口的玻璃液,进入玻璃液的主流道,玻璃液进入联结着有2-30个玻璃液分流道;玻璃液进入各个分流道联结着的玻璃制品的2-30个卫浴玻璃制品的吹制成型装置,分别制成卫浴玻璃制品;再经过玻璃制品的退火装置的处理,制成卫浴玻璃制品。Choice of the sixth glass product molding process: The aforementioned glass liquid that has passed through the top outlet of the ascending channel structure (40) enters the main channel of the glass liquid, and the glass liquid enters and is connected with 2-30 glass liquid distribution channels; the glass liquid Enter the blow molding device of 2-30 sanitary glass products connected to the glass products of each shunt, and make sanitary glass products respectively; and then process the annealing device of the glass products to make sanitary glass products.
一种玻璃窗,包含玻璃四周边上安装有树脂边框或金属边框支撑装置;其特征在于:其玻璃是[一种新横向火焰池窑生产系统的工艺方法所生产的超高铝玻璃制品]权利要求1所述的平板玻璃。A glass window comprising a resin frame or a metal frame supporting device installed on the four perimeters of the glass; characterized in that its glass is [an ultra-high aluminum glass product produced by a process method of a new horizontal flame pool kiln production system] The flat glass according to claim 1 is required.
一种彩釉平板玻璃,其特征在于:玻璃表面有1~10种色彩的彩釉层;其玻璃是[一种新横向火焰池窑生产系统的工艺方法所生产的超高铝玻璃制品]权利要求1所述的平板玻璃。A colored glaze flat glass, characterized in that the glass surface has colored glaze layers of 1 to 10 colors; its glass is [an ultra-high aluminum glass product produced by a new horizontal flame pool kiln production system process method] The flat glass according to claim 1 is required.
一种中空玻璃,包含各层玻璃四周边上有支撑装置;各层玻璃之间有3-50mm的经抽真空的隔离空间;其特征在于:其玻璃是[一种新横向火焰池窑生产系统的工艺方法所生产的超高铝玻璃制品]权利要求1所述的平板玻璃。A kind of hollow glass includes support devices on the four perimeters of each layer of glass; there is a vacuum insulation space of 3-50mm between each layer of glass; its characteristics are: its glass is [a new transverse flame tank kiln production system The ultra-high alumina glass products produced by the method] The flat glass according to claim 1.
一种建筑物玻璃幕墙,玻璃被固定在上金属支撑装置上;其特征在于:其玻璃是[一种新横向火焰池窑生产系统的工艺方法所生产的超高铝玻璃制品]权利要求1所述的平板玻璃。A glass curtain wall of a building, the glass is fixed on an upper metal supporting device; characterized in that the glass is [an ultra-high aluminum glass product produced by a process method of a new horizontal flame pool kiln production system] as claimed in claim 1 The described flat glass.
一种超大面积的建筑物薄玻璃窗,其特征在于:其玻璃的厚度为4~10mm,其玻璃的尺寸为3~40平方米,或其玻璃的厚度为.4-20mm,其玻璃的尺寸为15.1~80平方米;其玻璃是[一种新横向火焰池窑生产系统的工艺方法所生产的超高铝玻璃制品]权利要求1所述的平板玻璃。An ultra-large area building with thin glass windows, characterized in that the thickness of its glass is 4 to 10 mm, the size of its glass is 3 to 40 square meters, or the thickness of its glass is .4 to 20 mm, and the size of its glass It is 15.1 to 80 square meters; the glass is the flat glass according to claim 1 [a high-aluminum glass product produced by a process method of a new horizontal flame pool kiln production system].
一种钢化玻璃,其特征在于:玻璃经过化学钢化或物理钢化制成;其玻璃是[一种新横向火焰池窑生产系统的工艺方法所生产的超高铝玻璃制品]权利要求1所述的平板玻璃。A tempered glass, characterized in that the glass is made by chemical tempering or physical tempering; the glass is [ultra-high alumina glass products produced by a new transverse flame tank kiln production system process method] plate glass.
一种钢化玻璃台面家具,特征在于:其台面下部有支撑装置;其玻璃是[一种新横向火焰池窑生产系统的工艺方法所生产的超高铝玻璃制品]权利要求1所述的平板玻璃。A tempered glass countertop furniture, characterized in that: a supporting device is provided below the countertop; and the glass is [a high-aluminum glass product produced by a process method of a new horizontal flame pool kiln production system] the flat glass according to claim 1 .
一种夹胶玻璃,特征在于:其各层玻璃的之间有树脂材料层;其玻璃是[一种新横向火焰池窑生产系统的工艺方法所生产的超高铝玻璃制品]权利要求1所述的平板玻璃。A laminated glass is characterized in that a resin material layer is provided between each layer of the glass; the glass is [an ultra-high aluminum glass product produced by a process method of a new horizontal flame pool kiln production system] The described flat glass.
一种防弹防爆玻璃,特征在于:其各片玻璃板之由树脂片粘合;其玻璃是[一种新横向火焰池窑生产系统的工艺方法所生产的超高铝玻璃制品]权利要求1所述的平板玻璃。A bullet-proof and explosion-proof glass, characterized in that each glass plate is bonded by a resin sheet; and the glass is [an ultra-high aluminum glass product produced by a process method of a new horizontal flame pool kiln production system] The described flat glass.
一种彩釉玻璃板组合橱柜,其特征在于:其玻璃表面或背面有1~10种色彩的彩釉层;彩釉玻璃板组合橱柜平板玻璃四周有金属边框包围;在彩釉玻璃板组合橱柜金属边框之间有金属联接装置;其玻璃是[一种新横向火焰池窑生产系统的工艺方法所生产的超高铝玻璃制品]权利要求1所述的平板玻璃。A color-glazed glass plate combination cabinet is characterized in that: the glass surface has a color glaze layer of 1 to 10 colors on the back surface; the color-glazed glass plate combination cabinet is surrounded by a metal frame around the flat glass; and the color-glazed glass plate combination cabinet There is a metal connecting device between the metal frames; the glass is the flat glass according to claim 1 [a high-aluminum glass product produced by a process method of a new horizontal flame pool kiln production system].
一种彩釉玻璃板组合推拉门柜,其特征在于:组合推拉门柜玻璃表面或背面有1-10种色彩的彩釉层;组合推拉门柜玻璃四周有金属边框;金属边框的上下有滚轮;其玻璃是[一种新横向火焰池窑生产系统的工艺方法所生产的超高铝玻璃制品]权利要求1所述的平板玻璃。A color glaze glass panel combined sliding door cabinet is characterized in that: there are 1-10 colors of colored glaze layers on the surface or back of the combined sliding glass door cabinet; there is a metal frame around the glass of the combined sliding door cabinet glass; there are rollers on the upper and lower sides of the metal frame ; Its glass is the ultra-high alumina glass product produced by a process method of a new horizontal flame pool kiln production system] The flat glass according to claim 1.
一种彩釉玻璃板组合衣柜,其特征在于:玻璃板组合衣柜玻璃表面或背面有1-10种色彩的彩釉层;所述彩釉玻璃四周有金属边框包围,在金属边框之间有金属 联接装置;其玻璃是[一种新横向火焰池窑生产系统的工艺方法所生产的超高铝玻璃制品]权利要求1所述的平板玻璃。A colored-glazed glass-plate combination wardrobe is characterized in that: the glass-plate combined wardrobe has 1-10 colors of colored glaze layers on the surface or back of the glass; the colored-glazed glass is surrounded by a metal frame, and there is metal between the metal frames Coupling device; the glass is the flat glass according to claim 1 [a super high alumina glass product produced by a process method of a new horizontal flame pool kiln production system].
一种彩釉台面玻璃家俱,其特征在于:玻璃台面的表面或背面有1-10种色彩的彩釉层,其台面下部有支撑装置;其玻璃是[一种新横向火焰池窑生产系统的工艺方法所生产的超高铝玻璃制品]权利要求1所述的平板玻璃。A colored glaze countertop glass furniture is characterized in that: there are 1-10 colored glaze layers on the surface or back of the glass countertop, and the lower part of the countertop is provided with a supporting device; the glass is [a new type of horizontal flame pool kiln production system Ultra-high alumina glass product produced by the process method] The flat glass according to claim 1.
一种光伏太阳能装置,其特征在于:光伏太阳能装置包含太阳能电池,以及玻璃基板或外罩板;其玻璃是[一种新横向火焰池窑生产系统的工艺方法所生产的超高铝玻璃制品]权利要求1所述的平板玻璃。A photovoltaic solar device, characterized in that the photovoltaic solar device includes a solar cell, and a glass substrate or a cover plate; and the glass thereof is [an ultra-high aluminum glass product produced by a process method of a new horizontal flame pool kiln production system] The flat glass according to claim 1 is required.
一种薄膜太阳能装置,其特征在于:薄膜太阳能装置包含:薄膜太阳能电池;其玻璃是[一种新横向火焰池窑生产系统的工艺方法所生产的超高铝玻璃制品]权利要求1所述的平板玻璃。A thin-film solar device, characterized in that the thin-film solar device comprises: a thin-film solar cell; and the glass thereof is [an ultra-high aluminum glass product produced by a process method of a new horizontal flame pool kiln production system] according to claim 1 plate glass.
一种液晶显示屏,该液晶显示屏包括:数组基板,该数组基板包括基底,在该基底上的像素结构,该基底为请求项1所述一种组合物在超高氧化铝含量、超高强度、高软化点玻璃的应用;A liquid crystal display screen includes an array substrate including a substrate, a pixel structure on the substrate, and the substrate is a composition according to claim 1 with an ultra-high alumina content and ultra-high Application of strength and high softening point glass;
滤色器基板,该滤色器基板包括基底以及在该基底上的滤色器层,该基底为玻璃基板;A color filter substrate comprising a substrate and a color filter layer on the substrate, the substrate being a glass substrate;
液晶层,夹设在该数组基板和该滤色器基板之间;以及背光源系统;A liquid crystal layer sandwiched between the array substrate and the color filter substrate; and a backlight system;
其特征在于:其玻璃是[一种新横向火焰池窑生产系统的工艺方法所生产的超高铝玻璃制品]权利要求1所述的平板玻璃。It is characterized in that the glass is the flat glass according to claim 1 [ultra-high alumina glass products produced by a process method of a new horizontal flame pool kiln production system].
一种低温多晶硅显示屏,其包括:低温多晶硅数组基板,该数组基板包括基底及在该基底上的采用低温多晶硅工艺生产的像素结构;A low-temperature polysilicon display screen includes a low-temperature polysilicon array substrate including a substrate and a pixel structure produced on the substrate using a low-temperature polysilicon process;
滤色器基板,该滤色器基板包括基底以及在该基底上的滤色器层,该基底为玻璃基板;A color filter substrate comprising a substrate and a color filter layer on the substrate, the substrate being a glass substrate;
液晶层,夹设在该数组基板和该滤色器基板之间;以及A liquid crystal layer sandwiched between the array substrate and the color filter substrate; and
背光源系统;Backlight system;
其特征在于:其玻璃是[一种新横向火焰池窑生产系统的工艺方法所生产的超高铝玻璃制品]权利要求1所述的平板玻璃。It is characterized in that the glass is the flat glass according to claim 1 [ultra-high alumina glass products produced by a process method of a new horizontal flame pool kiln production system].
一种曲面液晶显示屏,A curved LCD screen,
包括:include:
基板玻璃;Substrate glass
数组基板,该数组基板包括基底及在该基底上的像素结构,该基底为玻璃板;An array substrate comprising a substrate and a pixel structure on the substrate, the substrate being a glass plate;
滤色器基板,该滤色器基板包括基底以及在该基底上的滤色器层,该基底为玻璃基板;A color filter substrate comprising a substrate and a color filter layer on the substrate, the substrate being a glass substrate;
液晶层,夹设在该数组基板和该滤色器基板之间;以及背光源系统;A liquid crystal layer sandwiched between the array substrate and the color filter substrate; and a backlight system;
其特征在于:其玻璃是[一种新横向火焰池窑生产系统的工艺方法所生产的超高铝玻璃制品]权利要求1所述的平板玻璃。It is characterized in that the glass is the flat glass according to claim 1 [ultra-high alumina glass products produced by a process method of a new horizontal flame pool kiln production system].
一种显示器正面或后背外壳结构,其特征在于:其玻璃是[一种横向火焰池窑生产系统的工艺方法所生产的超高铝玻璃制品]权利要求1所述的平板玻璃。A front or back shell structure of a display, characterized in that the glass is the flat glass according to claim 1 [a kind of ultra-high aluminum glass product produced by a process method of a transverse flame cell kiln production system].
一种防弹防爆汽车结构,其包含:1~10个车窗的1~3层玻璃,其各片玻璃板之由树脂片粘合;A bullet-proof and explosion-proof automobile structure, comprising: 1 to 3 layers of glass of 1 to 10 car windows, each of which is bonded by a resin sheet;
汽车的四周的金属板或金属架内的有防弹结构;Bulletproof structures in metal plates or metal frames around the car;
以及动力装置;仪表盘;方向控制器;汽车外壳;汽车底盘;汽车刹车装置;汽车轮胎;And power units; dashboards; direction controllers; car shells; car chassis; car brakes; car tires;
其特征在于:其玻璃是[一种新横向火焰池窑生产系统的工艺方法所生产的超高铝玻璃制品]权利要求1所述的平板玻璃。It is characterized in that the glass is the flat glass according to claim 1 [ultra-high alumina glass products produced by a process method of a new horizontal flame pool kiln production system].
一种防抢劫、防盗、防爆、防撞击、防滚翻伤害汽车,其包含:1~10个车窗的1~3层玻璃,防弹玻璃是如请求项1所述一种组合物在超高氧化铝含量、超高强度、高软化点玻璃的应用;以及动力装置;仪表盘;方向控制器;汽车外壳;汽车底盘;汽车刹车装置;汽车轮胎;其特征在于:其玻璃是[一种新横向火焰池窑生产系统的工艺方法所生产的超高铝玻璃制品]权利要求1所述的平板玻璃。An anti-robbery, anti-theft, explosion-proof, anti-impact, anti-rollover injury automobile, comprising: 1 to 3 layers of glass of 1 to 10 windows, and bulletproof glass is a composition as described in claim 1, which is highly oxidized Application of glass with aluminum content, ultra-high strength, and high softening point; and power units; instrument panels; direction controllers; car shells; car chassis; car brakes; car tires; characterized by: its glass is [a new horizontal Ultra-high alumina glass products produced by the process method of a flame tank kiln production system] The flat glass according to claim 1.
一种太阳能飞行器,其包含:具有推动飞行的缧旋桨动力的装置,机翼,驾驶控制系统装置,和一种薄膜太阳能装置,包含:薄膜太阳能电池;薄膜太阳能装置上的基板玻璃;其特征在于:其玻璃是[一种新横向火焰池窑生产系统的工艺方法所生产的超高铝玻璃制品]权利要求1所述的平板玻璃。A solar vehicle includes: a device having propeller power to propel flight, wings, a driving control system device, and a thin-film solar device, including: a thin-film solar cell; a substrate glass on the thin-film solar device; and its characteristics It is that the glass is the flat glass according to claim 1 [a super high alumina glass product produced by a process method of a new horizontal flame pool kiln production system].
一种彩釉平板玻璃与金属层的复合板,包含:其基板玻璃表面有1~10种色彩的彩釉层,0.1~5mm厚度的金属板材,在上述玻璃板和金属板材之间有一层粘合材料层;其特征在于:其玻璃是[一种新横向火焰池窑生产系统的工艺方法所生产的超高铝玻璃制品]权利要求1所述的平板玻璃。A composite plate with colored glaze flat glass and a metal layer, comprising: a glass glaze layer with 1 to 10 colors on the surface of the substrate glass, a metal plate with a thickness of 0.1 to 5 mm, and a layer of adhesion between the glass plate and the metal plate The material layer is characterized in that the glass is the flat glass according to claim 1 [a high-aluminum glass product produced by a process method of a new horizontal flame pool kiln production system].
一种彩釉玻璃复合材料板,包含:其基板玻璃表面有1~10种色彩的彩釉层,0.1~5mm厚度的金属板材,在上述玻璃板和金属板材之间有一层粘合材料层,其特征在于:其制品的复合板的背底面的金属板的2~4条边,比重叠后的表层彩釉装饰平板玻璃制品的边部伸出了10~30mm的距离;其特征在于:其玻璃是[一种新横向火焰池窑生产系统的工艺方法所生产的超高铝玻璃制品]权利要求1所述的平板玻璃。A colored glaze glass composite material plate comprises: a glass glaze layer with 1 to 10 colors on the substrate glass surface, a metal plate with a thickness of 0.1 to 5 mm, and a layer of adhesive material between the glass plate and the metal plate. It is characterized in that the 2 to 4 sides of the metal plate on the back bottom surface of the composite plate of the product protrude by a distance of 10 to 30 mm from the edge portion of the superimposed colored glaze decorative flat glass product; it is characterized in that: The glass is the flat glass according to claim 1 [a high-aluminum glass product produced by a process method of a new transverse flame cell kiln production system].
一种彩釉玻璃复合材料地板,包含:其底板层,或者是木材板;或者是金属材料板;或者是木板复合板;或者是木粉粒复合板;或者是树脂材料板;其特征在于:其玻璃是[一种新横向火焰池窑生产系统的工艺方法所生产的超高铝玻璃制品]权利要求1所述的平板玻璃。A colored glaze glass composite material floor comprises: a base layer thereof, or a wood board; or a metal material board; or a wood board composite board; or a wood flour particle composite board; or a resin material board; its characteristics are: The glass is the flat glass according to claim 1 [a high-aluminum glass product produced by a process method of a new transverse flame cell kiln production system].
一种玻璃洗面盆结构,其特征在于:其玻璃是[一种新横向火焰池窑生产系统的工艺方法所生产的超高铝玻璃制品]权利要求1所述的玻璃。A glass washbasin structure, characterized in that the glass is the glass according to claim 1 [a high-aluminum glass product produced by a process method of a new horizontal flame pool kiln production system].
一种玻璃抬面板和联体的洗面盆,其结构特征在于,1.平面型状的玻璃抬面板,2.其联体的另一个部分,是玻璃洗面盆;其特征在于:其玻璃是[一种新横向火焰池窑生产系统的工艺方法所生产的超高铝玻璃制品]权利要求1所述的玻璃。The utility model relates to a glass lifting panel and a combined wash basin, which are characterized in that: 1. a flat glass lifting panel; 2. another part of the combination is a glass wash basin; the feature is that the glass is [ Ultra-high alumina glass product produced by a process method of a new transverse flame pool kiln production system] The glass according to claim 1.
一种阳台保护拦的超长玻璃板,其阳台保护拦的玻璃板的长度为3~8m;其特征在于:其玻璃是[一种新横向火焰池窑生产系统的工艺方法所生产的超高铝玻璃制品]权利要求1所述的平板玻璃。The utility model relates to an ultra-long glass plate of a balcony protection bar. The length of the glass plate of the balcony protection bar is 3 to 8m. It is characterized in that the glass is an ultra-high glass produced by a process method of a new horizontal flame pool kiln production system. Aluminum glass products] The flat glass according to claim 1.
一种防弹建筑物结构,包括:墙面结构、地面结构、屋顶面结构、门结构、玻璃窗结构,玻璃窗结构的防弹玻璃或者门结构中的防弹玻璃;其特征在于:其玻璃是[一种新横向火焰池窑生产系统的工艺方法所生产的超高铝玻璃制品]权利要求1所述的平板玻璃。A bullet-proof building structure includes: a wall structure, a ground structure, a roof structure, a door structure, a glass window structure, a bullet-proof glass in a glass window structure, or a bullet-proof glass in a door structure; characterized in that its glass is [一Ultra-high alumina glass product produced by a process method of a new transverse flame pool kiln production system] The flat glass according to claim 1.
一种显示器的玻璃后背外壳,其玻璃后背外壳或为平面状,其玻璃后背外壳或为3D的曲面形状,其玻璃后背外壳上附着了一层彩色釉料层,或附着了具有光栅特征的结构层;其特征在于:其玻璃是[一种新横向火焰池窑生产系统的工艺方法所生产的超高铝玻璃制品]权利要求1所述的平板玻璃。A glass back shell of a display, the glass back shell is flat, the glass back shell is a 3D curved shape, and a glass glaze layer is attached to the glass back shell, or The structural layer of the grating feature; characterized in that the glass is the flat glass according to claim 1 [an ultra-high alumina glass product produced by a process method of a new horizontal flame pool kiln production system].
一种显示器结构中的玻璃后背外壳结构,其玻璃后背外壳或为平面状,其玻璃后背外壳或为3D的曲面形状,其玻璃后背外壳上附着了一层彩色釉料层,或附 着了具有光栅特征的结构层;其特征在于:其玻璃是[一种新横向火焰池窑生产系统的工艺方法所生产的超高铝玻璃制品]权利要求1所述的玻璃。A glass back shell structure in a display structure, the glass back shell is flat, the glass back shell is a 3D curved shape, and a glass glaze layer is attached to the glass back shell, or A structure layer with a grating feature is attached; the glass is an ultra-high alumina glass product produced by the process method of a new transverse flame tank kiln production system].
一种玻璃纤维复合材料,包含:塑料基体,以及嵌入塑料基体中的玻璃纤维;其特征在于:其玻璃纤维是[一种新横向火焰池窑生产系统的工艺方法所生产的超高铝玻璃制品]权利要求1所述的玻璃。A glass fiber composite material includes: a plastic matrix and glass fibers embedded in the plastic matrix; the glass fiber is an ultra-high aluminum glass product produced by a process method of a new horizontal flame pool kiln production system The glass according to claim 1.
一种风电用玻璃纤维复合材料叶片,包含:塑料基体,以及嵌入塑料基体中的玻璃纤维,所制造的复合材料,制成的风电用叶片;A glass fiber composite material blade for wind power includes a plastic substrate and glass fiber embedded in the plastic substrate, a composite material manufactured by the same, and a blade for wind power production;
风叶片组成:玻璃纤维复合材料风叶片叶壳;玻璃纤维复合材料风叶片叶根;玻璃纤维复合材料风叶片结构大梁;Wind blade composition: glass fiber composite wind blade leaf shell; glass fiber composite wind blade blade root; glass fiber composite wind blade structure beam;
其特征在于:其玻璃纤维是[一种新横向火焰池窑生产系统的工艺方法所生产的超高铝玻璃制品]权利要求1所述的玻璃。It is characterized in that the glass fiber is the glass according to claim 1 [ultra-high alumina glass product produced by a process method of a new horizontal flame pool kiln production system].
一种玻璃纤维复合材料飞行器壳体,包含:塑料基体,以及嵌入塑料基体中的玻璃纤维,所制造的复合材料,制成的飞行器壳体结构;其特征在于:其玻璃纤维是[一种新横向火焰池窑生产系统的工艺方法所生产的超高铝玻璃制品]权利要求1所述的玻璃。A glass fiber composite material aircraft shell includes: a plastic matrix and glass fiber embedded in the plastic matrix, a composite material manufactured by the aircraft, and an aircraft shell structure; characterized in that its glass fiber is [A new Ultra-high alumina glass products produced by the process method of a transverse flame cell kiln production system] The glass according to claim 1.
一种玻璃纤维复合材料结构的水上船舶,A marine vessel with a glass fiber composite material structure,
包含塑料基体,以及Contains a plastic matrix, and
嵌入塑料基体中的玻璃纤维,所制造的复合材料,制成的船体结构;动力装置;驾驶舱;船甲板;Glass fiber embedded in plastic matrix, composite materials manufactured, hull structure made; power plant; cockpit; ship deck;
其特征在于:其玻璃纤维是[一种新横向火焰池窑生产系统的工艺方法所生产的超高铝玻璃制品]权利要求1所述的玻璃。It is characterized in that the glass fiber is the glass according to claim 1 [ultra-high alumina glass product produced by a process method of a new horizontal flame pool kiln production system].
一种玻璃纤维复合材料化工管结构,包含塑料基体,以及嵌入塑料基体中的玻璃纤维,所制造的复合材料,制成的化工或石油管或天然气复合材料管道;A glass fiber composite material chemical pipe structure includes a plastic matrix and glass fibers embedded in the plastic matrix, a manufactured composite material, and a chemical or petroleum pipe or a natural gas composite pipe;
其特征在于:其玻璃纤维是[一种新横向火焰池窑生产系统的工艺方法所生产的超高铝玻璃制品]权利要求1所述的玻璃。It is characterized in that the glass fiber is the glass according to claim 1 [ultra-high alumina glass product produced by a process method of a new horizontal flame pool kiln production system].
一种玻璃纤维复合材料壳体或底盘的汽车,其包含:塑料基体,以及,嵌入塑料基体中的玻璃纤维所制造的车辆壳体或汽车底盘;汽车窗结构;以及动力装置;仪表盘;方向控制器;汽车外壳;汽车底盘;汽车刹车装置;汽车轮胎;其特征在于:其玻璃纤维是[一种新横向火焰池窑生产系统的工艺方法所生产的超高铝玻璃制品]权利要求1所述的玻璃。A glass fiber composite material shell or chassis automobile includes a plastic substrate and a vehicle shell or vehicle chassis made of glass fiber embedded in the plastic substrate; a car window structure; and a power unit; an instrument panel; an orientation Controller; automobile casing; automobile chassis; automobile brake device; automobile tire; characterized in that its glass fiber is [an ultra-high aluminum glass product produced by a process method of a new transverse flame pool kiln production system] Mentioned glass.
一种风力发电装置结构,其包含:风叶片包含塑料基体,以及嵌入塑料A wind power generation device structure includes: a wind blade includes a plastic substrate and embedded plastic
基体中的的玻璃纤维,所制造的复合材料制成的风电叶片;还包括轴承;发电机;风电塔支柱;其特征在于:其玻璃纤维是[一种新横向火焰池窑生产系统的工艺方法所生产的超高铝玻璃制品]权利要求1所述的玻璃。The glass fiber in the matrix, the wind power blade made of the composite material manufactured; also includes bearings; generators; wind power tower pillars; characterized in that its glass fiber is [a new process method of a new transverse flame pond kiln production system Produced ultra-high alumina glass article] The glass according to claim 1.
一种日用器皿玻璃与工业用玻璃制品,其特征在于:其玻璃是[一种横A daily-use glass and industrial glass product is characterized in that its glass is [A horizontal
向火焰池窑生产系统的工艺方法所生产的超高铝玻璃制品权利要求1所述的玻璃]。The ultra-high alumina glass product produced by the process method of the flame tank kiln production system is the glass according to claim 1].
一种玻璃绝缘子制品,其特征在于:其玻璃纤维是[一种新横向火焰池窑生产系统的工艺方法所生产的超高铝玻璃制品]权利要求1所述的玻璃。A glass insulator product, characterized in that the glass fiber is the glass according to claim 1 [a high-aluminum glass product produced by a process method of a new horizontal flame pool kiln production system].
一种玻璃坐便器制品,其特征在于:其玻璃是[一种新横向火焰池窑生产系统的工艺方法所生产的超高铝玻璃制品]权利要求1所述的玻璃。A glass toilet product, characterized in that its glass is the glass according to claim 1 [a high-aluminum glass product produced by a process method of a new horizontal flame pool kiln production system].
附图说明BRIEF DESCRIPTION OF THE DRAWINGS
图1和摘要附图,是本发明一种采用新横向火焰池窑生产系统的工艺方法所 生产的超高铝玻璃制品,的平板玻璃产品的平面示意图;1 and the accompanying drawings are schematic plan views of flat glass products of ultra-high alumina glass products produced by a process method using a new lateral flame pool kiln production system according to the present invention;
图2是本发明一种采用新横向火焰池窑生产系统的工艺方法所生产的超高铝玻璃制品,的玻璃纤维产品的切面示意图;2 is a schematic cross-sectional view of a glass fiber product of ultra-high aluminum glass products produced by a process method using a new transverse flame tank kiln production system according to the present invention;
图3是本发明一种采用新横向火焰池窑生产系统的工艺方法所生产的超高铝玻璃制品,的吹制玻璃产品的剖面示意图;3 is a cross-sectional schematic view of a blown glass product of ultra-high alumina glass products produced by a process method using a new transverse flame pool kiln production system according to the present invention;
图4是本发明一种采用新横向火焰池窑生产系统的工艺方法所生产的超高铝玻璃制品,的拉制玻璃管产品的剖面示意图;4 is a schematic cross-sectional view of a drawn glass tube product of ultra-high aluminum glass products produced by a process method using a new transverse flame tank kiln production system according to the present invention;
图5是本发明一种采用新横向火焰池窑生产系统的工艺方法所生产的超高铝玻璃制品,的压制玻璃产品的剖面示意图;5 is a schematic cross-sectional view of a pressed glass product of ultra-high alumina glass products produced by a process method using a new lateral flame pool kiln production system according to the present invention;
图6是本发明一种采用新横向火焰池窑生产系统的工艺方法所生产的超高铝玻璃制品,的工艺方法的设备组成的侧剖面示意图。FIG. 6 is a schematic side sectional view of the equipment composition of a process method for ultra-high aluminum glass products produced by a process method using a new transverse flame tank kiln production system according to the present invention.
图7是本发明一种采用新横向火焰池窑生产系统的工艺方法所生产的超高铝玻璃制品的浮法玻璃制备工艺的流程示意图。FIG. 7 is a schematic flow chart of a float glass manufacturing process for ultra-high alumina glass products produced by a process method using a new lateral flame pool kiln production system according to the present invention.
图8是本发明一种采用新横向火焰池窑生产系统的工艺方法所生产的超高铝玻璃制品的玻璃纤维制备工艺的流程示意图。FIG. 8 is a schematic flow chart of a glass fiber preparation process for an ultra-high alumina glass product produced by a process method using a new transverse flame tank kiln production system according to the present invention.
图9是本发明一种采用新横向火焰池窑生产系统的工艺方法所生产的超高铝玻璃制品的底部流液通道(20)的切面图。FIG. 9 is a cross-sectional view of a bottom flow channel (20) of an ultra-high alumina glass product produced by a process method using a new transverse flame tank kiln production system according to the present invention.
符号说明Symbol Description
图6是本发明一种采用新横向火焰池窑生产系统的工艺方法所生产的超高铝玻璃制品,的工艺方法的设备组成的侧剖面示意图:FIG. 6 is a schematic side sectional view of the equipment composition of a process method for ultra-high alumina glass products produced by a process method using a new transverse flame tank kiln production system according to the present invention:
符号10表示火焰热能主导玻璃熔化的横向火焰池窑结抅装置;The symbol 10 represents a lateral flame pool kiln crusting device in which flame heat dominates glass melting;
符号60表示,玻璃液的卡脖流道装置;The symbol 60 represents a device for clamping the channel of the liquid glass;
符号30表示采用电极对从上向下流动的玻璃液进行温度控制的装置; Symbol 30 denotes a device for controlling the temperature of the glass liquid flowing from the top to the bottom by using an electrode;
符号40表示采用电极,对从下向上流动的玻璃液进行温度控制的玻璃液上升通道结构; Symbol 40 represents a glass liquid ascending channel structure that uses electrodes to control the temperature of the glass liquid flowing from bottom to top;
符号20符号表示底部流液通道;The symbol 20 indicates the bottom flow channel;
符号50表示,玻璃制品的成型装置; Reference numeral 50 denotes a molding device for glass products;
符号8表示玻璃液中的电极(8);The symbol 8 represents the electrode (8) in the glass liquid;
符号9表示玻璃液上层面空间的电加热装置(9);The symbol 9 represents the electric heating device (9) of the upper space of the glass liquid;
图7是本发明一种采用新横向火焰池窑生产系统的工艺方法所生产的超高铝玻璃制品的浮法玻璃制备工艺的流程示意图:FIG. 7 is a schematic flow chart of a float glass preparation process for ultra-high aluminum glass products produced by a process method using a new transverse flame pool kiln production system according to the present invention:
符号10表示火焰热能主导玻璃熔化的横向火焰池窑结抅装置;The symbol 10 represents a lateral flame pool kiln crusting device in which flame heat dominates glass melting;
符号60表示,玻璃液的卡脖流道装置;The symbol 60 represents a device for clamping the channel of the liquid glass;
符号30表示采用电极对从上向下流动的玻璃液进行温度控制的装置; Symbol 30 denotes a device for controlling the temperature of the glass liquid flowing from the top to the bottom by using an electrode;
符号40表示采用电极,对从下向上流动的玻璃液进行温度控制的玻璃液上升通道结构; Symbol 40 represents a glass liquid ascending channel structure that uses electrodes to control the temperature of the glass liquid flowing from bottom to top;
符号20符号表示底部流液通道;The symbol 20 indicates the bottom flow channel;
符号50表示,玻璃制品的成型装置。 Reference numeral 50 denotes a molding device for glass products.
图8是本发明一种采用新横向火焰池窑生产系统的工艺方法所生产的超高铝玻璃制品的玻璃纤维制备工艺的流程示意图:FIG. 8 is a schematic flowchart of a glass fiber preparation process for ultra-high alumina glass products produced by a process method using a new transverse flame tank kiln production system according to the present invention:
符号10表示火焰热能主导玻璃熔化的横向火焰池窑结抅装置;The symbol 10 represents a lateral flame pool kiln crusting device in which flame heat dominates glass melting;
符号60表示,玻璃液的卡脖流道装置;The symbol 60 represents a device for clamping the channel of the liquid glass;
符号30表示采用电极对从上向下流动的玻璃液进行温度控制的装置; Symbol 30 denotes a device for controlling the temperature of the glass liquid flowing from the top to the bottom by using an electrode;
符号40表示采用电极,对从下向上流动的玻璃液进行温度控制的玻璃液上升 通道结构的玻璃液; Reference numeral 40 denotes a glass liquid that uses an electrode to control the temperature of the glass liquid flowing from bottom to top, and a glass liquid having a channel structure;
符号20符号表示底部流液通道(20);The symbol 20 indicates the bottom flow channel (20);
符号50表示,玻璃纤维制品的成型装置。 Reference numeral 50 denotes a molding apparatus for a glass fiber product.
具体实施方式Detailed ways
以下参照图式说明本发明之实施例,应注意的是,以下图式系为简化之示意图式,而仅以示意方式说明本发明之基本构想,遂图式中仅例示与本发明有关之结构而非按照实际实施时之组件数目、形状及尺寸绘制,其实际实施时各组件之型态、数量及比例并非以图示为限,可依实际设计需要作变化,合先叙明。The embodiments of the present invention will be described below with reference to the drawings. It should be noted that the following drawings are simplified schematic diagrams, and the basic concept of the present invention is illustrated only in a schematic manner. Only the structures related to the present invention are illustrated in the drawings. Rather than drawing according to the number, shape and size of the components during actual implementation, the type, quantity and ratio of each component during actual implementation are not limited to the illustrations, and can be changed according to the actual design needs, which will be described first.
本发明,一种采用新横向火焰池窑生产系统的工艺方法所生产的超高铝玻璃制品实施例:In the present invention, an embodiment of an ultra-high aluminum glass product produced by a process method using a new transverse flame pool kiln production system:
[A]玻璃制品的组成是:按重量百分比计,其氧化铝含量为20%-49%;氧化镁含量为5%--20%,氧化硅含量是氧化钙含量的2.51-5.8倍,氧化钙含量是氧化镁含量的0.8倍-2.3倍;[A] The composition of glass products is: based on weight percentage, its alumina content is 20% -49%; magnesium oxide content is 5% -20%; silicon oxide content is 2.51-5.8 times of calcium oxide content; The calcium content is 0.8 times to 2.3 times the magnesium oxide content;
[B]一种采用新横向火焰池窑生产系统的工艺方法是:[B] A process method using a new horizontal flame pool kiln production system is:
(a)、准备好横向火焰池窑生产系统设备,包括:(a) Prepare the production equipment of the horizontal flame tank kiln, including:
火焰热能主导玻璃熔化的横向火焰池窑结抅装置(10);玻璃液的卡脖流道装置(60);采用电极对从上向下流动的玻璃液进行温度控制的澄清、排气泡和防析晶装置(30);底部流液通道(20);采用电极,对从下向上流动的玻璃液进行温度控制的玻璃液上升通道结构(40);玻璃制品的成型装置(50):Flame thermal energy dominates glass melting in a transverse flame cell kiln crusting device (10); glass liquid chuck channel device (60); uses electrodes to temperature control the glass liquid flowing from top to bottom to clarify, remove bubbles and Anti-crystallization device (30); bottom flow channel (20); glass liquid ascending channel structure (40) for temperature control of glass liquid flowing from bottom to top using electrodes; molding device (50) for glass products:
其玻璃液的卡脖流道装置(60)中,玻璃液的表面与装置底部之间的深度,是火焰热能主导玻璃熔化的横向火焰池窑结抅装置(10)和采用电极对从上向下流动的玻璃液进行温度控制的澄清、排气泡和防析晶装置(30)中,玻璃液的表面与 装置底部之间的深度的10%-40%;玻璃液的卡脖流道装置(60)的距离底部耐火材5-30CM的区域中的玻璃液中,设计有3-20个电极装置;The depth of the glass liquid flow channel device (60) between the surface of the liquid glass and the bottom of the device is the horizontal flame pool kiln crusting device (10) that uses flame thermal energy to dominate glass melting and uses electrode pairs from top to bottom. 10% -40% of the depth between the surface of the glass liquid and the bottom of the device in the device (30) for clarifying, de-airing and anti-crystallization of the glass liquid flowing downward; (60) 3-20 electrode devices are designed in the glass liquid in the area 5-30CM from the bottom refractory;
其采用电极对从上向下流动的玻璃液进行温度控制的澄清、排气泡和防析晶装置(30)的四周设计有4-50个控制玻璃液温度的电极,采用电极对从上向下流动的玻璃液进行温度控制的澄清、排气泡和防析晶装置(30)的距离底部耐火材5-30CM的区域中的玻璃液中,设计有3-20个电极装置;It uses electrodes to control the temperature of the glass liquid flowing from top to bottom to clarify, remove bubbles and prevent the crystallization (30). Around the device is designed 4-50 electrodes to control the temperature of the glass liquid. The glass liquid in the lower flowing glass liquid for temperature control clarification, degassing and anti-crystallizing device (30) is located at a distance of 5-30CM from the bottom refractory, and 3-20 electrode devices are designed;
其底部流液通道(20)的,距离底部耐火材5-30CM的区域中的玻璃液中,设计有3-20个电极装置;3-20 electrode devices are designed in the glass liquid in the bottom liquid flow channel (20) in the area 5-30CM away from the bottom refractory;
其采用电极对从下向上流动的玻璃液进行温度控制的玻璃液上升通道结构--(40)的四周设计有4-50个控制玻璃液温度的电极;上升通道结构(40)的距离底部耐火材5-30CM的区域中的玻璃液中,设计有3-20个电极装置;The glass liquid ascending channel structure adopting electrodes to control the temperature of the glass liquid flowing from bottom to top-(40) is designed with 4-50 electrodes for controlling the temperature of the liquid glass; In the glass liquid in the area of 5-30CM, 3-20 electrode devices are designed;
所需的装置:火焰热能主导玻璃熔化的横向火焰池窑结抅装置(10),玻璃液的卡脖流道装置(60),采用电极对从上向下流动的玻璃液进行温度控制的澄清、排气泡和防析晶装置(30),采用电极对从下向上流动的玻璃液进行温度控制的玻璃液上升通道结构(40),玻璃制品的成型装置(50);这几个装置中的电极能量,都能在玻璃制品的成型装置(50)停止工作时,使各自装置内的玻璃液保持在1300℃以上,並保持在高于玻璃析晶温度之上;Desired devices: flame flame kiln crusting device (10) for glass melting, squeegee channel device (60) for glass liquid, electrode for temperature controlled clarification of glass liquid flowing from top to bottom The device for removing air bubbles and preventing crystallization (30), adopts electrodes to control the temperature of the glass liquid flowing from bottom to top, the glass liquid rising channel structure (40), and the glass product forming device (50); Of the electrode energy, when the glass product forming device (50) stops working, the glass liquid in the respective device is maintained above 1300 ° C and above the glass crystallization temperature;
(b)一种新横向火焰池窑生产系统的工艺方法来生产的超高铝玻璃制品的,工艺过程:(b) A process method of a new horizontal flame pool kiln production system for the production of ultra-high aluminum glass products, the process is as follows:
备好所需的装置:火焰热能主导玻璃熔化的横向火焰池窑结抅装置(10),玻璃液的卡脖流道装置(60),采用电极对从上向下流动的玻璃液进行温度控制的澄清、排气泡和防析晶装置(30),采用电极对从下向上流动的玻璃液进行温度控制的玻璃液上升通道结构(40),玻璃制品的成型装置(50);这几个装置中的电极能量,都能在玻璃制品的成型装置(50)停止工作时,使各自装置内的玻璃液保持在1300℃以上,並保持在高于玻璃析晶温度之上;Prepare the required devices: the flame heating kiln crusting device (10) for the glass melting, the glass liquid chuck channel device (60), the temperature of the glass liquid flowing from top to bottom is controlled by electrodes Device (30) for clarification, degassing, and anti-crystallization, using electrodes for glass liquid ascending channel structure (40) for temperature control of glass liquid flowing from bottom to top, forming device (50) of glass products; The energy of the electrodes in the device can keep the glass liquid in the respective devices above 1300 ° C and above the glass crystallization temperature when the glass product forming device (50) stops working;
步骤1.把预定的玻璃原料,通过玻璃原料运输装置,进入火焰热能主导玻璃熔化的横向火焰池窑结抅装置(10)中,进行溶化形成玻璃液,玻璃液再通过玻璃液的卡脖流道装置(60),从侧上部进入采用电极,对从上向下流动的玻璃液进行温度控制的澄清、排气泡和防析晶装置(30)中;并使卡脖流道装置(60)和采用电极对从上向下流动的玻璃液进行温度控制的澄清、排气泡和防析晶装置(30)中的玻璃液的温度,控制在高于澄清、排泡10
2帕·秒的粘度温度之上的区间和高于玻璃析晶温度之上的区间;
Step 1. The predetermined glass raw material is passed through a glass raw material transport device into a lateral flame pool kiln crusting device (10) where flame thermal energy predominates glass melting, and is melted to form a glass liquid, and the glass liquid passes through the neck of the glass liquid. Channel device (60), which enters from the upper part of the side into the clarification, bubble removal and anti-crystallization device (30) for controlling the temperature of the glass liquid flowing from top to bottom using electrodes; and the card neck channel device (60) ) And the temperature of the glass liquid in the clarifying, bubble-releasing and crystallizing preventing device (30) controlled by the electrode for the glass liquid flowing from top to bottom, are controlled to be higher than the clarifying and bubble-releasing 10 2 Pa · s Above the viscosity temperature and above the glass crystallization temperature;
工艺特点在于:通过玻璃液的卡脖流道装置(60)的距离底部耐火材5-30CM的区域中的玻璃液中,设计的3-20个电极装置,使卡脖流道装置(60)区域的,距耐火材料底部10-30CM距离的区域的玻璃液中,最少有100立方CM体积的区间的工作工艺温度,要保持在1320℃-1450℃,要高于距离底部耐火材料30-60CM距离的区域玻璃液的工作工艺温度20-80℃;The process is characterized by passing 3 to 20 electrode devices in the glass liquid in the region of the glass liquid in the area of 5-30CM from the bottom refractory through the glass liquid channel device (60), so that the liquid channel device (60) In the region of the glass liquid at a distance of 10-30CM from the bottom of the refractory, the working process temperature of the zone with a volume of at least 100 cubic CM must be maintained at 1320 ℃ -1450 ℃, which is higher than 30-60CM from the bottom refractory The working process temperature of the liquid glass in the distance area is 20-80 ℃;
工艺特点在于:通过从上向下流动的玻璃液进行温度控制的澄清、排气泡和防析晶装置(30)设计的距离底部耐火材5-30CM的区域中的玻璃液中,各自的3-20个电极装置,使从上向下流动的玻璃液进行温度控制的澄清、排气泡和防析晶装置(30)区域的,距耐火材料底部5-30CM距离的区域的玻璃液中,最少有100立方CM体积的区间的工作工艺温度,要保持在1320℃-1450℃,要高于距离底部耐火材料30-60CM距离的区域玻璃液的工作工艺温度20-80℃;The process features: temperature controlled clarification, bubble removal and anti-crystallization equipment (30) designed by glass liquid flowing from top to bottom. The glass liquid in the area 5-30CM away from the bottom refractory, each 3 -20 electrode devices, in the glass liquid in the area of 5-30cm distance from the bottom of the refractory, for the temperature control of the glass liquid flowing from top to bottom for clarification, bubble elimination and anti-crystallization equipment (30), The working process temperature in the area with a minimum volume of 100 cubic CM should be maintained at 1320 ° C-1450 ° C, which is higher than the working process temperature of the glass liquid in the area 30-60CM away from the bottom refractory material 20-80 ° C;
步骤2.使玻璃液从采用电极,对从上向下流动的玻璃液进行温度控制的澄清、排气泡和防析晶装置(30)下部,进入的底部流液通道(20),再进入联结着的一个采用电极对从下向上流动的玻璃液进行温度控制的玻璃液上升通道结构(40);Step 2. Make the glass liquid from the bottom of the liquid flow channel (20) entering the bottom liquid flow channel (20) by using the electrode to lower the temperature of the glass liquid flowing from the top to the bottom, and remove the bubbles. A connected glass liquid ascending channel structure using electrodes for temperature control of glass liquid flowing from bottom to top (40);
工艺特点在于:通过底部流液通道(20)中设计的,距离底部耐火材5-30CM的区域中的玻璃液中,设计的3-20个电极装置,使底部流液通道(20)区域的,距耐火材料底部5-30CM距离的区域的玻璃液中,最少有100立方CM体积的区间 的工作工艺温度,要保持在1320℃-1450℃,要高于距离底部耐火材料30-60CM距离的区域玻璃液的工作工艺温度20-80℃;The process is characterized by the design of 3-20 electrode devices in the glass liquid in the bottom liquid flow channel (20), 5-30CM away from the bottom refractory, and the bottom liquid flow channel (20) area. In the glass liquid in the area of 5-30CM distance from the bottom of the refractory material, the working process temperature in the section with a volume of at least 100 cubic CM must be maintained at 1320 ℃ -1450 ℃, which is higher than the distance of 30-60CM from the bottom refractory material. Regional glass liquid working process temperature 20-80 ℃;
工艺特点在于:通过采用电极对从下向上流动的玻璃液进行温度控制的玻璃液上升通道结构(40)中设计的,距离底部耐火材5-30CM的区域中的玻璃液中,设计的3-20个电极装置,使底部流液通道(20)区域的,距耐火材料底部5-30CM距离的区域的玻璃液中,最少有100立方CM体积的区间的工作工艺温度,要保持在1320℃-1450℃,要高于距离底部耐火材料30-60CM距离的区域玻璃液的工作工艺温度20-80℃;The process is characterized by: designed in the glass liquid ascending channel structure (40) for temperature control of glass liquid flowing from bottom to top by using electrodes, in the glass liquid in the area 5-30CM from the bottom refractory, the designed 3- 20 electrode devices, so that the working process temperature of the glass liquid in the area of the bottom flow channel (20), at a distance of 5-30CM away from the bottom of the refractory material, has a volume of at least 100 cubic CM, which must be maintained at 1320 ° C- 1450 ° C, which is 20-80 ° C higher than the working process temperature of the glass liquid in the area 30-60CM away from the bottom refractory;
工艺特点在于:通过其距离底部耐火材5-30CM的区域中的玻璃液中,设计的3-20个电极装置,使底部流液通道(20)区域的,距耐火材料底部5-30CM距离的区域的玻璃液中,最少有100立方CM体积的区间的工作工艺温度,要保持在1320℃-1450℃,要高于距离底部耐火材料30-60CM距离的区域玻璃液的工作工艺温度20-80℃;The process is characterized by the design of 3-20 electrode devices in the glass liquid in the area 5-30CM away from the bottom refractory, so that the bottom liquid flow channel (20) area is 5-30CM away from the bottom of the refractory. In the region of the liquid glass, the working process temperature of the zone with a volume of at least 100 cubic CM must be maintained at 1320 ° C to 1450 ° C, which is higher than the working process temperature of the liquid glass in the area at a distance of 30-60CM from the bottom refractory material. ℃
步骤3.玻璃液再由底部流液通道(20),进入用电极对从下向上流动的玻璃液进行温度控制的玻璃液上升通道结构(40); Step 3. The glass liquid flows from the bottom liquid flow channel (20) and enters the glass liquid rising channel structure (40) for controlling the temperature of the glass liquid flowing from bottom to top with an electrode;
工艺特点在于:通过其距离底部耐火材5-30CM的区域中的玻璃液中,设计的3-20个电极装置,使用电极对从下向上流动的玻璃液进行温度控制的玻璃液上升通道结构(40)区域的,距耐火材料底部5-30CM距离的区域的玻璃液中,最少有100立方CM体积的区间的工作工艺温度,要保持在1320℃-1450℃,要高于距离底部耐火材料30-60CM距离的区域玻璃液的工作工艺温度20-80℃;The process is characterized by a glass liquid ascending channel structure (3-20 electrode devices designed by the glass liquid in the area 5-30CM away from the bottom refractory, using electrodes to temperature control the glass liquid flowing from the bottom up) 40) In the glass liquid in the area with a distance of 5-30CM from the bottom of the refractory material, the working process temperature of the zone with a volume of at least 100 cubic CM must be maintained at 1320 ° C-1450 ° C, which is higher than 30 from the bottom refractory The working process temperature of the glass liquid in the region of -60CM distance is 20-80 ℃;
步骤4.成型工艺的选择:Step 4. Selection of molding process:
第一种玻璃制品成型工艺的选择:前述的经过上升通道结构(40)的顶部出口的玻璃液,进入玻璃制品的成型装置(5);其玻璃制品的成型装置(5)是浮法平板玻璃工艺的锡窑结构;玻璃液进入锡窑结构的平滑的布有溶化的锡金属 的平面,进行玻璃液趟平摊薄及抛光;再由两边的10-40对拉边机对形成的玻璃带拉成所需厚度;再经过退火,切材工序,形成浮法平板玻璃制品;或Selection of the first glass product molding process: The aforementioned glass liquid passing through the top outlet of the ascending channel structure (40) enters the glass product molding device (5); the glass product molding device (5) is float plate glass The tin kiln structure of the process; the molten glass enters the flat surface of the tin kiln structure which is melted with tin metal, and the glass liquid is thinned and polished; To the required thickness; and then annealing and cutting to form a float plate glass product; or
第二种玻璃制品成型工艺的选择:前述的经过上升通道结构(40)的顶部出口的玻璃液,进入玻璃液的主流道,玻璃液进入联结着有2-30个玻璃液分流道;玻璃液进入各个分流道联结着的玻璃制品的玻璃纤维生产的成型装置;分别流入对应的2-30个承载玻璃液的干埚,玻璃液经过对应的2-30个拉丝板,在对应的拉丝机的作用下形成玻璃纤维;或Selection of the second glass product molding process: the aforementioned glass liquid that passes through the top outlet of the ascending channel structure (40) enters the main channel of the glass liquid, and the glass liquid enters and is connected with 2-30 glass liquid distribution channels; the glass liquid Enter the molding device for glass fiber production of the glass products connected to each of the shunts; flow into the corresponding 2-30 dry pots carrying the glass liquid, and the glass liquid passes through the corresponding 2-30 drawing boards, in the corresponding drawing machine. Forms glass fibers under action; or
第三种玻璃制品成型工艺的选择:前述的经过上升通道结构(40)的顶部出口的玻璃液,进入玻璃液的主流道,玻璃液进入联结着有2-30个玻璃液分流道;玻璃液进入各个分流道联结着的玻璃制品的2-30个工业与日用玻璃器皿的吹制成型装置;分别吹制成工业与日用玻璃的制品;再经过玻璃制品的退火装置的处理,制成工业与日用玻璃的吹制成型制品;或Choice of the third glass product molding process: the aforementioned glass liquid passing through the top outlet of the ascending channel structure (40) enters the main channel of the glass liquid, and the glass liquid enters and is connected with 2-30 glass liquid distribution channels; the glass liquid Enter the 2-30 industrial and daily glassware blow molding devices of the glass products connected to each of the shunts; blow the products of industrial and daily glass separately; and then process them by the annealing device of the glass products. Blow moulded products for industrial and household glass; or
第四种玻璃制品成型工艺的选择:前述的经过上升通道结构(40)的顶部出口的玻璃液,进入玻璃液的主流道,玻璃液进入联结着有2-30个玻璃液分流道;玻璃液进入各个分流道联结着的玻璃制品的2-30个工业与日用玻璃器皿的压制成型装置;分别压制成工业与日用玻璃的制品;再经过玻璃制品的退火装置的处理,制成工业与日用玻璃的压制成型制品;或Choice of the fourth glass product molding process: The aforementioned glass liquid that passes through the top outlet of the ascending channel structure (40) enters the main channel of the glass liquid, and the glass liquid enters and is connected with 2-30 glass liquid branching channels; the glass liquid Enter the 2-30 industrial and daily glassware press forming devices of the glass products connected to each of the shunts; press the products of industrial and daily glass respectively; and then process them by the annealing device of glass products to make industrial and Pressed molded articles of daily glass; or
第五种玻璃制品成型工艺的选择:前述的经过上升通道结构(40)的顶部出口的玻璃液,进入玻璃液的主流道,玻璃液进入联结着有2-30个玻璃液分流道;玻璃液进入各个分流道联结着的玻璃制品的2-30个工业与日用玻璃的拉制成型装置,分别拉制成工业与日用玻璃的制品;再经过玻璃制品的退火装置的处理,制成工业与日用玻璃的拉制成型制品;或Selection of the fifth glass product molding process: The aforementioned glass liquid passing through the top outlet of the ascending channel structure (40) enters the main channel of the glass liquid, and the glass liquid enters and is connected with 2-30 glass liquid branching channels; the glass liquid Enter the 2-30 industrial and daily glass drawing devices of the glass products connected to each of the shunts, draw the industrial and daily glass products respectively; and then process them through the annealing device of the glass products to make Drawn products of industrial and household glass; or
第六种玻璃制品成型工艺的选择:前述的经过上升通道结构(40)的顶部出口的玻璃液,进入玻璃液的主流道,玻璃液进入联结着有2-30个玻璃液分流道;玻璃液进入各个分流道联结着的玻璃制品的2-30个卫浴玻璃制品的吹制成 型装置,分别制成卫浴玻璃制品;再经过玻璃制品的退火装置的处理,制成卫浴玻璃制品。Choice of the sixth glass product molding process: The aforementioned glass liquid that has passed through the top outlet of the ascending channel structure (40) enters the main channel of the glass liquid, and the glass liquid enters and is connected with 2-30 glass liquid distribution channels; the glass liquid Enter the blow molding device of 2-30 sanitary glass products connected to the glass products of each shunt, and make sanitary glass products respectively; and then process the annealing device of the glass products to make sanitary glass products.
关于本发明的显著进步性和创造性:Regarding the remarkable progress and creativity of the present invention:
本发明属于玻璃技术领域,涉及一种采用横向火焰池窑生产系统的工艺方法,所生产的超高铝玻璃制品。The invention belongs to the technical field of glass and relates to a process method using a transverse flame pool kiln production system to produce ultra-high aluminum glass products.
本发明技术方案,属于一种包含制备方法特征的产品权利要求的发明,不但产品比较先有技术对比文件的成份和结构,具有新颖性;而且本发明创新的工艺方法,比先有技术产品,能导致了氧化铝含量达20--49%的玻璃制品内部的微观变化和进步,本发明比较先有超高铝玻璃制品,才能真正具有不同的、稳定的-【透光性、高强度、轻薄化、轻量化性能】的玻璃制品内部的微观变化和进步的产品特征。The technical solution of the present invention belongs to an invention that includes the product claim characteristics of the preparation method. Not only the product has a novel composition and structure compared with the prior art, but also has novelty. In addition, the innovative process method of the present invention is superior to the prior art product. It can cause micro changes and progress inside glass products with alumina content of 20-49%. Compared with the ultra-high aluminum glass products, the present invention can truly have different and stable properties-[light transmission, high strength, Lightness, thinning, and lightweight performance] Microscopic changes in glass products and progressive product features.
本发明所述的独有的制造方法特征是:The unique manufacturing method of the present invention is characterized by:
其玻璃液的卡脖流道装置(60)的距离底部耐火材5-30CM的区域中的玻璃液中,设计有3-20个电极装置;The glass liquid clamping device (60) of the glass liquid is located at a distance of 5-30CM from the bottom refractory, and 3-20 electrode devices are designed;
其采用电极对从上向下流动的玻璃液进行温度控制的澄清、排气泡和防析晶装置(30)的距离底部耐火材5-30CM的区域中的玻璃液中,设计有3-20个电极装置;It uses electrodes to clarify the temperature of the glass liquid flowing from top to bottom, remove bubbles and prevent the crystallizing device (30). The glass liquid in the area 5-30CM from the bottom refractory is designed with 3-20 Electrode device
其底部流液通道(20)的,距离底部耐火材5-30CM的区域中的玻璃液中,设计有3-20个电极装置;3-20 electrode devices are designed in the glass liquid in the bottom liquid flow channel (20) in the area 5-30CM away from the bottom refractory;
其采用电极对从下向上流动的玻璃液进行温度控制的玻璃液上升通道结构(40)的距离底部耐火材5-30CM的区域中的玻璃液中,设计有3-20个电极装置;The glass liquid in the glass liquid ascending channel structure (40) whose temperature is controlled from the bottom to the top by using electrodes is provided with 3-20 electrode devices in the glass liquid in a region 5-30CM away from the bottom refractory;
步骤1不同于对比文件和一切先有技术的工艺特点在于:通过玻璃液的卡脖流道装置(60)的距离底部耐火材5-30CM的区域中的玻璃液中,设计的3-20个电极装置,使卡脖流道装置(60)区域的,距耐火材料底部10-30CM距离的区域的 玻璃液中,最少有100立方CM体积的区间的工作工艺温度,要保持在1320℃-1450℃,要高于距离底部耐火材料30-60CM距离的区域玻璃液的工作工艺温度20-80℃; Step 1 is different from the comparison file and all the prior art processes. The characteristics are: 3-20 pieces of glass liquid are designed in the area of 5-30CM from the bottom refractory through the card liquid channel device (60) of the glass liquid. Electrode device, so that the working process temperature of the glass liquid in the area of the card neck runner device (60) area at a distance of 10-30CM from the bottom of the refractory material has a volume of at least 100 cubic CM, which must be maintained at 1320 ° C-1450 ℃, which is 20-80 ℃ higher than the working process temperature of the glass liquid in the area 30-60CM away from the bottom refractory;
步骤2不同于对比文件和一切先有技术的工艺特点在于:从上向下流动的玻璃液进行温度控制的澄清、排气泡和防析晶装置(30),通过其设计的的距离底部耐火材5-30CM的区域中的玻璃液中,3-20个电极装置,使从上向下流动的玻璃液进行温度控制的澄清、排气泡和防析晶装置(30)区域的,距耐火材料底部5-30CM距离的区域的玻璃液中,最少有100立方CM体积的区间的工作工艺温度,要保持在1320℃-1450℃,要高于距离底部耐火材料30-60CM距离的区域玻璃液的工作工艺温度20-80℃;Step 2 is different from the comparison document and all the prior art processes. The characteristics are: the temperature controlled clarification, bubble removal and anti-crystallization device (30) flowing from the top to the bottom of the glass. In the glass liquid in the area of 5-30CM, 3-20 electrode devices are used to make the glass liquid flowing from top to bottom for temperature control clarification, bubble elimination and anti-crystallization equipment (30) area, away from fire resistance. In the glass liquid in the area with a distance of 5-30CM from the bottom of the material, the working process temperature in the area with a minimum volume of 100 cubic CM must be maintained at 1320 ° C-1450 ° C, which is higher than the glass liquid in the area with a distance of 30-60CM from the bottom refractory. Working process temperature of 20-80 ℃;
步骤3不同于对比文件和一切先有技术的工艺特点在于:通过底部流液通道(20)区域的距离底部耐火材5-30CM的区域中的玻璃液中,设计的3-20个电极装置,使底部流液通道(20)区域的,距耐火材料底部5-30CM距离的区域的玻璃液中,最少有100立方CM体积的区间的工作工艺温度,要保持在1320℃-1450℃,要高于距离底部耐火材料30-60CM距离的区域玻璃液的工作工艺温度20-80℃; Step 3 is different from the reference file and all the prior art processes. The characteristic is: 3-20 electrode devices are designed in the glass liquid in the area of 5-30CM from the bottom refractory through the area of the bottom flow channel (20). Keep the working process temperature in the glass liquid in the area of the bottom flow channel (20) at a distance of 5-30CM away from the bottom of the refractory at least 100 cubic CM volume, and maintain it at 1320 ℃ -1450 ℃. The working process temperature of the liquid glass in the area 30-60CM away from the bottom refractory material is 20-80 ℃;
步骤4不同于对比文件和一切先有技术的工艺特点在于:玻璃液再进入用电极对从下向上流动的玻璃液进行温度控制的玻璃液上升通道结构(40);通过其距离底部耐火材5-30CM的区域中的玻璃液中,设计的3-20个电极装置,使用电极对从下向上流动的玻璃液进行温度控制的玻璃液上升通道结构(40)区域的,距耐火材料底部5-30CM距离的区域的玻璃液中,最少有100立方CM体积的区间的工作工艺温度,要保持在1320℃-1450℃,要高于距离底部耐火材料30-60CM距离的区域玻璃液的工作工艺温度20-80℃。Step 4 is different from the reference file and all the prior art processes. The feature is that the glass liquid enters the glass liquid ascending channel structure (40) which controls the temperature of the glass liquid flowing from the bottom up with an electrode; In the glass liquid in the area of -30CM, the designed 3-20 electrode devices use electrodes to control the temperature of the glass liquid flowing from the bottom to the glass liquid ascending channel structure (40). The working process temperature of the glass liquid in the area with a distance of 30CM with a volume of at least 100 cubic CM volume must be maintained at 1320 ℃ -1450 ℃, which is higher than the working process temperature of the glass liquid in the area with a distance of 30-60CM from the bottom refractory. 20-80 ° C.
【比较先前技术】[Comparison of prior art]
(1)先有对比技术1:本发明人的先有发明:有高退火点及环保节能减排的高强度高平整度低粘度特征的平板玻璃的应用及相关部件,专利号 201110060944.4。(1) Prior comparative technology 1: The present inventor's prior invention: the application and related components of high-strength, flatness and low-viscosity flat glass with high annealing points, environmental protection, energy saving and emission reduction, patent number 201110060944.4.
(2)先有发明之2:本发明人的201510161553.61,一种具有低热膨胀系数的平板玻璃及其制备工艺。(2) Prior invention 2: 201510161553.61 of the present inventor, a flat glass with a low thermal expansion coefficient and a preparation process thereof.
(3)先有发明之3:本发明人的:PCT/CN2015/000795,一种高温区热膨胀系数的低差值、低析晶速度、超高强度、高软化点、防火防爆平板玻璃的应用。(3) The third invention: the inventor's: PCT / CN2015 / 000795, an application of low difference in thermal expansion coefficient, low crystallization speed, super high strength, high softening point, fireproof and explosion-proof flat glass in high temperature region .
(4)先有发明之4:本发明人的:PCT/CN2015/000793,一种低析晶温度、低析晶速度、耐高温、特高铝玻璃纤维的应用及其制备方法、复合材料。(4) Invention 4: The present inventor's: PCT / CN2015 / 000793, a low crystallization temperature, low crystallization speed, high temperature resistance, ultra-high aluminum glass fiber application, preparation method thereof, and composite material.
(5)先有发明之5:本发明人的:PCT/CN2015/000794,一种高温区热膨胀系数的低差值、低析晶速度、高软化点、耐高温防爆玻璃器皿或玻璃日用品的应用。(5) Prior Invention No. 5: The inventor's: PCT / CN2015 / 000794, an application of low difference in thermal expansion coefficient, low crystallization speed, high softening point, high temperature resistant explosion-proof glassware or glass daily necessities in high temperature area .
(6)在先有技术中,美国康宁公司的电子平板盖板大猩猩1-4代,15-22%氧化铝;但含氧化钙低于1%,不是在本发明[氧化硅含量是氧化钙含量的2.51-5.8倍,氧化钙含量是氧化镁含量的0.8倍-2.3倍]的范围。(6) In the prior art, Corning Corporation ’s electronic flat-panel cover gorilla 1-4 generations, 15-22% alumina; but containing calcium oxide less than 1%, not in the present invention [silicon oxide content is oxidized The content of calcium is 2.51 to 5.8 times, and the content of calcium oxide is in the range of 0.8 to 2.3 times that of magnesium oxide.
在先有技术中,S级玻纤含23-25-26%氧化铝,----但含氧化钙低于1%,也不是在本发明[氧化硅含量是氧化钙含量的2.51-5.8倍,氧化钙含量是氧化镁含量的0.8倍-2.3倍]的范围。In the prior art, S grade glass fiber contains 23-25-26% alumina, but it contains less than 1% calcium oxide, which is not in the present invention. [The silicon oxide content is 2.51-5.8 of the calcium oxide content Times, the calcium oxide content is in the range of 0.8 to 2.3 times the magnesium oxide content].
而且上述先有技术,在工艺上都采用-只有约10CM直径白金通道技术,产量很小;都不采用本发明的工艺技术生产方法。And the above-mentioned prior arts are all adopted in the process-only about 10CM diameter platinum channel technology, the output is very small; none of the process technology production methods of the present invention.
(7)先有电溶窑工艺技术及火焰窑工艺技术玻璃制品,主要生产氧化铝含量为1-4%的低铝制品、氧化铝含量为5-9%的中铝制品、氧化铝含量为10-16%的高铝制品。(7) Prior to the electrolysis kiln technology and flame kiln technology, glass products mainly produced low aluminum products with alumina content of 1-4%, medium aluminum products with alumina content of 5-9%, and alumina content of 10-16% high aluminum products.
先有电溶窑工艺技术及火焰窑工艺技术,不具有本发明工艺方法的几个技术要素结抅特征,所以,先有技术,不具有克服其技术难点的工艺条件。The prior electrolysis kiln process technology and flame kiln process technology do not have the characteristics of several technical elements of the process method of the present invention. Therefore, the prior art does not have the process conditions to overcome its technical difficulties.
先有电溶窑工艺技术及火焰窑工艺技术,主要考虑了溶化玻璃及排气泡和均化玻璃液,希望形成电极之间的电场[温度场]是均匀的为根本目标。不具有本发明耍求的,在多个区域中的距离底部耐火材5-30CM的区域中的玻璃液的特定区域位置,设计有3-20个电极装置的要求,和不具有本发明耍求的在多个区域中的,距耐火材料底部5-30CM距离的区域的玻璃液中,最少有100立方CM体积的区间的工作工艺温度,要保持在1320℃-1450℃,要高于距离底部耐火材料30-60CM距离的区域玻璃液的工作工艺温度20-80℃的工艺方法。Prior to the electrolysis kiln process technology and flame kiln process technology, the main considerations were the melting of the glass, the removal of air bubbles, and the homogenization of the glass liquid. It was hoped that the formation of the electric field [temperature field] between the electrodes was uniform. Without the requirements of the present invention, the requirements for the design of 3-20 electrode devices in a specific area of the glass liquid in a region 5-30CM away from the bottom refractory in a plurality of regions, and without the requirements of the present invention The working process temperature of the glass liquid in a region with a distance of 5-30CM from the bottom of the refractory in a plurality of areas with a volume of at least 100 cubic CM must be maintained at 1320 ° C-1450 ° C, which is higher than the distance from the bottom Process method for working glass temperature of refractory within 30-60CM distance from 20-80 ℃.
【本发明与先前技术(1)-(7)的不同】[Different from the prior art (1)-(7)]
(一)首先,本发明【一种采用新横向火焰池窑生产系统的工艺方法所生产的超高铝玻璃制品】与先有发明(1)-(7)的技术方案和任何先有技术方案的成份结构都不同:本发明--按重量百分比计,其氧化铝含量为20%-49%;氧化镁含量为5%--20%,氧化硅含量是氧化钙含量的2.51-5.8倍,氧化钙含量是氧化镁含量的0.8倍-2.3倍;所以本发明具有新颖性。(1) First, the present invention [an ultra-high alumina glass product produced by a process method using a new transverse flame tank kiln production system] and the technical solutions of the prior inventions (1)-(7) and any prior technical solutions The composition and structure of the components are all different: according to the present invention, the content of alumina is 20% -49%; the content of magnesium oxide is 5% -20%, and the content of silicon oxide is 2.51-5.8 times that of calcium oxide. The calcium oxide content is 0.8 times to 2.3 times the magnesium oxide content; therefore, the present invention is novel.
另外,本发明所述的工艺特点的制备方法,与先有发明(1)-(7)的技术方案和任何先有技术方案也都不同。本发明所述的制备方法特征,才能产生与先有类似产品完全不同的,【玻璃中完全沒有乳白色的富铝条纹或富铝区块,沒有玻璃分层的特征的,氧化铝含量达20--49%的玻璃制品】。In addition, the preparation method of the process features according to the present invention is also different from the technical solutions of the prior inventions (1) to (7) and any of the prior technical solutions. The characteristics of the preparation method described in the present invention can produce completely different from the previous similar products. [The glass has no milky white aluminum-rich stripes or aluminum-rich blocks at all, and the characteristics of glass delamination have no alumina content of 20- -49% glass products].
而如果不采用本发明所述的制备方法特征,氧化铝含量达20--49%的玻璃制品中,就会易于存在乳白色的富铝条纹或乳白色的富铝区块的不透明的重大缺陷,或出现玻璃分层的重大缺陷问题。However, if the characteristics of the preparation method described in the present invention are not adopted, glass products with an alumina content of 20-49% will be susceptible to major defects such as milky white aluminum-rich stripes or opaque aluminum-rich blocks, or Major defects in glass delamination occurred.
(二)而本发明因为采用了全新的工艺:在多个区域溶窑结抅装置,的底部耐火材5-30CM距离的区域中的玻璃液中,全部设计了3-20个电极装置,采用了全新的工艺:使多个区域溶窑结抅装置区域的底部耐火材料10-30CM距离的区域的玻璃液中,最少各自有1个区间的工作工艺温度保持在1320℃-1450℃,高于距离底部耐火材料30-60CM距离的区域玻璃液的工作工艺温度20-80℃。所以能形成 这几个区域的,距离底部耐火材料5-30-60CM距离的玻璃液小范围的上下流动均化,使“富铝沉降堆积现象--即高氧化铝成份含量的玻璃液部分,因比重大而沉降堆积在底部的现象”,得到均化,得到解决。能从根本上解决进而造成玻璃成品成型阶段因成份严重不均,出现玻筋,条纹,白色不透明富氧块与条等产品根本不合格的难点,使高合格率的生产20--49%的氧化铝含量的玻璃制品成为可能。(2) Because the present invention adopts a completely new process: 3-20 electrode devices are all designed in the glass liquid in the area of the refractory with a distance of 5-30CM at the bottom of the melting kiln crusting device in multiple areas. A new process is adopted: at least one section of the glass liquid in the region of the refractory material at a distance of 10-30CM from the bottom of the kiln crusting device area in multiple areas is maintained at a temperature of 1320 ℃ -1450 ℃, which is higher than The working process temperature of the liquid glass in the area of 30-60CM from the bottom refractory is 20-80 ° C. Therefore, the upper and lower flows of the glass liquid with a distance of 5-30-60CM from the bottom refractory can be formed in these areas, so that the "aluminum-rich sedimentation phenomenon-that is, the glass liquid part with high alumina content, "The phenomenon of sedimentation and accumulation at the bottom due to the large specific gravity" was homogenized and resolved. It can fundamentally solve the problem that the glass finished product is severely uneven in the molding stage, which causes glass bars, stripes, white opaque oxygen-enriched blocks and strips to be completely unqualified, making high-qualified production of 20--49%. Glass products with alumina content are possible.
而且本发明还能克服先有技术中,通过先有技术试图采用传统的搅拌工艺来达到目的采用传统的搅拌工艺,克服在玻璃液底部出现“富铝沉降堆积现象”产生的难点。In addition, the present invention can also overcome the difficulties caused by the "aluminum-rich sedimentation phenomenon" at the bottom of the glass liquid by using the traditional stirring process to achieve the purpose through the prior art.
克服其传统的搅拌工艺难点之一:采用传统的搅拌工艺是在靠近玻璃成型区的电熔窑底部或上升通道顶部位置,搅拌工艺易于产生二次气泡,使大量气泡直接出现在产品中;Overcoming one of the difficulties of its traditional stirring process: The traditional stirring process is used near the bottom of the electric melting furnace or the top of the ascending channel of the glass forming area. The stirring process is prone to generate secondary bubbles and a large number of bubbles appear directly in the product;
克服其传统的搅拌工艺难点之二:采用传统的搅拌工艺,在超过如果1300℃的环境中,使用加冷却水循环降温的不锈钢搅拌器,会造成严重的搅拌器边壁附近玻璃液,因长期水冷降温传导,而产生玻璃液大量析晶,在靠近玻璃成型区的电熔窑底部或上升通道顶部位置,析晶会直接大量出现在产品中;Overcoming the difficulties of its traditional mixing process: using the traditional mixing process, if the temperature exceeds 1300 ° C, using a stainless steel mixer with cooling water circulation to reduce the temperature will cause serious glass liquid near the side wall of the mixer, due to long-term water cooling When the temperature is reduced, a large amount of crystallization of the molten glass is generated. At the bottom of the electric melting furnace near the glass forming area or at the top of the ascending channel, the crystallization will directly appear in the product in large quantities;
克服其传统的搅拌工艺难点之三:采用白金搅拌器,会存在成本太高和白金在高温下与玻璃反应出现新的气泡,在靠近玻璃成型区的电熔窑底部或上升通道顶部位置,产生的二次气泡,也会使大量气泡直接出现在产品中。这是现有的技术都无法合格的生产含20%以上的超高铝含量的玻璃制品的重要原因。Overcoming the difficulties of its traditional mixing process: the use of platinum stirrers will cause too high costs and platinum will react with glass at high temperatures. New bubbles will appear at the bottom of the electric melting kiln near the glass forming area or at the top of the ascending channel. Secondary bubbles will also cause a large number of bubbles to appear directly in the product. This is an important reason why the existing technologies are not qualified to produce glass products with an ultra-high aluminum content of more than 20%.
所以能做到,生产20--49%的氧化铝含量的玻璃制品,不但要在正常生产时,能使各自装置内,尤其底部区域的玻璃液保持在1300℃以上;并能在玻璃制品的成型装置(5)停止工作时,即也沒有从溶化窑结抅装置流动过来的高温玻璃液时的玻璃液,也能形成这几个区域的,距离底部耐火材料5-30-60CM距离的玻璃液最少各自有1个区间的工作工艺温度保持在1320℃-1450℃,最少各自有1个区间的工作工艺温度保持在1320℃-1450℃,高于距离底部耐火材料30-60CM距离的区域玻璃液的工作工艺温度20-80℃;并小范围的上下流动均化,使“富铝沉降 堆积现象--即高氧化铝成份含量的玻璃液部分,因比重大而沉降堆积在底部的现象”,得到均化,得到解决。Therefore, it is possible to produce glass products with an alumina content of 20-49%, not only to keep the glass liquid in the respective devices, especially the bottom region, above 1300 ° C during normal production; When the molding device (5) stops working, that is, the glass liquid when the high temperature glass liquid does not flow from the melting furnace crusting device, it can also form a glass with a distance of 5-30-60cm from the bottom refractory in these areas. The working process temperature of at least one section of the liquid is maintained at 1320 ° C to 1450 ° C, and the working process temperature of at least one section is maintained at 1320 ° C to 1450 ° C, which is higher than the area glass at a distance of 30-60CM from the bottom refractory. The working process temperature of the liquid is 20-80 ° C; and the upper and lower flows are homogenized in a small range, so that "the phenomenon of aluminum-rich sedimentation and accumulation-that is, the phenomenon that the glass liquid part with a high alumina content content sediments and accumulates at the bottom due to the specific gravity" , Get homogenized and get resolved.
全新的工艺发明构思方案,是一种在特定的环境中,对特定的区域的工艺技术方案生产的玻璃产品的发明,产生了予料不到的技术效果。The brand-new process invention concept is an invention of glass products produced in a specific environment for a specific region's process technology solution, which has produced unexpected technical effects.
根椐专利审查指南的第三部分第四章【175页】3.2.2 显著的进步性判断、、、、、、。以下情怳,通常应当认为发明具有有益的技术效果,具有显著的进步性。(2)发明提供了一种技术构思不同的技术方案,其枝术效果能够基本上达到现有技术水平;【例如质量的改善、产量的提高、节约能源、防治环境污染等】。而本发明【一种采用新横向火焰池窑生产系统的工艺方法,所生产的超高铝玻璃制品】在电子平板玻璃、建筑与工业平板玻璃、玻璃纤维、工业或日用玻璃器皿与器件的领域中,产生了予料不到的能克服先有技术重大缺陷问题的效果,尤其能克服本人的先有发明中的工艺方法,在生产氧化铝含量达20--49%的玻璃制品中,就会易于存在乳白色的富铝条纹或乳白色的富铝区块的不透明的重大缺陷,或出现玻璃分层的重大缺陷问题;因本发明【一种采用新横向火焰池窑生产系统的工艺方法,所生产的超高铝玻璃制品】,能克服上述问题,所以本发明的氧化铝含量达20--49%的玻璃制品,才能达到比先有超高铝玻璃制品真正具有稳定的-【透光性、高强度、轻薄化、轻量化性能】的目的(因为业内人士都了解,如果玻璃制品出现乳白色的富铝条纹或乳白色的富铝区块的不透明的重大缺陷,或出现玻璃分层的重大缺陷,不可能具备本发明产品不同于一切先有技术的-【合格的透光性、超高铝的超高强度、更轻薄化、更轻量化的性能】)。所以本发明具有显著的进步性。Based on Chapter 3 of Chapter 4 of the Patent Examination Guidelines [Page 175] 3.2.2 Significant Progressive Judgment ,,,,,,,. In the following circumstances, the invention should generally be considered to have beneficial technical effects and significant progress. (2) The invention provides a technical solution with different technical concepts, the effect of which can basically reach the current technology level; [for example, improvement in quality, increase in yield, energy conservation, prevention of environmental pollution, etc.]. And the present invention [a process method using a new horizontal flame pool kiln production system, ultra-high aluminum glass products produced] in electronic flat glass, architectural and industrial flat glass, fiberglass, industrial or daily glassware and devices In the field, there are unexpected effects that can overcome the major defects of the prior art, especially the process in my prior invention. In the production of glass products with alumina content of 20-49%, It will be prone to opaque major defects of milky aluminum-rich stripes or milky-white aluminum-rich blocks, or major defects of glass layering; because of the present invention [a process method using a new transverse flame pool kiln production system, Produced ultra-high alumina glass products] can overcome the above problems, so the glass products with an alumina content of 20-49% according to the present invention can achieve true stability than the previous ultra-high alumina glass products-[light transmission Performance, high strength, thin and light, lightweight performance] (because the industry knows that if glass products appear milky rich aluminum stripes or milky rich The major opaque defects of the block, or the major defects of glass delamination, cannot have the products of the present invention different from all the prior arts-[qualified light transmission, ultra-high strength of ultra-high aluminum, lighter and thinner, Lighter performance]). Therefore, the present invention has remarkable progress.
以上所述的解决现有技术在生产高于20%的氧化铝含量的玻璃制品的问题,是超高铝的高强玻璃生产领域中,人们一直渴望解决但始终未能获得成功 的技术难题。本技发明,解决了这个人们一直渴望解决但始终未能获得成功的技术难题,所以本发明,具有突出的实质性特点和显著的进步性,具有创造性。The above-mentioned solution to the problem of producing glass products with an alumina content of more than 20% in the prior art is the high-strength glass production field of ultra-high aluminum. People have been eager to solve but have never been successful. The technical invention solves the technical problem that people have been eager to solve but has not been successful. Therefore, the present invention has outstanding substantive features, remarkable progress, and creativity.
根据专利审查指南第二部分第四章,3.2.2-175页-显著进步性的判断--之(2)发明提供了一种技术构思不同的技术方案,其技术效果基本上能达到现有技术的水平。而本发明也属于比较本人的先有发明,提供了一种技术构思不同的新技术方案,其技术效果不仅能达到本人的先有发明技术的水平,还超过了本人的先有发明技术的水平。According to Chapter IV of Part Two of the Patent Examination Guidelines, page 3.2.2-175-Judgment of Significant Progress-(2) The invention provides a technical solution with different technical concepts, and its technical effect can basically reach the existing The level of technology. The present invention also belongs to the comparison of my prior inventions, and provides a new technical solution with different technical concepts. The technical effect can not only reach the level of my prior invention technology, but also exceed the level of my prior invention technology. .
根据专利审查指南第二部分第四章,判断要求保护的发明对本领域的技术人员来说是否显而易见:判断过程中,要确定的是现有技术整体上是否存在某种技术启示....,下述情况,通常认为现有技术中存在上述技术启示:(i)所述区别特征为公知常识,例如,本领域中解决该重新确定的技术问题的惯用手段,或敎科书或者工具书等中披露的解决该重新确定的技术问题的技术手段。而本发明的技术方案,都不是公知常识,不是本领域中解决该重新确定的技术问题的惯用手段,或敎科书或者工具书等中披露的解决该重新确定的技术问题的技术手段。According to Chapter 2 of Chapter 4 of the Patent Examination Guidelines, it is judged whether the claimed invention is obvious to those skilled in the art: in the judgment process, it is necessary to determine whether there is some technical inspiration in the existing technology as a whole ... The above-mentioned technical inspiration is generally considered to exist in the prior art in the following situations: (i) the distinguishing feature is common knowledge, for example, the conventional means in the art to solve the re-determined technical problem, or a monograph or reference book The technical means disclosed in the technical solution to this re-determined technical problem. However, the technical solutions of the present invention are not common knowledge, nor are the conventional methods in the art to solve the technical problems that are re-determined, or the technical methods for solving the technical problems that are re-determined as disclosed in the medical books or reference books.
根据专利审查指南第二部分第四章,法22.3的2发明创造性的概念:发明的创造性,是指与现有技术相比,该发明有突出的实质性特点和显著进步性。2.2突出的实质性特点,是指对所属技术领域的技术人员来说,发明相对于现有技术是非显而易见的。如果发明是所属技术领域的技术人员在现有技术的基础上仅仅通过合乎逻辑的分析、推理或者有限的试验可以得到的,则该发明是显而易见的,也就不具备突击的实质性特点。According to the second chapter of Chapter 4 of the Patent Examination Guidelines, the concept of inventiveness of invention in Law 22.3: The inventiveness of invention means that the invention has outstanding substantive features and significant advancement compared with the prior art. 2.2 The outstanding substantive features refer to the fact that the invention is not obvious to those skilled in the art in comparison with the prior art. If the invention can be obtained by a person skilled in the art based on the existing technology only through logical analysis, reasoning, or limited experimentation, then the invention is obvious and does not have the substantive characteristics of assault.
而本发明的技术方案,都不是所属技术领域的技术人员在现有技术的基础上仅仅通过合乎逻辑的分析、推理或者有限的试验可以得到的。However, none of the technical solutions of the present invention can be obtained by those skilled in the art based on the existing technology only through logical analysis, reasoning, or limited experiments.
总之,本发明技术方案属于一种包含制备方法特征的产品权利要求的发明,不但产品比较先有技术对比文件的成份和结构,具有新颖性;而且本发明创新的工艺方法,比先有技术产品,能导致了氧化铝含量达20--49%的玻璃制品内部的微观变化和进步,本发明比较先有超高铝玻璃制品,才能真正具有不同的、稳定的-【透光性、高强度、轻薄化、轻量化性能】的玻璃制品内部的微观变化和进步的产品特征。In short, the technical solution of the present invention belongs to an invention that includes the product claim characteristics of the preparation method. Not only the product has a novel composition and structure compared with the prior art, and has novelty. In addition, the innovative process method of the present invention is superior to the prior art product. Can lead to microscopic changes and progress inside glass products with alumina content of 20-49%. Compared with the ultra-high aluminum glass products, the present invention can truly have different and stable properties-[light transmission, high strength] , Thin and light, light weight performance] micro changes in glass products and advanced product characteristics.
本发明制备方法导致了氧化铝含量达20--49%的玻璃制品中,与先有产品不同,产品中不存在乳白色的富铝条纹或乳白色的富铝区块的不透明缺陷结构,或不存在玻璃分层的缺陷结构;另外本发明创新的工艺方法,比先有技术产品,能导致了氧化铝含量达20--49%的玻璃制品内部的微观变化和进步,本发明比较先有超高铝玻璃制品,才能真正具有不同的、稳定的-【透光性、高强度、轻薄化、轻量化性能】的产品特征。The preparation method of the present invention results in glass products with an alumina content of 20-49%. Unlike previous products, there is no opaque defect structure of milky white aluminum-rich stripes or milky white aluminum-rich blocks in the product, or does not exist. Defective structure of glass delamination; In addition, the innovative process of the present invention can cause microscopic changes and advances in glass products with alumina content of 20-49% compared to the prior art products. Only aluminous glass products can have different and stable product characteristics of [transmittance, high strength, light weight, light weight performance].
因为业内人士都了解,如果玻璃制品出现乳白色的富铝条纹或乳白色的富铝区块的不透明的重大缺陷,或出现玻璃分层的重大缺陷,不可能具备本发明产品不同于一切先有技术的-【合格的透光性、超高铝的超高强度、更轻薄化、更轻量化的性能】。Because people in the industry understand that if glass products have milky white aluminum-rich stripes or milky white aluminum-rich blocks with major opacity defects or major defects in glass delamination, it is impossible to have the product of this invention different from all the prior art. -[Qualified light transmission, ultra-high aluminum ultra-high strength, lighter and thinner, lighter performance].
所以本发明不但具有新颖性,也具有显著的进步性。Therefore, the present invention is not only novel, but also significantly improved.
以上所述,仅是为了说明本发明一种采用新横向火焰池窑生产系统的工艺方法所生产的超高铝玻璃制品,的较佳优选实施例而已,然而其并非是对本发明的限制,任何熟悉本项技术的人员可能利用上述揭示的技术内容加以变更或修饰为等同变化的等效实施例,都可以按不同要求和性能实施本发明一种采用新横向火焰池窑生产系统的工艺方法所生产的超高铝玻璃制品。可见,凡是未脱离本发明技术方案的内容,尤其是请求项之内容,依据本发明的技术实质对以上实施例所作的任何简单修改,等同变化与修饰,均仍属本发明技术方案的范围内。The above description is only for the purpose of illustrating the preferred embodiment of the ultra-high alumina glass products produced by the process method of the new transverse flame tank kiln production system of the present invention, but it is not a limitation on the present invention. Any Those skilled in the art may use the disclosed technical content to modify or modify the equivalent embodiments with equivalent changes, and they may implement a process method using a new transverse flame tank kiln production system according to different requirements and performances of the present invention. Production of ultra-high aluminum glass products. It can be seen that, without departing from the content of the technical solution of the present invention, especially the content of the claims, any simple modifications, equivalent changes and modifications made to the above embodiments in accordance with the technical essence of the present invention still fall within the scope of the technical solution of the present invention. .