WO2019117678A1 - Élément décoratif - Google Patents

Élément décoratif Download PDF

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Publication number
WO2019117678A1
WO2019117678A1 PCT/KR2018/015943 KR2018015943W WO2019117678A1 WO 2019117678 A1 WO2019117678 A1 WO 2019117678A1 KR 2018015943 W KR2018015943 W KR 2018015943W WO 2019117678 A1 WO2019117678 A1 WO 2019117678A1
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WO
WIPO (PCT)
Prior art keywords
layer
light
decorative member
light absorbing
color
Prior art date
Application number
PCT/KR2018/015943
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English (en)
Korean (ko)
Inventor
김용찬
김기환
허난슬아
손정우
송진숙
조필성
Original Assignee
주식회사 엘지화학
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Priority claimed from KR1020180088857A external-priority patent/KR102201578B1/ko
Application filed by 주식회사 엘지화학 filed Critical 주식회사 엘지화학
Priority to US16/767,944 priority Critical patent/US20200290311A1/en
Priority to CN201880080476.7A priority patent/CN111479682B/zh
Priority to JP2020529449A priority patent/JP7024941B2/ja
Priority to EP18888203.9A priority patent/EP3725505A4/fr
Publication of WO2019117678A1 publication Critical patent/WO2019117678A1/fr

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/28—Layered products comprising a layer of synthetic resin comprising synthetic resins not wholly covered by any one of the sub-groups B32B27/30 - B32B27/42
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B3/00—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar form; Layered products having particular features of form
    • B32B3/26—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar form; Layered products having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer
    • B32B3/30—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar form; Layered products having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer characterised by a layer formed with recesses or projections, e.g. hollows, grooves, protuberances, ribs
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/02—Physical, chemical or physicochemical properties

Definitions

  • the present application relates to a decorative member.
  • Cosmetic containers, various mobile devices, and home appliances have a great role in designing products, such as color, shape, pattern, etc., of products other than the functions of products, to give value to customers. Depending on the design, the preference and price of the product are also influenced.
  • the conventional deco film color development was attempted through printing, deposition, and the like. If different colors are expressed on a single plane, they must be printed more than twice, and it is difficult to implement them when various colors are to be applied to a three-dimensional pattern.
  • the conventional deco film has a fixed color depending on viewing angles, and even if there is a slight change, it is limited to the degree of color difference.
  • the present application provides a decorative member.
  • the present invention relates to a color reproduction layer comprising a light reflection layer and a light absorption layer provided on the light reflection layer; And a base material provided on one side of the color developing layer and including a pattern layer,
  • the light absorbing layer comprises aluminum oxynitride (Al a O b N c )
  • T x is represented by the formula (2)
  • ⁇ x is represented by the formula (3)
  • T 1 is the thickness of the light absorbing layer including one point of the light absorbing layer subjected to the component analysis, silver , T 0 is 100 nm,
  • a represents an element content ratio of aluminum (Al)
  • b represents an element content ratio of oxygen (O)
  • c represents an element content ratio of nitrogen (N).
  • the decorative member according to one embodiment of the present invention may include a color tone of cool tone as it includes aluminum oxynitride but includes a light absorbing layer whose content of each element is adjusted to a specific ratio.
  • the present application provides a decorative member having a dichroic property that exhibits a different color depending on a viewing direction and has improved dichroism and visibility.
  • FIG. 1 shows a decorative member according to an embodiment of the present invention.
  • FIG. 2 shows a method of distinguishing a light absorbing layer from a light reflecting layer.
  • Fig. 3 shows one point of the light absorbing layer and the thickness of the light absorbing layer including the same.
  • Fig. 4 illustrates the principle of interference of light in the light absorbing layer and the light reflection layer.
  • 5 to 13 show decorative members according to an embodiment of the present invention.
  • Figs. 14 to 31 show patterns of the pattern layer.
  • Fig. 34 shows the color change according to the thickness of the decorative member in the experimental example.
  • Figure 35 shows a graph for Equation 2A.
  • the term " layer " means that at least 70% of the area in which the layer is present is covered. , Preferably at least 75%, more preferably at least 80%.
  • the "thickness" of any layer means the shortest distance from the lower surface to the upper surface of the layer.
  • the hue represented by the decorative member can be defined by the spectral characteristics of the light source, the reflectance of the object, and the color vision sensitivity efficiency of the observer.
  • the color of the decorative member may be represented by CIE Lab (L * a * b *) coordinates or LCh coordinates that provide a visually uniform color space.
  • L * represents brightness
  • + a * represents redness
  • -a * represents greenness
  • + b * represents yellowness
  • -b * represents blueness
  • C * and h * will be described later.
  • the total color difference according to the observation position in the color space is . ≪ / RTI >
  • the color measurement can be performed by using a spectrophotometer (CM-2600d, manufactured by Konica Minolta).
  • CM-2600d manufactured by Konica Minolta
  • the spectral reflectance of the sample can be measured by a spectrophotometer, and the reflectance of each wavelength can be expressed. From the spectral reflectance graph and the converted color coordinates . At this time, the data is obtained at an 8-degree viewing angle and measured in the horizontal direction and the vertical direction with respect to the decorative member to see the dichroism of the decorative member.
  • the viewing angle is an angle formed by a straight line d1 in the normal direction of the color developing layer surface of the decorative member and a straight line d2 passing through the spectrophotometer and one point of the decorative member to be measured, And has a range of 0 to 90 degrees.
  • the viewing angle When the viewing angle is 0 degree, it means that the viewing angle is measured in the same direction as the normal direction of the surface of the color developing layer of the decorative member.
  • the "light absorbing layer” and the “light reflecting layer” are layers having relative physical properties
  • the light absorbing layer means a layer having a higher light absorbing property than the light reflecting layer, It can mean a layer having high light reflectivity.
  • Each of the light absorbing layer and the light reflecting layer may be composed of a single layer, or may be composed of two or more layers.
  • the light absorbing layer and the light reflecting layer are named according to their functions. With respect to light having a specific wavelength, a layer that reflects a relatively large amount of light can be expressed by a light reflecting layer, and a layer that reflects light with relatively little light can be expressed by a light absorbing layer.
  • Fig. 1 illustrates a laminated structure of a decorative member according to an embodiment of the present invention.
  • Fig. 1 shows a decorative member including the color developing layer 100 and the substrate 101.
  • the color developing layer (100) includes a light reflecting layer (201) and a light absorbing layer (301). 1 shows that the substrate 101 is provided on the light absorbing layer 301 side of the color developing layer 100, it may be provided on the light reflecting layer 201 side.
  • each layer is laminated in the order of L i-1 layer, L i layer and L i + 1 layer in the order of the incoming light, and between the L i-1 layer and the L i layer
  • the interface I i is located, and the interface I i + 1 is located between the L i layer and the L i + 1 layer.
  • the reflectance at the interface I i can be expressed by the following equation (1) when light having a specific wavelength is irradiated in a direction perpendicular to each layer so that thin film interference does not occur.
  • K i ( ⁇ ) is an extinction coefficient according to the wavelength ⁇ of the i-th layer
  • n i ( ⁇ ) denotes a refractive index according to the wavelength ⁇ of the i-th layer, .
  • the extinction coefficient is a measure to define how strongly an object absorbs light at a specific wavelength, and the definition is as described above.
  • Equation (2) When the sum of the reflectances of the respective wavelengths at the interface I i calculated at each wavelength is defined as R i by applying Equation (1), R i is represented by Equation (2) below.
  • the decorative member including the light reflection layer and the light absorption layer will be described.
  • the present invention relates to a color reproduction layer comprising a light reflection layer and a light absorption layer provided on the light reflection layer; And a base material provided on one side of the color developing layer and including a pattern layer,
  • the light absorbing layer comprises aluminum oxynitride (Al a O b N c )
  • T x is represented by the formula (2)
  • ⁇ x is represented by the formula (3)
  • T 1 is the thickness of the light absorbing layer including one point of the light absorbing layer subjected to the component analysis, silver , T 0 is 100 nm,
  • a represents an element content ratio of aluminum (Al)
  • b represents an element content ratio of oxygen (O)
  • c represents an element content ratio of nitrogen (N).
  • the content of a specific element may refer to an atomic percent (atomic percent) of a specific element at a certain point in the light absorption layer subjected to the component analysis.
  • the decorative member according to one embodiment of the present invention is characterized in that the light absorbing layer contains aluminum oxynitride (Al a O b N c ), the content ratio of each element of aluminum oxynitride is adjusted, and the thickness of the light absorbing layer is set to a specific range By adjusting, a cool tone can be observed through the light absorbing layer.
  • a cool tone parameter ⁇ expressed by the following equation (1). Kulton the parameter ⁇ may be expressed as ⁇ c.
  • the subscript c of ⁇ c means cool tone.
  • ⁇ represented by the formula 1 is 0.81 or more, preferably 0.81 or more and 1.5 or less, more preferably 0.81 or more and 1.3 or less, at any one point (x) .
  • a cool color cool tone
  • the user can easily express a desired color among cold colors.
  • the 'one point of the light absorption layer' may mean a point on the surface or inside of the light absorption layer.
  • T x is a thickness parameter expressed by the following equation (2).
  • Light absorption layer appear alternately hot and cold color (womton, warm tone) or cold color (kulton, cool tone) according to the thickness change, the color change appears to have a constant cycle (T 0) thickness.
  • Tx may mean the ratio of the light absorbing layer thickness (T 1 ) at a certain point to a certain period (T 0 ) of the thickness of the light absorbing layer. For example, if a constant period of thickness is 100 nm, the Tx value when the thickness of the light absorption layer is 70 nm, 170 nm and 270 nm is equal to 0.7.
  • equation (2) can be expressed by the following equation (2A).
  • T x is the function value of the T 1 of the function represented by the f (T 1), n is high in one or more positive integer, T 1 is one of the light absorbing layer subjected to the composition analysis The thickness of the light absorbing layer including one point, and T 0 is 100 nm.
  • T 1 is the thickness of the light absorbing layer including one point of the light absorbing layer.
  • T 1 denotes the thickness of the light absorbing layer including one point when one point of the light absorbing layer is selected.
  • SEM scanning electron microscope
  • AlON aluminum oxynitride
  • a, b, and c are the same or different from each other, and each may have a value of more than 0 and less than 1.
  • the thickness T 1 may mean the length in the direction of the surface of the light absorbing layer in the cross section in the direction perpendicular to the surface direction of the light absorbing layer, including any one point of the light absorbing layer.
  • FIG. 3 shows a method of determining one point and thickness of the light absorbing layer.
  • the content ratio parameter represented by the formula (3) is calculated through the analysis of the component at this point,
  • the thickness (T 1 ) can be calculated by calculating the width of the in-line segment.
  • T 1 can be achieved by adjusting the process pressure used for deposition in forming the light absorbing layer, the flow rate of the reactive gas to the plasma gas, the voltage, the deposition time, or the temperature.
  • silver Lt; / RTI > [x] is a Gaussian symbol commonly used in the field to which this technique belongs, or in mathematics, and means the maximum integer not exceeding x.
  • T 0 can be expressed as "kulton the period of the thickness of the light absorption repeated,".
  • the thickness T 1 of the light absorption layer is 100 nm or less, and the Tx can be expressed by the following formula 2-1.
  • Tx T 1 / T 0
  • T 1 and T 0 are as shown in the formula 2.
  • a represents an element content ratio of aluminum (Al)
  • b represents an element content ratio of oxygen (O)
  • c represents an element content ratio of nitrogen (N).
  • the elemental content ratio of each element of the light absorbing layer can be measured by a method commonly used in the field to which the present invention belongs, and X-ray photoelectron spectroscopy (XPS) or electron spectroscopy Chemical Analysis: ESCA, Thermo Fisher Scientific Inc.).
  • the transmission X-ray analysis may be the X-ray photoelectron spectroscopy.
  • the thickness parameter Tx may be 0.51 or more and 1 or less, preferably 0.55 or more and 0.95 or less, more preferably 0.6 or more and 0.9 or less.
  • the Tx of 1 means that T 1 corresponds to a numerical value obtained by multiplying T 0 by an integer. For example, when T 1 is 100 nm, 200 nm or 300 nm
  • the content ratio parameter x may be 1.1 or more and 1.9 or less, preferably 1.2 or more and 1.8 or less, more preferably 1.2 or more and 1.7 or less.
  • the cool color (cool tone) in the decorative member can be more clearly observed.
  • the ratio between the elements can be achieved by adjusting the gas fraction at the time of aluminum oxynitride deposition.
  • a survey scan is performed on the surface and thickness direction of the light absorption layer using X-ray photoelectron spectroscopy (XPS) or electron spectroscopy for chemical analysis (ESCA, Thermo Fisher Scientific Inc.) After qualitative analysis, proceed with quantitative analysis with narrow scan. At this time, a survey scan and a narraw scan are performed under the conditions shown in Table 1, and qualitative and quantitative analysis are performed. Peak background uses smart method.
  • XPS X-ray photoelectron spectroscopy
  • ESA electron spectroscopy for chemical analysis
  • the component analysis can be performed by preparing a light absorption layer slice having the same composition as that of the light absorption layer before laminating the decorative member.
  • the decorative member has the structure of the substrate / pattern layer / light reflecting layer / light absorbing layer
  • the outermost part of the decorative member can be analyzed by the above-described method.
  • the light absorbing layer can be confirmed visually by observing a cross-sectional photograph of the decorative member. For example, in the case where the decorative member has the structure of the substrate / pattern layer / light reflection layer / light absorption layer, it can be confirmed that the interface exists between the respective layers in the cross-sectional photograph of the decorative member, wherein the outermost layer corresponds to the light absorption layer .
  • the hue angle h * in the CIE LCh color space of the light absorbing layer is in the range of 105 to 315, in the range of 120 to 300, 135 Lt; 0 > to 300 [deg.], 150 [deg.] To 300 [deg.], Or 200 [
  • L in the CIE LCh color space of the light absorbing layer may be 0 to 100, or 30 to 100.
  • C in the CIE LCh color space of the light absorbing layer may be from 0 to 100, from 1 to 80, or from 1 to 60.
  • the CIE LCh color space is a CIE Lab color space, where cylinder coordinates C * (saturation, relative color saturation (relative color saturation) instead of a *, b * of Cartesian coordinates saturation), distance from the L axis) and h * (hue angle, hue angle in the CIE Lab color circle) were used.
  • the light absorbing layer preferably has a refractive index (n) of 0 to 8 at a wavelength of 400 nm, may be 0 to 7, may be 0.01 to 3, and may be 2 to 2.5 .
  • the refractive index n can be calculated by sin ⁇ a / sin ⁇ b (where ⁇ is the angle of light incident on the surface of the light absorbing layer and ⁇ b is the refracting angle of light within the light absorbing layer).
  • the light absorbing layer preferably has a refractive index (n) of 0 to 8 at a wavelength of 380 to 780 nm, may be 0 to 7, may be 0.01 to 3, Lt; / RTI >
  • the light absorption layer has an extinction coefficient (k) of more than 0 and less than 4 at a wavelength of 400 nm, preferably 0.01 to 4, may be 0.01 to 3.5, may be 0.01 to 3 , 0.1 to 1.
  • the extinction coefficient k is a value obtained by multiplying the reduction unit dI / I of the intensity of light per 1 m, i.e., the path unit length dx in the light absorption layer, by lambda / 4 pi, Where ⁇ is the wavelength of light.
  • the light absorption layer has an extinction coefficient (k) of more than 0 and less than 4, preferably 0.01 to 4, more preferably 0.01 to 3.5, in a wavelength range of 380 to 780 nm, 3, and may be from 0.1 to 1. Since the extinction coefficient (k) in the entire wavelength range of visible light of 400 nm, preferably 380 to 780 nm is within the above range, it can serve as a light absorbing layer within the visible light range.
  • the principle that the light absorbing layer having the specific extinction coefficient and the refractive index express color and the color expression principle of the decorative member which expresses the color by adding the dye to the conventional substrate are different.
  • a method of absorbing light by adding a dye to a resin is used, and when a material having the extinction coefficient as described above is used, the spectrum that absorbs light differs.
  • the absorption wavelength band is fixed and only the absorption amount changes depending on the change in coating thickness.
  • a thickness variation of at least several micrometers is necessary in order to adjust the light absorption amount.
  • the wavelength range of light to be absorbed varies even if the thickness changes to several tens or nanometers scale.
  • the light absorbing layer of the present invention has an advantage that various colors can be exhibited by a light interference phenomenon without adding a dye by using a specific material other than a resin.
  • Fig. 4 shows a schematic diagram of such a working principle. 4 shows a structure in which the substrate 101 is provided on the light reflection layer 201 side. However, the structure is not limited to such a structure, and the positions of the substrate 101 may be arranged at different positions.
  • the light absorbing layer may be a single layer, or may be a multilayer of two or more layers.
  • the light absorbing layer may further include one or two or more selected from the group consisting of a metal, a metalloid, and an oxide, a nitride, an oxynitride and a carbide of a metal or a metalloid.
  • the oxide, nitride, oxynitride or carbide of the metal or metalloid can be formed by deposition conditions set by a person skilled in the art.
  • the light absorbing layer may contain the same metal, semi-metal, two or more kinds of alloys or oxynitrides as the light reflecting layer.
  • the thickness T 1 of the light absorbing layer may be determined according to a desired color in the final structure, and may be, for example, 1 nm or more and 300 nm or less, 51 nm or more and 100 nm or less, 151 nm or more and 200 nm or less, .
  • the light reflection layer is not particularly limited as long as it is a material capable of reflecting light, but the light reflectance can be determined depending on the material, and it is easy to implement colors at a light reflectance of 50% or more, for example.
  • the light reflectance can be measured using an ellipsometer.
  • the light reflecting layer may be a metal layer, a metal oxide layer, a metal nitride layer, a metal oxynitride layer, or an inorganic layer.
  • the light reflection layer may be formed of a single layer, or may be composed of two or more layers.
  • the light reflection layer is formed of a material selected from the group consisting of indium (In), titanium (Ti), tin (Sn), silicon (Si), germanium (Ge), aluminum (Al) Ni, vanadium, tungsten, tantalum, molybdenum, neodymium, iron, chromium, cobalt, gold and silver, Ag); Oxides thereof; Its nitride; Its oxynitrides; carbon; And a carbon composite material.
  • the carbon nanofibers of the present invention can be used alone or in combination of two or more.
  • the light reflection layer may comprise two or more alloys selected from the above materials, oxides thereof, nitrides or oxynitrides.
  • the light reflecting layer is manufactured using an ink containing a carbon or carbon composite, thereby realizing a high-resistance reflecting layer.
  • the carbon or carbon composite include carbon black and CNT.
  • the ink comprising the carbon or carbon composite material may include the above-described materials or oxides, nitrides or oxynitrides thereof, such as indium (In), titanium (Ti), tin ), Silicon (Si), germanium (Ge).
  • Aluminum, aluminum, copper, nickel, vanadium, tungsten, tantalum, molybdenum, neodymium, iron, chromium, One or more oxides selected from cobalt (Co), gold (Au), and silver (Ag) may be included.
  • two or more kinds of materials may be formed by one process, for example, a deposition or printing method
  • a method may be used in which a layer is formed first and then a layer is formed thereon with one or more kinds of materials.
  • an ink containing carbon may be printed and cured to form a light reflection layer.
  • the ink may further include an oxide such as titanium oxide or silicon oxide.
  • the thickness of the light reflection layer can be determined according to a desired color in the final structure, for example, 1 nm or more, 25 nm or more, 50 nm or more, and preferably 70 nm or more.
  • the light absorbing layer may exhibit various shapes by adjusting deposition conditions and the like at the time of forming the light absorbing layer.
  • the light absorbing layer includes two or more points having different thicknesses.
  • the light absorbing layer includes two or more regions having different thicknesses.
  • the light absorbing layer may include an inclined surface.
  • Fig. 5 and 6 illustrate a structure in which the light reflection layer 201 and the light absorption layer 301 are laminated (not shown).
  • the light absorbing layer 301 has two or more points having different thicknesses from each other.
  • the thickness of the light absorbing layer 301 at the point A and the point B is different.
  • the thickness of the light absorbing layer 301 in the C region and the D region is different.
  • the light absorbing layer includes at least one region having an inclined surface whose top surface has an inclination angle of more than 0 degrees and not more than 90 degrees, and the light absorbing layer has a thickness different from that of the region having any one of the inclined surfaces And at least one region having a thickness.
  • the inclined surface can be defined as an angle formed by a straight line included in the upper surface of the light absorbing layer and a straight line parallel to the light reflecting layer.
  • the inclination angle of the upper surface of the light absorption layer in Fig. 5 may be about 20 degrees.
  • the surface characteristics such as the inclination of the upper surface of the light reflecting layer may be the same as the upper surface of the light absorbing layer.
  • the upper surface of the light absorbing layer may have the same inclination as the upper surface of the light reflecting layer by using the vapor deposition method when forming the light absorbing layer.
  • the inclination of the upper surface of the light absorbing layer of Fig. 5 is different from the inclination of the upper surface of the light reflecting layer.
  • Fig. 7 illustrates the structure of a decorative member having a light absorbing layer whose top surface has an inclined surface.
  • the thickness t1 of the light absorbing layer 301 in the E region and the thickness t2 in the F region are different from each other in the structure in which the substrate 101, the light reflecting layer 201 and the light absorbing layer 301 are laminated.
  • Reference numeral 401 may be a color film.
  • Fig. 7 relates to a light absorbing layer having a sloped surface facing each other, that is, a triangular section.
  • the thickness of the light absorbing layer may be varied on two surfaces of the triangular structure even if the deposition proceeds under the same conditions in the structure of the pattern having the inclined surfaces facing each other.
  • a light absorbing layer having two or more regions having different thicknesses can be formed by only one step.
  • the color hue differs depending on the thickness of the light absorbing layer.
  • the thickness of the light reflecting layer is more than a predetermined value, the color change is not affected.
  • the structure is not limited to this structure, and the positions of the substrate 101 may be arranged at different positions as described above .
  • the difference in the thickness of the light absorbing layer may also be caused by the difference in the inclination of the pattern of the base material.
  • the present invention is not limited to this, and even if the substrate and the light absorbing layer have different slopes by using another vapor deposition method, the thickness of the light absorbing layer may be different on both sides of the pattern, and the dichroism described later can be exhibited.
  • the light absorbing layer includes at least one region whose thickness gradually changes. 9 illustrates a structure in which the thickness of the light absorbing layer 301 is gradually changed.
  • the light absorbing layer includes at least one region having an inclined surface whose top surface has an inclination angle of more than 0 degrees and not more than 90 degrees, and at least one of the regions having the inclined surfaces has a progressive .
  • Fig. 9 illustrates the structure of the light absorbing layer including a region having a sloped upper surface. Both the G region and the H region in Fig. 9 have a structure in which the upper surface of the light absorbing layer has an inclined surface and the thickness of the light absorbing layer gradually changes.
  • the structure in which the thickness of the light absorbing layer is changed means that the cross section in the thickness direction of the light absorbing layer includes the point where the thickness of the light absorbing layer is the smallest and the thickness of the light absorbing layer is the largest, The thickness of the light absorbing layer increases with the direction of the light absorbing layer where the thickness of the light absorbing layer is the smallest.
  • the point where the thickness of the light absorption layer is the smallest and the point where the thickness of the light absorption layer is the largest may be any point on the interface with the light reflection layer of the light absorption layer.
  • the light absorbing layer includes a first region having a first inclined face whose inclination angle is within a range of 1 degree to 90 degrees, and the upper face is different from the first inclined face in the oblique direction, May have different inclined planes, or may further include two or more areas whose top surfaces are horizontal. At this time, the thicknesses of the light absorbing layers in the first region and the two or more regions may be different from each other.
  • the decorative member includes a substrate provided on one side of the color developing layer and including a pattern layer.
  • the opposite surface of the light reflection layer opposite to the light absorption layer Fig. 10 (a)
  • the substrate may be provided on the opposite side of the surface of the light absorbing layer facing the light reflection layer (Fig. 10 (b)).
  • the substrate may comprise a plastic substrate or a glass substrate for a cosmetic container.
  • the plastic molded article may be formed of at least one of polypropylene (PP), polystyrene (PS), polyvinyl acetate (PVAc), polyacrylate, polyethylene terephthalate (PET), polyvinyl chloride (PVA), ethylene-vinyl acetate copolymer (EVA), polycarbonate (PC), polyamide, and styrene-acrylonitrile copolymer But is not limited thereto.
  • the plastic molded article may be a flat plate-shaped plastic molded article having no bending (specific pattern), or may be a plastic molded article having a bending (specific pattern) shape.
  • the plastic injection can be produced by a plastic molding method.
  • the plastic molding method includes compression molding, injection molding, air blow molding, thermoforming, hot melt molding, foam molding, and roll molding reinforced plastic molding.
  • compression molding the material is put into a mold, heated, and then pressure is applied.
  • This is the oldest molding method and can be mainly used for molding a thermosetting resin such as phenol resin.
  • the injection molding is a molding method in which a plastic melt is pushed out by a transporting machine and filled in a mold through a nozzle, and both of a thermoplastic resin and a thermosetting resin can be molded, which is the most widely used molding method.
  • resin used in cosmetic case is SAN.
  • the air blow molding is a method of molding a product by injecting air into a plastic parison at the center of the mold, and the production speed of the product is very fast due to a molding method of forming a plastic bottle or a small container.
  • the glass substrate may be glass having a transmittance of 80% or more.
  • the thickness of the substrate may be selected as required, and may range, for example, from 50 ⁇ to 200 ⁇ .
  • the decorative member can be manufactured by forming a light reflecting layer on the substrate and a light absorbing layer provided on the light reflecting layer. More specifically, the decorative member can sequentially form a light absorbing layer and a light reflecting layer on a substrate by using a vapor deposition process or the like, and sequentially form a light reflecting layer and a light absorbing layer on the substrate using a vapor deposition process or the like But is not limited thereto.
  • the color developing layer further includes a color film.
  • the decorative member is a surface opposite to a surface of the light absorbing layer facing the light reflecting layer; Between the light absorbing layer and the light reflecting layer; Or a color film on the opposite surface of the light reflection layer against the light absorption layer.
  • the color film may serve as a substrate.
  • it can be used as a color film by adding a dye or pigment to what can be used as a substrate.
  • the color film has L * a * b * on the color coordinate CIE L * a * b * of the color developing layer when the color film is present compared to the case where the color film is not provided Is not particularly limited as long as the color difference DELTA E * ab, which is the distance in the space of *
  • the color representation can be expressed as CIE L * a * b *, and the color difference can be defined using the distance ( ⁇ E * ab) in the L * a * b * space. Specifically, , And the observer can not recognize the color difference within the range of 0 ⁇ DELTA E * ab ⁇ 1 (Reference: Machine Graphics and Vision 20 (4): 383-411). Therefore, in this specification, the color difference due to the addition of the color film can be defined as DELTA E * ab > 1.
  • FIG. 11 shows a color reproduction layer including a color film.
  • FIG. 11A shows a structure in which a light reflection layer 201, a light absorption layer 301 and a color film 401 are sequentially laminated.
  • the substrate is provided on the opposite surface of the light reflecting layer opposite to the light absorbing layer, and the color film is located on the opposite surface of the light reflecting layer opposite to the light absorbing layer , The color film is formed between the substrate and the light reflection layer; Or on the opposite surface of the substrate facing the light reflection layer.
  • the substrate is provided on the opposite surface of the light absorbing layer opposite to the light reflecting layer, and the color film is located on the opposite side of the light absorbing layer to the light reflecting layer, The color film being disposed between the substrate and the light absorbing layer; Or on the opposite surface of the substrate facing the light absorption layer.
  • a substrate is provided on the opposite surface of the light reflecting layer opposite to the light absorbing layer, and a color film is additionally provided.
  • 12A shows a structure in which the color film 401 is provided on the opposite surface of the light absorbing layer 301 on the side of the light reflection layer 201.
  • FIG. 12B shows a structure in which the color film 401 is provided on the light absorbing layer 301 A structure in which a color film 401 is provided between the light reflection layer 201 and the substrate 101 and a structure in which a color film 401 is provided between the light reflection layer 201 and the substrate 101 is shown in FIG.
  • a film 401 is provided on the opposite surface of the substrate 101 on the light reflection layer 201 side.
  • the color films 401a, 401b, 401c and 401d are respectively provided on opposite sides of the light absorbing layer 301 on the light reflecting layer 201 side, between the light absorbing layer 301 and the light reflecting layer 201, but the present invention is not limited thereto and the color films 401a, 401b, 401c, and 401c may be formed on the opposite surfaces of the reflective layer 201 and the substrate 101, 401d may be omitted.
  • a substrate is provided on the opposite surface of the light absorbing layer opposite to the light reflection layer, and a color film is additionally provided.
  • 13A shows a structure in which the color film 401 is provided on the opposite surface of the substrate 101 on the side of the light absorbing layer 301.
  • FIG. 13B shows a structure in which the color film 401 is provided on the substrate 101 A structure in which the color film 401 is provided between the light absorbing layer 301 and the light reflecting layer 201 is shown in Figure 13C and a structure in which the color film 401 is provided between the light absorbing layer 301 and the light reflecting layer 201, (401) is provided on the opposite surface of the light reflection layer (201) on the side of the light absorption layer (301).
  • the color films 401a, 401b, 401c and 401d are formed on the opposite side of the substrate 101 on the light absorbing layer 301 side, between the substrate 101 and the light absorbing layer 301, The present invention is not limited thereto and the color films 401a, 401b, and 401c (not shown in the drawings) may be used as the light reflection layer 201 , And 401d may be omitted.
  • the transmittance is 1% or more, preferably 3% or more, and more preferably 5% or more. This is because the transmitted light can be mixed with the color of the color film in the visible light transmittance range.
  • the color film may be provided in a state in which one color film or two or more kinds of color films are stacked.
  • the color film may be combined with the color developed from the above-described laminated structure of the light reflection layer and the light absorption layer to exhibit a desired color.
  • a color film may be used in which one or more of pigments and dyes are dispersed in the matrix resin to exhibit color.
  • the color film may be formed by coating a composition for forming a color film directly at a position where the color film may be provided, or may be formed by coating a composition for forming a color film on a separate substrate, Method is used to manufacture a color film, and then a color film is placed or adhered to a position where the color film can be provided.
  • the coating method may be a wet coating or a dry coating.
  • the pigments and dyes that can be included in the color film may be selected from those known in the art as being capable of achieving a desired color from the final decorative member, and may be selected from red, yellow, purple, And pigments and dyes such as pigments, pigments, pigments, pigments, etc. Specific examples thereof include perinone red dyes, anthraquinone dyes, anthraquinone dyes, methine dyes, anthraquinone dyes, anthraquinone dyes, phthalocyanine dyes, thioindigo dyes, isoindigo dyes, Dyes such as isoxindigo-based pink dyes may be used alone or in combination.
  • Carbon black, copper phthalocyanine (CI Pigment Blue 15: 3), C.I. Pigment Red 112, Pigment blue, and Isoindoline yellow may be used alone or in combination.
  • Commercially available materials such as dyes or pigments may be used.
  • materials such as Ciba ORACET Co., Ltd. or Chohwa Paint Co., Ltd. can be used.
  • the types of the dyes or pigments and their hue are merely examples, and known dyes or pigments can be used in various ways, thereby realizing more various colors.
  • the matrix resin included in the color film materials known as materials such as a transparent film, a primer layer, an adhesive layer, and a coating layer can be used, and the material is not particularly limited thereto.
  • materials such as an acrylic resin, a polyethylene terephthalate resin, a urethane resin, a linear olefin resin, a cycloolefin resin, an epoxy resin, and a triacetylcellulose resin may be selected. Mixtures may also be used.
  • the color film has a light transmittance of not less than 1%, preferably not less than 3%, more preferably not less than 5%, which is expressed from the light reflection layer, the light absorption layer or the laminated structure of the light reflection layer and the light absorption layer desirable.
  • hues expressed from the color film and the light reflected from the light reflecting layer, the light absorbing layer, or the laminated structure thereof can be combined together to achieve a desired color.
  • the thickness of the color film is not particularly limited and can be selected by a person having ordinary knowledge in the art as long as it can exhibit a desired color.
  • the thickness of the color film may be 500 nm to 1 mm.
  • the substrate includes a pattern layer, and the pattern layer is provided adjacent to the color reproduction layer.
  • the fact that the pattern layer is provided adjacent to the color developing layer means that the pattern layer is in direct contact with the color developing layer.
  • the pattern layer may be in direct contact with the light reflection layer of the color reproduction layer, or the pattern layer may be in direct contact with the light absorption layer of the color reproduction layer.
  • the pattern layer includes a convex portion or a concave portion having an asymmetrical cross section.
  • the pattern layer includes a convex shape having an asymmetrical cross section.
  • the pattern layer includes a concave shape having an asymmetrical cross section.
  • the pattern layer includes a convex portion having an asymmetrical cross-section and a concave portion having an asymmetrical cross-section.
  • cross-section means a surface when the convex portion or concave portion is cut in one direction.
  • the cross section may mean a plane when the convex portion or the concave portion is cut in a direction parallel to the paper surface or perpendicular to the paper surface when the decorative member is placed on a paper surface.
  • the convex portion or the concave portion-shaped surface of the pattern layer of the decorative member according to the above-described embodiment has an asymmetric structure in at least one of the cross sections in the direction perpendicular to the paper surface.
  • asymmetric cross section means that the figure composed of the rim of the cross section has a structure that does not have line symmetry or point symmetry.
  • Linear symmetry refers to a feature that overlaps when a figure is symmetrically centered on a straight line.
  • Point symmetry means that when a figure is rotated 180 degrees from one point, it has a symmetrical property completely overlapping the original figure.
  • the rim of the cross section of the asymmetric structure may be a straight line, a curve, or a combination thereof.
  • the shape of the convex portion or the concave portion having the asymmetric cross section includes at least two sides having different inclination angles, different degrees of curvature, or different sides.
  • the convex section or the concave section has an asymmetric structure.
  • the decorative member can exhibit dichroism by the convex portion or the concave portion having the asymmetric cross-section included in the surface of the pattern layer.
  • Dichroism means that different colors are observed depending on the viewing angle.
  • the color representation can be expressed as CIE L * a * b *, and the color difference can be defined using the distance ( ⁇ E * ab) in the L * a * b * space. Specifically, the color difference , And the observer can not recognize the color difference within the range of 0 ⁇ ? E * ab ⁇ 1 (Reference: Machine Graphics and Vision 20 (4): 383-411). Therefore, in the present specification, dichroism can be defined as DELTA E * ab > 1.
  • the color developing layer has a dichroism of DELTA E * ab > 1.
  • the chrominance DELTA E * ab which is the distance in the space of L * a * b * on the chromaticity coordinates CIE L * a * b * of the color reproduction layer, may exceed 1.
  • the decorative member has a dichroism of DELTA E * ab > 1.
  • the color difference DELTA E * ab which is the distance in the space of L * a * b * on the color coordinate system CIE L * a * b * in the entire decorative member, may exceed one.
  • the shape of the convex portion or the concave portion includes a first inclined surface and a second inclined surface having different inclination angles.
  • the shape of the convex portion or the concave portion includes a first inclined side and a second inclined side at least one of which the inclination angle is different from each other.
  • the shapes of the first inclined side and the second inclined side are the same or different from each other, and each is a straight line or a curved line.
  • the rim of the cross section of the asymmetric structure is a straight line, a curve, or a combination thereof.
  • Fig. 14 shows that the shapes of the first inclined sides and the second inclined sides are linear.
  • Each convex shape includes a first region D1 including a first inclined side and a second region D2 including a second inclined side.
  • the first oblique side and the second oblique side are in a linear shape.
  • the angle c3 formed by the first inclined side and the second inclined side may be from 75 degrees to 105 degrees.
  • the angle c1 formed by the first inclined side and the ground (base) is different from the angle c2 formed by the second inclined side and the ground.
  • the combination of c1 and c2 may be 20 degrees / 80 degrees, 10 degrees / 70 degrees, or 30 degrees / 70 degrees.
  • the cross section of the pattern layer has a convex shape, and the convex cross-section includes a first area E1 including a first inclined side and a second area E2 including a second inclined side. At least one of the first inclined side and the second inclined side may be curved. For example, both the first inclined sides and the second inclined sides may be curved, the first inclined sides may be linear, and the second inclined sides may be curved.
  • the angle c1 may be larger than the angle c2.
  • the angle formed by the curved slope with the ground surface can be calculated from the angle formed by the straight line and the ground surface when an arbitrary straight line is drawn from the point where the slope side contacts the ground surface to the point where the first slope side contacts the second slope side .
  • the curved second inclined sides may have different degrees of curvature depending on the height of the pattern layer, and the curved line may have a radius of curvature.
  • the radius of curvature may be 10 times or less the width (E1 + E2) of the convex shape.
  • 15 (a) shows that the radius of curvature of the curve is twice the width of the convex portion, and Fig.
  • 15 (b) shows that the radius of curvature of the curve is one times the width of the convex portion.
  • the ratio of the curvature portion E2 to the width E1 + E2 of the convex portion may be 90% or less.
  • 15A and 15B show that the ratio of the curved portion E2 to the width E1 + E2 of the convex portion is 60%.
  • the inclination angle of the inclined side can be handled the same as the inclination angle of the inclined side.
  • sides may be a straight line, but is not limited thereto, and may be a curve in whole or in part.
  • the sides may include structures such as a circle, a part of an arc of an ellipse, a wave structure, a zigzag, and the like.
  • the circle or the ellipse when a circle or an ellipse includes a part of the arc of the mutation source or the ellipse, the circle or the ellipse may have a radius of curvature (radius of curvature).
  • the radius of curvature can be defined as the radius of an arc when converting an extremely short section of the curve into an arc.
  • the inclination angle of the convex portion may mean an angle formed by the inclined plane of the convex portion and the horizontal plane of the pattern layer.
  • the first inclined surface may be defined as a left inclined surface of the convex portion and the second inclined surface may be defined as a right inclined surface of the convex portion.
  • first inclined side can be defined as the left inclined side of the convex portion
  • second inclined side can mean the right side inclined side of the convex portion
  • the term “inclined side” means a side having an angle of 0 degrees or more and 90 degrees or less with respect to the ground when the decorative member is placed on the ground. In this case, when the side is a straight line, the angle between the straight line and the ground can be measured. When the decorative member is placed on the ground, an angle between a point nearest to the ground surface and a straight line connecting the point farthest from the ground surface to the ground surface is measured to the ground surface .
  • the term “inclined surface” means a surface having an angle formed by a surface with respect to the ground surface of 0 DEG to 90 DEG, when the decorative member is placed on the ground surface. At this time, when the surface is plane, the angle between the plane and the ground can be measured. When the decorative member is placed on the ground, an angle between a point nearest to the surface of the surface and a straight line connecting the point farthest from the surface of the surface at the shortest distance to the ground surface is measured .
  • the term “inclination angle" refers to an angle formed between the decorative member on the surface of the decorative sheet and the surface or the surface of the sheet constituting the pattern layer. (A'-b ') generated when a point (a') contacting the surface constituting the pattern layer or the surface of the variable layer and a point (b ') farthest from the surface constituting the pattern layer or the surface of the variable layer are connected to each other, ) And the ground surface.
  • curvature refers to the degree of change in the slope of the tangent at successive points on a side or face. The greater the change in the slope of the tangent at successive points on the sides or sides, the greater the degree of curvature.
  • the convex portion may be in the shape of a convex portion
  • the concave portion may be in the shape of a concave portion.
  • the convex unit shape or the concave unit shape means a shape including two inclined sides (first inclined sides and second inclined sides) and not a shape including three or more inclined sides.
  • the convex portion P1 of the circle C1 has one convex portion unit shape including the first oblique side and the second oblique side.
  • the shape contained in the circle C2 includes two convex unit pieces.
  • the first inclined side may be defined as a left inclined side of the convex portion or the concave portion
  • the second inclined side may mean the right side inclined side of the convex portion or the concave portion.
  • the angle formed by the first inclined side and the second inclined side may be in a range of 80 degrees to 100 degrees.
  • the angle may be specifically greater than 80 degrees, greater than 83 degrees, greater than 86 degrees, or greater than 89 degrees, less than 100 degrees, less than 97 degrees, less than 94 degrees, or less than 91 degrees.
  • the angle may mean the angle of the vertex including the first inclined side and the second inclined side. If the first inclined side and the second inclined side do not form a vertex, it may mean the angle of the vertex in which the first inclined side and the second inclined side are virtually extended to form a vertex.
  • the difference between the inclination angle of the first inclined side of the convex portion and the inclination angle of the second inclined side may be within the range of 30 degrees to 70 degrees.
  • the difference between the inclination angle of the first inclined side and the inclination angle of the second inclined side may be, for example, 30 degrees or more, 35 degrees or more, 40 degrees or 45 degrees, 70 degrees or less, 65 degrees or less, Or less. If the difference between the inclination angle of the first inclined side and the inclined side of the second inclined side is within the above range, it may be advantageous in terms of implementation of the color expression according to the direction. That is, when the difference between the inclination angles of the inclined sides is within the above range, the thickness of the light absorbing layer formed on the first inclined sides and the second inclined sides may be different, (See Table 2 below).
  • the convex or concave section may be in the form of a triangular or quadrangular polygonal shape.
  • 16 shows that the convex shape is a rectangular shape.
  • the rectangular shape may be a general rectangular shape and is not particularly limited as long as the inclination angles of the respective inclined sides are different from each other.
  • the square shape may be a shape that partially cuts off the triangle.
  • a pair of faeces may be in the form of a rectangle having a parallel quadrangle, or a rectangle having no pair of mutually parallel faeces.
  • the convex shape includes a first region F1 including a first inclined side, a second region F2 including a second inclined side, and a third region F3 including a third inclined side.
  • the third inclined side may be parallel to the ground, or may not be parallel.
  • the third inclined side is parallel to the ground.
  • At least one of the first slant sides to the third slant sides may be a curved shape, and the content of the curved shape is the same as described above.
  • the total length of F1 + F2 + F3 can be defined as a convex-shaped pitch, and the content of the pitch is as described above.
  • the convex shape may be a shape obtained by removing a specific area of the ABO1 triangle shape.
  • a method for determining the specific area to be removed is as follows. The contents of the inclination angles c1 and c2 are the same as those described above.
  • the ratios of L1: L2, m1: m2, n1: n2 and o1: o2 may be the same or different and independently from 1: 1000 to 1000: 1.
  • the shape of the ABP2P3P1 polygon is taken as the section of the convexity.
  • the convex shape can be modified into various shapes by controlling the ratio of L1: L2, m1: m2, n1: n2 and o1: o2. For example, when L1 and m1 are large, the height of the pattern can be increased, and when o1 is large, the height of the concave portion formed on the convex portion can be made small, and by adjusting the ratio of n1, The position of the lowest point of the concave portion can be adjusted close to either one of the inclined sides of the convex portion.
  • the shape of the cross section may be trapezoidal (FIG. 20).
  • the heights ha and hb of the trapezoid can be varied by adjusting the ratio of L1: L2.
  • FIG. 20 (a) shows a case where the ratio of L1: L2 is 1: 1, the ratio of L1: L2 is 2: 1, the ratio of m1: m2 is 1: 1 , and o1: o2 ratio of 1: 8, respectively.
  • the shape of the convex portion or the concave portion includes two or more convex portions or concave portions. As described above, by having two or more convex portions or concave portions, the dichroism can be further increased. At this time, the shape of the convex portion or the concave portion of two or more may be a shape in which the same shape is repeated, but different shapes may be included. This is shown in FIG. 21 to FIG.
  • FIG. 21 shows that two or more different convex shapes are alternately arranged. And a second convex portion P2 having a height smaller than that of the convex portion is disposed between the convex portions P1.
  • the convex portion previously described before the second convex portion may be referred to as the first convex portion.
  • Fig. 22 shows that concave portions are included between two or more convex shapes.
  • the surface of the pattern layer may have a shape including a concave portion P3 having a height smaller than that of the convex portion at a tip portion (pointed portion) of the convex portion P1.
  • Such a decoration member can exhibit an effect that the color of the image is changed depending on the viewing angle.
  • Fig. 23 may be one in which each shape is arranged in a reversed phase structure.
  • the pattern layer may include a convex portion or a concave portion, and each shape may be arranged in a reversed phase structure.
  • the surface of the pattern layer may have a shape in which a plurality of convex portions are arranged in a reversed phase structure of 180 degrees.
  • the surface of the pattern layer may include a first region C1 having a larger inclination angle of the second inclined plane than the first inclined plane, and a second region C2 having a larger inclination angle of the second inclined plane than the first inclined plane .
  • the convex portion included in the first region may be referred to as a first convex portion P1
  • the convex portion included in the second region may be referred to as a fourth convex portion P4.
  • the height, the width, the inclination angle, and the angle formed by the first and second inclined surfaces of the first and second convex portions P1 and P4 may be the same as those described in the item of the convex portion P1 have.
  • any one of the first region and the second region may correspond to an image or a logo, and the other region may correspond to a background portion.
  • a decoration member can exhibit an effect that the image or logo color is varied depending on the viewing angle.
  • the image or logo part and the base part can show the decorative effect that the color changes according to the viewing direction.
  • the first region and the second region may each include a plurality of convex portions.
  • the widths and the number of convexities of the first region and the second region may be appropriately adjusted in consideration of the size of the desired image or logo.
  • the pattern layer includes at least two convex portions, and may further include a flat portion at a portion or all of the convex portions.
  • a flat portion may be included between each convex portion of the pattern layer.
  • the flat portion means a region where no convex portion exists.
  • the description of the remaining components D1, D2, c1, c2, c3, the first inclined sides and the second inclined sides is the same as described above, except that the pattern layer further includes the flat part.
  • the total length of D1 + D2 + G1 is defined as the pitch of the pattern, which is different from the width of the pattern described above.
  • the height H1 of the convex portion P1 may be 5 ⁇ ⁇ to 30 ⁇ ⁇ . If the height of the convex portion is within the above range, it may be advantageous in terms of production process. In this specification, the height of the convex portion may mean the shortest distance between the highest portion and the lowest portion of the convex portion with respect to the horizontal plane of the pattern layer. The same numerical range can be applied to the depth of the concave portion described above with respect to the height of the convex portion.
  • the width W1 of the convex portion P1 may be 10 ⁇ ⁇ to 90 ⁇ ⁇ . When the width of the convex portion is within the above range, it may be advantageous from the viewpoint of processing and forming the pattern.
  • the width W1 of the convex portion P1 may be, for example, 10 ⁇ ⁇ or more, 15 ⁇ ⁇ or more, 20 ⁇ ⁇ or 25 ⁇ ⁇ or more, 90 ⁇ ⁇ or less, 80 ⁇ ⁇ or less, 70 ⁇ ⁇ or less, Mu m or less, 40 mu m or less, or 35 mu m or less.
  • the description related to this width can be applied not only to the convex portion but also to the above-mentioned concave portion.
  • the distance between the convex portions P1 may be 0 ⁇ ⁇ to 20 ⁇ ⁇ .
  • the distance between the convex portions may mean the shortest distance between the point where one convex portion ends and the point where another convex portion starts, in two adjacent convex portions.
  • the distance between the convex portions is appropriately maintained, it is possible to improve the phenomenon that the decorative region is relatively bright when viewed from the inclined side having a larger inclination angle of the convex portion, and the reflection region is dark due to the shading.
  • the height H2 of the second convex portion P2 may range from 1/5 to 1/4 of the height H1 of the first convex portion P1.
  • the difference (H1-H2) between the height of the first convex portion and the height of the second convex portion may be 10 mu m to 30 mu m.
  • the width W2 of the second convex portion may be 1 ⁇ to 10 ⁇ .
  • the width W2 of the second convex portion may be specifically 1 mu m or more, 2 mu m or more, 3 mu m or more, 4 mu m or more, or 4.5 mu m or more, 10 mu m or less, 9 mu m or less, 6 mu m or less or 5.5 mu m or less.
  • the second convex portion may have two inclined surfaces (S3, S4) whose inclination angles are different from each other.
  • the angle (a4) formed by the two inclined surfaces of the second convex portion may be 20 degrees to 100 degrees.
  • the angle a4 may be more than 20 degrees, more than 30 degrees, more than 40 degrees, more than 50 degrees, more than 60 degrees, more than 70 degrees, more than 80 degrees, more than 85 degrees, less than 100 degrees or less than 95 degrees have.
  • the difference (a6-a5) between the inclination angles of both inclined surfaces of the second convex portion may be 0 degree to 60 degree.
  • the difference (a6-a5) of the inclination angles may be 0 degree or more, 10 degrees or more, 20 degrees or more, 30 degrees or more, 40 degrees or more or 45 degrees or more, 60 degrees or less or 55 degrees or less. If the dimension of the second convex portion is within the above range, it may be advantageous in that a light color can be formed by increasing the inflow of light at a side having a large inclined angle.
  • the height H3 of the concave portion P3 may be 3 ⁇ to 15 ⁇ .
  • the height H3 of the concave portion P3 may be specifically 3 mu m or more, 15 mu m or less, 10 mu m or less, and 5 mu m or less.
  • the concave portion may have two inclined surfaces S5 and S6 having different inclination angles.
  • the angle (a7) formed by the two inclined surfaces of the concave portion may be 20 degrees to 100 degrees.
  • the angle a7 may be more than 20 degrees, more than 30 degrees, more than 40 degrees, more than 50 degrees, more than 60 degrees, more than 70 degrees, more than 80 degrees or more than 85 degrees, less than 100 degrees or less than 95 degrees have.
  • the difference (a9-a8) between the inclination angles of the inclined surfaces of the concave portion may be 0 degree to 60 degrees.
  • the difference (a9-a8) of the inclination angles may be 0 degree or more, 10 degrees or more, 20 degrees or more, 30 degrees or more, 40 degrees or more or 45 degrees or more, 60 degrees or less or 55 degrees or less.
  • coloring can be added to the mirror surface.
  • the convex portion or the concave portion shape of the surface of the pattern layer may be a cone-shaped convex portion protruding outside the surface of the pattern layer, or a cone- may be a cone-shaped recess.
  • the cone shape includes a cone, a cone, or a polygonal shape.
  • the shape of the bottom surface of a polygonal horn is triangular, square, and star shape with five or more protruding points.
  • the decorative member when the decorative member is placed on the ground, if the surface of the pattern layer has a cone-shaped convex shape, at least one of the convex-shaped vertical cross-sections to the ground may be triangular .
  • the decorative member is placed on the ground, if the surface of the pattern layer has a cone-shaped concave shape, at least one of the vertical cross-sections with respect to the ground surface of the concave- Lt; / RTI >
  • the convex portion of the cone shape or the concave shape of the cone shape may have at least one asymmetrical cross section.
  • Fig. 24 shows a cone-shaped convex shape viewed from the convex-shaped surface side.
  • Fig. 24 (a) shows a cone shape of a symmetric structure, and Fig. 24 will be.
  • the cone shape of the symmetrical structure is a regular polygonal shape in which the cross section in a direction horizontal to the ground (hereinafter referred to as horizontal cross section) is a circle or the length of each side is the same, Is a line existing perpendicular to the section of the center of gravity of the horizontal cross section.
  • horizontal cross section a regular polygonal shape in which the cross section in a direction horizontal to the ground (hereinafter referred to as horizontal cross section) is a circle or the length of each side is the same, Is a line existing perpendicular to the section of the center of gravity of the horizontal cross section.
  • a cone shape having an asymmetric cross-section is present on the vertical line of a point that is not the center of gravity of the cone's horizontal cross-section when the cone's vertex position is observed on the surface side of the cone-
  • a horizontal cross section of the cone is a polygon or an ellipse of an asymmetric structure.
  • the horizontal cross section of the cone is a
  • the position of the vertex of the cone can be changed.
  • the vertex of the cone is designed to be located on the vertical line of the center of gravity 01 of the horizontal cross section with respect to the ground of the cone when observed from the surface of the cone-shaped convex portion as shown in the first figure of Fig. 25,
  • Four degrees of symmetry can be obtained when rotating the cone by 360 degrees from the vertex of the cone.
  • the symmetrical structure is broken by designing the vertex of the cone at the position 02 instead of the center of gravity 01 of the horizontal cross section with respect to the ground.
  • the cosine value can be obtained for the plane 1, plane 2, plane 3, and plane 4 in FIG. 25 as follows.
  • Fig. 26 shows a surface having the shape of a convex portion having a line-shaped peak, wherein a) illustrates a pattern having convex portions that do not exhibit dichroism, and b) shows a pattern having convex portions that exhibit dichroism .
  • 26A) is an isosceles triangle or an equilateral triangle, and the Y-Y 'cross section of FIG. 26B is a triangle having side lengths different from each other.
  • the pattern layer has a concave-shaped surface having a line-shaped convex portion or a line-shaped convex portion at the highest point.
  • the line shape may be a linear shape, a curved shape, a curved line, a straight line, or a zigzag shape. This is shown in Figs. 27 to 29.
  • the center of gravity of the horizontal cross- When 360 degree rotation is used as a standard, only one identical form exists, which is advantageous in expressing dichroism.
  • the pattern layer has a convex portion or a concave-shaped surface of a cone-shaped structure in which a cone-shaped tip portion is cut out.
  • Fig. 30 shows a photograph in which an inverted trapezoidal concave portion having an asymmetrical cross section perpendicular to the paper surface when the decorative member is placed on the ground is shown.
  • Such an asymmetric cross section may be in a trapezoidal or inverted trapezoidal shape. Even in this case, dichroism can be expressed by the cross section of the asymmetric structure.
  • the term "surface” may be planar, but is not limited thereto, and may be all or part of a curved surface, unless otherwise stated.
  • the shape of the cross section in the direction perpendicular to the plane may include a structure of a circle, a part of the arc of the ellipse, a wave structure, a zigzag structure, and the like.
  • the pattern layer includes a pattern of a symmetric structure.
  • the symmetric structure includes a prism structure, a lenticular lens structure, and the like.
  • the decorative member includes a surface facing the light reflection layer of the light absorption layer; Between the light absorbing layer and the light reflecting layer; Or a pattern layer including a convex portion or a concave portion having a cross section of an asymmetric structure on a surface of the light reflection layer facing the light absorption layer.
  • the pattern layer has a flat portion on the surface opposite to the surface on which the convex portion or the concave portion is formed, and the flat portion may be formed on the substrate.
  • a plastic substrate may be used as the substrate layer.
  • Plastic substrates include TAC (triacetyl cellulose); A cycloolefin copolymer (COP) such as a norbornene derivative; Poly (methyl methacrylate), PC (polycarbonate), polyethylene (PE), polypropylene (PVP), polyvinyl alcohol (PVA), diacetyl cellulose (DAC), polyacrylate (PAC), polyether sulfone (PES) ), PPS (polyarylate), amorphous fluorine resin, or the like can be used, but the present invention is not limited thereto, and it is possible to use a polyimide no.
  • TAC triacetyl cellulose
  • COP cycloolefin copolymer
  • Poly methyl methacrylate
  • PC polycarbonate
  • the pattern layer may include a thermosetting resin or an ultraviolet ray curing resin.
  • a thermosetting resin for example, a silicone resin, a silicon resin, a flan resin, a polyurethane resin, an epoxy resin, an amino resin, a phenol resin, a urea resin, a polyester resin or a melamine resin may be used, .
  • the ultraviolet ray curable resin is typically an acrylic polymer such as a polyester acrylate polymer, a polystyrene acrylate polymer, an epoxy acrylate polymer, a polyurethane acrylate polymer or a polybutadiene acrylate polymer, a silicone acrylate polymer or an alkyl acrylate Polymers, and the like, but are not limited thereto.
  • a color dye may be further included in the pattern layer or on at least one side of the pattern layer.
  • the inclusion of a colored dye on at least one side of the pattern layer may mean, for example, the case where the above-mentioned base layer provided on the flat side of the pattern layer contains a colored dye.
  • the colored dyes include anthraquinone dyes, phthalocyanine dyes, thioindigo dyes, perinone dyes, isoxindigo dyes, Based dyes, methane-based dyes, monoazo-based dyes, and 1: 2 metal complex-based dyes.
  • the dye when the pattern layer contains a colored dye, the dye may be added to the curable resin.
  • the dye layer when the dye layer is further included in the lower part of the pattern layer, the dye layer may be coated on the upper or lower surface of the substrate layer.
  • the content of the colored dye may be, for example, 0 to 50 wt%.
  • the content of the colored dyes can determine the transmittance and the haze range of the pattern layer or decorative member, and the transmittance can be, for example, 20% to 90%, and the haze can be, for example, 1% to 40%.
  • the color-developing layer can impart a metallic texture and a sense of depth to the decorative member when viewed.
  • the color developing layer may be displayed in various colors depending on an angle of view of the image of the decorative member. This is because the wavelength of light reflected from the surface of the inorganic layer passing through the pattern layer changes according to the wavelength of incident light.
  • the color developing layer may have the same convex or concave portion as the surface of the above-mentioned pattern layer.
  • the color developing layer may have the same inclination as the surface of the pattern layer described above.
  • the decorative member is provided between the substrate and the color developing layer; A surface of the color developing layer facing the substrate; Or a protective layer provided on a surface of the substrate opposite to the color developing layer.
  • the decorative member is disposed between the substrate and the pattern layer, between the pattern layer and the light reflection layer, between the light reflection layer and the light absorption layer, and between the light reflection layer and the light reflection layer And a protective layer provided on at least one of the opposite surfaces. That is, the protective layer is provided between each layer of the decorative member or at the outermost portion of the decorative member, thereby protecting the decorative member.
  • protecting layer means a layer capable of protecting other layers of the decorative member, unless otherwise defined. For example, it is possible to prevent the inorganic layer from being deteriorated in a moisture-resistant or heat-resistant environment. Alternatively, scratches on the inorganic layer or the pattern layer due to external factors are effectively suppressed, so that the dichroism of the decorative member can be effectively expressed.
  • inorganic layer means a light absorbing layer or a light reflecting layer unless otherwise defined.
  • an example of the decorative member structure including the protective layer is as follows.
  • it may have a structure of substrate / protective layer / pattern layer / light reflecting layer / light absorbing layer / protective layer or substrate / protective layer / pattern layer / light absorbing layer / light reflecting layer / protective layer.
  • the protective layer comprises aluminum oxynitride.
  • AlON aluminum oxynitride
  • the function of the protective layer described later can be enhanced compared with the case where the protective layer does not contain aluminum oxynitride (AlON). Further, when the ratio of each element of the aluminum oxynitride is adjusted, the protective function can be further improved.
  • the decorative member further includes a protective layer, so that damage to the pattern layer and the inorganic layer is suppressed even if the decorative member is left in a high temperature and high humidity environment, so that excellent decorative effect can be maintained even in a harsh environment.
  • the decorative member of the present specification can be applied to a known object requiring application.
  • portable electronic devices electronic products, cosmetic containers, furniture, building materials, and the like.
  • the method of applying the decorative member to a portable electronic device, an electronic product, a cosmetic container, a furniture, a building material, etc. is not particularly limited, and a known method known as a method of applying a deco film in the art can be applied.
  • the decorative member may further include an adhesive layer as needed.
  • the decorative member may be applied by direct coating to a portable electronic device or an electronic product. In this case, a separate adhesive layer for attaching the decorative member to the portable electronic device or the electronic product may not be required.
  • the decorative member may be attached to a portable electronic device or an electronic product via an adhesive layer.
  • the adhesive layer may be an optically clear adhesive tape (OCA tape) or an adhesive resin. As the OCA tape or adhesive resin, OCA tape or adhesive resin known in the art can be applied without limitation. If necessary, a release liner for protecting the adhesive layer may further be provided.
  • the light reflecting layer and the light absorbing layer may be formed by a sputtering method, an evaporation method, a vapor deposition method, a CVD (chemical vapor deposition) method, a wet coating method, Or on the pattern of the patterned layer of the substrate.
  • a sputtering method since the sputtering method has a linearity, it is possible to maximize the difference in deposition thickness between the inclined surfaces of the convex portions by tilting the position of the target.
  • the light reflecting layer and the light absorbing layer may be formed by a reactive sputtering method, respectively.
  • Reactive sputtering is a method in which ions with energy (e.g., Ar &lt ; + & gt ; ) impact the target material, and the target material is deposited on the surface to be deposited.
  • the base pressure may be 1.0 X 10 -5 Torr or less, 6.0 X 10 -6 Torr or less, and preferably 3.0 X 10 -6 Torr or less.
  • the reactive sputtering method may be performed in a chamber including a plasma gas and a reactive gas.
  • the plasma gas may be argon (Ar) gas.
  • the reactive gas necessary for forming the inorganic material layer is oxygen (O 2 ) and nitrogen (N 2 ), and is a gas for providing oxygen or nitrogen atoms, and is separated from the plasma gas.
  • the flow rate of the plasma gas may be 10 sccm to 300 sccm, preferably 20 sccm to 200 sccm.
  • the sccm means Standard Cubic Centimeer per minute.
  • the process pressure p1 in the chamber may be 1.0 mTorr to 10.0 mTorr, preferably 1.5 mTorr to 10.0 mTorr.
  • the process pressure is higher than the above range in the sputtering, the Ar particles existing in the chamber are increased and the particles emitted from the target collide with the Ar particles to lose energy, so that the growth rate of the thin film may be lowered.
  • the process pressure is kept too low, the energy loss of the aluminum oxynitride particles by the Ar particles is reduced, but there is a disadvantage that the substrate may be damaged by the particles having high energy or the quality of the protective layer may be deteriorated.
  • the fraction of the reactive gas with respect to the plasma gas may be 30% or more and 70% or less, preferably 40% or more and 70% or less, more preferably 50% or more and 70% or less.
  • the fraction of the reactive gas may be calculated as (Q reactive gas / (Q plasma process gas + Q reactive gas ) * 100%).
  • the Q reactive gas means the flow rate of the reactive gas in the chamber and the Q plasma process gas may be the flow rate of the plasma process gas in the chamber.
  • the reactive sputtering method may have a driving power of 100 W or more and 500 W or less, preferably 150 W or more and 300 W or less.
  • the range of the voltage applied in the reactive sputtering method may be 350V to 500V.
  • the range of the voltage can be adjusted according to the state of the target, the process pressure, the driving power (process power) or the fraction of the reactive gas.
  • the deposition temperature of the reactive sputtering method may be 20 ° C or higher and 300 ° C or lower.
  • the crystallinity of the thin film growth is deteriorated due to a lack of energy required for crystal growth of the particles falling off from the target and arriving at the substrate. Evaporation or re-evaporation may cause a problem that the growth rate of the thin film is lowered.
  • An ultraviolet curable resin was applied onto the PET substrate to form a prismatic pattern layer having an inclination angle of 20 degrees / 70 degrees. Then, a color developing layer including a light absorbing layer and a light reflecting layer was formed on the pattern layer by reactive sputtering.
  • reactive sputtering was used to adjust the flow rate of nitrogen gas to 1.5 to 13.0% relative to the flow rate of argon gas to form a 60 nm light absorption layer having the composition shown in Table 3 below. Then, A 70 nm thick In was deposited by a sputtering method to form a light reflection layer.
  • a decorative member was prepared in the same manner as in Comparative Example 1 except that the flow rates of the oxygen gas and the nitrogen gas were adjusted to 12.8% with respect to the flow rate of the argon gas.
  • the thickness of the light absorbing layer was adjusted to 80 nm.
  • a decorative member was prepared in the same manner as in Example 1 except that the flow rates of the oxygen gas and the nitrogen gas were adjusted to 13% with respect to the flow rate of the argon gas.
  • the thickness of the light absorbing layer was adjusted to 100 nm.
  • a decorative member was prepared in the same manner as in Example 1 except that the flow rates of the oxygen gas and the nitrogen gas were adjusted to 13% with respect to the flow rate of the argon gas.
  • the thickness of the light absorbing layer was adjusted to 20 nm.
  • a decorative member was prepared in the same manner as in Example 1 except that the flow rates of the oxygen gas and the nitrogen gas were adjusted to 13% with respect to the flow rate of the argon gas.
  • the thickness of the light absorbing layer was adjusted to 40 nm.
  • a decorative member was prepared in the same manner as in Example 1 except that the flow rates of the oxygen gas and the nitrogen gas were adjusted to 13% with respect to the flow rate of the argon gas.
  • the thickness of the light absorbing layer was adjusted to 50 nm.
  • the thickness of the light absorbing layer, the thickness parameter, and the composition ratio at each position of the examples and comparative examples were measured and shown in Table 3 below.
  • composition ratios of the decorative members prepared in the above Examples and Comparative Examples were analyzed, and hues appearing in each thickness were observed and recorded in Table 4 below.

Abstract

La présente invention se rapporte à un élément décoratif.
PCT/KR2018/015943 2017-12-15 2018-12-14 Élément décoratif WO2019117678A1 (fr)

Priority Applications (4)

Application Number Priority Date Filing Date Title
US16/767,944 US20200290311A1 (en) 2017-12-15 2018-12-14 Decorative member
CN201880080476.7A CN111479682B (zh) 2017-12-15 2018-12-14 装饰构件
JP2020529449A JP7024941B2 (ja) 2017-12-15 2018-12-14 装飾部材
EP18888203.9A EP3725505A4 (fr) 2017-12-15 2018-12-14 Élément décoratif

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
KR10-2017-0173250 2017-12-15
KR20170173250 2017-12-15
KR1020180088857A KR102201578B1 (ko) 2017-12-15 2018-07-30 장식 부재
KR10-2018-0088857 2018-07-30

Publications (1)

Publication Number Publication Date
WO2019117678A1 true WO2019117678A1 (fr) 2019-06-20

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Application Number Title Priority Date Filing Date
PCT/KR2018/015943 WO2019117678A1 (fr) 2017-12-15 2018-12-14 Élément décoratif

Country Status (1)

Country Link
WO (1) WO2019117678A1 (fr)

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KR101512236B1 (ko) * 2012-08-31 2015-04-16 주식회사 엘지화학 금속 구조체 및 이의 제조방법
KR20160035998A (ko) * 2014-09-24 2016-04-01 주식회사 엘지화학 전도성 구조체 및 이의 제조방법
JP2016079051A (ja) * 2014-10-14 2016-05-16 旭硝子株式会社 積層膜付き透明基板およびその製造方法
KR20170008572A (ko) * 2015-07-14 2017-01-24 주식회사 엘지화학 전도성 구조체, 이의 제조방법, 이를 포함하는 터치패널 및 이를 포함하는 디스플레이 장치
KR20170067156A (ko) * 2015-12-07 2017-06-15 주식회사 엘지화학 전도성 구조체, 이의 제조방법 및 전도성 구조체를 포함하는 전극
KR20180088857A (ko) 2015-12-02 2018-08-07 로베르트 보쉬 게엠베하 차량 거동에 영향을 미치기 위한 방법 및 장치

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KR101512236B1 (ko) * 2012-08-31 2015-04-16 주식회사 엘지화학 금속 구조체 및 이의 제조방법
KR20160035998A (ko) * 2014-09-24 2016-04-01 주식회사 엘지화학 전도성 구조체 및 이의 제조방법
JP2016079051A (ja) * 2014-10-14 2016-05-16 旭硝子株式会社 積層膜付き透明基板およびその製造方法
KR20170008572A (ko) * 2015-07-14 2017-01-24 주식회사 엘지화학 전도성 구조체, 이의 제조방법, 이를 포함하는 터치패널 및 이를 포함하는 디스플레이 장치
KR20180088857A (ko) 2015-12-02 2018-08-07 로베르트 보쉬 게엠베하 차량 거동에 영향을 미치기 위한 방법 및 장치
KR20170067156A (ko) * 2015-12-07 2017-06-15 주식회사 엘지화학 전도성 구조체, 이의 제조방법 및 전도성 구조체를 포함하는 전극

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MACHINE GRAPHICS AND VISION, vol. 20, no. 4, pages 383 - 411
See also references of EP3725505A4

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