WO2019100471A1 - Pp-pe-pen three-matrix resin composite material - Google Patents

Pp-pe-pen three-matrix resin composite material Download PDF

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Publication number
WO2019100471A1
WO2019100471A1 PCT/CN2017/116559 CN2017116559W WO2019100471A1 WO 2019100471 A1 WO2019100471 A1 WO 2019100471A1 CN 2017116559 W CN2017116559 W CN 2017116559W WO 2019100471 A1 WO2019100471 A1 WO 2019100471A1
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parts
pen
ethylene
oxide
resin composite
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PCT/CN2017/116559
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French (fr)
Chinese (zh)
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宋懂强
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南通展鹏塑料有限公司
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • C08L67/02Polyesters derived from dicarboxylic acids and dihydroxy compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/06Polyethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10Homopolymers or copolymers of propene
    • C08L23/12Polypropene
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K5/00Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
    • C09K5/08Materials not undergoing a change of physical state when used
    • C09K5/14Solid materials, e.g. powdery or granular
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2227Oxides; Hydroxides of metals of aluminium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/04Antistatic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/14Polymer mixtures characterised by other features containing polymeric additives characterised by shape
    • C08L2205/16Fibres; Fibrils

Definitions

  • the invention relates to the technical field of plastics, in particular to a PP-PE-PEN three-base resin composite material.
  • Polypropylene non-toxic, odorless, tasteless milky white highly crystalline polymer the density of only 0.90 - "0.91g / cm 3, the plastic is one of the lightest of all its varieties of water particularly stable in water.
  • the water absorption rate is only 0.01%, the molecular weight is about 80,100,000.
  • the moldability is good, but the shrinkage rate is large (1% to 2.5%).
  • the thick-walled products are easy to sag, and it is difficult for some parts with high dimensional accuracy. To meet the requirements, the surface gloss of the product is good.
  • Different additives can be added according to different purposes.
  • Polypropylene plastic can exhibit different physical properties and mechanical properties.
  • the existing polypropylene-based composite material only has one resin matrix. How to design one The PP-PE-PEN three-matrix resin composite material is an urgent problem to be solved in the industry.
  • a PP-PE-PEN three-matrix resin composite material composed of parts by weight of the following components: PP 70-90 parts; high density PE 60-80 parts; PEN 70-90 parts; styrene-ethylene-butadiene-styrene copolymer 5-15 parts; ethylene-methyl acrylate copolymer 5-10 parts; ethylene-vinyl acetate copolymer 10-20 parts; silicon nitride particles 3-10 parts; 5-10 parts of alumina particles; 1-3 parts of azobisisoheptanenitrile; 2-5 parts of antimony trioxide; 1-3 parts of titanate coupling agent; butyl acrylate 2-7 Parts; diethylenetriamine 0.5-2 parts; trimethylolpropane trimethacrylate 0.2-1 parts; ethyl acetate 1-5 parts; manganese oxide 1-3 parts; magnesium oxide 1-4 parts; 1-3 parts of cuprous oxide, 1-5 parts of ferroferric oxide; 1-3 parts of silicon carbide; 5-10
  • the PP-PE-PEN tri-matrix resin composite is composed of parts by weight of the following components: PP 80 parts; high density PE 70 parts; PEN 90 parts; styrene-ethylene-butadiene-styrene copolymerization 10 parts; 7 parts of ethylene-methyl acrylate copolymer; 15 parts of ethylene-vinyl acetate copolymer; 5 parts of silicon nitride particles; 7 parts of alumina particles; 2 parts of azobisisoheptanenitrile; Parts; 2 parts of titanate coupling agent; 5 parts of butyl acrylate; 1 part of diethylene triamine; 0.5 part of trimethylolpropane trimethacrylate; 3 parts of ethyl acetate; 2 parts of manganese oxide; 1 part of magnesium oxide; 2 parts of cuprous oxide, four 3 parts of ferric oxide; 3 parts of silicon carbide; 7 parts of polyethylene glycol fatty acid ester; 3 parts of epoxy soybean oil; 8 parts
  • the PP-PE-PEN tri-matrix resin composite is composed of parts by weight of the following components: PP 70 parts; high density PE 80 parts; PEN 80 parts; styrene-ethylene-butadiene-styrene copolymerization 6 parts; 9 parts of ethylene-methyl acrylate copolymer; 17 parts of ethylene-vinyl acetate copolymer; 4 parts of silicon nitride particles; 6 parts of alumina particles; 3 parts of azobisisoheptanenitrile; 2 parts; titanate coupling agent 2 parts; butyl acrylate 6 parts; diethylene triamine 0.5 parts; trimethylolpropane trimethacrylate 1 part; ethyl acetate 2 parts; manganese oxide 2 parts; 3 parts of magnesium oxide; 3 parts of cuprous oxide, 5 parts of ferroferric oxide; 3 parts of silicon carbide; 9 parts of polyethylene glycol fatty acid ester; 4 parts of epoxy soybean oil; 8 parts of butyryl cit
  • the PP-PE-PEN tri-matrix resin composite is composed of parts by weight of the following components: PP 90 parts; high density PE 60 parts; PEN 80 parts; styrene-ethylene-butadiene-styrene copolymerization 12 parts; 6 parts of ethylene-methyl acrylate copolymer; 12 parts of ethylene-vinyl acetate copolymer; 8 parts of silicon nitride particles; 9 parts of alumina particles; 3 parts of azobisisoheptanenitrile; Parts; 2 parts of titanate coupling agent; 4 parts of butyl acrylate; 2 parts of diethylene triamine; 1 part of trimethylolpropane trimethacrylate; 2 parts of ethyl acetate; 3 parts of manganese oxide; 2 parts of magnesium oxide; 2 parts of cuprous oxide, 4 parts of ferroferric oxide; 2 parts of silicon carbide; 6 parts of polyethylene glycol fatty acid ester; 4 parts of epoxy soybean oil; 6 parts
  • the PP-PE-PEN tri-matrix resin composite is composed of parts by weight of the following components: PP 85 parts; high density PE 70 parts; PEN 90 parts; styrene-ethylene-butadiene-styrene copolymerization 9 parts; 7 parts of ethylene-methyl acrylate copolymer; 12 parts of ethylene-vinyl acetate copolymer; 5 parts of silicon nitride particles; 9 parts of alumina particles; 2 parts of azobisisoheptanenitrile; Parts; titanate coupling agent 3 parts; butyl acrylate 5 parts; diethylene triamine 0.5 parts; trimethylolpropane trimethacrylate 0.2 parts; ethyl acetate 4 parts; manganese oxide 3 parts; 4 parts of magnesium oxide; 2 parts of cuprous oxide, 2 parts of ferroferric oxide; 3 parts of silicon carbide; 7 parts of polyethylene glycol fatty acid ester; 3 parts of epoxy soybean oil; 7 parts of butyryl
  • the invention has the beneficial effects that the PP-PE-PEN three-matrix resin composite material of the invention has excellent comprehensive performance, good processing performance, low cost and simple production process.
  • the PP-PE-PEN three-matrix resin composite material of the present invention is added with silicon nitride particles, alumina particles, antimony trioxide, manganese oxide, magnesium oxide, cuprous oxide, triiron tetroxide, silicon carbide, indium oxide. Tin, the cooperation of various inorganic particles
  • the utility model can effectively improve the thermal conductivity and antistatic property of the PP-PE-PEN tri-base resin composite material, thereby preventing the high temperature aging of the PP-PE-PEN tri-base resin composite material.
  • the PP-PE-PEN three-matrix resin composite material of the invention is added with boron fiber and nylon fiber, and the above materials are cross-linked in the PP-PE-PEN three-base resin composite material, thereby effectively improving the PP-PE-PEN three-matrix body.
  • the toughness and tensile strength of the resin composite is added with boron fiber and nylon fiber, and the above materials are cross-linked in the PP-PE-PEN three-base resin composite material, thereby effectively improving the PP-PE-PEN three-matrix body.
  • the PP-PE-PEN three-matrix resin composite material of the invention adopts PP, PE and PEN as a tri-base body, and various additives are added at the same time, and the components are complemented by optimizing the content of each component to form a complementary phase.
  • PP-PE-PEN tri-base resin composites have excellent comprehensive properties and are suitable for use in many fields.
  • the invention provides a PP-PE-PEN three-matrix resin composite material, wherein the PP-PE-PEN three-base resin composite material is composed of the following components: PP 70-90 parts; high-density PE 60-80 parts PEN 70-90 parts; styrene-ethylene-butadiene-styrene copolymer 5-15 parts; ethylene-methyl acrylate copolymer 5-10 parts; ethylene-vinyl acetate copolymer 10-20 parts; nitriding 3-10 parts of silicon particles; 5-10 parts of alumina particles; 1-3 parts of azobisisoheptanenitrile; 2-5 parts of antimony trioxide; 1-3 parts of titanate coupling agent; butyl acrylate 2 -7 parts; diethylenetriamine 0.5-2 parts; trimethylolpropane trimethacrylate 0.2-1 parts; ethyl acetate 1-5 parts; manganese oxide 1-3 parts; magnesium oxide 1-4 Parts: 1-3 parts of cuprous oxide, 1-5
  • a PP-PE-PEN three-matrix resin composite material is composed of the following components: PP 80 parts; high density PE 70 parts; PEN 90 parts; styrene - ethylene-butadiene-styrene copolymer 10 parts; ethylene-methyl acrylate copolymer 7 parts; ethylene-vinyl acetate copolymer 15 parts; silicon nitride particles 5 parts; alumina particles 7 parts; azo diiso 2 parts of heptonitrile; 4 parts of antimony trioxide; 2 parts of titanate coupling agent; 5 parts of butyl acrylate; 1 part of diethylene triamine; 0.5 part of trimethylolpropane trimethacrylate; 3 parts of ethyl ester; 2 parts of manganese oxide; 1 part of magnesium oxide; 2 parts of cuprous oxide, 3 parts of triiron tetroxide; 3 parts of silicon carbide; 7 parts of polyethylene glycol fatty acid
  • a PP-PE-PEN three-matrix resin composite material is composed of the following components: PP 70 parts; high density PE 80 parts; PEN 80 parts; styrene - ethylene-butadiene-styrene copolymer 6 parts; ethylene-methyl acrylate copolymer 9 parts; ethylene-vinyl acetate copolymer 17 parts; silicon nitride particles 4 parts; alumina particles 6 parts; azo diiso 3 parts of heptonitrile; 2 parts of antimony trioxide; 2 parts of titanate coupling agent; 6 parts of butyl acrylate; 0.5 part of diethylene triamine; 1 part of trimethylolpropane trimethacrylate; 2 parts of ethyl ester; 2 parts of manganese oxide; 3 parts of magnesium oxide; 3 parts of cuprous oxide, 5 parts of ferroferric oxide; 3 parts of silicon carbide; 9 parts of polyethylene glycol fatty acid ester;
  • a PP-PE-PEN three-matrix resin composite material composed of parts by weight of the following components: PP 90 parts; high density PE 60 parts; PEN 80 parts; styrene - ethylene-butadiene-styrene copolymer 12 parts; ethylene-methyl acrylate copolymer 6 parts; ethylene-vinyl acetate copolymer 12 parts; silicon nitride particles 8 parts; alumina particles 9 parts; azo diiso 3 parts of heptonitrile; 3 parts of antimony trioxide; 2 parts of titanate coupling agent; 4 parts of butyl acrylate; 2 parts of diethylene triamine; 1 part of trimethylolpropane trimethacrylate; 2 parts of ethyl ester; 3 parts of manganese oxide; 2 parts of magnesium oxide; 2 parts of cuprous oxide, 4 parts of ferroferric oxide; 2 parts of silicon carbide; 6 parts of polyethylene glycol fatty acid ester; 4 parts of epoxy soybean oil; 6 parts of but
  • a PP-PE-PEN three-matrix resin composite material is composed of the following components: PP 85 parts; high density PE 70 parts; PEN 90 parts; styrene - ethylene-butadiene-styrene copolymer 9 parts; ethylene-methyl acrylate copolymer 7 parts; ethylene-vinyl acetate copolymer 12 parts; silicon nitride particles 5 parts; alumina particles 9 parts; azo diiso 2 parts of heptonitrile; 2 parts of antimony trioxide; 3 parts of titanate coupling agent; 5 parts of butyl acrylate; 0.5 part of diethylene triamine; 0.2 part of trimethylolpropane trimethacrylate; 4 parts of ethyl ester; 3 parts of manganese oxide; 4 parts of magnesium oxide; 2 parts of cuprous oxide, 2 parts of ferroferric oxide; 3 parts of silicon carbide; 7 parts of polyethylene glycol fatty acid ester
  • the PP-PE-PEN three-matrix resin composite material of the invention has excellent comprehensive performance, good processing performance, low cost and simple production process.
  • the PP-PE-PEN tri-base resin composite material of the invention is added with silicon nitride particles, alumina particles, The combination of antimony trioxide, manganese oxide, magnesium oxide, cuprous oxide, triiron tetroxide, silicon carbide, indium tin oxide and various inorganic particles effectively improves the thermal conductivity of PP-PE-PEN tri-base resin composites. Performance and antistatic properties to prevent high temperature aging of PP-PE-PEN tri-base resin composites.
  • the PP-PE-PEN three-matrix resin composite material of the invention is added with boron fiber and nylon fiber, and the above materials are cross-linked in the PP-PE-PEN three-base resin composite material, thereby effectively improving the PP-PE-PEN three-matrix body.
  • the PP-PE-PEN three-matrix resin composite material of the invention adopts PP, PE and PEN as a tri-base body, and various additives are added at the same time, and the components are complemented by optimizing the content of each component to form a complementary phase.
  • PP-PE-PEN tri-base resin composites have excellent comprehensive properties and are suitable for use in many fields.

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Combustion & Propulsion (AREA)
  • Thermal Sciences (AREA)
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  • Compositions Of Macromolecular Compounds (AREA)

Abstract

A PP-PE-PEN three-matrix resin composite material, which relates to the technical field of plastics. The PP-PE-PEN three-matrix resin composite material uses PP, PE and PEN as matrices of the resin composite material, and contains various functional assistants. By optimizing the types and the contents of the assistants, the PP-PE-PEN three-matrix resin composite material has excellent comprehensive performance, good processing performance, low costs and a simple production process.

Description

[根据细则37.2由ISA制定的发明名称] PP-PE-PEN三基体树脂复合材料[Name of invention established by ISA according to Rule 37.2] PP-PE-PEN tri-base resin composite 技术领域Technical field
本发明涉及塑料技术领域,特别是涉及一种PP-PE-PEN三基体树脂复合材料。The invention relates to the technical field of plastics, in particular to a PP-PE-PEN three-base resin composite material.
背景技术Background technique
聚丙烯为无毒、无臭、无味的乳白色高结晶的聚合物,密度只有0.90--"0.91g/cm3,是目前所有塑料中最轻的品种之一。它对水特别稳定,在水中的吸水率仅为0.01%,分子量约8万一15万。成型性好,但因收缩率大(为1%~2.5%).厚壁制品易凹陷,对一些尺寸精度较高零件,很难于达到要求,制品表面光泽好。根据不同的用途可以加入不同的添加剂,聚丙烯塑料可呈现不同的物理性能和力学性能。而现有的基于聚丙烯的复合材料仅具有一个树脂基体。如何设计一种PP-PE-PEN三基体树脂复合材料,是业界亟待解决的问题。Polypropylene non-toxic, odorless, tasteless milky white highly crystalline polymer, the density of only 0.90 - "0.91g / cm 3, the plastic is one of the lightest of all its varieties of water particularly stable in water. The water absorption rate is only 0.01%, the molecular weight is about 80,100,000. The moldability is good, but the shrinkage rate is large (1% to 2.5%). The thick-walled products are easy to sag, and it is difficult for some parts with high dimensional accuracy. To meet the requirements, the surface gloss of the product is good. Different additives can be added according to different purposes. Polypropylene plastic can exhibit different physical properties and mechanical properties. The existing polypropylene-based composite material only has one resin matrix. How to design one The PP-PE-PEN three-matrix resin composite material is an urgent problem to be solved in the industry.
发明内容Summary of the invention
本发明的目的在于避免现有技术中的不足之处而提供一种PP-PE-PEN三基体树脂复合材料。It is an object of the present invention to provide a PP-PE-PEN tri-matrix resin composite material that avoids the deficiencies in the prior art.
本发明的目的通过以下技术方案实现:The object of the invention is achieved by the following technical solutions:
提供一种PP-PE-PEN三基体树脂复合材料,所述PP-PE-PEN三基体树脂复合材料由以下组分的重量份组成:PP 70-90份;高密度PE 60-80份;PEN 70-90份;苯乙烯-乙烯-丁二烯-苯乙烯共聚物5-15份;乙烯-丙烯酸甲酯共聚物5-10份;乙烯-醋酸乙烯共聚物10-20份;氮化硅颗粒3-10份;氧化铝颗粒5-10份;偶氮二异庚腈1-3份;三氧化二锑2-5份;钛酸酯偶联剂1-3份;丙烯酸丁酯2-7份;二亚乙基三胺0.5-2份;三羟甲基丙烷三甲基丙烯酸酯0.2-1份;醋酸乙酯1-5份;氧化锰1-3份;氧化镁1-4份;氧化亚铜1-3份,四氧化三铁1-5份;碳化硅1-3份;聚乙二醇脂肪酸酯5-10份;环氧大豆油2-5份;丁酰柠檬酸三正己酯5-10份;二碱式亚磷酸铅2-5份;锡酸锌1-5份;聚脂肪酸酯2-6份;石蜡1-3份;十八烷基三溴化铵1-3份;二烷基马来酸二丁基锡3-8份;硼纤维3-6份;尼龙纤维2-5份;氧化铟锡1-3份。Provided is a PP-PE-PEN three-matrix resin composite material composed of parts by weight of the following components: PP 70-90 parts; high density PE 60-80 parts; PEN 70-90 parts; styrene-ethylene-butadiene-styrene copolymer 5-15 parts; ethylene-methyl acrylate copolymer 5-10 parts; ethylene-vinyl acetate copolymer 10-20 parts; silicon nitride particles 3-10 parts; 5-10 parts of alumina particles; 1-3 parts of azobisisoheptanenitrile; 2-5 parts of antimony trioxide; 1-3 parts of titanate coupling agent; butyl acrylate 2-7 Parts; diethylenetriamine 0.5-2 parts; trimethylolpropane trimethacrylate 0.2-1 parts; ethyl acetate 1-5 parts; manganese oxide 1-3 parts; magnesium oxide 1-4 parts; 1-3 parts of cuprous oxide, 1-5 parts of ferroferric oxide; 1-3 parts of silicon carbide; 5-10 parts of polyethylene glycol fatty acid ester; 2-5 parts of epoxidized soybean oil; 5-10 parts of n-hexyl ester; 2-5 parts of dibasic lead phosphite; 1-5 parts of zinc stannate; 2-6 parts of poly fatty acid ester; 1-3 parts of paraffin; octadecyl ammonium tribromide 1 -3 parts; 3-8 parts of dibutyltin dialkyl maleate; 3-6 parts of boron fiber; 2-5 parts of nylon fiber; 1-3 parts of indium tin oxide.
作为优选,所述PP-PE-PEN三基体树脂复合材料由以下组分的重量份组成:PP 80份;高密度PE 70份;PEN 90份;苯乙烯-乙烯-丁二烯-苯乙烯共聚物10份;乙烯-丙烯酸甲酯共聚物7份;乙烯-醋酸乙烯共聚物15份;氮化硅颗粒5份;氧化铝颗粒7份;偶氮二异庚腈2份;三氧化二锑4份;钛酸酯偶联剂2份;丙烯酸丁酯5份;二亚乙基三胺1份;三羟甲基丙烷三甲基丙烯酸酯0.5份;醋酸乙酯3份;氧化锰2份;氧化镁1份;氧化亚铜2份,四 氧化三铁3份;碳化硅3份;聚乙二醇脂肪酸酯7份;环氧大豆油3份;丁酰柠檬酸三正己酯8份;二碱式亚磷酸铅3份;锡酸锌3份;聚脂肪酸酯4份;石蜡2份;十八烷基三溴化铵1份;二烷基马来酸二丁基锡6份;硼纤维4份;尼龙纤维2份;氧化铟锡2份。Preferably, the PP-PE-PEN tri-matrix resin composite is composed of parts by weight of the following components: PP 80 parts; high density PE 70 parts; PEN 90 parts; styrene-ethylene-butadiene-styrene copolymerization 10 parts; 7 parts of ethylene-methyl acrylate copolymer; 15 parts of ethylene-vinyl acetate copolymer; 5 parts of silicon nitride particles; 7 parts of alumina particles; 2 parts of azobisisoheptanenitrile; Parts; 2 parts of titanate coupling agent; 5 parts of butyl acrylate; 1 part of diethylene triamine; 0.5 part of trimethylolpropane trimethacrylate; 3 parts of ethyl acetate; 2 parts of manganese oxide; 1 part of magnesium oxide; 2 parts of cuprous oxide, four 3 parts of ferric oxide; 3 parts of silicon carbide; 7 parts of polyethylene glycol fatty acid ester; 3 parts of epoxy soybean oil; 8 parts of butyric acid tri-n-hexyl citrate; 3 parts of dibasic lead phosphite; zinc stannate 3 parts; 4 parts of poly fatty acid ester; 2 parts of paraffin; 1 part of octadecyl ammonium tribromide; 6 parts of dibutyltin dialkyl maleate; 4 parts of boron fiber; 2 parts of nylon fiber; Share.
作为优选,所述PP-PE-PEN三基体树脂复合材料由以下组分的重量份组成:PP 70份;高密度PE 80份;PEN 80份;苯乙烯-乙烯-丁二烯-苯乙烯共聚物6份;乙烯-丙烯酸甲酯共聚物9份;乙烯-醋酸乙烯共聚物17份;氮化硅颗粒4份;氧化铝颗粒6份;偶氮二异庚腈3份;三氧化二锑2份;钛酸酯偶联剂2份;丙烯酸丁酯6份;二亚乙基三胺0.5份;三羟甲基丙烷三甲基丙烯酸酯1份;醋酸乙酯2份;氧化锰2份;氧化镁3份;氧化亚铜3份,四氧化三铁5份;碳化硅3份;聚乙二醇脂肪酸酯9份;环氧大豆油4份;丁酰柠檬酸三正己酯8份;二碱式亚磷酸铅3份;锡酸锌2份;聚脂肪酸酯3份;石蜡3份;十八烷基三溴化铵1份;二烷基马来酸二丁基锡4份;硼纤维5份;尼龙纤维4份;氧化铟锡3份。Preferably, the PP-PE-PEN tri-matrix resin composite is composed of parts by weight of the following components: PP 70 parts; high density PE 80 parts; PEN 80 parts; styrene-ethylene-butadiene-styrene copolymerization 6 parts; 9 parts of ethylene-methyl acrylate copolymer; 17 parts of ethylene-vinyl acetate copolymer; 4 parts of silicon nitride particles; 6 parts of alumina particles; 3 parts of azobisisoheptanenitrile; 2 parts; titanate coupling agent 2 parts; butyl acrylate 6 parts; diethylene triamine 0.5 parts; trimethylolpropane trimethacrylate 1 part; ethyl acetate 2 parts; manganese oxide 2 parts; 3 parts of magnesium oxide; 3 parts of cuprous oxide, 5 parts of ferroferric oxide; 3 parts of silicon carbide; 9 parts of polyethylene glycol fatty acid ester; 4 parts of epoxy soybean oil; 8 parts of butyryl citrate tri-n-hexyl ester; 3 parts of dibasic lead phosphite; 2 parts of zinc stannate; 3 parts of poly fatty acid ester; 3 parts of paraffin; 1 part of octadecyl ammonium tribromide; 4 parts of dibutyltin dialkyl maleate; 5 parts; 4 parts of nylon fiber; 3 parts of indium tin oxide.
作为优选,所述PP-PE-PEN三基体树脂复合材料由以下组分的重量份组成:PP 90份;高密度PE 60份;PEN 80份;苯乙烯-乙烯-丁二烯-苯乙烯共聚物12份;乙烯-丙烯酸甲酯共聚物6份;乙烯-醋酸乙烯共聚物12份;氮化硅颗粒8份;氧化铝颗粒9份;偶氮二异庚腈3份;三氧化二锑3份;钛酸酯偶联剂2份;丙烯酸丁酯4份;二亚乙基三胺2份;三羟甲基丙烷三甲基丙烯酸酯1份;醋酸乙酯2份;氧化锰3份;氧化镁2份;氧化亚铜2份,四氧化三铁4份;碳化硅2份;聚乙二醇脂肪酸酯6份;环氧大豆油4份;丁酰柠檬酸三正己酯6份;二碱式亚磷酸铅4份;锡酸锌4份;聚脂肪酸酯2份;石蜡3份;十八烷基三溴化铵3份;二烷基马来酸二丁基锡6份;硼纤维4份;尼龙纤维3份;氧化铟锡2份。Preferably, the PP-PE-PEN tri-matrix resin composite is composed of parts by weight of the following components: PP 90 parts; high density PE 60 parts; PEN 80 parts; styrene-ethylene-butadiene-styrene copolymerization 12 parts; 6 parts of ethylene-methyl acrylate copolymer; 12 parts of ethylene-vinyl acetate copolymer; 8 parts of silicon nitride particles; 9 parts of alumina particles; 3 parts of azobisisoheptanenitrile; Parts; 2 parts of titanate coupling agent; 4 parts of butyl acrylate; 2 parts of diethylene triamine; 1 part of trimethylolpropane trimethacrylate; 2 parts of ethyl acetate; 3 parts of manganese oxide; 2 parts of magnesium oxide; 2 parts of cuprous oxide, 4 parts of ferroferric oxide; 2 parts of silicon carbide; 6 parts of polyethylene glycol fatty acid ester; 4 parts of epoxy soybean oil; 6 parts of butyryl citrate tri-n-hexyl ester; 4 parts of dibasic lead phosphite; 4 parts of zinc stannate; 2 parts of poly fatty acid ester; 3 parts of paraffin; 3 parts of octadecyl ammonium tribromide; 6 parts of dibutyltin dialkyl maleate; 4 parts; 3 parts of nylon fiber; 2 parts of indium tin oxide.
作为优选,所述PP-PE-PEN三基体树脂复合材料由以下组分的重量份组成:PP 85份;高密度PE 70份;PEN 90份;苯乙烯-乙烯-丁二烯-苯乙烯共聚物9份;乙烯-丙烯酸甲酯共聚物7份;乙烯-醋酸乙烯共聚物12份;氮化硅颗粒5份;氧化铝颗粒9份;偶氮二异庚腈2份;三氧化二锑2份;钛酸酯偶联剂3份;丙烯酸丁酯5份;二亚乙基三胺0.5份;三羟甲基丙烷三甲基丙烯酸酯0.2份;醋酸乙酯4份;氧化锰3份;氧化镁4份;氧化亚铜2份,四氧化三铁2份;碳化硅3份;聚乙二醇脂肪酸酯7份;环氧大豆油3份;丁酰柠檬酸三正己酯7份;二碱式亚磷酸铅2份;锡酸锌5份;聚脂肪酸酯3份;石蜡2份;十八烷基三溴化铵2份;二烷基马来酸二丁基锡3份;硼纤维4份;尼龙纤维5份;氧化铟锡3份。Preferably, the PP-PE-PEN tri-matrix resin composite is composed of parts by weight of the following components: PP 85 parts; high density PE 70 parts; PEN 90 parts; styrene-ethylene-butadiene-styrene copolymerization 9 parts; 7 parts of ethylene-methyl acrylate copolymer; 12 parts of ethylene-vinyl acetate copolymer; 5 parts of silicon nitride particles; 9 parts of alumina particles; 2 parts of azobisisoheptanenitrile; Parts; titanate coupling agent 3 parts; butyl acrylate 5 parts; diethylene triamine 0.5 parts; trimethylolpropane trimethacrylate 0.2 parts; ethyl acetate 4 parts; manganese oxide 3 parts; 4 parts of magnesium oxide; 2 parts of cuprous oxide, 2 parts of ferroferric oxide; 3 parts of silicon carbide; 7 parts of polyethylene glycol fatty acid ester; 3 parts of epoxy soybean oil; 7 parts of butyryl citrate tri-n-hexyl ester; 2 parts of dibasic lead phosphite; 5 parts of zinc stannate; 3 parts of poly fatty acid ester; 2 parts of paraffin; 2 parts of octadecyl ammonium tribromide; 3 parts of dibutyltin dialkyl maleate; boron fiber 4 parts; 5 parts of nylon fiber; 3 parts of indium tin oxide.
本发明的有益效果:本发明的PP-PE-PEN三基体树脂复合材料具有优异的综合性能,且加工性能好,成本低,生产工艺简单。The invention has the beneficial effects that the PP-PE-PEN three-matrix resin composite material of the invention has excellent comprehensive performance, good processing performance, low cost and simple production process.
本发明的PP-PE-PEN三基体树脂复合材料中添加有氮化硅颗粒、氧化铝颗粒、三氧化二锑、氧化锰、氧化镁、氧化亚铜、四氧化三铁、碳化硅、氧化铟锡,多种无机颗粒的配合作 用,有效提高了PP-PE-PEN三基体树脂复合材料的导热性能以及抗静电性能,进而防止PP-PE-PEN三基体树脂复合材料高温老化。The PP-PE-PEN three-matrix resin composite material of the present invention is added with silicon nitride particles, alumina particles, antimony trioxide, manganese oxide, magnesium oxide, cuprous oxide, triiron tetroxide, silicon carbide, indium oxide. Tin, the cooperation of various inorganic particles The utility model can effectively improve the thermal conductivity and antistatic property of the PP-PE-PEN tri-base resin composite material, thereby preventing the high temperature aging of the PP-PE-PEN tri-base resin composite material.
本发明的PP-PE-PEN三基体树脂复合材料中添加有硼纤维、尼龙纤维,上述材料在PP-PE-PEN三基体树脂复合材料中相互交联,有效提高了PP-PE-PEN三基体树脂复合材料的韧性和拉伸强度。The PP-PE-PEN three-matrix resin composite material of the invention is added with boron fiber and nylon fiber, and the above materials are cross-linked in the PP-PE-PEN three-base resin composite material, thereby effectively improving the PP-PE-PEN three-matrix body. The toughness and tensile strength of the resin composite.
本发明的PP-PE-PEN三基体树脂复合材料中以PP、PE和PEN为三基体,同时添加有各种助剂,通过优化各组分的含量,使得各组分之间相辅相成,形成的PP-PE-PEN三基体树脂复合材料综合性能优异,适合用于多种领域。The PP-PE-PEN three-matrix resin composite material of the invention adopts PP, PE and PEN as a tri-base body, and various additives are added at the same time, and the components are complemented by optimizing the content of each component to form a complementary phase. PP-PE-PEN tri-base resin composites have excellent comprehensive properties and are suitable for use in many fields.
具体实施方式Detailed ways
以下结合实施例对本发明作进一步详细描述。The invention is further described in detail below with reference to the embodiments.
本发明提供一种PP-PE-PEN三基体树脂复合材料,所述PP-PE-PEN三基体树脂复合材料由以下组分的重量份组成:PP 70-90份;高密度PE 60-80份;PEN 70-90份;苯乙烯-乙烯-丁二烯-苯乙烯共聚物5-15份;乙烯-丙烯酸甲酯共聚物5-10份;乙烯-醋酸乙烯共聚物10-20份;氮化硅颗粒3-10份;氧化铝颗粒5-10份;偶氮二异庚腈1-3份;三氧化二锑2-5份;钛酸酯偶联剂1-3份;丙烯酸丁酯2-7份;二亚乙基三胺0.5-2份;三羟甲基丙烷三甲基丙烯酸酯0.2-1份;醋酸乙酯1-5份;氧化锰1-3份;氧化镁1-4份;氧化亚铜1-3份,四氧化三铁1-5份;碳化硅1-3份;聚乙二醇脂肪酸酯5-10份;环氧大豆油2-5份;丁酰柠檬酸三正己酯5-10份;二碱式亚磷酸铅2-5份;锡酸锌1-5份;聚脂肪酸酯2-6份;石蜡1-3份;十八烷基三溴化铵1-3份;二烷基马来酸二丁基锡3-8份;硼纤维3-6份;尼龙纤维2-5份;氧化铟锡1-3份。The invention provides a PP-PE-PEN three-matrix resin composite material, wherein the PP-PE-PEN three-base resin composite material is composed of the following components: PP 70-90 parts; high-density PE 60-80 parts PEN 70-90 parts; styrene-ethylene-butadiene-styrene copolymer 5-15 parts; ethylene-methyl acrylate copolymer 5-10 parts; ethylene-vinyl acetate copolymer 10-20 parts; nitriding 3-10 parts of silicon particles; 5-10 parts of alumina particles; 1-3 parts of azobisisoheptanenitrile; 2-5 parts of antimony trioxide; 1-3 parts of titanate coupling agent; butyl acrylate 2 -7 parts; diethylenetriamine 0.5-2 parts; trimethylolpropane trimethacrylate 0.2-1 parts; ethyl acetate 1-5 parts; manganese oxide 1-3 parts; magnesium oxide 1-4 Parts: 1-3 parts of cuprous oxide, 1-5 parts of ferroferric oxide; 1-3 parts of silicon carbide; 5-10 parts of polyethylene glycol fatty acid ester; 2-5 parts of epoxy soybean oil; butyryl lemon 5-10 parts of tri-n-hexyl acrylate; 2-5 parts of dibasic lead phosphite; 1-5 parts of zinc stannate; 2-6 parts of poly-fatty acid ester; 1-3 parts of paraffin; octadecyl tribromination 1-3 parts of ammonium; 3-8 parts of dibutyltin dialkyl maleate; 3-6 parts of boron fiber; 2-5 parts of nylon fiber; 1-3 parts of indium tin oxide.
实施例1Example 1
一种PP-PE-PEN三基体树脂复合材料,所述PP-PE-PEN三基体树脂复合材料由以下组分的重量份组成:PP 80份;高密度PE 70份;PEN 90份;苯乙烯-乙烯-丁二烯-苯乙烯共聚物10份;乙烯-丙烯酸甲酯共聚物7份;乙烯-醋酸乙烯共聚物15份;氮化硅颗粒5份;氧化铝颗粒7份;偶氮二异庚腈2份;三氧化二锑4份;钛酸酯偶联剂2份;丙烯酸丁酯5份;二亚乙基三胺1份;三羟甲基丙烷三甲基丙烯酸酯0.5份;醋酸乙酯3份;氧化锰2份;氧化镁1份;氧化亚铜2份,四氧化三铁3份;碳化硅3份;聚乙二醇脂肪酸酯7份;环氧大豆油3份;丁酰柠檬酸三正己酯8份;二碱式亚磷酸铅3份;锡酸锌3份;聚脂肪酸酯4份;石蜡2份;十八烷基三溴化铵1份;二烷基马来酸二丁基锡6份;硼纤维4份;尼龙纤维2份;氧化铟锡2份。A PP-PE-PEN three-matrix resin composite material, the PP-PE-PEN three-matrix resin composite material is composed of the following components: PP 80 parts; high density PE 70 parts; PEN 90 parts; styrene - ethylene-butadiene-styrene copolymer 10 parts; ethylene-methyl acrylate copolymer 7 parts; ethylene-vinyl acetate copolymer 15 parts; silicon nitride particles 5 parts; alumina particles 7 parts; azo diiso 2 parts of heptonitrile; 4 parts of antimony trioxide; 2 parts of titanate coupling agent; 5 parts of butyl acrylate; 1 part of diethylene triamine; 0.5 part of trimethylolpropane trimethacrylate; 3 parts of ethyl ester; 2 parts of manganese oxide; 1 part of magnesium oxide; 2 parts of cuprous oxide, 3 parts of triiron tetroxide; 3 parts of silicon carbide; 7 parts of polyethylene glycol fatty acid ester; 3 parts of epoxy soybean oil; 8 parts of butyryl citrate tri-n-hexyl ester; 3 parts of dibasic lead phosphite; 3 parts of zinc stannate; 4 parts of poly-fatty acid ester; 2 parts of paraffin; 1 part of octadecyl ammonium tribromide; 6 parts of dibutyltin maleate; 4 parts of boron fiber; 2 parts of nylon fiber; 2 parts of indium tin oxide.
实施例2 Example 2
一种PP-PE-PEN三基体树脂复合材料,所述PP-PE-PEN三基体树脂复合材料由以下组分的重量份组成:PP 70份;高密度PE 80份;PEN 80份;苯乙烯-乙烯-丁二烯-苯乙烯共聚物6份;乙烯-丙烯酸甲酯共聚物9份;乙烯-醋酸乙烯共聚物17份;氮化硅颗粒4份;氧化铝颗粒6份;偶氮二异庚腈3份;三氧化二锑2份;钛酸酯偶联剂2份;丙烯酸丁酯6份;二亚乙基三胺0.5份;三羟甲基丙烷三甲基丙烯酸酯1份;醋酸乙酯2份;氧化锰2份;氧化镁3份;氧化亚铜3份,四氧化三铁5份;碳化硅3份;聚乙二醇脂肪酸酯9份;环氧大豆油4份;丁酰柠檬酸三正己酯8份;二碱式亚磷酸铅3份;锡酸锌2份;聚脂肪酸酯3份;石蜡3份;十八烷基三溴化铵1份;二烷基马来酸二丁基锡4份;硼纤维5份;尼龙纤维4份;氧化铟锡3份。A PP-PE-PEN three-matrix resin composite material, the PP-PE-PEN three-base resin composite material is composed of the following components: PP 70 parts; high density PE 80 parts; PEN 80 parts; styrene - ethylene-butadiene-styrene copolymer 6 parts; ethylene-methyl acrylate copolymer 9 parts; ethylene-vinyl acetate copolymer 17 parts; silicon nitride particles 4 parts; alumina particles 6 parts; azo diiso 3 parts of heptonitrile; 2 parts of antimony trioxide; 2 parts of titanate coupling agent; 6 parts of butyl acrylate; 0.5 part of diethylene triamine; 1 part of trimethylolpropane trimethacrylate; 2 parts of ethyl ester; 2 parts of manganese oxide; 3 parts of magnesium oxide; 3 parts of cuprous oxide, 5 parts of ferroferric oxide; 3 parts of silicon carbide; 9 parts of polyethylene glycol fatty acid ester; 4 parts of epoxy soybean oil; 8 parts of butyryl citrate tri-n-hexyl acrylate; 3 parts of dibasic lead phosphite; 2 parts of zinc stannate; 3 parts of poly-fatty acid ester; 3 parts of paraffin; 1 part of octadecyl ammonium tribromide; 4 parts of dibutyltin maleate; 5 parts of boron fiber; 4 parts of nylon fiber; 3 parts of indium tin oxide.
实施例3Example 3
一种PP-PE-PEN三基体树脂复合材料,所述PP-PE-PEN三基体树脂复合材料由以下组分的重量份组成:PP 90份;高密度PE 60份;PEN 80份;苯乙烯-乙烯-丁二烯-苯乙烯共聚物12份;乙烯-丙烯酸甲酯共聚物6份;乙烯-醋酸乙烯共聚物12份;氮化硅颗粒8份;氧化铝颗粒9份;偶氮二异庚腈3份;三氧化二锑3份;钛酸酯偶联剂2份;丙烯酸丁酯4份;二亚乙基三胺2份;三羟甲基丙烷三甲基丙烯酸酯1份;醋酸乙酯2份;氧化锰3份;氧化镁2份;氧化亚铜2份,四氧化三铁4份;碳化硅2份;聚乙二醇脂肪酸酯6份;环氧大豆油4份;丁酰柠檬酸三正己酯6份;二碱式亚磷酸铅4份;锡酸锌4份;聚脂肪酸酯2份;石蜡3份;十八烷基三溴化铵3份;二烷基马来酸二丁基锡6份;硼纤维4份;尼龙纤维3份;氧化铟锡2份。A PP-PE-PEN three-matrix resin composite material composed of parts by weight of the following components: PP 90 parts; high density PE 60 parts; PEN 80 parts; styrene - ethylene-butadiene-styrene copolymer 12 parts; ethylene-methyl acrylate copolymer 6 parts; ethylene-vinyl acetate copolymer 12 parts; silicon nitride particles 8 parts; alumina particles 9 parts; azo diiso 3 parts of heptonitrile; 3 parts of antimony trioxide; 2 parts of titanate coupling agent; 4 parts of butyl acrylate; 2 parts of diethylene triamine; 1 part of trimethylolpropane trimethacrylate; 2 parts of ethyl ester; 3 parts of manganese oxide; 2 parts of magnesium oxide; 2 parts of cuprous oxide, 4 parts of ferroferric oxide; 2 parts of silicon carbide; 6 parts of polyethylene glycol fatty acid ester; 4 parts of epoxy soybean oil; 6 parts of butyryl citrate tri-n-hexyl ester; 4 parts of dibasic lead phosphite; 4 parts of zinc stannate; 2 parts of poly-fatty acid ester; 3 parts of paraffin; 3 parts of octadecyl ammonium tribromide; 6 parts of dibutyltin maleate; 4 parts of boron fiber; 3 parts of nylon fiber; 2 parts of indium tin oxide.
实施例4Example 4
一种PP-PE-PEN三基体树脂复合材料,所述PP-PE-PEN三基体树脂复合材料由以下组分的重量份组成:PP 85份;高密度PE 70份;PEN 90份;苯乙烯-乙烯-丁二烯-苯乙烯共聚物9份;乙烯-丙烯酸甲酯共聚物7份;乙烯-醋酸乙烯共聚物12份;氮化硅颗粒5份;氧化铝颗粒9份;偶氮二异庚腈2份;三氧化二锑2份;钛酸酯偶联剂3份;丙烯酸丁酯5份;二亚乙基三胺0.5份;三羟甲基丙烷三甲基丙烯酸酯0.2份;醋酸乙酯4份;氧化锰3份;氧化镁4份;氧化亚铜2份,四氧化三铁2份;碳化硅3份;聚乙二醇脂肪酸酯7份;环氧大豆油3份;丁酰柠檬酸三正己酯7份;二碱式亚磷酸铅2份;锡酸锌5份;聚脂肪酸酯3份;石蜡2份;十八烷基三溴化铵2份;二烷基马来酸二丁基锡3份;硼纤维4份;尼龙纤维5份;氧化铟锡3份。A PP-PE-PEN three-matrix resin composite material, the PP-PE-PEN three-base resin composite material is composed of the following components: PP 85 parts; high density PE 70 parts; PEN 90 parts; styrene - ethylene-butadiene-styrene copolymer 9 parts; ethylene-methyl acrylate copolymer 7 parts; ethylene-vinyl acetate copolymer 12 parts; silicon nitride particles 5 parts; alumina particles 9 parts; azo diiso 2 parts of heptonitrile; 2 parts of antimony trioxide; 3 parts of titanate coupling agent; 5 parts of butyl acrylate; 0.5 part of diethylene triamine; 0.2 part of trimethylolpropane trimethacrylate; 4 parts of ethyl ester; 3 parts of manganese oxide; 4 parts of magnesium oxide; 2 parts of cuprous oxide, 2 parts of ferroferric oxide; 3 parts of silicon carbide; 7 parts of polyethylene glycol fatty acid ester; 3 parts of epoxy soybean oil; 7 parts of butyryl citrate tri-n-hexyl acrylate; 2 parts of dibasic lead phosphite; 5 parts of zinc stannate; 3 parts of poly-fatty acid ester; 2 parts of paraffin; 2 parts of octadecyl ammonium tribromide; 3 parts of dibutyltin maleate; 4 parts of boron fiber; 5 parts of nylon fiber; 3 parts of indium tin oxide.
本发明的PP-PE-PEN三基体树脂复合材料具有优异的综合性能,且加工性能好,成本低,生产工艺简单。本发明的PP-PE-PEN三基体树脂复合材料中添加有氮化硅颗粒、氧化铝颗粒、 三氧化二锑、氧化锰、氧化镁、氧化亚铜、四氧化三铁、碳化硅、氧化铟锡,多种无机颗粒的配合作用,有效提高了PP-PE-PEN三基体树脂复合材料的导热性能以及抗静电性能,进而防止PP-PE-PEN三基体树脂复合材料高温老化。本发明的PP-PE-PEN三基体树脂复合材料中添加有硼纤维、尼龙纤维,上述材料在PP-PE-PEN三基体树脂复合材料中相互交联,有效提高了PP-PE-PEN三基体树脂复合材料的韧性和拉伸强度。本发明的PP-PE-PEN三基体树脂复合材料中以PP、PE和PEN为三基体,同时添加有各种助剂,通过优化各组分的含量,使得各组分之间相辅相成,形成的PP-PE-PEN三基体树脂复合材料综合性能优异,适合用于多种领域。The PP-PE-PEN three-matrix resin composite material of the invention has excellent comprehensive performance, good processing performance, low cost and simple production process. The PP-PE-PEN tri-base resin composite material of the invention is added with silicon nitride particles, alumina particles, The combination of antimony trioxide, manganese oxide, magnesium oxide, cuprous oxide, triiron tetroxide, silicon carbide, indium tin oxide and various inorganic particles effectively improves the thermal conductivity of PP-PE-PEN tri-base resin composites. Performance and antistatic properties to prevent high temperature aging of PP-PE-PEN tri-base resin composites. The PP-PE-PEN three-matrix resin composite material of the invention is added with boron fiber and nylon fiber, and the above materials are cross-linked in the PP-PE-PEN three-base resin composite material, thereby effectively improving the PP-PE-PEN three-matrix body. The toughness and tensile strength of the resin composite. The PP-PE-PEN three-matrix resin composite material of the invention adopts PP, PE and PEN as a tri-base body, and various additives are added at the same time, and the components are complemented by optimizing the content of each component to form a complementary phase. PP-PE-PEN tri-base resin composites have excellent comprehensive properties and are suitable for use in many fields.
最后应当说明的是,以上实施例仅用于说明本发明的技术方案而非对本发明保护范围的限制,尽管参照较佳实施例对本发明作了详细说明,本领域的普通技术人员应当理解,可以对本发明的技术方案进行修改或者等同替换,而不脱离本发明技术方案的实质和范围。 It should be noted that the above embodiments are only used to illustrate the technical solutions of the present invention and are not intended to limit the scope of the present invention. Although the present invention is described in detail with reference to the preferred embodiments, those skilled in the art The technical solutions of the present invention are modified or equivalently substituted without departing from the spirit and scope of the technical solutions of the present invention.

Claims (5)

  1. 一种PP-PE-PEN三基体树脂复合材料,其特征在于,所述PP-PE-PEN三基体树脂复合材料由以下组分的重量份组成:PP 70-90份;高密度PE 60-80份;PEN 70-90份;苯乙烯-乙烯-丁二烯-苯乙烯共聚物5-15份;乙烯-丙烯酸甲酯共聚物5-10份;乙烯-醋酸乙烯共聚物10-20份;氮化硅颗粒3-10份;氧化铝颗粒5-10份;偶氮二异庚腈1-3份;三氧化二锑2-5份;钛酸酯偶联剂1-3份;丙烯酸丁酯2-7份;二亚乙基三胺0.5-2份;三羟甲基丙烷三甲基丙烯酸酯0.2-1份;醋酸乙酯1-5份;氧化锰1-3份;氧化镁1-4份;氧化亚铜1-3份,四氧化三铁1-5份;碳化硅1-3份;聚乙二醇脂肪酸酯5-10份;环氧大豆油2-5份;丁酰柠檬酸三正己酯5-10份;二碱式亚磷酸铅2-5份;锡酸锌1-5份;聚脂肪酸酯2-6份;石蜡1-3份;十八烷基三溴化铵1-3份;二烷基马来酸二丁基锡3-8份;硼纤维3-6份;尼龙纤维2-5份;氧化铟锡1-3份。A PP-PE-PEN three-matrix resin composite material, characterized in that the PP-PE-PEN three-base resin composite material is composed of parts by weight of the following components: PP 70-90 parts; high density PE 60-80 Parts; PEN 70-90 parts; styrene-ethylene-butadiene-styrene copolymer 5-15 parts; ethylene-methyl acrylate copolymer 5-10 parts; ethylene-vinyl acetate copolymer 10-20 parts; nitrogen 3-10 parts of silicon particles; 5-10 parts of alumina particles; 1-3 parts of azobisisoheptonitrile; 2-5 parts of antimony trioxide; 1-3 parts of titanate coupling agent; butyl acrylate 2-7 parts; diethylenetriamine 0.5-2 parts; trimethylolpropane trimethacrylate 0.2-1 part; ethyl acetate 1-5 parts; manganese oxide 1-3 parts; magnesium oxide 1- 4 parts; 1-3 parts of cuprous oxide, 1-5 parts of ferroferric oxide; 1-3 parts of silicon carbide; 5-10 parts of polyethylene glycol fatty acid ester; 2-5 parts of epoxy soybean oil; butyryl 5-10 parts of tri-n-hexyl citrate; 2-5 parts of dibasic lead phosphite; 1-5 parts of zinc stannate; 2-6 parts of poly-fatty acid ester; 1-3 parts of paraffin; octadecyl tribromide 1-3 parts of ammonium; 3-8 parts of dibutyltin dialkyl maleate; 3-6 parts of boron fiber; 2-5 parts of nylon fiber; 1-3 parts of indium tin oxide.
  2. 根据权利要求1所述的PP-PE-PEN三基体树脂复合材料,其特征在于,所述PP-PE-PEN三基体树脂复合材料由以下组分的重量份组成:PP 80份;高密度PE 70份;PEN 90份;苯乙烯-乙烯-丁二烯-苯乙烯共聚物10份;乙烯-丙烯酸甲酯共聚物7份;乙烯-醋酸乙烯共聚物15份;氮化硅颗粒5份;氧化铝颗粒7份;偶氮二异庚腈2份;三氧化二锑4份;钛酸酯偶联剂2份;丙烯酸丁酯5份;二亚乙基三胺1份;三羟甲基丙烷三甲基丙烯酸酯0.5份;醋酸乙酯3份;氧化锰2份;氧化镁1份;氧化亚铜2份,四氧化三铁3份;碳化硅3份;聚乙二醇脂肪酸酯7份;环氧大豆油3份;丁酰柠檬酸三正己酯8份;二碱式亚磷酸铅3份;锡酸锌3份;聚脂肪酸酯4份;石蜡2份;十八烷基三溴化铵1份;二烷基马来酸二丁基锡6份;硼纤维4份;尼龙纤维2份;氧化铟锡2份。The PP-PE-PEN tri-matrix resin composite according to claim 1, wherein the PP-PE-PEN tri-matrix resin composite is composed of parts by weight of the following components: PP 80 parts; high density PE 70 parts; 90 parts of PEN; 10 parts of styrene-ethylene-butadiene-styrene copolymer; 7 parts of ethylene-methyl acrylate copolymer; 15 parts of ethylene-vinyl acetate copolymer; 5 parts of silicon nitride particles; oxidation 7 parts of aluminum particles; 2 parts of azobisisoheptanenitrile; 4 parts of antimony trioxide; 2 parts of titanate coupling agent; 5 parts of butyl acrylate; 1 part of diethylene triamine; trimethylolpropane 0.5 parts of trimethacrylate; 3 parts of ethyl acetate; 2 parts of manganese oxide; 1 part of magnesium oxide; 2 parts of cuprous oxide, 3 parts of triiron tetroxide; 3 parts of silicon carbide; Parts; epoxidized soybean oil 3 parts; butyryl citrate tri-n-hexyl ester 8 parts; dibasic lead phosphite 3 parts; zinc stannate 3 parts; poly fatty acid ester 4 parts; paraffin 2 parts; octadecyl three 1 part of ammonium bromide; 6 parts of dibutyltin dialkyl maleate; 4 parts of boron fiber; 2 parts of nylon fiber; 2 parts of indium tin oxide.
  3. 根据权利要求1所述的PP-PE-PEN三基体树脂复合材料,其特征在于,所述PP-PE-PEN三基体树脂复合材料由以下组分的重量份组成:PP 70份;高密度PE 80份;PEN 80份;苯乙烯-乙烯-丁二烯-苯乙烯共聚物6份;乙烯-丙烯酸甲酯共聚物9份;乙烯-醋酸乙烯共聚物17份;氮化硅颗粒4份;氧化铝颗粒6份;偶氮二异庚腈3份;三氧化二锑2份;钛酸酯偶联剂2份;丙烯酸丁酯6份;二亚乙基三胺0.5份;三羟甲基丙烷三甲基丙烯酸酯1份;醋酸乙酯2份;氧化锰2份;氧化镁3份;氧化亚铜3份,四氧化三铁5份;碳化硅3份;聚乙二醇脂肪酸酯9份;环氧大豆油4份;丁酰柠檬酸三正己酯8份;二碱式亚磷酸铅3份;锡酸锌2份;聚脂肪酸酯3份;石蜡3份;十八烷基三溴化铵1份;二烷基马来酸二丁基锡4份;硼纤维5份;尼龙纤维4份;氧化铟锡3份。 The PP-PE-PEN tri-matrix resin composite according to claim 1, wherein the PP-PE-PEN tri-base resin composite is composed of parts by weight of the following components: PP 70 parts; high density PE 80 parts; 80 parts of PEN; 6 parts of styrene-ethylene-butadiene-styrene copolymer; 9 parts of ethylene-methyl acrylate copolymer; 17 parts of ethylene-vinyl acetate copolymer; 4 parts of silicon nitride particles; oxidation 6 parts of aluminum particles; 3 parts of azobisisoheptanenitrile; 2 parts of antimony trioxide; 2 parts of titanate coupling agent; 6 parts of butyl acrylate; 0.5 parts of diethylene triamine; trimethylolpropane 1 part of trimethacrylate; 2 parts of ethyl acetate; 2 parts of manganese oxide; 3 parts of magnesium oxide; 3 parts of cuprous oxide, 5 parts of ferroferric oxide; 3 parts of silicon carbide; 4 parts; epoxy soybean oil 4 parts; butyryl citrate tri-n-hexyl ester 8 parts; dibasic lead phosphite 3 parts; zinc stannate 2 parts; poly fatty acid ester 3 parts; paraffin 3 parts; octadecyl three 1 part of ammonium bromide; 4 parts of dibutyltin dialkyl maleate; 5 parts of boron fiber; 4 parts of nylon fiber; 3 parts of indium tin oxide.
  4. 根据权利要求1所述的PP-PE-PEN三基体树脂复合材料,其特征在于,所述PP-PE-PEN三基体树脂复合材料由以下组分的重量份组成:PP 90份;高密度PE 60份;PEN 80份;苯乙烯-乙烯-丁二烯-苯乙烯共聚物12份;乙烯-丙烯酸甲酯共聚物6份;乙烯-醋酸乙烯共聚物12份;氮化硅颗粒8份;氧化铝颗粒9份;偶氮二异庚腈3份;三氧化二锑3份;钛酸酯偶联剂2份;丙烯酸丁酯4份;二亚乙基三胺2份;三羟甲基丙烷三甲基丙烯酸酯1份;醋酸乙酯2份;氧化锰3份;氧化镁2份;氧化亚铜2份,四氧化三铁4份;碳化硅2份;聚乙二醇脂肪酸酯6份;环氧大豆油4份;丁酰柠檬酸三正己酯6份;二碱式亚磷酸铅4份;锡酸锌4份;聚脂肪酸酯2份;石蜡3份;十八烷基三溴化铵3份;二烷基马来酸二丁基锡6份;硼纤维4份;尼龙纤维3份;氧化铟锡2份。The PP-PE-PEN tri-matrix resin composite according to claim 1, wherein the PP-PE-PEN tri-matrix resin composite is composed of parts by weight of the following components: PP 90 parts; high density PE 60 parts; 80 parts of PEN; 12 parts of styrene-ethylene-butadiene-styrene copolymer; 6 parts of ethylene-methyl acrylate copolymer; 12 parts of ethylene-vinyl acetate copolymer; 8 parts of silicon nitride particles; oxidation 9 parts of aluminum particles; 3 parts of azobisisoheptanenitrile; 3 parts of antimony trioxide; 2 parts of titanate coupling agent; 4 parts of butyl acrylate; 2 parts of diethylene triamine; trimethylolpropane 1 part of trimethacrylate; 2 parts of ethyl acetate; 3 parts of manganese oxide; 2 parts of magnesium oxide; 2 parts of cuprous oxide, 4 parts of ferroferric oxide; 2 parts of silicon carbide; Parts; epoxidized soybean oil 4 parts; butyryl citrate tri-n-hexyl ester 6 parts; dibasic lead phosphite 4 parts; zinc stannate 4 parts; poly-fatty acid ester 2 parts; paraffin 3 parts; octadecyl three 3 parts of ammonium bromide; 6 parts of dibutyltin dialkyl maleate; 4 parts of boron fiber; 3 parts of nylon fiber; 2 parts of indium tin oxide.
  5. 根据权利要求1所述的PP-PE-PEN三基体树脂复合材料,其特征在于,所述PP-PE-PEN三基体树脂复合材料由以下组分的重量份组成:PP 85份;高密度PE 70份;PEN 90份;苯乙烯-乙烯-丁二烯-苯乙烯共聚物9份;乙烯-丙烯酸甲酯共聚物7份;乙烯-醋酸乙烯共聚物12份;氮化硅颗粒5份;氧化铝颗粒9份;偶氮二异庚腈2份;三氧化二锑2份;钛酸酯偶联剂3份;丙烯酸丁酯5份;二亚乙基三胺0.5份;三羟甲基丙烷三甲基丙烯酸酯0.2份;醋酸乙酯4份;氧化锰3份;氧化镁4份;氧化亚铜2份,四氧化三铁2份;碳化硅3份;聚乙二醇脂肪酸酯7份;环氧大豆油3份;丁酰柠檬酸三正己酯7份;二碱式亚磷酸铅2份;锡酸锌5份;聚脂肪酸酯3份;石蜡2份;十八烷基三溴化铵2份;二烷基马来酸二丁基锡3份;硼纤维4份;尼龙纤维5份;氧化铟锡3份。 The PP-PE-PEN tri-matrix resin composite according to claim 1, wherein the PP-PE-PEN tri-matrix resin composite is composed of parts by weight of the following components: PP 85 parts; high density PE 70 parts; 90 parts of PEN; 9 parts of styrene-ethylene-butadiene-styrene copolymer; 7 parts of ethylene-methyl acrylate copolymer; 12 parts of ethylene-vinyl acetate copolymer; 5 parts of silicon nitride particles; oxidation 9 parts of aluminum particles; 2 parts of azobisisoheptanenitrile; 2 parts of antimony trioxide; 3 parts of titanate coupling agent; 5 parts of butyl acrylate; 0.5 parts of diethylene triamine; trimethylolpropane 0.2 parts of trimethacrylate; 4 parts of ethyl acetate; 3 parts of manganese oxide; 4 parts of magnesium oxide; 2 parts of cuprous oxide, 2 parts of ferroferric oxide; 3 parts of silicon carbide; Parts; epoxidized soybean oil 3 parts; butyryl citrate tri-n-hexyl ester 7 parts; dibasic lead phosphite 2 parts; zinc stannate 5 parts; poly-fatty acid ester 3 parts; paraffin 2 parts; octadecyl three 2 parts of ammonium bromide; 3 parts of dibutyltin dialkyl maleate; 4 parts of boron fiber; 5 parts of nylon fiber; 3 parts of indium tin oxide.
PCT/CN2017/116559 2017-11-22 2017-12-15 Pp-pe-pen three-matrix resin composite material WO2019100471A1 (en)

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CN103396658A (en) * 2013-07-11 2013-11-20 旭阳化学技术研究院有限公司 Polyethylene naphthalate resin composition and preparation method thereof
CN104927150A (en) * 2015-05-12 2015-09-23 天津金发新材料有限公司 Halogen-free flame-retardant polyethylene/polyester heat-shrinkable tube and preparation method thereof
CN105906908A (en) * 2016-05-06 2016-08-31 王泽陆 Degradable flame-retardant wood-plastic composite material and preparation method thereof

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103073854A (en) * 2012-08-22 2013-05-01 金发科技股份有限公司 Polyester composition, preparation method and applications thereof
CN103396658A (en) * 2013-07-11 2013-11-20 旭阳化学技术研究院有限公司 Polyethylene naphthalate resin composition and preparation method thereof
CN104927150A (en) * 2015-05-12 2015-09-23 天津金发新材料有限公司 Halogen-free flame-retardant polyethylene/polyester heat-shrinkable tube and preparation method thereof
CN105906908A (en) * 2016-05-06 2016-08-31 王泽陆 Degradable flame-retardant wood-plastic composite material and preparation method thereof

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