WO2019199292A1 - Device housings with glass beads - Google Patents

Device housings with glass beads Download PDF

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Publication number
WO2019199292A1
WO2019199292A1 PCT/US2018/027000 US2018027000W WO2019199292A1 WO 2019199292 A1 WO2019199292 A1 WO 2019199292A1 US 2018027000 W US2018027000 W US 2018027000W WO 2019199292 A1 WO2019199292 A1 WO 2019199292A1
Authority
WO
WIPO (PCT)
Prior art keywords
glass beads
film
base substrate
ion
device housing
Prior art date
Application number
PCT/US2018/027000
Other languages
French (fr)
Inventor
Kuan-Ting Wu
Ya-Ting Yeh
Chao-wen CHENG
Hsin-Yi Lee
Original Assignee
Hewlett-Packard Development Company, L.P.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hewlett-Packard Development Company, L.P. filed Critical Hewlett-Packard Development Company, L.P.
Priority to PCT/US2018/027000 priority Critical patent/WO2019199292A1/en
Priority to US16/965,127 priority patent/US11393554B2/en
Priority to TW108107468A priority patent/TWI725390B/en
Publication of WO2019199292A1 publication Critical patent/WO2019199292A1/en

Links

Classifications

    • GPHYSICS
    • G12INSTRUMENT DETAILS
    • G12BCONSTRUCTIONAL DETAILS OF INSTRUMENTS, OR COMPARABLE DETAILS OF OTHER APPARATUS, NOT OTHERWISE PROVIDED FOR
    • G12B9/00Housing or supporting of instruments or other apparatus
    • G12B9/02Casings; Housings; Cabinets
    • G12B9/04Details, e.g. cover
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C21/00Treatment of glass, not in the form of fibres or filaments, by diffusing ions or metals in the surface
    • C03C21/001Treatment of glass, not in the form of fibres or filaments, by diffusing ions or metals in the surface in liquid phase, e.g. molten salts, solutions
    • C03C21/002Treatment of glass, not in the form of fibres or filaments, by diffusing ions or metals in the surface in liquid phase, e.g. molten salts, solutions to perform ion-exchange between alkali ions
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N55/00Biocides, pest repellants or attractants, or plant growth regulators, containing organic compounds containing elements other than carbon, hydrogen, halogen, oxygen, nitrogen and sulfur
    • A01N55/02Biocides, pest repellants or attractants, or plant growth regulators, containing organic compounds containing elements other than carbon, hydrogen, halogen, oxygen, nitrogen and sulfur containing metal atoms
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
    • A01N59/16Heavy metals; Compounds thereof
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C12/00Powdered glass; Bead compositions
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C27/00Joining pieces of glass to pieces of other inorganic material; Joining glass to glass other than by fusing
    • C03C27/04Joining glass to metal by means of an interlayer
    • C03C27/048Joining glass to metal by means of an interlayer consisting of an adhesive specially adapted for that purpose
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/16Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
    • C23C18/31Coating with metals
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C20/00Chemical coating by decomposition of either solid compounds or suspensions of the coating forming compounds, without leaving reaction products of surface material in the coating
    • C23C20/02Coating with metallic material

Definitions

  • Electronic devices such as notebook computers, tablet computers, MP3 players, personal digital assistances (PDAs), mobile phones, and the like may include housings to house various electronic components.
  • PDAs personal digital assistances
  • housings to house various electronic components.
  • decorative raeta!Sic- appearing coatings may be formed on the housings of electronic devices.
  • FIG. 1 illustrates a schematic representation of an example device housing having ton-exchanged glass beads disposed on an outer surface
  • FSG 2 illustrates a schematic representation of an example device housing, depicting a film with glass beads disposed on a base substrate via a molding process
  • FIGs. 3A and 38 illustrate example processes for forming glass beads on a film
  • FSG. 4A illustrates an example in-mold decoration process fo applying a film with glass beads to a base substrate
  • FIGs. 4B and 40 illustrate example out-mold decoration processes for applying a film with glass beads to a base substrate
  • FIGs. 5A an 58 illustrate schematic representations of cross-sectional side-views of an example electronic device, depicting a glass bead texture on an outer surface of a device housing;
  • RG. 8 illustrates a schematic representation of an example device housing, depicting an intermediate layer disposed between a base substrate an a film with glass beads;
  • FIG. 7 illustrates a schematic representation of an example device housing, depicting a film with glass beads in combination with an anodized layer on an aluminum/aluminum alloy substrate;
  • FIG. 8 illustrates a schematic representation of an example device housing, depicting a film with glass beads in combination with a micro-arc oxidation (MAO) layer on a metal substrate;
  • MAO micro-arc oxidation
  • FIG 9 illustrates a schematic representation of an example device housing, depicting a film with glass beads in combination with a passive layer on a metal substrate;
  • FIG 10 illustrates a schematic representation of an example device housing, depicting a film with glass beads on a carbon fiber/plastic substrate,
  • Decorative metallic-appearing coatings may be formed on articles (e.g , housings of electronic devices).
  • the metallic-appearing coatings may also provide a metallic luster.
  • the metallic-appearing coating surface may foe susceptible to contamination with microbes, and therefore may cause bacteria!, viral, fungal, or other undesirable infections to users.
  • Some example device housings may be coated with paints, which include silver powder in the painting formulation in an effort to reduce microbial activity.
  • a surface of the silver powder may be covered by a resin, which can reduce the ability for the powder to provide the anti-microbial effect,
  • Examples described herein may provide an anti-microbial glass bead surface on a device housing.
  • the anti-microbial glass beads can be sprayed and then stabilized on an adhesive layer of the device housing.
  • Example anti-microbial glass beads may include silver ion-exchanged glass beads.
  • the anti- microbial activity or effect of a stiver ⁇ oh-exchanged glass bead against bacteria and fungi may be about 99.9%
  • examples described herein may provide a glass bead texture surface finish on a metal substrate (e.g., art anodized aluminum/aluminum alloy substrate), which can maintain metallic luster, provide a tactile touch feeling, and provide a high abrasion-resistant surface finish. Examples described herein may be implemented in electronic devices such as tablets, notebooks, personal digital assistants (PDAs), smart phones, healthcare devices, and the like
  • Examples described herein may provide a device housing, which may include a base substrate and ion-exchanged glass beads disposed on the base substrate.
  • the Ion-exchanged glass beads may have an antimicrobial property or effect
  • FIG. 1 illustrates a schematic representation of an example device housing 100 having ion-exchanged glass beads 104 disposed on an outer surface.
  • Example device housing 100 may be a housing of a computing device (e.g., a notebook, a tablet, a smart phone, or the like), a healthcare device, or the like,
  • Example device housing 1Q0 may include a base substrate 102,
  • base substrate 102 may include a etal, a metal alloy, a carbon fiber, a plastic, or any combination thereof.
  • device housing 100 may include ion- exchanged glass beads 104 disposed on an outer surface of base substrate 102.
  • ion-exchanged glass beads 104 may have an anti-microbiai property.
  • Example ion-exchariged glass beads 104 may include silver ion- exchanged glass beads.
  • ton-exchanged glass beads 104 may be disposed on the outer su face of base substrate 102 via an adhesive layer.
  • device housing 100 may include a film having a first surface adhered to the outer surface of base substrate 102 and a second surface opposite to the first surface,
  • ion-exchanged glass beads 104 may be dispose on the secon surface of the film. This is explained in Figure 2.
  • FIG. 2 illustrates a schematic representation of an example device housing 200, depicting a film 204 with glass beads 206 disposed on a base substrate 202 via a molding process.
  • Example device housing 200 may be a housing of a mobile phone, personal digital assistant (PDA), notebook computer, tablet computer, MP3 or MP4 player, global positioning system (GPS) navigator, digital camera, convertible device, a personal gaming device, a medical device, or the like,
  • PDA personal digital assistant
  • GPS global positioning system
  • Device housing 200 may include a film 204 an glass beads 206 adhered on film 204, for instance, via an adhesive layer.
  • film 204 may include a plastic, a carbon fiber, or a combination thereof.
  • glass beads 206 may include ion-exchanged glass beads.
  • Example ion-exchanged glass beads may include silver ion-exchanged glass beads having an anti-microbial activity.
  • glass beads 206 may impart a three-dimensional feeling to device housing 200 and enhance the aesthetic appearance by reflection of tight. An example process for forming glass beads 206 on film 204 is explained in FiGs. 3A and 3B,
  • device housing 200 may Include base substrate 202.
  • Example base substrate 20 may include a metal, a metal alloy, a carbon fiber, a plastic, or any combination thereof.
  • film 204 with glass beads 206 may be applied on an outer surface of base substrate 202 using a molding process.
  • Example molding process may include an in-mold decoration process or an out- mold decoration process. An example in-mold decoration process is explained in F!G. 4A and example out-mold decoration processes are explained in FIGs. 4S and 4C
  • device housing 200 may include an intermediate layer disposed between base substrate 202 and film 204.
  • Example intermediate layer may be a corrosion resistance layer such as a passivation layer, a micro arc oxidation layer, an anodized layer, or any combination thereof.
  • Example intermediate Sayers are explained in FIGs 6-9.
  • FIGs. 3A and 38 illustrate example processes for forming glass beads 318 on a film 308
  • FIG. 3A illustrates an example roller coating apparatus 300A for forming an adhesive interface 318 on film 308 (e.g , film 204 as shown in FIG. 2)
  • roller coating apparatus 300A may include an application roller 302, a support roller 304, and a metering roller 306 During the coating process, support roller 304 may rotate in a counterclockwise direction (e.g., in the orientation as shown In FIG 3A) to dra a continuous film 308 past application rosie 302, which may rotate in the same direction as support roller 3Q4.
  • supported b application roller 302 and metering roller 308 is a quantity of adhesive 310.
  • a thin layer 312 of adhesive having a thickness equal to a size of a gap formed between application roller 302 and metering roller 306, may form on a surface of application roller 302, which carries adhesive 310 to a surface 314 of film 308, thereby resulting in an adhesive interface 316 being deposited on surface 314 of fil 308.
  • FIG 38 illustrates an example schematic 300B, depicting a spraying apparatus 320 for spraying glass beads 318 (e.g., glass beads 208 as shown in FIG, 2 ⁇ on adhesive interface 316. Upon spraying, glass beads 318 can be stabilized on adhesive interface 318 of film 308. Further, film 308 with glass beads 318 may be attached to a base substrate using an in-mold decoration process or an out-mold decoration process as shown in FIGs. 4A-4C.
  • FiG. 4A illustrates an example in-mold decoration process 400A for applying a film with glass beads on a base substrate.
  • the term“in-mold decoration process” may refer to inserting a film with glass beads into a mold and then injecting, hardening, and adhering a liquid substrate onto the film to form a decorated product during a molding cycle.
  • film 308 with glass beads 318 on a first surface may be provided.
  • the mold may be composed of a cavity 412 and a core 414.
  • Example cavity 412 may be a concave cavity plate.
  • Example core 414 may be a convex core plate.
  • decorated ft! m 410 may be inserted into cavity 412.
  • a liquid base substrate 416 may be injecte through core 414 into the space between cavity 412 and core 414.
  • liquid base substrate 418 may be hardened and adhered to a second surface (i.e , opposite to the first surface) of film 308.
  • Example liquid base substrate may include a liquid plastic or a liquid metal.
  • the device housing with decorated film 410 on the outer surface of base substrate 416 may be formed during the molding cycle of base substrate 416.
  • FiGs, 4S and 4C illustrate example out-mold decoration processes for applying a film with glass beads on a base substrate
  • FIG. 4B illustrates an example out-mold decoration process 400B for disposing film 308 with adhesive interface 3188 on a base substrate.
  • the term“out-mold decoration process” may refer to molding the film (e.g., with glass beads) on the outer surface of the base substrate using a high-pressure vacuum transfer.
  • Example base substrate may include a plastic, a metal, or a carbon fiber substrate.
  • film 308 with glass beads 318 disposed on a first surface via an adhesive Interface 816A and an adhesive Interface 316B on a second surface (hereinafter referred to as“decorated film 482”) may be provided.
  • a base substrate 468 may be inserted into mold 484.
  • the base substrate 468 may be formed using a previous molding process or other manufacturing process.
  • decorated film 482 may be inserted into mold 464 such that decorated film 482 may be placed on base substrate 466 via adhesive interface 3168.
  • decorated film 462 arid base substrate 466 may be compressed in mold 464 using a high-pressure vacuum transfer. As shown in 460, the device housing with decorated film 462 on the outer surface of base substrate 466 may be formed.
  • FIG. 40 il!ustrates another example out-mold decoration process 400C for disposing a film 306 on a base substrate.
  • film 308 with glass beads 318 disposed on a first surface via an adhesive interface 316 (hereinafter referred to as “decorated film 482”) may be provided.
  • a base substrate 486 may be Inserted into mold 484.
  • an adhesive interface 488 may be sprayed on base substrate 486.
  • decorated fiim 482 may be inserted into mold 484 such that decorated film 482 may be placed on base substrate 486 via adhesive interface 488.
  • decorated film 482 and base substrate 486 may be compressed i mold 484 using a high-pressure vacuum transfer to directly bond decorated film 482 an base substrate 486.
  • the device housing with decorated film 482 on the outer surface of base substrate 488 may be formed
  • FIG. 5A illustrates a schematic representation of a cross-sectional side- view of an example electronic device 500, depicting a glass bea texture 508 on an outer surface of a device housing 504.
  • Example electronic device 500 may be a mobile phone, personal digital assistant (PDA), notebook computer, tablet computer, MP3 or MP4 player, global positioning system (GPS) navigator, digital camera, convertible device, personal gaming device, medical device, or the like.
  • Example convertible device may refer to a device that can be“converted” from; a laptop mode to a tablet mode.
  • electronic device 500 ma include a first housing and a second housing rotatably, detachably, or twistably connected to the first housing. Examples described herein can be implemented in the first housing, second housing, or a combination thereof.
  • Example electronic device 500 may include an electronic component 502 and housing 504 to house electronic component 502.
  • electronic component 502 may be a display (e.g., a touchscreen display).
  • Example display may include liquid crystal display (LCD), light emitting diode (LED), electroluminescent (EL) display, or the like.
  • electronic component 502 may include an antenna, a processor, a memory, a battery, a graphics processor, a camera, an input/output device (e.g., a keyboard, a touch pad, and the like), an audio/video device, and the like, depending on the functions of electronic device 500.
  • LCD liquid crystal display
  • LED light emitting diode
  • EL electroluminescent
  • electronic component 502 may include an antenna, a processor, a memory, a battery, a graphics processor, a camera, an input/output device (e.g., a keyboard, a touch pad, and the like), an audio/video device, and the like, depending on the functions of electronic device 500.
  • Housing 504 may include a base substrate 508.
  • Example base substrate 508 may include a metal, a metal alloy, a carbon fiber, a plastic, or any combination thereof.
  • housing 504 may include glass bead texture 508 formed on an outer surface of base substrate 506, glass bead texture 508 including ion-exchanged glass beads.
  • glass bead texture 508 having the ion-exchanged glass beads may be formed on the outer surface of base substrate 506 via an adhesive layer fn another example, glass bead texture 508 may be formed on the outer surface of base substrate 506 via a film as shown in F!G. 5B.
  • FIG. 5B illustrates a schematic representation of a cross-sectional side- view of example electronic device 500, depicting additional features.
  • Housin 504 may include a film 510.
  • Film 510 may include a first surface 514 and a second surface 516 opposite to first surface 514.
  • Housing 504 may include an adhesive layer 512 disposed on second surface 516 of film 510.
  • Housing 504 may include glass bead texture 508 (e.g., pattern design or a uniform; design) formed on second surface 516 of the film 510 via adhesive layer 512.
  • film 510 with glass bea texture 508 may be disposed on base substrate 506 via an in-mold decoration process or an out-mold decoration process, which may apply film; 510, and thus the glass bead texture 508, to base substrate 506.
  • Example ion-exchanged glass beads may include silver ion-exchanged glass beads having an anti-microbiaS activity or quality. Further, glass bead texture 508 on the surface of housing 504 can improve the three-dimensional feeling and the aesthetic appearance of electronic device 500. [0040] RG.
  • Example intermediate layer 810 illustrates a schematic representation of an example device housing 600, depicting an intermediate layer 610 disposed between a base substrate 602 and a decorated film 604
  • decorated film 604 may include a film 606 and glass beads 608 adhered on film 608
  • Device housing 600 may include base substrate 602 and intermediate layer 610 disposed on base substrate 602
  • device housing 600 may include decorated film 604 disposed on intermediate layer 610 using a molding process (e.g,, an out-mold decoration process).
  • Example intermediate layer 810 may be a corrosion resistance layer.
  • Example intermediate layer 810 may be a passivation layer, a micro arc oxidation layer, an anodized layer, or any combination thereof
  • intermediate layer 610 may have a smooth surface for enhancing bonding between base substrate 802 and decorated film 804
  • intermediate layer 610 can be omitted, and decorated film 604 can be directly formed on base substrate 602
  • Example intermediate layers may be explained in FIGs. 74).
  • FIG. 7 illustrates a schematic representation of an example device housing 700, depicting a decorated film 704 in combination with an anodized layer 706 on an aluminum/aiuminum alloy substrate 702.
  • Device housing 700 may include aluminum/aluminum alloy substrate 702 and an anodized layer 706 formed on opposite surfaces of aluminum/aiuminum alloy substrate 702, Further, device housing 700 may include decorated film 704 disposed on anodized layer 706 via adhesive layer 708 using a molding process (i,edeem an out-mold decoration process).
  • decorated film 704 may include a film 710 disposed on anodized layer 706 and glass beads 714 adhered on film 710 via adhesive layer 712
  • decorated film 704 with glass beads 714 e.g., glass bead texture
  • anodizing aluminum/aiuminum alloy substrate 702 can maintain metallic luster, provide glass bead texture tactile touch feeling, an provide a high abrasion- resistant surface finish.
  • FIG. 8 illustrates a schematic representation of an example device housing 800, depicting a decorated film 804 in combination with a micro-arc oxidation (MAO) layer 806 on a metal substrate 802
  • Example metal substrate 802 may be a forged/die casted/CNC machined metal alloy.
  • Example metal may include an aluminum, magnesium, titanium, lithium, niobium, or associated alloy, in one example, metal substrate 802 may be formed into a desired shape by forging, die casting, or CMC machining.
  • MAO layer 806 may be formed on opposite surfaces of metal substrate 802.
  • MAO layer 80S may be formed on metal substrate 802 using an MAO process, which may be an electrochemical surface treatment process for generating oxide coatings on metals.
  • Device housing 800 may include decorated film 804 disposed on MAO layer 808 via adhesive layer 808 using a molding process (i.e., an out-mold decoration process).
  • decorated film 804 may include a film 810 and glass beads 814 adhered on film 810 via adhesive layer 812.
  • Micro-arc oxidized metal substrate 802 may include properties such as wearing resistance, corrosion resistance, high hardness, and electrical insulation.
  • FIG. 9 Illustrates a schematic representation of an example device housing 900, depicting a decorated film 904 in combination with a passive layer 908 on a metal substrate 902.
  • Example metal su strate 902 may be a forged/die casted/CNC machined magnesium alloy.
  • FIG. 9 depicts passive layer 908 formed on opposite surfaces of metal substrate 902 and decorated film 904 formed on passive layer 908 via adhesive layer 90S using a molding process (e.g,, an out- mold decoration process).
  • decorated fil 904 may include a film 910 disposed on passive layer 908 and glass beads 914 adhered on film 910 via adhesive layer 912.
  • Passive layer 906 may nvolve creation of an outer layer of shield material around metal substrate 902 to make metal substrate 902 "passive", I.e., less affected or corroded b the environment
  • FIG. 10 illustrates a schematic representation of an example device housing 1000, depicting a decorated film 1004 disposed on a carbon fiber/plastic substrate 1002 via adhesive layer 1008.
  • decorated film 1004 may include a film 1008 and glass beads 1012 adhered on film 1008 via adhesive layer 1010,
  • examples described in FIGs. 1-10 may provide an anti-microbial surface of a device housing, which can have a Song-lasting reliable antiseptic effect. Further, examples described in FIGs. 1-10 may provide a device housing having an anti-microbial activity, which can be maintained for a significant time.

Abstract

In one example, a device housing is described, which may include a base substrate and ion-exchanged glass beads disposed on an outer surface of the base substrate.

Description

DEVICE HOUSINGS WITH GLASS BEADS
BACKGROUND
[0001] Electronic devices such as notebook computers, tablet computers, MP3 players, personal digital assistances (PDAs), mobile phones, and the like may include housings to house various electronic components. To make the electronic devices fashionably and aesthetically appealing to users, decorative raeta!Sic- appearing coatings may be formed on the housings of electronic devices.
BRIEF DESCRlPTiON QF THE DRAWINGS
[0002] Examples are described in the following detailed description and in reference to the drawings, in which:
[0003] FIG. 1 illustrates a schematic representation of an example device housing having ton-exchanged glass beads disposed on an outer surface;
[0004] FSG 2 illustrates a schematic representation of an example device housing, depicting a film with glass beads disposed on a base substrate via a molding process;
[0005] FIGs. 3A and 38 illustrate example processes for forming glass beads on a film;
[0006] FSG. 4A illustrates an example in-mold decoration process fo applying a film with glass beads to a base substrate;
[0007] FIGs. 4B and 40 illustrate example out-mold decoration processes for applying a film with glass beads to a base substrate;
[0008] FIGs. 5A an 58 illustrate schematic representations of cross-sectional side-views of an example electronic device, depicting a glass bead texture on an outer surface of a device housing; [0009] RG. 8 illustrates a schematic representation of an example device housing, depicting an intermediate layer disposed between a base substrate an a film with glass beads; m FIG. 7 illustrates a schematic representation of an example device housing, depicting a film with glass beads in combination with an anodized layer on an aluminum/aluminum alloy substrate;
[0011] FIG. 8 illustrates a schematic representation of an example device housing, depicting a film with glass beads in combination with a micro-arc oxidation (MAO) layer on a metal substrate;
[0012] FIG 9 illustrates a schematic representation of an example device housing, depicting a film with glass beads in combination with a passive layer on a metal substrate; and
[0013] FIG 10 illustrates a schematic representation of an example device housing, depicting a film with glass beads on a carbon fiber/plastic substrate,
DETAILED DESCRIPTION
E0014] Decorative metallic-appearing coatings may be formed on articles (e.g , housings of electronic devices). The metallic-appearing coatings may also provide a metallic luster. However, the metallic-appearing coating surface may foe susceptible to contamination with microbes, and therefore may cause bacteria!, viral, fungal, or other undesirable infections to users. Some example device housings may be coated with paints, which include silver powder in the painting formulation in an effort to reduce microbial activity. However, a surface of the silver powder may be covered by a resin, which can reduce the ability for the powder to provide the anti-microbial effect,
[0015] Examples described herein may provide an anti-microbial glass bead surface on a device housing. The anti-microbial glass beads can be sprayed and then stabilized on an adhesive layer of the device housing. Example anti-microbial glass beads may include silver ion-exchanged glass beads. For example, the anti- microbial activity or effect of a stiver ίoh-exchanged glass bead against bacteria and fungi may be about 99.9%, In addition, examples described herein may provide a glass bead texture surface finish on a metal substrate (e.g., art anodized aluminum/aluminum alloy substrate), which can maintain metallic luster, provide a tactile touch feeling, and provide a high abrasion-resistant surface finish. Examples described herein may be implemented in electronic devices such as tablets, notebooks, personal digital assistants (PDAs), smart phones, healthcare devices, and the like
[0016] In the following description, for purposes of explanation, numerous specific details are set forth in order to provide a thorough understanding of the present techniques. St will be apparent, however, to one skilled in the art that the present apparatus, devices and systems may be practiced without these specific details. Reference in the specification to“an example” or similar language means that a particular feature, structure, or characteristic described may be included in at least that one example, but not necessarily in other examples.
[0017] Examples described herein may provide a device housing, which may include a base substrate and ion-exchanged glass beads disposed on the base substrate. In one example, the Ion-exchanged glass beads may have an antimicrobial property or effect
[0018] Turning now to the figures, FIG. 1 illustrates a schematic representation of an example device housing 100 having ion-exchanged glass beads 104 disposed on an outer surface. Example device housing 100 may be a housing of a computing device (e.g., a notebook, a tablet, a smart phone, or the like), a healthcare device, or the like,
[0019] Example device housing 1Q0 may include a base substrate 102, For example, base substrate 102 may include a etal, a metal alloy, a carbon fiber, a plastic, or any combination thereof. Further, device housing 100 may include ion- exchanged glass beads 104 disposed on an outer surface of base substrate 102. in one example, ion-exchanged glass beads 104 may have an anti-microbiai property. Example ion-exchariged glass beads 104 may include silver ion- exchanged glass beads.
[0020] in one example, ton-exchanged glass beads 104 may be disposed on the outer su face of base substrate 102 via an adhesive layer. In another example, device housing 100 may include a film having a first surface adhered to the outer surface of base substrate 102 and a second surface opposite to the first surface, In this example, ion-exchanged glass beads 104 may be dispose on the secon surface of the film. This is explained in Figure 2.
[0021] FIG. 2 illustrates a schematic representation of an example device housing 200, depicting a film 204 with glass beads 206 disposed on a base substrate 202 via a molding process. Example device housing 200 may be a housing of a mobile phone, personal digital assistant (PDA), notebook computer, tablet computer, MP3 or MP4 player, global positioning system (GPS) navigator, digital camera, convertible device, a personal gaming device, a medical device, or the like,
[0022] Device housing 200 may include a film 204 an glass beads 206 adhered on film 204, for instance, via an adhesive layer. For example, film 204 may include a plastic, a carbon fiber, or a combination thereof. Further, glass beads 206 may include ion-exchanged glass beads. Example ion-exchanged glass beads may include silver ion-exchanged glass beads having an anti-microbial activity. For example, glass beads 206 may impart a three-dimensional feeling to device housing 200 and enhance the aesthetic appearance by reflection of tight. An example process for forming glass beads 206 on film 204 is explained in FiGs. 3A and 3B,
[0023] Further, device housing 200 may Include base substrate 202. Example base substrate 20 may include a metal, a metal alloy, a carbon fiber, a plastic, or any combination thereof. In one example, film 204 with glass beads 206 may be applied on an outer surface of base substrate 202 using a molding process. Example molding process may include an in-mold decoration process or an out- mold decoration process. An example in-mold decoration process is explained in F!G. 4A and example out-mold decoration processes are explained in FIGs. 4S and 4C
[0024] In other examples, device housing 200 may include an intermediate layer disposed between base substrate 202 and film 204. Example intermediate layer may be a corrosion resistance layer such as a passivation layer, a micro arc oxidation layer, an anodized layer, or any combination thereof. Example intermediate Sayers are explained in FIGs 6-9.
[0025] FIGs. 3A and 38 illustrate example processes for forming glass beads 318 on a film 308 FIG. 3A illustrates an example roller coating apparatus 300A for forming an adhesive interface 318 on film 308 (e.g , film 204 as shown in FIG. 2) As Indicate in FIG 3A, roller coating apparatus 300A may include an application roller 302, a support roller 304, and a metering roller 306 During the coating process, support roller 304 may rotate in a counterclockwise direction (e.g., in the orientation as shown In FIG 3A) to dra a continuous film 308 past application rosie 302, which may rotate in the same direction as support roller 3Q4.
[0026] Further, supported b application roller 302 and metering roller 308 is a quantity of adhesive 310. A thin layer 312 of adhesive, having a thickness equal to a size of a gap formed between application roller 302 and metering roller 306, may form on a surface of application roller 302, which carries adhesive 310 to a surface 314 of film 308, thereby resulting in an adhesive interface 316 being deposited on surface 314 of fil 308.
[0027] FIG 38 illustrates an example schematic 300B, depicting a spraying apparatus 320 for spraying glass beads 318 (e.g., glass beads 208 as shown in FIG, 2} on adhesive interface 316. Upon spraying, glass beads 318 can be stabilized on adhesive interface 318 of film 308. Further, film 308 with glass beads 318 may be attached to a base substrate using an in-mold decoration process or an out-mold decoration process as shown in FIGs. 4A-4C. [0028] FiG. 4A illustrates an example in-mold decoration process 400A for applying a film with glass beads on a base substrate. The term“in-mold decoration process” may refer to inserting a film with glass beads into a mold and then injecting, hardening, and adhering a liquid substrate onto the film to form a decorated product during a molding cycle.
[8029] At 402, film 308 with glass beads 318 on a first surface (hereinafter referred to as“decorated film 410”) may be provided. As shown in FIG. 4A, the mold may be composed of a cavity 412 and a core 414. Example cavity 412 may be a concave cavity plate. Example core 414 may be a convex core plate. At 404, decorated ft! m 410 may be inserted into cavity 412. At 406, after closing the mold, a liquid base substrate 416 may be injecte through core 414 into the space between cavity 412 and core 414. Further, liquid base substrate 418 may be hardened and adhered to a second surface (i.e , opposite to the first surface) of film 308. Example liquid base substrate may include a liquid plastic or a liquid metal. Thus, as shown tn 408, the device housing with decorated film 410 on the outer surface of base substrate 416 may be formed during the molding cycle of base substrate 416.
[0030] FiGs, 4S and 4C illustrate example out-mold decoration processes for applying a film with glass beads on a base substrate, FIG. 4B illustrates an example out-mold decoration process 400B for disposing film 308 with adhesive interface 3188 on a base substrate. The term“out-mold decoration process” may refer to molding the film (e.g., with glass beads) on the outer surface of the base substrate using a high-pressure vacuum transfer. Example base substrate may include a plastic, a metal, or a carbon fiber substrate.
[0031] At 452, film 308 with glass beads 318 disposed on a first surface via an adhesive Interface 816A and an adhesive Interface 316B on a second surface (hereinafter referred to as“decorated film 482”) may be provided. At 454, a base substrate 468 may be inserted into mold 484. The base substrate 468 may be formed using a previous molding process or other manufacturing process. At 456, decorated film 482 may be inserted into mold 464 such that decorated film 482 may be placed on base substrate 466 via adhesive interface 3168. At 458,
8 decorated film 462 arid base substrate 466 may be compressed in mold 464 using a high-pressure vacuum transfer. As shown in 460, the device housing with decorated film 462 on the outer surface of base substrate 466 may be formed.
[0032] FIG. 40 il!ustrates another example out-mold decoration process 400C for disposing a film 306 on a base substrate. At 470, film 308 with glass beads 318 disposed on a first surface via an adhesive interface 316 (hereinafter referred to as “decorated film 482”) may be provided. At 472, a base substrate 486 may be Inserted into mold 484. At 474, an adhesive interface 488 may be sprayed on base substrate 486. At 476, decorated fiim 482 may be inserted into mold 484 such that decorated film 482 may be placed on base substrate 486 via adhesive interface 488. At 478, decorated film 482 and base substrate 486 may be compressed i mold 484 using a high-pressure vacuum transfer to directly bond decorated film 482 an base substrate 486. As shown in 480, the device housing with decorated film 482 on the outer surface of base substrate 488 may be formed
[0033] FIG. 5A illustrates a schematic representation of a cross-sectional side- view of an example electronic device 500, depicting a glass bea texture 508 on an outer surface of a device housing 504. Example electronic device 500 may be a mobile phone, personal digital assistant (PDA), notebook computer, tablet computer, MP3 or MP4 player, global positioning system (GPS) navigator, digital camera, convertible device, personal gaming device, medical device, or the like. Example convertible device may refer to a device that can be“converted” from; a laptop mode to a tablet mode. In some examples, electronic device 500 ma include a first housing and a second housing rotatably, detachably, or twistably connected to the first housing. Examples described herein can be implemented in the first housing, second housing, or a combination thereof.
[0034] Example electronic device 500 may include an electronic component 502 and housing 504 to house electronic component 502. In some examples, electronic component 502 may be a display (e.g., a touchscreen display). Example display may include liquid crystal display (LCD), light emitting diode (LED), electroluminescent (EL) display, or the like. In other examples, electronic component 502 may include an antenna, a processor, a memory, a battery, a graphics processor, a camera, an input/output device (e.g., a keyboard, a touch pad, and the like), an audio/video device, and the like, depending on the functions of electronic device 500.
[0035] Housing 504 may include a base substrate 508. Example base substrate 508 may include a metal, a metal alloy, a carbon fiber, a plastic, or any combination thereof. Further, housing 504 may include glass bead texture 508 formed on an outer surface of base substrate 506, glass bead texture 508 including ion-exchanged glass beads.
[0036] In one example, glass bead texture 508 having the ion-exchanged glass beads may be formed on the outer surface of base substrate 506 via an adhesive layer fn another example, glass bead texture 508 may be formed on the outer surface of base substrate 506 via a film as shown in F!G. 5B.
[0037] FIG. 5B illustrates a schematic representation of a cross-sectional side- view of example electronic device 500, depicting additional features. Housin 504 may include a film 510. Film 510 may include a first surface 514 and a second surface 516 opposite to first surface 514.
[0038] Housing 504 may include an adhesive layer 512 disposed on second surface 516 of film 510. Housing 504 may include glass bead texture 508 (e.g., pattern design or a uniform; design) formed on second surface 516 of the film 510 via adhesive layer 512. Further, film 510 with glass bea texture 508 may be disposed on base substrate 506 via an in-mold decoration process or an out-mold decoration process, which may apply film; 510, and thus the glass bead texture 508, to base substrate 506.
[0039] Example ion-exchanged glass beads may include silver ion-exchanged glass beads having an anti-microbiaS activity or quality. Further, glass bead texture 508 on the surface of housing 504 can improve the three-dimensional feeling and the aesthetic appearance of electronic device 500. [0040] RG. 8 illustrates a schematic representation of an example device housing 600, depicting an intermediate layer 610 disposed between a base substrate 602 and a decorated film 604 In one example, decorated film 604 may include a film 606 and glass beads 608 adhered on film 608, Device housing 600 may include base substrate 602 and intermediate layer 610 disposed on base substrate 602 Further, device housing 600 may include decorated film 604 disposed on intermediate layer 610 using a molding process (e.g,, an out-mold decoration process). Example intermediate layer 810 may be a corrosion resistance layer. Example intermediate layer 810 may be a passivation layer, a micro arc oxidation layer, an anodized layer, or any combination thereof
[0041] For example, intermediate layer 610 may have a smooth surface for enhancing bonding between base substrate 802 and decorated film 804 In some examples, intermediate layer 610 can be omitted, and decorated film 604 can be directly formed on base substrate 602 Example intermediate layers may be explained in FIGs. 74).
[0042] FIG. 7 illustrates a schematic representation of an example device housing 700, depicting a decorated film 704 in combination with an anodized layer 706 on an aluminum/aiuminum alloy substrate 702. Device housing 700 may include aluminum/aluminum alloy substrate 702 and an anodized layer 706 formed on opposite surfaces of aluminum/aiuminum alloy substrate 702, Further, device housing 700 may include decorated film 704 disposed on anodized layer 706 via adhesive layer 708 using a molding process (i,e„ an out-mold decoration process). In one example, decorated film 704 may include a film 710 disposed on anodized layer 706 and glass beads 714 adhered on film 710 via adhesive layer 712 In one example, decorated film 704 with glass beads 714 (e.g., glass bead texture) on anodizing aluminum/aiuminum alloy substrate 702 can maintain metallic luster, provide glass bead texture tactile touch feeling, an provide a high abrasion- resistant surface finish.
[0043] FIG. 8 illustrates a schematic representation of an example device housing 800, depicting a decorated film 804 in combination with a micro-arc oxidation (MAO) layer 806 on a metal substrate 802 Example metal substrate 802 may be a forged/die casted/CNC machined metal alloy. Example metal may include an aluminum, magnesium, titanium, lithium, niobium, or associated alloy, in one example, metal substrate 802 may be formed into a desired shape by forging, die casting, or CMC machining.
[0044] As shown in FIG. 8 MAO layer 806 may be formed on opposite surfaces of metal substrate 802. For example, MAO layer 80S may be formed on metal substrate 802 using an MAO process, which may be an electrochemical surface treatment process for generating oxide coatings on metals.
[0045] Device housing 800 may include decorated film 804 disposed on MAO layer 808 via adhesive layer 808 using a molding process (i.e., an out-mold decoration process). In one example, decorated film 804 may include a film 810 and glass beads 814 adhered on film 810 via adhesive layer 812. Micro-arc oxidized metal substrate 802 may include properties such as wearing resistance, corrosion resistance, high hardness, and electrical insulation.
[0846] FIG. 9 Illustrates a schematic representation of an example device housing 900, depicting a decorated film 904 in combination with a passive layer 908 on a metal substrate 902. Example metal su strate 902 may be a forged/die casted/CNC machined magnesium alloy. FIG. 9 depicts passive layer 908 formed on opposite surfaces of metal substrate 902 and decorated film 904 formed on passive layer 908 via adhesive layer 90S using a molding process (e.g,, an out- mold decoration process). In one example, decorated fil 904 may include a film 910 disposed on passive layer 908 and glass beads 914 adhered on film 910 via adhesive layer 912. Passive layer 906 may nvolve creation of an outer layer of shield material around metal substrate 902 to make metal substrate 902 "passive", I.e., less affected or corroded b the environment
[8047] Alternatively, the decorate film can be directly disposed on the base substrate without any intermediate coatings as shown in FIG. 10. FIG. 10 illustrates a schematic representation of an example device housing 1000, depicting a decorated film 1004 disposed on a carbon fiber/plastic substrate 1002 via adhesive layer 1008. In one example, decorated film 1004 may include a film 1008 and glass beads 1012 adhered on film 1008 via adhesive layer 1010,
[0048] Thus, examples described in FIGs. 1-10 may provide an anti-microbial surface of a device housing, which can have a Song-lasting reliable antiseptic effect. Further, examples described in FIGs. 1-10 may provide a device housing having an anti-microbial activity, which can be maintained for a significant time.
[004S] it may be noted that the above-described examples of the present solution are for the purpose of illustration only. Although the solution has been described in conjunction with a specific implementation thereof, numerous modifications may be possible without materially departing from the teachings and advantages of the subject matter described herein. Other substitutions, modifications and changes may be made without departing from the spirit of the present solution. Ail of the features disclosed in this specification (including any accompanying claims, abstract and drawings), and/or all of the steps of any method or process so disclosed, may be combined in any combination, except combinations where at least some of such features and/or steps are mutually exclusive.
[0050] The terms“include,”“have,” and variations thereof, as used herein, have the same meaning as the term "comprise” or appropriate variation thereof. Furthermore, the term“based on”, as used herein, means“based at least in part on” Thus, a feature that is described as based on some stimulus can be based on the stimulus or a combination of stimuli including the stimulus.
[0051] The present description has been shown and described with reference to the foregoing examples. It is understood, however, that other forms, details, and examples can be made without departing from the spirit and scope of the present subject matter that Is defined in the following claims.

Claims

WHAT IS CLAIMED IS:
1. A device housing comprising:
a base substrate; an
ion-exchanged glass beads disposed on an outer surface of the base substrate.
2. The device housing of claim 1 , wherein the base substrate includes ametal, a metal alloy, a carbon fiber, a plastic, or any combination thereof.
3. The device housing of claim 1 , further comprising;
a film comprising:
a first surface adhered to the outer surface of the base substrate; and
a second surface opposite to the first surface, wherein the ion- exchanged glass beads are disposed on the second surface.
4. The device housing of claim 1 s wherein the ion-exchanged glass beads are disposed on the outer surface of the base substrate via an adhesive layer.
5. The device housing of claim 1 , wherein the ion-exchanged glass beads have an anti-microbial property, and wherein the ion-exchanged glass beads comprise silver ion-exchanged glass beads,
6. A device housing comprising:
a film;
glass beads adhered on the film; and
a base substrate, wherein the film with the glass beads is applied on an outer surface of the base substrate using a molding process.
7. The device housing of claim 8, wherein the molding process comprises an in-mold decoration process or an out-mold decoration process. 8 The device housing of claim 6, further comprising:
an intermediate layer disposed between the base substrate and the film, wherein the intermediate layer comprises a passivation layer, a micro arc oxidation layer, an anodized !ayer, or any combination thereof.
9 The device housing of claim 6, wherein the film; is a plastic, a carbon fiber, or a combination thereof,
10 The device housing of claim 6, wherein the glass beads comprise ion- exchanged glass beads, wherein the ion-exchange glass beads comprise stiver ion-exchanged glass beads having an anti-microbial activity.
11 An electronic device comprising:
an electronic component; and
a housing to house the electronic component, wherein the housing comprises:
a base substrate; and
a glass bead texture formed on an outer surface of the base substrate using ion-exchanged glass beads.
12 The electronic device of claim 11 further comprising:
a film, wherein the glass bead texture is formed on the film, and wherein the film with the glass bead texture is disposed on the base substrate via an inmold decoration process or an out-mol decoration process.
13 The electronic device of claim 12, wherein the bousing further comprises an intermediate layer disposed between the base substrate and the film, and wherein the intermediate layer comprises a corrosion resistance layer.
14, The electronic device of claim 12, wherein the glass bead texture having the Ion-exchanged glass beads is formed on the outer surface of the base substrate via an adhesive layer. 15, The electronic device of claim 14, wherein the ton-exchanged glass beads comprise stiver ion-exchanged glass beads having an anti-microbial activity.
PCT/US2018/027000 2018-04-11 2018-04-11 Device housings with glass beads WO2019199292A1 (en)

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US16/965,127 US11393554B2 (en) 2018-04-11 2018-04-11 Device housings with glass beads
TW108107468A TWI725390B (en) 2018-04-11 2019-03-06 Device housings with glass beads

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