WO2019132089A1 - Method for manufacturing waterproof fabric having antibacterial function - Google Patents

Method for manufacturing waterproof fabric having antibacterial function Download PDF

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Publication number
WO2019132089A1
WO2019132089A1 PCT/KR2017/015786 KR2017015786W WO2019132089A1 WO 2019132089 A1 WO2019132089 A1 WO 2019132089A1 KR 2017015786 W KR2017015786 W KR 2017015786W WO 2019132089 A1 WO2019132089 A1 WO 2019132089A1
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Prior art keywords
fabric
antibacterial function
producing
waterproof
waterproof fabric
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PCT/KR2017/015786
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French (fr)
Korean (ko)
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김영준
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주식회사 쇼미미디어앤트레이딩
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Publication of WO2019132089A1 publication Critical patent/WO2019132089A1/en

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/12—Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B32B27/304—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl halide (co)polymers, e.g. PVC, PVDC, PVF, PVDF
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
    • B32B27/322—Layered products comprising a layer of synthetic resin comprising polyolefins comprising halogenated polyolefins, e.g. PTFE
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/40—Layered products comprising a layer of synthetic resin comprising polyurethanes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/14—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers
    • B32B37/16—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with all layers existing as coherent layers before laminating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00—Ancillary operations in connection with laminating processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00—Ancillary operations in connection with laminating processes
    • B32B38/08—Impregnating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00—Ancillary operations in connection with laminating processes
    • B32B38/16—Drying; Softening; Cleaning
    • B32B38/164—Drying
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2260/00—Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
    • B32B2260/02—Composition of the impregnated, bonded or embedded layer
    • B32B2260/021—Fibrous or filamentary layer
    • B32B2260/023—Two or more layers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/714—Inert, i.e. inert to chemical degradation, corrosion
    • B32B2307/7145—Rot proof, resistant to bacteria, mildew, mould, fungi
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2437/00—Clothing

Definitions

  • the present invention relates to a method for producing a waterproof fabric, and more particularly, to a method for producing a waterproof fabric having an antibacterial function that is waterproof and has a waterproof laminate film and has antibacterial properties by impregnating silica nanopowder containing silver coating layer .
  • denim is a kind of cotton fabric which is woven with twill or twill weave using deep blue slope and white or gray weft. It is made of 100% cotton fiber, or it is woven by using cotton fiber with nylon or other fibers. do.
  • Denim has excellent durability and resilience. It has good flexibility and bendability. It is not brittle and has low stainability. It is mainly used for jeans and jackets. Depending on the composition and thickness of fabric, It may also be used as a cover for articles.
  • the present invention provides a waterproof denim fabric by adhering a laminate film to a base fabric and adhering interlock fabrics thereon, and treating antibacterial antimicrobial by treatment with a silica nanopowder containing silver coating layer
  • the present invention provides a method for manufacturing a waterproof fabric having a function of a waterproof fabric.
  • the method for producing a waterproof fabric having an antibacterial function according to the present invention comprises
  • A attaching a laminate film to one side of a base fabric;
  • B bonding an interlock fabric, a single pique fabric, or a napping fabric onto the laminated film;
  • C immersing the prepared clothes in a silver nanopowder containing silver coating for 10 to 40 minutes, and then taking out and drying.
  • the silver nanopowder containing the silver coating layer may be prepared by reacting a silicon alkoxide in the presence of a catalyst in the presence of a catalyst to form silica particles having an average particle size of 75 nm to 150 nm and then mixing the silica particles with a silver precursor in an alcohol solvent, And the silver precursor is reduced to form a silver coating layer on the surface of the silica particles.
  • the method for producing a waterproof fabric having an antibacterial function is characterized in that after the step (B), before the step (C), (D) the fabric is immersed in an aqueous solution of hydrochloric acid or sodium hypochlorite for 10 to 30 minutes, Step < / RTI >
  • the dried fabric may be immersed in sodium hydrate, sodium percarbonate, or acetic acid solution for 10 to 40 minutes, and then taken out and dried.
  • the fluorinated synthetic resin thin film may be a thin film of a polymer selected from the group consisting of polytetrafluoroethylene, polyvinylidene fluoride, and mixtures thereof.
  • the laminated film may be a polyester or polyurethane thin film containing poly ethylene oxide interposed between the cloths.
  • the method for manufacturing a waterproof fabric having an antibacterial function according to the present invention is characterized in that a waterproof laminate film is attached to a base fabric and then an interlock fabric, a single pique fabric or a napping fabric is adhered thereto, , The laminated film is not melted and it is possible to manufacture a fabric having a waterproof property.
  • the denim fabric made according to the method for manufacturing a waterproof fabric having an antibacterial function of the present invention can be applied without limitation to a general fabric processing method such as a silica nanopowder processing including a silver coating layer, . ≪ / RTI >
  • first, second, etc. may be used to describe various components, but the components should not be limited by the terms. The terms are used only for the purpose of distinguishing one component from another.
  • first component may be referred to as a second component, and similarly, the second component may also be referred to as a first component.
  • the method for producing a waterproof fabric having an antibacterial function of the present invention solves the problem that the waterproof thin film is melted due to the high temperature in the drying process which is carried out after decoloring and dye treatment on the base fabric for fabricating clothes.
  • the waterproof fabric manufactured by the manufacturing method of the present invention can have waterproof property and antimicrobial function, and it is possible to manufacture clothes which are difficult to manufacture with conventional fabrics such as ski suits and winter clothes.
  • the method for producing the waterproof fabric having antibacterial function of the present invention starts from the step of attaching the laminate film to one side of the base fabric.
  • the laminate film is a waterproof-breathable thin film which permits passage of water droplets having a large size and permits the passage of water vapor having a small size or a protective layer such as a cloth for protecting the thin film on one or both sides of the thin film.
  • a microporous membrane and a hydrophilic membrane are widely used.
  • the pore size of the microporous membrane is about 20,000 times smaller than that of the small droplet size, so that the water droplet can not pass through but the water vapor molecule passes easily.
  • a fluorine-based synthetic resin thin film is preferable, and a thin film of a polymer selected from the group consisting of polytetrafluoroethylene, polyvinylidene fluoride, and mixtures thereof is particularly preferable.
  • a polyester or polyurethane thin film containing poly (ethylene oxide) is preferable.
  • the present invention solves this melting problem by bonding interlock fabrics, single-pique fabrics or napping fabrics onto the laminate film. That is, by adhering a cloth interlock fabric, a single peak fabric or brushed fabric woven on a waterproof-breathable laminate film, the surface of the drying frame heated at a high temperature does not come into direct contact with the laminate film but comes into contact with the interlock fabric do. As a result, the heat of the mold for drying can be prevented from being directly transferred to the laminate film, thereby preventing melting.
  • the base fabric may be a denim fabric.
  • the laminate film is attached so that a vintage design can be formed through the overall decolorization of the base fabric, and the base fabric adhered to the interlock, single peak or brushed fabric is laminated by 5 to 30 weight % Hydrochloric acid or hypochlorite solution, stirring for 10 to 30 minutes and then drying.
  • the base fabric is immersed again in an aqueous solution of 5 to 30% by weight of sodium hydrate, sodium percarbonate or acetic acid, followed by stirring for 10 to 40 minutes .
  • the base fabric may be immersed in the silver nanofibers containing the silver coating layer to add antimicrobial properties to the discoloration process.
  • the silica nanopowder containing the silver coating layer is prepared by reacting the silicon alkoxide in the presence of a catalyst in the presence of a catalyst to form silica particles having an average particle size of 75 nm to 150 nm and then mixing the silica particles with the silver precursor in an alcohol solvent, And the silver precursor is reduced to form a silver coating layer on the surface of the silica particles.
  • the method includes reacting a silicon alkoxide alcohol in a solvent in the presence of a catalyst at a suitable temperature for a predetermined period of time to form silica particles having an average particle size of 100 to 150 nm and mixing the silica particles with a silver ion precursor and a metal salt And a reducing agent is added thereto, followed by reaction at a suitable temperature for a certain period of time to form a coating on the surface of the silica particles.
  • the base fabric of the present invention which has undergone the above-described process, can be used as a fabrics for producing winter clothes, ski suits, etc. for outdoor activities during the winter by adding waterproof and antibacterial properties.
  • the present invention is applied to the production of a fabric for producing a waterproof garment and is highly industrially applicable.

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  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Plant Pathology (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Laminated Bodies (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)

Abstract

The present invention relates to a method for manufacturing a waterproof fabric having an antibacterial function, the waterproof fabric having a waterproof laminate film attached thereto so as to have waterproofness and having silver coating layer-containing silica nanopowder impregnated therein so as to have an antibacterial property. The method for manufacturing a waterproof fabric having an antibacterial function, according to the present invention, comprises the steps of: (A) attaching a laminate film to one surface of a base fabric; (B) adhering interlock fabric, single pique fabric, or napping fabric onto the attached laminate film; and (C) immersing the manufactured clothes in silver coating layer-containing silica nanopowder for 10-40 minutes, and then taking out the clothes so as to dry the same.

Description

항균기능을 갖는 방수원단의 제조방법Method for manufacturing waterproof fabric having antibacterial function
본 발명은 방수원단의 제조방법에 관한 것으로, 더욱 상세하게는 방수성 라미네이트 필름을 부착하여 방수성이 있으며, 은 코팅층 함유 실리카 나노분말을 함침시켜 항균성을 갖는 항균기능을 갖는 방수원단의 제조방법에 관한 것이다. The present invention relates to a method for producing a waterproof fabric, and more particularly, to a method for producing a waterproof fabric having an antibacterial function that is waterproof and has a waterproof laminate film and has antibacterial properties by impregnating silica nanopowder containing silver coating layer .
일반적으로, 데님(denim)은 짙은 청색의 경사와 백색이나 회색의 위사를 이용하여 능직이나 파능직으로 짠 면직물의 일종으로서, 100%의 면섬유로 제직되거나 또는 면섬유에 나일론이나 기타 섬유를 혼용하여 제직된다.Generally, denim is a kind of cotton fabric which is woven with twill or twill weave using deep blue slope and white or gray weft. It is made of 100% cotton fiber, or it is woven by using cotton fiber with nylon or other fibers. do.
데님은 내구성과 복원력이 우수하고 유연성 및 굴곡성이 좋아 잘 구겨지지 않으며 오염성이 낮다는 특성으로 인해 주로 청바지나 재킷의 소재로 이용되고 있으며, 섬유 원단의 성분 및 두께 등에 따라 작업복이나 운동복 또는 가구와 같은 물품의 커버로 사용되기도 한다.Denim has excellent durability and resilience. It has good flexibility and bendability. It is not brittle and has low stainability. It is mainly used for jeans and jackets. Depending on the composition and thickness of fabric, It may also be used as a cover for articles.
이러한 데님은 중량이 무거운 편이고 촉감이 차가우며 보온성이 좋지 않음에 따라 겨울철 의복 또는 다양한 기능성 의복으로는 적합하지 않다는 단점이 있는데, 최근 들어서는 섬유의 가공기술이 더욱 발전한데다가 다양한 기능 및 개성적인 디자인을 원하는 소비자의 요구가 많아짐에 따라 종래의 데님 원단이 가진 단점을 보강하거나 새로운 기능을 부여하기 위 한 여러 가지 기술이 시도되고 있는 중이다.Such denim is disadvantageous in that it is not suitable for winter clothes or various functional apparels due to its heavy weight, soft feel and poor heat retention. In recent years, the processing technology of fibers has been further developed and various functions and unique designs As consumer demand increases, various techniques are being tried to reinforce the disadvantages of conventional denim fabrics or to give new functions.
한편, 겨울철 추운 날씨에 체온을 유지하기 위해서는 일정 두께 이상의 의류를 착용하거나 여러 벌을 겹쳐 입기도 하고 또는 방풍 및 방한성이 우수한 기능성 의류를 착용하기도 하는데, 두꺼운 의류를 착용하거나 여러 벌을 겹쳐서 입을 경우에는 움직임에 제약이 있을 뿐 아니라 중량감으로 인해 착용이 불편하며, 더욱이 기능성 의류의 경우 대부분 가격이 고가이어서 사용자로 하여금 경제적인 부담을 주고 있다.Meanwhile, in order to maintain the body temperature in cold weather in the winter season, clothing of a certain thickness or more, a plurality of beads may be overlapped, or functional clothing excellent in wind and cold weather may be worn. In case of wearing thick clothes or multiple beads In addition to the limitation of movement, it is inconvenient to wear due to the heavy feeling. Further, in the case of the functional garment, the price is high and the user is giving an economic burden.
이를 위하여 데님을 비롯한 섬유 원단에 보온성을 부여하기 위한 다양한 방법이 지속적으로 개발되고 있는바, 예컨대, 섬유 원단을 이중으로 구성하여 재봉하거나 접착하는 방법이 있는데, 이러한 섬유 원단은 보온성은 향상되는 반면 그 두께로 인하여 재봉이 어렵고 신축성이 저하되어 착용이 편하지 않다는 문제점이 여전히 남아있었다.For this purpose, various methods for imparting warmth to denim and other fiber fabrics have been continuously developed. For example, there is a method of sewing or adhering a fabric having a double structure. Such a fabric has improved warmth, There was still a problem that the sewing was difficult due to the thickness and the elasticity was lowered and the wearing was not easy.
또한 섬유 원단의 표면을 긁거나 섬유를 뽑아내어 벌키한(bulky) 구조를 이루도록 기모 가공하는 방법이 있는데, 이와 같이 기모(napping) 가공한 원단은 공기함량이 증가하면서 보온성이 좋아지고 촉감이 부드러워지기 때문에 최근 들어 가장 많이 애용되고 있기는 하나, 기모 가공 원단의 경우 인장강도가 저하되고 두께 증가로 인해 착용감이 좋지 않으며, 특히 날씬한 옷맵시를 원하는 사용자는 그 두께감으로 인하여 기피하는 경향이 있었다.In addition, there is a method of brushed to make a bulky structure by scratching the surface of the fabric or pulling out the fibers. Such a napped fabric has an increased air content and a better warmth and softness In recent years, brushed fabric has been used most frequently, but the tensile strength is lowered and the thickness is not improved due to the increase in thickness. In particular, a user who wants to wear a thin clothes tends to avoid it due to the thick feeling.
아울러 열차폐성 재료를 코팅한 섬유 원사로 원단을 직조하여 인체에서 발생하는 열의 외부 방출을 차단하거나 섬유 수지에 금속분말이나 세라믹분말 등을 혼합하여 만들어진 합성섬유를 이용하여 원단을 직조하여 보온성 및 항균성을 갖도록 하는 기술이 개시되어 있으나, 이러한 종래 기술은 원재료비가 많이 소요되고 공정이 다소 복잡하다는 등의 단점이 있었다.In addition, textile fabric coated with heat-shielding material is woven to prevent external heat generated from the human body, or synthetic fiber made of fiber resin mixed with metal powder or ceramic powder is used to weave the fabric, However, such a conventional technique has disadvantages such as a large amount of raw material costs and a complicated process.
본 발명은 상기 문제점을 해결하기 위한 것으로, 베이스원단에 라미네이트 필름을 부착하고, 그 위에 인터록 원단을 접착시켜 방수성의 데님원단을 제조하며, 은 코팅층 함유 실리카 나노분말로 처리하여 항균성을 갖도록 형성한 항균기능을 갖는 방수원단의 제조방법을 제공하는데 그 목적이 있다. Disclosure of the Invention In order to solve the above-described problems, the present invention provides a waterproof denim fabric by adhering a laminate film to a base fabric and adhering interlock fabrics thereon, and treating antibacterial antimicrobial by treatment with a silica nanopowder containing silver coating layer The present invention provides a method for manufacturing a waterproof fabric having a function of a waterproof fabric.
본 발명에 따른 항균기능을 갖는 방수원단의 제조방법은The method for producing a waterproof fabric having an antibacterial function according to the present invention comprises
(A) 베이스원단의 일면에 라미네이트 필름을 부착하는 단계; (B) 상기 부착된 라미네이트 필름 위에 인터록 원단, 싱글 피크(pique) 원단 또는 기모(napping) 원단을 접착시키는 단계; (C) 상기 제작된 옷을 은 코팅층 함유 실리카 나노분말에 10 내지 40분 동안 침지한 후 꺼내어 건조하는 단계를 포함한다. (A) attaching a laminate film to one side of a base fabric; (B) bonding an interlock fabric, a single pique fabric, or a napping fabric onto the laminated film; (C) immersing the prepared clothes in a silver nanopowder containing silver coating for 10 to 40 minutes, and then taking out and drying.
상기 은 코팅층 함유 실리카 나노분말은 촉매 존재 하에서 실리콘 알콕사이드를 알코올 용매 내에서 반응시켜 75nm 내지 150nm의 평균 입경을 갖는 실리카 입자를 형성한 후, 상기 실리카 입자를 알코올 용매 내에서 은 전구체와 혼합하고 환원제를 첨가하여 상기 은 전구체를 환원시켜 상기 실리카 입자의 표면상에 은 코팅층을 형성하여 형성된 것이 바람직하다. The silver nanopowder containing the silver coating layer may be prepared by reacting a silicon alkoxide in the presence of a catalyst in the presence of a catalyst to form silica particles having an average particle size of 75 nm to 150 nm and then mixing the silica particles with a silver precursor in an alcohol solvent, And the silver precursor is reduced to form a silver coating layer on the surface of the silica particles.
항균기능을 갖는 방수원단의 제조방법은 상기 단계 (B) 이후, 단계 (C) 이전에 (D) 상기 제작된 원단을 염산 또는 소듐 하이포클로라이트 수용액에 10 내지 30분 동안 침지한 후 꺼내어 건조하는 단계를 더 포함할 수 있다. The method for producing a waterproof fabric having an antibacterial function is characterized in that after the step (B), before the step (C), (D) the fabric is immersed in an aqueous solution of hydrochloric acid or sodium hypochlorite for 10 to 30 minutes, Step < / RTI >
아울러 상기 단계 (D) 직후에, (E) 상기 건조된 원단을 소듐 하이드레이트, 소듐 퍼카보네이트 또는 아세트산 용액에 10 내지 40 분 동안 침지한 후 꺼내어 건조하는 단계를 더 포함할 수 있다. In addition, immediately after the step (D), (E) the dried fabric may be immersed in sodium hydrate, sodium percarbonate, or acetic acid solution for 10 to 40 minutes, and then taken out and dried.
상기 라미네이트 필름은 천 사이에 불소계 합성수지 박막이 개재된 것이 바람직하며, 상기 불소계 합성수지 박막은 폴리테트라플루오로에틸렌, 폴리플루오르화비닐리덴, 및 그 혼합물로 이루어진 군에서 선택된 중합체의 박막일 수 있다. The fluorinated synthetic resin thin film may be a thin film of a polymer selected from the group consisting of polytetrafluoroethylene, polyvinylidene fluoride, and mixtures thereof.
상기 라미네이트 필름은 천 사이에 폴리산화에틸렌을 포함한 폴리에스테르 또는 폴리우레탄 박막이 개재된 것일 수 있다.The laminated film may be a polyester or polyurethane thin film containing poly ethylene oxide interposed between the cloths.
본 발명의 항균기능을 갖는 방수원단의 제조방법은 베이스원단에 방수성 라미네이트 필름을 부착한 후 그 위에 인터록 원단, 싱글 피크(pique) 원단 또는 기모(napping) 원단을 접착함으로써 고온의 형틀을 이용한 건조단계에서도 상기 라미네이트 필름이 용융되지 않아, 방수성을 보유한 원단의 제조가 가능하다.The method for manufacturing a waterproof fabric having an antibacterial function according to the present invention is characterized in that a waterproof laminate film is attached to a base fabric and then an interlock fabric, a single pique fabric or a napping fabric is adhered thereto, , The laminated film is not melted and it is possible to manufacture a fabric having a waterproof property.
아울러 본 발명의 항균기능을 갖는 방수원단의 제조방법에 따라 만들어진 데님원단은 은 코팅층 함유 실리카 나노분말 처리와 같은 일반적인 원단의 가공 처리방법을 제한 없이 적용할 수 있어서, 다양한 형태의 방한의류 또는 기능성 의류의 제조가 가능하다.In addition, the denim fabric made according to the method for manufacturing a waterproof fabric having an antibacterial function of the present invention can be applied without limitation to a general fabric processing method such as a silica nanopowder processing including a silver coating layer, . ≪ / RTI >
이하, 본 발명의 실시예에 따른 항균기능을 갖는 방수원단의 제조방법에 대해 상세히 설명한다. 본 발명은 다양한 변경을 가할 수 있고 여러 가지 형태를 가질 수 있는 바, 특정 실시 예들을 도면에 예시하고 본문에 상세하게 설명하고자 한다. 그러나 이는 본 발명을 특정한 개시 형태에 대해 한정하려는 것이 아니며, 본 발명의 사상 및 기술 범위에 포함되는 모든 변경, 균등물 내지 대체물을 포함하는 것으로 이해되어야 한다. 각 도면을 설명하면서 유사한 참조부호를 유사한 구성요소에 대해 사용하였다. 첨부된 도면에 있어서, 구조물들의 치수는 본 발명의 명확성을 기하기 위하여 실제보다 확대하여 도시한 것이다. Hereinafter, a method for producing a waterproof fabric having an antibacterial function according to an embodiment of the present invention will be described in detail. The present invention is capable of various modifications and various forms, and specific embodiments are illustrated in the drawings and described in detail in the text. It is to be understood, however, that the invention is not intended to be limited to the particular forms disclosed, but on the contrary, is intended to cover all modifications, equivalents, and alternatives falling within the spirit and scope of the invention. Like reference numerals are used for like elements in describing each drawing. In the accompanying drawings, the dimensions of the structures are enlarged to illustrate the present invention in order to clarify the present invention.
제1, 제2 등의 용어는 다양한 구성요소들을 설명하는데 사용될 수 있지만, 상기 구성요소들은 상기 용어들에 의해 한정되어서는 안 된다. 상기 용어들은 하나의 구성요소를 다른 구성요소로부터 구별하는 목적으로만 사용된다. 예를 들어, 본 발명의 권리 범위를 벗어나지 않으면서 제1 구성요소는 제2 구성요소로 명명될 수 있고, 유사하게 제2 구성요소도 제1 구성요소로 명명될 수 있다. The terms first, second, etc. may be used to describe various components, but the components should not be limited by the terms. The terms are used only for the purpose of distinguishing one component from another. For example, without departing from the scope of the present invention, the first component may be referred to as a second component, and similarly, the second component may also be referred to as a first component.
본 출원에서 사용한 용어는 단지 특정한 실시 예를 설명하기 위해 사용된 것으로, 본 발명을 한정하려는 의도가 아니다. 단수의 표현은 문맥상 명백하게 다르게 뜻하지 않는 한, 복수의 표현을 포함한다. 본 출원에서, "포함하다" 또는 "가지다" 등의 용어는 명세서 상에 기재된 특징, 숫자, 단계, 동작, 구성요소, 부분품 또는 이들을 조합한 것이 존재함을 지정하려는 것이지, 하나 또는 그 이상의 다른 특징들이나 숫자, 단계, 동작, 구성요소, 부분품 또는 이들을 조합한 것들의 존재 또는 부가 가능성을 미리 배제하지 않는 것으로 이해되어야 한다.The terminology used in this application is used only to describe a specific embodiment and is not intended to limit the invention. The singular expressions include plural expressions unless the context clearly dictates otherwise. In this application, the terms "comprises", "having", and the like are used to specify that a feature, a number, a step, an operation, an element, a part or a combination thereof is described in the specification, But do not preclude the presence or addition of one or more other features, integers, steps, operations, components, parts, or combinations thereof.
다르게 정의되지 않는 한, 기술적이거나 과학적인 용어를 포함해서 여기서 사용되는 모든 용어들은 본 발명이 속하는 기술 분야에서 통상의 지식을 가진 자에 의해 일반적으로 이해되는 것과 동일한 의미를 가지고 있다. 일반적으로 사용되는 사전에 정의되어 있는 것과 같은 용어들은 관련 기술의 문맥 상 가지는 의미와 일치하는 의미를 가지는 것으로 해석되어야 하며, 본 출원에서 명백하게 정의하지 않는 한, 이상적이거나 과도하게 형식적인 의미로 해석되지 않는다.Unless defined otherwise, all terms used herein, including technical or scientific terms, have the same meaning as commonly understood by one of ordinary skill in the art to which this invention belongs. Terms such as those defined in commonly used dictionaries are to be interpreted as having a meaning consistent with the contextual meaning of the related art and are to be interpreted as either ideal or overly formal in the sense of the present application Do not.
본 발명의 항균기능을 갖는 방수원단의 제조방법은 옷의 제작을 위한 베이스원단에 탈색 및 염료 처리 후 거치게 되는 건조과정에서의 고온으로 인해 방수성 박막이 용융되는 문제점을 해결한 것이다. 그 결과 본 발명의 제조방법으로 제조된 방수원단은 방수성 및 항균기능 등을 보유할 수 있어 스키복, 방한복 등 종래 원단으로 제작하기 어려웠던 의류의 제작이 가능하다. The method for producing a waterproof fabric having an antibacterial function of the present invention solves the problem that the waterproof thin film is melted due to the high temperature in the drying process which is carried out after decoloring and dye treatment on the base fabric for fabricating clothes. As a result, the waterproof fabric manufactured by the manufacturing method of the present invention can have waterproof property and antimicrobial function, and it is possible to manufacture clothes which are difficult to manufacture with conventional fabrics such as ski suits and winter clothes.
이러한 본 발명의 항균기능을 갖는 방수원단의 제조방법은 베이스원단의 일면에 라미네이트 필름을 부착하는 단계로부터 시작된다. 상기 라미네이트 필름은 크기가 큰 물방울의 통과는 막고, 크기가 작은 수증기의 통과는 허용하는 방수-통기성 박막 단독이거나 상기 박막의 일면 또는 양면에 상기 박막을 보호하기 위한 천 등의 보호층이 형성된 것이다.The method for producing the waterproof fabric having antibacterial function of the present invention starts from the step of attaching the laminate film to one side of the base fabric. The laminate film is a waterproof-breathable thin film which permits passage of water droplets having a large size and permits the passage of water vapor having a small size or a protective layer such as a cloth for protecting the thin film on one or both sides of the thin film.
상기 방수-통기성 박막으로는 마이크로 세공막과 친수성 막이 널리 사용되고 있다. 상기 마이크로 세공막의 세공 크기는 작은 물방울 크기의 20,000 분의 1 정도로 작아 물방울은 통과하지 못하지만, 수증기 분자는 쉽게 통과한다. 마이크로 세공막으로는 불소계 합성수지 박막이 바람직하며, 그 중에서도 특히 폴리테트라플루오로에틸렌, 폴리플루오르화비닐리덴, 및 그 혼합물로 이루어진 군에서 선택된 중합체의 박막이 더욱 바람직하다. 그리고 친수성 막으로는 폴리산화에틸렌을 포함한 폴리에스테르 또는 폴리우레탄 박막이 바람직하다.As the waterproof-breathable thin film, a microporous membrane and a hydrophilic membrane are widely used. The pore size of the microporous membrane is about 20,000 times smaller than that of the small droplet size, so that the water droplet can not pass through but the water vapor molecule passes easily. As the microporous membrane, a fluorine-based synthetic resin thin film is preferable, and a thin film of a polymer selected from the group consisting of polytetrafluoroethylene, polyvinylidene fluoride, and mixtures thereof is particularly preferable. As the hydrophilic film, a polyester or polyurethane thin film containing poly (ethylene oxide) is preferable.
종래에는 원단에 대한 여러 가지 처리 후의 건조단계에서, 이러한 라미네이트 필름의 용융이 발생했다. 원단 또는 원단을 재단과 재봉을 통해 제작한 옷을 고온의 형틀에 씌워 건조하는 과정을 거쳤는데, 이러한 고온의 형틀에 의해 라미네이트 필름의 용융이 발생하고 방수성이 저하된 것이다. Conventionally, the melting of such a laminated film has occurred in the drying step after various treatments of the fabric. The cloth or fabric was cut and sewed, and the clothes were covered with a high-temperature mold and dried. Such a high-temperature mold caused melting of the laminate film and decreased water resistance.
본 발명은 상기 라미네이트 필름 위에 인터록 원단, 싱글 피크(pique) 원단 또는 기모(napping) 원단을 접착시킴으로써, 이러한 용융 문제를 해결한다. 즉, 방수-통기성 라미네이트 필름 위에 직조된 천인 인터록 원단, 싱글 피크 원단 또는 기모 원단 등을 접착시킴에 따라, 고온으로 가열된 건조용 형틀의 표면이 라미네이트 필름과 직접 접촉하지 않고 상기 인터록 원단 등과 접촉하게 된다. 그 결과, 상기 건조용 형틀의 열이 라미네이트 필름에 직접 전달되는 것을 방지함으로써 용융을 예방할 수 있다.The present invention solves this melting problem by bonding interlock fabrics, single-pique fabrics or napping fabrics onto the laminate film. That is, by adhering a cloth interlock fabric, a single peak fabric or brushed fabric woven on a waterproof-breathable laminate film, the surface of the drying frame heated at a high temperature does not come into direct contact with the laminate film but comes into contact with the interlock fabric do. As a result, the heat of the mold for drying can be prevented from being directly transferred to the laminate film, thereby preventing melting.
상기 베이스원단은 데님원단일 수 있다. The base fabric may be a denim fabric.
데님의 경우 다른 원단과는 달리 탈색이 이루어진 빈티지 스타일을 선호하는 경향이 있다. 이를 위해 옷의 특정 부위를 탈색하거나 심지어 마모시키기도 한다. In the case of denim, unlike other fabrics, there is a tendency to prefer vintage style with discoloration. For this purpose, certain areas of the garment may be discolored or even worn.
본 발명의 베이스원단으로 데님원단이 이용될 경우 베이스원단의 전체적인 탈색을 통해 빈티지한 디자인을 구성할 수 있도록 상기 라미네이트 필름을 부착하고 인터록, 싱글피크 또는 기모원단을 접착한 베이스원단을 5 내지 30 중량%의 염산 또는 하이포클로라이트 수용액에 침지시키고, 10 내지 30분 동안 교반한 후 건조한다. When the denim fabric is used as the base fabric of the present invention, the laminate film is attached so that a vintage design can be formed through the overall decolorization of the base fabric, and the base fabric adhered to the interlock, single peak or brushed fabric is laminated by 5 to 30 weight % Hydrochloric acid or hypochlorite solution, stirring for 10 to 30 minutes and then drying.
나아가, 상기 염산 또는 소듐 하이포클로라이트 수용액에 침지 후 건조한 다음 베이스원단을 다시 5 내지 30 중량%의 소듐 하이드레이트, 소듐 퍼카보네이트 또는 아세트산 수용액에 침지한 후, 10 내지 40분 동안 교반 후 건조할 수도 있다. Further, after immersing in the aqueous solution of hydrochloric acid or sodium hypochlorite, the base fabric is immersed again in an aqueous solution of 5 to 30% by weight of sodium hydrate, sodium percarbonate or acetic acid, followed by stirring for 10 to 40 minutes .
상기 탈색과정까지 거친 베이스원단은 은 코팅층 함유 실리카 나노분발에 침지하여 항균성을 부가할 수 있다. The base fabric may be immersed in the silver nanofibers containing the silver coating layer to add antimicrobial properties to the discoloration process.
상기 은 코팅층 함유 실리카 나노분말은 촉매존재 하에서 실리콘 알콕사이드를 알코올 용매 내에서 반응시켜 75nm 내지 150nm의 평균 입경을 갖는 실리카 입자를 형성한 후, 상기 실리카 입자를 알코올 용매 내에서 은 전구체와 혼합하고 환원제를 첨가하여 상기 은 전구체를 환원시켜 상기 실리카 입자의 표면상에 은 코팅층을 형성한 것이다. The silica nanopowder containing the silver coating layer is prepared by reacting the silicon alkoxide in the presence of a catalyst in the presence of a catalyst to form silica particles having an average particle size of 75 nm to 150 nm and then mixing the silica particles with the silver precursor in an alcohol solvent, And the silver precursor is reduced to form a silver coating layer on the surface of the silica particles.
상기 기술 내용은 촉매 존재하에서 실리콘 알콕사이드르 알코올 용매에 적당한 온도에서 일정시간 동안 반응시켜 100~150nm의 평균 입경을 갖는 실리카 입자를 형성하는 단계 및 상기 실리카 입자를 알코올 용매에 은이온 전구체 및 금속염과 혼합하고 환원제를 첨가한 후 적당한 온도에서 일정시간 동안 반응시켜 상기 실리카 입자의 표면상에 코팅을 형성한다.The method includes reacting a silicon alkoxide alcohol in a solvent in the presence of a catalyst at a suitable temperature for a predetermined period of time to form silica particles having an average particle size of 100 to 150 nm and mixing the silica particles with a silver ion precursor and a metal salt And a reducing agent is added thereto, followed by reaction at a suitable temperature for a certain period of time to form a coating on the surface of the silica particles.
상기 과정을 거친 본 발명의 베이스원단은 방수성 및 항균성이 부가되어 겨울철 실외활동을 위한 방한복, 스키복 등의 제작을 위한 원단으로도 활용할 수 있다. The base fabric of the present invention, which has undergone the above-described process, can be used as a fabrics for producing winter clothes, ski suits, etc. for outdoor activities during the winter by adding waterproof and antibacterial properties.
제시된 실시예들에 대한 설명은 임의의 본 발명의 기술분야에서 통상의 지식을 가진 자가 본 발명을 이용하거나 또는 실시할 수 있도록 제공된다. 이러한 실시예들에 대한 다양한 변형들은 본 발명의 기술 분야에서 통상의 지식을 가진자에게 명백할 것이며, 여기에 정의된 일반적인 원리들은 본 발명의 범위를 벗어남이 없이 다른 실시예들에 적용될 수 있다. 그리하여, 본 발명은 여기에 제시된 실시예들로 한정되는 것이 아니라, 여기에 제시된 원리들 및 신규한 특징들과 일관되는 최광의의 범위에서 해석되어야 할 것이다.The description of the disclosed embodiments is provided to enable any person skilled in the art to make or use the present invention. Various modifications to these embodiments will be readily apparent to those skilled in the art, and the generic principles defined herein may be applied to other embodiments without departing from the scope of the invention. Thus, the present invention is not intended to be limited to the embodiments shown herein but is to be accorded the widest scope consistent with the principles and novel features presented herein.
본 발명은 방수성을 갖는 의류 제작을 위한 원단의 제조에 적용되는 기술로서, 산업상 이용가능성이 높다. INDUSTRIAL APPLICABILITY The present invention is applied to the production of a fabric for producing a waterproof garment and is highly industrially applicable.

Claims (7)

  1. (A) 베이스원단의 일면에 라미네이트 필름을 부착하는 단계;(A) attaching a laminate film to one side of a base fabric;
    (B) 상기 부착된 라미네이트 필름 위에 인터록 원단, 싱글 피크(pique) 원단 또는 기모(napping) 원단을 접착시키는 단계;(B) bonding an interlock fabric, a single pique fabric, or a napping fabric onto the laminated film;
    (C) 상기 제작된 옷을 은 코팅층 함유 실리카 나노분말에 10 내지 40분 동안 침지한 후 꺼내어 건조하는 단계를 포함하는(C) immersing the fabricated clothes in a silver nanopowder containing silver coating for 10 to 40 minutes, and then taking out and drying
    항균기능을 갖는 방수원단의 제조방법.A method for producing a waterproof fabric having an antibacterial function.
  2. 제 1항에 있어서,The method according to claim 1,
    상기 은 코팅층 함유 실리카 나노분말은The silver nanopowder containing the silver coating layer
    촉매 존재 하에서 실리콘 알콕사이드를 알코올 용매 내에서 반응시켜 75nm 내지 150nm의 평균 입경을 갖는 실리카 입자를 형성한 후, 상기 실리카 입자를 알코올 용매 내에서 은 전구체와 혼합하고 환원제를 첨가하여 상기 은 전구체를 환원시켜 상기 실리카 입자의 표면상에 은 코팅층을 형성하여 형성된 것을 특징으로 하는 Reacting the silicon alkoxide in an alcohol solvent in the presence of a catalyst to form silica particles having an average particle diameter of 75 to 150 nm, mixing the silica particles with a silver precursor in an alcohol solvent, and adding a reducing agent to reduce the silver precursor And a silver coating layer is formed on the surface of the silica particles
    항균기능을 갖는 방수원단의 제조방법.A method for producing a waterproof fabric having an antibacterial function.
  3. 제 1항에 있어서,The method according to claim 1,
    상기 단계 (B) 이후 단계 (C) 이전에,Prior to step (B) and after step (C)
    (D) 상기 제작된 원단을 염산 또는 소듐 하이포클로라이트 수용액에 10 내지 30분 동안 침지한 후 꺼내어 건조하는 단계를 더 포함하는 것을 특징으로 하는 (D) further comprising the step of immersing the prepared fabric in an aqueous solution of hydrochloric acid or sodium hypochlorite for 10 to 30 minutes, followed by taking out and drying
    항균기능을 갖는 방수원단의 제조방법.A method for producing a waterproof fabric having an antibacterial function.
  4. 제 3항에 있어서,The method of claim 3,
    상기 단계 (D) 직후에,Immediately after the step (D)
    (E) 상기 건조된 원단을 소듐 하이드레이트, 소듐 퍼카보네이트 또는 아세트산 용액에 10 내지 40 분 동안 침지한 후 꺼내어 건조하는 단계를 더 포함하는 것을 특징으로 하는 (E) further comprising the step of immersing the dried fabric in a sodium hydrate, sodium percarbonate or acetic acid solution for 10 to 40 minutes, followed by taking out and drying
    항균기능을 갖는 방수원단의 제조방법.A method for producing a waterproof fabric having an antibacterial function.
  5. 제 1항에 있어서,The method according to claim 1,
    상기 라미네이트 필름은 천 사이에 불소계 합성수지 박막이 개재된 것을 특징을 하는Wherein the laminated film is characterized in that a thin film of fluorinated synthetic resin is interposed between the cloths
    항균기능을 갖는 방수원단의 제조방법.A method for producing a waterproof fabric having an antibacterial function.
  6. 제 5항에 있어서,6. The method of claim 5,
    상기 불소계 합성수지 박막은 폴리테트라플루오로에틸렌, 폴리플루오르화비닐리덴, 및 그 혼합물로 이루어진 군에서 선택된 중합체의 박막인 것을 특징으로 하는Wherein the fluorine-based synthetic resin thin film is a thin film of a polymer selected from the group consisting of polytetrafluoroethylene, polyvinylidene fluoride, and mixtures thereof
    항균기능을 갖는 방수원단의 제조방법.A method for producing a waterproof fabric having an antibacterial function.
  7. 제 1항에 있어서,The method according to claim 1,
    상기 라미네이트 필름은 천 사이에 폴리산화에틸렌을 포함한 폴리에스테르 또는 폴리우레탄 박막이 개재된 것을 특징으로 하는Wherein the laminate film is characterized in that a polyester or polyurethane thin film including poly ethylene oxide is interposed between the cloths
    항균기능을 갖는 방수원단의 제조방법.A method for producing a waterproof fabric having an antibacterial function.
PCT/KR2017/015786 2017-12-28 2017-12-29 Method for manufacturing waterproof fabric having antibacterial function WO2019132089A1 (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2022057587A1 (en) * 2020-09-16 2022-03-24 苏州经结纬面料科技有限公司 Device for preparing breathable fiber fabric and preparation method therefor

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100806915B1 (en) * 2006-10-10 2008-02-22 요업기술원 Silver coated silica, method of making the same, and products using the same
KR101063540B1 (en) * 2008-03-17 2011-09-07 (주)에이씨티 Manufacturing method of silica nano powder containing silver coating layer
KR20120049579A (en) * 2010-11-09 2012-05-17 박승권 Environmental-friendly treating agent of textiles and the textiles treated by the agent and treating method thereof
KR101218248B1 (en) * 2011-07-21 2013-01-03 김성훈 Manufacturing method of waterproof and water repelling denim clothes
KR101452785B1 (en) * 2014-01-14 2014-10-22 유봉옥 Functional suits having a functions of far infrared rarys radiation and antimicrobial

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100297999B1 (en) 1999-05-24 2001-10-18 김영철 Processing method of whisker of the jeans

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100806915B1 (en) * 2006-10-10 2008-02-22 요업기술원 Silver coated silica, method of making the same, and products using the same
KR101063540B1 (en) * 2008-03-17 2011-09-07 (주)에이씨티 Manufacturing method of silica nano powder containing silver coating layer
KR20120049579A (en) * 2010-11-09 2012-05-17 박승권 Environmental-friendly treating agent of textiles and the textiles treated by the agent and treating method thereof
KR101218248B1 (en) * 2011-07-21 2013-01-03 김성훈 Manufacturing method of waterproof and water repelling denim clothes
KR101452785B1 (en) * 2014-01-14 2014-10-22 유봉옥 Functional suits having a functions of far infrared rarys radiation and antimicrobial

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2022057587A1 (en) * 2020-09-16 2022-03-24 苏州经结纬面料科技有限公司 Device for preparing breathable fiber fabric and preparation method therefor

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