WO2019193676A1 - Beer-taste beverage with suppressed flavor degradation, and production method thereof - Google Patents

Beer-taste beverage with suppressed flavor degradation, and production method thereof Download PDF

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Publication number
WO2019193676A1
WO2019193676A1 PCT/JP2018/014396 JP2018014396W WO2019193676A1 WO 2019193676 A1 WO2019193676 A1 WO 2019193676A1 JP 2018014396 W JP2018014396 W JP 2018014396W WO 2019193676 A1 WO2019193676 A1 WO 2019193676A1
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WO
WIPO (PCT)
Prior art keywords
beer
taste beverage
acid
taste
wheat
Prior art date
Application number
PCT/JP2018/014396
Other languages
French (fr)
Japanese (ja)
Inventor
悠一 加藤
敏 倉兼
朋子 吉田
和輝 齋藤
伊玖磨 水口
Original Assignee
サントリーホールディングス株式会社
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by サントリーホールディングス株式会社 filed Critical サントリーホールディングス株式会社
Priority to PCT/JP2018/014396 priority Critical patent/WO2019193676A1/en
Priority to JP2020512152A priority patent/JP7181284B2/en
Publication of WO2019193676A1 publication Critical patent/WO2019193676A1/en

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Classifications

    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L2/00Non-alcoholic beverages; Dry compositions or concentrates therefor; Their preparation
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L2/00Non-alcoholic beverages; Dry compositions or concentrates therefor; Their preparation
    • A23L2/40Effervescence-generating compositions
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L2/00Non-alcoholic beverages; Dry compositions or concentrates therefor; Their preparation
    • A23L2/42Preservation of non-alcoholic beverages
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L2/00Non-alcoholic beverages; Dry compositions or concentrates therefor; Their preparation
    • A23L2/52Adding ingredients
    • A23L2/56Flavouring or bittering agents
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L2/00Non-alcoholic beverages; Dry compositions or concentrates therefor; Their preparation
    • A23L2/52Adding ingredients
    • A23L2/60Sweeteners
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L2/00Non-alcoholic beverages; Dry compositions or concentrates therefor; Their preparation
    • A23L2/52Adding ingredients
    • A23L2/68Acidifying substances
    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12CBEER; PREPARATION OF BEER BY FERMENTATION; PREPARATION OF MALT FOR MAKING BEER; PREPARATION OF HOPS FOR MAKING BEER
    • C12C5/00Other raw materials for the preparation of beer
    • C12C5/02Additives for beer
    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12GWINE; PREPARATION THEREOF; ALCOHOLIC BEVERAGES; PREPARATION OF ALCOHOLIC BEVERAGES NOT PROVIDED FOR IN SUBCLASSES C12C OR C12H
    • C12G3/00Preparation of other alcoholic beverages
    • C12G3/04Preparation of other alcoholic beverages by mixing, e.g. for preparation of liqueurs

Definitions

  • the present invention relates to a beer-taste beverage in which flavor deterioration is suppressed and a method for producing the same.
  • beer-taste beverages are generally supplied on the premise that they are sealed in cans and bottles and can be consumed at one time.
  • supply using re-capable containers is also required.
  • flavor deterioration may occur due to oxidation or gas loss between the opening and the end of drinking.
  • refreshing aftertaste, sharpness, and irritation of beer-taste beverages may be impaired by oxidation and gas loss.
  • a beer-taste beverage containing a preservative has been studied (for example, Patent Document 1).
  • Measures for preventing flavor deterioration of beer-taste beverages include addition of antioxidants in addition to preservatives, but antioxidants may not be able to sufficiently suppress flavor deterioration due to oxidation.
  • antioxidants may not be able to sufficiently suppress flavor deterioration due to oxidation.
  • PET bottles are more likely to deteriorate in flavor due to more oxygen intrusion and gas loss into the container over time than when bottles are opened.
  • a component derived from wheat is oxidized and an unfavorable paper-like scent (hereinafter, papery) is generated.
  • an unfavorable grain-like aroma (hereinafter referred to as grainy) may be noticeable due to gas loss.
  • grainy an unfavorable grain-like aroma
  • the amount of wheat contained in the raw material is reduced, papery and grainy are suppressed, but the amount of protein derived from the wheat is reduced, and there is a possibility that the feeling of drinking is reduced. Therefore, it has excellent flavor as a beer-taste beverage while using wheat as a raw material so that it can be used in a re-capable container such as a PET bottle, and flavor deterioration due to oxidation and / or gas loss.
  • beer-taste beverages that are suppressed.
  • the present invention has been made to solve such problems.
  • the present invention includes an acidulant and a pH within a predetermined range, and further includes a bitterness-imparting agent and a sweetener.
  • a concentration within a predetermined concentration range it is possible to obtain a beer-taste beverage that has excellent flavor as a beer-taste beverage while using wheat as a raw material, and in which flavor deterioration due to oxidation and / or gas loss is suppressed. I learned that I can do it.
  • the present invention is based on these findings.
  • the present invention includes the following aspects of the invention.
  • Including acidulants, pH is 2-4, The content of the bitterness-imparting agent is 0.10 mg / L to 50 mg / L, A beer-taste beverage comprising wheat as a raw material and containing a sweetener in a sucrose equivalent concentration of 0.01% by weight or more and less than 0.50% by weight.
  • the acidulant is at least one selected from the group consisting of phosphoric acid, citric acid, gluconic acid, tartaric acid, lactic acid, malic acid, phytic acid, acetic acid, and succinic acid.
  • bitterness-imparting agent is at least one selected from the group consisting of hop-derived components, wormwood, naringin, and quassin.
  • hop-derived component is one or more components selected from the group consisting of iso- ⁇ acid and ⁇ -acid.
  • sweetener is a high-intensity sweetener.
  • a method for producing a beer-taste beverage wherein the final product has a pH of 2 to 4, Acidity and bitterness imparting so that the content of the bitterness-imparting agent is 0.10 mg / L to 50 mg / L and the sweetener is contained at a sucrose equivalent concentration of 0.01 wt% or more and less than 0.50 wt% Adding an agent and a sweetener, A production method in which wheat is added as a raw material.
  • the sour agent is included, the pH is within a predetermined range, and the bitterness-imparting agent and the sweetener concentration are within a predetermined concentration range, while using wheat as a raw material,
  • the beer taste drink which has the outstanding flavor as a beer taste drink, and the flavor deterioration by oxidation and / or gas loss was suppressed can be provided.
  • the beer-taste beverage of the present invention contains a sour agent, has a pH of 2 to 4, has a bitterness-imparting agent content of 0.10 mg / L to 50 mg / L, contains wheat as a raw material, And it is a beer-taste drink which contains a sweetener with the sucrose conversion density
  • beer-taste beverage refers to an alcohol-containing or non-alcoholic carbonated beverage having a beer-like flavor. That is, the beer-taste beverage of this specification includes any carbonated beverage having a beer flavor regardless of the presence or absence of a fermentation process using yeast, unless otherwise specified.
  • the types of beer-taste beverages of the present invention include, for example, alcohol-containing beer-taste beverages (beer-taste beverages having an alcohol content of 0.05 to 40%), non-alcohol beer-taste beverages (alcohol content is less than 0.05%) Beer-taste beverages) and beer-taste soft drinks.
  • the beer-taste beverage of the present invention contains a sour agent and has a pH of 2-4.
  • the content of the acidulant is not particularly limited as long as the pH is within this range.
  • the pH is preferably 2 to 3.
  • the beer-taste beverage of the present invention has a bitterness-imparting agent content of 0.10 mg / L to 50 mg / L, preferably 1 mg / L to 45 mg / L, more preferably 4 mg / L to 40 mg / L. is there. If it is in the said range, the lift of a bitter taste can be suppressed, ensuring the refreshing aftertaste, sharpness, and irritation
  • the beer-taste beverage of the present invention contains a sweetener at a sucrose equivalent concentration of 0.01 wt% or more and less than 0.50 wt%, preferably 0.01 wt% to 0.48 wt%, more preferably It is contained at a sucrose equivalent concentration of 0.02 wt% to 0.43 wt%, more preferably 0.04 wt% to 0.38 wt%. If it is in the said range, richness can be given to a drink, suppressing sweetness.
  • sucrose conversion concentration is a value obtained by converting sweetness of a sweetener in a beverage by sucrose concentration, and based on a relative ratio of sweetness of each sweetener to sweetness 1 of sucrose, It can be determined by converting to a corresponding amount of sucrose and then totaling the sucrose sweetness conversion amounts of all sweeteners contained in the beverage.
  • the relative ratio of the sweetness of various sweeteners to the sweetness 1 of sucrose can be determined from a known sugar sweetness conversion table (for example, Beverage Japan “Beverage Glossary”, page 11).
  • acesulfame potassium has a sweetness of about 200
  • sucralose has a sweetness of about 600
  • stevia (extract) has a sweetness of about 150 to 200 times
  • aspartame has a sweetness of about 180 times.
  • sucrose equivalent concentration 0.01 wt% or more and less than 0.50 wt%
  • the concentration is 0.50 ppm or more and less than 25 ppm.
  • sucralose is contained at a sucrose equivalent concentration of 0.01% by weight or more and less than 0.50% by weight, the concentration is 0.17 ppm or more and less than 8.3 ppm.
  • the beer-taste beverage of the present invention may contain a plurality of kinds of sweeteners at a total concentration of 0.01% by weight or more and less than 0.50% by weight in terms of sucrose.
  • “including wheat as a raw material” means that wheat is positively added when producing a beer-taste beverage. Whether or not wheat is actively added to the ingredients of beer-taste beverages depends on the Food Labeling Law, Food Sanitation Law, JAS Law, Premium Labeling Law, Health Promotion Law, regulations and voluntary standards established by industry groups, etc. It can be confirmed from the raw material display determined by For example, when wheat is included, the name of the raw material is represented as “wheat” or “malt”. Alternatively, since wheat is actively added, the protein content in the beer-taste beverage is 0.006 mg / 100 mL or more. 1 aspect of this invention WHEREIN: The beer taste drink of this invention is a beer taste drink manufactured by adding wheat as a raw material.
  • the amount of protein derived from wheat contained in beer-taste beverages is the total nitrogen content of the product (hereinafter referred to as “ It can be specified by measuring (TN amount).
  • Total nitrogen content (TN) means the total amount of nitrogen contained in the entire beverage.
  • the TN value of the beer-taste beverage of the present invention is preferably 0.001 mg / 100 mL to 200 mg / 100 mL, more preferably 0.01 mg / 100 mL to 175 mg / 100 mL, and still more preferably 0.1 mg / 100 mL to 150 mg / 100 mL. It is. Concentrations around 0.001 mg / 100 mL are close to the measurement limit, but can be measured in a concentrated (concentrated stock solution) state. For example, it can be quantified by preparing a 100-fold concentrated product.
  • the beer-taste beverage of the present invention may be a beer-taste beverage having an alcohol content of 0.05 to 40 (v / v)%, such as beer or sparkling liquor, and an alcohol content (content) of non-alcohol beer. ) May be a beer-taste beverage of less than 0.05 (v / v)%.
  • the alcohol content is preferably 0.5 to 20 (v / v)%, more preferably 1.0 to 10 (v / v)%.
  • the beer-taste beverage of the present invention does not contain alcohol, the alcohol content is preferably less than 0.05 (v / v)%, and more preferably 0.00 (v / v)%.
  • the alcohol content is expressed as a volume / volume basis percentage (v / v%).
  • alcohol content of a drink can be measured by any well-known method, it can be measured with a vibration-type density meter, for example.
  • the color of the beer-taste beverage of the present invention is not particularly limited, but may be amber like normal beer or colorless and transparent. Or a coloring agent etc. may be added and a desired color may be given.
  • the color of a beer-taste beverage can be determined with the naked eye, but may be defined by the total light transmittance, chromaticity, and the like.
  • the total extract amount of the beer-taste beverage of the present invention is not particularly limited, but in the case of a non-alcohol beer-taste beverage, it is preferably 1.50% by weight or less, more preferably 1.10% by weight or less, and still more preferably 0.80. % By weight or less. In the case of a beer-taste beverage containing alcohol, it is preferably 11% by weight or less, more preferably 8% by weight or less, and still more preferably 6% by weight or less. By setting the total extract amount within the above range, a light drinking mouth can be provided.
  • total extract amount in the present specification is the amount of the non-volatile component contained in the original volume of 100 cubic centimeters when the alcohol content of the beverage is 0.005% or more, that is, the extract content in the Japanese liquor tax law, that is, when the temperature is 15 degrees.
  • the extract value % by weight measured for the degassed sample according to the “Beer Analysis Method 7.2 Extract” established by the International Technical Committee of the Brewery Association (BCOJ) Say.
  • flavor deterioration due to oxidation and / or gas loss is suppressed.
  • Suppression of flavor deterioration due to oxidation and / or gas loss can be evaluated by measuring a change in flavor before and after leaving a sample filled with the contents in a PET bottle container at a high temperature for a predetermined period.
  • it is possible to evaluate the degree of flavor deterioration due to oxidation and / or gas loss by filling beer-taste beverages with PET bottles and allowing them to stand at 45 ° C. for 3 days and measuring changes in flavor before and after that.
  • the condition of 45 ° C. for 3 days corresponds to deterioration equivalent to 1 month at room temperature. The higher the temperature, the faster the deterioration due to oxidation and gas loss.
  • the beer-taste beverage of the present invention is suitable for containerized embodiments.
  • containers include bottles, plastic bottles, cans (bottle cans), or barrels, but are particularly suitable for use in re-capable containers such as bottles, bottle cans and plastic bottles.
  • re-capable containers such as bottles, bottle cans and plastic bottles.
  • the beer-taste beverage of the present invention can be suitably used for a re-capable container such as a bottle, a plastic bottle or a bottle can.
  • the acidulant, the bitterness-imparting agent, the sweetener, and optional additive materials contained in the beer-taste beverage of the present invention will be described in detail in “1.1 Raw Materials”.
  • raw materials for the beer-taste beverage of the present invention acidulants, bitterness imparting agents, sweeteners and wheat are used.
  • water, fragrances, alcohol, antioxidants, cereals, dietary fiber, various additives, and the like used as raw materials for general beer-taste beverages may be used.
  • the acidulant is not particularly limited as long as it is usually used in beer-taste beverages, and is selected from, for example, phosphoric acid, citric acid, gluconic acid, tartaric acid, lactic acid, malic acid, phytic acid, acetic acid, and succinic acid. More than one kind can be used.
  • bitterness-imparting agent is not particularly limited, and a bitterness-imparting agent used as a raw material for ordinary beer or happoshu can be used.
  • hop-derived ingredients quassin, naringin, sagebrush (or sagebrush extract or sagebrush fragrance), citrus extract, scallop extract, coffee extract, tea extract, bitter gourd extract, lotus germ extract, beetle aloe extract Mannen wax extract, litchi extract, laurel extract, sage extract, caraway extract, isohumulones, reduced isohumulones and the like.
  • the bitterness-imparting agent contains at least one selected from the group consisting of a hop-derived component, sagebrush, naringin and quassin.
  • a hop means the normal pellet hop used for manufacture of beer etc., a bale hop, a hop extract, a hop processed product (isolated hop, hexa hop, tetra hop), etc.
  • the hop-derived component preferably contains one or more selected from the group consisting of iso- ⁇ acid and ⁇ -acid, and more preferably contains iso- ⁇ acid.
  • Sweeteners are not particularly limited and may be natural sweeteners or artificial sweeteners. Natural sweeteners include sucrose, oligosaccharides, glucose, maltose, stevia (extract), rebaudioside A, rebaudioside D, rebaudioside M, xylitol, sorbitol, trehalose, thaumatin and the like, and artificial sweeteners such as aspartame, acesulfame Examples include potassium and sucralose. Among natural sweeteners and artificial sweeteners, high-sweetness sweeteners having a high sweetness with respect to sucrose are preferable. For example, stevia (extract), rebaudioside A, rebaudioside D, rebaudioside M, aspartame, acesulfame potassium and sucralose One or more selected from are preferred.
  • the wheat one or more kinds selected from malt and ungerminated barley, wheat, rye, oats, oats, pigeons and oats can be used.
  • the fragrance is not particularly limited, and a general beer fragrance can be used.
  • the beer flavor is used for beer-like flavoring, and includes brewing components generated by fermentation.
  • beer flavors include esters and higher alcohols.
  • esters and higher alcohols include one or more components selected from isoamyl acetate, ethyl acid acid, n-propanol, isobutanol and acetaldehyde.
  • ethanol ethyl alcohol
  • ethanol what was manufactured using various raw materials can be used. For example, distilled spirits such as spirits, whiskey and shochu, and brewed sake such as Japanese sake may be used.
  • grains other than wheat include rice (white rice, brown rice, etc.), corn, corn, potato, beans (soybean, peas, etc.), buckwheat, sorghum, rice bran, mushrooms, and extracts (extracts) thereof. Can be given.
  • the antioxidant is not particularly limited, and an antioxidant added to ordinary beer or sparkling liquor can be used.
  • an antioxidant added to ordinary beer or sparkling liquor can be used.
  • at least one selected from ascorbic acid, erythorbic acid and catechin can be used.
  • Carbon dioxide contained in the beer-taste beverage of the present invention may use carbon dioxide contained in the raw material, or may be dissolved by mixing with carbonated water or adding carbon dioxide.
  • Carbon dioxide gas contained in the beer-taste beverage of the present invention can be used as it is because carbon dioxide gas is generated in the fermentation process when a fermented liquid is used as a raw material.
  • carbon dioxide gas generated in the fermentation process cannot be used.
  • Carbon dioxide gas can be dissolved in a taste beverage.
  • the amount of carbon dioxide contained in the beer-taste beverage of the present invention is represented by the carbon dioxide pressure of the beverage, and this is not particularly limited as long as the effects of the present invention are not hindered.
  • the upper limit of the carbon dioxide gas pressure of the beverage is 4.0kg / cm 2, 3.4kg / cm 2 or 2.8 kg / cm 2
  • the lower limit is 0.2kg / cm 2, 0.9kg / cm 2 or 1.5 kg / cm 2 , and any of these upper and lower limits may be combined.
  • carbon dioxide gas pressure of the beverage 0.2 kg / cm 2 or more 4.0 kg / cm 2 or less, 0.2 kg / cm 2 or more 3.4 kg / cm 2 or less, 0.9 kg / cm 2 or more 2.8 kg / cm 2 or less, or 1.5 kg / cm 2 or more 2.8 kg / cm 2 may be less.
  • the gas pressure in this specification means the gas pressure in a container except a special case. The pressure is measured by a method well known to those skilled in the art, for example, after fixing a sample at 20 ° C.
  • additives may be added as necessary within a range not impeding the effects of the present invention.
  • dietary fiber, preservatives, colorants, foam-forming agents, fermentation promoters, yeast extracts, protein-containing substances such as peptide-containing substances, seasonings such as amino acids, various acidulants, etc. that do not interfere with the effects of the present invention Can be added as needed.
  • Dietary fiber includes water soluble dietary fiber and insoluble dietary fiber. Examples of the water-soluble dietary fiber include indigestible dextrin, polydextrose, guar gum degradation product, pectin, glucomannan, alginic acid, laminarin, fucoidin and carrageenan.
  • the colorant is used to give a beverage a beer-like color, and a caramel color or the like can be used.
  • the foam-forming agent is used to form a beer-like foam in a beverage, or to retain the foam of a beverage.
  • Plant-extracted saponin substances such as soybean saponin and kiraya saponin, plants such as corn and soybean Protein and peptide containing substances, protein substances such as bovine serum albumin, yeast extract and the like can be used as appropriate.
  • the fermentation promoter is used for promoting fermentation by yeast. For example, yeast extract, rice bran ingredients such as rice and wheat, vitamins, mineral agents and the like can be used alone or in combination.
  • the beer-taste beverage of the present invention may be a container-packed beverage packed in a container.
  • Containers of any form and material may be used for the container-packed beverage, and examples of the container include bottles, plastic bottles, cans (bottle cans), and barrels. Bottles, bottle cans and PET bottles are preferred.
  • the beer taste drink of this invention can be used conveniently for the container which can be re-plugged.
  • the method for producing a beer-taste beverage of the present invention has a pH of 2 to 4 in the final product and a bitterness-imparting agent content of 0.10 mg / L to 50 mg / L. And adding a sour agent, a bitterness-imparting agent and a sweetener so as to contain a sweetener at a sucrose conversion concentration of 0.01 wt% or more and less than 0.50 wt%, and adding wheat as a raw material, It is a manufacturing method.
  • the pH, the bitterness-imparting agent content, and the sweetener content in the final product are within the above ranges.
  • These raw materials may be added, and the timing of addition is not particularly limited.
  • “adding wheat as a raw material” means that wheat is positively added when producing a beer-taste beverage.
  • the meaning of “wheat” is as described in “1.1 Raw materials”.
  • a specific method for producing a beer-taste beverage will be described below separately for a case where fermentation is performed and a case where fermentation is not performed.
  • the beer-taste drink used in the method for producing a beer-taste drink of the present invention is, for example, a beer-taste drink well known to those skilled in the art such as a preparation process, a fermentation process, a storage process, and a filtration process. It is obtained by the manufacturing process. Specifically, the raw materials are put into a charging tank or a charging tank, and an enzyme such as amylase is added as necessary, gelatinized and saccharified, filtered and boiled. Remove solids. Thereafter, yeast is further added and fermented, the yeast is removed with a filter or the like, and additives such as water, fragrance, and pigment are added as necessary to obtain a beer-taste beverage.
  • a beer-taste drink well known to those skilled in the art such as a preparation process, a fermentation process, a storage process, and a filtration process. It is obtained by the manufacturing process. Specifically, the raw materials are put into a charging tank or a charging tank, and an enzyme such as amylase is added as necessary
  • Sweeteners, bitterness imparting agents, fragrances, acidulants, pigments, etc. may be added in a predetermined amount after the fermentation process, but may be added at any timing during the production process including the gelatinization / saccharification process, The addition timing is not limited.
  • the fermentation process may be any process in which yeast is added to a stock solution containing wheat, malt, malt extract, soybean peptide, etc. and water, and fermentation is performed, and various conditions such as fermentation temperature and fermentation period are set freely. be able to.
  • yeast In addition to wort, other grains (soybeans, corn, peas, etc.), amino acids, peptides, sugar solutions, etc. containing nutrients necessary for fermentation may be used as the stock solution.
  • a beer-taste fermented beverage it may be fermented under conditions of 8 to 25 ° C. and 5 to 10 days, which are fermentation conditions for producing ordinary beer and sparkling liquor.
  • the maximum fermentation period is 14 days. You may change the temperature (temperature rise or temperature fall) or pressure of a fermented liquid in the middle of a fermentation process.
  • the yeast used in the fermentation process can be selected in consideration of the type of fermented beverage to be produced, the intended flavor and fermentation conditions.
  • commercially available yeast such as Weihenstephan-34 strain can be used.
  • the yeast may be added to the wort as a yeast suspension, or a slurry obtained by concentrating the yeast by centrifugation or sedimentation may be added to the wort. Moreover, you may add what removed the supernatant completely after centrifugation.
  • the amount of yeast added to the wort can be appropriately set, and is, for example, about 5 ⁇ 10 6 cells / ml to 1 ⁇ 10 8 cells / ml.
  • the manufacturing process of the beer-taste beverage used in the method for manufacturing a beer-taste beverage of the present invention does not include a fermentation process, and includes water such as wheat, malt, malt extract, soybean peptide, and the like. It is obtained by a mixing process in which carbonated water or carbon dioxide gas is mixed with the stock solution. In that case, you may add additives, such as alcohol, a fragrance
  • the undiluted solution is not limited to wort, and nutrients necessary for fermentation may be supplied as other grains (soybean, corn, peas, etc.), amino acids, peptides, sugar solutions, and the like.
  • the non-fermented liquid may further include a process for producing a beer-taste beverage known to those skilled in the art, such as a preparation process, a saccharification process, and a liquor storage process.
  • a process for producing a beer-taste beverage known to those skilled in the art, such as a preparation process, a saccharification process, and a liquor storage process.
  • Sweeteners, bitterness-imparting agents, wheat, flavorings, acidulants, pigments, etc. may be added in predetermined amounts in the mixing step, but may be added in any other step other than the mixing step, and the timing of addition is limited. Not.
  • the container-packing method for beer-taste beverages of the present invention is not particularly limited, and container packing methods well known to those skilled in the art can be used.
  • the container filling step the beer-taste beverage of the present invention is filled and sealed in the container.
  • Any form and material of the container may be used for the container filling step, and examples of the container include the container described in “1.4 Container-packed beverage”.
  • Example A Examination of effects due to difference in pH and acidulant Add each raw material to water so as to have the composition described in Tables 1 and 2 below, add carbon dioxide gas, and fill a PET bottle container.
  • the beer-taste beverages of Examples 1 to 18 were prepared. The pH value of each beer-taste beverage was adjusted by the amount of ascorbic acid and acidulant added.
  • ISOHOP manufactured by Barth-Haas
  • ascorbic acid manufactured by DSM
  • acesulfame potassium acesulfame K
  • SANNET manufactured by Celanese
  • phosphoric acid manufactured by Nippon Chemical Industry
  • citric acid manufactured by Fuso Chemical Industry
  • gluconic acid manufactured by Fuso Chemical Industry
  • tartaric acid manufactured by Fuso Chemical Industry
  • lactic acid manufactured by Fuso Chemical Industries
  • apple Acid manufactured by Fuso Chemical Industries
  • phytic acid manufactured by Tsukuno Food Industry
  • acetic acid manufactured by Nippon Gosei Kagaku
  • succinic acid manufactured by Fuso Chemical Industries
  • wheat (10% wort) is obtained by saccharifying, boiling and filtering a mixture containing malt and water, and has an extract amount of 10 w / w%.
  • the TN amount of this wort is 106 mg / 100 mL.
  • the flavor of the beer-taste beverage thus obtained before and after the oxidation / gas loss treatment was confirmed, and the stability against oxidation / gas loss was evaluated. Details of each step are as follows.
  • the evaluation of the flavor was performed before and after the oxidation / gas loss treatment, and the evaluation value of the flavor at each stage was recorded. The average score of flavor evaluation values at each stage was calculated, and the average score of flavor evaluation values of 2 or more before and after the oxidation / gas loss treatment was regarded as acceptable. The results are shown in Tables 1 and 2.
  • the content of the bitterness imparting agent is 10 mg / L
  • the content of the sweetener is 0.38% by weight in terms of sucrose (w / In beer-taste beverages fixed at w%)
  • the deterioration of flavor due to oxidation / gas loss treatment can be suppressed by adjusting the content of various acidulants and adjusting the pH within the range of 2-3.
  • Examples 1 to 18 had a sufficient flavor, and there was little deterioration in flavor due to oxidation / gas loss treatment.
  • Example B Examination of effect due to difference in pH (adjustment with phosphoric acid) and bitterness imparting agent The effect due to difference in bitterness imparting agent concentration when pH was adjusted with phosphoric acid was examined.
  • each raw material was added to water so as to have the composition described in Tables 3 and 4, carbon dioxide gas was added, and the bottles were filled into Examples 19 to 22 and Comparative Example 1.
  • ⁇ 4 beer-taste beverages were prepared and subjected to oxidation / gas loss treatment and evaluation in the same manner as in Example A. The results are shown in Tables 3 and 4.
  • Example C Examination of effects due to differences in acidulant and bitterness imparting agent concentrations The effects of differences in bitterness imparting agent concentrations when citric acid or lactic acid was used as an acidulant were examined.
  • beer-taste beverages of Examples 23 to 26 were prepared by adding each raw material to water so as to have the composition shown in Table 5, adding carbon dioxide gas, and filling the PET bottle container. Then, the oxidation / gas loss treatment and evaluation were performed in the same manner as in Example A. The results are shown in Table 5.
  • citric acid was used as a sour agent in beer-taste beverages containing wheat as a raw material and having a sweetener (acesulfame K) content fixed at 0.38% by weight (w / w%) in terms of sucrose.
  • a sweetener acesulfame K
  • the content of lactic acid to adjust the pH to 3
  • the content of the bitterness imparting agent isoalpha acid
  • Examples 2, 5 and 23 to 26 had a sufficient flavor, and there was little deterioration of the flavor due to the oxidation / gas loss treatment.
  • Example D Examination of effect by use of plural kinds of acidulants The effect when plural kinds of acidulants were used was examined.
  • beer-taste beverages of Examples 27 to 30 were prepared by adding each raw material to water so as to have the composition shown in Table 6, adding carbon dioxide gas, and filling a plastic bottle container. Then, the oxidation / gas loss treatment and evaluation were performed in the same manner as in Example A. The results are shown in Table 6.
  • Example E Examination of effect by presence or absence of alcohol The effect by the presence or absence of alcohol was examined.
  • beer-taste beverages of Examples 31 to 33 were prepared by adding each raw material to water so as to have the composition shown in Table 7, adding carbon dioxide gas, and filling the plastic bottle container. Then, the oxidation / gas loss treatment and evaluation were performed in the same manner as in Example A. The alcohol concentration was adjusted by adding wheat spirits. The results are shown in Table 7.
  • Example F Examination of effect due to difference in bitterness imparting agent The effect due to difference in bitterness imparting agent was examined.
  • the beer-taste beverage of Example 34 is prepared by adding each raw material to water so as to have the composition shown in Table 8 in the same manner as in Example A, adding carbon dioxide gas, and filling a plastic bottle container. In the same manner as in Example A, oxidation / gas loss treatment and evaluation were performed.
  • 250 mg / L of scented perfume manufactured by San-Ei Gen FFI Co., Ltd.
  • bitterness is imparted by containing the content of sweetener (acesulfame K), acidulant, pH and bitterness-imparting agent (isoalpha acid) within the prescribed ranges while containing wheat as a raw material. Regardless of the type of agent, it had a sufficient flavor and there was little deterioration in flavor due to oxidation and gas loss treatment.
  • Example G Examination of effect by difference in content of sweetener The effect by difference in content of sweetener was examined.
  • each raw material was added to water so as to have the composition shown in Table 9, carbon dioxide gas was added, and the bottles were filled into Examples 35 and 36 and Comparative Examples 5 and 6
  • a beer-taste beverage was prepared and subjected to oxidation / gas loss treatment and evaluation in the same manner as in Example A. The results are shown in Table 9.
  • Example H Examination of effect by difference in addition amount of wheat Effect by difference in addition amount of wheat was examined.
  • each raw material was added to water so as to have the composition shown in Table 10, carbon dioxide gas was added, and the bottles of Examples 37 and 38 and Reference Example 1 were filled by filling the PET bottle container.
  • a taste beverage was prepared and subjected to oxidation / gas loss treatment and evaluation in the same manner as in Example A. The results are shown in Table 10.
  • the content of sweetener (acesulfame K), acidulant, pH and bitterness-imparting agent (iso- ⁇ acid) are within the predetermined ranges, so that the amount of wheat added as a raw material is related. It had a sufficient flavor, and there was little deterioration in flavor due to oxidation / gas loss treatment.
  • the present invention can provide a beer-taste beverage that has an excellent flavor as a beer-taste beverage and that suppresses flavor deterioration due to oxidation and / or gas loss.

Abstract

A beer-taste beverage is provided which has a superior flavor as a beer-taste beverage and in which flavor degradation due to oxidation and/or gas loss is suppressed. This beer-taste beverage contains an acidulant, has a pH of 2-4, contains 0.10-50 mg/L of a bittering agent, contains wheat as a raw ingredient, and contains a sweetener in a sucrose-equivalent concentration of greater than or equal to 0.01 wt% and less than 0.50 wt%.

Description

香味劣化が抑制されたビールテイスト飲料およびその製造方法Beer-taste beverage with suppressed flavor deterioration and method for producing the same
 本発明は、香味劣化が抑制されたビールテイスト飲料およびその製造方法に関する。 The present invention relates to a beer-taste beverage in which flavor deterioration is suppressed and a method for producing the same.
 ビールなどのビールテイスト飲料に求められる消費者の要求は多様化している。それに伴い、ビールテイスト飲料の供給方法も多様化している。
 従来ビールテイスト飲料は、一般的に缶やビンに密封されて一度に飲みきることを前提として供給されていたが、近年では再栓可能な容器を用いた供給も求められている。しかしながら、このような容器で供給される場合、従来の容器で供給される場合よりも飲用終了まで長い時間がかかる傾向がある。そのため、開栓から飲用終了までの間に酸化やガスロスにより香味劣化がおこる虞がある。具体的には、酸化やガスロスによりビールテイスト飲料がもつ後味のスッキリさやキレ、刺激が損なわれる虞がある。そのような香味劣化を抑える一つの手段として、保存料を含むビールテイスト飲料が検討されている(例えば、特許文献1)。
Consumer demands for beer-taste beverages such as beer are diversifying. Along with this, the supply method of beer-taste beverages has also diversified.
Conventionally, beer-taste beverages are generally supplied on the premise that they are sealed in cans and bottles and can be consumed at one time. However, in recent years, supply using re-capable containers is also required. However, when it is supplied in such a container, it tends to take longer to finish drinking than in the case where it is supplied in a conventional container. Therefore, there is a possibility that flavor deterioration may occur due to oxidation or gas loss between the opening and the end of drinking. Specifically, there is a possibility that the refreshing aftertaste, sharpness, and irritation of beer-taste beverages may be impaired by oxidation and gas loss. As one means for suppressing such flavor deterioration, a beer-taste beverage containing a preservative has been studied (for example, Patent Document 1).
特許第5249197号公報Japanese Patent No. 5249197
 ビールテイスト飲料の香味劣化を防止する方策としては、保存料の他に酸化防止剤の添加が挙げられるが、酸化防止剤では酸化による香味劣化を十分に抑制することができない可能性がある。さらに、再栓可能容器としてペットボトルへの需要が高まっているが、ペットボトルは開栓時はもちろん経時で容器内への酸素侵入やガスロスがビンよりも多く生じるため、香味が劣化しやすいという課題がある。また、ビールテイスト飲料に原料として麦が入っていると、麦由来の成分が酸化して好ましくない紙様の香り(以下papery)が発生する虞がある。特にガスロスによって穀物様の好ましくない香り(以下grainy)が目立ってしまう虞もある。原料に含まれる麦の量を減らせばpaperyやgrainyは抑制されるが、麦由来のタンパク質の量が減り、飲みごたえが減ってしまう虞があった。したがって、ペットボトルのような再栓可能容器での使用にも耐えられるように、原料として麦を使用しつつ、ビールテイスト飲料として優れた香味を有し、かつ、酸化および/またはガスロスによる香味劣化が抑制されたビールテイスト飲料が求められている。 Measures for preventing flavor deterioration of beer-taste beverages include addition of antioxidants in addition to preservatives, but antioxidants may not be able to sufficiently suppress flavor deterioration due to oxidation. Furthermore, there is an increasing demand for PET bottles as re-pluggable containers. However, PET bottles are more likely to deteriorate in flavor due to more oxygen intrusion and gas loss into the container over time than when bottles are opened. There are challenges. Moreover, when wheat is contained as a raw material in a beer-taste beverage, there is a possibility that a component derived from wheat is oxidized and an unfavorable paper-like scent (hereinafter, papery) is generated. In particular, there is a possibility that an unfavorable grain-like aroma (hereinafter referred to as grainy) may be noticeable due to gas loss. If the amount of wheat contained in the raw material is reduced, papery and grainy are suppressed, but the amount of protein derived from the wheat is reduced, and there is a possibility that the feeling of drinking is reduced. Therefore, it has excellent flavor as a beer-taste beverage while using wheat as a raw material so that it can be used in a re-capable container such as a PET bottle, and flavor deterioration due to oxidation and / or gas loss. There is a need for beer-taste beverages that are suppressed.
 本発明はこのような課題を解決するためになされたものであり、本発明者らが鋭意検討した結果、酸味料を含み、かつpHを所定の範囲内とし、さらに苦味付与剤と甘味料の濃度を所定の濃度範囲とすることで、原料として麦を使用しつつビールテイスト飲料として優れた香味を有し、かつ、酸化および/またはガスロスによる香味劣化が抑制されたビールテイスト飲料を得ることができるとの知見を得た。本発明はこれらの知見に基づくものである。 The present invention has been made to solve such problems. As a result of intensive studies by the present inventors, the present invention includes an acidulant and a pH within a predetermined range, and further includes a bitterness-imparting agent and a sweetener. By setting the concentration within a predetermined concentration range, it is possible to obtain a beer-taste beverage that has excellent flavor as a beer-taste beverage while using wheat as a raw material, and in which flavor deterioration due to oxidation and / or gas loss is suppressed. I learned that I can do it. The present invention is based on these findings.
 本発明には以下の態様の発明が含まれる。
[1]
 酸味料を含み、
 pHが2~4であり、
 苦味付与剤の含有量が0.10mg/L~50mg/Lであり、
 原料として麦を含み、かつ
 甘味料を0.01重量%以上0.50重量%未満のショ糖換算濃度で含有する、ビールテイスト飲料。
[2]
 前記酸味料が、リン酸、クエン酸、グルコン酸、酒石酸、乳酸、リンゴ酸、フィチン酸、酢酸およびコハク酸からなる群から選択される一種以上である、[1]に記載のビールテイスト飲料。
[3]
 前記苦味付与剤が、ホップ由来の成分、ニガヨモギ、ナリンジンおよびクワシンからなる群から選択される一種以上である、[1]または[2]に記載のビールテイスト飲料。
[4]
 前記ホップ由来の成分が、イソα酸およびα酸からなる群から選択される一種以上の成分である、[3]に記載のビールテイスト飲料。
[5]
 前記甘味料が高甘味度甘味料である、[1]~[4]のいずれかに記載のビールテイスト飲料。
[6]
 前記高甘味度甘味料が、アセスルファムカリウム、スクラロース、アスパルテームおよびステビアからなる群から選択される一種以上である、[5]に記載のビールテイスト飲料。
[7]
 pHが2~3である、[1]~[6]のいずれかに記載のビールテイスト飲料。
[8]
 前記苦味付与剤の含有量が4mg/L~40mg/Lである、[1]~[7]のいずれかに記載のビールテイスト飲料。
[9]
 アルコール度数が0.05~40%である、[1]~[8]のいずれかに記載のビールテイスト飲料。
[10]
 アルコール度数が0.05%未満である、[1]~[8]のいずれかに記載のビールテイスト飲料。
[11]
 前記麦が、麦芽、ならびに、未発芽の大麦、小麦、ライ麦、カラス麦、オート麦、ハト麦およびエン麦からなる群から選択される一種以上である、[1]~[10]のいずれかに記載のビールテイスト飲料。
[12]
 T-N量が0.001mg/100mL~200mg/100mLである、[1]~[11]のいずれかに記載のビールテイスト飲料。
[13]
 [1]~[12]のいずれかに記載のビールテイスト飲料が再栓可能な容器に詰められた、容器詰飲料。
[14]
 前記再栓可能容器が、ビン、ペットボトルまたはボトル缶である、[13]に記載の容器詰飲料。
[15]
 ビールテイスト飲料の製造方法であって、最終製品中の
 pHが2~4であり、
 苦味付与剤の含有量が0.10mg/L~50mg/Lであり、かつ
 甘味料を0.01重量%以上0.50重量%未満のショ糖換算濃度で含有するように酸味料、苦味付与剤および甘味料を添加する工程を含み、
 原料として麦を添加する、製造方法。
The present invention includes the following aspects of the invention.
[1]
Including acidulants,
pH is 2-4,
The content of the bitterness-imparting agent is 0.10 mg / L to 50 mg / L,
A beer-taste beverage comprising wheat as a raw material and containing a sweetener in a sucrose equivalent concentration of 0.01% by weight or more and less than 0.50% by weight.
[2]
The beer-taste beverage according to [1], wherein the acidulant is at least one selected from the group consisting of phosphoric acid, citric acid, gluconic acid, tartaric acid, lactic acid, malic acid, phytic acid, acetic acid, and succinic acid.
[3]
The beer-taste beverage according to [1] or [2], wherein the bitterness-imparting agent is at least one selected from the group consisting of hop-derived components, wormwood, naringin, and quassin.
[4]
The beer-taste beverage according to [3], wherein the hop-derived component is one or more components selected from the group consisting of iso-α acid and α-acid.
[5]
The beer-taste beverage according to any one of [1] to [4], wherein the sweetener is a high-intensity sweetener.
[6]
The beer-taste beverage according to [5], wherein the high-intensity sweetener is at least one selected from the group consisting of acesulfame potassium, sucralose, aspartame, and stevia.
[7]
The beer-taste beverage according to any one of [1] to [6], which has a pH of 2 to 3.
[8]
The beer-taste beverage according to any one of [1] to [7], wherein a content of the bitterness imparting agent is 4 mg / L to 40 mg / L.
[9]
The beer-taste beverage according to any one of [1] to [8], which has an alcohol content of 0.05 to 40%.
[10]
The beer-taste beverage according to any one of [1] to [8], wherein the alcohol content is less than 0.05%.
[11]
Any one of [1] to [10], wherein the wheat is one or more selected from the group consisting of malt and ungerminated barley, wheat, rye, oats, oats, pigeons, and oats The beer-taste beverage described in 1.
[12]
The beer-taste beverage according to any one of [1] to [11], wherein the TN amount is 0.001 mg / 100 mL to 200 mg / 100 mL.
[13]
A container-packed beverage in which the beer-taste beverage according to any one of [1] to [12] is packed in a re-capable container.
[14]
The container-packed beverage according to [13], wherein the re-capable container is a bottle, a plastic bottle, or a bottle can.
[15]
A method for producing a beer-taste beverage, wherein the final product has a pH of 2 to 4,
Acidity and bitterness imparting so that the content of the bitterness-imparting agent is 0.10 mg / L to 50 mg / L and the sweetener is contained at a sucrose equivalent concentration of 0.01 wt% or more and less than 0.50 wt% Adding an agent and a sweetener,
A production method in which wheat is added as a raw material.
 本発明の一態様によれば、酸味料を含み、かつpHを所定の範囲内とし、さらに苦味付与剤と甘味料の濃度を所定の濃度範囲とすることで、原料として麦を使用しつつ、ビールテイスト飲料として優れた香味を有し、かつ、酸化および/またはガスロスによる香味劣化が抑制されたビールテイスト飲料を提供できる。 According to one aspect of the present invention, the sour agent is included, the pH is within a predetermined range, and the bitterness-imparting agent and the sweetener concentration are within a predetermined concentration range, while using wheat as a raw material, The beer taste drink which has the outstanding flavor as a beer taste drink, and the flavor deterioration by oxidation and / or gas loss was suppressed can be provided.
1 ビールテイスト飲料
 本発明のビールテイスト飲料は、酸味料を含み、pHが2~4であり、苦味付与剤の含有量が0.10mg/L~50mg/Lであり、原料として麦を含み、かつ甘味料を0.01重量%以上0.50重量%未満のショ糖換算濃度で含有する、ビールテイスト飲料である。
1 Beer-taste beverage The beer-taste beverage of the present invention contains a sour agent, has a pH of 2 to 4, has a bitterness-imparting agent content of 0.10 mg / L to 50 mg / L, contains wheat as a raw material, And it is a beer-taste drink which contains a sweetener with the sucrose conversion density | concentration of 0.01 weight% or more and less than 0.50 weight%.
 本明細書において、「ビールテイスト飲料」とは、ビール様の風味をもつアルコール含有またはノンアルコールの炭酸飲料をいう。つまり、本明細書のビールテイスト飲料は、特に断わりがない場合、酵母による発酵工程の有無に拘わらず、ビール風味を有するいずれの炭酸飲料をも包含する。本発明のビールテイスト飲料の種類としては、例えば、アルコール含有のビールテイスト飲料(アルコール度数が0.05~40%のビールテイスト飲料)、ノンアルコールのビールテイスト飲料(アルコール度数が0.05%未満のビールテイスト飲料)、ビールテイストの清涼飲料なども含まれる。 In this specification, “beer-taste beverage” refers to an alcohol-containing or non-alcoholic carbonated beverage having a beer-like flavor. That is, the beer-taste beverage of this specification includes any carbonated beverage having a beer flavor regardless of the presence or absence of a fermentation process using yeast, unless otherwise specified. The types of beer-taste beverages of the present invention include, for example, alcohol-containing beer-taste beverages (beer-taste beverages having an alcohol content of 0.05 to 40%), non-alcohol beer-taste beverages (alcohol content is less than 0.05%) Beer-taste beverages) and beer-taste soft drinks.
 本発明のビールテイスト飲料は酸味料を含み、pHが2~4である。酸味料の含有量はpHがこの範囲内であれば特に限定されない。pHは、好ましくは2~3である。pHを上記範囲内とすることで後味のスッキリさやキレ、刺激を担保しつつ飲料としての酸っぱさを抑えることができる。 The beer-taste beverage of the present invention contains a sour agent and has a pH of 2-4. The content of the acidulant is not particularly limited as long as the pH is within this range. The pH is preferably 2 to 3. By setting the pH within the above range, the sourness as a beverage can be suppressed while ensuring the cleanliness, sharpness and irritation of the aftertaste.
 本発明のビールテイスト飲料は、苦味付与剤の含有量が0.10mg/L~50mg/Lであり、好ましくは1mg/L~45mg/Lであり、より好ましくは4mg/L~40mg/Lである。上記範囲内であれば、後味のスッキリさやキレ、刺激を担保しつつ、苦味の浮きを抑えることができる。 The beer-taste beverage of the present invention has a bitterness-imparting agent content of 0.10 mg / L to 50 mg / L, preferably 1 mg / L to 45 mg / L, more preferably 4 mg / L to 40 mg / L. is there. If it is in the said range, the lift of a bitter taste can be suppressed, ensuring the refreshing aftertaste, sharpness, and irritation | stimulation.
 本発明のビールテイスト飲料は、甘味料を0.01重量%以上0.50重量%未満のショ糖換算濃度で含有し、好ましくは、0.01重量%~0.48重量%、より好ましくは0.02重量%~0.43重量%、さらに好ましくは0.04重量%~0.38重量%のショ糖換算濃度で含有する。上記範囲内であれば、甘さを抑えつつ、飲料にコクを与えることができる。本明細書において、「ショ糖換算濃度」とは、飲料中の甘味料による甘味をショ糖濃度で換算した値であり、ショ糖の甘味1に対する各甘味料の甘味の相対比に基づいて、ショ糖の相当量に換算し、次いで当該飲料に含まれる全ての甘味料のショ糖甘味換算量を総計することによって求めることができる。なお、ショ糖の甘味1に対する各種甘味料の甘味の相対比は、公知の砂糖甘味換算表(例えば、ビバレッジジャパン社「飲料用語辞典」資料11頁)等から求めることができる。 The beer-taste beverage of the present invention contains a sweetener at a sucrose equivalent concentration of 0.01 wt% or more and less than 0.50 wt%, preferably 0.01 wt% to 0.48 wt%, more preferably It is contained at a sucrose equivalent concentration of 0.02 wt% to 0.43 wt%, more preferably 0.04 wt% to 0.38 wt%. If it is in the said range, richness can be given to a drink, suppressing sweetness. In the present specification, “sucrose conversion concentration” is a value obtained by converting sweetness of a sweetener in a beverage by sucrose concentration, and based on a relative ratio of sweetness of each sweetener to sweetness 1 of sucrose, It can be determined by converting to a corresponding amount of sucrose and then totaling the sucrose sweetness conversion amounts of all sweeteners contained in the beverage. In addition, the relative ratio of the sweetness of various sweeteners to the sweetness 1 of sucrose can be determined from a known sugar sweetness conversion table (for example, Beverage Japan “Beverage Glossary”, page 11).
 例えば、アセスルファムカリウムの甘味度は約200であり、スクラロースの甘味度は約600であり、ステビア(抽出物)の甘味度は約150~200倍であり、アスパルテームの甘味度は約180倍である。したがって、アセスルファムカリウムを0.01重量%以上0.50重量%未満のショ糖換算濃度で含有する場合、その濃度は、0.50ppm以上25ppm未満である。スクラロースを0.01重量%以上0.50重量%未満のショ糖換算濃度で含有する場合、その濃度は、0.17ppm以上8.3ppm未満である。ステビア(抽出物)を0.01重量%以上0.50重量%未満のショ糖換算濃度で含有する場合、その濃度は、0.50ppm以上33ppm未満である。アスパルテームを0.01重量%以上0.50重量%未満のショ糖換算濃度で含有する場合、その濃度は、0.56ppm以上28ppm未満である。本発明のビールテイスト飲料は、複数種の甘味料を合計で0.01重量%以上0.50重量%未満のショ糖換算濃度で含有していてもよい。 For example, acesulfame potassium has a sweetness of about 200, sucralose has a sweetness of about 600, stevia (extract) has a sweetness of about 150 to 200 times, and aspartame has a sweetness of about 180 times. . Therefore, when acesulfame potassium is contained at a sucrose equivalent concentration of 0.01 wt% or more and less than 0.50 wt%, the concentration is 0.50 ppm or more and less than 25 ppm. When sucralose is contained at a sucrose equivalent concentration of 0.01% by weight or more and less than 0.50% by weight, the concentration is 0.17 ppm or more and less than 8.3 ppm. When stevia (extract) is contained at a sucrose equivalent concentration of 0.01 wt% or more and less than 0.50 wt%, the concentration is 0.50 ppm or more and less than 33 ppm. When aspartame is contained at a sucrose equivalent concentration of 0.01 wt% or more and less than 0.50 wt%, the concentration is 0.56 ppm or more and less than 28 ppm. The beer-taste beverage of the present invention may contain a plurality of kinds of sweeteners at a total concentration of 0.01% by weight or more and less than 0.50% by weight in terms of sucrose.
 本明細書において、「原料として麦を含む」とは、ビールテイスト飲料を製造する際に麦を積極的に添加することを意味する。なお、ビールテイスト飲料の原材料に麦が積極的に添加されているか否かは、食品表示法、食品衛生法、JAS法、景品表示法、健康増進法あるいは業界団体が定めた規約や自主基準などによって定められた原材料表示から確認することができる。例えば、麦が含まれている場合、原材料名に「小麦」や「麦芽」のように表記される。あるいは、麦は積極的に添加されているため、ビールテイスト飲料中のタンパク質の含有量は0.006mg/100mL以上である。本発明の一態様において、本発明のビールテイスト飲料は、麦を原料として添加して製造されたビールテイスト飲料である。 In the present specification, “including wheat as a raw material” means that wheat is positively added when producing a beer-taste beverage. Whether or not wheat is actively added to the ingredients of beer-taste beverages depends on the Food Labeling Law, Food Sanitation Law, JAS Law, Premium Labeling Law, Health Promotion Law, regulations and voluntary standards established by industry groups, etc. It can be confirmed from the raw material display determined by For example, when wheat is included, the name of the raw material is represented as “wheat” or “malt”. Alternatively, since wheat is actively added, the protein content in the beer-taste beverage is 0.006 mg / 100 mL or more. 1 aspect of this invention WHEREIN: The beer taste drink of this invention is a beer taste drink manufactured by adding wheat as a raw material.
 また、原材料表示に麦由来のタンパク質以外のタンパク質(大豆、アミノ酸など)が含まれていない場合は、ビールテイスト飲料に含まれる麦由来のタンパク質の量は、製品の総窒素含有量(以下、「T-N量」とも称する)を測定することで特定することができる。「総窒素含有量(T-N)」とは、飲料全体に含まれる窒素の総量を意味し、「改訂  BCOJビール分析法  8.9.2 燃焼法(改良デュマ法)、ビール酒造組合国際技術委員会(分析委員会)編  2013年増補改訂、財団法人  日本醸造協会」に記載の方法によって測定することができる。本発明のビールテイスト飲料のT-N値は、好ましくは0.001mg/100mL~200mg/100mLであり、より好ましくは、0.01mg/100mL~175mg/100mLであり、さらに好ましくは0.1mg/100mL~150mg/100mLである。0.001mg/100mL付近の濃度については測定限界値に近いが、濃縮(コンク原液)状態で測定することができる。例えば、100倍濃縮品を調製することで定量することができる。 Moreover, when proteins other than wheat-derived proteins (soybeans, amino acids, etc.) are not included in the raw material display, the amount of protein derived from wheat contained in beer-taste beverages is the total nitrogen content of the product (hereinafter referred to as “ It can be specified by measuring (TN amount). “Total nitrogen content (TN)” means the total amount of nitrogen contained in the entire beverage. “Revised BCOJ beer analysis method 8.9.2 Combustion method (improved Dumas method), International technology of the Brewery Association It can be measured by the method described in the Committee (Analysis Committee) edited in 2013, revised and revised, Japan Brewing Association. The TN value of the beer-taste beverage of the present invention is preferably 0.001 mg / 100 mL to 200 mg / 100 mL, more preferably 0.01 mg / 100 mL to 175 mg / 100 mL, and still more preferably 0.1 mg / 100 mL to 150 mg / 100 mL. It is. Concentrations around 0.001 mg / 100 mL are close to the measurement limit, but can be measured in a concentrated (concentrated stock solution) state. For example, it can be quantified by preparing a 100-fold concentrated product.
 本発明のビールテイスト飲料は、ビールや発泡酒のようなアルコール度数が0.05~40(v/v)%のビールテイスト飲料であってもよく、ノンアルコールビールのようなアルコール度数(含有量)が0.05(v/v)%未満のビールテイスト飲料であってもよい。本発明のビールテイスト飲料がアルコールを含む場合は、アルコール度数が0.5~20(v/v)%であることが好ましく、1.0~10(v/v)%であることがさらに好ましい。本発明のビールテイスト飲料がアルコールを含まない場合は、アルコール度数が0.05(v/v)%未満であり、さらに0.00(v/v)%であることが好ましい。なお本明細書において、アルコール度数は体積/体積基準の百分率(v/v%)で示されるものとする。また、飲料のアルコール含有量は、公知のいずれの方法によっても測定することができるが、例えば、振動式密度計によって測定することができる。 The beer-taste beverage of the present invention may be a beer-taste beverage having an alcohol content of 0.05 to 40 (v / v)%, such as beer or sparkling liquor, and an alcohol content (content) of non-alcohol beer. ) May be a beer-taste beverage of less than 0.05 (v / v)%. When the beer-taste beverage of the present invention contains alcohol, the alcohol content is preferably 0.5 to 20 (v / v)%, more preferably 1.0 to 10 (v / v)%. . When the beer-taste beverage of the present invention does not contain alcohol, the alcohol content is preferably less than 0.05 (v / v)%, and more preferably 0.00 (v / v)%. In the present specification, the alcohol content is expressed as a volume / volume basis percentage (v / v%). Moreover, although alcohol content of a drink can be measured by any well-known method, it can be measured with a vibration-type density meter, for example.
 本発明のビールテイスト飲料の色は、特に限定されないが、通常のビールのような琥珀色であってもよく、無色透明であってもよい。あるいは着色料などを添加して、所望の色を付けてもよい。ビールテイスト飲料の色は、肉眼でも判別することができるが、全光線透過率や色度等によって規定してもよい。 The color of the beer-taste beverage of the present invention is not particularly limited, but may be amber like normal beer or colorless and transparent. Or a coloring agent etc. may be added and a desired color may be given. The color of a beer-taste beverage can be determined with the naked eye, but may be defined by the total light transmittance, chromaticity, and the like.
 本発明のビールテイスト飲料の総エキス量は特に限定されないが、ノンアルコールビールテイスト飲料の場合は、好ましくは1.50重量%以下、より好ましくは1.10重量%以下、さらに好ましくは0.80重量%以下である。アルコールを含むビールテイスト飲料の場合は、好ましくは11重量%以下、より好ましくは8重量%以下、さらに好ましくは6重量%以下である。総エキス量を上記範囲内とすることで軽快な飲み口を付与することができる。本明細書における「総エキス量」は、飲料のアルコール度数が0.005%以上の場合、日本の酒税法におけるエキス分、すなわち、温度15度の時において原容量100立方センチメートル中に含有する不揮発性成分のグラム数をいい、アルコール度数が0.005%未満の飲料においては、脱ガスしたサンプルをビール酒造組合国際技術委員会(BCOJ)が定める「ビール分析法 7.2 エキス」に従い測定したエキス値(重量%)をいう。 The total extract amount of the beer-taste beverage of the present invention is not particularly limited, but in the case of a non-alcohol beer-taste beverage, it is preferably 1.50% by weight or less, more preferably 1.10% by weight or less, and still more preferably 0.80. % By weight or less. In the case of a beer-taste beverage containing alcohol, it is preferably 11% by weight or less, more preferably 8% by weight or less, and still more preferably 6% by weight or less. By setting the total extract amount within the above range, a light drinking mouth can be provided. The “total extract amount” in the present specification is the amount of the non-volatile component contained in the original volume of 100 cubic centimeters when the alcohol content of the beverage is 0.005% or more, that is, the extract content in the Japanese liquor tax law, that is, when the temperature is 15 degrees. For beverages with an alcohol content of less than 0.005%, the extract value (% by weight) measured for the degassed sample according to the “Beer Analysis Method 7.2 Extract” established by the International Technical Committee of the Brewery Association (BCOJ) Say.
 本発明のビールテイスト飲料は、酸化および/またはガスロスによる香味劣化が抑制されている。酸化および/またはガスロスによる香味劣化が抑制はペットボトル容器に中味を充填したサンプルを高温で所定期間静置する前後での香味変化を測定することで評価することができる。例えば、ビールテイスト飲料をペットボトル充填して45℃で3日間静置し、その前後での香味の変化を測定することで酸化および/またはガスロスによる香味劣化の程度を評価することができる。45℃、3日間の条件は常温1か月相当の劣化に該当する。温度が高いほど酸化やガスロスによる劣化は早まる。 In the beer-taste beverage of the present invention, flavor deterioration due to oxidation and / or gas loss is suppressed. Suppression of flavor deterioration due to oxidation and / or gas loss can be evaluated by measuring a change in flavor before and after leaving a sample filled with the contents in a PET bottle container at a high temperature for a predetermined period. For example, it is possible to evaluate the degree of flavor deterioration due to oxidation and / or gas loss by filling beer-taste beverages with PET bottles and allowing them to stand at 45 ° C. for 3 days and measuring changes in flavor before and after that. The condition of 45 ° C. for 3 days corresponds to deterioration equivalent to 1 month at room temperature. The higher the temperature, the faster the deterioration due to oxidation and gas loss.
 本発明のビールテイスト飲料は、容器詰の態様に適している。容器の例としては、ビン、ペットボトル、缶(ボトル缶)、または樽が挙げられるが、特に再栓可能な容器、例えば、ビン、ボトル缶およびペットボトルでの使用に適している。再栓可能な容器に充填する場合、従来の容器で供給される場合よりも飲用終了まで長い時間がかかる傾向がある。そのため、開栓から飲用終了までの間に酸化やガスロスにより香味劣化がおこる虞があるが、本発明のビールテイスト飲料は酸化および/またはガスロスによる香味劣化が抑制されているため、このような香味劣化を効果的に抑制することができる。したがって、本発明のビールテイスト飲料はビン、ペットボトルまたはボトル缶などの再栓可能な容器に好適に使用することができる。 The beer-taste beverage of the present invention is suitable for containerized embodiments. Examples of containers include bottles, plastic bottles, cans (bottle cans), or barrels, but are particularly suitable for use in re-capable containers such as bottles, bottle cans and plastic bottles. When filling a re-capable container, it tends to take longer to finish drinking than when it is supplied in a conventional container. Therefore, there is a possibility that flavor deterioration may occur due to oxidation or gas loss between the opening of the bottle and the end of drinking, but the flavor deterioration due to oxidation and / or gas loss is suppressed in the beer-taste beverage of the present invention. Deterioration can be effectively suppressed. Therefore, the beer-taste beverage of the present invention can be suitably used for a re-capable container such as a bottle, a plastic bottle or a bottle can.
 本発明のビールテイスト飲料に含まれる、酸味料、苦味付与剤および甘味料、並びに任意の添加原料については、「1.1原材料」において詳述する。 The acidulant, the bitterness-imparting agent, the sweetener, and optional additive materials contained in the beer-taste beverage of the present invention will be described in detail in “1.1 Raw Materials”.
1.1 原材料
 本発明のビールテイスト飲料の原材料としては酸味料、苦味付与剤、甘味料および麦が用いられる。その他に一般的なビールテイスト飲料の原材料として用いられる、水、香料、アルコール、酸化防止剤、穀物、食物繊維および各種添加物等を用いてもよい。
1.1 Raw materials As raw materials for the beer-taste beverage of the present invention, acidulants, bitterness imparting agents, sweeteners and wheat are used. In addition, water, fragrances, alcohol, antioxidants, cereals, dietary fiber, various additives, and the like used as raw materials for general beer-taste beverages may be used.
 酸味料としては、ビールテイスト飲料に通常使用されるものであれば特に限定されないが、例えば、リン酸、クエン酸、グルコン酸、酒石酸、乳酸、リンゴ酸、フィチン酸、酢酸およびコハク酸から選択される一種以上を用いることができる。 The acidulant is not particularly limited as long as it is usually used in beer-taste beverages, and is selected from, for example, phosphoric acid, citric acid, gluconic acid, tartaric acid, lactic acid, malic acid, phytic acid, acetic acid, and succinic acid. More than one kind can be used.
 苦味付与剤としては、特に限定されず、通常のビールや発泡酒の原料として用いられる苦味付与剤を用いることができる。例えば、ホップ由来の成分、クワシン、ナリンジン、ニガヨモギ(あるいはニガヨモギ抽出物やニガヨモギ香料)、柑橘抽出物、ニガキ抽出物、コーヒー抽出物、茶抽出物、ゴーヤ抽出物、ハス胚芽抽出物、キダチアロエ抽出物、マンネンロウ抽出物、レイシ抽出物、ローレル抽出物、セージ抽出物、キャラウェイ抽出物、イソフムロン類および還元型イソフムロン類等が挙げられる。好ましくは、苦味付与剤としてホップ由来の成分、ニガヨモギ、ナリンジンおよびクワシンからなる群から選択される一種以上を含有する。ホップとは、ビールなどの製造に使用される通常のペレットホップ、ベールホップ、ホップエキス、ホップ加工品(イソ化ホップ、ヘキサホップ、テトラホップ)などをいう。ホップ由来の成分としては、イソα酸およびα酸からなる群から選択される一種以上を含むことが好ましく、イソα酸を含むことがより好ましい。 The bitterness-imparting agent is not particularly limited, and a bitterness-imparting agent used as a raw material for ordinary beer or happoshu can be used. For example, hop-derived ingredients, quassin, naringin, sagebrush (or sagebrush extract or sagebrush fragrance), citrus extract, scallop extract, coffee extract, tea extract, bitter gourd extract, lotus germ extract, beetle aloe extract Mannen wax extract, litchi extract, laurel extract, sage extract, caraway extract, isohumulones, reduced isohumulones and the like. Preferably, the bitterness-imparting agent contains at least one selected from the group consisting of a hop-derived component, sagebrush, naringin and quassin. A hop means the normal pellet hop used for manufacture of beer etc., a bale hop, a hop extract, a hop processed product (isolated hop, hexa hop, tetra hop), etc. The hop-derived component preferably contains one or more selected from the group consisting of iso-α acid and α-acid, and more preferably contains iso-α acid.
 甘味料としては、特に限定されず、天然甘味料や人工甘味料であってもよい。天然甘味料としては、スクロース、オリゴ糖、ブドウ糖、麦芽糖、ステビア(抽出物)、レバウディオシドA,レバウディオシドD、レバウディオシドM、キシリトール、ソルビトール、トレハロース、ソーマチン等が挙げられ、人工甘味料としてはアスパルテーム、アセスルファムカリウム、スクラロース等が挙げられる。天然甘味料や人工甘味料の中でも、ショ糖に対して甘味度の高い高甘味度甘味料が好ましく、例えば、ステビア(抽出物)、レバウディオシドA,レバウディオシドD、レバウディオシドM、アスパルテーム、アセスルファムカリウムおよびスクラロースから選択される一種以上が好ましい。 Sweeteners are not particularly limited and may be natural sweeteners or artificial sweeteners. Natural sweeteners include sucrose, oligosaccharides, glucose, maltose, stevia (extract), rebaudioside A, rebaudioside D, rebaudioside M, xylitol, sorbitol, trehalose, thaumatin and the like, and artificial sweeteners such as aspartame, acesulfame Examples include potassium and sucralose. Among natural sweeteners and artificial sweeteners, high-sweetness sweeteners having a high sweetness with respect to sucrose are preferable. For example, stevia (extract), rebaudioside A, rebaudioside D, rebaudioside M, aspartame, acesulfame potassium and sucralose One or more selected from are preferred.
 麦としては、麦芽、ならびに、未発芽の大麦、小麦、ライ麦、カラス麦、オート麦、ハト麦およびエン麦から選択される一種以上を使用することができる。 As the wheat, one or more kinds selected from malt and ungerminated barley, wheat, rye, oats, oats, pigeons and oats can be used.
 香料としては、特に限定されず、一般的なビール香料を用いることができる。ビール香料は、ビール様の風味付けのために用いるものであり、発酵により発生する醸造成分等が含まれる。具体的にはビール香料にはエステルや高級アルコールなどが含まれる。そのようなエステルや高級アルコールとしては、酢酸イソアミル、酸酸エチル、n-プロパノール、イソブタノールおよびアセトアルデヒドなどから選択される1種以上の成分が含まれる。 The fragrance is not particularly limited, and a general beer fragrance can be used. The beer flavor is used for beer-like flavoring, and includes brewing components generated by fermentation. Specifically, beer flavors include esters and higher alcohols. Such esters and higher alcohols include one or more components selected from isoamyl acetate, ethyl acid acid, n-propanol, isobutanol and acetaldehyde.
 アルコールとしては、一般的なエタノール(エチルアルコール)を用いることができる。エタノールとしては、種々の原料を用いて製造したものを使用することができる。例えば、スピリッツ、ウイスキー、焼酎などの蒸留酒や、日本酒などの醸造酒を用いてもよい。 As the alcohol, general ethanol (ethyl alcohol) can be used. As ethanol, what was manufactured using various raw materials can be used. For example, distilled spirits such as spirits, whiskey and shochu, and brewed sake such as Japanese sake may be used.
 麦以外の穀物としては、例えば、米(白米、玄米など)、とうもろこし、こうりゃん、ばれいしょ、豆(大豆、えんどう豆など)、そば、ソルガム、粟、ひえおよびこれらの抽出物(エキス)などがあげられる。 Examples of grains other than wheat include rice (white rice, brown rice, etc.), corn, corn, potato, beans (soybean, peas, etc.), buckwheat, sorghum, rice bran, mushrooms, and extracts (extracts) thereof. Can be given.
 酸化防止剤としては、特に限定されず、通常のビールや発泡酒の添加する酸化防止剤を用いることができる。例えばアスコルビン酸、エリソルビン酸およびカテキンから選択される一種以上を用いることができる。 The antioxidant is not particularly limited, and an antioxidant added to ordinary beer or sparkling liquor can be used. For example, at least one selected from ascorbic acid, erythorbic acid and catechin can be used.
1.2 炭酸ガス
 本発明のビールテイスト飲料に含まれる炭酸ガスは、原材料に含まれる炭酸ガスを利用してもよく、また、炭酸水との混和または炭酸ガスの添加などで溶解させてもよい。
 本発明のビールテイスト飲料に含まれる炭酸ガスは、原材料に発酵液を用いた場合、発酵工程で炭酸ガスが発生するため、当該炭酸ガスをそのまま用いることができる。また、原材料に非発酵液を用いた場合、発酵工程で発生する炭酸ガスを利用できないため、非発酵液と炭酸水との混和、または非発酵液に炭酸ガスの添加によって、容器詰ノンアルコールビールテイスト飲料に炭酸ガスを溶解させることができる。
1.2 Carbon dioxide The carbon dioxide contained in the beer-taste beverage of the present invention may use carbon dioxide contained in the raw material, or may be dissolved by mixing with carbonated water or adding carbon dioxide. .
Carbon dioxide gas contained in the beer-taste beverage of the present invention can be used as it is because carbon dioxide gas is generated in the fermentation process when a fermented liquid is used as a raw material. In addition, when non-fermented liquid is used as a raw material, carbon dioxide gas generated in the fermentation process cannot be used. Carbon dioxide gas can be dissolved in a taste beverage.
 本発明のビールテイスト飲料に含まれる炭酸ガスの量は、飲料の炭酸ガス圧によって表され、これは、本発明の効果を妨げない限り、特に限定されない。典型的には、飲料の炭酸ガス圧の上限は4.0kg/cm、3.4kg/cmまたは2.8kg/cmであり、下限は0.2kg/cm、0.9kg/cmまたは1.5kg/cmであり、これらの上限および下限のいずれを組み合わせてもよい。例えば、飲料の炭酸ガス圧は、0.2kg/cm以上4.0kg/cm以下、0.2kg/cm以上3.4kg/cm以下、0.9kg/cm以上2.8kg/cm以下または1.5kg/cm以上2.8kg/cm以下であってよい。本明細書におけるガス圧とは、特別な場合を除き、容器内におけるガス圧をいう。圧力の測定は、当業者によく知られた方法、例えば20℃にした試料をガス内圧計に固定した後、一度ガス内圧計の活栓を開いてガスを抜き、再び活栓を閉じ、ガス内圧計を振り動かして指針が一定の位置に達したときの値を読み取る方法を用いて、または市販のガス圧測定装置を用いて測定することができる。 The amount of carbon dioxide contained in the beer-taste beverage of the present invention is represented by the carbon dioxide pressure of the beverage, and this is not particularly limited as long as the effects of the present invention are not hindered. Typically, the upper limit of the carbon dioxide gas pressure of the beverage is 4.0kg / cm 2, 3.4kg / cm 2 or 2.8 kg / cm 2, the lower limit is 0.2kg / cm 2, 0.9kg / cm 2 or 1.5 kg / cm 2 , and any of these upper and lower limits may be combined. For example, carbon dioxide gas pressure of the beverage, 0.2 kg / cm 2 or more 4.0 kg / cm 2 or less, 0.2 kg / cm 2 or more 3.4 kg / cm 2 or less, 0.9 kg / cm 2 or more 2.8 kg / cm 2 or less, or 1.5 kg / cm 2 or more 2.8 kg / cm 2 may be less. The gas pressure in this specification means the gas pressure in a container except a special case. The pressure is measured by a method well known to those skilled in the art, for example, after fixing a sample at 20 ° C. to a gas internal pressure gauge, once opening the stopcock of the gas internal pressure gauge, venting the gas, closing the stopcock again, Can be measured using a method of reading the value when the pointer reaches a certain position by swinging or using a commercially available gas pressure measuring device.
1.3 その他の添加物
 本発明では、本発明の効果を妨げない範囲で、必要に応じて、様々な添加物を添加してもよい。例えば、食物繊維、保存料、着色料、泡形成剤、発酵促進剤、酵母エキス、ペプチド含有物などのタンパク質系物質、アミノ酸などの調味料、各種酸味料などを本発明の効果を妨げない範囲で必要に応じて添加することができる。食物繊維としては、水溶性食物繊維および不溶性食物繊維が挙げられる。水溶性食物繊維としては、例えば、難消化性デキストリン、ポリデキストロース、グアーガム分解物、ペクチン、グルコマンナン、アルギン酸、ラミナリン、フコイジンおよびカラギーナンが挙げられる。着色料は、飲料にビール様の色を与えるために使用するものであり、カラメル色素などを用いることができる。泡形成剤は、飲料にビール様の泡を形成させるため、あるいは飲料の泡を保持させるために使用するものであり、大豆サポニン、キラヤサポニン等の植物抽出サポニン系物質、コーン、大豆などの植物タンパクおよびペプチド含有物、ウシ血清アルブミン等のタンパク質系物質、酵母エキスなどを適宜使用することができる。発酵促進剤は、酵母による発酵を促進させるために使用するものであり、例えば、酵母エキス、米や麦などの糠成分、ビタミン、ミネラル剤などを単独または組み合わせて使用することができる。
1.3 Other Additives In the present invention, various additives may be added as necessary within a range not impeding the effects of the present invention. For example, dietary fiber, preservatives, colorants, foam-forming agents, fermentation promoters, yeast extracts, protein-containing substances such as peptide-containing substances, seasonings such as amino acids, various acidulants, etc. that do not interfere with the effects of the present invention Can be added as needed. Dietary fiber includes water soluble dietary fiber and insoluble dietary fiber. Examples of the water-soluble dietary fiber include indigestible dextrin, polydextrose, guar gum degradation product, pectin, glucomannan, alginic acid, laminarin, fucoidin and carrageenan. The colorant is used to give a beverage a beer-like color, and a caramel color or the like can be used. The foam-forming agent is used to form a beer-like foam in a beverage, or to retain the foam of a beverage. Plant-extracted saponin substances such as soybean saponin and kiraya saponin, plants such as corn and soybean Protein and peptide containing substances, protein substances such as bovine serum albumin, yeast extract and the like can be used as appropriate. The fermentation promoter is used for promoting fermentation by yeast. For example, yeast extract, rice bran ingredients such as rice and wheat, vitamins, mineral agents and the like can be used alone or in combination.
1.4 容器詰飲料
 本発明のビールテイスト飲料は、容器に詰められた容器詰飲料であってもよい。容器詰飲料にはいずれの形態・材質の容器を用いてもよく、容器の例としては、ビン、ペットボトル、缶(ボトル缶)、または樽が挙げられるが、特に再栓可能な容器、例えば、ビン、ボトル缶およびペットボトルが好ましい。また、本発明のビールテイスト飲料は酸化および/またはガスロスによる香味劣化が抑制されているため、再栓可能な容器に好適に使用することができる。
1.4 Container-packed beverage The beer-taste beverage of the present invention may be a container-packed beverage packed in a container. Containers of any form and material may be used for the container-packed beverage, and examples of the container include bottles, plastic bottles, cans (bottle cans), and barrels. Bottles, bottle cans and PET bottles are preferred. Moreover, since the flavor deterioration by oxidation and / or gas loss is suppressed, the beer taste drink of this invention can be used conveniently for the container which can be re-plugged.
2 ビールテイスト飲料の製造方法
 ビールテイスト飲料の製造工程として、以下にビールテイスト飲料の製造方法と容器詰め方法について説明する。
2. Manufacturing method of beer taste drink As a manufacturing process of a beer taste drink, the manufacturing method and container packing method of a beer taste drink are demonstrated below.
2.1 ビールテイスト飲料の製造方法
 本発明のビールテイスト飲料の製造方法は、最終製品中のpHが2~4であり、苦味付与剤の含有量が0.10mg/L~50mg/Lであり、かつ甘味料を0.01重量%以上0.50重量%未満のショ糖換算濃度で含有するように酸味料、苦味付与剤および甘味料を添加する工程を含み、原料として麦を添加する、製造方法である。本発明のビールテイスト飲料の製造方法において、最終製品(すなわち、製品として流通・販売するビールテイスト飲料)中のpH、苦味付与剤の含有量および甘味料の含有量が上記範囲内となるようにこれらの原料を添加すればよく、添加のタイミングなどは特に限定されない。また、本明細書において「原料として麦を添加する」とは、ビールテイスト飲料を製造する際に麦を積極的に添加することを意味する。なお、「麦」の意味は、「1.1 原材料」に記載のとおりである。
 具体的なビールテイスト飲料の製造方法は、発酵を行う場合と発酵を行わない場合とに分けて以下に説明する。
2.1 Method for producing beer-taste beverage The method for producing a beer-taste beverage of the present invention has a pH of 2 to 4 in the final product and a bitterness-imparting agent content of 0.10 mg / L to 50 mg / L. And adding a sour agent, a bitterness-imparting agent and a sweetener so as to contain a sweetener at a sucrose conversion concentration of 0.01 wt% or more and less than 0.50 wt%, and adding wheat as a raw material, It is a manufacturing method. In the method for producing a beer-taste beverage of the present invention, the pH, the bitterness-imparting agent content, and the sweetener content in the final product (that is, beer-taste beverage distributed and sold as a product) are within the above ranges. These raw materials may be added, and the timing of addition is not particularly limited. In the present specification, “adding wheat as a raw material” means that wheat is positively added when producing a beer-taste beverage. The meaning of “wheat” is as described in “1.1 Raw materials”.
A specific method for producing a beer-taste beverage will be described below separately for a case where fermentation is performed and a case where fermentation is not performed.
 具体的なビールテイスト飲料の製造方法は、発酵を行う場合と発酵を行わない場合とに分けて以下に説明する。 The specific method for producing a beer-taste beverage will be described below separately for the case where fermentation is performed and the case where fermentation is not performed.
(1) 発酵を行う場合の製造工程
 本発明のビールテイスト飲料の製造方法に用いられるビールテイスト飲料は、例えば、仕込み工程、発酵工程、貯酒工程およびろ過工程などの当業者に周知のビールテイスト飲料の製造工程によって得られる。
 具体的には、原料を仕込釜または仕込槽に投入し、必要に応じてアミラーゼなどの酵素を添加し、糊化、糖化を行わせ、ろ過して煮沸し、清澄タンクにて凝固タンパクなどの固形分を取り除く。その後、さらに酵母を添加して発酵させ、ろ過機などで酵母を取り除き、必要に応じて水や香料、色素などの添加剤を加え、ビールテイスト飲料を得る。甘味料、苦味付与剤、香料、酸味料、色素などは、発酵工程後において所定量添加してもよいが、糊化・糖化工程を含む製造工程中の任意のタイミングで添加してもよく、添加タイミングは限定されない。
(1) Production process in the case of fermentation The beer-taste drink used in the method for producing a beer-taste drink of the present invention is, for example, a beer-taste drink well known to those skilled in the art such as a preparation process, a fermentation process, a storage process, and a filtration process. It is obtained by the manufacturing process.
Specifically, the raw materials are put into a charging tank or a charging tank, and an enzyme such as amylase is added as necessary, gelatinized and saccharified, filtered and boiled. Remove solids. Thereafter, yeast is further added and fermented, the yeast is removed with a filter or the like, and additives such as water, fragrance, and pigment are added as necessary to obtain a beer-taste beverage. Sweeteners, bitterness imparting agents, fragrances, acidulants, pigments, etc. may be added in a predetermined amount after the fermentation process, but may be added at any timing during the production process including the gelatinization / saccharification process, The addition timing is not limited.
 発酵工程は、麦、麦芽、麦芽エキス、大豆ペプチドなどと水を含む原液に酵母を添加し、発酵を行う工程であればよく、発酵温度、および発酵期間などの諸条件は、自由に設定することができる。原液には、麦汁に加えて発酵に必要な栄養源を含むその他の穀物(大豆、コーン、えんどうなど)やアミノ酸、ペプチド、糖液などをもちいてもよい。ビールテイスト発酵飲料を製造する場合、通常のビールや発泡酒の製造のための発酵条件である、8~25℃、5~10日間、の条件で発酵させてもよい。発酵期間は最大で14日間である。発酵工程の途中で発酵液の温度(昇温、または降温)または圧力を変化させてもよい。 The fermentation process may be any process in which yeast is added to a stock solution containing wheat, malt, malt extract, soybean peptide, etc. and water, and fermentation is performed, and various conditions such as fermentation temperature and fermentation period are set freely. be able to. In addition to wort, other grains (soybeans, corn, peas, etc.), amino acids, peptides, sugar solutions, etc. containing nutrients necessary for fermentation may be used as the stock solution. When producing a beer-taste fermented beverage, it may be fermented under conditions of 8 to 25 ° C. and 5 to 10 days, which are fermentation conditions for producing ordinary beer and sparkling liquor. The maximum fermentation period is 14 days. You may change the temperature (temperature rise or temperature fall) or pressure of a fermented liquid in the middle of a fermentation process.
 発酵工程で用いる酵母は、製造すべき発酵飲料の種類、目的とする香味や発酵条件などを考慮して選択することができる。例えばWeihenstephan-34株など、市販の酵母を用いることができる。酵母は、酵母懸濁液のまま麦汁に添加しても良いし、遠心分離あるいは沈降により酵母を濃縮したスラリーを麦汁に添加しても良い。また、遠心分離の後、完全に上澄みを取り除いたものを添加しても良い。酵母の麦汁への添加量は適宜設定できるが、例えば、5×106cells/ml~1×108cells/ml程度である。 The yeast used in the fermentation process can be selected in consideration of the type of fermented beverage to be produced, the intended flavor and fermentation conditions. For example, commercially available yeast such as Weihenstephan-34 strain can be used. The yeast may be added to the wort as a yeast suspension, or a slurry obtained by concentrating the yeast by centrifugation or sedimentation may be added to the wort. Moreover, you may add what removed the supernatant completely after centrifugation. The amount of yeast added to the wort can be appropriately set, and is, for example, about 5 × 10 6 cells / ml to 1 × 10 8 cells / ml.
(2)  発酵を行わない場合の製造工程
 本発明のビールテイスト飲料の製造方法に用いられるビールテイスト飲料の製造工程は、発酵工程を含まず、麦、麦芽、麦芽エキス、大豆ペプチドなどと水を含む原液に、炭酸水または炭酸ガスを混和する混和工程によって得られる。その際、必要に応じてアルコール、香料、色素などの添加剤を加えてもよい。原液に用いられるのは麦汁に限られず、発酵に必要な栄養源をその他の穀物(大豆、コーン、えんどうなど)やアミノ酸、ペプチド、糖液などで供給してもよい。非発酵液は混和工程の他に、さらに、仕込み工程、糖化工程および貯酒工程などの当業者に周知のビールテイスト飲料の製造工程を含んでもよい。甘味料、苦味付与剤、麦、香料、酸味料、色素などは、混和工程において所定量添加してもよいが、混和工程以外の他の任意の工程において添加してもよく、添加タイミングは限定されない。
(2) Manufacturing process when fermentation is not performed The manufacturing process of the beer-taste beverage used in the method for manufacturing a beer-taste beverage of the present invention does not include a fermentation process, and includes water such as wheat, malt, malt extract, soybean peptide, and the like. It is obtained by a mixing process in which carbonated water or carbon dioxide gas is mixed with the stock solution. In that case, you may add additives, such as alcohol, a fragrance | flavor, and a pigment | dye, as needed. The undiluted solution is not limited to wort, and nutrients necessary for fermentation may be supplied as other grains (soybean, corn, peas, etc.), amino acids, peptides, sugar solutions, and the like. In addition to the mixing step, the non-fermented liquid may further include a process for producing a beer-taste beverage known to those skilled in the art, such as a preparation process, a saccharification process, and a liquor storage process. Sweeteners, bitterness-imparting agents, wheat, flavorings, acidulants, pigments, etc. may be added in predetermined amounts in the mixing step, but may be added in any other step other than the mixing step, and the timing of addition is limited. Not.
2.2 ビールテイスト飲料の容器詰め方法
 本発明のビールテイスト飲料の容器詰め方法は特に限定されず、当業者に周知の容器詰め方法を用いることができる。容器詰め工程によって、本発明のビールテイスト飲料は容器に充填・密閉される。容器詰め工程には、いずれの形態・材質の容器を用いてもよく、容器の例としては、「1.4 容器詰飲料」に記載の容器が挙げられる。
2.2 Container-packing method for beer-taste beverages The container-packing method for beer-taste beverages of the present invention is not particularly limited, and container packing methods well known to those skilled in the art can be used. By the container filling step, the beer-taste beverage of the present invention is filled and sealed in the container. Any form and material of the container may be used for the container filling step, and examples of the container include the container described in “1.4 Container-packed beverage”.
 以下に、実施例を挙げて本発明をより具体的に説明するが、本発明はこれら実施例によっては制限されない。         Hereinafter, the present invention will be described more specifically with reference to examples. However, the present invention is not limited to these examples.
[実施例A]pHおよび酸味料の違いによる効果の検討
 各原料を後述の表1、2に記載の組成となるように水に添加し、炭酸ガスを添加し、ペットボトル容器に充填することで、実施例1~18のビールテイスト飲料を調製した。各ビールテイスト飲料のpH値はアスコルビン酸と酸味料の添加量によって調節した。イソα酸としてはISOHOP(Barth-Haas社製)を、アスコルビン酸としてはアスコルビン酸(DSM社製)を、ビール香料としてはビールの醸造成分が含まれているものを、アセスルファムカリウム(アセスルファムK)としてはサネット(Celanese社製)をそれぞれ用いた。また、酸味料として、リン酸(日本化学工業製)、クエン酸(扶桑化学工業製)、グルコン酸(扶桑化学工業製)、酒石酸(扶桑化学工業製)、乳酸(扶桑化学工業製)、リンゴ酸(扶桑化学工業製)、フィチン酸(築野食品工業製)、酢酸(日本合成化学製)またはコハク酸(扶桑化学工業製)を、麦としては麦(10%麦汁)を使用した。ここで、麦(10%麦汁)は、麦芽および水を含む混合物を糖化、煮沸および濾過して得たものであり、エキス量が10w/w%のものである。この麦汁のT-N量は106mg/100mLである。
 このようにして得られたビールテイスト飲料の酸化・ガスロス処理前後の香味を確認し、酸化・ガスロスに対する安定性を評価した。各工程の詳細は下記のとおりである。
[Example A] Examination of effects due to difference in pH and acidulant Add each raw material to water so as to have the composition described in Tables 1 and 2 below, add carbon dioxide gas, and fill a PET bottle container. The beer-taste beverages of Examples 1 to 18 were prepared. The pH value of each beer-taste beverage was adjusted by the amount of ascorbic acid and acidulant added. ISOHOP (manufactured by Barth-Haas) as iso-alpha acid, ascorbic acid (manufactured by DSM) as ascorbic acid, and beer fragrance containing brewing ingredients of beer, acesulfame potassium (acesulfame K) As the above, SANNET (manufactured by Celanese) was used. As acidulants, phosphoric acid (manufactured by Nippon Chemical Industry), citric acid (manufactured by Fuso Chemical Industry), gluconic acid (manufactured by Fuso Chemical Industry), tartaric acid (manufactured by Fuso Chemical Industry), lactic acid (manufactured by Fuso Chemical Industries), apple Acid (manufactured by Fuso Chemical Industries), phytic acid (manufactured by Tsukuno Food Industry), acetic acid (manufactured by Nippon Gosei Kagaku) or succinic acid (manufactured by Fuso Chemical Industries), and wheat (10% wort) were used as wheat. Here, wheat (10% wort) is obtained by saccharifying, boiling and filtering a mixture containing malt and water, and has an extract amount of 10 w / w%. The TN amount of this wort is 106 mg / 100 mL.
The flavor of the beer-taste beverage thus obtained before and after the oxidation / gas loss treatment was confirmed, and the stability against oxidation / gas loss was evaluated. Details of each step are as follows.
(酸化・ガスロス処理)
 ビールテイスト飲料の酸化・ガスロスによる香味劣化を評価するために、ペットボトル容器に充填されたサンプルを、45℃で3日間静置し、その前後での香味の変化を測定した。
(Oxidation / gas loss treatment)
In order to evaluate flavor deterioration due to oxidation and gas loss of a beer-taste beverage, the sample filled in the PET bottle container was allowed to stand at 45 ° C. for 3 days, and the change in flavor before and after that was measured.
(香味の評価)
 本明細書において、ビールテイスト飲料の香味を、評点法による官能試験によって評価した。良く訓練された官能評価者6名が、パネラーとなって評価を行い、下記の基準に基づいて数値で評価した。いずれの評価も点数が高いほど良い評価である。
 
(酸化・ガスロス処理前の香味)
 ビールテイスト飲料としての味質を以下の基準で評価した。評点1はビールテイスト飲料として不合格である。
  1:不可
  2:良
  3:優
 
(酸化・ガスロス処理後の香味)
 ビールテイスト飲料としての味質を以下の基準で評価した。評点1はビールテイスト飲料として不合格である。
  1:(劣化が酷く)不可
  2:(劣化が抑えられており)良
  3:(劣化が抑えられており)優
 
(Evaluation of flavor)
In this specification, the flavor of the beer taste drink was evaluated by the sensory test by a scoring method. Six well-trained sensory evaluators were evaluated as panelists and evaluated numerically based on the following criteria. In any case, the higher the score, the better the evaluation.

(Flavor before oxidation / gas loss treatment)
The taste quality as a beer-taste beverage was evaluated according to the following criteria. A score of 1 is rejected as a beer-taste beverage.
1: Impossibility 2: Good 3: Excellent
(Flavor after oxidation / gas loss treatment)
The taste quality as a beer-taste beverage was evaluated according to the following criteria. A score of 1 is rejected as a beer-taste beverage.
1: (Severe deterioration) Impossible 2: (Deterioration is suppressed) Good 3: (Deterioration is suppressed) Excellent
 香味の評価は、酸化・ガスロス処理の前と後にそれぞれ行い、それぞれの段階での香味の評価値を記録した。それぞれの段階での香味の評価値の平均点を算出し、酸化・ガスロス処理の前と後の両方で香味の評価値の平均点が2以上のものを合格とした。結果を表1、2に示す。
Figure JPOXMLDOC01-appb-T000001
Figure JPOXMLDOC01-appb-T000002
The evaluation of the flavor was performed before and after the oxidation / gas loss treatment, and the evaluation value of the flavor at each stage was recorded. The average score of flavor evaluation values at each stage was calculated, and the average score of flavor evaluation values of 2 or more before and after the oxidation / gas loss treatment was regarded as acceptable. The results are shown in Tables 1 and 2.
Figure JPOXMLDOC01-appb-T000001
Figure JPOXMLDOC01-appb-T000002
 上記の結果から、原料として麦を含み、苦味付与剤(イソα酸)の含有量を10mg/L、甘味料(アセスルファムK)の含有量をショ糖換算濃度で0.38重量%(w/w%)に固定したビールテイスト飲料において、種々の酸味料の含有量を調整してpHを2~3の範囲内に調整することで、酸化・ガスロス処理による香味の劣化を抑制することができることが分かった。具体的には、実施例1~18は十分な香味を有しており、酸化・ガスロス処理による香味の劣化が少なかった。 From the above results, wheat is included as a raw material, the content of the bitterness imparting agent (isoalpha acid) is 10 mg / L, and the content of the sweetener (acesulfame K) is 0.38% by weight in terms of sucrose (w / In beer-taste beverages fixed at w%), the deterioration of flavor due to oxidation / gas loss treatment can be suppressed by adjusting the content of various acidulants and adjusting the pH within the range of 2-3. I understood. Specifically, Examples 1 to 18 had a sufficient flavor, and there was little deterioration in flavor due to oxidation / gas loss treatment.
[実施例B]pH(リン酸での調整)および苦味付与剤濃度の違いによる効果の検討
 リン酸でpHを調整した場合の苦味付与剤濃度の違いによる効果を検討した。
 実施例Aと同様に表3、4に記載の組成となるように各原料を水に添加し、炭酸ガスを添加し、ペットボトル容器に充填することで、実施例19~22および比較例1~4のビールテイスト飲料を調製し、実施例Aと同様に酸化・ガスロス処理および評価を行った。結果を表3、4に示す。
Figure JPOXMLDOC01-appb-T000003
Figure JPOXMLDOC01-appb-T000004
[Example B] Examination of effect due to difference in pH (adjustment with phosphoric acid) and bitterness imparting agent The effect due to difference in bitterness imparting agent concentration when pH was adjusted with phosphoric acid was examined.
In the same manner as in Example A, each raw material was added to water so as to have the composition described in Tables 3 and 4, carbon dioxide gas was added, and the bottles were filled into Examples 19 to 22 and Comparative Example 1. ~ 4 beer-taste beverages were prepared and subjected to oxidation / gas loss treatment and evaluation in the same manner as in Example A. The results are shown in Tables 3 and 4.
Figure JPOXMLDOC01-appb-T000003
Figure JPOXMLDOC01-appb-T000004
 上記の結果から、原料として麦を含み、甘味料(アセスルファムK)の含有量をショ糖換算濃度で0.38重量%(w/w%)に固定したビールテイスト飲料において、酸味料としてリン酸の含有量を調整してpHを2~3の範囲内に調整し、苦味付与剤(イソα酸)の含有量を所定の範囲内とすることで、酸化・ガスロス処理による香味の劣化を抑制することができることが分かった。具体的には、実施例1、10および19~22は、苦味付与剤(イソα酸)の含有量が所定の範囲外である比較例1~4に対して、十分な香味を有しており、酸化・ガスロス処理による香味の劣化が少なかった。 From the above results, in beer-taste beverages containing wheat as a raw material and the content of sweetener (acesulfame K) fixed at 0.38% by weight (w / w%) in terms of sucrose, phosphoric acid as an acidulant By adjusting the pH content to a value in the range of 2 to 3, and controlling the bitterness-imparting agent (isoalpha acid) content within the specified range, flavor deterioration due to oxidation / gas loss treatment is suppressed. I found out that I can do it. Specifically, Examples 1, 10 and 19 to 22 have a sufficient flavor as compared with Comparative Examples 1 to 4 in which the content of the bitterness imparting agent (isoalpha acid) is outside the predetermined range. There was little deterioration in flavor due to oxidation / gas loss treatment.
[実施例C]酸味料および苦味付与剤濃度の違いによる効果の検討
 酸味料としてクエン酸または乳酸を使用した場合の苦味付与剤濃度の違いによる効果を検討した。
 実施例Aと同様に表5に記載の組成となるように各原料を水に添加し、炭酸ガスを添加し、ペットボトル容器に充填することで、実施例23~26のビールテイスト飲料を調製し、実施例Aと同様に酸化・ガスロス処理および評価を行った。結果を表5に示す。
Figure JPOXMLDOC01-appb-T000005
[Example C] Examination of effects due to differences in acidulant and bitterness imparting agent concentrations The effects of differences in bitterness imparting agent concentrations when citric acid or lactic acid was used as an acidulant were examined.
As in Example A, beer-taste beverages of Examples 23 to 26 were prepared by adding each raw material to water so as to have the composition shown in Table 5, adding carbon dioxide gas, and filling the PET bottle container. Then, the oxidation / gas loss treatment and evaluation were performed in the same manner as in Example A. The results are shown in Table 5.
Figure JPOXMLDOC01-appb-T000005
 上記の結果から、原料として麦を含み、甘味料(アセスルファムK)の含有量をショ糖換算濃度で0.38重量%(w/w%)に固定したビールテイスト飲料において、酸味料としてクエン酸または乳酸の含有量を調整してpHを3に調整し、苦味付与剤(イソα酸)の含有量を所定の範囲内とすることで、酸化・ガスロス処理による香味の劣化を抑制することができることが分かった。具体的には、実施例2、5および23~26は、十分な香味を有しており、酸化・ガスロス処理による香味の劣化が少なかった。 From the above results, citric acid was used as a sour agent in beer-taste beverages containing wheat as a raw material and having a sweetener (acesulfame K) content fixed at 0.38% by weight (w / w%) in terms of sucrose. Or, by adjusting the content of lactic acid to adjust the pH to 3, and by setting the content of the bitterness imparting agent (isoalpha acid) within a predetermined range, it is possible to suppress flavor deterioration due to oxidation / gas loss treatment I understood that I could do it. Specifically, Examples 2, 5 and 23 to 26 had a sufficient flavor, and there was little deterioration of the flavor due to the oxidation / gas loss treatment.
[実施例D]複数種の酸味料の使用による効果の検討
 複数種の酸味料を使用した場合の効果を検討した。
 実施例Aと同様に表6に記載の組成となるように各原料を水に添加し、炭酸ガスを添加し、ペットボトル容器に充填することで、実施例27~30のビールテイスト飲料を調製し、実施例Aと同様に酸化・ガスロス処理および評価を行った。結果を表6に示す。
Figure JPOXMLDOC01-appb-T000006
[Example D] Examination of effect by use of plural kinds of acidulants The effect when plural kinds of acidulants were used was examined.
As in Example A, beer-taste beverages of Examples 27 to 30 were prepared by adding each raw material to water so as to have the composition shown in Table 6, adding carbon dioxide gas, and filling a plastic bottle container. Then, the oxidation / gas loss treatment and evaluation were performed in the same manner as in Example A. The results are shown in Table 6.
Figure JPOXMLDOC01-appb-T000006
 上記の結果から、原料として麦を含み、甘味料(アセスルファムK)の含有量をショ糖換算濃度で0.38重量%(w/w%)に固定したビールテイスト飲料において、酸味料として複数の酸味料の含有量を調整してpHを3に調整し、苦味付与剤(イソα酸)の含有量を所定の範囲内とすることで、酸化・ガスロス処理による香味の劣化を抑制することができることが分かった。具体的には、実施例27~30は、十分な香味を有しており、酸化・ガスロス処理による香味の劣化が少なかった。 From the above results, in beer-taste beverages containing wheat as a raw material and fixing the content of sweetener (acesulfame K) to 0.38% by weight (w / w%) in terms of sucrose, a plurality of sour agents By adjusting the content of the sour agent to adjust the pH to 3, and making the content of the bitterness imparting agent (iso-α acid) within a predetermined range, it is possible to suppress flavor deterioration due to oxidation / gas loss treatment I understood that I could do it. Specifically, Examples 27 to 30 had a sufficient flavor, and there was little deterioration in flavor due to oxidation / gas loss treatment.
[実施例E]アルコールの有無による効果の検討
 アルコールの有無による効果を検討した。
 実施例Aと同様に表7に記載の組成となるように各原料を水に添加し、炭酸ガスを添加し、ペットボトル容器に充填することで、実施例31~33のビールテイスト飲料を調製し、実施例Aと同様に酸化・ガスロス処理および評価を行った。アルコール濃度は小麦スピリッツを添加して調節した。結果を表7に示す。
Figure JPOXMLDOC01-appb-T000007
[Example E] Examination of effect by presence or absence of alcohol The effect by the presence or absence of alcohol was examined.
As in Example A, beer-taste beverages of Examples 31 to 33 were prepared by adding each raw material to water so as to have the composition shown in Table 7, adding carbon dioxide gas, and filling the plastic bottle container. Then, the oxidation / gas loss treatment and evaluation were performed in the same manner as in Example A. The alcohol concentration was adjusted by adding wheat spirits. The results are shown in Table 7.
Figure JPOXMLDOC01-appb-T000007
 上記の結果から、原料として麦を含みつつ、甘味料(アセスルファムK)の含有量、酸味料、pHおよび苦味付与剤(イソα酸)の含有量を所定の範囲内とすることで、アルコール添加の有無に係わらず、十分な香味を有しており、酸化・ガスロス処理による香味の劣化が少なかった。 From the above results, while adding wheat as a raw material, the content of sweetener (acesulfame K), acidulant, pH and bitterness-imparting agent (isoalpha acid) are within the predetermined range, so that alcohol is added. Regardless of the presence or absence of this, it had a sufficient flavor, and there was little deterioration in flavor due to oxidation / gas loss treatment.
[実施例F]苦味付与剤の違いによる効果の検討
 苦味付与剤の違いによる効果を検討した。
 実施例Aと同様に表8に記載の組成となるように各原料を水に添加し、炭酸ガスを添加し、ペットボトル容器に充填することで、実施例34のビールテイスト飲料を調製し、実施例Aと同様に酸化・ガスロス処理および評価を行った。実施例1と比較すると、実施例34では苦味付与剤として10mg/Lのイソα酸の代わりに250mg/Lのニガヨモギ香料(三栄源エフ・エフ・アイ株式会社製)を添加した。結果を表8に示す。
Figure JPOXMLDOC01-appb-T000008
[Example F] Examination of effect due to difference in bitterness imparting agent The effect due to difference in bitterness imparting agent was examined.
The beer-taste beverage of Example 34 is prepared by adding each raw material to water so as to have the composition shown in Table 8 in the same manner as in Example A, adding carbon dioxide gas, and filling a plastic bottle container. In the same manner as in Example A, oxidation / gas loss treatment and evaluation were performed. Compared to Example 1, in Example 34, 250 mg / L of scented perfume (manufactured by San-Ei Gen FFI Co., Ltd.) was added as a bitterness-imparting agent instead of 10 mg / L isoα acid. The results are shown in Table 8.
Figure JPOXMLDOC01-appb-T000008
 上記の結果から、原料として麦を含みつつ、甘味料(アセスルファムK)の含有量、酸味料、pHおよび苦味付与剤(イソα酸)の含有量を所定の範囲内とすることで、苦味付与剤の種類に係わらず、十分な香味を有しており、酸化・ガスロス処理による香味の劣化が少なかった。 From the above results, bitterness is imparted by containing the content of sweetener (acesulfame K), acidulant, pH and bitterness-imparting agent (isoalpha acid) within the prescribed ranges while containing wheat as a raw material. Regardless of the type of agent, it had a sufficient flavor and there was little deterioration in flavor due to oxidation and gas loss treatment.
[実施例G]甘味料の含有量の違いによる効果の検討
 甘味料の含有量の違いによる効果を検討した。
 実施例Aと同様に表9に記載の組成となるように各原料を水に添加し、炭酸ガスを添加し、ペットボトル容器に充填することで、実施例35、36および比較例5、6のビールテイスト飲料を調製し、実施例Aと同様に酸化・ガスロス処理および評価を行った。結果を表9に示す。
Figure JPOXMLDOC01-appb-T000009
[Example G] Examination of effect by difference in content of sweetener The effect by difference in content of sweetener was examined.
In the same manner as in Example A, each raw material was added to water so as to have the composition shown in Table 9, carbon dioxide gas was added, and the bottles were filled into Examples 35 and 36 and Comparative Examples 5 and 6 A beer-taste beverage was prepared and subjected to oxidation / gas loss treatment and evaluation in the same manner as in Example A. The results are shown in Table 9.
Figure JPOXMLDOC01-appb-T000009
 上記の結果から、原料として麦を含み、苦味付与剤(イソα酸)とpHを固定したビールテイスト飲料において、甘味料(アセスルファムK)の含有量を所定の範囲内とすることで、酸化・ガスロス処理による香味の劣化を抑制することができることが分かった。具体的には、比較例5、6に対して、実施例35、36は、十分な香味を有しており、酸化・ガスロス処理による香味の劣化が少なかった。 From the above results, in the beer-taste beverage containing wheat as a raw material and fixing the bitterness-imparting agent (iso-alpha acid) and pH, the content of the sweetener (acesulfame K) is within a predetermined range, thereby oxidizing and It was found that flavor deterioration due to gas loss treatment can be suppressed. Specifically, compared with Comparative Examples 5 and 6, Examples 35 and 36 had a sufficient flavor, and there was little deterioration of the flavor due to oxidation / gas loss treatment.
[実施例H]麦の添加量の違いによる効果の検討
 麦の添加量の違いによる効果を検討した。
 実施例Aと同様に表10に記載の組成となるように各原料を水に添加し、炭酸ガスを添加し、ペットボトル容器に充填することで、実施例37、38および参考例1のビールテイスト飲料を調製し、実施例Aと同様に酸化・ガスロス処理および評価を行った。結果を表10に示す。
Figure JPOXMLDOC01-appb-T000010
[Example H] Examination of effect by difference in addition amount of wheat Effect by difference in addition amount of wheat was examined.
As in Example A, each raw material was added to water so as to have the composition shown in Table 10, carbon dioxide gas was added, and the bottles of Examples 37 and 38 and Reference Example 1 were filled by filling the PET bottle container. A taste beverage was prepared and subjected to oxidation / gas loss treatment and evaluation in the same manner as in Example A. The results are shown in Table 10.
Figure JPOXMLDOC01-appb-T000010
 上記の結果から、甘味料(アセスルファムK)の含有量、酸味料、pHおよび苦味付与剤(イソα酸)の含有量を所定の範囲内とすることで、原料としての麦の添加量に係わらず、十分な香味を有しており、酸化・ガスロス処理による香味の劣化が少なかった。 From the above results, the content of sweetener (acesulfame K), acidulant, pH and bitterness-imparting agent (iso-α acid) are within the predetermined ranges, so that the amount of wheat added as a raw material is related. It had a sufficient flavor, and there was little deterioration in flavor due to oxidation / gas loss treatment.
 本発明は、ビールテイスト飲料として優れた香味を有し、かつ、酸化および/またはガスロスによる香味劣化が抑制されたビールテイスト飲料を提供できる。
 
The present invention can provide a beer-taste beverage that has an excellent flavor as a beer-taste beverage and that suppresses flavor deterioration due to oxidation and / or gas loss.

Claims (15)

  1.  酸味料を含み、
     pHが2~4であり、
     苦味付与剤の含有量が0.10mg/L~50mg/Lであり、
     原料として麦を含み、かつ
     甘味料を0.01重量%以上0.50重量%未満のショ糖換算濃度で含有する、ビールテイスト飲料。
    Including acidulants,
    pH is 2-4,
    The content of the bitterness-imparting agent is 0.10 mg / L to 50 mg / L,
    A beer-taste beverage comprising wheat as a raw material and containing a sweetener in a sucrose equivalent concentration of 0.01% by weight or more and less than 0.50% by weight.
  2.  前記酸味料が、リン酸、クエン酸、グルコン酸、酒石酸、乳酸、リンゴ酸、フィチン酸、酢酸およびコハク酸からなる群から選択される一種以上である、請求項1に記載のビールテイスト飲料。 The beer-taste beverage according to claim 1, wherein the acidulant is at least one selected from the group consisting of phosphoric acid, citric acid, gluconic acid, tartaric acid, lactic acid, malic acid, phytic acid, acetic acid and succinic acid.
  3.  前記苦味付与剤が、ホップ由来の成分、ニガヨモギ、ナリンジンおよびクワシンからなる群から選択される一種以上である、請求項1または2に記載のビールテイスト飲料。 The beer-taste beverage according to claim 1 or 2, wherein the bitterness-imparting agent is at least one selected from the group consisting of hop-derived ingredients, sagebrush, naringin and quassin.
  4.  前記ホップ由来の成分が、イソα酸およびα酸からなる群から選択される一種以上の成分である、請求項3に記載のビールテイスト飲料。 The beer-taste beverage according to claim 3, wherein the hop-derived component is one or more components selected from the group consisting of iso-α acid and α-acid.
  5.  前記甘味料が高甘味度甘味料である、請求項1~4のいずれか一項に記載のビールテイスト飲料。 The beer-taste beverage according to any one of claims 1 to 4, wherein the sweetener is a high-intensity sweetener.
  6.  前記高甘味度甘味料が、アセスルファムカリウム、スクラロース、アスパルテームおよびステビアからなる群から選択される一種以上である、請求項5に記載のビールテイスト飲料。 The beer-taste beverage according to claim 5, wherein the high-intensity sweetener is at least one selected from the group consisting of acesulfame potassium, sucralose, aspartame, and stevia.
  7.  pHが2~3である、請求項1~6のいずれか一項に記載のビールテイスト飲料。 The beer-taste beverage according to any one of claims 1 to 6, having a pH of 2 to 3.
  8.  前記苦味付与剤の含有量が4mg/L~40mg/Lである、請求項1~7のいずれか一項に記載のビールテイスト飲料。 The beer-taste beverage according to any one of claims 1 to 7, wherein the content of the bitterness imparting agent is 4 mg / L to 40 mg / L.
  9.  アルコール度数が0.05~40%である、請求項1~8のいずれか一項に記載のビールテイスト飲料。 The beer-taste beverage according to any one of claims 1 to 8, wherein the alcohol content is 0.05 to 40%.
  10.  アルコール度数が0.05%未満である、請求項1~8のいずれか一項に記載のビールテイスト飲料。 The beer-taste beverage according to any one of claims 1 to 8, wherein the alcohol content is less than 0.05%.
  11.  前記麦が、麦芽、ならびに、未発芽の大麦、小麦、ライ麦、カラス麦、オート麦、ハト麦およびエン麦からなる群から選択される一種以上である、請求項1~10のいずれか一項に記載のビールテイスト飲料。 11. The wheat according to claim 1, wherein the wheat is at least one selected from the group consisting of malt and ungerminated barley, wheat, rye, oats, oats, pigeons, and oats. The beer-taste beverage described in 1.
  12.  T-N量が0.001mg/100mL~200mg/100mLである、請求項1~11のいずれか一項に記載のビールテイスト飲料。 The beer-taste beverage according to any one of claims 1 to 11, wherein the TN amount is 0.001 mg / 100 mL to 200 mg / 100 mL.
  13.  請求項1~12のいずれか一項に記載のビールテイスト飲料が再栓可能な容器に詰められた、容器詰飲料。 A container-packed beverage in which the beer-taste beverage according to any one of claims 1 to 12 is packed in a re-capable container.
  14.  前記再栓可能容器が、ビン、ペットボトルまたはボトル缶である、請求項13に記載の容器詰飲料。 The container-packed beverage according to claim 13, wherein the re-capable container is a bottle, a plastic bottle or a bottle can.
  15.  ビールテイスト飲料の製造方法であって、最終製品中の
     pHが2~4であり、
     苦味付与剤の含有量が0.10mg/L~50mg/Lであり、かつ
     甘味料を0.01重量%以上0.50重量%未満のショ糖換算濃度で含有するように酸味料、苦味付与剤および甘味料を添加する工程を含み、
     原料として麦を添加する、製造方法。
    A method for producing a beer-taste beverage, wherein the final product has a pH of 2 to 4,
    Acidity and bitterness imparting so that the content of the bitterness-imparting agent is 0.10 mg / L to 50 mg / L and the sweetener is contained at a sucrose equivalent concentration of 0.01 wt% or more and less than 0.50 wt% Adding an agent and a sweetener,
    A production method in which wheat is added as a raw material.
PCT/JP2018/014396 2018-04-04 2018-04-04 Beer-taste beverage with suppressed flavor degradation, and production method thereof WO2019193676A1 (en)

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