WO2019101003A1 - Filler and use thereof - Google Patents

Filler and use thereof Download PDF

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WO2019101003A1
WO2019101003A1 PCT/CN2018/115788 CN2018115788W WO2019101003A1 WO 2019101003 A1 WO2019101003 A1 WO 2019101003A1 CN 2018115788 W CN2018115788 W CN 2018115788W WO 2019101003 A1 WO2019101003 A1 WO 2019101003A1
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fiber
sheath
core
filler
melting point
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PCT/CN2018/115788
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French (fr)
Chinese (zh)
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顾金凤
景红川
许金碧
铃木英俊
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东丽纤维研究所(中国)有限公司
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    • DTEXTILES; PAPER
    • D02YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02GCRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/22Yarns or threads characterised by constructional features, e.g. blending, filament/fibre
    • D02G3/24Bulked yarns or threads, e.g. formed from staple fibre components with different relaxation characteristics
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/02Cotton wool; Wadding

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
  • Multicomponent Fibers (AREA)

Abstract

A filler and a use thereof, the filler comprising short fibre cotton formed from core fibre and sheath fibre, the core fibre being composed of a low melting point fibre and a high melting point fibre, the low melting point fibre melting to cause fixation of the core fibre and the sheath fibre, the average length of the core fibre being 1-10 cm and the standard deviation of the length being 0-1.6, and the bulkiness of the short fibre cotton being 200-800 inch3/30 g.

Description

一种填充物及其用途Filler and use thereof 技术领域Technical field
本发明涉及一种填充物及其用途。The invention relates to a filler and its use.
背景技术Background technique
在众多种类的保温填充物中,羽毛以其优异的轻量性、蓬松性以及保温性,常被用于制作被子或羽绒服等产品,长期占据着重要地位。In many types of insulation fillers, feathers are often used for making quilts or down jackets for their long-term importance because of their excellent lightness, bulkiness and heat retention.
但是,天然的羽毛来自于水禽,存在着诸多缺陷。例如,①生产成本高,供给量有限,并且其价格易受市场供求而发生较大变动;②生产过程中会产生大量污水、废水等,从而带来污染环境的问题,而且羽毛要是洗涤不充分的话,还会产生恶臭;③不宜机洗,一般作为罩布使用的面料密度都比较大,洗衣机洗涤时容易鼓起来、洗不干净,而且洗涤后羽绒容易偏移,导致局部保暖性变差。However, natural feathers come from waterfowl and there are many defects. For example, 1 production cost is high, supply is limited, and its price is subject to large changes in market supply and demand; 2 a large amount of sewage, waste water, etc. are generated in the production process, which brings problems of environmental pollution, and feathers are not adequately washed. In addition, it will produce bad odor; 3 is not suitable for machine washing. Generally, the density of the fabric used as the tarpaulin is relatively large. The washing machine is easy to bulge and wash when it is washed, and the down is easy to be distorted after washing, resulting in poor local warming.
化纤类填充物既具备了天然羽绒的轻量的风格,又具有防菌防潮、成本安定、价格便宜等的优点。如中国专利文献CN103097280A中公开了一种填充物体,其内部的填充物是用芯丝与花式丝一体化而成的长纤维填充棉,花式丝被开纤形成环状纤维,长纤维棉在至少一个方向上被多根地并丝,并随罩布一起被缝制而与罩布一体化,有效解决了羽绒类填充物的上述缺陷,而且手感、蓬松性等也比普通的短纤维棉要好,但是这样的填充物只能手工填充,成本高、效率低,而且其在蓬松性等方面仍存在欠缺。The chemical fiber filler has the advantages of lightweight and natural feather, and has the advantages of anti-bacterial and moisture-proof, cost stability, and low price. For example, Chinese Patent Publication No. CN103097280A discloses a filling object, wherein the inner filling is a long fiber filled cotton formed by integrating a core wire and a fancy wire, and the fancy wire is opened to form a loop fiber, and a long fiber cotton. It is multi-filamented in at least one direction and is sewn together with the cover cloth to integrate with the cover cloth, effectively solving the above defects of the down filling, and the hand feeling, bulkiness and the like are also shorter than ordinary short fibers. Cotton is good, but such fillers can only be filled by hand, costly, inefficient, and still lacking in fluffiness.
发明内容Summary of the invention
本发明的目的在于提供一种可以代替羽绒而且能够利用充绒机进行充填的填充物及其用途。It is an object of the present invention to provide a filler which can be used in place of down and which can be filled by a filling machine and its use.
本发明的填充物包括由芯纤维和鞘纤维形成的短纤维棉,芯纤维由低熔点纤维与高熔点纤维构成,低熔点纤维熔融使得芯纤维和鞘纤维固着,芯纤维的平均长度为1~10cm、长度的标准差为0~1.6,短纤维棉的蓬松度(FP值)为200~800inch 3/30g。 The filler of the present invention comprises short fiber cotton formed by a core fiber and a sheath fiber. The core fiber is composed of a low melting point fiber and a high melting point fiber, and the low melting point fiber is melted to fix the core fiber and the sheath fiber, and the average length of the core fiber is 1 to The standard deviation of 10 cm and length is 0 to 1.6, and the bulkiness (FP value) of staple fiber is 200 to 800 inch 3 / 30 g.
本发明的填充物,包括由芯鞘纤维构成的短纤维棉,由于构成短纤维棉的芯纤维中的低熔点纤维发生熔融,使得芯纤维和鞘纤维固着,芯鞘结构得以保持,与长纤维棉相比,这样的短纤维棉的蓬松度更好,而且也不会出现洗涤团聚的问题,特别是可以使用羽毛充填机进行充填,改善了长纤维棉充填效率低的缺点,是羽绒(羽毛)的最佳替代品。The filler of the present invention comprises a staple fiber cotton composed of a core-sheath fiber, and the core fiber and the sheath fiber are fixed due to the melting of the low-melting fiber in the core fiber constituting the staple fiber cotton, and the core-sheath structure is maintained, and the long fiber is maintained. Compared with cotton, such short-fiber cotton has better bulkiness, and there is no problem of washing and agglomeration. In particular, feather filling machine can be used for filling, which improves the shortcoming of low-fiber cotton filling efficiency, and is feather (feather). The best alternative.
附图说明DRAWINGS
图1为本发明芯鞘结构的加工丝的数码显微镜照片(倍率100倍)。Fig. 1 is a digital microscope photograph (magnification of 100 times) of a processed yarn of a core-sheath structure of the present invention.
图2为解舒后的鞘丝,其中白色半圆弧为测试圆环半径的圆弧。Figure 2 shows the sheath wire after unwinding, in which the white semicircular arc is the arc of the radius of the test ring.
具体实施方式Detailed ways
本发明的填充物,包括由芯纤维和鞘纤维形成的短纤维棉,其中芯纤维由低熔点纤维与高熔点纤维构成,低熔点纤维熔融使得芯纤维和鞘纤维固着。本发明中所述的高熔点纤维和与低熔点纤维并非是指特定数值以上或以下熔点的纤维,而是指具有一定熔点差的两种纤维。由于芯纤维之间存在熔点差,在同样的热处理条件下,低熔点纤维发生部分融化现象,具体体现为一部分自身融着、粘合,一部分融 断,一部分熔融粘合在高熔点纤维上,在短纤维棉中形成了分散的熔融粘合点,这些熔融粘合点的存在保证了短纤维棉作为填充材料使用时,即便受到外力挤压,芯纤维和鞘纤维也不会分散开,芯鞘结构得以维持,而且与长纤维棉相比,存储静止空气的空间增多,蓬松性能更为优越。The filler of the present invention comprises staple fiber cotton formed of a core fiber and a sheath fiber, wherein the core fiber is composed of a low melting point fiber and a high melting point fiber, and the low melting point fiber is melted to fix the core fiber and the sheath fiber. The high-melting-point fibers and the low-melting-point fibers described in the present invention are not intended to mean fibers having a melting point above or below a specific value, but rather two fibers having a certain difference in melting point. Due to the difference in melting point between the core fibers, under the same heat treatment conditions, the low-melting fiber partially melts, which is partly caused by a part of itself melting, bonding, a part of the melting, and a part of the fusion bonding on the high-melting fiber. Dispersed fusion bonding points are formed in the short-fiber cotton. The presence of these fusion bonding points ensures that when the short-fiber cotton is used as a filling material, even if it is pressed by an external force, the core fiber and the sheath fiber are not dispersed, and the core sheath The structure is maintained and the space for storing still air is increased compared to long-fiber cotton, and the bulkiness is superior.
如果短纤维棉过长的话,只能手工进行填充,充填效率低下,人工成本也比较高;而短纤维棉过短的话,难以获得蓬松的手感,并且容易发生钻绒现象,特别是洗涤后容易发生偏移、团聚,严重影响到了穿着保暖性。本发明的短纤维棉的长度由芯纤维所决定。为了兼顾充填效率以及蓬松性等,本发明的短纤维棉的芯纤维的平均长度要求在1~10cm之间,优选为2~10cm,更优选为3~8cm。If the short-fiber cotton is too long, it can only be filled by hand, the filling efficiency is low, and the labor cost is relatively high. When the short-fiber cotton is too short, it is difficult to obtain a fluffy hand, and it is easy to cause a lint phenomenon, especially after washing. Offset and agglomeration have seriously affected the wearing of warmth. The length of the staple fiber of the present invention is determined by the core fiber. In order to achieve both the filling efficiency and the bulkiness, the average length of the core fiber of the staple fiber of the present invention is required to be 1 to 10 cm, preferably 2 to 10 cm, and more preferably 3 to 8 cm.
考虑到本发明的短纤维棉是通过剪切得到的,每根短纤维棉之间的长度存在一定偏差,本发明中这个长度的误差用长度标准差来表示。长度标准差越小,表明长度的偏差越小,反之,长度偏差越大。本发明中芯纤维长度的标准差为0~1.6,优选0~1.0。标准差是一组数值自平均值分散开来的程度的一种测量观念。一个较大的标准差,代表大部分的数值和其平均值之间差异较大;一个较小的标准差,代表这些数值较接近平均值。其中标准差的计算公式如下所示:In view of the fact that the staple fiber cotton of the present invention is obtained by shearing, there is a certain deviation in the length between each of the staple fiber cottons, and the error of this length in the present invention is represented by the standard deviation of the length. The smaller the standard deviation of the length, the smaller the deviation of the length, and the greater the deviation of the length. The standard deviation of the length of the core fibers in the present invention is from 0 to 1.6, preferably from 0 to 1.0. The standard deviation is a measure of the extent to which a set of values is spread out from the average. A large standard deviation represents a large difference between most of the values and their average values; a smaller standard deviation means that these values are closer to the average. The formula for calculating the standard deviation is as follows:
Figure PCTCN2018115788-appb-000001
Figure PCTCN2018115788-appb-000001
μ为X 1,X 2,X 3,......Xn的平均值。 μ is the average of X 1 , X 2 , X 3 , ... Xn.
FP值(fill power)越大,说明物体的蓬松效果越好。本发明的填充物,其FP值为200~800inch 3/30g,具有较好的蓬松效果。FP 值优选为400~800inch 3/30g。 The larger the FP value, the better the fluffy effect of the object. The filler of the present invention has a FP value of 200 to 800 inch 3 / 30 g and has a good bulking effect. The FP value is preferably 400 to 800 inch 3 / 30 g.
考虑到加工性以及获得适当个数的熔融粘合点,本发明优选芯纤维中高熔点纤维与低熔点纤维的熔点差为30℃~150℃。从手感以及抵抗偏移的角度考虑,进一步优选熔点差为30℃~100℃,更优选为50℃~80℃。In view of workability and obtaining an appropriate number of fusion bonding points, it is preferred in the present invention that the difference in melting point between the high melting point fiber and the low melting point fiber in the core fiber is from 30 ° C to 150 ° C. It is more preferable that the difference in melting point is from 30 ° C to 100 ° C, and more preferably from 50 ° C to 80 ° C from the viewpoint of hand feeling and resistance deviation.
本发明中,优选相对于短纤维棉的总重量,低熔点纤维所占比例为0.2~30.0重量%,更优选为0.2~10.0重量%。低熔点纤维所占比例高于30.0重量%时,熔融粘合点有增加的趋势,有可能会影响到短纤维棉的蓬松度,导致手感变硬;而低于0.2重量%时,熔融粘合点有降低的趋势,特别是同时芯纤维又比较短的话,则无法固定在一起的芯鞘纤维数量变多,有可能会影响到充填性以及洗涤偏移性。In the present invention, the proportion of the low-melting fiber is preferably 0.2 to 30.0% by weight, and more preferably 0.2 to 10.0% by weight based on the total weight of the staple fiber. When the proportion of the low-melting fiber is more than 30.0% by weight, the fusion bonding point tends to increase, which may affect the bulkiness of the short-fiber cotton, resulting in hardening of the hand; and when it is less than 0.2% by weight, the fusion bonding The point has a tendency to decrease, especially when the core fiber is relatively short, the number of core sheath fibers that cannot be fixed together increases, which may affect the filling property and the washing offset.
本发明中,优选鞘纤维在芯纤维外侧形成圆环状,圆环的半径为2~12mm,鞘纤维的单丝纤度为3.5~10.0dtex。所谓交叉是指鞘纤维开纤后和芯纤维相互交叉形成的交点(非固定点),相互交叉是指方向不同的几根纤维互相穿过。但是该交点并没有融着在一起,可以自由移动。鞘纤维形成的圆环半径小于2mm的话,鞘纤维几乎是紧贴在芯纤维上,芯鞘纤维之间的立体空间(空气层)较小,短纤维棉的蓬松性以及保温性有下降的趋势。反之,鞘纤维形成的圆环半径大于12mm的话,虽然短纤维棉的蓬松性和柔软性会有很大的提高,但是耐压缩性能有变差的趋势,也就是说受外力挤压时会形成永久性的变形,有可能会影响到最终产品的外观等。圆环的半径更优选为4~9mm。与此同时,鞘纤维的单丝纤度小于3.5dtex的话,虽然纤维的柔软性 增加,但是鞘纤维所形成的圆环的耐压缩能力反而会下降;反之,鞘纤维的单丝纤度超过10.0dtex的话,纤维的刚性变高,短纤维棉的手感有变差的趋势。鞘纤维的单丝纤度更优选为4.0~8.0dtex。In the present invention, it is preferred that the sheath fibers form an annular shape on the outer side of the core fiber, the radius of the ring is 2 to 12 mm, and the single fiber fineness of the sheath fiber is 3.5 to 10.0 dtex. The term "crossing" refers to the intersection (non-fixed point) formed by the intersection of the sheath fibers and the core fibers, and the mutual crossing means that a plurality of fibers having different directions pass through each other. But the intersection is not melted together and can move freely. When the radius of the ring formed by the sheath fiber is less than 2 mm, the sheath fiber is almost in close contact with the core fiber, and the three-dimensional space (air layer) between the core sheath fibers is small, and the bulkiness and heat retention of the short fiber cotton tend to decrease. . On the other hand, if the radius of the ring formed by the sheath fiber is larger than 12 mm, although the bulkiness and flexibility of the short fiber cotton are greatly improved, the compression resistance tends to be deteriorated, that is, it is formed when pressed by an external force. Permanent deformation may affect the appearance of the final product. The radius of the ring is more preferably 4 to 9 mm. At the same time, if the monofilament fineness of the sheath fiber is less than 3.5 dtex, although the softness of the fiber increases, the compression resistance of the ring formed by the sheath fiber may decrease; on the contrary, if the monofilament fineness of the sheath fiber exceeds 10.0 dtex. The rigidity of the fiber becomes high, and the hand of the short fiber cotton tends to be deteriorated. The monofilament fineness of the sheath fiber is more preferably 4.0 to 8.0 dtex.
交叉点的个数和鞘纤维形成的圆环个数之间存在一定的关联性。鞘纤维和芯纤维形成的交叉点个数少的话,说明鞘纤维形成的圆环个数少,这样的话短纤维棉的蓬松性就会比较低;反之,鞘纤维和芯纤维形成的交叉点个数多的话,说明鞘纤维形成的圆环个数多,虽然短纤维棉的蓬松度在一定范围有所提高,但是鞘纤维与芯纤维之间的立体空间不会增加,反而会导致短纤维棉单位长度的重量增加,导致蓬松度下降。本发明中鞘纤维和芯纤维所形成的交叉点的个数优选30~150个/cm,更优选30~80个/cm。There is a certain correlation between the number of intersections and the number of rings formed by the sheath fibers. When the number of intersections formed by the sheath fiber and the core fiber is small, it indicates that the number of rings formed by the sheath fiber is small, so that the bulkiness of the short fiber cotton is relatively low; otherwise, the intersection of the sheath fiber and the core fiber is formed. If the number is large, the number of rings formed by the sheath fibers is large. Although the bulkiness of the short fiber cotton is increased within a certain range, the three-dimensional space between the sheath fibers and the core fibers is not increased, but the short fiber cotton is caused. The weight per unit length increases, resulting in a decrease in bulkiness. The number of intersections formed by the sheath fibers and the core fibers in the present invention is preferably 30 to 150 / cm, more preferably 30 to 80 / cm.
本发明的填充物,鞘纤维和芯纤维可以均为实心断面,也可以均为中空断面,还可以其中一方为实心、另一方为中空。对于实心断面的形状没有特别的规定,可以是圆形、三角、十字、八叶等。和实心纤维相比,中空纤维的密度较小,在同样的短纤维棉形态和克重下,由中空纤维制得的短纤维棉的长度更长,更有利于提高短纤维棉的蓬松性能,但是中空度越高,对生产工艺的要求也就越高,生产性也随之降低。本发明中,优选鞘纤维和芯纤维均为中空纤维,中空度为20%~50%,中空度更优选为25%~40%。In the filler of the present invention, the sheath fiber and the core fiber may each have a solid cross section, or may have a hollow cross section, or one of them may be solid and the other may be hollow. There is no particular limitation on the shape of the solid section, and it may be a circle, a triangle, a cross, an eight-leaf or the like. Compared with the solid fiber, the density of the hollow fiber is small. Under the same short fiber cotton form and gram weight, the length of the short fiber cotton made of the hollow fiber is longer, which is more favorable for improving the bulkiness of the short fiber cotton. However, the higher the degree of hollowness, the higher the requirements for the production process and the lower the productivity. In the present invention, it is preferred that both the sheath fiber and the core fiber are hollow fibers having a hollowness of 20% to 50% and a hollowness of more preferably 25% to 40%.
本发明的填充物,可以全部为芯鞘结构的短纤维棉,也可以为芯鞘结构的短纤维棉和羽毛的混合物。添加羽毛,可以进一步提高蓬松性。The filler of the present invention may be a short fiber cotton of a core-sheath structure or a mixture of short fiber cotton of a core-sheath structure and feathers. Adding feathers can further improve the fluffiness.
本发明中,优选所用短纤维棉包括曲率半径为5~20mm的鞘纤维,可以进一步提高短纤维棉的蓬松度。这里的曲率半径为鞘纤维解舒后三维立体状螺旋的半径。鞘纤维的曲率半径小于5mm的话,加工过程中鞘纤维开纤难度变大,由其形成的圆环的直径变小,加工丝的蓬松性有下降的趋势;反之,鞘纤维的曲率半径大于20mm话,鞘纤维形成的圆环直径会比较大,有可能会减弱或者无法体现鞘纤维原本的三维立体效果。In the present invention, it is preferred that the staple fiber cotton used includes a sheath fiber having a radius of curvature of 5 to 20 mm, which can further improve the bulkiness of the staple fiber. The radius of curvature here is the radius of the three-dimensional spiral of the sheath fiber after unwinding. If the radius of curvature of the sheath fiber is less than 5 mm, the difficulty of opening the sheath fiber during processing becomes larger, the diameter of the ring formed by the sheath becomes smaller, and the bulkiness of the processed yarn decreases. Conversely, the radius of curvature of the sheath fiber is greater than 20 mm. If the diameter of the ring formed by the sheath fiber is relatively large, it may weaken or fail to reflect the original three-dimensional effect of the sheath fiber.
本发明所用鞘纤维的种类,没有特别限定,可以为普通聚酯(PET)、改性PET、聚烯烃、聚对苯二甲酸丁二醇酯(PBT)等的一种或几种。芯纤维中的高熔点纤维可以为普通PET、改性PET、聚烯烃、PBT等的一种或几种;低熔点纤维可以为低熔点PET、聚丙烯(PP)、聚乙烯或尼龙纤维中的至少一种。The type of the sheath fiber used in the present invention is not particularly limited, and may be one or more of ordinary polyester (PET), modified PET, polyolefin, and polybutylene terephthalate (PBT). The high melting point fiber in the core fiber may be one or more of ordinary PET, modified PET, polyolefin, PBT, etc.; the low melting point fiber may be in low melting point PET, polypropylene (PP), polyethylene or nylon fiber. At least one.
本发明的短纤维棉可以通过如下方法制备得到,但不限于该方法:利用不同的喂入罗拉或喂入辊分别喂入鞘纤维以及高低熔点的芯纤维,通过调整鞘纤维和芯纤维的喂入速度来控制鞘纤维和芯纤维的丝长差;鞘纤维和芯纤维随着气流的牵引通过喷嘴,然后芯纤维和鞘纤维在喷嘴出口处随着混乱气流的作用下形成交络得到加工丝。根据鞘纤维、芯纤维的不同,鞘纤维的长度是芯纤维长度的5~50倍。喷嘴处的空气流速设置在30L/分钟~150L/分钟之间。混乱气流是指,压缩空气由于鞘纤维和芯纤维的干扰,由单一流向变得混乱且呈周期性变化的气流。鞘纤维随着混乱气流进行开纤,和芯纤维形成周期性的交叉,然后进行150~170℃的高温定型,使低熔点纤维发生熔融 得到加工丝。根据需要,将所得加工丝剪成所需的长度得到本发明的短纤维棉,然后利用羽毛充填机进行充填。The staple fiber cotton of the present invention can be prepared by the following method, but is not limited to the method: feeding the sheath fiber and the high and low melting core fiber separately by using different feeding rollers or feeding rollers, by adjusting the feeding of the sheath fiber and the core fiber. Into the speed to control the silk length difference between the sheath fiber and the core fiber; the sheath fiber and the core fiber pass through the nozzle with the airflow, and then the core fiber and the sheath fiber form an entanglement with the chaotic airflow at the nozzle exit to obtain the processed wire. . The length of the sheath fiber is 5 to 50 times the length of the core fiber, depending on the sheath fiber and the core fiber. The air flow rate at the nozzle is set between 30 L/min and 150 L/min. The chaotic airflow refers to a flow of compressed air that becomes chaotic and periodically changes from a single flow due to interference of the sheath fibers and the core fibers. The sheath fibers are opened with a chaotic gas flow, and periodically intersect with the core fibers, and then subjected to high-temperature setting at 150 to 170 ° C to melt the low-melting fibers to obtain processed yarns. The obtained processed yarn was cut into a desired length as needed to obtain the staple fiber cotton of the present invention, which was then filled with a feather filling machine.
鞘纤维和芯纤维喂入时,可通过调整各自的喂入速度形成丝长差。鞘纤维的长度虽然对填充效率不会产生太大的影响,但是如果鞘纤维与芯纤维之间的长度比(丝长差)过小的话,鞘纤维对芯纤维的包覆就会较少、较小,作为填充材料的话,蓬松保暖性有下降的趋势;而长度比(丝长差)过大的话,由于鞘纤维在芯纤维外形成的圆环较多,手感有变硬的趋势。从手感和蓬松效果来考虑,优选鞘纤维的喂入速度是芯纤维的10~40倍,更优选为10~30倍。When the sheath fibers and the core fibers are fed, the filament length difference can be formed by adjusting the respective feeding speeds. Although the length of the sheath fiber does not have much influence on the filling efficiency, if the length ratio (length difference) between the sheath fiber and the core fiber is too small, the sheath fiber will have less coating on the core fiber. If it is a filler, the bulkiness of the fluffy body tends to decrease. When the length ratio (length difference) is too large, the sheath fibers tend to form a ring outside the core fiber, and the texture tends to become hard. From the viewpoint of the hand feeling and the fluffy effect, it is preferred that the sheath fibers are fed at a rate of 10 to 40 times, more preferably 10 to 30 times, the core fibers.
为了进一步提高短纤维棉的柔软性,还可以在其表面附着一层硅系树脂。根据鞘纤维和芯纤维表面积的不同,硅系树脂的附着量也有所不同,树脂附着量优选为0.1wt%~5.0wt%。In order to further improve the softness of the staple fiber cotton, a layer of a silicon-based resin may be attached to the surface. The amount of adhesion of the silicone resin varies depending on the surface area of the sheath fiber and the core fiber, and the amount of the resin adhered is preferably from 0.1% by weight to 5.0% by weight.
本发明的填充物蓬松度高,手感柔软,制成的外套、裤子、背心、连体服、冲锋衣、被子、枕头、睡袋、内衣、睡衣、毛衣、紧身裤、袜子或者运动服等保温制品具有不漏绒、不钻绒等优点。The filling material of the invention has high bulkiness and soft hand feeling, and the heat-insulating products such as jackets, pants, vests, jumpsuits, jackets, quilts, pillows, sleeping bags, underwear, pajamas, sweaters, tight pants, socks or sportswear have No leakage, no velvet and so on.
以下通过实施例及比较例对本发明作进一步说明,但是本发明并不局限于此。The present invention will be further illustrated by the following examples and comparative examples, but the invention is not limited thereto.
本发明所涉及的各参数的测试方法如下:The test methods of each parameter involved in the present invention are as follows:
(1)芯纤维的平均长度(1) Average length of core fiber
从短纤维棉中抽取10根加工丝,将短纤维棉安装在测长台上,吊上加工丝的1/10/D丹尼尔重量的荷重(g),测出短纤维棉的长度并取平均值作为本发明芯纤维的长度。10 processing yarns were taken from short-fiber cotton, short-fiber cotton was mounted on the measuring platform, and the weight of the 1/10/D denier weight (g) of the processed yarn was hoisted, and the length of the short-fiber cotton was measured and averaged. The value is the length of the core fiber of the present invention.
(2)芯纤维的熔点差(2) the difference in melting point of the core fiber
从短纤维棉中分离出芯纤维,利用DSC差示扫描量热仪进行测定并计算出熔点差。The core fiber was separated from the staple fiber cotton and measured by a DSC differential scanning calorimeter to calculate the difference in melting point.
(3)鞘纤维形成的圆环半径(3) Ring radius formed by sheath fibers
取长度约1cm左右的短纤维棉5根并将其两端固定,中间部分呈自由状态,在光学显微镜下放大到50倍的倍率进行拍照,然后根据鞘纤维形成的圆环上的三个点来画圆测得圆的半径,取3个圆环进行观察记录数值,一共测15组数据计算平均值作为本发明的鞘纤维形成的圆环半径。Take 5 short staple fiber cottons with a length of about 1 cm and fix them at both ends. The middle part is in a free state, and is magnified to a magnification of 50 times under a light microscope to take a picture, and then according to the three points on the ring formed by the sheath fibers. To draw the radius of the circle, the three rings were taken to observe the recorded values, and a total of 15 sets of data were measured to calculate the average value as the radius of the ring formed by the sheath fibers of the present invention.
(4)鞘纤维和芯纤维交叉点个数(4) Number of intersections of sheath fibers and core fibers
取长度约1cm左右的短纤维棉5根并将其两端固定,中间部分呈自由状态,在光学显微镜下放大到20倍的倍率进行拍照,然后根据照片对鞘单丝纤维和芯纤维所形成的交叉点进行计数,如果多根鞘纤维和芯纤维形成的交叉点在同一位置,按照一个交叉点计数,单位为个/cm。按照上述方法测得5组数据计算出平均值作为鞘纤维和芯纤维交叉点个数。Take 5 short staple fiber cottons with a length of about 1 cm and fix them at both ends. The middle part is in a free state, and is magnified to a magnification of 20 times under a light microscope to take a picture, and then according to the photo, the sheath monofilament fiber and the core fiber are formed. The intersection is counted, if the intersection of the multiple sheath fibers and the core fibers is at the same position, counted in one intersection, in units of /cm. Five sets of data were measured as described above to calculate an average value as the number of intersections of sheath fibers and core fibers.
(5)中空度(5) Hollowness
首先将短纤维棉中未熔融粘合的芯纤维和鞘纤维分离开,接着将分离出来的芯纤维和鞘纤维分别沿纵向切断成薄片(即纤维横截面),在光学显微镜下放大到1000倍的倍率进行拍照,根据照片计算出中空部分的面积S1和纤维整体的面积S2(包括中空部),然后计算:First, the unmelted core fiber and the sheath fiber in the short fiber cotton are separated, and then the separated core fiber and sheath fiber are respectively cut into thin slices (ie, fiber cross section) in the longitudinal direction, and magnified 1000 times under an optical microscope. The magnification is taken, and the area S1 of the hollow portion and the area S2 of the entire fiber (including the hollow portion) are calculated from the photograph, and then calculated:
中空率=(S1/S2)×100%。Hollow ratio = (S1/S2) × 100%.
(6)曲率半径(6) radius of curvature
准备长约30cm左右的鞘纤维原丝样品,将其在恒温恒湿环境(20℃×65%RH)中放置8小时或以上使其状态稳定,然后选取弯曲部分(目测)在数码显微镜下放大到20倍的倍率下进行半径测量,在弯曲部分上任意取三个点,点击数码显微镜的测半径的功能键,得到半径,任取20个弯曲部分测量后计算平均值作为曲率半径。Prepare a sample of sheath fiber precursor about 30cm long, and place it in a constant temperature and humidity environment (20 °C × 65% RH) for 8 hours or more to stabilize its state, then select the curved part (visual) to enlarge under a digital microscope. Radius measurement is performed at a magnification of 20 times, and three points are randomly selected on the curved portion. Click the function key of the radius of the digital microscope to obtain the radius, and take 20 bending portions to measure and calculate the average value as the radius of curvature.
(7)总纤度及单丝纤度(7) Total denier and monofilament fineness
总纤度根据JIS L 1013:2010标准测得;单丝纤度通过总纤度和单丝根数计算得到。The total fineness was measured according to the JIS L 1013:2010 standard; the monofilament fineness was calculated by the total fineness and the number of filaments.
(8)蓬松度(FP值)(8) Bulkness (FP value)
根据IDFB(International Down&Feather Bureau国际羽毛协会)规定的方法进行测试:Tested according to the method specified by IDFB (International Down & Feather Bureau):
①首先将待测试样放置在20℃×65%RH的环境中调试8小时或8小时以上,使得待测试样稳定;1 Firstly, the sample to be tested is placed in an environment of 20 ° C × 65% RH for 8 hours or more, so that the sample to be tested is stable;
②称取试样30g,手动将其抖动到蓬松状态后将其放入测量桶内并盖上盖子;2 Weigh the sample 30g, shake it to the fluffy state manually, put it into the measuring barrel and cover it;
③将重量盘向下移动至接触试样的最高点,然后放开重量盘使其自由下落,放开重量盘的同时计时,稳定1分钟后读出高度并记录;3 Move the weight plate down to the highest point of contact with the sample, then release the weight plate to make it fall freely, release the weight plate while timing, stabilize the height for 1 minute and record;
④打开盖子取出试样,再次将其抖动至蓬松状态,放入测量桶(内径d=28.8cm)内盖上盖子,按照步骤③再次测量,同样的方法测试5次;⑤算出5次的平均高度H后,根据下式计算得出蓬松度:4 Open the cover and take out the sample, shake it again to the fluffy state, put it into the measuring barrel (inner diameter d=28.8cm), cover it, and measure again according to step 3, test 5 times in the same way; 5 calculate the average of 5 times After the height H, the fluff is calculated according to the following formula:
FP=V/16.39=πd 2H/(16.39×4)=39.73H(单位:in 3/30g) FP=V/16.39=πd 2 H/(16.39×4)=39.73H (unit: in 3 /30g)
其中1in 3=16.39cm 3Wherein 1in 3 = 16.39cm 3 .
(9)手感(9) feel
取填充物30g左右,找10个人用手进行触感评价。评价判级结果如下:About 30 g of the filler was taken, and 10 people were asked to evaluate the touch by hand. The evaluation results are as follows:
◎完全感觉不到有熔融点,非常滑爽、柔软,认为手感非常好◎ I don’t feel any melting point at all, it’s very smooth and soft, I think it feels very good.
○基本感觉不到有熔融点,比较滑爽、柔软,认为手感好○ Basically, there is no melting point, it is smooth and soft, and it feels good.
△明显感觉到有熔融点,熔融点硬,不柔软,认为手感一般△ It is obvious that there is a melting point, the melting point is hard, not soft, and the hand feels normal.
×感觉很多地方发生熔融,很硬,认为手感差×I feel that melting occurs in many places, it is very hard, and I feel that it feels bad.
10人中有超过5人认定为同一级别时,则判定为该级别。如果出现一个级别判级人数少于等于5人的话,则考虑再找10人进行评级。If more than 5 out of 10 people are considered to be at the same level, it is judged to be the level. If there is a level of judgement less than or equal to 5 people, then consider looking for another 10 people to rate.
(10)洗涤后偏移率(10) Offset rate after washing
洗涤偏移率越大,则说明样品的手感风格越差。具体评价方法如下:①准备面料4块长72cm*宽52cm,每两块合一起绗缝成多个52cm长*5cm宽的条形格,在每个条形格中使用羽毛充填机充入填充物,将两端分别平缝固定后得到填充体;The greater the wash offset rate, the worse the feel of the sample. The specific evaluation methods are as follows: 1 Prepare the fabric 4 pieces of length 72cm* width 52cm, each of which is quilted into a plurality of strips of 52cm long * 5cm wide, and fill the filling with feather filling machine in each strip shape. And fixing the two ends to each other to obtain a filler;
②将填充体根据JIS L-0217标准进行洗涤,沿填充体上任一条形格切线处剪开,拍照,将照片上条形格内的有纤维的部分和无纤维的部分分别进行称量,有纤维的部分记为W1,无纤维的部分记为W2;2 The filling body is washed according to the JIS L-0217 standard, cut along any tangential line on the filling body, photographed, and the fiber-containing portion and the fiber-free portion in the strip on the photo are respectively weighed, The part of the fiber is denoted as W1, and the part without fiber is denoted as W2;
③计算,充填物洗涤后在宽度方向上的偏移率=W2/(W1+W2)*100%。以下结合实施例及比较例对本发明作进一步说明,但是本发明并不局限于以下内容。3 Calculate, the offset ratio in the width direction after the filling is washed = W2 / (W1 + W2) * 100%. The present invention will be further described below in conjunction with the examples and comparative examples, but the present invention is not limited to the following.
(11)羽毛充填机充填效率(11) Feather filling machine filling efficiency
以普通羽绒服的条形格45cm*5cm为例,使用羽毛充填机进行充填,充填效率如下评价:Taking the strip shape 45cm*5cm of the ordinary down jacket as an example, the feather filling machine is used for filling, and the filling efficiency is evaluated as follows:
如果充填一格所需时间少于2秒,认为充填效率高○;If the time required to fill a cell is less than 2 seconds, the filling efficiency is considered to be high ○;
如果充填一格所需时间为2~10秒,认为充填效率一般△;If the time required to fill a cell is 2 to 10 seconds, the filling efficiency is considered to be generally Δ;
如果充填一格所需时间超过10秒,认为充填效率低×。If it takes more than 10 seconds to fill a cell, it is considered that the filling efficiency is low ×.
实施例1Example 1
选用中空度为30%、卷曲半径为20mm的42dtex-6f-PET作为鞘纤维原料,选用中空度为20%的42dtex-12f-PET(熔点220℃)和56dtex-48f-PP DTY(熔点170℃)作为芯纤维原料,并利用不同的喂入罗拉分别喂入,其中芯纤维由熔点差为50℃的高低熔点两种纤维组成、其喂入速度为20m/min,鞘纤维的曲率半径为20mm、其喂入速度为400m/min,芯纤维中低熔点纤维所占比例为10.0重量%。设置喷嘴内空气的流速为70L/分钟,喷嘴的压空为0.35MPa,鞘丝和芯丝通过空气喷嘴形成加工丝束,接着将得到的加工丝束通过170℃的热箱进行预热处理后,再经过由硅系平滑剂调制成的硅系水溶液进行浸轧,然后经过热箱固着,得到圆环半径为5.0mm、交叉点个数为50个/cm的蓬松加工丝,接着将所得蓬松加工丝剪切成平均长度(即芯纤维平均长度)2cm、长度标准差0.2的短纤维棉,得到本发明的填充物,具体参数见表1。42dtex-6f-PET with a hollowness of 30% and a crimp radius of 20mm was selected as the sheath fiber raw material, and 42dtex-12f-PET (melting point 220°C) and 56dtex-48f-PP DTY (melting point 170°C) with a hollowness of 20% were selected. As the core fiber raw material, and fed separately by different feeding rollers, wherein the core fiber is composed of two high and low melting points with a melting point difference of 50 ° C, the feeding speed is 20 m / min, and the radius of curvature of the sheath fiber is 20 mm. The feeding speed was 400 m/min, and the proportion of the low melting point fibers in the core fiber was 10.0% by weight. The flow rate of the air in the nozzle was set to 70 L/min, and the air pressure of the nozzle was 0.35 MPa. The sheath wire and the core wire were formed into a processed tow through an air nozzle, and then the obtained processed tow was preheated by passing through a 170 ° C hot box. Then, it is padded by a silicon-based aqueous solution prepared by a silicon-based smoothing agent, and then fixed by a hot box to obtain a fluffy processed wire having a ring radius of 5.0 mm and a number of intersections of 50/cm, and then the resulting fluffy yarn is obtained. The processed yarn was cut into short fiber cotton having an average length (i.e., an average length of the core fibers) of 2 cm and a standard deviation of 0.2 in length, and the filler of the present invention was obtained. The specific parameters are shown in Table 1.
实施例2Example 2
将所得蓬松加工丝剪切成平均长度4cm、长度标准差0.3的短纤维棉,其余同实施例1,得到本发明的填充物,其各项参数见表1。The obtained fluffy processed yarn was cut into short fiber cotton having an average length of 4 cm and a standard deviation of 0.3, and the remainder was the same as in Example 1 to obtain a filler of the present invention, and the parameters thereof are shown in Table 1.
实施例3Example 3
将所得蓬松加工丝剪切成平均长度8cm、长度标准差0.3的短纤维棉,其余同实施例1,得到本发明的填充物,其各项参数见表1。The obtained fluffy processed yarn was cut into staple fiber cotton having an average length of 8 cm and a standard deviation of 0.3, and the remainder of the same manner as in Example 1 was obtained. The fillers of the present invention were obtained, and the parameters thereof are shown in Table 1.
实施例4Example 4
将作为芯纤维原料的56dtex-48f-PP DTY(熔点170℃)替换为56dtex-48f-PP DTY(熔点140℃),得到蓬松加工丝后将其剪切成长度标准差0.1的短纤维棉,其余同实施例2,得到本发明的填充物,其各项参数见表1。56dtex-48f-PP DTY (melting point 170 ° C) as a core fiber raw material was replaced with 56dtex-48f-PP DTY (melting point 140 ° C), and the fluffy processed yarn was obtained and cut into staple fiber cotton with a standard deviation of 0.1. The rest of the same as in Example 2, the filler of the present invention was obtained, and the parameters thereof are shown in Table 1.
实施例5Example 5
将作为芯纤维原料的56dtex-48f-PP DTY(熔点170℃)替换为56dtex-48f-PET DTY(熔点200℃),得到蓬松加工丝后将其剪切成长度标准差0.5的短纤维棉,其余同实施例2,得到本发明的填充物,其各项参数见表1。56dtex-48f-PP DTY (melting point 170 ° C) as a core fiber raw material was replaced by 56dtex-48f-PET DTY (melting point 200 ° C), and the fluffy processed yarn was obtained and cut into staple fiber cotton with a standard deviation of 0.5. The rest of the same as in Example 2, the filler of the present invention was obtained, and the parameters thereof are shown in Table 1.
实施例6Example 6
芯纤维中低熔点纤维所占比例调整为0.2重量%,得到蓬松加工丝后将其剪切成长度标准差0.6的短纤维棉,其余同实施例2,得到本发明的填充物,其各项参数见表1。The proportion of the low-melting fiber in the core fiber is adjusted to 0.2% by weight, and the fluffy processed yarn is obtained and then cut into short-fiber cotton having a standard deviation of 0.6, and the remainder is the same as in Example 2, and the filler of the present invention is obtained. The parameters are shown in Table 1.
实施例7Example 7
芯纤维中低熔点纤维所占比例调整为0.1重量%,得到蓬松加工丝后将其剪切成长度标准差0.8的短纤维棉,其余同实施例2,得到本发明的填充物,其各项参数见表1。The proportion of the low-melting fiber in the core fiber is adjusted to 0.1% by weight, and the fluffy processed yarn is obtained and then cut into short-fiber cotton having a standard deviation of 0.8. The remainder of the same embodiment 2 is obtained, and the filler of the present invention is obtained. The parameters are shown in Table 1.
实施例8Example 8
将鞘纤维原料替换为单丝纤度2.5dtex的PET纤维,得到蓬松加工丝后将其剪切成长度标准差1.0的短纤维棉,其余同实施例2,得到本发明的填充物,其各项参数见表1。The sheath fiber raw material was replaced with a PET fiber having a single-filament fineness of 2.5 dtex, and the fluffy processed yarn was obtained, which was then cut into staple fiber cotton having a standard deviation of 1.0. The remainder of the same manner as in Example 2, the filler of the present invention was obtained. The parameters are shown in Table 1.
实施例9Example 9
将鞘纤维原料替换为单丝纤度4.0dtex的PET纤维,得到蓬松加工丝后将其剪切成长度标准差0.4的短纤维棉,其余同实施例2,得到本发明的填充物,其各项参数见表1。The sheath fiber raw material was replaced with a PET fiber having a single-filament fineness of 4.0 dtex, and the fluffy processed yarn was obtained and cut into short-fiber cotton having a standard deviation of 0.4. The remainder of the same manner as in Example 2, the filler of the present invention was obtained. The parameters are shown in Table 1.
实施例10Example 10
鞘纤维原料替换为单丝纤度10.0dtex的PET纤维,得到蓬松加工丝后将其剪切成长度标准差0.3的短纤维棉,其余同实施例2,得到本发明的填充物,其各项参数见表1。The sheath fiber material was replaced with a PET fiber having a monofilament fineness of 10.0 dtex, and the fluffy processed yarn was obtained and cut into short fiber cotton having a length standard deviation of 0.3. The rest of the same as in Example 2, the filler of the present invention was obtained, and the parameters thereof were obtained. See Table 1.
实施例11Example 11
喷嘴的压空调节为0.20MPa,所得蓬松加工丝中,鞘纤维的圆环半径为1.0cm,得到蓬松加工丝后将其剪切成长度标准差0.1的短纤维棉,其余同实施例2,得到本发明的填充物,其各项参数见表2。The pressure adjustment of the nozzle is 0.20 MPa, and the radius of the ring of the sheath fiber is 1.0 cm in the obtained fluffy processed yarn, and the fluffy processed yarn is obtained and cut into short fiber cotton with a standard deviation of 0.1. The rest is the same as in the second embodiment. The filler of the present invention was obtained, and its various parameters are shown in Table 2.
实施例12Example 12
喷嘴的压空调节为0.40MPa,得到鞘纤维的圆环半径为2.0cm的蓬松加工丝,接着将其剪切成长度标准差0.2的短纤维棉,其余同实施例11,得到本发明的填充物,其各项参数见表2。The pressure of the nozzle was adjusted to 0.40 MPa, and a fluffy processed yarn having a ring radius of 2.0 cm of the sheath fiber was obtained, which was then cut into short fiber cotton having a standard deviation of 0.2, and the rest was the same as in Example 11 to obtain the filling of the present invention. The parameters of the substance are shown in Table 2.
实施例13Example 13
喷嘴的压空调节为0.30MPa,得到鞘纤维的圆环半径为8.0cm的蓬松加工丝,接着将其剪切成长度标准差0.5的短纤维棉,其余同实 施例2,得到本发明的填充物,其各项参数见表2。The pressure reduction of the nozzle was adjusted to 0.30 MPa, and a fluffy processed yarn having a ring radius of 8.0 cm of the sheath fiber was obtained, which was then cut into short fiber cotton having a standard deviation of 0.5, and the same as in Example 2, the filling of the present invention was obtained. The parameters of the substance are shown in Table 2.
实施例14Example 14
鞘纤维和芯纤维的原料均替换为非中空PET纤维,得到蓬松加工丝后将其剪切成长度标准差0.5的的短纤维棉,其余同实施例2,得到本发明的填充物,其各项参数见表2。The raw materials of the sheath fiber and the core fiber are replaced with non-hollow PET fibers, and the fluffy processed yarn is obtained and then cut into short fiber cotton having a standard deviation of 0.5, and the rest is the same as in Example 2, and the filler of the present invention is obtained. The item parameters are shown in Table 2.
实施例15Example 15
加工时,芯纤维的喂入速度为20m/min,鞘纤维的喂入速度为300m/min,得到鞘纤维和芯纤维的交叉点个数为38个/cm的蓬松加工丝,接着将其剪切成长度标准差0.6的短纤维棉,其余同实施例2,得到本发明的填充物,其各项参数见表2。When processing, the feeding speed of the core fiber is 20 m/min, the feeding speed of the sheath fiber is 300 m/min, and the fluffy processed yarn having the number of intersections of the sheath fiber and the core fiber of 38/cm is obtained, and then the scissors are cut. The staple fiber cotton having a length standard deviation of 0.6 was cut, and the remainder was the same as in Example 2, and the filler of the present invention was obtained, and the parameters thereof are shown in Table 2.
实施例16Example 16
加工时,芯纤维的喂入速度为20m/min,鞘纤维的喂入速度为200m/min,得到鞘纤维和芯纤维的交叉点个数为25个/cm的蓬松加工丝,接着将其剪切成长度标准差0.6的短纤维棉,其余同实施例2,得到本发明的填充物,其各项参数见表2。When processing, the feeding speed of the core fiber is 20 m/min, the feeding speed of the sheath fiber is 200 m/min, and the fluffy processed wire having the number of intersections of the sheath fiber and the core fiber of 25/cm is obtained, and then the scissors are cut. The staple fiber cotton having a length standard deviation of 0.6 was cut, and the remainder was the same as in Example 2, and the filler of the present invention was obtained, and the parameters thereof are shown in Table 2.
实施例17Example 17
所用鞘纤维的曲率半径为50mm,得到蓬松加工丝后将其剪切成长度标准差为0.3的短纤维棉,其余同实施例2,得到本发明的填充物,其各项参数见表2。The sheath fiber used had a radius of curvature of 50 mm, and was obtained by shearing the fluffed yarn into a short-fiber cotton having a standard deviation of 0.3. The remainder of the same manner as in Example 2, the filler of the present invention was obtained, and the parameters thereof are shown in Table 2.
实施例18Example 18
将羽毛与短纤维棉进行混合,混合比为50:50,其余同实施例2,得到本发明的填充物,其各项参数见表2。The feathers were mixed with the staple fiber cotton at a mixing ratio of 50:50, and the remainder was the same as in Example 2 to obtain the filler of the present invention, and the parameters thereof are shown in Table 2.
比较例1Comparative example 1
得到蓬松加工丝后将其剪切成平均长度为11cm、长度标准差为0.5的短纤维棉,其余同实施例3,得到填充物,其各项参数见表2。After the fluffy processed yarn was obtained, it was cut into staple fiber cotton having an average length of 11 cm and a standard deviation of 0.5. The remainder was the same as in Example 3, and the filler was obtained. The parameters are shown in Table 2.
比较例2Comparative example 2
得到蓬松加工丝后将其剪切成长度标准差为2.0的短纤维棉,其余同实施例3,得到填充物,其各项参数见表2。After the fluffy processed yarn was obtained, it was cut into staple fiber cotton having a standard deviation of 2.0, and the rest was obtained in the same manner as in Example 3, and the parameters thereof are shown in Table 2.
Figure PCTCN2018115788-appb-000002
Figure PCTCN2018115788-appb-000002
Figure PCTCN2018115788-appb-000003
Figure PCTCN2018115788-appb-000003
根据上表1、表2,According to the above Table 1, Table 2,
(1)由实施例2与实施例4相比可知,同等条件下,由熔点差为50℃的芯纤维形成的填充物与由熔点差为80℃的芯纤维形成的填充物相比,两者的蓬松度、羽绒充填机充填效率均相当,但前者的手感以及洗涤抗偏移性优于后者。(1) As compared with Example 4, in Example 2, it was found that under the same conditions, the filler formed of the core fiber having a difference in melting point of 50 ° C was compared with the filler formed of the core fiber having a difference in melting point of 80 ° C. The bulkiness of the person and the filling efficiency of the down filling machine are all comparable, but the former feels better than the latter.
(2)由实施例2与实施例5相比可知,同等条件下,由熔点差为50℃的芯纤维形成的填充物与由熔点差为20℃的芯纤维形成的填充物相比,两者的羽绒充填机充填效率均相当,但前者的蓬松度、手感以及洗涤抗偏移性优于后者。(2) As compared with Example 5, in Example 2, it was found that under the same conditions, the filler formed of the core fiber having a difference in melting point of 50 ° C was compared with the filler formed of the core fiber having a difference in melting point of 20 ° C. The filling efficiency of the down filling machine is equivalent, but the former has better bulkiness, feel and washing resistance than the latter.
(3)由实施例6与实施例7相比可知,同等条件下,由低熔点纤维占比为0.2重量%的芯纤维形成的填充物与由低熔点纤维占比为0.1重量%的芯纤维形成的填充物相比,两者的羽绒充填机充填效率以及手感均相当,但前者洗涤抗偏移性优于后者。(3) It can be seen from Example 6 that, under the same conditions, a filler formed of a core fiber having a low melting point fiber ratio of 0.2% by weight and a core fiber having a low melting point fiber content of 0.1% by weight. Compared with the formed filling, the filling efficiency and the hand feeling of the down filling machine are both comparable, but the former has better washing resistance than the latter.
(4)由实施例2与实施例10相比可知,同等条件下,单丝纤度7.0dtex的鞘纤维形成的填充物和单丝纤度10.0dtex的鞘纤维形成的填充物相比,两者的羽绒充填机充填效率均相当,但前者的蓬松度、洗涤抗偏移性以及手感优于后者。(4) In comparison with Example 10, it can be seen that, under the same conditions, the filler formed of the sheath fiber having a single-filament fineness of 7.0 dtex and the filler formed by the sheath fiber having a single-filament fineness of 10.0 dtex are both The filling efficiency of the down filling machine is equivalent, but the former has better bulkiness, washing anti-offset and feel than the latter.
(5)由实施例2与实施例11相比可知,同等条件下,鞘纤维圆环半径为5.0mm的填充物和鞘纤维圆环半径为1.0mm的填充物相比,两者的羽绒充填机充填效率以及手感均相当,前者的蓬松度、洗涤抗偏移性优于后者。(5) Comparing Example 2 with Example 11, it can be seen that under the same conditions, the filler having a sheath fiber ring radius of 5.0 mm and the sheath fiber ring having a radius of 1.0 mm have a lower filling filling. The filling efficiency and feel of the machine are comparable, and the former's bulkiness and washing resistance are better than the latter.
(6)由实施例2与实施例14相比可知,同等条件下,由非中空纤维作为原料形成的填充物与由中空纤维作为原料形成的填充物相比,两者的羽绒充填机充填效率以及洗涤抗偏移性均相当,但前者的蓬松度以及手感优于后者。(6) It can be seen from the comparison between Example 2 and Example 14 that under the same conditions, the filling efficiency of the both of the fillings formed of the non-hollow fibers as the raw material and the filler formed of the hollow fibers as the raw materials And the washing resistance is equal to the offset, but the former has better bulk and feel than the latter.
(7)由实施例2与实施例16相比可知,同等条件下,芯鞘纤维交叉点为 50个/cm的填充物和芯鞘纤维交叉点为25个/cm的填充物相比,两者的羽绒充填机充填效率、洗涤抗偏移性以及手感均相当,但前者的蓬松度优于后者。(7) Comparing Example 2 with Example 16, it can be seen that, under the same conditions, the filler having a core-sheath fiber intersection of 50/cm and the core-sheath fiber having a cross-section of 25/cm are compared. The down filling machine has the same filling efficiency, washing anti-offset and feel, but the former has better bulk than the latter.
(8)由比较例1与实施例3可知,同等条件下,由平均长度11cm的芯纤维所形成的填充物和由平均长度8cm的芯纤维所形成的填充物相比,前者的蓬松度、洗涤抗偏移性和手感均不及后者,羽绒充填机充填效率特别差。(8) It can be seen from Comparative Example 1 and Example 3 that, under the same conditions, the filling of the core fiber having an average length of 11 cm is smaller than the filling of the core fiber having an average length of 8 cm. The anti-offset and feel of the washing are not as good as the latter, and the filling efficiency of the down filling machine is particularly poor.
(9)由比较例2与实施例3可知,同等条件下,由平均长度标准差为0.3的芯纤维所形成的填充物和由平均长度标准差为2.0的芯纤维所形成的填充物相比,两者的蓬松度、羽绒充填机充填效率以及手感均相当,但前者的羽绒充填机充填效率比较差。(9) From Comparative Example 2 and Example 3, it was found that, under the same conditions, the filler formed of the core fiber having an average length standard deviation of 0.3 was compared with the filler formed of the core fiber having an average length standard deviation of 2.0. The fluffiness of the two, the filling efficiency of the down filling machine and the feel are quite the same, but the filling efficiency of the former's down filling machine is relatively poor.

Claims (8)

  1. 一种填充物,包括由芯纤维和鞘纤维形成的短纤维棉,其特征是:所述芯纤维由低熔点纤维与高熔点纤维构成,且低熔点纤维熔融使得芯纤维和鞘纤维固着,其中所述芯纤维的平均长度为1~10cm、长度的标准差为0~1.6,所述短纤维棉的蓬松度为200~800inch 3/30g。 A filler comprising a staple fiber cotton formed of a core fiber and a sheath fiber, wherein the core fiber is composed of a low melting point fiber and a high melting point fiber, and the low melting point fiber is melted to fix the core fiber and the sheath fiber, wherein The core fiber has an average length of 1 to 10 cm, a standard deviation of length of 0 to 1.6, and a bulkiness of the staple fiber cotton of 200 to 800 inch 3 / 30 g.
  2. 根据权利要求1所述填充物,其特征是:所述低熔点纤维与高熔点纤维的熔点差为30~150℃。The filler according to claim 1, wherein said low melting point fiber and said high melting point fiber have a melting point difference of from 30 to 150 °C.
  3. 根据权利要求1或2所述填充物,其特征是:相对于短纤维棉的总重量,所述低熔点纤维所占比例为0.2~30.0重量%。The filler according to claim 1 or 2, wherein the proportion of the low melting point fibers is from 0.2 to 30.0% by weight based on the total weight of the staple fiber.
  4. 根据权利要求1或2所述填充物,其特征是:所述芯纤维和鞘纤维交叉且鞘纤维在芯纤维外侧形成圆环状,圆环的半径为2~12mm,鞘纤维的单丝纤度为3.5~10.0dtex。The filler according to claim 1 or 2, wherein the core fiber and the sheath fiber intersect and the sheath fiber forms an annular shape on the outer side of the core fiber, and the radius of the ring is 2 to 12 mm, and the single fiber fineness of the sheath fiber It is 3.5 to 10.0 dtex.
  5. 根据权利要求4所述填充物,其特征是:所述鞘纤维与芯纤维所形成的交叉点的个数为30~150个/cm。The filler according to claim 4, wherein the number of intersections between the sheath fibers and the core fibers is 30 to 150 / cm.
  6. 根据权利要求1或2所述填充物,其特征是:所述鞘纤维和芯纤维均为中空纤维,其中空度为20%~50%。The filler according to claim 1 or 2, wherein the sheath fibers and the core fibers are hollow fibers, wherein the space is from 20% to 50%.
  7. 根据权利要求1所述填充物,其特征是:所述填充物中还包括羽毛。The filler of claim 1 wherein said filler further comprises feathers.
  8. 一种含有权利要求1所述填充物的外套、裤子、背心、连体服、冲锋衣、被子、枕头、睡袋、内衣、睡衣、毛衣、紧身裤、袜子或者运动服。A jacket, pants, vest, coveralls, jacket, quilt, pillow, sleeping bag, underwear, pajamas, sweater, leggings, socks or sportswear containing the filler of claim 1.
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WO2022093596A1 (en) * 2020-10-30 2022-05-05 Nike Innovate C.V. Sustainable nonwoven textile
US20230193524A1 (en) * 2020-06-29 2023-06-22 Toray Industries, Inc. Chenille yarn, textile product, clothing, and bedding

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CN112575443A (en) * 2019-09-30 2021-03-30 东丽纤维研究所(中国)有限公司 Filling material
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WO2022093596A1 (en) * 2020-10-30 2022-05-05 Nike Innovate C.V. Sustainable nonwoven textile

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