WO2019200922A1 - Electrostatic dust removal device for high-temperature coal gas - Google Patents

Electrostatic dust removal device for high-temperature coal gas Download PDF

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Publication number
WO2019200922A1
WO2019200922A1 PCT/CN2018/117574 CN2018117574W WO2019200922A1 WO 2019200922 A1 WO2019200922 A1 WO 2019200922A1 CN 2018117574 W CN2018117574 W CN 2018117574W WO 2019200922 A1 WO2019200922 A1 WO 2019200922A1
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WIPO (PCT)
Prior art keywords
insulator
casing
gas
electrostatic precipitator
dust
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PCT/CN2018/117574
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French (fr)
Chinese (zh)
Inventor
方梦祥
陈泉霖
岑建孟
王勤辉
郑成航
高翔
骆仲泱
岑可法
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浙江大学
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Publication of WO2019200922A1 publication Critical patent/WO2019200922A1/en

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B03SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03CMAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03C3/00Separating dispersed particles from gases or vapour, e.g. air, by electrostatic effect
    • B03C3/02Plant or installations having external electricity supply
    • B03C3/04Plant or installations having external electricity supply dry type
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B03SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03CMAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03C3/00Separating dispersed particles from gases or vapour, e.g. air, by electrostatic effect
    • B03C3/34Constructional details or accessories or operation thereof
    • B03C3/66Applications of electricity supply techniques
    • B03C3/70Applications of electricity supply techniques insulating in electric separators
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B03SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03CMAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03C3/00Separating dispersed particles from gases or vapour, e.g. air, by electrostatic effect
    • B03C3/34Constructional details or accessories or operation thereof
    • B03C3/74Cleaning the electrodes
    • B03C3/76Cleaning the electrodes by using a mechanical vibrator, e.g. rapping gear ; by using impact

Definitions

  • the invention belongs to the technical field of high temperature dust removal, and particularly relates to an electrostatic dust removal device for high temperature gas.
  • Coal-based polygeneration technology based on coal pyrolysis is an important technical means for efficient and clean coal utilization. Pyrolysis and gasification of coal with high volatile content in high temperature and anoxic environment can obtain gas, tar and Semi-coke, gas can be separated and purified to obtain high-quality gas fuel. The tar can obtain high-quality chemical products through further deep processing. The semi-coke can be directly used for combustion and power generation, so as to achieve clean utilization of coal graded conversion, which has broad application prospects.
  • the crude gas produced by pyrolysis gasification of coal contains a large amount of particulate matter such as fly ash and coal.
  • the tar obtained by direct condensation separation contains a large amount of particulate matter, which will have a great adverse effect on subsequent processing and utilization.
  • High-temperature pyrolysis gas has high temperature (600 ° C and above), gas composition mainly in reducing atmosphere (such as CH 4 , H 2 ), tar-containing (easy to condense below 400 ° C), etc. More difficult.
  • high temperature (above 400 °C) pyrolysis gas dedusting has not been well solved.
  • high-temperature dust removal technologies mainly include cyclone dust removal technology, ceramic/metal filtration dust removal technology, particle layer dust removal technology and electrostatic dust removal technology.
  • Cyclone dust collector has low dust removal efficiency for fine particles and can only be used as pretreatment equipment; ceramic/metal filter dust collector has high dust removal efficiency, but ceramic filter dust removal equipment has poor thermal shock and brittleness, and metal filter dust collector is easy to corrode at high temperature;
  • the layer dust collector faces the problems of large pressure loss, high energy consumption and difficulty in regenerating the working medium.
  • the electrostatic precipitator technology has the advantages of high dust removal efficiency, low pressure loss and large amount of flue gas treatment. It has been widely used in conventional coal-fired power plants. However, in the high-temperature pyrolysis gas environment, the following difficulties exist.
  • the discharge current is mainly composed of electron current, and the efficiency of particle charging is greatly reduced, thereby affecting dust removal efficiency;
  • the gap between the dizzying voltage and the breakdown voltage is reduced, which causes the electrostatic precipitator to be easily broken down during operation, which affects the stable operation of the precipitator.
  • the high temperature pyrolysis gas is rich in tar.
  • the insulator tends to adhere to tar and dust particles, especially the inner wall surface of the insulator, causing the insulator to creep up, affecting the stable operation of the dust collector; dust particles mixed with tar Adhesion is enhanced and adheres to the dust collecting plate, which makes it difficult to clean the dust, thus affecting the stable operation of the dust collector.
  • the object of the present invention is to provide an electrostatic precipitator for high temperature gas, which can effectively reduce the adhesion of tar and dust particles on the insulator and avoid creepage of the insulator.
  • An electrostatic precipitator for a high temperature gas comprising: a casing having a gas inlet and outlet, a ash hopper disposed at a lower portion of the casing, an electrode wire and a dust collecting plate disposed in the casing, and an insulating electrode wire and a casing Insulator, a hot air purging mechanism for purging the insulator, and a high voltage power source connected to the electrode line;
  • the insulator is in the shape of a hollow cylinder, the hollow structure of the insulator faces the inside of the casing, and the inner side of the bottom of the insulator is provided for Through the cylinder of the electrode wire, the side wall of the insulator is provided with a ventilation structure.
  • the temperature of the insulator can be controlled at 350-450 ° C to prevent condensation of tar on the surface and the inside of the insulator in the pyrolysis gas. Creepage, at the same time, can avoid the occurrence of leakage due to the deterioration of insulation performance due to excessive temperature.
  • the high temperature gas in the present invention includes pyrolysis gas, high temperature gasification gas, and the like.
  • the insulator in the invention is made of 99% corundum and is a high-purity corundum insulator for ensuring the insulation performance at high temperature and ensuring the insulation between the electrode wire and the casing; the insulation performance requirement of the high-purity corundum insulator is: volume resistivity Above room temperature exceeds 10 14 ⁇ cm, the Te value (temperature at which the volume resistivity drops to 1 M ⁇ cm) is greater than 1000 ° C.
  • the shape of the insulator is a hollow cylinder having a diameter of more than 300 mm and a height of more than 500 mm, and the thickness of the insulator wall is greater than 10 mm.
  • the ventilation structure is a venting hole, and 4-16 holes are arranged on the side wall of the insulator, and the aperture is 10-50 mm. It is further preferred to open a hole in the middle portion of the side wall of the insulator.
  • the length of the cylinder is greater than 600 mm.
  • the cylindrical hollow is used to pass through the electrode wire, and its wall thickness can be greater than 5 mm, and the structure of the cylinder can extend the creepage distance.
  • the hot air purging mechanism of the present invention comprises a sleeve, a gas supply pipe connecting the sleeve and a gas electric heater; the sleeve is mounted on the casing and sleeved outside the insulator.
  • the hot air purging mechanism is used for the insulation and purging of the insulator to prevent the tar in the pyrolysis gas from condensing on the surface of the insulator to cause creepage, and at the same time avoid leakage such as leakage due to excessive temperature.
  • the hot air purge wind speed at the ventilating structure of the insulator is controlled to be 0.5-5 m/s by controlling the gas electric heater, and the temperature of the insulator is controlled at 350-450 °C.
  • the hot air in the hot air purging mechanism is made of steam or hot gas (the same as the oil-free gas component in the electrostatic precipitator).
  • the hot gas component of the hot air purging mechanism cannot contain oxygen, and it is prevented from mixing with the gas in the electrostatic precipitator under high temperature and exploding.
  • a cavity is formed between the sleeve and the side wall of the insulator such that the air supply tube and the cavity are in communication with the venting structure.
  • the structure is arranged such that the purged hot gas can sequentially pass through the air supply pipe, the cavity and the ventilation structure, and enter the inner side of the insulator to prevent the tar in the pyrolysis gas from condensing inside the insulator and causing creepage.
  • a sealing gasket is provided at the side wall seal of the sleeve and the insulator.
  • the middle of the casing is a hollow cylinder, and the two ends of the hollow cylinder are respectively a conical gas inlet and a gas outlet.
  • the electrostatic precipitator adopts a cylindrical outer casing to prevent deformation caused by high temperature thermal expansion.
  • the cylindrical outer casing has the advantages of pressure resistance, explosion proof and more uniform temperature field.
  • the gas inlet and the gas outlet are tapered in shape to facilitate control of the amount of gas in and out.
  • the high-temperature dust-containing pyrolysis gas has a flow rate of 0.8-1.5 m/s in the device, ensuring a high migration rate of the dust particles in the device, and the residence time of the dust-containing gas in the device is 8-15 s. Ensure that dust particles are fully removed.
  • the gas inlet and the gas outlet are respectively provided with baffles to ensure uniform flow of gas within the device.
  • the outer side of the casing is provided with a heating mechanism and a heat insulating layer.
  • the heating mechanism can adopt electric heating or hot gas heating.
  • the temperature in the casing is controlled to be 400-600 ° C, which is used to prevent the tar from condensing in the casing due to the low temperature, resulting in cohesiveness.
  • the accumulation of ash, while preventing the temperature from being too high, causes the housing to be unstable during discharge and operation.
  • the material of the insulation layer is rock wool board with a thickness of 150-200mm, and the outside temperature of the control insulation layer is not higher than 50 °C.
  • the hot gas is an inert gas such as hot nitrogen or hot flue gas, which can provide heating and heat preservation for the electrostatic precipitator, and can also serve as a sealing layer to avoid electrostatic precipitator.
  • the internal gas is in contact with the outside air and an explosion occurs.
  • said high voltage power source is a switchable polarity high voltage DC power source.
  • the supply voltage of the switchable polarity high voltage DC power supply can be 50-200kV.
  • a non-electron negative atmosphere CH 4 , H 2 , N 2
  • the use of a positive-voltage high-voltage power source has the advantages of high dust removal efficiency and low energy consumption; in the gas component, an electronegative gas (water vapor, CO 2 )
  • the use of a negative-voltage high-voltage power supply is more efficient in dust removal.
  • the device can switch the polarity high-voltage DC power supply, which can effectively deal with the problem of unstable operation and low dust removal efficiency caused by the change of pyrolysis gas composition.
  • a plurality of dust collecting plates are disposed in the casing, and the dust collecting plates are disposed in parallel in the airflow direction of the casing; the electrode wires are disposed between adjacent dust collecting plates.
  • the dust collecting plate adopts a C-shaped dust collecting electrode plate, and the dust collecting plate is rolled by a steel plate of 1.5-10 mm, the width is 350-850 mm, and the dust collecting electrode is formed by splicing a plurality of C-shaped dust collecting plates.
  • the C-shaped dust collecting plate has a large dust-covered area, which is beneficial for reducing the secondary dust of the dust.
  • the spacing of the adjacent dust collecting plates is 400-800mm, and the wide dust collecting pole spacing is used to improve the breakdown voltage, thereby adopting a higher power supply voltage and improving the dust removing efficiency.
  • the electrode wire is a light round wire having a diameter of 2-5 mm, and the spacing of adjacent electrode wires is 400-900 mm. The use of a light round wire is beneficial to increase the breakdown voltage, thereby improving dust removal efficiency and operational stability.
  • the dust collecting plate is hung in the casing, and a high frequency rapping mechanism is arranged at the bottom thereof to prevent the dust from being blocked due to agglomeration.
  • the top of the electrode line is provided with a high-frequency rapping mechanism for preventing dust from sticking on the high-voltage electrode line, causing the corona line to be enlarged, affecting the dust removal efficiency and stable operation.
  • a baffle is disposed between the casing and the outermost dust collecting plate.
  • the baffle is used to reduce the proportion of dust-laden gas passing through the airflow, thereby improving the overall dust removal efficiency.
  • the ash hopper is disposed at the lower portion of the casing for collecting dust.
  • the number of ash hoppers can be selected according to actual working conditions, preferably 1 to 10.
  • the ash bucket is provided with a high frequency oscillating mechanism. It can prevent dust from being clogged due to agglomeration.
  • a baffle is disposed in the ash hopper.
  • the baffle is used to reduce the proportion of dust-laden gas passing through the airflow, thereby improving the overall dust removal efficiency.
  • the outer periphery of the ash hopper is provided with a heat insulating mechanism and a ash hopper insulation layer to prevent tar from condensing in the ash hopper.
  • the material of the casing, the ash hopper, the electrode wire and the dust collecting plate of the device can be made of heat-resistant alloy steel or 310S stainless steel to achieve stable operation under high temperature conditions of 800 ° C.
  • the electrostatic precipitator for high-temperature gas in the present invention can effectively reduce the adhesion of tar and dust particles on the insulator by avoiding the creepage of the insulator by improving the structure of the insulator.
  • the electrostatic precipitator for high temperature gas in the present invention can be applied to high temperature coal pyrolysis gas purification, and is used for particle trapping of oily dusty gas generated by coal pyrolysis. It not only can form a stable discharge in a high-temperature reducing atmosphere, but also can achieve stable operation under high temperature conditions of 400-600 ° C and effectively capture particulate matter in the pyrolysis gas.
  • the electrostatic precipitator for high temperature gas in the present invention can improve the energy of the system by capturing the particulate matter in the pyrolysis gas of the high temperature coal to purify the gas, improve the quality of the subsequent condensed tar and other gasification products, and the like. Utilization efficiency; in addition, the equipment operating resistance is less than 600Pa.
  • FIG. 1 is a schematic structural view of an electrostatic precipitator for a high temperature pyrolysis gas
  • Figure 2 is a left side view of an electrostatic precipitator for high temperature pyrolysis gas
  • Figure 3 is an enlarged view of the area A in Figure 1;
  • FIG. 4 is a schematic structural view of an insulator
  • Figure 5 is a schematic view showing the structure of the B-B surface of Figure 4.
  • An electrostatic precipitator for high temperature pyrolysis gas as shown in FIGS. 1 and 2, comprising: a casing 1 having a gas inlet and outlet, an ash hopper 3 disposed at a lower portion of the casing 1, and an electrode wire disposed in the casing 1 101 and a dust collecting plate 102, an insulator 2 for insulating the electrode wire 101 and the casing 1, a hot air purging mechanism for purging the insulator 2, and a high voltage power source 4 connected to the electrode wire 101.
  • the middle of the casing 1 is a hollow cylinder, and the two ends of the hollow cylinder are respectively a tapered gas inlet 104 and a gas outlet 105.
  • the electrostatic precipitator adopts a cylindrical outer casing to prevent deformation caused by high temperature thermal expansion.
  • the cylindrical outer casing has the advantages of pressure resistance, explosion proof and more uniform temperature field.
  • the gas inlet 104 and the gas outlet 105 are tapered in shape to facilitate control of the amount of gas in and out.
  • the gas inlet 104 and the gas outlet 105 are provided with an inlet baffle 106 and an outlet baffle 107, respectively, to ensure uniform flow of gas within the device.
  • the high-temperature dust-containing pyrolysis gas has a flow rate of 0.8-1.5m/s in the device, ensuring a high migration rate of dust particles in the device, and the residence time of the dust-containing pyrolysis gas in the device is 8-15s, ensuring dust particles. Can be fully removed.
  • a heating mechanism 109 and an insulating layer 110 are provided on the outer side of the casing 1.
  • the heating mechanism 109 can be electrically heated or heated by hot gas.
  • the temperature in the casing 1 is controlled to be 400-600 ° C, and the temperature is too low to cause the tar to condense in the casing 1 . , causing cohesive ash accumulation, while preventing the temperature from being too high, resulting in instability of the casing 1 during discharge and operation.
  • the material of the heat insulating layer 110 is rock wool board with a thickness of 150-200 mm, and the temperature outside the control heat insulating layer 110 is not higher than 50 °C.
  • a plurality of dust collecting plates 102 are disposed in the casing 1 , and the dust collecting plate 102 is hung in the casing 1 through the fixing frame 103 , and a high frequency rapping mechanism 108 is disposed at the bottom thereof to prevent the dust from being blocked due to agglomeration.
  • the dust collecting plate 102 is arranged in parallel in the air flow direction of the casing 1, and the dust collecting plate 102 is formed by a C-shaped dust collecting electrode plate, which is rolled by a steel plate of 1.5-10 mm, has a width of 350-850 mm, and the dust collecting electrode 102 is composed of a plurality of pieces. C-shaped dust collecting plates are spliced together.
  • the C-shaped dust collecting plate has a large dust-covered area, which is beneficial for reducing the secondary dust of the dust.
  • the spacing of the adjacent dust collecting plates 102 is 400-800 mm, and the wide dust collecting pole spacing is adopted, which is advantageous for increasing the breakdown voltage, thereby adopting a higher power supply voltage and improving the dust removing efficiency.
  • a first spoiler 111 is disposed between the casing 1 and the outermost dust collecting plate 102.
  • the first spoiler 111 is used to reduce the proportion of the dust-containing gas passing through the airflow bypass, thereby improving the overall dust removal efficiency.
  • the electrode line 101 is disposed between the adjacent dust collecting plates 102.
  • the electrode line 101 is a light round line having a diameter of 2-5 mm, and the spacing of the adjacent electrode lines 101 is 400-900 mm.
  • the use of a light round wire is beneficial to increase the breakdown voltage, thereby improving dust removal efficiency and operational stability.
  • a high-frequency rapping mechanism (not shown) is disposed on the top of the electrode wire 101 for preventing dust from sticking on the high-voltage electrode wire 101, causing the corona wire to be enlarged, affecting dust removal efficiency and stable operation.
  • the electrode wire 101 is in communication with the high voltage power source 4 through the electric wire 401.
  • the high voltage power supply 4 is a switchable polarity high voltage DC power supply.
  • the supply voltage of the switchable polarity high voltage DC power supply can be 50-200kV.
  • a non-electron negative atmosphere CH 4 , H 2 , N 2
  • the use of a positive-voltage high-voltage power source has the advantages of high dust removal efficiency and low energy consumption; in the gas component, an electronegative gas (water vapor, CO 2 )
  • the use of a negative-voltage high-voltage power supply is more efficient in dust removal.
  • the device can switch the polarity high-voltage DC power supply, which can effectively deal with the problem of unstable operation and low dust removal efficiency caused by the change of pyrolysis gas composition.
  • the insulator 2 is made of 99% corundum and is a high-purity corundum insulator for ensuring insulation at high temperatures and ensuring insulation between the electrode wire 101 and the casing 1; high-purity corundum insulator insulation
  • the performance requirements are as follows: the volume resistivity exceeds 10 14 ⁇ cm at normal temperature, and the Te value (temperature at which the volume resistivity drops to 1 M ⁇ cm) is greater than 1000 °C.
  • the insulator 2 is in the form of a hollow cylinder having a diameter of more than 300 mm, a height of more than 500 mm, and a thickness of the insulator wall of more than 10 mm.
  • the hollow structure 203 of the insulator 2 faces the inside of the casing 1.
  • the inner side of the bottom of the insulator 2 is provided with a cylinder 201 having a length of more than 600 mm and a wall thickness of more than 5 mm.
  • the structure of the cylinder can extend the creepage distance.
  • the cylinder 201 is provided with a through hole 202 for passing through the electrode wire 101, and four vent holes 205 are distributed in the middle portion of the side wall of the insulator 2, and the hole diameter may be 10-50 mm.
  • the temperature of the insulator 2 can be controlled at 350-450 ° C to prevent the tar in the pyrolysis gas from condensing on the surface and the inside of the insulator 2 to cause climbing. At the same time, it is possible to avoid leakage or the like caused by a decrease in insulation performance due to an excessive temperature.
  • the hot air purging mechanism includes a sleeve 501, an air supply pipe 502 that communicates with the sleeve 501, and a gas electric heater 5.
  • the sleeve 501 is mounted on the housing 1 and sleeved outside the insulator 2.
  • the hot air purging mechanism is used for the heat preservation and purging of the insulator 2 to prevent the tar in the pyrolysis gas from condensing on the surface of the insulator 2 to cause creepage, and to avoid leakage due to a decrease in insulation performance due to excessive temperature.
  • the hot air purge wind speed at the vent 205 of the insulator is controlled to 0.5 - 5 m/s, and the temperature of the insulator 2 is controlled at 350 - 450 °C.
  • a cavity 206 is formed between the sleeve 501 and the side wall of the insulator 2, and the air supply pipe 502 is connected to the air inlet hole 503 of the sleeve 501, so that the air supply pipe 502 and the cavity 206 communicate with the air vent 205.
  • the structure is arranged such that the purged hot gas can sequentially pass through the supply air 502, the cavity 206 and the venting opening 205, and enter the inside of the insulator 2 to prevent the tar in the pyrolysis gas from condensing inside the insulator 2 to cause creepage.
  • a sealing gasket 204 is provided at the side wall seal of the sleeve 501 and the insulator 2.
  • the ash hopper 3 is disposed at the lower portion of the casing 1 for collecting dust, and the dust is discharged by opening the ash discharging valve 301.
  • the number of ash hoppers 3 can be selected according to actual working conditions, and is three in this embodiment.
  • the ash bucket 3 can also be provided with a high-frequency oscillating mechanism (not shown) to prevent clogging of dust due to agglomeration.
  • a second spoiler 303 is disposed in the hopper 3, and the second spoiler 303 is used to reduce the proportion of the dust-containing gas passing through the airflow, thereby improving the overall dust removal efficiency.
  • the periphery of the hopper 3 is also provided with a heat insulating mechanism (not shown) and a ash insulation layer 302 to prevent tar from condensing in the hopper 3.
  • the gas inlet 104, the inlet deflector 106, the electrode wire 101, the dust collecting plate 102, the casing 1, the ash hopper 3, the gas outlet 105, and the outlet deflector 107 in the components of the electrostatic precipitator are all made of a heat resistant alloy. Steel or 310S stainless steel, able to withstand long-term stability at 800 °C.
  • the high-temperature oil-containing dust-containing pyrolysis gas enters the inside of the casing 1 of the device after passing through the gas inlet 104 and the inlet baffle 106, and the electrode wire 102 and the casing 1 are insulated by the high-purity corundum insulator 2, and the insulator 2
  • the outer sleeve is provided with a hot air purging mechanism, and the wind speed of purging the hot air at the vent 205 of the insulator 2 is controlled to 0.5-5 m/s by the operation of the hot air purging mechanism, and the surface temperature of the insulator is controlled at 350-450 ° C, Prevent the tar in the pyrolysis gas from condensing on the surface of the insulator 2 to cause creepage, and at the same time avoid the occurrence of leakage due to the deterioration of the insulation performance due to excessive temperature.
  • the electrode line 101 is connected with a switchable polarity high voltage DC power source for forming a high voltage electric field and a corona discharge between the electrode line 101 and the dust collecting plate 102.
  • a switchable polarity high voltage DC power source for forming a high voltage electric field and a corona discharge between the electrode line 101 and the dust collecting plate 102.
  • the dust particles in the high temperature gas are taken.
  • the upper charge is applied to the dust collecting plate 102 under the action of the electric field force.
  • the high-frequency rapping mechanism 108 performs rapping to cause the dust to fall off the dust collecting plate 102, and falls into the ash hopper 3.
  • the ash discharging valve 301 is opened to discharge the dust. Waiting for the next processing and utilization; the purified gas enters the downstream process through the gas outlet 105 and the outlet deflector 107.
  • the invention can fully capture fine particles in the oily dusty pyrolysis gas at high temperature, ensure the purity of the tar during the subsequent condensation preparation of the tar, and the quality of the gas. It can achieve 95% dust removal efficiency at 600 °C, 98% dust removal efficiency at 400 °C, and the running resistance of the device is less than 600Pa.

Abstract

Disclosed is an electrostatic dust removal device for high-temperature coal gas, comprising: a shell (1) provided with a gas inlet (104) and a gas outlet (105), dust hoppers (3) arranged at the lower part of the shell (1), electrode wires (101) and dust collecting electrode plates (102) arranged in the shell (1), insulators (2) for insulating the electrode wires (101) and the shell (1), a hot gas purging mechanism for purging the insulators (2), and a high-pressure power supply (4) connected to the electrode wires (101); and the insulator (2) is shaped like a hollow cylinder, the hollow structure of the insulator (2) faces the interior of the shell (1), a cylinder (201) used for penetrating through the electrode wire (101) is arranged on an inner side of the bottom of the insulator (2), and a ventilation structure is arranged on a side wall of the insulator (2). With the device, tar oil and dust particles adhered to the insulator (2) can be effectively reduced, thereby avoiding creepage of the insulator (2).

Description

一种用于高温煤气的静电除尘装置Electrostatic dust removing device for high temperature gas 技术领域Technical field
本发明属于高温除尘的技术领域,具体涉及一种用于高温煤气的静电除尘装置。The invention belongs to the technical field of high temperature dust removal, and particularly relates to an electrostatic dust removal device for high temperature gas.
背景技术Background technique
以煤炭热解为基础的煤基多联产技术是一种煤炭高效清洁利用的重要技术手段,在高温缺氧环境下对富含挥发分的煤炭进行热解气化,可获得煤气、焦油和半焦,煤气经分离提纯可获得高品质气体燃料,焦油通过进一步深加工可获得高品质的化工产品,半焦可直接用于燃烧发电,从而实现煤炭分级转化清洁利用,具有广阔的应用前景。Coal-based polygeneration technology based on coal pyrolysis is an important technical means for efficient and clean coal utilization. Pyrolysis and gasification of coal with high volatile content in high temperature and anoxic environment can obtain gas, tar and Semi-coke, gas can be separated and purified to obtain high-quality gas fuel. The tar can obtain high-quality chemical products through further deep processing. The semi-coke can be directly used for combustion and power generation, so as to achieve clean utilization of coal graded conversion, which has broad application prospects.
煤炭经热解气化产生的粗煤气中含有大量的飞灰、煤炭等颗粒物,对其直接冷凝分离得到的焦油中含有大量的颗粒物,对后续加工利用将产生较大的不利影响。高温热解煤气具有温度高(600℃及以上)、气体成分以还原性气氛(如CH 4、H 2)为主、含焦油(在400℃以下易冷凝)等特点,对其进行颗粒物脱除较为困难。当前,阻碍煤基多联产技术工业应用的一个重要问题就是高温(400℃以上)热解煤气除尘尚未得到较好解决。 The crude gas produced by pyrolysis gasification of coal contains a large amount of particulate matter such as fly ash and coal. The tar obtained by direct condensation separation contains a large amount of particulate matter, which will have a great adverse effect on subsequent processing and utilization. High-temperature pyrolysis gas has high temperature (600 ° C and above), gas composition mainly in reducing atmosphere (such as CH 4 , H 2 ), tar-containing (easy to condense below 400 ° C), etc. More difficult. At present, an important problem that hinders the industrial application of coal-based polygeneration technology is that high temperature (above 400 °C) pyrolysis gas dedusting has not been well solved.
当前,高温除尘技术主要有旋风除尘技术、陶瓷/金属过滤除尘技术、颗粒层除尘技术和静电除尘技术。旋风除尘器对细微颗粒除尘效率低,只能作为预处理设备;陶瓷/金属过滤除尘器除尘效率高,但是陶瓷过滤除尘设备热震性差、易碎,金属过滤除尘器在高温下易腐蚀;颗粒层除尘器面临压力损失大、能耗较高以及工质再生困难的问题。At present, high-temperature dust removal technologies mainly include cyclone dust removal technology, ceramic/metal filtration dust removal technology, particle layer dust removal technology and electrostatic dust removal technology. Cyclone dust collector has low dust removal efficiency for fine particles and can only be used as pretreatment equipment; ceramic/metal filter dust collector has high dust removal efficiency, but ceramic filter dust removal equipment has poor thermal shock and brittleness, and metal filter dust collector is easy to corrode at high temperature; The layer dust collector faces the problems of large pressure loss, high energy consumption and difficulty in regenerating the working medium.
静电除尘技术具有除尘效率高、压力损失小以及可处理烟气量大等优点,在常规燃煤电厂已得到大规模应用,然而,在高温热解煤气环境下,存在以下困难。The electrostatic precipitator technology has the advantages of high dust removal efficiency, low pressure loss and large amount of flue gas treatment. It has been widely used in conventional coal-fired power plants. However, in the high-temperature pyrolysis gas environment, the following difficulties exist.
在静电除尘器放电过程中,由于热解煤气主要成分为甲烷、氢气等非电负性气体,造成放电电流以电子电流为主,颗粒荷电效率大大降低,从而影响除尘效率;另外,高温下起晕电压和击穿电压之间差距缩小,造成静电除尘器在运行过程中极易发生击穿,影响除尘器稳定运行。In the discharge process of electrostatic precipitator, since the main component of pyrolysis gas is non-electron negative gas such as methane and hydrogen, the discharge current is mainly composed of electron current, and the efficiency of particle charging is greatly reduced, thereby affecting dust removal efficiency; The gap between the dizzying voltage and the breakdown voltage is reduced, which causes the electrostatic precipitator to be easily broken down during operation, which affects the stable operation of the precipitator.
高温热解煤气中富含焦油,在静电除尘器运行过程中,绝缘子上易黏附焦油以及灰尘颗粒,尤其是绝缘子的内侧壁面,造成绝缘子爬电,影响除尘器稳定运行;混有焦油的灰尘颗粒黏附性增强,黏附在收尘极板上,造成清灰困难,从而影响除尘器的稳定运行。The high temperature pyrolysis gas is rich in tar. During the operation of the electrostatic precipitator, the insulator tends to adhere to tar and dust particles, especially the inner wall surface of the insulator, causing the insulator to creep up, affecting the stable operation of the dust collector; dust particles mixed with tar Adhesion is enhanced and adheres to the dust collecting plate, which makes it difficult to clean the dust, thus affecting the stable operation of the dust collector.
发明内容Summary of the invention
本发明的目的在于针对现有技术的不足,提供一种用于高温煤气的静电除尘装置,能够有效地减少绝缘子上黏附焦油和灰尘颗粒,避免绝缘子爬电。The object of the present invention is to provide an electrostatic precipitator for high temperature gas, which can effectively reduce the adhesion of tar and dust particles on the insulator and avoid creepage of the insulator.
本发明所提供的技术方案为:The technical solution provided by the invention is:
一种用于高温煤气的静电除尘装置,包括:具有气体进出口的壳体,设置在壳体下部的灰斗,设置在壳体内的电极线和收尘极板,用于绝缘电极线与壳体的绝缘子,用于吹扫绝缘子的热气吹扫机构,以及与电极线连接的高压电源;所述绝缘子的形状为中空圆筒,绝缘子的中空结构朝向壳体内部,绝缘子的底部内侧设有用于穿过电极线的圆柱,绝缘子侧壁设有通风结构。An electrostatic precipitator for a high temperature gas, comprising: a casing having a gas inlet and outlet, a ash hopper disposed at a lower portion of the casing, an electrode wire and a dust collecting plate disposed in the casing, and an insulating electrode wire and a casing Insulator, a hot air purging mechanism for purging the insulator, and a high voltage power source connected to the electrode line; the insulator is in the shape of a hollow cylinder, the hollow structure of the insulator faces the inside of the casing, and the inner side of the bottom of the insulator is provided for Through the cylinder of the electrode wire, the side wall of the insulator is provided with a ventilation structure.
上述的技术方案中,由于绝缘子的侧壁设有通风结构,热气吹扫机构针对绝缘子工作时,能够控制绝缘子的温度在350-450℃,防止热解煤气中焦油在绝缘子表面与内侧冷凝而造成爬电,同时能够避免由于温度过高而导致绝 缘性能下降造成的漏电等现象地发生。In the above technical solution, since the side wall of the insulator is provided with a ventilation structure, when the hot gas purging mechanism works for the insulator, the temperature of the insulator can be controlled at 350-450 ° C to prevent condensation of tar on the surface and the inside of the insulator in the pyrolysis gas. Creepage, at the same time, can avoid the occurrence of leakage due to the deterioration of insulation performance due to excessive temperature.
本发明中的高温煤气包括高温裂解煤气、高温气化煤气等。The high temperature gas in the present invention includes pyrolysis gas, high temperature gasification gas, and the like.
本发明中的绝缘子使用99%刚玉烧制,为高纯刚玉绝缘子,用于保证高温下的绝缘性能,保证电极线与壳体之间的绝缘;高纯刚玉绝缘子绝缘性能要求达到:体积电阻率常温下超过10 14Ωcm,Te值(体积电阻率降到1MΩcm时的温度)大于1000℃。绝缘子形状为中空圆筒,其直径大于300mm,高度大于500mm,绝缘子壁面的厚度大于10mm。 The insulator in the invention is made of 99% corundum and is a high-purity corundum insulator for ensuring the insulation performance at high temperature and ensuring the insulation between the electrode wire and the casing; the insulation performance requirement of the high-purity corundum insulator is: volume resistivity Above room temperature exceeds 10 14 Ωcm, the Te value (temperature at which the volume resistivity drops to 1 M Ω cm) is greater than 1000 ° C. The shape of the insulator is a hollow cylinder having a diameter of more than 300 mm and a height of more than 500 mm, and the thickness of the insulator wall is greater than 10 mm.
作为优选,所述通风结构为通风孔,所述绝缘子侧壁上分布4-16个孔,孔径为10-50mm。进一步优选在绝缘子侧壁中间部分开孔。Preferably, the ventilation structure is a venting hole, and 4-16 holes are arranged on the side wall of the insulator, and the aperture is 10-50 mm. It is further preferred to open a hole in the middle portion of the side wall of the insulator.
作为优选,所述圆柱的长度大于600mm。圆柱中空用于穿过电极线,其壁厚度可以大于5mm,该圆柱的结构设置能够延长爬电距离。Preferably, the length of the cylinder is greater than 600 mm. The cylindrical hollow is used to pass through the electrode wire, and its wall thickness can be greater than 5 mm, and the structure of the cylinder can extend the creepage distance.
本发明中所述热气吹扫机构包括套筒,连通套筒的供气管以及气体电加热器;所述套筒安装在壳体上,套设在绝缘子外部。热气吹扫机构用于绝缘子的保温和吹扫,防止热解煤气中焦油在绝缘子表面冷凝而造成爬电,同时避免由于温度过高而导致绝缘性能下降造成的漏电等现象地发生。通过控制气体电加热器使得绝缘子的通风结构处的热气吹扫风速控制为0.5-5m/s,并控制绝缘子的温度在350-450℃。The hot air purging mechanism of the present invention comprises a sleeve, a gas supply pipe connecting the sleeve and a gas electric heater; the sleeve is mounted on the casing and sleeved outside the insulator. The hot air purging mechanism is used for the insulation and purging of the insulator to prevent the tar in the pyrolysis gas from condensing on the surface of the insulator to cause creepage, and at the same time avoid leakage such as leakage due to excessive temperature. The hot air purge wind speed at the ventilating structure of the insulator is controlled to be 0.5-5 m/s by controlling the gas electric heater, and the temperature of the insulator is controlled at 350-450 °C.
作为优选,热气吹扫机构中热气采用水蒸气或热煤气(与静电除尘装置内不含油气体成分相同)。热气吹扫机构中热气成分不能含有氧气,避免高温情况下与静电除尘装置内煤气混合,发生爆炸。Preferably, the hot air in the hot air purging mechanism is made of steam or hot gas (the same as the oil-free gas component in the electrostatic precipitator). The hot gas component of the hot air purging mechanism cannot contain oxygen, and it is prevented from mixing with the gas in the electrostatic precipitator under high temperature and exploding.
作为优选,所述套筒与绝缘子的侧壁之间形成空腔,使得供气管、空腔与通风结构连通。该结构设置使得吹扫的热气能够依次经过供气管、空腔与通风结构,进入绝缘子的内侧,防止热解煤气中焦油在绝缘子内侧冷凝而造成爬电。Preferably, a cavity is formed between the sleeve and the side wall of the insulator such that the air supply tube and the cavity are in communication with the venting structure. The structure is arranged such that the purged hot gas can sequentially pass through the air supply pipe, the cavity and the ventilation structure, and enter the inner side of the insulator to prevent the tar in the pyrolysis gas from condensing inside the insulator and causing creepage.
作为优选,所述套筒与绝缘子的侧壁密封处设有密封垫片。Preferably, a sealing gasket is provided at the side wall seal of the sleeve and the insulator.
本发明中所述壳体中间为中空圆柱体,中空圆柱体两端分别为锥形的气体入口和气体出口。静电除尘装置采用圆柱体外壳,用于防止高温热膨胀产生的形变,此外,圆柱体外壳还具有抗压、防爆、温度场更均匀的优点。气体入口和气体出口的形状为锥形,有利于气体进出量的控制。优选地,所述高温含尘热解煤气在装置内流速为0.8-1.5m/s,保证灰尘颗粒在装置内有较高的迁移速率,含尘气体在装置内的停留时间为8-15s,保证灰尘颗粒能够充分脱除。优选地,所述气体入口和气体出口分别设置导流板,保证气体在装置内均匀流动。In the present invention, the middle of the casing is a hollow cylinder, and the two ends of the hollow cylinder are respectively a conical gas inlet and a gas outlet. The electrostatic precipitator adopts a cylindrical outer casing to prevent deformation caused by high temperature thermal expansion. In addition, the cylindrical outer casing has the advantages of pressure resistance, explosion proof and more uniform temperature field. The gas inlet and the gas outlet are tapered in shape to facilitate control of the amount of gas in and out. Preferably, the high-temperature dust-containing pyrolysis gas has a flow rate of 0.8-1.5 m/s in the device, ensuring a high migration rate of the dust particles in the device, and the residence time of the dust-containing gas in the device is 8-15 s. Ensure that dust particles are fully removed. Preferably, the gas inlet and the gas outlet are respectively provided with baffles to ensure uniform flow of gas within the device.
作为优选,所述壳体外侧设有加热机构和保温层。加热机构可以采用电加热或者热气加热,通过调节电辅助加热装置的功率或者热气的流量,控制壳体内温度在400-600℃,用于防止温度过低导致焦油在壳体内冷凝,造成粘结性积灰,同时防止温度过高导致壳体在放电、运行过程中的不稳定。保温层的材料选用岩棉板,厚度为150-200mm,控制保温层外侧温度不高于50℃。Preferably, the outer side of the casing is provided with a heating mechanism and a heat insulating layer. The heating mechanism can adopt electric heating or hot gas heating. By adjusting the power of the electric auxiliary heating device or the flow rate of the hot gas, the temperature in the casing is controlled to be 400-600 ° C, which is used to prevent the tar from condensing in the casing due to the low temperature, resulting in cohesiveness. The accumulation of ash, while preventing the temperature from being too high, causes the housing to be unstable during discharge and operation. The material of the insulation layer is rock wool board with a thickness of 150-200mm, and the outside temperature of the control insulation layer is not higher than 50 °C.
静电除尘装置的壳体外侧加热机构若采用热气加热,作为优选,热气采用热氮气或热烟气等惰性气体,既可以为静电除尘装置提供加热和保温,又可以作为密封层,避免静电除尘装置内煤气和外界空气接触,发生爆炸。If the heating mechanism outside the casing of the electrostatic precipitator is heated by hot gas, it is preferred that the hot gas is an inert gas such as hot nitrogen or hot flue gas, which can provide heating and heat preservation for the electrostatic precipitator, and can also serve as a sealing layer to avoid electrostatic precipitator. The internal gas is in contact with the outside air and an explosion occurs.
作为优选,所述高压电源为可切换极性高压直流电源。可切换极性高压直流电源的供电电压可以为50-200kV。在非电负性气氛(CH 4、H 2、N 2)中,使用正极性高压电源具有除尘效率高、能耗低的优点;在气体组分以电负性气体(水蒸气、CO 2)为主的气氛中,使用负极性高压电源除尘效率更高。本装置中使用可切换极性高压直流电源,可以有效应对热解煤气组分变动带来的运行不稳定、除尘效率低的难题。 Advantageously, said high voltage power source is a switchable polarity high voltage DC power source. The supply voltage of the switchable polarity high voltage DC power supply can be 50-200kV. In a non-electron negative atmosphere (CH 4 , H 2 , N 2 ), the use of a positive-voltage high-voltage power source has the advantages of high dust removal efficiency and low energy consumption; in the gas component, an electronegative gas (water vapor, CO 2 ) In the main atmosphere, the use of a negative-voltage high-voltage power supply is more efficient in dust removal. The device can switch the polarity high-voltage DC power supply, which can effectively deal with the problem of unstable operation and low dust removal efficiency caused by the change of pyrolysis gas composition.
本发明中所述壳体内设有若干收尘极板,所述收尘极板平行设置于壳体 内气流方向;所述电极线设置在相邻收尘极板之间。所述收尘极板采用C形收尘电极板,收尘极板采用1.5-10mm的钢板轧成,宽度为350-850mm,收尘电极由多块C形收尘极板拼接而成。C形收尘极板具有较大的沉尘面积,有利于降低粉尘的二次扬尘。相邻收尘极板的间距为400-800mm,采用较宽的收尘极间距,有利于提高击穿电压,从而采用更高的电源电压,提升除尘效率。优选地,电极线采用光圆线,直径2-5mm,相邻电极线的间距为400-900mm。采用光圆线,有利于提高击穿电压,从而提升除尘效率及运行稳定性。In the present invention, a plurality of dust collecting plates are disposed in the casing, and the dust collecting plates are disposed in parallel in the airflow direction of the casing; the electrode wires are disposed between adjacent dust collecting plates. The dust collecting plate adopts a C-shaped dust collecting electrode plate, and the dust collecting plate is rolled by a steel plate of 1.5-10 mm, the width is 350-850 mm, and the dust collecting electrode is formed by splicing a plurality of C-shaped dust collecting plates. The C-shaped dust collecting plate has a large dust-covered area, which is beneficial for reducing the secondary dust of the dust. The spacing of the adjacent dust collecting plates is 400-800mm, and the wide dust collecting pole spacing is used to improve the breakdown voltage, thereby adopting a higher power supply voltage and improving the dust removing efficiency. Preferably, the electrode wire is a light round wire having a diameter of 2-5 mm, and the spacing of adjacent electrode wires is 400-900 mm. The use of a light round wire is beneficial to increase the breakdown voltage, thereby improving dust removal efficiency and operational stability.
作为优选,所述收尘极板挂设在壳体内,其底部设有高频振打机构,可以防止灰尘由于结块而造成堵塞。Preferably, the dust collecting plate is hung in the casing, and a high frequency rapping mechanism is arranged at the bottom thereof to prevent the dust from being blocked due to agglomeration.
作为优选,所述电极线的顶部设置高频振打机构,用于防止粉尘在高压电极线上粘结,造成电晕线肥大,影响除尘效率及稳定运行。Preferably, the top of the electrode line is provided with a high-frequency rapping mechanism for preventing dust from sticking on the high-voltage electrode line, causing the corona line to be enlarged, affecting the dust removal efficiency and stable operation.
作为优选,所述壳体与最外侧的收尘极板间设有阻流板。阻流板用于减少含尘气体经过气流旁路的比例,从而提升整体除尘效率。Preferably, a baffle is disposed between the casing and the outermost dust collecting plate. The baffle is used to reduce the proportion of dust-laden gas passing through the airflow, thereby improving the overall dust removal efficiency.
本发明中灰斗设置在壳体下部用于收集粉尘。灰斗的数量可以根据实际工况进行选择,优选1~10个。所述灰斗设置高频振打机构。可以防止灰尘由于结块而造成堵塞。In the present invention, the ash hopper is disposed at the lower portion of the casing for collecting dust. The number of ash hoppers can be selected according to actual working conditions, preferably 1 to 10. The ash bucket is provided with a high frequency oscillating mechanism. It can prevent dust from being clogged due to agglomeration.
作为优选,所述灰斗内设有阻流板。阻流板用于减少含尘气体经过气流旁路的比例,从而提升整体除尘效率。Preferably, a baffle is disposed in the ash hopper. The baffle is used to reduce the proportion of dust-laden gas passing through the airflow, thereby improving the overall dust removal efficiency.
作为优选,所述灰斗的外围设有保温机构和灰斗保温层,防止焦油在灰斗内冷凝。Preferably, the outer periphery of the ash hopper is provided with a heat insulating mechanism and a ash hopper insulation layer to prevent tar from condensing in the ash hopper.
作为优选,所述装置的壳体、灰斗、电极线以及收尘极板的材料均可以使用耐热合金钢或310S不锈钢,实现800℃高温条件下的稳定运行。Preferably, the material of the casing, the ash hopper, the electrode wire and the dust collecting plate of the device can be made of heat-resistant alloy steel or 310S stainless steel to achieve stable operation under high temperature conditions of 800 ° C.
同现有技术相比,本发明的有益效果体现在:Compared with the prior art, the beneficial effects of the present invention are embodied in:
(1)本发明中用于高温煤气的静电除尘装置通过对绝缘子的结构进行改进,能够有效地减少绝缘子上黏附焦油和灰尘颗粒,避免绝缘子爬电。(1) The electrostatic precipitator for high-temperature gas in the present invention can effectively reduce the adhesion of tar and dust particles on the insulator by avoiding the creepage of the insulator by improving the structure of the insulator.
(2)本发明中用于高温煤气的静电除尘装置可应用于高温煤炭热解气净化,用于煤炭热解生成的含油含尘煤气的颗粒捕集。其不仅能够在高温还原性气氛中形成稳定放电,而且能够实现400-600℃高温条件下稳定工作并有效捕集热解气中的颗粒物。(2) The electrostatic precipitator for high temperature gas in the present invention can be applied to high temperature coal pyrolysis gas purification, and is used for particle trapping of oily dusty gas generated by coal pyrolysis. It not only can form a stable discharge in a high-temperature reducing atmosphere, but also can achieve stable operation under high temperature conditions of 400-600 ° C and effectively capture particulate matter in the pyrolysis gas.
(3)本发明中用于高温煤气的静电除尘装置通过捕集高温煤热解气中的颗粒物以达到净化煤气、提高后续冷凝焦油品质及其他气化产物品质等目的,并可提高系统的能量利用效率;另外,该设备运行阻力小于600Pa。(3) The electrostatic precipitator for high temperature gas in the present invention can improve the energy of the system by capturing the particulate matter in the pyrolysis gas of the high temperature coal to purify the gas, improve the quality of the subsequent condensed tar and other gasification products, and the like. Utilization efficiency; in addition, the equipment operating resistance is less than 600Pa.
附图说明DRAWINGS
图1为用于高温热解煤气的静电除尘装置的结构示意图;1 is a schematic structural view of an electrostatic precipitator for a high temperature pyrolysis gas;
图2为用于高温热解煤气的静电除尘装置的左视图;Figure 2 is a left side view of an electrostatic precipitator for high temperature pyrolysis gas;
图3为图1中A区域的放大图;Figure 3 is an enlarged view of the area A in Figure 1;
图4为绝缘子的结构示意图;4 is a schematic structural view of an insulator;
图5为图4中B-B面的结构示意图。Figure 5 is a schematic view showing the structure of the B-B surface of Figure 4;
其中,1、壳体;101、电极线;102、收尘极板;103、固定架;104、气体入口;105、气体出口;106、入口导流板;107、出口导流板;108、高频振打机构;109、加热机构;110、保温层;111、第一阻流板;2、绝缘子;201、圆柱;202、穿孔;203、中空结构;204、密封垫片;205、通风孔;206、空腔;3、灰斗;301、卸灰阀;302、灰斗保温层;303、第二阻流板;4、高压电源;401、电线;5、气体电加热器;501、套筒;502、供气管;503、进气孔。Wherein, 1, housing; 101, electrode line; 102, dust collecting plate; 103, fixing frame; 104, gas inlet; 105, gas outlet; 106, inlet deflector; 107, outlet deflector; High frequency rapping mechanism; 109, heating mechanism; 110, thermal insulation layer; 111, first spoiler; 2, insulator; 201, cylinder; 202, perforation; 203, hollow structure; 204, sealing gasket; 205, ventilation hole; 206, cavity; 3, ash bucket; 301, ash discharge valve; 302, ash bucket insulation layer; 303, second spoiler; 4, high voltage power supply; 401, wire; 5, gas electric heater; 501, set Cartridge; 502, air supply pipe; 503, air intake.
具体实施方式detailed description
下面结合附图和具体实例对本发明作进一步说明,但本发明的保护范围并不限于此。The present invention will be further described below in conjunction with the drawings and specific examples, but the scope of the present invention is not limited thereto.
如图1和2所示的用于高温热解煤气的静电除尘装置,包括:具有气体进出口的壳体1,设置在壳体1下部的灰斗3,设置在壳体1内的电极线101和收尘极板102,用于绝缘电极线101与壳体1的绝缘子2,用于吹扫绝缘子2的热气吹扫机构,以及与电极线101连接的高压电源4。An electrostatic precipitator for high temperature pyrolysis gas as shown in FIGS. 1 and 2, comprising: a casing 1 having a gas inlet and outlet, an ash hopper 3 disposed at a lower portion of the casing 1, and an electrode wire disposed in the casing 1 101 and a dust collecting plate 102, an insulator 2 for insulating the electrode wire 101 and the casing 1, a hot air purging mechanism for purging the insulator 2, and a high voltage power source 4 connected to the electrode wire 101.
壳体1中间为中空圆柱体,中空圆柱体两端分别为锥形的气体入口104和气体出口105。静电除尘装置采用圆柱体外壳,用于防止高温热膨胀产生的形变,此外,圆柱体外壳还具有抗压、防爆、温度场更均匀的优点。气体入口104和气体出口105的形状为锥形,有利于气体进出量的控制。气体入口104和气体出口105分别设置入口导流板106和出口导流板107,保证气体在装置内均匀流动。高温含尘热解煤气在装置内流速为0.8-1.5m/s,保证灰尘颗粒在装置内有较高的迁移速率,含尘热解煤气在装置内的停留时间为8-15s,保证灰尘颗粒能够充分脱除。The middle of the casing 1 is a hollow cylinder, and the two ends of the hollow cylinder are respectively a tapered gas inlet 104 and a gas outlet 105. The electrostatic precipitator adopts a cylindrical outer casing to prevent deformation caused by high temperature thermal expansion. In addition, the cylindrical outer casing has the advantages of pressure resistance, explosion proof and more uniform temperature field. The gas inlet 104 and the gas outlet 105 are tapered in shape to facilitate control of the amount of gas in and out. The gas inlet 104 and the gas outlet 105 are provided with an inlet baffle 106 and an outlet baffle 107, respectively, to ensure uniform flow of gas within the device. The high-temperature dust-containing pyrolysis gas has a flow rate of 0.8-1.5m/s in the device, ensuring a high migration rate of dust particles in the device, and the residence time of the dust-containing pyrolysis gas in the device is 8-15s, ensuring dust particles. Can be fully removed.
壳体1的外侧设有加热机构109和保温层110。加热机构109可以采用电加热或者热气加热,通过调节电辅助加热装置的功率或者热气的流量,控制壳体1内温度在400-600℃,用于防止温度过低导致焦油在壳体1内冷凝,造成粘结性积灰,同时防止温度过高导致壳体1在放电、运行过程中的不稳定。保温层110的材料选用岩棉板,厚度为150-200mm,控制保温层110外侧温度不高于50℃。A heating mechanism 109 and an insulating layer 110 are provided on the outer side of the casing 1. The heating mechanism 109 can be electrically heated or heated by hot gas. By adjusting the power of the electric auxiliary heating device or the flow rate of the hot gas, the temperature in the casing 1 is controlled to be 400-600 ° C, and the temperature is too low to cause the tar to condense in the casing 1 . , causing cohesive ash accumulation, while preventing the temperature from being too high, resulting in instability of the casing 1 during discharge and operation. The material of the heat insulating layer 110 is rock wool board with a thickness of 150-200 mm, and the temperature outside the control heat insulating layer 110 is not higher than 50 °C.
其中,壳体1内设有若干收尘极板102,收尘极板102通过固定架103挂设在壳体1内,其底部设有高频振打机构108,可以防止灰尘由于结块而造成堵塞。收尘极板102平行设置于壳体1内气流方向,收尘极板102采用C形 收尘电极板,采用1.5-10mm的钢板轧成,宽度为350-850mm,收尘电极102由多块C形收尘极板拼接而成。C形收尘极板具有较大的沉尘面积,有利于降低粉尘的二次扬尘。相邻收尘极板102的间距为400-800mm,采用较宽的收尘极间距,有利于提高击穿电压,从而采用更高的电源电压,提升除尘效率。A plurality of dust collecting plates 102 are disposed in the casing 1 , and the dust collecting plate 102 is hung in the casing 1 through the fixing frame 103 , and a high frequency rapping mechanism 108 is disposed at the bottom thereof to prevent the dust from being blocked due to agglomeration. . The dust collecting plate 102 is arranged in parallel in the air flow direction of the casing 1, and the dust collecting plate 102 is formed by a C-shaped dust collecting electrode plate, which is rolled by a steel plate of 1.5-10 mm, has a width of 350-850 mm, and the dust collecting electrode 102 is composed of a plurality of pieces. C-shaped dust collecting plates are spliced together. The C-shaped dust collecting plate has a large dust-covered area, which is beneficial for reducing the secondary dust of the dust. The spacing of the adjacent dust collecting plates 102 is 400-800 mm, and the wide dust collecting pole spacing is adopted, which is advantageous for increasing the breakdown voltage, thereby adopting a higher power supply voltage and improving the dust removing efficiency.
如图2所示,壳体1与最外侧的收尘极板102间设有第一阻流板111。第一阻流板111用于减少含尘气体经过气流旁路的比例,从而提升整体除尘效率。As shown in FIG. 2, a first spoiler 111 is disposed between the casing 1 and the outermost dust collecting plate 102. The first spoiler 111 is used to reduce the proportion of the dust-containing gas passing through the airflow bypass, thereby improving the overall dust removal efficiency.
而电极线101设置在相邻收尘极板102之间,电极线101采用光圆线,直径2-5mm,相邻电极线101的间距为400-900mm。采用光圆线,有利于提高击穿电压,从而提升除尘效率及运行稳定性。同样,电极线101的顶部设置高频振打机构(图中未给出),用于防止粉尘在高压电极线101上粘结,造成电晕线肥大,影响除尘效率及稳定运行。The electrode line 101 is disposed between the adjacent dust collecting plates 102. The electrode line 101 is a light round line having a diameter of 2-5 mm, and the spacing of the adjacent electrode lines 101 is 400-900 mm. The use of a light round wire is beneficial to increase the breakdown voltage, thereby improving dust removal efficiency and operational stability. Similarly, a high-frequency rapping mechanism (not shown) is disposed on the top of the electrode wire 101 for preventing dust from sticking on the high-voltage electrode wire 101, causing the corona wire to be enlarged, affecting dust removal efficiency and stable operation.
电极线101通过电线401与高压电源4连通。高压电源4为可切换极性高压直流电源。可切换极性高压直流电源的供电电压可以为50-200kV。在非电负性气氛(CH 4、H 2、N 2)中,使用正极性高压电源具有除尘效率高、能耗低的优点;在气体组分以电负性气体(水蒸气、CO 2)为主的气氛中,使用负极性高压电源除尘效率更高。本装置中使用可切换极性高压直流电源,可以有效应对热解煤气组分变动带来的运行不稳定、除尘效率低的难题。 The electrode wire 101 is in communication with the high voltage power source 4 through the electric wire 401. The high voltage power supply 4 is a switchable polarity high voltage DC power supply. The supply voltage of the switchable polarity high voltage DC power supply can be 50-200kV. In a non-electron negative atmosphere (CH 4 , H 2 , N 2 ), the use of a positive-voltage high-voltage power source has the advantages of high dust removal efficiency and low energy consumption; in the gas component, an electronegative gas (water vapor, CO 2 ) In the main atmosphere, the use of a negative-voltage high-voltage power supply is more efficient in dust removal. The device can switch the polarity high-voltage DC power supply, which can effectively deal with the problem of unstable operation and low dust removal efficiency caused by the change of pyrolysis gas composition.
如图3~5所示,绝缘子2使用99%刚玉烧制,为高纯刚玉绝缘子,用于保证高温下的绝缘性能,保证电极线101与壳体1之间的绝缘;高纯刚玉绝缘子绝缘性能要求达到:体积电阻率常温下超过10 14Ωcm,Te值(体积电阻率降到1MΩcm时的温度)大于1000℃。 As shown in Figures 3 to 5, the insulator 2 is made of 99% corundum and is a high-purity corundum insulator for ensuring insulation at high temperatures and ensuring insulation between the electrode wire 101 and the casing 1; high-purity corundum insulator insulation The performance requirements are as follows: the volume resistivity exceeds 10 14 Ωcm at normal temperature, and the Te value (temperature at which the volume resistivity drops to 1 MΩcm) is greater than 1000 °C.
绝缘子2形状为中空圆筒,其直径大于300mm,高度大于500mm,绝缘 子壁面的厚度大于10mm。绝缘子2的中空结构203朝向壳体1内部。绝缘子2的底部内侧设有圆柱201,圆柱的长度大于600mm,其壁厚度可以大于5mm,该圆柱的结构设置能够延长爬电距离。圆柱201设有穿孔202用于穿过电极线101,绝缘子2侧壁中间部分分布设有4个通风孔205,孔径可以为10-50mm。由于绝缘子2的侧壁设有通风孔205,热气吹扫机构针对绝缘子2工作时,能够控制绝缘子2的温度在350-450℃,防止热解煤气中焦油在绝缘子2表面与内侧冷凝而造成爬电,同时能够避免由于温度过高而导致绝缘性能下降造成的漏电等现象地发生。The insulator 2 is in the form of a hollow cylinder having a diameter of more than 300 mm, a height of more than 500 mm, and a thickness of the insulator wall of more than 10 mm. The hollow structure 203 of the insulator 2 faces the inside of the casing 1. The inner side of the bottom of the insulator 2 is provided with a cylinder 201 having a length of more than 600 mm and a wall thickness of more than 5 mm. The structure of the cylinder can extend the creepage distance. The cylinder 201 is provided with a through hole 202 for passing through the electrode wire 101, and four vent holes 205 are distributed in the middle portion of the side wall of the insulator 2, and the hole diameter may be 10-50 mm. Since the side wall of the insulator 2 is provided with the venting hole 205, when the hot air purging mechanism works for the insulator 2, the temperature of the insulator 2 can be controlled at 350-450 ° C to prevent the tar in the pyrolysis gas from condensing on the surface and the inside of the insulator 2 to cause climbing. At the same time, it is possible to avoid leakage or the like caused by a decrease in insulation performance due to an excessive temperature.
热气吹扫机构包括套筒501,连通套筒501的供气管502以及气体电加热器5。套筒501安装在壳体1上,套设在绝缘子2外部。热气吹扫机构用于绝缘子2的保温和吹扫,防止热解煤气中焦油在绝缘子2表面冷凝而造成爬电,同时避免由于温度过高而导致绝缘性能下降造成的漏电等现象地发生。通过控制气体电加热器5使得绝缘子的通风孔205处的热气吹扫风速控制为0.5-5m/s,并控制绝缘子2的温度在350-450℃。The hot air purging mechanism includes a sleeve 501, an air supply pipe 502 that communicates with the sleeve 501, and a gas electric heater 5. The sleeve 501 is mounted on the housing 1 and sleeved outside the insulator 2. The hot air purging mechanism is used for the heat preservation and purging of the insulator 2 to prevent the tar in the pyrolysis gas from condensing on the surface of the insulator 2 to cause creepage, and to avoid leakage due to a decrease in insulation performance due to excessive temperature. By controlling the gas electric heater 5, the hot air purge wind speed at the vent 205 of the insulator is controlled to 0.5 - 5 m/s, and the temperature of the insulator 2 is controlled at 350 - 450 °C.
如图3所示,套筒501与绝缘子2的侧壁之间形成空腔206,供气管502与套筒501上的进气孔503连接,使得供气管502、空腔206与通风孔205连通,该结构设置使得吹扫的热气能够依次经过供气502、空腔206与通风孔205,并进入绝缘子2的内侧,防止热解煤气中焦油在绝缘子2内侧冷凝而造成爬电。套筒501与绝缘子2的侧壁密封处设有密封垫片204。As shown in FIG. 3, a cavity 206 is formed between the sleeve 501 and the side wall of the insulator 2, and the air supply pipe 502 is connected to the air inlet hole 503 of the sleeve 501, so that the air supply pipe 502 and the cavity 206 communicate with the air vent 205. The structure is arranged such that the purged hot gas can sequentially pass through the supply air 502, the cavity 206 and the venting opening 205, and enter the inside of the insulator 2 to prevent the tar in the pyrolysis gas from condensing inside the insulator 2 to cause creepage. A sealing gasket 204 is provided at the side wall seal of the sleeve 501 and the insulator 2.
灰斗3设置在壳体1下部用于收集粉尘,通过打开卸灰阀301将粉尘排出。灰斗3的数量可以根据实际工况进行选择,本实施例中为3个。灰斗3同样可以设置高频振打机构(图中未给出),可以防止灰尘由于结块而造成堵塞。此外,灰斗3内设有第二阻流板303,第二阻流板303用于减少含尘气体经过气流旁路的比例,从而提升整体除尘效率。灰斗3的外围还设有保温机 构(图中未给出)和灰斗保温层302,防止焦油在灰斗3内冷凝。The ash hopper 3 is disposed at the lower portion of the casing 1 for collecting dust, and the dust is discharged by opening the ash discharging valve 301. The number of ash hoppers 3 can be selected according to actual working conditions, and is three in this embodiment. The ash bucket 3 can also be provided with a high-frequency oscillating mechanism (not shown) to prevent clogging of dust due to agglomeration. In addition, a second spoiler 303 is disposed in the hopper 3, and the second spoiler 303 is used to reduce the proportion of the dust-containing gas passing through the airflow, thereby improving the overall dust removal efficiency. The periphery of the hopper 3 is also provided with a heat insulating mechanism (not shown) and a ash insulation layer 302 to prevent tar from condensing in the hopper 3.
静电除尘装置的组成部分中的气体入口104、入口导流板106、电极线101、收尘极板102、壳体1、灰斗3、气体出口105、出口导流板107均使用耐热合金钢或310S不锈钢,能够承受800℃的长期工作稳定。The gas inlet 104, the inlet deflector 106, the electrode wire 101, the dust collecting plate 102, the casing 1, the ash hopper 3, the gas outlet 105, and the outlet deflector 107 in the components of the electrostatic precipitator are all made of a heat resistant alloy. Steel or 310S stainless steel, able to withstand long-term stability at 800 °C.
工作过程如下:The working process is as follows:
高温含油含尘热解煤气在经过气体入口104、入口导流板106的均流后,进入到装置的壳体1内部,电极线102与壳体1之间通过高纯刚玉绝缘子2绝缘,绝缘子2外部套设有热气吹扫机构,通过热气吹扫机构的工作,绝缘子2的通风孔205处吹扫热气的风速控制为0.5-5m/s,并控制绝缘子的表面温度在350-450℃,防止热解煤气中焦油在绝缘子2表面冷凝而造成爬电,同时避免由于温度过高而导致绝缘性能下降造成的漏电等现象的发生。The high-temperature oil-containing dust-containing pyrolysis gas enters the inside of the casing 1 of the device after passing through the gas inlet 104 and the inlet baffle 106, and the electrode wire 102 and the casing 1 are insulated by the high-purity corundum insulator 2, and the insulator 2 The outer sleeve is provided with a hot air purging mechanism, and the wind speed of purging the hot air at the vent 205 of the insulator 2 is controlled to 0.5-5 m/s by the operation of the hot air purging mechanism, and the surface temperature of the insulator is controlled at 350-450 ° C, Prevent the tar in the pyrolysis gas from condensing on the surface of the insulator 2 to cause creepage, and at the same time avoid the occurrence of leakage due to the deterioration of the insulation performance due to excessive temperature.
电极线101连接有可切换极性高压直流电源,用于在电极线101和收尘极板102之间形成高压电场和电晕放电,在静电力的作用下,高温煤气中的粉尘颗粒被带上电荷,并在电场力作用下运动到收尘极板102上。经过一段时间的堆积之后,高频振打机构108进行振打使粉尘从收尘极板102上脱落,落入到灰斗3中,粉尘积累到一定量之后,再打开卸灰阀301,将粉尘放出等待下一步处理和利用;净化处理后的气体经气体出口105和出口导流板107进入下游工艺。The electrode line 101 is connected with a switchable polarity high voltage DC power source for forming a high voltage electric field and a corona discharge between the electrode line 101 and the dust collecting plate 102. Under the action of the electrostatic force, the dust particles in the high temperature gas are taken. The upper charge is applied to the dust collecting plate 102 under the action of the electric field force. After a period of accumulation, the high-frequency rapping mechanism 108 performs rapping to cause the dust to fall off the dust collecting plate 102, and falls into the ash hopper 3. After the dust accumulates to a certain amount, the ash discharging valve 301 is opened to discharge the dust. Waiting for the next processing and utilization; the purified gas enters the downstream process through the gas outlet 105 and the outlet deflector 107.
本发明可以在高温下充分捕集含油含尘热解气中的细微颗粒物,确保后续冷凝制备焦油过程中的焦油纯度,以及煤气的品质。在600℃下可达95%的除尘效率,400℃下可达98%的除尘效率,且装置的运行阻力小于600Pa。The invention can fully capture fine particles in the oily dusty pyrolysis gas at high temperature, ensure the purity of the tar during the subsequent condensation preparation of the tar, and the quality of the gas. It can achieve 95% dust removal efficiency at 600 °C, 98% dust removal efficiency at 400 °C, and the running resistance of the device is less than 600Pa.

Claims (10)

  1. 一种用于高温煤气的静电除尘装置,其特征在于,包括:具有气体进出口的壳体,设置在壳体下部的灰斗,设置在壳体内的电极线和收尘极板,用于绝缘电极线与壳体的绝缘子,用于吹扫绝缘子的热气吹扫机构,以及与电极线连接的高压电源;所述绝缘子的形状为中空圆筒,绝缘子的中空结构朝向壳体内部,绝缘子的底部内侧设有用于穿过电极线的圆柱,绝缘子侧壁设有通风结构。An electrostatic precipitator for a high-temperature gas, comprising: a casing having a gas inlet and outlet, a ash hopper disposed at a lower portion of the casing, and an electrode wire and a dust collecting plate disposed in the casing for insulation An insulator of the electrode wire and the casing, a hot gas purging mechanism for purging the insulator, and a high voltage power source connected to the electrode wire; the insulator is in the shape of a hollow cylinder, and the hollow structure of the insulator faces the inside of the casing, and the bottom of the insulator A cylinder for passing through the electrode wire is provided on the inner side, and a side wall of the insulator is provided with a ventilation structure.
  2. 根据权利要求1所述的用于高温煤气的静电除尘装置,其特征在于,所述通风结构为通风孔,所述绝缘子侧壁上分布4-16个孔,孔径为10-50mm;所述圆柱的长度大于600mm。The electrostatic precipitator for high temperature gas according to claim 1, wherein the ventilation structure is a venting hole, and 4-16 holes are arranged on the side wall of the insulator, and the aperture is 10-50 mm; The length is greater than 600mm.
  3. 根据权利要求1所述的用于高温煤气的静电除尘装置,其特征在于,所述热气吹扫机构包括套筒,连通套筒的供气管以及气体电加热器;所述套筒安装在壳体上,套设在绝缘子外部。The electrostatic precipitator for high temperature gas according to claim 1, wherein the hot gas purging mechanism comprises a sleeve, an air supply pipe connecting the sleeve, and a gas electric heater; the sleeve is mounted on the casing On the outside, set on the outside of the insulator.
  4. 根据权利要求3所述的用于高温煤气的静电除尘装置,其特征在于,所述套筒与绝缘子的侧壁之间形成空腔,使得供气管、空腔与通风结构连通。The electrostatic precipitator for high temperature gas according to claim 3, wherein a cavity is formed between the sleeve and the side wall of the insulator such that the air supply pipe and the cavity communicate with the ventilation structure.
  5. 根据权利要求1所述的用于高温煤气的静电除尘装置,其特征在于,所述壳体中间为中空圆柱体,中空圆柱体两端分别为锥形的气体入口和气体出口。The electrostatic precipitator for high temperature gas according to claim 1, wherein the middle of the casing is a hollow cylinder, and the two ends of the hollow cylinder are respectively a conical gas inlet and a gas outlet.
  6. 根据权利要求1所述的用于高温煤气的静电除尘装置,其特征在于,所述壳体外侧设有加热机构和保温层。The electrostatic precipitator for high temperature gas according to claim 1, wherein a heating mechanism and a heat insulating layer are disposed outside the casing.
  7. 根据权利要求1所述的用于高温煤气的静电除尘装置,其特征在于,所述高压电源为可切换极性高压直流电源。The electrostatic precipitator for high temperature gas according to claim 1, wherein the high voltage power source is a switchable polarity high voltage DC power source.
  8. 根据权利要求1所述的用于高温煤气的静电除尘装置,其特征在于,所述壳体内设有若干收尘极板,所述收尘极板平行设置于壳体内气流方向; 所述电极线设置在相邻收尘极板之间。The electrostatic precipitator for high-temperature gas according to claim 1, wherein a plurality of dust collecting plates are disposed in the casing, and the dust collecting plates are disposed in parallel in a direction of airflow in the casing; Set between adjacent dust collecting plates.
  9. 根据权利要求8所述的用于高温煤气的静电除尘装置,其特征在于,所述壳体与最外侧的收尘极板间设有阻流板。The electrostatic precipitator for high temperature gas according to claim 8, wherein a baffle is disposed between the casing and the outermost dust collecting plate.
  10. 根据权利要求1所述的用于高温煤气的静电除尘装置,其特征在于,所述灰斗内设有阻流板。The electrostatic precipitator for high temperature gas according to claim 1, wherein a baffle is disposed in the ash hopper.
PCT/CN2018/117574 2018-04-19 2018-11-27 Electrostatic dust removal device for high-temperature coal gas WO2019200922A1 (en)

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