CN110510868A - A kind of process superelevation lead glass product produced using new lateral flame furnace production system - Google Patents

A kind of process superelevation lead glass product produced using new lateral flame furnace production system Download PDF

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Publication number
CN110510868A
CN110510868A CN201810545807.1A CN201810545807A CN110510868A CN 110510868 A CN110510868 A CN 110510868A CN 201810545807 A CN201810545807 A CN 201810545807A CN 110510868 A CN110510868 A CN 110510868A
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Prior art keywords
glass
glass metal
metal
glassware
region
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CN201810545807.1A
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Chinese (zh)
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杨德宁
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Shenzhen Qianhai Fawei New Material Technology Co ltd
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Individual
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Priority to CN201810545807.1A priority Critical patent/CN110510868A/en
Priority to PCT/CN2019/000091 priority patent/WO2019223323A1/en
Publication of CN110510868A publication Critical patent/CN110510868A/en
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/10009—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets
    • B32B17/10036—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets comprising two outer glass sheets
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/10165—Functional features of the laminated safety glass or glazing
    • B32B17/10366—Reinforcements of the laminated safety glass or glazing against impact or intrusion
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04—Interconnection of layers
    • B32B7/10—Interconnection of layers at least one layer having inter-reactive properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B60—VEHICLES IN GENERAL
    • B60J—WINDOWS, WINDSCREENS, NON-FIXED ROOFS, DOORS, OR SIMILAR DEVICES FOR VEHICLES; REMOVABLE EXTERNAL PROTECTIVE COVERINGS SPECIALLY ADAPTED FOR VEHICLES
    • B60J1/00—Windows; Windscreens; Accessories therefor
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B11/00—Pressing molten glass or performed glass reheated to equivalent low viscosity without blowing
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B18/00—Shaping glass in contact with the surface of a liquid
    • C03B18/02—Forming sheets
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B19/00—Other methods of shaping glass
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B37/00—Manufacture or treatment of flakes, fibres, or filaments from softened glass, minerals, or slags
    • C03B37/01—Manufacture of glass fibres or filaments
    • C03B37/02—Manufacture of glass fibres or filaments by drawing or extruding, e.g. direct drawing of molten glass from nozzles; Cooling fins therefor
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B5/00—Melting in furnaces; Furnaces so far as specially adapted for glass manufacture
    • C03B5/04—Melting in furnaces; Furnaces so far as specially adapted for glass manufacture in tank furnaces
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B5/00—Melting in furnaces; Furnaces so far as specially adapted for glass manufacture
    • C03B5/16—Special features of the melting process; Auxiliary means specially adapted for glass-melting furnaces
    • C03B5/225—Refining
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B5/00—Melting in furnaces; Furnaces so far as specially adapted for glass manufacture
    • C03B5/16—Special features of the melting process; Auxiliary means specially adapted for glass-melting furnaces
    • C03B5/235—Heating the glass
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B9/00—Blowing glass; Production of hollow glass articles
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C13/00—Fibre or filament compositions
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/02—Surface treatment of glass, not in the form of fibres or filaments, by coating with glass
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C3/00—Glass compositions
    • C03C3/04—Glass compositions containing silica
    • C03C3/062—Glass compositions containing silica with less than 40% silica by weight
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C3/00—Glass compositions
    • C03C3/04—Glass compositions containing silica
    • C03C3/062—Glass compositions containing silica with less than 40% silica by weight
    • C03C3/064—Glass compositions containing silica with less than 40% silica by weight containing boron
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C3/00—Glass compositions
    • C03C3/04—Glass compositions containing silica
    • C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
    • C03C3/083—Glass compositions containing silica with 40% to 90% silica, by weight containing aluminium oxide or an iron compound
    • C03C3/085—Glass compositions containing silica with 40% to 90% silica, by weight containing aluminium oxide or an iron compound containing an oxide of a divalent metal
    • C03C3/087—Glass compositions containing silica with 40% to 90% silica, by weight containing aluminium oxide or an iron compound containing an oxide of a divalent metal containing calcium oxide, e.g. common sheet or container glass
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00—Use of ingredients characterised by shape
    • C08K7/02—Fibres or whiskers
    • C08K7/04—Fibres or whiskers inorganic
    • C08K7/14—Glass
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L101/00—Compositions of unspecified macromolecular compounds
    • E—FIXED CONSTRUCTIONS
    • E06—DOORS, WINDOWS, SHUTTERS, OR ROLLER BLINDS IN GENERAL; LADDERS
    • E06B—FIXED OR MOVABLE CLOSURES FOR OPENINGS IN BUILDINGS, VEHICLES, FENCES OR LIKE ENCLOSURES IN GENERAL, e.g. DOORS, WINDOWS, BLINDS, GATES
    • E06B3/00—Window sashes, door leaves, or like elements for closing wall or like openings; Layout of fixed or moving closures, e.g. windows in wall or like openings; Features of rigidly-mounted outer frames relating to the mounting of wing frames
    • E06B3/54—Fixing of glass panes or like plates
    • E06B3/58—Fixing of glass panes or like plates by means of borders, cleats, or the like
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F41—WEAPONS
    • F41H—ARMOUR; ARMOURED TURRETS; ARMOURED OR ARMED VEHICLES; MEANS OF ATTACK OR DEFENCE, e.g. CAMOUFLAGE, IN GENERAL
    • F41H5/00—Armour; Armour plates
    • F41H5/06—Shields
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • G—PHYSICS
    • G02—OPTICS
    • G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333—Constructional arrangements; Manufacturing methods
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00—Layers arrangement
    • B32B2250/40—Symmetrical or sandwich layers, e.g. ABA, ABCBA, ABCCBA
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2571/00—Protective equipment
    • B32B2571/02—Protective equipment defensive, e.g. armour plates, anti-ballistic clothing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2605/00—Vehicles
    • B32B2605/08—Cars
    • G—PHYSICS
    • G02—OPTICS
    • G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333—Constructional arrangements; Manufacturing methods
    • G02F1/133302—Rigid substrates, e.g. inorganic substrates

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Abstract

A kind of process superelevation lead glass product produced using new lateral flame furnace production system of the present invention, alumina content reaches 20--49%, and it is higher in calcium oxide content -- [silica content is 2.51-5.8 times of calcium oxide content, and calcium oxide content is 0.8 times -2.3 times of range of content of magnesia]；Technical solution of the present invention belongs to a kind of invention of claim to a product comprising preparation method characteristic, and not only product compares the composition and structure of prior art documents, has novelty；And the process that the present invention innovates, than prior art product, alumina content can be resulted in up to the micro-variations and progress inside the glassware of 20--49%, the present invention more first has superelevation lead glass product, could micro-variations and progress inside the glassware really with different, stable-[translucency, high intensity, lightening, lightweight performance] product feature.

Description

A kind of process superelevation produced using new lateral flame furnace production system Lead glass product
[technical field]
The invention belongs to glass technology fields, are related to a kind of process using lateral flame furnace production system, institute The superelevation lead glass product of production.
Technical solution of the present invention:
Belong to a kind of invention of claim to a product comprising preparation method characteristic, not only product compares prior art comparison The composition and structure of file have novelty；And the process that the present invention innovates can be resulted in than prior art product Alumina content more first has superelevation lead glass system up to the micro-variations and progress inside the glassware of 20--49%, the present invention Product, could be inside the glassware really with different, stable-[translucency, high intensity, lightening, lightweight performance] Micro-variations and progress product feature.
The present invention [a kind of process using new lateral flame furnace production system, superelevation lead glass system produced Product] in the field of electronic plane glass, building and industrial plate glass, glass fibre, industry or utility glass ware and device In, produce the technical effect given unexpectedly.
The present invention [a kind of process using new lateral flame furnace production system, superelevation lead glass system produced Product] it represents in these fields, a kind of technology trends；Invention also overcomes in these above-mentioned purposes fields, Ren Menke Hope the technical problem that solves but must not succeed always.
[prior art]
(1) first have correlation technique 1: the present inventor's first has invention: having the high intensity of high annealing point and environment-friendly and energy-saving emission-reduction The application of the plate glass of high-flatness low-viscosity and associated components, the patent No. 201110060944.4.
(2) first have the 2 of invention: the 201510161553.61 of the present inventor, a kind of plate glass with low thermal coefficient of expansion Glass and its preparation process.
(3) first have the 3 of invention: the present inventor's: PCT/CN2015/000795, a kind of high-temperature region thermal expansion coefficient it is low The application of difference, low crystallization speed, superhigh intensity, high softening-point, fire-proof and explosion-proof plate glass.
(4) first have the 4 of invention: the present inventor's: PCT/CN2015/000793, a kind of low crystallization temperature, low crystallization speed Degree, high temperature resistant, extra-high lead glass fiber application and preparation method thereof, composite material.
(5) first have the 5 of invention: the present inventor's: PCT/CN2015/000794, a kind of high-temperature region thermal expansion coefficient it is low The application of difference, low crystallization speed, high softening-point, high temperature resistant explosion-proof glassware or glass daily necessities.
(6) in the prior art, the electronic plane cover board gorilla 1-4 generation of Corning Incorporated, 15-22% aluminium oxide； But it is lower than 1% containing calcium oxide, is not that [silica content is 2.51-5.8 times of calcium oxide content, calcium oxide content in the present invention 0.8 times -2.3 times of content of magnesia] range.
In the prior art, S grades of glass aluminium oxide containing 23-25-26%, ----but it is lower than 1% containing calcium oxide, nor [silica content is 2.51-5.8 times of calcium oxide content to the present invention, and calcium oxide content is 0.8 times -2.3 of content of magnesia Range again].
And above-mentioned prior art, all use-only has about 10CM diameter platinum channel technology, yield very little in technique； Technology production method of the invention is not used.
(7) first there are the molten kiln technology of electricity and flame kiln technology, the All Electric Melting Furnace glassware production of the prior art Device, middle aluminum products, the aluminium oxide that low aluminum products, the alumina content that main production alumina content is 1-4% are 5-9% contain Amount is the high alumina products of 10-16%.
First there are the molten kiln technology of electricity and flame kiln technology, several technology essential factors without present invention process method Jie Ju feature, so, first there is the molten kiln technology of electricity, without the process conditions for overcoming its technological difficulties.
First there are the molten kiln technology of electricity and flame kiln technology, mainly considers and dissolve glass and exhaust bubble and homogenizing glass Glass liquid, it is desirable to which the electric field [temperature field] formed between electrode is uniformly for basic goal.It plays and asks without the present invention, more The specific region position of the glass metal in the region apart from bottom refractory material 5-30CM in a region, design have 3-20 electrode The requirement of device, and without the present invention play ask in multiple regions, the region away from refractory material bottom 5-30CM distance Glass metal in, the work technological temperature in the section of a minimum of 100 cubes of CM volumes will be maintained at 1320 DEG C -1450 DEG C, high In the process of 20-80 DEG C of technological temperature of the work of the region glass metal apart from bottom refractory material 30-60CM distance.
Firstly, the present invention [a kind of process using new lateral flame furnace production system, superelevation aluminium glass produced Glass product] from first have the constituent structure of invention (1)-(7) technical solution and any prior art proposal all different: the present invention -- By weight percentage, alumina content 20%-49%；Content of magnesia is 5%--20%, and silica content is oxidation 2.51-5.8 times of calcium content, calcium oxide content are 0.8 times -2.3 times of content of magnesia；So the present invention has novelty.
In addition, the preparation method of process characteristic of the present invention, and first there is invention (1)-(7) technical solution and any Prior art proposal is also all different.Preparation method characteristic of the present invention could generate and first have similar products entirely different , [absolutely not milky rich aluminum strip line or rich aluminium block in glass, without the feature of glass layering, alumina content Up to the glassware of 20--49%].
And if not using preparation method characteristic of the present invention, alumina content reaches the glassware of 20--49% In, it will be easy to the opaque significant deficiency there are milky rich aluminum strip line or milky rich aluminium block, or glass occur The significant deficiency problem of glass layering.
[summary of the invention]
A kind of process superelevation lead glass product produced using new lateral flame furnace production system
The composition of [A] glassware is: by weight percentage, alumina content 20%-49%；Content of magnesia For 5%--20%, silica content is 2.51-5.8 times of calcium oxide content, calcium oxide content is 0.8 times of content of magnesia- 2.3 again；
A kind of [B] process using new lateral flame furnace production system is:
(a), lateral flame furnace production system equipment is got out, comprising:
Flame thermal energy dominates the lateral flame furnace Jie Ju device (10) of glass melting；The card neck flow passage device of glass metal (60)；Temperature controlled clarification, exhaust bubble and anti-crystallization device (30) are carried out to the glass metal flowed from the top to the bottom using electrode； Bottom flow liquid channel (20)；Using electrode, temperature controlled glass metal rising passway is carried out to the glass metal flowed from bottom to top Structure (40)；The molding machine (50) of glassware:
In the card neck flow passage device (60) of its glass metal, depth between the surface and bottom of device of glass metal is flame Thermal energy dominate glass melting lateral flame furnace Jie Ju device (10) and using electrode to the glass metal flowed from the top to the bottom into The clarification of trip temperature control is vented in bubble and anti-crystallization device (30), the depth between the surface and bottom of device of glass metal 10%-40%；In glass metal in the region apart from bottom refractory material 5-30CM of the card neck flow passage device (60) of glass metal, if In respect of 3-20 electrode assembly；
It uses electrode to carry out temperature controlled clarification, exhaust bubble and anti-crystallization device to the glass metal flowed from the top to the bottom (30) surrounding design has the electrode of 4-50 control temperature of glass liquid, is carried out using electrode to the glass metal flowed from the top to the bottom Glass metal in the region apart from bottom refractory material 5-30CM of temperature controlled clarification, exhaust bubble and anti-crystallization device (30) In, design has 3-20 electrode assembly；
Its bottom flow liquid channel (20), in the glass metal in region apart from bottom refractory material 5-30CM, design has 3- 20 electrode assemblies；
It uses electrode to carry out temperature controlled glass metal rise channel s structure to the glass metal flowed from bottom to top -- (40) surrounding design has the electrode of 4-50 control temperature of glass liquid；Rise channel s structure (40) apart from bottom refractory material 5- In glass metal in the region of 30CM, design has 3-20 electrode assembly；
Required device: flame thermal energy dominates the lateral flame furnace Jie Ju device (10) of glass melting, the card of glass metal Neck flow passage device (60) carries out temperature controlled clarification, exhaust bubble and anti-analysis to the glass metal flowed from the top to the bottom using electrode Brilliant device (30) carries out temperature controlled glass metal rise channel s structure to the glass metal flowed from bottom to top using electrode (40), the molding machine (50) of glassware；Electrode energy in these devices, can be in the molding machine of glassware (50) when stopping working, the glass metal in respective device is made to be maintained at 1300 DEG C or more, Asia is maintained at higher than devitrification of glass temperature On；
(b) a kind of process of new lateral flame furnace production system is come the superelevation lead glass product that produces, technique Process:
Get required device ready: flame thermal energy dominates the lateral flame furnace Jie Ju device (10) of glass melting, glass metal Card neck flow passage device (60), using electrode to the glass metal that flows from the top to the bottom carry out temperature controlled clarification, exhaust bubble and Anti- crystallization device (30) carries out temperature controlled glass metal rise channel s structure to the glass metal flowed from bottom to top using electrode (40), the molding machine (50) of glassware；Electrode energy in these devices, can be in the molding machine of glassware (50) when stopping working, the glass metal in respective device is made to be maintained at 1300 DEG C or more, Asia is maintained at higher than devitrification of glass temperature On；
Step 1. is scheduled glass raw material, by glass raw material transport device, dominates glass melting into flame thermal energy Lateral flame furnace Jie Ju device (10) in, carry out dissolving to form glass metal, glass metal passes through the card neck runner of glass metal again Device (60), enters from upper lateral part using electrode, carries out temperature controlled clarification to the glass metal flowed from the top to the bottom, exhaust is steeped In anti-crystallization device (30)；And makes card neck flow passage device (60) and temperature is carried out to the glass metal flowed from the top to the bottom using electrode The clarification of control, the temperature of exhaust bubble and the glass metal in anti-crystallization device (30) are spent, control is being higher than clarification, row's bubble 102 Pa Sec viscosity temperature on section and higher than the section on devitrification of glass temperature；
Process characteristic is: passing through the region apart from bottom refractory material 5-30CM of the card neck flow passage device (60) of glass metal In glass metal in, 3-20 electrode assembly of design makes card neck flow passage device (60) region, away from refractory material bottom 10- In the glass metal in the region of 30CM distance, the work technological temperature in the section of a minimum of 100 cubes of CM volumes will be maintained at 1320 DEG C -1450 DEG C, it is higher than 20-80 DEG C of the work technological temperature of the region glass metal apart from bottom refractory material 30-60CM distance；
Process characteristic is: carrying out temperature controlled clarification, exhaust bubble and anti-analysis by the glass metal flowed from the top to the bottom In glass metal in the region apart from bottom refractory material 5-30CM of brilliant device (30) design, respective 3-20 electrode assembly, The glass metal flowed from the top to the bottom is set to carry out temperature controlled clarification, exhaust bubble and anti-crystallization device (30) region, away from fire resisting In the glass metal in the region of material bottom 5-30CM distance, the work technological temperature in the section of a minimum of 100 cubes of CM volumes is wanted 1320 DEG C -1450 DEG C are maintained at, the work process warm of the region glass metal apart from bottom refractory material 30-60CM distance is higher than 20-80 DEG C of degree；
Step 2. makes glass metal from using electrode, carries out temperature controlled clarification, row to the glass metal flowed from the top to the bottom Bubble and anti-crystallization device (30) lower part, the bottom flow liquid channel (20) of entrance enter back into one be coupled and use electrode pair The glass metal flowed from bottom to top carries out temperature controlled glass metal rise channel s structure (40)；
Process characteristic is: the region by what is designed in bottom flow liquid channel (20), apart from bottom refractory material 5-30CM In glass metal in, 3-20 electrode assembly of design makes bottom flow liquid channel (20) region, away from refractory material bottom 5- In the glass metal in the region of 30CM distance, the work technological temperature in the section of a minimum of 100 cubes of CM volumes will be maintained at 1320 DEG C -1450 DEG C, it is higher than 20-80 DEG C of the work technological temperature of the region glass metal apart from bottom refractory material 30-60CM distance；
Process characteristic is: carrying out on temperature controlled glass metal by using electrode to the glass metal flowed from bottom to top Design in channel design (40) is risen, in the glass metal in region apart from bottom refractory material 5-30CM, 3-20 electricity of design Pole device makes bottom flow liquid channel (20) region, in the glass metal in the region away from refractory material bottom 5-30CM distance, at least There is the work technological temperature in the section of 100 cubes of CM volumes, to be maintained at 1320 DEG C -1450 DEG C, be higher than apart from bottom refractory 20-80 DEG C of the work technological temperature of the region glass metal of material 30-60CM distance；
Process characteristic is: by the glass metal in its region apart from bottom refractory material 5-30CM, the 3-20 of design A electrode assembly makes bottom flow liquid channel (20) region, in the glass metal in the region away from refractory material bottom 5-30CM distance, The work technological temperature in the section of a minimum of 100 cubes of CM volumes, will be maintained at 1320 DEG C -1450 DEG C, be higher than apart from bottom 20-80 DEG C of the work technological temperature of the region glass metal of refractory material 30-60CM distance；
Step 3. glass metal by bottom flow liquid channel (20), carries out the glass metal flowed from bottom to top into electrode again Temperature controlled glass metal rise channel s structure (40)；
Process characteristic is: by the glass metal in its region apart from bottom refractory material 5-30CM, the 3-20 of design A electrode assembly carries out temperature controlled glass metal rise channel s structure (40) to the glass metal flowed from bottom to top using electrode Region, in the glass metal in the region away from refractory material bottom 5-30CM distance, the work in the section of a minimum of 100 cubes of CM volumes Make technological temperature, to be maintained at 1320 DEG C -1450 DEG C, is higher than the region glass apart from bottom refractory material 30-60CM distance 20-80 DEG C of the work technological temperature of liquid；
The selection of step 4. moulding process:
The selection of the first glassware moulding process: the glass of the top exit above-mentioned by rise channel s structure (40) Glass liquid, into the molding machine (5) of glassware；The molding machine (5) of its glassware is the tin of float flat glass technique Kiln structure；Glass metal enters the smooth plane for being furnished with the tin metal dissolved of tin kiln structure, carry out glass metal time divide it is thin and Polishing；Required thickness is pulled into glass tape of the edge machine to formation by the 10-40 on both sides again；Using annealing, material process, shape are cut At float flat glass product；Or
The selection of second of glassware moulding process: the glass of the top exit above-mentioned by rise channel s structure (40) Glass liquid, into the sprue of glass metal, glass metal, which enters to be coupled, 2-30 glass metal runner；Glass metal enters each point The molding machine of the glass fibre production for the glassware that runner is coupled；Separately flow into corresponding 2-30 bearing glass liquid Dry crucible, glass metal pass through corresponding 2-30 bushing, form glass fibre under the action of corresponding wire drawing machine；Or
The selection of the third glassware moulding process: the glass of the top exit above-mentioned by rise channel s structure (40) Glass liquid, into the sprue of glass metal, glass metal, which enters to be coupled, 2-30 glass metal runner；Glass metal enters each point The blow molding device of 2-30 industry and utility glass ware of the glassware that runner is coupled；Be blow molded into respectively industry with The product of domestic glass；Using the processing of the annealing device of glassware, the blow molding system of industry with domestic glass is made Product；Or
The selection of 4th kind of glassware moulding process: the glass of the top exit above-mentioned by rise channel s structure (40) Glass liquid, into the sprue of glass metal, glass metal, which enters to be coupled, 2-30 glass metal runner；Glass metal enters each point The compression molding device of 2-30 industry and utility glass ware of the glassware that runner is coupled；Be pressed into respectively industry with The product of domestic glass；Using the processing of the annealing device of glassware, the compression moulding system of industry with domestic glass is made Product；Or
The selection of 5th kind of glassware moulding process: the glass of the top exit above-mentioned by rise channel s structure (40) Glass liquid, into the sprue of glass metal, glass metal, which enters to be coupled, 2-30 glass metal runner；Glass metal enters each point The drawing molding device of 2-30 of the glassware that runner is coupled industry and domestic glass, be drawn into respectively industry with it is daily The product of glass；Using the processing of the annealing device of glassware, the drawing moulded products of industry with domestic glass are made；Or
The selection of 6th kind of glassware moulding process: the glass of the top exit above-mentioned by rise channel s structure (40) Glass liquid, into the sprue of glass metal, glass metal, which enters to be coupled, 2-30 glass metal runner；Glass metal enters each point The blow molding device of 2-30 bathroom glassware of the glassware that runner is coupled, is respectively prepared bathroom glassware； Using the processing of the annealing device of glassware, bathroom glassware is made.
A kind of windowpane, comprising being equipped with resin edge or metal edge frame support device on glass surrounding；Its feature exists In: its glass is that a kind of [process superelevation lead glass product produced of new lateral flame furnace production system] right is wanted Plate glass described in asking 1.
A kind of colored glaze plate glass, it is characterised in that: glass surface has the glazed colour layer of 1~10 kind of color；Its glass is [one The process superelevation lead glass product produced of the new lateral flame furnace production system of kind] plate described in claim 1 Glass.
A kind of hollow glass, comprising having support device on each layer glass surrounding；There is the warp of 3-50mm between each layer glass The insulating space vacuumized；It is characterized by: its glass is that [a kind of process of new lateral flame furnace production system is given birth to The superelevation lead glass product of production] plate glass described in claim 1.
A kind of glass of building curtain wall, glass are fixed in metal support device；It is characterized by: its glass is [a kind of process superelevation lead glass product produced of new lateral flame furnace production system] is described in claim 1 flat Glass sheet.
A kind of building thin glass window of overlarge area, it is characterised in that: its glass with a thickness of 4~10mm, glass Size be 3~40 square metres or its glass with a thickness of .4-20mm, the size of glass is 15.1~80 square metres；Its glass Glass is described in a kind of [process superelevation lead glass product produced of new lateral flame furnace production system] claim 1 Plate glass.
A kind of tempered glass, it is characterised in that: glass is by chemical tempering or physical toughened is made；Its glass is [a kind of The process superelevation lead glass product produced of new transverse direction flame furnace production system] plate glass described in claim 1 Glass.
A kind of tempered glass table top furniture, is characterized in that: support device is arranged at its table top lower part；Its glass is a kind of [new cross To the process superelevation lead glass product produced of flame furnace production system] plate glass described in claim 1.
A kind of doubling glass, is characterized in that: having resin material layer between its each layer glass；Its glass is a kind of [new cross To the process superelevation lead glass product produced of flame furnace production system] plate glass described in claim 1.
A kind of shellproof implosion guard, is characterized in that: its each glass sheets is bonded by resin sheet；Its glass is [a kind of new The process of lateral flame furnace production system superelevation lead glass product produced] plate glass described in claim 1.
A kind of colored glazed glass plate combined cabinet, it is characterised in that: there is the colored glaze of 1~10 kind of color at its glass surface or the back side Layer；Colored glazed glass plate combined cabinet plate glass surrounding has metal edge frame encirclement；In colored glazed glass plate combined cabinet metal edge frame Between have metal coupling arrangement；Its glass is a kind of [process superelevation produced of new lateral flame furnace production system Lead glass product] plate glass described in claim 1.
A kind of colored glazed glass board group conjunction sliding door cabinet, it is characterised in that: there is 1- at combination sliding door cabinet glass surface or the back side The glazed colour layer of 10 kinds of colors；Combination sliding door cabinet glass surrounding has metal edge frame；The upper and lower of metal edge frame has idler wheel；Its glass is [a kind of process superelevation lead glass product produced of new lateral flame furnace production system] is described in claim 1 flat Glass sheet.
A kind of colored glazed glass plate combined garderobe, it is characterised in that: there is 1-10 at glass plate combined garderobe glass surface or the back side The glazed colour layer of kind color；The colored glazed glass surrounding has metal edge frame encirclement, there is metal coupling arrangement between metal edge frame；Its Glass is a kind of [process superelevation lead glass product produced of new lateral flame furnace production system] claim 1 institute The plate glass stated.
A kind of colored glaze table top glass furniture, it is characterised in that: there is the coloured silk of 1-10 kind color on the surface or the back side of glass table top Support device is arranged at glaze layer, table top lower part；Its glass is that [a kind of process of new lateral flame furnace production system is produced Superelevation lead glass product] plate glass described in claim 1.
A kind of photovoltaic solar device, it is characterised in that: photovoltaic solar device includes solar battery and glass base Plate or outer cover plate；Its glass is a kind of [process superelevation lead glass system produced of new lateral flame furnace production system Product] plate glass described in claim 1.
A kind of thin film solar device, it is characterised in that: thin film solar device includes: thin-film solar cells；Its glass Glass is described in a kind of [process superelevation lead glass product produced of new lateral flame furnace production system] claim 1 Plate glass.
A kind of liquid crystal display, the liquid crystal display include: multiple substrate, which includes substrate, in the substrate On dot structure, which is a kind of composition described in claims 1 in superelevation alumina content, superhigh intensity, high softening-point The application of glass；
Filter substrate, the filter substrate include substrate and color-filter layer on this substrate, which is glass Substrate；
Liquid crystal layer is folded between the multiple substrate and the filter substrate；And back light source system；
It is characterized by: its glass is a kind of [process superelevation produced of new lateral flame furnace production system Lead glass product] plate glass described in claim 1.
A kind of low temperature polycrystalline silicon display screen comprising: low temperature polycrystalline silicon multiple substrate, the multiple substrate include substrate and The dot structure produced using low temperature polysilicon process in the substrate；
Filter substrate, the filter substrate include substrate and color-filter layer on this substrate, which is glass Substrate；
Liquid crystal layer is folded between the multiple substrate and the filter substrate；And
Back light source system；
It is characterized by: its glass is a kind of [process superelevation produced of new lateral flame furnace production system Lead glass product] plate glass described in claim 1.
A kind of curved surface liquid crystal display,
Include:
Base plate glass；
Multiple substrate, the multiple substrate include substrate and dot structure on this substrate, which is glass plate；
Filter substrate, the filter substrate include substrate and color-filter layer on this substrate, which is glass Substrate；
Liquid crystal layer is folded between the multiple substrate and the filter substrate；And back light source system；
It is characterized by: its glass is a kind of [process superelevation produced of new lateral flame furnace production system Lead glass product] plate glass described in claim 1.
A kind of display front or back shell mechanism, it is characterised in that: its glass is a kind of [transverse direction flame furnace production The process of system superelevation lead glass product produced] plate glass described in claim 1.
A kind of shellproof explosion-proof vehicle structure, it includes 1~3 layer of glass of 1~10 vehicle window, each glass sheets by Resin sheet bonding；
The metal plate of the surrounding of automobile has ballistic structure in metal frame；
And power device；Instrument board；Direction controller；Automobile case；Automobile chassis；Automobile braking device；Automotive wheels Tire；
It is characterized by: its glass is a kind of [process superelevation produced of new lateral flame furnace production system Lead glass product] plate glass described in claim 1.
A kind of rob-proof, antitheft, explosion-proof, anticollision, anti-roll injure automobile, it includes: 1~3 layer of 1~10 vehicle window Glass, bulletproof glass be as described in claims 1 a kind of composition in superelevation alumina content, superhigh intensity, high softening-point glass Application；And power device；Instrument board；Direction controller；Automobile case；Automobile chassis；Automobile braking device；Automotive wheels Tire；It is characterized by: its glass is a kind of [process superelevation lead glass produced of new lateral flame furnace production system Product] plate glass described in claim 1.
A kind of Helios, it includes: there is the device for a chain for binding criminals rotation paddle power for pushing flight, wing, Driving control System and device and a kind of thin film solar device include: thin-film solar cells；Base plate glass on thin film solar device； It is characterized by: its glass is a kind of [process superelevation lead glass system produced of new lateral flame furnace production system Product] plate glass described in claim 1.
A kind of composite plate of colored glaze plate glass and metal layer, include: there is the coloured silk of 1~10 kind of color on its base plate glass surface Glaze layer, the sheet metal of 0.1~5mm thickness have one layer of bonding material layer between above-mentioned glass plate and sheet metal；Its feature Be: its glass is a kind of [process superelevation lead glass product produced of new lateral flame furnace production system] right It is required that plate glass described in 1.
A kind of colored glazed glass composite panel includes: there is a glazed colour layer of 1~10 kind of color on its base plate glass surface, 0.1~ The sheet metal of 5mm thickness has one layer of bonding material layer between above-mentioned glass plate and sheet metal, it is characterised in that: it is made 2~4 sides of the metal plate in the back end face of the composite plate of product, the edge of the surface layer colored glaze decorative flat glass product of specific gravity poststack The distance of 10~30mm is stretched out；It is characterized by: its glass is a kind of [process of new lateral flame furnace production system Superelevation lead glass product produced] plate glass described in claim 1.
A kind of colored glazed glass composite floor includes: its backplane level or wood plank；Either sheet of metallic material； Either plank composite plate；Either wood powder grain composite plate；Either resinous wood flitch；It is characterized by: its glass is [a kind of The process superelevation lead glass product produced of new transverse direction flame furnace production system] plate glass described in claim 1 Glass.
A kind of glass washbowl structure, it is characterised in that: its glass is a kind of [work of new lateral flame furnace production system Process superelevation lead glass product produced] glass described in claim 1.
A kind of glass lift panel and conjuncted washbowl, structure feature be, the glass of 1. plane shapes lifts panel, 2. Its another conjuncted part is glass washbowl；It is characterized by: its glass is a kind of [new lateral flame furnace production system The process of system superelevation lead glass product produced] glass described in claim 1.
A kind of super long glass plate that balcony protection is blocked, the length for the glass plate that balcony protection is blocked are 3~8m；Its feature exists In: its glass is that a kind of [process superelevation lead glass product produced of new lateral flame furnace production system] right is wanted Plate glass described in asking 1.
A kind of shelter object structure, comprising: metope structure, ground structure, deck structure, door, windowpane knot Structure, the bulletproof glass or the bulletproof glass in door of glazing structure；It is characterized by: its glass is a kind of [new transverse direction The process of flame furnace production system superelevation lead glass product produced] plate glass described in claim 1.
A kind of glass back shell of display, glass back shell or to be planar or are at glass back shell The curve form of 3D is attached to one layer of colored glaze layer on glass back shell, or is attached to the structure with spectra features Layer；It is characterized by: its glass is a kind of [process superelevation lead glass produced of new lateral flame furnace production system Product] plate glass described in claim 1.
A kind of glass back shell mechanism in display device structure, glass back shell or be it is planar, after glass Shell or the curve form for 3D are carried on the back, one layer of colored glaze layer is attached on glass back shell, or be attached to grating The structure sheaf of feature；It is characterized by: its glass is that [a kind of process of new lateral flame furnace production system is produced Superelevation lead glass product] glass described in claim 1.
A kind of glass fiber compound material includes: plastic substrate, and the glass fibre in insertion plastic substrate；It is special Sign is: its glass fibre is a kind of [process superelevation lead glass system produced of new lateral flame furnace production system Product] glass described in claim 1.
A kind of wind-powered electricity generation glass fiber compound material blade includes: plastic substrate, and the glass in insertion plastic substrate Fiber, manufactured composite material, manufactured wind-powered electricity generation blade；
Air blade composition: glass fiber compound material air blade leaf shell；Glass fiber compound material air blade blade root；Glass Fibrous composite fan blade chip architecture crossbeam；
It is characterized by: its glass fibre is that [a kind of process of new lateral flame furnace production system is produced Superelevation lead glass product] glass described in claim 1.
A kind of glass fiber compound material aircraft casing includes: plastic substrate, and the glass in insertion plastic substrate Fiber, manufactured composite material, manufactured aircraft casing structure；It is characterized by: its glass fibre is a kind of [new transverse direction The process of flame furnace production system superelevation lead glass product produced] glass described in claim 1.
A kind of water craft of glass fiber compound material structure,
Comprising plastic substrate, and
The glass fibre being embedded in plastic substrate, manufactured composite material, manufactured Ship Structure；Power device；It drives Sail cabin；Boat deck；
It is characterized by: its glass fibre is that [a kind of process of new lateral flame furnace production system is produced Superelevation lead glass product] glass described in claim 1.
A kind of glass fiber compound material chemical industry pipe structure includes the glass in plastic substrate, and insertion plastic substrate Fiber, manufactured composite material, manufactured chemical industry or petroleum pipeline or natural gas composite material conduit；
It is characterized by: its glass fibre is that [a kind of process of new lateral flame furnace production system is produced Superelevation lead glass product] glass described in claim 1.
A kind of glass fiber compound material shell or the automobile on chassis, it includes: plastic substrate, and, it is embedded in plastics base Vehicle shell or automobile chassis manufactured by glass fibre in body；Automobile window construction；And power device；Instrument board；Direction Controller；Automobile case；Automobile chassis；Automobile braking device；Automobile tire；It is characterized by: its glass fibre is [a kind of new The process of lateral flame furnace production system superelevation lead glass product produced] glass described in claim 1.
A kind of wind power generation device structure, it includes: air blade includes plastic substrate, and insertion plastics
Glass fibre in matrix, phoenix electricity blade made of manufactured composite material；It further include bearing；Generator； Wind tower pillar；It is characterized by: its glass fibre is that [a kind of process of new lateral flame furnace production system is produced Superelevation lead glass product] glass described in claim 1.
A kind of daily utensil glass and industrial glassware, it is characterised in that: its glass is a kind of [cross
To the process superelevation lead glass product glass described in claim 1 produced of flame furnace production system Glass].
A kind of glass insulator product, it is characterised in that: its glass fibre is a kind of [new lateral flame furnace production system Process superelevation lead glass product produced] glass described in claim 1.
A kind of glass toilet seat product, it is characterised in that: its glass is a kind of [work of new lateral flame furnace production system Process superelevation lead glass product produced] glass described in claim 1.
Detailed description of the invention
Fig. 1 and Figure of abstract are that a kind of process using new lateral flame furnace production system of the present invention is produced Superelevation lead glass product, flat glass product floor map；
Fig. 2 is a kind of process superelevation lead glass produced using new lateral flame furnace production system of the present invention Product, glass fiber product section schematic diagram；
Fig. 3 is a kind of process superelevation lead glass produced using new lateral flame furnace production system of the present invention Product, blow-molded glass product diagrammatic cross-section；
Fig. 4 is a kind of process superelevation lead glass produced using new lateral flame furnace production system of the present invention Product, drawing glass tube product diagrammatic cross-section；
Fig. 5 is a kind of process superelevation lead glass produced using new lateral flame furnace production system of the present invention Product, pressed glass product diagrammatic cross-section；
Fig. 6 is a kind of process superelevation lead glass produced using new lateral flame furnace production system of the present invention Product, process equipment composition side diagrammatic cross-section.
Fig. 7 is a kind of process superelevation lead glass produced using new lateral flame furnace production system of the present invention The flow diagram of the float glass preparation process of product.
Fig. 8 is a kind of process superelevation lead glass produced using new lateral flame furnace production system of the present invention The flow diagram of the glass fibre preparation process of product.
Fig. 9 is a kind of process superelevation lead glass produced using new lateral flame furnace production system of the present invention The sectional drawing in the bottom flow liquid channel (20) of product.
Symbol description
Fig. 6 is a kind of process superelevation lead glass produced using new lateral flame furnace production system of the present invention Product, process equipment composition side diagrammatic cross-section:
Symbol 10 indicates that flame thermal energy dominates the lateral flame furnace Jie Ju device of glass melting；
The expression of symbol 60, the card neck flow passage device of glass metal；
Symbol 30 indicates to carry out temperature controlled device to the glass metal flowed from the top to the bottom using electrode；
Symbol 40 indicates to use electrode, to the temperature controlled glass metal rising passway of glass metal progress flowed from bottom to top Structure；
20 symbol of symbol indicates bottom flow liquid channel；
The expression of symbol 50, the molding machine of glassware；
Symbol 8 indicates the electrode (8) in glass metal；
The electric heater unit (9) of the expression glass metal upper layer space of planes of symbol 9；
Fig. 7 is a kind of process superelevation lead glass produced using new lateral flame furnace production system of the present invention The flow diagram of the float glass preparation process of product:
Symbol 10 indicates that flame thermal energy dominates the lateral flame furnace Jie Ju device of glass melting；
The expression of symbol 60, the card neck flow passage device of glass metal；
Symbol 30 indicates to carry out temperature controlled device to the glass metal flowed from the top to the bottom using electrode；
Symbol 40 indicates to use electrode, to the temperature controlled glass metal rising passway of glass metal progress flowed from bottom to top Structure；
20 symbol of symbol indicates bottom flow liquid channel；
The expression of symbol 50, the molding machine of glassware.
Fig. 8 is a kind of process superelevation lead glass produced using new lateral flame furnace production system of the present invention The flow diagram of the glass fibre preparation process of product:
Symbol 10 indicates that flame thermal energy dominates the lateral flame furnace Jie Ju device of glass melting；
The expression of symbol 60, the card neck flow passage device of glass metal；
Symbol 30 indicates to carry out temperature controlled device to the glass metal flowed from the top to the bottom using electrode；
Symbol 40 indicates to use electrode, to the temperature controlled glass metal rising passway of glass metal progress flowed from bottom to top The glass metal of structure；
20 symbol of symbol indicates bottom flow liquid channel (20)；
The expression of symbol 50, the molding machine of fiberglass products.
Specific embodiment
Illustrating embodiments of the present invention referring to schema, it is noted that following figures system is the signal schema of simplification, And the basic conception that only the invention is illustrated in a schematic way, the structure related with the present invention is only illustrated in schema then rather than according to reality Component count, shape and size when border is implemented are drawn, when actual implementation each component kenel, quantity and ratio not to scheme It is shown as limiting, can need to make to change according to actual design, conjunction is first chatted bright.
The present invention, a kind of process superelevation lead glass product produced using new lateral flame furnace production system Embodiment:
The composition of [A] glassware is: by weight percentage, alumina content 20%-49%；Content of magnesia For 5%--20%, silica content is 2.51-5.8 times of calcium oxide content, calcium oxide content is 0.8 times of content of magnesia- 2.3 again；
A kind of [B] process using new lateral flame furnace production system is:
(a), lateral flame furnace production system equipment is got out, comprising:
Flame thermal energy dominates the lateral flame furnace Jie Ju device (10) of glass melting；The card neck flow passage device of glass metal (60)；Temperature controlled clarification, exhaust bubble and anti-crystallization device (30) are carried out to the glass metal flowed from the top to the bottom using electrode； Bottom flow liquid channel (20)；Using electrode, temperature controlled glass metal rising passway is carried out to the glass metal flowed from bottom to top Structure (40)；The molding machine (50) of glassware:
In the card neck flow passage device (60) of its glass metal, depth between the surface and bottom of device of glass metal is flame Thermal energy dominate glass melting lateral flame furnace Jie Ju device (10) and using electrode to the glass metal flowed from the top to the bottom into The clarification of trip temperature control is vented in bubble and anti-crystallization device (30), the depth between the surface and bottom of device of glass metal 10%-40%；In glass metal in the region apart from bottom refractory material 5-30CM of the card neck flow passage device (60) of glass metal, if In respect of 3-20 electrode assembly；
It uses electrode to carry out temperature controlled clarification, exhaust bubble and anti-crystallization device to the glass metal flowed from the top to the bottom (30) surrounding design has the electrode of 4-50 control temperature of glass liquid, is carried out using electrode to the glass metal flowed from the top to the bottom Glass metal in the region apart from bottom refractory material 5-30CM of temperature controlled clarification, exhaust bubble and anti-crystallization device (30) In, design has 3-20 electrode assembly；
Its bottom flow liquid channel (20), in the glass metal in region apart from bottom refractory material 5-30CM, design has 3- 20 electrode assemblies；
It uses electrode to carry out temperature controlled glass metal rise channel s structure to the glass metal flowed from bottom to top -- (40) surrounding design has the electrode of 4-50 control temperature of glass liquid；Rise channel s structure (40) apart from bottom refractory material 5- In glass metal in the region of 30CM, design has 3-20 electrode assembly；
Required device: flame thermal energy dominates the lateral flame furnace Jie Ju device (10) of glass melting, the card of glass metal Neck flow passage device (60) carries out temperature controlled clarification, exhaust bubble and anti-analysis to the glass metal flowed from the top to the bottom using electrode Brilliant device (30) carries out temperature controlled glass metal rise channel s structure to the glass metal flowed from bottom to top using electrode (40), the molding machine (50) of glassware；Electrode energy in these devices, can be in the molding machine of glassware (50) when stopping working, the glass metal in respective device is made to be maintained at 1300 DEG C or more, Asia is maintained at higher than devitrification of glass temperature On；
(b) a kind of process of new lateral flame furnace production system is come the superelevation lead glass product that produces, technique Process:
Get required device ready: flame thermal energy dominates the lateral flame furnace Jie Ju device (10) of glass melting, glass metal Card neck flow passage device (60), using electrode to the glass metal that flows from the top to the bottom carry out temperature controlled clarification, exhaust bubble and Anti- crystallization device (30) carries out temperature controlled glass metal rise channel s structure to the glass metal flowed from bottom to top using electrode (40), the molding machine (50) of glassware；Electrode energy in these devices, can be in the molding machine of glassware (50) when stopping working, the glass metal in respective device is made to be maintained at 1300 DEG C or more, Asia is maintained at higher than devitrification of glass temperature On；
Step 1. is scheduled glass raw material, by glass raw material transport device, dominates glass melting into flame thermal energy Lateral flame furnace Jie Ju device (10) in, carry out dissolving to form glass metal, glass metal passes through the card neck runner of glass metal again Device (60), enters from upper lateral part using electrode, carries out temperature controlled clarification to the glass metal flowed from the top to the bottom, exhaust is steeped In anti-crystallization device (30)；And makes card neck flow passage device (60) and temperature is carried out to the glass metal flowed from the top to the bottom using electrode The clarification of control, the temperature of exhaust bubble and the glass metal in anti-crystallization device (30) are spent, control is being higher than clarification, row's bubble 102 Pa Sec viscosity temperature on section and higher than the section on devitrification of glass temperature；
Process characteristic is: passing through the region apart from bottom refractory material 5-30CM of the card neck flow passage device (60) of glass metal In glass metal in, 3-20 electrode assembly of design makes card neck flow passage device (60) region, away from refractory material bottom 10- In the glass metal in the region of 30CM distance, the work technological temperature in the section of a minimum of 100 cubes of CM volumes will be maintained at 1320 DEG C -1450 DEG C, it is higher than 20-80 DEG C of the work technological temperature of the region glass metal apart from bottom refractory material 30-60CM distance；
Process characteristic is: carrying out temperature controlled clarification, exhaust bubble and anti-analysis by the glass metal flowed from the top to the bottom In glass metal in the region apart from bottom refractory material 5-30CM of brilliant device (30) design, respective 3-20 electrode assembly, The glass metal flowed from the top to the bottom is set to carry out temperature controlled clarification, exhaust bubble and anti-crystallization device (30) region, away from fire resisting In the glass metal in the region of material bottom 5-30CM distance, the work technological temperature in the section of a minimum of 100 cubes of CM volumes is wanted 1320 DEG C -1450 DEG C are maintained at, the work process warm of the region glass metal apart from bottom refractory material 30-60CM distance is higher than 20-80 DEG C of degree；
Step 2. makes glass metal from using electrode, carries out temperature controlled clarification, row to the glass metal flowed from the top to the bottom Bubble and anti-crystallization device (30) lower part, the bottom flow liquid channel (20) of entrance enter back into one be coupled and use electrode pair The glass metal flowed from bottom to top carries out temperature controlled glass metal rise channel s structure (40)；
Process characteristic is: the region by what is designed in bottom flow liquid channel (20), apart from bottom refractory material 5-30CM In glass metal in, 3-20 electrode assembly of design makes bottom flow liquid channel (20) region, away from refractory material bottom 5- In the glass metal in the region of 30CM distance, the work technological temperature in the section of a minimum of 100 cubes of CM volumes will be maintained at 1320 DEG C -1450 DEG C, it is higher than 20-80 DEG C of the work technological temperature of the region glass metal apart from bottom refractory material 30-60CM distance；
Process characteristic is: carrying out on temperature controlled glass metal by using electrode to the glass metal flowed from bottom to top Design in channel design (40) is risen, in the glass metal in region apart from bottom refractory material 5-30CM, 3-20 electricity of design Pole device makes bottom flow liquid channel (20) region, in the glass metal in the region away from refractory material bottom 5-30CM distance, at least There is the work technological temperature in the section of 100 cubes of CM volumes, to be maintained at 1320 DEG C -1450 DEG C, be higher than apart from bottom refractory 20-80 DEG C of the work technological temperature of the region glass metal of material 30-60CM distance；
Process characteristic is: by the glass metal in its region apart from bottom refractory material 5-30CM, the 3-20 of design A electrode assembly makes bottom flow liquid channel (20) region, in the glass metal in the region away from refractory material bottom 5-30CM distance, The work technological temperature in the section of a minimum of 100 cubes of CM volumes, will be maintained at 1320 DEG C -1450 DEG C, be higher than apart from bottom 20-80 DEG C of the work technological temperature of the region glass metal of refractory material 30-60CM distance；
Step 3. glass metal by bottom flow liquid channel (20), carries out the glass metal flowed from bottom to top into electrode again Temperature controlled glass metal rise channel s structure (40)；
Process characteristic is: by the glass metal in its region apart from bottom refractory material 5-30CM, the 3-20 of design A electrode assembly carries out temperature controlled glass metal rise channel s structure (40) to the glass metal flowed from bottom to top using electrode Region, in the glass metal in the region away from refractory material bottom 5-30CM distance, the work in the section of a minimum of 100 cubes of CM volumes Make technological temperature, to be maintained at 1320 DEG C -1450 DEG C, is higher than the region glass apart from bottom refractory material 30-60CM distance 20-80 DEG C of the work technological temperature of liquid；
The selection of step 4. moulding process:
The selection of the first glassware moulding process: the glass of the top exit above-mentioned by rise channel s structure (40) Glass liquid, into the molding machine (5) of glassware；The molding machine (5) of its glassware is the tin of float flat glass technique Kiln structure；Glass metal enters the smooth plane for being furnished with the tin metal dissolved of tin kiln structure, carry out glass metal time divide it is thin and Polishing；Required thickness is pulled into glass tape of the edge machine to formation by the 10-40 on both sides again；Using annealing, material process, shape are cut At float flat glass product；Or
The selection of second of glassware moulding process: the glass of the top exit above-mentioned by rise channel s structure (40) Glass liquid, into the sprue of glass metal, glass metal, which enters to be coupled, 2-30 glass metal runner；Glass metal enters each point The molding machine of the glass fibre production for the glassware that runner is coupled；Separately flow into corresponding 2-30 bearing glass liquid Dry crucible, glass metal pass through corresponding 2-30 bushing, form glass fibre under the action of corresponding wire drawing machine；Or
The selection of the third glassware moulding process: the glass of the top exit above-mentioned by rise channel s structure (40) Glass liquid, into the sprue of glass metal, glass metal, which enters to be coupled, 2-30 glass metal runner；Glass metal enters each point The blow molding device of 2-30 industry and utility glass ware of the glassware that runner is coupled；Be blow molded into respectively industry with The product of domestic glass；Using the processing of the annealing device of glassware, the blow molding system of industry with domestic glass is made Product；Or
The selection of 4th kind of glassware moulding process: the glass of the top exit above-mentioned by rise channel s structure (40) Glass liquid, into the sprue of glass metal, glass metal, which enters to be coupled, 2-30 glass metal runner；Glass metal enters each point The compression molding device of 2-30 industry and utility glass ware of the glassware that runner is coupled；Be pressed into respectively industry with The product of domestic glass；Using the processing of the annealing device of glassware, the compression moulding system of industry with domestic glass is made Product；Or
The selection of 5th kind of glassware moulding process: the glass of the top exit above-mentioned by rise channel s structure (40) Glass liquid, into the sprue of glass metal, glass metal, which enters to be coupled, 2-30 glass metal runner；Glass metal enters each point The drawing molding device of 2-30 of the glassware that runner is coupled industry and domestic glass, be drawn into respectively industry with it is daily The product of glass；Using the processing of the annealing device of glassware, the drawing moulded products of industry with domestic glass are made；Or
The selection of 6th kind of glassware moulding process: the glass of the top exit above-mentioned by rise channel s structure (40) Glass liquid, into the sprue of glass metal, glass metal, which enters to be coupled, 2-30 glass metal runner；Glass metal enters each point The blow molding device of 2-30 bathroom glassware of the glassware that runner is coupled, is respectively prepared bathroom glassware； Using the processing of the annealing device of glassware, bathroom glassware is made.
About marked improvement and creativeness of the invention:
The invention belongs to glass technology fields, are related to a kind of process using lateral flame furnace production system, institute The superelevation lead glass product of production.
Technical solution of the present invention belongs to a kind of invention of claim to a product comprising preparation method characteristic, not only product Compare the composition and structure of prior art documents, there is novelty；And the process that the present invention innovates, there is skill than first Art product can result in alumina content up to the micro-variations and progress inside the glassware of 20--49%, and the present invention compares First there is superelevation lead glass product, it could be really with different, stable-[translucency, high intensity, lightening, lightweight Can] glassware inside micro-variations and progress product feature.
Exclusive manufacturing method of the present invention is characterized in:
In glass metal in the region apart from bottom refractory material 5-30CM of the card neck flow passage device (60) of its glass metal, if In respect of 3-20 electrode assembly；
It uses electrode to carry out temperature controlled clarification, exhaust bubble and anti-crystallization device to the glass metal flowed from the top to the bottom (30) in the glass metal in the region apart from bottom refractory material 5-30CM, design has 3-20 electrode assembly；
Its bottom flow liquid channel (20), in the glass metal in region apart from bottom refractory material 5-30CM, design has 3- 20 electrode assemblies；
It uses electrode to carry out temperature controlled glass metal rise channel s structure (40) to the glass metal flowed from bottom to top The region apart from bottom refractory material 5-30CM in glass metal in, design have 3-20 electrode assembly；
Step 1 is different from documents and the process characteristic of all prior arts is: by the card neck runner of glass metal In glass metal in the region apart from bottom refractory material 5-30CM of device (60), 3-20 electrode assembly of design makes card neck Flow passage device (60) region, in the glass metal in the region away from refractory material bottom 10-30CM distance, a minimum of 100 cubes of CM The work technological temperature in the section of volume, will be maintained at 1320 DEG C -1450 DEG C, be higher than apart from bottom refractory material 30-60CM 20-80 DEG C of the work technological temperature of the region glass metal of distance；
Step 2 is different from documents and the process characteristic of all prior arts is: the glass metal flowed from the top to the bottom Temperature controlled clarification, exhaust bubble and anti-crystallization device (30) are carried out, by its design apart from bottom refractory material 5-30CM Region in glass metal in, 3-20 electrode assembly makes the glass metal flowed from the top to the bottom carry out temperature controlled clarification, row Bubble and anti-crystallization device (30) region, in the glass metal in the region away from refractory material bottom 5-30CM distance, a minimum of 100 The work technological temperature in the section of cube CM volume, will be maintained at 1320 DEG C -1450 DEG C, be higher than apart from bottom refractory material 20-80 DEG C of the work technological temperature of the region glass metal of 30-60CM distance；
Step 3 is different from documents and the process characteristic of all prior arts is: by bottom flow liquid channel (20) In glass metal in the region apart from bottom refractory material 5-30CM in region, 3-20 electrode assembly of design makes bottom flow liquid Channel (20) region, in the glass metal in the region away from refractory material bottom 5-30CM distance, a minimum of 100 cubes of CM volumes The work technological temperature in section, will be maintained at 1320 DEG C -1450 DEG C, be higher than apart from bottom refractory material 30-60CM distance 20-80 DEG C of the work technological temperature of region glass metal；
Step 4 is different from documents and the process characteristic of all prior arts is: glass metal is entered back into electrode pair The glass metal flowed from bottom to top carries out temperature controlled glass metal rise channel s structure (40)；By it apart from bottom refractory material In glass metal in the region of 5-30CM, 3-20 electrode assembly of design, using electrode to the glass metal flowed from bottom to top Carry out temperature controlled glass metal rise channel s structure (40) region, the glass in the region away from refractory material bottom 5-30CM distance In glass liquid, the work technological temperature in the section of a minimum of 100 cubes of CM volumes will be maintained at 1320 DEG C -1450 DEG C, be higher than away from 20-80 DEG C of the work technological temperature of region glass metal with a distance from bottom refractory material 30-60CM.
[comparing prior art]
(1) first have correlation technique 1: the present inventor's first has invention: having the high intensity of high annealing point and environment-friendly and energy-saving emission-reduction The application of the plate glass of high-flatness low-viscosity and associated components, the patent No. 201110060944.4.
(2) first have the 2 of invention: the 201510161553.61 of the present inventor, a kind of plate glass with low thermal coefficient of expansion Glass and its preparation process.
(3) first have the 3 of invention: the present inventor's: PCT/CN2015/000795, a kind of high-temperature region thermal expansion coefficient it is low The application of difference, low crystallization speed, superhigh intensity, high softening-point, fire-proof and explosion-proof plate glass.
(4) first have the 4 of invention: the present inventor's: PCT/CN2015/000793, a kind of low crystallization temperature, low crystallization speed Degree, high temperature resistant, extra-high lead glass fiber application and preparation method thereof, composite material.
(5) first have the 5 of invention: the present inventor's: PCT/CN2015/000794, a kind of high-temperature region thermal expansion coefficient it is low The application of difference, low crystallization speed, high softening-point, high temperature resistant explosion-proof glassware or glass daily necessities.
(6) in the prior art, the electronic plane cover board gorilla 1-4 generation of Corning Incorporated, 15-22% aluminium oxide； But it is lower than 1% containing calcium oxide, is not that [silica content is 2.51-5.8 times of calcium oxide content, calcium oxide content in the present invention 0.8 times -2.3 times of content of magnesia] range.
In the prior art, S grades of glass aluminium oxide containing 23-25-26%, ----but it is lower than 1% containing calcium oxide, nor [silica content is 2.51-5.8 times of calcium oxide content to the present invention, and calcium oxide content is 0.8 times -2.3 of content of magnesia Range again].
And above-mentioned prior art, all use-only has about 10CM diameter platinum channel technology, yield very little in technique； Technology production method of the invention is not used.
(7) first there are the molten kiln technology of electricity and flame firer's skill technical glass product, the main alumina content that produces is 1- The high alumina products that middle aluminum products that 4% low aluminum products, alumina content are 5-9%, alumina content are 10-16%.
First there are the molten kiln technology of electricity and flame kiln technology, several technology essential factors without present invention process method Jie Ju feature, so, prior art, without the process conditions for overcoming its technological difficulties.
First there are the molten kiln technology of electricity and flame kiln technology, mainly considers and dissolve glass and exhaust bubble and homogenizing glass Glass liquid, it is desirable to which the electric field [temperature field] formed between electrode is uniformly for basic goal.It plays and asks without the present invention, more The specific region position of the glass metal in the region apart from bottom refractory material 5-30CM in a region, design have 3-20 electrode The requirement of device, and without the present invention play ask in multiple regions, the region away from refractory material bottom 5-30CM distance Glass metal in, the work technological temperature in the section of a minimum of 100 cubes of CM volumes will be maintained at 1320 DEG C -1450 DEG C, high In the process of 20-80 DEG C of technological temperature of the work of the region glass metal apart from bottom refractory material 30-60CM distance.
[difference of the present invention and prior art (1)-(7)]
(1) firstly, a kind of present invention [process superelevation produced using new lateral flame furnace production system Lead glass product] from first have the constituent structure of invention (1)-(7) technical solution and any prior art proposal all different: this hair It is bright -- by weight percentage, alumina content 20%-49%；Content of magnesia is 5%--20%, and silica content is 2.51-5.8 times of calcium oxide content, calcium oxide content are 0.8 times -2.3 times of content of magnesia；So the present invention has novelty Property.
In addition, the preparation method of process characteristic of the present invention, and first there is invention (1)-(7) technical solution and any Prior art proposal is also all different.Preparation method characteristic of the present invention could generate and first have similar products entirely different , [absolutely not milky rich aluminum strip line or rich aluminium block in glass, without the feature of glass layering, alumina content Up to the glassware of 20--49%].
And if not using preparation method characteristic of the present invention, alumina content reaches the glassware of 20--49% In, it will be easy to the opaque significant deficiency there are milky rich aluminum strip line or milky rich aluminium block, or glass occur The significant deficiency problem of glass layering.
(2) and the present invention because using completely new technique: in the molten Yao Jie Ju device of multiple regions, bottom refractory material In glass metal in the region of 5-30CM distance, 3-20 electrode assembly is all devised, using completely new technique: making multiple In the glass metal in the region of the bottom refractory material 10-30CM distance in the molten kiln knot Ju device region in region, minimum each own 1 area Between work technological temperature be maintained at 1320 DEG C -1450 DEG C, higher than the region glass apart from bottom refractory material 30-60CM distance 20-80 DEG C of the work technological temperature of liquid.So these regions can be formed, apart from bottom refractory material 5-30-60CM distance Glass metal it is small-scale flow up and down homogenizing, make " rich aluminium deposition phenomenon -- the i.e. glass metal of high-alumina component content It the phenomenon that part, deposition is in bottom due to than great ", is homogenized, is resolved.It can fundamentally solve in turn result in There is glass muscle, striped, the products such as oxygen-enriched piece of White-opalescent and item are not because composition is seriously uneven in glass finished-product formative stage Qualified difficult point, make it possible high qualification rate production 20--49% alumina content glassware.
And the present invention can also overcome in prior art, attempt to reach using traditional stirring technique by prior art Purpose uses traditional stirring technique, overcomes and the difficult point that " rich aluminium deposition phenomenon " generates occurs in glass metal bottom.
One of the stirring technique difficult point for overcoming its traditional: being in the electricity close to glass shaping area using traditional stirring technique Melting furnaces bottom or rising passway top position, stirring technique are easy to generate secondary bubble, and a large amount of bubbles is made to occur directly in product In；
The two of the stirring technique difficult point for overcoming its traditional: traditional stirring technique is used, if being more than 1300 DEG C of ring In border, using the stainless steel mixer for adding cooling cooling water circulation, serious blender side wall glass metal nearby will cause, because of length The conduction of phase water-cooled cooling, and a large amount of crystallizations of glass metal are generated, in the electric melting furnace bottom or rising passway top close to glass shaping area Portion position, crystallization directly can largely occur in the product；
The three of the stirring technique difficult point for overcoming its traditional: using platinum blender, can have cost too high and platinum in height There is new bubble in lower react with glass of temperature, and electric melting furnace bottom or rising passway top position in close glass shaping area produce Raw secondary bubble, also can be such that a large amount of bubbles occur directly in product.This is that the production that existing technology all can not be qualified contains The major reason of the glassware of 20% or more superelevation aluminium content.
So can accomplish, the glassware of the alumina content of 20--49% is produced, can not only be made during normal production In respective device, the glass metal of especially bottom section is maintained at 1300 DEG C or more；And it can stop in the molding machine (5) of glassware When only working, i.e., it is several also also to form this not from the glass metal dissolved when Yao Jie Ju device flows over the high-temperature glass liquid come A region, the work technological temperature in minimum each own 1 section of glass metal apart from bottom refractory material 5-30-60CM distance Be maintained at 1320 DEG C -1450 DEG C, the work technological temperature in minimum each own 1 section is maintained at 1320 DEG C -1450 DEG C, be higher than away from 20-80 DEG C of the work technological temperature of region glass metal with a distance from bottom refractory material 30-60CM；And it small-scale flows up and down Homogenizing, makes that " rich aluminium deposition phenomenon -- i.e. the glass metal part of high-alumina component content, deposition exists due to than great The phenomenon that bottom ", is homogenized, and is resolved.
Completely new art inventions conception plans are one kind in specific environment, to the technology side in specific region The invention of the glass product of case production, produces the technical effect given unexpectedly.
Part III chapter 4 [page 175] the 3.2.2 significant progress judgement of root Ju Guidelines for Patent Examination,,,.With Xia Qing Indistinct has significant progress usually it will be understood that invention has beneficial technical effect.(2) invention provides one kind The different technical solution of technical concept, an art effect can substantially achieve state of the art；[such as quality improvement, The raising of yield, energy saving, prevention and treatment environmental pollution etc.].And the present invention is [a kind of using new lateral flame furnace production system Process, superelevation lead glass product produced] in electronic plane glass, building and industrial plate glass, glass fibre, work In the field of industry or utility glass ware and device, the effect that can overcome the problems, such as prior art significant deficiency given unexpectedly is produced Fruit can especially overcome my process first having in invention, reach the glassware of 20--49% in production alumina content In, it will be easy to the opaque significant deficiency there are milky rich aluminum strip line or milky rich aluminium block, or glass occur The significant deficiency problem of glass layering；Because [a kind of process using new lateral flame furnace production system, is produced the present invention Superelevation lead glass product], the above problem can be overcome, thus alumina content of the invention reach 20--49% glassware, It can be only achieved than first there is superelevation lead glass product that really there is stable-[translucency, high intensity, lightening, lightweight performance] Purpose (because insider knows about, if there is milky rich aluminum strip line or milky rich aluminium block in glassware Opaque significant deficiency, or there is the significant deficiency of glass layering, it is impossible to have product of the present invention different from all elder generations Have technology-[superhigh intensity of qualified translucency, superelevation aluminium, more lightening, more light-weighted performance]).So of the invention With significant progress.
It is above-described to solve the problems, such as that the prior art is super in the glassware of alumina content of the production higher than 20% In the high-strength glass production field of high alumina, people thirst for solving always but fail the technical problem to succeed always.This skill hair It is bright, it solves this people and thirsts for solving but failing always the technical problem to succeed always, thus it is of the invention, have and protrudes Substantive distinguishing features and significant progress, it is creative.
According to Guidelines for Patent Examination second part chapter 4, the judgement of 3.2.2-175 pages-marked improvement -- its (2) hair Bright to provide a kind of technical solution that technical concept is different, technical effect can substantially reach the level of the prior art.And this Invention also belong to compare me first have invention, provide a kind of new solution that technical concept is different, technical effect is not It is only capable of reaching my level for first having inventive technique, has also been more than my level for first having inventive technique.
According to Guidelines for Patent Examination second part chapter 4, the invention of determination requirement protection carrys out those skilled in the art It whether apparent says: in deterministic process, it is confirmed that the prior art whether there is certain technical inspiration ... on the whole, under State situation, it is generally recognized that above-mentioned technical inspiration exists in the prior art: (i) described distinguishing characteristics is common knowledge, for example, ability Solved in domain the solution disclosed in the customary means or Teaching-with section book or reference book etc. for the technical issues of this is redefined this again The technological means of determining technical problem.And technical solution of the present invention, it is not common knowledge, is not to solve to be somebody's turn to do in this field The solution technology redefined disclosed in the customary means or Teaching-with section book or reference book etc. of the technical issues of redefining The technological means of problem.
According to Guidelines for Patent Examination second part chapter 4, the WHATSOEVER of 2 innovation and creation of method 22.3 is read: the creation of invention Property, refer to compared with prior art, which has substantive distinguishing features outstanding and marked improvement.2.2 is outstanding substantive special Point, refers to for person of ordinary skill in the field, and invention is non-obvious compared with the existing technology.If invention It is person of ordinary skill in the field on the basis of existing technology only by logical analysis, reasoning or limited Test it is available, then the invention is it will be apparent that also just not having the substantive distinguishing features of assault.
And technical solution of the present invention, be not person of ordinary skill in the field on the basis of existing technology only It is available by logical analysis, reasoning or limited test.
In short, technical solution of the present invention belongs to a kind of invention of claim to a product comprising preparation method characteristic, not only Product compares the composition and structure of prior art documents, has novelty；And the process that the present invention innovates, than elder generation There are technical products, alumina content can be resulted in up to the micro-variations and progress inside the glassware of 20--49%, the present invention More first there is superelevation lead glass product, it could be really with different, stable-[translucency, high intensity, lightening, lightweight Performance] glassware inside micro-variations and progress product feature.
Preparation method of the present invention results in alumina content up in the glassware of 20--49%, and first has that product is different, There is no the opaque defect structures of milky rich aluminum strip line or milky rich aluminium block in product, or there is no glass point The defect sturcture of layer；In addition the process that the present invention innovates can result in alumina content up to 20-- than prior art product Micro-variations and progress inside 49% glassware, the present invention more first have superelevation lead glass product, could really have The product feature of different, stable-[translucency, high intensity, lightening, lightweight performance].
Because insider knows about, if there is milky rich aluminum strip line or milky rich aluminium block in glassware Opaque significant deficiency, or there is the significant deficiency of glass layering, it is impossible to have product of the present invention different from all elder generations Have technology-[superhigh intensity of qualified translucency, superelevation aluminium, more lightening, more light-weighted performance].
So the present invention not only has novelty, it may have significant progress.
The above, merely to illustrating a kind of process institute using new lateral flame furnace production system of the present invention The superelevation lead glass product of production, preferable preferred embodiment, however its be not be limitation of the present invention, it is any be familiar with The personnel of the technology are changed or are modified to the equivalent embodiment of equivalent variations possibly also with the technology contents of the disclosure above, It can implement a kind of process using new lateral flame furnace production system of the present invention by different requirements and performance to be given birth to The superelevation lead glass product of production.As it can be seen that the content of anything that does not depart from the technical scheme of the invention, especially claims, according to According to technical spirit any simple modification to the above embodiments of the invention, equivalent variations and modification still belong to the present invention In the range of technical solution.

Claims (11)

1. a kind of process superelevation lead glass product produced using new lateral flame furnace production system,
The composition of [A] glassware is: by weight percentage, alumina content 20%-49%；Content of magnesia is 5%--20%, silica content are 2.51-5.8 times of calcium oxide content, calcium oxide content is 0.8 times of content of magnesia- 2.3 again；
A kind of [B] process using new lateral flame furnace production system is:
(a), lateral flame furnace production system equipment is got out, comprising:
Flame thermal energy dominates the lateral flame furnace Jie Ju device (10) of glass melting；The card neck flow passage device (60) of glass metal； Temperature controlled clarification, exhaust bubble and anti-crystallization device (30) are carried out to the glass metal flowed from the top to the bottom using electrode；Bottom Flow liquid channel (20)；Using electrode, temperature controlled glass metal rise channel s structure is carried out to the glass metal flowed from bottom to top (40)；The molding machine (50) of glassware:
In the card neck flow passage device (60) of its glass metal, depth between the surface and bottom of device of glass metal is flame thermal energy It dominates the lateral flame furnace Jie Ju device (10) of glass melting and temperature is carried out to the glass metal flowed from the top to the bottom using electrode It spends in clarification, exhaust bubble and the anti-crystallization device (30) of control, the 10%- of the depth between the surface and bottom of device of glass metal 40%；In glass metal in the region apart from bottom refractory material 5-30CM of the card neck flow passage device (60) of glass metal, design has 3-20 electrode assembly；
It uses electrode to carry out temperature controlled clarification, exhaust bubble and anti-crystallization device (30) to the glass metal flowed from the top to the bottom Surrounding design have 4-50 control temperature of glass liquid electrode, using electrode to flow from the top to the bottom glass metal progress temperature In the clarification of control, the glass metal being vented in the region apart from bottom refractory material 5-30CM of bubble and anti-crystallization device (30), if In respect of 3-20 electrode assembly；
Its bottom flow liquid channel (20), in the glass metal in region apart from bottom refractory material 5-30CM, design has 3-20 Electrode assembly；
It uses electrode to carry out temperature controlled glass metal rise channel s structure to the glass metal flowed from bottom to top -- (40) Surrounding design has the electrode of 4-50 control temperature of glass liquid；Rise channel s structure (40) apart from bottom refractory material 5-30CM's In glass metal in region, design has 3-20 electrode assembly；
Required device: flame thermal energy dominates the lateral flame furnace Jie Ju device (10) of glass melting, the card neck stream of glass metal Road device (60) carries out temperature controlled clarification, exhaust bubble and anti-crystallization to the glass metal flowed from the top to the bottom using electrode and fills (30) are set, temperature controlled glass metal rise channel s structure (40), glass are carried out to the glass metal flowed from bottom to top using electrode The molding machine (50) of glass product；Electrode energy in these devices can stop in the molding machine (50) of glassware When work, the glass metal in respective device is made to be maintained at 1300 DEG C or more, and is maintained at higher than on devitrification of glass temperature；
(b) a kind of process of new lateral flame furnace production system is come the superelevation lead glass product that produces, technical process:
Get required device ready: flame thermal energy dominates the lateral flame furnace Jie Ju device (10) of glass melting, the card of glass metal Neck flow passage device (60) carries out temperature controlled clarification, exhaust bubble and anti-analysis to the glass metal flowed from the top to the bottom using electrode Brilliant device (30) carries out temperature controlled glass metal rise channel s structure to the glass metal flowed from bottom to top using electrode (40), the molding machine (50) of glassware；Electrode energy in these devices, can be in the molding machine of glassware (50) when stopping working, the glass metal in respective device is made to be maintained at 1300 DEG C or more, and be maintained at higher than devitrification of glass temperature On；
Scheduled glass raw material is dominated the cross of glass melting into flame thermal energy by glass raw material transport device by step 1. It into flame furnace Jie Ju device (10), carries out dissolving to form glass metal, glass metal passes through the card neck flow passage device of glass metal again (60), enter from upper lateral part using electrode, temperature controlled clarification is carried out to the glass metal flowed from the top to the bottom, exhaust is steeped and anti- In crystallization device (30)；And makes card neck flow passage device (60) and temperature control is carried out to the glass metal flowed from the top to the bottom using electrode Clarification, the exhaust of system are steeped and the temperature of the glass metal in anti-crystallization device (30), and control is steeping 10 higher than clarification, row2Pa Sec Viscosity temperature on section and higher than the section on devitrification of glass temperature；
Process characteristic is: in the region apart from bottom refractory material 5-30CM by the card neck flow passage device (60) of glass metal In glass metal, 3-20 electrode assembly of design makes card neck flow passage device (60) region, away from refractory material bottom 10-30CM In the glass metal in the region of distance, the work technological temperature in the section of a minimum of 100 cubes of CM volumes, to be maintained at 1320 DEG C- 1450 DEG C, it is higher than 20-80 DEG C of the work technological temperature of the region glass metal apart from bottom refractory material 30-60CM distance；
Process characteristic is: carrying out temperature controlled clarification, exhaust bubble and anti-crystallization by the glass metal flowed from the top to the bottom and fills Set (30) design the region apart from bottom refractory material 5-30CM in glass metal in, respective 3-20 electrode assembly, make from On the glass metal that flows downward carry out temperature controlled clarification, exhaust bubble and anti-crystallization device (30) region, away from refractory material In the glass metal in the region of bottom 5-30CM distance, the work technological temperature in the section of a minimum of 100 cubes of CM volumes will be kept At 1320 DEG C -1450 DEG C, it is higher than the work technological temperature of the region glass metal apart from bottom refractory material 30-60CM distance 20-80℃；
Step 2. makes glass metal from using electrode, carries out temperature controlled clarification to the glass metal flowed from the top to the bottom, exhaust is steeped With anti-crystallization device (30) lower part, the bottom flow liquid channel (20) of entrance enters back into one be coupled using electrode under The glass metal flowed up carries out temperature controlled glass metal rise channel s structure (40)；
Process characteristic is: by what is designed in bottom flow liquid channel (20), in the region apart from bottom refractory material 5-30CM In glass metal, 3-20 electrode assembly of design makes bottom flow liquid channel (20) region, away from refractory material bottom 5-30CM away from From region glass metal in, the work technological temperature in the section of a minimum of 100 cubes of CM volumes, to be maintained at 1320 DEG C- 1450 DEG C, it is higher than 20-80 DEG C of the work technological temperature of the region glass metal apart from bottom refractory material 30-60CM distance；
Process characteristic is: it is logical to carry out temperature controlled glass metal rising to the glass metal flowed from bottom to top by using electrode It is designed in road structure (40), in the glass metal in region apart from bottom refractory material 5-30CM, 3-20 electrode of design is filled It sets, makes bottom flow liquid channel (20) region, it is a minimum of in the glass metal in the region away from refractory material bottom 5-30CM distance The work technological temperature in the section of 100 cubes of CM volumes, will be maintained at 1320 DEG C -1450 DEG C, be higher than apart from bottom refractory material Expect 20-80 DEG C of the work technological temperature of the region glass metal of 30-60CM distance；
Process characteristic is: by the way that in the glass metal in its region apart from bottom refractory material 5-30CM, 3-20 of design is electric Pole device makes bottom flow liquid channel (20) region, in the glass metal in the region away from refractory material bottom 5-30CM distance, at least There is the work technological temperature in the section of 100 cubes of CM volumes, to be maintained at 1320 DEG C -1450 DEG C, be higher than apart from bottom refractory 20-80 DEG C of the work technological temperature of the region glass metal of material 30-60CM distance；
Step 3. glass metal carries out temperature to the glass metal flowed from bottom to top into electrode again by bottom flow liquid channel (20) The glass metal rise channel s structure (40) of control；
Process characteristic is: by the way that in the glass metal in its region apart from bottom refractory material 5-30CM, 3-20 of design is electric Pole device carries out temperature controlled glass metal rise channel s structure (40) region to the glass metal flowed from bottom to top using electrode , in the glass metal in the region away from refractory material bottom 5-30CM distance, the work work in the section of a minimum of 100 cubes of CM volumes Skill temperature will be maintained at 1320 DEG C -1450 DEG C, be higher than the region glass metal apart from bottom refractory material 30-60CM distance 20-80 DEG C of technological temperature of work；
The selection of step 4. moulding process:
The selection of the first glassware moulding process: the glass of the top exit above-mentioned by rise channel s structure (40) Liquid, into the molding machine (5) of glassware；The molding machine (5) of its glassware is the tin kiln of float flat glass technique Structure；Glass metal enters the smooth plane for being furnished with the tin metal dissolved of tin kiln structure, carries out glass metal time and divides thin and throw Light；Required thickness is pulled into glass tape of the edge machine to formation by the 10-40 on both sides again；Using annealing, material process is cut, is formed Float flat glass product；Or
The selection of second of glassware moulding process: the glass of the top exit above-mentioned by rise channel s structure (40) Liquid, into the sprue of glass metal, glass metal, which enters to be coupled, 2-30 glass metal runner；Glass metal enters each shunting The molding machine of the glass fibre production for the glassware that road is coupled；Separately flow into the dry of corresponding 2-30 bearing glass liquid Crucible, glass metal pass through corresponding 2-30 bushing, form glass fibre under the action of corresponding wire drawing machine；Or
The selection of the third glassware moulding process: the glass of the top exit above-mentioned by rise channel s structure (40) Liquid, into the sprue of glass metal, glass metal, which enters to be coupled, 2-30 glass metal runner；Glass metal enters each shunting The blow molding device of 2-30 industry and utility glass ware of the glassware that road is coupled；It is blow molded into industry and day respectively With the product of glass；Using the processing of the annealing device of glassware, the blow molding product of industry with domestic glass is made； Or
The selection of 4th kind of glassware moulding process: the glass of the top exit above-mentioned by rise channel s structure (40) Liquid, into the sprue of glass metal, glass metal, which enters to be coupled, 2-30 glass metal runner；Glass metal enters each shunting The compression molding device of 2-30 industry and utility glass ware of the glassware that road is coupled；It is pressed into industry and day respectively With the product of glass；Using the processing of the annealing device of glassware, the compression moulding product of industry with domestic glass is made； Or
The selection of 5th kind of glassware moulding process: the glass of the top exit above-mentioned by rise channel s structure (40) Liquid, into the sprue of glass metal, glass metal, which enters to be coupled, 2-30 glass metal runner；Glass metal enters each shunting The drawing molding device of 2-30 industry and domestic glass of the glassware that road is coupled, is drawn into industry and daily glass respectively The product of glass；Using the processing of the annealing device of glassware, the drawing moulded products of industry with domestic glass are made；Or
The selection of 6th kind of glassware moulding process: the glass of the top exit above-mentioned by rise channel s structure (40) Liquid, into the sprue of glass metal, glass metal, which enters to be coupled, 2-30 glass metal runner；Glass metal enters each shunting The blow molding device of 2-30 bathroom glassware of the glassware that road is coupled, is respectively prepared bathroom glassware；Again By the processing of the annealing device of glassware, bathroom glassware is made.
2. a kind of windowpane, comprising being equipped with resin edge or metal edge frame support device on glass surrounding；It is characterized by: Its glass is a kind of [process superelevation lead glass product produced of new lateral flame furnace production system] claim 1 The plate glass.
3. a kind of colored glaze plate glass, it is characterised in that: glass surface has the glazed colour layer of 1~10 kind of color；Its glass is [a kind of The process superelevation lead glass product produced of new transverse direction flame furnace production system] plate glass described in claim 1 Glass.
4. a kind of building thin glass window of overlarge area, it is characterised in that: its glass with a thickness of 4~10mm, glass Having a size of 3~40 square metres or its glass with a thickness of .4-20mm, the size of glass is 15.1~80 square metres；Its glass It is that [a kind of process superelevation lead glass product produced of new lateral flame furnace production system] is described in claim 1 Plate glass.
5. a kind of shellproof implosion guard, is characterized in that: its each glass sheets is bonded by resin sheet；Its glass is a kind of [new cross To the process superelevation lead glass product produced of flame furnace production system] plate glass described in claim 1.
6. a kind of liquid crystal display, which includes: multiple substrate, which includes substrate, on this substrate Dot structure, which is a kind of composition described in claims 1 in superelevation alumina content, superhigh intensity, high softening-point glass The application of glass；
Filter substrate, the filter substrate include substrate and color-filter layer on this substrate, which is glass substrate；
Liquid crystal layer is folded between the multiple substrate and the filter substrate；And back light source system；
It is characterized by: its glass is a kind of [process superelevation aluminium glass produced of new lateral flame furnace production system Glass product] plate glass described in claim 1.
7. a kind of shellproof explosion-proof vehicle structure, it includes 1~3 layer of glass of 1~10 vehicle window, each glass sheets by setting The bonding of rouge piece；
The metal plate of the surrounding of automobile has ballistic structure in metal frame；
And power device；Instrument board；Direction controller；Automobile case；Automobile chassis；Automobile braking device；Automobile tire；
It is characterized by: its glass is a kind of [process superelevation aluminium glass produced of new lateral flame furnace production system Glass product] plate glass described in claim 1.
8. a kind of rob-proof, antitheft, explosion-proof, anticollision, anti-roll injure automobile, it includes: 1~3 layer of glass of 1~10 vehicle window Glass, bulletproof glass be as described in claims 1 a kind of composition in superelevation alumina content, superhigh intensity, high softening-point glass Using；And power device；Instrument board；Direction controller；Automobile case；Automobile chassis；Automobile braking device；Automobile tire； It is characterized by: its glass is a kind of [process superelevation lead glass system produced of new lateral flame furnace production system Product] plate glass described in claim 1.
9. a kind of glass fibre, it is characterised in that: its glass fibre is a kind of [technique side of new lateral flame furnace production system Method superelevation lead glass product produced] glass described in claim 1.
10. a kind of glass fiber compound material, includes: the glass fibre in plastic substrate, and insertion plastic substrate, feature Be: its glass fibre is [a kind of process superelevation lead glass product produced of new lateral flame furnace production system] Glass described in claim 1.
11. a kind of glass toilet seat product, it is characterised in that: its glass is a kind of [technique of transverse direction flame furnace production system Method superelevation lead glass product produced] glass described in claim 1.
CN201810545807.1A 2018-05-21 2018-05-21 A kind of process superelevation lead glass product produced using new lateral flame furnace production system Withdrawn CN110510868A (en)

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PCT/CN2019/000091 WO2019223323A1 (en) 2018-05-21 2019-05-07 Ultra-high alumina glass product manufactured by means of industrial method employing novel cross-fired furnace production system

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