WO2019151545A1 - Adhesive sheet having embossments having different aspect ratios - Google Patents
Adhesive sheet having embossments having different aspect ratios Download PDFInfo
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- WO2019151545A1 WO2019151545A1 PCT/KR2018/001283 KR2018001283W WO2019151545A1 WO 2019151545 A1 WO2019151545 A1 WO 2019151545A1 KR 2018001283 W KR2018001283 W KR 2018001283W WO 2019151545 A1 WO2019151545 A1 WO 2019151545A1
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- WO
- WIPO (PCT)
- Prior art keywords
- embossing
- rhombus
- film
- release film
- lattice pattern
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/40—Adhesives in the form of films or foils characterised by release liners
Definitions
- the present invention relates to a pressure-sensitive adhesive sheet having a rhombus embossing having a different aspect ratio, and more particularly, a release film in which rhombus shapes consisting of squares having four sides having the same length and two diagonal lengths are arranged regularly, and the release film
- a pressure-sensitive adhesive sheet consisting of a pressure-sensitive adhesive film laminated on the substrate to reduce the longitudinal and horizontal elongation deviation of the pressure-sensitive adhesive sheet when the adhesive film is attached to an adherend such as metal or glass, it is possible to smooth out bubbles and reduce the collection phenomenon.
- the present invention relates to an adhesive sheet having a rhombus embossing having a different aspect ratio.
- the adhesive sheet used for the exterior is attached to various materials having a metal, glass, plastic sheet, painted surface or a flat surface and is used for the purpose of making the appearance beautiful or preventing the material from being damaged.
- FIG. 1 One example of the configuration of such an adhesive sheet is composed of a surface treatment layer 1, a substrate layer 2, an adhesive layer 3, a release liner layer 4, and the like from above, as shown in FIG. 1.
- the layer 2 may be subjected to various types of processing such as a printing layer (not shown) in addition to the surface treatment layer 1 of FIG. 1 to impart additional functions.
- the release liner layer 4 is formed with various types of embossing protrusions to improve the bubble release function of the pressure-sensitive adhesive layer 3, and the protrusion shape applied to the release liner layer 4 is the pressure-sensitive adhesive layer 3 of the adhesive sheet. Is transferred to.
- the pressure-sensitive adhesive layer 3 has an embossed pattern of grooves having a recessed shape.
- the engraved embossed pattern formed on the pressure-sensitive adhesive layer 3 has a function of providing workability by providing bubble release property when attached to a flat surface.
- This phenomenon tends to be more severe in appearance unevenness when the embossed release liner layer 4 is used for the bubble release treatment than when the flat non-bubble general release liner layer is used.
- the appearance product may cause a deterioration in use in the appearance product, such as a problem that the appearance becomes uneven after the adhesive coating, drying, and the base plywood.
- An object of the present invention is to provide a pressure-sensitive adhesive sheet that has been proposed to solve the above-described conventional problems and has improved the bubble omission phenomenon by reducing the vertical and horizontal elongation variation.
- an object of the present invention is to reduce the bubble collection phenomenon in the embossed protrusions mainly collected in the longitudinal direction.
- the pressure-sensitive adhesive sheet having a rhombic embossing having different aspect ratios proposed in the present invention is a release film in which rhombus-shaped lattice patterns formed by crossing four sides of the same length and protruding embossing are regularly arranged, and laminated on the release film. It consists of an adhesive film.
- the four sides of the embossing to form the lattice pattern has a predetermined height and a predetermined width, the upper end and both side portions are made of embossing having a predetermined radius of curvature, the longitudinal direction relative to the horizontal diagonal length of the rhombus shape It is preferable that the ratio of the diagonal length is larger than one.
- the predetermined height of the embossing is 6 ⁇ 18 ⁇ m
- the predetermined width is 10 ⁇ 100 ⁇ m
- the predetermined radius of curvature is 1 ⁇ m ⁇ 50 ⁇ m
- the area of the rhombus is 1089 ⁇ 6600 ⁇ m 2
- the ratio of the diagonal length to the diagonal length in the longitudinal direction is designed to be proportional to the elongation in the transverse and longitudinal directions of the fabric. However, if necessary, the ratio of the diagonal length to the horizontal diagonal length of the rhombus shape is greater than one. You can also change the height, width, and length of the horizontal and vertical diagonals freely.
- the variation in the longitudinal elongation of the adhesive sheet may be reduced to smooth out bubbles when the adhesive film is attached to a metal or glass, thereby reducing the collection phenomenon.
- the shape of the embossed protrusion on the release film is rounded to have a predetermined radius of curvature so that the surface tension of the adhesive layer to which the shape is transferred is easily acted on.
- 1 is an example of sectional drawing of a conventional adhesive sheet.
- FIGS 2 and 3 are examples of the appearance and cross-sectional view of the pressure-sensitive adhesive sheet of the present invention.
- 4 and 5 is a cross-sectional view of a pattern consisting of a lattice pattern formed by the intersection of the projecting embossing on the release film.
- Figure 6 is a view showing a projection cross-sectional view and the like of the projecting embossing to form a grid pattern according to the present invention.
- 7 to 10 are various embodiments according to the aspect ratio of the diagonal length of the projecting embossing to form a grid pattern according to the present invention.
- FIG. 11 is a view formed in another embodiment of the present invention.
- FIGS 2 and 3 are examples of the appearance and cross-sectional view of the pressure-sensitive adhesive sheet of the present invention.
- the pressure sensitive adhesive sheet of the present invention largely consists of an adhesive film and a release film.
- the adhesive film is composed of a pressure-sensitive adhesive layer laminated on the base layer and the base layer
- the release film is a structure in which the support layer and the molding layer are sequentially laminated on the slip prevention layer.
- a release coating layer may be applied on the release film as needed.
- a lattice pattern formed by intersecting intersecting embossing is molded into a rhombus shape, and thus, the adhesive layer of the pressure-sensitive adhesive film laminated to the shaping layer of the release film has concave-convex shapes corresponding thereto. Is formed.
- polyolefins such as polyethylene and polypropylene
- polyesters such as polyethylene terephthalate and polybutylene terephthalate, polyvinyl chloride, polystyrene, polyurethane, polycarbonate, poly Amide, polyimide, polymethyl methacrylate, polybutene, polybutadiene, polymethylpentene, ethylene vinyl acetate copolymer, ethylene (meth) acrylic acid copolymer, ethylene (meth) acrylic acid ester copolymer, ABS resin, ionomer resin Since it can be used widely in the industry or commercially available, such as a film consisting of a film, a foam film, or a laminated film thereof, further description will be omitted.
- 4 and 5 is a cross-sectional view of a pattern consisting of a lattice pattern formed by the intersection of the projecting embossing on the release film.
- lattice patterns are regularly arranged in a rhombus shape in which four sides have the same length and two diagonal lines (the two diagonal lengths are different) cross each other at right angles. have.
- the convex-convex protrusions having the intaglio shape corresponding thereto will be transferred to the adhesive layer of the adhesive film laminated with the release film.
- the four sides constituting the illustrated embossing protrusion have a predetermined height and a predetermined width.
- the ratio of the longitudinal diagonal length to the horizontal diagonal length of the embossing protrusion part which forms a grid pattern was made larger than one.
- the height of the embossing to form a lattice pattern is 6 ⁇ 18 ⁇ m, the width is 10 ⁇ 100 ⁇ m but this is only one embodiment, depending on the design may be possible to change the size of the height and dimensions.
- the ratio of the diagonal length in the horizontal direction and the diagonal length in the longitudinal direction is proportional to the elongation in the transverse direction and the longitudinal direction in the state of setting the area of the lattice pattern lattice pattern to 1089 to 6400 ⁇ m 2 .
- the diagonal length in the horizontal direction and the diagonal length in the vertical direction may be partially changed as necessary in proportion to the height or width of the embossing.
- the embossing forming the lattice pattern of the present invention described above has a ratio of the length of the horizontal diagonal to the length of the diagonal diagonal larger than 1, provided that the lengths of the four sides are the same.
- the adhesive film is laminated on the release film, and the work of winding the roller with the roller is continuously performed. Therefore, a variation in longitudinal and horizontal elongation of the adhesive film occurs, and for this reason, the adhesive film separated from the release film is separated from the metal, glass, When attached to a plastic or the like, there is a difference in bubble release performance in the horizontal and vertical directions.
- FIG. 8 is a view showing a projection cross-sectional view and the like of the projecting embossing to form a grid pattern according to the present invention.
- the upper and lower end portions of the embossing consisting of the projections forming a lattice pattern, both sides of the lower portion was rounded so as to have a predetermined curvature (curve radius of 1 ⁇ m ⁇ 50 ⁇ m).
- the reason for providing such a shape is that when the adhesive film is negatively transferred to the adhesive film, when the adhesive film is pressurized to the adherend such as glass, plastic, or stainless steel, the surface tension of the adhesive layer can be increased to suppress the phenomenon of bubbles being collected. Because.
- the reason for setting the radius of curvature of the embossing to 1 ⁇ m to 50 ⁇ m is to consider the height and width of the embossing.
- Figures 7 to 10 show various embodiments according to the aspect ratio of the diagonal length of the embossing constituting the grid pattern according to the present invention.
- the ratio of the longitudinal length to the longitudinal length may be variously designed as 0.92: 1.08, 0.91: 1.09, 0.94: 1.06, 0.93: 1.07, and the like.
- the preferred design ratios were 1: 1.17, 1: 1.2, 1: 1.13, 1: 1.15, etc., and thus the specific design range was more than about 1: 1 and 1.3 or less.
- the ratio of the length in the longitudinal direction to the length in the horizontal direction is greater than about 1: 1 and 1.3 or less
- the pressure-sensitive adhesive film is pushed in a predetermined direction to adhere to a glass surface or the like, the elongation of the transverse and vertical directions of the pressure-sensitive adhesive film is increased. This is because it is possible to prevent the trapping of bubbles, which mostly occur along the longitudinal direction due to the deviation, in advance.
- a line of 5 ⁇ m may be formed in the center of the dry hair shape so as to be formed in a triangular shape as a whole, in which case air is more smoothly removed, thereby doubling the effect of the present invention.
Abstract
Description
Claims (2)
- 일정한 높이와 폭을 가진 돌출된 엠보싱이 교차하여 형성된 마름모 형상의 격자 패턴이 규칙적으로 배열되는 이형 필름과,A release film in which rhombus-shaped lattice patterns formed by intersections of projecting embossing having a constant height and width are arranged regularly;상기 이형 필름상에 적층된 점착 필름을 포함하며, 돌출된 상기 엠보싱의 높이는 6~18㎛이고, 폭은 10~100㎛이며, 상기 마름모 형상의 상기 격자 패턴을 형성하는 엠보싱의 네변의 길이는 동일하고, 상기 마름모 형상의 상기 격자 패턴을 형성하는 상기 엠보싱의 가로 방향 대각선 길이 대비 세로 방향 대각선 길이의 비율은 1: 1 초과 1.3 이하이며, 상기 마름모 형상의 상기 격자 패턴의 면적은 1089~64000㎛2이며, 상기 세로 방향은 상기 이형 필름에 상기 점착 필름을 합판하여 롤러로 감아 당기는 방향이고, 상기 가로 방향은 상기 세로 방향에 수직인 방향이며, 상기 격자 패턴을 형성하는 상기 엠보싱의 상단부와 하단부의 양 측면부는 1㎛~50㎛의 곡률 반경을 갖도록 라운딩 처리하여 상기 점착 필름이 피착제에 가압 부착시 점착층의 표면 장력을 크게 하여 기포의 포집 현상을 억제할 수 있도록 한 것을 특징으로 하는 종횡 비율이 상이한 마름모형 엠보싱을 갖는 점착 시트.It includes an adhesive film laminated on the release film, the height of the embossed protruding is 6 ~ 18㎛, the width is 10 ~ 100㎛, the length of the four sides of the embossing to form the lattice pattern of the rhombus shape is the same In addition, the ratio of the longitudinal diagonal length to the horizontal diagonal length of the embossing forming the rhombus-shaped lattice pattern is greater than 1: 1 and 1.3 or less, and the area of the lattice-shaped lattice pattern is 1089 to 6400 µm 2. Wherein the longitudinal direction is a direction in which the adhesive film is laminated on the release film and rolled with a roller, and the horizontal direction is a direction perpendicular to the longitudinal direction, and the upper and lower ends of the embossing forming the lattice pattern The side portion is rounded to have a radius of curvature of 1 μm to 50 μm to increase the surface tension of the pressure-sensitive adhesive layer when the pressure-sensitive adhesive film adheres to the adhesive. Four of the pressure-sensitive adhesive sheet having a lozenge embossing the different aspect ratio, characterized in that to suppress the trapping phenomenon.
- 일정한 높이와 폭을 가진 돌출된 엠보싱이 교차하여 형성된 마름모 형상의 격자 패턴이 규칙적으로 배열되는 이형 필름과,A release film in which rhombus-shaped lattice patterns formed by intersections of projecting embossing having a constant height and width are arranged regularly;상기 이형 필름상에 적층된 점착 필름을 포함하며, 돌출된 상기 엠보싱의 높이는 6~18㎛이고, 폭은 10~100㎛이며, 상기 마름모 형상의 상기 격자 패턴을 형성하는 엠보싱의 네변의 길이는 동일하고, 상기 마름모 형상의 상기 격자 패턴을 형성하는 상기 엠보싱의 가로 방향 대각선 길이 대비 세로 방향 대각선 길이의 비율은 1: 1 초과 1.3 이하이며, 상기 마름모 형상의 상기 격자 패턴의 면적은 1089~64000㎛2이며, 상기 마름모 형상의 격자패턴의 가운데에는 5㎛의 선이 형성되고, It includes an adhesive film laminated on the release film, the height of the embossed protruding is 6 ~ 18㎛, the width is 10 ~ 100㎛, the length of the four sides of the embossing to form the lattice pattern of the rhombus shape is the same In addition, the ratio of the longitudinal diagonal length to the horizontal diagonal length of the embossing forming the rhombus-shaped lattice pattern is greater than 1: 1 and 1.3 or less, and the area of the lattice-shaped lattice pattern is 1089 to 6400 µm 2. In the center of the rhombus grid pattern is formed a line of 5㎛,상기 세로 방향은 상기 이형 필름에 상기 점착 필름을 합판하여 롤러로 감아 당기는 방향이고, 상기 가로 방향은 상기 세로 방향에 수직인 방향이며, 상기 격자 패턴을 형성하는 상기 엠보싱의 상단부와 하단부의 양 측면부는 1㎛~50㎛의 곡률 반경을 갖도록 라운딩 처리하여 상기 점착 필름이 피착제에 가압 부착시 점착층의 표면 장력을 크게 하여 기포의 포집 현상을 억제할 수 있도록 한 것을 특징으로 하는 종횡 비율이 상이한 마름모형 엠보싱을 갖는 점착 시트.The vertical direction is a direction in which the adhesive film is laminated on the release film and rolled with a roller, and the horizontal direction is a direction perpendicular to the vertical direction, and both side portions of the upper and lower ends of the embossing forming the lattice pattern are formed. A rounding treatment having a radius of curvature of 1 μm to 50 μm to increase the surface tension of the pressure-sensitive adhesive layer when the pressure-sensitive adhesive film adheres to the adherend, thereby preventing bubbles from being trapped. Adhesive sheet with model embossing.
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Citations (5)
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JP2013040336A (en) * | 1996-12-31 | 2013-02-28 | 3M Co | Adhesive having microreplicated topography and methods for making and using the same |
KR101320300B1 (en) * | 2013-02-15 | 2013-10-23 | 광성기업 주식회사 | Pressure-sensitive adhesive sheet with air-eliminable channels |
KR101588824B1 (en) * | 2015-03-24 | 2016-01-26 | 주식회사 한국후지야마산업 | Adhesive sheet having rhombic type embossing array |
KR101719750B1 (en) * | 2016-01-12 | 2017-03-24 | 에스케이씨 주식회사 | Embossed adhesive sheet and preparation method thereof |
KR101725237B1 (en) * | 2015-12-31 | 2017-04-26 | 강태욱 | Attaching sheet enhanced function of depriving air bubble |
-
2018
- 2018-01-30 WO PCT/KR2018/001283 patent/WO2019151545A1/en active Application Filing
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2013040336A (en) * | 1996-12-31 | 2013-02-28 | 3M Co | Adhesive having microreplicated topography and methods for making and using the same |
KR101320300B1 (en) * | 2013-02-15 | 2013-10-23 | 광성기업 주식회사 | Pressure-sensitive adhesive sheet with air-eliminable channels |
KR101588824B1 (en) * | 2015-03-24 | 2016-01-26 | 주식회사 한국후지야마산업 | Adhesive sheet having rhombic type embossing array |
KR101725237B1 (en) * | 2015-12-31 | 2017-04-26 | 강태욱 | Attaching sheet enhanced function of depriving air bubble |
KR101719750B1 (en) * | 2016-01-12 | 2017-03-24 | 에스케이씨 주식회사 | Embossed adhesive sheet and preparation method thereof |
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