WO2019098608A2 - Oxidative hair dye composition - Google Patents

Abstract

The present invention relates to an oxidative hair dye composition and, more particularly, to an oxidative hair dye composition comprising a mixture of a higher aliphatic alcohol, a sorbitan-based surfactant and a glucose-based surfactant as active ingredients. The oxidative hair dye composition has significantly improved the pungent and unpleasant odor of ammonia.

Description

Oxidation type hair dye composition

More particularly, the present invention relates to an oxidation type hair dye composition comprising a mixture of a higher aliphatic alcohol, a sorbitan-based surfactant and a glucose-based surfactant as an active ingredient, Type hair dye composition.

In general, hair decolorizing agents and hair dyeing agents are oxidants of peroxides such as hydrogene peroxide, urea peroxide, and melamine phehydrate, which act to discolor hair. Ammonia is an effective activator that accelerates the action of these peroxides to discolor and dye hair, that is, the oxidative destruction of melanin, and increases the oxidation coupling ratio of the dye. In addition, the pH must be adjusted to the alkaline side for the hydrogen peroxide water to work effectively with hair bleach. This pH control effect can be achieved with other alkalis, but ammonia is the most preferred alkaline agent because it acts effectively on both activator effect and pH control effect, and can be easily removed after swelling of hair and dyeing. Because of this effect, ammonia is the most commonly used hair bleaching agent or hair dye.

Ammonia, which is a highly volatile alkaline agent, generates irritating odor peculiar to ammonia when mixed with the first agent and the second agent or applied to the hair, thereby causing eye irritation and skin irritation as well as a very unpleasant odor, .

Other organic / inorganic alkalis can be used as a means of alleviating the stimulation by ammonia, but since the dyeing effect does not reach ammonia, it may cause hair and scalp to increase scalp irritation and hair damage. So far, ammonia is the most universally used Lt; / RTI > Therefore, it is very important to reduce ammonia irritation.

In the prior art regarding ammonia deodorization (deodorizing), ammonia is chemically neutralized by mixing an appropriate acid-basic component to chemically neutralize the source of offensive odor, Eporion N7C is commercially available. However, when it is applied to a hair dye, the content of ammonia itself is reduced, thereby deteriorating the original purpose of using ammonia in the hair dye.

In addition, there has been proposed a sensory neutralization method in which deodorization is attempted by adding a common perfume material or a vegetable complex extract appropriately combined (see Patent Document 1: Korean Publication No. 2000-0025753) or peppermint oil as a natural essential oil, Although the ammonia content can be maintained in the hair dye, the deodorant effect is relatively weak, and the stability of the fragrance component, the vegetable extract component (vegetable complex extract), and the natural essential oil component in the cosmetic composition is seriously changed due to the extremely high basicity There has been a problem that when the cosmetic is stored or used for a long period of time, the effect of suppressing or reducing the irritation of ammonia and unpleasant odor (hereinafter, abbreviated as "deodorizing effect of ammonia odor") is deteriorated and the cosmetic is deteriorated.

[Prior Art Literature]

[Patent Literature]

Korean Patent Publication No. 2000-0025753 (published on May 6, 2000)

An object of the present invention is to provide an oxidative hair dye composition which is remarkably improved in irritating and unpleasant odor derived from an ammonia component incorporated in an oxidative hair dye composition.

The inventors of the present invention have intensively investigated a substance having excellent stimulating and unpleasant odor-evoking effects derived from the ammonia component blended in the hair dye composition and a combination thereof. As a result, it has been found that the high aliphatic alcohol, sorbitan series surfactant, It has been found that the addition of a mixture of glucose-based surfactants to a hair dye formulation containing ammonia (such as an aqueous ammonia solution) not only significantly improves the deodorizing effect of the ammonia odor but also maintains such deodorant effect for a prolonged period of time.

On the basis of this finding,

In an oxidized hair dye composition comprising a first agent and a second agent,

A material for generating ammonia as an alkaline agent in the first agent,

The present invention provides an oxidation type hair dye composition excellent in deodorization effect of ammonia odor, which comprises as an active ingredient, a mixture composed of a high-grade aliphatic alcohol, a sorbitan-based surfactant and a glucose-based surfactant.

Further, according to the present invention,

A first agent containing an oxidation dye precursor and a coupler, and a substance generating ammonia as an alkali agent; And a second agent containing an oxidizing agent, a combination of a higher aliphatic alcohol, a sorbitan-based surfactant and a glucose-based surfactant for improving the deodorizing effect against ammonia odor during use, and It provides its use.

The oxidation type hair dye composition according to the present invention is applicable to a hair dye cosmetic product having excellent deodorizing effect of ammonia odor and causing ammonia odor.

Unless otherwise defined, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this invention belongs. In general, the nomenclature used herein is well known and commonly used in the art.

Hereinafter, the present invention will be described in more detail.

As used herein, the term " about " used to describe length, area, volume, time (period), concentration, capacity (content etc.), temperature, etc. means that there is a maximum tolerance of 10% it means.

The present invention, in one aspect,

In an oxidized hair dye composition comprising a first agent and a second agent,

A material for generating ammonia as an alkaline agent in the first agent,

A high aliphatic alcohol, a sorbitan-based surfactant, and a glucose-based surfactant as an active ingredient.

In the present invention, the first agent may further contain a conventional oxidation dye precursor and a coupler, preferably two or more oxidation dye precursors and couplers, and may contain most of the oxidation dye precursors and couplers presently known have.

The type of the oxidation dye precursor is not particularly limited, and examples thereof include o-aminophenol, p-aminophenol, m-aminophenol, p-phenylenediamine, toluene-2,5-diamine hydrochloride, , Toluene-2,5-diamine, p-phenylenediamine sulfate, p-methylaminophenol sulfate, o-aminophenol sulfate, p-aminophenol sulfate, toluene-2,5-diamine sulfate, , And the oxidation dye precursor is used in an amount of 0.001 to 5.0% by weight based on the total weight of the first composition.

As the coupler, there may be mentioned 2-methyl-5-hydroxyethylaminophenol, p-amino-ocresol, m-aminophenol, 2,4-diaminophenoxyethanol hydrochloride, m- m-phenylenediamine,? -naphthol, resorcinol, 2-methylresorcinol, etc., and the coupler is used in an amount of 0.001 to 5.0% by weight based on the total weight of the first composition, And can be used in combination with the oxidation dye precursor to exhibit various hues on the hair.

The direct dye may be added to the oxidative dye composition of the present invention to the extent that it does not impair the object of the present invention. Examples of such direct dyes include Arianol dye, p- Nitro-phenylenediamine, nitro-p-phenylenediamine, 2-amino-4-nitrophenol, 2-amino-5-nitrophenol, nitro-p-phenylenediamine hydrochloride, Henna and the like can be used.

In addition, the oxidizing type hair dye composition of the present invention can be used within a range that does not impair the effect of the present invention. For example, antioxidants, metal sequestrants, solvents, surfactants, thickeners, perfumes, and conditioning agents are used, but they are not particularly limited as they can be commonly used in hair dyeing agents.

The metal blockade agent may not contain the metal salt in the composition of the present invention or may contain a very small amount because the metal salt is deteriorated in reactivity. Examples of the metal sequestering agent include EDTA, disodium iodide, tetrasodium-idtite, pentasodium pentitate, etidronic acid, and salts thereof.

Examples of the antioxidant include ascorbic acid, erythorbic acid, cysteine hydrochloride, sodium sulfite and thioglycolic acid. Examples of the solvent include ethanol, propyl alcohol, isopropyl alcohol, propylene glycol, hexylene glycol, diethylene glycol As the surfactant, a cationic surfactant, an anionic surfactant or a nonionic surfactant can be used. As the thickener, a higher alcohol having 14 to 22 carbon atoms can be used singly or as a mixture. Nonionic Polymer and anionic polymer, paraffin, light flowing isoparaffin and the like can be used. As the conditioning agent, a cationic polymer, quaternary ammonium salt, silicon or the like can be used.

Next, components of the second agent of the oxidative salt hair dye composition of the present invention will be described.

The second agent contains an oxidizing agent. As the oxidizing agent, at least one selected from the group consisting of hydrogen peroxide, peroxide element, alkali metal bromate, pericyanide, perborate and persulfate commonly used in the oxidizing type hair dye composition , And it is particularly preferable to contain hydrogen peroxide.

The oxidizing agent may be used in an amount of usually 0.1 to 10.0% by weight based on the total weight of the second composition.

The second component of the present invention can also be used within the range that does not impair the effect of the present invention. For example, emulsions such as paraffin, hard flowing isoparaffin, higher fatty alcohol and higher fatty acid ester, cationic or nonionic surfactants, stabilizers such as phenacetin, and pH adjusters such as phosphoric acid.

The first agent and the second agent of the oxidative salt hair dye composition according to the present invention usually contain water in addition to the above-mentioned components. As the water, it is preferable to use purified water such as ion-exchanged water and distilled water, and the content thereof is not particularly limited, and it may be any amount that sufficiently dissolves or disperses each component used in the hair dye composition.

The oxidative hair dye composition according to the present invention is used by mixing a first agent and a second agent immediately before applying to the hair. In this case, although not particularly limited, it is preferable that the first agent and the second agent are mixed in a weight ratio of usually 1: 1 to 1: 2, more preferably in a range of 1: 1 Can be mixed and used.

When the ratio of the first agent is lowered when the ratio of the first agent and the second agent is decreased, the amount of the dye is decreased, the amount of dye penetrated into the hair is decreased and the coloring power is decreased. When the ratio of the second agent is increased, The addition reaction takes place, and the lower the ratio, the slower the reaction rate becomes.

As a method of hair dyeing using the oxidative hair dye composition according to the present invention, there is a method of preparing an oxidized hair dye by mixing the first and second agents, applying the oxidized hair dye to the hair, and washing the hair after a predetermined time And a conventional hair dyeing method.

In the present invention, the higher aliphatic alcohol may be at least one selected from the group consisting of Cetyl Alcohol, Stearyl Alcohol, Cetearyl Alcohol and Behenyl Alcohol, And is preferably a cetearyl alcohol.

In the present invention, the sorbitan-based surfactant may be at least one selected from the group consisting of cetearyl olivate / sorbitan olivate, sorbitan sesquioleate and sorbitan stearate / sorbityl laurate, May be characterized by being a mixture of cetearyl olivate / sorbitan olivate.

In the present invention, the glucose-based surfactant is selected from the group consisting of C12-20 alkyl glucoside, C14-22 alcohol / C12-20 alkyl glucoside, cetearyl alcohol / cetearyl glucoside and arachidyl alcohol / behenyl alcohol / arachidyl glucoside , Preferably at least one selected from the group consisting of C12-20 alkyl glucoside.

In the present invention, the mixture is preferably present in an amount of from 10: 0.1 to 4.8: 1, preferably from 10: 1 to 4: 1, most preferably from 10: 1 to 4: 1 by weight, based on the weight of the higher aliphatic alcohol, the sorbitan surfactant and the glucose surfactant. By weight, and a mixing ratio of 10: 1.5 to 3: 1.

In the present invention, the content of the higher aliphatic alcohol is 0.1 to 15% by weight, preferably 5 to 15% by weight, and most preferably 8 to 12% by weight, based on the total weight of the first agent. If the content of the higher aliphatic alcohol is less than 0.1% by weight based on the total weight of the first agent, the deodorizing effect of the ammonia odor is insignificant. When the content of the higher aliphatic alcohol is higher than 15% by weight, And may lower the stability of the formulation and the feeling of use.

In the present invention, the content of the sorbitan-based surfactant is 0.1 to 15% by weight, preferably 0.8 to 5.0% by weight, and most preferably 1.0 to 4.0% by weight, based on the total weight of the first agent If the content of the surfactant of the sorbitan series is less than 0.1% by weight based on the total weight of the first agent, the deodorizing effect of the ammonia odor is insignificant. When the content of the surfactant exceeds 15% by weight, The increase of the effect is not so large, and the stability and feeling of use of the composition may be lowered.

In the present invention, the content of the glucose-based surfactant is 0.1 to 15% by weight, preferably 0.1 to 5% by weight, and most preferably 0.5 to 1.5% by weight, based on the total weight of the first agent If the amount of the glucose-based surfactant is less than 0.1% by weight based on the total weight of the first agent, the deodorizing effect of the ammonia odor is insignificant. When the content of the surfactant exceeds 15% by weight, The stability of the formulation and feeling of use can be reduced.

In the present invention, the ammonia content of the ammonia-generating material may be 0.1 to 10% by weight, preferably 2 to 8% by weight based on the total weight of the first agent, If the ammonia content of the material is less than 0.1% by weight based on the total weight of the first agent, the hair dyeing / bleaching effect of the hair is insignificant. If the ammonia content exceeds 10% by weight, The feeling of use may be lowered.

In the present invention, the substance generating ammonia may be aqueous ammonia solution, preferably 28% w / w ammonia water, but is not limited thereto.

In the present invention, the composition may be characterized by containing conventional carriers and additives known in the art. For example, conventional cosmetic ingredients may be contained according to cosmetic formulation.

In the present invention, the composition may be characterized by reducing the feeling of scalp stimulation and hair damage.

Hereinafter, the present invention will be described in more detail with reference to Examples. It is to be understood by those skilled in the art that these examples are for illustrative purposes only and that the scope of the present invention is not construed as being limited by these examples.

[Preparation Example 1] Preparation of the first agent and the second agent of the hair dye composition

Using the components and contents of Tables 1 to 3 below, a conventional ammonia-type permanent hair dye first agent was prepared according to a manufacturing method commonly known in the art.

The first hair dye preparation agents of Examples 1 to 6 and Comparative Examples 1 to 9 and the second hair dye preparation agent were prepared in the compositions of Tables 1 to 3 and Table 4, respectively.

Tables 1 to 3 below show the hair dye first agent (unit: wt%).

Configuration	Hair dye first agent	Example 1	Example 2	Example 3	Example 4	Example 5
Awards	Erysorbic acid	0.5	0.5	0.5	0.5	0.5
Awards	Sodium pyrosulfite	0.5	0.5	0.5	0.5	0.5
Awards	PPD	3.0	3.0	3.0	3.0	3.0
Awards	m-Aminophenol	0.5	0.5	0.5	0.5	0.5
Awards	Resorcinol	2.5	2.5	2.5	2.5	2.5
Paid	Cetyl alcohol	-	-	-	-	10.0
Paid	Stearyl alcohol	-	-	-	-	-
Paid	Cetearyl alcohol	10.0	10.0	10.0	10.0	-
Paid	Polyoxyethylene stearyl ether	1.0	1.0	1.0	1.0	1.0
Paid	Cetearyl Olivate * Sorbitan Olivate	1.5	2.0	2.5	3.0	2.0
Awards	C12-20 alkyl glucoside	1.0	1.0	1.0	1.0	1.0
Awards	ammonia	8.0	8.0	8.0	8.0	8.0
Awards	Purified water	Balance	Balance	Balance	Balance	Balance

Configuration	Hair dye first agent	Example 6	Comparative Example 1	Comparative Example 2	Comparative Example 3	Comparative Example 4
Awards	Erysorbic acid	0.5	0.5	0.5	0.5	0.5
Awards	Sodium pyrosulfite	0.5	0.5	0.5	0.5	0.5
Awards	PPD	3.0	3.0	3.0	3.0	3.0
Awards	m-Aminophenol	0.5	0.5	0.5	0.5	0.5
Awards	Resorcinol	2.5	2.5	2.5	2.5	2.5
Paid	Cetyl alcohol	-	10.0	10.0	-	-
Paid	Stearyl alcohol	10.0	-	-	-	-
Paid	Cetearyl alcohol	-	-	-	10.0	10.0
Paid	Polyoxyethylene stearyl ether	1.0	1.0	1.0	1.0	1.0
Paid	Cetearyl Olivate * Sorbitan Olivate	2.0	5.0	2.0	5.0	2.0
Awards	C12-20 alkyl glucoside	1.0	1.0	5.0	1.0	5.0
Awards	ammonia	8.0	8.0	8.0	8.0	8.0
Awards	Purified water	Balance	Balance	Balance	Balance	Balance

Configuration	Hair dye first agent	Comparative Example 5	Comparative Example 6	Comparative Example 7	Comparative Example 8	Comparative Example 9
Awards	Erysorbic acid	0.5	0.5	0.5	0.5	0.5
Awards	Sodium pyrosulfite	0.5	0.5	0.5	0.5	0.5
Awards	PPD	3.0	3.0	3.0	3.0	3.0
Awards	m-Aminophenol	0.5	0.5	0.5	0.5	0.5
Awards	Resorcinol	2.5	2.5	2.5	2.5	2.5
Paid	Cetyl alcohol	-	-	-	-	-
Paid	Stearyl alcohol	-	-	-	-	-
Paid	Cetearyl alcohol	10.0	10.0	10.0	10.0	10.0
Paid	Polyoxyethylene stearyl ether	1.0	1.0	1.0	1.0	1.0
Paid	Cetearyl Olivate * Sorbitan Olivate	0.5	2.0	-	2.0	3.0
Awards	C12-20 alkyl glucoside	5.0	-	1.0	5.0	1.0
Awards	ammonia	8.0	8.0	8.0	12.0	12.0
Awards	Purified water	Balance	Balance	Balance	Balance	Balance

According to the composition ratios shown in Tables 1 to 3, the water phase can be purified water, an antioxidant (erythorbic acid), a reducing agent (sodium pyrosulfite), PPD (p-phenylene diamine) Sorcinol) was added and dissolved by heating to about 75 ° C. As the oil phase, cetyl alcohol, stearyl alcohol or cetearyl alcohol, polyoxyethylene stearyl ether, cetearyl olivate / sorbitan olivate were added and dissolved by heating to about 75 ° C. Then, the oil phase and water phase were mixed and emulsified, and after cooling to about 55 ° C, the final concentration of C12-20 alkyl glucoside and ammonia (ammonia was 8.0 wt% or 12.0 wt% based on the total weight of the hair dye preparation 1 Ammonia water (28% w / w) was added thereto to prepare a hair dye preparation. Table 4 below shows the hair dye second agent (unit: wt%).

Configuration	Hair dye second agent
Awards	Disodium iodide	0.2
Awards	Phosphoric acid	Suitable amount
Paid	Cetearyl alcohol	5.0
Paid	Polyoxyethylene stearyl ether	1.0
Paid	Polyoxyethylene < / RTI >	0.5
Awards	Hydrogen peroxide water	5.9
Awards	Purified water	Balance

The hair dye second agent (oxidizing agent) was prepared by dissolving cetearyl alcohol, polyoxyethylene stearyl ether and polyoxyethylene sarcoyl ether in an oil state at about 75 ° C according to the composition ratios shown in Table 4, Dithia and purified water were dissolved by heating to about 75 ° C to emulsify the water phase and the oil phase at the same temperature and cooled to about 55 ° C to obtain a final concentration of phosphoric acid and hydrogen peroxide (35% w / w) was used so as to have a concentration of 5.9% by weight), and the mixture was uniformly mixed and stirred to prepare a hair dye-forming agent.

[ Test Example  One] Detector tube  exam

The oxidative hair dye composition prepared by mixing 30 g of the hair dye preparation 1 prepared in Preparation Example 1 and 30 g of the hair dye formulation 2 was placed in a 500 ml flask and left at room temperature for about 30 minutes. Then, a detector tube for detecting ammonia (GASTEC No. 3HM Ammonia, GASTEC) was connected to the flask and a pump was operated to suck ammonia generated from the oxidative hair dyeing composition. The scale of the changed color was read and the amount of ammonia generated from the oxidation type hair dye composition was measured.

As a result, as shown in the following Tables 5 to 7, it was confirmed that a high aliphatic alcohol (cetyl alcohol, stearyl alcohol or cetearyl alcohol), a sorbitan surfactant (cetearyl olivate / sorbitan olivate) (C12-20 alkyl glucoside) were mixed in a weight ratio of 10: 1.5: 1 to 10: 3: 1 to form a hair dye preparation (Forms 1 to 6) 1 < tb > < tb > < tb > < tb > < / TABLE > In particular, it was confirmed that the amount of ammonia generated was lowest when the higher aliphatic alcohol contained in the oxidation type hair dye composition was cetearyl alcohol (Formulation Examples 1 to 4).

On the other hand, when the mixing ratio of the higher aliphatic alcohol: sorbitan surfactant: glucosurfactant = 10: 1 to 3: 1 was not satisfied (Comparative Formulation Examples 1 to 7), the amount of ammonia produced was high. In addition, it was confirmed that the amount of ammonia generated in the oxidation type hair dye composition is also very high when the content of ammonia exceeds 10% by weight based on the total weight of the hair dye formulation (Comparative Formulations 8 to 9).

Tables 5 to 7 show the amounts of ammonia generated by NH ₃ detection tube measurement.

		Formulation Example 1	Formulation Example 2	Formulation Example 3	Formulation Example 4	Formulation Example 5
Combination of hair dye (first agent: second agent = 1: 1)	The first agent	Example 1	Example 2	Example 3	Example 4	Example 5
	Second article	Table 4 < tb > <
NH 3 detection tube measurement value		0.55	0.55	0.55	0.55	0.58

		Formulation Example 6	Comparative Formulation Example 1	Comparative Formulation Example 2	Comparative Formulation Example 3	Comparative Formulation Example 4
Combination of hair dye (first agent: second agent = 1: 1)	The first agent	Example 6	Comparative Example 1	Comparative Example 2	Comparative Example 3	Comparative Example 4
	Second article	Table 4 < tb > <
NH 3 detection tube measurement value		0.58	0.75	0.73	0.71	0.70

		Comparative Formulation Example 5	Comparative Formulation Example 6	Comparative Formulation Example 7	Comparative Formulation Example 8	Comparative Formulation Example 9
Combination of hair dye formulation ((first agent: second agent = 1: 1))	The first agent	Comparative Example 5	Comparative Example 6	Comparative Example 7	Comparative Example 8	Comparative Example 9
	Second article	Table 4 < tb > <
NH 3 detection tube measurement value		0.72	0.65	0.65	1.35	1.35

[ Test Example  2] Sensory evaluation

The evaluation of the deodorizing effect on the ammonia odor of the oxidative dyeing composition prepared by mixing 30 g of the hair dyeing agent 1 prepared in Preparation Example 1 and 30 g of the hair dyeing agent 2 was carried out through 15 sensory evaluation specialists Next, the average score was calculated by the 10 point scaling method.

Table 8 below shows the sensory evaluation criteria.

Rating	Degree of detection of ammonia odor
0	Odorless (completely deodorized)
1.0 to 2.0	Minimal detection of ammonia odor
2.1 to 4.0	Detect ammonia slightly weakly
4.1 to 5.0	Weak detection of ammonia odor
5.1 to 6.0	Detect ammonia properly
6.1 ~ 7.0	Strongly detect ammonia odor
7.1 to 10	Very strong detection of Aromonychia (feeling spicy and irritated)

 As a result, as shown in the following Tables 9 to 11, it was confirmed that a high aliphatic alcohol (cetyl alcohol, stearyl alcohol or cetearyl alcohol), a sorbitan surfactant (cetearyl olivate / sorbitan olivate) (C12-20 alkyl glucoside) were mixed in a weight ratio of 10: 1.5: 1 to 10: 3: 1 to form a hair dye preparation (Forms 1 to 6) 1 < tb > < tb > < tb > < tb > < tb > In particular, when the higher aliphatic alcohol contained in the oxidative salt hair dye composition was cetearyl alcohol (Formulation Examples 1 to 4), it was confirmed that the ammonia adsorption strength was the lowest.

On the other hand, when the mixing ratio of the higher aliphatic alcohol: sorbitan surfactant: glucose surfactant = 10: 1 to 3: 1 was not satisfied (Comparative Formulation Examples 1 to 7), the ammonia tear strength was high. In addition, it was confirmed that the ammonia wicking strength is also very high when the content of ammonia contained in the oxidation type hair dyeing composition exceeds 10% by weight based on the total weight of the hair dyeing agent (Comparative Formulations 8 to 9) .

The following Tables 9 to 11 show the results of sensory evaluation of the ammonia tear strength.

	Formulation Example 1	Formulation Example 2	Formulation Example 3	Formulation Example 4	Formulation Example 5
Stimulus intensity evaluation	5.0	5.0	5.0	5.0	5.5
Improvement of feeling (comfort) by reduction of irritant odor	Great	Great	Great	Great	usually

	Formulation Example 6	Comparative Formulation Example 1	Comparative Formulation Example 2	Comparative Formulation Example 3	Comparative Formulation Example 4
Stimulus intensity evaluation	5.5	9.1	8.9	8.7	8.6
Improvement of feeling (comfort) by reduction of irritant odor	usually	Very low	Very low	Very low	Very low

	Comparative Formulation Example 5	Comparative Formulation Example 6	Comparative Formulation Example 7	Comparative Formulation Example 8	Comparative Formulation Example 9
Stimulus intensity evaluation	8.8	6.5	6.5	10	10
Improvement of feeling (comfort) by reduction of irritant odor	Very low	lowness	lowness	Very low	Very low

While the present invention has been particularly shown and described with reference to specific embodiments thereof, those skilled in the art will appreciate that such specific embodiments are merely preferred embodiments and that the scope of the present invention is not limited thereby. something to do. It is therefore intended that the scope of the invention be defined by the claims appended hereto and their equivalents.

Claims (10)

1. In an oxidized hair dye composition comprising a first agent and a second agent,

   A material for generating ammonia as an alkaline agent in the first agent,

   A high aliphatic alcohol, a sorbitan-based surfactant, and a glucose-based surfactant as an active ingredient.
2. The oxidation dyeing composition according to claim 1, wherein the higher aliphatic alcohol is at least one selected from the group consisting of cetyl alcohol, stearyl alcohol, cetearyl alcohol and behenyl alcohol.
3. The surfactant according to claim 1, wherein the sorbitan-based surfactant is at least one selected from the group consisting of cetearyl olivate / sorbitan olivate, sorbitan sesquioleate and sorbitan stearate / sorbitol laurate ≪ / RTI >
4. The method of claim 1, wherein the glucose-based surfactant is selected from the group consisting of C12-20 alkyl glucoside, C14-22 alcohol / C12-20 alkyl glucoside, cetearyl alcohol / cetearyl glucoside and arachidyl alcohol / behenyl alcohol / arachidyl Glucoside, or a pharmaceutically acceptable salt thereof.
5. The composition according to claim 1, wherein the mixture is a mixture of a high-grade aliphatic alcohol, a sorbitan-based surfactant and a glucose-based surfactant on a weight basis at a combination ratio of 10: 0.1 to 4.8: Composition.
6. The oxidation dyeing composition according to claim 1, wherein the content of the higher aliphatic alcohol is 0.1 to 15% by weight, based on the total weight of the first agent.
7. The oxidation dyeing composition according to claim 1, wherein the content of the sorbitan-based surfactant is 0.1 to 15% by weight, based on the total weight of the first agent.
8. The oxidation dyeing composition according to claim 1, wherein the content of the glucose-based surfactant is 0.1 to 15% by weight based on the total weight of the first agent.
9. 2. The oxidation hair dyeing composition according to claim 1, wherein the content of the ammonia-generating material is 0.1 to 10% by weight based on the total weight of the first agent.
10. The oxidative hair dyeing composition of claim 1, wherein the composition reduces the sensation of scalp irritation and hair damage.